# 
#  This database corresponds to the PHREEQCi version of the
#  ThermoChimie v.7.b, developed by Amphos 21, BRGM and HydrAsa for
#  ANDRA, the French National Radioactive Waste Management Agency.The
#  data selection process includes a compilation of the thermodynamic
#  data reported in previous databases such as SUPCRT92, NBS (Wagman,
#  D.D., Evans, W.H., Parker, V.B., Schumm, R.H., Halow, I., Bailey,
#  S.M.,Churney, K.L., Nuttall, R.L., (1982), The NBS tables of
#  chemical thermodynamic properties, selected values for inorganic
#  and c1 and c2 organic substances in SI units. J. Phys. Chem. Ref.
#  Data, V. 11, supp. 2, 392p), USGS Database (Robie R.A., and
#  Hemingway B.S., 1995. Thermodynamic properties of minerals and
#  related substances at 298.15 K and 1 Bar (105 Pascals) pressure
#  and at higher temperatures. U.S. Geol. Survey Bull., 2131, 461 p)
#  for major elements and the IAEA (Fuger J., Oetting F.L. The
#  Chemical thermodynamics of actinide elements and compounds: Part
#  I. The actinide aqueous ions, IAEA Vienna, 1976, 65pp.). Special
#  review efforts are focused on elements of interest for radioactive
#  waste management: Rb; Cs; Ba; Ra; B; Sn; Pb; Sb; Se; Zr; Hf; Nb;
#  Mo; Mn; Tc; Fe; Co; Ni; Pd; Ag; Cd; Sm; Eu; Ho; Th; Pa; U; Np; Pu;
#  Am; Cm; (Main data sources for U, Np, Pu, Am, Se, Ni and Zr and
#  auxiliary species are the OECD NEA TDB Project compilations. The
#  specific ionic theory for activity corrections has been used in
#  the derivation of the stability constants when possible.
# 
# Grenthe, I., Fuger, J., Konings, R.J.M., Lemire, R.J., Muller,
# A.B., Nguyen-Trung, C., Wanner, H. (1992): Chemical Thermodynamics
# 1; Chemical Thermodynamics of Uranium. NEA OECD, Elsevier;
# 
# Lemire, R.J., Fuger, J., Nitsche, H., Potter, P., Rand, M.H.,
# Rydberg, J., Spahiu, K., Sullivan, J.C., Ullman, W.J., Vitorge, P.,
# Wanner, H. (2001) Chemical Thermodynamics 4. Chemical
# thermodynamics of neptunium and plutonium. NEA OECD, Elsevier;
# 
# Guillaumont, R., Fanghänel, J., Neck, V., Fuger, J., Palmer, D.A.,
# Grenthe, I., Rand, M.H. (2003) Chemical Thermodynamics 5. Update on
# the Chemical Thermodynamics of Uranium, Neptunium, Plutonium,
# Americium and Technetium. NEA OECD, Elsevier;
# 
# Brown, P., Curti, E., Grambow, B. (with a collaboration from
# Ekberg, C.) (2005) Chemical Thermodynamics 8. Chemical
# Thermodynamics of Zirconium. NEA Data bank, OECD. North Holland
# Elsevier Science Publishers B.V., Amsterdam, Netherlands;
# 
# Hummel, W., Anderegg, G., Rao, L., Puigdomènech, I., Tochiyama, O.,
# (2005). Chemical Thermodynamics 9: Chemical Thermodynamics of
# Compounds and Complexes of U, Np, Pu, Am, Tc, Se, Ni and Zr with
# Selected Organic Ligands. NEA OECD. Elsevier.
# 
# Gamsjäger, H., Bugajski, J., Gajda, T., Lemire, R.J. and Preis, W.
# (2005). Chemical Thermodynamics 6: Chemical Thermodynamics of
# Nickel. NEA OECD, Elsevier
# 
# Olin, A., Noläng, B., Osadchii, E.G., Öhman, L.O. and Rosén, E.
# (2005). Chemical Thermodynamics 7: Chemical Thermodynamics of
# Selenium. NEA OECD, Elsevier
# 
# Rand, M. H., J. Fuger, I. Grenthe, V. Neck and D. Rai.  2009.
# Chemical Thermodynamics of Thorium. Chemical Thermodynamics 11. NEA
# OECD.  Issy-les- Moulineaux, France
# 
# SIT coefficients have been implemented in the Thermochimie data
# base, following two purposes:
# 
# - Ensure and make comprehensive the data selection with
# respect to species activity calculations, from the literature
# survey up to the extrapolation at the standard state. NEA TDB
# guidelines are currently applied here for consistency with the
# recommended values from this project; 
#
# - Give relevant data sets for numerical applications under high
# ionic strength conditions. Modelling exercises are addressed to
# natural systems or material behaviour, which require large number of
# chemical equilibria. It is then needed to complete thermodynamic
# functions and SIT coefficients, in comparison to data sets available
# in literature.
#  
# Data gaps for estabilty, entropy/enthalpy and SIT coefficients have
# been filled in by estimations. More detailed information about some
# of the methodologies used for data estimation can be found in the
# following references. Three main estimation methods have been
# followed for SIT interaction coefficients: a) by analogy to similar
# compounds, b) by correlation with "epsilon" of the same complex but
# with other ionic media (nitrate or perchlorate) and c) by using the
# approach of (Ciavatta, L.. (1990) The specific interaction theory
# in equilibrium analysis. Some empirical rules for estimating
# interaction coefficients of metal ion complexes. Annali di Chimica,
# 80, 255-263).
# 
# Bruno, J., Duro, L., Cera, E., Grivé, M., El Aamrani, F., Rovira,
# M. (2001) Revision of the ThermoChimie Thermodynamic Database for
# radioelements. Version A. ANDRA report C.RP. 0ENQ.01.002 211 pp.
# 
# Duro, L., Cera, E. And Bruno, J. (2002) Revision of the
# thermodynamic database for radioelements. Version B. Final report.
# ANDRA report C.RP.0ENQ.02-001. 352 pp.
# 
# Duro, L., Cera, E., Grivé, M., Domènech, C., Gaona, X. and Bruno,
# J. (2006) Development of the ThermoChimie thermodynamic database.
# Janvier 2006. ANDRA report C.RP.0ENQ.06.0001. 373 pp.
# 
# Colàs, E., Montoya, V., Gaona, X., Domènech, C., Grivé, M. and
# Duro, L. (2007) Development of ThermoChimie data base. Version 6.
# up-date. ANDRA report D.RP.0ENQ.07.0001. 362 pp.
# 
# Montoya, V., Tamayo, A, Gaona, X, Grivé, M and Duro, L. (2008)
# Update of the ThermoChimie database. Reporting of new data
# selection 2007 Project ANDRA-TDB6-Task 1. Amphos 21 Progress Report
# vs.01.
# 
# Gaona X., Tamayo A., Grivé M., Duro L. Review and assessment of
# enthalpy data: procedures for data estimation and final data
# selection for aqueous species. June 2008. Project ANDRA-TDB6-
# Task2.
# 
# Duro L, Grivé M., Gaona X., Tamayo A (2009). Review and assessment
# of enthalpy data: procedures for data estimation and final data
# selection for solid compounds. December 2009. Project ANDRA- TDB6-
# Task2. v01. Amphos 21 internal report.
# 
# Grivé M., Riba O., Montoya V. and Duro L. (2009) Update of the
# ThermoChimie database: Reporting of new data selection 2009.
# November 2009 Project ANDRA-TDB6-Task1.
# 
# Gaona X., Montoya V., Colàs E., Grivé M., Duro L.. (2008) Review of
# the complexation of tetravalent actinides by ISA and gluconate
# under alkaline to hyperalkaline conditions. Journal of Contaminant
# Hydrology 102 (2008) 217–227.
# 
# Blanc, P., Piantone, P., Lassin, A., Burnol, A. (2006) ThemoChimie:
# Sélection de constantes thermodynamiques pour les éléments
# majeours, le plom et le cadmium. ANDRA report C RP PSTR.07.0014
# 
# This version has to be periodically up-dated and tested. Kindly
# send comments or corrections to thermochimie@amphos21.com
SOLUTION_MASTER_SPECIES

#element      species       alk           gfw_formula   element_gfw
Ag            Ag+            0            Ag             107.8682 
Al            Al+3           0            Al             26.9815 
Alkalinity    CO3-2          1            Ca0.5(CO3)0.5  50.05 
Am            Am+3           0            Am             243 
Am(+2)        Am+2           0            Am             243 
Am(+3)        Am+3           0            Am             243 
Am(+4)        Am+4           0            Am             243 
Am(+5)        AmO2+          0            Am             243 
Am(+6)        AmO2+2         0            Am             243 
As            AsO4-3         0            As             74.9216 
B             B(OH)4-        0            B              10.811 
Ba            Ba+2           0            Ba             137.327 
Br            Br-            0            Br             79.904 
C             CO3-2          2            CO3            12.011 
C(+4)         CO3-2          2            CO3            12.011 
C(-4)         CH4            0            CH4            12.011 
Ca            Ca+2           0            Ca             40.078 
Cd            Cd+2           0            Cd             112.411 
Cit           Cit-3          0            Cit            189.1013 
Cl            Cl-            0            Cl             35.4527 
Cm            Cm+3           0            Cm             247 
Cn            Cn-            0            Cn             26.018 
Co            Co+2           0            Co             58.9332 
Cr            CrO4-2         0            CrO4           51.9961 
Cr(+2)        Cr+2           0            Cr             51.9961 
Cr(+3)        Cr+3           0            Cr             51.9961 
Cr(+6)        CrO4-2         0            CrO4           51.9961 
Cs            Cs+            0            Cs             132.9054 
Cu            Cu+2           0            Cu             63.546 
Cu(+1)        Cu+            0            Cu             63.546 
Cu(+2)        Cu+2           0            Cu             63.546 
E             e-             0                           0 
Edta          Edta-4         0            Edta           288.2134 
Eu            Eu+3           0            Eu             151.965 
Eu(+2)        Eu+2           0            Eu             151.965 
Eu(+3)        Eu+3           0            Eu             151.965 
F             F-             0            F              18.9984 
Fe            Fe+2           0            Fe             55.847 
Fe(+2)        Fe+2           0            Fe             55.847 
Fe(+3)        Fe+3           0            Fe             55.847 
Glu           HGlu-          0            Glu            195.1459 
H             H+            -1            H              1.0079 
H(+1)         H+            -1            H              1.0079 
H(0)          H2             0            H              1.0079 
Hf            Hf+4           0            Hf             178.49 
Hg            Hg+2           0            Hg             200.59 
Hg(+2)        Hg+2           0            Hg             200.59 
Hg2(+2)       Hg2+2          0            Hg2            401.18 
Ho            Ho+3           0            Ho             164.9303 
I             I-             0            I              126.9045 
I(+5)         IO3-           0            I              126.9045 
I(-1)         I-             0            I              126.9045 
Isa           HIsa-          0            HIsa           180.1548 
K             K+             0            K              39.0983 
Li            Li+            0            Li             6.941 
Mg            Mg+2           0            Mg             24.305 
Mn            Mn+2           0            Mn             54.938 
Mo            MoO4-2         0            Mo             95.94 
N             NO3-           0            N              14.0067 
N(+5)         NO3-           0            N              14.0067 
N(-3)         NH3            1            N              14.0067 
Na            Na+            0            Na             22.9898 
Nb            Nb(OH)6-       0            Nb             92.9064 
Ni            Ni+2           0            Ni             58.69 
Np            NpO2+2         0            Np             237.048 
Np(+3)        Np+3           0            Np             237.048 
Np(+4)        Np+4           0            Np             237.048 
Np(+5)        NpO2+          0            Np             237.048 
Np(+6)        NpO2+2         0            Np             237.048 
Nta           Nta-3          0            Nta            188.1165 
O             H2O            0            O              15.999 
O(0)          O2             0            O              15.9994 
O(-2)         H2O            0            O              15.9994 
Ox            Ox-2           0            Ox             88.0196 
P             H2(PO4)-       1            P              30.9738 
Pa            Pa+4           0            Pa             231.0359 
Pa(+4)        Pa+4           0            Pa             231.0359 
Pa(+5)        PaO2+          0            Pa             231.0359 
Pb            Pb+2           0            Pb             207.2 
Pd            Pd+2           0            Pd             106.42 
Pu            PuO2+2         0            Pu             244 
Pu(+3)        Pu+3           0            Pu             244 
Pu(+4)        Pu+4           0            Pu             244 
Pu(+5)        PuO2+          0            Pu             244 
Pu(+6)        PuO2+2         0            Pu             244 
Pyrophos      Pyrophos-4     0            Pyrophos       173.95 
Ra            Ra+2           0            Ra             226.025 
Rb            Rb+            0            Rb             85.4678 
S             SO4-2          0            SO4            32.066 
S(+2)         S2O3-2         0            S              32.066 
S(+3)         S2O4-2         0            S2O4-2         128.128 
S(+4)         SO3-2          0            S              32.066 
S(+6)         SO4-2          0            SO4            32.066 
S(-2)         HS-            1            S              32.066 
Sb            Sb(OH)3        0            Sb             121.76 
Sb(+3)        Sb(OH)3        0            Sb             121.76 
Sb(+5)        Sb(OH)5        0            Sb             121.76 
Scn           Scn-           0            Scn            58.084 
Se            SeO4-2         0            Se             78.96 
Se(+4)        SeO3-2         0            Se             78.96 
Se(+6)        SeO4-2         0            Se             78.96 
Se(-2)        HSe-           0            Se             78.96 
Si            H4(SiO4)       0            Si             28.0855 
Sm            Sm+3           0            Sm             150.36 
Sn            Sn+2           0            Sn             118.71 
Sn(+2)        Sn+2           0            Sn             118.71 
Sn(+4)        Sn+4           0            Sn             118.71 
Sr            Sr+2           0            Sr             87.62 
Tc            TcO(OH)2       0            Tc             98 
Tc(+4)        TcO(OH)2       0            Tc             98 
Tc(+6)        TcO4-2         0            Tc             98 
Tc(+7)        TcO4-          0            Tc             98 
Th            Th+4           0            Th             232.0381 
U             UO2+2          0            U              238.0289 
U(+3)         U+3            0            U              238.0289 
U(+4)         U+4            0            U              238.0289 
U(+5)         UO2+           0            U              238.0289 
U(+6)         UO2+2          0            U              238.0289 
Zn            Zn+2           0            Zn             65.39 
Zr            Zr+4           0            Zr             91.22 


SIT
-epsilon

(NpO2)2(OH)2+2          Cl-            -0.248 
(NpO2)3(OH)5+           Cl-            -0.226 
PuO2(OH)+               Cl-            -0.003 
(PuO2)2(OH)2+2          Cl-            -0.248 
PuO2Cl+                 Cl-             0.318 
(UO2)2(OH)2+2           Cl-             0.69 
(UO2)3(OH)4+2           Cl-             0.5 
(UO2)3(OH)5+            Cl-             0.81 
Ag+                     Cl-             0.031 
Al(OH)+2                Cl-             0.09 
Al(OH)2+                Cl-             0.09 
Al+3                    Cl-             0.33 
Am(CO3)+                Cl-             0.129 
Am(H2PO4)+2             Cl-             0.191 
Am(NO3)+2               Cl-             0.191 
Am(OH)+2                Cl-            -0.04 
Am(OH)2+                Cl-            -0.29 
Am(SO4)+                Cl-             0.157 
Am+3                    Cl-             0.23 
AmCl+2                  Cl-             0.191 
AmCl2+                  Cl-             0.129 
AmF+2                   Cl-             0.191 
AmF2+                   Cl-             0.129 
AmO2+                   Cl-             0.09 
AmO2+2                  Cl-             0.39 
Ba+2                    Cl-             0.07 
Ca+2                    Cl-             0.14 
Ca4Th(OH)8+4            Cl-            -0.01 
Ca4Th(OH)8+4            ClO4-           0.21 
Cd(HCO3)+               Cl-             0.2 
Cd+2                    Cl-             0.16 
CdCl+                   Cl-             0.127 
CdI+                    Cl-             0.136 
Cm(OH)+2                Cl-            -0.04 
Cm(OH)2+                Cl-            -0.27 
Cm+3                    Cl-             0.23 
CmCO3+                  Cl-             0.35 
Cu+2                    Cl-             0.08 
Eu(CO3)+                Cl-             0.129 
Eu(H2PO4)+2             Cl-             0.191 
Eu(NO3)+2               Cl-             0.191 
Eu(OH)+2                Cl-            -0.04 
Eu(OH)2+                Cl-            -0.29 
Eu(SO4)+                Cl-             0.157 
Eu+3                    Cl-             0.23 
EuCl+2                  Cl-             0.191 
EuCl2+                  Cl-             0.129 
EuF+2                   Cl-             0.191 
EuF2+                   Cl-             0.129 
Fe(OH)+2                Cl-             0.186 
H+                      Cl-             0.12 
Hf+4                    Cl-             0.07 
Hg+2                    Cl-             0.168 
Hg2+2                   Cl-             0.054 
Ho(CO3)+                Cl-             0.129 
Ho(H2PO4)+2             Cl-             0.191 
Ho(NO3)+2               Cl-             0.191 
Ho(OH)+2                Cl-            -0.04 
Ho(OH)2+                Cl-            -0.29 
Ho(SO4)+                Cl-             0.157 
Ho+3                    Cl-             0.23 
HoCl+2                  Cl-             0.191 
HoCl2+                  Cl-             0.129 
HoF+2                   Cl-             0.191 
Mg+2                    Cl-             0.19 
Mn+2                    Cl-             0.13 
Na+                     Cl-             0.03 
NH4+                    Cl-            -0.01 
Ni(HCO3)+               Cl-             0.085 
Ni(NO3)+                Cl-             0.06 
Ni(OH)+                 Cl-            -0.01 
Ni(Scn)+                Cl-             0.11 
Ni+2                    Cl-             0.17 
NiCl+                   Cl-             0.1 
NiF+                    Cl-             0.065 
Np(CO3)+                Cl-             0.129 
Np(OH)+2                Cl-            -0.04 
Np(OH)+3                Cl-             0.2 
Np(OH)2+                Cl-            -0.29 
Np(OH)2+2               Cl-             0.1 
Np(OH)3+                Cl-             0.05 
Np(SO4)+                Cl-             0.157 
Np(SO4)+2               Cl-             0.232 
Np+3                    Cl-             0.23 
Np+4                    Cl-             0.4 
NpF2+2                  Cl-             0.186 
NpF3+                   Cl-             0.1 
NpO2(NO3)+              Cl-             0.22 
NpO2(OH)+               Cl-            -0.003 
NpO2+                   Cl-             0.09 
NpO2+2                  Cl-             0.223 
NpO2Cl+                 Cl-             0.318 
NpO2F+                  Cl-             0.197 
Pa+4                    Cl-             0.3 
PaO(OH)+2               Cl-             0.13 
Pb+2                    Cl-             0.081 
PbF+                    Cl-             0.14 
Pd+2                    Cl-             0.16 
PdBr+                   Cl-             0.175 
PdCl+                   Cl-             0.175 
Pu(CO3)+                Cl-             0.129 
Pu(NO3)+2               Cl-             0.191 
Pu(OH)+2                Cl-            -0.04 
Pu(OH)+3                Cl-             0.2 
Pu(OH)2+                Cl-            -0.29 
Pu(OH)2+2               Cl-             0.1 
Pu(OH)3+                Cl-             0.05 
Pu(SO4)+                Cl-             0.157 
Pu(SO4)+2               Cl-             0.232 
Pu+3                    Cl-             0.23 
Pu+4                    Cl-             0.4 
PuBr+3                  Cl-             0.1 
PuCl+3                  Cl-             0.1 
PuF+3                   Cl-             0.1 
PuF2+2                  Cl-             0.177 
PuF3+                   Cl-             0.1 
PuI+2                   Cl-             0.191 
PuI+3                   Cl-             0.1 
PuO2+                   Cl-             0.129 
PuO2+2                  Cl-             0.223 
PuO2F+                  Cl-             0.197 
PuO2NO3+                Cl-             0.22 
Sm(CO3)+                Cl-             0.129 
Sm(H2PO4)+2             Cl-             0.191 
Sm(NO3)+2               Cl-             0.191 
Sm(OH)+2                Cl-            -0.04 
Sm(OH)2+                Cl-            -0.29 
Sm(SO4)+                Cl-             0.157 
Sm+3                    Cl-             0.23 
SmCl+2                  Cl-             0.191 
SmF+2                   Cl-             0.191 
Sn(OH)+                 Cl-             0.2 
Sn+2                    Cl-             0.26 
Th(H2PO4)+3             ClO4-           0.5 
Th(H2PO4)2+2            ClO4-           0.4 
Th(H3PO4)(H2PO4)+3      ClO4-           0.5 
Th(H3PO4)+4             ClO4-           0.7 
Th(NO3)+3               ClO4-           0.56 
Th(NO3)2+2              ClO4-           0.43 
Th(OH)+3                Cl-             0.19 
Th(OH)+3                ClO4-           0.48 
Th(OH)2+2               Cl-             0.13 
Th(OH)2+2               ClO4-           0.33 
Th(OH)3+                Cl-             0.06 
Th(OH)3+                ClO4-           0.15 
Th(SO4)+2               Cl-             0.14 
Th(SO4)+2               ClO4-           0.3 
Th+4                    Cl-             0.25 
Th+4                    ClO4-           0.7 
Th2(OH)2+6              Cl-             0.4 
Th2(OH)2+6              ClO4-           1.22 
Th2(OH)3+5              Cl-             0.29 
Th2(OH)3+5              ClO4-           0.91 
Th4(OH)12+4             Cl-             0.25 
Th4(OH)12+4             ClO4-           0.56 
Th4(OH)8+8              Cl-             0.7 
Th4(OH)8+8              ClO4-           1.69 
Th6(OH)14+10            Cl-             0.83 
Th6(OH)14+10            ClO4-           2.2 
Th6(OH)15+9             Cl-             0.72 
Th6(OH)15+9             ClO4-           1.85 
ThCl+3                  Cl-             0.62 
ThCl+3                  ClO4-           0.62 
ThF+3                   ClO4-           0.48 
ThF2+2                  ClO4-           0.3 
ThF3+                   ClO4-           0.1 
U(NO3)2+2               Cl-             0.236 
U(OH)+3                 Cl-             0.2 
U(OH)2+2                Cl-             0.1 
U(OH)3+                 Cl-             0.05 
U(SO4)+2                Cl-             0.149 
U+3                     Cl-             0.23 
U+4                     Cl-             0.36 
UCl+3                   Cl-             0.1 
UF+3                    Cl-             0.1 
UF2+2                   Cl-             0.149 
UF3+                    Cl-             0.1 
UO2(NO3)+               Cl-             0.22 
UO2(OH)+                Cl-            -0.003 
UO2+                    Cl-             0.18 
UO2+2                   Cl-             0.21 
UO2Br+                  Cl-             0.169 
UO2Cl+                  Cl-             0.22 
UO2F+                   Cl-             0.04 
Zn+2                    Cl-             0.163 
(NpO2)2CO3(OH)3-        Na+             0 
(NpO2)3(CO3)6-6         Na+            -0.46 
(PuO2)3(CO3)6-6         Na+            -0.46 
(UO2)2(CO3)(OH)3-       Na+             0 
(UO2)2(NpO2)(CO3)6-6    Na+             0.09 
(UO2)3(CO3)6-6          Na+             0.37 
Ag(SeO3)-               Na+            -0.024 
Am(CO3)2-               Na+            -0.14 
Am(CO3)3-3              Na+            -0.23 
Am(CO3)5-6              Na+            -0.3 
Am(SO4)2-               Na+            -0.05 
AmO2(CO3)-              Na+            -0.18 
AmO2(CO3)2-3            Na+            -0.33 
AmO2(CO3)3-5            Na+            -0.53 
B(OH)4-                 Na+            -0.07 
Br-                     Na+             0.05 
Cl-                     Na+             0.03 
Cm(CO3)2-               Na+             0.34 
Cm(CO3)3-3              Na+             0.16 
Cm(SO4)2-               Na+            -0.05 
CO3-2                   Na+            -0.08 
Eu(CO3)2-               Na+            -0.05 
Eu(SO4)2-               Na+            -0.05 
F-                      Na+             0.02 
H(SeO3)-                Na+             0.02 
H(SeO4)-                Na+             0 
H(SO4)-                 Na+            -0.01 
H2(PO4)-                Na+            -0.08 
H2(SiO4)-2              Na+            -0.1 
H3(SiO4)-               Na+            -0.08 
Hg(SeO3)2-2             Na+             0.008 
HMoO4-                  Na+            -0.099 
Ho(CO3)2-               Na+            -0.05 
Ho(SO4)2-               Na+            -0.05 
HPO4-2                  Na+            -0.15 
I-                      Na+             0.08 
IO3-                    Na+            -0.06 
Mo7O21(OH)3-3           Na+            -1.455 
Mo7O22(OH)2-4           Na+            -1.346 
Mo7O23(OH)-5            Na+            -1.145 
Mo7O24-6                Na+            -1.265 
MoO4-2                  Na+             0.034 
Ni(Cn)4-2               Na+             0.185 
Ni(Cn)5-3               Na+             0.25 
Ni(CO3)2-2              Na+             0.003 
Ni(OH)3-                Na+             0.88 
Ni(Scn)3-               Na+             0.66 
Ni(SO4)2-2              Na+            -0.263 
NO3-                    Na+            -0.04 
Np(CO3)(OH)3-           Na+            -0.11 
Np(CO3)2-               Na+            -0.05 
Np(CO3)3-3              Na+            -0.15 
Np(CO3)4-4              Na+            -0.09 
Np(CO3)5-6              Na+             0 
Np(OH)4(CO3)-2          Na+            -0.13 
Np(SO4)2-               Na+            -0.05 
NpO2(CO3)-              Na+            -0.18 
NpO2(CO3)2-2            Na+            -0.02 
NpO2(CO3)2-3            Na+            -0.33 
NpO2(CO3)2OH-4          Na+            -0.4 
NpO2(CO3)3-4            Na+            -0.4 
NpO2(CO3)3-5            Na+            -0.53 
NpO2(HPO4)2-2           Na+            -0.1 
NpO2(OH)2-              Na+            -0.01 
NpO2(SO4)-              Na+            -0.74 
NpO2(SO4)2-2            Na+            -0.12 
OH-                     Na+             0.04 
Pb(OH)3-                Na+             0.02 
Pb(SO4)2-2              Na+            -0.52 
Pd(SO4)2-2              Na+            -0.12 
PdBr3-                  Na+             0 
PdBr4-2                 Na+             0.1 
PdCl3-                  Na+             0 
PdCl4-2                 Na+             0.1 
PO4-3                   Na+            -0.25 
Pu(CO3)2-               Na+            -0.05 
Pu(CO3)3-3              Na+            -0.15 
Pu(CO3)4-4              Na+            -0.09 
Pu(CO3)5-6              Na+             0 
Pu(SO4)2-               Na+            -0.05 
PuO2(CO3)2-2            Na+            -0.7 
PuO2(CO3)3-4            Na+            -0.2 
PuO2(CO3)3-5            Na+            -0.53 
PuO2(SO4)-              Na+            -0.74 
PuO2(SO4)2-2            Na+            -0.12 
PuO2CO3-                Na+            -0.18 
PuO2F3-                 Na+             0 
Scn-                    Na+             0.05 
SeO3-2                  Na+            -0.08 
SeO4-2                  Na+            -0.12 
Si2O2(OH)5-             Na+            -0.08 
Si2O3(OH)4-2            Na+            -0.15 
Si3O5(OH)5-3            Na+            -0.25 
Si3O6(OH)3-3            Na+            -0.25 
Si4O7(OH)5-3            Na+            -0.25 
Sm(CO3)2-               Na+            -0.05 
Sm(SO4)2-               Na+            -0.05 
Sn(OH)3-                Na+             0.33 
SnBr3-                  Na+            -0.04 
SnCl3-                  Na+            -0.36 
SO3-2                   Na+            -0.08 
SO4-2                   Na+            -0.12 
Th(CO3)5-6              Na+            -0.3 
Th(OH)(CO3)4-5          Na+            -0.22 
Th(OH)2(CO3)2-2         Na+            -0.1 
Th(OH)3(CO3)-           Na+            -0.05 
Th(OH)4(CO3)-2          Na+            -0.1 
Th(SO4)3-2              Na+            -0.091 
U(CO3)4-4               Na+            -0.09 
U(CO3)5-6               Na+            -0.3 
UO2(CO3)2-2             Na+            -0.02 
UO2(CO3)3-4             Na+            -0.01 
UO2(CO3)3-5             Na+            -0.62 
UO2(OH)3-               Na+            -0.09 
UO2(SO4)2-2             Na+            -0.12 
UO2F3-                  Na+            -0.14 
UO2F4-2                 Na+            -0.3 
Zr(CO3)4-4              Na+            -0.09 
Zr(OH)6-2               Na+            -0.1 
ZrF5-                   Na+            -0.14 
ZrF6-2                  Na+            -0.15 


SOLUTION_SPECIES

+1.000Co+2          = Co+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -57.6         kJ/mol        98PLY/ZHA


+1.000Mn+2          = Mn+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -220.8        kJ/mol        95ROB/HEM


+1.000Cu+2          = Cu+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:              64.9         kJ/mol        92GRE/FUG


+1.000Ca+2          = Ca+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -543          kJ/mol        89COX/WAG


+1.000Ni+2          = Ni+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -55.012       kJ/mol        05GAM/BUG


+1.000Hg+2          = Hg+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:              170.21       kJ/mol        92GRE/FUG


+1.000Mg+2     +2.000NH3          = Mg(NH3)2+2
     log_k     0            #NAGRA, TR 91-18; F.J. PEARSON, U. BERNER, W. HUMMEL; Nagra thermochemical data base, supplemental data 05/92
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -629.296      kJ/mol        


+1.000Mg+2          = Mg+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -467          kJ/mol        89COX/WAG


+1.000Eu+3          = Eu+3
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -605.331      kJ/mol        


+1.000Li+          = Li+
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2          = Sr+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -550.9        kJ/mol        84BUS/PLUS


+1.000Th+4          = Th+4
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -768.7        kJ/mol        09RAN/FUG


+1.000PuO2+2          = PuO2+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -822.036      kJ/mol        01LEM/FUG


+1.000K+          = K+
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -252.14       kJ/mol        89COX/WAG


+1.000NpO2+2          = NpO2+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -860.733      kJ/mol        01LEM/FUG


+1.000Sm+3          = Sm+3
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -691.199      kJ/mol        


+1.000Cd+2          = Cd+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -75.92        kJ/mol        89COX/WAG


+1.000Pyrophos-4          = Pyrophos-4
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H4(SiO4)          = H4(SiO4)
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -1461.194     kJ/mol        


+1.000Na+          = Na+
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -240.34       kJ/mol        92GRE/FUG (89COX/WAG)


+1.000H+          = H+
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        89COX/WAG


+1.000Pd+2          = Pd+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:              189.883      kJ/mol        


+1.000Am+3          = Am+3
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -616.7        kJ/mol        95SIL/BID


+1.000Ra+2          = Ra+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -528.025      kJ/mol        


+1.000Ho+3          = Ho+3
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -707.042      kJ/mol        


+1.000Nb(OH)6-          = Nb(OH)6-
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -1925.665     kJ/mol        


+1.000e-          = e-
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        89COX/WAG


+1.000Ba+2          = Ba+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -534.8        kJ/mol        95SIL/BID


+1.000Cn-          = Cn-
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:              150.624      kJ/mol        92JOH/OEL


+1.000Cit-3          = Cit-3
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -1519.92      kJ/mol        


+1.000Ox-2          = Ox-2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -830.66       kJ/mol        


+1.000Zn+2          = Zn+2
     log_k     0            #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -153.39       kJ/mol        92GRE/FUG


+1.000H2(PO4)-          = H2(PO4)-
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -1302.6       kJ/mol        89COX/WAG


+1.000Nta-3          = Nta-3
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Edta-4          = Edta-4
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -1704.8       kJ/mol        05HUM/AND


+1.000HIsa-          = HIsa-
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cs+          = Cs+
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -258          kJ/mol        95SIL/BID


+1.000HGlu-          = HGlu-
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Hf+4          = Hf+4
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -628.91       kJ/mol        99VAS/LYT


+1.000Sb(OH)3          = Sb(OH)3
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -733.892      kJ/mol        


+1.000B(OH)4-          = B(OH)4-
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -1345.116     kJ/mol        99RAR/RAN


+1.000Fe+2          = Fe+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -90           kJ/mol        98CHI


+1.000Pb+2          = Pb+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:              0.92         kJ/mol        89COX/WAG


+1.000MoO4-2          = MoO4-2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -997          kJ/mol        74OHA


+1.000SeO4-2          = SeO4-2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -603.5        kJ/mol        05OLI/NOL


+1.000Ag+          = Ag+
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:              105.79       kJ/mol        95SIL/BID


+1.000Al+3          = Al+3
     log_k     0            #
     delta_h   0            kJ/mol        #
     # Enthalpy of formation:             -538.4        kJ/mol        95POK/HEL


+1.000Rb+          = Rb+
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -251.12       kJ/mol        92GRE/FUG


+1.000Pa+4          = Pa+4
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -620          kJ/mol        85BAR/PAR


+1.000Zr+4          = Zr+4
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -608.5        kJ/mol        05BRO/CUR


+1.000Cm+3          = Cm+3
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -615          kJ/mol        01KON


+1.000CrO4-2          = CrO4-2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -879          kJ/mol        


+1.000H2O          = H2O
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2          = Sn+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -8.9          kJ/mol        89COX/WAG


+1.000UO2+2          = UO2+2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -1019         kJ/mol        92GRE/FUG


+1.000TcO(OH)2          = TcO(OH)2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -749.32       kJ/mol        


+1.000CO3-2          = CO3-2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -675.23       kJ/mol        89COX/WAG


+1.000SO4-2          = SO4-2
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -909.34       kJ/mol        89COX/WAG


+1.000Cl-          = Cl-
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -167.08       kJ/mol        89COX/WAG


+1.000F-          = F-
     log_k     0            #95SIL/BID
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -335.35       kJ/mol        95SIL/BID


+1.000Br-          = Br-
     log_k     0            #95SIL/BID
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -121.41       kJ/mol        95SIL/BID


+1.000I-          = I-
     log_k     0            #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -56.78        kJ/mol        92GRE/FUG


+1.000Scn-          = Scn-
     log_k     0            #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:              76.4         kJ/mol        92GRE/FUG


+1.000AsO4-3          = AsO4-3
     log_k     0            #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -888.14       kJ/mol        01LEM/FUG


+1.000NO3-          = NO3-
     log_k     0            #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -206.85       kJ/mol        92GRE/FUG


+1.000Ca+2     +1.000Ox-2          = Ca(Ox)
     log_k     3.19         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +2.000Ox-2          = Ca(Ox)2-2
     log_k     4.02         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +2.000H+     +1.000Cit-3          = Ca(H2Cit)+
     log_k     12.67        #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +1.000H+     +1.000Cit-3          = Ca(HCit)
     log_k     9.28         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +1.000Cit-3          = Ca(Cit)-
     log_k     4.8          #05HUM/AND
     delta_h   0            kJ/mol        #
     # Enthalpy of formation:             -2062.92      kJ/mol        


+1.000Ca+2     +1.000Nta-3          = Ca(Nta)-
     log_k     7.73         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +1.000H+     +1.000Nta-3          = Ca(HNta)
     log_k     13.4         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +2.000H+     +2.000Nta-3          = Ca(HNta)2-2
     log_k     23.63        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +1.000H+     +1.000Edta-4          = Ca(HEdta)-
     log_k     16.23        #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +1.000Edta-4          = Ca(Edta)-2
     log_k     12.69        #05HUM/AND
     delta_h  -22.2         kJ/mol        #
     # Enthalpy of formation:             -2270         kJ/mol        


+1.000Ca+2     +1.000HIsa-          = Ca(HIsa)+
     log_k     1.7          #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     -1.000H+     +1.000HIsa-          = Ca(Isa)
     log_k    -10.4         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +1.000HGlu-          = Ca(HGlu)+
     log_k     1.73         #52SCH/LIN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     -1.000H+     +1.000HGlu-     +1.000H2O          = Ca(OH)(HGlu)
     log_k    -10.4         #02TIT/WIE
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +1.000Th+4     -4.000H+     +2.000HGlu-     +4.000H2O          = CaTh(OH)4(HGlu)2
     log_k    -0.6          #05TIT/WIE
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +2.000Cl-          = CaCl2
     log_k    -0.64         #97SVE/SHO
     delta_h  -5.858        kJ/mol        #
     # Enthalpy of formation:             -883.018      kJ/mol        


+1.000Ca+2     +1.000CrO4-2          = CaCrO4
     log_k     2.77         #00PER/PAL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +1.000Sm+3     -3.000H+     +3.000H2O          = Ca(Sm(OH)3)+2
     log_k    -26.3         #07RAB/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000Ca+2     +1.000Sm+3     -4.000H+     +4.000H2O          = Ca2(Sm(OH)4)+3
     log_k    -37.2         #07RAB/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000Ca+2     +1.000Sm+3     -6.000H+     +6.000H2O          = Ca3(Sm(OH)6)+3
     log_k    -60.7         #07RAB/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +1.000Eu+3     -3.000H+     +3.000H2O          = Ca(Eu(OH)3)+2
     log_k    -26.3         #07RAB/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+4.000Mg+2     -4.000H+     +4.000H2O          = Mg4(OH)4+4
     log_k    -39.75        #76BAE/MES
     delta_h   229.186      kJ/mol        #
     # Enthalpy of formation:             -2782.134     kJ/mol        


+1.000Mg+2     +1.000Ox-2          = Mg(Ox)
     log_k     3.56         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mg+2     +2.000Ox-2          = Mg(Ox)2-2
     log_k     5.17         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mg+2     +2.000H+     +1.000Cit-3          = Mg(H2Cit)+
     log_k     12.45        #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mg+2     +1.000H+     +1.000Cit-3          = Mg(HCit)
     log_k     8.96         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mg+2     +1.000Cit-3          = Mg(Cit)-
     log_k     4.81         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mg+2     +1.000Nta-3          = Mg(Nta)-
     log_k     6.79         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mg+2     +1.000H+     +1.000Edta-4          = Mg(HEdta)-
     log_k     15.4         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mg+2     +1.000Edta-4          = Mg(Edta)-2
     log_k     10.9         #05HUM/AND
     delta_h   19.8         kJ/mol        #
     # Enthalpy of formation:             -2152         kJ/mol        


+2.000Ca+2     +1.000Eu+3     -4.000H+     +4.000H2O          = Ca2(Eu(OH)4)+3
     log_k    -37.2         #07RAB/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mg+2     +1.000B(OH)4-          = MgB(OH)4+
     log_k     1.6          #97CRO
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000Ca+2     +1.000Eu+3     -6.000H+     +6.000H2O          = Ca3(Eu(OH)6)+3
     log_k    -60.7         #07RAB/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     -3.000H+     +1.000Ho+3     +3.000H2O          = Ca(Ho(OH)3)+2
     log_k    -26.3         #07RAB/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000Ca+2     -4.000H+     +1.000Ho+3     +4.000H2O          = Ca2(Ho(OH)4)+3
     log_k    -37.2         #07RAB/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000Ca+2     -6.000H+     +1.000Ho+3     +6.000H2O          = Ca3(Ho(OH)6)+3
     log_k    -60.7         #07RAB/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     -3.000H+     +1.000Am+3     +3.000H2O          = Ca(Am(OH)3)+2
     log_k    -26.3         #07RAB/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000Ca+2     -4.000H+     +1.000Am+3     +4.000H2O          = Ca2(Am(OH)4)+3
     log_k    -37.2         #07RAB/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000Ca+2     -6.000H+     +1.000Am+3     +6.000H2O          = Ca3(Am(OH)6)+3
     log_k    -60.7         #07RAB/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     -3.000H+     +1.000Cm+3     +3.000H2O          = Ca(Cm(OH)3)+2
     log_k    -26.3         #07RAB/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000Ca+2     -4.000H+     +1.000Cm+3     +4.000H2O          = Ca2(Cm(OH)4)+3
     log_k    -37.2         #07RAB/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000Ca+2     -6.000H+     +1.000Cm+3     +6.000H2O          = Ca3(Cm(OH)6)+3
     log_k    -60.7         #07RAB/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +1.000H+     +1.000Ox-2          = Sr(HOx)+
     log_k     5.8          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +1.000Ox-2          = Sr(Ox)
     log_k     2.54         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +2.000H+     +2.000Ox-2          = Sr(HOx)2
     log_k     10.8         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +2.000Ox-2          = Sr(Ox)2-2
     log_k     3            #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +2.000H+     +1.000Cit-3          = Sr(H2Cit)+
     log_k     12.46        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +1.000H+     +1.000Cit-3          = Sr(HCit)
     log_k     9            #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +1.000Cit-3          = Sr(Cit)-
     log_k     4.24         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +2.000Cit-3          = Sr(Cit)2-4
     log_k     4.84         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     -1.000H+     +2.000Cit-3     +1.000H2O          = Sr(Cit)2(OH)-5
     log_k    -1.78         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000Sr+2     -1.000H+     +1.000Cit-3     +1.000H2O          = Sr2(Cit)(OH)
     log_k     0.38         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +1.000Nta-3          = Sr(Nta)-
     log_k     6.25         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +1.000H+     +1.000Edta-4          = Sr(HEdta)-
     log_k     14.7         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +1.000Edta-4          = Sr(Edta)-2
     log_k     10.3         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000K+     +1.000Cl-          = KCl
     log_k    -0.5          #97MAR/SMI
     delta_h   4.184        kJ/mol        #97MAR/SMI
     # Enthalpy of formation:             -415.036      kJ/mol        


+1.000K+     +1.000H+     +1.000Nta-3          = K(HNta)-
     log_k     10.3         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000K+     +1.000Nta-3          = K(Nta)-2
     log_k     1.3          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000K+     +1.000Edta-4          = K(Edta)-3
     log_k     1.8          #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000K+     +1.000Al+3     -4.000H+     +4.000H2O          = KAl(OH)4
     log_k    -24.22        #
     delta_h   211.675      kJ/mol        #
     # Enthalpy of formation:             -1722.185     kJ/mol        97POK/HEL


+1.000K+     -2.000H+     +1.000H2(PO4)-          = KPO4-2
     log_k    -18.26        #97MAR/SMI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000K+     +1.000H2(PO4)-          = KH2PO4
     log_k     0.44         #97MAR/SMI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Na+     +1.000B(OH)4-          = NaB(OH)4
     log_k    -0.1          #
     delta_h   1.226        kJ/mol        #
     # Enthalpy of formation:             -1584.23      kJ/mol        


+1.000Na+     +1.000H+     +1.000Nta-3          = Na(HNta)-
     log_k     10.32        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Na+     +1.000Nta-3          = Na(Nta)-2
     log_k     1.88         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Na+     +1.000Edta-4          = Na(Edta)-3
     log_k     2.8          #05HUM/AND
     delta_h  -4            kJ/mol        #
     # Enthalpy of formation:             -1949.14      kJ/mol        


+2.000Na+     +1.000Pyrophos-4          = Na2(Pyrophos)-2
     log_k     2.29         #76SMI/MAR
     delta_h   5.858        kJ/mol        #76SMI/MAR
     # Enthalpy of formation:             -2761.716     kJ/mol        


+1.000Na+     -1.000H+     +1.000H4(SiO4)          = NaH3SiO4
     log_k    -8.01         #97SVE/SHO
     delta_h   7.728        kJ/mol        #
     # Enthalpy of formation:             -1693.806     kJ/mol        


+1.000Na+     -2.000H+     +1.000H2(PO4)-          = NaPO4-2
     log_k    -18.07        #97MAR/SMI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Na+     +1.000H2(PO4)-          = NaH2PO4
     log_k     0.41         #97MAR/SMI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pb+2     -1.000H+     +1.000H2(PO4)-          = PbHPO4
     log_k    -4.11         #74NRI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pb+2     +1.000H2(PO4)-          = Pb(H2PO4)+
     log_k     1.5          #74NRI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pb+2     -4.000H+     +4.000H2O          = Pb(OH)4-2
     log_k    -38.9         #01PER/HEF
     delta_h   197.474      kJ/mol        #
     # Enthalpy of formation:             -944.926      kJ/mol        


+1.000Co+2     +1.000SeO4-2          = Co(SeO4)
     log_k     2.7          #05OLI/NOL
     delta_h  -3.654        kJ/mol        #
     # Enthalpy of formation:             -664.754      kJ/mol        


+1.000Co+2     -2.000H+     +2.000H2O          = Co(OH)2
     log_k    -18.6         #98PLY/ZHA
     delta_h   105.707      kJ/mol        #
     # Enthalpy of formation:             -523.553      kJ/mol        


+1.000Co+2     -3.000H+     +3.000H2O          = Co(OH)3-
     log_k    -31.7         #98PLY/ZHA
     delta_h   160.297      kJ/mol        #
     # Enthalpy of formation:             -754.792      kJ/mol        


+1.000Co+2     -4.000H+     +4.000H2O          = Co(OH)4-2
     log_k    -46.42        #98PLY/ZHA
     delta_h   214.483      kJ/mol        #
     # Enthalpy of formation:             -986.436      kJ/mol        


+1.000Co+2     -1.000H+     +1.000H2O          = Co(OH)+
     log_k    -9.23         #98PLY/ZHA
     delta_h   45.962       kJ/mol        #
     # Enthalpy of formation:             -297.468      kJ/mol        


+2.000Co+2     -1.000H+     +1.000H2O          = Co2(OH)+3
     log_k    -9.83         #98PLY/ZHA
     delta_h   30.03        kJ/mol        #
     # Enthalpy of formation:             -371          kJ/mol        98PLY/ZHA


+4.000Co+2     -4.000H+     +4.000H2O          = Co4(OH)4+4
     log_k    -29.88        #98PLY/ZHA
     delta_h   149.72       kJ/mol        #
     # Enthalpy of formation:             -1224         kJ/mol        98PLY/ZHA


+1.000Co+2     +1.000CO3-2          = CoCO3
     log_k     4.23         #97MAR/SMI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Co+2     +1.000H+     +1.000CO3-2          = CoHCO3+
     log_k     12.22        #97MAR/SMI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Co+2     -1.000H+     +1.000H2(PO4)-          = CoHPO4
     log_k    -4.15         #97MAR/SMI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Co+2     +1.000SO4-2          = CoSO4
     log_k     2.3          #97MAR/SMI
     delta_h   2.092        kJ/mol        #74NAU/RYZ
     # Enthalpy of formation:             -964.848      kJ/mol        


+1.000Co+2     +1.000HS-          = CoHS+
     log_k     5.67         #66KHO
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Co+2     +2.000HS-          = Co(HS)2
     log_k     8.77         #66KHO
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Co+2     +1.000S2O3-2          = CoS2O3
     log_k     2.05         #51DEN/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Co+2     +1.000F-          = CoF+
     log_k     1.5          #97MAR/SMI
     delta_h  -0.631        kJ/mol        #
     # Enthalpy of formation:             -393.581      kJ/mol        


+1.000Co+2     +1.000Cl-          = CoCl+
     log_k     0.57         #81TUR/WHI
     delta_h  -2.18         kJ/mol        #
     # Enthalpy of formation:             -226.859      kJ/mol        


+1.000Co+2     +2.000Cl-          = CoCl2
     log_k     0.02         #06BLA/ING
     delta_h   4.074        kJ/mol        #06BLA/ING
     # Enthalpy of formation:             -387.686      kJ/mol        


+1.000Co+2     +3.000Cl-          = CoCl3-
     log_k    -1.71         #06BLA/ING
     delta_h   6.688        kJ/mol        #06BLA/ING
     # Enthalpy of formation:             -552.152      kJ/mol        


+1.000Fe+2     -1.000e-          = Fe+3
     log_k    -13.01        #
     delta_h   41           kJ/mol        #
     # Enthalpy of formation:             -49           kJ/mol        98CHI


+1.000Fe+3     +2.000Br-          = FeBr2+
     log_k     0.9          #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     -1.000H+     +1.000CO3-2     +1.000H2O          = FeCO3OH
     log_k     10.76        #05GRI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000CrO4-2          = FeCrO4+
     log_k     7.8          #96BAR/PAL
     delta_h   19.1         kJ/mol        #96BAR/PAL
     # Enthalpy of formation:             -908.9        kJ/mol        


+1.000Fe+3     +1.000H+     +1.000Ox-2          = Fe(HOx)+2
     log_k     9.3          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000Ox-2          = Fe(Ox)+
     log_k     9.53         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +2.000Ox-2          = Fe(Ox)2-
     log_k     15.75        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +3.000Ox-2          = Fe(Ox)3-3
     log_k     20.2         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +2.000H+     +1.000Cit-3          = Fe(H2Cit)+2
     log_k     30.4         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000H+     +1.000Cit-3          = Fe(HCit)+
     log_k     13.56        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000Cit-3          = Fe(Cit)
     log_k     12.65        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     -1.000H+     +1.000Cit-3     +1.000H2O          = Fe(Cit)(OH)-
     log_k     10.33        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     -2.000H+     +1.000Cit-3     +2.000H2O          = Fe(OH)2(Cit)-2
     log_k     2.9          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +2.000H+     +2.000Cit-3          = Fe(HCit)2-
     log_k     24.92        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000H+     +2.000Cit-3          = Fe(HCit)(Cit)-2
     log_k     19.3         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +2.000Cit-3          = Fe(Cit)2-3
     log_k     18.15        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     -2.000H+     +2.000Cit-3     +2.000H2O          = Fe(Cit)2(OH)2-5
     log_k     3.44         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000Fe+3     -2.000H+     +2.000Cit-3     +2.000H2O          = Fe2(Cit)2(OH)2-2
     log_k     45           #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000Nta-3          = Fe(Nta)
     log_k     18.6         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     -1.000H+     +1.000Nta-3     +1.000H2O          = Fe(OH)(Nta)-
     log_k     14.6         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     -2.000H+     +1.000Nta-3     +2.000H2O          = Fe(OH)2(Nta)-2
     log_k     6            #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +2.000Nta-3          = Fe(Nta)2-3
     log_k     27           #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000H+     +1.000Edta-4          = Fe(HEdta)
     log_k     29.2         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000Edta-4          = Fe(Edta)-
     log_k     27.7         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     -1.000H+     +1.000Edta-4     +1.000H2O          = Fe(OH)(Edta)-2
     log_k     20.84        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     -2.000H+     +1.000Edta-4     +2.000H2O          = Fe(OH)2(Edta)-3
     log_k     10.06        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     -3.000H+     +1.000Edta-4     +3.000H2O          = Fe(OH)3(Edta)-4
     log_k     8.3          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000Fe+3     -2.000H+     +2.000Edta-4     +2.000H2O          = Fe2(OH)2(Edta)2-4
     log_k     68           #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +6.000Cn-          = Fe(Cn)6-3
     log_k     43.6         #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000NO3-          = Fe(NO3)+2
     log_k     0.95         #HATCHES 8.0 1996
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +2.000H+     +1.000Pyrophos-4          = FeH2Pyrophos+
     log_k     26           #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000H+     +1.000SO4-2          = FeHSO4+2
     log_k     4.47         #90NOR/PLU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000S2O3-2          = FeS2O3+
     log_k     3.9          #82SCH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000Scn-          = FeScn+2
     log_k     3.1          #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +3.000Cl-          = FeCl3
     log_k     1.13         #90NOR/PLU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +4.000Cl-          = FeCl4-
     log_k    -0.79         #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000Br-          = FeBr+2
     log_k     0.7          #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000I-          = FeI+2
     log_k     2.1          #96BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +3.000CO3-2          = Fe(CO3)3-3
     log_k     24.24        #05GRI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     -4.000H+     +4.000H2O          = Fe(OH)4-2
     log_k    -46           #76BAE/MES in 99CHIa
     delta_h   158.797      kJ/mol        #
     # Enthalpy of formation:             -1074.523     kJ/mol        


+1.000Fe+2     -1.000H+     +1.000CO3-2     +1.000H2O          = FeCO3OH-
     log_k    -4.03         #98KIN in 99CHIb
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +2.000CO3-2          = Fe(CO3)2-2
     log_k     7.45         #98KIN in 99CHIb
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +1.000Ox-2          = Fe(Ox)
     log_k     4.1          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +2.000Ox-2          = Fe(Ox)2-2
     log_k     6.2          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +3.000Ox-2          = Fe(Ox)3-4
     log_k     5.22         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +2.000H+     +1.000Cit-3          = Fe(H2Cit)+
     log_k     24.7         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +1.000H+     +1.000Cit-3          = Fe(HCit)
     log_k     10.02        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +1.000Cit-3          = Fe(Cit)-
     log_k     6.1          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     -1.000H+     +1.000Cit-3     +1.000H2O          = Fe(OH)(Cit)-2
     log_k     1.5          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +1.000H+     +1.000Nta-3          = Fe(HNta)
     log_k     12.3         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +1.000Nta-3          = Fe(Nta)-
     log_k     10.6         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     -1.000H+     +1.000Nta-3     +1.000H2O          = Fe(OH)(Nta)-2
     log_k    -0.12         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +2.000Nta-3          = Fe(Nta)2-4
     log_k     13.5         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +1.000H+     +1.000Edta-4          = Fe(HEdta)-
     log_k     18.3         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +1.000Edta-4          = Fe(Edta)-2
     log_k     16.02        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     -1.000H+     +1.000Edta-4     +1.000H2O          = Fe(OH)(Edta)-3
     log_k     6.4          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     -2.000H+     +1.000Edta-4     +2.000H2O          = Fe(OH)2(Edta)-4
     log_k    -4.4          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +1.000H+     +1.000CO3-2          = FeHCO3+
     log_k     11.77        #95CHI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +6.000Cn-          = Fe(Cn)6-4
     log_k     35.4         #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +1.000NH3          = Fe(NH3)+2
     log_k     1.3          #82SCH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +2.000NH3          = Fe(NH3)2+2
     log_k     2.1          #82SCH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +4.000NH3          = Fe(NH3)4+2
     log_k     3.6          #82SCH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +1.000HS-          = Fe(HS)+
     log_k     4.34         #04CHI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +2.000HS-          = Fe(HS)2
     log_k     6.45         #04CHI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     -8.000H+     -3.000e-     +4.000H2O          = MnO4-3
     log_k    -113          #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cu+2     +1.000e-          = Cu+
     log_k     2.64         #
     delta_h   6.77         kJ/mol        #
     # Enthalpy of formation:              71.67        kJ/mol        82WAG/EVA


+1.000Cu+2     +1.000SeO4-2          = Cu(SeO4)
     log_k     2.2          #Upper value suggested in 05OLI/NOL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +1.000CO3-2          = CaCO3
     log_k     3.22         #96BOU
     delta_h   14.83        kJ/mol        #
     # Enthalpy of formation:             -1203.4       kJ/mol        96BOU


+1.000Ba+2     +1.000F-          = BaF+
     log_k     0.4          #
     delta_h   6.697        kJ/mol        #
     # Enthalpy of formation:             -863.452      kJ/mol        97SVE/SHO


+1.000Ca+2     +1.000H+     +1.000CO3-2          = Ca(HCO3)+
     log_k     11.43        #96BOU
     delta_h  -23.597       kJ/mol        #
     # Enthalpy of formation:             -1241.827     kJ/mol        


+1.000Ca+2     +1.000Cl-          = CaCl+
     log_k    -0.29         #97SVE/SHO
     delta_h   7.15         kJ/mol        #
     # Enthalpy of formation:             -702.93       kJ/mol        


+1.000Ca+2     +1.000SO4-2          = Ca(SO4)
     log_k     2.31         #53BEL/GEO
     delta_h   4.292        kJ/mol        #
     # Enthalpy of formation:             -1448.048     kJ/mol        


+1.000Ca+2     +1.000B(OH)4-          = CaB(OH)4+
     log_k     1.8          #97CRO
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +1.000F-          = CaF+
     log_k     0.94         #ANDRA, CRP OHEM 95.002, X. BOURBON, janvier1996; Sélection de données thermodynamiques afférentes aux corrections de Température sur les principaux équilibres chimiques en milieu naturel
     delta_h   17.238       kJ/mol        #
     # Enthalpy of formation:             -861.112      kJ/mol        


+1.000Ca+2     +1.000I-          = CaI+
     log_k     0.14         #estimation NEA87     08/2/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +2.000I-          = CaI2
     log_k    -0.02         #estimation NEA87     08/2/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +1.000NH3          = Ca(NH3)+2
     log_k    -0.1          #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +2.000NH3          = Ca(NH3)2+2
     log_k    -0.7          #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +3.000NH3          = Ca(NH3)3+2
     log_k    -1.5          #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +4.000NH3          = Ca(NH3)4+2
     log_k    -2.6          #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     -1.000H+     +1.000H2(PO4)-          = Ca(HPO4)
     log_k    -4.37         #68CHU/MAR
     delta_h   17.565       kJ/mol        #
     # Enthalpy of formation:             -1828.035     kJ/mol        


