diff --git a/ex1.out b/ex1.out index 334c1a0a..2d5ebd88 100644 --- a/ex1.out +++ b/ex1.out @@ -143,139 +143,139 @@ Initial solution 1. SEAWATER FROM NORDSTROM AND OTHERS (1979) ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.674e-06 1.629e-06 -5.573 -5.788 -0.215 - H+ 7.981e-09 6.026e-09 -8.098 -8.220 -0.122 - H2O 5.551e+01 9.806e-01 1.744 -0.009 0.000 -C(4) 2.180e-03 - HCO3- 1.514e-03 1.023e-03 -2.820 -2.990 -0.170 - MgHCO3+ 2.195e-04 1.640e-04 -3.658 -3.785 -0.127 - NaHCO3 1.667e-04 1.948e-04 -3.778 -3.710 0.067 - MgCO3 8.913e-05 1.041e-04 -4.050 -3.982 0.067 - NaCO3- 6.718e-05 5.020e-05 -4.173 -4.299 -0.127 - CaHCO3+ 4.597e-05 3.106e-05 -4.337 -4.508 -0.170 - CO3-2 3.821e-05 7.959e-06 -4.418 -5.099 -0.681 - CaCO3 2.725e-05 3.183e-05 -4.565 -4.497 0.067 - CO2 1.210e-05 1.413e-05 -4.917 -4.850 0.067 - UO2(CO3)3-4 1.255e-08 1.184e-10 -7.901 -9.927 -2.025 - UO2(CO3)2-2 1.814e-09 5.653e-10 -8.741 -9.248 -0.506 - MnCO3 2.696e-10 3.150e-10 -9.569 -9.502 0.067 - MnHCO3+ 6.077e-11 4.541e-11 -10.216 -10.343 -0.127 - UO2CO3 7.429e-12 8.678e-12 -11.129 -11.062 0.067 - FeCO3 1.878e-20 2.194e-20 -19.726 -19.659 0.067 - FeHCO3+ 1.573e-20 1.175e-20 -19.803 -19.930 -0.127 -Ca 1.066e-02 - Ca+2 9.504e-03 2.380e-03 -2.022 -2.623 -0.601 - CaSO4 1.083e-03 1.266e-03 -2.965 -2.898 0.067 - CaHCO3+ 4.597e-05 3.106e-05 -4.337 -4.508 -0.170 - CaCO3 2.725e-05 3.183e-05 -4.565 -4.497 0.067 - CaOH+ 8.604e-08 6.429e-08 -7.065 -7.192 -0.127 - CaHSO4+ 5.979e-11 4.467e-11 -10.223 -10.350 -0.127 -Cl 5.657e-01 - Cl- 5.657e-01 3.528e-01 -0.247 -0.452 -0.205 - MnCl+ 9.582e-10 7.160e-10 -9.019 -9.145 -0.127 - MnCl2 9.439e-11 1.103e-10 -10.025 -9.958 0.067 - MnCl3- 1.434e-11 1.071e-11 -10.844 -10.970 -0.127 - FeCl+2 9.557e-19 2.978e-19 -18.020 -18.526 -0.506 - FeCl2+ 6.281e-19 4.693e-19 -18.202 -18.329 -0.127 - FeCl+ 7.488e-20 5.595e-20 -19.126 -19.252 -0.127 - FeCl3 1.417e-20 1.656e-20 -19.849 -19.781 0.067 -Fe(2) 6.645e-19 - Fe+2 5.006e-19 1.149e-19 -18.301 -18.940 -0.639 - FeCl+ 7.488e-20 5.595e-20 -19.126 -19.252 -0.127 - FeSO4 4.660e-20 5.444e-20 -19.332 -19.264 0.067 - FeCO3 1.878e-20 2.194e-20 -19.726 -19.659 0.067 - FeHCO3+ 1.573e-20 1.175e-20 -19.803 -19.930 -0.127 - FeOH+ 7.913e-21 5.912e-21 -20.102 -20.228 -0.127 - FeHSO4+ 2.886e-27 2.156e-27 -26.540 -26.666 -0.127 -Fe(3) 3.711e-08 - Fe(OH)3 2.841e-08 3.318e-08 -7.547 -7.479 0.067 - Fe(OH)4- 6.591e-09 4.924e-09 -8.181 -8.308 -0.127 - Fe(OH)2+ 2.118e-09 1.583e-09 -8.674 -8.801 -0.127 - FeOH+2 9.425e-14 2.937e-14 -13.026 -13.532 -0.506 - FeSO4+ 1.093e-18 8.167e-19 -17.961 -18.088 -0.127 - FeCl+2 9.557e-19 2.978e-19 -18.020 -18.526 -0.506 - FeCl2+ 6.281e-19 4.693e-19 -18.202 -18.329 -0.127 - Fe+3 3.509e-19 2.796e-20 -18.455 -19.554 -1.099 - Fe(SO4)2- 6.372e-20 4.761e-20 -19.196 -19.322 -0.127 - FeCl3 1.417e-20 1.656e-20 -19.849 -19.781 0.067 - Fe2(OH)2+4 2.462e-24 2.322e-26 -23.609 -25.634 -2.025 - FeHSO4+2 4.228e-26 1.318e-26 -25.374 -25.880 -0.506 - Fe3(OH)4+5 1.122e-29 7.679e-33 -28.950 -32.115 -3.165 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.470 -44.402 0.067 -K 1.058e-02 - K+ 1.042e-02 6.495e-03 -1.982 -2.187 -0.205 - KSO4- 1.627e-04 1.216e-04 -3.789 -3.915 -0.127 - KOH 3.137e-09 3.665e-09 -8.503 -8.436 0.067 -Mg 5.507e-02 - Mg+2 4.742e-02 1.371e-02 -1.324 -1.863 -0.539 - MgSO4 7.330e-03 8.562e-03 -2.135 -2.067 0.067 - MgHCO3+ 2.195e-04 1.640e-04 -3.658 -3.785 -0.127 - MgCO3 8.913e-05 1.041e-04 -4.050 -3.982 0.067 - MgOH+ 1.084e-05 8.100e-06 -4.965 -5.092 -0.127 -Mn(2) 3.773e-09 - Mn+2 2.171e-09 4.982e-10 -8.663 -9.303 -0.639 - MnCl+ 9.582e-10 7.160e-10 -9.019 -9.145 -0.127 - MnCO3 2.696e-10 3.150e-10 -9.569 -9.502 0.067 - MnSO4 2.021e-10 2.360e-10 -9.695 -9.627 0.067 - MnCl2 9.439e-11 1.103e-10 -10.025 -9.958 0.067 - MnHCO3+ 6.077e-11 4.541e-11 -10.216 -10.343 -0.127 - MnCl3- 1.434e-11 1.071e-11 -10.844 -10.970 -0.127 - MnOH+ 2.789e-12 2.084e-12 -11.555 -11.681 -0.127 - Mn(NO3)2 1.375e-20 1.607e-20 -19.862 -19.794 0.067 -Mn(3) 5.993e-26 - Mn+3 5.993e-26 4.349e-27 -25.222 -26.362 -1.139 -N(-3) 1.724e-06 - NH4+ 1.609e-06 9.049e-07 -5.794 -6.043 -0.250 - NH3 7.326e-08 8.558e-08 -7.135 -7.068 0.067 - NH4SO4- 4.157e-08 3.106e-08 -7.381 -7.508 -0.127 -N(5) 4.847e-06 - NO3- 4.847e-06 2.846e-06 -5.314 -5.546 -0.231 - Mn(NO3)2 1.375e-20 1.607e-20 -19.862 -19.794 0.067 -Na 4.854e-01 - Na+ 4.791e-01 3.387e-01 -0.320 -0.470 -0.151 - NaSO4- 6.053e-03 4.523e-03 -2.218 -2.345 -0.127 - NaHCO3 1.667e-04 1.948e-04 -3.778 -3.710 0.067 - NaCO3- 6.718e-05 5.020e-05 -4.173 -4.299 -0.127 - NaOH 3.117e-07 3.641e-07 -6.506 -6.439 0.067 -O(0) 4.377e-04 - O2 2.189e-04 2.556e-04 -3.660 -3.592 0.067 -S(6) 2.926e-02 - SO4-2 1.463e-02 2.664e-03 -1.835 -2.574 -0.740 - MgSO4 7.330e-03 8.562e-03 -2.135 -2.067 0.067 - NaSO4- 6.053e-03 4.523e-03 -2.218 -2.345 -0.127 - CaSO4 1.083e-03 1.266e-03 -2.965 -2.898 0.067 - KSO4- 1.627e-04 1.216e-04 -3.789 -3.915 -0.127 - NH4SO4- 4.157e-08 3.106e-08 -7.381 -7.508 -0.127 - HSO4- 2.089e-09 1.561e-09 -8.680 -8.807 -0.127 - MnSO4 2.021e-10 2.360e-10 -9.695 -9.627 0.067 - CaHSO4+ 5.979e-11 4.467e-11 -10.223 -10.350 -0.127 - FeSO4+ 1.093e-18 8.167e-19 -17.961 -18.088 -0.127 - Fe(SO4)2- 6.372e-20 4.761e-20 -19.196 -19.322 -0.127 - FeSO4 4.660e-20 5.444e-20 -19.332 -19.264 0.067 - FeHSO4+2 4.228e-26 1.318e-26 -25.374 -25.880 -0.506 - FeHSO4+ 2.886e-27 2.156e-27 -26.540 -26.666 -0.127 -Si 7.382e-05 - H4SiO4 7.110e-05 8.306e-05 -4.148 -4.081 0.067 - H3SiO4- 2.720e-06 2.032e-06 -5.565 -5.692 -0.127 - H2SiO4-2 7.362e-11 2.294e-11 -10.133 -10.639 -0.506 -U(4) 1.034e-21 - U(OH)5- 1.034e-21 7.725e-22 -20.985 -21.112 -0.127 - U(OH)4 1.652e-25 1.930e-25 -24.782 -24.715 0.067 - U+4 0.000e+00 0.000e+00 -46.997 -49.022 -2.025 -U(5) 1.622e-18 - UO2+ 1.622e-18 1.212e-18 -17.790 -17.916 -0.127 -U(6) 1.437e-08 - UO2(CO3)3-4 1.255e-08 1.184e-10 -7.901 -9.927 -2.025 - UO2(CO3)2-2 1.814e-09 5.653e-10 -8.741 -9.248 -0.506 - UO2CO3 7.429e-12 8.678e-12 -11.129 -11.062 0.067 - UO2OH+ 3.385e-14 2.530e-14 -13.470 -13.597 -0.127 - UO2+2 3.019e-16 9.409e-17 -15.520 -16.026 -0.506 - (UO2)2(OH)2+2 1.780e-21 5.547e-22 -20.750 -21.256 -0.506 - (UO2)3(OH)5+ 2.908e-23 2.173e-23 -22.536 -22.663 -0.127 + OH- 2.674e-06 1.629e-06 -5.573 -5.788 -0.215 (0) + H+ 7.981e-09 6.026e-09 -8.098 -8.220 -0.122 0.00 + H2O 5.551e+01 9.806e-01 1.744 -0.009 0.000 18.07 +C(4) 2.180e-03 + HCO3- 1.514e-03 1.023e-03 -2.820 -2.990 -0.170 24.63 + MgHCO3+ 2.195e-04 1.640e-04 -3.658 -3.785 -0.127 (0) + NaHCO3 1.667e-04 1.948e-04 -3.778 -3.710 0.067 (0) + MgCO3 8.913e-05 1.041e-04 -4.050 -3.982 0.067 (0) + NaCO3- 6.718e-05 5.020e-05 -4.173 -4.299 -0.127 (0) + CaHCO3+ 4.597e-05 3.106e-05 -4.337 -4.508 -0.170 (0) + CO3-2 3.821e-05 7.959e-06 -4.418 -5.099 -0.681 -2.43 + CaCO3 2.725e-05 3.183e-05 -4.565 -4.497 0.067 (0) + CO2 1.210e-05 1.413e-05 -4.917 -4.850 0.067 (0) + UO2(CO3)3-4 1.255e-08 1.184e-10 -7.901 -9.927 -2.025 (0) + UO2(CO3)2-2 1.814e-09 5.653e-10 -8.741 -9.248 -0.506 (0) + MnCO3 2.696e-10 3.150e-10 -9.569 -9.502 0.067 (0) + MnHCO3+ 6.077e-11 4.541e-11 -10.216 -10.343 -0.127 (0) + UO2CO3 7.429e-12 8.678e-12 -11.129 -11.062 0.067 (0) + FeCO3 1.878e-20 2.194e-20 -19.726 -19.659 0.067 (0) + FeHCO3+ 1.573e-20 1.175e-20 -19.803 -19.930 -0.127 (0) +Ca 1.066e-02 + Ca+2 9.504e-03 2.380e-03 -2.022 -2.623 -0.601 -16.48 + CaSO4 1.083e-03 1.266e-03 -2.965 -2.898 0.067 (0) + CaHCO3+ 4.597e-05 3.106e-05 -4.337 -4.508 -0.170 (0) + CaCO3 2.725e-05 3.183e-05 -4.565 -4.497 0.067 (0) + CaOH+ 8.604e-08 6.429e-08 -7.065 -7.192 -0.127 (0) + CaHSO4+ 5.979e-11 4.467e-11 -10.223 -10.350 -0.127 (0) +Cl 5.657e-01 + Cl- 5.657e-01 3.528e-01 -0.247 -0.452 -0.205 18.16 + MnCl+ 9.582e-10 7.160e-10 -9.019 -9.145 -0.127 (0) + MnCl2 9.439e-11 1.103e-10 -10.025 -9.958 0.067 (0) + MnCl3- 1.434e-11 1.071e-11 -10.844 -10.970 -0.127 (0) + FeCl+2 9.557e-19 2.978e-19 -18.020 -18.526 -0.506 (0) + FeCl2+ 6.281e-19 4.693e-19 -18.202 -18.329 -0.127 (0) + FeCl+ 7.488e-20 5.595e-20 -19.126 -19.252 -0.127 (0) + FeCl3 1.417e-20 1.656e-20 -19.849 -19.781 0.067 (0) +Fe(2) 6.645e-19 + Fe+2 5.006e-19 1.149e-19 -18.301 -18.940 -0.639 (0) + FeCl+ 7.488e-20 5.595e-20 -19.126 -19.252 -0.127 (0) + FeSO4 4.660e-20 5.444e-20 -19.332 -19.264 0.067 (0) + FeCO3 1.878e-20 2.194e-20 -19.726 -19.659 0.067 (0) + FeHCO3+ 1.573e-20 1.175e-20 -19.803 -19.930 -0.127 (0) + FeOH+ 7.913e-21 5.912e-21 -20.102 -20.228 -0.127 (0) + FeHSO4+ 2.886e-27 2.156e-27 -26.540 -26.666 -0.127 (0) +Fe(3) 3.711e-08 + Fe(OH)3 2.841e-08 3.318e-08 -7.547 -7.479 0.067 (0) + Fe(OH)4- 6.591e-09 4.924e-09 -8.181 -8.308 -0.127 (0) + Fe(OH)2+ 2.118e-09 1.583e-09 -8.674 -8.801 -0.127 (0) + FeOH+2 9.425e-14 2.937e-14 -13.026 -13.532 -0.506 (0) + FeSO4+ 1.093e-18 8.167e-19 -17.961 -18.088 -0.127 (0) + FeCl+2 9.557e-19 2.978e-19 -18.020 -18.526 -0.506 (0) + FeCl2+ 6.281e-19 4.693e-19 -18.202 -18.329 -0.127 (0) + Fe+3 3.509e-19 2.796e-20 -18.455 -19.554 -1.099 (0) + Fe(SO4)2- 6.372e-20 4.761e-20 -19.196 -19.322 -0.127 (0) + FeCl3 1.417e-20 1.656e-20 -19.849 -19.781 0.067 (0) + Fe2(OH)2+4 2.462e-24 2.322e-26 -23.609 -25.634 -2.025 (0) + FeHSO4+2 4.228e-26 1.318e-26 -25.374 -25.880 -0.506 (0) + Fe3(OH)4+5 1.122e-29 7.679e-33 -28.950 -32.115 -3.165 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.470 -44.402 0.067 (0) +K 1.058e-02 + K+ 1.042e-02 6.495e-03 -1.982 -2.187 -0.205 9.37 + KSO4- 1.627e-04 1.216e-04 -3.789 -3.915 -0.127 (0) + KOH 3.137e-09 3.665e-09 -8.503 -8.436 0.067 (0) +Mg 5.507e-02 + Mg+2 4.742e-02 1.371e-02 -1.324 -1.863 -0.539 -19.80 + MgSO4 7.330e-03 8.562e-03 -2.135 -2.067 0.067 (0) + MgHCO3+ 2.195e-04 1.640e-04 -3.658 -3.785 -0.127 (0) + MgCO3 8.913e-05 1.041e-04 -4.050 -3.982 0.067 (0) + MgOH+ 1.084e-05 8.100e-06 -4.965 -5.092 -0.127 (0) +Mn(2) 3.773e-09 + Mn+2 2.171e-09 4.982e-10 -8.663 -9.303 -0.639 (0) + MnCl+ 9.582e-10 7.160e-10 -9.019 -9.145 -0.127 (0) + MnCO3 2.696e-10 3.150e-10 -9.569 -9.502 0.067 (0) + MnSO4 2.021e-10 2.360e-10 -9.695 -9.627 0.067 (0) + MnCl2 9.439e-11 1.103e-10 -10.025 -9.958 0.067 (0) + MnHCO3+ 6.077e-11 4.541e-11 -10.216 -10.343 -0.127 (0) + MnCl3- 1.434e-11 1.071e-11 -10.844 -10.970 -0.127 (0) + MnOH+ 2.789e-12 2.084e-12 -11.555 -11.681 -0.127 (0) + Mn(NO3)2 1.375e-20 1.607e-20 -19.862 -19.794 0.067 (0) +Mn(3) 5.993e-26 + Mn+3 5.993e-26 4.349e-27 -25.222 -26.362 -1.139 (0) +N(-3) 1.724e-06 + NH4+ 1.609e-06 9.049e-07 -5.794 -6.043 -0.250 18.20 + NH3 7.326e-08 8.558e-08 -7.135 -7.068 0.067 (0) + NH4SO4- 4.157e-08 3.106e-08 -7.381 -7.508 -0.127 (0) +N(5) 4.847e-06 + NO3- 4.847e-06 2.846e-06 -5.314 -5.546 -0.231 29.33 + Mn(NO3)2 1.375e-20 1.607e-20 -19.862 -19.794 0.067 (0) +Na 4.854e-01 + Na+ 4.791e-01 3.387e-01 -0.320 -0.470 -0.151 -0.87 + NaSO4- 6.053e-03 4.523e-03 -2.218 -2.345 -0.127 (0) + NaHCO3 1.667e-04 1.948e-04 -3.778 -3.710 0.067 (0) + NaCO3- 6.718e-05 5.020e-05 -4.173 -4.299 -0.127 (0) + NaOH 3.117e-07 3.641e-07 -6.506 -6.439 0.067 (0) +O(0) 4.377e-04 + O2 2.189e-04 2.556e-04 -3.660 -3.592 0.067 (0) +S(6) 2.926e-02 + SO4-2 1.463e-02 2.664e-03 -1.835 -2.574 -0.740 15.33 + MgSO4 7.330e-03 8.562e-03 -2.135 -2.067 0.067 (0) + NaSO4- 6.053e-03 4.523e-03 -2.218 -2.345 -0.127 (0) + CaSO4 1.083e-03 1.266e-03 -2.965 -2.898 0.067 (0) + KSO4- 1.627e-04 1.216e-04 -3.789 -3.915 -0.127 (0) + NH4SO4- 4.157e-08 3.106e-08 -7.381 -7.508 -0.127 (0) + HSO4- 2.089e-09 1.561e-09 -8.680 -8.807 -0.127 (0) + MnSO4 2.021e-10 2.360e-10 -9.695 -9.627 0.067 (0) + CaHSO4+ 5.979e-11 4.467e-11 -10.223 -10.350 -0.127 (0) + FeSO4+ 1.093e-18 8.167e-19 -17.961 -18.088 -0.127 (0) + Fe(SO4)2- 6.372e-20 4.761e-20 -19.196 -19.322 -0.127 (0) + FeSO4 4.660e-20 5.444e-20 -19.332 -19.264 0.067 (0) + FeHSO4+2 4.228e-26 1.318e-26 -25.374 -25.880 -0.506 (0) + FeHSO4+ 2.886e-27 2.156e-27 -26.540 -26.666 -0.127 (0) +Si 7.382e-05 + H4SiO4 7.110e-05 8.306e-05 -4.148 -4.081 0.067 56.00 + H3SiO4- 2.720e-06 2.032e-06 -5.565 -5.692 -0.127 (0) + H2SiO4-2 7.362e-11 2.294e-11 -10.133 -10.639 -0.506 (0) +U(4) 1.034e-21 + U(OH)5- 1.034e-21 7.725e-22 -20.985 -21.112 -0.127 (0) + U(OH)4 1.652e-25 1.930e-25 -24.782 -24.715 0.067 (0) + U+4 0.000e+00 0.000e+00 -46.997 -49.022 -2.025 (0) +U(5) 1.622e-18 + UO2+ 1.622e-18 1.212e-18 -17.790 -17.916 -0.127 (0) +U(6) 1.437e-08 + UO2(CO3)3-4 1.255e-08 1.184e-10 -7.901 -9.927 -2.025 (0) + UO2(CO3)2-2 1.814e-09 5.653e-10 -8.741 -9.248 -0.506 (0) + UO2CO3 7.429e-12 8.678e-12 -11.129 -11.062 0.067 (0) + UO2OH+ 3.385e-14 2.530e-14 -13.470 -13.597 -0.127 (0) + UO2+2 3.019e-16 9.409e-17 -15.520 -16.026 -0.506 (0) + (UO2)2(OH)2+2 1.780e-21 5.547e-22 -20.750 -21.256 -0.506 (0) + (UO2)3(OH)5+ 2.908e-23 2.173e-23 -22.536 -22.663 -0.127 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex10.out b/ex10.out index 9a7bb298..c5965391 100644 --- a/ex10.out +++ b/ex10.out @@ -135,29 +135,29 @@ Initial solution 1. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.039e-06 9.312e-07 -5.983 -6.031 -0.048 - H+ 1.181e-08 1.075e-08 -7.928 -7.969 -0.041 - H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -75.157 -75.156 0.001 -C(4) 7.864e-03 - HCO3- 7.325e-03 6.602e-03 -2.135 -2.180 -0.045 - CaHCO3+ 2.216e-04 1.997e-04 -3.654 -3.700 -0.045 - CO2 1.592e-04 1.596e-04 -3.798 -3.797 0.001 - CaCO3 1.145e-04 1.147e-04 -3.941 -3.940 0.001 - CO3-2 4.365e-05 2.881e-05 -4.360 -4.541 -0.181 -Ca 3.932e-03 - Ca+2 3.596e-03 2.371e-03 -2.444 -2.625 -0.181 - CaHCO3+ 2.216e-04 1.997e-04 -3.654 -3.700 -0.045 - CaCO3 1.145e-04 1.147e-04 -3.941 -3.940 0.001 - CaOH+ 4.077e-08 3.661e-08 -7.390 -7.436 -0.047 -H(0) 1.632e-27 - H2 8.158e-28 8.179e-28 -27.088 -27.087 0.001 -O(0) 1.243e-38 - O2 6.213e-39 6.229e-39 -38.207 -38.206 0.001 + OH- 1.039e-06 9.312e-07 -5.983 -6.031 -0.048 (0) + H+ 1.181e-08 1.075e-08 -7.928 -7.969 -0.041 0.00 + H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -75.157 -75.156 0.001 (0) +C(4) 7.864e-03 + HCO3- 7.325e-03 6.602e-03 -2.135 -2.180 -0.045 24.29 + CaHCO3+ 2.216e-04 1.997e-04 -3.654 -3.700 -0.045 (0) + CO2 1.592e-04 1.596e-04 -3.798 -3.797 0.001 (0) + CaCO3 1.145e-04 1.147e-04 -3.941 -3.940 0.001 (0) + CO3-2 4.365e-05 2.881e-05 -4.360 -4.541 -0.181 -3.78 +Ca 3.932e-03 + Ca+2 3.596e-03 2.371e-03 -2.444 -2.625 -0.181 -17.83 + CaHCO3+ 2.216e-04 1.997e-04 -3.654 -3.700 -0.045 (0) + CaCO3 1.145e-04 1.147e-04 -3.941 -3.940 0.001 (0) + CaOH+ 4.077e-08 3.661e-08 -7.390 -7.436 -0.047 (0) +H(0) 1.632e-27 + H2 8.158e-28 8.179e-28 -27.088 -27.087 0.001 (0) +O(0) 1.243e-38 + O2 6.213e-39 6.229e-39 -38.207 -38.206 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -216,29 +216,29 @@ CO2(g) -0.01 -1.48 -1.47 1.000e+01 9.961e+00 -3.944e-02 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 9.885e-07 8.654e-07 -6.005 -6.063 -0.058 - OH- 1.366e-08 1.155e-08 -7.865 -7.937 -0.073 - H2O 5.551e+01 9.989e-01 1.744 -0.000 0.000 -C(-4) 7.043e-22 - CH4 7.043e-22 7.091e-22 -21.152 -21.149 0.003 -C(4) 5.392e-02 - CO2 3.285e-02 3.307e-02 -1.483 -1.481 0.003 - HCO3- 1.979e-02 1.698e-02 -1.703 -1.770 -0.067 - CaHCO3+ 1.266e-03 1.086e-03 -2.897 -2.964 -0.067 - CaCO3 7.698e-06 7.750e-06 -5.114 -5.111 0.003 - CO3-2 1.700e-06 9.199e-07 -5.770 -6.036 -0.267 -Ca 1.054e-02 - Ca+2 9.265e-03 5.015e-03 -2.033 -2.300 -0.267 - CaHCO3+ 1.266e-03 1.086e-03 -2.897 -2.964 -0.067 - CaCO3 7.698e-06 7.750e-06 -5.114 -5.111 0.003 - CaOH+ 1.128e-09 9.606e-10 -8.948 -9.017 -0.070 -H(0) 1.359e-14 - H2 6.794e-15 6.839e-15 -14.168 -14.165 0.003 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -64.054 -64.051 0.003 + H+ 9.885e-07 8.654e-07 -6.005 -6.063 -0.058 0.00 + OH- 1.366e-08 1.155e-08 -7.865 -7.937 -0.073 (0) + H2O 5.551e+01 9.989e-01 1.744 -0.000 0.000 18.07 +C(-4) 7.043e-22 + CH4 7.043e-22 7.091e-22 -21.152 -21.149 0.003 (0) +C(4) 5.392e-02 + CO2 3.285e-02 3.307e-02 -1.483 -1.481 0.003 (0) + HCO3- 1.979e-02 1.698e-02 -1.703 -1.770 -0.067 24.34 + CaHCO3+ 1.266e-03 1.086e-03 -2.897 -2.964 -0.067 (0) + CaCO3 7.698e-06 7.750e-06 -5.114 -5.111 0.003 (0) + CO3-2 1.700e-06 9.199e-07 -5.770 -6.036 -0.267 -3.58 +Ca 1.054e-02 + Ca+2 9.265e-03 5.015e-03 -2.033 -2.300 -0.267 -17.63 + CaHCO3+ 1.266e-03 1.086e-03 -2.897 -2.964 -0.067 (0) + CaCO3 7.698e-06 7.750e-06 -5.114 -5.111 0.003 (0) + CaOH+ 1.128e-09 9.606e-10 -8.948 -9.017 -0.070 (0) +H(0) 1.359e-14 + H2 6.794e-15 6.839e-15 -14.168 -14.165 0.003 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -64.054 -64.051 0.003 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex11.out b/ex11.out index 90306701..7e38bcfa 100644 --- a/ex11.out +++ b/ex11.out @@ -76,21 +76,21 @@ Initial solution 0. CaCl2 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.052e-07 1.006e-07 -6.978 -6.997 -0.019 - OH- 1.043e-07 9.948e-08 -6.982 -7.002 -0.021 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Ca 6.000e-04 - Ca+2 6.000e-04 4.985e-04 -3.222 -3.302 -0.081 - CaOH+ 8.617e-10 8.221e-10 -9.065 -9.085 -0.020 -Cl 1.200e-03 - Cl- 1.200e-03 1.144e-03 -2.921 -2.941 -0.021 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.404 -44.404 0.000 -O(0) 5.352e-04 - O2 2.676e-04 2.677e-04 -3.573 -3.572 0.000 + H+ 1.052e-07 1.006e-07 -6.978 -6.997 -0.019 0.00 + OH- 1.043e-07 9.948e-08 -6.982 -7.002 -0.021 (0) + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Ca 6.000e-04 + Ca+2 6.000e-04 4.985e-04 -3.222 -3.302 -0.081 -17.83 + CaOH+ 8.617e-10 8.221e-10 -9.065 -9.085 -0.020 (0) +Cl 1.200e-03 + Cl- 1.200e-03 1.144e-03 -2.921 -2.941 -0.021 17.82 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.404 -44.404 0.000 (0) +O(0) 5.352e-04 + O2 2.676e-04 2.677e-04 -3.573 -3.572 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -132,24 +132,24 @@ Initial solution 1. Initial solution for column ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.040e-07 1.002e-07 -6.983 -6.999 -0.016 - OH- 1.039e-07 9.991e-08 -6.983 -7.000 -0.017 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.404 -44.404 0.000 -K 2.000e-04 - K+ 2.000e-04 1.923e-04 -3.699 -3.716 -0.017 - KOH 6.654e-12 6.656e-12 -11.177 -11.177 0.000 -N(5) 1.200e-03 - NO3- 1.200e-03 1.154e-03 -2.921 -2.938 -0.017 -Na 1.000e-03 - Na+ 1.000e-03 9.621e-04 -3.000 -3.017 -0.017 - NaOH 6.342e-11 6.344e-11 -10.198 -10.198 0.000 -O(0) 5.352e-04 - O2 2.676e-04 2.677e-04 -3.572 -3.572 0.000 + H+ 1.040e-07 1.002e-07 -6.983 -6.999 -0.016 0.00 + OH- 1.039e-07 9.991e-08 -6.983 -7.000 -0.017 (0) + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.404 -44.404 0.000 (0) +K 2.000e-04 + K+ 2.000e-04 1.923e-04 -3.699 -3.716 -0.017 9.05 + KOH 6.654e-12 6.656e-12 -11.177 -11.177 0.000 (0) +N(5) 1.200e-03 + NO3- 1.200e-03 1.154e-03 -2.921 -2.938 -0.017 29.01 +Na 1.000e-03 + Na+ 1.000e-03 9.621e-04 -3.000 -3.017 -0.017 -1.19 + NaOH 6.342e-11 6.344e-11 -10.198 -10.198 0.000 (0) +O(0) 5.352e-04 + O2 2.676e-04 2.677e-04 -3.572 -3.572 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -450,31 +450,31 @@ X 1.100e-03 mol ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.040e-07 1.002e-07 -6.983 -6.999 -0.016 - OH- 1.039e-07 9.991e-08 -6.983 -7.000 -0.017 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.404 -44.404 0.000 -K 2.000e-04 - K+ 2.000e-04 1.923e-04 -3.699 -3.716 -0.017 - KOH 6.654e-12 6.656e-12 -11.177 -11.177 0.000 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -62.857 -62.874 -0.017 - NH3 0.000e+00 0.000e+00 -65.120 -65.120 0.000 -N(0) 1.729e-19 - N2 8.645e-20 8.647e-20 -19.063 -19.063 0.000 -N(3) 2.485e-16 - NO2- 2.485e-16 2.389e-16 -15.605 -15.622 -0.017 -N(5) 1.200e-03 - NO3- 1.200e-03 1.154e-03 -2.921 -2.938 -0.017 -Na 1.000e-03 - Na+ 1.000e-03 9.621e-04 -3.000 -3.017 -0.017 - NaOH 6.342e-11 6.344e-11 -10.198 -10.198 0.000 -O(0) 5.352e-04 - O2 2.676e-04 2.677e-04 -3.572 -3.572 0.000 + H+ 1.040e-07 1.002e-07 -6.983 -6.999 -0.016 0.00 + OH- 1.039e-07 9.991e-08 -6.983 -7.000 -0.017 (0) + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.404 -44.404 0.000 (0) +K 2.000e-04 + K+ 2.000e-04 1.923e-04 -3.699 -3.716 -0.017 9.05 + KOH 6.654e-12 6.656e-12 -11.177 -11.177 0.000 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -62.857 -62.874 -0.017 17.88 + NH3 0.000e+00 0.000e+00 -65.120 -65.120 0.000 (0) +N(0) 1.729e-19 + N2 8.645e-20 8.647e-20 -19.063 -19.063 0.000 (0) +N(3) 2.485e-16 + NO2- 2.485e-16 2.389e-16 -15.605 -15.622 -0.017 (0) +N(5) 1.200e-03 + NO3- 1.200e-03 1.154e-03 -2.921 -2.938 -0.017 29.01 +Na 1.000e-03 + Na+ 1.000e-03 9.621e-04 -3.000 -3.017 -0.017 -1.19 + NaOH 6.342e-11 6.344e-11 -10.198 -10.198 0.000 (0) +O(0) 5.352e-04 + O2 2.676e-04 2.677e-04 -3.572 -3.572 0.000 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex13a.out b/ex13a.out index 9053e9be..8c9ca076 100644 --- a/ex13a.out +++ b/ex13a.out @@ -71,23 +71,23 @@ Initial solution 0. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.046e-07 1.001e-07 -6.981 -7.000 -0.019 - H+ 1.042e-07 1.000e-07 -6.982 -7.000 -0.018 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -Cl 1.000e-03 - Cl- 1.000e-03 9.576e-04 -3.000 -3.019 -0.019 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 -N(5) 1.000e-03 - NO3- 1.000e-03 9.573e-04 -3.000 -3.019 -0.019 -Na 1.000e-03 - Na+ 1.000e-03 9.580e-04 -3.000 -3.019 -0.019 - NaOH 6.327e-11 6.329e-11 -10.199 -10.199 0.000 -O(0) 5.111e-04 - O2 2.556e-04 2.556e-04 -3.593 -3.592 0.000 + OH- 1.046e-07 1.001e-07 -6.981 -7.000 -0.019 (0) + H+ 1.042e-07 1.000e-07 -6.982 -7.000 -0.018 0.00 + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +Cl 1.000e-03 + Cl- 1.000e-03 9.576e-04 -3.000 -3.019 -0.019 17.82 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 (0) +N(5) 1.000e-03 + NO3- 1.000e-03 9.573e-04 -3.000 -3.019 -0.019 28.99 +Na 1.000e-03 + Na+ 1.000e-03 9.580e-04 -3.000 -3.019 -0.019 -1.21 + NaOH 6.327e-11 6.329e-11 -10.199 -10.199 0.000 (0) +O(0) 5.111e-04 + O2 2.556e-04 2.556e-04 -3.593 -3.592 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -155,21 +155,21 @@ Initial solution 1. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 - H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 -K 1.000e-03 - K+ 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 - KOH 3.345e-11 3.346e-11 -10.476 -10.476 0.000 -N(5) 1.000e-03 - NO3- 1.000e-03 9.647e-04 -3.000 -3.016 -0.016 -O(0) 5.112e-04 - O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 + OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 (0) + H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 (0) +K 1.000e-03 + K+ 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 9.05 + KOH 3.345e-11 3.346e-11 -10.476 -10.476 0.000 (0) +N(5) 1.000e-03 + NO3- 1.000e-03 9.647e-04 -3.000 -3.016 -0.016 29.01 +O(0) 5.112e-04 + O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -240,28 +240,28 @@ X 1.000e-03 mol ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 - H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 -K 1.000e-03 - K+ 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 - KOH 3.345e-11 3.346e-11 -10.476 -10.476 0.000 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -62.898 -62.914 -0.016 - NH3 0.000e+00 0.000e+00 -65.158 -65.158 0.000 -N(0) 1.351e-19 - N2 6.755e-20 6.756e-20 -19.170 -19.170 0.000 -N(3) 2.119e-16 - NO2- 2.119e-16 2.044e-16 -15.674 -15.689 -0.016 -N(5) 1.000e-03 - NO3- 1.000e-03 9.647e-04 -3.000 -3.016 -0.016 -O(0) 5.112e-04 - O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 + OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 (0) + H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 (0) +K 1.000e-03 + K+ 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 9.04 + KOH 3.345e-11 3.346e-11 -10.476 -10.476 0.000 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -62.898 -62.914 -0.016 17.87 + NH3 0.000e+00 0.000e+00 -65.158 -65.158 0.000 (0) +N(0) 1.351e-19 + N2 6.755e-20 6.756e-20 -19.170 -19.170 0.000 (0) +N(3) 2.119e-16 + NO2- 2.119e-16 2.044e-16 -15.674 -15.689 -0.016 (0) +N(5) 1.000e-03 + NO3- 1.000e-03 9.647e-04 -3.000 -3.016 -0.016 29.00 +O(0) 5.112e-04 + O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex13ac.out b/ex13ac.out index d091237a..cf2bd91a 100644 --- a/ex13ac.out +++ b/ex13ac.out @@ -71,23 +71,23 @@ Initial solution 0. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.046e-07 1.001e-07 -6.981 -7.000 -0.019 - H+ 1.042e-07 1.000e-07 -6.982 -7.000 -0.018 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -Cl 1.000e-03 - Cl- 1.000e-03 9.576e-04 -3.000 -3.019 -0.019 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 -N(5) 1.000e-03 - NO3- 1.000e-03 9.573e-04 -3.000 -3.019 -0.019 -Na 1.000e-03 - Na+ 1.000e-03 9.580e-04 -3.000 -3.019 -0.019 - NaOH 6.327e-11 6.329e-11 -10.199 -10.199 0.000 -O(0) 5.111e-04 - O2 2.556e-04 2.556e-04 -3.593 -3.592 0.000 + OH- 1.046e-07 1.001e-07 -6.981 -7.000 -0.019 (0) + H+ 1.042e-07 1.000e-07 -6.982 -7.000 -0.018 0.00 + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +Cl 1.000e-03 + Cl- 1.000e-03 9.576e-04 -3.000 -3.019 -0.019 17.82 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 (0) +N(5) 1.000e-03 + NO3- 1.000e-03 9.573e-04 -3.000 -3.019 -0.019 28.99 +Na 1.000e-03 + Na+ 1.000e-03 9.580e-04 -3.000 -3.019 -0.019 -1.21 + NaOH 6.327e-11 6.329e-11 -10.199 -10.199 0.000 (0) +O(0) 5.111e-04 + O2 2.556e-04 2.556e-04 -3.593 -3.592 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -155,21 +155,21 @@ Initial solution 1. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 - H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 -K 1.000e-03 - K+ 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 - KOH 3.345e-11 3.346e-11 -10.476 -10.476 0.000 -N(5) 1.000e-03 - NO3- 1.000e-03 9.647e-04 -3.000 -3.016 -0.016 -O(0) 5.112e-04 - O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 + OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 (0) + H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 (0) +K 1.000e-03 + K+ 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 9.05 + KOH 3.345e-11 3.346e-11 -10.476 -10.476 0.000 (0) +N(5) 1.000e-03 + NO3- 1.000e-03 9.647e-04 -3.000 -3.016 -0.016 29.01 +O(0) 5.112e-04 + O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -240,28 +240,28 @@ X 1.000e-03 mol ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 - H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 -K 1.000e-03 - K+ 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 - KOH 3.345e-11 3.346e-11 -10.476 -10.476 0.000 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -62.898 -62.914 -0.016 - NH3 0.000e+00 0.000e+00 -65.158 -65.158 0.000 -N(0) 1.351e-19 - N2 6.755e-20 6.756e-20 -19.170 -19.170 0.000 -N(3) 2.119e-16 - NO2- 2.119e-16 2.044e-16 -15.674 -15.689 -0.016 -N(5) 1.000e-03 - NO3- 1.000e-03 9.647e-04 -3.000 -3.016 -0.016 -O(0) 5.112e-04 - O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 + OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 (0) + H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 (0) +K 1.000e-03 + K+ 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 9.04 + KOH 3.345e-11 3.346e-11 -10.476 -10.476 0.000 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -62.898 -62.914 -0.016 17.87 + NH3 0.000e+00 0.000e+00 -65.158 -65.158 0.000 (0) +N(0) 1.351e-19 + N2 6.755e-20 6.756e-20 -19.170 -19.170 0.000 (0) +N(3) 2.119e-16 + NO2- 2.119e-16 2.044e-16 -15.674 -15.689 -0.016 (0) +N(5) 1.000e-03 + NO3- 1.000e-03 9.647e-04 -3.000 -3.016 -0.016 29.00 +O(0) 5.112e-04 + O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex13b.out b/ex13b.out index 994af5cb..b904485c 100644 --- a/ex13b.out +++ b/ex13b.out @@ -71,23 +71,23 @@ Initial solution 0. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.046e-07 1.001e-07 -6.981 -7.000 -0.019 - H+ 1.042e-07 1.000e-07 -6.982 -7.000 -0.018 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -Cl 1.000e-03 - Cl- 1.000e-03 9.576e-04 -3.000 -3.019 -0.019 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 -N(5) 1.000e-03 - NO3- 1.000e-03 9.573e-04 -3.000 -3.019 -0.019 -Na 1.000e-03 - Na+ 1.000e-03 9.580e-04 -3.000 -3.019 -0.019 - NaOH 6.327e-11 6.329e-11 -10.199 -10.199 0.000 -O(0) 5.111e-04 - O2 2.556e-04 2.556e-04 -3.593 -3.592 0.000 + OH- 1.046e-07 1.001e-07 -6.981 -7.000 -0.019 (0) + H+ 1.042e-07 1.000e-07 -6.982 -7.000 -0.018 0.00 + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +Cl 1.000e-03 + Cl- 1.000e-03 9.576e-04 -3.000 -3.019 -0.019 17.82 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 (0) +N(5) 1.000e-03 + NO3- 1.000e-03 9.573e-04 -3.000 -3.019 -0.019 28.99 +Na 1.000e-03 + Na+ 1.000e-03 9.580e-04 -3.000 -3.019 -0.019 -1.21 + NaOH 6.327e-11 6.329e-11 -10.199 -10.199 0.000 (0) +O(0) 5.111e-04 + O2 2.556e-04 2.556e-04 -3.593 -3.592 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -155,21 +155,21 @@ Initial solution 1. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 - H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 -K 1.000e-03 - K+ 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 - KOH 3.345e-11 3.346e-11 -10.476 -10.476 0.000 -N(5) 1.000e-03 - NO3- 1.000e-03 9.647e-04 -3.000 -3.016 -0.016 -O(0) 5.112e-04 - O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 + OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 (0) + H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 (0) +K 1.000e-03 + K+ 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 9.05 + KOH 3.345e-11 3.346e-11 -10.476 -10.476 0.000 (0) +N(5) 1.000e-03 + NO3- 1.000e-03 9.647e-04 -3.000 -3.016 -0.016 29.01 +O(0) 5.112e-04 + O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -240,28 +240,28 @@ X 1.000e-03 mol ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 - H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 -K 1.000e-03 - K+ 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 - KOH 3.345e-11 3.346e-11 -10.476 -10.476 0.000 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -62.898 -62.914 -0.016 - NH3 0.000e+00 0.000e+00 -65.158 -65.158 0.000 -N(0) 1.351e-19 - N2 6.755e-20 6.756e-20 -19.170 -19.170 0.000 -N(3) 2.119e-16 - NO2- 2.119e-16 2.044e-16 -15.674 -15.689 -0.016 -N(5) 1.000e-03 - NO3- 1.000e-03 9.647e-04 -3.000 -3.016 -0.016 -O(0) 5.112e-04 - O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 + OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 (0) + H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 (0) +K 1.000e-03 + K+ 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 9.04 + KOH 3.345e-11 3.346e-11 -10.476 -10.476 0.000 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -62.898 -62.914 -0.016 17.87 + NH3 0.000e+00 0.000e+00 -65.158 -65.158 0.000 (0) +N(0) 1.351e-19 + N2 6.755e-20 6.756e-20 -19.170 -19.170 0.000 (0) +N(3) 2.119e-16 + NO2- 2.119e-16 2.044e-16 -15.674 -15.689 -0.016 (0) +N(5) 1.000e-03 + NO3- 1.000e-03 9.647e-04 -3.000 -3.016 -0.016 29.00 +O(0) 5.112e-04 + O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex13c.out b/ex13c.out index 70b9556b..731edac8 100644 --- a/ex13c.out +++ b/ex13c.out @@ -71,23 +71,23 @@ Initial solution 0. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.046e-07 1.001e-07 -6.981 -7.000 -0.019 - H+ 1.042e-07 1.000e-07 -6.982 -7.000 -0.018 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -Cl 1.000e-03 - Cl- 1.000e-03 9.576e-04 -3.000 -3.019 -0.019 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 -N(5) 1.000e-03 - NO3- 1.000e-03 9.573e-04 -3.000 -3.019 -0.019 -Na 1.000e-03 - Na+ 1.000e-03 9.580e-04 -3.000 -3.019 -0.019 - NaOH 6.327e-11 6.329e-11 -10.199 -10.199 0.000 -O(0) 5.111e-04 - O2 2.556e-04 2.556e-04 -3.593 -3.592 0.000 + OH- 1.046e-07 1.001e-07 -6.981 -7.000 -0.019 (0) + H+ 1.042e-07 1.000e-07 -6.982 -7.000 -0.018 0.00 + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +Cl 1.000e-03 + Cl- 1.000e-03 9.576e-04 -3.000 -3.019 -0.019 17.82 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 (0) +N(5) 1.000e-03 + NO3- 1.000e-03 9.573e-04 -3.000 -3.019 -0.019 28.99 +Na 1.000e-03 + Na+ 1.000e-03 9.580e-04 -3.000 -3.019 -0.019 -1.21 + NaOH 6.327e-11 6.329e-11 -10.199 -10.199 0.000 (0) +O(0) 5.111e-04 + O2 2.556e-04 2.556e-04 -3.593 -3.592 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -155,21 +155,21 @@ Initial solution 1. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 - H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 -K 1.000e-03 - K+ 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 - KOH 3.345e-11 3.346e-11 -10.476 -10.476 0.000 -N(5) 1.000e-03 - NO3- 1.000e-03 9.647e-04 -3.000 -3.016 -0.016 -O(0) 5.112e-04 - O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 + OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 (0) + H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 (0) +K 1.000e-03 + K+ 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 9.05 + KOH 3.345e-11 3.346e-11 -10.476 -10.476 0.000 (0) +N(5) 1.000e-03 + NO3- 1.000e-03 9.647e-04 -3.000 -3.016 -0.016 29.01 +O(0) 5.112e-04 + O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -240,28 +240,28 @@ X 1.000e-03 mol ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 - H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 -K 1.000e-03 - K+ 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 - KOH 3.345e-11 3.346e-11 -10.476 -10.476 0.000 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -62.898 -62.914 -0.016 - NH3 0.000e+00 0.000e+00 -65.158 -65.158 0.000 -N(0) 1.351e-19 - N2 6.755e-20 6.756e-20 -19.170 -19.170 0.000 -N(3) 2.119e-16 - NO2- 2.119e-16 2.044e-16 -15.674 -15.689 -0.016 -N(5) 1.000e-03 - NO3- 1.000e-03 9.647e-04 -3.000 -3.016 -0.016 -O(0) 5.112e-04 - O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 + OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 (0) + H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 (0) +K 1.000e-03 + K+ 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 9.04 + KOH 3.345e-11 3.346e-11 -10.476 -10.476 0.000 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -62.898 -62.914 -0.016 17.87 + NH3 0.000e+00 0.000e+00 -65.158 -65.158 0.000 (0) +N(0) 1.351e-19 + N2 6.755e-20 6.756e-20 -19.170 -19.170 0.000 (0) +N(3) 2.119e-16 + NO2- 2.119e-16 2.044e-16 -15.674 -15.689 -0.016 (0) +N(5) 1.000e-03 + NO3- 1.000e-03 9.647e-04 -3.000 -3.016 -0.016 29.00 +O(0) 5.112e-04 + O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex14.out b/ex14.out index 71c94a99..fe4d94ce 100644 --- a/ex14.out +++ b/ex14.out @@ -102,79 +102,79 @@ Initial solution 1. Brine ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 2.755e-06 1.936e-06 -5.560 -5.713 -0.153 - OH- 7.396e-10 4.056e-09 -9.131 -8.392 0.739 - H2O 5.551e+01 7.846e-01 1.744 -0.105 0.000 -As(3) 1.105e-33 - H3AsO3 1.104e-33 5.888e-33 -32.957 -32.230 0.727 - H2AsO3- 3.925e-37 2.152e-36 -36.406 -35.667 0.739 - H4AsO3+ 1.030e-39 5.649e-39 -38.987 -38.248 0.739 - HAsO3-2 0.000e+00 0.000e+00 -47.611 -44.654 2.956 - AsO3-3 0.000e+00 0.000e+00 -61.293 -54.641 6.652 - AsS(OH)(HS)- 0.000e+00 0.000e+00 -302.845 -302.106 0.739 - As3S4(HS)2- 0.000e+00 0.000e+00 -899.967 -899.227 0.739 -As(5) 2.500e-08 - H2AsO4- 2.498e-08 1.370e-07 -7.602 -6.863 0.739 - H3AsO4 8.647e-12 4.611e-11 -11.063 -10.336 0.727 - HAsO4-2 8.576e-12 7.758e-09 -11.067 -8.110 2.956 - AsO4-3 2.823e-21 1.267e-14 -20.549 -13.897 6.652 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -143.997 -143.270 0.727 -C(4) 3.960e-03 - HCO3- 1.045e-03 6.049e-04 -2.981 -3.218 -0.238 - CaHCO3+ 1.002e-03 5.494e-03 -2.999 -2.260 0.739 - MgHCO3+ 6.754e-04 3.704e-03 -3.170 -2.431 0.739 - CO2 6.296e-04 3.357e-03 -3.201 -2.474 0.727 - NaHCO3 6.026e-04 3.213e-03 -3.220 -2.493 0.727 - CaCO3 3.278e-06 1.748e-05 -5.484 -4.758 0.727 - MgCO3 1.372e-06 7.316e-06 -5.863 -5.136 0.727 - NaCO3- 4.698e-07 2.577e-06 -6.328 -5.589 0.739 - CO3-2 1.307e-07 1.465e-08 -6.884 -7.834 -0.950 -Ca 4.655e-01 - Ca+2 4.629e-01 7.121e-01 -0.335 -0.147 0.187 - CaSO4 1.606e-03 8.565e-03 -2.794 -2.067 0.727 - CaHCO3+ 1.002e-03 5.494e-03 -2.999 -2.260 0.739 - CaCO3 3.278e-06 1.748e-05 -5.484 -4.758 0.727 - CaHSO4+ 1.772e-08 9.716e-08 -7.752 -7.012 0.739 - CaOH+ 8.731e-09 4.788e-08 -8.059 -7.320 0.739 -Cl 6.642e+00 - Cl- 6.642e+00 3.947e+00 0.822 0.596 -0.226 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -45.226 -44.499 0.727 -Mg 1.609e-01 - Mg+2 1.588e-01 5.233e-01 -0.799 -0.281 0.518 - MgSO4 1.387e-03 7.395e-03 -2.858 -2.131 0.727 - MgHCO3+ 6.754e-04 3.704e-03 -3.170 -2.431 0.739 - MgCO3 1.372e-06 7.316e-06 -5.863 -5.136 0.727 - MgOH+ 1.404e-07 7.698e-07 -6.853 -6.114 0.739 -Na 5.402e+00 - Na+ 5.401e+00 9.445e+00 0.732 0.975 0.243 - NaHCO3 6.026e-04 3.213e-03 -3.220 -2.493 0.727 - NaSO4- 5.203e-04 2.854e-03 -3.284 -2.545 0.739 - NaCO3- 4.698e-07 2.577e-06 -6.328 -5.589 0.739 -O(0) 9.589e-05 - O2 4.795e-05 2.556e-04 -4.319 -3.592 0.727 -S(-2) 0.000e+00 - H2S 0.000e+00 0.000e+00 -140.704 -139.977 0.727 - HS- 0.000e+00 0.000e+00 -141.945 -141.206 0.739 - S5-2 0.000e+00 0.000e+00 -144.615 -145.088 -0.473 - S4-2 0.000e+00 0.000e+00 -144.764 -145.322 -0.558 - S6-2 0.000e+00 0.000e+00 -144.964 -145.374 -0.410 - S3-2 0.000e+00 0.000e+00 -148.095 -148.775 -0.680 - S2-2 0.000e+00 0.000e+00 -149.207 -150.021 -0.813 - S-2 0.000e+00 0.000e+00 -151.367 -148.411 2.956 - AsS(OH)(HS)- 0.000e+00 0.000e+00 -302.845 -302.106 0.739 - As3S4(HS)2- 0.000e+00 0.000e+00 -899.967 -899.227 0.739 -S(6) 4.725e-03 - CaSO4 1.606e-03 8.565e-03 -2.794 -2.067 0.727 - MgSO4 1.387e-03 7.395e-03 -2.858 -2.131 0.727 - SO4-2 1.211e-03 6.028e-05 -2.917 -4.220 -1.303 - NaSO4- 5.203e-04 2.854e-03 -3.284 -2.545 0.739 - CaHSO4+ 1.772e-08 9.716e-08 -7.752 -7.012 0.739 - HSO4- 2.069e-09 1.135e-08 -8.684 -7.945 0.739 + H+ 2.755e-06 1.936e-06 -5.560 -5.713 -0.153 0.00 + OH- 7.396e-10 4.056e-09 -9.131 -8.392 0.739 (0) + H2O 5.551e+01 7.846e-01 1.744 -0.105 0.000 18.07 +As(3) 1.105e-33 + H3AsO3 1.104e-33 5.888e-33 -32.957 -32.230 0.727 (0) + H2AsO3- 3.925e-37 2.152e-36 -36.406 -35.667 0.739 (0) + H4AsO3+ 1.030e-39 5.649e-39 -38.987 -38.248 0.739 (0) + HAsO3-2 0.000e+00 0.000e+00 -47.611 -44.654 2.956 (0) + AsO3-3 0.000e+00 0.000e+00 -61.293 -54.641 6.652 (0) + AsS(OH)(HS)- 0.000e+00 0.000e+00 -302.845 -302.106 0.739 (0) + As3S4(HS)2- 0.000e+00 0.000e+00 -899.967 -899.227 0.739 (0) +As(5) 2.500e-08 + H2AsO4- 2.498e-08 1.370e-07 -7.602 -6.863 0.739 (0) + H3AsO4 8.647e-12 4.611e-11 -11.063 -10.336 0.727 (0) + HAsO4-2 8.576e-12 7.758e-09 -11.067 -8.110 2.956 (0) + AsO4-3 2.823e-21 1.267e-14 -20.549 -13.897 6.652 (0) +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -143.997 -143.270 0.727 (0) +C(4) 3.960e-03 + HCO3- 1.045e-03 6.049e-04 -2.981 -3.218 -0.238 (0) + CaHCO3+ 1.002e-03 5.494e-03 -2.999 -2.260 0.739 (0) + MgHCO3+ 6.754e-04 3.704e-03 -3.170 -2.431 0.739 (0) + CO2 6.296e-04 3.357e-03 -3.201 -2.474 0.727 (0) + NaHCO3 6.026e-04 3.213e-03 -3.220 -2.493 0.727 (0) + CaCO3 3.278e-06 1.748e-05 -5.484 -4.758 0.727 (0) + MgCO3 1.372e-06 7.316e-06 -5.863 -5.136 0.727 (0) + NaCO3- 4.698e-07 2.577e-06 -6.328 -5.589 0.739 (0) + CO3-2 1.307e-07 1.465e-08 -6.884 -7.834 -0.950 (0) +Ca 4.655e-01 + Ca+2 4.629e-01 7.121e-01 -0.335 -0.147 0.187 (0) + CaSO4 1.606e-03 8.565e-03 -2.794 -2.067 0.727 (0) + CaHCO3+ 1.002e-03 5.494e-03 -2.999 -2.260 0.739 (0) + CaCO3 3.278e-06 1.748e-05 -5.484 -4.758 0.727 (0) + CaHSO4+ 1.772e-08 9.716e-08 -7.752 -7.012 0.739 (0) + CaOH+ 8.731e-09 4.788e-08 -8.059 -7.320 0.739 (0) +Cl 6.642e+00 + Cl- 6.642e+00 3.947e+00 0.822 0.596 -0.226 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -45.226 -44.499 0.727 (0) +Mg 1.609e-01 + Mg+2 1.588e-01 5.233e-01 -0.799 -0.281 0.518 (0) + MgSO4 1.387e-03 7.395e-03 -2.858 -2.131 0.727 (0) + MgHCO3+ 6.754e-04 3.704e-03 -3.170 -2.431 0.739 (0) + MgCO3 1.372e-06 7.316e-06 -5.863 -5.136 0.727 (0) + MgOH+ 1.404e-07 7.698e-07 -6.853 -6.114 0.739 (0) +Na 5.402e+00 + Na+ 5.401e+00 9.445e+00 0.732 0.975 0.243 (0) + NaHCO3 6.026e-04 3.213e-03 -3.220 -2.493 0.727 (0) + NaSO4- 5.203e-04 2.854e-03 -3.284 -2.545 0.739 (0) + NaCO3- 4.698e-07 2.577e-06 -6.328 -5.589 0.739 (0) +O(0) 9.589e-05 + O2 4.795e-05 2.556e-04 -4.319 -3.592 0.727 (0) +S(-2) 0.000e+00 + H2S 0.000e+00 0.000e+00 -140.704 -139.977 0.727 (0) + HS- 0.000e+00 0.000e+00 -141.945 -141.206 0.739 (0) + S5-2 0.000e+00 0.000e+00 -144.615 -145.088 -0.473 (0) + S4-2 0.000e+00 0.000e+00 -144.764 -145.322 -0.558 (0) + S6-2 0.000e+00 0.000e+00 -144.964 -145.374 -0.410 (0) + S3-2 0.000e+00 0.000e+00 -148.095 -148.775 -0.680 (0) + S2-2 0.000e+00 0.000e+00 -149.207 -150.021 -0.813 (0) + S-2 0.000e+00 0.000e+00 -151.367 -148.411 2.956 (0) + AsS(OH)(HS)- 0.000e+00 0.000e+00 -302.845 -302.106 0.739 (0) + As3S4(HS)2- 0.000e+00 0.000e+00 -899.967 -899.227 0.739 (0) +S(6) 4.725e-03 + CaSO4 1.606e-03 8.565e-03 -2.794 -2.067 0.727 (0) + MgSO4 1.387e-03 7.395e-03 -2.858 -2.131 0.727 (0) + SO4-2 1.211e-03 6.028e-05 -2.917 -4.220 -1.303 (0) + NaSO4- 5.203e-04 2.854e-03 -3.284 -2.545 0.739 (0) + CaHSO4+ 1.772e-08 9.716e-08 -7.752 -7.012 0.739 (0) + HSO4- 2.069e-09 1.135e-08 -8.684 -7.945 0.739 (0) ------------------------------Saturation indices------------------------------- @@ -286,79 +286,79 @@ Dolomite 0.00 -17.09 -17.09 1.600e+00 1.599e+00 -7.679e-04 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 6.361e-06 4.471e-06 -5.196 -5.350 -0.153 - OH- 3.204e-10 1.757e-09 -9.494 -8.755 0.739 - H2O 5.551e+01 7.846e-01 1.744 -0.105 0.000 -As(3) 2.549e-33 - H3AsO3 2.549e-33 1.359e-32 -32.594 -31.867 0.727 - H2AsO3- 3.924e-37 2.152e-36 -36.406 -35.667 0.739 - H4AsO3+ 5.489e-39 3.010e-38 -38.260 -37.521 0.739 - HAsO3-2 0.000e+00 0.000e+00 -47.974 -45.018 2.956 - AsO3-3 0.000e+00 0.000e+00 -62.020 -55.368 6.652 - AsS(OH)(HS)- 0.000e+00 0.000e+00 -301.392 -300.653 0.739 - As3S4(HS)2- 0.000e+00 0.000e+00 -894.882 -894.143 0.739 -As(5) 2.500e-08 - H2AsO4- 2.498e-08 1.370e-07 -7.602 -6.863 0.739 - H3AsO4 1.996e-11 1.064e-10 -10.700 -9.973 0.727 - HAsO4-2 3.715e-12 3.359e-09 -11.430 -8.474 2.956 - AsO4-3 5.299e-22 2.376e-15 -21.276 -14.624 6.652 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -143.767 -143.040 0.727 -C(4) 3.514e-03 - CO2 1.068e-03 5.694e-03 -2.971 -2.245 0.727 - HCO3- 7.680e-04 4.444e-04 -3.115 -3.352 -0.238 - CaHCO3+ 7.345e-04 4.028e-03 -3.134 -2.395 0.739 - MgHCO3+ 4.991e-04 2.737e-03 -3.302 -2.563 0.739 - NaHCO3 4.428e-04 2.361e-03 -3.354 -2.627 0.727 - CaCO3 1.041e-06 5.550e-06 -5.983 -5.256 0.727 - MgCO3 4.392e-07 2.341e-06 -6.357 -5.631 0.727 - NaCO3- 1.495e-07 8.199e-07 -6.825 -6.086 0.739 - CO3-2 4.158e-08 4.662e-09 -7.381 -8.331 -0.950 -Ca 4.643e-01 - Ca+2 4.619e-01 7.106e-01 -0.335 -0.148 0.187 - CaSO4 1.601e-03 8.538e-03 -2.796 -2.069 0.727 - CaHCO3+ 7.345e-04 4.028e-03 -3.134 -2.395 0.739 - CaCO3 1.041e-06 5.550e-06 -5.983 -5.256 0.727 - CaHSO4+ 4.078e-08 2.236e-07 -7.390 -6.650 0.739 - CaOH+ 3.774e-09 2.069e-08 -8.423 -7.684 0.739 -Cl 6.642e+00 - Cl- 6.642e+00 3.947e+00 0.822 0.596 -0.226 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -45.226 -44.499 0.727 -Mg 1.617e-01 - Mg+2 1.598e-01 5.263e-01 -0.796 -0.279 0.518 - MgSO4 1.394e-03 7.430e-03 -2.856 -2.129 0.727 - MgHCO3+ 4.991e-04 2.737e-03 -3.302 -2.563 0.739 - MgCO3 4.392e-07 2.341e-06 -6.357 -5.631 0.727 - MgOH+ 6.115e-08 3.353e-07 -7.214 -6.475 0.739 -Na 5.402e+00 - Na+ 5.401e+00 9.445e+00 0.732 0.975 0.243 - NaSO4- 5.199e-04 2.851e-03 -3.284 -2.545 0.739 - NaHCO3 4.428e-04 2.361e-03 -3.354 -2.627 0.727 - NaCO3- 1.495e-07 8.199e-07 -6.825 -6.086 0.739 -O(0) 9.589e-05 - O2 4.795e-05 2.556e-04 -4.319 -3.592 0.727 -S(-2) 0.000e+00 - H2S 0.000e+00 0.000e+00 -139.978 -139.251 0.727 - HS- 0.000e+00 0.000e+00 -141.582 -140.843 0.739 - S5-2 0.000e+00 0.000e+00 -144.616 -145.088 -0.473 - S4-2 0.000e+00 0.000e+00 -144.765 -145.322 -0.558 - S6-2 0.000e+00 0.000e+00 -144.964 -145.374 -0.410 - S3-2 0.000e+00 0.000e+00 -148.095 -148.775 -0.680 - S2-2 0.000e+00 0.000e+00 -149.208 -150.021 -0.813 - S-2 0.000e+00 0.000e+00 -151.367 -148.411 2.956 - AsS(OH)(HS)- 0.000e+00 0.000e+00 -301.392 -300.653 0.739 - As3S4(HS)2- 0.000e+00 0.000e+00 -894.882 -894.143 0.739 -S(6) 4.725e-03 - CaSO4 1.601e-03 8.538e-03 -2.796 -2.069 0.727 - MgSO4 1.394e-03 7.430e-03 -2.856 -2.129 0.727 - SO4-2 1.210e-03 6.022e-05 -2.917 -4.220 -1.303 - NaSO4- 5.199e-04 2.851e-03 -3.284 -2.545 0.739 - CaHSO4+ 4.078e-08 2.236e-07 -7.390 -6.650 0.739 - HSO4- 4.774e-09 2.618e-08 -8.321 -7.582 0.739 + H+ 6.361e-06 4.471e-06 -5.196 -5.350 -0.153 0.00 + OH- 3.204e-10 1.757e-09 -9.494 -8.755 0.739 (0) + H2O 5.551e+01 7.846e-01 1.744 -0.105 0.000 18.07 +As(3) 2.549e-33 + H3AsO3 2.549e-33 1.359e-32 -32.594 -31.867 0.727 (0) + H2AsO3- 3.924e-37 2.152e-36 -36.406 -35.667 0.739 (0) + H4AsO3+ 5.489e-39 3.010e-38 -38.260 -37.521 0.739 (0) + HAsO3-2 0.000e+00 0.000e+00 -47.974 -45.018 2.956 (0) + AsO3-3 0.000e+00 0.000e+00 -62.020 -55.368 6.652 (0) + AsS(OH)(HS)- 0.000e+00 0.000e+00 -301.392 -300.653 0.739 (0) + As3S4(HS)2- 0.000e+00 0.000e+00 -894.882 -894.143 0.739 (0) +As(5) 2.500e-08 + H2AsO4- 2.498e-08 1.370e-07 -7.602 -6.863 0.739 (0) + H3AsO4 1.996e-11 1.064e-10 -10.700 -9.973 0.727 (0) + HAsO4-2 3.715e-12 3.359e-09 -11.430 -8.474 2.956 (0) + AsO4-3 5.299e-22 2.376e-15 -21.276 -14.624 6.652 (0) +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -143.767 -143.040 0.727 (0) +C(4) 3.514e-03 + CO2 1.068e-03 5.694e-03 -2.971 -2.245 0.727 (0) + HCO3- 7.680e-04 4.444e-04 -3.115 -3.352 -0.238 (0) + CaHCO3+ 7.345e-04 4.028e-03 -3.134 -2.395 0.739 (0) + MgHCO3+ 4.991e-04 2.737e-03 -3.302 -2.563 0.739 (0) + NaHCO3 4.428e-04 2.361e-03 -3.354 -2.627 0.727 (0) + CaCO3 1.041e-06 5.550e-06 -5.983 -5.256 0.727 (0) + MgCO3 4.392e-07 2.341e-06 -6.357 -5.631 0.727 (0) + NaCO3- 1.495e-07 8.199e-07 -6.825 -6.086 0.739 (0) + CO3-2 4.158e-08 4.662e-09 -7.381 -8.331 -0.950 (0) +Ca 4.643e-01 + Ca+2 4.619e-01 7.106e-01 -0.335 -0.148 0.187 (0) + CaSO4 1.601e-03 8.538e-03 -2.796 -2.069 0.727 (0) + CaHCO3+ 7.345e-04 4.028e-03 -3.134 -2.395 0.739 (0) + CaCO3 1.041e-06 5.550e-06 -5.983 -5.256 0.727 (0) + CaHSO4+ 4.078e-08 2.236e-07 -7.390 -6.650 0.739 (0) + CaOH+ 3.774e-09 2.069e-08 -8.423 -7.684 0.739 (0) +Cl 6.642e+00 + Cl- 6.642e+00 3.947e+00 0.822 0.596 -0.226 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -45.226 -44.499 0.727 (0) +Mg 1.617e-01 + Mg+2 1.598e-01 5.263e-01 -0.796 -0.279 0.518 (0) + MgSO4 1.394e-03 7.430e-03 -2.856 -2.129 0.727 (0) + MgHCO3+ 4.991e-04 2.737e-03 -3.302 -2.563 0.739 (0) + MgCO3 4.392e-07 2.341e-06 -6.357 -5.631 0.727 (0) + MgOH+ 6.115e-08 3.353e-07 -7.214 -6.475 0.739 (0) +Na 5.402e+00 + Na+ 5.401e+00 9.445e+00 0.732 0.975 0.243 (0) + NaSO4- 5.199e-04 2.851e-03 -3.284 -2.545 0.739 (0) + NaHCO3 4.428e-04 2.361e-03 -3.354 -2.627 0.727 (0) + NaCO3- 1.495e-07 8.199e-07 -6.825 -6.086 0.739 (0) +O(0) 9.589e-05 + O2 4.795e-05 2.556e-04 -4.319 -3.592 0.727 (0) +S(-2) 0.000e+00 + H2S 0.000e+00 0.000e+00 -139.978 -139.251 0.727 (0) + HS- 0.000e+00 0.000e+00 -141.582 -140.843 0.739 (0) + S5-2 0.000e+00 0.000e+00 -144.616 -145.088 -0.473 (0) + S4-2 0.000e+00 0.000e+00 -144.765 -145.322 -0.558 (0) + S6-2 0.000e+00 0.000e+00 -144.964 -145.374 -0.410 (0) + S3-2 0.000e+00 0.000e+00 -148.095 -148.775 -0.680 (0) + S2-2 0.000e+00 0.000e+00 -149.208 -150.021 -0.813 (0) + S-2 0.000e+00 0.000e+00 -151.367 -148.411 2.956 (0) + AsS(OH)(HS)- 0.000e+00 0.000e+00 -301.392 -300.653 0.739 (0) + As3S4(HS)2- 0.000e+00 0.000e+00 -894.882 -894.143 0.739 (0) +S(6) 4.725e-03 + CaSO4 1.601e-03 8.538e-03 -2.796 -2.069 0.727 (0) + MgSO4 1.394e-03 7.430e-03 -2.856 -2.129 0.727 (0) + SO4-2 1.210e-03 6.022e-05 -2.917 -4.220 -1.303 (0) + NaSO4- 5.199e-04 2.851e-03 -3.284 -2.545 0.739 (0) + CaHSO4+ 4.078e-08 2.236e-07 -7.390 -6.650 0.739 (0) + HSO4- 4.774e-09 2.618e-08 -8.321 -7.582 0.739 (0) ------------------------------Saturation indices------------------------------- @@ -523,64 +523,64 @@ Initial solution 0. 20 x precipitation ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 2.600e-05 2.512e-05 -4.585 -4.600 -0.015 - OH- 4.132e-10 3.985e-10 -9.384 -9.400 -0.016 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -145.553 -145.553 0.000 -C(4) 1.096e-05 - CO2 1.076e-05 1.076e-05 -4.968 -4.968 0.000 - HCO3- 1.975e-07 1.906e-07 -6.704 -6.720 -0.015 - CaHCO3+ 4.049e-10 3.905e-10 -9.393 -9.408 -0.016 - MgHCO3+ 6.905e-11 6.660e-11 -10.161 -10.177 -0.016 - NaHCO3 1.267e-11 1.267e-11 -10.897 -10.897 0.000 - CO3-2 4.105e-13 3.559e-13 -12.387 -12.449 -0.062 - CaCO3 9.575e-14 9.577e-14 -13.019 -13.019 0.000 - MgCO3 1.014e-14 1.014e-14 -13.994 -13.994 0.000 - NaCO3- 8.122e-16 7.833e-16 -15.090 -15.106 -0.016 -Ca 1.916e-04 - Ca+2 1.853e-04 1.606e-04 -3.732 -3.794 -0.062 - CaSO4 6.296e-06 6.297e-06 -5.201 -5.201 0.000 - CaHSO4+ 9.608e-10 9.267e-10 -9.017 -9.033 -0.016 - CaHCO3+ 4.049e-10 3.905e-10 -9.393 -9.408 -0.016 - CaOH+ 1.100e-12 1.061e-12 -11.958 -11.974 -0.016 - CaCO3 9.575e-14 9.577e-14 -13.019 -13.019 0.000 -Cl 1.337e-04 - Cl- 1.337e-04 1.289e-04 -3.874 -3.890 -0.016 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 -Mg 3.580e-05 - Mg+2 3.442e-05 2.986e-05 -4.463 -4.525 -0.062 - MgSO4 1.375e-06 1.375e-06 -5.862 -5.862 0.000 - MgHCO3+ 6.905e-11 6.660e-11 -10.161 -10.177 -0.016 - MgOH+ 4.475e-12 4.316e-12 -11.349 -11.365 -0.016 - MgCO3 1.014e-14 1.014e-14 -13.994 -13.994 0.000 -Na 1.227e-04 - Na+ 1.225e-04 1.182e-04 -3.912 -3.927 -0.016 - NaSO4- 1.207e-07 1.164e-07 -6.918 -6.934 -0.016 - NaHCO3 1.267e-11 1.267e-11 -10.897 -10.897 0.000 - NaCO3- 8.122e-16 7.833e-16 -15.090 -15.106 -0.016 -O(0) 5.112e-04 - O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 -S(-2) 0.000e+00 - H2S 0.000e+00 0.000e+00 -137.238 -137.238 0.000 - HS- 0.000e+00 0.000e+00 -139.564 -139.580 -0.016 - S5-2 0.000e+00 0.000e+00 -144.517 -144.575 -0.058 - S4-2 0.000e+00 0.000e+00 -144.749 -144.809 -0.059 - S6-2 0.000e+00 0.000e+00 -144.804 -144.861 -0.057 - S-2 0.000e+00 0.000e+00 -147.835 -147.898 -0.063 - S3-2 0.000e+00 0.000e+00 -148.201 -148.262 -0.060 - S2-2 0.000e+00 0.000e+00 -149.446 -149.508 -0.061 -S(6) 2.351e-04 - SO4-2 2.268e-04 1.965e-04 -3.644 -3.707 -0.062 - CaSO4 6.296e-06 6.297e-06 -5.201 -5.201 0.000 - MgSO4 1.375e-06 1.375e-06 -5.862 -5.862 0.000 - HSO4- 4.975e-07 4.798e-07 -6.303 -6.319 -0.016 - NaSO4- 1.207e-07 1.164e-07 -6.918 -6.934 -0.016 - CaHSO4+ 9.608e-10 9.267e-10 -9.017 -9.033 -0.016 + H+ 2.600e-05 2.512e-05 -4.585 -4.600 -0.015 0.00 + OH- 4.132e-10 3.985e-10 -9.384 -9.400 -0.016 (0) + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -145.553 -145.553 0.000 (0) +C(4) 1.096e-05 + CO2 1.076e-05 1.076e-05 -4.968 -4.968 0.000 (0) + HCO3- 1.975e-07 1.906e-07 -6.704 -6.720 -0.015 (0) + CaHCO3+ 4.049e-10 3.905e-10 -9.393 -9.408 -0.016 (0) + MgHCO3+ 6.905e-11 6.660e-11 -10.161 -10.177 -0.016 (0) + NaHCO3 1.267e-11 1.267e-11 -10.897 -10.897 0.000 (0) + CO3-2 4.105e-13 3.559e-13 -12.387 -12.449 -0.062 (0) + CaCO3 9.575e-14 9.577e-14 -13.019 -13.019 0.000 (0) + MgCO3 1.014e-14 1.014e-14 -13.994 -13.994 0.000 (0) + NaCO3- 8.122e-16 7.833e-16 -15.090 -15.106 -0.016 (0) +Ca 1.916e-04 + Ca+2 1.853e-04 1.606e-04 -3.732 -3.794 -0.062 (0) + CaSO4 6.296e-06 6.297e-06 -5.201 -5.201 0.000 (0) + CaHSO4+ 9.608e-10 9.267e-10 -9.017 -9.033 -0.016 (0) + CaHCO3+ 4.049e-10 3.905e-10 -9.393 -9.408 -0.016 (0) + CaOH+ 1.100e-12 1.061e-12 -11.958 -11.974 -0.016 (0) + CaCO3 9.575e-14 9.577e-14 -13.019 -13.019 0.000 (0) +Cl 1.337e-04 + Cl- 1.337e-04 1.289e-04 -3.874 -3.890 -0.016 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.394 -44.394 0.000 (0) +Mg 3.580e-05 + Mg+2 3.442e-05 2.986e-05 -4.463 -4.525 -0.062 (0) + MgSO4 1.375e-06 1.375e-06 -5.862 -5.862 0.000 (0) + MgHCO3+ 6.905e-11 6.660e-11 -10.161 -10.177 -0.016 (0) + MgOH+ 4.475e-12 4.316e-12 -11.349 -11.365 -0.016 (0) + MgCO3 1.014e-14 1.014e-14 -13.994 -13.994 0.000 (0) +Na 1.227e-04 + Na+ 1.225e-04 1.182e-04 -3.912 -3.927 -0.016 (0) + NaSO4- 1.207e-07 1.164e-07 -6.918 -6.934 -0.016 (0) + NaHCO3 1.267e-11 1.267e-11 -10.897 -10.897 0.000 (0) + NaCO3- 8.122e-16 7.833e-16 -15.090 -15.106 -0.016 (0) +O(0) 5.112e-04 + O2 2.556e-04 2.556e-04 -3.592 -3.592 0.000 (0) +S(-2) 0.000e+00 + H2S 0.000e+00 0.000e+00 -137.238 -137.238 0.000 (0) + HS- 0.000e+00 0.000e+00 -139.564 -139.580 -0.016 (0) + S5-2 0.000e+00 0.000e+00 -144.517 -144.575 -0.058 (0) + S4-2 0.000e+00 0.000e+00 -144.749 -144.809 -0.059 (0) + S6-2 0.000e+00 0.000e+00 -144.804 -144.861 -0.057 (0) + S-2 0.000e+00 0.000e+00 -147.835 -147.898 -0.063 (0) + S3-2 0.000e+00 0.000e+00 -148.201 -148.262 -0.060 (0) + S2-2 0.000e+00 0.000e+00 -149.446 -149.508 -0.061 (0) +S(6) 2.351e-04 + SO4-2 2.268e-04 1.965e-04 -3.644 -3.707 -0.062 (0) + CaSO4 6.296e-06 6.297e-06 -5.201 -5.201 0.000 (0) + MgSO4 1.375e-06 1.375e-06 -5.862 -5.862 0.000 (0) + HSO4- 4.975e-07 4.798e-07 -6.303 -6.319 -0.016 (0) + NaSO4- 1.207e-07 1.164e-07 -6.918 -6.934 -0.016 (0) + CaHSO4+ 9.608e-10 9.267e-10 -9.017 -9.033 -0.016 (0) ------------------------------Saturation indices------------------------------- @@ -663,64 +663,64 @@ Dolomite -0.00 -17.09 -17.09 1.600e+00 1.599e+00 -1.349e-03 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.234e-07 1.115e-07 -6.909 -6.953 -0.044 - H+ 9.814e-08 8.977e-08 -7.008 -7.047 -0.039 - H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -143.556 -143.555 0.001 -C(4) 7.120e-03 - HCO3- 5.883e-03 5.333e-03 -2.230 -2.273 -0.043 - CO2 1.074e-03 1.077e-03 -2.969 -2.968 0.001 - CaHCO3+ 8.950e-05 8.087e-05 -4.048 -4.092 -0.044 - MgHCO3+ 6.082e-05 5.496e-05 -4.216 -4.260 -0.044 - CaCO3 5.537e-06 5.550e-06 -5.257 -5.256 0.001 - CO3-2 4.124e-06 2.786e-06 -5.385 -5.555 -0.170 - MgCO3 2.336e-06 2.341e-06 -5.631 -5.631 0.001 - NaHCO3 3.310e-07 3.317e-07 -6.480 -6.479 0.001 - NaCO3- 6.351e-09 5.738e-09 -8.197 -8.241 -0.044 -Ca 1.885e-03 - Ca+2 1.761e-03 1.189e-03 -2.754 -2.925 -0.171 - CaHCO3+ 8.950e-05 8.087e-05 -4.048 -4.092 -0.044 - CaSO4 2.881e-05 2.887e-05 -4.540 -4.539 0.001 - CaCO3 5.537e-06 5.550e-06 -5.257 -5.256 0.001 - CaOH+ 2.432e-09 2.198e-09 -8.614 -8.658 -0.044 - CaHSO4+ 1.681e-11 1.518e-11 -10.775 -10.819 -0.044 -Cl 1.337e-04 - Cl- 1.337e-04 1.206e-04 -3.874 -3.919 -0.045 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.395 -44.394 0.001 -Mg 1.385e-03 - Mg+2 1.296e-03 8.806e-04 -2.887 -3.055 -0.168 - MgHCO3+ 6.082e-05 5.496e-05 -4.216 -4.260 -0.044 - MgSO4 2.507e-05 2.513e-05 -4.601 -4.600 0.001 - MgCO3 2.336e-06 2.341e-06 -5.631 -5.631 0.001 - MgOH+ 3.941e-08 3.561e-08 -7.404 -7.448 -0.044 -Na 1.227e-04 - Na+ 1.223e-04 1.106e-04 -3.913 -3.956 -0.044 - NaHCO3 3.310e-07 3.317e-07 -6.480 -6.479 0.001 - NaSO4- 7.467e-08 6.747e-08 -7.127 -7.171 -0.044 - NaCO3- 6.351e-09 5.738e-09 -8.197 -8.241 -0.044 -O(0) 5.112e-04 - O2 2.556e-04 2.562e-04 -3.592 -3.591 0.001 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -142.192 -142.236 -0.044 - H2S 0.000e+00 0.000e+00 -142.342 -142.341 0.001 - S5-2 0.000e+00 0.000e+00 -144.640 -144.784 -0.144 - S4-2 0.000e+00 0.000e+00 -144.867 -145.018 -0.151 - S6-2 0.000e+00 0.000e+00 -144.933 -145.070 -0.138 - S-2 0.000e+00 0.000e+00 -147.931 -148.107 -0.176 - S3-2 0.000e+00 0.000e+00 -148.312 -148.471 -0.159 - S2-2 0.000e+00 0.000e+00 -149.552 -149.717 -0.165 -S(6) 2.351e-04 - SO4-2 1.811e-04 1.217e-04 -3.742 -3.915 -0.173 - CaSO4 2.881e-05 2.887e-05 -4.540 -4.539 0.001 - MgSO4 2.507e-05 2.513e-05 -4.601 -4.600 0.001 - NaSO4- 7.467e-08 6.747e-08 -7.127 -7.171 -0.044 - HSO4- 1.176e-09 1.062e-09 -8.930 -8.974 -0.044 - CaHSO4+ 1.681e-11 1.518e-11 -10.775 -10.819 -0.044 + OH- 1.234e-07 1.115e-07 -6.909 -6.953 -0.044 (0) + H+ 9.814e-08 8.977e-08 -7.008 -7.047 -0.039 0.00 + H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -143.556 -143.555 0.001 (0) +C(4) 7.120e-03 + HCO3- 5.883e-03 5.333e-03 -2.230 -2.273 -0.043 (0) + CO2 1.074e-03 1.077e-03 -2.969 -2.968 0.001 (0) + CaHCO3+ 8.950e-05 8.087e-05 -4.048 -4.092 -0.044 (0) + MgHCO3+ 6.082e-05 5.496e-05 -4.216 -4.260 -0.044 (0) + CaCO3 5.537e-06 5.550e-06 -5.257 -5.256 0.001 (0) + CO3-2 4.124e-06 2.786e-06 -5.385 -5.555 -0.170 (0) + MgCO3 2.336e-06 2.341e-06 -5.631 -5.631 0.001 (0) + NaHCO3 3.310e-07 3.317e-07 -6.480 -6.479 0.001 (0) + NaCO3- 6.351e-09 5.738e-09 -8.197 -8.241 -0.044 (0) +Ca 1.885e-03 + Ca+2 1.761e-03 1.189e-03 -2.754 -2.925 -0.171 (0) + CaHCO3+ 8.950e-05 8.087e-05 -4.048 -4.092 -0.044 (0) + CaSO4 2.881e-05 2.887e-05 -4.540 -4.539 0.001 (0) + CaCO3 5.537e-06 5.550e-06 -5.257 -5.256 0.001 (0) + CaOH+ 2.432e-09 2.198e-09 -8.614 -8.658 -0.044 (0) + CaHSO4+ 1.681e-11 1.518e-11 -10.775 -10.819 -0.044 (0) +Cl 1.337e-04 + Cl- 1.337e-04 1.206e-04 -3.874 -3.919 -0.045 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.395 -44.394 0.001 (0) +Mg 1.385e-03 + Mg+2 1.296e-03 8.806e-04 -2.887 -3.055 -0.168 (0) + MgHCO3+ 6.082e-05 5.496e-05 -4.216 -4.260 -0.044 (0) + MgSO4 2.507e-05 2.513e-05 -4.601 -4.600 0.001 (0) + MgCO3 2.336e-06 2.341e-06 -5.631 -5.631 0.001 (0) + MgOH+ 3.941e-08 3.561e-08 -7.404 -7.448 -0.044 (0) +Na 1.227e-04 + Na+ 1.223e-04 1.106e-04 -3.913 -3.956 -0.044 (0) + NaHCO3 3.310e-07 3.317e-07 -6.480 -6.479 0.001 (0) + NaSO4- 7.467e-08 6.747e-08 -7.127 -7.171 -0.044 (0) + NaCO3- 6.351e-09 5.738e-09 -8.197 -8.241 -0.044 (0) +O(0) 5.112e-04 + O2 2.556e-04 2.562e-04 -3.592 -3.591 0.001 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -142.192 -142.236 -0.044 (0) + H2S 0.000e+00 0.000e+00 -142.342 -142.341 0.001 (0) + S5-2 0.000e+00 0.000e+00 -144.640 -144.784 -0.144 (0) + S4-2 0.000e+00 0.000e+00 -144.867 -145.018 -0.151 (0) + S6-2 0.000e+00 0.000e+00 -144.933 -145.070 -0.138 (0) + S-2 0.000e+00 0.000e+00 -147.931 -148.107 -0.176 (0) + S3-2 0.000e+00 0.000e+00 -148.312 -148.471 -0.159 (0) + S2-2 0.000e+00 0.000e+00 -149.552 -149.717 -0.165 (0) +S(6) 2.351e-04 + SO4-2 1.811e-04 1.217e-04 -3.742 -3.915 -0.173 (0) + CaSO4 2.881e-05 2.887e-05 -4.540 -4.539 0.001 (0) + MgSO4 2.507e-05 2.513e-05 -4.601 -4.600 0.001 (0) + NaSO4- 7.467e-08 6.747e-08 -7.127 -7.171 -0.044 (0) + HSO4- 1.176e-09 1.062e-09 -8.930 -8.974 -0.044 (0) + CaHSO4+ 1.681e-11 1.518e-11 -10.775 -10.819 -0.044 (0) ------------------------------Saturation indices------------------------------- @@ -1066,79 +1066,79 @@ X 1.000e+00 mol ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.231e-07 1.112e-07 -6.910 -6.954 -0.044 - H+ 9.839e-08 9.000e-08 -7.007 -7.046 -0.039 - H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 -As(3) 4.168e-38 - H3AsO3 4.131e-38 4.141e-38 -37.384 -37.383 0.001 - H2AsO3- 3.605e-40 3.257e-40 -39.443 -39.487 -0.044 - H4AsO3+ 0.000e+00 0.000e+00 -44.690 -44.734 -0.044 - HAsO3-2 0.000e+00 0.000e+00 -46.965 -47.141 -0.176 - AsO3-3 0.000e+00 0.000e+00 -55.399 -55.796 -0.396 - AsS(OH)(HS)- 0.000e+00 0.000e+00 -310.817 -310.861 -0.044 - As3S4(HS)2- 0.000e+00 0.000e+00 -928.430 -928.475 -0.044 -As(5) 6.090e-11 - HAsO4-2 3.793e-11 2.529e-11 -10.421 -10.597 -0.176 - H2AsO4- 2.297e-11 2.075e-11 -10.639 -10.683 -0.044 - AsO4-3 2.213e-15 8.885e-16 -14.655 -15.051 -0.396 - H3AsO4 3.239e-16 3.246e-16 -15.490 -15.489 0.001 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -143.555 -143.554 0.001 -C(4) 7.117e-03 - HCO3- 5.879e-03 5.330e-03 -2.231 -2.273 -0.043 - CO2 1.076e-03 1.079e-03 -2.968 -2.967 0.001 - CaHCO3+ 8.738e-05 7.896e-05 -4.059 -4.103 -0.044 - MgHCO3+ 6.261e-05 5.658e-05 -4.203 -4.247 -0.044 - CaCO3 5.393e-06 5.404e-06 -5.268 -5.267 0.001 - CO3-2 4.110e-06 2.777e-06 -5.386 -5.556 -0.170 - MgCO3 2.399e-06 2.404e-06 -5.620 -5.619 0.001 - NaHCO3 3.310e-07 3.317e-07 -6.480 -6.479 0.001 - NaCO3- 6.335e-09 5.724e-09 -8.198 -8.242 -0.044 -Ca 1.841e-03 - Ca+2 1.720e-03 1.161e-03 -2.764 -2.935 -0.171 - CaHCO3+ 8.738e-05 7.896e-05 -4.059 -4.103 -0.044 - CaSO4 2.814e-05 2.820e-05 -4.551 -4.550 0.001 - CaCO3 5.393e-06 5.404e-06 -5.268 -5.267 0.001 - CaOH+ 2.370e-09 2.141e-09 -8.625 -8.669 -0.044 - CaHSO4+ 1.645e-11 1.487e-11 -10.784 -10.828 -0.044 -Cl 1.337e-04 - Cl- 1.337e-04 1.206e-04 -3.874 -3.919 -0.045 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.395 -44.394 0.001 -Mg 1.426e-03 - Mg+2 1.335e-03 9.072e-04 -2.874 -3.042 -0.168 - MgHCO3+ 6.261e-05 5.658e-05 -4.203 -4.247 -0.044 - MgSO4 2.582e-05 2.588e-05 -4.588 -4.587 0.001 - MgCO3 2.399e-06 2.404e-06 -5.620 -5.619 0.001 - MgOH+ 4.050e-08 3.659e-08 -7.393 -7.437 -0.044 -Na 1.228e-04 - Na+ 1.223e-04 1.107e-04 -3.912 -3.956 -0.044 - NaHCO3 3.310e-07 3.317e-07 -6.480 -6.479 0.001 - NaSO4- 7.470e-08 6.750e-08 -7.127 -7.171 -0.044 - NaCO3- 6.335e-09 5.724e-09 -8.198 -8.242 -0.044 -O(0) 5.112e-04 - O2 2.556e-04 2.562e-04 -3.592 -3.591 0.001 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -142.191 -142.235 -0.044 - H2S 0.000e+00 0.000e+00 -142.340 -142.339 0.001 - S5-2 0.000e+00 0.000e+00 -144.640 -144.784 -0.144 - S4-2 0.000e+00 0.000e+00 -144.867 -145.018 -0.151 - S6-2 0.000e+00 0.000e+00 -144.933 -145.070 -0.138 - S-2 0.000e+00 0.000e+00 -147.931 -148.107 -0.176 - S3-2 0.000e+00 0.000e+00 -148.313 -148.471 -0.159 - S2-2 0.000e+00 0.000e+00 -149.552 -149.717 -0.165 - AsS(OH)(HS)- 0.000e+00 0.000e+00 -310.817 -310.861 -0.044 - As3S4(HS)2- 0.000e+00 0.000e+00 -928.430 -928.475 -0.044 -S(6) 2.351e-04 - SO4-2 1.810e-04 1.217e-04 -3.742 -3.915 -0.173 - CaSO4 2.814e-05 2.820e-05 -4.551 -4.550 0.001 - MgSO4 2.582e-05 2.588e-05 -4.588 -4.587 0.001 - NaSO4- 7.470e-08 6.750e-08 -7.127 -7.171 -0.044 - HSO4- 1.178e-09 1.065e-09 -8.929 -8.973 -0.044 - CaHSO4+ 1.645e-11 1.487e-11 -10.784 -10.828 -0.044 + OH- 1.231e-07 1.112e-07 -6.910 -6.954 -0.044 (0) + H+ 9.839e-08 9.000e-08 -7.007 -7.046 -0.039 0.00 + H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 18.07 +As(3) 4.168e-38 + H3AsO3 4.131e-38 4.141e-38 -37.384 -37.383 0.001 (0) + H2AsO3- 3.605e-40 3.257e-40 -39.443 -39.487 -0.044 (0) + H4AsO3+ 0.000e+00 0.000e+00 -44.690 -44.734 -0.044 (0) + HAsO3-2 0.000e+00 0.000e+00 -46.965 -47.141 -0.176 (0) + AsO3-3 0.000e+00 0.000e+00 -55.399 -55.796 -0.396 (0) + AsS(OH)(HS)- 0.000e+00 0.000e+00 -310.817 -310.861 -0.044 (0) + As3S4(HS)2- 0.000e+00 0.000e+00 -928.430 -928.475 -0.044 (0) +As(5) 6.090e-11 + HAsO4-2 3.793e-11 2.529e-11 -10.421 -10.597 -0.176 (0) + H2AsO4- 2.297e-11 2.075e-11 -10.639 -10.683 -0.044 (0) + AsO4-3 2.213e-15 8.885e-16 -14.655 -15.051 -0.396 (0) + H3AsO4 3.239e-16 3.246e-16 -15.490 -15.489 0.001 (0) +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -143.555 -143.554 0.001 (0) +C(4) 7.117e-03 + HCO3- 5.879e-03 5.330e-03 -2.231 -2.273 -0.043 (0) + CO2 1.076e-03 1.079e-03 -2.968 -2.967 0.001 (0) + CaHCO3+ 8.738e-05 7.896e-05 -4.059 -4.103 -0.044 (0) + MgHCO3+ 6.261e-05 5.658e-05 -4.203 -4.247 -0.044 (0) + CaCO3 5.393e-06 5.404e-06 -5.268 -5.267 0.001 (0) + CO3-2 4.110e-06 2.777e-06 -5.386 -5.556 -0.170 (0) + MgCO3 2.399e-06 2.404e-06 -5.620 -5.619 0.001 (0) + NaHCO3 3.310e-07 3.317e-07 -6.480 -6.479 0.001 (0) + NaCO3- 6.335e-09 5.724e-09 -8.198 -8.242 -0.044 (0) +Ca 1.841e-03 + Ca+2 1.720e-03 1.161e-03 -2.764 -2.935 -0.171 (0) + CaHCO3+ 8.738e-05 7.896e-05 -4.059 -4.103 -0.044 (0) + CaSO4 2.814e-05 2.820e-05 -4.551 -4.550 0.001 (0) + CaCO3 5.393e-06 5.404e-06 -5.268 -5.267 0.001 (0) + CaOH+ 2.370e-09 2.141e-09 -8.625 -8.669 -0.044 (0) + CaHSO4+ 1.645e-11 1.487e-11 -10.784 -10.828 -0.044 (0) +Cl 1.337e-04 + Cl- 1.337e-04 1.206e-04 -3.874 -3.919 -0.045 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.395 -44.394 0.001 (0) +Mg 1.426e-03 + Mg+2 1.335e-03 9.072e-04 -2.874 -3.042 -0.168 (0) + MgHCO3+ 6.261e-05 5.658e-05 -4.203 -4.247 -0.044 (0) + MgSO4 2.582e-05 2.588e-05 -4.588 -4.587 0.001 (0) + MgCO3 2.399e-06 2.404e-06 -5.620 -5.619 0.001 (0) + MgOH+ 4.050e-08 3.659e-08 -7.393 -7.437 -0.044 (0) +Na 1.228e-04 + Na+ 1.223e-04 1.107e-04 -3.912 -3.956 -0.044 (0) + NaHCO3 3.310e-07 3.317e-07 -6.480 -6.479 0.001 (0) + NaSO4- 7.470e-08 6.750e-08 -7.127 -7.171 -0.044 (0) + NaCO3- 6.335e-09 5.724e-09 -8.198 -8.242 -0.044 (0) +O(0) 5.112e-04 + O2 2.556e-04 2.562e-04 -3.592 -3.591 0.001 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -142.191 -142.235 -0.044 (0) + H2S 0.000e+00 0.000e+00 -142.340 -142.339 0.001 (0) + S5-2 0.000e+00 0.000e+00 -144.640 -144.784 -0.144 (0) + S4-2 0.000e+00 0.000e+00 -144.867 -145.018 -0.151 (0) + S6-2 0.000e+00 0.000e+00 -144.933 -145.070 -0.138 (0) + S-2 0.000e+00 0.000e+00 -147.931 -148.107 -0.176 (0) + S3-2 0.000e+00 0.000e+00 -148.313 -148.471 -0.159 (0) + S2-2 0.000e+00 0.000e+00 -149.552 -149.717 -0.165 (0) + AsS(OH)(HS)- 0.000e+00 0.000e+00 -310.817 -310.861 -0.044 (0) + As3S4(HS)2- 0.000e+00 0.000e+00 -928.430 -928.475 -0.044 (0) +S(6) 2.351e-04 + SO4-2 1.810e-04 1.217e-04 -3.742 -3.915 -0.173 (0) + CaSO4 2.814e-05 2.820e-05 -4.551 -4.550 0.001 (0) + MgSO4 2.582e-05 2.588e-05 -4.588 -4.587 0.001 (0) + NaSO4- 7.470e-08 6.750e-08 -7.127 -7.171 -0.044 (0) + HSO4- 1.178e-09 1.065e-09 -8.929 -8.973 -0.044 (0) + CaHSO4+ 1.645e-11 1.487e-11 -10.784 -10.828 -0.044 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex16.out b/ex16.out index d9289f8a..159ec126 100644 --- a/ex16.out +++ b/ex16.out @@ -94,63 +94,63 @@ Initial solution 1. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 6.464e-07 6.310e-07 -6.189 -6.200 -0.011 - OH- 1.627e-08 1.587e-08 -7.789 -7.800 -0.011 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -C(4) 7.825e-04 - CO2 4.540e-04 4.540e-04 -3.343 -3.343 0.000 - HCO3- 3.281e-04 3.200e-04 -3.484 -3.495 -0.011 - CaHCO3+ 2.940e-07 2.868e-07 -6.532 -6.542 -0.011 - MgHCO3+ 1.003e-07 9.783e-08 -6.999 -7.010 -0.011 - CO3-2 2.628e-08 2.379e-08 -7.580 -7.624 -0.043 - NaHCO3 2.351e-08 2.352e-08 -7.629 -7.629 0.000 - CaCO3 2.806e-09 2.807e-09 -8.552 -8.552 0.000 - MgCO3 5.929e-10 5.930e-10 -9.227 -9.227 0.000 - NaCO3- 5.935e-11 5.788e-11 -10.227 -10.237 -0.011 -Ca 7.800e-05 - Ca+2 7.758e-05 7.023e-05 -4.110 -4.153 -0.043 - CaHCO3+ 2.940e-07 2.868e-07 -6.532 -6.542 -0.011 - CaSO4 1.244e-07 1.245e-07 -6.905 -6.905 0.000 - CaCO3 2.806e-09 2.807e-09 -8.552 -8.552 0.000 - CaOH+ 1.894e-11 1.847e-11 -10.723 -10.733 -0.011 - CaHSO4+ 4.717e-13 4.600e-13 -12.326 -12.337 -0.011 -Cl 1.400e-05 - Cl- 1.400e-05 1.365e-05 -4.854 -4.865 -0.011 -H(0) 5.636e-24 - H2 2.818e-24 2.818e-24 -23.550 -23.550 0.000 -K 2.800e-05 - K+ 2.800e-05 2.730e-05 -4.553 -4.564 -0.011 - KSO4- 1.747e-09 1.704e-09 -8.758 -8.769 -0.011 - KOH 1.500e-13 1.500e-13 -12.824 -12.824 0.000 -Mg 2.900e-05 - Mg+2 2.885e-05 2.612e-05 -4.540 -4.583 -0.043 - MgHCO3+ 1.003e-07 9.783e-08 -6.999 -7.010 -0.011 - MgSO4 5.438e-08 5.439e-08 -7.265 -7.264 0.000 - MgCO3 5.929e-10 5.930e-10 -9.227 -9.227 0.000 - MgOH+ 1.541e-10 1.503e-10 -9.812 -9.823 -0.011 -Na 1.340e-04 - Na+ 1.340e-04 1.307e-04 -3.873 -3.884 -0.011 - NaHCO3 2.351e-08 2.352e-08 -7.629 -7.629 0.000 - NaSO4- 5.964e-09 5.816e-09 -8.224 -8.235 -0.011 - NaCO3- 5.935e-11 5.788e-11 -10.227 -10.237 -0.011 - NaOH 1.368e-12 1.368e-12 -11.864 -11.864 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -45.280 -45.280 0.000 -S(6) 1.000e-05 - SO4-2 9.813e-06 8.882e-06 -5.008 -5.052 -0.043 - CaSO4 1.244e-07 1.245e-07 -6.905 -6.905 0.000 - MgSO4 5.438e-08 5.439e-08 -7.265 -7.264 0.000 - NaSO4- 5.964e-09 5.816e-09 -8.224 -8.235 -0.011 - KSO4- 1.747e-09 1.704e-09 -8.758 -8.769 -0.011 - HSO4- 5.587e-10 5.448e-10 -9.253 -9.264 -0.011 - CaHSO4+ 4.717e-13 4.600e-13 -12.326 -12.337 -0.011 -Si 2.730e-04 - H4SiO4 2.729e-04 2.730e-04 -3.564 -3.564 0.000 - H3SiO4- 6.541e-08 6.379e-08 -7.184 -7.195 -0.011 - H2SiO4-2 7.604e-15 6.877e-15 -14.119 -14.163 -0.044 + H+ 6.464e-07 6.310e-07 -6.189 -6.200 -0.011 0.00 + OH- 1.627e-08 1.587e-08 -7.789 -7.800 -0.011 (0) + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +C(4) 7.825e-04 + CO2 4.540e-04 4.540e-04 -3.343 -3.343 0.000 (0) + HCO3- 3.281e-04 3.200e-04 -3.484 -3.495 -0.011 24.29 + CaHCO3+ 2.940e-07 2.868e-07 -6.532 -6.542 -0.011 (0) + MgHCO3+ 1.003e-07 9.783e-08 -6.999 -7.010 -0.011 (0) + CO3-2 2.628e-08 2.379e-08 -7.580 -7.624 -0.043 -3.78 + NaHCO3 2.351e-08 2.352e-08 -7.629 -7.629 0.000 (0) + CaCO3 2.806e-09 2.807e-09 -8.552 -8.552 0.000 (0) + MgCO3 5.929e-10 5.930e-10 -9.227 -9.227 0.000 (0) + NaCO3- 5.935e-11 5.788e-11 -10.227 -10.237 -0.011 (0) +Ca 7.800e-05 + Ca+2 7.758e-05 7.023e-05 -4.110 -4.153 -0.043 -17.83 + CaHCO3+ 2.940e-07 2.868e-07 -6.532 -6.542 -0.011 (0) + CaSO4 1.244e-07 1.245e-07 -6.905 -6.905 0.000 (0) + CaCO3 2.806e-09 2.807e-09 -8.552 -8.552 0.000 (0) + CaOH+ 1.894e-11 1.847e-11 -10.723 -10.733 -0.011 (0) + CaHSO4+ 4.717e-13 4.600e-13 -12.326 -12.337 -0.011 (0) +Cl 1.400e-05 + Cl- 1.400e-05 1.365e-05 -4.854 -4.865 -0.011 17.82 +H(0) 5.636e-24 + H2 2.818e-24 2.818e-24 -23.550 -23.550 0.000 (0) +K 2.800e-05 + K+ 2.800e-05 2.730e-05 -4.553 -4.564 -0.011 9.03 + KSO4- 1.747e-09 1.704e-09 -8.758 -8.769 -0.011 (0) + KOH 1.500e-13 1.500e-13 -12.824 -12.824 0.000 (0) +Mg 2.900e-05 + Mg+2 2.885e-05 2.612e-05 -4.540 -4.583 -0.043 -21.15 + MgHCO3+ 1.003e-07 9.783e-08 -6.999 -7.010 -0.011 (0) + MgSO4 5.438e-08 5.439e-08 -7.265 -7.264 0.000 (0) + MgCO3 5.929e-10 5.930e-10 -9.227 -9.227 0.000 (0) + MgOH+ 1.541e-10 1.503e-10 -9.812 -9.823 -0.011 (0) +Na 1.340e-04 + Na+ 1.340e-04 1.307e-04 -3.873 -3.884 -0.011 -1.21 + NaHCO3 2.351e-08 2.352e-08 -7.629 -7.629 0.000 (0) + NaSO4- 5.964e-09 5.816e-09 -8.224 -8.235 -0.011 (0) + NaCO3- 5.935e-11 5.788e-11 -10.227 -10.237 -0.011 (0) + NaOH 1.368e-12 1.368e-12 -11.864 -11.864 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -45.280 -45.280 0.000 (0) +S(6) 1.000e-05 + SO4-2 9.813e-06 8.882e-06 -5.008 -5.052 -0.043 13.98 + CaSO4 1.244e-07 1.245e-07 -6.905 -6.905 0.000 (0) + MgSO4 5.438e-08 5.439e-08 -7.265 -7.264 0.000 (0) + NaSO4- 5.964e-09 5.816e-09 -8.224 -8.235 -0.011 (0) + KSO4- 1.747e-09 1.704e-09 -8.758 -8.769 -0.011 (0) + HSO4- 5.587e-10 5.448e-10 -9.253 -9.264 -0.011 (0) + CaHSO4+ 4.717e-13 4.600e-13 -12.326 -12.337 -0.011 (0) +Si 2.730e-04 + H4SiO4 2.729e-04 2.730e-04 -3.564 -3.564 0.000 56.00 + H3SiO4- 6.541e-08 6.379e-08 -7.184 -7.195 -0.011 (0) + H2SiO4-2 7.604e-15 6.877e-15 -14.119 -14.163 -0.044 (0) ------------------------------Saturation indices------------------------------- @@ -210,63 +210,63 @@ Initial solution 2. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.647e-07 1.585e-07 -6.783 -6.800 -0.017 - OH- 6.579e-08 6.316e-08 -7.182 -7.200 -0.018 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -C(4) 1.199e-03 - HCO3- 8.907e-04 8.559e-04 -3.050 -3.068 -0.017 - CO2 3.049e-04 3.050e-04 -3.516 -3.516 0.000 - CaHCO3+ 2.485e-06 2.387e-06 -5.605 -5.622 -0.017 - MgHCO3+ 6.235e-07 5.987e-07 -6.205 -6.223 -0.018 - CO3-2 2.971e-07 2.533e-07 -6.527 -6.596 -0.069 - NaHCO3 1.196e-07 1.197e-07 -6.922 -6.922 0.000 - CaCO3 9.299e-08 9.302e-08 -7.032 -7.031 0.000 - MgCO3 1.444e-08 1.445e-08 -7.840 -7.840 0.000 - NaCO3- 1.221e-09 1.173e-09 -8.913 -8.931 -0.018 -Ca 2.600e-04 - Ca+2 2.566e-04 2.186e-04 -3.591 -3.660 -0.069 - CaHCO3+ 2.485e-06 2.387e-06 -5.605 -5.622 -0.017 - CaSO4 8.841e-07 8.843e-07 -6.054 -6.053 0.000 - CaCO3 9.299e-08 9.302e-08 -7.032 -7.031 0.000 - CaOH+ 2.384e-10 2.289e-10 -9.623 -9.640 -0.018 - CaHSO4+ 8.551e-13 8.211e-13 -12.068 -12.086 -0.018 -Cl 3.000e-05 - Cl- 3.000e-05 2.880e-05 -4.523 -4.541 -0.018 -H(0) 3.555e-25 - H2 1.778e-25 1.778e-25 -24.750 -24.750 0.000 -K 4.000e-05 - K+ 4.000e-05 3.840e-05 -4.398 -4.416 -0.018 - KSO4- 5.696e-09 5.470e-09 -8.244 -8.262 -0.018 - KOH 8.398e-13 8.401e-13 -12.076 -12.076 0.000 -Mg 7.101e-05 - Mg+2 7.008e-05 5.978e-05 -4.154 -4.223 -0.069 - MgHCO3+ 6.235e-07 5.987e-07 -6.205 -6.223 -0.018 - MgSO4 2.840e-07 2.841e-07 -6.547 -6.547 0.000 - MgCO3 1.444e-08 1.445e-08 -7.840 -7.840 0.000 - MgOH+ 1.426e-09 1.370e-09 -8.846 -8.863 -0.018 -Na 2.590e-04 - Na+ 2.589e-04 2.486e-04 -3.587 -3.604 -0.018 - NaHCO3 1.196e-07 1.197e-07 -6.922 -6.922 0.000 - NaSO4- 2.631e-08 2.526e-08 -7.580 -7.598 -0.018 - NaCO3- 1.221e-09 1.173e-09 -8.913 -8.931 -0.018 - NaOH 1.036e-11 1.036e-11 -10.985 -10.984 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -42.880 -42.880 0.000 -S(6) 2.500e-05 - SO4-2 2.380e-05 2.027e-05 -4.623 -4.693 -0.070 - CaSO4 8.841e-07 8.843e-07 -6.054 -6.053 0.000 - MgSO4 2.840e-07 2.841e-07 -6.547 -6.547 0.000 - NaSO4- 2.631e-08 2.526e-08 -7.580 -7.598 -0.018 - KSO4- 5.696e-09 5.470e-09 -8.244 -8.262 -0.018 - HSO4- 3.253e-10 3.124e-10 -9.488 -9.505 -0.018 - CaHSO4+ 8.551e-13 8.211e-13 -12.068 -12.086 -0.018 -Si 4.100e-04 - H4SiO4 4.096e-04 4.098e-04 -3.388 -3.387 0.000 - H3SiO4- 3.970e-07 3.812e-07 -6.401 -6.419 -0.018 - H2SiO4-2 1.924e-13 1.636e-13 -12.716 -12.786 -0.070 + H+ 1.647e-07 1.585e-07 -6.783 -6.800 -0.017 0.00 + OH- 6.579e-08 6.316e-08 -7.182 -7.200 -0.018 (0) + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +C(4) 1.199e-03 + HCO3- 8.907e-04 8.559e-04 -3.050 -3.068 -0.017 24.30 + CO2 3.049e-04 3.050e-04 -3.516 -3.516 0.000 (0) + CaHCO3+ 2.485e-06 2.387e-06 -5.605 -5.622 -0.017 (0) + MgHCO3+ 6.235e-07 5.987e-07 -6.205 -6.223 -0.018 (0) + CO3-2 2.971e-07 2.533e-07 -6.527 -6.596 -0.069 -3.74 + NaHCO3 1.196e-07 1.197e-07 -6.922 -6.922 0.000 (0) + CaCO3 9.299e-08 9.302e-08 -7.032 -7.031 0.000 (0) + MgCO3 1.444e-08 1.445e-08 -7.840 -7.840 0.000 (0) + NaCO3- 1.221e-09 1.173e-09 -8.913 -8.931 -0.018 (0) +Ca 2.600e-04 + Ca+2 2.566e-04 2.186e-04 -3.591 -3.660 -0.069 -17.79 + CaHCO3+ 2.485e-06 2.387e-06 -5.605 -5.622 -0.017 (0) + CaSO4 8.841e-07 8.843e-07 -6.054 -6.053 0.000 (0) + CaCO3 9.299e-08 9.302e-08 -7.032 -7.031 0.000 (0) + CaOH+ 2.384e-10 2.289e-10 -9.623 -9.640 -0.018 (0) + CaHSO4+ 8.551e-13 8.211e-13 -12.068 -12.086 -0.018 (0) +Cl 3.000e-05 + Cl- 3.000e-05 2.880e-05 -4.523 -4.541 -0.018 17.83 +H(0) 3.555e-25 + H2 1.778e-25 1.778e-25 -24.750 -24.750 0.000 (0) +K 4.000e-05 + K+ 4.000e-05 3.840e-05 -4.398 -4.416 -0.018 9.04 + KSO4- 5.696e-09 5.470e-09 -8.244 -8.262 -0.018 (0) + KOH 8.398e-13 8.401e-13 -12.076 -12.076 0.000 (0) +Mg 7.101e-05 + Mg+2 7.008e-05 5.978e-05 -4.154 -4.223 -0.069 -21.11 + MgHCO3+ 6.235e-07 5.987e-07 -6.205 -6.223 -0.018 (0) + MgSO4 2.840e-07 2.841e-07 -6.547 -6.547 0.000 (0) + MgCO3 1.444e-08 1.445e-08 -7.840 -7.840 0.000 (0) + MgOH+ 1.426e-09 1.370e-09 -8.846 -8.863 -0.018 (0) +Na 2.590e-04 + Na+ 2.589e-04 2.486e-04 -3.587 -3.604 -0.018 -1.20 + NaHCO3 1.196e-07 1.197e-07 -6.922 -6.922 0.000 (0) + NaSO4- 2.631e-08 2.526e-08 -7.580 -7.598 -0.018 (0) + NaCO3- 1.221e-09 1.173e-09 -8.913 -8.931 -0.018 (0) + NaOH 1.036e-11 1.036e-11 -10.985 -10.984 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -42.880 -42.880 0.000 (0) +S(6) 2.500e-05 + SO4-2 2.380e-05 2.027e-05 -4.623 -4.693 -0.070 14.02 + CaSO4 8.841e-07 8.843e-07 -6.054 -6.053 0.000 (0) + MgSO4 2.840e-07 2.841e-07 -6.547 -6.547 0.000 (0) + NaSO4- 2.631e-08 2.526e-08 -7.580 -7.598 -0.018 (0) + KSO4- 5.696e-09 5.470e-09 -8.244 -8.262 -0.018 (0) + HSO4- 3.253e-10 3.124e-10 -9.488 -9.505 -0.018 (0) + CaHSO4+ 8.551e-13 8.211e-13 -12.068 -12.086 -0.018 (0) +Si 4.100e-04 + H4SiO4 4.096e-04 4.098e-04 -3.388 -3.387 0.000 56.00 + H3SiO4- 3.970e-07 3.812e-07 -6.401 -6.419 -0.018 (0) + H2SiO4-2 1.924e-13 1.636e-13 -12.716 -12.786 -0.070 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex17.out b/ex17.out index 868d9118..1daa067c 100644 --- a/ex17.out +++ b/ex17.out @@ -112,35 +112,35 @@ Initial solution 1. Black Sea water MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.658e-06 9.949e-07 -5.780 -6.002 -0.222 - H+ 1.290e-08 1.000e-08 -7.889 -8.000 -0.111 - H2O 5.551e+01 9.903e-01 1.744 -0.004 0.000 -Br 4.401e-04 - Br- 4.401e-04 3.004e-04 -3.356 -3.522 -0.166 -C(4) 8.426e-04 - HCO3- 7.975e-04 4.902e-04 -3.098 -3.310 -0.211 - CO3-2 1.598e-05 2.244e-06 -4.796 -5.649 -0.853 - MgCO3 1.429e-05 1.429e-05 -4.845 -4.845 0.000 - CO2 1.010e-05 1.077e-05 -4.996 -4.968 0.028 - CaCO3 4.680e-06 4.680e-06 -5.330 -5.330 0.000 -Ca 5.841e-03 - Ca+2 5.837e-03 1.472e-03 -2.234 -2.832 -0.598 - CaCO3 4.680e-06 4.680e-06 -5.330 -5.330 0.000 -Cl 2.930e-01 - Cl- 2.930e-01 1.960e-01 -0.533 -0.708 -0.175 -K 4.960e-03 - K+ 4.960e-03 3.418e-03 -2.305 -2.466 -0.162 -Mg 2.807e-02 - Mg+2 2.805e-02 7.511e-03 -1.552 -2.124 -0.572 - MgCO3 1.429e-05 1.429e-05 -4.845 -4.845 0.000 - MgOH+ 1.244e-06 1.155e-06 -5.905 -5.938 -0.032 -Na 2.544e-01 - Na+ 2.544e-01 1.836e-01 -0.595 -0.736 -0.142 -S(6) 1.527e-02 - SO4-2 1.527e-02 2.118e-03 -1.816 -2.674 -0.858 - HSO4- 2.952e-09 2.017e-09 -8.530 -8.695 -0.165 + OH- 1.658e-06 9.949e-07 -5.780 -6.002 -0.222 (0) + H+ 1.290e-08 1.000e-08 -7.889 -8.000 -0.111 0.00 + H2O 5.551e+01 9.903e-01 1.744 -0.004 0.000 18.07 +Br 4.401e-04 + Br- 4.401e-04 3.004e-04 -3.356 -3.522 -0.166 24.71 +C(4) 8.426e-04 + HCO3- 7.975e-04 4.902e-04 -3.098 -3.310 -0.211 24.29 + CO3-2 1.598e-05 2.244e-06 -4.796 -5.649 -0.853 -3.78 + MgCO3 1.429e-05 1.429e-05 -4.845 -4.845 0.000 (0) + CO2 1.010e-05 1.077e-05 -4.996 -4.968 0.028 (0) + CaCO3 4.680e-06 4.680e-06 -5.330 -5.330 0.000 (0) +Ca 5.841e-03 + Ca+2 5.837e-03 1.472e-03 -2.234 -2.832 -0.598 -17.83 + CaCO3 4.680e-06 4.680e-06 -5.330 -5.330 0.000 (0) +Cl 2.930e-01 + Cl- 2.930e-01 1.960e-01 -0.533 -0.708 -0.175 17.82 +K 4.960e-03 + K+ 4.960e-03 3.418e-03 -2.305 -2.466 -0.162 9.03 +Mg 2.807e-02 + Mg+2 2.805e-02 7.511e-03 -1.552 -2.124 -0.572 -21.15 + MgCO3 1.429e-05 1.429e-05 -4.845 -4.845 0.000 (0) + MgOH+ 1.244e-06 1.155e-06 -5.905 -5.938 -0.032 (0) +Na 2.544e-01 + Na+ 2.544e-01 1.836e-01 -0.595 -0.736 -0.142 -1.21 +S(6) 1.527e-02 + SO4-2 1.527e-02 2.118e-03 -1.816 -2.674 -0.858 13.98 + HSO4- 2.952e-09 2.017e-09 -8.530 -8.695 -0.165 (0) ------------------------------Saturation indices------------------------------- @@ -226,31 +226,31 @@ Initial solution 2. Composition during halite precipitation MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 5.602e-07 1.000e-05 -6.252 -5.000 1.252 - OH- 1.202e-08 6.837e-10 -7.920 -9.165 -1.245 - H2O 5.551e+01 6.806e-01 1.744 -0.167 0.000 -Br 3.785e-02 - Br- 3.785e-02 4.950e-02 -1.422 -1.305 0.116 -C(4) 6.839e-06 - HCO3- 4.519e-06 3.369e-07 -5.345 -6.473 -1.128 - CO2 2.248e-06 1.077e-05 -5.648 -4.968 0.680 - MgCO3 6.655e-08 6.655e-08 -7.177 -7.177 0.000 - CO3-2 5.827e-09 1.543e-12 -8.235 -11.812 -3.577 -Cl 6.004e+00 - Cl- 6.004e+00 4.512e+00 0.778 0.654 -0.124 -K 4.578e-01 - K+ 4.578e-01 4.785e-01 -0.339 -0.320 0.019 -Mg 2.354e+00 - Mg+2 2.354e+00 5.091e+01 0.372 1.707 1.335 - MgOH+ 6.271e-06 5.379e-06 -5.203 -5.269 -0.067 - MgCO3 6.655e-08 6.655e-08 -7.177 -7.177 0.000 -Na 2.720e+00 - Na+ 2.720e+00 8.671e+00 0.435 0.938 0.503 -S(6) 8.986e-01 - SO4-2 8.986e-01 2.260e-03 -0.046 -2.646 -2.599 - HSO4- 2.669e-06 2.153e-06 -5.574 -5.667 -0.093 + H+ 5.602e-07 1.000e-05 -6.252 -5.000 1.252 0.00 + OH- 1.202e-08 6.837e-10 -7.920 -9.165 -1.245 (0) + H2O 5.551e+01 6.806e-01 1.744 -0.167 0.000 18.07 +Br 3.785e-02 + Br- 3.785e-02 4.950e-02 -1.422 -1.305 0.116 25.00 +C(4) 6.839e-06 + HCO3- 4.519e-06 3.369e-07 -5.345 -6.473 -1.128 24.58 + CO2 2.248e-06 1.077e-05 -5.648 -4.968 0.680 (0) + MgCO3 6.655e-08 6.655e-08 -7.177 -7.177 0.000 (0) + CO3-2 5.827e-09 1.543e-12 -8.235 -11.812 -3.577 -2.64 +Cl 6.004e+00 + Cl- 6.004e+00 4.512e+00 0.778 0.654 -0.124 18.11 +K 4.578e-01 + K+ 4.578e-01 4.785e-01 -0.339 -0.320 0.019 9.32 +Mg 2.354e+00 + Mg+2 2.354e+00 5.091e+01 0.372 1.707 1.335 -20.01 + MgOH+ 6.271e-06 5.379e-06 -5.203 -5.269 -0.067 (0) + MgCO3 6.655e-08 6.655e-08 -7.177 -7.177 0.000 (0) +Na 2.720e+00 + Na+ 2.720e+00 8.671e+00 0.435 0.938 0.503 -0.92 +S(6) 8.986e-01 + SO4-2 8.986e-01 2.260e-03 -0.046 -2.646 -2.599 15.12 + HSO4- 2.669e-06 2.153e-06 -5.574 -5.667 -0.093 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex17b.out b/ex17b.out index 71846bc8..b75ad2be 100644 --- a/ex17b.out +++ b/ex17b.out @@ -114,35 +114,35 @@ Initial solution 1. Black Sea water MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.658e-06 9.949e-07 -5.780 -6.002 -0.222 - H+ 1.290e-08 1.000e-08 -7.889 -8.000 -0.111 - H2O 5.551e+01 9.903e-01 1.744 -0.004 0.000 -Br 4.401e-04 - Br- 4.401e-04 3.004e-04 -3.356 -3.522 -0.166 -C(4) 8.426e-04 - HCO3- 7.975e-04 4.902e-04 -3.098 -3.310 -0.211 - CO3-2 1.598e-05 2.244e-06 -4.796 -5.649 -0.853 - MgCO3 1.429e-05 1.429e-05 -4.845 -4.845 0.000 - CO2 1.010e-05 1.077e-05 -4.996 -4.968 0.028 - CaCO3 4.680e-06 4.680e-06 -5.330 -5.330 0.000 -Ca 5.841e-03 - Ca+2 5.837e-03 1.472e-03 -2.234 -2.832 -0.598 - CaCO3 4.680e-06 4.680e-06 -5.330 -5.330 0.000 -Cl 2.930e-01 - Cl- 2.930e-01 1.960e-01 -0.533 -0.708 -0.175 -K 4.960e-03 - K+ 4.960e-03 3.418e-03 -2.305 -2.466 -0.162 -Mg 2.807e-02 - Mg+2 2.805e-02 7.511e-03 -1.552 -2.124 -0.572 - MgCO3 1.429e-05 1.429e-05 -4.845 -4.845 0.000 - MgOH+ 1.244e-06 1.155e-06 -5.905 -5.938 -0.032 -Na 2.544e-01 - Na+ 2.544e-01 1.836e-01 -0.595 -0.736 -0.142 -S(6) 1.527e-02 - SO4-2 1.527e-02 2.118e-03 -1.816 -2.674 -0.858 - HSO4- 2.952e-09 2.017e-09 -8.530 -8.695 -0.165 + OH- 1.658e-06 