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New release notes.
git-svn-id: svn://136.177.114.72/svn_GW/phreeqc3/branches/concrete@10760 1feff8c3-07ed-0310-ac33-dd36852eb9cd
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RELEASE.TXT
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RELEASE.TXT
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Version @PHREEQC_VER@: @PHREEQC_DATE@
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Version @PHREEQC_VER@: @PHREEQC_DATE@
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svn 10759
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Created an option to enter cell-porosties in keyword TRANSPORT:
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-porosities 0.3 0.29 0.28 # porosities of cells 1, 2, 3-n, used for calculating
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# tortuosity in multicomponent diffusion calculations. The
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# numbers entered here take precedence over the value given
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# with -multi_D. If one stagnant layer is defined together with
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# an exchange-factor > 0 ('-stagnant 1 4e-6 0.3 0.1'), the
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# mobile (here = 0.3) and immobile (here = 0.1) porosities
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# defined with -stagnant are used.
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The electric potential can be defined in keyword SOLUTION:
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-potential 3 # Volt
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The effect of an electrical field on multicomponent diffusion (electro-migration) is calculated with
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the Nernst-Planck equation if one of the 2 column end-cell solutions has a potential different from 0
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(SOLUTION 0, SOLUTION cells + 1). For examples of electro-migration, see
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http://www.hydrochemistry.eu/exmpls/electro_dif.html
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Added special BASIC functions for obtaining parameters calculated in electro-migration:
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CURRENT_A # the current (A) through the column
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POT_V # potential (V) in a cell
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If the properties in a regular column (surface areas, lengths, double layers,
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tortuosities, diffusion coefficients) are different for the two cells, the harmonic
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mean is used for calculating the mass transfer (Appelo et al., 2010, Geochim. Cosmochim.
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Acta 74, 1201-1219).
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A temperature damping factor was added for the temperature effect of viscosity on the diffusion
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coefficient of a solute species:
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SOLUTION_SPECIES
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H+ = H+
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-dw 9.31e-9 831 # Dw(TK) = 9.31e-9 * exp(831 / TK - 831 / 298.15) * TK * 0.89 / (298.15 * viscos)
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The equation was proposed by Smolyakov, according to Anderko and Lencka, 1997, Ind. Chem. Eng. Res.
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36, 1932–1943.
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svn 10409
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svn 10409
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