+1.000Ca+2     -2.000H+     +1.000H2(PO4)-          = Ca(PO4)-
     log_k    -13.11        #68CHU/MAR
     delta_h   38.532       kJ/mol        #
     # Enthalpy of formation:             -1807.068     kJ/mol        


+1.000Ca+2     +1.000H2(PO4)-          = Ca(H2PO4)+
     log_k     1.5          #68CHU/MAR
     delta_h   7.777        kJ/mol        #
     # Enthalpy of formation:             -1837.823     kJ/mol        


+1.000Ca+2     +1.000Pyrophos-4          = Ca(Pyrophos)-2
     log_k     7.5          #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +1.000H+     +1.000Pyrophos-4          = Ca(HPyrophos)-
     log_k     13.8         #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     +1.000S2O3-2          = Cd(S2O3)
     log_k     2.46         #
     delta_h   5.405        kJ/mol        #
     # Enthalpy of formation:             -722.801      kJ/mol        74NAU/RYZ


+1.000Cd+2     -1.000H+     -2.000e-     +1.000Cn-     +1.000HSe-          = Cd(SeCn)+
     log_k     15.27        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     -2.000H+     -4.000e-     +2.000Cn-     +2.000HSe-          = Cd(SeCn)2
     log_k     29.39        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     -3.000H+     -6.000e-     +3.000Cn-     +3.000HSe-          = Cd(SeCn)3-
     log_k     42.89        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     -4.000H+     -8.000e-     +4.000Cn-     +4.000HSe-          = Cd(SeCn)4-2
     log_k     56.71        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     +2.000HS-          = Cd(HS)2
     log_k     14.43        #99WAN/TES
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     +1.000HS-          = CdHS+
     log_k     7.38         #99WAN/TES
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     -1.000H+     +1.000H2(PO4)-          = CdHPO4
     log_k    -2.38         #01AYA/MAD
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     -1.000H+     +1.000H4(SiO4)          = Ca(H3SiO4)+
     log_k    -8.83         #97SVE/SHO
     delta_h   31.633       kJ/mol        #
     # Enthalpy of formation:             -1972.561     kJ/mol        


+1.000Ca+2     +1.000NO3-          = Ca(NO3)+
     log_k     0.6          #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +2.000NO3-          = Ca(NO3)2
     log_k     0.5          #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +1.000S2O3-2          = Ca(S2O3)
     log_k     1.9          #NAGRA, TR 91-18; F.J. PEARSON, U. BERNER, W. HUMMEL; Nagra thermochemical data base, supplemental data 05/92  (provient de Hatches3.0)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -1191.5       kJ/mol        


+1.000Cd+2     +1.000SeO4-2          = Cd(SeO4)
     log_k     2.27         #05OLI/NOL
     delta_h   8.3          kJ/mol        #05OLI/NOL
     # Enthalpy of formation:             -671.12       kJ/mol        


+1.000Zn+2     -1.000H+     -2.000e-     +1.000Cn-     +1.000HSe-          = Zn(SeCn)+
     log_k     14.24        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Zn+2     -2.000H+     -4.000e-     +2.000Cn-     +2.000HSe-          = Zn(SeCn)2
     log_k     27.73        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +1.000Pyrophos-4          = Ni(Pyrophos)-2
     log_k     8.73         #05GAM/BUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +1.000H+     +1.000Pyrophos-4          = NiHPyrophos-
     log_k     14.54        #05GAM/BUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     -3.000H+     +1.000H2(PO4)-     +2.000H2O          = Ni(OH)2(HPO4)-2
     log_k    -23.24        #95LEM
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +1.000Cl-          = NiCl+
     log_k     0.08         #05GAM/BUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +1.000Ox-2          = Ni(Ox)
     log_k     5.19         #05HUM/AND
     delta_h   0            kJ/mol        #
     # Enthalpy of formation:             -885.672      kJ/mol        


+1.000Ni+2     +2.000Ox-2          = Ni(Ox)2-2
     log_k     7.64         #05HUM/AND
     delta_h  -7.8          kJ/mol        #
     # Enthalpy of formation:             -1724.132     kJ/mol        


+1.000Ni+2     +2.000H+     +1.000Cit-3          = Ni(H2Cit)+
     log_k     13.19        #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +1.000H+     +1.000Cit-3          = Ni(HCit)
     log_k     10.52        #05HUM/BER
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +1.000Cit-3          = Ni(Cit)-
     log_k     6.76         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +2.000Cit-3          = Ni(Cit)2-4
     log_k     8.5          #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +1.000Nta-3          = Ni(Nta)-
     log_k     12.75        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +2.000Nta-3          = Ni(Nta)2-4
     log_k     16.95        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     -1.000H+     +1.000Nta-3     +1.000H2O          = Ni(OH)(Nta)-2
     log_k     1.47         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +1.000H+     +1.000Edta-4          = Ni(HEdta)-
     log_k     24.2         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +1.000Edta-4          = Ni(Edta)-2
     log_k     20.54        #05HUM/AND
     delta_h  -26.1         kJ/mol        #
     # Enthalpy of formation:             -1785.912     kJ/mol        


+1.000Ni+2     +1.000NH3          = Ni(NH3)+2
     log_k     2.61         #70LET/ROC in 82HOG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +2.000NH3          = Ni(NH3)2+2
     log_k     4.76         #70LET/ROC in 82HOG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +3.000NH3          = Ni(NH3)3+2
     log_k     6.79         #70LET/ROC in 82HOG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +4.000NH3          = Ni(NH3)4+2
     log_k     8.34         #70LET/ROC in 82HOG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +1.000S2O3-2          = Ni(S2O3)
     log_k     2.06         #51DEU/HEI in 64SIL/MAR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +1.000HS-          = NiHS+
     log_k     5.5          #02HUM/BER
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +2.000HS-          = Ni(HS)2
     log_k     11.1         #02HUM/BER
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +4.000Cn-          = Ni(Cn)4-2
     log_k     30.2         #
     delta_h  -180.7        kJ/mol        #05GAM/BUG
     # Enthalpy of formation:              353.688      kJ/mol        


+1.000Ni+2     +5.000Cn-          = Ni(Cn)5-3
     log_k     28.5         #
     delta_h  -191.1        kJ/mol        #05GAM/BUG
     # Enthalpy of formation:              490.638      kJ/mol        


+1.000Ni+2     +1.000Scn-          = Ni(Scn)+
     log_k     1.81         #
     delta_h  -11.8         kJ/mol        #05GAM/BUG
     # Enthalpy of formation:              9.588        kJ/mol        


+1.000Ni+2     +2.000Scn-          = Ni(Scn)2
     log_k     2.69         #
     delta_h  -21           kJ/mol        #05GAM/BUG
     # Enthalpy of formation:              76.788       kJ/mol        


+1.000Ni+2     +3.000Scn-          = Ni(Scn)3-
     log_k     3.02         #
     delta_h  -29           kJ/mol        #05GAM/BUG
     # Enthalpy of formation:              145.188      kJ/mol        


+1.000Ni+2     +1.000H+     +1.000AsO4-3          = NiHAsO4
     log_k     14.5         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     -1.000H+     +1.000H2O          = Ca(OH)+
     log_k    -12.78        #87GAR/PAR
     delta_h   77.206       kJ/mol        #
     # Enthalpy of formation:             -751.624      kJ/mol        


+1.000Ca+2     +1.000IO3-          = Ca(IO3)+
     log_k     0.4          #estimation NEA87     08/2/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mg+2     +1.000CO3-2          = Mg(CO3)
     log_k     2.98         #97SVE/SHO
     delta_h   8.804        kJ/mol        #
     # Enthalpy of formation:             -1133.426     kJ/mol        


+1.000Mg+2     +1.000H+     +1.000CO3-2          = Mg(HCO3)+
     log_k     11.37        #95SHO/KOR
     delta_h  -12.859       kJ/mol        #
     # Enthalpy of formation:             -1155.089     kJ/mol        


+1.000Mg+2     +1.000SO4-2          = Mg(SO4)
     log_k     2.23         #76SMI/MAR
     delta_h   5.858        kJ/mol        #76SMI/MAR
     # Enthalpy of formation:             -1370.482     kJ/mol        


+1.000Mg+2     +1.000F-          = MgF+
     log_k     1.8          #ANDRA, CRP OHEM 95.002, X. BOURBON, janvier1996; Sélection de données thermodynamiques afférentes aux corrections de Température sur les principaux équilibres chimiques en milieu naturel
     delta_h   13.389       kJ/mol        #
     # Enthalpy of formation:             -788.961      kJ/mol        


+1.000Mg+2     +1.000I-          = MgI+
     log_k     0.18         #estimation NEA87     08/2/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mg+2     +1.000NH3          = Mg(NH3)+2
     log_k     0.1          #NAGRA, TR 91-18; F.J. PEARSON, U. BERNER, W. HUMMEL; Nagra thermochemical data base, supplemental data 05/92
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -548.148      kJ/mol        


+2.000Hg+2     +2.000e-          = Hg2+2
     log_k     30.79        #
     delta_h  -173.55       kJ/mol        #
     # Enthalpy of formation:              166.87       kJ/mol        01LEM/FUG


+1.000Hg+2     -1.000H+     +1.000HSe-          = HgSe
     log_k     37.59        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Hg+2     -2.000H+     +2.000HSe-          = HgSe2-2
     log_k     32.63        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mg+2     +3.000NH3          = Mg(NH3)3+2
     log_k    -0.3          #NAGRA, TR 91-18; F.J. PEARSON, U. BERNER, W. HUMMEL; Nagra thermochemical data base, supplemental data 05/92
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -710.444      kJ/mol        


+1.000Mg+2     +4.000NH3          = Mg(NH3)4+2
     log_k    -1            #NAGRA, TR 91-18; F.J. PEARSON, U. BERNER, W. HUMMEL; Nagra thermochemical data base, supplemental data 05/92
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -791.592      kJ/mol        


+1.000Mg+2     -2.000H+     +1.000H2(PO4)-          = Mg(PO4)-
     log_k    -14.71        #81TUR/WHI
     delta_h   31.17        kJ/mol        #96BOU
     # Enthalpy of formation:             -1738.43      kJ/mol        


+1.000Mg+2     -1.000H+     +1.000H2(PO4)-          = Mg(HPO4)
     log_k    -4.3          #76SMI/MAR
     delta_h   16.152       kJ/mol        #76SMI/MAR
     # Enthalpy of formation:             -1753.448     kJ/mol        


+1.000Mg+2     +1.000H2(PO4)-          = Mg(H2PO4)+
     log_k     1.17         #81TUR/WHI
     delta_h   13.514       kJ/mol        #96BOU
     # Enthalpy of formation:             -1756.086     kJ/mol        


+1.000Mg+2     +1.000Pyrophos-4          = Mg(Pyrophos)-2
     log_k     7.2          #76SMI/MAR
     delta_h   12.542       kJ/mol        #
     # Enthalpy of formation:             -2741.352     kJ/mol        


+1.000Mg+2     +1.000S2O3-2          = Mg(S2O3)
     log_k     1.82         #76SMI/MAR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pb+2     +2.000I-          = PbI2
     log_k     3.15         #82HÖG
     delta_h   7.106        kJ/mol        #
     # Enthalpy of formation:             -105.534      kJ/mol        


+1.000Pb+2     +1.000F-          = PbF+
     log_k     2.27         #99LOT/OCH
     delta_h  -4.054        kJ/mol        #
     # Enthalpy of formation:             -338.484      kJ/mol        


+1.000Pb+2     +2.000F-          = PbF2
     log_k     3.01         #99LOT/OCH
     delta_h  -8.881        kJ/mol        #
     # Enthalpy of formation:             -678.661      kJ/mol        


+1.000Pb+2     +2.000HS-          = Pb(HS)2
     log_k     15.01        #06BLA/PIA
     delta_h  -65.579       kJ/mol        #
     # Enthalpy of formation:             -97.259       kJ/mol        


+1.000Pb+2     +3.000HS-          = Pb(HS)3-
     log_k     16.26        #06BLA/PIA
     delta_h  -73.328       kJ/mol        #
     # Enthalpy of formation:             -121.308      kJ/mol        


+1.000Pb+2     +1.000Pyrophos-4          = PbPyrophos-2
     log_k     8.33         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Co+2     +4.000Cl-          = CoCl4-2
     log_k    -2.09         #06BLA/ING
     delta_h   22.57        kJ/mol        #06BLA/ING
     # Enthalpy of formation:             -703.35       kJ/mol        


+1.000Mg+2     +1.000IO3-          = Mg(IO3)+
     log_k     0.7          #estimation NEA87     08/2/95 ;
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mg+2     -1.000H+     +1.000H2O          = Mg(OH)+
     log_k    -11.68        #97SHO/SAS
     delta_h   62.835       kJ/mol        #
     # Enthalpy of formation:             -689.995      kJ/mol        


+1.000Sr+2     -1.000H+     +1.000H2(PO4)-          = Sr(HPO4)
     log_k    -4.7          #97MAR/SMI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +1.000H2(PO4)-          = Sr(H2PO4)+
     log_k     0.83         #97MAR/SMI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     -2.000H+     +1.000H2(PO4)-          = Sr(PO4)-
     log_k    -13.56        #96BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +1.000Pyrophos-4          = Sr(Pyrophos)-2
     log_k     5.4          #76SMI/MAR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +1.000S2O3-2          = Sr(S2O3)
     log_k     2.04         #76SMI/MAR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ag+     -2.000H+     +2.000H2O          = Ag(OH)2-
     log_k    -24           #76BAE/MES
     delta_h   111.634      kJ/mol        #
     # Enthalpy of formation:             -354.236      kJ/mol        


+1.000Ag+     +2.000CO3-2          = Ag(CO3)2-3
     log_k     2.16         #97SVE/SHO
     delta_h  -28.044       kJ/mol        #
     # Enthalpy of formation:             -1272.714     kJ/mol        


+1.000Ag+     +1.000CO3-2          = AgCO3-
     log_k     2.69         #97SVE/SHO
     delta_h  -22.832       kJ/mol        #
     # Enthalpy of formation:             -592.272      kJ/mol        


+1.000Ag+     +1.000NO3-          = AgNO3
     log_k    -0.29         #91BAL/NOR, 68WAG
     delta_h  -0.74         kJ/mol        #
     # Enthalpy of formation:             -101.8        kJ/mol        82WAG/EVA


+1.000Ag+     +4.000Cl-          = AgCl4-3
     log_k     5.51         #91BAL/NOR
     delta_h  -26.094       kJ/mol        #
     # Enthalpy of formation:             -588.624      kJ/mol        


+1.000Sr+2     -1.000H+     +1.000H2O          = Sr(OH)+
     log_k    -13.29        #76BAE/MES
     delta_h   82.609       kJ/mol        #
     # Enthalpy of formation:             -754.12       kJ/mol        


+1.000Sr+2     +1.000CO3-2          = Sr(CO3)
     log_k     2.81         #84BUS/PLU
     delta_h   21.824       kJ/mol        #
     # Enthalpy of formation:             -1204.306     kJ/mol        


+1.000Sr+2     +1.000H+     +1.000CO3-2          = Sr(HCO3)+
     log_k     11.51        #84BUS/PLUS
     delta_h   10.598       kJ/mol        #
     # Enthalpy of formation:             -1215.533     kJ/mol        


+1.000Sr+2     +1.000SO4-2          = Sr(SO4)
     log_k     2.3          #06BLA/ING
     delta_h   7.029        kJ/mol        #06BLA/ING
     # Enthalpy of formation:             -1453.211     kJ/mol        


+1.000Sr+2     +1.000Cl-          = SrCl+
     log_k     0.23         #96BOU
     delta_h   4.924        kJ/mol        #
     # Enthalpy of formation:             -713.054      kJ/mol        


+1.000Sr+2     +1.000F-          = SrF+
     log_k     0.3          #
     delta_h   16.74        kJ/mol        #
     # Enthalpy of formation:             -869.51       kJ/mol        


+1.000Sr+2     +2.000F-          = SrF2
     log_k     2.02         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +1.000I-          = SrI+
     log_k     0.14         #estimation NEA87     01/02/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +2.000I-          = SrI2
     log_k    -0.04         #estimation NEA87     01/02/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +1.000NH3          = Sr(NH3)+2
     log_k    -0.55         #estimation NEA87     08/02/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +1.000NO3-          = Sr(NO3)+
     log_k     0.6          #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +2.000NO3-          = Sr(NO3)2
     log_k     0.31         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +1.000IO3-          = Sr(IO3)+
     log_k     0.33         #estimation NEA87     01/02/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +2.000IO3-          = Sr(IO3)2
     log_k    -0.55         #estimation NEA87     01/02/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +1.000Cn-          = Sr(Cn)+
     log_k     0.71         #estimation NEA87     08/02/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +2.000Cn-          = Sr(Cn)2
     log_k     0.2          #estimation NEA87     08/02/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000K+     +1.000SO4-2          = K(SO4)-
     log_k     0.88         #97SVE/SHO
     delta_h   2.949        kJ/mol        #
     # Enthalpy of formation:             -1158.531     kJ/mol        


+1.000K+     +1.000I-          = KI
     log_k    -1.57         #estimation NEA87     08/2/95
     delta_h   9.011        kJ/mol        #
     # Enthalpy of formation:             -299.909      kJ/mol        


+1.000K+     -1.000H+     +1.000H2(PO4)-          = K(HPO4)-
     log_k    -6.4          #97MAR/SMI
     delta_h   31.589       kJ/mol        #97MAR/SMI
     # Enthalpy of formation:             -1523.151     kJ/mol        


+1.000K+     +1.000Pyrophos-4          = K(Pyrophos)-3
     log_k     2.1          #76MAR/SMI
     delta_h   7.113        kJ/mol        #76MAR/SMI
     # Enthalpy of formation:             -2531.921     kJ/mol        


+1.000K+     +1.000IO3-          = K(IO3)
     log_k     0.02         #estimation NEA87     08/2/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Na+     +1.000CO3-2          = Na(CO3)-
     log_k     1.27         #90NOR/PLU
     delta_h   37.279       kJ/mol        #90NOR/PLU
     # Enthalpy of formation:             -878.291      kJ/mol        


+1.000Na+     +1.000SO4-2          = Na(SO4)-
     log_k     0.94         #99cap/hef
     delta_h  -2.81         kJ/mol        #
     # Enthalpy of formation:             -1152.49      kJ/mol        


+1.000Mg+2     +1.000Cl-          = MgCl+
     log_k     0.35         #96BOU
     delta_h  -1.729        kJ/mol        #
     # Enthalpy of formation:             -635.809      kJ/mol        


+1.000Na+     +1.000I-          = NaI
     log_k    -1.52         #estimation NEA87     08/2/95
     delta_h   7.252        kJ/mol        #
     # Enthalpy of formation:             -289.868      kJ/mol        


+1.000Al+3     +1.000Ox-2          = Al(Ox)+
     log_k     9.4          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     +2.000Ox-2          = Al(Ox)2-
     log_k     15.39        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     +3.000Ox-2          = Al(Ox)3-3
     log_k     18.3         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000Al+3     -2.000H+     +4.000Ox-2     +2.000H2O          = Al2(Ox)4(OH)2-4
     log_k    -6            #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000Al+3     -3.000H+     +3.000Ox-2     +3.000H2O          = Al3(Ox)3(OH)3
     log_k     16           #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+4.000Al+3     -4.000H+     +4.000Ox-2     +4.000H2O          = Al4(Ox)4(OH)4
     log_k     21           #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     +1.000H+     +1.000Cit-3          = Al(HCit)+
     log_k     12.9         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     +1.000Cit-3          = Al(Cit)
     log_k     9.9          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     -1.000H+     +1.000Cit-3     +1.000H2O          = Al(OH)(Cit)-
     log_k     8.1          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     +2.000Cit-3          = Al(Cit)2-3
     log_k     14.13        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     -1.000H+     +2.000Cit-3     +1.000H2O          = Al(Cit)2(OH)-4
     log_k     10.19        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000Al+3     -4.000H+     +3.000Cit-3     +4.000H2O          = Al3(Cit)3(OH)4-4
     log_k     20.6         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     +1.000Nta-3          = Al(Nta)
     log_k     13.23        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     +1.000H+     +1.000Nta-3          = Al(HNta)+
     log_k     15.13        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     -1.000H+     +1.000Nta-3     +1.000H2O          = Al(OH)(Nta)-
     log_k     6.79         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     -2.000H+     +1.000Nta-3     +2.000H2O          = Al(Nta)(OH)2-2
     log_k    -0.3          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     +2.000Nta-3          = Al(Nta)2-3
     log_k     20.8         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     +1.000H+     +1.000Edta-4          = Al(HEdta)
     log_k     21.82        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     +1.000Edta-4          = Al(Edta)-
     log_k     19.08        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     -1.000H+     +1.000Edta-4     +1.000H2O          = Al(OH)(Edta)-2
     log_k     13           #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Na+     +1.000S2O3-2          = Na(S2O3)-
     log_k     0.61         #
     delta_h   4.656        kJ/mol        #
     # Enthalpy of formation:             -887.97       kJ/mol        82WAG/EVA


+1.000Al+3     -2.000H+     +1.000Edta-4     +2.000H2O          = Al(OH)2(Edta)-3
     log_k     2.3          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     -2.000H+     +1.000F-     +2.000H2O          = Al(OH)2F
     log_k    -4.21         #
     delta_h   118.636      kJ/mol        #
     # Enthalpy of formation:             -1326.774     kJ/mol        01TAG/SCH


+1.000Al+3     -2.000H+     +2.000F-     +2.000H2O          = Al(OH)2F2-
     log_k    -1.99         #
     delta_h   134.839      kJ/mol        #
     # Enthalpy of formation:             -1645.921     kJ/mol        01TAG/SCH


+1.000Al+3     -1.000H+     +1.000H4(SiO4)          = AlH3SiO4+2
     log_k    -2.38         #01TAG/SCH
     delta_h   77.389       kJ/mol        #
     # Enthalpy of formation:             -1922.205     kJ/mol        


+1.000Al+3     -1.000H+     +2.000F-     +1.000H2O          = AlOHF2
     log_k     0.21         #
     delta_h   139.337      kJ/mol        #
     # Enthalpy of formation:             -1355.593     kJ/mol        01TAG/SCH


+1.000Na+     +1.000Al+3     -4.000H+     +4.000H2O          = NaAl(OH)4
     log_k    -23.63        #
     delta_h   190.348      kJ/mol        #
     # Enthalpy of formation:             -1731.712     kJ/mol        95POK/HEL


+1.000Al+3     +1.000H+     +1.000Ox-2          = Al(HOx)+2
     log_k     7.5          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Na+     +1.000IO3-          = Na(IO3)
     log_k     0.06         #estimation NEA87     08/2/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000SO4-2          = Fe(SO4)+
     log_k     4.1          #95BOU in 98CHI
     delta_h   16.359       kJ/mol        #
     # Enthalpy of formation:             -941.981      kJ/mol        


+1.000Fe+3     +1.000Cl-          = FeCl+2
     log_k     1.4          #95BOU in 98CHI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +2.000Cl-          = FeCl2+
     log_k     2.1          #95BOU in 98CHI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mg+2     -1.000H+     +1.000H4(SiO4)          = Mg(H3SiO4)+
     log_k    -8.58         #97SVE/SHO
     delta_h   27.114       kJ/mol        #
     # Enthalpy of formation:             -1901.08      kJ/mol        


+1.000Cs+     +1.000Cit-3          = Cs(Cit)-2
     log_k     0.98         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mg+2     +1.000Br-          = MgBr+
     log_k    -0.14         #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cs+     +1.000Edta-4          = Cs(Edta)-3
     log_k     1.3          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cs+     +1.000Nta-3          = Cs(Nta)-2
     log_k     0.85         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cs+     +1.000Br-          = CsBr
     log_k     0.09         #
     delta_h   5.922        kJ/mol        #
     # Enthalpy of formation:             -373.488      kJ/mol        


+1.000Mg+2     +1.000SeO4-2          = Mg(SeO4)
     log_k     2.2          #05OLI/NOL
     delta_h  -6.614        kJ/mol        #
     # Enthalpy of formation:             -1077.114     kJ/mol        


+1.000NpO2+2     -2.000H+     +2.000H2(PO4)-          = NpO2(HPO4)2-2
     log_k    -4.92         #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NpO2+2     +1.000Nta-3          = NpO2(Nta)-
     log_k     11           #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NpO2+2     +1.000H2(PO4)-          = NpO2H2PO4+
     log_k     3.32         #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000NpO2+2     -5.000H+     +5.000H2O          = (NpO2)3(OH)5+
     log_k    -17.12        #01LEM/FUG
     delta_h   110.667      kJ/mol        #
     # Enthalpy of formation:             -3900.682     kJ/mol        


+1.000TcO(OH)2     +1.000H+     +1.000Nta-3     -1.000H2O          = TcO(OH)(Nta)-2
     log_k     13.3         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000TcO(OH)2     +1.000H+     +1.000CO3-2          = Tc(OH)3CO3-
     log_k     10.96        #99RAR/RAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000TcO(OH)2     +2.000H+     -2.000H2O          = TcO+2
     log_k     2.58         #97NGU/LAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000TcO(OH)2     +1.000H+     +2.000Nta-3     -1.000H2O          = TcO(OH)(Nta)2-5
     log_k     11.7         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000TcO(OH)2     +1.000H+     +1.000Edta-4     -1.000H2O          = TcO(OH)(Edta)-3
     log_k     19           #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000TcO(OH)2     -4.000H+     -3.000e-     +1.000H2O          = TcO4-
     log_k    -29.43        #
     delta_h   305.75       kJ/mol        #
     # Enthalpy of formation:             -729.4        kJ/mol        99RAR/RAN


+1.000Eu+3     +3.000CO3-2          = Eu(CO3)3-3
     log_k     14.8         #05VER/VIT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Eu+3     +1.000e-          = Eu+2
     log_k    -5.97         #
     delta_h   77.729       kJ/mol        #
     # Enthalpy of formation:             -527.602      kJ/mol        92JOH/OEL


+1.000Eu+3     -1.000H+     +1.000H4(SiO4)          = EuSiO(OH)3+2
     log_k    -2.62         #Original data 07THA/SIN and 96JEN/CHO
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Eu+3     +1.000NO3-          = Eu(NO3)+2
     log_k     0.8          #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Eu+3     +3.000F-          = EuF3
     log_k     10.6         #95SPA/BRU
     delta_h  -8.343        kJ/mol        #
     # Enthalpy of formation:             -1619.724     kJ/mol        


+1.000Ba+2     +1.000CO3-2          = Ba(CO3)
     log_k     2.71         #86BUS/PLU
     delta_h   14.841       kJ/mol        #86BUS/PLU
     # Enthalpy of formation:             -1195.189     kJ/mol        


+1.000Ba+2     +1.000SO4-2          = Ba(SO4)
     log_k     2.7          #76SMI/MAR
     delta_h   7.367        kJ/mol        #
     # Enthalpy of formation:             -1436.773     kJ/mol        


+1.000Fe+3     +1.000F-          = FeF+2
     log_k     6.13         #92PEA/BER in 98CHI
     delta_h   11.297       kJ/mol        #
     # Enthalpy of formation:             -373.053      kJ/mol        


+1.000Fe+3     +2.000F-          = FeF2+
     log_k     10.8         #92PEA/BER in 98CHI
     delta_h   19.665       kJ/mol        #
     # Enthalpy of formation:             -700.035      kJ/mol        


+1.000Mg+2     +2.000I-          = MgI2
     log_k     0.03         #estimation NEA87     08/2/95 ;
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +3.000F-          = FeF3
     log_k     14           #92PEA/BER in 98CHI
     delta_h   22.595       kJ/mol        #
     # Enthalpy of formation:             -1032.455     kJ/mol        


+1.000Fe+3     -1.000H+     +1.000H2(PO4)-          = Fe(HPO4)+
     log_k     1.63         #ANDRA, CRP OHEM 95.002, X. BOURBON, janvier1996; Sélection de données thermodynamiques afférentes aux corrections de Température sur les principaux équilibres chimiques en milieu naturel
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000H2(PO4)-          = Fe(H2PO4)+2
     log_k     5.42         #USGS original
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     -1.000H+     +1.000H4(SiO4)          = Fe(H3SiO4)+2
     log_k     0.36         #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +1.000Ox-2          = Sn(Ox)
     log_k     6.5          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +1.000H+     +1.000CO3-2          = SnHCO3+
     log_k     14.9         #87BRO/WAN estimated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +2.000Ox-2          = Sn(Ox)2-2
     log_k     12.9         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     -1.000H+     +1.000Cl-     +1.000H2O          = Sn(OH)Cl
     log_k    -3.1          #52VAN/RHO recalculated in 02HUM/BER
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +3.000Ox-2          = Sn(Ox)3-4
     log_k     17.1         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +1.000Cit-3          = Sn(Cit)-
     log_k     8.7          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +2.000Cit-3          = Sn(Cit)2-4
     log_k     11.9         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +1.000Nta-3          = Sn(Nta)-
     log_k     13.4         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +2.000H+     +1.000Edta-4          = Sn(H2Edta)
     log_k     24.3         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +1.000H+     +1.000Edta-4          = Sn(HEdta)-
     log_k     23.4         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +1.000Edta-4          = Sn(Edta)-2
     log_k     24.6         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +2.000CO3-2          = Sn(CO3)2-2
     log_k     17.85        #87BRO/WAN estimated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +1.000CO3-2          = Sn(CO3)
     log_k     9.72         #87BRO/WAN estimated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     -1.000H+     +1.000H2(PO4)-          = SnHPO4
     log_k     2.29         #00CIA/MUL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     -2.000H+     +1.000H2(PO4)-          = SnPO4-
     log_k    -1.56         #00CIA/MUL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +4.000Cl-          = SnCl4-2
     log_k     3.33         #62HAI/ZOL in 99LOT/OCH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000H+     +1.000SeO3-2          = Fe(HSeO3)+2
     log_k     12.35        #01SEB/POT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     -1.000H+     +1.000H2O          = Fe(OH)+2
     log_k    -2.19         #76BAE/MES in 98CHI
     delta_h   43.514       kJ/mol        #
     # Enthalpy of formation:             -291.316      kJ/mol        


+1.000Fe+3     -2.000H+     +2.000H2O          = Fe(OH)2+
     log_k    -5.67         #76BAE/MES in 98CHI
     delta_h   71.546       kJ/mol        #
     # Enthalpy of formation:             -549.114      kJ/mol        


+1.000Fe+3     -3.000H+     +3.000H2O          = Fe(OH)3
     log_k    -12.56        #91PEA/VER in 98CHI
     delta_h   103.764      kJ/mol        #
     # Enthalpy of formation:             -802.726      kJ/mol        


+1.000Fe+3     -4.000H+     +4.000H2O          = Fe(OH)4-
     log_k    -21.6         #76BAE/MES in 76CHI
     delta_h   133.471      kJ/mol        #
     # Enthalpy of formation:             -1058.849     kJ/mol        


+1.000Sn+4     +4.000CO3-2          = Sn(CO3)4-4
     log_k     38.14        #87BRO/WAN estimated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+4     +5.000CO3-2          = Sn(CO3)5-6
     log_k     44.47        #87BRO/WAN estimated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+4     +2.000Cl-          = SnCl2+2
     log_k     10.22        #78FAT/ROU recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+4     +3.000Cl-          = SnCl3+
     log_k     13.62        #78FAT/ROU recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+4     +4.000Cl-          = SnCl4
     log_k     14.85        #78FAT/ROU recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+4     +5.000Cl-          = SnCl5-
     log_k     16.6         #78FAT/ROU recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+4     +6.000Cl-          = SnCl6-2
     log_k     17.24        #78FAT/ROU recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000Fe+3     -2.000H+     +2.000H2O          = Fe2(OH)2+4
     log_k    -2.95         #91PEA/BER in 98CHI
     delta_h   56.484       kJ/mol        #
     # Enthalpy of formation:             -613.175      kJ/mol        


+1.000Fe+2     +1.000Cl-          = FeCl+
     log_k     0.14         #91PEA/BER in 98CHI
     delta_h  -0.078        kJ/mol        #
     # Enthalpy of formation:             -257.158      kJ/mol        


+1.000Fe+2     -1.000H+     +1.000H2(PO4)-          = Fe(HPO4)
     log_k    -3.61         #USGS original
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +1.000H2(PO4)-          = Fe(H2PO4)+
     log_k     2.69         #USGS original
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +1.000H+     +1.000Ox-2          = Th(HOx)+3
     log_k     11           #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +1.000Ox-2          = Th(Ox)+2
     log_k     9.8          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +2.000H+     +2.000Ox-2          = Th(HOx)2+2
     log_k     18.13        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +2.000Ox-2          = Th(Ox)2
     log_k     17.5         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +3.000Ox-2          = Th(Ox)3-2
     log_k     26.4         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +4.000Ox-2          = Th(Ox)4-4
     log_k     29.6         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +4.000H+     +4.000Ox-2          = Th(HOx)4
     log_k     24.3         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000Th+4     -1.000H+     +1.000Ox-2     +1.000H2O          = Th2(Ox)(OH)+5
     log_k     26.24        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +1.000Cit-3          = Th(Cit)+
     log_k     16.8         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +2.000Cit-3          = Th(Cit)2-2
     log_k     25.8         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +1.000Nta-3          = Th(Nta)+
     log_k     17.15        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     -1.000H+     +1.000Nta-3     +1.000H2O          = Th(OH)(Nta)
     log_k     25.2         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     -2.000H+     +1.000Nta-3     +2.000H2O          = Th(OH)2(Nta)-
     log_k     35.2         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +1.000H+     +1.000Edta-4          = Th(HEdta)+
     log_k     28.7         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +1.000Edta-4          = Th(Edta)
     log_k     26.95        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     -1.000H+     +1.000Edta-4     +1.000H2O          = Th(OH)(Edta)-
     log_k     19.5         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+4.000Th+4     -12.000H+     +12.000H2O          = Th4(OH)12+4
     log_k    -26.6         #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +3.000SO4-2          = Th(SO4)3-2
     log_k     10.75        #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     -1.000H+     +4.000CO3-2     +1.000H2O          = Th(OH)(CO3)4-5
     log_k     21.6         #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     -2.000H+     +1.000CO3-2     +2.000H2O          = Th(OH)2(CO3)
     log_k     2.5          #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     -2.000H+     +2.000CO3-2     +2.000H2O          = Th(OH)2(CO3)2-2
     log_k     8.8          #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     -4.000H+     +1.000CO3-2     +4.000H2O          = Th(OH)4(CO3)-2
     log_k    -15.6         #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     -3.000H+     +1.000HIsa-     +3.000H2O          = Th(OH)3(HIsa)
     log_k    -5.65         #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     -3.000H+     +2.000HIsa-     +3.000H2O          = Th(OH)3(HIsa)2-
     log_k    -3.5          #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     -4.000H+     +1.000HIsa-     +4.000H2O          = Th(OH)4(HIsa)-
     log_k    -11.4         #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     -4.000H+     +2.000HIsa-     +4.000H2O          = Th(OH)4(HIsa)2-2
     log_k    -11.4         #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ca+2     +1.000Th+4     -4.000H+     +2.000HIsa-     +4.000H2O          = CaTh(OH)4(HIsa)2
     log_k    -3.6          #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     -3.000H+     +1.000HGlu-     +3.000H2O          = Th(OH)3(HGlu)
     log_k    -6.7          #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     -4.000H+     +1.000HGlu-     +4.000H2O          = Th(OH)4(HGlu)-
     log_k    -13.2         #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     -5.000H+     +1.000HGlu-     +4.000H2O          = Th(OH)4(Glu)-2
     log_k    -22.4         #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000Th+4     -2.000H+     +2.000Edta-4     +2.000H2O          = (Th(OH)(Edta))2-2
     log_k     43.7         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     -1.000H+     +1.000H4(SiO4)          = UO2SiO(OH)3+
     log_k    -1.84         #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000UO2+2     +2.000Cit-3          = (UO2)2(Cit)2-2
     log_k     21.3         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+11.000UO2+2     -12.000H+     +6.000CO3-2     +12.000H2O          = (UO2)11(CO3)6(OH)12-2
     log_k     36.43        #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     -6.000H+     -6.000e-     +1.000Br-     +3.000H2O          = UO2BrO3+
     log_k    -145.54       #92GRE/FUG
     delta_h   912.3        kJ/mol        #
     # Enthalpy of formation:             -1085.6       kJ/mol        


+1.000UO2+2     -6.000H+     -6.000e-     +1.000Cl-     +3.000H2O          = UO2ClO3+
     log_k    -145.74       #92GRE/FUG
     delta_h   916.67       kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -1126.9       kJ/mol        


+1.000UO2+2     +1.000Ox-2          = UO2(Ox)
     log_k     7.13         #05HUM/AND
     delta_h   25.36        kJ/mol        #
     # Enthalpy of formation:             -1824.3       kJ/mol        05HUM/AND


+1.000UO2+2     +2.000Ox-2          = UO2(Ox)2-2
     log_k     11.65        #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     +3.000Ox-2          = UO2(Ox)3-4
     log_k     13.8         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     +1.000H+     +1.000Cit-3          = UO2(HCit)
     log_k     11.36        #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     +1.000Cit-3          = UO2(Cit)-
     log_k     8.96         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     +1.000H+     +1.000Nta-3          = UO2(HNta)
     log_k     9            #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     +1.000Nta-3          = UO2(Nta)-
     log_k     10.8         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     +1.000H+     +1.000Edta-4          = UO2(HEdta)-
     log_k     19.61        #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     +1.000Edta-4          = UO2(Edta)-2
     log_k     13.7         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000UO2+2     +1.000Edta-4          = (UO2)2(Edta)
     log_k     20.6         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     +3.000SO4-2          = UO2(SO4)3-4
     log_k     3.02         #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     +2.000SeO4-2          = UO2(SeO4)2-2
     log_k     3.1          #99DJO/PIZ recalculated in 05OLI/NOL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     -6.000H+     -6.000e-     +1.000I-     +3.000H2O          = UO2IO3+
     log_k    -109.56       #92GRE/FUG
     delta_h   704.37       kJ/mol        #
     # Enthalpy of formation:             -1228.9       kJ/mol        


+1.000UO2+2     -12.000H+     -12.000e-     +2.000I-     +6.000H2O          = UO2(IO3)2
     log_k    -219.54       #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     +1.000HIsa-          = UO2(HIsa)+
     log_k     3.7          #04RAO/GAR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     +2.000HIsa-          = UO2(HIsa)2
     log_k     6.6          #04RAO/GAR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     +3.000HIsa-          = UO2(HIsa)3-
     log_k     8.5          #04RAO/GAR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     -4.000H+     +1.000HIsa-     +4.000H2O          = UO2(OH)4(HIsa)-3
     log_k    -28.1         #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     -1.000H+     +1.000H2O          = Fe(OH)+
     log_k    -9.5          #76BAE/MES in 99CHIa
     delta_h   55.304       kJ/mol        #
     # Enthalpy of formation:             -320.526      kJ/mol        


+1.000Fe+2     +1.000SeO4-2          = Fe(SeO4)
     log_k     2.71         #01SEB/POT
     delta_h  -12.601       kJ/mol        #
     # Enthalpy of formation:             -706.101      kJ/mol        


+1.000Mn+2     +1.000H+     +1.000CO3-2          = Mn(HCO3)+
     log_k     11.61        #95CHI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +1.000SO4-2          = Mn(SO4)
     log_k     2.25         #95CHI
     delta_h   14.1         kJ/mol        #
     # Enthalpy of formation:             -1115.99      kJ/mol        


+1.000Mn+2     +1.000Cl-          = MnCl+
     log_k     0.3          #
     delta_h   18.466       kJ/mol        #
     # Enthalpy of formation:             -369.364      kJ/mol        


+1.000Mn+2     +2.000Cl-          = MnCl2
     log_k     0.25         #NAGRA, TR 91-18; F.J. PEARSON, U. BERNER, W. HUMMEL; Nagra thermochemical data base, supplemental data 05/92 (provient de la base 0391 MINEQL- PSY)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +3.000Cl-          = MnCl3-
     log_k    -0.31         #NAGRA, TR 91-18; F.J. PEARSON, U. BERNER, W. HUMMEL; Nagra thermochemical data base, supplemental data 05/92 (provient de la base 0391 MINEQL- PSY)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +1.000I-          = MnI+
     log_k     0.23         #estimation NEA87     08/2/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +1.000NH3          = Mn(NH3)+2
     log_k     0.7          #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +2.000NH3          = Mn(NH3)2+2
     log_k     1.2          #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     -1.000H+     +1.000H2(PO4)-          = Mn(HPO4)
     log_k    -3.26         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +1.000Pyrophos-4          = Mn(Pyrophos)-2
     log_k     6            #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +1.000S2O3-2          = Mn(S2O3)
     log_k     1.9          #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000PuO2+2     +1.000NO3-          = PuO2NO3+
     log_k     0.3          #In analogy to U
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000PuO2+2     +1.000Ox-2          = PuO2(Ox)
     log_k     7            #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000PuO2+2     +2.000Ox-2          = PuO2(Ox)2-2
     log_k     10.5         #73POR/PAO in 96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000PuO2+2     +1.000Nta-3          = PuO2(Nta)-
     log_k     11           #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000PuO2+     -1.000H+     +1.000H2O          = PuO2OH
     log_k    -11.3         #01LEM/FUG
     delta_h   71.826       kJ/mol        #
     # Enthalpy of formation:             -1124.131     kJ/mol        


+1.000PuO2+     +1.000CO3-2          = PuO2CO3-
     log_k     5.12         #01LEM/FUG
     delta_h   44.874       kJ/mol        #
     # Enthalpy of formation:             -1540.483     kJ/mol        


+1.000PuO2+     +1.000Nta-3          = PuO2(Nta)-2
     log_k     7.5          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000PuO2+     +4.000H+     +1.000e-     -2.000H2O          = Pu+4
     log_k     17.45        #
     delta_h  -201.428      kJ/mol        #
     # Enthalpy of formation:             -539.895      kJ/mol        01LEM/FUG


+1.000Pu+4     +1.000Ox-2          = Pu(Ox)+2
     log_k     11.4         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     +2.000Ox-2          = Pu(Ox)2
     log_k     20.6         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     +3.000Ox-2          = Pu(Ox)3-2
     log_k     26.5         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     +4.000Ox-2          = Pu(Ox)4-4
     log_k     28.3         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     +1.000Nta-3          = Pu(Nta)+
     log_k     21           #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     +1.000Edta-4          = Pu(Edta)
     log_k     31.8         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     -2.000H+     +2.000CO3-2     +2.000H2O          = Pu(CO3)2(OH)2-2
     log_k     16.76        #99RAI/HES
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     +1.000H+     +1.000H2(PO4)-          = PuH3PO4+4
     log_k     4.54         #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     -3.000H+     +1.000HIsa-     +3.000H2O          = Pu(OH)3(HIsa)
     log_k     4.75         #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     -3.000H+     +2.000HIsa-     +3.000H2O          = Pu(OH)3(HIsa)2-
     log_k     6.86         #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     -4.000H+     +1.000HIsa-     +4.000H2O          = Pu(OH)4(HIsa)-
     log_k    -3.6          #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     -4.000H+     +2.000HIsa-     +4.000H2O          = Pu(OH)4(HIsa)2-2
     log_k     0.7          #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     -3.000H+     +1.000HGlu-     +3.000H2O          = Pu(OH)3(HGlu)
     log_k     4.75         #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     -4.000H+     +1.000HGlu-     +4.000H2O          = Pu(OH)4(HGlu)-
     log_k    -2.7          #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+3     -2.000H+     +1.000H2(PO4)-          = PuPO4
     log_k    -7.92         #Estimated by correlation with An(III) in function of ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+3     -4.000H+     +2.000H2(PO4)-          = Pu(PO4)2-3
     log_k    -19.73        #Estimated by correlation with An(III) in function of ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+3     +1.000Nta-3          = Pu(Nta)
     log_k     13.1         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+3     +1.000H+     +1.000Edta-4          = Pu(HEdta)
     log_k     22.02        #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+3     +1.000Edta-4          = Pu(Edta)-
     log_k     20.18        #05HUM/AND
     delta_h  -8.7          kJ/mol        #
     # Enthalpy of formation:             -2305.29      kJ/mol        


+1.000Mn+2     +1.000Scn-          = Mn(Scn)+
     log_k     1.4          #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +1.000IO3-          = Mn(IO3)+
     log_k     0.84         #estimation NEA87     08/2/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +2.000IO3-          = Mn(IO3)2
     log_k     0.13         #estimation NEA87     08/2/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +1.000SeO4-2          = Mn(SeO4)
     log_k     2.43         #05OLI/NOL
     delta_h  -1.282        kJ/mol        #
     # Enthalpy of formation:             -825.582      kJ/mol        


+1.000Mn+2     -1.000H+     +1.000H2O          = Mn(OH)+
     log_k    -10.59        #95CHI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     -3.000H+     +3.000H2O          = Mn(OH)3-
     log_k    -34.8         #95CHI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000U+4     -2.000H+     +2.000H2O          = U(OH)2+2
     log_k    -1.1          #01NEC/KIM
     delta_h   59.974       kJ/mol        #
     # Enthalpy of formation:             -1102.886     kJ/mol        


+1.000U+4     -3.000H+     +3.000H2O          = U(OH)3+
     log_k    -4.7          #01NEC/KIM
     delta_h   82.944       kJ/mol        #
     # Enthalpy of formation:             -1365.746     kJ/mol        


+1.000U+4     +1.000Nta-3          = U(Nta)+
     log_k     20           #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000U+4     +1.000Edta-4          = U(Edta)
     log_k     29.5         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000U+4     -1.000H+     +1.000Edta-4     +1.000H2O          = U(OH)(Edta)-
     log_k     24.6         #63ERM/KRO
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000U+4     -3.000H+     +1.000HIsa-     +3.000H2O          = U(OH)3(HIsa)
     log_k     0.29         #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000U+4     -3.000H+     +2.000HIsa-     +3.000H2O          = U(OH)3(HIsa)2-
     log_k     2.4          #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000U+4     -4.000H+     +1.000HIsa-     +4.000H2O          = U(OH)4(HIsa)-
     log_k    -6.7          #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000U+4     -4.000H+     +2.000HIsa-     +4.000H2O          = U(OH)4(HIsa)2-2
     log_k    -5.1          #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000U+4     -3.000H+     +1.000HGlu-     +3.000H2O          = U(OH)3(HGlu)
     log_k     0.29         #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000U+4     -4.000H+     +1.000HGlu-     +4.000H2O          = U(OH)4(HGlu)-
     log_k    -5.94         #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000U+4     -2.000H+     +1.000Edta-4     +2.000H2O          = U(OH)2(Edta)-2
     log_k     16.5         #63ERM/KRO
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000U+4     -2.000H+     +2.000Edta-4     +2.000H2O          = (U(OH)(Edta))2-2
     log_k     51.7         #63ERM/KRO
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000K+     -1.000H+     +1.000H2O          = K(OH)
     log_k    -14.46        #76BAE/MES
     delta_h   66.438       kJ/mol        #
     # Enthalpy of formation:             -471.532      kJ/mol        


+1.000K+     +1.000NO3-          = K(NO3)
     log_k    -0.15         #88CAH/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+3     -2.000H+     +1.000H2(PO4)-          = NpPO4
     log_k    -7.83         #Estimated by correlation with An(III) in function of ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+3     -4.000H+     +2.000H2(PO4)-          = Np(PO4)2-3
     log_k    -19.57        #Estimated by correlation with An(III) in function of ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+3     -1.000H+     +1.000H2(PO4)-          = NpHPO4+
     log_k    -1.78         #Estimated by correlation with An(III) in function of ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+3     +1.000Nta-3          = Np(Nta)
     log_k     13           #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+3     +1.000Edta-4          = Np(Edta)-
     log_k     19.9         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+3     -2.000H+     +2.000H2(PO4)-          = Np(HPO4)2-
     log_k    -5.38         #Estimated by correlation with An(III) in function of ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     -2.000H+     +2.000H2O          = Np(OH)2+2
     log_k     0.35         #03GUI/FAN
     delta_h   54.53        kJ/mol        #
     # Enthalpy of formation:             -1073.152     kJ/mol        


+1.000Np+4     -3.000H+     +3.000H2O          = Np(OH)3+
     log_k    -2.8          #01NEC/KIM, 99NEC
     delta_h   74.932       kJ/mol        #
     # Enthalpy of formation:             -1338.58      kJ/mol        


+1.000Np+4     -4.000H+     +1.000CO3-2     +4.000H2O          = Np(OH)4(CO3)-2
     log_k    -6.83         #93ERI/NDA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     -2.000H+     +2.000CO3-2     +2.000H2O          = Np(OH)2(CO3)2-2
     log_k     15.17        #99RAI/HES
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     +1.000Br-          = NpBr+3
     log_k     1.55         #Estimated by correlation with An(IV) in function of ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     +1.000Ox-2          = Np(Ox)+2
     log_k     12.4         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     +1.000Nta-3          = Np(Nta)+
     log_k     20.7         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     +2.000Nta-3          = Np(Nta)2-2
     log_k     36.3         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     +1.000Edta-4          = Np(Edta)
     log_k     31.2         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     -4.000H+     +1.000HIsa-     +4.000H2O          = Np(OH)4(HIsa)-
     log_k    -4.06         #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     -4.000H+     +2.000HIsa-     +4.000H2O          = Np(OH)4(HIsa)2-2
     log_k    -2.2          #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     -3.000H+     +1.000HIsa-     +3.000H2O          = Np(OH)3(HIsa)
     log_k     3.27         #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     -3.000H+     +2.000HIsa-     +3.000H2O          = Np(OH)3(HIsa)2-
     log_k     5.38         #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     -3.000H+     +1.000HGlu-     +3.000H2O          = Np(OH)3(HGlu)
     log_k     3.27         #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     -4.000H+     +1.000HGlu-     +4.000H2O          = Np(OH)4(HGlu)-
     log_k    -3.7          #06GAO/MON
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NpO2+     -2.000H+     +2.000H2O          = NpO2(OH)2-
     log_k    -23.6         #01LEM/FUG
     delta_h   118.61       kJ/mol        #
     # Enthalpy of formation:             -1431.23      kJ/mol        


+1.000NpO2+     -1.000H+     +2.000CO3-2     +1.000H2O          = NpO2(CO3)2OH-4
     log_k    -5.31         #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NpO2+     +1.000Ox-2          = NpO2(Ox)-
     log_k     3.9          #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NpO2+     +2.000Ox-2          = NpO2(Ox)2-3
     log_k     5.8          #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NpO2+     +1.000Cit-3          = NpO2(Cit)-2
     log_k     3.68         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NpO2+     +1.000H+     +1.000Nta-3          = NpO2(HNta)-
     log_k     11.7         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NpO2+     +1.000Nta-3          = NpO2(Nta)-2
     log_k     7.46         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NpO2+     -1.000H+     +1.000Nta-3     +1.000H2O          = NpO2(OH)(Nta)-3
     log_k    -4.7          #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NpO2+     +1.000H+     +1.000Edta-4          = NpO2(HEdta)-2
     log_k     17.06        #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NpO2+     +1.000Edta-4          = NpO2(Edta)-3
     log_k     9.23         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NpO2+     +4.000H+     +1.000e-     -2.000H2O          = Np+4
     log_k     10.21        #
     delta_h  -149.501      kJ/mol        #
     # Enthalpy of formation:             -556.022      kJ/mol        01LEM/FUG


+1.000NpO2+     -1.000H+     +1.000H2(PO4)-          = NpO2HPO4-
     log_k    -4.26         #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NpO2+     +2.000H+     +1.000Edta-4          = NpO2(H2Edta)-
     log_k     22.51        #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000NpO2+2     -3.000H+     +1.000CO3-2     +3.000H2O          = (NpO2)2CO3(OH)3-
     log_k    -2.87         #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ba+2     +1.000Cl-          = BaCl+
     log_k     0.06         #
     delta_h   11.479       kJ/mol        #
     # Enthalpy of formation:             -690.399      kJ/mol        97SVE/SHO


+1.000Sm+3     +3.000CO3-2          = Sm(CO3)3-3
     log_k     14.8         #05VER/VIT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+10.000H+     +8.000e-     +2.000SO4-2     -5.000H2O          = S2O3-2
     log_k     38.56        #
     delta_h  -262.756      kJ/mol        #
     # Enthalpy of formation:             -652.286      kJ/mol        04CHI


+8.000H+     +6.000e-     +2.000SO4-2     -4.000H2O          = S2O4-2
     log_k     10.7         #
     delta_h  -78.14        kJ/mol        #
     # Enthalpy of formation:             -735.5        kJ/mol        82WAG/EVA


+4.000H+     +2.000e-     +1.000SO4-2     -2.000H2O          = SO2
     log_k     5.41         #
     delta_h   13.9         kJ/mol        #
     # Enthalpy of formation:             -323.78       kJ/mol        85GOL/PAR


+16.000H+     +14.000e-     +2.000SO4-2     -8.000H2O          = S2-2
     log_k     56.85        #
     delta_h  -432.92       kJ/mol        #
     # Enthalpy of formation:              35.04        kJ/mol        04CHI


+24.000H+     +20.000e-     +3.000SO4-2     -12.000H2O          = S3-2
     log_k     94.57        #
     delta_h  -676          kJ/mol        #
     # Enthalpy of formation:              25.94        kJ/mol        74NAU/RYZ


+32.000H+     +26.000e-     +4.000SO4-2     -16.000H2O          = S4-2
     log_k     131.19       #
     delta_h  -912.91       kJ/mol        #
     # Enthalpy of formation:              23.01        kJ/mol        74NAU/RYZ


+40.000H+     +32.000e-     +5.000SO4-2     -20.000H2O          = S5-2
     log_k     167.59       #
     delta_h  -1148.56      kJ/mol        #
     # Enthalpy of formation:              21.34        kJ/mol        74NAU/RYZ


+12.000H+     +8.000e-     +3.000SO4-2     -6.000H2O          = S3O6-2
     log_k     25.96        #
     delta_h  -154.296      kJ/mol        #
     # Enthalpy of formation:             -1167.336     kJ/mol        04CHI


+20.000H+     +14.000e-     +4.000SO4-2     -10.000H2O          = S4O6-2
     log_k     76.32        #
     delta_h  -445.178      kJ/mol        #
     # Enthalpy of formation:             -1224.238     kJ/mol        04CHI


+28.000H+     +20.000e-     +5.000SO4-2     -14.000H2O          = S5O6-2
     log_k     97.28        #
     delta_h  -630.624      kJ/mol        #
     # Enthalpy of formation:             -1175.704     kJ/mol        04CHI


-2.000e-     +2.000SO4-2          = S2O8-2
     log_k    -65.38        #
     delta_h   473.98       kJ/mol        #
     # Enthalpy of formation:             -1344.7       kJ/mol        82WAG/EVA


-1.000H+     -2.000e-     +1.000SO4-2     +1.000H2O          = HSO5-
     log_k    -60.21        #
     delta_h   419.54       kJ/mol        #
     # Enthalpy of formation:             -775.63       kJ/mol        88SHO/HEL


+9.000H+     +8.000e-     +1.000SO4-2     -4.000H2O          = HS-
     log_k     33.69        #
     delta_h  -250.28       kJ/mol        #
     # Enthalpy of formation:             -16.3         kJ/mol        89COX/WAG


-2.000e-     +2.000Cl-          = Cl2
     log_k    -47.21        #
     delta_h   310.76       kJ/mol        #
     # Enthalpy of formation:             -23.4         kJ/mol        82WAG/EVA


+1.000Ho+3     +2.000Cl-          = HoCl2+
     log_k    -0.29         #81TUR/WHI
     delta_h   36.3         kJ/mol        #
     # Enthalpy of formation:             -1004.902     kJ/mol        


-8.000H+     -8.000e-     +1.000Cl-     +4.000H2O          = ClO4-
     log_k    -188.09       #
     delta_h   1182.3       kJ/mol        #
     # Enthalpy of formation:             -128.1        kJ/mol        89COX/WAG


+1.000Al+3     +1.000IO3-          = Al(IO3)+2
     log_k     2.46         #estimation NEA87     08/2/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     +2.000IO3-          = Al(IO3)2+
     log_k     4.3          #estimation NEA87     08/2/95
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Al+3     -1.000H+     +1.000H2O          = Al(OH)+2
     log_k    -4.95         #95POK/HEL
     delta_h   49.76        kJ/mol        #
     # Enthalpy of formation:             -774.47       kJ/mol        


+1.000Al+3     -2.000H+     +2.000H2O          = Al(OH)2+
     log_k    -10.58        #
     delta_h   98.264       kJ/mol        #
     # Enthalpy of formation:             -1011.796     kJ/mol        95POK/HEL