9.949e-07 -5.780 -6.002 -0.222 (0) + H+ 1.290e-08 1.000e-08 -7.889 -8.000 -0.111 0.00 + H2O 5.551e+01 9.903e-01 1.744 -0.004 0.000 18.07 +Br 4.401e-04 + Br- 4.401e-04 3.004e-04 -3.356 -3.522 -0.166 24.71 +C(4) 8.426e-04 + HCO3- 7.975e-04 4.902e-04 -3.098 -3.310 -0.211 24.29 + CO3-2 1.598e-05 2.244e-06 -4.796 -5.649 -0.853 -3.78 + MgCO3 1.429e-05 1.429e-05 -4.845 -4.845 0.000 (0) + CO2 1.010e-05 1.077e-05 -4.996 -4.968 0.028 (0) + CaCO3 4.680e-06 4.680e-06 -5.330 -5.330 0.000 (0) +Ca 5.841e-03 + Ca+2 5.837e-03 1.472e-03 -2.234 -2.832 -0.598 -17.83 + CaCO3 4.680e-06 4.680e-06 -5.330 -5.330 0.000 (0) +Cl 2.930e-01 + Cl- 2.930e-01 1.960e-01 -0.533 -0.708 -0.175 17.82 +K 4.960e-03 + K+ 4.960e-03 3.418e-03 -2.305 -2.466 -0.162 9.03 +Mg 2.807e-02 + Mg+2 2.805e-02 7.511e-03 -1.552 -2.124 -0.572 -21.15 + MgCO3 1.429e-05 1.429e-05 -4.845 -4.845 0.000 (0) + MgOH+ 1.244e-06 1.155e-06 -5.905 -5.938 -0.032 (0) +Na 2.544e-01 + Na+ 2.544e-01 1.836e-01 -0.595 -0.736 -0.142 -1.21 +S(6) 1.527e-02 + SO4-2 1.527e-02 2.118e-03 -1.816 -2.674 -0.858 13.98 + HSO4- 2.952e-09 2.017e-09 -8.530 -8.695 -0.165 (0) ------------------------------Saturation indices------------------------------- @@ -269,35 +269,35 @@ Polyhalite -9.68 -23.43 -13.74 0.000e+00 0 0.000e+00 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.658e-06 9.949e-07 -5.780 -6.002 -0.222 - H+ 1.290e-08 1.000e-08 -7.889 -8.000 -0.111 - H2O 5.551e+01 9.903e-01 1.744 -0.004 0.000 -Br 4.401e-04 - Br- 4.401e-04 3.004e-04 -3.356 -3.522 -0.166 -C(4) 8.426e-04 - HCO3- 7.975e-04 4.902e-04 -3.098 -3.310 -0.211 - CO3-2 1.598e-05 2.244e-06 -4.796 -5.649 -0.853 - MgCO3 1.429e-05 1.429e-05 -4.845 -4.845 0.000 - CO2 1.010e-05 1.077e-05 -4.996 -4.968 0.028 - CaCO3 4.680e-06 4.680e-06 -5.330 -5.330 0.000 -Ca 5.841e-03 - Ca+2 5.837e-03 1.472e-03 -2.234 -2.832 -0.598 - CaCO3 4.680e-06 4.680e-06 -5.330 -5.330 0.000 -Cl 2.930e-01 - Cl- 2.930e-01 1.960e-01 -0.533 -0.708 -0.175 -K 4.960e-03 - K+ 4.960e-03 3.418e-03 -2.305 -2.466 -0.162 -Mg 2.807e-02 - Mg+2 2.805e-02 7.511e-03 -1.552 -2.124 -0.572 - MgCO3 1.429e-05 1.429e-05 -4.845 -4.845 0.000 - MgOH+ 1.244e-06 1.155e-06 -5.905 -5.938 -0.032 -Na 2.544e-01 - Na+ 2.544e-01 1.836e-01 -0.595 -0.736 -0.142 -S(6) 1.527e-02 - SO4-2 1.527e-02 2.118e-03 -1.816 -2.674 -0.858 - HSO4- 2.952e-09 2.017e-09 -8.530 -8.695 -0.165 + OH- 1.658e-06 9.949e-07 -5.780 -6.002 -0.222 (0) + H+ 1.290e-08 1.000e-08 -7.889 -8.000 -0.111 0.00 + H2O 5.551e+01 9.903e-01 1.744 -0.004 0.000 18.07 +Br 4.401e-04 + Br- 4.401e-04 3.004e-04 -3.356 -3.522 -0.166 25.00 +C(4) 8.426e-04 + HCO3- 7.975e-04 4.902e-04 -3.098 -3.310 -0.211 24.58 + CO3-2 1.598e-05 2.244e-06 -4.796 -5.649 -0.853 -2.64 + MgCO3 1.429e-05 1.429e-05 -4.845 -4.845 0.000 (0) + CO2 1.010e-05 1.077e-05 -4.996 -4.968 0.028 (0) + CaCO3 4.680e-06 4.680e-06 -5.330 -5.330 0.000 (0) +Ca 5.841e-03 + Ca+2 5.837e-03 1.472e-03 -2.234 -2.832 -0.598 -16.69 + CaCO3 4.680e-06 4.680e-06 -5.330 -5.330 0.000 (0) +Cl 2.930e-01 + Cl- 2.930e-01 1.960e-01 -0.533 -0.708 -0.175 18.11 +K 4.960e-03 + K+ 4.960e-03 3.418e-03 -2.305 -2.466 -0.162 9.32 +Mg 2.807e-02 + Mg+2 2.805e-02 7.511e-03 -1.552 -2.124 -0.572 -20.01 + MgCO3 1.429e-05 1.429e-05 -4.845 -4.845 0.000 (0) + MgOH+ 1.244e-06 1.155e-06 -5.905 -5.938 -0.032 (0) +Na 2.544e-01 + Na+ 2.544e-01 1.836e-01 -0.595 -0.736 -0.142 -0.92 +S(6) 1.527e-02 + SO4-2 1.527e-02 2.118e-03 -1.816 -2.674 -0.858 15.12 + HSO4- 2.952e-09 2.017e-09 -8.530 -8.695 -0.165 (0) ------------------------------Saturation indices------------------------------- @@ -420,35 +420,35 @@ Polyhalite -7.21 -20.95 -13.74 0.000e+00 0 0.000e+00 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.460e-06 6.853e-07 -5.836 -6.164 -0.328 - H+ 1.627e-08 1.425e-08 -7.789 -7.846 -0.058 - H2O 5.551e+01 9.722e-01 1.744 -0.012 0.000 -Br 1.252e-03 - Br- 1.252e-03 7.911e-04 -2.902 -3.102 -0.200 -C(4) 7.220e-04 - HCO3- 6.692e-04 3.377e-04 -3.174 -3.472 -0.297 - CO3-2 1.928e-05 1.085e-06 -4.715 -5.965 -1.250 - MgCO3 1.899e-05 1.899e-05 -4.721 -4.721 0.000 - CO2 8.981e-06 1.077e-05 -5.047 -4.968 0.079 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Ca 1.576e-02 - Ca+2 1.576e-02 3.618e-03 -1.803 -2.442 -0.639 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 8.339e-01 - Cl- 8.339e-01 4.997e-01 -0.079 -0.301 -0.222 -K 1.411e-02 - K+ 1.411e-02 8.942e-03 -1.850 -2.049 -0.198 -Mg 7.987e-02 - Mg+2 7.985e-02 2.066e-02 -1.098 -1.685 -0.587 - MgCO3 1.899e-05 1.899e-05 -4.721 -4.721 0.000 - MgOH+ 2.219e-06 2.188e-06 -5.654 -5.660 -0.006 -Na 7.238e-01 - Na+ 7.238e-01 5.131e-01 -0.140 -0.290 -0.149 -S(6) 4.345e-02 - SO4-2 4.345e-02 2.722e-03 -1.362 -2.565 -1.203 - HSO4- 6.053e-09 3.695e-09 -8.218 -8.432 -0.214 + OH- 1.460e-06 6.853e-07 -5.836 -6.164 -0.328 (0) + H+ 1.627e-08 1.425e-08 -7.789 -7.846 -0.058 0.00 + H2O 5.551e+01 9.722e-01 1.744 -0.012 0.000 18.07 +Br 1.252e-03 + Br- 1.252e-03 7.911e-04 -2.902 -3.102 -0.200 25.19 +C(4) 7.220e-04 + HCO3- 6.692e-04 3.377e-04 -3.174 -3.472 -0.297 24.77 + CO3-2 1.928e-05 1.085e-06 -4.715 -5.965 -1.250 -1.85 + MgCO3 1.899e-05 1.899e-05 -4.721 -4.721 0.000 (0) + CO2 8.981e-06 1.077e-05 -5.047 -4.968 0.079 (0) + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Ca 1.576e-02 + Ca+2 1.576e-02 3.618e-03 -1.803 -2.442 -0.639 -15.90 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 8.339e-01 + Cl- 8.339e-01 4.997e-01 -0.079 -0.301 -0.222 18.30 +K 1.411e-02 + K+ 1.411e-02 8.942e-03 -1.850 -2.049 -0.198 9.51 +Mg 7.987e-02 + Mg+2 7.985e-02 2.066e-02 -1.098 -1.685 -0.587 -19.22 + MgCO3 1.899e-05 1.899e-05 -4.721 -4.721 0.000 (0) + MgOH+ 2.219e-06 2.188e-06 -5.654 -5.660 -0.006 (0) +Na 7.238e-01 + Na+ 7.238e-01 5.131e-01 -0.140 -0.290 -0.149 -0.73 +S(6) 4.345e-02 + SO4-2 4.345e-02 2.722e-03 -1.362 -2.565 -1.203 15.91 + HSO4- 6.053e-09 3.695e-09 -8.218 -8.432 -0.214 (0) ------------------------------Saturation indices------------------------------- @@ -571,35 +571,35 @@ Polyhalite -6.65 -20.39 -13.74 0.000e+00 0 0.000e+00 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.366e-06 5.999e-07 -5.864 -6.222 -0.358 - H+ 1.721e-08 1.616e-08 -7.764 -7.792 -0.027 - H2O 5.551e+01 9.647e-01 1.744 -0.016 0.000 -Br 1.575e-03 - Br- 1.575e-03 9.876e-04 -2.803 -3.005 -0.203 -C(4) 6.681e-04 - HCO3- 6.153e-04 2.956e-04 -3.211 -3.529 -0.318 - MgCO3 1.953e-05 1.953e-05 -4.709 -4.709 0.000 - CO3-2 1.915e-05 8.377e-07 -4.718 -6.077 -1.359 - CO2 8.571e-06 1.077e-05 -5.067 -4.968 0.099 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Ca 1.970e-02 - Ca+2 1.970e-02 4.685e-03 -1.706 -2.329 -0.624 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 1.049e+00 - Cl- 1.049e+00 6.161e-01 0.021 -0.210 -0.231 -K 1.775e-02 - K+ 1.775e-02 1.112e-02 -1.751 -1.954 -0.203 -Mg 1.005e-01 - Mg+2 1.005e-01 2.751e-02 -0.998 -1.561 -0.563 - MgCO3 1.953e-05 1.953e-05 -4.709 -4.709 0.000 - MgOH+ 2.590e-06 2.550e-06 -5.587 -5.593 -0.007 -Na 9.105e-01 - Na+ 9.105e-01 6.539e-01 -0.041 -0.185 -0.144 -S(6) 5.466e-02 - SO4-2 5.466e-02 2.769e-03 -1.262 -2.558 -1.295 - HSO4- 7.171e-09 4.262e-09 -8.144 -8.370 -0.226 + OH- 1.366e-06 5.999e-07 -5.864 -6.222 -0.358 (0) + H+ 1.721e-08 1.616e-08 -7.764 -7.792 -0.027 0.00 + H2O 5.551e+01 9.647e-01 1.744 -0.016 0.000 18.07 +Br 1.575e-03 + Br- 1.575e-03 9.876e-04 -2.803 -3.005 -0.203 25.25 +C(4) 6.681e-04 + HCO3- 6.153e-04 2.956e-04 -3.211 -3.529 -0.318 24.83 + MgCO3 1.953e-05 1.953e-05 -4.709 -4.709 0.000 (0) + CO3-2 1.915e-05 8.377e-07 -4.718 -6.077 -1.359 -1.62 + CO2 8.571e-06 1.077e-05 -5.067 -4.968 0.099 (0) + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Ca 1.970e-02 + Ca+2 1.970e-02 4.685e-03 -1.706 -2.329 -0.624 -15.67 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 1.049e+00 + Cl- 1.049e+00 6.161e-01 0.021 -0.210 -0.231 18.36 +K 1.775e-02 + K+ 1.775e-02 1.112e-02 -1.751 -1.954 -0.203 9.57 +Mg 1.005e-01 + Mg+2 1.005e-01 2.751e-02 -0.998 -1.561 -0.563 -18.99 + MgCO3 1.953e-05 1.953e-05 -4.709 -4.709 0.000 (0) + MgOH+ 2.590e-06 2.550e-06 -5.587 -5.593 -0.007 (0) +Na 9.105e-01 + Na+ 9.105e-01 6.539e-01 -0.041 -0.185 -0.144 -0.67 +S(6) 5.466e-02 + SO4-2 5.466e-02 2.769e-03 -1.262 -2.558 -1.295 16.14 + HSO4- 7.171e-09 4.262e-09 -8.144 -8.370 -0.226 (0) ------------------------------Saturation indices------------------------------- @@ -722,35 +722,35 @@ Polyhalite -5.88 -19.62 -13.74 0.000e+00 0 0.000e+00 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.229e-06 4.896e-07 -5.911 -6.310 -0.400 - H+ 1.826e-08 1.953e-08 -7.738 -7.709 0.029 - H2O 5.551e+01 9.516e-01 1.744 -0.022 0.000 -Br 2.123e-03 - Br- 2.123e-03 1.331e-03 -2.673 -2.876 -0.203 -C(4) 5.904e-04 - HCO3- 5.381e-04 2.412e-04 -3.269 -3.618 -0.348 - MgCO3 2.036e-05 2.036e-05 -4.691 -4.691 0.000 - CO3-2 1.854e-05 5.657e-07 -4.732 -6.247 -1.516 - CO2 7.918e-06 1.077e-05 -5.101 -4.968 0.133 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Ca 2.639e-02 - Ca+2 2.639e-02 6.937e-03 -1.579 -2.159 -0.580 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 1.414e+00 - Cl- 1.414e+00 8.132e-01 0.150 -0.090 -0.240 -K 2.393e-02 - K+ 2.393e-02 1.487e-02 -1.621 -1.828 -0.207 -Mg 1.354e-01 - Mg+2 1.354e-01 4.247e-02 -0.868 -1.372 -0.504 - MgCO3 2.036e-05 2.036e-05 -4.691 -4.691 0.000 - MgOH+ 3.324e-06 3.213e-06 -5.478 -5.493 -0.015 -Na 1.227e+00 - Na+ 1.227e+00 9.120e-01 0.089 -0.040 -0.129 -S(6) 7.366e-02 - SO4-2 7.366e-02 2.760e-03 -1.133 -2.559 -1.426 - HSO4- 8.960e-09 5.133e-09 -8.048 -8.290 -0.242 + OH- 1.229e-06 4.896e-07 -5.911 -6.310 -0.400 (0) + H+ 1.826e-08 1.953e-08 -7.738 -7.709 0.029 0.00 + H2O 5.551e+01 9.516e-01 1.744 -0.022 0.000 18.07 +Br 2.123e-03 + Br- 2.123e-03 1.331e-03 -2.673 -2.876 -0.203 25.34 +C(4) 5.904e-04 + HCO3- 5.381e-04 2.412e-04 -3.269 -3.618 -0.348 24.92 + MgCO3 2.036e-05 2.036e-05 -4.691 -4.691 0.000 (0) + CO3-2 1.854e-05 5.657e-07 -4.732 -6.247 -1.516 -1.27 + CO2 7.918e-06 1.077e-05 -5.101 -4.968 0.133 (0) + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Ca 2.639e-02 + Ca+2 2.639e-02 6.937e-03 -1.579 -2.159 -0.580 -15.32 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 1.414e+00 + Cl- 1.414e+00 8.132e-01 0.150 -0.090 -0.240 18.45 +K 2.393e-02 + K+ 2.393e-02 1.487e-02 -1.621 -1.828 -0.207 9.66 +Mg 1.354e-01 + Mg+2 1.354e-01 4.247e-02 -0.868 -1.372 -0.504 -18.64 + MgCO3 2.036e-05 2.036e-05 -4.691 -4.691 0.000 (0) + MgOH+ 3.324e-06 3.213e-06 -5.478 -5.493 -0.015 (0) +Na 1.227e+00 + Na+ 1.227e+00 9.120e-01 0.089 -0.040 -0.129 -0.58 +S(6) 7.366e-02 + SO4-2 7.366e-02 2.760e-03 -1.133 -2.559 -1.426 16.49 + HSO4- 8.960e-09 5.133e-09 -8.048 -8.290 -0.242 (0) ------------------------------Saturation indices------------------------------- @@ -873,35 +873,35 @@ Polyhalite -4.85 -18.59 -13.74 0.000e+00 0 0.000e+00 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.054e-06 3.603e-07 -5.977 -6.443 -0.466 - H+ 1.781e-08 2.573e-08 -7.749 -7.590 0.160 - H2O 5.551e+01 9.228e-01 1.744 -0.035 0.000 -Br 3.255e-03 - Br- 3.255e-03 2.101e-03 -2.487 -2.677 -0.190 -C(4) 5.041e-04 - HCO3- 4.480e-04 1.775e-04 -3.349 -3.751 -0.402 - MgCO3 2.549e-05 2.549e-05 -4.594 -4.594 0.000 - CO3-2 1.837e-05 3.160e-07 -4.736 -6.500 -1.764 - CO2 6.744e-06 1.077e-05 -5.171 -4.968 0.203 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Ca 3.469e-02 - Ca+2 3.469e-02 1.242e-02 -1.460 -1.906 -0.446 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 2.167e+00 - Cl- 2.167e+00 1.231e+00 0.336 0.090 -0.246 -K 3.668e-02 - K+ 3.668e-02 2.315e-02 -1.436 -1.636 -0.200 -Mg 2.076e-01 - Mg+2 2.076e-01 9.521e-02 -0.683 -1.021 -0.338 - MgCO3 2.549e-05 2.549e-05 -4.594 -4.594 0.000 - MgOH+ 5.834e-06 5.301e-06 -5.234 -5.276 -0.042 -Na 1.881e+00 - Na+ 1.881e+00 1.550e+00 0.274 0.190 -0.084 -S(6) 1.074e-01 - SO4-2 1.074e-01 2.484e-03 -0.969 -2.605 -1.636 - HSO4- 1.125e-08 6.089e-09 -7.949 -8.215 -0.267 + OH- 1.054e-06 3.603e-07 -5.977 -6.443 -0.466 (0) + H+ 1.781e-08 2.573e-08 -7.749 -7.590 0.160 0.00 + H2O 5.551e+01 9.228e-01 1.744 -0.035 0.000 18.07 +Br 3.255e-03 + Br- 3.255e-03 2.101e-03 -2.487 -2.677 -0.190 25.48 +C(4) 5.041e-04 + HCO3- 4.480e-04 1.775e-04 -3.349 -3.751 -0.402 25.06 + MgCO3 2.549e-05 2.549e-05 -4.594 -4.594 0.000 (0) + CO3-2 1.837e-05 3.160e-07 -4.736 -6.500 -1.764 -0.69 + CO2 6.744e-06 1.077e-05 -5.171 -4.968 0.203 (0) + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Ca 3.469e-02 + Ca+2 3.469e-02 1.242e-02 -1.460 -1.906 -0.446 -14.74 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 2.167e+00 + Cl- 2.167e+00 1.231e+00 0.336 0.090 -0.246 18.59 +K 3.668e-02 + K+ 3.668e-02 2.315e-02 -1.436 -1.636 -0.200 9.80 +Mg 2.076e-01 + Mg+2 2.076e-01 9.521e-02 -0.683 -1.021 -0.338 -18.06 + MgCO3 2.549e-05 2.549e-05 -4.594 -4.594 0.000 (0) + MgOH+ 5.834e-06 5.301e-06 -5.234 -5.276 -0.042 (0) +Na 1.881e+00 + Na+ 1.881e+00 1.550e+00 0.274 0.190 -0.084 -0.44 +S(6) 1.074e-01 + SO4-2 1.074e-01 2.484e-03 -0.969 -2.605 -1.636 17.07 + HSO4- 1.125e-08 6.089e-09 -7.949 -8.215 -0.267 (0) ------------------------------Saturation indices------------------------------- @@ -1024,35 +1024,35 @@ Polyhalite -4.63 -18.37 -13.74 0.000e+00 0 0.000e+00 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.039e-06 3.375e-07 -5.983 -6.472 -0.488 - H+ 1.625e-08 2.707e-08 -7.789 -7.568 0.222 - H2O 5.551e+01 9.093e-01 1.744 -0.041 0.000 -Br 3.756e-03 - Br- 3.756e-03 2.474e-03 -2.425 -2.607 -0.181 -C(4) 5.073e-04 - HCO3- 4.436e-04 1.663e-04 -3.353 -3.779 -0.426 - MgCO3 3.187e-05 3.187e-05 -4.497 -4.497 0.000 - CO3-2 1.995e-05 2.813e-07 -4.700 -6.551 -1.851 - CO2 6.300e-06 1.077e-05 -5.201 -4.968 0.233 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Ca 3.300e-02 - Ca+2 3.299e-02 1.395e-02 -1.482 -1.855 -0.374 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 2.501e+00 - Cl- 2.501e+00 1.423e+00 0.398 0.153 -0.245 -K 4.233e-02 - K+ 4.233e-02 2.712e-02 -1.373 -1.567 -0.193 -Mg 2.396e-01 - Mg+2 2.395e-01 1.337e-01 -0.621 -0.874 -0.253 - MgCO3 3.187e-05 3.187e-05 -4.497 -4.497 0.000 - MgOH+ 7.881e-06 6.973e-06 -5.103 -5.157 -0.053 -Na 2.171e+00 - Na+ 2.171e+00 1.889e+00 0.337 0.276 -0.060 -S(6) 1.169e-01 - SO4-2 1.169e-01 2.278e-03 -0.932 -2.643 -1.710 - HSO4- 1.109e-08 5.873e-09 -7.955 -8.231 -0.276 + OH- 1.039e-06 3.375e-07 -5.983 -6.472 -0.488 (0) + H+ 1.625e-08 2.707e-08 -7.789 -7.568 0.222 0.00 + H2O 5.551e+01 9.093e-01 1.744 -0.041 0.000 18.07 +Br 3.756e-03 + Br- 3.756e-03 2.474e-03 -2.425 -2.607 -0.181 25.54 +C(4) 5.073e-04 + HCO3- 4.436e-04 1.663e-04 -3.353 -3.779 -0.426 25.12 + MgCO3 3.187e-05 3.187e-05 -4.497 -4.497 0.000 (0) + CO3-2 1.995e-05 2.813e-07 -4.700 -6.551 -1.851 -0.47 + CO2 6.300e-06 1.077e-05 -5.201 -4.968 0.233 (0) + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Ca 3.300e-02 + Ca+2 3.299e-02 1.395e-02 -1.482 -1.855 -0.374 -14.52 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 2.501e+00 + Cl- 2.501e+00 1.423e+00 0.398 0.153 -0.245 18.65 +K 4.233e-02 + K+ 4.233e-02 2.712e-02 -1.373 -1.567 -0.193 9.86 +Mg 2.396e-01 + Mg+2 2.395e-01 1.337e-01 -0.621 -0.874 -0.253 -17.84 + MgCO3 3.187e-05 3.187e-05 -4.497 -4.497 0.000 (0) + MgOH+ 7.881e-06 6.973e-06 -5.103 -5.157 -0.053 (0) +Na 2.171e+00 + Na+ 2.171e+00 1.889e+00 0.337 0.276 -0.060 -0.38 +S(6) 1.169e-01 + SO4-2 1.169e-01 2.278e-03 -0.932 -2.643 -1.710 17.29 + HSO4- 1.109e-08 5.873e-09 -7.955 -8.231 -0.276 (0) ------------------------------Saturation indices------------------------------- @@ -1175,35 +1175,35 @@ Polyhalite -4.34 -18.08 -13.74 0.000e+00 0 0.000e+00 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.016e-06 3.092e-07 -5.993 -6.510 -0.517 - H+ 1.423e-08 2.892e-08 -7.847 -7.539 0.308 - H2O 5.551e+01 8.902e-01 1.744 -0.051 0.000 -Br 4.440e-03 - Br- 4.440e-03 3.019e-03 -2.353 -2.520 -0.168 -C(4) 5.152e-04 - HCO3- 4.391e-04 1.523e-04 -3.357 -3.817 -0.460 - MgCO3 4.297e-05 4.297e-05 -4.367 -4.367 0.000 - CO3-2 2.185e-05 2.412e-07 -4.661 -6.618 -1.957 - CO2 5.742e-06 1.077e-05 -5.241 -4.968 0.273 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Ca 3.016e-02 - Ca+2 3.015e-02 1.627e-02 -1.521 -1.789 -0.268 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 2.957e+00 - Cl- 2.957e+00 1.693e+00 0.471 0.229 -0.242 -K 5.004e-02 - K+ 5.004e-02 3.292e-02 -1.301 -1.483 -0.182 -Mg 2.832e-01 - Mg+2 2.831e-01 2.102e-01 -0.548 -0.677 -0.129 - MgCO3 4.297e-05 4.297e-05 -4.367 -4.367 0.000 - MgOH+ 1.181e-05 1.005e-05 -4.928 -4.998 -0.070 -Na 2.566e+00 - Na+ 2.566e+00 2.421e+00 0.409 0.384 -0.025 -S(6) 1.294e-01 - SO4-2 1.294e-01 2.037e-03 -0.888 -2.691 -1.803 - HSO4- 1.089e-08 5.614e-09 -7.963 -8.251 -0.288 + OH- 1.016e-06 3.092e-07 -5.993 -6.510 -0.517 (0) + H+ 1.423e-08 2.892e-08 -7.847 -7.539 0.308 0.00 + H2O 5.551e+01 8.902e-01 1.744 -0.051 0.000 18.07 +Br 4.440e-03 + Br- 4.440e-03 3.019e-03 -2.353 -2.520 -0.168 25.60 +C(4) 5.152e-04 + HCO3- 4.391e-04 1.523e-04 -3.357 -3.817 -0.460 25.18 + MgCO3 4.297e-05 4.297e-05 -4.367 -4.367 0.000 (0) + CO3-2 2.185e-05 2.412e-07 -4.661 -6.618 -1.957 -0.20 + CO2 5.742e-06 1.077e-05 -5.241 -4.968 0.273 (0) + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Ca 3.016e-02 + Ca+2 3.015e-02 1.627e-02 -1.521 -1.789 -0.268 -14.25 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 2.957e+00 + Cl- 2.957e+00 1.693e+00 0.471 0.229 -0.242 18.71 +K 5.004e-02 + K+ 5.004e-02 3.292e-02 -1.301 -1.483 -0.182 9.92 +Mg 2.832e-01 + Mg+2 2.831e-01 2.102e-01 -0.548 -0.677 -0.129 -17.57 + MgCO3 4.297e-05 4.297e-05 -4.367 -4.367 0.000 (0) + MgOH+ 1.181e-05 1.005e-05 -4.928 -4.998 -0.070 (0) +Na 2.566e+00 + Na+ 2.566e+00 2.421e+00 0.409 0.384 -0.025 -0.32 +S(6) 1.294e-01 + SO4-2 1.294e-01 2.037e-03 -0.888 -2.691 -1.803 17.56 + HSO4- 1.089e-08 5.614e-09 -7.963 -8.251 -0.288 (0) ------------------------------Saturation indices------------------------------- @@ -1326,35 +1326,35 @@ Polyhalite -3.95 -17.69 -13.74 0.000e+00 0 0.000e+00 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 9.794e-07 2.732e-07 -6.009 -6.563 -0.554 - H+ 1.158e-08 3.166e-08 -7.936 -7.500 0.437 - H2O 5.551e+01 8.610e-01 1.744 -0.065 0.000 -Br 5.429e-03 - Br- 5.429e-03 3.891e-03 -2.265 -2.410 -0.145 -C(4) 5.373e-04 - HCO3- 4.367e-04 1.346e-04 -3.360 -3.871 -0.511 - MgCO3 6.591e-05 6.591e-05 -4.181 -4.181 0.000 - CO3-2 2.411e-05 1.947e-07 -4.618 -6.711 -2.093 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 - CO2 5.024e-06 1.077e-05 -5.299 -4.968 0.331 -Ca 2.556e-02 - Ca+2 2.556e-02 2.016e-02 -1.593 -1.696 -0.103 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 3.615e+00 - Cl- 3.615e+00 2.104e+00 0.558 0.323 -0.235 -K 6.118e-02 - K+ 6.118e-02 4.214e-02 -1.213 -1.375 -0.162 -Mg 3.462e-01 - Mg+2 3.462e-01 3.995e-01 -0.461 -0.399 0.062 - MgCO3 6.591e-05 6.591e-05 -4.181 -4.181 0.000 - MgOH+ 2.105e-05 1.687e-05 -4.677 -4.773 -0.096 -Na 3.138e+00 - Na+ 3.138e+00 3.366e+00 0.497 0.527 0.031 -S(6) 1.469e-01 - SO4-2 1.469e-01 1.758e-03 -0.833 -2.755 -1.922 - HSO4- 1.068e-08 5.303e-09 -7.971 -8.275 -0.304 + OH- 9.794e-07 2.732e-07 -6.009 -6.563 -0.554 (0) + H+ 1.158e-08 3.166e-08 -7.936 -7.500 0.437 0.00 + H2O 5.551e+01 8.610e-01 1.744 -0.065 0.000 18.07 +Br 5.429e-03 + Br- 5.429e-03 3.891e-03 -2.265 -2.410 -0.145 25.69 +C(4) 5.373e-04 + HCO3- 4.367e-04 1.346e-04 -3.360 -3.871 -0.511 25.27 + MgCO3 6.591e-05 6.591e-05 -4.181 -4.181 0.000 (0) + CO3-2 2.411e-05 1.947e-07 -4.618 -6.711 -2.093 0.16 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) + CO2 5.024e-06 1.077e-05 -5.299 -4.968 0.331 (0) +Ca 2.556e-02 + Ca+2 2.556e-02 2.016e-02 -1.593 -1.696 -0.103 -13.89 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 3.615e+00 + Cl- 3.615e+00 2.104e+00 0.558 0.323 -0.235 18.80 +K 6.118e-02 + K+ 6.118e-02 4.214e-02 -1.213 -1.375 -0.162 10.01 +Mg 3.462e-01 + Mg+2 3.462e-01 3.995e-01 -0.461 -0.399 0.062 -17.21 + MgCO3 6.591e-05 6.591e-05 -4.181 -4.181 0.000 (0) + MgOH+ 2.105e-05 1.687e-05 -4.677 -4.773 -0.096 (0) +Na 3.138e+00 + Na+ 3.138e+00 3.366e+00 0.497 0.527 0.031 -0.23 +S(6) 1.469e-01 + SO4-2 1.469e-01 1.758e-03 -0.833 -2.755 -1.922 17.92 + HSO4- 1.068e-08 5.303e-09 -7.971 -8.275 -0.304 (0) ------------------------------Saturation indices------------------------------- @@ -1477,35 +1477,35 @@ Polyhalite -3.34 -17.09 -13.74 0.000e+00 0 0.000e+00 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 9.216e-07 2.260e-07 -6.035 -6.646 -0.611 - H+ 8.155e-09 3.609e-08 -8.089 -7.443 0.646 - H2O 5.551e+01 8.116e-01 1.744 -0.091 0.000 -Br 6.984e-03 - Br- 6.984e-03 5.501e-03 -2.156 -2.260 -0.104 -C(4) 6.116e-04 - HCO3- 4.457e-04 1.113e-04 -3.351 -3.953 -0.602 - MgCO3 1.296e-04 1.296e-04 -3.887 -3.887 0.000 - CO3-2 2.663e-05 1.413e-07 -4.575 -6.850 -2.275 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 - CO2 4.072e-06 1.077e-05 -5.390 -4.968 0.422 -Ca 1.849e-02 - Ca+2 1.849e-02 2.778e-02 -1.733 -1.556 0.177 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 4.650e+00 - Cl- 4.650e+00 2.806e+00 0.667 0.448 -0.219 -K 7.870e-02 - K+ 7.870e-02 5.905e-02 -1.104 -1.229 -0.125 -Mg 4.454e-01 - Mg+2 4.452e-01 1.083e+00 -0.351 0.035 0.386 - MgCO3 1.296e-04 1.296e-04 -3.887 -3.887 0.000 - MgOH+ 5.175e-05 3.781e-05 -4.286 -4.422 -0.136 -Na 4.036e+00 - Na+ 4.036e+00 5.414e+00 0.606 0.734 0.128 -S(6) 1.746e-01 - SO4-2 1.746e-01 1.436e-03 -0.758 -2.843 -2.085 - HSO4- 1.056e-08 4.935e-09 -7.976 -8.307 -0.330 + OH- 9.216e-07 2.260e-07 -6.035 -6.646 -0.611 (0) + H+ 8.155e-09 3.609e-08 -8.089 -7.443 0.646 0.00 + H2O 5.551e+01 8.116e-01 1.744 -0.091 0.000 18.07 +Br 6.984e-03 + Br- 6.984e-03 5.501e-03 -2.156 -2.260 -0.104 25.82 +C(4) 6.116e-04 + HCO3- 4.457e-04 1.113e-04 -3.351 -3.953 -0.602 25.40 + MgCO3 1.296e-04 1.296e-04 -3.887 -3.887 0.000 (0) + CO3-2 2.663e-05 1.413e-07 -4.575 -6.850 -2.275 0.66 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) + CO2 4.072e-06 1.077e-05 -5.390 -4.968 0.422 (0) +Ca 1.849e-02 + Ca+2 1.849e-02 2.778e-02 -1.733 -1.556 0.177 -13.39 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 4.650e+00 + Cl- 4.650e+00 2.806e+00 0.667 0.448 -0.219 18.93 +K 7.870e-02 + K+ 7.870e-02 5.905e-02 -1.104 -1.229 -0.125 10.14 +Mg 4.454e-01 + Mg+2 4.452e-01 1.083e+00 -0.351 0.035 0.386 -16.71 + MgCO3 1.296e-04 1.296e-04 -3.887 -3.887 0.000 (0) + MgOH+ 5.175e-05 3.781e-05 -4.286 -4.422 -0.136 (0) +Na 4.036e+00 + Na+ 4.036e+00 5.414e+00 0.606 0.734 0.128 -0.10 +S(6) 1.746e-01 + SO4-2 1.746e-01 1.436e-03 -0.758 -2.843 -2.085 18.42 + HSO4- 1.056e-08 4.935e-09 -7.976 -8.307 -0.330 (0) ------------------------------Saturation indices------------------------------- @@ -1628,35 +1628,35 @@ Polyhalite -2.49 -16.23 -13.74 0.000e+00 0 0.000e+00 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 9.417e-07 1.893e-07 -6.026 -6.723 -0.697 - H+ 4.582e-09 3.931e-08 -8.339 -7.405 0.933 - H2O 5.551e+01 7.406e-01 1.744 -0.130 0.000 -Br 9.746e-03 - Br- 9.746e-03 8.889e-03 -2.011 -2.051 -0.040 -C(4) 9.763e-04 - HCO3- 5.295e-04 9.325e-05 -3.276 -4.030 -0.754 - MgCO3 4.035e-04 4.035e-04 -3.394 -3.394 0.000 - CO3-2 3.471e-05 1.086e-07 -4.460 -6.964 -2.505 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 - CO2 3.071e-06 1.077e-05 -5.513 -4.968 0.545 -Ca 9.637e-03 - Ca+2 9.631e-03 3.614e-02 -2.016 -1.442 0.574 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 5.999e+00 - Cl- 5.999e+00 3.851e+00 0.778 0.586 -0.192 -K 1.098e-01 - K+ 1.098e-01 9.405e-02 -0.959 -1.027 -0.067 -Mg 6.216e-01 - Mg+2 6.210e-01 4.384e+00 -0.207 0.642 0.849 - MgCO3 4.035e-04 4.035e-04 -3.394 -3.394 0.000 - MgOH+ 1.948e-04 1.282e-04 -3.710 -3.892 -0.182 -Na 5.142e+00 - Na+ 5.142e+00 9.647e+00 0.711 0.984 0.273 -S(6) 2.273e-01 - SO4-2 2.273e-01 1.203e-03 -0.643 -2.920 -2.276 - HSO4- 1.034e-08 4.507e-09 -7.985 -8.346 -0.361 + OH- 9.417e-07 1.893e-07 -6.026 -6.723 -0.697 (0) + H+ 4.582e-09 3.931e-08 -8.339 -7.405 0.933 0.00 + H2O 5.551e+01 7.406e-01 1.744 -0.130 0.000 18.07 +Br 9.746e-03 + Br- 9.746e-03 8.889e-03 -2.011 -2.051 -0.040 25.98 +C(4) 9.763e-04 + HCO3- 5.295e-04 9.325e-05 -3.276 -4.030 -0.754 25.56 + MgCO3 4.035e-04 4.035e-04 -3.394 -3.394 0.000 (0) + CO3-2 3.471e-05 1.086e-07 -4.460 -6.964 -2.505 1.28 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) + CO2 3.071e-06 1.077e-05 -5.513 -4.968 0.545 (0) +Ca 9.637e-03 + Ca+2 9.631e-03 3.614e-02 -2.016 -1.442 0.574 -12.77 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 5.999e+00 + Cl- 5.999e+00 3.851e+00 0.778 0.586 -0.192 19.09 +K 1.098e-01 + K+ 1.098e-01 9.405e-02 -0.959 -1.027 -0.067 10.30 +Mg 6.216e-01 + Mg+2 6.210e-01 4.384e+00 -0.207 0.642 0.849 -16.09 + MgCO3 4.035e-04 4.035e-04 -3.394 -3.394 0.000 (0) + MgOH+ 1.948e-04 1.282e-04 -3.710 -3.892 -0.182 (0) +Na 5.142e+00 + Na+ 5.142e+00 9.647e+00 0.711 0.984 0.273 0.06 +S(6) 2.273e-01 + SO4-2 2.273e-01 1.203e-03 -0.643 -2.920 -2.276 19.04 + HSO4- 1.034e-08 4.507e-09 -7.985 -8.346 -0.361 (0) ------------------------------Saturation indices------------------------------- @@ -1779,35 +1779,35 @@ Polyhalite -1.53 -15.27 -13.74 0.000e+00 0 0.000e+00 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.422e-06 2.087e-07 -5.847 -6.681 -0.834 - H+ 3.632e-09 3.517e-08 -8.440 -7.454 0.986 - H2O 5.551e+01 7.307e-01 1.744 -0.136 0.000 -Br 1.621e-02 - Br- 1.621e-02 1.605e-02 -1.790 -1.794 -0.004 -C(4) 1.787e-03 - MgCO3 1.019e-03 1.019e-03 -2.992 -2.992 0.000 - HCO3- 6.776e-04 1.028e-04 -3.169 -3.988 -0.819 - CO3-2 8.154e-05 1.338e-07 -4.089 -6.873 -2.785 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 - CO2 2.932e-06 1.077e-05 -5.533 -4.968 0.565 -Ca 6.850e-03 - Ca+2 6.845e-03 2.932e-02 -2.165 -1.533 0.632 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 5.983e+00 - Cl- 5.983e+00 3.956e+00 0.777 0.597 -0.180 -K 1.827e-01 - K+ 1.827e-01 1.637e-01 -0.738 -0.786 -0.048 -Mg 1.034e+00 - Mg+2 1.033e+00 8.987e+00 0.014 0.954 0.940 - MgCO3 1.019e-03 1.019e-03 -2.992 -2.992 0.000 - MgOH+ 4.214e-04 2.898e-04 -3.375 -3.538 -0.163 -Na 4.484e+00 - Na+ 4.484e+00 9.392e+00 0.652 0.973 0.321 -S(6) 3.319e-01 - SO4-2 3.319e-01 1.483e-03 -0.479 -2.829 -2.350 - HSO4- 9.639e-09 4.970e-09 -8.016 -8.304 -0.288 + OH- 1.422e-06 2.087e-07 -5.847 -6.681 -0.834 (0) + H+ 3.632e-09 3.517e-08 -8.440 -7.454 0.986 0.00 + H2O 5.551e+01 7.307e-01 1.744 -0.136 0.000 18.07 +Br 1.621e-02 + Br- 1.621e-02 1.605e-02 -1.790 -1.794 -0.004 26.04 +C(4) 1.787e-03 + MgCO3 1.019e-03 1.019e-03 -2.992 -2.992 0.000 (0) + HCO3- 6.776e-04 1.028e-04 -3.169 -3.988 -0.819 25.62 + CO3-2 8.154e-05 1.338e-07 -4.089 -6.873 -2.785 1.53 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) + CO2 2.932e-06 1.077e-05 -5.533 -4.968 0.565 (0) +Ca 6.850e-03 + Ca+2 6.845e-03 2.932e-02 -2.165 -1.533 0.632 -12.52 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 5.983e+00 + Cl- 5.983e+00 3.956e+00 0.777 0.597 -0.180 19.15 +K 1.827e-01 + K+ 1.827e-01 1.637e-01 -0.738 -0.786 -0.048 10.36 +Mg 1.034e+00 + Mg+2 1.033e+00 8.987e+00 0.014 0.954 0.940 -15.84 + MgCO3 