New release notes.

git-svn-id: svn://136.177.114.72/svn_GW/phreeqc3/branches/concrete@10760 1feff8c3-07ed-0310-ac33-dd36852eb9cd
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David L Parkhurst 2016-01-28 23:58:25 +00:00
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Version @PHREEQC_VER@: @PHREEQC_DATE@
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svn 10759
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Created an option to enter cell-porosties in keyword TRANSPORT:
-porosities 0.3 0.29 0.28 # porosities of cells 1, 2, 3-n, used for calculating
# tortuosity in multicomponent diffusion calculations. The
# numbers entered here take precedence over the value given
# with -multi_D. If one stagnant layer is defined together with
# an exchange-factor > 0 ('-stagnant 1 4e-6 0.3 0.1'), the
# mobile (here = 0.3) and immobile (here = 0.1) porosities
# defined with -stagnant are used.
The electric potential can be defined in keyword SOLUTION:
-potential 3 # Volt
The effect of an electrical field on multicomponent diffusion (electro-migration) is calculated with
the Nernst-Planck equation if one of the 2 column end-cell solutions has a potential different from 0
(SOLUTION 0, SOLUTION cells + 1). For examples of electro-migration, see
http://www.hydrochemistry.eu/exmpls/electro_dif.html
Added special BASIC functions for obtaining parameters calculated in electro-migration:
CURRENT_A # the current (A) through the column
POT_V # potential (V) in a cell
If the properties in a regular column (surface areas, lengths, double layers,
tortuosities, diffusion coefficients) are different for the two cells, the harmonic
mean is used for calculating the mass transfer (Appelo et al., 2010, Geochim. Cosmochim.
Acta 74, 1201-1219).
A temperature damping factor was added for the temperature effect of viscosity on the diffusion
coefficient of a solute species:
SOLUTION_SPECIES
H+ = H+
-dw 9.31e-9 831 # Dw(TK) = 9.31e-9 * exp(831 / TK - 831 / 298.15) * TK * 0.89 / (298.15 * viscos)
The equation was proposed by Smolyakov, according to Anderko and Lencka, 1997, Ind. Chem. Eng. Res.
36, 19321943.
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svn 10409
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