+1.000Al+3     -3.000H+     +3.000H2O          = Al(OH)3
     log_k    -16.42        #
     delta_h   144.686      kJ/mol        #
     # Enthalpy of formation:             -1251.204     kJ/mol        95POK/HEL


+1.000Al+3     -4.000H+     +4.000H2O          = Al(OH)4-
     log_k    -22.87        #
     delta_h   180.881      kJ/mol        #
     # Enthalpy of formation:             -1500.839     kJ/mol        95POK/HEL


+1.000Cs+     -1.000H+     +1.000H2O          = Cs(OH)
     log_k    -15.64        #
     delta_h   65.736       kJ/mol        #
     # Enthalpy of formation:             -478.094      kJ/mol        97SHO/SAS


+1.000Cs+     +1.000Cl-          = CsCl
     log_k    -0.09         #
     delta_h   7.523        kJ/mol        #
     # Enthalpy of formation:             -417.557      kJ/mol        


+1.000Cs+     +1.000F-          = CsF
     log_k    -0.38         #
     delta_h   2.446        kJ/mol        #
     # Enthalpy of formation:             -590.904      kJ/mol        


+1.000Cs+     +1.000I-          = CsI
     log_k     1.05         #
     delta_h  -0.055        kJ/mol        #
     # Enthalpy of formation:             -314.835      kJ/mol        


-2.000e-     +2.000Cl-     +1.000I-          = ICl2-
     log_k    -26.8         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-2.000e-     +3.000I-          = I3-
     log_k    -18.17        #
     delta_h   118.877      kJ/mol        #
     # Enthalpy of formation:             -51.463       kJ/mol        


-8.000H+     -8.000e-     +1.000I-     +4.000H2O          = IO4-
     log_k    -164.98       #
     delta_h   1048.639     kJ/mol        #
     # Enthalpy of formation:             -151.461      kJ/mol        


+9.000H+     +8.000e-     +1.000NO3-     -3.000H2O          = NH3
     log_k     110          #95SIL/BID
     delta_h  -731.81       kJ/mol        #
     # Enthalpy of formation:             -81.17        kJ/mol        95SIL/BID


-1.000H+     +1.000HS-          = S-2
     log_k    -17.1         #04CHI
     delta_h   73.278       kJ/mol        #
     # Enthalpy of formation:              56.978       kJ/mol        


+1.000H+     +1.000HS-          = H2S
     log_k     6.99         #
     delta_h  -22.3         kJ/mol        #
     # Enthalpy of formation:             -38.6         kJ/mol        89COX/WAG


+1.000Sn+2     +1.000SO4-2          = Sn(SO4)
     log_k     2.6          #81PET/MIL recalculated in 02HUM/BER
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +1.000Cl-          = SnCl+
     log_k     1.7          #02HUM/BER
     delta_h   7.023        kJ/mol        #
     # Enthalpy of formation:             -168.956      kJ/mol        


+1.000Sn+2     +2.000Cl-          = SnCl2
     log_k     2.36         #02HUM/BER
     delta_h   9.039        kJ/mol        #
     # Enthalpy of formation:             -334.018      kJ/mol        


+1.000Sn+2     +3.000Cl-          = SnCl3-
     log_k     2.1          #02HUM/BER
     delta_h   19.587       kJ/mol        #
     # Enthalpy of formation:             -490.549      kJ/mol        


+1.000Sn+2     +1.000F-          = SnF+
     log_k     5            #02HUM/BER
     delta_h  -8.152        kJ/mol        #
     # Enthalpy of formation:             -352.402      kJ/mol        


+1.000Sn+2     +2.000F-          = SnF2
     log_k     7.74         #99LOT/OCH
     delta_h  -3.405        kJ/mol        #
     # Enthalpy of formation:             -683.004      kJ/mol        


+1.000Sn+2     +3.000F-          = SnF3-
     log_k     9.61         #99LOT/OCH
     delta_h   6.309        kJ/mol        #
     # Enthalpy of formation:             -1008.64      kJ/mol        


+1.000Sn+2     +1.000Br-          = SnBr+
     log_k     1.07         #01SEB/POT2
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +2.000Br-          = SnBr2
     log_k     1.88         #01SEB/POT2
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +3.000Br-          = SnBr3-
     log_k     1.5          #01SEB/POT2
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +1.000I-          = SnI+
     log_k     1.74         #68HAI/JOH recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     -1.000H+     +1.000H2O          = Sn(OH)+
     log_k    -3.8          #02HUM/BER
     delta_h   20.153       kJ/mol        #
     # Enthalpy of formation:             -274.577      kJ/mol        


+1.000Sn+2     -2.000H+     +2.000H2O          = Sn(OH)2
     log_k    -7.7          #02HUM/BER
     delta_h   40.876       kJ/mol        #
     # Enthalpy of formation:             -539.684      kJ/mol        


+1.000Sn+2     -3.000H+     +3.000H2O          = Sn(OH)3-
     log_k    -17.5         #02HUM/BER
     delta_h   95.277       kJ/mol        #
     # Enthalpy of formation:             -771.113      kJ/mol        


+3.000Sn+2     -4.000H+     +4.000H2O          = Sn3(OH)4+2
     log_k    -5.6          #02HUM/BER
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+4     -4.000H+     +4.000H2O          = Sn(OH)4
     log_k    -0.49         #
     delta_h  -3.35         kJ/mol        #
     # Enthalpy of formation:             -1116.169     kJ/mol        


+1.000Sn+4     +1.000Cl-          = SnCl+3
     log_k     5.86         #78FAT/ROU recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     +1.000H+     +1.000CO3-2          = Cd(HCO3)+
     log_k     11.83        #93STI/PAR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     +2.000CO3-2          = Cd(CO3)2-2
     log_k     6.5          #91RAI/FEL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     +1.000H2(PO4)-          = Cd(H2PO4)+
     log_k     1.8          #01AYA/MAD
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-2.000H+     +2.000H4(SiO4)     -1.000H2O          = Si2O3(OH)4-2
     log_k    -19           #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sm+3     -1.000H+     +1.000H4(SiO4)          = SmSiO(OH)3+2
     log_k    -2.62         #Orginal data 07THA/SIN and 96JEN/CHO
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sm+3     +2.000F-          = SmF2+
     log_k     6.43         #Original data 99SCH/BYR and 04LUO/BYR
     delta_h   18.85        kJ/mol        #
     # Enthalpy of formation:             -1343.049     kJ/mol        


-2.000H+     -2.000e-     +1.000I-     +1.000H2O          = IO-
     log_k    -44           #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Na+     +1.000H+     +1.000CO3-2          = Na(HCO3)
     log_k     10.08        #90NOR/PLU
     delta_h  -26.127       kJ/mol        #
     # Enthalpy of formation:             -941.697      kJ/mol        


+1.000H+     +1.000Cit-3          = H(Cit)-2
     log_k     6.36         #05HUM/AND
     delta_h   3.3          kJ/mol        #
     # Enthalpy of formation:             -1516.62      kJ/mol        


+1.000Na+     +1.000Cl-          = NaCl
     log_k    -0.5          #04smi/mar
     delta_h   2            kJ/mol        #04smi/mar
     # Enthalpy of formation:             -405.42       kJ/mol        


+1.000Na+     +1.000F-          = NaF
     log_k    -0.45         #ANDRA, CRP OHEM 95.002, X. BOURBON, janvier1996; Sélection de données thermodynamiques afférentes aux corrections de Température sur les principaux équilibres chimiques en milieu naturel
     delta_h  -12.552       kJ/mol        #
     # Enthalpy of formation:             -588.242      kJ/mol        


+1.000Na+     -1.000H+     +1.000H2(PO4)-          = Na(HPO4)-
     log_k    -6.34         #97MAR/SMI
     delta_h   34.936       kJ/mol        #97MAR/SMI
     # Enthalpy of formation:             -1508.004     kJ/mol        


+1.000Na+     +1.000NO3-          = Na(NO3)
     log_k    -0.4          #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000H+     +1.000Cit-3          = H2(Cit)-
     log_k     11.14        #05HUM/AND
     delta_h   0.9          kJ/mol        #
     # Enthalpy of formation:             -1519.02      kJ/mol        


+2.000H+     +2.000e-          = H2
     log_k    -3.08         #
     delta_h  -4.2          kJ/mol        #
     # Enthalpy of formation:             -4.2          kJ/mol        82WAG/EVA


+3.000H+     +1.000Cit-3          = H3(Cit)
     log_k     14.27        #05HUM/AND
     delta_h  -3.6          kJ/mol        #
     # Enthalpy of formation:             -1523.52      kJ/mol        


+1.000Eu+3     -4.000H+     +4.000H2O          = Eu(OH)4-
     log_k    -40.7         #07NEC/ALT
     delta_h   296.791      kJ/mol        #
     # Enthalpy of formation:             -1451.86      kJ/mol        


+1.000H+     +1.000Ox-2          = H(Ox)-
     log_k     4.25         #05HUM/AND
     delta_h   7.3          kJ/mol        #
     # Enthalpy of formation:             -823.36       kJ/mol        


+2.000H+     +1.000Ox-2          = H2(Ox)
     log_k     5.65         #05HUM/AND
     delta_h   10.6         kJ/mol        #05HUM/AND
     # Enthalpy of formation:             -820.06       kJ/mol        


+1.000H+     +1.000Nta-3          = H(Nta)-2
     log_k     10.28        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000H+     +1.000Nta-3          = H2(Nta)-
     log_k     13.2         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000H+     +1.000Nta-3          = H3(Nta)
     log_k     15.33        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+4.000H+     +1.000Nta-3          = H4(Nta)+
     log_k     16.13        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H+     +1.000Edta-4          = H(Edta)-3
     log_k     11.24        #05HUM/AND
     delta_h  -19.8         kJ/mol        #
     # Enthalpy of formation:             -1724.6       kJ/mol        


+2.000H+     +1.000Edta-4          = H2(Edta)-2
     log_k     18.04        #05HUM/AND
     delta_h  -35           kJ/mol        #
     # Enthalpy of formation:             -1739.8       kJ/mol        


+3.000H+     +1.000Edta-4          = H3(Edta)-
     log_k     21.19        #05HUM/AND
     delta_h  -27.9         kJ/mol        #
     # Enthalpy of formation:             -1732.7       kJ/mol        


+4.000H+     +1.000Edta-4          = H4(Edta)
     log_k     23.42        #05HUM/AND
     delta_h  -26           kJ/mol        #
     # Enthalpy of formation:             -1730.8       kJ/mol        


+5.000H+     +1.000Edta-4          = H5(Edta)+
     log_k     24.72        #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+6.000H+     +1.000Edta-4          = H6(Edta)+2
     log_k     24.22        #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H+     +1.000HIsa-          = H2Isa
     log_k     4            #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H+     +1.000HGlu-          = H2Glu
     log_k     3.9          #98ZUB/CAS
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H+     +1.000Cl-          = HCl
     log_k    -0.71         #97TAG/ZOT
     delta_h  -12.298       kJ/mol        #
     # Enthalpy of formation:             -179.378      kJ/mol        


+1.000H4(SiO4)     -1.000H+     +1.000PuO2+2          = PuO2(OSi(OH)3)+
     log_k    -3.64         #03YUS/FED
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000H+     +2.000e-     +0.500O2          = H2O
     log_k     42.99        #
     delta_h  -279.763      kJ/mol        #
     # Enthalpy of formation:             -285.83       kJ/mol        89COX/WAG


+1.000Ba+2     +1.000NO3-          = Ba(NO3)+
     log_k    -0.31         #
     delta_h   6.819        kJ/mol        #
     # Enthalpy of formation:             -734.831      kJ/mol        


+1.000Ba+2     -1.000H+     +1.000H2O          = Ba(OH)+
     log_k    -13.47        #76BAE/MES
     delta_h   87.395       kJ/mol        #
     # Enthalpy of formation:             -733.235      kJ/mol        


+1.000Cd+2     +1.000CO3-2          = Cd(CO3)
     log_k     4.7          #91RAI/FEL
     delta_h   4.299        kJ/mol        #
     # Enthalpy of formation:             -746.851      kJ/mol        


+1.000Cd+2     +1.000SO4-2          = Cd(SO4)
     log_k     2.37         #97MAR/SMI
     delta_h   8.7          kJ/mol        #97MAR/SMI
     # Enthalpy of formation:             -976.56       kJ/mol        


+1.000Cd+2     +2.000SO4-2          = Cd(SO4)2-2
     log_k     3.44         #76SMI/MAR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     +1.000Cl-          = CdCl+
     log_k     1.97         #76BAE/MES
     delta_h  -5.52         kJ/mol        #
     # Enthalpy of formation:             -248.52       kJ/mol        


+1.000Cd+2     +2.000Cl-          = CdCl2
     log_k     2.59         #76BAE/MES
     delta_h  -14.068       kJ/mol        #
     # Enthalpy of formation:             -424.148      kJ/mol        


+1.000Na+     -1.000H+     +1.000H2O          = Na(OH)
     log_k    -14.75        #95pok/hel
     delta_h   53.394       kJ/mol        #
     # Enthalpy of formation:             -472.776      kJ/mol        


+1.000Cd+2     +3.000Cl-          = CdCl3-
     log_k     2.4          #76BAE/MES
     delta_h  -25.804       kJ/mol        #
     # Enthalpy of formation:             -602.964      kJ/mol        


+1.000Cd+2     +4.000Cl-          = CdCl4-2
     log_k     1.47         #76BAE/MES
     delta_h  -44.765       kJ/mol        #
     # Enthalpy of formation:             -789.005      kJ/mol        


+1.000Cd+2     +1.000Br-          = CdBr+
     log_k     2.16         #
     delta_h  -7.959        kJ/mol        #
     # Enthalpy of formation:             -205.289      kJ/mol        


+1.000Cd+2     +2.000Br-          = CdBr2
     log_k     2.92         #
     delta_h  -15.742       kJ/mol        #
     # Enthalpy of formation:             -334.482      kJ/mol        


+1.000Cd+2     +3.000Br-          = CdBr3-
     log_k     3.19         #
     delta_h  -28.845       kJ/mol        #
     # Enthalpy of formation:             -468.995      kJ/mol        


+1.000Cd+2     +1.000I-          = CdI+
     log_k     2.09         #
     delta_h  -8.739        kJ/mol        #
     # Enthalpy of formation:             -141.439      kJ/mol        


+1.000Cd+2     +2.000I-          = CdI2
     log_k     3.52         #
     delta_h  -18.988       kJ/mol        #
     # Enthalpy of formation:             -208.468      kJ/mol        


+1.000Cd+2     +3.000I-          = CdI3-
     log_k     4.64         #
     delta_h  -38.647       kJ/mol        #
     # Enthalpy of formation:             -284.907      kJ/mol        


+1.000Cd+2     +4.000I-          = CdI4-2
     log_k     5.48         #
     delta_h  -75.609       kJ/mol        #
     # Enthalpy of formation:             -378.649      kJ/mol        


+1.000Pd+2     +3.000Br-          = PdBr3-
     log_k     13.75        #72ELD
     delta_h  -92.385       kJ/mol        #
     # Enthalpy of formation:             -266.731      kJ/mol        


+1.000Pd+2     +4.000Br-          = PdBr4-2
     log_k     15.11        #72ELD
     delta_h  -126.683      kJ/mol        #
     # Enthalpy of formation:             -422.439      kJ/mol        


+1.000Pd+2     +3.000NH3          = Pd(NH3)3+2
     log_k     26           #68RAS/JOR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pd+2     +4.000NH3          = Pd(NH3)4+2
     log_k     32.8         #68RAS/JOR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     +1.000Pd+2     +3.000Cl-     +1.000H2O          = PdCl3(OH)-2
     log_k     2.31         #00BYR/YAO
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pd+2     +2.000Br-          = PdBr2
     log_k     10.06        #72ELD
     delta_h  -57.708       kJ/mol        #
     # Enthalpy of formation:             -110.645      kJ/mol        


+1.000Pd+2     +1.000CO3-2          = Pd(CO3)
     log_k     6.83         #87BRO/WAN
     delta_h  -8.829        kJ/mol        #
     # Enthalpy of formation:             -494.175      kJ/mol        


+1.000Cd+2     +1.000NH3          = Cd(NH3)+2
     log_k     2.52         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pd+2     +2.000CO3-2          = Pd(CO3)2-2
     log_k     12.53        #87BRO/WAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     +2.000NH3          = Cd(NH3)2+2
     log_k     4.87         #
     delta_h  -27.965       kJ/mol        #
     # Enthalpy of formation:             -266.225      kJ/mol        


+1.000Cd+2     +3.000NH3          = Cd(NH3)3+2
     log_k     5.93         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     +4.000NH3          = Cd(NH3)4+2
     log_k     7.3          #
     delta_h  -49.714       kJ/mol        #
     # Enthalpy of formation:             -450.314      kJ/mol        


+1.000Cd+2     +1.000Pyrophos-4          = Cd(Pyrophos)-2
     log_k     8.7          #92CLE/JOH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     +1.000Cn-          = Cd(Cn)+
     log_k     5.3          #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     +2.000Cn-          = Cd(Cn)2
     log_k     10.34        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     +3.000Cn-          = Cd(Cn)3-
     log_k     14.81        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     +4.000Cn-          = Cd(Cn)4-2
     log_k     18.25        #
     delta_h  -98.48        kJ/mol        #
     # Enthalpy of formation:              428.096      kJ/mol        


+1.000Am+3     +1.000e-          = Am+2
     log_k    -38.88        #95SIL/BID
     delta_h   262.076      kJ/mol        #
     # Enthalpy of formation:             -354.624      kJ/mol        


+1.000Am+3     -1.000e-     +5.000CO3-2          = Am(CO3)5-6
     log_k    -5.1          #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     +1.000Am+3     +1.000H4(SiO4)          = AmOSi(OH)3+2
     log_k    -2.31         #Original data 07THA/SIN, 05PAN/KIM and 97STE/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-2.000H+     +1.000Am+3     +1.000H2(PO4)-          = AmPO4
     log_k    -7.76         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-4.000H+     +1.000Am+3     +2.000H2(PO4)-          = Am(PO4)2-3
     log_k    -19.43        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     +1.000Am+3     +1.000H2(PO4)-          = Am(HPO4)+
     log_k    -1.74         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-2.000H+     +1.000Am+3     +2.000H2(PO4)-          = Am(HPO4)2-
     log_k    -5.31         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Am+3     +3.000F-          = AmF3
     log_k     10.82        #69AZI/LYL
     delta_h  -12.119       kJ/mol        #
     # Enthalpy of formation:             -1634.869     kJ/mol        


-3.000H+     +1.000Am+3     +1.000HIsa-     +3.000H2O          = Am(OH)3(HIsa)-
     log_k    -21.5         #05TIT/WIE
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-3.000H+     +1.000Am+3     +1.000HGlu-     +3.000H2O          = Am(OH)3(HGlu)-
     log_k    -19.7         #05TIT/WIE
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Am+3     +1.000Ox-2          = Am(Ox)+
     log_k     6.51         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Am+3     +2.000Ox-2          = Am(Ox)2-
     log_k     10.71        #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Am+3     +3.000Ox-2          = Am(Ox)3-3
     log_k     13           #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H+     +1.000Am+3     +1.000Cit-3          = Am(HCit)+
     log_k     12.86        #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Am+3     +1.000Cit-3          = Am(Cit)
     log_k     8.55         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000H+     +1.000Am+3     +2.000Cit-3          = Am(HCit)2-
     log_k     23.52        #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Am+3     +2.000Cit-3          = Am(Cit)2-3
     log_k     13.9         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Am+3     +1.000Nta-3          = Am(Nta)
     log_k     13           #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Am+3     +2.000Nta-3          = Am(Nta)2-3
     log_k     22           #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H+     +1.000Am+3     +1.000Edta-4          = Am(HEdta)
     log_k     21.84        #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Am+3     +1.000Edta-4          = Am(Edta)-
     log_k     19.67        #05HUM/AND
     delta_h  -10.6         kJ/mol        #
     # Enthalpy of formation:             -2332.1       kJ/mol        


+1.000H+     +1.000Am+3     +1.000CO3-2          = Am(HCO3)+2
     log_k     13.43        #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-4.000H+     +1.000Am+3     +4.000H2O          = Am(OH)4-
     log_k    -40.7         #07NEC/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H+     +1.000Ra+2     +1.000CO3-2          = Ra(HCO3)+
     log_k     10.92        #01ILE/TWE
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ra+2     +2.000Cl-          = RaCl2
     log_k    -0.1          #
     delta_h   0.496        kJ/mol        #
     # Enthalpy of formation:             -861.689      kJ/mol        


+1.000Cd+2     +1.000NO3-          = Cd(NO3)+
     log_k     0.46         #74FED/ROB in 82HÖG
     delta_h  -21.757       kJ/mol        #74NAU/RYZ in 91BAL/NOR
     # Enthalpy of formation:             -304.527      kJ/mol        


+1.000Cd+2     +2.000NO3-          = Cd(NO3)2
     log_k     0.17         #97CRO
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cd+2     -1.000H+     +1.000H2O          = Cd(OH)+
     log_k    -10.08        #81BAE/MES
     delta_h   54.81        kJ/mol        #81BAE/MES
     # Enthalpy of formation:             -306.94       kJ/mol        


+1.000Cd+2     -2.000H+     +2.000H2O          = Cd(OH)2
     log_k    -20.9         #91RAI/FEL
     delta_h   114.9        kJ/mol        #
     # Enthalpy of formation:             -532.68       kJ/mol        


+1.000Cd+2     -3.000H+     +3.000H2O          = Cd(OH)3-
     log_k    -33.3         #81BAE/MES
     delta_h   156.416      kJ/mol        #
     # Enthalpy of formation:             -776.994      kJ/mol        


+1.000Cd+2     -4.000H+     +4.000H2O          = Cd(OH)4-2
     log_k    -47.48        #91RAI/FEL
     delta_h   229.571      kJ/mol        #
     # Enthalpy of formation:             -989.669      kJ/mol        


+4.000Cd+2     -4.000H+     +4.000H2O          = Cd4(OH)4+4
     log_k    -32.07        #
     delta_h   172.135      kJ/mol        #
     # Enthalpy of formation:             -1274.865     kJ/mol        99YUN/GLU


+1.000Fe+3     +2.000SO4-2          = Fe(SO4)2-
     log_k     5.4          #91PEA/BER in 98CHI
     delta_h   19.248       kJ/mol        #
     # Enthalpy of formation:             -1848.432     kJ/mol        


+3.000Fe+3     -4.000H+     +4.000H2O          = Fe3(OH)4+5
     log_k    -6.3          #76BAE/MES in 98CHI
     delta_h   59.831       kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000SeO3-2          = Fe(SeO3)+
     log_k     11.15        #05OLI/NOL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     +1.000Ho+3     +1.000H2O          = Ho(OH)+2
     log_k    -7.9          #95SPA/BRU
     delta_h   79.9         kJ/mol        #
     # Enthalpy of formation:             -912.972      kJ/mol        


-2.000H+     +1.000Ho+3     +2.000H2O          = Ho(OH)2+
     log_k    -15.7         #07NEC/ALT
     delta_h   143.846      kJ/mol        #
     # Enthalpy of formation:             -1134.856     kJ/mol        


-3.000H+     +1.000Ho+3     +3.000H2O          = Ho(OH)3
     log_k    -26.2         #07NEC/ALT
     delta_h   226.067      kJ/mol        #
     # Enthalpy of formation:             -1338.465     kJ/mol        


-4.000H+     +1.000Ho+3     +4.000H2O          = Ho(OH)4-
     log_k    -40.7         #07NEC/ALT
     delta_h   295.822      kJ/mol        #
     # Enthalpy of formation:             -1554.54      kJ/mol        


+1.000Ho+3     +3.000CO3-2          = Ho(CO3)3-3
     log_k     14.8         #05VER/VIT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     +1.000Ho+3     +1.000H4(SiO4)          = HoSiO(OH)3+2
     log_k    -2.62         #Original data from 07THA/SIN and 96JEN/CHO
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ho+3     +2.000F-          = HoF2+
     log_k     6.52         #Original data from 99SCH/BYR and 04LUO/BYR
     delta_h   21.11        kJ/mol        #04LUO/MIL
     # Enthalpy of formation:             -1356.632     kJ/mol        


+1.000Zn+2     +1.000SeO4-2          = Zn(SeO4)
     log_k     2.16         #05OLI/NOL
     delta_h   4.6          kJ/mol        #05OLI/NOL
     # Enthalpy of formation:             -752.29       kJ/mol        


+1.000Ni+2     +1.000CO3-2          = Ni(CO3)
     log_k     4.2          #03BAE/BRA in 05GAM/BUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +2.000CO3-2          = Ni(CO3)2-2
     log_k     6.2          #03BAE/BRA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +1.000H+     +1.000CO3-2          = Ni(HCO3)+
     log_k     11.73        #03BAE/BRA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +1.000SO4-2          = Ni(SO4)
     log_k     2.35         #05GAM/BUG
     delta_h   5.66         kJ/mol        #05GAM/BUG
     # Enthalpy of formation:             -958.692      kJ/mol        


+1.000Ni+2     +2.000SO4-2          = Ni(SO4)2-2
     log_k     3.01         #89BAE/McK
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +1.000F-          = NiF+
     log_k     1.43         #05GAM/BUG
     delta_h   9.5          kJ/mol        #05GAM/BUG
     # Enthalpy of formation:             -380.862      kJ/mol        


+1.000Ni+2     -1.000H+     +1.000H2(PO4)-          = Ni(HPO4)
     log_k    -4.16         #05GAM/BUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     +1.000AmO2+     +1.000H2O          = AmO2OH
     log_k    -11.3         #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-2.000H+     +1.000AmO2+     +2.000H2O          = AmO2(OH)2-
     log_k    -23.6         #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000AmO2+     +1.000CO3-2          = AmO2(CO3)-
     log_k     5.1          #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000AmO2+     +2.000CO3-2          = AmO2(CO3)2-3
     log_k     6.7          #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000AmO2+     +3.000CO3-2          = AmO2(CO3)3-5
     log_k     5.1          #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     -2.000H+     +2.000H2O          = Fe(OH)2
     log_k    -20.6         #76BAE/MES in 99CHIa
     delta_h   119.662      kJ/mol        #
     # Enthalpy of formation:             -541.998      kJ/mol        


+1.000Fe+2     -3.000H+     +3.000H2O          = Fe(OH)3-
     log_k    -31.9         #76BAE/MES in 99CHIa
     delta_h   138.072      kJ/mol        #
     # Enthalpy of formation:             -809.418      kJ/mol        


+1.000Fe+2     +1.000H+     +1.000SO4-2          = Fe(HSO4)+
     log_k     3.07         #NAGRA, TR 91-18; F.J. PEARSON, U. BERNER, W. HUMMEL; Nagra thermochemical data base, supplemental data 05/92 (provient de la base 0391 MINEQL- PSY)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +1.000CO3-2          = Fe(CO3)
     log_k     5.69         #99CHIb
     delta_h  -5.764        kJ/mol        #
     # Enthalpy of formation:             -770.994      kJ/mol        


+1.000Fe+2     +1.000F-          = FeF+
     log_k     1            #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+2     +1.000SO4-2          = Fe(SO4)
     log_k     2.2          #91PEA/BER in 98CHI
     delta_h   13.514       kJ/mol        #
     # Enthalpy of formation:             -985.826      kJ/mol        


+3.000H+     +1.000Nb(OH)6-     +1.000Ox-2     -4.000H2O          = NbO2(HOx)
     log_k     13.7         #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000H+     +1.000Nb(OH)6-     -3.000H2O          = Nb(OH)3+2
     log_k     7.5          #97PEI/NGU
     delta_h  -10.23        kJ/mol        #97PEI/NGU
     # Enthalpy of formation:             -1078.405     kJ/mol        


+4.000H+     +1.000Nb(OH)6-     +2.000Ox-2     -4.000H2O          = NbO2(HOx)2-
     log_k     20.96        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000H+     +1.000Nb(OH)6-     +1.000Ox-2     -4.000H2O          = NbO2(Ox)-
     log_k     10.94        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+5.000H+     +1.000Nb(OH)6-     +1.000Cit-3     -4.000H2O          = NbO2(H3Cit)+
     log_k     25.64        #96AKR/BOU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +1.000NO3-          = Ni(NO3)+
     log_k     0.5          #05GAM/BUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +2.000NO3-          = Ni(NO3)2
     log_k    -0.6          #76SMI/MAR in 89BAE/McK
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     +1.000SeO4-2          = Ni(SeO4)
     log_k     2.67         #05OLI/NOL
     delta_h  -0.675        kJ/mol        #
     # Enthalpy of formation:             -659.187      kJ/mol        


+1.000Ni+2     -1.000H+     +1.000H2O          = Ni(OH)+
     log_k    -9.54         #05GAM/BUG
     delta_h   53.8         kJ/mol        #05GAM/BUG
     # Enthalpy of formation:             -287.042      kJ/mol        


+1.000Ni+2     -2.000H+     +2.000H2O          = Ni(OH)2
     log_k    -18           #49GAY/GAR reevaluated in 05GAM/BUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     -3.000H+     +3.000H2O          = Ni(OH)3-
     log_k    -29.38        #49GAY/GAR reevaluated in 05GAM/BUG
     delta_h   121.2        kJ/mol        #05GAM/BUG
     # Enthalpy of formation:             -791.302      kJ/mol        


+2.000Ni+2     -1.000H+     +1.000H2O          = Ni2(OH)+3
     log_k    -10.6         #05GAM/BUG
     delta_h   45.9         kJ/mol        #05GAM/BUG
     # Enthalpy of formation:             -349.954      kJ/mol        


+4.000Ni+2     -4.000H+     +4.000H2O          = Ni4(OH)4+4
     log_k    -27.52        #05GAM/BUG
     delta_h   190          kJ/mol        #05GAM/BUG
     # Enthalpy of formation:             -1173.368     kJ/mol        


+1.000Pb+2     +1.000CO3-2          = Pb(CO3)
     log_k     7            #06BLA/PIA
     delta_h  -3.015        kJ/mol        #
     # Enthalpy of formation:             -677.325      kJ/mol        


+1.000Pb+2     +2.000CO3-2          = Pb(CO3)2-2
     log_k     10.13        #99LOT/OCH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pb+2     +1.000SO4-2          = Pb(SO4)
     log_k     2.82         #99LOT/OCH
     delta_h   6.861        kJ/mol        #
     # Enthalpy of formation:             -901.559      kJ/mol        


+1.000Pb+2     +2.000SO4-2          = Pb(SO4)2-2
     log_k     3.47         #97MAR/SMI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pb+2     +1.000Cl-          = PbCl+
     log_k     1.44         #97SVE/SHO
     delta_h   4.318        kJ/mol        #
     # Enthalpy of formation:             -161.842      kJ/mol        


+1.000Pb+2     +2.000Cl-          = PbCl2
     log_k     2            #97SVE/SHO
     delta_h   7.949        kJ/mol        #
     # Enthalpy of formation:             -325.291      kJ/mol        


+1.000Pb+2     +3.000Cl-          = PbCl3-
     log_k     1.69         #97SVE/SHO
     delta_h   7.813        kJ/mol        #
     # Enthalpy of formation:             -492.507      kJ/mol        


+1.000Pb+2     +4.000Cl-          = PbCl4-2
     log_k     1.4          #97SVE/SHO
     delta_h   1.323        kJ/mol        #
     # Enthalpy of formation:             -666.077      kJ/mol        


+1.000Mn+2     -1.000e-          = Mn+3
     log_k    -25.51        #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     -8.000H+     -4.000e-     +4.000H2O          = MnO4-2
     log_k    -118.4        #NAGRA, TR 91-18; F.J. PEARSON, U. BERNER, W. HUMMEL; Nagra thermochemical data base, supplemental data 05/92
     delta_h   711.366      kJ/mol        #
     # Enthalpy of formation:             -652.704      kJ/mol        


+1.000Mn+2     -8.000H+     -5.000e-     +4.000H2O          = MnO4-
     log_k    -127.78       #NAGRA, TR 91-18; F.J. PEARSON, U. BERNER, W. HUMMEL; Nagra thermochemical data base, supplemental data 05/92
     delta_h   822.66       kJ/mol        #
     # Enthalpy of formation:             -541.41       kJ/mol        


+1.000Mn+2     -2.000H+     +2.000H2O          = Mn(OH)2
     log_k    -22.2         #95CHI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pb+2     +1.000Br-          = PbBr+
     log_k     1.7          #82HÖG
     delta_h   4.228        kJ/mol        #
     # Enthalpy of formation:             -116.262      kJ/mol        


+1.000Mn+2     -4.000H+     +4.000H2O          = Mn(OH)4-2
     log_k    -48.3         #NAGRA, TR 91-18; F.J. PEARSON, U. BERNER, W. HUMMEL; Nagra thermochemical data base, supplemental data 05/92EUR 11891 EN ; Nagra TR 91-18 (mai 1992, Hatches 3.0) (provient de la base 0391 MINEQL- PSY)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000Mn+2     -3.000H+     +3.000H2O          = Mn2(OH)3+
     log_k    -24.9         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +1.000CO3-2          = Mn(CO3)
     log_k     6.5          #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +1.000NO3-          = Mn(NO3)+
     log_k     0.16         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +2.000NO3-          = Mn(NO3)2
     log_k     0.5          #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +1.000F-          = MnF+
     log_k     0.85         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +2.000F-          = MnF2
     log_k     9.04         #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +3.000F-          = MnF3-
     log_k     11.64        #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pb+2     +2.000Br-          = PbBr2
     log_k     1.9          #82HÖG
     delta_h   10.991       kJ/mol        #
     # Enthalpy of formation:             -230.909      kJ/mol        


+1.000Mn+2     +4.000F-          = MnF4-2
     log_k     13.4         #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +6.000F-          = MnF6-4
     log_k     15.5         #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +1.000Br-          = MnBr+
     log_k     0.13         #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000Mn+2     -1.000H+     +1.000H2O          = Mn2(OH)+3
     log_k    -10.1         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     -2.000H+     +2.000H2(PO4)-          = Mn(HPO4)2-2
     log_k    -9.12         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Mn+2     +5.000F-          = MnF5-3
     log_k     14.7         #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pb+2     +3.000Br-          = PbBr3-
     log_k     2.9          #82HÖG
     delta_h   10.653       kJ/mol        #
     # Enthalpy of formation:             -352.657      kJ/mol        


+1.000Pb+2     +1.000I-          = PbI+
     log_k     1.98         #82HÖG
     delta_h   3.874        kJ/mol        #
     # Enthalpy of formation:             -51.986       kJ/mol        


+1.000Pb+2     +3.000I-          = PbI3-
     log_k     3.81         #82HÖG
     delta_h   3.163        kJ/mol        #
     # Enthalpy of formation:             -166.257      kJ/mol        


+1.000Pb+2     +4.000I-          = PbI4-2
     log_k     3.75         #82HÖG
     delta_h  -15.561       kJ/mol        #
     # Enthalpy of formation:             -241.761      kJ/mol        


+1.000Pb+2     +1.000NO3-          = Pb(NO3)+
     log_k     1.06         #99LOT/OCH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pb+2     +2.000NO3-          = Pb(NO3)2
     log_k     1.48         #99LOT/OCH
     delta_h  -11.012       kJ/mol        #
     # Enthalpy of formation:              401.768      kJ/mol        


+1.000Pb+2     -1.000H+     +1.000H2O          = Pb(OH)+
     log_k    -7.51         #99LOT/OCH
     delta_h   53.92        kJ/mol        #
     # Enthalpy of formation:             -230.99       kJ/mol        


+1.000Pb+2     -2.000H+     +2.000H2O          = Pb(OH)2
     log_k    -16.95        #99LOT/OCH
     delta_h   97.824       kJ/mol        #
     # Enthalpy of formation:             -472.916      kJ/mol        


+1.000Pb+2     -3.000H+     +3.000H2O          = Pb(OH)3-
     log_k    -27.2         #01PER/HEF
     delta_h   130.485      kJ/mol        #
     # Enthalpy of formation:             -726.085      kJ/mol        


+2.000Pb+2     -1.000H+     +1.000H2O          = Pb2(OH)+3
     log_k    -7.18         #99LOT/OCH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+4.000Pb+2     -4.000H+     +4.000H2O          = Pb4(OH)4+4
     log_k    -20.63        #99LOT/OCH
     delta_h   82.038       kJ/mol        #
     # Enthalpy of formation:             -1057.602     kJ/mol        


+1.000Ag+     +1.000SO4-2          = Ag(SO4)-
     log_k     1.38         #
     delta_h   4.646        kJ/mol        #
     # Enthalpy of formation:             -798.904      kJ/mol        


+1.000Ag+     +1.000Cl-          = AgCl
     log_k     3.27         #91BAL/NOR
     delta_h  -17.099       kJ/mol        #
     # Enthalpy of formation:             -78.389       kJ/mol        


+1.000Ag+     +2.000Cl-          = AgCl2-
     log_k     5.27         #91BAL/NOR
     delta_h  -28.752       kJ/mol        #
     # Enthalpy of formation:             -257.122      kJ/mol        


+1.000Ag+     +3.000Cl-          = AgCl3-2
     log_k     5.29         #91BAL/NOR
     delta_h  -29.163       kJ/mol        #
     # Enthalpy of formation:             -424.613      kJ/mol        


+1.000Ag+     +1.000Br-          = AgBr
     log_k     4.24         #91BAL/NOR, 68WAG
     delta_h  -23.129       kJ/mol        #
     # Enthalpy of formation:             -38.749       kJ/mol        


+1.000Ag+     +2.000Br-          = AgBr2-
     log_k     7.28         #91BAL/NOR, 68WAG
     delta_h  -45.296       kJ/mol        #
     # Enthalpy of formation:             -182.326      kJ/mol        


+1.000Ag+     +3.000Br-          = AgBr3-2
     log_k     8.71         #91BAL/NOR, 68WAG
     delta_h  -66.741       kJ/mol        #
     # Enthalpy of formation:             -325.181      kJ/mol        


+1.000Ag+     +1.000I-          = AgI
     log_k     6.58         #76SMI/MAR
     delta_h  -36.962       kJ/mol        #
     # Enthalpy of formation:              12.048       kJ/mol        


+1.000Ag+     +2.000I-          = AgI2-
     log_k     11.7         #76SMI/MAR
     delta_h  -76.578       kJ/mol        #
     # Enthalpy of formation:             -84.348       kJ/mol        


+1.000Ag+     +3.000I-          = AgI3-2
     log_k     13.28        #
     delta_h  -114.911      kJ/mol        #
     # Enthalpy of formation:             -179.461      kJ/mol        


+1.000Ag+     +1.000HS-          = Ag(HS)
     log_k     14.05        #74NAU/RYZ in 91BAL/NOR
     delta_h  -78.826       kJ/mol        #
     # Enthalpy of formation:              10.664       kJ/mol        


+1.000Ag+     +2.000HS-          = Ag(HS)2-
     log_k     18.45        #74NAU/RYZ in 91BAL/NOR
     delta_h  -105.805      kJ/mol        #
     # Enthalpy of formation:             -32.615       kJ/mol        


+1.000Ag+     +1.000S2O3-2          = Ag(S2O3)-
     log_k     9.23         #74BEL/MAR in 82HÖG
     delta_h  -58.994       kJ/mol        #74BEL/MAR in 82HÖG
     # Enthalpy of formation:             -601.724      kJ/mol        


+1.000Ag+     +2.000S2O3-2          = Ag(S2O3)2-3
     log_k     13.64        #72POU/RIG in 82HÖG
     delta_h  -94.45        kJ/mol        #
     # Enthalpy of formation:             -1285.7       kJ/mol        82WAG/EVA


+1.000Ag+     +1.000SO3-2          = Ag(SO3)-
     log_k     5.21         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ag+     -1.000H+     +1.000H2O          = Ag(OH)
     log_k    -12           #76BAE/MES
     delta_h   47.178       kJ/mol        #
     # Enthalpy of formation:             -132.862      kJ/mol        


+1.000Al+3     +1.000SO4-2          = Al(SO4)+
     log_k     3.17         #01TAG/SCH
     delta_h   18.87        kJ/mol        #
     # Enthalpy of formation:             -1428.87      kJ/mol        


+1.000Al+3     +1.000F-          = AlF+2
     log_k     6.98         #01TAG/SCH
     delta_h  -0.346        kJ/mol        #
     # Enthalpy of formation:             -874.096      kJ/mol        


+1.000Al+3     +2.000F-          = AlF2+
     log_k     12.5         #01TAG/SCH
     delta_h   0.42         kJ/mol        #
     # Enthalpy of formation:             -1208.68      kJ/mol        


+1.000Al+3     +3.000F-          = AlF3
     log_k     16.55        #01TAG/SCH
     delta_h   0.615        kJ/mol        #
     # Enthalpy of formation:             -1543.835     kJ/mol        


+1.000Al+3     +4.000F-          = AlF4-
     log_k     18.93        #01TAG/SCH
     delta_h   0.823        kJ/mol        #
     # Enthalpy of formation:             -1878.977     kJ/mol        


+1.000H+     +1.000CO3-2          = HCO3-
     log_k     10.33        #
     delta_h  -14.7         kJ/mol        #
     # Enthalpy of formation:             -689.93       kJ/mol        89COX/WAG


+4.000H+     +2.000e-     +1.000CO3-2     -2.000H2O          = CO
     log_k     11.6         #
     delta_h  -17.39        kJ/mol        #
     # Enthalpy of formation:             -120.96       kJ/mol        82WAG/EVA


+2.000H+     +1.000CO3-2     -1.000H2O          = CO2
     log_k     16.68        #
     delta_h  -23.86        kJ/mol        #
     # Enthalpy of formation:             -413.26       kJ/mol        89COX/WAG


+10.000H+     +8.000e-     +1.000CO3-2     -3.000H2O          = CH4
     log_k     38.19        #
     delta_h  -270.166      kJ/mol        #
     # Enthalpy of formation:             -87.906       kJ/mol        01SCH/SHO


+1.000Ba+2     +1.000H+     +1.000CO3-2          = Ba(HCO3)+
     log_k     11.31        #86BUS/PLU
     delta_h   8.56         kJ/mol        #86BUS/PLU
     # Enthalpy of formation:             -1201.47      kJ/mol        


-1.000H+     +2.000H4(SiO4)     -1.000H2O          = Si2O2(OH)5-
     log_k    -8.1          #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-3.000H+     +3.000H4(SiO4)     -3.000H2O          = Si3O6(OH)3-3
     log_k    -28.6         #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-3.000H+     +3.000H4(SiO4)     -2.000H2O          = Si3O5(OH)5-3
     log_k    -27.5         #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-4.000H+     +4.000H4(SiO4)     -4.000H2O          = Si4O8(OH)4-4
     log_k    -36.3         #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-3.000H+     +4.000H4(SiO4)     -4.000H2O          = Si4O7(OH)5-3
     log_k    -25.5         #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-2.000H+     +1.000H4(SiO4)          = H2(SiO4)-2
     log_k    -23.14        #92GRE/FUG
     delta_h   75           kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -1386.194     kJ/mol        


+1.000H+     +1.000SO4-2          = H(SO4)-
     log_k     1.98         #
     delta_h   22.44        kJ/mol        #
     # Enthalpy of formation:             -886.9        kJ/mol        


+1.000H+     +1.000NH3          = NH4+
     log_k     9.23         #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -133.26       kJ/mol        92GRE/FUG


-1.000H+     +1.000H2(PO4)-          = HPO4-2
     log_k    -7.21         #
     delta_h   3.6          kJ/mol        #
     # Enthalpy of formation:             -1299         kJ/mol        89COX/WAG


+1.000H+     +1.000H2(PO4)-          = H3(PO4)
     log_k     2.14         #92GRE/FUG
     delta_h   8.48         kJ/mol        #
     # Enthalpy of formation:             -1294.12      kJ/mol        


+1.000H+     +1.000Pyrophos-4          = H(Pyrophos)-3
     log_k     9.4          #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000H+     +1.000Pyrophos-4          = H2(Pyrophos)-2
     log_k     16.05        #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000H+     +1.000Pyrophos-4          = H3(Pyrophos)-
     log_k     18.3         #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+4.000H+     +1.000Pyrophos-4          = H4(Pyrophos)
     log_k     19.3         #92GRE/FUG
     delta_h   6.684        kJ/mol        #
     # Enthalpy of formation:             -2280.21      kJ/mol        92GRE/FUG


-1.000H+     +1.000H4(SiO4)          = H3(SiO4)-
     log_k    -9.84         #06BLA/PIA
     delta_h   29.363       kJ/mol        #
     # Enthalpy of formation:             -1431.831     kJ/mol        


+1.000H+     +1.000S2O3-2          = H(S2O3)-
     log_k     1.72         #04CHI
     delta_h   8.253        kJ/mol        #
     # Enthalpy of formation:             -644.033      kJ/mol        


+2.000H+     +1.000S2O3-2          = H2(S2O3)
     log_k     2.32         #04CHI
     delta_h   22.917       kJ/mol        #
     # Enthalpy of formation:             -629.369      kJ/mol        


-1.000H+     +1.000Hf+4     +1.000H2O          = Hf(OH)+3
     log_k    -0.2          #01RAI/XIA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-4.000H+     +1.000Hf+4     +4.000H2O          = Hf(OH)4
     log_k    -11.2         #01RAI/XIA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-5.000H+     +1.000Hf+4     +5.000H2O          = Hf(OH)5-
     log_k    -20.3         #01RAI/XIA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-6.000H+     +1.000Hf+4     +6.000H2O          = Hf(OH)6-2
     log_k    -32.8         #01RAI/XIA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+4.000CO3-2     +1.000Hf+4          = Hf(CO3)4-4
     log_k     42.9         #analogy with Zr
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NO3-     +1.000Hf+4          = HfNO3+3
     log_k     1.85         #65DES/KHO 69HAL/SMO recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000NO3-     +1.000Hf+4          = Hf(NO3)2+2
     log_k     2.49         #65DES/KHO recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000SO4-2     +1.000Hf+4          = HfSO4+2
     log_k     6.06         #65DES/KHO recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000SO4-2     +1.000Hf+4          = Hf(SO4)2
     log_k     10.11        #65DES/KHO recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000F-     +1.000Hf+4          = HfF+3
     log_k     9.29         #05SAW/THA and others recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000F-     +1.000Hf+4          = HfF2+2
     log_k     17.85        #05SAW/THA and others recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000F-     +1.000Hf+4          = HfF3+
     log_k     25.08        #05SAW/THA and others recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+4.000F-     +1.000Hf+4          = HfF4
     log_k     31.41        #05SAW/THA and others recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cl-     +1.000Hf+4          = HfCl+3
     log_k     2.2          #65DES/KHO and others recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000Cl-     +1.000Hf+4          = HfCl2+2
     log_k     2.05         #65DES/KHO and others recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Br-     +1.000Hf+4          = HfBr+3
     log_k     0.38         #67HAL/POH recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000I-     +1.000Hf+4          = HfI+3
     log_k     0.02         #67HAL/POH recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-2.000H+     -2.000e-     +1.000Sb(OH)3     +2.000H2O          = Sb(OH)5
     log_k    -21.74        #99LOT/OCH recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000H+     +1.000Sb(OH)3     -3.000H2O          = Sb+3
     log_k    -0.73         #99LOT/OCH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000H+     +1.000Sb(OH)3     -2.000H2O          = Sb(OH)+2
     log_k     0.74         #99LOT/OCH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H+     +1.000Sb(OH)3     -1.000H2O          = Sb(OH)2+
     log_k     1.33         #77ANT/NET and others recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     +1.000Sb(OH)3     +1.000H2O          = Sb(OH)4-
     log_k    -11.82        #52GAY/GAR recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000H+     +4.000HS-     +2.000Sb(OH)3     -6.000H2O          = Sb2S4-2
     log_k     43.38        #88KRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000H+     +4.000HS-     +2.000Sb(OH)3     -6.000H2O          = Sb2HS4-
     log_k     52.9         #88KRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+4.000H+     +4.000HS-     +2.000Sb(OH)3     -6.000H2O          = Sb2H2S4
     log_k     57.81        #88KRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000H+     +1.000F-     +1.000Sb(OH)3     -3.000H2O          = SbF+2
     log_k     6.37         #70BON recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000H+     +2.000F-     +1.000Sb(OH)3     -3.000H2O          = SbF2+
     log_k     12.42        #70BON recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000H+     +3.000F-     +1.000Sb(OH)3     -3.000H2O          = SbF3
     log_k     18.2         #70BON recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000H+     +1.000Cl-     +1.000Sb(OH)3     -3.000H2O          = SbCl+2
     log_k     2.8          #70BON/WAU and others recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000H+     +2.000Cl-     +1.000Sb(OH)3     -3.000H2O          = SbCl2+
     log_k     3.27         #70BON/WAU and others recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H+     +1.000Sb(OH)5     -1.000H2O          = Sb(OH)4+
     log_k    -3.26         #57PIT/POU in 99LOT/OCH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H+     +1.000SO3-2          = H(SO3)-
     log_k     7.17         #85GOL/PAR
     delta_h   3.668        kJ/mol        #
     # Enthalpy of formation:             -627.392      kJ/mol        


+2.000H+     +1.000SO3-2          = H2(SO3)
     log_k     9.03         #85GOL/PAR
     delta_h   21.453       kJ/mol        #
     # Enthalpy of formation:             -609.607      kJ/mol        


+1.000H+     +1.000AsO4-3          = H(AsO4)-2
     log_k     11.6         #
     delta_h  -18.2         kJ/mol        #
     # Enthalpy of formation:             -906.34       kJ/mol        01LEM/FUG


+2.000H+     +1.000AsO4-3          = H2(AsO4)-
     log_k     18.37        #
     delta_h  -21.42        kJ/mol        #
     # Enthalpy of formation:             -909.56       kJ/mol        01LEM/FUG


+3.000H+     +1.000AsO4-3          = H3(AsO4)
     log_k     20.63        #
     delta_h  -14.36        kJ/mol        #
     # Enthalpy of formation:             -902.5        kJ/mol        01LEM/FUG


+1.000H+     +1.000SeO3-2          = H(SeO3)-
     log_k     8.36         #05OLI/NOL
     delta_h  -5.17         kJ/mol        #
     # Enthalpy of formation:             -512.33       kJ/mol        05OLI/NOL


+2.000H+     +1.000SeO3-2          = H2(SeO3)
     log_k     11           #05OLI/NOL
     delta_h   1.84         kJ/mol        #
     # Enthalpy of formation:             -505.32       kJ/mol        05OLI/NOL


+1.000H+     +1.000SeO4-2          = H(SeO4)-
     log_k     1.75         #05OLI/NOL
     delta_h   20.8         kJ/mol        #05OLI/NOL
     # Enthalpy of formation:             -582.7        kJ/mol        


+1.000H+     +1.000HSe-          = H2Se
     log_k     3.85         #
     delta_h   0            kJ/mol        #
     # Enthalpy of formation:              14.3         kJ/mol        05OLI/NOL


-1.000H+     +1.000H2O          = OH-
     log_k    -14           #
     delta_h   55.815       kJ/mol        #
     # Enthalpy of formation:             -230.015      kJ/mol        89COX/WAG


+1.000Hg+2     +2.000SeO3-2          = Hg(SeO3)2-2
     log_k     14.85        #05OLI/NOL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H+     +2.000B(OH)4-     -4.000H2O          = HB2O4-
     log_k     9.17         #97CRO
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000H+     +3.000B(OH)4-     -7.000H2O          = B3O5-
     log_k     20.9         #97CRO
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000H+     +4.000B(OH)4-     -9.000H2O          = B4O7-2
     log_k     21.9         #97CRO
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H+     +1.000B(OH)4-     -1.000H2O          = B(OH)3
     log_k     9.24         #
     delta_h  -13.514       kJ/mol        #
     # Enthalpy of formation:             -1072.8       kJ/mol        01LEM/FUG


+1.000Cu+2     +1.000B(OH)4-          = Cu(B(OH)4)+
     log_k     7.13         #80BAS
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cu+2     +2.000B(OH)4-          = Cu(B(OH)4)2
     log_k     12.45        #80BAS
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cu+2     +3.000B(OH)4-          = Cu(B(OH)4)3-
     log_k     15.17        #80BAS
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +1.000B(OH)4-          = Fe(B(OH)4)+2
     log_k     8.58         #80BAS
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Fe+3     +2.000B(OH)4-          = Fe(B(OH)4)2+
     log_k     15.54        #80BAS
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pb+2     +1.000B(OH)4-          = Pb(B(OH)4)+
     log_k     5.2          #80BAS
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pb+2     +3.000B(OH)4-          = Pb(B(OH)4)3-
     log_k     11.18        #80BAS
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ba+2     +1.000B(OH)4-          = BaB(OH)4+
     log_k     1.49         #80BAS
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sr+2     +1.000B(OH)4-          = SrB(OH)4+
     log_k     1.55         #80BAS
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H+     +1.000F-     +1.000B(OH)4-     -1.000H2O          = BF(OH)3-
     log_k     8.94         #77NOR/JEN
     delta_h  -39.078       kJ/mol        #77NOR/JEN
     # Enthalpy of formation:             -1433.714     kJ/mol        


+2.000H+     +2.000F-     +1.000B(OH)4-     -2.000H2O          = BF2(OH)2-
     log_k     16.97        #77NOR/JEN
     delta_h  -38.702       kJ/mol        #77NOR/JEN
     # Enthalpy of formation:             -1482.858     kJ/mol        


+3.000H+     +3.000F-     +1.000B(OH)4-     -3.000H2O          = BF3(OH)-
     log_k     23.01        #77NOR/JEN
     delta_h  -38.326       kJ/mol        #77NOR/JEN
     # Enthalpy of formation:             -1532.002     kJ/mol        


+4.000H+     +4.000F-     +1.000B(OH)4-     -4.000H2O          = BF4-
     log_k     29.62        #77NOR/JEN
     delta_h   73.68        kJ/mol        #77NOR/JEN
     # Enthalpy of formation:             -1616.876     kJ/mol        


+2.000H+     +2.000SO3-2     -1.000H2O          = S2O5-2
     log_k     12.85        #85GOL/PAR
     delta_h   2.606        kJ/mol        #
     # Enthalpy of formation:             -973.684      kJ/mol        


+1.000Sn+2     -2.000e-          = Sn+4
     log_k    -5.07         #calculated from 34HUE/TAR, 79VAS/GLA
     delta_h   39.4         kJ/mol        #
     # Enthalpy of formation:              30.5         kJ/mol        82WAG/EVA


+6.000Pb+2     -8.000H+     +8.000H2O          = Pb6(OH)8+4
     log_k    -42.68        #99LOT/OCH
     delta_h   192.157      kJ/mol        #
     # Enthalpy of formation:             -2088.963     kJ/mol        


+1.000H+     +1.000MoO4-2          = HMoO4-
     log_k     4.11         #68SAS/SIL, 64AVE/ANA
     delta_h   58.576       kJ/mol        #68ARN/SZI in 76BAE/MES
     # Enthalpy of formation:             -938.424      kJ/mol        


+2.000H+     +1.000MoO4-2          = H2MoO4
     log_k     8.15         #68SAS/SIL, 64AVE/ANA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+8.000H+     +7.000MoO4-2     -4.000H2O          = Mo7O24-6
     log_k     50.35        #68SAS/SIL, 64AVE/ANA
     delta_h  -234.304      kJ/mol        #68ARN/SZI in 76BAE/MES
     # Enthalpy of formation:             -6069.984     kJ/mol        


+9.000H+     +7.000MoO4-2     -4.000H2O          = Mo7O23(OH)-5
     log_k     57.21        #68SAS/SIL, 64AVE/ANA
     delta_h  -223.426      kJ/mol        #68ARN/SZI in 76BAE/MES
     # Enthalpy of formation:             -6059.106     kJ/mol        


+10.000H+     +7.000MoO4-2     -4.000H2O          = Mo7O22(OH)2-4
     log_k     62.71        #68SAS/SIL, 64AVE/ANA
     delta_h  -220.079      kJ/mol        #68ARN/SZI in 76BAE/MES
     # Enthalpy of formation:             -6055.759     kJ/mol        


+11.000H+     +7.000MoO4-2     -4.000H2O          = Mo7O21(OH)3-3
     log_k     66.48        #68SAS/SIL, 64AVE/ANA
     delta_h  -222.589      kJ/mol        #68ARN/SZI in 76BAE/MES
     # Enthalpy of formation:             -6058.269     kJ/mol        


+34.000H+     +19.000MoO4-2     -17.000H2O          = Mo19O59-4
     log_k     196.3        #68SAS/SIL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+5.000H+     +2.000MoO4-2     -2.000H2O          = Mo2O5(OH)+
     log_k     19           #68SAS/SIL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+8.000H+     +3.000e-     +1.000MoO4-2     -4.000H2O          = Mo+3
     log_k     21.76        #68SAS/SIL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000H+     +2.000e-     +1.000AsO4-3     -1.000H2O          = H(AsO3)-2
     log_k     19.8         #
     delta_h  -86.969       kJ/mol        #
     # Enthalpy of formation:             -689.279      kJ/mol        