1.019e-03 1.019e-03 -2.992 -2.992 0.000 (0) + MgOH+ 4.214e-04 2.898e-04 -3.375 -3.538 -0.163 (0) +Na 4.484e+00 + Na+ 4.484e+00 9.392e+00 0.652 0.973 0.321 0.12 +S(6) 3.319e-01 + SO4-2 3.319e-01 1.483e-03 -0.479 -2.829 -2.350 19.29 + HSO4- 9.639e-09 4.970e-09 -8.016 -8.304 -0.288 (0) ------------------------------Saturation indices------------------------------- @@ -1930,35 +1930,35 @@ Polyhalite -1.19 -14.94 -13.74 0.000e+00 0 0.000e+00 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.685e-06 2.113e-07 -5.773 -6.675 -0.902 - H+ 3.317e-09 3.448e-08 -8.479 -7.462 1.017 - H2O 5.551e+01 7.252e-01 1.744 -0.140 0.000 -Br 1.944e-02 - Br- 1.944e-02 2.001e-02 -1.711 -1.699 0.013 -C(4) 2.290e-03 - MgCO3 1.424e-03 1.424e-03 -2.847 -2.847 0.000 - HCO3- 7.421e-04 1.041e-04 -3.130 -3.983 -0.853 - CO3-2 1.154e-04 1.382e-07 -3.938 -6.859 -2.921 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 - CO2 2.874e-06 1.077e-05 -5.542 -4.968 0.574 -Ca 6.075e-03 - Ca+2 6.070e-03 2.839e-02 -2.217 -1.547 0.670 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 5.993e+00 - Cl- 5.993e+00 4.020e+00 0.778 0.604 -0.173 -K 2.191e-01 - K+ 2.191e-01 2.017e-01 -0.659 -0.695 -0.036 -Mg 1.240e+00 - Mg+2 1.238e+00 1.215e+01 0.093 1.085 0.992 - MgCO3 1.424e-03 1.424e-03 -2.847 -2.847 0.000 - MgOH+ 5.570e-04 3.968e-04 -3.254 -3.401 -0.147 -Na 4.152e+00 - Na+ 4.152e+00 9.242e+00 0.618 0.966 0.347 -S(6) 3.737e-01 - SO4-2 3.737e-01 1.532e-03 -0.427 -2.815 -2.387 - HSO4- 8.983e-09 5.031e-09 -8.047 -8.298 -0.252 + OH- 1.685e-06 2.113e-07 -5.773 -6.675 -0.902 (0) + H+ 3.317e-09 3.448e-08 -8.479 -7.462 1.017 0.00 + H2O 5.551e+01 7.252e-01 1.744 -0.140 0.000 18.07 +Br 1.944e-02 + Br- 1.944e-02 2.001e-02 -1.711 -1.699 0.013 26.07 +C(4) 2.290e-03 + MgCO3 1.424e-03 1.424e-03 -2.847 -2.847 0.000 (0) + HCO3- 7.421e-04 1.041e-04 -3.130 -3.983 -0.853 25.65 + CO3-2 1.154e-04 1.382e-07 -3.938 -6.859 -2.921 1.64 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) + CO2 2.874e-06 1.077e-05 -5.542 -4.968 0.574 (0) +Ca 6.075e-03 + Ca+2 6.070e-03 2.839e-02 -2.217 -1.547 0.670 -12.41 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 5.993e+00 + Cl- 5.993e+00 4.020e+00 0.778 0.604 -0.173 19.18 +K 2.191e-01 + K+ 2.191e-01 2.017e-01 -0.659 -0.695 -0.036 10.39 +Mg 1.240e+00 + Mg+2 1.238e+00 1.215e+01 0.093 1.085 0.992 -15.73 + MgCO3 1.424e-03 1.424e-03 -2.847 -2.847 0.000 (0) + MgOH+ 5.570e-04 3.968e-04 -3.254 -3.401 -0.147 (0) +Na 4.152e+00 + Na+ 4.152e+00 9.242e+00 0.618 0.966 0.347 0.15 +S(6) 3.737e-01 + SO4-2 3.737e-01 1.532e-03 -0.427 -2.815 -2.387 19.40 + HSO4- 8.983e-09 5.031e-09 -8.047 -8.298 -0.252 (0) ------------------------------Saturation indices------------------------------- @@ -2081,35 +2081,35 @@ Polyhalite -0.75 -14.50 -13.74 0.000e+00 0 0.000e+00 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.166e-06 2.154e-07 -5.664 -6.667 -1.002 - H+ 2.859e-09 3.339e-08 -8.544 -7.476 1.067 - H2O 5.551e+01 7.160e-01 1.744 -0.145 0.000 -Br 2.427e-02 - Br- 2.427e-02 2.650e-02 -1.615 -1.577 0.038 -C(4) 3.327e-03 - MgCO3 2.265e-03 2.265e-03 -2.645 -2.645 0.000 - HCO3- 8.617e-04 1.061e-04 -3.065 -3.974 -0.909 - CO3-2 1.917e-04 1.455e-07 -3.717 -6.837 -3.120 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 - CO2 2.769e-06 1.077e-05 -5.558 -4.968 0.590 -Ca 5.013e-03 - Ca+2 5.008e-03 2.696e-02 -2.300 -1.569 0.731 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 6.007e+00 - Cl- 6.007e+00 4.125e+00 0.779 0.615 -0.163 -K 2.735e-01 - K+ 2.735e-01 2.626e-01 -0.563 -0.581 -0.018 -Mg 1.548e+00 - Mg+2 1.545e+00 1.837e+01 0.189 1.264 1.075 - MgCO3 2.265e-03 2.265e-03 -2.645 -2.645 0.000 - MgOH+ 8.105e-04 6.114e-04 -3.091 -3.214 -0.122 -Na 3.680e+00 - Na+ 3.680e+00 9.007e+00 0.566 0.955 0.389 -S(6) 4.487e-01 - SO4-2 4.487e-01 1.613e-03 -0.348 -2.792 -2.444 - HSO4- 8.133e-09 5.130e-09 -8.090 -8.290 -0.200 + OH- 2.166e-06 2.154e-07 -5.664 -6.667 -1.002 (0) + H+ 2.859e-09 3.339e-08 -8.544 -7.476 1.067 0.00 + H2O 5.551e+01 7.160e-01 1.744 -0.145 0.000 18.07 +Br 2.427e-02 + Br- 2.427e-02 2.650e-02 -1.615 -1.577 0.038 26.11 +C(4) 3.327e-03 + MgCO3 2.265e-03 2.265e-03 -2.645 -2.645 0.000 (0) + HCO3- 8.617e-04 1.061e-04 -3.065 -3.974 -0.909 25.69 + CO3-2 1.917e-04 1.455e-07 -3.717 -6.837 -3.120 1.82 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) + CO2 2.769e-06 1.077e-05 -5.558 -4.968 0.590 (0) +Ca 5.013e-03 + Ca+2 5.008e-03 2.696e-02 -2.300 -1.569 0.731 -12.23 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 6.007e+00 + Cl- 6.007e+00 4.125e+00 0.779 0.615 -0.163 19.22 +K 2.735e-01 + K+ 2.735e-01 2.626e-01 -0.563 -0.581 -0.018 10.43 +Mg 1.548e+00 + Mg+2 1.545e+00 1.837e+01 0.189 1.264 1.075 -15.55 + MgCO3 2.265e-03 2.265e-03 -2.645 -2.645 0.000 (0) + MgOH+ 8.105e-04 6.114e-04 -3.091 -3.214 -0.122 (0) +Na 3.680e+00 + Na+ 3.680e+00 9.007e+00 0.566 0.955 0.389 0.19 +S(6) 4.487e-01 + SO4-2 4.487e-01 1.613e-03 -0.348 -2.792 -2.444 19.58 + HSO4- 8.133e-09 5.130e-09 -8.090 -8.290 -0.200 (0) ------------------------------Saturation indices------------------------------- @@ -2232,35 +2232,35 @@ Polyhalite -0.33 -14.07 -13.74 0.000e+00 0 0.000e+00 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.815e-06 2.201e-07 -5.551 -6.657 -1.107 - H+ 2.398e-09 3.217e-08 -8.620 -7.492 1.128 - H2O 5.551e+01 7.049e-01 1.744 -0.152 0.000 -Br 2.941e-02 - Br- 2.941e-02 3.421e-02 -1.531 -1.466 0.066 -C(4) 4.984e-03 - MgCO3 3.621e-03 3.621e-03 -2.441 -2.441 0.000 - HCO3- 1.031e-03 1.084e-04 -2.987 -3.965 -0.978 - CO3-2 3.242e-04 1.543e-07 -3.489 -6.812 -3.322 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 - CO2 2.631e-06 1.077e-05 -5.580 -4.968 0.612 -Ca 4.021e-03 - Ca+2 4.015e-03 2.543e-02 -2.396 -1.595 0.802 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 6.017e+00 - Cl- 6.017e+00 4.247e+00 0.779 0.628 -0.151 -K 3.315e-01 - K+ 3.315e-01 3.332e-01 -0.480 -0.477 0.002 -Mg 1.876e+00 - Mg+2 1.871e+00 2.769e+01 0.272 1.442 1.170 - MgCO3 3.621e-03 3.621e-03 -2.441 -2.441 0.000 - MgOH+ 1.167e-03 9.418e-04 -2.933 -3.026 -0.093 -Na 3.213e+00 - Na+ 3.213e+00 8.747e+00 0.507 0.942 0.435 -S(6) 5.489e-01 - SO4-2 5.489e-01 1.710e-03 -0.261 -2.767 -2.507 - HSO4- 7.380e-09 5.241e-09 -8.132 -8.281 -0.149 + OH- 2.815e-06 2.201e-07 -5.551 -6.657 -1.107 (0) + H+ 2.398e-09 3.217e-08 -8.620 -7.492 1.128 0.00 + H2O 5.551e+01 7.049e-01 1.744 -0.152 0.000 18.07 +Br 2.941e-02 + Br- 2.941e-02 3.421e-02 -1.531 -1.466 0.066 26.16 +C(4) 4.984e-03 + MgCO3 3.621e-03 3.621e-03 -2.441 -2.441 0.000 (0) + HCO3- 1.031e-03 1.084e-04 -2.987 -3.965 -0.978 25.74 + CO3-2 3.242e-04 1.543e-07 -3.489 -6.812 -3.322 2.02 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) + CO2 2.631e-06 1.077e-05 -5.580 -4.968 0.612 (0) +Ca 4.021e-03 + Ca+2 4.015e-03 2.543e-02 -2.396 -1.595 0.802 -12.03 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 6.017e+00 + Cl- 6.017e+00 4.247e+00 0.779 0.628 -0.151 19.27 +K 3.315e-01 + K+ 3.315e-01 3.332e-01 -0.480 -0.477 0.002 10.48 +Mg 1.876e+00 + Mg+2 1.871e+00 2.769e+01 0.272 1.442 1.170 -15.35 + MgCO3 3.621e-03 3.621e-03 -2.441 -2.441 0.000 (0) + MgOH+ 1.167e-03 9.418e-04 -2.933 -3.026 -0.093 (0) +Na 3.213e+00 + Na+ 3.213e+00 8.747e+00 0.507 0.942 0.435 0.24 +S(6) 5.489e-01 + SO4-2 5.489e-01 1.710e-03 -0.261 -2.767 -2.507 19.78 + HSO4- 7.380e-09 5.241e-09 -8.132 -8.281 -0.149 (0) ------------------------------Saturation indices------------------------------- @@ -2383,35 +2383,35 @@ Polyhalite -0.18 -13.93 -13.74 0.000e+00 0 0.000e+00 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 3.093e-06 2.218e-07 -5.510 -6.654 -1.144 - H+ 2.238e-09 3.172e-08 -8.650 -7.499 1.152 - H2O 5.551e+01 7.005e-01 1.744 -0.155 0.000 -Br 3.130e-02 - Br- 3.130e-02 3.728e-02 -1.505 -1.429 0.076 -C(4) 5.790e-03 - MgCO3 4.283e-03 4.283e-03 -2.368 -2.368 0.000 - HCO3- 1.107e-03 1.093e-04 -2.956 -3.961 -1.006 - CO3-2 3.911e-04 1.578e-07 -3.408 -6.802 -3.394 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 - CO2 2.574e-06 1.077e-05 -5.589 -4.968 0.621 -Ca 3.695e-03 - Ca+2 3.689e-03 2.487e-02 -2.433 -1.604 0.829 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 6.018e+00 - Cl- 6.018e+00 4.295e+00 0.779 0.633 -0.147 -K 3.527e-01 - K+ 3.527e-01 3.606e-01 -0.453 -0.443 0.010 -Mg 1.996e+00 - Mg+2 1.990e+00 3.204e+01 0.299 1.506 1.207 - MgCO3 4.283e-03 4.283e-03 -2.368 -2.368 0.000 - MgOH+ 1.326e-03 1.098e-03 -2.878 -2.959 -0.082 -Na 3.052e+00 - Na+ 3.052e+00 8.651e+00 0.485 0.937 0.452 -S(6) 5.918e-01 - SO4-2 5.918e-01 1.748e-03 -0.228 -2.757 -2.530 - HSO4- 7.140e-09 5.283e-09 -8.146 -8.277 -0.131 + OH- 3.093e-06 2.218e-07 -5.510 -6.654 -1.144 (0) + H+ 2.238e-09 3.172e-08 -8.650 -7.499 1.152 0.00 + H2O 5.551e+01 7.005e-01 1.744 -0.155 0.000 18.07 +Br 3.130e-02 + Br- 3.130e-02 3.728e-02 -1.505 -1.429 0.076 26.18 +C(4) 5.790e-03 + MgCO3 4.283e-03 4.283e-03 -2.368 -2.368 0.000 (0) + HCO3- 1.107e-03 1.093e-04 -2.956 -3.961 -1.006 25.76 + CO3-2 3.911e-04 1.578e-07 -3.408 -6.802 -3.394 2.10 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) + CO2 2.574e-06 1.077e-05 -5.589 -4.968 0.621 (0) +Ca 3.695e-03 + Ca+2 3.689e-03 2.487e-02 -2.433 -1.604 0.829 -11.95 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 6.018e+00 + Cl- 6.018e+00 4.295e+00 0.779 0.633 -0.147 19.29 +K 3.527e-01 + K+ 3.527e-01 3.606e-01 -0.453 -0.443 0.010 10.50 +Mg 1.996e+00 + Mg+2 1.990e+00 3.204e+01 0.299 1.506 1.207 -15.27 + MgCO3 4.283e-03 4.283e-03 -2.368 -2.368 0.000 (0) + MgOH+ 1.326e-03 1.098e-03 -2.878 -2.959 -0.082 (0) +Na 3.052e+00 + Na+ 3.052e+00 8.651e+00 0.485 0.937 0.452 0.26 +S(6) 5.918e-01 + SO4-2 5.918e-01 1.748e-03 -0.228 -2.757 -2.530 19.86 + HSO4- 7.140e-09 5.283e-09 -8.146 -8.277 -0.131 (0) ------------------------------Saturation indices------------------------------- @@ -2534,35 +2534,35 @@ Polyhalite -0.02 -13.77 -13.74 0.000e+00 0 0.000e+00 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 3.440e-06 2.238e-07 -5.463 -6.650 -1.187 - H+ 2.061e-09 3.120e-08 -8.686 -7.506 1.180 - H2O 5.551e+01 6.952e-01 1.744 -0.158 0.000 -Br 3.344e-02 - Br- 3.344e-02 4.093e-02 -1.476 -1.388 0.088 -C(4) 6.871e-03 - MgCO3 5.174e-03 5.174e-03 -2.286 -2.286 0.000 - HCO3- 1.206e-03 1.103e-04 -2.919 -3.957 -1.039 - CO3-2 4.827e-04 1.619e-07 -3.316 -6.791 -3.475 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 - CO2 2.505e-06 1.077e-05 -5.601 -4.968 0.633 -Ca 3.349e-03 - Ca+2 3.343e-03 2.425e-02 -2.476 -1.615 0.860 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 6.017e+00 - Cl- 6.017e+00 4.350e+00 0.779 0.638 -0.141 -K 3.768e-01 - K+ 3.768e-01 3.927e-01 -0.424 -0.406 0.018 -Mg 2.133e+00 - Mg+2 2.126e+00 3.773e+01 0.328 1.577 1.249 - MgCO3 5.174e-03 5.174e-03 -2.286 -2.286 0.000 - MgOH+ 1.527e-03 1.305e-03 -2.816 -2.884 -0.068 -Na 2.877e+00 - Na+ 2.877e+00 8.541e+00 0.459 0.932 0.473 -S(6) 6.451e-01 - SO4-2 6.451e-01 1.793e-03 -0.190 -2.746 -2.556 - HSO4- 6.887e-09 5.331e-09 -8.162 -8.273 -0.111 + OH- 3.440e-06 2.238e-07 -5.463 -6.650 -1.187 (0) + H+ 2.061e-09 3.120e-08 -8.686 -7.506 1.180 0.00 + H2O 5.551e+01 6.952e-01 1.744 -0.158 0.000 18.07 +Br 3.344e-02 + Br- 3.344e-02 4.093e-02 -1.476 -1.388 0.088 26.20 +C(4) 6.871e-03 + MgCO3 5.174e-03 5.174e-03 -2.286 -2.286 0.000 (0) + HCO3- 1.206e-03 1.103e-04 -2.919 -3.957 -1.039 25.78 + CO3-2 4.827e-04 1.619e-07 -3.316 -6.791 -3.475 2.18 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) + CO2 2.505e-06 1.077e-05 -5.601 -4.968 0.633 (0) +Ca 3.349e-03 + Ca+2 3.343e-03 2.425e-02 -2.476 -1.615 0.860 -11.87 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 6.017e+00 + Cl- 6.017e+00 4.350e+00 0.779 0.638 -0.141 19.31 +K 3.768e-01 + K+ 3.768e-01 3.927e-01 -0.424 -0.406 0.018 10.52 +Mg 2.133e+00 + Mg+2 2.126e+00 3.773e+01 0.328 1.577 1.249 -15.19 + MgCO3 5.174e-03 5.174e-03 -2.286 -2.286 0.000 (0) + MgOH+ 1.527e-03 1.305e-03 -2.816 -2.884 -0.068 (0) +Na 2.877e+00 + Na+ 2.877e+00 8.541e+00 0.459 0.932 0.473 0.28 +S(6) 6.451e-01 + SO4-2 6.451e-01 1.793e-03 -0.190 -2.746 -2.556 19.94 + HSO4- 6.887e-09 5.331e-09 -8.162 -8.273 -0.111 (0) ------------------------------Saturation indices------------------------------- @@ -2685,35 +2685,35 @@ Polyhalite -0.00 -13.74 -13.74 0.000e+00 3.453e-04 3.453e-04 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 3.820e-06 2.245e-07 -5.418 -6.649 -1.231 - H+ 1.934e-09 3.092e-08 -8.714 -7.510 1.204 - H2O 5.551e+01 6.910e-01 1.744 -0.161 0.000 -Br 3.593e-02 - Br- 3.593e-02 4.499e-02 -1.445 -1.347 0.098 -C(4) 8.012e-03 - MgCO3 6.112e-03 6.112e-03 -2.214 -2.214 0.000 - HCO3- 1.298e-03 1.106e-04 -2.887 -3.956 -1.069 - CO3-2 5.937e-04 1.638e-07 -3.226 -6.786 -3.559 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 - CO2 2.445e-06 1.077e-05 -5.612 -4.968 0.644 -Ca 3.072e-03 - Ca+2 3.066e-03 2.395e-02 -2.513 -1.621 0.893 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 5.989e+00 - Cl- 5.989e+00 4.376e+00 0.777 0.641 -0.136 -K 3.485e-01 - K+ 3.485e-01 3.711e-01 -0.458 -0.431 0.027 -Mg 2.263e+00 - Mg+2 2.256e+00 4.403e+01 0.353 1.644 1.290 - MgCO3 6.112e-03 6.112e-03 -2.214 -2.214 0.000 - MgOH+ 1.719e-03 1.527e-03 -2.765 -2.816 -0.051 -Na 2.728e+00 - Na+ 2.728e+00 8.489e+00 0.436 0.929 0.493 -S(6) 6.921e-01 - SO4-2 6.921e-01 1.815e-03 -0.160 -2.741 -2.581 - HSO4- 6.599e-09 5.347e-09 -8.181 -8.272 -0.091 + OH- 3.820e-06 2.245e-07 -5.418 -6.649 -1.231 (0) + H+ 1.934e-09 3.092e-08 -8.714 -7.510 1.204 0.00 + H2O 5.551e+01 6.910e-01 1.744 -0.161 0.000 18.07 +Br 3.593e-02 + Br- 3.593e-02 4.499e-02 -1.445 -1.347 0.098 26.22 +C(4) 8.012e-03 + MgCO3 6.112e-03 6.112e-03 -2.214 -2.214 0.000 (0) + HCO3- 1.298e-03 1.106e-04 -2.887 -3.956 -1.069 25.80 + CO3-2 5.937e-04 1.638e-07 -3.226 -6.786 -3.559 2.26 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) + CO2 2.445e-06 1.077e-05 -5.612 -4.968 0.644 (0) +Ca 3.072e-03 + Ca+2 3.066e-03 2.395e-02 -2.513 -1.621 0.893 -11.79 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 5.989e+00 + Cl- 5.989e+00 4.376e+00 0.777 0.641 -0.136 19.33 +K 3.485e-01 + K+ 3.485e-01 3.711e-01 -0.458 -0.431 0.027 10.54 +Mg 2.263e+00 + Mg+2 2.256e+00 4.403e+01 0.353 1.644 1.290 -15.11 + MgCO3 6.112e-03 6.112e-03 -2.214 -2.214 0.000 (0) + MgOH+ 1.719e-03 1.527e-03 -2.765 -2.816 -0.051 (0) +Na 2.728e+00 + Na+ 2.728e+00 8.489e+00 0.436 0.929 0.493 0.30 +S(6) 6.921e-01 + SO4-2 6.921e-01 1.815e-03 -0.160 -2.741 -2.581 20.02 + HSO4- 6.599e-09 5.347e-09 -8.181 -8.272 -0.091 (0) ------------------------------Saturation indices------------------------------- @@ -2836,35 +2836,35 @@ Polyhalite 0.00 -13.74 -13.74 3.453e-04 7.058e-04 3.605e-04 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 4.279e-06 2.233e-07 -5.369 -6.651 -1.282 - H+ 1.807e-09 3.085e-08 -8.743 -7.511 1.232 - H2O 5.551e+01 6.858e-01 1.744 -0.164 0.000 -Br 3.883e-02 - Br- 3.883e-02 4.985e-02 -1.411 -1.302 0.108 -C(4) 9.464e-03 - MgCO3 7.311e-03 7.311e-03 -2.136 -2.136 0.000 - HCO3- 1.402e-03 1.100e-04 -2.853 -3.958 -1.105 - CO3-2 7.429e-04 1.633e-07 -3.129 -6.787 -3.658 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 - CO2 2.384e-06 1.077e-05 -5.623 -4.968 0.655 -Ca 2.800e-03 - Ca+2 2.794e-03 2.403e-02 -2.554 -1.619 0.935 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 5.968e+00 - Cl- 5.968e+00 4.412e+00 0.776 0.645 -0.131 -K 3.130e-01 - K+ 3.130e-01 3.424e-01 -0.504 -0.465 0.039 -Mg 2.414e+00 - Mg+2 2.405e+00 5.284e+01 0.381 1.723 1.342 - MgCO3 7.311e-03 7.311e-03 -2.136 -2.136 0.000 - MgOH+ 1.953e-03 1.823e-03 -2.709 -2.739 -0.030 -Na 2.555e+00 - Na+ 2.555e+00 8.420e+00 0.407 0.925 0.518 -S(6) 7.388e-01 - SO4-2 7.388e-01 1.809e-03 -0.131 -2.743 -2.611 - HSO4- 6.226e-09 5.318e-09 -8.206 -8.274 -0.069 + OH- 4.279e-06 2.233e-07 -5.369 -6.651 -1.282 (0) + H+ 1.807e-09 3.085e-08 -8.743 -7.511 1.232 0.00 + H2O 5.551e+01 6.858e-01 1.744 -0.164 0.000 18.07 +Br 3.883e-02 + Br- 3.883e-02 4.985e-02 -1.411 -1.302 0.108 26.24 +C(4) 9.464e-03 + MgCO3 7.311e-03 7.311e-03 -2.136 -2.136 0.000 (0) + HCO3- 1.402e-03 1.100e-04 -2.853 -3.958 -1.105 25.82 + CO3-2 7.429e-04 1.633e-07 -3.129 -6.787 -3.658 2.34 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) + CO2 2.384e-06 1.077e-05 -5.623 -4.968 0.655 (0) +Ca 2.800e-03 + Ca+2 2.794e-03 2.403e-02 -2.554 -1.619 0.935 -11.71 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 5.968e+00 + Cl- 5.968e+00 4.412e+00 0.776 0.645 -0.131 19.35 +K 3.130e-01 + K+ 3.130e-01 3.424e-01 -0.504 -0.465 0.039 10.56 +Mg 2.414e+00 + Mg+2 2.405e+00 5.284e+01 0.381 1.723 1.342 -15.03 + MgCO3 7.311e-03 7.311e-03 -2.136 -2.136 0.000 (0) + MgOH+ 1.953e-03 1.823e-03 -2.709 -2.739 -0.030 (0) +Na 2.555e+00 + Na+ 2.555e+00 8.420e+00 0.407 0.925 0.518 0.32 +S(6) 7.388e-01 + SO4-2 7.388e-01 1.809e-03 -0.131 -2.743 -2.611 20.10 + HSO4- 6.226e-09 5.318e-09 -8.206 -8.274 -0.069 (0) ------------------------------Saturation indices------------------------------- @@ -2987,35 +2987,35 @@ Polyhalite -0.00 -13.74 -13.74 7.058e-04 8.694e-04 1.636e-04 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 4.559e-06 2.177e-07 -5.341 -6.662 -1.321 - H+ 1.743e-09 3.144e-08 -8.759 -7.503 1.256 - H2O 5.551e+01 6.814e-01 1.744 -0.167 0.000 -Br 4.079e-02 - Br- 4.079e-02 5.321e-02 -1.389 -1.274 0.115 -C(4) 1.040e-02 - MgCO3 8.103e-03 8.103e-03 -2.091 -2.091 0.000 - HCO3- 1.448e-03 1.073e-04 -2.839 -3.969 -1.130 - CO3-2 8.420e-04 1.562e-07 -3.075 -6.806 -3.732 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 - CO2 2.361e-06 1.077e-05 -5.627 -4.968 0.659 -Ca 2.670e-03 - Ca+2 2.664e-03 2.512e-02 -2.574 -1.600 0.974 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 5.996e+00 - Cl- 5.996e+00 4.464e+00 0.778 0.650 -0.128 -K 2.986e-01 - K+ 2.986e-01 3.346e-01 -0.525 -0.475 0.050 -Mg 2.521e+00 - Mg+2 2.511e+00 6.120e+01 0.400 1.787 1.387 - MgCO3 8.103e-03 8.103e-03 -2.091 -2.091 0.000 - MgOH+ 2.114e-03 2.059e-03 -2.675 -2.686 -0.012 -Na 2.411e+00 - Na+ 2.411e+00 8.324e+00 0.382 0.920 0.538 -S(6) 7.451e-01 - SO4-2 7.451e-01 1.731e-03 -0.128 -2.762 -2.634 - HSO4- 5.833e-09 5.185e-09 -8.234 -8.285 -0.051 + OH- 4.559e-06 2.177e-07 -5.341 -6.662 -1.321 (0) + H+ 1.743e-09 3.144e-08 -8.759 -7.503 1.256 0.00 + H2O 5.551e+01 6.814e-01 1.744 -0.167 0.000 18.07 +Br 4.079e-02 + Br- 4.079e-02 5.321e-02 -1.389 -1.274 0.115 26.25 +C(4) 1.040e-02 + MgCO3 8.103e-03 8.103e-03 -2.091 -2.091 0.000 (0) + HCO3- 1.448e-03 1.073e-04 -2.839 -3.969 -1.130 25.83 + CO3-2 8.420e-04 1.562e-07 -3.075 -6.806 -3.732 2.38 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) + CO2 2.361e-06 1.077e-05 -5.627 -4.968 0.659 (0) +Ca 2.670e-03 + Ca+2 2.664e-03 2.512e-02 -2.574 -1.600 0.974 -11.67 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 5.996e+00 + Cl- 5.996e+00 4.464e+00 0.778 0.650 -0.128 19.36 +K 2.986e-01 + K+ 2.986e-01 3.346e-01 -0.525 -0.475 0.050 10.57 +Mg 2.521e+00 + Mg+2 2.511e+00 6.120e+01 0.400 1.787 1.387 -14.99 + MgCO3 8.103e-03 8.103e-03 -2.091 -2.091 0.000 (0) + MgOH+ 2.114e-03 2.059e-03 -2.675 -2.686 -0.012 (0) +Na 2.411e+00 + Na+ 2.411e+00 8.324e+00 0.382 0.920 0.538 0.33 +S(6) 7.451e-01 + SO4-2 7.451e-01 1.731e-03 -0.128 -2.762 -2.634 20.14 + HSO4- 5.833e-09 5.185e-09 -8.234 -8.285 -0.051 (0) ------------------------------Saturation indices------------------------------- @@ -3138,35 +3138,35 @@ Polyhalite 0.00 -13.74 -13.74 8.694e-04 1.030e-03 1.607e-04 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 4.887e-06 2.116e-07 -5.311 -6.674 -1.364 - H+ 1.671e-09 3.211e-08 -8.777 -7.493 1.284 - H2O 5.551e+01 6.763e-01 1.744 -0.170 0.000 -Br 4.297e-02 - Br- 4.297e-02 5.703e-02 -1.367 -1.244 0.123 -C(4) 1.158e-02 - MgCO3 9.097e-03 9.097e-03 -2.041 -2.041 0.000 - HCO3- 1.504e-03 1.043e-04 -2.823 -3.982 -1.159 - CO3-2 9.663e-04 1.487e-07 -3.015 -6.828 -3.813 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 - CO2 2.335e-06 1.077e-05 -5.632 -4.968 0.664 -Ca 2.525e-03 - Ca+2 2.519e-03 2.639e-02 -2.599 -1.578 1.020 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 6.031e+00 - Cl- 6.031e+00 4.525e+00 0.780 0.656 -0.125 -K 2.831e-01 - K+ 2.831e-01 3.262e-01 -0.548 -0.486 0.062 -Mg 2.640e+00 - Mg+2 2.629e+00 7.221e+01 0.420 1.859 1.439 - MgCO3 9.097e-03 9.097e-03 -2.041 -2.041 0.000 - MgOH+ 2.311e-03 2.361e-03 -2.636 -2.627 0.009 -Na 2.255e+00 - Na+ 2.255e+00 8.210e+00 0.353 0.914 0.561 -S(6) 7.525e-01 - SO4-2 7.525e-01 1.647e-03 -0.123 -2.783 -2.660 - HSO4- 5.427e-09 5.039e-09 -8.265 -8.298 -0.032 + OH- 4.887e-06 2.116e-07 -5.311 -6.674 -1.364 (0) + H+ 1.671e-09 3.211e-08 -8.777 -7.493 1.284 0.00 + H2O 5.551e+01 6.763e-01 1.744 -0.170 0.000 18.07 +Br 4.297e-02 + Br- 4.297e-02 5.703e-02 -1.367 -1.244 0.123 26.26 +C(4) 1.158e-02 + MgCO3 9.097e-03 9.097e-03 -2.041 -2.041 0.000 (0) + HCO3- 1.504e-03 1.043e-04 -2.823 -3.982 -1.159 25.84 + CO3-2 9.663e-04 1.487e-07 -3.015 -6.828 -3.813 2.44 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) + CO2 2.335e-06 1.077e-05 -5.632 -4.968 0.664 (0) +Ca 2.525e-03 + Ca+2 2.519e-03 2.639e-02 -2.599 -1.578 1.020 -11.61 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 6.031e+00 + Cl- 6.031e+00 4.525e+00 0.780 0.656 -0.125 19.37 +K 2.831e-01 + K+ 2.831e-01 3.262e-01 -0.548 -0.486 0.062 10.58 +Mg 2.640e+00 + Mg+2 2.629e+00 7.221e+01 0.420 1.859 1.439 -14.93 + MgCO3 9.097e-03 9.097e-03 -2.041 -2.041 0.000 (0) + MgOH+ 2.311e-03 2.361e-03 -2.636 -2.627 0.009 (0) +Na 2.255e+00 + Na+ 2.255e+00 8.210e+00 0.353 0.914 0.561 0.34 +S(6) 7.525e-01 + SO4-2 7.525e-01 1.647e-03 -0.123 -2.783 -2.660 20.20 + HSO4- 5.427e-09 5.039e-09 -8.265 -8.298 -0.032 (0) ------------------------------Saturation indices------------------------------- @@ -3289,35 +3289,35 @@ Polyhalite -0.00 -13.74 -13.74 1.030e-03 1.188e-03 1.575e-04 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 5.276e-06 2.048e-07 -5.278 -6.689 -1.411 - H+ 1.588e-09 3.287e-08 -8.799 -7.483 1.316 - H2O 5.551e+01 6.701e-01 1.744 -0.174 0.000 -Br 4.539e-02 - Br- 4.539e-02 6.144e-02 -1.343 -1.212 0.131 -C(4) 1.308e-02 - MgCO3 1.038e-02 1.038e-02 -1.984 -1.984 0.000 - HCO3- 1.573e-03 1.009e-04 -2.803 -3.996 -1.193 - CO3-2 1.125e-03 1.406e-07 -2.949 -6.852 -3.903 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 - CO2 2.303e-06 1.077e-05 -5.638 -4.968 0.670 -Ca 2.363e-03 - Ca+2 2.357e-03 2.792e-02 -2.628 -1.554 1.074 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 6.076e+00 - Cl- 6.076e+00 4.600e+00 0.784 0.663 -0.121 -K 2.666e-01 - K+ 2.666e-01 3.170e-01 -0.574 -0.499 0.075 -Mg 2.772e+00 - Mg+2 2.759e+00 8.713e+01 0.441 1.940 1.499 - MgCO3 1.038e-02 1.038e-02 -1.984 -1.984 0.000 - MgOH+ 2.557e-03 2.757e-03 -2.592 -2.559 0.033 -Na 2.087e+00 - Na+ 2.087e+00 8.077e+00 0.320 0.907 0.588 -S(6) 7.612e-01 - SO4-2 7.612e-01 1.557e-03 -0.118 -2.808 -2.689 - HSO4- 5.010e-09 4.877e-09 -8.300 -8.312 -0.012 + OH- 5.276e-06 2.048e-07 -5.278 -6.689 -1.411 (0) + H+ 1.588e-09 3.287e-08 -8.799 -7.483 1.316 0.00 + H2O 5.551e+01 6.701e-01 1.744 -0.174 0.000 18.07 +Br 4.539e-02 + Br- 4.539e-02 6.144e-02 -1.343 -1.212 0.131 26.28 +C(4) 1.308e-02 + MgCO3 1.038e-02 1.038e-02 -1.984 -1.984 0.000 (0) + HCO3- 1.573e-03 1.009e-04 -2.803 -3.996 -1.193 25.86 + CO3-2 1.125e-03 1.406e-07 -2.949 -6.852 -3.903 2.49 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) + CO2 2.303e-06 1.077e-05 -5.638 -4.968 0.670 (0) +Ca 2.363e-03 + Ca+2 2.357e-03 2.792e-02 -2.628 -1.554 1.074 -11.56 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 6.076e+00 + Cl- 6.076e+00 4.600e+00 0.784 0.663 -0.121 19.39 +K 2.666e-01 + K+ 2.666e-01 3.170e-01 -0.574 -0.499 0.075 10.60 +Mg 2.772e+00 + Mg+2 2.759e+00 8.713e+01 0.441 1.940 1.499 -14.88 + MgCO3 1.038e-02 1.038e-02 -1.984 -1.984 0.000 (0) + MgOH+ 2.557e-03 2.757e-03 -2.592 -2.559 0.033 (0) +Na 2.087e+00 + Na+ 2.087e+00 8.077e+00 0.320 0.907 0.588 0.36 +S(6) 7.612e-01 + SO4-2 7.612e-01 1.557e-03 -0.118 -2.808 -2.689 20.25 + HSO4- 5.010e-09 4.877e-09 -8.300 -8.312 -0.012 (0) ------------------------------Saturation indices------------------------------- @@ -3440,35 +3440,35 @@ Polyhalite 0.00 -13.74 -13.74 1.188e-03 1.341e-03 1.538e-04 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 5.741e-06 1.972e-07 -5.241 -6.705 -1.464 - H+ 1.493e-09 3.375e-08 -8.826 -7.472 1.354 - H2O 5.551e+01 6.626e-01 1.744 -0.179 0.000 -Br 4.810e-02 - Br- 4.810e-02 6.656e-02 -1.318 -1.177 0.141 -C(4) 1.508e-02 - MgCO3 1.208e-02 1.208e-02 -1.918 -1.918 0.000 - HCO3- 1.661e-03 9.716e-05 -2.780 -4.013 -1.233 - CO3-2 1.331e-03 1.318e-07 -2.876 -6.880 -4.004 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 - CO2 2.264e-06 1.077e-05 -5.645 -4.968 0.677 -Ca 2.182e-03 - Ca+2 2.177e-03 2.978e-02 -2.662 -1.526 1.136 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 6.134e+00 - Cl- 6.134e+00 4.692e+00 0.788 0.671 -0.116 -K 2.489e-01 - K+ 2.489e-01 3.069e-01 -0.604 -0.513 0.091 -Mg 2.921e+00 - Mg+2 2.906e+00 1.081e+02 0.463 2.034 1.571 - MgCO3 1.208e-02 1.208e-02 -1.918 -1.918 0.000 - MgOH+ 2.870e-03 3.295e-03 -2.542 -2.482 0.060 -Na 1.907e+00 - Na+ 1.907e+00 7.918e+00 0.280 0.899 0.618 -S(6) 7.714e-01 - SO4-2 7.714e-01 1.460e-03 -0.113 -2.836 -2.723 - HSO4- 4.580e-09 4.696e-09 -8.339 -8.328 0.011 + OH- 5.741e-06 1.972e-07 -5.241 -6.705 -1.464 (0) + H+ 1.493e-09 3.375e-08 -8.826 -7.472 1.354 0.00 + H2O 5.551e+01 6.626e-01 1.744 -0.179 0.000 18.07 +Br 4.810e-02 + Br- 4.810e-02 6.656e-02 -1.318 -1.177 0.141 26.30 +C(4) 1.508e-02 + MgCO3 1.208e-02 1.208e-02 -1.918 -1.918 0.000 (0) + HCO3- 1.661e-03 9.716e-05 -2.780 -4.013 -1.233 25.88 + CO3-2 1.331e-03 1.318e-07 -2.876 -6.880 -4.004 2.56 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) + CO2 2.264e-06 1.077e-05 -5.645 -4.968 0.677 (0) +Ca 2.182e-03 + Ca+2 2.177e-03 2.978e-02 -2.662 -1.526 1.136 -11.49 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 6.134e+00 + Cl- 6.134e+00 4.692e+00 0.788 0.671 -0.116 19.41 +K 2.489e-01 + K+ 2.489e-01 3.069e-01 -0.604 -0.513 0.091 10.62 +Mg 2.921e+00 + Mg+2 2.906e+00 1.081e+02 0.463 2.034 1.571 -14.81 + MgCO3 1.208e-02 1.208e-02 -1.918 -1.918 0.000 (0) + MgOH+ 2.870e-03 3.295e-03 -2.542 -2.482 0.060 (0) +Na 1.907e+00 + Na+ 1.907e+00 7.918e+00 0.280 0.899 0.618 0.38 +S(6) 7.714e-01 + SO4-2 7.714e-01 1.460e-03 -0.113 -2.836 -2.723 20.32 + HSO4- 4.580e-09 4.696e-09 -8.339 -8.328 0.011 (0) ------------------------------Saturation indices------------------------------- @@ -3591,35 +3591,35 @@ Polyhalite 0.00 -13.74 -13.74 1.341e-03 1.491e-03 1.495e-04 MacInnes MacInnes MacInnes Log Log Log - Species Molality Activity Molality Activity Gamma + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 6.304e-06 1.887e-07 -5.200 -6.724 -1.524 - H+ 1.385e-09 3.479e-08 -8.858 -7.459 1.400 - H2O 5.551e+01 6.534e-01 1.744 -0.185 0.000 -Br 5.115e-02 - Br- 5.115e-02 7.258e-02 -1.291 -1.139 0.152 -C(4) 1.780e-02 - MgCO3 1.441e-02 1.441e-02 -1.841 -1.841 0.000 - HCO3- 1.775e-03 9.296e-05 -2.751 -4.032 -1.281 - CO3-2 1.605e-03 1.223e-07 -2.795 -6.912 -4.118 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 - CO2 2.216e-06 1.077e-05 -5.654 -4.968 0.687 -Ca 1.982e-03 - Ca+2 1.976e-03 3.208e-02 -2.704 -1.494 1.210 - CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 -Cl 6.209e+00 - Cl- 6.209e+00 4.807e+00 0.793 0.682 -0.111 -K 2.299e-01 - K+ 2.299e-01 2.957e-01 -0.638 -0.529 0.109 -Mg 3.089e+00 - Mg+2 3.071e+00 1.390e+02 0.487 2.143 1.656 - MgCO3 1.441e-02 1.441e-02 -1.841 -1.841 0.000 - MgOH+ 3.282e-03 4.053e-03 -2.484 -2.392 0.092 -Na 1.713e+00 - Na+ 1.713e+00 7.729e+00 0.234 0.888 0.654 -S(6) 7.834e-01 - SO4-2 7.834e-01 1.355e-03 -0.106 -2.868 -2.762 - HSO4- 4.140e-09 4.493e-09 -8.383 -8.347 0.035 + OH- 6.304e-06 1.887e-07 -5.200 -6.724 -1.524 (0) + H+ 1.385e-09 3.479e-08 -8.858 -7.459 1.400 0.00 + H2O 5.551e+01 6.534e-01 1.744 -0.185 0.000 18.07 +Br 5.115e-02 + Br- 5.115e-02 7.258e-02 -1.291 -1.139 0.152 26.32 +C(4) 1.780e-02 + MgCO3 1.441e-02 1.441e-02 -1.841 -1.841 0.000 (0) + HCO3- 1.775e-03 9.296e-05 -2.751 -4.032 -1.281 25.90 + CO3-2 1.605e-03 1.223e-07 -2.795 -6.912 -4.118 2.64 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) + CO2 2.216e-06 1.077e-05 -5.654 -4.968 0.687 (0) +Ca 1.982e-03 + Ca+2 1.976e-03 3.208e-02 -2.704 -1.494 1.210 -11.41 + CaCO3 5.560e-06 5.560e-06 -5.255 -5.255 0.000 (0) +Cl 6.209e+00 + Cl- 6.209e+00 4.807e+00 0.793 0.682 -0.111 19.43 +K 2.299e-01 + K+ 2.299e-01 2.957e-01 -0.638 -0.529 0.109 10.64 +Mg 3.089e+00 + Mg+2 3.071e+00 1.390e+02 0.487 2.143 1.656 -14.73 + MgCO3 1.441e-02 1.441e-02 -1.841 -1.841 0.000 (0) + MgOH+ 3.282e-03 4.053e-03 -2.484 -2.392 0.092 (0) +Na 1.713e+00 + Na+ 1.713e+00 7.729e+00 0.234 0.888 0.654 0.40 +S(6) 7.834e-01 + SO4-2 7.834e-01 1.355e-03 -0.106 -2.868 -2.762 20.40 + HSO4- 4.140e-09 4.493e-09 -8.383 -8.347 0.035 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex18.out b/ex18.out index 2ceab2bb..a7c24e43 100644 --- a/ex18.out +++ b/ex18.out @@ -133,72 +133,72 @@ Initial solution 1. Recharge number 3 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.120e-07 1.029e-07 -6.951 -6.988 -0.037 - H+ 3.038e-08 2.818e-08 -7.517 -7.550 -0.033 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -C(4) 4.300e-03 - HCO3- 3.929e-03 3.623e-03 -2.406 -2.441 -0.035 - CO2 2.970e-04 2.974e-04 -3.527 -3.527 0.001 - MgHCO3+ 3.098e-05 2.850e-05 -4.509 -4.545 -0.036 - CaHCO3+ 3.027e-05 2.792e-05 -4.519 -4.554 -0.035 - CO3-2 5.765e-06 4.168e-06 -5.239 -5.380 -0.141 - CaCO3 4.727e-06 4.734e-06 -5.325 -5.325 0.001 - MgCO3 2.208e-06 2.211e-06 -5.656 -5.655 0.001 - FeHCO3+ 2.086e-07 1.919e-07 -6.681 -6.717 -0.036 - FeCO3 5.289e-08 5.297e-08 -7.277 -7.276 0.001 - NaHCO3 3.737e-08 3.742e-08 -7.428 -7.427 0.001 - NaCO3- 6.948e-10 6.391e-10 -9.158 -9.194 -0.036 -Ca 1.200e-03 - Ca+2 1.151e-03 8.317e-04 -2.939 -3.080 -0.141 - CaHCO3+ 3.027e-05 2.792e-05 -4.519 -4.554 -0.035 - CaSO4 1.393e-05 1.395e-05 -4.856 -4.855 0.001 - CaCO3 4.727e-06 4.734e-06 -5.325 -5.325 0.001 - CaOH+ 5.323e-09 4.897e-09 -8.274 -8.310 -0.036 - CaHSO4+ 2.136e-12 1.965e-12 -11.670 -11.707 -0.036 -Cl 2.000e-05 - Cl- 2.000e-05 1.838e-05 -4.699 -4.736 -0.037 - FeCl+ 1.461e-11 1.344e-11 -10.835 -10.872 -0.036 -Fe(2) 1.000e-06 - Fe+2 7.296e-07 5.298e-07 -6.137 -6.276 -0.139 - FeHCO3+ 2.086e-07 1.919e-07 -6.681 -6.717 -0.036 - FeCO3 5.289e-08 5.297e-08 -7.277 -7.276 0.001 - FeSO4 6.861e-09 6.871e-09 -8.164 -8.163 0.001 - FeOH+ 1.969e-09 1.811e-09 -8.706 -8.742 -0.036 - FeCl+ 1.461e-11 1.344e-11 -10.835 -10.872 -0.036 - FeHSO4+ 1.361e-15 1.252e-15 -14.866 -14.903 -0.036 -H(0) 1.316e-18 - H2 6.579e-19 6.588e-19 -18.182 -18.181 0.001 -K 2.000e-05 - K+ 1.999e-05 1.837e-05 -4.699 -4.736 -0.037 - KSO4- 1.037e-08 9.538e-09 -7.984 -8.021 -0.036 - KOH 2.256e-12 2.260e-12 -11.647 -11.646 0.001 -Mg 1.010e-03 - Mg+2 9.662e-04 7.011e-04 -3.015 -3.154 -0.139 - MgHCO3+ 3.098e-05 2.850e-05 -4.509 -4.545 -0.036 - MgSO4 1.063e-05 1.064e-05 -4.974 -4.973 0.001 - MgCO3 2.208e-06 2.211e-06 -5.656 -5.655 0.001 - MgOH+ 2.335e-08 2.148e-08 -7.632 -7.668 -0.036 -Na 2.000e-05 - Na+ 1.995e-05 1.837e-05 -4.700 -4.736 -0.036 - NaHCO3 3.737e-08 3.742e-08 -7.428 -7.427 0.001 - NaSO4- 8.826e-09 8.119e-09 -8.054 -8.090 -0.036 - NaCO3- 6.948e-10 6.391e-10 -9.158 -9.194 -0.036 - NaOH 4.299e-12 4.306e-12 -11.367 -11.366 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -61.151 -61.151 0.001 -S(6) 1.600e-04 - SO4-2 1.354e-04 9.754e-05 -3.868 -4.011 -0.142 - CaSO4 1.393e-05 1.395e-05 -4.856 -4.855 0.001 - MgSO4 1.063e-05 1.064e-05 -4.974 -4.973 0.001 - KSO4- 1.037e-08 9.538e-09 -7.984 -8.021 -0.036 - NaSO4- 8.826e-09 8.119e-09 -8.054 -8.090 -0.036 - FeSO4 6.861e-09 6.871e-09 -8.164 -8.163 0.001 - HSO4- 2.136e-10 1.965e-10 -9.670 -9.707 -0.036 - CaHSO4+ 2.136e-12 1.965e-12 -11.670 -11.707 -0.036 - FeHSO4+ 1.361e-15 1.252e-15 -14.866 -14.903 -0.036 + OH- 1.120e-07 1.029e-07 -6.951 -6.988 -0.037 (0) + H+ 3.038e-08 2.818e-08 -7.517 -7.550 -0.033 0.00 + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.02 +C(4) 4.300e-03 + HCO3- 3.929e-03 3.623e-03 -2.406 -2.441 -0.035 22.68 + CO2 2.970e-04 2.974e-04 -3.527 -3.527 0.001 (0) + MgHCO3+ 3.098e-05 2.850e-05 -4.509 -4.545 -0.036 (0) + CaHCO3+ 3.027e-05 2.792e-05 -4.519 -4.554 -0.035 (0) + CO3-2 5.765e-06 4.168e-06 -5.239 -5.380 -0.141 -6.17 + CaCO3 4.727e-06 4.734e-06 -5.325 -5.325 0.001 (0) + MgCO3 2.208e-06 2.211e-06 -5.656 -5.655 0.001 (0) + FeHCO3+ 2.086e-07 1.919e-07 -6.681 -6.717 -0.036 (0) + FeCO3 5.289e-08 5.297e-08 -7.277 -7.276 0.001 (0) + NaHCO3 3.737e-08 3.742e-08 -7.428 -7.427 0.001 (0) + NaCO3- 6.948e-10 6.391e-10 -9.158 -9.194 -0.036 (0) +Ca 1.200e-03 + Ca+2 1.151e-03 8.317e-04 -2.939 -3.080 -0.141 -18.77 + CaHCO3+ 3.027e-05 2.792e-05 -4.519 -4.554 -0.035 (0) + CaSO4 1.393e-05 1.395e-05 -4.856 -4.855 0.001 (0) + CaCO3 4.727e-06 4.734e-06 -5.325 -5.325 0.001 (0) + CaOH+ 5.323e-09 4.897e-09 -8.274 -8.310 -0.036 (0) + CaHSO4+ 2.136e-12 1.965e-12 -11.670 -11.707 -0.036 (0) +Cl 2.000e-05 + Cl- 2.000e-05 1.838e-05 -4.699 -4.736 -0.037 17.13 + FeCl+ 1.461e-11 1.344e-11 -10.835 -10.872 -0.036 (0) +Fe(2) 1.000e-06 + Fe+2 7.296e-07 5.298e-07 -6.137 -6.276 -0.139 (0) + FeHCO3+ 2.086e-07 1.919e-07 -6.681 -6.717 -0.036 (0) + FeCO3 5.289e-08 5.297e-08 -7.277 -7.276 0.001 (0) + FeSO4 6.861e-09 6.871e-09 -8.164 -8.163 0.001 (0) + FeOH+ 1.969e-09 1.811e-09 -8.706 -8.742 -0.036 (0) + FeCl+ 1.461e-11 1.344e-11 -10.835 -10.872 -0.036 (0) + FeHSO4+ 1.361e-15 1.252e-15 -14.866 -14.903 -0.036 (0) +H(0) 1.316e-18 + H2 6.579e-19 6.588e-19 -18.182 -18.181 0.001 (0) +K 2.000e-05 + K+ 1.999e-05 1.837e-05 -4.699 -4.736 -0.037 8.07 + KSO4- 1.037e-08 9.538e-09 -7.984 -8.021 -0.036 (0) + KOH 2.256e-12 2.260e-12 -11.647 -11.646 0.001 (0) +Mg 1.010e-03 + Mg+2 9.662e-04 7.011e-04 -3.015 -3.154 -0.139 -21.62 + MgHCO3+ 3.098e-05 2.850e-05 -4.509 -4.545 -0.036 (0) + MgSO4 1.063e-05 1.064e-05 -4.974 -4.973 0.001 (0) + MgCO3 2.208e-06 2.211e-06 -5.656 -5.655 0.001 (0) + MgOH+ 2.335e-08 2.148e-08 -7.632 -7.668 -0.036 (0) +Na 2.000e-05 + Na+ 1.995e-05 1.837e-05 -4.700 -4.736 -0.036 -2.45 + NaHCO3 3.737e-08 3.742e-08 -7.428 -7.427 0.001 (0) + NaSO4- 8.826e-09 8.119e-09 -8.054 -8.090 -0.036 (0) + NaCO3- 6.948e-10 6.391e-10 -9.158 -9.194 -0.036 (0) + NaOH 4.299e-12 4.306e-12 -11.367 -11.366 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -61.151 -61.151 0.001 (0) +S(6) 1.600e-04 + SO4-2 1.354e-04 9.754e-05 -3.868 -4.011 -0.142 11.70 + CaSO4 1.393e-05 1.395e-05 -4.856 -4.855 0.001 (0) + MgSO4 1.063e-05 1.064e-05 -4.974 -4.973 0.001 (0) + KSO4- 1.037e-08 9.538e-09 -7.984 -8.021 -0.036 (0) + NaSO4- 8.826e-09 8.119e-09 -8.054 -8.090 -0.036 (0) + FeSO4 6.861e-09 6.871e-09 -8.164 -8.163 0.001 (0) + HSO4- 2.136e-10 1.965e-10 -9.670 -9.707 -0.036 (0) + CaHSO4+ 2.136e-12 1.965e-12 -11.670 -11.707 -0.036 (0) + FeHSO4+ 1.361e-15 1.252e-15 -14.866 -14.903 -0.036 (0) ------------------------------Saturation indices------------------------------- @@ -262,80 +262,80 @@ Initial solution 2. Mysse ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 5.726e-07 4.419e-07 -6.242 -6.355 -0.112 - H+ 2.963e-07 2.455e-07 -6.528 -6.610 -0.082 - H2O 5.551e+01 9.985e-01 1.744 -0.001 0.000 -C(4) 6.870e-03 - HCO3- 4.711e-03 3.746e-03 -2.327 -2.426 -0.100 - CO2 1.784e-03 1.814e-03 -2.749 -2.741 0.007 - CaHCO3+ 2.347e-04 1.867e-04 -3.629 -3.729 -0.100 - MgHCO3+ 6.578e-05 5.169e-05 -4.182 -4.287 -0.105 - NaHCO3 5.046e-05 5.131e-05 -4.297 -4.290 0.007 - CaCO3 1.560e-05 1.586e-05 -4.807 -4.800 0.007 - NaCO3- 3.512e-06 2.760e-06 -5.454 -5.559 -0.105 - CO3-2 2.780e-06 1.112e-06 -5.556 -5.954 -0.398 - MgCO3 1.642e-06 1.670e-06 -5.784 -5.777 0.007 - FeHCO3+ 1.177e-08 9.248e-09 -7.929 -8.034 -0.105 - FeCO3 6.474e-10 6.583e-10 -9.189 -9.182 0.007 -Ca 1.128e-02 - Ca+2 7.217e-03 2.899e-03 -2.142 -2.538 -0.396 - CaSO4 3.813e-03 3.877e-03 -2.419 -2.411 0.007 - CaHCO3+ 2.347e-04 1.867e-04 -3.629 -3.729 -0.100 - CaCO3 1.560e-05 1.586e-05 -4.807 -4.800 0.007 - CaHSO4+ 1.322e-08 1.039e-08 -7.879 -7.983 -0.105 - CaOH+ 2.491e-09 1.957e-09 -8.604 -8.708 -0.105 -Cl 1.785e-02 - Cl- 1.785e-02 1.381e-02 -1.748 -1.860 -0.111 - FeCl+ 5.988e-10 4.706e-10 -9.223 -9.327 -0.105 -Fe(2) 4.000e-07 - Fe(HS)2 2.830e-07 2.878e-07 -6.548 -6.541 0.007 - Fe+2 5.978e-08 2.468e-08 -7.223 -7.608 -0.384 - FeSO4 3.911e-08 3.977e-08 -7.408 -7.400 0.007 - FeHCO3+ 1.177e-08 9.248e-09 -7.929 -8.034 -0.105 - Fe(HS)3- 4.561e-09 3.585e-09 -8.341 -8.446 -0.105 - FeCO3 6.474e-10 6.583e-10 -9.189 -9.182 0.007 - FeCl+ 5.988e-10 4.706e-10 -9.223 -9.327 -0.105 - FeOH+ 5.014e-10 3.940e-10 -9.300 -9.404 -0.105 - FeHSO4+ 1.125e-13 8.843e-14 -12.949 -13.053 -0.105 -H(0) 1.190e-09 - H2 5.948e-10 6.048e-10 -9.226 -9.218 0.007 -K 2.540e-03 - K+ 2.394e-03 1.852e-03 -2.621 -2.732 -0.111 - KSO4- 1.459e-04 1.146e-04 -3.836 -3.941 -0.105 - KOH 2.569e-11 2.613e-11 -10.590 -10.583 0.007 -Mg 4.540e-03 - MgSO4 2.360e-03 2.399e-03 -2.627 -2.620 0.007 - Mg+2 2.113e-03 8.783e-04 -2.675 -3.056 -0.381 - MgHCO3+ 6.578e-05 5.169e-05 -4.182 -4.287 -0.105 - MgCO3 1.642e-06 1.670e-06 -5.784 -5.777 0.007 - MgOH+ 3.463e-07 2.721e-07 -6.461 -6.565 -0.105 -Na 3.189e-02 - Na+ 3.090e-02 2.435e-02 -1.510 -1.613 -0.103 - NaSO4- 9.408e-04 7.393e-04 -3.027 -3.131 -0.105 - NaHCO3 5.046e-05 5.131e-05 -4.297 -4.290 0.007 - NaCO3- 3.512e-06 2.760e-06 -5.454 -5.559 -0.105 - NaOH 6.437e-10 6.545e-10 -9.191 -9.184 0.007 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -63.075 -63.067 0.007 -S(-2) 2.600e-04 - HS- 1.482e-04 1.144e-04 -3.829 -3.942 -0.112 - H2S 1.112e-04 1.131e-04 -3.954 -3.947 0.007 - Fe(HS)2 2.830e-07 2.878e-07 -6.548 -6.541 0.007 - Fe(HS)3- 4.561e-09 3.585e-09 -8.341 -8.446 -0.105 - S-2 1.449e-09 5.662e-10 -8.839 -9.247 -0.408 -S(6) 1.986e-02 - SO4-2 1.260e-02 4.892e-03 -1.900 -2.311 -0.411 - CaSO4 3.813e-03 3.877e-03 -2.419 -2.411 0.007 - MgSO4 2.360e-03 2.399e-03 -2.627 -2.620 0.007 - NaSO4- 9.408e-04 7.393e-04 -3.027 -3.131 -0.105 - KSO4- 1.459e-04 1.146e-04 -3.836 -3.941 -0.105 - HSO4- 3.792e-07 2.980e-07 -6.421 -6.526 -0.105 - FeSO4 3.911e-08 3.977e-08 -7.408 -7.400 0.007 - CaHSO4+ 1.322e-08 1.039e-08 -7.879 -7.983 -0.105 - FeHSO4+ 1.125e-13 8.843e-14 -12.949 -13.053 -0.105 + OH- 5.726e-07 4.419e-07 -6.242 -6.355 -0.112 (0) + H+ 2.963e-07 2.455e-07 -6.528 -6.610 -0.082 0.00 + H2O 5.551e+01 9.985e-01 1.744 -0.001 0.000 18.35 +C(4) 6.870e-03 + HCO3- 4.711e-03 3.746e-03 -2.327 -2.426 -0.100 23.86 + CO2 1.784e-03 1.814e-03 -2.749 -2.741 0.007 (0) + CaHCO3+ 2.347e-04 1.867e-04 -3.629 -3.729 -0.100 (0) + MgHCO3+ 6.578e-05 5.169e-05 -4.182 -4.287 -0.105 (0) + NaHCO3 5.046e-05 5.131e-05 -4.297 -4.290 0.007 (0) + CaCO3 1.560e-05 1.586e-05 -4.807 -4.800 0.007 (0) + NaCO3- 3.512e-06 2.760e-06 -5.454 -5.559 -0.105 (0) + CO3-2 2.780e-06 1.112e-06 -5.556 -5.954 -0.398 -5.76 + MgCO3 1.642e-06 1.670e-06 -5.784 -5.777 0.007 (0) + FeHCO3+ 1.177e-08 9.248e-09 -7.929 -8.034 -0.105 (0) + FeCO3 6.474e-10 6.583e-10 -9.189 -9.182 0.007 (0) +Ca 1.128e-02 + Ca+2 7.217e-03 2.899e-03 -2.142 -2.538 -0.396 -17.80 + CaSO4 3.813e-03 3.877e-03 -2.419 -2.411 0.007 (0) + CaHCO3+ 2.347e-04 1.867e-04 -3.629 -3.729 -0.100 (0) + CaCO3 1.560e-05 1.586e-05 -4.807 -4.800 0.007 (0) + CaHSO4+ 1.322e-08 1.039e-08 -7.879 -7.983 -0.105 (0) + CaOH+ 2.491e-09 1.957e-09 -8.604 -8.708 -0.105 (0) +Cl 1.785e-02 + Cl- 1.785e-02 1.381e-02 -1.748 -1.860 -0.111 17.05 + FeCl+ 5.988e-10 4.706e-10 -9.223 -9.327 -0.105 (0) +Fe(2) 4.000e-07 + Fe(HS)2 2.830e-07 2.878e-07 -6.548 -6.541 0.007 (0) + Fe+2 5.978e-08 2.468e-08 -7.223 -7.608 -0.384 (0) + FeSO4 3.911e-08 3.977e-08 -7.408 -7.400 0.007 (0) + FeHCO3+ 1.177e-08 9.248e-09 -7.929 -8.034 -0.105 (0) + Fe(HS)3- 4.561e-09 3.585e-09 -8.341 -8.446 -0.105 (0) + FeCO3 6.474e-10 6.583e-10 -9.189 -9.182 0.007 (0) + FeCl+ 5.988e-10 4.706e-10 -9.223 -9.327 -0.105 (0) + FeOH+ 5.014e-10 3.940e-10 -9.300 -9.404 -0.105 (0) + FeHSO4+ 1.125e-13 8.843e-14 -12.949 -13.053 -0.105 (0) +H(0) 1.190e-09 + H2 5.948e-10 6.048e-10 -9.226 -9.218 0.007 (0) +K 2.540e-03 + K+ 2.394e-03 1.852e-03 -2.621 -2.732 -0.111 10.01 + KSO4- 1.459e-04 1.146e-04 -3.836 -3.941 -0.105 (0) + KOH 2.569e-11 2.613e-11 -10.590 -10.583 0.007 (0) +Mg 4.540e-03 + MgSO4 2.360e-03 2.399e-03 -2.627 -2.620 0.007 (0) + Mg+2 2.113e-03 8.783e-04 -2.675 -3.056 -0.381 -22.99 + MgHCO3+ 6.578e-05 5.169e-05 -4.182 -4.287 -0.105 (0) + MgCO3 1.642e-06 1.670e-06 -5.784 -5.777 0.007 (0) + MgOH+ 3.463e-07 2.721e-07 -6.461 -6.565 -0.105 (0) +Na 3.189e-02 + Na+ 3.090e-02 2.435e-02 -1.510 -1.613 -0.103 0.42 + NaSO4- 9.408e-04 7.393e-04 -3.027 -3.131 -0.105 (0) + NaHCO3 5.046e-05 5.131e-05 -4.297 -4.290 0.007 (0) + NaCO3- 3.512e-06 2.760e-06 -5.454 -5.559 -0.105 (0) + NaOH 6.437e-10 6.545e-10 -9.191 -9.184 0.007 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -63.075 -63.067 0.007 (0) +S(-2) 2.600e-04 + HS- 1.482e-04 1.144e-04 -3.829 -3.942 -0.112 (0) + H2S 1.112e-04 1.131e-04 -3.954 -3.947 0.007 (0) + Fe(HS)2 2.830e-07 2.878e-07 -6.548 -6.541 0.007 (0) + Fe(HS)3- 4.561e-09 3.585e-09 -8.341 -8.446 -0.105 (0) + S-2 1.449e-09 5.662e-10 -8.839 -9.247 -0.408 (0) +S(6) 1.986e-02 + SO4-2 1.260e-02 4.892e-03 -1.900 -2.311 -0.411 12.25 + CaSO4 3.813e-03 3.877e-03 -2.419 -2.411 0.007 (0) + MgSO4 2.360e-03 2.399e-03 -2.627 -2.620 0.007 (0) + NaSO4- 9.408e-04 7.393e-04 -3.027 -3.131 -0.105 (0) + KSO4- 1.459e-04 1.146e-04 -3.836 -3.941 -0.105 (0) + HSO4- 3.792e-07 2.980e-07 -6.421 -6.526 -0.105 (0) + FeSO4 3.911e-08 3.977e-08 -7.408 -7.400 0.007 (0) + CaHSO4+ 1.322e-08 1.039e-08 -7.879 -7.983 -0.105 (0) + FeHSO4+ 1.125e-13 8.843e-14 -12.949 -13.053 -0.105 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex2.out b/ex2.out index b198f45d..e5c1bd1e 100644 --- a/ex2.out +++ b/ex2.out @@ -85,16 +85,16 @@ Initial solution 1. Pure water ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.002e-07 1.001e-07 -6.999 -6.999 -0.000 - H+ 1.001e-07 1.000e-07 -7.000 -7.000 -0.000 - H2O 5.551e+01 1.000e+00 1.744 0.000 0.000 -H(0) 1.416e-25 - H2 7.079e-26 7.079e-26 -25.150 -25.150 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 + OH- 1.002e-07 1.001e-07 -6.999 -6.999 -0.000 (0) + H+ 1.001e-07 1.000e-07 -7.000 -7.000 -0.000 0.00 + H2O 5.551e+01 1.000e+00 1.744 0.000 0.000 18.07 +H(0) 1.416e-25 + H2 7.079e-26 7.079e-26 -25.150 -25.150 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -151,30 +151,30 @@ Gypsum -0.00 -4.58 -4.58 1.000e+00 1.985e+00 9.849e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.417e-07 1.167e-07 -6.849 -6.933 -0.084 - H+ 9.957e-08 8.575e-08 -7.002 -7.067 -0.065 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.564e-02 - Ca+2 1.045e-02 5.176e-03 -1.981 -2.286 -0.305 - CaSO4 5.191e-03 5.242e-03 -2.285 -2.281 0.004 - CaOH+ 1.204e-08 1.001e-08 -7.919 -7.999 -0.080 - CaHSO4+ 3.166e-09 2.633e-09 -8.499 -8.580 -0.080 -H(0) 4.382e-39 - H2 2.191e-39 2.212e-39 -38.659 -38.655 0.004 -O(0) 1.686e-15 - O2 8.431e-16 8.512e-16 -15.074 -15.070 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -117.647 -117.731 -0.084 - H2S 0.000e+00 0.000e+00 -117.861 -117.856 0.004 - S-2 0.000e+00 0.000e+00 -123.271 -123.583 -0.312 -S(6) 1.564e-02 - SO4-2 1.045e-02 5.075e-03 -1.981 -2.295 -0.313 - CaSO4 5.191e-03 5.242e-03 -2.285 -2.281 0.004 - HSO4- 5.088e-08 4.231e-08 -7.293 -7.374 -0.080 - CaHSO4+ 3.166e-09 2.633e-09 -8.499 -8.580 -0.080 + OH- 1.417e-07 1.167e-07 -6.849 -6.933 -0.084 (0) + H+ 9.957e-08 8.575e-08 -7.002 -7.067 -0.065 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.07 +Ca 1.564e-02 + Ca+2 1.045e-02 5.176e-03 -1.981 -2.286 -0.305 -17.83 + CaSO4 5.191e-03 5.242e-03 -2.285 -2.281 0.004 (0) + CaOH+ 1.204e-08 1.001e-08 -7.919 -7.999 -0.080 (0) + CaHSO4+ 3.166e-09 2.633e-09 -8.499 -8.580 -0.080 (0) +H(0) 4.382e-39 + H2 2.191e-39 2.212e-39 -38.659 -38.655 0.004 (0) +O(0) 1.686e-15 + O2 8.431e-16 8.512e-16 -15.074 -15.070 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -117.647 -117.731 -0.084 (0) + H2S 0.000e+00 0.000e+00 -117.861 -117.856 0.004 (0) + S-2 0.000e+00 0.000e+00 -123.271 -123.583 -0.312 (0) +S(6) 1.564e-02 + SO4-2 1.045e-02 5.075e-03 -1.981 -2.295 -0.313 13.98 + CaSO4 5.191e-03 5.242e-03 -2.285 -2.281 0.004 (0) + HSO4- 5.088e-08 4.231e-08 -7.293 -7.374 -0.080 (0) + CaHSO4+ 3.166e-09 2.633e-09 -8.499 -8.580 -0.080 (0) ------------------------------Saturation indices------------------------------- @@ -231,30 +231,30 @@ Gypsum -0.00 -4.58 -4.58 1.000e+00 1.985e+00 9.849e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.482e-07 1.220e-07 -6.829 -6.914 -0.084 - H+ 1.027e-07 8.845e-08 -6.988 -7.053 -0.065 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.569e-02 - Ca+2 1.046e-02 5.174e-03 -1.981 -2.286 -0.306 - CaSO4 5.236e-03 5.287e-03 -2.281 -2.277 0.004 - CaOH+ 1.167e-08 9.704e-09 -7.933 -8.013 -0.080 - CaHSO4+ 3.337e-09 2.774e-09 -8.477 -8.557 -0.080 -H(0) 6.347e-39 - H2 3.173e-39 3.204e-39 -38.498 -38.494 0.004 -O(0) 1.685e-15 - O2 8.427e-16 8.508e-16 -15.074 -15.070 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -117.120 -117.205 -0.084 - H2S 0.000e+00 0.000e+00 -117.333 -117.329 0.004 - S-2 0.000e+00 0.000e+00 -122.727 -123.040 -0.312 -S(6) 1.569e-02 - SO4-2 1.046e-02 5.073e-03 -1.981 -2.295 -0.314 - CaSO4 5.236e-03 5.287e-03 -2.281 -2.277 0.004 - HSO4- 5.364e-08 4.459e-08 -7.270 -7.351 -0.080 - CaHSO4+ 3.337e-09 2.774e-09 -8.477 -8.557 -0.080 + OH- 1.482e-07 1.220e-07 -6.829 -6.914 -0.084 (0) + H+ 1.027e-07 8.845e-08 -6.988 -7.053 -0.065 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.07 +Ca 1.569e-02 + Ca+2 1.046e-02 5.174e-03 -1.981 -2.286 -0.306 -17.79 + CaSO4 5.236e-03 5.287e-03 -2.281 -2.277 0.004 (0) + CaOH+ 1.167e-08 9.704e-09 -7.933 -8.013 -0.080 (0) + CaHSO4+ 3.337e-09 2.774e-09 -8.477 -8.557 -0.080 (0) +H(0) 6.347e-39 + H2 3.173e-39 3.204e-39 -38.498 -38.494 0.004 (0) +O(0) 1.685e-15 + O2 8.427e-16 8.508e-16 -15.074 -15.070 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -117.120 -117.205 -0.084 (0) + H2S 0.000e+00 0.000e+00 -117.333 -117.329 0.004 (0) + S-2 0.000e+00 0.000e+00 -122.727 -123.040 -0.312 (0) +S(6) 1.569e-02 + SO4-2 1.046e-02 5.073e-03 -1.981 -2.295 -0.314 14.07 + CaSO4 5.236e-03 5.287e-03 -2.281 -2.277 0.004 (0) + HSO4- 5.364e-08 4.459e-08 -7.270 -7.351 -0.080 (0) + CaHSO4+ 3.337e-09 2.774e-09 -8.477 -8.557 -0.080 (0) ------------------------------Saturation indices------------------------------- @@ -311,30 +311,30 @@ Gypsum 0.00 -4.58 -4.58 1.000e+00 1.985e+00 9.848e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.548e-07 1.274e-07 -6.810 -6.895 -0.085 - H+ 1.060e-07 9.122e-08 -6.975 -7.040 -0.065 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.574e-02 - Ca+2 1.047e-02 5.172e-03 -1.980 -2.286 -0.306 - CaSO4 5.279e-03 5.330e-03 -2.277 -2.273 0.004 - CaOH+ 1.132e-08 9.405e-09 -7.946 -8.027 -0.080 - CaHSO4+ 3.516e-09 2.922e-09 -8.454 -8.534 -0.080 -H(0) 9.205e-39 - H2 4.602e-39 4.647e-39 -38.337 -38.333 0.004 -O(0) 1.672e-15 - O2 8.360e-16 8.441e-16 -15.078 -15.074 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -116.590 -116.675 -0.085 - H2S 0.000e+00 0.000e+00 -116.803 -116.799 0.004 - S-2 0.000e+00 0.000e+00 -122.181 -122.494 -0.313 -S(6) 1.574e-02 - SO4-2 1.047e-02 5.071e-03 -1.980 -2.295 -0.315 - CaSO4 5.279e-03 5.330e-03 -2.277 -2.273 0.004 - HSO4- 5.655e-08 4.699e-08 -7.248 -7.328 -0.080 - CaHSO4+ 3.516e-09 2.922e-09 -8.454 -8.534 -0.080 + OH- 1.548e-07 1.274e-07 -6.810 -6.895 -0.085 (0) + H+ 1.060e-07 9.122e-08 -6.975 -7.040 -0.065 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.08 +Ca 1.574e-02 + Ca+2 1.047e-02 5.172e-03 -1.980 -2.286 -0.306 -17.75 + CaSO4 5.279e-03 5.330e-03 -2.277 -2.273 0.004 (0) + CaOH+ 1.132e-08 9.405e-09 -7.946 -8.027 -0.080 (0) + CaHSO4+ 3.516e-09 2.922e-09 -8.454 -8.534 -0.080 (0) +H(0) 9.205e-39 + H2 4.602e-39 4.647e-39 -38.337 -38.333 0.004 (0) +O(0) 1.672e-15 + O2 8.360e-16 8.441e-16 -15.078 -15.074 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -116.590 -116.675 -0.085 (0) + H2S 0.000e+00 0.000e+00 -116.803 -116.799 0.004 (0) + S-2 0.000e+00 0.000e+00 -122.181 -122.494 -0.313 (0) +S(6) 1.574e-02 + SO4-2 1.047e-02 5.071e-03 -1.980 -2.295 -0.315 14.15 + CaSO4 5.279e-03 5.330e-03 -2.277 -2.273 0.004 (0) + HSO4- 5.655e-08 4.699e-08 -7.248 -7.328 -0.080 (0) + CaHSO4+ 3.516e-09 2.922e-09 -8.454 -8.534 -0.080 (0) ------------------------------Saturation indices------------------------------- @@ -391,30 +391,30 @@ Gypsum 0.00 -4.58 -4.58 1.000e+00 1.985e+00 9.848e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.617e-07 1.330e-07 -6.791 -6.876 -0.085 - H+ 1.093e-07 9.404e-08 -6.961 -7.027 -0.065 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.579e-02 - Ca+2 1.047e-02 5.168e-03 -1.980 -2.287 -0.307 - CaSO4 5.321e-03 5.373e-03 -2.274 -2.270 0.004 - CaOH+ 1.097e-08 9.117e-09 -7.960 -8.040 -0.081 - CaHSO4+ 3.703e-09 3.076e-09 -8.431 -8.512 -0.081 -H(0) 1.324e-38 - H2 6.618e-39 6.682e-39 -38.179 -38.175 0.004 -O(0) 1.679e-15 - O2 8.396e-16 8.478e-16 -15.076 -15.072 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -116.074 -116.159 -0.085 - H2S 0.000e+00 0.000e+00 -116.286 -116.282 0.004 - S-2 0.000e+00 0.000e+00 -121.649 -121.962 -0.314 -S(6) 1.579e-02 - SO4-2 1.047e-02 5.067e-03 -1.980 -2.295 -0.315 - CaSO4 5.321e-03 5.373e-03 -2.274 -2.270 0.004 - HSO4- 5.959e-08 4.950e-08 -7.225 -7.305 -0.081 - CaHSO4+ 3.703e-09 3.076e-09 -8.431 -8.512 -0.081 + OH- 1.617e-07 1.330e-07 -6.791 -6.876 -0.085 (0) + H+ 1.093e-07 9.404e-08 -6.961 -7.027 -0.065 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.08 +Ca 1.579e-02 + Ca+2 1.047e-02 5.168e-03 -1.980 -2.287 -0.307 -17.71 + CaSO4 5.321e-03 5.373e-03 -2.274 -2.270 0.004 (0) + CaOH+ 1.097e-08 9.117e-09 -7.960 -8.040 -0.081 (0) + CaHSO4+ 3.703e-09 3.076e-09 -8.431 -8.512 -0.081 (0) +H(0) 1.324e-38 + H2 6.618e-39 6.682e-39 -38.179 -38.175 0.004 (0) +O(0) 1.679e-15 + O2 8.396e-16 8.478e-16 -15.076 -15.072 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -116.074 -116.159 -0.085 (0) + H2S 0.000e+00 0.000e+00 -116.286 -116.282 0.004 (0) + S-2 0.000e+00 0.000e+00 -121.649 -121.962 -0.314 (0) +S(6) 1.579e-02 + SO4-2 1.047e-02 5.067e-03 -1.980 -2.295 -0.315 14.23 + CaSO4 5.321e-03 5.373e-03 -2.274 -2.270 0.004 (0) + HSO4- 5.959e-08 4.950e-08 -7.225 -7.305 -0.081 (0) + CaHSO4+ 3.703e-09 3.076e-09 -8.431 -8.512 -0.081 (0) ------------------------------Saturation indices------------------------------- @@ -471,30 +471,30 @@ Gypsum 0.00 -4.58 -4.58 1.000e+00 1.985e+00 9.847e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.688e-07 1.388e-07 -6.773 -6.858 -0.085 - H+ 1.127e-07 9.693e-08 -6.948 -7.014 -0.065 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.584e-02 - Ca+2 1.048e-02 5.164e-03 -1.980 -2.287 -0.307 - CaSO4 5.361e-03 5.413e-03 -2.271 -2.267 0.004 - CaOH+ 1.064e-08 8.838e-09 -7.973 -8.054 -0.081 - CaHSO4+ 3.899e-09 3.238e-09 -8.409 -8.490 -0.081 -H(0) 1.902e-38 - H2 9.512e-39 9.604e-39 -38.022 -38.018 0.004 -O(0) 1.680e-15 - O2 8.400e-16 8.482e-16 -15.076 -15.072 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -115.559 -115.644 -0.085 - H2S 0.000e+00 0.000e+00 -115.770 -115.766 0.004 - S-2 0.000e+00 0.000e+00 -121.117 -121.431 -0.314 -S(6) 1.584e-02 - SO4-2 1.048e-02 5.063e-03 -1.980 -2.296 -0.316 - CaSO4 5.361e-03 5.413e-03 -2.271 -2.267 0.004 - HSO4- 6.279e-08 5.214e-08 -7.202 -7.283 -0.081 - CaHSO4+ 3.899e-09 3.238e-09 -8.409 -8.490 -0.081 + OH- 1.688e-07 1.388e-07 -6.773 -6.858 -0.085 (0) + H+ 1.127e-07 9.693e-08 -6.948 -7.014 -0.065 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.09 +Ca 1.584e-02 + Ca+2 1.048e-02 5.164e-03 -1.980 -2.287 -0.307 -17.68 + CaSO4 5.361e-03 5.413e-03 -2.271 -2.267 0.004 (0) + CaOH+ 1.064e-08 8.838e-09 -7.973 -8.054 -0.081 (0) + CaHSO4+ 3.899e-09 3.238e-09 -8.409 -8.490 -0.081 (0) +H(0) 1.902e-38 + H2 9.512e-39 9.604e-39 -38.022 -38.018 0.004 (0) +O(0) 1.680e-15 + O2 8.400e-16 8.482e-16 -15.076 -15.072 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -115.559 -115.644 -0.085 (0) + H2S 0.000e+00 0.000e+00 -115.770 -115.766 0.004 (0) + S-2 0.000e+00 0.000e+00 -121.117 -121.431 -0.314 (0) +S(6) 1.584e-02 + SO4-2 1.048e-02 5.063e-03 -1.980 -2.296 -0.316 14.29 + CaSO4 5.361e-03 5.413e-03 -2.271 -2.267 0.004 (0) + HSO4- 6.279e-08 5.214e-08 -7.202 -7.283 -0.081 (0) + CaHSO4+ 3.899e-09 3.238e-09 -8.409 -8.490 -0.081 (0) ------------------------------Saturation indices------------------------------- @@ -551,30 +551,30 @@ Gypsum 0.00 -4.58 -4.58 1.000e+00 1.985e+00 9.847e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.762e-07 1.448e-07 -6.754 -6.839 -0.085 - H+ 1.161e-07 9.988e-08 -6.935 -7.001 -0.065 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.588e-02 - Ca+2 1.048e-02 5.160e-03 -1.980 -2.287 -0.308 - CaSO4 5.400e-03 5.453e-03 -2.268 -2.263 0.004 - CaOH+ 1.032e-08 8.569e-09 -7.986 -8.067 -0.081 - CaHSO4+ 4.103e-09 3.406e-09 -8.387 -8.468 -0.081 -H(0) 2.618e-38 - H2 1.309e-38 1.322e-38 -37.883 -37.879 0.004 -O(0) 1.824e-15 - O2 9.122e-16 9.211e-16 -15.040 -15.036 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -115.118 -115.203 -0.085 - H2S 0.000e+00 0.000e+00 -115.328 -115.324 0.004 - S-2 0.000e+00 0.000e+00 -120.659 -120.974 -0.315 -S(6) 1.588e-02 - SO4-2 1.048e-02 5.059e-03 -1.980 -2.296 -0.316 - CaSO4 5.400e-03 5.453e-03 -2.268 -2.263 0.004 - HSO4- 6.614e-08 5.491e-08 -7.180 -7.260 -0.081 - CaHSO4+ 4.103e-09 3.406e-09 -8.387 -8.468 -0.081 + OH- 1.762e-07 1.448e-07 -6.754 -6.839 -0.085 (0) + H+ 1.161e-07 9.988e-08 -6.935 -7.001 -0.065 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.09 +Ca 1.588e-02 + Ca+2 1.048e-02 5.160e-03 -1.980 -2.287 -0.308 -17.65 + CaSO4 5.400e-03 5.453e-03 -2.268 -2.263 0.004 (0) + CaOH+ 1.032e-08 8.569e-09 -7.986 -8.067 -0.081 (0) + CaHSO4+ 4.103e-09 3.406e-09 -8.387 -8.468 -0.081 (0) +H(0) 