+4.000H+     +2.000e-     +1.000AsO4-3     -1.000H2O          = H2(AsO3)-
     log_k     30.81        #
     delta_h  -112.48       kJ/mol        #
     # Enthalpy of formation:             -714.79       kJ/mol        01LEM/FUG


+5.000H+     +2.000e-     +1.000AsO4-3     -1.000H2O          = H3(AsO3)
     log_k     40.02        #
     delta_h  -139.89       kJ/mol        #
     # Enthalpy of formation:             -742.2        kJ/mol        01LEM/FUG


+1.000Pb+2     +1.000SeO3-2          = Pb(SeO3)
     log_k     5.73         #01SEB/POT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000e-     +1.000TcO4-          = TcO4-2
     log_k    -10.8         #99RAR/RAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     +1.000HSe-          = Se-2
     log_k    -14.91        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-4.000H+     -6.000e-     +4.000HSe-          = Se4-2
     log_k     13.38        #05OLI/NOL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-2.000H+     -2.000e-     +2.000HSe-          = Se2-2
     log_k    -4.5          #05OLI/NOL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-3.000H+     -4.000e-     +3.000HSe-          = Se3-2
     log_k     5.24         #05OLI/NOL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     -2.000e-     +1.000Cn-     +1.000HSe-          = SeCn-
     log_k     13.03        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Hg+2     -2.000H+     -4.000e-     +2.000Cn-     +2.000HSe-          = Hg(SeCn)2
     log_k     48.35        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Hg+2     -3.000H+     -6.000e-     +3.000Cn-     +3.000HSe-          = Hg(SeCn)3-
     log_k     65.88        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Hg+2     -4.000H+     -8.000e-     +4.000Cn-     +4.000HSe-          = Hg(SeCn)4-2
     log_k     81.41        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ag+     -3.000H+     -6.000e-     +3.000Cn-     +3.000HSe-          = Ag(SeCn)3-2
     log_k     52.93        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     -1.000H+     -2.000e-     +1.000Cn-     +1.000HSe-          = Ni(SeCn)+
     log_k     14.8         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ni+2     -2.000H+     -4.000e-     +2.000Cn-     +2.000HSe-          = Ni(SeCn)2
     log_k     28.29        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Co+2     -1.000H+     -2.000e-     +1.000Cn-     +1.000HSe-          = Co(SeCn)+
     log_k     14.53        #75SAT/SAH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     +1.000SeO4-2          = UO2(SeO4)
     log_k     2.74         #05OLI/NOL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+9.000H+     +8.000e-     +1.000SeO4-2     -4.000H2O          = HSe-
     log_k     81.57        #
     delta_h  -525.52       kJ/mol        #
     # Enthalpy of formation:              14.3         kJ/mol        05OLI/NOL


+1.000Ca+2     +1.000SeO4-2          = Ca(SeO4)
     log_k     2            #05OLI/NOL
     delta_h   1.475        kJ/mol        #
     # Enthalpy of formation:             -1145.025     kJ/mol        


+1.000Ag+     +1.000SeO3-2          = Ag(SeO3)-
     log_k     3.2          #Data from 68MEH and 69MEH/GUB in 05OLI/NOL corrected to I=0 by DH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000H2O     -4.000e-     -4.000H+          = O2
     log_k    -85.98        #89COX/WAG
     delta_h   559.526      kJ/mol        #
     # Enthalpy of formation:             -12.134       kJ/mol        01SCH/SHO


-1.000H+     +1.000Rb+     +1.000H2O          = RbOH
     log_k    -14.26        #
     delta_h   64.158       kJ/mol        #
     # Enthalpy of formation:             -472.792      kJ/mol        97SHO/SAS


+1.000F-     +1.000Rb+          = RbF
     log_k     0.94         #
     delta_h   1.923        kJ/mol        #
     # Enthalpy of formation:             -584.547      kJ/mol        97SVE/SHO


+1.000Cl-     +1.000Rb+          = RbCl
     log_k    -1.01         #
     delta_h   13.189       kJ/mol        #
     # Enthalpy of formation:             -405.011      kJ/mol        97SVE/SHO


+1.000Br-     +1.000Rb+          = RbBr
     log_k    -1.24         #
     delta_h   13.836       kJ/mol        #
     # Enthalpy of formation:             -358.694      kJ/mol        97SVE/SHO


+1.000I-     +1.000Rb+          = RbI
     log_k    -0.84         #
     delta_h   6.987        kJ/mol        #
     # Enthalpy of formation:             -300.913      kJ/mol        97SVE/SHO


-4.000H+     -1.000e-     +1.000Pa+4     +2.000H2O          = PaO2+
     log_k     4.22         #85BAR/PAR, 76BAE/MES
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     +1.000Pa+4     +1.000H2O          = Pa(OH)+3
     log_k     0.84         #76BAE/MES
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-2.000H+     +1.000Pa+4     +2.000H2O          = Pa(OH)2+2
     log_k    -0.02         #76BAE/MES
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-3.000H+     +1.000Pa+4     +3.000H2O          = Pa(OH)3+
     log_k    -1.5          #76BAE/MES
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H+     +1.000PaO2+          = PaO(OH)+2
     log_k     1.25         #Original data 03TRU/LEN and 04FOU/PER
     delta_h  -5.7          kJ/mol        #03TRU/LEN
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     +1.000PaO2+     +1.000H2O          = PaO2(OH)
     log_k    -7            #Original data 03TRU/LEN and 04FOU/PER
     delta_h   61           kJ/mol        #03TRU/LEN
     # Enthalpy of formation:                           kJ/mol        


+2.000H+     +1.000SO4-2     +1.000PaO2+     -1.000H2O          = PaO(SO4)+
     log_k     5.13         #07GIA/TRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000H+     +2.000SO4-2     +1.000PaO2+     -1.000H2O          = PaO(SO4)2-
     log_k     8.24         #07GIA/TRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000H+     +3.000SO4-2     +1.000PaO2+     -1.000H2O          = PaO(SO4)3-3
     log_k     9.83         #07GIA/TRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-2.000H+     +1.000PaO2+     +2.000H2O          = PaO2(OH)2-
     log_k    -16.4         #04FOU/PER
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     +1.000Zr+4     +1.000H2O          = Zr(OH)+3
     log_k     0.32         #05BRO/CUR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-2.000H+     +1.000Zr+4     +2.000H2O          = Zr(OH)2+2
     log_k     0.98         #05BRO/CUR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-4.000H+     +1.000Zr+4     +4.000H2O          = Zr(OH)4
     log_k    -2.19         #05BRO/CUR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-6.000H+     +1.000Zr+4     +6.000H2O          = Zr(OH)6-2
     log_k    -29           #05BRO/CUR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-15.000H+     +4.000Zr+4     +15.000H2O          = Zr4(OH)15+
     log_k     12.58        #05BRO/CUR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-16.000H+     +4.000Zr+4     +16.000H2O          = Zr4(OH)16
     log_k     8.39         #05BRO/CUR
     delta_h   301.12       kJ/mol        #
     # Enthalpy of formation:             -6706.16      kJ/mol        05BRO/CUR


+1.000NO3-     +1.000Zr+4          = ZrNO3+3
     log_k     1.59         #05BRO/CUR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000NO3-     +1.000Zr+4          = Zr(NO3)2+2
     log_k     2.64         #05BRO/CUR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000SO4-2     +1.000Zr+4          = ZrSO4+2
     log_k     7.04         #05BRO/CUR
     delta_h   36.94        kJ/mol        #
     # Enthalpy of formation:             -1480.9       kJ/mol        05BRO/CUR


+1.000F-     +1.000Zr+4          = ZrF+3
     log_k     10.12        #05BRO/CUR
     delta_h  -17.5         kJ/mol        #05BRO/CUR
     # Enthalpy of formation:             -961.35       kJ/mol        


+2.000F-     +1.000Zr+4          = ZrF2+2
     log_k     18.55        #05BRO/CUR
     delta_h  -16.8         kJ/mol        #05BRO/CUR
     # Enthalpy of formation:             -1296         kJ/mol        


+3.000F-     +1.000Zr+4          = ZrF3+
     log_k     24.72        #05BRO/CUR
     delta_h  -11.2         kJ/mol        #05BRO/CUR
     # Enthalpy of formation:             -1625.75      kJ/mol        


+4.000F-     +1.000Zr+4          = ZrF4
     log_k     30.11        #05BRO/CUR
     delta_h  -22           kJ/mol        #05BRO/CUR
     # Enthalpy of formation:             -1971.9       kJ/mol        


+5.000F-     +1.000Zr+4          = ZrF5-
     log_k     34.6         #05BRO/CUR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+6.000F-     +1.000Zr+4          = ZrF6-2
     log_k     38.11        #05BRO/CUR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cl-     +1.000Zr+4          = ZrCl+3
     log_k     1.59         #05BRO/CUR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000Cl-     +1.000Zr+4          = ZrCl2+2
     log_k     2.17         #05BRO/CUR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-4.000H+     +3.000Zr+4     +4.000H2O          = Zr3(OH)4+8
     log_k     0.4          #05BRO/CUR
     delta_h  -1.98         kJ/mol        #
     # Enthalpy of formation:             -2970.8       kJ/mol        05BRO/CUR


+4.000CO3-2     +1.000Zr+4          = Zr(CO3)4-4
     log_k     42.9         #05BRO/CUR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000SO4-2     +1.000Zr+4          = Zr(SO4)2
     log_k     11.54        #05BRO/CUR
     delta_h   67.38        kJ/mol        #
     # Enthalpy of formation:             -2359.8       kJ/mol        05BRO/CUR


+3.000SO4-2     +1.000Zr+4          = Zr(SO4)3-2
     log_k     14.3         #05BRO/CUR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     +1.000Sb(OH)5     +1.000H2O          = Sb(OH)6-
     log_k    -2.72         #63LEF/MAR in 76BAE/MES
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-4.000H+     +12.000Sb(OH)5     +4.000H2O          = Sb12(OH)64-4
     log_k     20.34        #63LEF/MAR in 76BAE/MES
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-5.000H+     +12.000Sb(OH)5     +5.000H2O          = Sb12(OH)65-5
     log_k     16.72        #63LEF/MAR in 76BAE/MES
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-6.000H+     +12.000Sb(OH)5     +6.000H2O          = Sb12(OH)66-6
     log_k     11.89        #63LEF/MAR in 76BAE/MES
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-7.000H+     +12.000Sb(OH)5     +7.000H2O          = Sb12(OH)67-7
     log_k     6.07         #63LEF/MAR in 76BAE/MES
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     +1.000Cm+3     +1.000H2O          = Cm(OH)+2
     log_k    -7.2          #03GUI/FAN
     delta_h   79.365       kJ/mol        #
     # Enthalpy of formation:             -821.465      kJ/mol        


-2.000H+     +1.000Cm+3     +2.000H2O          = Cm(OH)2+
     log_k    -15.1         #03GUI/FAN
     delta_h   144.956      kJ/mol        #
     # Enthalpy of formation:             -1041.704     kJ/mol        


-3.000H+     +1.000Cm+3     +3.000H2O          = Cm(OH)3
     log_k    -26.2         #03GUI/FAN
     delta_h   231.675      kJ/mol        #
     # Enthalpy of formation:             -1240.815     kJ/mol        


+1.000CO3-2     +1.000Cm+3          = CmCO3+
     log_k     7.9          #06DUR/CER
     delta_h   153.982      kJ/mol        #
     # Enthalpy of formation:             -1136.248     kJ/mol        


+2.000CO3-2     +1.000Cm+3          = Cm(CO3)2-
     log_k     12.6         #06DUR/CER
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000CO3-2     +1.000Cm+3          = Cm(CO3)3-3
     log_k     14.6         #06DUR/CER
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H+     +1.000CO3-2     +1.000Cm+3          = CmHCO3+2
     log_k     13.43        #03GUI/FAN, same as Am
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     +1.000H4(SiO4)     +1.000Cm+3          = CmSiO(OH)3+2
     log_k    -2.31         #Original data 07THA/SIN, 05PAN/KIM and 97STE/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NO3-     +1.000Cm+3          = CmNO3+2
     log_k     1.33         #95SIL/BID
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-2.000H+     +1.000H2(PO4)-     +1.000Cm+3          = CmPO4
     log_k    -7.66         #estimated by correlation with Ln(III)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-4.000H+     +2.000H2(PO4)-     +1.000Cm+3          = Cm(PO4)2-3
     log_k    -19.23        #estimated by corrlation with Ln(III)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     +1.000H2(PO4)-     +1.000Cm+3          = Cm(HPO4)+
     log_k    -1.7          #estimated by correlation with Ln(III)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-2.000H+     +2.000H2(PO4)-     +1.000Cm+3          = Cm(HPO4)2-
     log_k    -5.21         #estimated by correlation with Ln(III)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-4.000H+     +1.000Cm+3     +4.000H2O          = Cm(OH)4-
     log_k    -40.7         #07NEC/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000SO4-2     +1.000Cm+3          = CmSO4+
     log_k     3.3          #03GUI/FAN, same as Am
     delta_h   15.64        kJ/mol        #
     # Enthalpy of formation:             -1508.7       kJ/mol        estimated by analogy with Ln


+2.000SO4-2     +1.000Cm+3          = Cm(SO4)2-
     log_k     3.7          #03GUI/FAN, same as Am
     delta_h   20.88        kJ/mol        #
     # Enthalpy of formation:             -2412.8       kJ/mol        estimated by analogy with Ln


+1.000F-     +1.000Cm+3          = CmF+2
     log_k     3.4          #03GUI/FAN, same as Am
     delta_h   25.613       kJ/mol        #
     # Enthalpy of formation:             -924.737      kJ/mol        


+2.000F-     +1.000Cm+3          = CmF2+
     log_k     5.8          #03GUI/FAN, same as Am
     delta_h   20.62        kJ/mol        #
     # Enthalpy of formation:             -1265.08      kJ/mol        


+3.000F-     +1.000Cm+3          = CmF3
     log_k     11.18        #69AZI/LYL
     delta_h  -15.485       kJ/mol        #
     # Enthalpy of formation:             -1636.535     kJ/mol        


+1.000Cl-     +1.000Cm+3          = CmCl+2
     log_k     0.24         #03GUI/FAN, same as Am
     delta_h   22.512       kJ/mol        #
     # Enthalpy of formation:             -759.568      kJ/mol        


+2.000Cl-     +1.000Cm+3          = CmCl2+
     log_k    -0.74         #03GUI/FAN, same as Am
     delta_h   41.165       kJ/mol        #
     # Enthalpy of formation:             -907.995      kJ/mol        


+1.000H2(PO4)-     +1.000Cm+3          = Cm(H2PO4)+2
     log_k     2.4          #estimated by correlation with Ln(III)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000H+     +1.000S2O4-2          = H2S2O4
     log_k     2.8          #04CHI
     delta_h   20.207       kJ/mol        #
     # Enthalpy of formation:             -733.293      kJ/mol        


+1.000H+     +1.000S2O4-2          = HS2O4-
     log_k     2.5          #04CHI
     delta_h   3.834        kJ/mol        #
     # Enthalpy of formation:             -749.666      kJ/mol        


+8.000H+     +4.000e-     +1.000CrO4-2     -4.000H2O          = Cr+2
     log_k     67.22        #04CHI
     delta_h  -421.939      kJ/mol        #
     # Enthalpy of formation:             -157.62       kJ/mol        


+8.000H+     +3.000e-     +1.000CrO4-2     -4.000H2O          = Cr+3
     log_k     73.62        #
     delta_h  -504.82       kJ/mol        #
     # Enthalpy of formation:             -240.5        kJ/mol        04CHI


+1.000H+     +1.000CrO4-2          = HCrO4-
     log_k     6.52         #87PAL/WES, 04CHI
     delta_h   6.016        kJ/mol        #
     # Enthalpy of formation:             -872.984      kJ/mol        


+2.000H+     +1.000CrO4-2          = H2CrO4
     log_k     6.32         #76BAE/MES, 04CHI
     delta_h   39.596       kJ/mol        #
     # Enthalpy of formation:             -839.404      kJ/mol        


+2.000H+     +2.000CrO4-2     -1.000H2O          = Cr2O7-2
     log_k     14.75        #87PAL/WES, 04CHI
     delta_h  -3.752        kJ/mol        #
     # Enthalpy of formation:             -1475.923     kJ/mol        


+1.000H+     +1.000H2(PO4)-     +1.000CrO4-2     -1.000H2O          = HCrPO7-2
     log_k     6.37         #
     delta_h  -36.39        kJ/mol        #
     # Enthalpy of formation:             -1932.16      kJ/mol        76DEL/HEP


+2.000H+     +1.000H2(PO4)-     +1.000CrO4-2     -1.000H2O          = H2CrPO7-
     log_k     9.02         #
     delta_h  -51.49        kJ/mol        #
     # Enthalpy of formation:             -1947.26      kJ/mol        76DEL/HWP


+2.000H+     +1.000Cl-     +1.000CrO4-2     -1.000H2O          = CrO3Cl-
     log_k     8.08         #
     delta_h   5.5          kJ/mol        #
     # Enthalpy of formation:             -754.8        kJ/mol        76DEL/HEP


-1.000H+     +1.000Cr+2     +1.000H2O          = Cr(OH)+
     log_k    -5.3          #83MIC/DEB, 04CHI
     delta_h   30.327       kJ/mol        #
     # Enthalpy of formation:             -413.123      kJ/mol        


+1.000Cl-     +1.000Cr+2          = CrCl+
     log_k     5.6          #91ALL/BRO
     delta_h  -20.2         kJ/mol        #91ALL/BRO
     # Enthalpy of formation:             -344.9        kJ/mol        


-1.000H+     +1.000Cr+3     +1.000H2O          = Cr(OH)+2
     log_k    -3.57         #87RAI/SAS, 04CHI
     delta_h   38.079       kJ/mol        #
     # Enthalpy of formation:             -488.251      kJ/mol        


-2.000H+     +1.000Cr+3     +2.000H2O          = Cr(OH)2+
     log_k    -9.84         #87RAI/SAS, 04CHI
     delta_h   98.567       kJ/mol        #
     # Enthalpy of formation:             -713.593      kJ/mol        


-3.000H+     +1.000Cr+3     +3.000H2O          = Cr(OH)3
     log_k    -16.19        #87RAI/SAS, 04CHI
     delta_h   154.249      kJ/mol        #
     # Enthalpy of formation:             -943.74       kJ/mol        


-4.000H+     +1.000Cr+3     +4.000H2O          = Cr(OH)4-
     log_k    -27.65        #87RAI/SAS, 04CHI
     delta_h   203.822      kJ/mol        #
     # Enthalpy of formation:             -1179.997     kJ/mol        


-2.000H+     +2.000Cr+3     +2.000H2O          = Cr2(OH)2+4
     log_k    -5            #87RAI/SAS, 04CHI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-4.000H+     +3.000Cr+3     +4.000H2O          = Cr3(OH)4+5
     log_k    -10.75        #87RAI/SAS, 04CHI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     +1.000H2(PO4)-     +1.000Cr+3          = Cr(HPO4)+
     log_k     2.25         #76ALE/MAS
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H2(PO4)-     +1.000Cr+3          = Cr(H2PO4)+2
     log_k     2.56         #66LAH/ADI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-3.000H+     +1.000H2(PO4)-     +1.000Cr+3     +3.000H2O          = Cr(OH)3(H2PO4)-
     log_k    -7.87         #98ZIE/JON
     delta_h   12.2         kJ/mol        #98ZIE/JON
     # Enthalpy of formation:             -2388.42      kJ/mol        


-4.000H+     +1.000H2(PO4)-     +1.000Cr+3     +3.000H2O          = Cr(OH)3(HPO4)-2
     log_k    -17.92        #98ZIE/JON
     delta_h   13.9         kJ/mol        #98ZIE/JON
     # Enthalpy of formation:             -2386.7       kJ/mol        


-5.000H+     +1.000H2(PO4)-     +1.000Cr+3     +3.000H2O          = Cr(OH)3(PO4)-3
     log_k    -30.39        #98ZIE/JON
     delta_h   23.8         kJ/mol        #98ZIE/JON
     # Enthalpy of formation:             -2376.8       kJ/mol        


-5.000H+     +2.000H2(PO4)-     +1.000Cr+3     +4.000H2O          = Cr(OH)4(HPO4)(H2PO4)-4
     log_k    -28.76        #98ZIE/JON
     delta_h   14           kJ/mol        #98ZIE/JON
     # Enthalpy of formation:             -3975.04      kJ/mol        


+1.000SO4-2     +1.000Cr+3          = CrSO4+
     log_k     4.61         #81TUR/WHI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Cl-     +1.000Cr+3          = CrCl+2
     log_k     0.62         #64SIL/MAR
     delta_h   20.92        kJ/mol        #64SIL/MAR
     # Enthalpy of formation:             -386.66       kJ/mol        


+2.000Cl-     +1.000Cr+3          = CrCl2+
     log_k    -0.71         #64SIL/MAR
     delta_h   20.92        kJ/mol        #64SIL/MAR
     # Enthalpy of formation:             -553.74       kJ/mol        


-1.000H+     +2.000Cl-     +1.000Cr+3     +1.000H2O          = Cr(OH)Cl2
     log_k    -5.73         #
     delta_h   32.72        kJ/mol        #
     # Enthalpy of formation:             -827.77       kJ/mol        76DEL/HEP


+1.000Br-     +1.000Cr+3          = CrBr+2
     log_k    -0.62         #
     delta_h   22.6         kJ/mol        #
     # Enthalpy of formation:             -339.322      kJ/mol        76DEL/HEP


+1.000F-     +1.000Cr+3          = CrF+2
     log_k     5.21         #81TUR/WHI
     delta_h  -2.51         kJ/mol        #53HEP/JOL
     # Enthalpy of formation:             -578.36       kJ/mol        


+2.000F-     +1.000Cr+3          = CrF2+
     log_k     9.31         #81TUR/WHI
     delta_h  -0.418        kJ/mol        #53HEP/JOL
     # Enthalpy of formation:             -911.618      kJ/mol        


+3.000F-     +1.000Cr+3          = CrF3
     log_k     11.91        #81TUR/WHI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+2     +2.000I-          = SnI2
     log_k     2.69         #68HAI/JOH recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+4     -6.000H+     +6.000H2O          = Sn(OH)6-2
     log_k    -18.88        #98ODA/AMA in 99LOT/OCH recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sn+4     -5.000H+     +5.000H2O          = Sn(OH)5-
     log_k    -8.46         #98ODA/AMA in 99 LOT/OCH recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     -1.000H+     +1.000H2O          = Th(OH)+3
     log_k    -2.5          #09RAN/FUG
     delta_h   44.2         kJ/mol        #09RAN/FUG
     # Enthalpy of formation:             -1010.33      kJ/mol        


+1.000Th+4     -2.000H+     +2.000H2O          = Th(OH)2+2
     log_k    -6.2          #09RAN/FUG
     delta_h   85.7         kJ/mol        #09RAN/FUG
     # Enthalpy of formation:             -1254.66      kJ/mol        


+1.000Th+4     -3.000H+     +3.000H2O          = Th(OH)3+
     log_k    -11           #09GRI/RIB
     delta_h   125.623      kJ/mol        #
     # Enthalpy of formation:             -1500.554     kJ/mol        


+2.000Th+4     -2.000H+     +2.000H2O          = Th2(OH)2+6
     log_k    -5.9          #09RAN/FUG
     delta_h   58.3         kJ/mol        #09RAN/FUG
     # Enthalpy of formation:             -2050.76      kJ/mol        


+4.000Th+4     -8.000H+     +8.000H2O          = Th4(OH)8+8
     log_k    -20.4         #09RAN/FUG
     delta_h   243          kJ/mol        #09RAN/FUG
     # Enthalpy of formation:             -5118.44      kJ/mol        


+1.000Th+4     +1.000F-          = ThF+3
     log_k     8.87         #09RAN/FUG
     delta_h  -0.4          kJ/mol        #09RAN/FUG
     # Enthalpy of formation:             -1104.45      kJ/mol        


+1.000Th+4     +2.000F-          = ThF2+2
     log_k     15.63        #09RAN/FUG
     delta_h  -3.3          kJ/mol        #09RAN/FUG
     # Enthalpy of formation:             -1442.7       kJ/mol        


+1.000Th+4     +3.000F-          = ThF3+
     log_k     20.67        #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +4.000F-          = ThF4
     log_k     25.58        #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +1.000Cl-          = ThCl+3
     log_k     1.7          #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +1.000SO4-2          = Th(SO4)+2
     log_k     6.17         #09RAN/FUG
     delta_h   20.92        kJ/mol        #09RAN/FUG
     # Enthalpy of formation:             -1657.12      kJ/mol        


+1.000Th+4     +2.000SO4-2          = Th(SO4)2
     log_k     9.69         #09RAN/FUG
     delta_h   40.38        kJ/mol        #09RAN/FUG
     # Enthalpy of formation:             -2547         kJ/mol        


+1.000Th+4     +1.000NO3-          = Th(NO3)+3
     log_k     1.3          #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +5.000CO3-2          = Th(CO3)5-6
     log_k     31           #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+6.000Th+4     -15.000H+     +15.000H2O          = Th6(OH)15+9
     log_k    -36.8         #09RAN/FUG
     delta_h   472.8        kJ/mol        #09RAN/FUG
     # Enthalpy of formation:             -8426.85      kJ/mol        


+1.000Th+4     -3.000H+     +1.000CO3-2     +3.000H2O          = Th(OH)3(CO3)-
     log_k    -3.7          #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     -4.000H+     +4.000H2O          = Th(OH)4
     log_k    -17.4         #09RAN/FUG
     delta_h   152.688      kJ/mol        #
     # Enthalpy of formation:             -1759.319     kJ/mol        


+1.000UO2+2     -1.000H+     +1.000H2O          = UO2(OH)+
     log_k    -5.25         #03GUI/FAN
     delta_h   43.458       kJ/mol        #
     # Enthalpy of formation:             -1261.372     kJ/mol        


+2.000UO2+2     -1.000H+     +1.000H2O          = (UO2)2(OH)+3
     log_k    -2.7          #92GRE/FUG
     delta_h   14.354       kJ/mol        #
     # Enthalpy of formation:             -2309.476     kJ/mol        


+2.000UO2+2     -2.000H+     +2.000H2O          = (UO2)2(OH)2+2
     log_k    -5.62         #92GRE/FUG
     delta_h   37.595       kJ/mol        #
     # Enthalpy of formation:             -2572.065     kJ/mol        


+3.000UO2+2     -5.000H+     +5.000H2O          = (UO2)3(OH)5+
     log_k    -15.55        #92GRE/FUG
     delta_h   97.063       kJ/mol        #
     # Enthalpy of formation:             -4389.086     kJ/mol        


+3.000UO2+2     -7.000H+     +7.000H2O          = (UO2)3(OH)7-
     log_k    -32.2         #92SAN/BRU
     delta_h   229.868      kJ/mol        #
     # Enthalpy of formation:             -4827.942     kJ/mol        


+1.000UO2+2     -2.000H+     +2.000H2O          = UO2(OH)2
     log_k    -12.15        #03GUI/FAN
     delta_h   111.16       kJ/mol        #
     # Enthalpy of formation:             -1479.5       kJ/mol        82WAG/EVA


+1.000UO2+2     -3.000H+     +3.000H2O          = UO2(OH)3-
     log_k    -20.25        #03GUI/FAN
     delta_h   148.06       kJ/mol        #Estimated by linear correlations
     # Enthalpy of formation:             -1728.43      kJ/mol        


+1.000UO2+2     -4.000H+     +4.000H2O          = UO2(OH)4-2
     log_k    -32.4         #03GUI/FAN
     delta_h   156.138      kJ/mol        #
     # Enthalpy of formation:             -2006.182     kJ/mol        


+1.000UO2+2     +1.000SO4-2          = UO2(SO4)
     log_k     3.15         #03GUI/FAN
     delta_h   19.5         kJ/mol        #03GUI/FAN
     # Enthalpy of formation:             -1908.84      kJ/mol        


+1.000UO2+2     +2.000SO4-2          = UO2(SO4)2-2
     log_k     4.14         #03GUI/FAN
     delta_h   35.1         kJ/mol        #03GUI/FAN
     # Enthalpy of formation:             -2802.58      kJ/mol        


+1.000UO2+2     +1.000Cl-          = UO2Cl+
     log_k     0.17         #92GRE/FUG
     delta_h   8            kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -1178.08      kJ/mol        


+1.000UO2+2     +2.000Cl-          = UO2Cl2
     log_k    -1.1          #92GRE/FUG
     delta_h   15           kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -1338.16      kJ/mol        


+1.000UO2+2     +1.000F-          = UO2F+
     log_k     5.16         #03GUI/FAN
     delta_h   1.7          kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -1352.65      kJ/mol        


+1.000UO2+2     +2.000F-          = UO2F2
     log_k     8.83         #03GUI/FAN
     delta_h   2.1          kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -1687.6       kJ/mol        


+1.000UO2+2     +3.000F-          = UO2F3-
     log_k     10.9         #03GUI/FAN
     delta_h   2.35         kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -2022.7       kJ/mol        


+1.000UO2+2     +4.000F-          = UO2F4-2
     log_k     11.84        #03GUI/FAN
     delta_h   0.29         kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -2360.11      kJ/mol        


+1.000UO2+2     +1.000Br-          = UO2Br+
     log_k     0.22         #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     +1.000NO3-          = UO2(NO3)+
     log_k     0.3          #92GRE/FUG
     delta_h   3.9          kJ/mol        #08RAO/TIA
     # Enthalpy of formation:             -1221.95      kJ/mol        


+1.000UO2+2     +2.000CO3-2          = UO2(CO3)2-2
     log_k     16.61        #03GUI/FAN
     delta_h   18.5         kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -2350.96      kJ/mol        


+1.000UO2+2     +3.000CO3-2          = UO2(CO3)3-4
     log_k     21.84        #03GUI/FAN
     delta_h  -39.2         kJ/mol        #
     # Enthalpy of formation:             -3083.89      kJ/mol        


+1.000UO2+2     +1.000S2O3-2          = UO2(S2O3)
     log_k     2.8          #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000UO2+2     +6.000CO3-2          = (UO2)3(CO3)6-6
     log_k     54           #92GRE/FUG
     delta_h  -62.7         kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -7171.08      kJ/mol        


+1.000UO2+2     +1.000CO3-2          = UO2(CO3)
     log_k     9.94         #03GUI/FAN
     delta_h   5            kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -1689.23      kJ/mol        


+1.000UO2+2     +1.000H2(PO4)-          = UO2(H2PO4)+
     log_k     3.26         #92GRE/FUG
     delta_h  -15.34        kJ/mol        #
     # Enthalpy of formation:             -2336.94      kJ/mol        


+1.000UO2+2     +2.000H2(PO4)-          = UO2(H2PO4)2
     log_k     4.92         #92GRE/FUG
     delta_h  -51.871       kJ/mol        #
     # Enthalpy of formation:             -6902.925     kJ/mol        


+1.000UO2+2     -2.000H+     +1.000H2(PO4)-          = UO2(PO4)-
     log_k    -6.33         #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     -1.000H+     +1.000H2(PO4)-          = UO2(HPO4)
     log_k     0.03         #92GRE/FUG
     delta_h   2.795        kJ/mol        #
     # Enthalpy of formation:             -4408.507     kJ/mol        


+1.000UO2+2     +1.000H+     +1.000H2(PO4)-          = UO2(H3PO4)+2
     log_k     2.9          #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     +1.000H+     +2.000H2(PO4)-          = UO2H5(PO4)2+
     log_k     5.93         #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     +1.000SO3-2          = UO2(SO3)
     log_k     6.6          #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000UO2+2     +1.000NpO2+2     +6.000CO3-2          = (UO2)2(NpO2)(CO3)6-6
     log_k     53.59        #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000UO2+2     -3.000H+     +1.000CO3-2     +3.000H2O          = (UO2)2(CO3)(OH)3-
     log_k    -0.86         #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+3.000UO2+2     -3.000H+     +1.000CO3-2     +3.000H2O          = (UO2)3(CO3)(OH)3+
     log_k     0.66         #92GRE/FUG
     delta_h   81.159       kJ/mol        #
     # Enthalpy of formation:             -4361.23      kJ/mol        


+3.000UO2+2     -4.000H+     +4.000H2O          = (UO2)3(OH)4+2
     log_k    -11.9         #92GRE/FUG
     delta_h   84.264       kJ/mol        #
     # Enthalpy of formation:             -4251.906     kJ/mol        


+4.000UO2+2     -7.000H+     +7.000H2O          = (UO2)4(OH)7+
     log_k    -21.9         #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000PuO2+2     -1.000H+     +1.000H2O          = PuO2(OH)+
     log_k    -5.5          #01LEM/FUG
     delta_h   28           kJ/mol        #01LEM/FUG
     # Enthalpy of formation:             -1079.866     kJ/mol        


+1.000PuO2+2     -2.000H+     +2.000H2O          = PuO2(OH)2
     log_k    -13.2         #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000PuO2+2     -2.000H+     +2.000H2O          = (PuO2)2(OH)2+2
     log_k    -7.5          #01LEM/FUG
     delta_h   43.583       kJ/mol        #
     # Enthalpy of formation:             -2172.149     kJ/mol        


+1.000PuO2+2     +1.000CO3-2          = PuO2(CO3)
     log_k     9.5          #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000PuO2+2     +2.000CO3-2          = PuO2(CO3)2-2
     log_k     14.7         #03GUI/FAN
     delta_h  -27           kJ/mol        #03GUI/FAN
     # Enthalpy of formation:             -2199.496     kJ/mol        


+1.000PuO2+2     +3.000CO3-2          = PuO2(CO3)3-4
     log_k     18           #03GUI/FAN
     delta_h  -38.6         kJ/mol        #03GUI/FAN
     # Enthalpy of formation:             -2886.326     kJ/mol        


+3.000PuO2+2     +6.000CO3-2          = (PuO2)3(CO3)6-6
     log_k     46.02        #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000UO2+2     +1.000PuO2+2     +6.000CO3-2          = PuO2(CO3)6(UO2)2-6
     log_k     53.48        #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000PuO2+2     +1.000Cl-          = PuO2Cl+
     log_k     0.23         #03GUI/FAN
     delta_h   4.187        kJ/mol        #
     # Enthalpy of formation:             -984.929      kJ/mol        


+1.000PuO2+2     +2.000Cl-          = PuO2Cl2
     log_k    -1.15         #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000PuO2+2     +1.000F-          = PuO2F+
     log_k     4.56         #01LEM/FUG
     delta_h  -3.653        kJ/mol        #
     # Enthalpy of formation:             -1161.039     kJ/mol        


+1.000PuO2+2     +2.000F-          = PuO2F2
     log_k     7.25         #01LEM/FUG
     delta_h   1.208        kJ/mol        #
     # Enthalpy of formation:             -1491.528     kJ/mol        


+1.000PuO2+2     +3.000F-          = PuO2F3-
     log_k     9.59         #85SAW/CHA
     delta_h   2.401        kJ/mol        #
     # Enthalpy of formation:             -1825.685     kJ/mol        


+1.000PuO2+2     +1.000SO4-2          = PuO2(SO4)
     log_k     3.38         #01LEM/FUG
     delta_h   16.1         kJ/mol        #01LEM/FUG
     # Enthalpy of formation:             -1715.276     kJ/mol        


+1.000PuO2+2     +2.000SO4-2          = PuO2(SO4)2-2
     log_k     4.4          #01LEM/FUG
     delta_h   43           kJ/mol        #01LEM/FUG
     # Enthalpy of formation:             -2597.716     kJ/mol        


+1.000PuO2+2     +1.000e-          = PuO2+
     log_k     15.82        #
     delta_h  -88.091       kJ/mol        #01LEM/FUG
     # Enthalpy of formation:             -910.127      kJ/mol        


+1.000PuO2+     +3.000CO3-2          = PuO2(CO3)3-5
     log_k     5.03         #
     delta_h  -19.11        kJ/mol        #01LEM/FUG
     # Enthalpy of formation:             -2954.927     kJ/mol        


+1.000PuO2+     +1.000SO4-2          = PuO2(SO4)-
     log_k     0.44         #In analogy to NpO2)(SO4)-
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000PuO2+     +1.000F-          = PuO2F
     log_k     1.2          #In analogy to NpO2)F
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000PuO2+     -1.000H+     +1.000H2(PO4)-          = PuO2(HPO4)-
     log_k    -4.86         #NEA Guidelines in 01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     -1.000H+     +1.000H2O          = Pu(OH)+3
     log_k     0.6          #99NEC, 01NEC/KIM, 03GUI/FAN
     delta_h   36           kJ/mol        #01LEM/FUG
     # Enthalpy of formation:             -789.725      kJ/mol        


+1.000Pu+4     -2.000H+     +2.000H2O          = Pu(OH)2+2
     log_k     0.6          #99NEC, 01NEC/KIM, 03GUI/FAN
     delta_h   49.569       kJ/mol        #
     # Enthalpy of formation:             -1061.986     kJ/mol        


+1.000Pu+4     -3.000H+     +3.000H2O          = Pu(OH)3+
     log_k    -2.3          #99NEC, 01NEC/KIM, 03GUI/FAN
     delta_h   68.543       kJ/mol        #
     # Enthalpy of formation:             -1328.842     kJ/mol        


+1.000Pu+4     -4.000H+     +4.000H2O          = Pu(OH)4
     log_k    -8.5          #03GUI/FAN
     delta_h   99.049       kJ/mol        #
     # Enthalpy of formation:             -1584.166     kJ/mol        


+1.000Pu+4     +5.000CO3-2          = Pu(CO3)5-6
     log_k     35.65        #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     +4.000CO3-2          = Pu(CO3)4-4
     log_k     37           #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     +1.000SO4-2          = Pu(SO4)+2
     log_k     6.89         #01LEM/FUG
     delta_h   13.753       kJ/mol        #
     # Enthalpy of formation:             -1435.482     kJ/mol        


+1.000Pu+4     +2.000SO4-2          = Pu(SO4)2
     log_k     11.14        #01LEM/FUG
     delta_h   43.906       kJ/mol        #
     # Enthalpy of formation:             -2314.669     kJ/mol        


+1.000Pu+4     +1.000Cl-          = PuCl+3
     log_k     1.8          #01LEM/FUG
     delta_h   19.82        kJ/mol        #
     # Enthalpy of formation:             -687.155      kJ/mol        


+1.000Pu+4     +1.000F-          = PuF+3
     log_k     8.84         #01LEM/FUG
     delta_h   9.1          kJ/mol        #01LEM/FUG
     # Enthalpy of formation:             -866.145      kJ/mol        


+1.000Pu+4     +2.000F-          = PuF2+2
     log_k     15.7         #01LEM/FUG
     delta_h   11           kJ/mol        #01LEM/FUG
     # Enthalpy of formation:             -1199.595     kJ/mol        


+1.000Pu+4     +1.000I-          = PuI+3
     log_k     1.62         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     +1.000NO3-          = Pu(NO3)+3
     log_k     1.95         #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     +1.000Br-          = PuBr+3
     log_k     1.6          #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     +3.000F-          = PuF3+
     log_k     20.11        #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+4     +1.000e-          = Pu+3
     log_k     17.69        #
     delta_h  -51.895       kJ/mol        #
     # Enthalpy of formation:             -591.79       kJ/mol        01LEM/FUG


+1.000Pu+3     -1.000H+     +1.000H2O          = Pu(OH)+2
     log_k    -6.9          #01LEM/FUG
     delta_h   78.274       kJ/mol        #
     # Enthalpy of formation:             -799.346      kJ/mol        


+1.000Pu+3     -2.000H+     +2.000H2O          = Pu(OH)2+
     log_k    -15.9         #80ALL/KIP
     delta_h   150.342      kJ/mol        #
     # Enthalpy of formation:             -1013.108     kJ/mol        


+1.000Pu+3     -3.000H+     +3.000H2O          = Pu(OH)3
     log_k    -25.3         #80ALL/KIP
     delta_h   227.54       kJ/mol        #
     # Enthalpy of formation:             -1221.74      kJ/mol        


+1.000Pu+3     +1.000CO3-2          = Pu(CO3)+
     log_k     7.64         #Estimated by correlation with An(III) in function of ionic radii
     delta_h   152.754      kJ/mol        #
     # Enthalpy of formation:             -1114.266     kJ/mol        


+1.000Pu+3     +2.000CO3-2          = Pu(CO3)2-
     log_k     12.54        #Estimated by correlation with An(III) in function of ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+3     +3.000CO3-2          = Pu(CO3)3-3
     log_k     16.4         #Estimated by correlation with An(III) in function of ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+3     +1.000SO4-2          = Pu(SO4)+
     log_k     3.91         #01LEM/FUG
     delta_h   17.24        kJ/mol        #01LEM/FUG
     # Enthalpy of formation:             -1483.89      kJ/mol        


+1.000Pu+3     +2.000SO4-2          = Pu(SO4)2-
     log_k     5.7          #01LEM/FUG
     delta_h   11.88        kJ/mol        #01LEM/FUG
     # Enthalpy of formation:             -2398.59      kJ/mol        


+1.000Pu+3     +1.000I-          = PuI+2
     log_k     1.1          #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+3     -1.000H+     +1.000H2(PO4)-          = Pu(HPO4)+
     log_k    -1.82         #Estimated by correlation with An(III) in function of ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+3     -2.000H+     +2.000H2(PO4)-          = Pu(HPO4)2-
     log_k    -5.46         #Estimated by correlation with An(III) in function of ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pu+3     +1.000NO3-          = Pu(NO3)+2
     log_k     1.33         #95SIL/BID
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000U+4     +1.000e-          = U+3
     log_k    -9.35         #92GRE/FUG
     delta_h   102.1        kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -489.1        kJ/mol        


+1.000UO2+2     +4.000H+     +2.000e-     -2.000H2O          = U+4
     log_k     9.04         #92GRE/FUG
     delta_h  -143.86       kJ/mol        #
     # Enthalpy of formation:             -591.2        kJ/mol        92GRE/FUG


+1.000U+4     -1.000H+     +1.000H2O          = U(OH)+3
     log_k    -0.54         #92GRE/FUG
     delta_h   46.91        kJ/mol        #
     # Enthalpy of formation:             -830.12       kJ/mol        


+1.000U+4     -4.000H+     +4.000H2O          = U(OH)4
     log_k    -10           #03GUI/FAN
     delta_h   109.881      kJ/mol        #
     # Enthalpy of formation:             -1624.639     kJ/mol        


+1.000U+4     +5.000CO3-2          = U(CO3)5-6
     log_k     34           #03GUI/FAN
     delta_h  -20           kJ/mol        #03GUI/FAN
     # Enthalpy of formation:             -3987.35      kJ/mol        


+1.000U+4     +1.000SO4-2          = U(SO4)+2
     log_k     6.58         #92GRE/FUG
     delta_h   8            kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -1492.54      kJ/mol        


+1.000U+4     +2.000SO4-2          = U(SO4)2
     log_k     10.51        #92GRE/FUG
     delta_h   32.7         kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -2377.18      kJ/mol        


+1.000U+4     +1.000Cl-          = UCl+3
     log_k     1.72         #92GRE/FUG
     delta_h  -19           kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -777.28       kJ/mol        


+1.000U+4     +1.000Br-          = UBr+3
     log_k     1.46         #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000U+4     +1.000F-          = UF+3
     log_k     9.42         #03GUI/FAN
     delta_h  -5.6          kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -932.15       kJ/mol        


+1.000U+4     +2.000F-          = UF2+2
     log_k     16.56        #03GUI/FAN
     delta_h  -3.5          kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -1265.4       kJ/mol        


+1.000U+4     +3.000F-          = UF3+
     log_k     21.89        #03GUI/FAN
     delta_h   0.5          kJ/mol        #92GRE/FUG
     # Enthalpy of formation:             -1596.75      kJ/mol        


+1.000U+4     +4.000F-          = UF4
     log_k     26.34        #03GUI/FAN
     delta_h  -8.429        kJ/mol        #
     # Enthalpy of formation:             -1941.029     kJ/mol        


+1.000U+4     +5.000F-          = UF5-
     log_k     27.73        #03GUI/FAN
     delta_h  -11.624       kJ/mol        #
     # Enthalpy of formation:             -2279.574     kJ/mol        


+1.000U+4     +6.000F-          = UF6-2
     log_k     29.8         #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000U+4     +1.000I-          = UI+3
     log_k     1.25         #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000U+4     +1.000NO3-          = U(NO3)+3
     log_k     1.47         #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000U+4     +2.000NO3-          = U(NO3)2+2
     log_k     2.3          #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000U+4     +4.000CO3-2          = U(CO3)4-4
     log_k     35.12        #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000UO2+2     +1.000e-          = UO2+
     log_k     1.48         #
     delta_h  -6.127        kJ/mol        #
     # Enthalpy of formation:             -1025.127     kJ/mol        


+1.000UO2+     +3.000CO3-2          = UO2(CO3)3-5
     log_k     6.95         #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     +1.000e-          = Np+3
     log_k     3.7          #
     delta_h   28.838       kJ/mol        #
     # Enthalpy of formation:             -527.184      kJ/mol        01LEM/FUG


+1.000Np+3     -1.000H+     +1.000H2O          = Np(OH)+2
     log_k    -6.8          #01LEM/FUG
     delta_h   77.089       kJ/mol        #
     # Enthalpy of formation:             -735.925      kJ/mol        


+1.000Np+3     -2.000H+     +2.000H2O          = Np(OH)2+
     log_k    -17           #80ALL/KIP
     delta_h   155.529      kJ/mol        #
     # Enthalpy of formation:             -943.315      kJ/mol        


+1.000Np+3     -3.000H+     +3.000H2O          = Np(OH)3
     log_k    -27           #80ALL/KIP
     delta_h   235.824      kJ/mol        #
     # Enthalpy of formation:             -1148.85      kJ/mol        


+1.000Np+3     +1.000CO3-2          = Np(CO3)+
     log_k     7.67         #Estimated by correlation with An(III) in function of ionic radii
     delta_h   156.37       kJ/mol        #
     # Enthalpy of formation:             -1046.044     kJ/mol        


+1.000Np+3     +2.000CO3-2          = Np(CO3)2-
     log_k     12.6         #Estimated by correlation with An(III) in function of ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+3     +3.000CO3-2          = Np(CO3)3-3
     log_k     15.66        #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+3     +1.000SO4-2          = Np(SO4)+
     log_k     3.86         #Estimated by correlation with An(III) in function of ionic radii
     delta_h   17.886       kJ/mol        #
     # Enthalpy of formation:             -1418.638     kJ/mol        


+1.000Np+3     +2.000SO4-2          = Np(SO4)2-
     log_k     5.56         #Estimated by correlation with An(III) in function of ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     -1.000H+     +1.000H2O          = Np(OH)+3
     log_k     0.55         #03GUI/FAN
     delta_h   38.192       kJ/mol        #
     # Enthalpy of formation:             -803.66       kJ/mol        


+1.000Np+4     -4.000H+     +4.000H2O          = Np(OH)4
     log_k    -8.3          #03GUI/FAN
     delta_h   101.442      kJ/mol        #
     # Enthalpy of formation:             -1597.9       kJ/mol        


+1.000Np+4     +4.000CO3-2          = Np(CO3)4-4
     log_k     36.68        #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     +5.000CO3-2          = Np(CO3)5-6
     log_k     35.61        #01LEM/FUG
     delta_h  -1.612        kJ/mol        #
     # Enthalpy of formation:             -3933.784     kJ/mol        


+1.000Np+4     +1.000SO4-2          = Np(SO4)+2
     log_k     6.85         #01LEM/FUG
     delta_h   29.84        kJ/mol        #01LEM/FUG
     # Enthalpy of formation:             -1435.522     kJ/mol        01LEM/FUG


+1.000Np+4     +2.000SO4-2          = Np(SO4)2
     log_k     11.05        #01LEM/FUG
     delta_h   55.38        kJ/mol        #01LEM/FUG
     # Enthalpy of formation:             -2319.322     kJ/mol        


+1.000Np+4     +1.000Cl-          = NpCl+3
     log_k     1.5          #01LEM/FUG
     delta_h   24.173       kJ/mol        #
     # Enthalpy of formation:             -698.929      kJ/mol        


+1.000Np+4     +1.000F-          = NpF+3
     log_k     8.96         #01LEM/FUG
     delta_h   1.5          kJ/mol        #01LEM/FUG
     # Enthalpy of formation:             -889.872      kJ/mol        


+1.000Np+4     +2.000F-          = NpF2+2
     log_k     15.7         #01LEM/FUG
     delta_h   15.93        kJ/mol        #
     # Enthalpy of formation:             -1210.792     kJ/mol        


+1.000Np+4     +3.000F-          = NpF3+
     log_k     20.05        #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     +4.000F-          = NpF4
     log_k     25.95        #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     +1.000I-          = NpI+3
     log_k     1.5          #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     +1.000NO3-          = Np(NO3)+3
     log_k     1.9          #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Np+4     -3.000H+     +1.000CO3-2     +3.000H2O          = Np(CO3)(OH)3-
     log_k     3.82         #93ERI/NDA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NpO2+2     +1.000e-          = NpO2+
     log_k     19.59        #
     delta_h  -117.448      kJ/mol        #
     # Enthalpy of formation:             -978.181      kJ/mol        01LEM/FUG


+1.000NpO2+     -1.000H+     +1.000H2O          = NpO2(OH)
     log_k    -11.3         #01LEM/FUG
     delta_h   64.785       kJ/mol        #
     # Enthalpy of formation:             -1199.226     kJ/mol        


+1.000NpO2+     +1.000CO3-2          = NpO2(CO3)-
     log_k     4.96         #01LEM/FUG
     delta_h   59.904       kJ/mol        #
     # Enthalpy of formation:             -1593.507     kJ/mol        


+1.000NpO2+     +2.000CO3-2          = NpO2(CO3)2-3
     log_k     6.53         #01LEM/FUG
     delta_h   39.027       kJ/mol        #
     # Enthalpy of formation:             -2289.614     kJ/mol        


+1.000NpO2+     +3.000CO3-2          = NpO2(CO3)3-5
     log_k     5.5          #
     delta_h  -13.249       kJ/mol        #
     # Enthalpy of formation:             -3017.12      kJ/mol        01LEM/FUG


+1.000NpO2+     +1.000SO4-2          = NpO2(SO4)-
     log_k     0.44         #01LEM/FUG
     delta_h   23.2         kJ/mol        #01LEM/FUG
     # Enthalpy of formation:             -1864.321     kJ/mol        


+1.000NpO2+     +1.000Cl-          = NpO2Cl
     log_k    -0.93         #94NEC/KIM
     delta_h   25.972       kJ/mol        #
     # Enthalpy of formation:             -1119.289     kJ/mol        


+1.000NpO2+     +1.000F-          = NpO2F
     log_k     1.2          #01LEM/FUG
     delta_h   40.768       kJ/mol        #
     # Enthalpy of formation:             -1272.763     kJ/mol        


+1.000NpO2+2     +3.000CO3-2          = NpO2(CO3)3-4
     log_k     19.37        #
     delta_h  -41.9         kJ/mol        #
     # Enthalpy of formation:             -2928.323     kJ/mol        01LEM/FUG


+1.000NpO2+2     -1.000H+     +1.000H2O          = NpO2(OH)+
     log_k    -5.1          #01LEM/FUG
     delta_h   42.957       kJ/mol        #
     # Enthalpy of formation:             -1103.606     kJ/mol        


+1.000NpO2+2     -2.000H+     +2.000H2O          = NpO2(OH)2
     log_k    -12.21        #Estimated by correlation with An(VI) in funciton of ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000NpO2+2     -2.000H+     +2.000H2O          = (NpO2)2(OH)2+2
     log_k    -6.27         #01LEM/FUG
     delta_h   44.996       kJ/mol        #
     # Enthalpy of formation:             -2248.13      kJ/mol        


+1.000NpO2+2     +1.000CO3-2          = NpO2(CO3)
     log_k     9.32         #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NpO2+2     +2.000CO3-2          = NpO2(CO3)2-2
     log_k     16.52        #01LEM/FUG
     delta_h   13.776       kJ/mol        #
     # Enthalpy of formation:             -2197.417     kJ/mol        


+3.000NpO2+2     +6.000CO3-2          = (NpO2)3(CO3)6-6
     log_k     49.84        #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NpO2+2     +1.000SO4-2          = NpO2(SO4)
     log_k     3.28         #01LEM/FUG
     delta_h   16.7         kJ/mol        #01LEM/FUG
     # Enthalpy of formation:             -1753.373     kJ/mol        


+1.000NpO2+2     +2.000SO4-2          = NpO2(SO4)2-2
     log_k     4.7          #01LEM/FUG
     delta_h   26           kJ/mol        #01LEM/FUG
     # Enthalpy of formation:             -2653.413     kJ/mol        


+1.000NpO2+2     +1.000Cl-          = NpO2Cl+
     log_k     0.4          #01LEM/FUG
     delta_h   8.387        kJ/mol        #
     # Enthalpy of formation:             -1019.426     kJ/mol        


+1.000NpO2+2     +1.000F-          = NpO2F+
     log_k     4.57         #01LEM/FUG
     delta_h   1.4          kJ/mol        #
     # Enthalpy of formation:             -1194.683     kJ/mol        


+1.000NpO2+2     +2.000F-          = NpO2F2
     log_k     7.6          #01LEM/FUG
     delta_h   4.321        kJ/mol        #
     # Enthalpy of formation:             -1527.112     kJ/mol        


+1.000NpO2+2     -1.000H+     +1.000H2(PO4)-          = NpO2(HPO4)
     log_k    -1.01         #01LEM/FUG
     delta_h   92.209       kJ/mol        #
     # Enthalpy of formation:             -2071.124     kJ/mol        


+1.000NpO2+2     +1.000NO3-          = NpO2(NO3)+
     log_k     0.3          #logK value in analogy to UO2NO3+
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000NpO2+2     -2.000H+     +1.000CO3-2     +2.000H2O          = NpO2(CO3)(OH)2-2
     log_k    -7.69         #99CHO/BRO
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000TcO(OH)2     +1.000H+     -1.000H2O          = TcO(OH)+
     log_k     2.79         #
     delta_h   4.02         kJ/mol        #97NGU/LAN
     # Enthalpy of formation:             -459.47       kJ/mol        


+1.000TcO(OH)2     -1.000H+     +1.000H2O          = (TcO)(OH)3-
     log_k    -10.8         #
     delta_h   39.03        kJ/mol        #97NGU/LAN
     # Enthalpy of formation:             -996.12       kJ/mol        


+1.000Eu+3     -1.000H+     +1.000H2O          = Eu(OH)+2
     log_k    -7.8          #95SPA/BRU
     delta_h   79.824       kJ/mol        #
     # Enthalpy of formation:             -811.337      kJ/mol        


+1.000Eu+3     -2.000H+     +2.000H2O          = Eu(OH)2+
     log_k    -15.7         #07NEC/ALT
     delta_h   144.521      kJ/mol        #
     # Enthalpy of formation:             -1032.471     kJ/mol        


+1.000Eu+3     -3.000H+     +3.000H2O          = Eu(OH)3
     log_k    -26.2         #07NEC/ALT
     delta_h   226.86       kJ/mol        #
     # Enthalpy of formation:             -1235.961     kJ/mol        


+1.000Eu+3     +1.000CO3-2          = Eu(CO3)+
     log_k     7.9          #95SPA/BRU
     delta_h   167.549      kJ/mol        #
     # Enthalpy of formation:             -1113.013     kJ/mol        


+1.000Eu+3     +1.000F-          = EuF+2
     log_k     4.33         #07LUO/BYR
     delta_h   24.956       kJ/mol        #
     # Enthalpy of formation:             -915.725      kJ/mol        


+1.000Eu+3     +2.000F-          = EuF2+
     log_k     6.55         #Original data from 99SCH/BYR and 04LUO/BYR
     delta_h   21.483       kJ/mol        #
     # Enthalpy of formation:             -1254.548     kJ/mol        


+1.000Eu+3     +1.000Br-          = EuBr+2
     log_k     0.25         #95SPA/BRU
     delta_h   16.223       kJ/mol        #
     # Enthalpy of formation:             -710.518      kJ/mol        


+1.000Eu+3     +2.000Br-          = EuBr2+
     log_k    -0.09         #95SPA/BRU
     delta_h   26.498       kJ/mol        #
     # Enthalpy of formation:             -821.653      kJ/mol        


+1.000Eu+3     +2.000CO3-2          = Eu(CO3)2-
     log_k     12.9         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Eu+3     +1.000H+     +1.000CO3-2          = Eu(HCO3)+2
     log_k     12.43        #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Eu+3     -2.000H+     +1.000H2(PO4)-          = Eu(PO4)
     log_k    -7.36         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Eu+3     -4.000H+     +2.000H2(PO4)-          = Eu(PO4)2-3
     log_k    -18.46        #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Eu+3     +1.000SO4-2          = Eu(SO4)+
     log_k     3.5          #95SPA/BRU
     delta_h   15.577       kJ/mol        #
     # Enthalpy of formation:             -1499.094     kJ/mol        


+1.000Eu+3     +2.000SO4-2          = Eu(SO4)2-
     log_k     5.2          #95SPA/BRU
     delta_h   27.787       kJ/mol        #
     # Enthalpy of formation:             -2396.224     kJ/mol        


+1.000Eu+3     -1.000H+     +1.000H2(PO4)-          = Eu(HPO4)+
     log_k    -1.51         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Eu+3     -2.000H+     +2.000H2(PO4)-          = Eu(HPO4)2-
     log_k    -4.82         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Eu+3     +1.000H2(PO4)-          = Eu(H2PO4)+2
     log_k     2.4          #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Eu+3     +1.000Cl-          = EuCl+2
     log_k     0.76         #Original data 01LUO/BYR and 04LUO/BYR
     delta_h   21.929       kJ/mol        #
     # Enthalpy of formation:             -750.482      kJ/mol        


+1.000Eu+3     +2.000Cl-          = EuCl2+
     log_k    -0.05         #95SPA/BRU
     delta_h   35.334       kJ/mol        #
     # Enthalpy of formation:             -904.158      kJ/mol        


+1.000Sm+3     -1.000H+     +1.000H2O          = Sm(OH)+2
     log_k    -7.9          #95SPA/BRU
     delta_h   81.304       kJ/mol        #
     # Enthalpy of formation:             -895.725      kJ/mol        


+1.000Sm+3     +1.000Cl-          = SmCl+2
     log_k     0.72         #Original data 01LUO/BYR and 07LUO/BYR
     delta_h   22.277       kJ/mol        #
     # Enthalpy of formation:             -836.002      kJ/mol        


+1.000Sm+3     +1.000F-          = SmF+2
     log_k     4.21         #07LUO/BYR
     delta_h   24.18        kJ/mol        #
     # Enthalpy of formation:             -1002.369     kJ/mol        


+1.000Sm+3     +1.000Br-          = SmBr+2
     log_k     0.23         #96FAL/REA
     delta_h   17.023       kJ/mol        #
     # Enthalpy of formation:             -795.586      kJ/mol        


+1.000Sm+3     +1.000H+     +1.000CO3-2          = Sm(HCO3)+2
     log_k     12.43        #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sm+3     +1.000NO3-          = Sm(NO3)+2
     log_k     0.9          #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sm+3     -2.000H+     +1.000H2(PO4)-          = Sm(PO4)
     log_k    -7.46         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sm+3     -4.000H+     +2.000H2(PO4)-          = Sm(PO4)2-3
     log_k    -18.72        #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sm+3     -1.000H+     +1.000H2(PO4)-          = Sm(HPO4)+
     log_k    -1.61         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sm+3     -2.000H+     +2.000H2(PO4)-          = Sm(HPO4)2-
     log_k    -5.02         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sm+3     +1.000H2(PO4)-          = Sm(H2PO4)+2
     log_k     2.35         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sm+3     -4.000H+     +4.000H2O          = Sm(OH)4-
     log_k    -40.7         #07NEC/ALT
     delta_h   298.594      kJ/mol        #
     # Enthalpy of formation:             -1535.925     kJ/mol        


+1.000Sm+3     -2.000H+     +2.000H2O          = Sm(OH)2+
     log_k    -15.7         #07NEC/ALT
     delta_h   145.698      kJ/mol        #
     # Enthalpy of formation:             -1117.161     kJ/mol        


+1.000Sm+3     -3.000H+     +3.000H2O          = Sm(OH)3
     log_k    -26.2         #07NEC/ALT
     delta_h   228.395      kJ/mol        #
     # Enthalpy of formation:             -1320.294     kJ/mol        


+1.000Sm+3     +1.000CO3-2          = Sm(CO3)+
     log_k     7.8          #95SPA/BRU
     delta_h   163.392      kJ/mol        #
     # Enthalpy of formation:             -1203.037     kJ/mol        


+1.000Sm+3     +2.000CO3-2          = Sm(CO3)2-
     log_k     12.8         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Sm+3     +1.000SO4-2          = Sm(SO4)+
     log_k     3.5          #95SPA/BRU
     delta_h   16.575       kJ/mol        #
     # Enthalpy of formation:             -1583.964     kJ/mol        


+1.000Sm+3     +2.000SO4-2          = Sm(SO4)2-
     log_k     5.2          #95SPA/BRU
     delta_h   24.91        kJ/mol        #
     # Enthalpy of formation:             -2484.969     kJ/mol        


-1.000H+     +1.000Pd+2     +1.000H2O          = Pd(OH)+
     log_k    -1.86         #70NAB/KAL
     delta_h   11.9         kJ/mol        #
     # Enthalpy of formation:             -84.047       kJ/mol        


-2.000H+     +1.000Pd+2     +2.000H2O          = Pd(OH)2
     log_k    -3.79         #70NAB/KAL
     delta_h   15.293       kJ/mol        #
     # Enthalpy of formation:             -366.483      kJ/mol        


-3.000H+     +1.000Pd+2     +3.000H2O          = Pd(OH)3-
     log_k    -15.93        #70NAB/KAL
     delta_h   54.863       kJ/mol        #
     # Enthalpy of formation:             -612.744      kJ/mol        


-4.000H+     +1.000Pd+2     +4.000H2O          = Pd(OH)4-2
     log_k    -29.36        #70NAB/KAL
     delta_h   118.563      kJ/mol        #
     # Enthalpy of formation:             -834.874      kJ/mol        


+1.000Pd+2     +1.000SO4-2          = Pd(SO4)
     log_k     2.91         #87BRO/WAN
     delta_h   4.596        kJ/mol        #
     # Enthalpy of formation:             -714.86       kJ/mol        


+1.000Pd+2     +2.000SO4-2          = Pd(SO4)2-2
     log_k     4.17         #82HOG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pd+2     +1.000Cl-          = PdCl+
     log_k     5.1          #99LOT/OCH
     delta_h  -24.542       kJ/mol        #
     # Enthalpy of formation:             -1.739        kJ/mol        


+1.000Pd+2     +2.000Cl-          = PdCl2
     log_k     8.3          #99LOT/OCH
     delta_h  -47.297       kJ/mol        #
     # Enthalpy of formation:             -191.573      kJ/mol        


+1.000Pd+2     +3.000Cl-          = PdCl3-
     log_k     10.9         #99LOT/OCH
     delta_h  -77.344       kJ/mol        #
     # Enthalpy of formation:             -388.7        kJ/mol        


+1.000Pd+2     +4.000Cl-          = PdCl4-2
     log_k     11.7         #99LOT/OCH
     delta_h  -112.469      kJ/mol        #
     # Enthalpy of formation:             -590.906      kJ/mol        


+1.000Pd+2     +1.000Br-          = PdBr+
     log_k     5.77         #72ELD
     delta_h  -30.14        kJ/mol        #
     # Enthalpy of formation:              38.344       kJ/mol        


+1.000Pd+2     +1.000NH3          = Pd(NH3)+2
     log_k     9.6          #68RAS/JOR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pd+2     +2.000NH3          = Pd(NH3)2+2
     log_k     18.5         #68RAS/JOR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Pd+2     +1.000I-          = PdI+
     log_k     10.4         #89BAE/McK
     delta_h  -58.201       kJ/mol        #
     # Enthalpy of formation:              74.902       kJ/mol        


+1.000Pd+2     +2.000I-          = PdI2
     log_k     14.5         #97BOU
     delta_h  -83.42        kJ/mol        #
     # Enthalpy of formation:             -7.096        kJ/mol        


+1.000Pd+2     +3.000I-          = PdI3-
     log_k     18.6         #97BOU
     delta_h  -121.75       kJ/mol        #
     # Enthalpy of formation:             -102.207      kJ/mol        


+1.000Pd+2     +4.000I-          = PdI4-2
     log_k     24.64        #
     delta_h  -190.052      kJ/mol        #
     # Enthalpy of formation:             -227.288      kJ/mol        


-1.000H+     +1.000Am+3     +1.000H2O          = Am(OH)+2
     log_k    -7.2          #03GUI/FAN, 88STA/KIM, 94RUN/KIM, 83EDE/BUC, 83CAC/CHO, 92WIM/KLE
     delta_h   78.411       kJ/mol        #
     # Enthalpy of formation:             -824.119      kJ/mol        


-2.000H+     +1.000Am+3     +2.000H2O          = Am(OH)2+
     log_k    -15.1         #03GUI/FAN, 88STA/KIM, 94RUN/KIM, 83EDE/BUC, 83CAC/CHO, 92WIM/KLE
     delta_h   143.704      kJ/mol        #
     # Enthalpy of formation:             -1044.656     kJ/mol        


-3.000H+     +1.000Am+3     +3.000H2O          = Am(OH)3
     log_k    -26.2         #03GUI/FAN, 88STA/KIM, 94RUN/KIM, 83EDE/BUC, 83CAC/CHO, 92WIM/KLE
     delta_h   230.125      kJ/mol        #
     # Enthalpy of formation:             -1244.065     kJ/mol        


+1.000Am+3     +1.000CO3-2          = Am(CO3)+
     log_k     7.9          #recalculated from 03GUI/FAN
     delta_h   158.156      kJ/mol        #
     # Enthalpy of formation:             -1133.774     kJ/mol        


+1.000Am+3     +2.000CO3-2          = Am(CO3)2-
     log_k     12.6         #recalculated from 03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Am+3     +3.000CO3-2          = Am(CO3)3-3
     log_k     14.6         #Recalculated from 03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Am+3     +1.000F-          = AmF+2
     log_k     3.4          #03GUI/FAN
     delta_h   27.134       kJ/mol        #
     # Enthalpy of formation:             -924.916      kJ/mol        


+1.000Am+3     +2.000F-          = AmF2+
     log_k     5.8          #95SIL/BID
     delta_h   22.32        kJ/mol        #
     # Enthalpy of formation:             -1265.08      kJ/mol        


+1.000Am+3     +1.000Cl-          = AmCl+2
     log_k     0.24         #97KÖN/FAN
     delta_h   25.106       kJ/mol        #
     # Enthalpy of formation:             -758.674      kJ/mol        


+1.000Am+3     +2.000Cl-          = AmCl2+
     log_k    -0.74         #97KÖN/FAN
     delta_h   40.568       kJ/mol        #
     # Enthalpy of formation:             -910.292      kJ/mol        


+1.000Am+3     +1.000SO4-2          = Am(SO4)+
     log_k     3.3          #03GUI/FAN
     delta_h   15.493       kJ/mol        #
     # Enthalpy of formation:             -1510.547     kJ/mol        


+1.000Am+3     +2.000SO4-2          = Am(SO4)2-
     log_k     3.7          #03GUI/FAN
     delta_h   20.927       kJ/mol        #
     # Enthalpy of formation:             -2414.453     kJ/mol        


+1.000Am+3     +1.000NO3-          = Am(NO3)+2
     log_k     1.33         #95SIL/BID
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Am+3     +1.000H2(PO4)-          = Am(H2PO4)+2
     log_k     3            #95SIL/BID
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Am+3     -1.000e-          = Am+4
     log_k    -44.21        #
     delta_h   210.7        kJ/mol        #
     # Enthalpy of formation:             -406          kJ/mol        95SIL/BID


-4.000H+     +1.000Am+3     -3.000e-     +2.000H2O          = AmO2+2
     log_k    -85.35        #
     delta_h   537.6        kJ/mol        #95SIL/BID
     # Enthalpy of formation:             -650.76       kJ/mol        


-4.000H+     +1.000Am+3     -2.000e-     +2.000H2O          = AmO2+
     log_k    -58.37        #
     delta_h   384.1        kJ/mol        #95SIL/BID
     # Enthalpy of formation:             -804.26       kJ/mol        


-1.000H+     +1.000Ra+2     +1.000H2O          = Ra(OH)+
     log_k    -13.49        #
     delta_h   60.417       kJ/mol        #85LAN/RIE
     # Enthalpy of formation:             -753.438      kJ/mol        


-2.000H+     +1.000Ra+2     +2.000H2O          = Ra(OH)2
     log_k    -28.07        #
     delta_h   112.197      kJ/mol        #
     # Enthalpy of formation:             -987.488      kJ/mol        


+1.000Ra+2     +1.000CO3-2          = Ra(CO3)
     log_k     2.5          #99SCH
     delta_h   4.496        kJ/mol        #
     # Enthalpy of formation:             -1198.76      kJ/mol        


+1.000Ra+2     +1.000SO4-2          = Ra(SO4)
     log_k     2.76         #
     delta_h   5.481        kJ/mol        #
     # Enthalpy of formation:             -1431.884     kJ/mol        


+1.000Ra+2     +1.000Cl-          = RaCl+
     log_k    -0.1          #85LAN/RIE
     delta_h   2.479        kJ/mol        #
     # Enthalpy of formation:             -692.626      kJ/mol        


+1.000Ra+2     +1.000F-          = RaF+
     log_k     0.48         #87BRO/WAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000H+     +2.000e-     +1.000SeO4-2     -1.000H2O          = SeO3-2
     log_k     28.04        #05OLI/NOL
     delta_h  -189.49       kJ/mol        #
     # Enthalpy of formation:             -507.16       kJ/mol        05OLI/NOL


+1.000Ho+3     +1.000Cl-          = HoCl+2
     log_k     0.74         #Original data from 01LUO/BYR and 04LUO/BYR
     delta_h   22.013       kJ/mol        #
     # Enthalpy of formation:             -852.109      kJ/mol        


+1.000Ho+3     +1.000F-          = HoF+2
     log_k     4.33         #07LUO/BYR
     delta_h   25.761       kJ/mol        #
     # Enthalpy of formation:             -1016.631     kJ/mol        


+1.000Ho+3     +1.000CO3-2          = Ho(CO3)+
     log_k     8            #95SPA/BRU
     delta_h   168.562      kJ/mol        #
     # Enthalpy of formation:             -1213.71      kJ/mol        


+1.000Ho+3     +2.000CO3-2          = Ho(CO3)2-
     log_k     13.3         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000H+     +1.000Ho+3     +1.000CO3-2          = Ho(HCO3)+2
     log_k     12.5         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ho+3     +1.000SO4-2          = Ho(SO4)+
     log_k     3.4          #95SPA/BRU
     delta_h   15.387       kJ/mol        #
     # Enthalpy of formation:             -1600.995     kJ/mol        


+1.000Ho+3     +2.000SO4-2          = Ho(SO4)2-
     log_k     4.9          #95SPA/BRU
     delta_h   23.67        kJ/mol        #
     # Enthalpy of formation:             -2502.052     kJ/mol        


+1.000Ho+3     +1.000NO3-          = Ho(NO3)+2
     log_k     0.5          #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-2.000H+     +1.000Ho+3     +1.000H2(PO4)-          = Ho(PO4)
     log_k    -6.96         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-4.000H+     +1.000Ho+3     +2.000H2(PO4)-          = Ho(PO4)2-3
     log_k    -17.82        #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-1.000H+     +1.000Ho+3     +1.000H2(PO4)-          = Ho(HPO4)+
     log_k    -1.41         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-2.000H+     +1.000Ho+3     +2.000H2(PO4)-          = Ho(HPO4)2-
     log_k    -4.52         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Ho+3     +1.000H2(PO4)-          = Ho(H2PO4)+2
     log_k     2.3          #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


-6.000H+     -6.000e-     +1.000I-     +3.000H2O          = IO3-
     log_k    -111.56       #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -219.7        kJ/mol        92GRE/FUG


+2.000H+     +1.000Nb(OH)6-     -2.000H2O          = Nb(OH)4+
     log_k     6.64         #97PEI/NGU
     delta_h  -35.35        kJ/mol        #97PEI/NGU
     # Enthalpy of formation:             -1389.355     kJ/mol        


+1.000H+     +1.000Nb(OH)6-     -1.000H2O          = Nb(OH)5
     log_k     5.08         #97PEI/NGU
     delta_h  -13.39        kJ/mol        #97PEI/NGU
     # Enthalpy of formation:             -1653.225     kJ/mol        


-1.000H+     +1.000Nb(OH)6-     +1.000H2O          = Nb(OH)7-2
     log_k    -8.88         #97PEI/NGU
     delta_h   10.17        kJ/mol        #97PEI/NGU
     # Enthalpy of formation:             -2201.325     kJ/mol        


+2.000H+     +2.000e-     +1.000SO4-2     -1.000H2O          = SO3-2
     log_k    -3.62         #
     delta_h  -7.55         kJ/mol        #
     # Enthalpy of formation:             -631.06       kJ/mol        85GOL/PAR


-2.000H+     +1.000H2(PO4)-          = PO4-3
     log_k    -19.56        #89COX/WAG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -1284.4       kJ/mol        89COX/WAG


+1.000Th+4     +8.000H2O     -8.000H+     +4.000Ca+2          = Ca4Th(OH)8+4
     log_k    -63.1         #08ALT/NEC
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +2.000NO3-          = Th(NO3)2+2
     log_k     2.3          #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +2.000H2(PO4)-     +1.000H+          = Th(H3PO4)(H2PO4)+3
     log_k     9.7          #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +1.000H2(PO4)-          = Th(H2PO4)+3
     log_k     5.59         #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +2.000H2(PO4)-          = Th(H2PO4)2+2
     log_k     10.48        #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+1.000Th+4     +1.000H2(PO4)-     +1.000H+          = Th(H3PO4)+4
     log_k     4.03         #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+2.000Th+4     +3.000H2O     -3.000H+          = Th2(OH)3+5
     log_k    -6.8          #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


+6.000Th+4     +14.000H2O     -14.000H+          = Th6(OH)14+10
     log_k    -36.8         #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        




PHASES

Ca(HPO4)(s)
Ca(HPO4) = +1.000Ca+2     -1.000H+     +1.000H2(PO4)-     
     log_k     0.3          #84NAN
     delta_h  -24.098       kJ/mol        #
     # Enthalpy of formation:             -1821.502     kJ/mol        


Ca(NO3)2(s)
Ca(NO3)2 = +1.000Ca+2     +2.000NO3-     
     log_k     5.89         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ca2Fe2O5(s)
Ca2Fe2O5 = +2.000Ca+2     +2.000Fe+3     -10.000H+     +5.000H2O     
     log_k     56.76        #
     delta_h  -473.87       kJ/mol        #
     # Enthalpy of formation:             -2138.3       kJ/mol        


CaF2:6H2O(s)
CaF2:6H2O = +1.000Ca+2     +2.000F-     +6.000H2O     
     log_k    -5.48         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


CaFe2O4(s)
CaFe2O4 = +1.000Ca+2     +2.000Fe+3     -8.000H+     +4.000H2O     
     log_k     21.24        #79ROB
     delta_h  -263.98       kJ/mol        #
     # Enthalpy of formation:             -1520.34      kJ/mol        


CaI2(s)
CaI2 = +1.000Ca+2     +2.000I-     
     log_k     22.5         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Cd3(PO4)2(s)
Cd3(PO4)2 = +3.000Cd+2     -4.000H+     +2.000H2(PO4)-     
     log_k     8.97         #
     delta_h  -206.96       kJ/mol        #
     # Enthalpy of formation:             -2626         kJ/mol        01BEN/JEM


CdO(s)
CdO = +1.000Cd+2     -2.000H+     +1.000H2O     
     log_k     15.1         #
     delta_h  -103.4        kJ/mol        #
     # Enthalpy of formation:             -258.35       kJ/mol        89COX/WAG


Gypsum
CaSO4:2H2O = +1.000Ca+2     +1.000SO4-2     +2.000H2O     
     log_k    -4.61         #
     delta_h  -1.05         kJ/mol        #
     # Enthalpy of formation:             -2022.95      kJ/mol        87GAR/PAR


Cd(SO4)(cr)
Cd(SO4) = +1.000Cd+2     +1.000SO4-2     
     log_k    -0.16         #
     delta_h  -51.98        kJ/mol        #
     # Enthalpy of formation:             -933.28       kJ/mol        82WAG/EVA


Fluorite
CaF2 = +1.000Ca+2     +2.000F-     
     log_k    -10.6         #
     delta_h   19.623       kJ/mol        #
     # Enthalpy of formation:             -1233.323     kJ/mol        


Chloroapatite
Ca5Cl(PO4)3  = +5.000Ca+2     -6.000H+     +1.000Cl-     +3.000H2(PO4)-     
     log_k     5.21         #68VAL/KOG
     delta_h  -132.541      kJ/mol        #
     # Enthalpy of formation:             -6657.339     kJ/mol        


Hydrophilite
CaCl2 = +1.000Ca+2     +2.000Cl-     
     log_k     11.77        #
     delta_h  -81.36        kJ/mol        #
     # Enthalpy of formation:             -795.8        kJ/mol        98CHA


CaMg3(CO3)4(s)
CaMg3(CO3)4 = +1.000Ca+2     +3.000Mg+2     +4.000CO3-2     
     log_k    -30.81        # 
     delta_h  -112.34       kJ/mol        #
     # Enthalpy of formation:             -4532.58      kJ/mol        73HEM/ROB


Anapaite
Ca2Fe(PO4)2:4H2O = +2.000Ca+2     +1.000Fe+2     -4.000H+     +2.000H2(PO4)-     +4.000H2O     
     log_k     5.02         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ettringite
Ca6Al2(SO4)3(OH)12:26H2O = +6.000Ca+2     +2.000Al+3     -12.000H+     +3.000SO4-2     +38.000H2O     
     log_k     56.97        #07BLA/BOU
     delta_h  -379.83       kJ/mol        #
     # Enthalpy of formation:             -17544.53     kJ/mol        07BLA/BOU


Hemicarboaluminate
Ca6O6:Al4O6:CaCO3:Ca(OH)2:21H2O = +8.000Ca+2     +4.000Al+3     -26.000H+     +1.000CO3-2     +35.000H2O     
     log_k     173.2        #07MAT/LOT
     delta_h  -1189.08      kJ/mol        #
     # Enthalpy of formation:             -15987.8      kJ/mol        


Jennite
Ca9Si6O16(OH)10:6(H2O) = +9.000Ca+2     -18.000H+     +6.000H4(SiO4)     +8.000H2O     
     log_k     147.33       #07BLA/BOU
     delta_h  -751.765      kJ/mol        #
     # Enthalpy of formation:             -15189.04     kJ/mol        07BLA/BOU


Afwillite
Ca3Si2O4(OH)6 = +3.000Ca+2     -6.000H+     +2.000H4(SiO4)     +2.000H2O     
     log_k     49.42        #07BLA/BOU
     delta_h  -269.228      kJ/mol        #
     # Enthalpy of formation:             -4853.82      kJ/mol        07BLA/BOU


C4AH13
Ca4Al2(OH)14:6H2O = +4.000Ca+2     +2.000Al+3     -14.000H+     +20.000H2O     
     log_k     103.65       #07BLA/BOU
     delta_h  -647.4        kJ/mol        #
     # Enthalpy of formation:             -8318         kJ/mol        76HOU/STE


C3ASH4
Ca3Al2(SiO4)(OH)8 = +3.000Ca+2     +2.000Al+3     -12.000H+     +1.000H4(SiO4)     +8.000H2O     
     log_k     71.16        #07BLA/BOU
     delta_h  -545.767      kJ/mol        #
     # Enthalpy of formation:             -5907.867     kJ/mol        


Stratlingite
Ca2Al2SiO3(OH)8:4H2O = +2.000Ca+2     +2.000Al+3     -10.000H+     +1.000H4(SiO4)     +11.000H2O     
     log_k     49.66        #07BLA/BOU
     delta_h  -397.95       kJ/mol        #
     # Enthalpy of formation:             -6370.175     kJ/mol        


Hillebrandite
Ca2SiO3(OH)2:0.17H2O = +2.000Ca+2     -4.000H+     +1.000H4(SiO4)     +1.170H2O     
     log_k     36.85        #07BLA/BOU
     delta_h  -219.135      kJ/mol        #
     # Enthalpy of formation:             -2662.48      kJ/mol        56NEW


Foshagite
Ca4Si3O9(OH)2:0.5H2O = +4.000Ca+2     -8.000H+     +3.000H4(SiO4)     -0.500H2O     
     log_k     65.96        #07BLA/BOU
     delta_h  -380.238      kJ/mol        #
     # Enthalpy of formation:             -6032.43      kJ/mol        56NEW


Xonotlite
Ca6Si6O17(OH)2 = +6.000Ca+2     -12.000H+     +6.000H4(SiO4)     -5.000H2O     
     log_k     91.34        #07BLA/BOU
     delta_h  -573.865      kJ/mol        #
     # Enthalpy of formation:             -10022.15     kJ/mol        56NEW


Gyrolite
Ca2Si3O7.5(OH):2H2O = +2.000Ca+2     -4.000H+     +3.000H4(SiO4)     -1.500H2O     
     log_k     22.34        #07BLA/BOU
     delta_h  -122.848      kJ/mol        #
     # Enthalpy of formation:             -4917.99      kJ/mol        07BLA/BOU


Okenite
CaSi2O5:2H2O = +1.000Ca+2     -2.000H+     +2.000H4(SiO4)     -1.000H2O     
     log_k     9.18         #
     delta_h  -44.388       kJ/mol        #
     # Enthalpy of formation:             -3135.17      kJ/mol        07BLA/BOU


Ca(Ox):H2O(s)
Ca(Ox):H2O = +1.000Ca+2     +1.000Ox-2     +1.000H2O     
     log_k    -8.73         #05HUM/AND
     delta_h   21.5         kJ/mol        #
     # Enthalpy of formation:             -1680.99      kJ/mol        


Ca(Ox):2H2O(s)
Ca(Ox):2H2O = +1.000Ca+2     +1.000Ox-2     +2.000H2O     
     log_k    -8.3          #05HUM/AND
     delta_h   25.2         kJ/mol        #
     # Enthalpy of formation:             -1970.52      kJ/mol        


Ca(Ox):3H2O(s)
Ca(Ox):3H2O = +1.000Ca+2     +1.000Ox-2     +3.000H2O     
     log_k    -8.19         #05HUM/AND
     delta_h   29.7         kJ/mol        #
     # Enthalpy of formation:             -2260.85      kJ/mol        


Ca3(Cit)2:4H2O(s)
Ca3(Cit)2:4H2O = +3.000Ca+2     +2.000Cit-3     +4.000H2O     
     log_k    -17.9         #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ca(HIsa)2(cr)
Ca(HIsa)2 = +1.000Ca+2     +2.000HIsa-     
     log_k    -6.4          #05HUM/AND
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ca(HGlu)2(s)
Ca(HGlu)2 = +1.000Ca+2     +2.000HGlu-     
     log_k    -4.19         #99VAN/GLA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Bassanite
CaSO4:0.5H2O = +1.000Ca+2     +1.000SO4-2     +0.500H2O     
     log_k    -3.92         #06BLA/PIA
     delta_h  -17.358       kJ/mol        #
     # Enthalpy of formation:             -1577.897     kJ/mol        


Ca(s)
Ca = +1.000Ca+2     +2.000e-     
     log_k     96.85        #
     delta_h  -543          kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        89COX/WAG


CaCO3:H2O(s)
CaCO3:H2O = +1.000Ca+2     +1.000CO3-2     +1.000H2O     
     log_k    -7.6          #73HUL/TUR
     delta_h  -5.77         kJ/mol        #
     # Enthalpy of formation:             -1498.29      kJ/mol        73HUL/TUR


Anorthite
CaAl2Si2O8 = +1.000Ca+2     +2.000Al+3     -8.000H+     +2.000H4(SiO4)     
     log_k     25.31        #
     delta_h  -314.358      kJ/mol        #
     # Enthalpy of formation:             -4227.83      kJ/mol        00ARN/STE


Antarcticite
CaCl2:6H2O = +1.000Ca+2     +2.000Cl-     +6.000H2O     
     log_k     3.94         #
     delta_h   13.99        kJ/mol        #
     # Enthalpy of formation:             -2606.13      kJ/mol        87GAR/PAR


CaCl2:4H2O(cr)
CaCl2:4H2O = +1.000Ca+2     +2.000Cl-     +4.000H2O     
     log_k     5.35         #
     delta_h  -11.31        kJ/mol        #
     # Enthalpy of formation:             -2009.17      kJ/mol        87GAR/PAR


Ca4Cl2(OH)6:13H2O(s)
Ca4Cl2(OH)6:13H2O = +4.000Ca+2     -6.000H+     +2.000Cl-     +19.000H2O     
     log_k     68.73        #84HAR/MOL
     delta_h  -271.93       kJ/mol        #
     # Enthalpy of formation:             -7665         kJ/mol        82WAG/EVA


Ca2Cl2(OH)2:H2O(s)
Ca2Cl2(OH)2:H2O = +2.000Ca+2     -2.000H+     +2.000Cl-     +3.000H2O     
     log_k     26.53        #84HAR/MOL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


CaCl2:2H2O(cr)
CaCl2:2H2O = +1.000Ca+2     +2.000Cl-     +2.000H2O     
     log_k     7.95         #
     delta_h  -44.79        kJ/mol        #
     # Enthalpy of formation:             -1404.03      kJ/mol        87GAR/PAR


CaCl2:H2O(s)
CaCl2:H2O = +1.000Ca+2     +2.000Cl-     +1.000H2O     
     log_k     7.85         #
     delta_h  -52.16        kJ/mol        #
     # Enthalpy of formation:             -1110.83      kJ/mol        87GAR/PAR


Gaylussite
CaNa2(CO3)2:5H2O = +1.000Ca+2     +2.000Na+     +2.000CO3-2     +5.000H2O     
     log_k    -9.43         #99KON/KON
     delta_h   31.099       kJ/mol        #
     # Enthalpy of formation:             -3834.389     kJ/mol        


Ca4H(PO4)3:2.5H2O(s)
Ca4H(PO4)3:2.5H2O = +4.000Ca+2     -5.000H+     +3.000H2(PO4)-     +2.500H2O     
     log_k     11.81        #84NAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


CaCrO4(s)
CaCrO4 = +1.000Ca+2     +1.000CrO4-2     
     log_k    -3.15         #03DEA
     delta_h  -22.814       kJ/mol        #
     # Enthalpy of formation:             -1399.186     kJ/mol        


Ca6(Al(OH)6)2(CrO4)3:26H2O(s)
Ca6(Al(OH)6)2(CrO4)3:26H2O = +6.000Ca+2     +2.000Al+3     -12.000H+     +3.000CrO4-2     +38.000H2O     
     log_k     60.28        #00PER/PAL
     delta_h  -509.59       kJ/mol        #00PER/PAL
     # Enthalpy of formation:             -17323.75     kJ/mol        


Ca4Al2O6(CrO4):15H2O(s)
Ca4Al2O6(CrO4):15H2O = +4.000Ca+2     +2.000Al+3     -12.000H+     +1.000CrO4-2     +21.000H2O     
     log_k     71.36        #01PER/PAL
     delta_h  -545.98       kJ/mol        #01PER/PAL
     # Enthalpy of formation:             -9584.25      kJ/mol        


Monosulfoaluminate
Ca4Al2(SO4)(OH)12:6H2O = +4.000Ca+2     +2.000Al+3     -12.000H+     +1.000SO4-2     +18.000H2O     
     log_k     72.73        #07BLA/BOU
     delta_h  -522.63       kJ/mol        #
     # Enthalpy of formation:             -8780.45      kJ/mol        82WAG/EVA


Monocarboaluminate
(CaO)3Al2O3:CaCO3:10.68H2O = +4.000Ca+2     +2.000Al+3     -12.000H+     +1.000CO3-2     +16.680H2O     
     log_k     70.3         #94DAM/GLA
     delta_h  -515.924      kJ/mol        #
     # Enthalpy of formation:             -8175.75      kJ/mol        07BLA/BOU


Friedel-salt
Ca4Al2(OH)12Cl2:4H2O  = +4.000Ca+2     +2.000Al+3     -12.000H+     +2.000Cl-     +16.000H2O     
     log_k     74.93        #07BLA/BOU
     delta_h  -486.2        kJ/mol        #
     # Enthalpy of formation:             -7670.04      kJ/mol        76HOU/STE


Hydrogarnet
Ca3Al2(OH)12 = +3.000Ca+2     +2.000Al+3     -12.000H+     +12.000H2O     
     log_k     80.32        #07BLA/BOU
     delta_h  -584.26       kJ/mol        #
     # Enthalpy of formation:             -5551.5       kJ/mol        99SCH/NAV


Chabazite
CaAl2Si4O12:6H2O = +1.000Ca+2     +2.000Al+3     -8.000H+     +4.000H4(SiO4)     +2.000H2O     
     log_k     13.67        #
     delta_h  -214.638      kJ/mol        #
     # Enthalpy of formation:             -7821.599     kJ/mol        07VIE


Gismondine
Ca2Al4Si4O16:9H2O = +2.000Ca+2     +4.000Al+3     -16.000H+     +4.000H4(SiO4)     +9.000H2O     
     log_k     37.44        #
     delta_h  -477.477      kJ/mol        #
     # Enthalpy of formation:             -11179.37     kJ/mol        07VIE


C4FH13
Ca4Fe2(OH)14:6H2O = +4.000Ca+2     +2.000Fe+3     -14.000H+     +20.000H2O     
     log_k     93.71        #
     delta_h  -568.99       kJ/mol        #
     # Enthalpy of formation:             -7417.61      kJ/mol        07BLA/BOU


C3FH6
Ca3Fe2(OH)12 = +3.000Ca+2     +2.000Fe+3     -12.000H+     +12.000H2O     
     log_k     70.38        #
     delta_h  -505.85       kJ/mol        #
     # Enthalpy of formation:             -4651.11      kJ/mol        07BLA/BOU


Ettringite-Fe
Ca6Fe2(SO4)3(OH)12:26H2O = +6.000Ca+2     +2.000Fe+3     -12.000H+     +3.000SO4-2     +38.000H2O     
     log_k     54.53        #07BLA/BOU
     delta_h  -344.219      kJ/mol        #
     # Enthalpy of formation:             -16601.341    kJ/mol        


Monosulfate-Fe
Ca4Fe2(SO4)(OH)12:6H2O = +4.000Ca+2     +2.000Fe+3     -12.000H+     +1.000SO4-2     +18.000H2O     
     log_k     65.6         #07BLA/BOU
     delta_h  -460.253      kJ/mol        #
     # Enthalpy of formation:             -7864.027     kJ/mol        


Tobermorite-14A
Ca5Si6O16.5(OH):10H2O = +5.000Ca+2     -10.000H+     +6.000H4(SiO4)     +3.500H2O     
     log_k     62.94        #07BLA/BOU
     delta_h  -307.42       kJ/mol        #
     # Enthalpy of formation:             -12175.15     kJ/mol        07BLA/BOU


Tobermorite-11A
Ca5Si6O16.5(OH):5H2O = +5.000Ca+2     -10.000H+     +6.000H4(SiO4)     -1.500H2O     
     log_k     65.58        #07BLA/BOU
     delta_h  -372.5        kJ/mol        #
     # Enthalpy of formation:             -10680.92     kJ/mol        00ZUE/FEH


Epsonite
Mg(SO4):7H2O  = +1.000Mg+2     +1.000SO4-2     +7.000H2O     
     log_k    -1.88         #84HAR/MOL
     delta_h   10.99        kJ/mol        #
     # Enthalpy of formation:             -3388.14      kJ/mol        


Mg(NO3)2(s)
Mg(NO3)2 = +1.000Mg+2     +2.000NO3-     
     log_k     15.5         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Mg(NO3)2:6H2O(s)
Mg(NO3)2:6H2O = +1.000Mg+2     +2.000NO3-     +6.000H2O     
     log_k     2.58         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


MgBr2(s)
MgBr2 = +1.000Mg+2     +2.000Br-     
     log_k     27.8         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


MgBr2:6H2O(s)
MgBr2:6H2O = +1.000Mg+2     +2.000Br-     +6.000H2O     
     log_k     5.22         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


MgCl2(s)
MgCl2 = +1.000Mg+2     +2.000Cl-     
     log_k     22.03        #
     delta_h  -159.54       kJ/mol        #
     # Enthalpy of formation:             -641.62       kJ/mol        98CHA


MgCl2:2H2O(s)
MgCl2:2H2O = +1.000Mg+2     +2.000Cl-     +2.000H2O     
     log_k     12.9         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


MgCl2:4H2O(s)
MgCl2:4H2O = +1.000Mg+2     +2.000Cl-     +4.000H2O     
     log_k     7.44         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Bischofite
MgCl2:6H2O = +1.000Mg+2     +2.000Cl-     +6.000H2O     
     log_k     4.46         #84HAR/MOL
     delta_h  -8.71         kJ/mol        #
     # Enthalpy of formation:             -2507.43      kJ/mol        


MgCl2:H2O(s)
MgCl2:H2O = +1.000Mg+2     +2.000Cl-     +1.000H2O     
     log_k     16.22        #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


MgI2(s)
MgI2 = +1.000Mg+2     +2.000I-     
     log_k     35           #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Mg(SO4)(s)
Mg(SO4) = +1.000Mg+2     +1.000SO4-2     
     log_k     9.1          #
     delta_h  -114.55       kJ/mol        #
     # Enthalpy of formation:             -1261.79      kJ/mol        98CHA


Hexahydrite
Mg(SO4):6H2O = +1.000Mg+2     +1.000SO4-2     +6.000H2O     
     log_k    -1.64         #84HAR/MOL
     delta_h  -4.625        kJ/mol        #
     # Enthalpy of formation:             -3086.695     kJ/mol        


Mg(SO4):H2O(s)
Mg(SO4):H2O = +1.000Mg+2     +1.000SO4-2     +1.000H2O     
     log_k    -0.12         #84HAR/MOL
     delta_h  -51.464       kJ/mol        #
     # Enthalpy of formation:             -1610.706     kJ/mol        


Hydrotalcite
Mg4Al2(OH)14:3H2O = +4.000Mg+2     +2.000Al+3     -14.000H+     +17.000H2O     
     log_k     73.74        #91ATK/GLA
     delta_h  -536.41       kJ/mol        #
     # Enthalpy of formation:             -7267.5       kJ/mol        06ALL/NAV


Magnesite(nat)
MgCO3 = +1.000Mg+2     +1.000CO3-2     
     log_k    -8.91         #
     delta_h  -24.29        kJ/mol        #
     # Enthalpy of formation:             -1117.94      kJ/mol        99KON/KON


Mg(cr)
Mg = +1.000Mg+2     +2.000e-     
     log_k     79.78        #
     delta_h  -467          kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        89COX/WAG


Leonhardtite
MgSO4:4H2O = +1.000Mg+2     +1.000SO4-2     +4.000H2O     
     log_k    -0.89         #80HAR/WEA
     delta_h  -24.03        kJ/mol        #
     # Enthalpy of formation:             -2495.63      kJ/mol        74NAU/RYZ


Mg-oxychlorur
Mg2Cl(OH)3:4H2O = +2.000Mg+2     -3.000H+     +1.000Cl-     +7.000H2O     
     log_k     26.03        #84HAR/MOL
     delta_h  -154.69       kJ/mol        #
     # Enthalpy of formation:             -2947.2       kJ/mol        82WAG/EVA


Pentahydrite
MgSO4:5H2O = +1.000Mg+2     +1.000SO4-2     +5.000H2O     
     log_k    -1.28         #80HAR/WEA
     delta_h  -14.187       kJ/mol        #
     # Enthalpy of formation:             -2791.303     kJ/mol        


Tachyhydrite
Mg2CaCl6:12H2O = +1.000Ca+2     +2.000Mg+2     +6.000Cl-     +12.000H2O     
     log_k     17.38        #84HAR/MOL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


MgCrO4(s)
MgCrO4 = +1.000Mg+2     +1.000CrO4-2     
     log_k    -86.99        #
     delta_h   437.6        kJ/mol        #
     # Enthalpy of formation:             -1783.6       kJ/mol        95ROB/HEM


Chrysotile
Mg3Si2O5(OH)4 = +3.000Mg+2     -6.000H+     +2.000H4(SiO4)     +1.000H2O     
     log_k     33.17        #
     delta_h  -249.218      kJ/mol        #
     # Enthalpy of formation:             -4360         kJ/mol        95ROB/HEM


Hydrotalcite-CO3
Mg4Al2(OH)12CO3:2H2O = +4.000Mg+2     +2.000Al+3     -12.000H+     +1.000CO3-2     +14.000H2O     
     log_k     50.86        #03JOH/GLA
     delta_h  -498.47       kJ/mol        #
     # Enthalpy of formation:             -7123.18      kJ/mol        06ALL/NAV


Clinochlore
Mg5Al2Si3O10(OH)8 = +5.000Mg+2     +2.000Al+3     -16.000H+     +3.000H4(SiO4)     +6.000H2O     
     log_k     60.7         #
     delta_h  -593.918      kJ/mol        #
     # Enthalpy of formation:             -8916.445     kJ/mol        07VIE


Amesite
Mg4Al4Si2O10(OH)8 = +4.000Mg+2     +4.000Al+3     -20.000H+     +2.000H4(SiO4)     +10.000H2O     
     log_k     63.59        #
     delta_h  -738.751      kJ/mol        #
     # Enthalpy of formation:             -9063.537     kJ/mol        07VIE


Sudoite
Mg2Al4Si3O10(OH)8 = +2.000Mg+2     +4.000Al+3     -16.000H+     +3.000H4(SiO4)     +6.000H2O     
     log_k     37.24        #
     delta_h  -530.404      kJ/mol        #
     # Enthalpy of formation:             -8655.759     kJ/mol        07VIE


Truscottite
Ca7Si12O29(OH)4:H2O = +7.000Ca+2     -14.000H+     +12.000H4(SiO4)     -14.000H2O     
     log_k     77.08        #
     delta_h  -479.091      kJ/mol        #
     # Enthalpy of formation:             -16854.62     kJ/mol        07BLA/BOU


C2SH(alfa)
Ca2(HSiO4)(OH) = +2.000Ca+2     -4.000H+     +1.000H4(SiO4)     +1.000H2O     
     log_k     35.54        #
     delta_h  -198.104      kJ/mol        #
     # Enthalpy of formation:             -2634.92      kJ/mol        07BLA/BOU


Jaffeite
Ca6(Si2O7)(OH)6 = +6.000Ca+2     -12.000H+     +2.000H4(SiO4)     +5.000H2O     
     log_k     114.06       #
     delta_h  -636.768      kJ/mol        #
     # Enthalpy of formation:             -6972.77      kJ/mol        07BLA/BOU


Mg-Montmorillonite-Ca
Ca0.17Mg0.33Al1.68Si3.99O10(OH)2 = +0.170Ca+2     +0.330Mg+2     +1.680Al+3     -6.040H+     +3.990H4(SiO4)     -3.960H2O     
     log_k     5.07         #
     delta_h  -160.38       kJ/mol        #
     # Enthalpy of formation:             -5688.83      kJ/mol        07VIE


Mg-Montmorillonite-Mg
Mg0.17Mg0.33Al1.68Si3.99O10(OH)2 = +0.500Mg+2     +1.680Al+3     -6.040H+     +3.990H4(SiO4)     -3.960H2O     
     log_k     4.48         #
     delta_h  -160.97       kJ/mol        #
     # Enthalpy of formation:             -5675.32      kJ/mol        07VIE


Beidellite-Ca
Ca0.17Al2.34Si3.66O10(OH)2 = +0.170Ca+2     +2.340Al+3     -7.360H+     +3.660H4(SiO4)     -2.640H2O     
     log_k     4.42         #
     delta_h  -200.226      kJ/mol        #
     # Enthalpy of formation:             -5745.32      kJ/mol        07VIE


Beidellite-Mg
Mg0.17Al2.34Si3.66O10(OH)2 = +0.170Mg+2     +2.340Al+3     -7.360H+     +3.660H4(SiO4)     -2.640H2O     
     log_k    -0.17         #
     delta_h  -200.166      kJ/mol        #
     # Enthalpy of formation:             -5732.46      kJ/mol        07VIE


Fe-Montmorillonite-Ca
Ca0.17Mg0.33Fe0.67Al1.01Si3.99O10(OH)2 = +0.170Ca+2     +0.330Mg+2     +0.670Fe+3     +1.010Al+3     -6.040H+     +3.990H4(SiO4)     -3.960H2O     
     log_k     3.69         #
     delta_h  -149.802      kJ/mol        #
     # Enthalpy of formation:             -5371.51      kJ/mol        07VIE


Fe-Montmorillonite-Mg
Mg0.17Mg0.33Fe0.67Al1.01Si3.99O10(OH)2 = +0.500Mg+2     +0.670Fe+3     +1.010Al+3     -6.040H+     +3.990H4(SiO4)     -3.960H2O     
     log_k     3.01         #
     delta_h  -149.892      kJ/mol        #
     # Enthalpy of formation:             -5358.5       kJ/mol        07VIE


Beidellite-FeCa
Ca0.17Fe0.66Al1.68Si3.66O10(OH)2 = +0.170Ca+2     +0.660Fe+3     +1.680Al+3     -7.360H+     +3.660H4(SiO4)     -2.640H2O     
     log_k     3.09         #
     delta_h  -190.202      kJ/mol        #
     # Enthalpy of formation:             -5432.34      kJ/mol        07VIE


Beidellite-FeMg
Mg0.17Fe0.66Al1.68Si3.66O10(OH)2 = +0.170Mg+2     +0.660Fe+3     +1.680Al+3     -7.360H+     +3.660H4(SiO4)     -2.640H2O     
     log_k     2.39         #
     delta_h  -190.142      kJ/mol        #
     # Enthalpy of formation:             -5419.48      kJ/mol        07VIE


Fe-Saponite-Ca
Ca0.17Fe3Al0.34Si3.66O10(OH)2 = +0.170Ca+2     +3.000Fe+2     +0.340Al+3     -7.360H+     +3.660H4(SiO4)     -2.640H2O     
     log_k     22.43        #
     delta_h  -222.166      kJ/mol        #
     # Enthalpy of formation:             -4916.58      kJ/mol        07VIE


Fe-Saponite-Mg
Mg0.17Fe3Al0.34Si3.66O10(OH)2 = +0.170Mg+2     +3.000Fe+2     +0.340Al+3     -7.360H+     +3.660H4(SiO4)     -2.640H2O     
     log_k     21.73        #
     delta_h  -222.096      kJ/mol        #
     # Enthalpy of formation:             -4903.73      kJ/mol        07VIE


Saponite-Ca
Ca0.17Mg3Al0.34Si3.66O10(OH)2 = +0.170Ca+2     +3.000Mg+2     +0.340Al+3     -7.360H+     +3.660H4(SiO4)     -2.640H2O     
     log_k     30.23        #
     delta_h  -273.696      kJ/mol        #
     # Enthalpy of formation:             -5996.05      kJ/mol        07VIE


Saponite-Mg
Mg3.17Al0.34Si3.66O10(OH)2 = +3.170Mg+2     +0.340Al+3     -7.360H+     +3.660H4(SiO4)     -2.640H2O     
     log_k     29.53        #
     delta_h  -273.636      kJ/mol        #
     # Enthalpy of formation:             -5983.19      kJ/mol        07VIE


Vermiculite-Ca
Ca0.43Mg3Si3.14Al0.86O10(OH)2 = +0.430Ca+2     +3.000Mg+2     +0.860Al+3     -9.440H+     +3.140H4(SiO4)     -0.560H2O     
     log_k     40.68        #
     delta_h  -378.219      kJ/mol        #
     # Enthalpy of formation:             -6147.38      kJ/mol        07VIE


Vermiculite-Mg
Mg0.43Mg3Si3.14Al0.86O10(OH)2 = +3.430Mg+2     +0.860Al+3     -9.440H+     +3.140H4(SiO4)     -0.560H2O     
     log_k     38.8         #
     delta_h  -377.469      kJ/mol        #
     # Enthalpy of formation:             -6115.45      kJ/mol        07VIE


Beidellite-Ca(hydrated)
Ca0.17Al2.34Si3.66O10(OH)2:5H2O = +0.170Ca+2     +2.340Al+3     -7.360H+     +3.660H4(SiO4)     +2.360H2O     
     log_k     6.95         #
     delta_h  -198.947      kJ/mol        #
     # Enthalpy of formation:             -7175.749     kJ/mol        


Beidellite-Mg(hydrated)
Mg0.17Al2.34Si3.66O10(OH)2:5H2O = +0.170Mg+2     +2.340Al+3     -7.360H+     +3.660H4(SiO4)     +2.360H2O     
     log_k     6.38         #
     delta_h  -199.611      kJ/mol        #
     # Enthalpy of formation:             -7162.165     kJ/mol        


Mg-Montmorillonite-Ca(hydrated)
Ca0.17Mg0.33Al1.68Si3.99O10(OH)2:5H2O = +0.170Ca+2     +0.330Mg+2     +1.680Al+3     -6.040H+     +3.990H4(SiO4)     +1.040H2O     
     log_k     6.59         #
     delta_h  -153.339      kJ/mol        #
     # Enthalpy of formation:             -7125.022     kJ/mol        


Mg-Montmorillonite-Mg(hydrated)
Mg0.17Mg0.33Al1.68Si3.99O10(OH)2:5H2O = +0.500Mg+2     +1.680Al+3     -6.040H+     +3.990H4(SiO4)     +1.040H2O     
     log_k     6.04         #
     delta_h  -154.162      kJ/mol        #
     # Enthalpy of formation:             -7111.278     kJ/mol        


Fe-Montmorillonite-Ca(hydrated)
Ca0.17Mg0.33Fe0.67Al1.01Si3.99O10(OH)2:5H2O = +0.170Ca+2     +0.330Mg+2     +0.670Fe+3     +1.010Al+3     -6.040H+     +3.990H4(SiO4)     +1.040H2O     
     log_k     0.73         #
     delta_h  -117.207      kJ/mol        #
     # Enthalpy of formation:             -6833.255     kJ/mol        


Fe-Montmorillonite-Mg(hydrated)
Mg0.17Mg0.33Fe0.67Al1.01Si3.99O10(OH)2:5H2O = +0.500Mg+2     +0.670Fe+3     +1.010Al+3     -6.040H+     +3.990H4(SiO4)     +1.040H2O     
     log_k     0.18         #
     delta_h  -118.031      kJ/mol        #
     # Enthalpy of formation:             -6819.512     kJ/mol        


Beidellite-FeCa(hydrated)
Ca0.17Fe0.66Al1.68Si3.66O10(OH)2:5H2O = +0.170Ca+2     +0.660Fe+3     +1.680Al+3     -7.360H+     +3.660H4(SiO4)     +2.360H2O     
     log_k     1.17         #
     delta_h  -163.546      kJ/mol        #
     # Enthalpy of formation:             -6888.146     kJ/mol        


Beidellite-FeMg(hydrated)
Mg0.17Fe0.66Al1.68Si3.66O10(OH)2:5H2O = +0.170Mg+2     +0.660Fe+3     +1.680Al+3     -7.360H+     +3.660H4(SiO4)     +2.360H2O     
     log_k     0.59         #
     delta_h  -164.2        kJ/mol        #
     # Enthalpy of formation:             -6874.572     kJ/mol        


Fe-Saponite-Ca(hydrated)
Ca0.17Fe3Al0.34Si3.66O10(OH)2:5H2O = +0.170Ca+2     +3.000Fe+2     +0.340Al+3     -7.360H+     +3.660H4(SiO4)     +2.360H2O     
     log_k     18.4         #
     delta_h  -183.462      kJ/mol        #
     # Enthalpy of formation:             -6384.434     kJ/mol        


Fe-Saponite-Mg(hydrated)
Mg0.17Fe3Al0.34Si3.66O10(OH)2:5H2O = +0.170Mg+2     +3.000Fe+2     +0.340Al+3     -7.360H+     +3.660H4(SiO4)     +2.360H2O     
     log_k     17.93        #
     delta_h  -184.715      kJ/mol        #
     # Enthalpy of formation:             -6370.26      kJ/mol        


Saponite-Ca(hydrated)
Ca0.17Mg3Al0.34Si3.66O10(OH)2:5H2O = +0.170Ca+2     +3.000Mg+2     +0.340Al+3     -7.360H+     +3.660H4(SiO4)     +2.360H2O     
     log_k     34.38        #
     delta_h  -281.705      kJ/mol        #
     # Enthalpy of formation:             -7417.19      kJ/mol        


Saponite-Mg(hydrated)
Mg3.17Al0.34Si3.66O10(OH)2:5H2O = +3.170Mg+2     +0.340Al+3     -7.360H+     +3.660H4(SiO4)     +2.360H2O     
     log_k     33.81        #
     delta_h  -282.359      kJ/mol        #
     # Enthalpy of formation:             -7403.617     kJ/mol        


Vermiculite-Ca(hydrated)
Ca0.43Mg3.00Si3.14Al0.86O10(OH)2:5H2O = +0.430Ca+2     +3.000Mg+2     +0.860Al+3     -9.440H+     +3.140H4(SiO4)     +4.440H2O     
     log_k     43.18        #
     delta_h  -376.798      kJ/mol        #
     # Enthalpy of formation:             -7577.951     kJ/mol        


Vermiculite-Mg(hydrated)
Mg0.43Mg3.00Si3.14Al0.86O10(OH)2:5H2O = +3.430Mg+2     +0.860Al+3     -9.440H+     +3.140H4(SiO4)     +4.440H2O     
     log_k     41.61        #
     delta_h  -377.827      kJ/mol        #
     # Enthalpy of formation:             -7544.242     kJ/mol        


CSH1.6
Ca1.6SiO3.6:2.58H2O = +1.600Ca+2     -3.200H+     +1.000H4(SiO4)     +2.180H2O     
     log_k     28           #07BLA/BOU
     delta_h  -133.314      kJ/mol        #
     # Enthalpy of formation:             -2819.79      kJ/mol        07BLA/BOU


CSH1.2
Ca1.2SiO3.2:2.06H2O = +1.200Ca+2     -2.400H+     +1.000H4(SiO4)     +1.260H2O     
     log_k     19.3         #07BLA/BOU
     delta_h  -88.6         kJ/mol        #
     # Enthalpy of formation:             -2384.34      kJ/mol        07BLA/BOU


CSH0.8
Ca0.8SiO2.8:1.54H2O = +0.800Ca+2     -1.600H+     +1.000H4(SiO4)     +0.340H2O     
     log_k     11.05        #07BLA/BOU
     delta_h  -47.646       kJ/mol        #
     # Enthalpy of formation:             -1945.13      kJ/mol        07BLA/BOU


MX80(hyd1)
(Ca0.01Na0.434K0.026)(Si3.612Al0.388)(Al1.608Fe0.184Fe0.038Mg0.228)O10(OH)2:5.441H2O = +0.010Ca+2     +0.228Mg+2     +0.026K+     +0.434Na+     +0.184Fe+3     +0.038Fe+2     +1.996Al+3     -7.552H+     +3.612H4(SiO4)     +2.993H2O     
     log_k     7.09         #
     delta_h  -194.364      kJ/mol        #
     # Enthalpy of formation:             -7248.81      kJ/mol        07GAI/BLA


MX80(hyd2)
(Ca0.01Na0.434K0.026)(Si3.612Al0.388)(Al1.608Fe0.184Fe0.038Mg0.228)O10(OH)2:4.183H2O = +0.010Ca+2     +0.228Mg+2     +0.026K+     +0.434Na+     +0.184Fe+3     +0.038Fe+2     +1.996Al+3     -7.552H+     +3.612H4(SiO4)     +1.735H2O     
     log_k     6.8          #
     delta_h  -199.17       kJ/mol        #
     # Enthalpy of formation:             -6884.43      kJ/mol        07GAI/BLA


Chlorite-Cca-2
(Mg2.964Fe1.712Fe0.215Al1.116Ca0.011)(Si2.633Al1.367)O10(OH)8 = +0.011Ca+2     +2.964Mg+2     +0.215Fe+3     +1.712Fe+2     +2.483Al+3     -17.468H+     +2.633H4(SiO4)     +7.468H2O     
     log_k     61.23        #
     delta_h  -632.836      kJ/mol        #
     # Enthalpy of formation:             -8240.69      kJ/mol        06GAI


SrCrO4(s)
SrCrO4 = +1.000Sr+2     +1.000CrO4-2     
     log_k    -4.65         #97MAR/SMI
     delta_h  -10.125       kJ/mol        #97MAR/SMI
     # Enthalpy of formation:             -1419.775     kJ/mol        


Sr(cr)
Sr = +1.000Sr+2     +2.000e-     
     log_k     98.79        #
     delta_h  -550.9        kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        


Sr(OH)2:8H2O(s)
Sr(OH)2:8H2O = +1.000Sr+2     -2.000H+     +10.000H2O     
     log_k     24.32        #98FEL/DIX
     delta_h  -57           kJ/mol        #
     # Enthalpy of formation:             -3352.2       kJ/mol        82WAG/EVA


SrSiO3(s)
SrSiO3 = +1.000Sr+2     -2.000H+     +1.000H4(SiO4)     -1.000H2O     
     log_k     13.16        #
     delta_h  -80.278       kJ/mol        #
     # Enthalpy of formation:             -1645.986     kJ/mol        74NAU/RYZ


Sr2SiO4(s)
Sr2SiO4 = +2.000Sr+2     -4.000H+     +1.000H4(SiO4)     
     log_k     43.25        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Sr5(PO4)3(OH)(s)
Sr5(PO4)3(OH) = +5.000Sr+2     -7.000H+     +3.000H2(PO4)-     +1.000H2O     
     log_k     7.17         #05KIM/PAR
     delta_h  -261.63       kJ/mol        #
     # Enthalpy of formation:             -6686.5       kJ/mol        95JEM/CHE


K2O(s)
K2O = +2.000K+     -2.000H+     +1.000H2O     
     log_k     84.11        #
     delta_h  -426.94       kJ/mol        #
     # Enthalpy of formation:             -363.17       kJ/mol        98CHA


KBr(s)
KBr = +1.000K+     +1.000Br-     
     log_k     1.13         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


KI(s)
KI = +1.000K+     +1.000I-     
     log_k     1.74         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


K(NO3)(s)
K(NO3) = +1.000K+     +1.000NO3-     
     log_k    -0.1          #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


K(OH)(s)
K(OH) = +1.000K+     -1.000H+     +1.000H2O     
     log_k     24.6         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Sylvite
KCl = +1.000K+     +1.000Cl-     
     log_k     0.87         #
     delta_h   17.46        kJ/mol        #
     # Enthalpy of formation:             -436.68       kJ/mol        98CHA


K(cr)
K = +1.000K+     +1.000e-     
     log_k     49.49        #
     delta_h  -252.14       kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        89COX/WAG


Sanidine
KAlSi3O8 = +1.000K+     +1.000Al+3     -4.000H+     +3.000H4(SiO4)     -4.000H2O     
     log_k     0.58         #
     delta_h  -65.073       kJ/mol        #
     # Enthalpy of formation:             -3965.73      kJ/mol        00ARN/STE


Muscovite
KAl3Si3O10(OH)2 = +1.000K+     +3.000Al+3     -10.000H+     +3.000H4(SiO4)     
     log_k     14           #
     delta_h  -276.123      kJ/mol        #
     # Enthalpy of formation:             -5974.8       kJ/mol        95HAS/CYG


Carnallite
KMgCl3:6H2O = +1.000Mg+2     +1.000K+     +3.000Cl-     +6.000H2O     
     log_k     4.33         #84HAR/MOL
     delta_h   9.339        kJ/mol        #
     # Enthalpy of formation:             -2944.699     kJ/mol        74NAU/RYZ


Kainite
KMgCl(SO4):3H2O = +1.000Mg+2     +1.000K+     +1.000SO4-2     +1.000Cl-     +3.000H2O     
     log_k    -0.19         #84HAR/MOL
     delta_h  -12.95        kJ/mol        #
     # Enthalpy of formation:             -2640.1       kJ/mol        82WAG/EVA


Kalicinite
KHCO3 = +1.000K+     +1.000H+     +1.000CO3-2     
     log_k    -10.06        #84HAR/MOL
     delta_h   34.95        kJ/mol        #
     # Enthalpy of formation:             -962.32       kJ/mol        74NAU/RYZ


K-carbonate
K2CO3:1.5H2O = +2.000K+     +1.000CO3-2     +1.500H2O     
     log_k     3.03         #84HAR/MOL
     delta_h  -1.188        kJ/mol        #
     # Enthalpy of formation:             -1607.067     kJ/mol        


K-trona
K2NaH(CO3)2:2H2O = +2.000K+     +1.000Na+     +1.000H+     +2.000CO3-2     +2.000H2O     
     log_k    -9.1          #84HAR/MOL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Leonite
K2Mg(SO4)2:4H2O = +1.000Mg+2     +2.000K+     +2.000SO4-2     +4.000H2O     
     log_k    -3.98         #84HAR/MOL
     delta_h   15.29        kJ/mol        #
     # Enthalpy of formation:             -3948.57      kJ/mol        74NAU/RYZ


Mercallite
KHSO4 = +1.000K+     +1.000H+     +1.000SO4-2     
     log_k    -1.4          #84HAR/MOL
     delta_h  -0.59         kJ/mol        #
     # Enthalpy of formation:             -1160.89      kJ/mol        74NAU/RYZ


Picromerite
K2Mg(SO4)2:6H2O = +1.000Mg+2     +2.000K+     +2.000SO4-2     +6.000H2O     
     log_k    -4.33         #84HAR/MOL
     delta_h   33.487       kJ/mol        #
     # Enthalpy of formation:             -4538.427     kJ/mol        74NAU/RYZ


Polyhalite
K2MgCa2(SO4)4:2H2O = +2.000Ca+2     +1.000Mg+2     +2.000K+     +4.000SO4-2     +2.000H2O     
     log_k    -13.74        #84HAR/MOL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Syngenite
K2Ca(SO4)2:6H2O = +1.000Ca+2     +2.000K+     +2.000SO4-2     +6.000H2O     
     log_k    -7.45         #84HAR/MOL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Arcanite
K2SO4  = +2.000K+     +1.000SO4-2     
     log_k    -1.85         #
     delta_h   24.08        kJ/mol        #
     # Enthalpy of formation:             -1437.7       kJ/mol        95ROB/HEM


KH2PO4(cr)
KH2PO4 = +1.000K+     +1.000H2(PO4)-     
     log_k    -0.37         #
     delta_h   19.686       kJ/mol        #74NAU/RYZ
     # Enthalpy of formation:             -1574.426     kJ/mol        


K2CO3(cr)
K2CO3 = +2.000K+     +1.000CO3-2     
     log_k     5.41         #
     delta_h  -31.798       kJ/mol        #
     # Enthalpy of formation:             -1147.712     kJ/mol        


KAl(SO4)2:12H2O(s)
KAl(SO4)2:12H2O = +1.000K+     +1.000Al+3     +2.000SO4-2     +12.000H2O     
     log_k    -6.68         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


KAl(SO4)2(s)
KAl(SO4)2 = +1.000K+     +1.000Al+3     +2.000SO4-2     
     log_k     3.74         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


KFe3(CrO4)2(OH)6(cr)
KFe3(CrO4)2(OH)6 = +1.000K+     +3.000Fe+3     -6.000H+     +2.000CrO4-2     +6.000H2O     
     log_k    -18.4         #95BAR/PAL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


KFe(CrO4)2:2H2O(s)
KFe(CrO4)2:2H2O = +1.000K+     +1.000Fe+3     +2.000CrO4-2     +2.000H2O     
     log_k    -19.39        #98BAR/PAL
     delta_h   27.54        kJ/mol        #85BAR/PAL
     # Enthalpy of formation:             -2658.34      kJ/mol        


Beidellite-K
K0.33Al2.33Si3.67O10(OH)2 = +0.330K+     +2.330Al+3     -7.320H+     +3.670H4(SiO4)     -2.680H2O     
     log_k     2.31         #
     delta_h  -179.107      kJ/mol        #
     # Enthalpy of formation:             -5755.13      kJ/mol        07VIE


Celadonite
KMgAlSi4O10(OH)2 = +1.000Mg+2     +1.000K+     +1.000Al+3     -6.000H+     +4.000H4(SiO4)     -4.000H2O     
     log_k     9.3          #
     delta_h  -123.57       kJ/mol        #
     # Enthalpy of formation:             -5835.427     kJ/mol        07VIE


Fe-celadonite
KFeAlSi4O10(OH)2 = +1.000K+     +1.000Fe+2     +1.000Al+3     -6.000H+     +4.000H4(SiO4)     -4.000H2O     
     log_k     2.73         #
     delta_h  -83.838       kJ/mol        #
     # Enthalpy of formation:             -5498.159     kJ/mol        07VIE


Mg-Montmorillonite-K
K0.33Mg0.33Al1.67Si4O10(OH)2 = +0.330Mg+2     +0.330K+     +1.670Al+3     -6.000H+     +4.000H4(SiO4)     -4.000H2O     
     log_k     2.83         #
     delta_h  -138.561      kJ/mol        #
     # Enthalpy of formation:             -5699.34      kJ/mol        07VIE


Fe-Montmorillonite-K
K0.33Mg0.33Fe0.67Al1.0Si4O10(OH)2 = +0.330Mg+2     +0.330K+     +0.670Fe+3     +1.000Al+3     -6.000H+     +4.000H4(SiO4)     -4.000H2O     
     log_k     1.39         #
     delta_h  -127.503      kJ/mol        #
     # Enthalpy of formation:             -5382.5       kJ/mol        07VIE


Beidellite-FeK
K0.33Fe0.66Al1.67Si3.67O10(OH)2 = +0.330K+     +0.660Fe+3     +1.670Al+3     -7.320H+     +3.670H4(SiO4)     -2.680H2O     
     log_k     0.98         #
     delta_h  -169.093      kJ/mol        #
     # Enthalpy of formation:             -5442.14      kJ/mol        07VIE


Fe-Saponite-K
K0.33Fe3Al0.33Si3.67O10(OH)2 = +0.330K+     +3.000Fe+2     +0.330Al+3     -7.320H+     +3.670H4(SiO4)     -2.680H2O     
     log_k     20.31        #
     delta_h  -201.017      kJ/mol        #
     # Enthalpy of formation:             -4926.42      kJ/mol        07VIE


Saponite-K
K0.33Mg3Al0.33Si3.67O10(OH)2 = +3.000Mg+2     +0.330K+     +0.330Al+3     -7.320H+     +3.670H4(SiO4)     -2.680H2O     
     log_k     28.1         #
     delta_h  -252.497      kJ/mol        #
     # Enthalpy of formation:             -6005.94      kJ/mol        07VIE


Illite-Mg
K0.85Mg0.25Al2.35Si3.4O10(OH)2 = +0.250Mg+2     +0.850K+     +2.350Al+3     -8.400H+     +3.400H4(SiO4)     -1.600H2O     
     log_k     10.25        #
     delta_h  -222.133      kJ/mol        #
     # Enthalpy of formation:             -5884.908     kJ/mol        07VIE


Illite-FeII
K0.85Fe0.25Al2.35Si3.4O10(OH)2 = +0.850K+     +0.250Fe+2     +2.350Al+3     -8.400H+     +3.400H4(SiO4)     -1.600H2O     
     log_k     7.86         #
     delta_h  -207.942      kJ/mol        #
     # Enthalpy of formation:             -5804.849     kJ/mol        07VIE


illite-FeIII
K0.85Fe0.25Al2.6Si3.15O10(OH)2 = +0.850K+     +0.250Fe+3     +2.600Al+3     -9.400H+     +3.150H4(SiO4)     -0.600H2O     
     log_k     10.07        #
     delta_h  -252.345      kJ/mol        #
     # Enthalpy of formation:             -5805.328     kJ/mol        07VIE


Illite-Al
K0.85Al2.85Si3.15O10(OH)2 = +0.850K+     +2.850Al+3     -9.400H+     +3.150H4(SiO4)     -0.600H2O     
     log_k     10.44        #
     delta_h  -254.658      kJ/mol        #
     # Enthalpy of formation:             -5925.364     kJ/mol        07VIE


Vermiculite-K
K0.85Mg3Si3.15Al0.85O10(OH)2 = +3.000Mg+2     +0.850K+     +0.850Al+3     -9.400H+     +3.150H4(SiO4)     -0.600H2O     
     log_k     36.86        #
     delta_h  -331.639      kJ/mol        #
     # Enthalpy of formation:             -6172.584     kJ/mol        07VIE


Beidellite-K(hydrated)
K0.33Al2.33Si3.67O10(OH)2:5H2O = +0.330K+     +2.330Al+3     -7.320H+     +3.670H4(SiO4)     +2.320H2O     
     log_k     6.74         #
     delta_h  -188.653      kJ/mol        #
     # Enthalpy of formation:             -7174.733     kJ/mol        


Mg-Montmorillonite-K(hydrated)
K0.33Mg0.33Al1.67Si4O10(OH)2:5H2O = +0.330Mg+2     +0.330K+     +1.670Al+3     -6.000H+     +4.000H4(SiO4)     +1.000H2O     
     log_k     6.09         #
     delta_h  -141.445      kJ/mol        #
     # Enthalpy of formation:             -7125.606     kJ/mol        


Fe-Montmorillonite-K(hydrated)
K0.33Mg0.33Fe0.67Al1.00Si4O10(OH)2:5H2O = +0.330Mg+2     +0.330K+     +0.670Fe+3     +1.000Al+3     -6.000H+     +4.000H4(SiO4)     +1.000H2O     
     log_k     0.24         #
     delta_h  -105.197      kJ/mol        #
     # Enthalpy of formation:             -6833.956     kJ/mol        


Beidellite-FeK(hydrated)
K0.33Fe0.66Al1.67Si3.67O10(OH)2:5H2O = +0.330K+     +0.660Fe+3     +1.670Al+3     -7.320H+     +3.670H4(SiO4)     +2.320H2O     
     log_k     0.85         #
     delta_h  -152.655      kJ/mol        #
     # Enthalpy of formation:             -6887.728     kJ/mol        


Fe-Saponite-K(hydrated)
K0.33Fe3Al0.33Si3.67O10(OH)2:5H2O = +0.330K+     +3.000Fe+2     +0.330Al+3     -7.320H+     +3.670H4(SiO4)     +2.320H2O     
     log_k     18.07        #
     delta_h  -172.533      kJ/mol        #
     # Enthalpy of formation:             -6384.054     kJ/mol        


Saponite-K(hydrated)
K0.33Mg3Al0.33Si3.67O10(OH)2:5H2O = +3.000Mg+2     +0.330K+     +0.330Al+3     -7.320H+     +3.670H4(SiO4)     +2.320H2O     
     log_k     34.05        #
     delta_h  -270.741      kJ/mol        #
     # Enthalpy of formation:             -7416.846     kJ/mol        


Vermiculite-K(hydrated)
K0.85Mg3.00Si3.15Al0.85O10(OH)2:5H2O = +3.000Mg+2     +0.850K+     +0.850Al+3     -9.400H+     +3.150H4(SiO4)     +4.400H2O     
     log_k     43.31        #
     delta_h  -352.755      kJ/mol        #
     # Enthalpy of formation:             -7580.618     kJ/mol        


Thermonatrite
Na2(CO3):H2O = +2.000Na+     +1.000CO3-2     +1.000H2O     
     log_k     0.48         #84HAR/MOL
     delta_h  -12.04        kJ/mol        #
     # Enthalpy of formation:             -1429.7       kJ/mol        82VAN


Dawsonite
NaAl(CO3)(OH)2 = +1.000Na+     +1.000Al+3     -2.000H+     +1.000CO3-2     +2.000H2O     
     log_k    -6            #
     delta_h  -61.63        kJ/mol        #
     # Enthalpy of formation:             -1964         kJ/mol        76FER/STU


Na2O(cr)
Na2O = +2.000Na+     -2.000H+     +1.000H2O     
     log_k     67.46        #
     delta_h  -351.71       kJ/mol        #
     # Enthalpy of formation:             -414.8        kJ/mol        95ROB/HEM


Halite
NaCl = +1.000Na+     +1.000Cl-     
     log_k     1.59         #
     delta_h   3.7          kJ/mol        #
     # Enthalpy of formation:             -411.12       kJ/mol        98CHA


NaF(s)
NaF = +1.000Na+     +1.000F-     
     log_k    -0.48         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Nahcolite
Na(HCO3) = +1.000Na+     +1.000H+     +1.000CO3-2     
     log_k    -10.74        #84HAR/MOL
     delta_h   33.43        kJ/mol        #
     # Enthalpy of formation:             -949          kJ/mol        82VAN


Na(NO3)(s)
Na(NO3) = +1.000Na+     +1.000NO3-     
     log_k     1.09         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Natron
Na2(CO3):10H2O = +2.000Na+     +1.000CO3-2     +10.000H2O     
     log_k    -0.83         #84HAR/MOL
     delta_h   64.87        kJ/mol        #
     # Enthalpy of formation:             -4079         kJ/mol        


NaBO2(s)
NaBO2 = +1.000Na+     +1.000B(OH)4-     -2.000H2O     
     log_k     3.62         #
     delta_h  -36.79        kJ/mol        #
     # Enthalpy of formation:             -977.006      kJ/mol        


NaAmO2CO3(s)
NaAmO2CO3 = +1.000Na+     +1.000AmO2+     +1.000CO3-2     
     log_k    -10.9         #94GIF, 94RUN/KIM, 94RUN/NEU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Albite-low
NaAlSi3O8 = +1.000Na+     +1.000Al+3     -4.000H+     +3.000H4(SiO4)     -4.000H2O     
     log_k     2.74         #
     delta_h  -82.813       kJ/mol        #
     # Enthalpy of formation:             -3936.19      kJ/mol        00ARN/STE


Albite-high
NaAlSi3O8 = +1.000Na+     +1.000Al+3     -4.000H+     +3.000H4(SiO4)     -4.000H2O     
     log_k     4.14         #
     delta_h  -95.623       kJ/mol        #
     # Enthalpy of formation:             -3923.38      kJ/mol        00ARN/STE


Bloedite
Na2Mg(SO4)2:4H2O = +1.000Mg+2     +2.000Na+     +2.000SO4-2     +4.000H2O     
     log_k    -2.35         #84HAR/MOL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Burkeite
Na6(CO3)(SO4)2 = +6.000Na+     +1.000CO3-2     +2.000SO4-2     
     log_k    -0.77         #84HAR/MOL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Glaserite
Na2K6(SO4)4 = +6.000K+     +2.000Na+     +4.000SO4-2     
     log_k    -7.61         #80HAR/WEA
     delta_h   78.36        kJ/mol        #
     # Enthalpy of formation:             -5709.24      kJ/mol        


Glauberite
Na2Ca(SO4)2 = +1.000Ca+2     +2.000Na+     +2.000SO4-2     
     log_k     1.97         #84HAR/MOL
     delta_h  -13.16        kJ/mol        #
     # Enthalpy of formation:             -2829.2       kJ/mol        82WAG/EVA


Mirabilite
Na2SO4:10H2O = +2.000Na+     +1.000SO4-2     +10.000H2O     
     log_k    -1.23         #84HAR/MOL
     delta_h   79.471       kJ/mol        #
     # Enthalpy of formation:             -4327.791     kJ/mol        


Thernardite
Na2SO4 = +2.000Na+     +1.000SO4-2     
     log_k    -0.36         #
     delta_h  -2.2          kJ/mol        #
     # Enthalpy of formation:             -1387.82      kJ/mol        98CHA


Na(cr)
Na = +1.000Na+     +1.000e-     
     log_k     45.89        #
     delta_h  -240.34       kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        92GRE/FUG (89COX/WAG)


Na2(CO3)(cr)
Na2(CO3) = +2.000Na+     +1.000CO3-2     
     log_k     1.12         #
     delta_h  -26.71        kJ/mol        #
     # Enthalpy of formation:             -1129.2       kJ/mol        95ROB/HEM


NaH2PO4(cr)
NaH2PO4 = +1.000Na+     +1.000H2(PO4)-     
     log_k     2.3          #
     delta_h  -6.14         kJ/mol        #
     # Enthalpy of formation:             -1536.8       kJ/mol        82WAG/EVA


Na2HPO4(cr)
Na2HPO4 = +2.000Na+     -1.000H+     +1.000H2(PO4)-     
     log_k     9.24         #
     delta_h  -35.18        kJ/mol        #
     # Enthalpy of formation:             -1748.1       kJ/mol        82WAG/EVA


Na3PO4(cr)
Na3PO4 = +3.000Na+     -2.000H+     +1.000H2(PO4)-     
     log_k     23.52        #
     delta_h  -106.218      kJ/mol        #
     # Enthalpy of formation:             -1917.402     kJ/mol        74NAU/RIZ


Trona
Na3H(CO3)2:2H2O = +3.000Na+     +1.000H+     +2.000CO3-2     +2.000H2O     
     log_k    -11.38        #84HAR/MOL
     delta_h   38.96        kJ/mol        #
     # Enthalpy of formation:             -2682.1       kJ/mol        82VAN


Pirssonite
Na2Ca(CO3)2:2H2O = +1.000Ca+2     +2.000Na+     +2.000CO3-2     +2.000H2O     
     log_k    -8.91         #99KON/KON
     delta_h   9.58         kJ/mol        #
     # Enthalpy of formation:             -2955.38      kJ/mol        


Na2CO3:7H2O(s)
Na2CO3:7H2O = +2.000Na+     +1.000CO3-2     +7.000H2O     
     log_k    -0.46         #84HAR/MOL
     delta_h   42.682       kJ/mol        #
     # Enthalpy of formation:             -3199.402     kJ/mol        


NaSm(CO3)2:5H2O(s)
NaSm(CO3)2:5H2O = +1.000Na+     +1.000Sm+3     +2.000CO3-2     +5.000H2O     
     log_k    -20.99        #Estimated by ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


NaEu(CO3)2:5H2O(s)
NaEu(CO3)2:5H2O = +1.000Na+     +1.000Eu+3     +2.000CO3-2     +5.000H2O     
     log_k    -20.9         #05VER/VIT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


NaHo(CO3)2:5H2O(s)
NaHo(CO3)2:5H2O = +1.000Na+     +1.000Ho+3     +2.000CO3-2     +5.000H2O     
     log_k    -20.5         #Estimated by ionic radii correlation
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


NaCm(CO3)2:5H2O(s)
NaCm(CO3)2:5H2O = +1.000Na+     +2.000CO3-2     +1.000Cm+3     +5.000H2O     
     log_k    -21           #estimated by correlation with Ln(III) and An(III)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Beidellite-Na
Na0.33Al2.33Si3.67O10(OH)2 = +0.330Na+     +2.330Al+3     -7.320H+     +3.670H4(SiO4)     -2.680H2O     
     log_k     3.73         #
     delta_h  -188.903      kJ/mol        #
     # Enthalpy of formation:             -5741.44      kJ/mol        07VIE


Litharge
PbO = +1.000Pb+2     -2.000H+     +1.000H2O     
     log_k     12.63        #
     delta_h  -65.501       kJ/mol        #
     # Enthalpy of formation:             -219.409      kJ/mol        98CHA


Clausthalite
PbSe = +1.000Pb+2     -1.000H+     +1.000HSe-     
     log_k    -20.53        #
     delta_h   113.72       kJ/mol        #
     # Enthalpy of formation:             -98.5         kJ/mol        05OLI/NOL


Massicot
PbO = +1.000Pb+2     -2.000H+     +1.000H2O     
     log_k     12.74        #
     delta_h  -66.848       kJ/mol        #
     # Enthalpy of formation:             -218.062      kJ/mol        98CHA


Laurionite
PbClOH = +1.000Pb+2     -1.000H+     +1.000Cl-     +1.000H2O     
     log_k     0.62         #99LOT/OCH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Plumbonacrite
Pb10(CO3)6O(OH)6 = +10.000Pb+2     -8.000H+     +6.000CO3-2     +7.000H2O     
     log_k    -42.09        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Phosgenite
Pb2(CO3)Cl2 = +2.000Pb+2     +1.000CO3-2     +2.000Cl-     
     log_k     19.9         #74NAU/RYZ
     delta_h  -163.291      kJ/mol        #
     # Enthalpy of formation:             -844.259      kJ/mol        


Lanarkite
PbSO4:PbO = +2.000Pb+2     -2.000H+     +1.000SO4-2     +1.000H2O     
     log_k     2.63         #82ABD/THO
     delta_h  -39.234       kJ/mol        #
     # Enthalpy of formation:             -1154.096     kJ/mol        


Alamosite
PbSiO3  = +1.000Pb+2     -2.000H+     +1.000H4(SiO4)     -1.000H2O     
     log_k     6.17         #
     delta_h  -29.451       kJ/mol        #
     # Enthalpy of formation:             -1144.993     kJ/mol        98CHA


PbSiO3(Glass)
PbSiO3 = +1.000Pb+2     -2.000H+     +1.000H4(SiO4)     -1.000H2O     
     log_k     6.6          #
     delta_h  -36.814       kJ/mol        #
     # Enthalpy of formation:             -1137.63      kJ/mol        74NAU/RYZ


Pb4O(PO4)2(cr)
Pb4O(PO4)2 = +4.000Pb+2     -6.000H+     +2.000H2(PO4)-     +1.000H2O     
     log_k     2.24         #74NRI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Pyromorphite
Pb5Cl(PO4)3 = +5.000Pb+2     -6.000H+     +1.000Cl-     +3.000H2(PO4)-     
     log_k    -25.75        #74NRI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Pyromorphite-F
Pb5F(PO4)3 = +5.000Pb+2     -6.000H+     +1.000F-     +3.000H2(PO4)-     
     log_k    -13.1         #74NRI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Pyromorphite-Br
Pb5Br(PO4)3 = +5.000Pb+2     -6.000H+     +1.000Br-     +3.000H2(PO4)-     
     log_k    -19.45        #74NRI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Plumbogummite
PbAl3(PO4)2(OH)5 = +1.000Pb+2     +3.000Al+3     -9.000H+     +2.000H2(PO4)-     +5.000H2O     
     log_k     13.24        #74NRI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Pb(H2PO4)2(cr)
Pb(H2PO4)2 = +1.000Pb+2     +2.000H2(PO4)-     
     log_k    -9.84         #74NRI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Pb(OH)2(s)
Pb(OH)2 = +1.000Pb+2     -2.000H+     +2.000H2O     
     log_k     13.51        #
     delta_h  -56.14        kJ/mol        #
     # Enthalpy of formation:             -514.6        kJ/mol        52LAT


Crocoite
PbCrO4 = +1.000Pb+2     +1.000CrO4-2     
     log_k    -12.55        #42KOL/PER
     delta_h   48.94        kJ/mol        #
     # Enthalpy of formation:             -927.02       kJ/mol        75DEL/MCC


Cotunnite
PbCl2 = +1.000Pb+2     +2.000Cl-     
     log_k    -4.81         #
     delta_h   26.16        kJ/mol        #
     # Enthalpy of formation:             -359.4        kJ/mol        98CHA


Paralaurionite
PbCl(OH) = +1.000Pb+2     -1.000H+     +1.000Cl-     +1.000H2O     
     log_k     0.62         #99LOT/OCH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Co(SeO3):2H2O(s)
Co(SeO3):2H2O = +1.000Co+2     +1.000SeO3-2     +2.000H2O     
     log_k    -7.9          #05OLI/NOL
     delta_h  -20.86        kJ/mol        #
     # Enthalpy of formation:             -1115.56      kJ/mol        05OLI/NOL


Co(SeO4):6H2O(s)
Co(SeO4):6H2O = +1.000Co+2     +1.000SeO4-2     +6.000H2O     
     log_k    -1.76         #05OLI/NOL
     delta_h  -3.299        kJ/mol        #
     # Enthalpy of formation:             -2372.781     kJ/mol        


CoSe2(cr)
CoSe2 = +1.000Co+2     -2.000H+     -2.000e-     +2.000HSe-     
     log_k    -23.09        #
     delta_h   76.5         kJ/mol        #
     # Enthalpy of formation:             -105.5        kJ/mol        05OLI/NOL


Co0.84Se(cr)
Co0.84Se = +0.840Co+2     -1.000H+     -0.320e-     +1.000HSe-     
     log_k    -9.3          #
     delta_h   21.316       kJ/mol        #
     # Enthalpy of formation:             -55.4         kJ/mol        05OLI/NOL


Co(cr)
Co = +1.000Co+2     +2.000e-     
     log_k     9.74         #
     delta_h  -57.6         kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        


Co(OH)2(s,rose1)
Co(OH)2 = +1.000Co+2     -2.000H+     +2.000H2O     
     log_k     12.2         #98PLY/ZHA
     delta_h  -88.46        kJ/mol        #
     # Enthalpy of formation:             -540.8        kJ/mol        98PLY/ZHA


Co(OH)2(s,rose2)
Co(OH)2 = +1.000Co+2     -2.000H+     +2.000H2O     
     log_k     13.2         #98PLY/ZHA
     delta_h  -93.56        kJ/mol        #
     # Enthalpy of formation:             -535.7        kJ/mol        98PLY/ZHA


Co(OH)2(s,blue)
Co(OH)2 = +1.000Co+2     -2.000H+     +2.000H2O     
     log_k     13.8         #98PLY/ZHA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


CoO(s)
CoO = +1.000Co+2     -2.000H+     +1.000H2O     
     log_k     13.77        #
     delta_h  -105.53       kJ/mol        #
     # Enthalpy of formation:             -237.9        kJ/mol        95ROB/HEM


Co3O4(s)
Co3O4 = +3.000Co+2     -8.000H+     -2.000e-     +4.000H2O     
     log_k     54.86        #
     delta_h  -397.3        kJ/mol        #
     # Enthalpy of formation:             -918.8        kJ/mol        95ROB/HEM


Sphaerocobaltite
CoCO3 = +1.000Co+2     +1.000CO3-2     
     log_k    -11.2         #99GRA
     delta_h  -9.421        kJ/mol        #
     # Enthalpy of formation:             -723.409      kJ/mol        


Co2SiO4(s)
Co2SiO4 = +2.000Co+2     -4.000H+     +1.000H4(SiO4)     
     log_k     7.35         #
     delta_h  -99.394       kJ/mol        #
     # Enthalpy of formation:             -1477         kJ/mol        82WAG/EVA


CoHPO4(s)
CoHPO4 = +1.000Co+2     -1.000H+     +1.000H2(PO4)-     
     log_k     0.49         #84VIE/TAR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Co3(PO4)2(s)
Co3(PO4)2 = +3.000Co+2     -4.000H+     +2.000H2(PO4)-     
     log_k     4.36         #84VIE/TAR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


CoSO4(s)
CoSO4 = +1.000Co+2     +1.000SO4-2     
     log_k     3.01         #
     delta_h  -78.68        kJ/mol        #
     # Enthalpy of formation:             -888.26       kJ/mol        98CHA


CoSO4:H2O(s)
CoSO4:H2O = +1.000Co+2     +1.000SO4-2     +1.000H2O     
     log_k    -1.05         #
     delta_h  -52.05        kJ/mol        #
     # Enthalpy of formation:             -1200.72      kJ/mol        74NAU/RYZ


CoSO4:6H2O(s)
CoSO4:6H2O = +1.000Co+2     +1.000SO4-2     +6.000H2O     
     log_k    -2.2          #
     delta_h   1.57         kJ/mol        #
     # Enthalpy of formation:             -2683.49      kJ/mol        74NAU/RYZ


Bieberite
CoSO4:7H2O = +1.000Co+2     +1.000SO4-2     +7.000H2O     
     log_k    -2.35         #
     delta_h   11.84        kJ/mol        #
     # Enthalpy of formation:             -2979.59      kJ/mol        74NAU/RYZ


CoS(alpha)
CoS = +1.000Co+2     -1.000H+     +1.000HS-     
     log_k    -7.44         #90DYR/KRE
     delta_h   11.836       kJ/mol        #
     # Enthalpy of formation:             -85.736       kJ/mol        


CoS(beta)
CoS = +1.000Co+2     -1.000H+     +1.000HS-     
     log_k    -11.07        #90DYR/KRE
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Cattierite
CoS2 = +1.000Co+2     -2.000H+     -2.000e-     +2.000HS-     
     log_k    -19.98        #
     delta_h   60.7         kJ/mol        #
     # Enthalpy of formation:             -150.9        kJ/mol        95ROB/HEM


Linnaeite
Co3S4  = +3.000Co+2     -4.000H+     -2.000e-     +4.000HS-     
     log_k    -42.76        #
     delta_h   136.5        kJ/mol        #
     # Enthalpy of formation:             -374.5        kJ/mol        95ROB/HEM


Mg-Montmorillonite-Na
Na0.33Mg0.33Al1.67Si4O10(OH)2 = +0.330Mg+2     +0.330Na+     +1.670Al+3     -6.000H+     +4.000H4(SiO4)     -4.000H2O     
     log_k     4.33         #
     delta_h  -148.827      kJ/mol        #
     # Enthalpy of formation:             -5685.18      kJ/mol        07VIE


Fe-Montmorillonite-Na
Na0.33Mg0.33Fe0.67Al1.0Si4O10(OH)2 = +0.330Mg+2     +0.330Na+     +0.670Fe+3     +1.000Al+3     -6.000H+     +4.000H4(SiO4)     -4.000H2O     
     log_k     2.89         #
     delta_h  -137.779      kJ/mol        #
     # Enthalpy of formation:             -5368.33      kJ/mol        07VIE


Beidellite-FeNa
Na0.33Fe0.66Al1.67Si3.67O10(OH)2 = +0.330Na+     +0.660Fe+3     +1.670Al+3     -7.320H+     +3.670H4(SiO4)     -2.680H2O     
     log_k     2.4          #
     delta_h  -178.899      kJ/mol        #
     # Enthalpy of formation:             -5428.44      kJ/mol        07VIE


Fe-Saponite-Na
Na0.33Fe3Al0.33Si3.67O10(OH)2 = +0.330Na+     +3.000Fe+2     +0.330Al+3     -7.320H+     +3.670H4(SiO4)     -2.680H2O     
     log_k     21.73        #
     delta_h  -210.823      kJ/mol        #
     # Enthalpy of formation:             -4912.72      kJ/mol        07VIE


Saponite-Na
Na0.33Mg3Al0.33Si3.67O10(OH)2 = +3.000Mg+2     +0.330Na+     +0.330Al+3     -7.320H+     +3.670H4(SiO4)     -2.680H2O     
     log_k     29.52        #
     delta_h  -262.303      kJ/mol        #
     # Enthalpy of formation:             -5992.24      kJ/mol        07VIE


Vermiculite-Na
Na0.85Mg3Si3.15Al0.85O10(OH)2 = +3.000Mg+2     +0.850Na+     +0.850Al+3     -9.400H+     +3.150H4(SiO4)     -0.600H2O     
     log_k     40.17        #
     delta_h  -354.987      kJ/mol        #
     # Enthalpy of formation:             -6139.206     kJ/mol        07VIE


Beidellite-Na(hydrated)
Na0.33Al2.33Si3.67O10(OH)2:5H2O = +0.330Na+     +2.330Al+3     -7.320H+     +3.670H4(SiO4)     +2.320H2O     
     log_k     6.88         #
     delta_h  -191.184      kJ/mol        #
     # Enthalpy of formation:             -7168.308     kJ/mol        


Mg-Montmorillonite-Na(hydrated)
Na0.33Mg0.33Al1.67Si4O10(OH)2:5H2O = +0.330Mg+2     +0.330Na+     +1.670Al+3     -6.000H+     +4.000H4(SiO4)     +1.000H2O     
     log_k     6.4          #
     delta_h  -144.936      kJ/mol        #
     # Enthalpy of formation:             -7118.221     kJ/mol        


Fe-Montmorillonite-Na(hydrated)
Na0.33Mg0.33Fe0.67Al1.00Si4O10(OH)2:5H2O = +0.330Mg+2     +0.330Na+     +0.670Fe+3     +1.000Al+3     -6.000H+     +4.000H4(SiO4)     +1.000H2O     
     log_k     0.54         #
     delta_h  -108.688      kJ/mol        #
     # Enthalpy of formation:             -6826.571     kJ/mol        


Beidellite-FeNa(hydrated)
Na0.33Fe0.66Al1.67Si3.67O10(OH)2:5H2O = +0.330Na+     +0.660Fe+3     +1.670Al+3     -7.320H+     +3.670H4(SiO4)     +2.320H2O     
     log_k     1.1          #
     delta_h  -155.786      kJ/mol        #
     # Enthalpy of formation:             -6880.703     kJ/mol        


Fe-Saponite-Na(hydrated)
Na0.33Fe3Al0.33Si3.67O10(OH)2:5H2O = +0.330Na+     +3.000Fe+2     +0.330Al+3     -7.320H+     +3.670H4(SiO4)     +2.320H2O     
     log_k     18.32        #
     delta_h  -175.662      kJ/mol        #
     # Enthalpy of formation:             -6377.031     kJ/mol        


Saponite-Na(hydrated)
Na0.33Mg3Al0.33Si3.67O10(OH)2:5H2O = +3.000Mg+2     +0.330Na+     +0.330Al+3     -7.320H+     +3.670H4(SiO4)     +2.320H2O     
     log_k     34.3         #
     delta_h  -273.873      kJ/mol        #
     # Enthalpy of formation:             -7409.82      kJ/mol        


Vermiculite-Na(hydrated)
Na0.85Mg3.00Si3.15Al0.85O10(OH)2:5H2O = +3.000Mg+2     +0.850Na+     +0.850Al+3     -9.400H+     +3.150H4(SiO4)     +4.400H2O     
     log_k     43.68        #
     delta_h  -359.36       kJ/mol        #
     # Enthalpy of formation:             -7563.982     kJ/mol        


ISCz-1(hyd)
(Na0.134K0.53)(Si3.565Al0.435)(Al1.717Fe0.05Fe0.017Mg0.218)O10(OH)2:2.966H2O = +0.218Mg+2     +0.530K+     +0.134Na+     +0.050Fe+3     +0.017Fe+2     +2.152Al+3     -7.740H+     +3.565H4(SiO4)     +0.706H2O     
     log_k     12.05        #
     delta_h  -216.866      kJ/mol        #
     # Enthalpy of formation:             -6624.35      kJ/mol        07GAI/BLA


ISCz-1(des)
(Na0.134K0.53)(Si3.565Al0.435)(Al1.717Fe0.05Fe0.017Mg0.218)O10(OH)2 = +0.218Mg+2     +0.530K+     +0.134Na+     +0.050Fe+3     +0.017Fe+2     +2.152Al+3     -7.740H+     +3.565H4(SiO4)     -2.260H2O     
     log_k     12.91        #
     delta_h  -232.234      kJ/mol        #
     # Enthalpy of formation:             -5761.21      kJ/mol        07GAI/BLA


Illite-Imt-2
(Na0.044K0.762)(Si3.387Al0.613)(Al1.427Fe0.292Fe0.084Mg0.241)O10(OH)2 = +0.241Mg+2     +0.762K+     +0.044Na+     +0.292Fe+3     +0.084Fe+2     +2.040Al+3     -8.452H+     +3.387H4(SiO4)     -1.548H2O     
     log_k     11.08        #
     delta_h  -229.127      kJ/mol        #
     # Enthalpy of formation:             -5712.93      kJ/mol        07GAI/BLA


Lepidocrocite
FeOOH = +1.000Fe+3     -3.000H+     +2.000H2O     
     log_k     0.75         #98DIA in 98CHI
     delta_h  -64.26        kJ/mol        #
     # Enthalpy of formation:             -556.4        kJ/mol        


Maghemite(ord)
Fe2O3 = +2.000Fe+3     -6.000H+     +3.000H2O     
     log_k     3.52         #98DIA in 98CHI
     delta_h  -149.69       kJ/mol        #
     # Enthalpy of formation:             -805.8        kJ/mol        


Maghemite(disord)
Fe2O3 = +2.000Fe+3     -6.000H+     +3.000H2O     
     log_k     3.31         #98DIA in 98CHI
     delta_h  -149.69       kJ/mol        #
     # Enthalpy of formation:             -805.8        kJ/mol        


Ferryhydrite
Fe(OH)3 = +1.000Fe+3     -3.000H+     +3.000H2O     
     log_k     1.19         #05GRI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


FeAl2O4(s)
FeAl2O4 = +1.000Fe+2     +2.000Al+3     -8.000H+     +4.000H2O     
     log_k     27.2         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Fe5(OH)(PO4)3(s)
Fe5(OH)(PO4)3 = +5.000Fe+2     -7.000H+     +3.000H2(PO4)-     +1.000H2O     
     log_k    -402.32       #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


FeO(s)
FeO = +1.000Fe+2     -2.000H+     +1.000H2O     
     log_k     13.37        #95ROB/HEM
     delta_h  -103.83       kJ/mol        #
     # Enthalpy of formation:             -272          kJ/mol        


Lawrencite
FeCl2 = +1.000Fe+2     +2.000Cl-     
     log_k     8.89         #
     delta_h  -82.46        kJ/mol        #
     # Enthalpy of formation:             -341.7        kJ/mol        95ROB/HEM


Fe(s)
Fe = +1.000Fe+2     +2.000e-     
     log_k     15.86        #95PAR/KHO in 98CHI
     delta_h  -90           kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        


Vivianite
Fe3(PO4)2:8H2O = +3.000Fe+2     -4.000H+     +2.000H2(PO4)-     +8.000H2O     
     log_k     3.12         #
     delta_h  -9.561        kJ/mol        #
     # Enthalpy of formation:             -5152.279     kJ/mol        


Magnetite
Fe3O4  = +2.000Fe+3     +1.000Fe+2     -8.000H+     +4.000H2O     
     log_k     10.41        #
     delta_h  -215.92       kJ/mol        #
     # Enthalpy of formation:             -1115.4       kJ/mol        88ONE


Fayalite
Fe2(SiO4)  = +2.000Fe+2     -4.000H+     +1.000H4(SiO4)     
     log_k     19.51        #
     delta_h  -163.054      kJ/mol        #
     # Enthalpy of formation:             -1478.14      kJ/mol        95ROB/HEM


Troilite
FeS  = +1.000Fe+2     -1.000H+     +1.000HS-     
     log_k    -5.31         #91DAV
     delta_h   2.015        kJ/mol        #
     # Enthalpy of formation:             -108.315      kJ/mol        


Mackinawite
FeS = +1.000Fe+2     -1.000H+     +1.000HS-     
     log_k    -3.6          #91DAV
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


FeS(am)
FeS = +1.000Fe+2     -1.000H+     +1.000HS-     
     log_k    -2.95         #91DAV
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ferroselite
FeSe2 = +1.000Fe+2     -2.000H+     -2.000e-     +2.000HSe-     
     log_k    -17.13        #05OLI/NOL
     delta_h   47.3         kJ/mol        #
     # Enthalpy of formation:             -108.7        kJ/mol        05OLI/NOL


Melanterite
FeSO4:7H2O  = +1.000Fe+2     +1.000SO4-2     +7.000H2O     
     log_k    -2.21         #90NOR/PLU
     delta_h   20.543       kJ/mol        #
     # Enthalpy of formation:             -3020.693     kJ/mol        


Fe7Se8(alfa)
Fe7Se8 = +7.000Fe+2     -8.000H+     -2.000e-     +8.000HSe-     
     log_k    -35.6         #
     delta_h  -52.1         kJ/mol        #
     # Enthalpy of formation:             -463.5        kJ/mol        05OLI/NOL


Fe3Se4(gamma)
Fe3Se4 = +3.000Fe+2     -4.000H+     -2.000e-     +4.000HSe-     
     log_k    -25.6         #
     delta_h   22.2         kJ/mol        #
     # Enthalpy of formation:             -235          kJ/mol        05OLI/NOL


Fe1.04Se(beta)
Fe1.04Se = +1.040Fe+2     -1.000H+     +0.080e-     +1.000HSe-     
     log_k    -3.4          #
     delta_h  -9.7          kJ/mol        #
     # Enthalpy of formation:             -69.6         kJ/mol        05OLI/NOL


Compreignacite
K2(UO2)6O4(OH)6:7H2O = +2.000K+     +17.000H2O     -14.000H+     +6.000UO2+2     
     log_k     35.8         #08GOR/FEI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Sodium-compreignacite
Na2(UO2)6O4(OH)6:7H2O = +2.000Na+     +6.000UO2+2     +17.000H2O     -14.000H+     
     log_k     39.4         #08GOR/FEI
     delta_h  -517.39       kJ/mol        #
     # Enthalpy of formation:             -10936.4      kJ/mol        06KUB/HEL


Clarkeite
Na(UO2)O(OH) = +1.000UO2+2     -3.000H+     +1.000Na+     +2.000H2O     
     log_k     9.4          #08GOR/FEI
     delta_h  -106.3        kJ/mol        #
     # Enthalpy of formation:             -1724.7       kJ/mol        06KUB/HEL


Chromite
FeCr2O4 = +1.000Fe+2     -8.000H+     +2.000Cr+3     +4.000H2O     
     log_k     15.12        #
     delta_h  -268.82       kJ/mol        #
     # Enthalpy of formation:             -1445.5       kJ/mol        95ROB/HEM


Chamosite
Fe5Al2Si3O10(OH)8 = +5.000Fe+2     +2.000Al+3     -16.000H+     +3.000H4(SiO4)     +6.000H2O     
     log_k     41.89        #
     delta_h  -472.892      kJ/mol        #
     # Enthalpy of formation:             -7152.471     kJ/mol        07VIE


Berthierine
Fe1.82Fe0.34Al0.67(Si1.33Al0.67O5)(OH)4 = +0.340Fe+3     +1.820Fe+2     +1.340Al+3     -8.680H+     +1.330H4(SiO4)     +3.680H2O     
     log_k     25.97        #
     delta_h  -302.108      kJ/mol        #
     # Enthalpy of formation:             -3595.051     kJ/mol        


Mn3(PO4)2:3H2O(s)
Mn3(PO4)2:3H2O = +3.000Mn+2     -4.000H+     +2.000H2(PO4)-     +3.000H2O     
     log_k     2.32         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Mn3(PO4)2(s)
Mn3(PO4)2 = +3.000Mn+2     -4.000H+     +2.000H2(PO4)-     
     log_k     15.32        #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


MnCl2:2H2O(s)
MnCl2:2H2O = +1.000Mn+2     +2.000Cl-     +2.000H2O     
     log_k     3.98         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


MnCl2:4H2O(s)
MnCl2:4H2O = +1.000Mn+2     +2.000Cl-     +4.000H2O     
     log_k     2.71         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


MnCl2:H2O(s)
MnCl2:H2O = +1.000Mn+2     +2.000Cl-     +1.000H2O     
     log_k     5.53         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Mn(HPO4)(s)
Mn(HPO4) = +1.000Mn+2     -1.000H+     +1.000H2(PO4)-     
     log_k    -5.74         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


MnO(s)
MnO = +1.000Mn+2     -2.000H+     +1.000H2O     
     log_k     17.9         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Mn(SO4)(s)
Mn(SO4) = +1.000Mn+2     +1.000SO4-2     
     log_k    -2.68         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Manganite
MnOOH = +1.000Mn+2     -3.000H+     -1.000e-     +2.000H2O     
     log_k     25.27        #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Sacchite
MnCl2  = +1.000Mn+2     +2.000Cl-     
     log_k     8.77         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


MnSe2(cr)
MnSe2 = +1.000Mn+2     -2.000H+     -2.000e-     +2.000HSe-     
     log_k    -8.15         #
     delta_h  -11.7         kJ/mol        #
     # Enthalpy of formation:             -180.5        kJ/mol        05OLI/NOL


Cu(cr)
Cu = +1.000Cu+2     +2.000e-     
     log_k    -11.39        #
     delta_h   64.9         kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        01LEM/FUG


Cu(SeO4):5H2O(s)
Cu(SeO4):5H2O = +1.000Cu+2     +1.000SeO4-2     +5.000H2O     
     log_k    -2.44         #05OLI/NOL
     delta_h   5.58         kJ/mol        #
     # Enthalpy of formation:             -1973.33      kJ/mol        05OLI/NOL


CuSe(beta)
CuSe = +1.000Cu+2     -1.000H+     +1.000HSe-     
     log_k    -25.13        #
     delta_h   116          kJ/mol        #
     # Enthalpy of formation:             -36.8         kJ/mol        05OLI/NOL


Ba(cr)
Ba = +1.000Ba+2     +2.000e-     
     log_k     97.7         #
     delta_h  -534.8        kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        92GRE/FUG


BaCl2:H2O(s)
BaCl2:H2O = +1.000Ba+2     +2.000Cl-     +1.000H2O     
     log_k     0.28         #
     delta_h   5.746        kJ/mol        #
     # Enthalpy of formation:             -1160.536     kJ/mol        


BaCl2:2H2O(s)
BaCl2:2H2O = +1.000Ba+2     +2.000Cl-     +2.000H2O     
     log_k    -0.34         #
     delta_h   19.418       kJ/mol        #
     # Enthalpy of formation:             -1460.038     kJ/mol        


BaHPO4(s)
BaHPO4 = +1.000Ba+2     -1.000H+     +1.000H2(PO4)-     
     log_k    -0.19         #66SPI/MIK in 76SMI/MAR
     delta_h  -22.8         kJ/mol        #
     # Enthalpy of formation:             -1814.6       kJ/mol        82WAG/EVA


BaS(s)
BaS = +1.000Ba+2     -1.000H+     +1.000HS-     
     log_k     15.66        #
     delta_h  -90.248       kJ/mol        #
     # Enthalpy of formation:             -460.852      kJ/mol        


U2O7Ba(cr)
U2O7Ba = +1.000Ba+2     +2.000UO2+2     -6.000H+     +3.000H2O     
     log_k     21.39        #
     delta_h  -193.09       kJ/mol        #
     # Enthalpy of formation:             -3237.2       kJ/mol        92GRE/FUG


U2O7Ba2(cr)
U2O7Ba2 = +2.000Ba+2     +2.000UO2+     -6.000H+     +3.000H2O     
     log_k     35.35        #
     delta_h  -237.344      kJ/mol        #
     # Enthalpy of formation:             -3740         kJ/mol        92GRE/FUG


UO6Ba3(cr)
UO6Ba3 = +3.000Ba+2     +1.000UO2+2     -8.000H+     +4.000H2O     
     log_k     92.7         #
     delta_h  -556.32       kJ/mol        #
     # Enthalpy of formation:             -3210.4       kJ/mol        92GRE/FUG


Ca3B2O6(s)
Ca3B2O6 = +3.000Ca+2     -4.000H+     +2.000B(OH)4-     -2.000H2O     
     log_k     40.58        #
     delta_h  -318.306      kJ/mol        #
     # Enthalpy of formation:             -3429.266     kJ/mol        


Dolomite
CaMg(CO3)2  = +1.000Ca+2     +1.000Mg+2     +2.000CO3-2     
     log_k    -17.12        #
     delta_h  -35.96        kJ/mol        #
     # Enthalpy of formation:             -2324.5       kJ/mol        95ROB/HEM


Cd(cr)
Cd = +1.000Cd+2     +2.000e-     
     log_k     13.62        #
     delta_h  -75.92        kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        89COX/WAG


Cd(SeCn)2(cr)
Cd(SeCn)2 = +1.000Cd+2     -2.000H+     -4.000e-     +2.000Cn-     +2.000HSe-     
     log_k    -31.75        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


CaO(cr)
CaO = +1.000Ca+2     -2.000H+     +1.000H2O     
     log_k     32.7         #
     delta_h  -193.91       kJ/mol        #
     # Enthalpy of formation:             -634.92       kJ/mol        89COX/WAG


Cd5(PO4)3Cl(cr)
Cd5(PO4)3Cl = +5.000Cd+2     -6.000H+     +1.000Cl-     +3.000H2(PO4)-     
     log_k     12.67        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Cd5(PO4)3OH(cr)
Cd5(PO4)3OH = +5.000Cd+2     -7.000H+     +3.000H2(PO4)-     +1.000H2O     
     log_k     19.84        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Cadmoselite
CdSe = +1.000Cd+2     -1.000H+     +1.000HSe-     
     log_k    -18.68        #
     delta_h   81.48        kJ/mol        #
     # Enthalpy of formation:             -143.1        kJ/mol        05OLI/NOL


CdCl2:2.5H2O(s)
CdCl2:2.5H2O = +1.000Cd+2     +2.000Cl-     +2.500H2O     
     log_k    -1.9          #
     delta_h   7.285        kJ/mol        #
     # Enthalpy of formation:             -1131.94      kJ/mol        82WAG/EVA


CdCl2:H2O(cr)
CdCl2:H2O = +1.000Cd+2     +2.000Cl-     +1.000H2O     
     log_k    -1.69         #
     delta_h  -7.47         kJ/mol        #
     # Enthalpy of formation:             -688.44       kJ/mol        82WAG/EVA


CdSiO3(cr)
CdSiO3 = +1.000Cd+2     -2.000H+     +1.000H4(SiO4)     -1.000H2O     
     log_k     7.79         #
     delta_h  -62.194       kJ/mol        #
     # Enthalpy of formation:             -1189.09      kJ/mol        77BAR/KNA


CdCl2(s)
CdCl2 = +1.000Cd+2     +2.000Cl-     
     log_k    -0.66         #
     delta_h  -18.58        kJ/mol        #
     # Enthalpy of formation:             -391.5        kJ/mol        74NAU/RYZ


Stilleite
ZnSe = +1.000Zn+2     -1.000H+     +1.000HSe-     
     log_k    -12.05        #
     delta_h   36.91        kJ/mol        #
     # Enthalpy of formation:             -176          kJ/mol        05OLI/NOL


NiCl2:2H2O(s)
NiCl2:2H2O = +1.000Ni+2     +2.000Cl-     +2.000H2O     
     log_k     4.92         #
     delta_h  -47.461       kJ/mol        #
     # Enthalpy of formation:             -913.371      kJ/mol        


Bunsenite
NiO  = +1.000Ni+2     -2.000H+     +1.000H2O     
     log_k     12.48        #
     delta_h  -101.142      kJ/mol        #
     # Enthalpy of formation:             -239.7        kJ/mol        05GAM/BUG


Ni2(Pyrophos)(cr)
Ni2(Pyrophos) = +2.000Ni+2     +1.000Pyrophos-4     
     log_k    -9.82         #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Millerite
NiS  = +1.000Ni+2     -1.000H+     +1.000HS-     
     log_k    -10.13        #
     delta_h   22.688       kJ/mol        #
     # Enthalpy of formation:             -94           kJ/mol        05GAM/BUG


Ni(CO3):5.5H2O(cr)
Ni(CO3):5.5H2O = +1.000Ni+2     +1.000CO3-2     +5.500H2O     
     log_k    -7.52         #
     delta_h   10.685       kJ/mol        #
     # Enthalpy of formation:             -2312.992     kJ/mol        05GAM/BUG


Ni3(AsO3)2(s)
Ni3(AsO3)2 = +3.000Ni+2     +4.000H+     +4.000e-     +2.000AsO4-3     -2.000H2O     
     log_k    -51.48        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ni3(AsO4)2:8H2O(s)
Ni3(AsO4)2:8H2O = +3.000Ni+2     +2.000AsO4-3     +8.000H2O     
     log_k    -28.1         #05GAM/BUG
     delta_h  -48.956       kJ/mol        #
     # Enthalpy of formation:             -4179         kJ/mol        05GAM/BUG


Ni(IO3)2(beta)
Ni(IO3)2 = +1.000Ni+2     +2.000IO3-     
     log_k    -4.43         #
     delta_h  -7.3          kJ/mol        #05GAM/BUG
     # Enthalpy of formation:             -487.112      kJ/mol        


Ni(IO3)2:2H2O(cr)
Ni(IO3)2:2H2O = +1.000Ni+2     +2.000IO3-     +2.000H2O     
     log_k    -5.14         #
     delta_h   21.6         kJ/mol        #05GAM/BUG
     # Enthalpy of formation:             -1087.672     kJ/mol        


NiSe2(cr)
NiSe2 = +1.000Ni+2     -2.000H+     -2.000e-     +2.000HSe-     
     log_k    -26.9         #
     delta_h   89.088       kJ/mol        #
     # Enthalpy of formation:             -115.5        kJ/mol        05OLI/NOL


Ni0.88Se(cr)
Ni0.88Se = +0.880Ni+2     -1.000H+     -0.240e-     +1.000HSe-     
     log_k    -12.76        #
     delta_h   35.689       kJ/mol        #
     # Enthalpy of formation:             -69.8         kJ/mol        05OLI/NOL


Minium
Pb3O4 = +3.000Pb+2     -8.000H+     -2.000e-     +4.000H2O     
     log_k     73.53        #
     delta_h  -421.874      kJ/mol        #
     # Enthalpy of formation:             -718.686      kJ/mol        


CoF2(s)
CoF2 = +1.000Co+2     +2.000F-     
     log_k    -1.39         #
     delta_h  -56.77        kJ/mol        #
     # Enthalpy of formation:             -671.53       kJ/mol        98CHA


CoCl2(s)
CoCl2 = +1.000Co+2     +2.000Cl-     
     log_k     8.47         #
     delta_h  -79.22        kJ/mol        #
     # Enthalpy of formation:             -312.54       kJ/mol        98CHA


CoCl2:6H2O(s)
CoCl2:6H2O = +1.000Co+2     +2.000Cl-     +6.000H2O     
     log_k     2.54         #97MAR/SMI
     delta_h   8.06         kJ/mol        #97MAR/SMI
     # Enthalpy of formation:             -2114.8       kJ/mol        


Co(FeO2)2(alpha)
Co(FeO2)2 = +2.000Fe+3     +1.000Co+2     -8.000H+     +4.000H2O     
     log_k     0.77         #
     delta_h  -159.2        kJ/mol        #
     # Enthalpy of formation:             -1139.72      kJ/mol        74NAU/RYZ


Ag3(PO4)(s)
Ag3(PO4) = +3.000Ag+     -2.000H+     +1.000H2(PO4)-     
     log_k     2.01         #03BÖT in 76SMI/MAR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ag2(SO4)(s)
Ag2(SO4) = +2.000Ag+     +1.000SO4-2     
     log_k    -5.01         #
     delta_h   18.162       kJ/mol        #
     # Enthalpy of formation:             -715.922      kJ/mol        


Ag(s)
Ag = +1.000Ag+     +1.000e-     
     log_k    -13.51        #
     delta_h   105.79       kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        95SIL/BID


Ag2Se(alfa)
Ag2Se = +2.000Ag+     -1.000H+     +1.000HSe-     
     log_k    -42.85        #
     delta_h   266.009      kJ/mol        #
     # Enthalpy of formation:             -40.129       kJ/mol        


Corundum
Al2O3 = +2.000Al+3     -6.000H+     +3.000H2O     
     log_k     18.3         #
     delta_h  -258.59       kJ/mol        #
     # Enthalpy of formation:             -1675.7       kJ/mol        89COX/WAG


Boehmite
AlO(OH) = +1.000Al+3     -3.000H+     +2.000H2O     
     log_k     7.62         #
     delta_h  -113.66       kJ/mol        #
     # Enthalpy of formation:             -996.4        kJ/mol        95ROB/HEM


Diaspore
AlO(OH) = +1.000Al+3     -3.000H+     +2.000H2O     
     log_k     6.86         #
     delta_h  -108.76       kJ/mol        #
     # Enthalpy of formation:             -1001.3       kJ/mol        95ROB/HEM


Dickite
Al2Si2O5(OH)4 = +2.000Al+3     -6.000H+     +2.000H4(SiO4)     +1.000H2O     
     log_k     9.39         #
     delta_h  -185.218      kJ/mol        #
     # Enthalpy of formation:             -4099.8       kJ/mol        03FIA/MAJ


Halloysite
Al2Si2O5(OH)4 = +2.000Al+3     -6.000H+     +2.000H4(SiO4)     +1.000H2O     
     log_k     10.32        #
     delta_h  -192.418      kJ/mol        #
     # Enthalpy of formation:             -4092.6       kJ/mol        99DEL/NAV


Pyrophillite
Al2Si4O10(OH)2 = +2.000Al+3     -6.000H+     +4.000H4(SiO4)     -4.000H2O     
     log_k    -0.44         #
     delta_h  -138.257      kJ/mol        #
     # Enthalpy of formation:             -5640         kJ/mol        95ROB/HEM


UO2(CO3)3Mg2:18H2O(s)
UO2(CO3)3Mg2:18H2O = +2.000Mg+2     +1.000UO2+2     +3.000CO3-2     +18.000H2O     
     log_k    -29.01        #
     delta_h   40.57        kJ/mol        #
     # Enthalpy of formation:             -9164.2       kJ/mol        99FAN/ROD


Microcline
KAlSi3O8 = +1.000K+     +1.000Al+3     -4.000H+     +3.000H4(SiO4)     -4.000H2O     
     log_k     0.05         #
     delta_h  -56.463       kJ/mol        #
     # Enthalpy of formation:             -3974.34      kJ/mol        00ARN/STE


Al(s)
Al = +1.000Al+3     +3.000e-     
     log_k     85.43        #
     delta_h  -538.4        kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        95POK/HEL


Cs2O(s)
Cs2O = +2.000Cs+     -2.000H+     +1.000H2O     
     log_k     89.68        #
     delta_h  -456.1        kJ/mol        #
     # Enthalpy of formation:             -345.73       kJ/mol        


Cs(s)
Cs = +1.000Cs+     +1.000e-     
     log_k     51.06        #
     delta_h  -258          kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        92GRE/FUG


Periclase
MgO = +1.000Mg+2     -2.000H+     +1.000H2O     
     log_k     21.58        #
     delta_h  -151.23       kJ/mol        #
     # Enthalpy of formation:             -601.6        kJ/mol        89COX/WAG


CsBr(cr)
CsBr = +1.000Cs+     +1.000Br-     
     log_k     0.72         #
     delta_h   26.19        kJ/mol        #
     # Enthalpy of formation:             -405.6        kJ/mol        01LEM/FUG


NpO2(NH4)4(CO3)3(s)
NpO2(NH4)4(CO3)3 = +1.000NpO2+2     +4.000H+     +3.000CO3-2     +4.000NH3     
     log_k    -26.81        #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


K4NpO2(CO3)3(s)
K4NpO2(CO3)3 = +4.000K+     +1.000NpO2+2     +3.000CO3-2     
     log_k    -26.4         #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


TcO2:1.63H2O(s)
TcO2:1.63H2O = +1.000TcO(OH)2     +0.630H2O     
     log_k    -8.4          #99RAR/RAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


TcCO3(OH)2(s)
TcCO3(OH)2 = +1.000TcO(OH)2     +2.000H+     +1.000CO3-2     -1.000H2O     
     log_k    -19.26        #99RAR/RAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Tc(cr)
Tc = +1.000TcO(OH)2     +4.000H+     +4.000e-     -3.000H2O     
     log_k    -25.08        #
     delta_h   108.17       kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        99RAR/RAN


Eu(cr)
Eu = +1.000Eu+3     +3.000e-     
     log_k     100.64       #
     delta_h  -605.331      kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        82WAG/EVA


Eu(OH)3(am)
Eu(OH)3 = +1.000Eu+3     -3.000H+     +3.000H2O     
     log_k     17.6         #98DIA/RAG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


EuO(s)
EuO = +1.000Eu+3     -2.000H+     +1.000e-     +1.000H2O     
     log_k     44.77        #
     delta_h  -299.121      kJ/mol        #
     # Enthalpy of formation:             -592.04       kJ/mol        


Eu2O3(cubic)
Eu2O3 = +2.000Eu+3     -6.000H+     +3.000H2O     
     log_k     52.4         #95SPA/BRU
     delta_h  -405.453      kJ/mol        #
     # Enthalpy of formation:             -1662.7       kJ/mol        82WAG/EVA


Eu3O4(s)
Eu3O4 = +3.000Eu+3     -8.000H+     +1.000e-     +4.000H2O     
     log_k     93.02        #
     delta_h  -689.314      kJ/mol        #
     # Enthalpy of formation:             -2270         kJ/mol        


Eu(OH)3(cr)
Eu(OH)3 = +1.000Eu+3     -3.000H+     +3.000H2O     
     log_k     15.46        #98DIA/RAG
     delta_h  -127.542      kJ/mol        #
     # Enthalpy of formation:             -1335.279     kJ/mol        


EuCl3(s)
EuCl3 = +1.000Eu+3     +3.000Cl-     
     log_k     19.72        #96FAL/REA
     delta_h  -170.571      kJ/mol        #
     # Enthalpy of formation:             -936          kJ/mol        82WAG/EVA


EuCl3:6H2O(s)
EuCl3:6H2O = +1.000Eu+3     +3.000Cl-     +6.000H2O     
     log_k     5.2          #95SPA/BRU
     delta_h  -41.414       kJ/mol        #
     # Enthalpy of formation:             -2780.137     kJ/mol        


EuOCl(s)
EuOCl = +1.000Eu+3     -2.000H+     +1.000Cl-     +1.000H2O     
     log_k     15.81        #95SPA/BRU
     delta_h  -154.741      kJ/mol        #
     # Enthalpy of formation:             -903.5        kJ/mol        


EuCl(OH)2(s)
EuCl(OH)2 = +1.000Eu+3     -2.000H+     +1.000Cl-     +2.000H2O     
     log_k     9.13         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


EuF3(s)
EuF3 = +1.000Eu+3     +3.000F-     
     log_k    -18.5         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


EuBr3(s)
EuBr3 = +1.000Eu+3     +3.000Br-     
     log_k     30.19        #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


EuF3:0.5H2O(s)
EuF3:0.5H2O = +1.000Eu+3     +3.000F-     +0.500H2O     
     log_k    -17.2         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


EuCl2(s)
EuCl2 = +1.000Eu+3     +1.000e-     +2.000Cl-     
     log_k     11.22        #95SPA/BRU
     delta_h  -115.491      kJ/mol        #
     # Enthalpy of formation:             -824          kJ/mol        82WAG/EVA


EuSO4(s)
EuSO4 = +1.000Eu+3     +1.000e-     +1.000SO4-2     
     log_k    -2.52         #95SPA/BRU
     delta_h  -92.864       kJ/mol        #
     # Enthalpy of formation:             -1421.807     kJ/mol        


Eu(NO3)3:6H2O(s)
Eu(NO3)3:6H2O = +1.000Eu+3     +3.000NO3-     +6.000H2O     
     log_k     1.84         #95SPA/BRU
     delta_h   16.839       kJ/mol        #
     # Enthalpy of formation:             -2957.7       kJ/mol        82WAG/EVA


Eu(PO4):xH2O(s)
Eu(PO4) = +1.000Eu+3     -2.000H+     +1.000H2(PO4)-     
     log_k    -4.84         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Eu(CO3)(OH):0.5H2O(s)
Eu(CO3)(OH):0.5H2O = +1.000Eu+3     -1.000H+     +1.000CO3-2     +1.500H2O     
     log_k    -7.8          #95SPA/BRU
     delta_h  -55.906       kJ/mol        #
     # Enthalpy of formation:             -1653.4       kJ/mol        05ROR/FUG


Eu(CO3)(OH)(cr)
Eu(CO3)(OH) = +1.000Eu+3     -1.000H+     +1.000CO3-2     +1.000H2O     
     log_k    -9.63         #
     delta_h  -43.391       kJ/mol        #
     # Enthalpy of formation:             -1523         kJ/mol        05ROR/FUG


EuPO4:H2O(cr)
EuPO4:H2O = +1.000Eu+3     -2.000H+     +1.000H2(PO4)-     +1.000H2O     
     log_k    -6.44         #97LIU/BYR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Eu2(SO4)3:8H2O(s)
Eu2(SO4)3:8H2O = +2.000Eu+3     +3.000SO4-2     +8.000H2O     
     log_k    -10.2         #95SPA/BRU
     delta_h  -90.974       kJ/mol        #
     # Enthalpy of formation:             -6134.348     kJ/mol        


Eu2O3(monoclinic)
Eu2O3 = +2.000Eu+3     -6.000H+     +3.000H2O     
     log_k     53.47        #
     delta_h  -418.514      kJ/mol        #
     # Enthalpy of formation:             -1649.638     kJ/mol        


Mg(SeO3):6H2O(s)
Mg(SeO3):6H2O = +1.000Mg+2     +1.000SeO3-2     +6.000H2O     
     log_k    -5.82         #05OLI/NOL
     delta_h   18.07        kJ/mol        #
     # Enthalpy of formation:             -2707.21      kJ/mol        05OLI/NOL


Magnesite(syn)
Mg(CO3) = +1.000Mg+2     +1.000CO3-2     
     log_k    -8.1          #
     delta_h  -28.93        kJ/mol        #
     # Enthalpy of formation:             -1113.3       kJ/mol        95ROB/HEM


Nesquehonite
Mg(CO3):3H2O = +1.000Mg+2     +1.000CO3-2     +3.000H2O     
     log_k    -5.1          #
     delta_h  -22.42        kJ/mol        #
     # Enthalpy of formation:             -1977.3       kJ/mol        73ROB/HEM


Lansfordite
Mg(CO3):5H2O = +1.000Mg+2     +1.000CO3-2     +5.000H2O     
     log_k    -5.04         #
     delta_h   2.89         kJ/mol        #
     # Enthalpy of formation:             -2574.27      kJ/mol        99KON/KON


Mg5(CO3)4(OH)2:4H2O(s)
Mg5(CO3)4(OH)2:4H2O = +5.000Mg+2     -2.000H+     +4.000CO3-2     +6.000H2O     
     log_k    -10.31        #
     delta_h  -234.9        kJ/mol        #
     # Enthalpy of formation:             -6516         kJ/mol        73ROB/HEM


Artinite
Mg2(CO3)(OH)2:3H2O = +2.000Mg+2     -2.000H+     +1.000CO3-2     +5.000H2O     
     log_k     9.81         #
     delta_h  -117.78       kJ/mol        #
     # Enthalpy of formation:             -2920.6       kJ/mol        73HEM/ROB


CsCl(cr)
CsCl  = +1.000Cs+     +1.000Cl-     
     log_k     1.55         #
     delta_h   17.23        kJ/mol        #
     # Enthalpy of formation:             -442.31       kJ/mol        01LEM/FUG


Sn(cr)
Sn = +1.000Sn+2     +2.000e-     
     log_k     4.84         #
     delta_h  -8.9          kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        


Sn(OH)Cl(s)
Sn(OH)Cl = +1.000Sn+2     -1.000H+     +1.000Cl-     +1.000H2O     
     log_k    -2.42         #30RAN/MUR recalculated in 99LOT/OCH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


SnSe2(s)
SnSe2 = +1.000Sn+2     -2.000H+     -2.000e-     +2.000HSe-     
     log_k    -30.75        #
     delta_h   134.6        kJ/mol        #
     # Enthalpy of formation:             -114.9        kJ/mol        05OLI/NOL


Cassiterite
SnO2 = +1.000Sn+4     -4.000H+     +2.000H2O     
     log_k    -7.51         #
     delta_h   36.47        kJ/mol        #
     # Enthalpy of formation:             -577.63       kJ/mol        89COX/WAG


CaSn(OH)6(s)
CaSn(OH)6 = +1.000Ca+2     +1.000Sn+4     -6.000H+     +6.000H2O     
     log_k     8.49         #99LOT/OCH
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Sr(SeO4)(s)
Sr(SeO4) = +1.000Sr+2     +1.000SeO4-2     
     log_k    -4.35         #Original source 59SEL/ZUB recalculated in 05OLI/NOL
     delta_h  -21.841       kJ/mol        #
     # Enthalpy of formation:             -1132.559     kJ/mol        


Th(cr)
Th = +1.000Th+4     +4.000e-     
     log_k     123.47       #
     delta_h  -768.7        kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        09RAN/FUG


SrO(cr)
SrO = +1.000Sr+2     -2.000H+     +1.000H2O     
     log_k     41.98        #
     delta_h  -244.69       kJ/mol        #
     # Enthalpy of formation:             -592.04       kJ/mol        98CHA


Sr(NO3)2:4H2O(s)
Sr(NO3)2:4H2O = +1.000Sr+2     +2.000NO3-     +4.000H2O     
     log_k    -0.87         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


SrS(s)
SrS = +1.000Sr+2     -1.000H+     +1.000HS-     
     log_k     14.68        # 
     delta_h  -93.57        kJ/mol        #
     # Enthalpy of formation:             -473.63       kJ/mol        82WAG/EVA


SrBr2:6H2O(s)
SrBr2:6H2O = +1.000Sr+2     +2.000Br-     +6.000H2O     
     log_k     2.82         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


SrBr2:H2O(s)
SrBr2:H2O = +1.000Sr+2     +2.000Br-     +1.000H2O     
     log_k     8.8          #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


SrBr2(s)
SrBr2 = +1.000Sr+2     +2.000Br-     
     log_k     12.5         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


SrCl2:2H2O(s)
SrCl2:2H2O = +1.000Sr+2     +2.000Cl-     +2.000H2O     
     log_k     3.47         #
     delta_h  -18.72        kJ/mol        #
     # Enthalpy of formation:             -1438         kJ/mol        82WAG/EVA


ThO2(mcr)
ThO2 = +1.000Th+4     -4.000H+     +2.000H2O     
     log_k     3            #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


UO2(Ox):3H2O(s)
UO2(Ox):3H2O = +1.000UO2+2     +1.000Ox-2     +3.000H2O     
     log_k    -8.93         #05HUM/AND
     delta_h  -5.15         kJ/mol        #
     # Enthalpy of formation:             -2702         kJ/mol        05HUM/AND


Uranophane 
Ca(UO2)2(SiO3OH)2:5H2O = +1.000Ca+2     +2.000UO2+2     -6.000H+     +2.000H4(SiO4)     +5.000H2O     
     log_k     9.42         #92NGU/SIL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Soddyite(synt1)
(UO2)2SiO4:2H2O = +2.000UO2+2     -4.000H+     +1.000H4(SiO4)     +2.000H2O     
     log_k     3.9          #97PER/CAS
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Soddyite(synt2)
(UO2)2SiO4:2H2O = +2.000UO2+2     -4.000H+     +1.000H4(SiO4)     +2.000H2O     
     log_k     6.43         #07GOR/MAZ
     delta_h  -25.454       kJ/mol        #
     # Enthalpy of formation:             -4045.4       kJ/mol        07GOR/MAZ


(UO2)3(PO4)2(cr)
(UO2)3(PO4)2 = +3.000UO2+2     -4.000H+     +2.000H2(PO4)-     
     log_k     2.8          #
     delta_h  -170.9        kJ/mol        #
     # Enthalpy of formation:             -5491.3       kJ/mol        92GRE/FUG


Bassetite
Fe(UO2)2(PO4)2 = +1.000Fe+2     +2.000UO2+2     -4.000H+     +2.000H2(PO4)-     
     log_k    -1.07         #65MUT/HIR
     delta_h  -36.464       kJ/mol        #
     # Enthalpy of formation:             -8996.928     kJ/mol        


Becquerelite(syn)
Ca(UO2)6O4(OH)6:8H2O = +1.000Ca+2     +6.000UO2+2     -14.000H+     +18.000H2O     
     log_k     40.5         #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Becquerelite(nat)
Ca(UO2)6O4(OH)6:8H2O = +1.000Ca+2     +6.000UO2+2     -14.000H+     +18.000H2O     
     log_k     29           #97CAS/BRU
     delta_h  -378.31       kJ/mol        #
     # Enthalpy of formation:             -11423.63     kJ/mol        99FAN/ROD


UO4Ba(s)
UO4Ba = +1.000Ba+2     +1.000UO2+2     -4.000H+     +2.000H2O     
     log_k     17.64        #
     delta_h  -131.66       kJ/mol        #
     # Enthalpy of formation:             -1993.8       kJ/mol        92GRE/FUG


CaU2O7:3H2O(cr)
CaU2O7:3H2O = +1.000Ca+2     +2.000UO2+2     -6.000H+     +6.000H2O     
     log_k     23.4         #05ALT/NEC
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


PuO2:2H2O(am)
PuO2:2H2O = +1.000Pu+4     -4.000H+     +4.000H2O     
     log_k    -2.37         #03GUI/FAN
     delta_h  -58.548       kJ/mol        #
     # Enthalpy of formation:             -1624.667     kJ/mol        


Pu(OH)4(am)
Pu(OH)4 = +1.000Pu+4     -4.000H+     +4.000H2O     
     log_k    -0.8          #89LEM/GAR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Pu(cr)
Pu = +1.000Pu+3     +3.000e-     
     log_k     101.43       #
     delta_h  -591.79       kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        01LEM/FUG


U(cr)
U = +1.000U+4     +4.000e-     
     log_k     92.83        #
     delta_h  -591.2        kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        92GRE/FUG


UO2:2H2O(am)
UO2:2H2O = +1.000U+4     -4.000H+     +4.000H2O     
     log_k     1.5          #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


UO2.25(s)
UO2.25 = +1.000U+4     -4.500H+     -0.500e-     +2.250H2O     
     log_k    -1            #
     delta_h  -106.318      kJ/mol        #
     # Enthalpy of formation:             -1128         kJ/mol        92GRE/FUG


UO2.34(beta)
UO2.34 = +1.000U+4     -4.680H+     -0.680e-     +2.340H2O     
     log_k     0.63         #
     delta_h  -117.127      kJ/mol        #
     # Enthalpy of formation:             -1141         kJ/mol        03GUI/FAN


UO2.67(s)
UO2.67 = +1.000U+4     -5.340H+     -1.340e-     +2.670H2O     
     log_k     6.85         #
     delta_h  -161.823      kJ/mol        #
     # Enthalpy of formation:             -1191.6       kJ/mol        92GRE/FUG


Coffinite(am)
U(SiO4)  = +1.000U+4     -4.000H+     +1.000H4(SiO4)     
     log_k    -1.5          #Estimation based on NEA Guidelines
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


PuO2(coll)
PuO2 = +1.000Pu+4     +2.000H2O     -4.000H+     
     log_k     0.2          #07NEC/ALT
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


SeU(cr)
SeU = +1.000U+4     -1.000H+     +2.000e-     +1.000HSe-     
     log_k     37.34        #
     delta_h  -304.9        kJ/mol        #
     # Enthalpy of formation:             -272          kJ/mol        05OLI/NOL


UO3Na(s)
UO3Na = +1.000Na+     +1.000UO2+     -2.000H+     +1.000H2O     
     log_k     8.34         #
     delta_h  -56.397       kJ/mol        #
     # Enthalpy of formation:             -1494.9       kJ/mol        92GRE/FUG


UO4Na3(cr)
UO4Na3 = +3.000Na+     +1.000UO2+     -4.000H+     +2.000H2O     
     log_k     56.28        #
     delta_h  -293.807      kJ/mol        #
     # Enthalpy of formation:             -2024         kJ/mol        92GRE/FUG


Np(cr)
Np = +1.000Np+3     +3.000e-     
     log_k     89.85        #
     delta_h  -527.184      kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        01LEM/FUG


NpO2OH(am,aged)
NpO2OH = +1.000NpO2+     -1.000H+     +1.000H2O     
     log_k     4.7          #01LEM/FUG
     delta_h  -41.111       kJ/mol        #
     # Enthalpy of formation:             -1222.9       kJ/mol        01LEM/FUG


NpO2OH(am,fresh)
NpO2OH = +1.000NpO2+     -1.000H+     +1.000H2O     
     log_k     5.3          #01LEM/FUG
     delta_h  -41.111       kJ/mol        #
     # Enthalpy of formation:             -1222.9       kJ/mol        01LEM/FUG


Np2O5(cr)
Np2O5 = +2.000NpO2+     -2.000H+     +1.000H2O     
     log_k     3.7          #
     delta_h  -79.492       kJ/mol        #
     # Enthalpy of formation:             -2162.7       kJ/mol        01LEM/FUG


NpO3:H2O(cr)
NpO3:H2O = +1.000NpO2+2     -2.000H+     +2.000H2O     
     log_k     5.47         #01LEM/FUG
     delta_h  -52.24        kJ/mol        #
     # Enthalpy of formation:             -1380.153     kJ/mol        


Sm(cr)
Sm = +1.000Sm+3     +3.000e-     
     log_k     116.62       #
     delta_h  -691.199      kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        79ROB/HEM


Sm2O3(s)
Sm2O3 = +2.000Sm+3     -6.000H+     +3.000H2O     
     log_k     43.11        #
     delta_h  -355.039      kJ/mol        #
     # Enthalpy of formation:             -1884.849     kJ/mol        


SmCl3:6H2O(s)
SmCl3:6H2O = +1.000Sm+3     +3.000Cl-     +6.000H2O     
     log_k     4.8          #96FAL/REA
     delta_h  -38.311       kJ/mol        #
     # Enthalpy of formation:             -2869.108     kJ/mol        


SmF3:0.5H2O(s)
SmF3:0.5H2O = +1.000Sm+3     +3.000F-     +0.500H2O     
     log_k    -17.5         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


SmOHCO3:0.5H2O(cr)
SmOHCO3:0.5H2O = +1.000Sm+3     -1.000H+     +1.000CO3-2     +1.500H2O     
     log_k    -7.31         #
     delta_h  -51.074       kJ/mol        #
     # Enthalpy of formation:             -1744.1       kJ/mol        05ROR/FUG


SmOHCO3(cr)
SmOHCO3 = +1.000Sm+3     -1.000H+     +1.000CO3-2     +1.000H2O     
     log_k    -10.23        #
     delta_h  -38.859       kJ/mol        #
     # Enthalpy of formation:             -1613.4       kJ/mol        05ROR/FUG


Sm2(SO4)3(s)
Sm2(SO4)3 = +2.000Sm+3     +3.000SO4-2     
     log_k    -9.8          #95SPA/BRU
     delta_h  -211.318      kJ/mol        #
     # Enthalpy of formation:             -3899.1       kJ/mol        82WAG/EVA


P(cr)
P = +6.000H+     +5.000e-     +1.000H2(PO4)-     -4.000H2O     
     log_k     33.04        #
     delta_h  -159.28       kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        89COX/WAG


Cd(SO4):2.67H2O(cr)
Cd(SO4):2.67H2O = +1.000Cd+2     +1.000SO4-2     +2.670H2O     
     log_k    -1.55         #
     delta_h  -20.126       kJ/mol        #
     # Enthalpy of formation:             -1728.3       kJ/mol        89COX/WAG


SmPO4:H2O(cr)
SmPO4:H2O = +1.000Sm+3     -2.000H+     +1.000H2(PO4)-     +1.000H2O     
     log_k    -6.67         #97LIU/BYR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


SmPO4:H2O(am)
SmPO4:H2O = +1.000Sm+3     -2.000H+     +1.000H2(PO4)-     +1.000H2O     
     log_k    -5            #05CET/WOO
     delta_h  -26.48        kJ/mol        #
     # Enthalpy of formation:             -2253.149     kJ/mol        05CET/WOO


Sm(OH)3(am)
Sm(OH)3 = +1.000Sm+3     -3.000H+     +3.000H2O     
     log_k     17.85        #98DIA/RAG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


UO2(CO3)3Na4(cr)
UO2(CO3)3Na4 = +4.000Na+     +1.000UO2+2     +3.000CO3-2     
     log_k    -27.18        #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Na(TcO4):4H2O(s)
Na(TcO4):4H2O = +1.000Na+     +1.000TcO4-     +4.000H2O     
     log_k     0.79         #99RAR/RAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


PdS(s)
PdS = -1.000H+     +1.000Pd+2     +1.000HS-     
     log_k    -46.86        #
     delta_h   244.293      kJ/mol        #
     # Enthalpy of formation:             -70.71        kJ/mol        74MIL


Pd(cr)
Pd = +1.000Pd+2     +2.000e-     
     log_k    -33.03        #43TEM/WAT
     delta_h   189.883      kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        


Am(cr)
Am = +1.000Am+3     +3.000e-     
     log_k     104.89       #
     delta_h  -616.7        kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        95SIL/BID


Am(CO3)(OH)(am)
Am(CO3)(OH) = -1.000H+     +1.000Am+3     +1.000CO3-2     +1.000H2O     
     log_k    -6.2          #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Am(CO3)(OH)(cr)
Am(CO3)(OH) = -1.000H+     +1.000Am+3     +1.000CO3-2     +1.000H2O     
     log_k    -11.51        #
     delta_h  -25.26        kJ/mol        #
     # Enthalpy of formation:             -1552.5       kJ/mol        05ROR/FUG


Ra(cr)
Ra = +1.000Ra+2     +2.000e-     
     log_k     98.44        #
     delta_h  -528.025      kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        82WAG/EVA


Ra(NO3)2(s)
Ra(NO3)2 = +1.000Ra+2     +2.000NO3-     
     log_k    -2.21         #
     delta_h   49.98        kJ/mol        #
     # Enthalpy of formation:             -991.706      kJ/mol        


Ra(SO4)(s)
Ra(SO4) = +1.000Ra+2     +1.000SO4-2     
     log_k    -10.26        #99SCH, 85LAN/RIE
     delta_h   38.91        kJ/mol        #
     # Enthalpy of formation:             -1476.275     kJ/mol        


RaCl2:2H2O(s)
RaCl2:2H2O = +1.000Ra+2     +2.000Cl-     +2.000H2O     
     log_k    -0.73         #
     delta_h   32.22        kJ/mol        #
     # Enthalpy of formation:             -1466.065     kJ/mol        


Ho(cr)
Ho = +1.000Ho+3     +3.000e-     
     log_k     118.31       #
     delta_h  -707.042      kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        82WAG/EVA


HoCl3:6H2O(s)
HoCl3:6H2O = +1.000Ho+3     +3.000Cl-     +6.000H2O     
     log_k     5.39         #95SPA/BRU
     delta_h  -43.855       kJ/mol        #
     # Enthalpy of formation:             -2879.407     kJ/mol        


HoF3:0.5H2O(s)
HoF3:0.5H2O = +1.000Ho+3     +3.000F-     +0.500H2O     
     log_k    -16.4         #95SPA/BRU
     delta_h  -149.007      kJ/mol        #
     # Enthalpy of formation:             -1707         kJ/mol        82WAG/EVA


Ho(OH)3(s)
Ho(OH)3 = -3.000H+     +1.000Ho+3     +3.000H2O     
     log_k     15.43        #98DIA/RAG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ho(PO4):xH2O(s)
Ho(PO4) = -2.000H+     +1.000Ho+3     +1.000H2(PO4)-     
     log_k    -4.64         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ho2O3(s)
Ho2O3 = -6.000H+     +2.000Ho+3     +3.000H2O     
     log_k     47.41        #
     delta_h  -390.718      kJ/mol        #
     # Enthalpy of formation:             -1880.856     kJ/mol        


Ho(OH)3(am)
Ho(OH)3 = -3.000H+     +1.000Ho+3     +3.000H2O     
     log_k     17.48        #98DIA/RAG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


HoPO4:H2O(cr)
HoPO4:H2O = -2.000H+     +1.000Ho+3     +1.000H2(PO4)-     +1.000H2O     
     log_k    -5.56         #97LIU/BYR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


AmO2OH(am)
AmO2OH = -1.000H+     +1.000AmO2+     +1.000H2O     
     log_k     5.3          #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ferrosilite
FeSiO3 = +1.000Fe+2     -2.000H+     +1.000H4(SiO4)     -1.000H2O     
     log_k     32.71        #95TRO: CEA, N.T.SESD n° 95/49, L. TROTIGNON avril 1996; Critique et sélection de données thermodynamiques en vue de modéliser les équilibres minéral - solution, rapport annuel 1995
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Pyrrhotite
Fe0.87S = +0.870Fe+2     -1.000H+     +1.000HS-     -0.260e-     
     log_k    -5.59         #
     delta_h   2.45         kJ/mol        #
     # Enthalpy of formation:             -97.5         kJ/mol        95ROB/HEM


Nb2O5(s)
Nb2O5 = +2.000H+     +2.000Nb(OH)6-     -7.000H2O     
     log_k    -28.38        #97PEI/NGU
     delta_h   52.4         kJ/mol        #97PEI/NGU
     # Enthalpy of formation:             -1902.92      kJ/mol        


Nb(cr)
Nb = +6.000H+     +1.000Nb(OH)6-     +5.000e-     -6.000H2O     
     log_k     41.82        #
     delta_h  -210.685      kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        82WAG/EVA


NaNbO3(s)
NaNbO3 = +1.000Na+     +1.000Nb(OH)6-     -3.000H2O     
     log_k    -3.66         #
     delta_h   7.504        kJ/mol        #
     # Enthalpy of formation:             -1316.013     kJ/mol        


Rhodochrosite
Mn(CO3) = +1.000Mn+2     +1.000CO3-2     
     log_k    -11.13        #NAGRA, TR 91-18; F.J. PEARSON, U. BERNER, W. HUMMEL; Nagra thermochemical data base, supplemental data 05/92 (provient de la base 0391 MINEQL- PSY)
     delta_h  -5.899        kJ/mol        #
     # Enthalpy of formation:             -890.081      kJ/mol        


PbI2(cr)
PbI2 = +1.000Pb+2     +2.000I-     
     log_k    -8.05         #
     delta_h   62.801       kJ/mol        #
     # Enthalpy of formation:             -175.441      kJ/mol        


Ba(SeO4)(cr)
Ba(SeO4) = +1.000Ba+2     +1.000SeO4-2     
     log_k    -7.56         #05OLI/NOL
     delta_h   5.7          kJ/mol        #
     # Enthalpy of formation:             -1144         kJ/mol        05OLI/NOL


Ho2(CO3)3(cr)
Ho2(CO3)3 = +2.000Ho+3     +3.000CO3-2     
     log_k    -33.8         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


BaCl2(cr)
BaCl2 = +1.000Ba+2     +2.000Cl-     
     log_k     2.3          #
     delta_h  -13.76        kJ/mol        #
     # Enthalpy of formation:             -855.2        kJ/mol        95SIL/BID


BaO(cr)
BaO = +1.000Ba+2     -2.000H+     +1.000H2O     
     log_k     48.07        #
     delta_h  -272.53       kJ/mol        #
     # Enthalpy of formation:             -548.1        kJ/mol        95SIL/BID


C(cr)
C = +6.000H+     +4.000e-     +1.000CO3-2     -3.000H2O     
     log_k    -32.15        #
     delta_h   182.26       kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        89COX/WAG


S(cr)
S = +8.000H+     +6.000e-     +1.000SO4-2     -4.000H2O     
     log_k    -35.84        #
     delta_h   233.98       kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        89COX/WAG


Si(cr)
Si = +4.000H+     +4.000e-     +1.000H4(SiO4)     -4.000H2O     
     log_k     63.19        #
     delta_h  -317.874      kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        89COX/WAG


Cristobalite
SiO2 = +1.000H4(SiO4)     -2.000H2O     
     log_k    -3.16         #
     delta_h   16.5         kJ/mol        #
     # Enthalpy of formation:             -906.034      kJ/mol        04FAB/SAX


H3Cit:H2O(cr)
H3Cit:H2O = +3.000H+     +1.000Cit-3     +1.000H2O     
     log_k    -12.94        #05HUM/AND
     delta_h   32.71        kJ/mol        #
     # Enthalpy of formation:             -1838.46      kJ/mol        


ZrBr4(cr)
ZrBr4 = +4.000Br-     +1.000Zr+4     
     log_k     38.52        #
     delta_h  -334.64       kJ/mol        #
     # Enthalpy of formation:             -759.5        kJ/mol        05BRO/CUR


ZrI4(cr)
ZrI4 = +4.000I-     +1.000Zr+4     
     log_k     44.59        #
     delta_h  -346.72       kJ/mol        #
     # Enthalpy of formation:             -488.9        kJ/mol        05BRO/CUR


AmCl6Cs2Na(cr)
AmCl6Cs2Na = +1.000Na+     +2.000Cs+     +1.000Am+3     +6.000Cl-     
     log_k     12.56        #
     delta_h  -59.72        kJ/mol        #
     # Enthalpy of formation:             -2315.8       kJ/mol        03GUI/FAN


HfO2(am)
HfO2 = -4.000H+     +1.000Hf+4     +2.000H2O     
     log_k     0.9          #01RAI/XIA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -1101.7       kJ/mol        98KAR/CHE


HfO2(cr)
HfO2 = -4.000H+     +1.000Hf+4     +2.000H2O     
     log_k    -5.6          #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -1117.63      kJ/mol        75KOR/USH


Hf(HPO4)2:H2O(s)
Hf(HPO4)2:H2O = -2.000H+     +2.000H2(PO4)-     +1.000Hf+4     +1.000H2O     
     log_k    -21.05        #25HEV/KIM recalculated
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -3481.6       kJ/mol        97KAR/CHE


Sb(cr)
Sb = +3.000H+     +3.000e-     +1.000Sb(OH)3     -3.000H2O     
     log_k    -11.67        #
     delta_h   83.6         kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        


Valentinite
Sb2O3 = +2.000Sb(OH)3     -3.000H2O     
     log_k    -8.48         #52GAY/GAY in 76BAE/MES
     delta_h   18.5         kJ/mol        #
     # Enthalpy of formation:             -708.77       kJ/mol        62MAH in 03ZOT/SHI


Stibnite
Sb2S3 = +3.000H+     +3.000HS-     +2.000Sb(OH)3     -6.000H2O     
     log_k    -56.03        #
     delta_h   269.695      kJ/mol        #
     # Enthalpy of formation:             -151.4        kJ/mol        95ROB/HEM


H4Edta(cr)
H4Edta = +4.000H+     +1.000Edta-4     
     log_k    -27.22        #05HUM/AND
     delta_h   55           kJ/mol        #
     # Enthalpy of formation:             -1759.8       kJ/mol        


Ni(SO4):6H2O(s)
Ni(SO4):6H2O = +1.000Ni+2     +1.000SO4-2     +6.000H2O     
     log_k    -2.25         #05GAM/BUG
     delta_h   4.485        kJ/mol        #05GAM/BUG
     # Enthalpy of formation:             -2683.817     kJ/mol        


Ni(SO4)(cr)
Ni(SO4) = +1.000Ni+2     +1.000SO4-2     
     log_k     4.75         #05GAM/BUG
     delta_h  -91.072       kJ/mol        #
     # Enthalpy of formation:             -873.28       kJ/mol        05GAM/BUG


Ni(s)
Ni = +1.000Ni+2     +2.000e-     
     log_k     8.02         #
     delta_h  -55.012       kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        05GAM/BUG


NiI2(s)
NiI2 = +1.000Ni+2     +2.000I-     
     log_k     9.61         #
     delta_h  -72.152       kJ/mol        #
     # Enthalpy of formation:             -96.42        kJ/mol        05GAM/BUG


NiBr2(s)
NiBr2 = +1.000Ni+2     +2.000Br-     
     log_k     10.17        #
     delta_h  -84.332       kJ/mol        #
     # Enthalpy of formation:             -213.5        kJ/mol        05GAM/BUG


Ni(BO2)2(s)
Ni(BO2)2 = +1.000Ni+2     +2.000B(OH)4-     -4.000H2O     
     log_k    -8.7          #92PEA/BER
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


B2O3(am)
B2O3 = +2.000H+     +2.000B(OH)4-     -5.000H2O     
     log_k    -10.63        #
     delta_h  -6.711        kJ/mol        #
     # Enthalpy of formation:             -1254.371     kJ/mol        


B(cr)
B = +4.000H+     +3.000e-     +1.000B(OH)4-     -4.000H2O     
     log_k     35.93        #
     delta_h  -201.796      kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        92GRE/FUG


CaB4O7(s)
CaB4O7 = +1.000Ca+2     +2.000H+     +4.000B(OH)4-     -9.000H2O     
     log_k    -23.44        #
     delta_h   9.373        kJ/mol        #
     # Enthalpy of formation:             -3360.367     kJ/mol        


B2O3(cr)
B2O3 = +2.000H+     +2.000B(OH)4-     -5.000H2O     
     log_k    -12.74        #
     delta_h   12.418       kJ/mol        #
     # Enthalpy of formation:             -1273.5       kJ/mol        01LEM/FUG


CaB2O4(s)
CaB2O4 = +1.000Ca+2     +2.000B(OH)4-     -4.000H2O     
     log_k    -2.18         #
     delta_h  -58.908       kJ/mol        #
     # Enthalpy of formation:             -2031.004     kJ/mol        


ZnB2O4(s)
ZnB2O4 = +1.000Zn+2     +2.000B(OH)4-     -4.000H2O     
     log_k    -10.19        #91BAL/NOR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


CdB2O4(s)
CdB2O4 = +1.000Cd+2     +2.000B(OH)4-     -4.000H2O     
     log_k    -8.64         #91BAL/NOR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


PbB2O4(s)
PbB2O4 = +1.000Pb+2     +2.000B(OH)4-     -4.000H2O     
     log_k    -10.87        #91BAL/NOR
     delta_h   2.761        kJ/mol        #91BAL/NOR
     # Enthalpy of formation:             -1548.753     kJ/mol        


Na2B4O7(cr)
Na2B4O7 = +2.000Na+     +2.000H+     +4.000B(OH)4-     -9.000H2O     
     log_k    -16.06        #
     delta_h   2.534        kJ/mol        #
     # Enthalpy of formation:             -3291.208     kJ/mol        


Na2B4O7:10H2O(s)
Na2B4O7:10H2O = +2.000Na+     +2.000H+     +4.000B(OH)4-     +1.000H2O     
     log_k    -24.58        #
     delta_h   141.721      kJ/mol        #
     # Enthalpy of formation:             -6288.445     kJ/mol        


Pb(SeO4)(s)
Pb(SeO4) = +1.000Pb+2     +1.000SeO4-2     
     log_k    -6.9          #05OLI/NOL
     delta_h   4.72         kJ/mol        #05OLI/NOL
     # Enthalpy of formation:             -607.3        kJ/mol        


Mo(s)
Mo = +8.000H+     +6.000e-     +1.000MoO4-2     -4.000H2O     
     log_k    -19.58        #
     delta_h   146.32       kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        82WAG/EVA


MoO2(s)
MoO2 = +4.000H+     +2.000e-     +1.000MoO4-2     -2.000H2O     
     log_k    -29.88        #
     delta_h   162.517      kJ/mol        #
     # Enthalpy of formation:             -587.857      kJ/mol        


MoO3(s)
MoO3 = +2.000H+     +1.000MoO4-2     -1.000H2O     
     log_k    -11.98        #
     delta_h   34.001       kJ/mol        #
     # Enthalpy of formation:             -745.171      kJ/mol        


H2MoO4(s)
H2MoO4 = +2.000H+     +1.000MoO4-2     
     log_k    -13.17        #
     delta_h   48.763       kJ/mol        #
     # Enthalpy of formation:             -1045.763     kJ/mol        


Mo3O8(s)
Mo3O8 = +8.000H+     +2.000e-     +3.000MoO4-2     -4.000H2O     
     log_k    -63.56        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


MoS2(s)
MoS2 = +6.000H+     +2.000e-     +2.000HS-     +1.000MoO4-2     -4.000H2O     
     log_k    -69.91        #
     delta_h   385.515      kJ/mol        #
     # Enthalpy of formation:             -271.795      kJ/mol        


MoS3(s)
MoS3 = +5.000H+     +3.000HS-     +1.000MoO4-2     -4.000H2O     
     log_k    -68.07        #
     delta_h   354.849      kJ/mol        #
     # Enthalpy of formation:             -257.429      kJ/mol        


Cs2MoO4(s)
Cs2MoO4 = +2.000Cs+     +1.000MoO4-2     
     log_k     2.21         #
     delta_h   1.581        kJ/mol        #
     # Enthalpy of formation:             -1514.581     kJ/mol        


Rb2MoO4(s)
Rb2MoO4 = +1.000MoO4-2     +2.000Rb+     
     log_k     3.1          #
     delta_h  -5.391        kJ/mol        #
     # Enthalpy of formation:             -1493.849     kJ/mol        


MgMoO4(s)
MgMoO4 = +1.000Mg+2     +1.000MoO4-2     
     log_k    -0.64         #
     delta_h  -62.967       kJ/mol        #
     # Enthalpy of formation:             -1401.033     kJ/mol        


CaMoO4(s)
CaMoO4 = +1.000Ca+2     +1.000MoO4-2     
     log_k    -7.9          #
     delta_h   1.424        kJ/mol        #
     # Enthalpy of formation:             -1541.424     kJ/mol        


SrMoO4(s)
SrMoO4 = +1.000Sr+2     +1.000MoO4-2     
     log_k    -6.59         #54RAO in 74OHA/KEN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


BaMoO4(s)
BaMoO4 = +1.000Ba+2     +1.000MoO4-2     
     log_k    -7.83         #
     delta_h   13.822       kJ/mol        #
     # Enthalpy of formation:             -1545.622     kJ/mol        


PbMoO4(s)
PbMoO4 = +1.000Pb+2     +1.000MoO4-2     
     log_k    -15.8         #
     delta_h   55.795       kJ/mol        #
     # Enthalpy of formation:             -1051.875     kJ/mol        


FeMoO4(s)
FeMoO4 = +1.000Fe+2     +1.000MoO4-2     
     log_k    -8.35         #
     delta_h  -11.534       kJ/mol        #
     # Enthalpy of formation:             -1075.466     kJ/mol        


As(s)
As = +8.000H+     +5.000e-     +1.000AsO4-3     -4.000H2O     
     log_k    -52.59        #
     delta_h   255.18       kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        92GRE/FUG


As2O5(s)
As2O5 = +6.000H+     +2.000AsO4-3     -3.000H2O     
     log_k    -34.54        #
     delta_h   6.08         kJ/mol        #
     # Enthalpy of formation:             -924.87       kJ/mol        92GRE/FUG


Claudetite
As2O3 = +10.000H+     +4.000e-     +2.000AsO4-3     -5.000H2O     
     log_k    -81.39        #
     delta_h   307.369      kJ/mol        #
     # Enthalpy of formation:             -654.499      kJ/mol        


Orpiment
As2S3 = +13.000H+     +4.000e-     +3.000HS-     +2.000AsO4-3     -8.000H2O     
     log_k    -127.46       #
     delta_h   552.683      kJ/mol        #
     # Enthalpy of formation:             -91.223       kJ/mol        


Realgar
AsS = +7.000H+     +3.000e-     +1.000HS-     +1.000AsO4-3     -4.000H2O     
     log_k    -67.06        #
     delta_h   310.286      kJ/mol        #
     # Enthalpy of formation:             -71.406       kJ/mol        


Ca(SeO3):H2O(s)
Ca(SeO3):H2O = +1.000Ca+2     +1.000SeO3-2     +1.000H2O     
     log_k    -6.4          #05OLI/NOL
     delta_h  -11.19        kJ/mol        #
     # Enthalpy of formation:             -1324.8       kJ/mol        05OLI/NOL


Cu(SeO3):2H2O(s)
Cu(SeO3):2H2O = +1.000Cu+2     +1.000SeO3-2     +2.000H2O     
     log_k    -9.5          #Average value from 56CHU and 93SLA/POP in 05OLI/NOL
     delta_h  -15.32        kJ/mol        #
     # Enthalpy of formation:             -998.6        kJ/mol        05OLI/NOL


Fe2(SeO3)3:6H2O(s)
Fe2(SeO3)3:6H2O = +2.000Fe+3     +3.000SeO3-2     +6.000H2O     
     log_k    -41.58        #05OLI/NOL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


HgSeO3(s)
HgSeO3 = +1.000Hg+2     +1.000SeO3-2     
     log_k    -16.2         #05OLI/NOL
     delta_h   36.65        kJ/mol        #
     # Enthalpy of formation:             -373.6        kJ/mol        05OLI/NOL


Downeyite
SeO2 = +2.000H+     +1.000SeO3-2     -1.000H2O     
     log_k    -8.15         #
     delta_h   4.06         kJ/mol        #
     # Enthalpy of formation:             -225.39       kJ/mol        05OLI/NOL


Tc2O7:H2O(s)
Tc2O7:H2O = +2.000H+     +2.000TcO4-     
     log_k     14.1         #
     delta_h  -44.654       kJ/mol        #
     # Enthalpy of formation:             -1414.146     kJ/mol        99RAR/RAN


Tc2O7(s)
Tc2O7 = +2.000H+     +2.000TcO4-     -1.000H2O     
     log_k     15.31        #
     delta_h  -46.47        kJ/mol        #
     # Enthalpy of formation:             -1126.5       kJ/mol        99RAR/RAN


K(TcO4)(s)
K(TcO4) = +1.000K+     +1.000TcO4-     
     log_k    -2.28         #
     delta_h   53.56        kJ/mol        #
     # Enthalpy of formation:             -1035.1       kJ/mol        99RAR/RAN


Cu2Se(alfa)
Cu2Se = +2.000Cu+     -1.000H+     +1.000HSe-     
     log_k    -45.89        #01SEB/POT
     delta_h   216.94       kJ/mol        #
     # Enthalpy of formation:             -59.3         kJ/mol        05OLI/NOL


CuSe(alfa)
CuSe = +1.000Cu+2     -1.000H+     +1.000HSe-     
     log_k    -25.46        #
     delta_h   118.7        kJ/mol        #
     # Enthalpy of formation:             -39.5         kJ/mol        05OLI/NOL


Tiemannite
HgSe = +1.000Hg+2     -1.000H+     +1.000HSe-     
     log_k    -45.43        #
     delta_h   241.521      kJ/mol        #
     # Enthalpy of formation:             -57.011       kJ/mol        


MnSe(alfa)
MnSe = +1.000Mn+2     -1.000H+     +1.000HSe-     
     log_k     0.3          #
     delta_h  -28.579       kJ/mol        #
     # Enthalpy of formation:             -177.921      kJ/mol        


PdSe(s)
PdSe = -1.000H+     +1.000Pd+2     +1.000HSe-     
     log_k    -49.11        #
     delta_h   254.463      kJ/mol        #
     # Enthalpy of formation:             -50.28        kJ/mol        74MIL


SnSe(alfa)
SnSe = +1.000Sn+2     -1.000H+     +1.000HSe-     
     log_k    -21.63        #
     delta_h   114.9        kJ/mol        #
     # Enthalpy of formation:             -109.5        kJ/mol        05OLI/NOL


Se(s)
Se = -1.000H+     -2.000e-     +1.000HSe-     
     log_k    -7.62         #
     delta_h   14.3         kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        92GRE/FUG


Se3U(cr)
Se3U = +1.000UO2+2     +1.000H+     +3.000HSe-     -2.000H2O     
     log_k    -18.27        #
     delta_h   47.56        kJ/mol        #
     # Enthalpy of formation:             -452          kJ/mol        92GRE/FUG


Ag(SeCn)(cr)
Ag(SeCn) = +1.000Ag+     -1.000H+     -2.000e-     +1.000Cn-     +1.000HSe-     
     log_k    -27.03        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ag2(SeO4)(s)
Ag2(SeO4) = +2.000Ag+     +1.000SeO4-2     
     log_k    -7.86         #05OLI/NOL
     delta_h   30.59        kJ/mol        #
     # Enthalpy of formation:             -422.51       kJ/mol        05OLI/NOL


Mg(SeO4):6H2O(s)
Mg(SeO4):6H2O = +1.000Mg+2     +1.000SeO4-2     +6.000H2O     
     log_k    -1.133        #05OLI/NOL
     delta_h  -4.08         kJ/mol        #
     # Enthalpy of formation:             -2781.4       kJ/mol        05OLI/NOL


SeO3(cr)
SeO3 = +2.000H+     +1.000SeO4-2     -1.000H2O     
     log_k     20.36        #
     delta_h  -154.57       kJ/mol        #
     # Enthalpy of formation:             -163.1        kJ/mol        05OLI/NOL


Zn(SeO4):6H2O(s)
Zn(SeO4):6H2O = +1.000Zn+2     +1.000SeO4-2     +6.000H2O     
     log_k    -1.538        #05OLI/NOL
     delta_h  -13.33        kJ/mol        #
     # Enthalpy of formation:             -2458.54      kJ/mol        05OLI/NOL


Ni(SeO4):6H2O(s)
Ni(SeO4):6H2O = +1.000Ni+2     +1.000SeO4-2     +6.000H2O     
     log_k    -1.381        #05OLI/NOL
     delta_h  -3.787        kJ/mol        #
     # Enthalpy of formation:             -2369.705     kJ/mol        


Calcite
CaCO3  = +1.000Ca+2     +1.000CO3-2     
     log_k    -8.48         #82PLUM/BUS
     delta_h  -10.62        kJ/mol        #82PLUM/BUS
     # Enthalpy of formation:             -1207.61      kJ/mol        


Aragonite
CaCO3  = +1.000Ca+2     +1.000CO3-2     
     log_k    -8.31         #
     delta_h  -10.454       kJ/mol        #
     # Enthalpy of formation:             -1207.776     kJ/mol        87GAR/PAR


Vaterite
CaCO3 = +1.000Ca+2     +1.000CO3-2     
     log_k    -7.9          #
     delta_h  -14.93        kJ/mol        #
     # Enthalpy of formation:             -1203.3       kJ/mol        87GAR/PAR


Anhydrite
Ca(SO4)  = +1.000Ca+2     +1.000SO4-2     
     log_k    -4.44         #
     delta_h  -17.94        kJ/mol        #
     # Enthalpy of formation:             -1434.4       kJ/mol        95ROB/HEM


Hydroxyapatite
Ca5(OH)(PO4)3 = +5.000Ca+2     -7.000H+     +3.000H2(PO4)-     +1.000H2O     
     log_k     0.35         #84NAN
     delta_h  -98.575       kJ/mol        #
     # Enthalpy of formation:             -6810.055     kJ/mol        


Fluorapatite
Ca5F(PO4)3 = +5.000Ca+2     -6.000H+     +1.000F-     +3.000H2(PO4)-     
     log_k    -0.91         #74HAG
     delta_h  -115.603      kJ/mol        #
     # Enthalpy of formation:             -6842.547     kJ/mol        


Brushite
Ca(HPO4):2H2O = +1.000Ca+2     -1.000H+     +1.000H2(PO4)-     +2.000H2O     
     log_k     0.6          #84NAN
     delta_h  -7.375        kJ/mol        #
     # Enthalpy of formation:             -2409.885     kJ/mol        


Ca3(PO4)2(alfa)
Ca3(PO4)2 = +3.000Ca+2     -4.000H+     +2.000H2(PO4)-     
     log_k     10.22        #84NAN
     delta_h  -125.3        kJ/mol        #
     # Enthalpy of formation:             -4108.9       kJ/mol        


Ca2(Pyrophos)(s)
Ca2(Pyrophos) = +2.000Ca+2     +1.000Pyrophos-4     
     log_k    -15.5         #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ca(SO3)(s)
Ca(SO3) = +1.000Ca+2     +1.000SO3-2     
     log_k    -6.5          #NAGRA, TR 91-18; F.J. PEARSON, U. BERNER, W. HUMMEL; Nagra thermochemical data base, supplemental data 05/92 (provient de la base 0391 MINEQL- PSY)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ca3(AsO4)2(s)
Ca3(AsO4)2 = +3.000Ca+2     +2.000AsO4-3     
     log_k    -18.9         #
     delta_h  -106.866      kJ/mol        #
     # Enthalpy of formation:             -3298.413     kJ/mol        


Rb(s)
Rb = +1.000e-     +1.000Rb+     
     log_k     49.76        #
     delta_h  -251.12       kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        92GRE/FUG


Al(PO4)(cr)
Al(PO4) = +1.000Al+3     -2.000H+     +1.000H2(PO4)-     
     log_k    -2.94         #NAGRA, TR 91-18; F.J. PEARSON, U. BERNER, W. HUMMEL; Nagra thermochemical data base, supplemental data 05/92 (provient de la base 0391 MINEQL- PSY)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:             -1822.8       kJ/mol        


Berlinite
Al(PO4) = +1.000Al+3     -2.000H+     +1.000H2(PO4)-     
     log_k    -0.57         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ca(SeO4):2H2O(s)
Ca(SeO4):2H2O = +1.000Ca+2     +1.000SeO4-2     +2.000H2O     
     log_k    -2.68         #05OLI/NOL
     delta_h  -9.16         kJ/mol        #
     # Enthalpy of formation:             -1709         kJ/mol        05OLI/NOL


Portlandite
Ca(OH)2 = +1.000Ca+2     -2.000H+     +2.000H2O     
     log_k     22.81        #07BLA/BOU
     delta_h  -130.107      kJ/mol        #
     # Enthalpy of formation:             -984.553      kJ/mol        


MgF2(cr)
MgF2 = +1.000Mg+2     +2.000F-     
     log_k    -9.22         #92GRE/FUG
     delta_h  -13.5         kJ/mol        #
     # Enthalpy of formation:             -1124.2       kJ/mol        


Mg(HPO4):3H2O(s)
Mg(HPO4):3H2O = +1.000Mg+2     -1.000H+     +1.000H2(PO4)-     +3.000H2O     
     log_k     1.41         #01WEN/MUS
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Mg3(PO4)2(cr)
Mg3(PO4)2 = +3.000Mg+2     -4.000H+     +2.000H2(PO4)-     
     log_k     15.82        #68RAC/SOP
     delta_h  -214.093      kJ/mol        #
     # Enthalpy of formation:             -3792.107     kJ/mol        


Mg3(PO4)2:8H2O(s)
Mg3(PO4)2:8H2O = +3.000Mg+2     -4.000H+     +2.000H2(PO4)-     +8.000H2O     
     log_k     13.9         #63TAY/FRA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Mg3(PO4)2:22H2O(s)
Mg3(PO4)2:22H2O = +3.000Mg+2     -4.000H+     +2.000H2(PO4)-     +22.000H2O     
     log_k     16           #63TAY/FRA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Brucite
Mg(OH)2 = +1.000Mg+2     -2.000H+     +2.000H2O     
     log_k     17.1         #03ALT/MET
     delta_h  -114.16       kJ/mol        #
     # Enthalpy of formation:             -924.5        kJ/mol        95ROB/HEM


Sr(OH)2(s)
Sr(OH)2 = +1.000Sr+2     -2.000H+     +2.000H2O     
     log_k     27.51        #
     delta_h  -153.67       kJ/mol        #
     # Enthalpy of formation:             -968.89       kJ/mol        98CHA


Strontianite
Sr(CO3)  = +1.000Sr+2     +1.000CO3-2     
     log_k    -9.27         #84BUS/PLU
     delta_h  -0.366        kJ/mol        #
     # Enthalpy of formation:             -1225.764     kJ/mol        


Celestite
Sr(SO4) = +1.000Sr+2     +1.000SO4-2     
     log_k    -6.62         #06BLA/ING
     delta_h  -2.451        kJ/mol        #
     # Enthalpy of formation:             -1457.788     kJ/mol        


SrCl2(s)
SrCl2 = +1.000Sr+2     +2.000Cl-     
     log_k     8.12         #
     delta_h  -56.21        kJ/mol        #
     # Enthalpy of formation:             -828.85       kJ/mol        98CHA


SrCl2:H2O(s)
SrCl2:H2O = +1.000Sr+2     +2.000Cl-     +1.000H2O     
     log_k     4.91         #
     delta_h  -34.09        kJ/mol        #
     # Enthalpy of formation:             -1136.8       kJ/mol        82WAG/EVA


SrCl2:6H2O(s)
SrCl2:6H2O = +1.000Sr+2     +2.000Cl-     +6.000H2O     
     log_k     1.61         #
     delta_h   23.76        kJ/mol        #
     # Enthalpy of formation:             -2623.8       kJ/mol        82WAG/EVA


SrF2(cr)
SrF2 = +1.000Sr+2     +2.000F-     
     log_k    -8.54         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Sr(HPO4)(s)
Sr(HPO4) = +1.000Sr+2     -1.000H+     +1.000H2(PO4)-     
     log_k     0.28         #97MAR/SMI
     delta_h  -19.487       kJ/mol        #
     # Enthalpy of formation:             -1834.012     kJ/mol        


Sr3(PO4)2(s)
Sr3(PO4)2 = +3.000Sr+2     -4.000H+     +2.000H2(PO4)-     
     log_k     10.53        #06BLA/ING
     delta_h  -147.9        kJ/mol        #
     # Enthalpy of formation:             -4110         kJ/mol        97KHA/JEM


Sr3(AsO4)2(s)
Sr3(AsO4)2 = +3.000Sr+2     +2.000AsO4-3     
     log_k    -16.08        #
     delta_h  -109.493      kJ/mol        #
     # Enthalpy of formation:             -3319.487     kJ/mol        


Sr(SeO3)(cr)
Sr(SeO3) = +1.000Sr+2     +1.000SeO3-2     
     log_k    -6.3          #05OLI/NOL
     delta_h  -6.16         kJ/mol        #
     # Enthalpy of formation:             -1051.9       kJ/mol        05OLI/NOL


Sr(NO3)2(cr)
Sr(NO3)2 = +1.000Sr+2     +2.000NO3-     
     log_k     0.4          #
     delta_h   17.76        kJ/mol        #
     # Enthalpy of formation:             -982.36       kJ/mol        92GRE/FUG


Sr(NO3)2:2H2O(s)
Sr(NO3)2:2H2O = +1.000Sr+2     +2.000NO3-     +2.000H2O     
     log_k     0.05         #25/08/1994
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Fe(PO4)(cr)
Fe(PO4) = +1.000Fe+3     -2.000H+     +1.000H2(PO4)-     
     log_k    -6.24         #NAGRA, TR 91-18; F.J. PEARSON, U. BERNER, W. HUMMEL; Nagra thermochemical data base, supplemental data 05/92 (provient de la base 0391 MINEQL- PSY)
     delta_h  -18.6         kJ/mol        #
     # Enthalpy of formation:             -1333         kJ/mol        


Ferrihydrite(am)
Fe(OH)3 = +1.000Fe+3     -3.000H+     +3.000H2O     
     log_k     2.54         #63SCH/MIC
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Goethite
FeOOH = +1.000Fe+3     -3.000H+     +2.000H2O     
     log_k     0.39         #63SCH/MIC
     delta_h  -61.522       kJ/mol        #
     # Enthalpy of formation:             -559.124      kJ/mol        


Hematite
Fe2O3 = +2.000Fe+3     -6.000H+     +3.000H2O     
     log_k    -1.02         #05GRI
     delta_h  -123.679      kJ/mol        #
     # Enthalpy of formation:             -831.811      kJ/mol        


Siderite
Fe(CO3) = +1.000Fe+2     +1.000CO3-2     
     log_k    -10.8         #92BRU/WER
     delta_h  -12.012       kJ/mol        #
     # Enthalpy of formation:             -753.218      kJ/mol        


Fe(OH)2(cr)
Fe(OH)2 = +1.000Fe+2     -2.000H+     +2.000H2O     
     log_k     12.76        #
     delta_h  -99.056       kJ/mol        #
     # Enthalpy of formation:             -574.011      kJ/mol        


Rhodochrosite(syn)
Mn(CO3) = +1.000Mn+2     +1.000CO3-2     
     log_k    -10.52        #
     delta_h  -6.792        kJ/mol        #
     # Enthalpy of formation:             -889.188      kJ/mol        92JOH


Alabandite
MnS = +1.000Mn+2     -1.000H+     +1.000HS-     
     log_k     0.9          #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Mn2(Pyrophos)(s)
Mn2(Pyrophos) = +2.000Mn+2     +1.000Pyrophos-4     
     log_k    -19.5         #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Mn(H2SiO4)(s)
Mn(H2SiO4) = +1.000Mn+2     -2.000H+     +1.000H4(SiO4)     
     log_k     12.44        #88CHA/NEW
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Mn(SeO3):2H2O(cr)
Mn(SeO3):2H2O = +1.000Mn+2     +1.000SeO3-2     +2.000H2O     
     log_k    -7.6          #05OLI/NOL
     delta_h  -18.92        kJ/mol        #
     # Enthalpy of formation:             -1280.7       kJ/mol        05OLI/NOL


Pyrochroite
Mn(OH)2  = +1.000Mn+2     -2.000H+     +2.000H2O     
     log_k     15.3         #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Cu3(AsO4)2(s)
Cu3(AsO4)2 = +3.000Cu+2     +2.000AsO4-3     
     log_k    -34.88        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ba(OH)2:8H2O(cr)
Ba(OH)2:8H2O = +1.000Ba+2     -2.000H+     +10.000H2O     
     log_k     23.87        #
     delta_h  -52.509       kJ/mol        #
     # Enthalpy of formation:             -3340.591     kJ/mol        


Witherite
Ba(CO3) = +1.000Ba+2     +1.000CO3-2     
     log_k    -8.56         #86BUS/PLU
     delta_h   2.941        kJ/mol        #86BUS/PLU
     # Enthalpy of formation:             -1212.971     kJ/mol        


Barite
Ba(SO4) = +1.000Ba+2     +1.000SO4-2     
     log_k    -9.97         #85LAN/MEL in 90NOR/PLU
     delta_h   26.46        kJ/mol        #85LAN/MEL in 90NOR/PLU
     # Enthalpy of formation:             -1470.6       kJ/mol        


BaF2(cr)
BaF2 = +1.000Ba+2     +2.000F-     
     log_k    -6.32         #
     delta_h   1.631        kJ/mol        #
     # Enthalpy of formation:             -1207.131     kJ/mol        


Ba(SeO3)(s)
Ba(SeO3) = +1.000Ba+2     +1.000SeO3-2     
     log_k    -6.5          #05OLI/NOL
     delta_h  -5.26         kJ/mol        #
     # Enthalpy of formation:             -1036.7       kJ/mol        05OLI/NOL


Cd(CO3)(s)
Cd(CO3) = +1.000Cd+2     +1.000CO3-2     
     log_k    -12.1         #91RAI/FEL
     delta_h   1.482        kJ/mol        #
     # Enthalpy of formation:             -752.632      kJ/mol        


CdS(s)
CdS = +1.000Cd+2     -1.000H+     +1.000HS-     
     log_k    -14.82        #99WAN/TES
     delta_h   56.57        kJ/mol        #
     # Enthalpy of formation:             -148.79       kJ/mol        06DEO/WAV


Pa(cr)
Pa = +4.000e-     +1.000Pa+4     
     log_k     98.75        #
     delta_h  -620          kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        85BAR/PAR


PaO2(s)
PaO2 = -4.000H+     +1.000Pa+4     +2.000H2O     
     log_k     0.6          #76BAE/MES
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Pa2O5(s)
Pa2O5 = -2.000H+     +2.000PaO2+     +1.000H2O     
     log_k    -4            #76BAE/MES
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Hg2SeO3(s)
Hg2SeO3 = +1.000SeO3-2     +1.000Hg2+2     
     log_k    -15.2         #05OLI/NOL
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Zr(cr)
Zr = +4.000e-     +1.000Zr+4     
     log_k     92.59        #
     delta_h  -608.5        kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        05BRO/CUR


ZrO2(cr)
ZrO2 = -4.000H+     +1.000Zr+4     +2.000H2O     
     log_k    -7            #
     delta_h  -79.56        kJ/mol        #
     # Enthalpy of formation:             -1100.6       kJ/mol        05BRO/CUR


Zr(OH)4(am,fresh)
Zr(OH)4 = -4.000H+     +1.000Zr+4     +4.000H2O     
     log_k    -3.24         #05BRO/CUR
     delta_h  -89.62        kJ/mol        #
     # Enthalpy of formation:             -1662.2       kJ/mol        05BRO/CUR


Zr(OH)4(am,aged)
Zr(OH)4 = -4.000H+     +1.000Zr+4     +4.000H2O     
     log_k    -5.55         #Recalculated from 04EKB/KAL in 05BRO/CUR
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


ZrSiO4(s)
ZrSiO4 = -4.000H+     +1.000H4(SiO4)     +1.000Zr+4     
     log_k    -14.36        #
     delta_h  -35.494       kJ/mol        #
     # Enthalpy of formation:             -2034.2       kJ/mol        05BRO/CUR


Zr(SO4)2(cr)
Zr(SO4)2 = +2.000SO4-2     +1.000Zr+4     
     log_k     1.24         #
     delta_h  -181.98       kJ/mol        #
     # Enthalpy of formation:             -2245.2       kJ/mol        05BRO/CUR


Zr(SO4)2:4H2O(s)
Zr(SO4)2:4H2O = +2.000SO4-2     +1.000Zr+4     +4.000H2O     
     log_k    -7.65         #
     delta_h  -99.6         kJ/mol        #
     # Enthalpy of formation:             -3470.9       kJ/mol        05BRO/CUR


ZrF2(s)
ZrF2 = +2.000e-     +2.000F-     +1.000Zr+4     
     log_k     32.61        #
     delta_h  -323.2        kJ/mol        #
     # Enthalpy of formation:             -956          kJ/mol        97VIS/COR


ZrF3(s)
ZrF3 = +1.000e-     +3.000F-     +1.000Zr+4     
     log_k     2.8          #
     delta_h  -181.55       kJ/mol        #
     # Enthalpy of formation:             -1433         kJ/mol        97VIS/COR


ZrF4(beta)
ZrF4 = +4.000F-     +1.000Zr+4     
     log_k    -27.25        #
     delta_h  -38.6         kJ/mol        #
     # Enthalpy of formation:             -1911.3       kJ/mol        05BRO/CUR


ZrCl(s)
ZrCl = +3.000e-     +1.000Cl-     +1.000Zr+4     
     log_k     69.24        #
     delta_h  -484.38       kJ/mol        #
     # Enthalpy of formation:             -291.2        kJ/mol        05BRO/CUR


ZrCl2(s)
ZrCl2 = +2.000e-     +2.000Cl-     +1.000Zr+4     
     log_k     51.65        #
     delta_h  -399.86       kJ/mol        #
     # Enthalpy of formation:             -542.8        kJ/mol        05BRO/CUR


ZrCl3(s)
ZrCl3 = +1.000e-     +3.000Cl-     +1.000Zr+4     
     log_k     40.72        #
     delta_h  -349.64       kJ/mol        #
     # Enthalpy of formation:             -760.1        kJ/mol        05BRO/CUR


ZrCl4(s)
ZrCl4 = +4.000Cl-     +1.000Zr+4     
     log_k     28.6         #
     delta_h  -296.02       kJ/mol        #
     # Enthalpy of formation:             -980.8        kJ/mol        05BRO/CUR


Zr(HPO4)2(alfa)
Zr(HPO4)2 = -2.000H+     +2.000H2(PO4)-     +1.000Zr+4     
     log_k    -32.27        #
     delta_h  -47.5         kJ/mol        #
     # Enthalpy of formation:             -3166.2       kJ/mol        05BRO/CUR


Ca2ZrSi3O12(cr)
Ca2ZrSi3O12 = +2.000Ca+2     -12.000H+     -4.000e-     +3.000H4(SiO4)     +1.000Zr+4     
     log_k    -68.27        #
     delta_h   204.918      kJ/mol        #
     # Enthalpy of formation:             -6283         kJ/mol        05BRO/CUR


Ca3ZrSi2O9(cr)
Ca3ZrSi2O9 = +3.000Ca+2     -10.000H+     +2.000H4(SiO4)     +1.000Zr+4     +1.000H2O     
     log_k     47.87        #
     delta_h  -416.718      kJ/mol        #
     # Enthalpy of formation:             -5029         kJ/mol        05BRO/CUR


SrZrSi2O7(cr)
SrZrSi2O7 = +1.000Sr+2     -6.000H+     +2.000H4(SiO4)     +1.000Zr+4     -1.000H2O     
     log_k     5.2          #
     delta_h  -155.158      kJ/mol        #
     # Enthalpy of formation:             -3640.8       kJ/mol        05BRO/CUR


Na2ZrSiO5(cr)
Na2ZrSiO5 = +2.000Na+     -6.000H+     +1.000H4(SiO4)     +1.000Zr+4     +1.000H2O     
     log_k     13.19        #
     delta_h  -166.204      kJ/mol        #
     # Enthalpy of formation:             -2670         kJ/mol        05BRO/CUR


Na2ZrSi2O7(cr)
Na2ZrSi2O7 = +2.000Na+     -6.000H+     +2.000H4(SiO4)     +1.000Zr+4     -1.000H2O     
     log_k     3.74         #
     delta_h  -119.738      kJ/mol        #
     # Enthalpy of formation:             -3606         kJ/mol        05BRO/CUR


Na2ZrSi3O9:2H2O(cr)
Na2ZrSi3O9:2H2O = +2.000Na+     -6.000H+     +3.000H4(SiO4)     +1.000Zr+4     -1.000H2O     
     log_k     15.58        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Na2ZrSi4O11(cr)
Na2ZrSi4O11 = +2.000Na+     -6.000H+     +4.000H4(SiO4)     +1.000Zr+4     -5.000H2O     
     log_k    -13.56        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Na2ZrSi6O15:3H2O(cr)
Na2ZrSi6O15:3H2O = +2.000Na+     -6.000H+     +6.000H4(SiO4)     +1.000Zr+4     -6.000H2O     
     log_k     16.46        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Na4Zr2Si3O12(cr)
Na4Zr2Si3O12 = +4.000Na+     -12.000H+     +3.000H4(SiO4)     +2.000Zr+4     
     log_k     15.51        #
     delta_h  -276.942      kJ/mol        #
     # Enthalpy of formation:             -6285         kJ/mol        05BRO/CUR


Zr(HPO4)2:H2O(cr)
Zr(HPO4)2:H2O = -2.000H+     +2.000H2(PO4)-     +1.000Zr+4     +1.000H2O     
     log_k    -27.08        #05BRO/CUR
     delta_h  -33.43        kJ/mol        #
     # Enthalpy of formation:             -3466.1       kJ/mol        05BRO/CUR


Sb2O5(s)
Sb2O5 = +2.000Sb(OH)5     -5.000H2O     
     log_k    -7.4          #48TOU/MOU in 76BAE/MES
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Cd3(AsO4)2(s)
Cd3(AsO4)2 = +3.000Cd+2     +2.000AsO4-3     
     log_k    -32.62        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Cm(cr)
Cm = +3.000e-     +1.000Cm+3     
     log_k     104.31       #01KON
     delta_h  -615          kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        


Cm(OH)3(am)
Cm(OH)3 = -3.000H+     +1.000Cm+3     +3.000H2O     
     log_k     17.9         #estimated from ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Cm(OH)3(cr)
Cm(OH)3 = -3.000H+     +1.000Cm+3     +3.000H2O     
     log_k     15.6         #estimated from ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Cm2O3(cr)
Cm2O3 = -6.000H+     +2.000Cm+3     +3.000H2O     
     log_k     53.1         #
     delta_h  -403.49       kJ/mol        #
     # Enthalpy of formation:             -1684         kJ/mol        01KON


CmOHCO3(am)
CmOHCO3 = -1.000H+     +1.000CO3-2     +1.000Cm+3     +1.000H2O     
     log_k    -6.12         #estimated in anlogy with Ln(III) and Am(III)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Cm2(CO3)3(am)
Cm2(CO3)3 = +3.000CO3-2     +2.000Cm+3     
     log_k    -33.9         #estimated in analogy wiht Ln(III) and Am(III)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Cd(OH)2(s)
Cd(OH)2 = +1.000Cd+2     -2.000H+     +2.000H2O     
     log_k     13.86        #91RAI/FEL
     delta_h  -87.73        kJ/mol        #
     # Enthalpy of formation:             -559.85       kJ/mol        


Cm(PO4):xH2O(s)
Cm(PO4) = -2.000H+     +1.000H2(PO4)-     +1.000Cm+3     
     log_k    -4.97         #estimated by correlation with Ln(III)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


CmF3(cr)
CmF3 = +3.000F-     +1.000Cm+3     
     log_k    -13.16        #
     delta_h  -32.036       kJ/mol        #
     # Enthalpy of formation:             -1589.014     kJ/mol        estimated by 97SVE/SHO equation


CmCl3(cr)
CmCl3 = +3.000Cl-     +1.000Cm+3     
     log_k     15.07        #
     delta_h  -141.84       kJ/mol        #
     # Enthalpy of formation:             -974.4        kJ/mol        85BAR/PAR


CmOCl(cr)
CmOCl = -2.000H+     +1.000Cl-     +1.000Cm+3     +1.000H2O     
     log_k     9.49         #
     delta_h  -104.71       kJ/mol        #
     # Enthalpy of formation:             -963.2        kJ/mol        85BAR/PAR


Cm(CO3)(OH):0.5H2O(s)
Cm(CO3)(OH):0.5H2O = -1.000H+     +1.000CO3-2     +1.000Cm+3     +1.500H2O     
     log_k    -7.78         #estimated by correlation with Ln(III) and An(III)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Cm(CO3)(OH)(cr)
Cm(CO3)(OH) = -1.000H+     +1.000CO3-2     +1.000Cm+3     +1.000H2O     
     log_k    -10.34        #estimated by correlation with Ln(III) and An(III)
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Zn3(AsO4)2(s)
Zn3(AsO4)2 = +3.000Zn+2     +2.000AsO4-3     
     log_k    -27.45        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ni(SO4):7H2O(s)
Ni(SO4):7H2O = +1.000Ni+2     +1.000SO4-2     +7.000H2O     
     log_k    -2.27         #05GAM/BUG
     delta_h   12.167       kJ/mol        #05GAM/BUG
     # Enthalpy of formation:             -2977.329     kJ/mol        


NiCl2(s)
NiCl2 = +1.000Ni+2     +2.000Cl-     
     log_k     8.67         #
     delta_h  -84.272       kJ/mol        #
     # Enthalpy of formation:             -304.9        kJ/mol        05GAM/BUG


NiCl2:4H2O(s)
NiCl2:4H2O = +1.000Ni+2     +2.000Cl-     +4.000H2O     
     log_k     3.82         #
     delta_h  -18.444       kJ/mol        #05GAM/BUG
     # Enthalpy of formation:             -1514.048     kJ/mol        


NiCl2:6H2O(s)
NiCl2:6H2O = +1.000Ni+2     +2.000Cl-     +6.000H2O     
     log_k     3.04         #
     delta_h   0.548        kJ/mol        #
     # Enthalpy of formation:             -2104.7       kJ/mol        05GAM/BUG


NiF2(s)
NiF2 = +1.000Ni+2     +2.000F-     
     log_k    -0.18         #
     delta_h  -68.412       kJ/mol        #
     # Enthalpy of formation:             -657.3        kJ/mol        05GAM/BUG


Heazlewoodite
Ni3S2 = +3.000Ni+2     -2.000H+     +2.000e-     +2.000HS-     
     log_k    -17.23        #
     delta_h   19.564       kJ/mol        #
     # Enthalpy of formation:             -217.2        kJ/mol        05GAM/BUG


Vaesite
NiS2 = +1.000Ni+2     -2.000H+     -2.000e-     +2.000HS-     
     log_k    -17.97        #
     delta_h   40.388       kJ/mol        #
     # Enthalpy of formation:             -128          kJ/mol        05GAM/BUG


Polydymite
Ni3S4 = +3.000Ni+2     -4.000H+     -2.000e-     +4.000HS-     
     log_k    -39.27        #
     delta_h   96.116       kJ/mol        #
     # Enthalpy of formation:             -326.352      kJ/mol        74MIL


Ni3(PO4)2(cr)
Ni3(PO4)2 = +3.000Ni+2     -4.000H+     +2.000H2(PO4)-     
     log_k     10.253       #
     delta_h  -188.236      kJ/mol        #
     # Enthalpy of formation:             -2582         kJ/mol        89BAE/McK


Ni(SeO3):2H2O(cr)
Ni(SeO3):2H2O = +1.000Ni+2     +1.000SeO3-2     +2.000H2O     
     log_k    -5.8          #05OLI/NOL
     delta_h  -24.502       kJ/mol        #
     # Enthalpy of formation:             -1109.33      kJ/mol        05OLI/NOL


Ni(OH)2(s)
Ni(OH)2 = +1.000Ni+2     -2.000H+     +2.000H2O     
     log_k     11.03        #
     delta_h  -84.39        kJ/mol        #
     # Enthalpy of formation:             -542.3        kJ/mol        05GAM/BUG


Trevorite
Fe2NiO4 = +2.000Fe+3     +1.000Ni+2     -8.000H+     +4.000H2O     
     log_k     9.4          #
     delta_h  -214.413      kJ/mol        #
     # Enthalpy of formation:             -1081.173     kJ/mol        


Cerussite
Pb(CO3) = +1.000Pb+2     +1.000CO3-2     
     log_k    -13.29        #
     delta_h   27.414       kJ/mol        #
     # Enthalpy of formation:             -701.723      kJ/mol        


Hydrocerussite
Pb3(CO3)2(OH)2 = +3.000Pb+2     -2.000H+     +2.000CO3-2     +2.000H2O     
     log_k    -17.91        #
     delta_h  -5.16         kJ/mol        #
     # Enthalpy of formation:             -1914.2       kJ/mol        83SAN/BAR


Cr(s)
Cr = +8.000H+     +6.000e-     +1.000CrO4-2     -4.000H2O     
     log_k    -39.31        #
     delta_h   264.3        kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        


CrO2(cr)
CrO2 = +4.000H+     +2.000e-     +1.000CrO4-2     -2.000H2O     
     log_k    -51.68        #
     delta_h   290.56       kJ/mol        #
     # Enthalpy of formation:             -597.9        kJ/mol        93BAR, 04CHI


CrO3(cr)
CrO3 = +2.000H+     +1.000CrO4-2     -1.000H2O     
     log_k    -3.02         #
     delta_h  -10.07        kJ/mol        #
     # Enthalpy of formation:             -583.1        kJ/mol        98BAL/NOR, 04CHI


Cr(OH)2(cr)
Cr(OH)2 = -2.000H+     +1.000Cr+2     +2.000H2O     
     log_k     11           #41HUM/STO, 04CHI
     delta_h  -75.459       kJ/mol        #
     # Enthalpy of formation:             -653.82       kJ/mol        


CrS(s)
CrS = -1.000H+     +1.000HS-     +1.000Cr+2     
     log_k     1.66         #
     delta_h  -38.8         kJ/mol        #
     # Enthalpy of formation:             -135.143      kJ/mol        84PAN


CrCl2(cr)
CrCl2 = +2.000Cl-     +1.000Cr+2     
     log_k     12.73        #
     delta_h  -103.5        kJ/mol        #
     # Enthalpy of formation:             -388.3        kJ/mol        98BAL/NOR


Cr(OH)3(cr)
Cr(OH)3 = -3.000H+     +1.000Cr+3     +3.000H2O     
     log_k     9.35         #87RAI/SAS, 04CHI
     delta_h  -115.31       kJ/mol        #
     # Enthalpy of formation:             -982.679      kJ/mol        


Cr2O3(cr)
Cr2O3 = -6.000H+     +2.000Cr+3     +3.000H2O     
     log_k     7.75         #
     delta_h  -198          kJ/mol        #
     # Enthalpy of formation:             -1140.5       kJ/mol        04CHI


CrPO4(green)
CrPO4 = -2.000H+     +1.000H2(PO4)-     +1.000Cr+3     
     log_k    -3.06         #51ZHA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


CrPO4(purple)
CrPO4 = -2.000H+     +1.000H2(PO4)-     +1.000Cr+3     
     log_k     2.56         #51ZHA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Cr2(SO4)3(s)
Cr2(SO4)3 = +3.000SO4-2     +2.000Cr+3     
     log_k     4.38         #
     delta_h  -277.72       kJ/mol        #
     # Enthalpy of formation:             -2931.3       kJ/mol        91KNA/KUB


Cr2S3(s)
Cr2S3 = -3.000H+     +3.000HS-     +2.000Cr+3     
     log_k     3.26         #
     delta_h  -195.2        kJ/mol        #
     # Enthalpy of formation:             -334.7        kJ/mol        84PAN


CrCl3(cr)
CrCl3 = +3.000Cl-     +1.000Cr+3     
     log_k     20.19        #
     delta_h  -197.3        kJ/mol        #
     # Enthalpy of formation:             -544.4        kJ/mol        98BAL/NOR


MX80(des)
(Ca0.01Na0.434K0.026)(Si3.612Al0.388)(Al1.608Fe0.184Fe0.038Mg0.228)O10(OH)2 = +0.010Ca+2     +0.228Mg+2     +0.026K+     +0.434Na+     +0.184Fe+3     +0.038Fe+2     +1.996Al+3     -7.552H+     +3.612H4(SiO4)     -2.448H2O     
     log_k     8.35         #
     delta_h  -215.133      kJ/mol        #
     # Enthalpy of formation:             -5672.84      kJ/mol        07GAI/BLA


UO4Li2(s)
UO4Li2 = +2.000Li+     +1.000UO2+2     -4.000H+     +2.000H2O     
     log_k     27.94        #
     delta_h  -179.4        kJ/mol        #
     # Enthalpy of formation:             -1968.2       kJ/mol        92GRE/FUG


Anglesite
Pb(SO4) = +1.000Pb+2     +1.000SO4-2     
     log_k    -7.85         #
     delta_h   11.55        kJ/mol        #
     # Enthalpy of formation:             -919.97       kJ/mol        89COX/WAG


PbF2(s)
PbF2 = +1.000Pb+2     +2.000F-     
     log_k    -7.52         #99LOT/OCH
     delta_h   6.53         kJ/mol        #
     # Enthalpy of formation:             -676.31       kJ/mol        


Galena
PbS = +1.000Pb+2     -1.000H+     +1.000HS-     
     log_k    -14.84        #
     delta_h   82.94        kJ/mol        #
     # Enthalpy of formation:             -98.32        kJ/mol        98CHA


Pb(HPO4)(s)
Pb(HPO4) = +1.000Pb+2     -1.000H+     +1.000H2(PO4)-     
     log_k    -4.25         #74NRI
     delta_h   16.436       kJ/mol        #
     # Enthalpy of formation:             -1318.116     kJ/mol        


Pb3(PO4)2(s)
Pb3(PO4)2 = +3.000Pb+2     -4.000H+     +2.000H2(PO4)-     
     log_k    -5.26         #74NRI
     delta_h  -3.548        kJ/mol        #
     # Enthalpy of formation:             -2598.892     kJ/mol        


Pyromorphite-OH
Pb5(OH)(PO4)3 = +5.000Pb+2     -7.000H+     +3.000H2(PO4)-     +1.000H2O     
     log_k    -4.15         #74NRI
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Pb2(SiO4)(s)
Pb2(SiO4) = +2.000Pb+2     -4.000H+     +1.000H4(SiO4)     
     log_k     15.89        #
     delta_h  -81.474       kJ/mol        #
     # Enthalpy of formation:             -1377.88      kJ/mol        98CHA


Pb3(AsO4)2(s)
Pb3(AsO4)2 = +3.000Pb+2     +2.000AsO4-3     
     log_k    -35.4         #74NAU/RYZ
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Pb(SeO3)(s)
Pb(SeO3) = +1.000Pb+2     +1.000SeO3-2     
     log_k    -12.5         #05OLI/NOL
     delta_h   25.84        kJ/mol        #
     # Enthalpy of formation:             -532.08       kJ/mol        05OLI/NOL


Pb(cr)
Pb = +1.000Pb+2     +2.000e-     
     log_k     4.25         #
     delta_h   0.92         kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        89COX/WAG


Co3(AsO4)2(s)
Co3(AsO4)2 = +3.000Co+2     +2.000AsO4-3     
     log_k    -27.56        #
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ag2(CO3)(s)
Ag2(CO3) = +2.000Ag+     +1.000CO3-2     
     log_k    -11.05        #
     delta_h   42.073       kJ/mol        #
     # Enthalpy of formation:             -505.723      kJ/mol        


AgCl(cr)
AgCl = +1.000Ag+     +1.000Cl-     
     log_k    -9.75         #
     delta_h   65.72        kJ/mol        #
     # Enthalpy of formation:             -127.01       kJ/mol        92GRE/FUG


AgBr(s)
AgBr = +1.000Ag+     +1.000Br-     
     log_k    -12.29        #
     delta_h   84.725       kJ/mol        #
     # Enthalpy of formation:             -100.345      kJ/mol        


AgI(s)
AgI = +1.000Ag+     +1.000I-     
     log_k    -16.04        #
     delta_h   110.764      kJ/mol        #
     # Enthalpy of formation:             -61.754       kJ/mol        


Acanthite
Ag2S = +2.000Ag+     -1.000H+     +1.000HS-     
     log_k    -36.07        #
     delta_h   224.768      kJ/mol        #
     # Enthalpy of formation:             -29.488       kJ/mol        


Ag2(MoO4)(s)
Ag2(MoO4) = +2.000Ag+     +1.000MoO4-2     
     log_k    -11.46        #
     delta_h   55.354       kJ/mol        #
     # Enthalpy of formation:             -840.774      kJ/mol        


Ag2(SeO3)(s)
Ag2(SeO3) = +2.000Ag+     +1.000SeO3-2     
     log_k    -15.8         #05OLI/NOL
     delta_h   67.86        kJ/mol        #
     # Enthalpy of formation:             -363.44       kJ/mol        05OLI/NOL


Ag(OH)(s)
Ag(OH) = +1.000Ag+     -1.000H+     +1.000H2O     
     log_k     6.3          #76BAE/MES
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Al(PO4):2H2O(s)
Al(PO4):2H2O = +1.000Al+3     -2.000H+     +1.000H2(PO4)-     +2.000H2O     
     log_k    -2.51         #620BRG91.025   ANDRA 21.10.94
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Al2(OH)(PO4)2(s)
Al2(OH)(PO4)2 = +2.000Al+3     -5.000H+     -1.000e-     +2.000H2(PO4)-     +1.000H2O     
     log_k    -15.88        #620BRG91.025   ANDRA 21.10.94
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Kaolinite
Al2(Si2O5)(OH)4 = +2.000Al+3     -6.000H+     +2.000H4(SiO4)     +1.000H2O     
     log_k     6.47         #
     delta_h  -169.718      kJ/mol        #
     # Enthalpy of formation:             -4115.3       kJ/mol        01FIA/NAV


Gibbsite
Al(OH)3 = +1.000Al+3     -3.000H+     +3.000H2O     
     log_k     7.74         #95POK/HEL
     delta_h  -102.759      kJ/mol        #
     # Enthalpy of formation:             -1293.131     kJ/mol        


Cs2(CO3)(s)
Cs2(CO3) = +2.000Cs+     +1.000CO3-2     
     log_k     9.9          #
     delta_h  -55.348       kJ/mol        #
     # Enthalpy of formation:             -1135.882     kJ/mol        


Cs2(SO4)(s)
Cs2(SO4) = +2.000Cs+     +1.000SO4-2     
     log_k     0.58         #
     delta_h   17.756       kJ/mol        #
     # Enthalpy of formation:             -1443.096     kJ/mol        


Romarchite
SnO = +1.000Sn+2     -2.000H+     +1.000H2O     
     log_k     2.5          #02HUM/BER
     delta_h  -15.439       kJ/mol        #
     # Enthalpy of formation:             -279.291      kJ/mol        


Herzenbergite
SnS = +1.000Sn+2     -1.000H+     +1.000HS-     
     log_k    -14.7         #87PEI/FRE recalculated in 02HUM/BER
     delta_h   75.951       kJ/mol        #
     # Enthalpy of formation:             -101.152      kJ/mol        


Sn(OH)4(s)
Sn(OH)4 = +1.000Sn+4     -4.000H+     +4.000H2O     
     log_k    -1.28         #70BAR/KLI in 01SEB/POT
     delta_h  -2.82         kJ/mol        #
     # Enthalpy of formation:             -1110         kJ/mol        82WAG/EVA


SnO2(am)
SnO2 = +1.000Sn+4     -4.000H+     +2.000H2O     
     log_k    -6.81         #02HUM/BER
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Berndtite
SnS2 = +1.000Sn+4     -2.000H+     +2.000HS-     
     log_k    -29.31        #
     delta_h   147.7        kJ/mol        #
     # Enthalpy of formation:             -149.8        kJ/mol        95ROB/HEM


Quartz
SiO2 = +1.000H4(SiO4)     -2.000H2O     
     log_k    -3.74         #
     delta_h   21.166       kJ/mol        #
     # Enthalpy of formation:             -910.7        kJ/mol        82RIC


Pyrite
FeS2  = +1.000Fe+2     -2.000H+     -2.000e-     +2.000HS-     
     log_k    -15.79        #
     delta_h   45.05        kJ/mol        #
     # Enthalpy of formation:             -167.65       kJ/mol        76RAU in 04CHI


MnO2(s)
MnO2 = +1.000Mn+2     -4.000H+     -2.000e-     +2.000H2O     
     log_k     42           #NAGRA, TR 91-18; F.J. PEARSON, U. BERNER, W. HUMMEL; Nagra thermochemical data base, supplemental data 05/92
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Plattnerite
PbO2 = +1.000Pb+2     -4.000H+     -2.000e-     +2.000H2O     
     log_k     49.6         #
     delta_h  -296.27       kJ/mol        #
     # Enthalpy of formation:             -274.47       kJ/mol        98CHA


UO4Sr(alfa)
UO4Sr = +1.000Sr+2     +1.000UO2+2     -4.000H+     +2.000H2O     
     log_k     19.16        #
     delta_h  -151.96       kJ/mol        #
     # Enthalpy of formation:             -1989.6       kJ/mol        92GRE/FUG


Th(HPO4)2(s)
Th(HPO4)2 = +1.000Th+4     -2.000H+     +2.000H2(PO4)-     
     log_k    -16.11        #Estimated from An(IV) correlations
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


ThO2(aged)
ThO2 = +1.000Th+4     -4.000H+     +2.000H2O     
     log_k     8.5          #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


UO2(SO4):3H2O(cr)
UO2(SO4):3H2O = +1.000UO2+2     +1.000SO4-2     +3.000H2O     
     log_k    -1.5          #92GRE/FUG
     delta_h  -34.33        kJ/mol        #
     # Enthalpy of formation:             -2751.5       kJ/mol        92GRE/FUG


UO2(SO4):3.5H2O(cr)
UO2(SO4):3.5H2O = +1.000UO2+2     +1.000SO4-2     +3.500H2O     
     log_k    -1.59         #
     delta_h  -27.145       kJ/mol        #
     # Enthalpy of formation:             -2901.6       kJ/mol        92GRE/FUG


UO2(SO3)(cr)
UO2(SO3) = +1.000UO2+2     +1.000SO3-2     
     log_k    -15.83        #
     delta_h   6.45         kJ/mol        #
     # Enthalpy of formation:             -1661         kJ/mol        92GRE/FUG


UO2(SO4)(cr)
UO2(SO4) = +1.000UO2+2     +1.000SO4-2     
     log_k     1.89         #92GRE/FUG
     delta_h  -83.2         kJ/mol        #
     # Enthalpy of formation:             -1845.14      kJ/mol        92GRE/FUG


(UO2)3(AsO4)2(cr)
(UO2)3(AsO4)2 = +3.000UO2+2     +2.000AsO4-3     
     log_k    -27.4         #
     delta_h  -143.88       kJ/mol        #
     # Enthalpy of formation:             -4689.4       kJ/mol        92GRE/FUG


(UO2)2(As2O7)(cr)
(UO2)2(As2O7) = +2.000UO2+2     +2.000H+     +2.000AsO4-3     -1.000H2O     
     log_k    -29.01        #
     delta_h  -102.45       kJ/mol        #
     # Enthalpy of formation:             -3426         kJ/mol        92GRE/FUG


(UO2)3(PO4)2:6H2O(s)
(UO2)3(PO4)2:6H2O = +3.000UO2+2     -4.000H+     +2.000H2(PO4)-     +6.000H2O     
     log_k    -10.2         #
     delta_h  -48.78        kJ/mol        #
     # Enthalpy of formation:             -7328.4       kJ/mol        03GUI/FAN


UO3(alfa)
UO3 = +1.000UO2+2     -2.000H+     +1.000H2O     
     log_k     9.52         #
     delta_h  -92.42        kJ/mol        #
     # Enthalpy of formation:             -1212.41      kJ/mol        03GUI/FAN


UO3(beta)
UO3 = +1.000UO2+2     -2.000H+     +1.000H2O     
     log_k     8.3          #
     delta_h  -84.53        kJ/mol        #
     # Enthalpy of formation:             -1220.3       kJ/mol        92GRE/FUG


UO2(OH)2(beta)
UO2(OH)2 = +1.000UO2+2     -2.000H+     +2.000H2O     
     log_k     4.93         #
     delta_h  -56.86        kJ/mol        #
     # Enthalpy of formation:             -1533.8       kJ/mol        92GRE/FUG


Schoepite
UO3:2H2O = +1.000UO2+2     -2.000H+     +3.000H2O     
     log_k     5.96         #91SAN/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Schoepite(desy)
UO3:0.9H2O = +1.000UO2+2     -2.000H+     +1.900H2O     
     log_k     5            #
     delta_h  -55.777       kJ/mol        #
     # Enthalpy of formation:             -1506.3       kJ/mol        92GRE/FUG


UO2(SO4):2.5H2O(cr)
UO2(SO4):2.5H2O = +1.000UO2+2     +1.000SO4-2     +2.500H2O     
     log_k    -1.59         #
     delta_h  -35.915       kJ/mol        #
     # Enthalpy of formation:             -2607         kJ/mol        92GRE/FUG


(UO2)3(PO4)2:4H2O(cr)
(UO2)3(PO4)2:4H2O = +3.000UO2+2     -4.000H+     +2.000H2(PO4)-     +4.000H2O     
     log_k    -14.15        #92SAN/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


UO2(HPO4):4H2O(cr)
UO2(HPO4):4H2O = +1.000UO2+2     -1.000H+     +1.000H2(PO4)-     +4.000H2O     
     log_k    -4.64         #92GRE/FUG
     delta_h   5.048        kJ/mol        #
     # Enthalpy of formation:             -3469.968     kJ/mol        


UO4Na2(alfa)
UO4Na2 = +2.000Na+     +1.000UO2+2     -4.000H+     +2.000H2O     
     log_k     30.03        #
     delta_h  -173.64       kJ/mol        #
     # Enthalpy of formation:             -1897.7       kJ/mol        92GRE/FUG


UO4Ca(cr)
UO4Ca = +1.000Ca+2     +1.000UO2+2     -4.000H+     +2.000H2O     
     log_k     15.93        #
     delta_h  -131.36       kJ/mol        #
     # Enthalpy of formation:             -2002.3       kJ/mol        92GRE/FUG


UO4Mg(cr)
UO4Mg = +1.000Mg+2     +1.000UO2+2     -4.000H+     +2.000H2O     
     log_k     23.23        #
     delta_h  -200.36       kJ/mol        #
     # Enthalpy of formation:             -1857.3       kJ/mol        92GRE/FUG


PuO2(OH)2:H2O(s)
PuO2(OH)2:H2O = +1.000PuO2+2     -2.000H+     +3.000H2O     
     log_k     5.5          #01LEM/FUG
     delta_h  -46.718       kJ/mol        #
     # Enthalpy of formation:             -1632.808     kJ/mol        


PuO2(CO3)(s)
PuO2(CO3) = +1.000PuO2+2     +1.000CO3-2     
     log_k    -14.65        #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


PuO2(OH)(s)
PuO2(OH) = +1.000PuO2+     -1.000H+     +1.000H2O     
     log_k     5            #01LEM/FUG
     delta_h  -36.164       kJ/mol        #
     # Enthalpy of formation:             -1159.793     kJ/mol        


PuO2(s)
PuO2 = +1.000Pu+4     -4.000H+     +2.000H2O     
     log_k    -8.03         #
     delta_h  -55.755       kJ/mol        #
     # Enthalpy of formation:             -1055.8       kJ/mol        01LEM/FUG


PuF4(s)
PuF4 = +1.000Pu+4     +4.000F-     
     log_k    -26.07        #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Pu(HPO4)2(am,hyd)
Pu(HPO4)2 = +1.000Pu+4     -2.000H+     +2.000H2(PO4)-     
     log_k    -16.03        #01LEM/FUG
     delta_h  -32.718       kJ/mol        #
     # Enthalpy of formation:             -3112.377     kJ/mol        


Pu2O3(s)
Pu2O3 = +2.000Pu+3     -6.000H+     +3.000H2O     
     log_k     50.63        #
     delta_h  -385.07       kJ/mol        #
     # Enthalpy of formation:             -1656         kJ/mol        01LEM/FUG


Pu(OH)3(cr)
Pu(OH)3 = +1.000Pu+3     -3.000H+     +3.000H2O     
     log_k     15.8         #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Pu(CO3)(OH)(s)
Pu(CO3)(OH) = +1.000Pu+3     -1.000H+     +1.000CO3-2     +1.000H2O     
     log_k    -5.74         #Estimated by correlation with An(III) in function of ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Pu(PO4)(s,hyd)
Pu(PO4) = +1.000Pu+3     -2.000H+     +1.000H2(PO4)-     
     log_k    -5.04         #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


U(HPO4)2:4H2O(s)
U(HPO4)2:4H2O = +1.000U+4     -2.000H+     +2.000H2(PO4)-     +4.000H2O     
     log_k    -16.07        #92GRE/FUG
     delta_h  -4.902        kJ/mol        #
     # Enthalpy of formation:             -4334.819     kJ/mol        


U(OH)2(SO4)(cr)
U(OH)2(SO4) = +1.000U+4     -2.000H+     +1.000SO4-2     +2.000H2O     
     log_k    -3.17         #92GRE/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


US2(cr)
US2 = +1.000U+4     -2.000H+     +2.000HS-     
     log_k    -2.43         #
     delta_h  -103.4        kJ/mol        #
     # Enthalpy of formation:             -520.4        kJ/mol        92GRE/FUG


U(SO4)2(cr)
U(SO4)2 = +1.000U+4     +2.000SO4-2     
     log_k    -11.68        #
     delta_h  -100.28       kJ/mol        #
     # Enthalpy of formation:             -2309.6       kJ/mol        92GRE/FUG


U(SO4)2:4H2O(cr)
U(SO4)2:4H2O = +1.000U+4     +2.000SO4-2     +4.000H2O     
     log_k    -11.72        #
     delta_h  -70           kJ/mol        #
     # Enthalpy of formation:             -3483.2       kJ/mol        92GRE/FUG


U(SO4)2:8H2O(cr)
U(SO4)2:8H2O = +1.000U+4     +2.000SO4-2     +8.000H2O     
     log_k    -12.77        #
     delta_h  -33.92        kJ/mol        #
     # Enthalpy of formation:             -4662.6       kJ/mol        92GRE/FUG


USe2(beta)
USe2 = +1.000U+4     -2.000H+     +2.000HSe-     
     log_k     2.82         #
     delta_h  -135.6        kJ/mol        #
     # Enthalpy of formation:             -427          kJ/mol        92GRE/FUG


Uraninite
UO2 = +1.000U+4     -4.000H+     +2.000H2O     
     log_k    -4.85         #
     delta_h  -77.86        kJ/mol        #
     # Enthalpy of formation:             -1085         kJ/mol        92GRE/FUG


Coffinite
U(SiO4) = +1.000U+4     -4.000H+     +1.000H4(SiO4)     
     log_k    -7.8          #
     delta_h  -61.07        kJ/mol        #
     # Enthalpy of formation:             -1991.326     kJ/mol        


Rutherfordine
(UO2)(CO3) = +1.000UO2+2     +1.000CO3-2     
     log_k    -14.76        #03GUI/FAN
     delta_h  -2.929        kJ/mol        #
     # Enthalpy of formation:             -1691.301     kJ/mol        


Np(CO3)(OH)(s)
Np(CO3)(OH) = +1.000Np+3     -1.000H+     +1.000CO3-2     +1.000H2O     
     log_k    -6.06         #Estimated by correlation with An(III) in function of ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Np(OH)3(s)
Np(OH)3 = +1.000Np+3     -3.000H+     +3.000H2O     
     log_k     18           #80ALL/KIP
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


NpO2(s)
NpO2 = +1.000Np+4     -4.000H+     +2.000H2O     
     log_k    -9.75         #
     delta_h  -53.682       kJ/mol        #
     # Enthalpy of formation:             -1074         kJ/mol        01LEM/FUG


NpO2:2H2O(am)
NpO2:2H2O = +1.000Np+4     -4.000H+     +4.000H2O     
     log_k    -0.7          #03GUI/FAN
     delta_h  -81.156       kJ/mol        #
     # Enthalpy of formation:             -1618.186     kJ/mol        


Np(HPO4)2(s)
Np(HPO4)2 = +1.000Np+4     -2.000H+     +2.000H2(PO4)-     
     log_k    -16.06        #Estimated by correlation with An(III) in function of ionic radii
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


NpO2(CO3)2Na3(s)
NpO2(CO3)2Na3 = +3.000Na+     +1.000NpO2+     +2.000CO3-2     
     log_k    -14.22        #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


NpO2(CO3)Na:3.5H2O(s)
NpO2(CO3)Na:3.5H2O = +1.000Na+     +1.000NpO2+     +1.000CO3-2     +3.500H2O     
     log_k    -11           #03GUI/FAN
     delta_h   30.995       kJ/mol        #
     # Enthalpy of formation:             -2925.151     kJ/mol        


NpO2(CO3)(s)
NpO2(CO3) = +1.000NpO2+2     +1.000CO3-2     
     log_k    -14.6         #01LEM/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


TcO2(cr)
TcO2 = +1.000TcO(OH)2     -1.000H2O     
     log_k    -9.14         #97NGU/LAN
     delta_h  -5.69         kJ/mol        #
     # Enthalpy of formation:             -457.8        kJ/mol        99RAR/RAN


Eu2(CO3)3:3H2O(s)
Eu2(CO3)3:3H2O = +2.000Eu+3     +3.000CO3-2     +3.000H2O     
     log_k    -35           #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Sm(OH)3(s)
Sm(OH)3 = +1.000Sm+3     -3.000H+     +3.000H2O     
     log_k     16.13        #98DIA/RAG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Sm2(CO3)3(s)
Sm2(CO3)3 = +2.000Sm+3     +3.000CO3-2     
     log_k    -34.5         #95SPA/BRU
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


U2O7Na2(s)
U2O7Na2 = +2.000Na+     +2.000UO2+2     -6.000H+     +3.000H2O     
     log_k     22.6         #
     delta_h  -172.37       kJ/mol        #
     # Enthalpy of formation:             -3203.8       kJ/mol        92GRE/FUG


PdBr2(cr)
PdBr2 = +1.000Pd+2     +2.000Br-     
     log_k    -13.31        #89BAE/McK
     delta_h   51.263       kJ/mol        #
     # Enthalpy of formation:             -104.2        kJ/mol        89BAE/McK


PdCl2(cr)
PdCl2 = +1.000Pd+2     +2.000Cl-     
     log_k    -9.2          #
     delta_h   54.423       kJ/mol        #
     # Enthalpy of formation:             -198.7        kJ/mol        82WAG/EVA


PdI2(cr)
PdI2 = +1.000Pd+2     +2.000I-     
     log_k    -25.87        #
     delta_h   139.923      kJ/mol        #
     # Enthalpy of formation:             -63.6         kJ/mol        89BAE/McK


Pd(OH)2(s)
Pd(OH)2 = -2.000H+     +1.000Pd+2     +2.000H2O     
     log_k    -1.61         #70NAB/KAL
     delta_h   13.223       kJ/mol        #
     # Enthalpy of formation:             -395          kJ/mol        82WAG/EVA


PdO(s)
PdO = -2.000H+     +1.000Pd+2     +1.000H2O     
     log_k    -6.02         #
     delta_h  -10.547       kJ/mol        #
     # Enthalpy of formation:             -85.4         kJ/mol        82WAG/EVA


AmO2(cr)
AmO2 = -4.000H+     +1.000Am+3     -1.000e-     +2.000H2O     
     log_k     34.21        #
     delta_h  -256.16       kJ/mol        #
     # Enthalpy of formation:             -932.2        kJ/mol        95SIL/BID


Am2O3(cr)
Am2O3 = -6.000H+     +2.000Am+3     +3.000H2O     
     log_k     53.15        #
     delta_h  -400.49       kJ/mol        #
     # Enthalpy of formation:             -1690.4       kJ/mol        95SIL/BID


AmF3(cr)
AmF3 = +1.000Am+3     +3.000F-     
     log_k    -13.4         #
     delta_h  -28.75        kJ/mol        #
     # Enthalpy of formation:             -1594         kJ/mol        03GUI/FAN


AmI3(cr)
AmI3 = +1.000Am+3     +3.000I-     
     log_k     25.3         #
     delta_h  -172.04       kJ/mol        #
     # Enthalpy of formation:             -615          kJ/mol        03GUI/FAN


AmOCl(cr)
AmOCl = -2.000H+     +1.000Am+3     +1.000Cl-     +1.000H2O     
     log_k     12.26        #
     delta_h  -119.81       kJ/mol        #
     # Enthalpy of formation:             -949.8        kJ/mol        95SIL/BID


AmCl3(cr)
AmCl3 = +1.000Am+3     +3.000Cl-     
     log_k     15.28        #
     delta_h  -140.14       kJ/mol        #
     # Enthalpy of formation:             -977.8        kJ/mol        95SIL/BID


AmOBr(cr)
AmOBr = -2.000H+     +1.000Am+3     +1.000Br-     +1.000H2O     
     log_k     15.98        #
     delta_h  -136.94       kJ/mol        #
     # Enthalpy of formation:             -887          kJ/mol        03GUI/FAN


AmBr3(cr)
AmBr3 = +1.000Am+3     +3.000Br-     
     log_k     23.93        #
     delta_h  -176.93       kJ/mol        #
     # Enthalpy of formation:             -804          kJ/mol        03GUI/FAN


Am(CO3)2Na:5H2O(s)
Am(CO3)2Na:5H2O = +1.000Na+     +1.000Am+3     +2.000CO3-2     +5.000H2O     
     log_k    -21           #03GUI/FAN
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Am2(CO3)3(cr)
Am2(CO3)3 = +2.000Am+3     +3.000CO3-2     
     log_k    -33.4         #95SIL/BID
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Am(CO3)(OH):0.5H2O(cr)
Am(CO3)(OH):0.5H2O = -1.000H+     +1.000Am+3     +1.000CO3-2     +1.500H2O     
     log_k    -8.4          #03GUI/FAN
     delta_h  -37.775       kJ/mol        #
     # Enthalpy of formation:             -1682.9       kJ/mol        03GUI/FAN


Am(OH)3(am)
Am(OH)3 = -3.000H+     +1.000Am+3     +3.000H2O     
     log_k     16.9         #03GUI/FAN, 83RAI/STR, 83EDE/BUC, 85NIT/EDE
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Am(OH)3(cr)
Am(OH)3 = -3.000H+     +1.000Am+3     +3.000H2O     
     log_k     15.6         #03GUI/FAN, 82SIL, 88STA/KIM
     delta_h  -120.992      kJ/mol        #
     # Enthalpy of formation:             -1353.2       kJ/mol        


Am(PO4):xH2O(am)
Am(PO4) = -2.000H+     +1.000Am+3     +1.000H2(PO4)-     
     log_k    -5.23         #95SIL/BID
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Ra(OH)2(s)
Ra(OH)2 = -2.000H+     +1.000Ra+2     +2.000H2O     
     log_k     30.99        #
     delta_h  -149.763      kJ/mol        #
     # Enthalpy of formation:             -949.923      kJ/mol        


Ra(CO3)(s)
Ra(CO3) = +1.000Ra+2     +1.000CO3-2     
     log_k    -8.3          #85LAN/RIE
     delta_h   13.39        kJ/mol        #
     # Enthalpy of formation:             -1216.646     kJ/mol        


Hausmannite
Mn3O4 = +3.000Mn+2     -8.000H+     -2.000e-     +4.000H2O     
     log_k     61.32        #96FAL/REA
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


SiO2(am)
SiO2 = +1.000H4(SiO4)     -2.000H2O     
     log_k    -2.71         #00GUN/ARN
     delta_h   13.522       kJ/mol        #
     # Enthalpy of formation:             -903.056      kJ/mol        


B(OH)3(cr)
B(OH)3 = +1.000H+     +1.000B(OH)4-     -1.000H2O     
     log_k    -9.31         #
     delta_h   35.514       kJ/mol        #
     # Enthalpy of formation:             -1094.8       kJ/mol        01LEM/FUG


Th(SO4)2:9H2O(cr)
Th(SO4)2:9H2O = +1.000Th+4     +2.000SO4-2     +9.000H2O     
     log_k    -11.25        #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


ThF4(cr)
ThF4 = +1.000Th+4     +4.000F-     
     log_k    -19.11        #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


ThO2(cr)
ThO2 = +1.000Th+4     +2.000H2O     -4.000H+     
     log_k     1.77         #
     delta_h  -113.96       kJ/mol        #
     # Enthalpy of formation:             -1226.4       kJ/mol        09RAN/FUG


ThO2(fresh)
ThO2 = +1.000Th+4     +2.000H2O     -4.000H+     
     log_k     9.3          #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


ThO2(coll)
ThO2 = +1.000Th+4     +2.000H2O     -4.000H+     
     log_k     11.1         #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


Na6Th(CO3)5:12H2O(cr)
Na6Th(CO3)5:12H2O = +1.000Th+4     +5.000CO3-2     +12.000H2O     +6.000Na+     
     log_k    -42.2         #09RAN/FUG
     #delta_h               kJ/mol        #
     # Enthalpy of formation:                           kJ/mol        


# PMATCH GASES

H2(g)
H2 = +2.000H+     +2.000e-     
     log_k     0            #
     delta_h   0            kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        89COX/WAG


SO2(g)
SO2 = +4.000H+     +2.000e-     +1.000SO4-2     -2.000H2O     
     log_k    -5.32         #
     delta_h  -40.87        kJ/mol        #
     # Enthalpy of formation:             -296.81       kJ/mol        89COX/WAG


Cl2(g)
Cl2 = -2.000e-     +2.000Cl-     
     log_k     45.98        #
     delta_h  -334.16       kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        89COX/WAG


HCl(g)
HCl = +1.000H+     +1.000Cl-     
     log_k     6.29         #
     delta_h  -74.77        kJ/mol        #
     # Enthalpy of formation:             -92.31        kJ/mol        89COX/WAG


H2O(g)
H2O = +2.000H+     +2.000e-     +0.500O2     
     log_k    -41.49        #
     delta_h   235.759      kJ/mol        #
     # Enthalpy of formation:             -241.826      kJ/mol        89COX/WAG


CO(g)
CO = +4.000H+     +2.000e-     +1.000CO3-2     -2.000H2O     
     log_k    -14.64        #
     delta_h   6.96         kJ/mol        #
     # Enthalpy of formation:             -110.53       kJ/mol        89COX/WAG


CH4(g)
CH4 = +10.000H+     +8.000e-     +1.000CO3-2     -3.000H2O     
     log_k    -41.05        #
     delta_h   257.133      kJ/mol        #
     # Enthalpy of formation:             -74.873       kJ/mol        98CHA


CO2(g)
CO2 = +2.000H+     +1.000CO3-2     -1.000H2O     
     log_k    -18.15        #
     delta_h   4.11         kJ/mol        #
     # Enthalpy of formation:             -393.51       kJ/mol        89COX/WAG


H2S(g)
H2S = +1.000H+     +1.000HS-     
     log_k    -8            #
     delta_h   4.3          kJ/mol        #
     # Enthalpy of formation:             -20.6         kJ/mol        89COX/WAG


O2(g)
O2 = +1.000O2     
     log_k    -2.9          #
     delta_h  -12.134       kJ/mol        #
     # Enthalpy of formation:              0            kJ/mol        