2.618e-38 + H2 1.309e-38 1.322e-38 -37.883 -37.879 0.004 (0) +O(0) 1.824e-15 + O2 9.122e-16 9.211e-16 -15.040 -15.036 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -115.118 -115.203 -0.085 (0) + H2S 0.000e+00 0.000e+00 -115.328 -115.324 0.004 (0) + S-2 0.000e+00 0.000e+00 -120.659 -120.974 -0.315 (0) +S(6) 1.588e-02 + SO4-2 1.048e-02 5.059e-03 -1.980 -2.296 -0.316 14.35 + CaSO4 5.400e-03 5.453e-03 -2.268 -2.263 0.004 (0) + HSO4- 6.614e-08 5.491e-08 -7.180 -7.260 -0.081 (0) + CaHSO4+ 4.103e-09 3.406e-09 -8.387 -8.468 -0.081 (0) ------------------------------Saturation indices------------------------------- @@ -631,30 +631,30 @@ Gypsum 0.00 -4.58 -4.58 1.000e+00 1.985e+00 9.846e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.837e-07 1.510e-07 -6.736 -6.821 -0.085 - H+ 1.197e-07 1.029e-07 -6.922 -6.988 -0.066 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.592e-02 - Ca+2 1.049e-02 5.154e-03 -1.979 -2.288 -0.308 - CaSO4 5.438e-03 5.491e-03 -2.265 -2.260 0.004 - CaOH+ 1.001e-08 8.310e-09 -7.999 -8.080 -0.081 - CaHSO4+ 4.317e-09 3.582e-09 -8.365 -8.446 -0.081 -H(0) 3.916e-38 - H2 1.958e-38 1.977e-38 -37.708 -37.704 0.004 -O(0) 1.669e-15 - O2 8.346e-16 8.427e-16 -15.079 -15.074 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -114.532 -114.617 -0.085 - H2S 0.000e+00 0.000e+00 -114.741 -114.737 0.004 - S-2 0.000e+00 0.000e+00 -120.057 -120.372 -0.315 -S(6) 1.592e-02 - SO4-2 1.048e-02 5.053e-03 -1.979 -2.296 -0.317 - CaSO4 5.438e-03 5.491e-03 -2.265 -2.260 0.004 - HSO4- 6.966e-08 5.780e-08 -7.157 -7.238 -0.081 - CaHSO4+ 4.317e-09 3.582e-09 -8.365 -8.446 -0.081 + OH- 1.837e-07 1.510e-07 -6.736 -6.821 -0.085 (0) + H+ 1.197e-07 1.029e-07 -6.922 -6.988 -0.066 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.10 +Ca 1.592e-02 + Ca+2 1.049e-02 5.154e-03 -1.979 -2.288 -0.308 -17.62 + CaSO4 5.438e-03 5.491e-03 -2.265 -2.260 0.004 (0) + CaOH+ 1.001e-08 8.310e-09 -7.999 -8.080 -0.081 (0) + CaHSO4+ 4.317e-09 3.582e-09 -8.365 -8.446 -0.081 (0) +H(0) 3.916e-38 + H2 1.958e-38 1.977e-38 -37.708 -37.704 0.004 (0) +O(0) 1.669e-15 + O2 8.346e-16 8.427e-16 -15.079 -15.074 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -114.532 -114.617 -0.085 (0) + H2S 0.000e+00 0.000e+00 -114.741 -114.737 0.004 (0) + S-2 0.000e+00 0.000e+00 -120.057 -120.372 -0.315 (0) +S(6) 1.592e-02 + SO4-2 1.048e-02 5.053e-03 -1.979 -2.296 -0.317 14.41 + CaSO4 5.438e-03 5.491e-03 -2.265 -2.260 0.004 (0) + HSO4- 6.966e-08 5.780e-08 -7.157 -7.238 -0.081 (0) + CaHSO4+ 4.317e-09 3.582e-09 -8.365 -8.446 -0.081 (0) ------------------------------Saturation indices------------------------------- @@ -711,30 +711,30 @@ Gypsum 0.00 -4.59 -4.59 1.000e+00 1.985e+00 9.846e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.916e-07 1.573e-07 -6.718 -6.803 -0.085 - H+ 1.233e-07 1.060e-07 -6.909 -6.975 -0.066 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.596e-02 - Ca+2 1.049e-02 5.148e-03 -1.979 -2.288 -0.309 - CaSO4 5.474e-03 5.527e-03 -2.262 -2.258 0.004 - CaOH+ 9.715e-09 8.059e-09 -8.013 -8.094 -0.081 - CaHSO4+ 4.540e-09 3.766e-09 -8.343 -8.424 -0.081 -H(0) 5.578e-38 - H2 2.789e-38 2.816e-38 -37.555 -37.550 0.004 -O(0) 1.677e-15 - O2 8.383e-16 8.464e-16 -15.077 -15.072 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -114.030 -114.115 -0.085 - H2S 0.000e+00 0.000e+00 -114.238 -114.234 0.004 - S-2 0.000e+00 0.000e+00 -119.539 -119.855 -0.316 -S(6) 1.596e-02 - SO4-2 1.049e-02 5.047e-03 -1.979 -2.297 -0.318 - CaSO4 5.474e-03 5.527e-03 -2.262 -2.258 0.004 - HSO4- 7.334e-08 6.084e-08 -7.135 -7.216 -0.081 - CaHSO4+ 4.540e-09 3.766e-09 -8.343 -8.424 -0.081 + OH- 1.916e-07 1.573e-07 -6.718 -6.803 -0.085 (0) + H+ 1.233e-07 1.060e-07 -6.909 -6.975 -0.066 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.11 +Ca 1.596e-02 + Ca+2 1.049e-02 5.148e-03 -1.979 -2.288 -0.309 -17.59 + CaSO4 5.474e-03 5.527e-03 -2.262 -2.258 0.004 (0) + CaOH+ 9.715e-09 8.059e-09 -8.013 -8.094 -0.081 (0) + CaHSO4+ 4.540e-09 3.766e-09 -8.343 -8.424 -0.081 (0) +H(0) 5.578e-38 + H2 2.789e-38 2.816e-38 -37.555 -37.550 0.004 (0) +O(0) 1.677e-15 + O2 8.383e-16 8.464e-16 -15.077 -15.072 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -114.030 -114.115 -0.085 (0) + H2S 0.000e+00 0.000e+00 -114.238 -114.234 0.004 (0) + S-2 0.000e+00 0.000e+00 -119.539 -119.855 -0.316 (0) +S(6) 1.596e-02 + SO4-2 1.049e-02 5.047e-03 -1.979 -2.297 -0.318 14.45 + CaSO4 5.474e-03 5.527e-03 -2.262 -2.258 0.004 (0) + HSO4- 7.334e-08 6.084e-08 -7.135 -7.216 -0.081 (0) + CaHSO4+ 4.540e-09 3.766e-09 -8.343 -8.424 -0.081 (0) ------------------------------Saturation indices------------------------------- @@ -791,30 +791,30 @@ Gypsum -0.00 -4.59 -4.59 1.000e+00 1.985e+00 9.846e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.996e-07 1.639e-07 -6.700 -6.785 -0.086 - H+ 1.270e-07 1.091e-07 -6.896 -6.962 -0.066 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -Ca 1.599e-02 - Ca+2 1.049e-02 5.142e-03 -1.979 -2.289 -0.309 - CaSO4 5.508e-03 5.562e-03 -2.259 -2.255 0.004 - CaOH+ 9.427e-09 7.818e-09 -8.026 -8.107 -0.081 - CaHSO4+ 4.772e-09 3.957e-09 -8.321 -8.403 -0.081 -H(0) 7.721e-38 - H2 3.860e-38 3.898e-38 -37.413 -37.409 0.004 -O(0) 1.775e-15 - O2 8.873e-16 8.959e-16 -15.052 -15.048 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -113.577 -113.663 -0.086 - H2S 0.000e+00 0.000e+00 -113.784 -113.780 0.004 - S-2 0.000e+00 0.000e+00 -119.070 -119.387 -0.316 -S(6) 1.599e-02 - SO4-2 1.048e-02 5.041e-03 -1.979 -2.297 -0.318 - CaSO4 5.508e-03 5.562e-03 -2.259 -2.255 0.004 - HSO4- 7.720e-08 6.402e-08 -7.112 -7.194 -0.081 - CaHSO4+ 4.772e-09 3.957e-09 -8.321 -8.403 -0.081 + OH- 1.996e-07 1.639e-07 -6.700 -6.785 -0.086 (0) + H+ 1.270e-07 1.091e-07 -6.896 -6.962 -0.066 0.00 + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.11 +Ca 1.599e-02 + Ca+2 1.049e-02 5.142e-03 -1.979 -2.289 -0.309 -17.57 + CaSO4 5.508e-03 5.562e-03 -2.259 -2.255 0.004 (0) + CaOH+ 9.427e-09 7.818e-09 -8.026 -8.107 -0.081 (0) + CaHSO4+ 4.772e-09 3.957e-09 -8.321 -8.403 -0.081 (0) +H(0) 7.721e-38 + H2 3.860e-38 3.898e-38 -37.413 -37.409 0.004 (0) +O(0) 1.775e-15 + O2 8.873e-16 8.959e-16 -15.052 -15.048 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -113.577 -113.663 -0.086 (0) + H2S 0.000e+00 0.000e+00 -113.784 -113.780 0.004 (0) + S-2 0.000e+00 0.000e+00 -119.070 -119.387 -0.316 (0) +S(6) 1.599e-02 + SO4-2 1.048e-02 5.041e-03 -1.979 -2.297 -0.318 14.49 + CaSO4 5.508e-03 5.562e-03 -2.259 -2.255 0.004 (0) + HSO4- 7.720e-08 6.402e-08 -7.112 -7.194 -0.081 (0) + CaHSO4+ 4.772e-09 3.957e-09 -8.321 -8.403 -0.081 (0) ------------------------------Saturation indices------------------------------- @@ -871,30 +871,30 @@ Gypsum -0.00 -4.59 -4.59 1.000e+00 1.985e+00 9.845e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.079e-07 1.707e-07 -6.682 -6.768 -0.086 - H+ 1.307e-07 1.123e-07 -6.884 -6.950 -0.066 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -Ca 1.602e-02 - Ca+2 1.048e-02 5.134e-03 -1.980 -2.290 -0.310 - CaSO4 5.541e-03 5.595e-03 -2.256 -2.252 0.004 - CaOH+ 9.149e-09 7.585e-09 -8.039 -8.120 -0.081 - CaHSO4+ 5.015e-09 4.157e-09 -8.300 -8.381 -0.081 -H(0) 1.124e-37 - H2 5.622e-38 5.677e-38 -37.250 -37.246 0.004 -O(0) 1.689e-15 - O2 8.446e-16 8.528e-16 -15.073 -15.069 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -113.035 -113.121 -0.086 - H2S 0.000e+00 0.000e+00 -113.241 -113.237 0.004 - S-2 0.000e+00 0.000e+00 -118.513 -118.830 -0.317 -S(6) 1.602e-02 - SO4-2 1.048e-02 5.034e-03 -1.980 -2.298 -0.319 - CaSO4 5.541e-03 5.595e-03 -2.256 -2.252 0.004 - HSO4- 8.124e-08 6.734e-08 -7.090 -7.172 -0.081 - CaHSO4+ 5.015e-09 4.157e-09 -8.300 -8.381 -0.081 + OH- 2.079e-07 1.707e-07 -6.682 -6.768 -0.086 (0) + H+ 1.307e-07 1.123e-07 -6.884 -6.950 -0.066 0.00 + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.12 +Ca 1.602e-02 + Ca+2 1.048e-02 5.134e-03 -1.980 -2.290 -0.310 -17.54 + CaSO4 5.541e-03 5.595e-03 -2.256 -2.252 0.004 (0) + CaOH+ 9.149e-09 7.585e-09 -8.039 -8.120 -0.081 (0) + CaHSO4+ 5.015e-09 4.157e-09 -8.300 -8.381 -0.081 (0) +H(0) 1.124e-37 + H2 5.622e-38 5.677e-38 -37.250 -37.246 0.004 (0) +O(0) 1.689e-15 + O2 8.446e-16 8.528e-16 -15.073 -15.069 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -113.035 -113.121 -0.086 (0) + H2S 0.000e+00 0.000e+00 -113.241 -113.237 0.004 (0) + S-2 0.000e+00 0.000e+00 -118.513 -118.830 -0.317 (0) +S(6) 1.602e-02 + SO4-2 1.048e-02 5.034e-03 -1.980 -2.298 -0.319 14.51 + CaSO4 5.541e-03 5.595e-03 -2.256 -2.252 0.004 (0) + HSO4- 8.124e-08 6.734e-08 -7.090 -7.172 -0.081 (0) + CaHSO4+ 5.015e-09 4.157e-09 -8.300 -8.381 -0.081 (0) ------------------------------Saturation indices------------------------------- @@ -951,30 +951,30 @@ Gypsum 0.00 -4.59 -4.59 1.000e+00 1.985e+00 9.845e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.165e-07 1.776e-07 -6.665 -6.750 -0.086 - H+ 1.345e-07 1.155e-07 -6.871 -6.937 -0.066 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -Ca 1.605e-02 - Ca+2 1.048e-02 5.126e-03 -1.980 -2.290 -0.310 - CaSO4 5.573e-03 5.627e-03 -2.254 -2.250 0.004 - CaOH+ 8.881e-09 7.360e-09 -8.052 -8.133 -0.082 - CaHSO4+ 5.267e-09 4.365e-09 -8.278 -8.360 -0.082 -H(0) 1.604e-37 - H2 8.021e-38 8.099e-38 -37.096 -37.092 0.004 -O(0) 1.668e-15 - O2 8.338e-16 8.418e-16 -15.079 -15.075 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -112.529 -112.615 -0.086 - H2S 0.000e+00 0.000e+00 -112.733 -112.729 0.004 - S-2 0.000e+00 0.000e+00 -117.990 -118.308 -0.317 -S(6) 1.605e-02 - SO4-2 1.048e-02 5.026e-03 -1.980 -2.299 -0.319 - CaSO4 5.573e-03 5.627e-03 -2.254 -2.250 0.004 - HSO4- 8.546e-08 7.082e-08 -7.068 -7.150 -0.082 - CaHSO4+ 5.267e-09 4.365e-09 -8.278 -8.360 -0.082 + OH- 2.165e-07 1.776e-07 -6.665 -6.750 -0.086 (0) + H+ 1.345e-07 1.155e-07 -6.871 -6.937 -0.066 0.00 + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.12 +Ca 1.605e-02 + Ca+2 1.048e-02 5.126e-03 -1.980 -2.290 -0.310 -17.52 + CaSO4 5.573e-03 5.627e-03 -2.254 -2.250 0.004 (0) + CaOH+ 8.881e-09 7.360e-09 -8.052 -8.133 -0.082 (0) + CaHSO4+ 5.267e-09 4.365e-09 -8.278 -8.360 -0.082 (0) +H(0) 1.604e-37 + H2 8.021e-38 8.099e-38 -37.096 -37.092 0.004 (0) +O(0) 1.668e-15 + O2 8.338e-16 8.418e-16 -15.079 -15.075 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -112.529 -112.615 -0.086 (0) + H2S 0.000e+00 0.000e+00 -112.733 -112.729 0.004 (0) + S-2 0.000e+00 0.000e+00 -117.990 -118.308 -0.317 (0) +S(6) 1.605e-02 + SO4-2 1.048e-02 5.026e-03 -1.980 -2.299 -0.319 14.54 + CaSO4 5.573e-03 5.627e-03 -2.254 -2.250 0.004 (0) + HSO4- 8.546e-08 7.082e-08 -7.068 -7.150 -0.082 (0) + CaHSO4+ 5.267e-09 4.365e-09 -8.278 -8.360 -0.082 (0) ------------------------------Saturation indices------------------------------- @@ -1031,30 +1031,30 @@ Gypsum -0.00 -4.59 -4.59 1.000e+00 1.984e+00 9.845e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.253e-07 1.848e-07 -6.647 -6.733 -0.086 - H+ 1.384e-07 1.189e-07 -6.859 -6.925 -0.066 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -Ca 1.608e-02 - Ca+2 1.047e-02 5.118e-03 -1.980 -2.291 -0.311 - CaSO4 5.603e-03 5.657e-03 -2.252 -2.247 0.004 - CaOH+ 8.622e-09 7.143e-09 -8.064 -8.146 -0.082 - CaHSO4+ 5.530e-09 4.582e-09 -8.257 -8.339 -0.082 -H(0) 2.255e-37 - H2 1.127e-37 1.138e-37 -36.948 -36.944 0.004 -O(0) 1.689e-15 - O2 8.443e-16 8.525e-16 -15.074 -15.069 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -112.048 -112.134 -0.086 - H2S 0.000e+00 0.000e+00 -112.250 -112.246 0.004 - S-2 0.000e+00 0.000e+00 -117.493 -117.811 -0.318 -S(6) 1.608e-02 - SO4-2 1.047e-02 5.018e-03 -1.980 -2.300 -0.320 - CaSO4 5.603e-03 5.657e-03 -2.252 -2.247 0.004 - HSO4- 8.988e-08 7.446e-08 -7.046 -7.128 -0.082 - CaHSO4+ 5.530e-09 4.582e-09 -8.257 -8.339 -0.082 + OH- 2.253e-07 1.848e-07 -6.647 -6.733 -0.086 (0) + H+ 1.384e-07 1.189e-07 -6.859 -6.925 -0.066 0.00 + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.13 +Ca 1.608e-02 + Ca+2 1.047e-02 5.118e-03 -1.980 -2.291 -0.311 -17.51 + CaSO4 5.603e-03 5.657e-03 -2.252 -2.247 0.004 (0) + CaOH+ 8.622e-09 7.143e-09 -8.064 -8.146 -0.082 (0) + CaHSO4+ 5.530e-09 4.582e-09 -8.257 -8.339 -0.082 (0) +H(0) 2.255e-37 + H2 1.127e-37 1.138e-37 -36.948 -36.944 0.004 (0) +O(0) 1.689e-15 + O2 8.443e-16 8.525e-16 -15.074 -15.069 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -112.048 -112.134 -0.086 (0) + H2S 0.000e+00 0.000e+00 -112.250 -112.246 0.004 (0) + S-2 0.000e+00 0.000e+00 -117.493 -117.811 -0.318 (0) +S(6) 1.608e-02 + SO4-2 1.047e-02 5.018e-03 -1.980 -2.300 -0.320 14.55 + CaSO4 5.603e-03 5.657e-03 -2.252 -2.247 0.004 (0) + HSO4- 8.988e-08 7.446e-08 -7.046 -7.128 -0.082 (0) + CaHSO4+ 5.530e-09 4.582e-09 -8.257 -8.339 -0.082 (0) ------------------------------Saturation indices------------------------------- @@ -1111,30 +1111,30 @@ Gypsum -0.00 -4.59 -4.59 1.000e+00 1.984e+00 9.845e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.344e-07 1.922e-07 -6.630 -6.716 -0.086 - H+ 1.423e-07 1.222e-07 -6.847 -6.913 -0.066 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -Ca 1.610e-02 - Ca+2 1.047e-02 5.109e-03 -1.980 -2.292 -0.311 - CaSO4 5.632e-03 5.686e-03 -2.249 -2.245 0.004 - CaOH+ 8.373e-09 6.934e-09 -8.077 -8.159 -0.082 - CaHSO4+ 5.804e-09 4.807e-09 -8.236 -8.318 -0.082 -H(0) 3.199e-37 - H2 1.600e-37 1.615e-37 -36.796 -36.792 0.004 -O(0) 1.671e-15 - O2 8.354e-16 8.435e-16 -15.078 -15.074 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -111.550 -111.636 -0.086 - H2S 0.000e+00 0.000e+00 -111.750 -111.746 0.004 - S-2 0.000e+00 0.000e+00 -116.979 -117.298 -0.318 -S(6) 1.610e-02 - SO4-2 1.047e-02 5.009e-03 -1.980 -2.300 -0.320 - CaSO4 5.632e-03 5.686e-03 -2.249 -2.245 0.004 - HSO4- 9.450e-08 7.827e-08 -7.025 -7.106 -0.082 - CaHSO4+ 5.804e-09 4.807e-09 -8.236 -8.318 -0.082 + OH- 2.344e-07 1.922e-07 -6.630 -6.716 -0.086 (0) + H+ 1.423e-07 1.222e-07 -6.847 -6.913 -0.066 0.00 + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.14 +Ca 1.610e-02 + Ca+2 1.047e-02 5.109e-03 -1.980 -2.292 -0.311 -17.49 + CaSO4 5.632e-03 5.686e-03 -2.249 -2.245 0.004 (0) + CaOH+ 8.373e-09 6.934e-09 -8.077 -8.159 -0.082 (0) + CaHSO4+ 5.804e-09 4.807e-09 -8.236 -8.318 -0.082 (0) +H(0) 3.199e-37 + H2 1.600e-37 1.615e-37 -36.796 -36.792 0.004 (0) +O(0) 1.671e-15 + O2 8.354e-16 8.435e-16 -15.078 -15.074 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -111.550 -111.636 -0.086 (0) + H2S 0.000e+00 0.000e+00 -111.750 -111.746 0.004 (0) + S-2 0.000e+00 0.000e+00 -116.979 -117.298 -0.318 (0) +S(6) 1.610e-02 + SO4-2 1.047e-02 5.009e-03 -1.980 -2.300 -0.320 14.56 + CaSO4 5.632e-03 5.686e-03 -2.249 -2.245 0.004 (0) + HSO4- 9.450e-08 7.827e-08 -7.025 -7.106 -0.082 (0) + CaHSO4+ 5.804e-09 4.807e-09 -8.236 -8.318 -0.082 (0) ------------------------------Saturation indices------------------------------- @@ -1191,30 +1191,30 @@ Gypsum -0.00 -4.59 -4.59 1.000e+00 1.984e+00 9.845e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.438e-07 1.999e-07 -6.613 -6.699 -0.086 - H+ 1.464e-07 1.256e-07 -6.835 -6.901 -0.066 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -Ca 1.612e-02 - Ca+2 1.046e-02 5.099e-03 -1.981 -2.293 -0.312 - CaSO4 5.659e-03 5.714e-03 -2.247 -2.243 0.004 - CaOH+ 8.132e-09 6.733e-09 -8.090 -8.172 -0.082 - CaHSO4+ 6.089e-09 5.042e-09 -8.215 -8.297 -0.082 -H(0) 4.483e-37 - H2 2.242e-37 2.263e-37 -36.649 -36.645 0.004 -O(0) 1.687e-15 - O2 8.435e-16 8.517e-16 -15.074 -15.070 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -111.072 -111.159 -0.086 - H2S 0.000e+00 0.000e+00 -111.271 -111.267 0.004 - S-2 0.000e+00 0.000e+00 -116.486 -116.805 -0.319 -S(6) 1.612e-02 - SO4-2 1.046e-02 4.999e-03 -1.981 -2.301 -0.321 - CaSO4 5.659e-03 5.714e-03 -2.247 -2.243 0.004 - HSO4- 9.933e-08 8.224e-08 -7.003 -7.085 -0.082 - CaHSO4+ 6.089e-09 5.042e-09 -8.215 -8.297 -0.082 + OH- 2.438e-07 1.999e-07 -6.613 -6.699 -0.086 (0) + H+ 1.464e-07 1.256e-07 -6.835 -6.901 -0.066 0.00 + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.14 +Ca 1.612e-02 + Ca+2 1.046e-02 5.099e-03 -1.981 -2.293 -0.312 -17.48 + CaSO4 5.659e-03 5.714e-03 -2.247 -2.243 0.004 (0) + CaOH+ 8.132e-09 6.733e-09 -8.090 -8.172 -0.082 (0) + CaHSO4+ 6.089e-09 5.042e-09 -8.215 -8.297 -0.082 (0) +H(0) 4.483e-37 + H2 2.242e-37 2.263e-37 -36.649 -36.645 0.004 (0) +O(0) 1.687e-15 + O2 8.435e-16 8.517e-16 -15.074 -15.070 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -111.072 -111.159 -0.086 (0) + H2S 0.000e+00 0.000e+00 -111.271 -111.267 0.004 (0) + S-2 0.000e+00 0.000e+00 -116.486 -116.805 -0.319 (0) +S(6) 1.612e-02 + SO4-2 1.046e-02 4.999e-03 -1.981 -2.301 -0.321 14.55 + CaSO4 5.659e-03 5.714e-03 -2.247 -2.243 0.004 (0) + HSO4- 9.933e-08 8.224e-08 -7.003 -7.085 -0.082 (0) + CaHSO4+ 6.089e-09 5.042e-09 -8.215 -8.297 -0.082 (0) ------------------------------Saturation indices------------------------------- @@ -1271,30 +1271,30 @@ Gypsum 0.00 -4.60 -4.60 1.000e+00 1.984e+00 9.844e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.534e-07 2.077e-07 -6.596 -6.683 -0.086 - H+ 1.504e-07 1.291e-07 -6.823 -6.889 -0.066 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -Ca 1.613e-02 - Ca+2 1.045e-02 5.089e-03 -1.981 -2.293 -0.312 - CaSO4 5.684e-03 5.739e-03 -2.245 -2.241 0.004 - CaOH+ 7.899e-09 6.538e-09 -8.102 -8.185 -0.082 - CaHSO4+ 6.386e-09 5.286e-09 -8.195 -8.277 -0.082 -H(0) 5.933e-37 - H2 2.967e-37 2.995e-37 -36.528 -36.524 0.004 -O(0) 1.901e-15 - O2 9.507e-16 9.599e-16 -15.022 -15.018 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -110.694 -110.780 -0.086 - H2S 0.000e+00 0.000e+00 -110.891 -110.887 0.004 - S-2 0.000e+00 0.000e+00 -116.092 -116.411 -0.319 -S(6) 1.613e-02 - SO4-2 1.045e-02 4.989e-03 -1.981 -2.302 -0.321 - CaSO4 5.684e-03 5.739e-03 -2.245 -2.241 0.004 - HSO4- 1.044e-07 8.640e-08 -6.981 -7.064 -0.082 - CaHSO4+ 6.386e-09 5.286e-09 -8.195 -8.277 -0.082 + OH- 2.534e-07 2.077e-07 -6.596 -6.683 -0.086 (0) + H+ 1.504e-07 1.291e-07 -6.823 -6.889 -0.066 0.00 + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.15 +Ca 1.613e-02 + Ca+2 1.045e-02 5.089e-03 -1.981 -2.293 -0.312 -17.47 + CaSO4 5.684e-03 5.739e-03 -2.245 -2.241 0.004 (0) + CaOH+ 7.899e-09 6.538e-09 -8.102 -8.185 -0.082 (0) + CaHSO4+ 6.386e-09 5.286e-09 -8.195 -8.277 -0.082 (0) +H(0) 5.933e-37 + H2 2.967e-37 2.995e-37 -36.528 -36.524 0.004 (0) +O(0) 1.901e-15 + O2 9.507e-16 9.599e-16 -15.022 -15.018 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -110.694 -110.780 -0.086 (0) + H2S 0.000e+00 0.000e+00 -110.891 -110.887 0.004 (0) + S-2 0.000e+00 0.000e+00 -116.092 -116.411 -0.319 (0) +S(6) 1.613e-02 + SO4-2 1.045e-02 4.989e-03 -1.981 -2.302 -0.321 14.54 + CaSO4 5.684e-03 5.739e-03 -2.245 -2.241 0.004 (0) + HSO4- 1.044e-07 8.640e-08 -6.981 -7.064 -0.082 (0) + CaHSO4+ 6.386e-09 5.286e-09 -8.195 -8.277 -0.082 (0) ------------------------------Saturation indices------------------------------- @@ -1351,30 +1351,30 @@ Gypsum 0.00 -4.60 -4.60 1.000e+00 1.984e+00 9.844e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.634e-07 2.158e-07 -6.579 -6.666 -0.086 - H+ 1.546e-07 1.326e-07 -6.811 -6.877 -0.067 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -Ca 1.614e-02 - Ca+2 1.044e-02 5.078e-03 -1.981 -2.294 -0.313 - CaSO4 5.708e-03 5.764e-03 -2.243 -2.239 0.004 - CaOH+ 7.675e-09 6.351e-09 -8.115 -8.197 -0.082 - CaHSO4+ 6.694e-09 5.539e-09 -8.174 -8.257 -0.082 -H(0) 8.832e-37 - H2 4.416e-37 4.459e-37 -36.355 -36.351 0.004 -O(0) 1.687e-15 - O2 8.433e-16 8.515e-16 -15.074 -15.070 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -110.111 -110.197 -0.086 - H2S 0.000e+00 0.000e+00 -110.306 -110.302 0.004 - S-2 0.000e+00 0.000e+00 -115.493 -115.813 -0.320 -S(6) 1.614e-02 - SO4-2 1.044e-02 4.979e-03 -1.981 -2.303 -0.321 - CaSO4 5.708e-03 5.764e-03 -2.243 -2.239 0.004 - HSO4- 1.097e-07 9.073e-08 -6.960 -7.042 -0.082 - CaHSO4+ 6.694e-09 5.539e-09 -8.174 -8.257 -0.082 + OH- 2.634e-07 2.158e-07 -6.579 -6.666 -0.086 (0) + H+ 1.546e-07 1.326e-07 -6.811 -6.877 -0.067 0.00 + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.16 +Ca 1.614e-02 + Ca+2 1.044e-02 5.078e-03 -1.981 -2.294 -0.313 -17.47 + CaSO4 5.708e-03 5.764e-03 -2.243 -2.239 0.004 (0) + CaOH+ 7.675e-09 6.351e-09 -8.115 -8.197 -0.082 (0) + CaHSO4+ 6.694e-09 5.539e-09 -8.174 -8.257 -0.082 (0) +H(0) 8.832e-37 + H2 4.416e-37 4.459e-37 -36.355 -36.351 0.004 (0) +O(0) 1.687e-15 + O2 8.433e-16 8.515e-16 -15.074 -15.070 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -110.111 -110.197 -0.086 (0) + H2S 0.000e+00 0.000e+00 -110.306 -110.302 0.004 (0) + S-2 0.000e+00 0.000e+00 -115.493 -115.813 -0.320 (0) +S(6) 1.614e-02 + SO4-2 1.044e-02 4.979e-03 -1.981 -2.303 -0.321 14.53 + CaSO4 5.708e-03 5.764e-03 -2.243 -2.239 0.004 (0) + HSO4- 1.097e-07 9.073e-08 -6.960 -7.042 -0.082 (0) + CaHSO4+ 6.694e-09 5.539e-09 -8.174 -8.257 -0.082 (0) ------------------------------Saturation indices------------------------------- @@ -1431,30 +1431,30 @@ Gypsum -0.00 -4.60 -4.60 1.000e+00 1.984e+00 9.844e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.736e-07 2.241e-07 -6.563 -6.649 -0.087 - H+ 1.588e-07 1.362e-07 -6.799 -6.866 -0.067 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -Ca 1.615e-02 - Ca+2 1.042e-02 5.066e-03 -1.982 -2.295 -0.313 - CaSO4 5.731e-03 5.786e-03 -2.242 -2.238 0.004 - CaOH+ 7.458e-09 6.170e-09 -8.127 -8.210 -0.082 - CaHSO4+ 7.014e-09 5.802e-09 -8.154 -8.236 -0.082 -H(0) 1.239e-36 - H2 6.197e-37 6.257e-37 -36.208 -36.204 0.004 -O(0) 1.676e-15 - O2 8.382e-16 8.463e-16 -15.077 -15.072 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -109.629 -109.716 -0.087 - H2S 0.000e+00 0.000e+00 -109.823 -109.818 0.004 - S-2 0.000e+00 0.000e+00 -114.996 -115.316 -0.320 -S(6) 1.615e-02 - SO4-2 1.042e-02 4.967e-03 -1.982 -2.304 -0.322 - CaSO4 5.731e-03 5.786e-03 -2.242 -2.238 0.004 - HSO4- 1.152e-07 9.526e-08 -6.939 -7.021 -0.082 - CaHSO4+ 7.014e-09 5.802e-09 -8.154 -8.236 -0.082 + OH- 2.736e-07 2.241e-07 -6.563 -6.649 -0.087 (0) + H+ 1.588e-07 1.362e-07 -6.799 -6.866 -0.067 0.00 + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.16 +Ca 1.615e-02 + Ca+2 1.042e-02 5.066e-03 -1.982 -2.295 -0.313 -17.46 + CaSO4 5.731e-03 5.786e-03 -2.242 -2.238 0.004 (0) + CaOH+ 7.458e-09 6.170e-09 -8.127 -8.210 -0.082 (0) + CaHSO4+ 7.014e-09 5.802e-09 -8.154 -8.236 -0.082 (0) +H(0) 1.239e-36 + H2 6.197e-37 6.257e-37 -36.208 -36.204 0.004 (0) +O(0) 1.676e-15 + O2 8.382e-16 8.463e-16 -15.077 -15.072 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -109.629 -109.716 -0.087 (0) + H2S 0.000e+00 0.000e+00 -109.823 -109.818 0.004 (0) + S-2 0.000e+00 0.000e+00 -114.996 -115.316 -0.320 (0) +S(6) 1.615e-02 + SO4-2 1.042e-02 4.967e-03 -1.982 -2.304 -0.322 14.50 + CaSO4 5.731e-03 5.786e-03 -2.242 -2.238 0.004 (0) + HSO4- 1.152e-07 9.526e-08 -6.939 -7.021 -0.082 (0) + CaHSO4+ 7.014e-09 5.802e-09 -8.154 -8.236 -0.082 (0) ------------------------------Saturation indices------------------------------- @@ -1511,30 +1511,30 @@ Gypsum 0.00 -4.60 -4.60 1.000e+00 1.984e+00 9.844e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.842e-07 2.327e-07 -6.546 -6.633 -0.087 - H+ 1.631e-07 1.398e-07 -6.788 -6.854 -0.067 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -Ca 1.616e-02 - Ca+2 1.041e-02 5.054e-03 -1.983 -2.296 -0.314 - CaSO4 5.752e-03 5.808e-03 -2.240 -2.236 0.004 - CaHSO4+ 7.346e-09 6.075e-09 -8.134 -8.216 -0.082 - CaOH+ 7.249e-09 5.995e-09 -8.140 -8.222 -0.082 -H(0) 1.724e-36 - H2 8.622e-37 8.705e-37 -36.064 -36.060 0.004 -O(0) 1.688e-15 - O2 8.439e-16 8.520e-16 -15.074 -15.070 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -109.162 -109.249 -0.087 - H2S 0.000e+00 0.000e+00 -109.354 -109.349 0.004 - S-2 0.000e+00 0.000e+00 -114.514 -114.834 -0.321 -S(6) 1.616e-02 - SO4-2 1.041e-02 4.956e-03 -1.983 -2.305 -0.322 - CaSO4 5.752e-03 5.808e-03 -2.240 -2.236 0.004 - HSO4- 1.209e-07 9.998e-08 -6.918 -7.000 -0.082 - CaHSO4+ 7.346e-09 6.075e-09 -8.134 -8.216 -0.082 + OH- 2.842e-07 2.327e-07 -6.546 -6.633 -0.087 (0) + H+ 1.631e-07 1.398e-07 -6.788 -6.854 -0.067 0.00 + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.17 +Ca 1.616e-02 + Ca+2 1.041e-02 5.054e-03 -1.983 -2.296 -0.314 -17.46 + CaSO4 5.752e-03 5.808e-03 -2.240 -2.236 0.004 (0) + CaHSO4+ 7.346e-09 6.075e-09 -8.134 -8.216 -0.082 (0) + CaOH+ 7.249e-09 5.995e-09 -8.140 -8.222 -0.082 (0) +H(0) 1.724e-36 + H2 8.622e-37 8.705e-37 -36.064 -36.060 0.004 (0) +O(0) 1.688e-15 + O2 8.439e-16 8.520e-16 -15.074 -15.070 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -109.162 -109.249 -0.087 (0) + H2S 0.000e+00 0.000e+00 -109.354 -109.349 0.004 (0) + S-2 0.000e+00 0.000e+00 -114.514 -114.834 -0.321 (0) +S(6) 1.616e-02 + SO4-2 1.041e-02 4.956e-03 -1.983 -2.305 -0.322 14.47 + CaSO4 5.752e-03 5.808e-03 -2.240 -2.236 0.004 (0) + HSO4- 1.209e-07 9.998e-08 -6.918 -7.000 -0.082 (0) + CaHSO4+ 7.346e-09 6.075e-09 -8.134 -8.216 -0.082 (0) ------------------------------Saturation indices------------------------------- @@ -1591,30 +1591,30 @@ Gypsum -0.00 -4.60 -4.60 1.000e+00 1.984e+00 9.844e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.950e-07 2.416e-07 -6.530 -6.617 -0.087 - H+ 1.674e-07 1.435e-07 -6.776 -6.843 -0.067 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -Ca 1.616e-02 - Ca+2 1.039e-02 5.042e-03 -1.983 -2.297 -0.314 - CaSO4 5.772e-03 5.827e-03 -2.239 -2.235 0.004 - CaHSO4+ 7.691e-09 6.359e-09 -8.114 -8.197 -0.083 - CaOH+ 7.048e-09 5.827e-09 -8.152 -8.235 -0.083 -H(0) 2.395e-36 - H2 1.197e-36 1.209e-36 -35.922 -35.918 0.004 -O(0) 1.698e-15 - O2 8.491e-16 8.572e-16 -15.071 -15.067 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -108.698 -108.785 -0.087 - H2S 0.000e+00 0.000e+00 -108.887 -108.883 0.004 - S-2 0.000e+00 0.000e+00 -114.034 -114.355 -0.321 -S(6) 1.616e-02 - SO4-2 1.039e-02 4.944e-03 -1.983 -2.306 -0.323 - CaSO4 5.772e-03 5.827e-03 -2.239 -2.235 0.004 - HSO4- 1.269e-07 1.049e-07 -6.897 -6.979 -0.083 - CaHSO4+ 7.691e-09 6.359e-09 -8.114 -8.197 -0.083 + OH- 2.950e-07 2.416e-07 -6.530 -6.617 -0.087 (0) + H+ 1.674e-07 1.435e-07 -6.776 -6.843 -0.067 0.00 + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.18 +Ca 1.616e-02 + Ca+2 1.039e-02 5.042e-03 -1.983 -2.297 -0.314 -17.46 + CaSO4 5.772e-03 5.827e-03 -2.239 -2.235 0.004 (0) + CaHSO4+ 7.691e-09 6.359e-09 -8.114 -8.197 -0.083 (0) + CaOH+ 7.048e-09 5.827e-09 -8.152 -8.235 -0.083 (0) +H(0) 2.395e-36 + H2 1.197e-36 1.209e-36 -35.922 -35.918 0.004 (0) +O(0) 1.698e-15 + O2 8.491e-16 8.572e-16 -15.071 -15.067 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -108.698 -108.785 -0.087 (0) + H2S 0.000e+00 0.000e+00 -108.887 -108.883 0.004 (0) + S-2 0.000e+00 0.000e+00 -114.034 -114.355 -0.321 (0) +S(6) 1.616e-02 + SO4-2 1.039e-02 4.944e-03 -1.983 -2.306 -0.323 14.43 + CaSO4 5.772e-03 5.827e-03 -2.239 -2.235 0.004 (0) + HSO4- 1.269e-07 1.049e-07 -6.897 -6.979 -0.083 (0) + CaHSO4+ 7.691e-09 6.359e-09 -8.114 -8.197 -0.083 (0) ------------------------------Saturation indices------------------------------- @@ -1671,30 +1671,30 @@ Gypsum -0.00 -4.61 -4.61 1.000e+00 1.984e+00 9.844e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 3.062e-07 2.506e-07 -6.514 -6.601 -0.087 - H+ 1.718e-07 1.473e-07 -6.765 -6.832 -0.067 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -Ca 1.617e-02 - Ca+2 1.038e-02 5.028e-03 -1.984 -2.299 -0.315 - CaSO4 5.790e-03 5.845e-03 -2.237 -2.233 0.004 - CaHSO4+ 8.049e-09 6.653e-09 -8.094 -8.177 -0.083 - CaOH+ 6.853e-09 5.665e-09 -8.164 -8.247 -0.083 -H(0) 3.322e-36 - H2 1.661e-36 1.677e-36 -35.780 -35.775 0.004 -O(0) 1.705e-15 - O2 8.527e-16 8.609e-16 -15.069 -15.065 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -108.235 -108.322 -0.087 - H2S 0.000e+00 0.000e+00 -108.422 -108.418 0.004 - S-2 0.000e+00 0.000e+00 -113.555 -113.877 -0.321 -S(6) 1.617e-02 - SO4-2 1.038e-02 4.931e-03 -1.984 -2.307 -0.323 - CaSO4 5.790e-03 5.845e-03 -2.237 -2.233 0.004 - HSO4- 1.331e-07 1.100e-07 -6.876 -6.958 -0.083 - CaHSO4+ 8.049e-09 6.653e-09 -8.094 -8.177 -0.083 + OH- 3.062e-07 2.506e-07 -6.514 -6.601 -0.087 (0) + H+ 1.718e-07 1.473e-07 -6.765 -6.832 -0.067 0.00 + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.19 +Ca 1.617e-02 + Ca+2 1.038e-02 5.028e-03 -1.984 -2.299 -0.315 -17.47 + CaSO4 5.790e-03 5.845e-03 -2.237 -2.233 0.004 (0) + CaHSO4+ 8.049e-09 6.653e-09 -8.094 -8.177 -0.083 (0) + CaOH+ 6.853e-09 5.665e-09 -8.164 -8.247 -0.083 (0) +H(0) 3.322e-36 + H2 1.661e-36 1.677e-36 -35.780 -35.775 0.004 (0) +O(0) 1.705e-15 + O2 8.527e-16 8.609e-16 -15.069 -15.065 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -108.235 -108.322 -0.087 (0) + H2S 0.000e+00 0.000e+00 -108.422 -108.418 0.004 (0) + S-2 0.000e+00 0.000e+00 -113.555 -113.877 -0.321 (0) +S(6) 1.617e-02 + SO4-2 1.038e-02 4.931e-03 -1.984 -2.307 -0.323 14.38 + CaSO4 5.790e-03 5.845e-03 -2.237 -2.233 0.004 (0) + HSO4- 1.331e-07 1.100e-07 -6.876 -6.958 -0.083 (0) + CaHSO4+ 8.049e-09 6.653e-09 -8.094 -8.177 -0.083 (0) ------------------------------Saturation indices------------------------------- @@ -1751,30 +1751,30 @@ Gypsum 0.00 -4.61 -4.61 1.000e+00 1.984e+00 9.844e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 3.177e-07 2.600e-07 -6.498 -6.585 -0.087 - H+ 1.762e-07 1.510e-07 -6.754 -6.821 -0.067 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -Ca 1.616e-02 - Ca+2 1.036e-02 5.015e-03 -1.985 -2.300 -0.315 - CaSO4 5.806e-03 5.862e-03 -2.236 -2.232 0.004 - CaHSO4+ 8.419e-09 6.957e-09 -8.075 -8.158 -0.083 - CaOH+ 6.666e-09 5.508e-09 -8.176 -8.259 -0.083 -H(0) 4.653e-36 - H2 2.327e-36 2.349e-36 -35.633 -35.629 0.004 -O(0) 1.673e-15 - O2 8.366e-16 8.446e-16 -15.078 -15.073 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -107.755 -107.842 -0.087 - H2S 0.000e+00 0.000e+00 -107.939 -107.935 0.004 - S-2 0.000e+00 0.000e+00 -113.060 -113.381 -0.322 -S(6) 1.616e-02 - SO4-2 1.036e-02 4.918e-03 -1.985 -2.308 -0.323 - CaSO4 5.806e-03 5.862e-03 -2.236 -2.232 0.004 - HSO4- 1.396e-07 1.154e-07 -6.855 -6.938 -0.083 - CaHSO4+ 8.419e-09 6.957e-09 -8.075 -8.158 -0.083 + OH- 3.177e-07 2.600e-07 -6.498 -6.585 -0.087 (0) + H+ 1.762e-07 1.510e-07 -6.754 -6.821 -0.067 0.00 + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.19 +Ca 1.616e-02 + Ca+2 1.036e-02 5.015e-03 -1.985 -2.300 -0.315 -17.47 + CaSO4 5.806e-03 5.862e-03 -2.236 -2.232 0.004 (0) + CaHSO4+ 8.419e-09 6.957e-09 -8.075 -8.158 -0.083 (0) + CaOH+ 6.666e-09 5.508e-09 -8.176 -8.259 -0.083 (0) +H(0) 4.653e-36 + H2 2.327e-36 2.349e-36 -35.633 -35.629 0.004 (0) +O(0) 1.673e-15 + O2 8.366e-16 8.446e-16 -15.078 -15.073 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -107.755 -107.842 -0.087 (0) + H2S 0.000e+00 0.000e+00 -107.939 -107.935 0.004 (0) + S-2 0.000e+00 0.000e+00 -113.060 -113.381 -0.322 (0) +S(6) 1.616e-02 + SO4-2 1.036e-02 4.918e-03 -1.985 -2.308 -0.323 14.33 + CaSO4 5.806e-03 5.862e-03 -2.236 -2.232 0.004 (0) + HSO4- 1.396e-07 1.154e-07 -6.855 -6.938 -0.083 (0) + CaHSO4+ 8.419e-09 6.957e-09 -8.075 -8.158 -0.083 (0) ------------------------------Saturation indices------------------------------- @@ -1831,30 +1831,30 @@ Gypsum 0.00 -4.61 -4.61 1.000e+00 1.984e+00 9.844e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 3.296e-07 2.696e-07 -6.482 -6.569 -0.087 - H+ 1.807e-07 1.549e-07 -6.743 -6.810 -0.067 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -Ca 1.616e-02 - Ca+2 1.034e-02 5.001e-03 -1.986 -2.301 -0.315 - CaSO4 5.821e-03 5.877e-03 -2.235 -2.231 0.004 - CaHSO4+ 8.804e-09 7.273e-09 -8.055 -8.138 -0.083 - CaOH+ 6.484e-09 5.357e-09 -8.188 -8.271 -0.083 -H(0) 6.455e-36 - H2 3.227e-36 3.258e-36 -35.491 -35.487 0.004 -O(0) 1.667e-15 - O2 8.333e-16 8.412e-16 -15.079 -15.075 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -107.291 -107.378 -0.087 - H2S 0.000e+00 0.000e+00 -107.473 -107.469 0.004 - S-2 0.000e+00 0.000e+00 -112.580 -112.902 -0.322 -S(6) 1.616e-02 - SO4-2 1.034e-02 4.904e-03 -1.986 -2.309 -0.324 - CaSO4 5.821e-03 5.877e-03 -2.235 -2.231 0.004 - HSO4- 1.464e-07 1.210e-07 -6.834 -6.917 -0.083 - CaHSO4+ 8.804e-09 7.273e-09 -8.055 -8.138 -0.083 + OH- 3.296e-07 2.696e-07 -6.482 -6.569 -0.087 (0) + H+ 1.807e-07 1.549e-07 -6.743 -6.810 -0.067 0.00 + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.20 +Ca 1.616e-02 + Ca+2 1.034e-02 5.001e-03 -1.986 -2.301 -0.315 -17.48 + CaSO4 5.821e-03 5.877e-03 -2.235 -2.231 0.004 (0) + CaHSO4+ 8.804e-09 7.273e-09 -8.055 -8.138 -0.083 (0) + CaOH+ 6.484e-09 5.357e-09 -8.188 -8.271 -0.083 (0) +H(0) 6.455e-36 + H2 3.227e-36 3.258e-36 -35.491 -35.487 0.004 (0) +O(0) 1.667e-15 + O2 8.333e-16 8.412e-16 -15.079 -15.075 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -107.291 -107.378 -0.087 (0) + H2S 0.000e+00 0.000e+00 -107.473 -107.469 0.004 (0) + S-2 0.000e+00 0.000e+00 -112.580 -112.902 -0.322 (0) +S(6) 1.616e-02 + SO4-2 1.034e-02 4.904e-03 -1.986 -2.309 -0.324 14.27 + CaSO4 5.821e-03 5.877e-03 -2.235 -2.231 0.004 (0) + HSO4- 1.464e-07 1.210e-07 -6.834 -6.917 -0.083 (0) + CaHSO4+ 8.804e-09 7.273e-09 -8.055 -8.138 -0.083 (0) ------------------------------Saturation indices------------------------------- @@ -1911,30 +1911,30 @@ Gypsum -0.00 -4.61 -4.61 1.000e+00 1.984e+00 9.844e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 3.417e-07 2.795e-07 -6.466 -6.554 -0.087 - H+ 1.852e-07 1.587e-07 -6.732 -6.799 -0.067 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.615e-02 - Ca+2 1.032e-02 4.986e-03 -1.986 -2.302 -0.316 - CaSO4 5.835e-03 5.891e-03 -2.234 -2.230 0.004 - CaHSO4+ 9.202e-09 7.600e-09 -8.036 -8.119 -0.083 - CaOH+ 6.310e-09 5.211e-09 -8.200 -8.283 -0.083 -H(0) 8.901e-36 - H2 4.450e-36 4.493e-36 -35.352 -35.347 0.004 -O(0) 1.673e-15 - O2 8.366e-16 8.445e-16 -15.078 -15.073 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -106.837 -106.924 -0.087 - H2S 0.000e+00 0.000e+00 -107.017 -107.013 0.004 - S-2 0.000e+00 0.000e+00 -112.111 -112.433 -0.323 -S(6) 1.615e-02 - SO4-2 1.032e-02 4.890e-03 -1.986 -2.311 -0.324 - CaSO4 5.835e-03 5.891e-03 -2.234 -2.230 0.004 - HSO4- 1.535e-07 1.268e-07 -6.814 -6.897 -0.083 - CaHSO4+ 9.202e-09 7.600e-09 -8.036 -8.119 -0.083 + OH- 3.417e-07 2.795e-07 -6.466 -6.554 -0.087 (0) + H+ 1.852e-07 1.587e-07 -6.732 -6.799 -0.067 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.21 +Ca 1.615e-02 + Ca+2 1.032e-02 4.986e-03 -1.986 -2.302 -0.316 -17.49 + CaSO4 5.835e-03 5.891e-03 -2.234 -2.230 0.004 (0) + CaHSO4+ 9.202e-09 7.600e-09 -8.036 -8.119 -0.083 (0) + CaOH+ 6.310e-09 5.211e-09 -8.200 -8.283 -0.083 (0) +H(0) 8.901e-36 + H2 4.450e-36 4.493e-36 -35.352 -35.347 0.004 (0) +O(0) 1.673e-15 + O2 8.366e-16 8.445e-16 -15.078 -15.073 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -106.837 -106.924 -0.087 (0) + H2S 0.000e+00 0.000e+00 -107.017 -107.013 0.004 (0) + S-2 0.000e+00 0.000e+00 -112.111 -112.433 -0.323 (0) +S(6) 1.615e-02 + SO4-2 1.032e-02 4.890e-03 -1.986 -2.311 -0.324 14.20 + CaSO4 5.835e-03 5.891e-03 -2.234 -2.230 0.004 (0) + HSO4- 1.535e-07 1.268e-07 -6.814 -6.897 -0.083 (0) + CaHSO4+ 9.202e-09 7.600e-09 -8.036 -8.119 -0.083 (0) ------------------------------Saturation indices------------------------------- @@ -1991,30 +1991,30 @@ Gypsum -0.00 -4.62 -4.62 1.000e+00 1.984e+00 9.844e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 3.543e-07 2.897e-07 -6.451 -6.538 -0.087 - H+ 1.898e-07 1.626e-07 -6.722 -6.789 -0.067 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.614e-02 - Ca+2 1.029e-02 4.971e-03 -1.987 -2.304 -0.316 - CaSO4 5.847e-03 5.903e-03 -2.233 -2.229 0.004 - CaHSO4+ 9.614e-09 7.938e-09 -8.017 -8.100 -0.083 - CaOH+ 6.141e-09 5.070e-09 -8.212 -8.295 -0.083 -H(0) 1.228e-35 - H2 6.140e-36 6.199e-36 -35.212 -35.208 0.004 -O(0) 1.671e-15 - O2 8.355e-16 8.435e-16 -15.078 -15.074 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -106.381 -106.468 -0.087 - H2S 0.000e+00 0.000e+00 -106.559 -106.554 0.004 - S-2 0.000e+00 0.000e+00 -111.640 -111.963 -0.323 -S(6) 1.614e-02 - SO4-2 1.029e-02 4.875e-03 -1.987 -2.312 -0.325 - CaSO4 5.847e-03 5.903e-03 -2.233 -2.229 0.004 - HSO4- 1.609e-07 1.328e-07 -6.794 -6.877 -0.083 - CaHSO4+ 9.614e-09 7.938e-09 -8.017 -8.100 -0.083 + OH- 3.543e-07 2.897e-07 -6.451 -6.538 -0.087 (0) + H+ 1.898e-07 1.626e-07 -6.722 -6.789 -0.067 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.22 +Ca 1.614e-02 + Ca+2 1.029e-02 4.971e-03 -1.987 -2.304 -0.316 -17.50 + CaSO4 5.847e-03 5.903e-03 -2.233 -2.229 0.004 (0) + CaHSO4+ 9.614e-09 7.938e-09 -8.017 -8.100 -0.083 (0) + CaOH+ 6.141e-09 5.070e-09 -8.212 -8.295 -0.083 (0) +H(0) 1.228e-35 + H2 6.140e-36 6.199e-36 -35.212 -35.208 0.004 (0) +O(0) 1.671e-15 + O2 8.355e-16 8.435e-16 -15.078 -15.074 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -106.381 -106.468 -0.087 (0) + H2S 0.000e+00 0.000e+00 -106.559 -106.554 0.004 (0) + S-2 0.000e+00 0.000e+00 -111.640 -111.963 -0.323 (0) +S(6) 1.614e-02 + SO4-2 1.029e-02 4.875e-03 -1.987 -2.312 -0.325 14.12 + CaSO4 5.847e-03 5.903e-03 -2.233 -2.229 0.004 (0) + HSO4- 1.609e-07 1.328e-07 -6.794 -6.877 -0.083 (0) + CaHSO4+ 9.614e-09 7.938e-09 -8.017 -8.100 -0.083 (0) ------------------------------Saturation indices------------------------------- @@ -2071,30 +2071,30 @@ Gypsum 0.00 -4.62 -4.62 1.000e+00 1.984e+00 9.844e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 3.672e-07 3.002e-07 -6.435 -6.523 -0.087 - H+ 1.945e-07 1.666e-07 -6.711 -6.778 -0.067 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.613e-02 - Ca+2 1.027e-02 4.956e-03 -1.988 -2.305 -0.317 - CaSO4 5.858e-03 5.914e-03 -2.232 -2.228 0.004 - CaHSO4+ 1.004e-08 8.288e-09 -7.998 -8.082 -0.083 - CaOH+ 5.978e-09 4.935e-09 -8.223 -8.307 -0.083 -H(0) 1.686e-35 - H2 8.432e-36 8.512e-36 -35.074 -35.070 0.004 -O(0) 1.678e-15 - O2 8.391e-16 8.471e-16 -15.076 -15.072 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -105.933 -106.021 -0.087 - H2S 0.000e+00 0.000e+00 -106.108 -106.104 0.004 - S-2 0.000e+00 0.000e+00 -111.176 -111.500 -0.323 -S(6) 1.613e-02 - SO4-2 1.027e-02 4.860e-03 -1.988 -2.313 -0.325 - CaSO4 5.858e-03 5.914e-03 -2.232 -2.228 0.004 - HSO4- 1.685e-07 1.391e-07 -6.773 -6.857 -0.083 - CaHSO4+ 1.004e-08 8.288e-09 -7.998 -8.082 -0.083 + OH- 3.672e-07 3.002e-07 -6.435 -6.523 -0.087 (0) + H+ 1.945e-07 1.666e-07 -6.711 -6.778 -0.067 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.23 +Ca 1.613e-02 + Ca+2 1.027e-02 4.956e-03 -1.988 -2.305 -0.317 -17.52 + CaSO4 5.858e-03 5.914e-03 -2.232 -2.228 0.004 (0) + CaHSO4+ 1.004e-08 8.288e-09 -7.998 -8.082 -0.083 (0) + CaOH+ 5.978e-09 4.935e-09 -8.223 -8.307 -0.083 (0) +H(0) 1.686e-35 + H2 8.432e-36 8.512e-36 -35.074 -35.070 0.004 (0) +O(0) 1.678e-15 + O2 8.391e-16 8.471e-16 -15.076 -15.072 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -105.933 -106.021 -0.087 (0) + H2S 0.000e+00 0.000e+00 -106.108 -106.104 0.004 (0) + S-2 0.000e+00 0.000e+00 -111.176 -111.500 -0.323 (0) +S(6) 1.613e-02 + SO4-2 1.027e-02 4.860e-03 -1.988 -2.313 -0.325 14.03 + CaSO4 5.858e-03 5.914e-03 -2.232 -2.228 0.004 (0) + HSO4- 1.685e-07 1.391e-07 -6.773 -6.857 -0.083 (0) + CaHSO4+ 1.004e-08 8.288e-09 -7.998 -8.082 -0.083 (0) ------------------------------Saturation indices------------------------------- @@ -2151,30 +2151,30 @@ Gypsum 0.00 -4.62 -4.62 1.000e+00 1.984e+00 9.845e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 3.805e-07 3.110e-07 -6.420 -6.507 -0.088 - H+ 1.992e-07 1.706e-07 -6.701 -6.768 -0.067 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.611e-02 - Ca+2 1.025e-02 4.940e-03 -1.989 -2.306 -0.317 - CaSO4 5.867e-03 5.923e-03 -2.232 -2.227 0.004 - CaHSO4+ 1.048e-08 8.650e-09 -7.980 -8.063 -0.083 - CaOH+ 5.820e-09 4.804e-09 -8.235 -8.318 -0.083 -H(0) 2.315e-35 - H2 1.158e-35 1.169e-35 -34.936 -34.932 0.004 -O(0) 1.680e-15 - O2 8.398e-16 8.478e-16 -15.076 -15.072 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -105.485 -105.573 -0.088 - H2S 0.000e+00 0.000e+00 -105.658 -105.654 0.004 - S-2 0.000e+00 0.000e+00 -110.713 -111.037 -0.324 -S(6) 1.611e-02 - SO4-2 1.025e-02 4.845e-03 -1.989 -2.315 -0.325 - CaSO4 5.867e-03 5.923e-03 -2.232 -2.227 0.004 - HSO4- 1.765e-07 1.457e-07 -6.753 -6.837 -0.083 - CaHSO4+ 1.048e-08 8.650e-09 -7.980 -8.063 -0.083 + OH- 3.805e-07 3.110e-07 -6.420 -6.507 -0.088 (0) + H+ 1.992e-07 1.706e-07 -6.701 -6.768 -0.067 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.23 +Ca 1.611e-02 + Ca+2 1.025e-02 4.940e-03 -1.989 -2.306 -0.317 -17.54 + CaSO4 5.867e-03 5.923e-03 -2.232 -2.227 0.004 (0) + CaHSO4+ 1.048e-08 8.650e-09 -7.980 -8.063 -0.083 (0) + CaOH+ 5.820e-09 4.804e-09 -8.235 -8.318 -0.083 (0) +H(0) 2.315e-35 + H2 1.158e-35 1.169e-35 -34.936 -34.932 0.004 (0) +O(0) 1.680e-15 + O2 8.398e-16 8.478e-16 -15.076 -15.072 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -105.485 -105.573 -0.088 (0) + H2S 0.000e+00 0.000e+00 -105.658 -105.654 0.004 (0) + S-2 0.000e+00 0.000e+00 -110.713 -111.037 -0.324 (0) +S(6) 1.611e-02 + SO4-2 1.025e-02 4.845e-03 -1.989 -2.315 -0.325 13.94 + CaSO4 5.867e-03 5.923e-03 -2.232 -2.227 0.004 (0) + HSO4- 1.765e-07 1.457e-07 -6.753 -6.837 -0.083 (0) + CaHSO4+ 1.048e-08 8.650e-09 -7.980 -8.063 -0.083 (0) ------------------------------Saturation indices------------------------------- @@ -2231,30 +2231,30 @@ Gypsum -0.00 -4.62 -4.62 1.000e+00 1.984e+00 9.845e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 3.941e-07 3.221e-07 -6.404 -6.492 -0.088 - H+ 2.039e-07 1.746e-07 -6.691 -6.758 -0.067 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.609e-02 - Ca+2 1.022e-02 4.923e-03 -1.991 -2.308 -0.317 - CaSO4 5.875e-03 5.930e-03 -2.231 -2.227 0.004 - CaHSO4+ 1.094e-08 9.025e-09 -7.961 -8.045 -0.083 - CaOH+ 5.668e-09 4.677e-09 -8.247 -8.330 -0.083 -H(0) 3.208e-35 - H2 1.604e-35 1.619e-35 -34.795 -34.791 0.004 -O(0) 1.644e-15 - O2 8.219e-16 8.297e-16 -15.085 -15.081 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -105.021 -105.108 -0.088 - H2S 0.000e+00 0.000e+00 -105.191 -105.186 0.004 - S-2 0.000e+00 0.000e+00 -110.233 -110.557 -0.324 -S(6) 1.609e-02 - SO4-2 1.022e-02 4.829e-03 -1.991 -2.316 -0.326 - CaSO4 5.875e-03 5.930e-03 -2.231 -2.227 0.004 - HSO4- 1.848e-07 1.525e-07 -6.733 -6.817 -0.083 - CaHSO4+ 1.094e-08 9.025e-09 -7.961 -8.045 -0.083 + OH- 3.941e-07 3.221e-07 -6.404 -6.492 -0.088 (0) + H+ 2.039e-07 1.746e-07 -6.691 -6.758 -0.067 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.24 +Ca 1.609e-02 + Ca+2 1.022e-02 4.923e-03 -1.991 -2.308 -0.317 -17.56 + CaSO4 5.875e-03 5.930e-03 -2.231 -2.227 0.004 (0) + CaHSO4+ 1.094e-08 9.025e-09 -7.961 -8.045 -0.083 (0) + CaOH+ 5.668e-09 4.677e-09 -8.247 -8.330 -0.083 (0) +H(0) 3.208e-35 + H2 1.604e-35 1.619e-35 -34.795 -34.791 0.004 (0) +O(0) 1.644e-15 + O2 8.219e-16 8.297e-16 -15.085 -15.081 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -105.021 -105.108 -0.088 (0) + H2S 0.000e+00 0.000e+00 -105.191 -105.186 0.004 (0) + S-2 0.000e+00 0.000e+00 -110.233 -110.557 -0.324 (0) +S(6) 1.609e-02 + SO4-2 1.022e-02 4.829e-03 -1.991 -2.316 -0.326 13.84 + CaSO4 5.875e-03 5.930e-03 -2.231 -2.227 0.004 (0) + HSO4- 1.848e-07 1.525e-07 -6.733 -6.817 -0.083 (0) + CaHSO4+ 1.094e-08 9.025e-09 -7.961 -8.045 -0.083 (0) ------------------------------Saturation indices------------------------------- @@ -2311,30 +2311,30 @@ Gypsum 0.00 -4.63 -4.63 1.000e+00 1.984e+00 9.845e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 4.081e-07 3.335e-07 -6.389 -6.477 -0.088 - H+ 2.087e-07 1.787e-07 -6.680 -6.748 -0.067 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.607e-02 - Ca+2 1.019e-02 4.906e-03 -1.992 -2.309 -0.318 - CaSO4 5.881e-03 5.937e-03 -2.231 -2.226 0.004 - CaHSO4+ 1.141e-08 9.411e-09 -7.943 -8.026 -0.084 - CaOH+ 5.521e-09 4.555e-09 -8.258 -8.342 -0.084 -H(0) 4.345e-35 - H2 2.172e-35 2.193e-35 -34.663 -34.659 0.004 -O(0) 1.677e-15 - O2 8.386e-16 8.465e-16 -15.076 -15.072 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -104.595 -104.683 -0.088 - H2S 0.000e+00 0.000e+00 -104.762 -104.758 0.004 - S-2 0.000e+00 0.000e+00 -109.792 -110.117 -0.324 -S(6) 1.607e-02 - SO4-2 1.019e-02 4.813e-03 -1.992 -2.318 -0.326 - CaSO4 5.881e-03 5.937e-03 -2.231 -2.226 0.004 - HSO4- 1.934e-07 1.596e-07 -6.714 -6.797 -0.084 - CaHSO4+ 1.141e-08 9.411e-09 -7.943 -8.026 -0.084 + OH- 4.081e-07 3.335e-07 -6.389 -6.477 -0.088 (0) + H+ 2.087e-07 1.787e-07 -6.680 -6.748 -0.067 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.25 +Ca 1.607e-02 + Ca+2 1.019e-02 4.906e-03 -1.992 -2.309 -0.318 -17.58 + CaSO4 5.881e-03 5.937e-03 -2.231 -2.226 0.004 (0) + CaHSO4+ 1.141e-08 9.411e-09 -7.943 -8.026 -0.084 (0) + CaOH+ 5.521e-09 4.555e-09 -8.258 -8.342 -0.084 (0) +H(0) 4.345e-35 + H2 2.172e-35 2.193e-35 -34.663 -34.659 0.004 (0) +O(0) 1.677e-15 + O2 8.386e-16 8.465e-16 -15.076 -15.072 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -104.595 -104.683 -0.088 (0) + H2S 0.000e+00 0.000e+00 -104.762 -104.758 0.004 (0) + S-2 0.000e+00 0.000e+00 -109.792 -110.117 -0.324 (0) +S(6) 1.607e-02 + SO4-2 1.019e-02 4.813e-03 -1.992 -2.318 -0.326 13.73 + CaSO4 5.881e-03 5.937e-03 -2.231 -2.226 0.004 (0) + HSO4- 1.934e-07 1.596e-07 -6.714 -6.797 -0.084 (0) + CaHSO4+ 1.141e-08 9.411e-09 -7.943 -8.026 -0.084 (0) ------------------------------Saturation indices------------------------------- @@ -2391,30 +2391,30 @@ Gypsum -0.00 -4.63 -4.63 1.000e+00 1.985e+00 9.845e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 4.225e-07 3.452e-07 -6.374 -6.462 -0.088 - H+ 2.136e-07 1.828e-07 -6.670 -6.738 -0.068 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.605e-02 - Ca+2 1.016e-02 4.889e-03 -1.993 -2.311 -0.318 - CaSO4 5.886e-03 5.942e-03 -2.230 -2.226 0.004 - CaHSO4+ 1.189e-08 9.811e-09 -7.925 -8.008 -0.084 - CaOH+ 5.379e-09 4.437e-09 -8.269 -8.353 -0.084 -H(0) 5.951e-35 - H2 2.975e-35 3.003e-35 -34.526 -34.522 0.004 -O(0) 1.667e-15 - O2 8.334e-16 8.412e-16 -15.079 -15.075 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -104.150 -104.238 -0.088 - H2S 0.000e+00 0.000e+00 -104.314 -104.310 0.004 - S-2 0.000e+00 0.000e+00 -109.332 -109.656 -0.325 -S(6) 1.605e-02 - SO4-2 1.016e-02 4.796e-03 -1.993 -2.319 -0.326 - CaSO4 5.886e-03 5.942e-03 -2.230 -2.226 0.004 - HSO4- 2.024e-07 1.669e-07 -6.694 -6.778 -0.084 - CaHSO4+ 1.189e-08 9.811e-09 -7.925 -8.008 -0.084 + OH- 4.225e-07 3.452e-07 -6.374 -6.462 -0.088 (0) + H+ 2.136e-07 1.828e-07 -6.670 -6.738 -0.068 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.26 +Ca 1.605e-02 + Ca+2 1.016e-02 4.889e-03 -1.993 -2.311 -0.318 -17.61 + CaSO4 5.886e-03 5.942e-03 -2.230 -2.226 0.004 (0) + CaHSO4+ 1.189e-08 9.811e-09 -7.925 -8.008 -0.084 (0) + CaOH+ 5.379e-09 4.437e-09 -8.269 -8.353 -0.084 (0) +H(0) 5.951e-35 + H2 2.975e-35 3.003e-35 -34.526 -34.522 0.004 (0) +O(0) 1.667e-15 + O2 8.334e-16 8.412e-16 -15.079 -15.075 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -104.150 -104.238 -0.088 (0) + H2S 0.000e+00 0.000e+00 -104.314 -104.310 0.004 (0) + S-2 0.000e+00 0.000e+00 -109.332 -109.656 -0.325 (0) +S(6) 1.605e-02 + SO4-2 1.016e-02 4.796e-03 -1.993 -2.319 -0.326 13.62 + CaSO4 5.886e-03 5.942e-03 -2.230 -2.226 0.004 (0) + HSO4- 2.024e-07 1.669e-07 -6.694 -6.778 -0.084 (0) + CaHSO4+ 1.189e-08 9.811e-09 -7.925 -8.008 -0.084 (0) ------------------------------Saturation indices------------------------------- @@ -2471,30 +2471,30 @@ Gypsum -0.00 -4.63 -4.63 1.000e+00 1.985e+00 9.845e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 4.374e-07 3.573e-07 -6.359 -6.447 -0.088 - H+ 2.184e-07 1.869e-07 -6.661 -6.728 -0.068 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.602e-02 - Ca+2 1.013e-02 4.871e-03 -1.994 -2.312 -0.318 - CaSO4 5.890e-03 5.945e-03 -2.230 -2.226 0.004 - CaHSO4+ 1.240e-08 1.022e-08 -7.907 -7.990 -0.084 - CaOH+ 5.242e-09 4.323e-09 -8.280 -8.364 -0.084 -H(0) 8.136e-35 - H2 4.068e-35 4.106e-35 -34.391 -34.387 0.004 -O(0) 1.656e-15 - O2 8.282e-16 8.359e-16 -15.082 -15.078 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -103.707 -103.795 -0.088 - H2S 0.000e+00 0.000e+00 -103.869 -103.865 0.004 - S-2 0.000e+00 0.000e+00 -108.874 -109.198 -0.325 -S(6) 1.602e-02 - SO4-2 1.013e-02 4.779e-03 -1.994 -2.321 -0.327 - CaSO4 5.890e-03 5.945e-03 -2.230 -2.226 0.004 - HSO4- 2.117e-07 1.746e-07 -6.674 -6.758 -0.084 - CaHSO4+ 1.240e-08 1.022e-08 -7.907 -7.990 -0.084 + OH- 4.374e-07 3.573e-07 -6.359 -6.447 -0.088 (0) + H+ 2.184e-07 1.869e-07 -6.661 -6.728 -0.068 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.27 +Ca 1.602e-02 + Ca+2 1.013e-02 4.871e-03 -1.994 -2.312 -0.318 -17.64 + CaSO4 5.890e-03 5.945e-03 -2.230 -2.226 0.004 (0) + CaHSO4+ 1.240e-08 1.022e-08 -7.907 -7.990 -0.084 (0) + CaOH+ 5.242e-09 4.323e-09 -8.280 -8.364 -0.084 (0) +H(0) 8.136e-35 + H2 4.068e-35 4.106e-35 -34.391 -34.387 0.004 (0) +O(0) 1.656e-15 + O2 8.282e-16 8.359e-16 -15.082 -15.078 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -103.707 -103.795 -0.088 (0) + H2S 0.000e+00 0.000e+00 -103.869 -103.865 0.004 (0) + S-2 0.000e+00 0.000e+00 -108.874 -109.198 -0.325 (0) +S(6) 1.602e-02 + SO4-2 1.013e-02 4.779e-03 -1.994 -2.321 -0.327 13.49 + CaSO4 5.890e-03 5.945e-03 -2.230 -2.226 0.004 (0) + HSO4- 2.117e-07 1.746e-07 -6.674 -6.758 -0.084 (0) + CaHSO4+ 1.240e-08 1.022e-08 -7.907 -7.990 -0.084 (0) ------------------------------Saturation indices------------------------------- @@ -2551,30 +2551,30 @@ Gypsum -0.00 -4.64 -4.64 1.000e+00 1.985e+00 9.846e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 4.526e-07 3.697e-07 -6.344 -6.432 -0.088 - H+ 2.233e-07 1.911e-07 -6.651 -6.719 -0.068 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.600e-02 - Ca+2 1.010e-02 4.853e-03 -1.995 -2.314 -0.318 - CaSO4 5.892e-03 5.947e-03 -2.230 -2.226 0.004 - CaHSO4+ 1.292e-08 1.065e-08 -7.889 -7.973 -0.084 - CaOH+ 5.110e-09 4.213e-09 -8.292 -8.375 -0.084 -H(0) 4.744e-35 - H2 2.372e-35 2.394e-35 -34.625 -34.621 0.004 -O(0) 9.014e-15 - O2 4.507e-15 4.549e-15 -14.346 -14.342 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -104.744 -104.832 -0.088 - H2S 0.000e+00 0.000e+00 -104.903 -104.899 0.004 - S-2 0.000e+00 0.000e+00 -109.895 -110.221 -0.325 -S(6) 1.600e-02 - SO4-2 1.010e-02 4.761e-03 -1.995 -2.322 -0.327 - CaSO4 5.892e-03 5.947e-03 -2.230 -2.226 0.004 - HSO4- 2.214e-07 1.825e-07 -6.655 -6.739 -0.084 - CaHSO4+ 1.292e-08 1.065e-08 -7.889 -7.973 -0.084 + OH- 4.526e-07 3.697e-07 -6.344 -6.432 -0.088 (0) + H+ 2.233e-07 1.911e-07 -6.651 -6.719 -0.068 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.28 +Ca 1.600e-02 + Ca+2 1.010e-02 4.853e-03 -1.995 -2.314 -0.318 -17.67 + CaSO4 5.892e-03 5.947e-03 -2.230 -2.226 0.004 (0) + CaHSO4+ 1.292e-08 1.065e-08 -7.889 -7.973 -0.084 (0) + CaOH+ 5.110e-09 4.213e-09 -8.292 -8.375 -0.084 (0) +H(0) 4.744e-35 + H2 2.372e-35 2.394e-35 -34.625 -34.621 0.004 (0) +O(0) 9.014e-15 + O2 4.507e-15 4.549e-15 -14.346 -14.342 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -104.744 -104.832 -0.088 (0) + H2S 0.000e+00 0.000e+00 -104.903 -104.899 0.004 (0) + S-2 0.000e+00 0.000e+00 -109.895 -110.221 -0.325 (0) +S(6) 1.600e-02 + SO4-2 1.010e-02 4.761e-03 -1.995 -2.322 -0.327 13.36 + CaSO4 5.892e-03 5.947e-03 -2.230 -2.226 0.004 (0) + HSO4- 2.214e-07 1.825e-07 -6.655 -6.739 -0.084 (0) + CaHSO4+ 1.292e-08 1.065e-08 -7.889 -7.973 -0.084 (0) ------------------------------Saturation indices------------------------------- @@ -2631,30 +2631,30 @@ Gypsum 0.00 -4.64 -4.64 1.000e+00 1.985e+00 9.846e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 4.683e-07 3.824e-07 -6.330 -6.417 -0.088 - H+ 2.283e-07 1.953e-07 -6.642 -6.709 -0.068 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.597e-02 - Ca+2 1.007e-02 4.835e-03 -1.997 -2.316 -0.319 - CaSO4 5.893e-03 5.948e-03 -2.230 -2.226 0.004 - CaHSO4+ 1.345e-08 1.109e-08 -7.871 -7.955 -0.084 - CaOH+ 4.982e-09 4.106e-09 -8.303 -8.387 -0.084 -H(0) 1.485e-34 - H2 7.427e-35 7.496e-35 -34.129 -34.125 0.004 -O(0) 1.695e-15 - O2 8.474e-16 8.553e-16 -15.072 -15.068 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -102.861 -102.949 -0.088 - H2S 0.000e+00 0.000e+00 -103.017 -103.013 0.004 - S-2 0.000e+00 0.000e+00 -107.997 -108.322 -0.325 -S(6) 1.597e-02 - SO4-2 1.007e-02 4.743e-03 -1.997 -2.324 -0.327 - CaSO4 5.893e-03 5.948e-03 -2.230 -2.226 0.004 - HSO4- 2.314e-07 1.907e-07 -6.636 -6.720 -0.084 - CaHSO4+ 1.345e-08 1.109e-08 -7.871 -7.955 -0.084 + OH- 4.683e-07 3.824e-07 -6.330 -6.417 -0.088 (0) + H+ 2.283e-07 1.953e-07 -6.642 -6.709 -0.068 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.29 +Ca 1.597e-02 + Ca+2 1.007e-02 4.835e-03 -1.997 -2.316 -0.319 -17.70 + CaSO4 5.893e-03 5.948e-03 -2.230 -2.226 0.004 (0) + CaHSO4+ 1.345e-08 1.109e-08 -7.871 -7.955 -0.084 (0) + CaOH+ 4.982e-09 4.106e-09 -8.303 -8.387 -0.084 (0) +H(0) 1.485e-34 + H2 7.427e-35 7.496e-35 -34.129 -34.125 0.004 (0) +O(0) 1.695e-15 + O2 8.474e-16 8.553e-16 -15.072 -15.068 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -102.861 -102.949 -0.088 (0) + H2S 0.000e+00 0.000e+00 -103.017 -103.013 0.004 (0) + S-2 0.000e+00 0.000e+00 -107.997 -108.322 -0.325 (0) +S(6) 1.597e-02 + SO4-2 1.007e-02 4.743e-03 -1.997 -2.324 -0.327 13.22 + CaSO4 5.893e-03 5.948e-03 -2.230 -2.226 0.004 (0) + HSO4- 2.314e-07 1.907e-07 -6.636 -6.720 -0.084 (0) + CaHSO4+ 1.345e-08 1.109e-08 -7.871 -7.955 -0.084 (0) ------------------------------Saturation indices------------------------------- @@ -2711,30 +2711,30 @@ Gypsum -0.00 -4.64 -4.64 1.000e+00 1.985e+00 9.846e-01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 4.844e-07 3.955e-07 -6.315 -6.403 -0.088 - H+ 2.333e-07 1.995e-07 -6.632 -6.700 -0.068 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.593e-02 - Ca+2 1.004e-02 4.816e-03 -1.998 -2.317 -0.319 - CaSO4 5.892e-03 5.947e-03 -2.230 -2.226 0.004 - CaHSO4+ 1.400e-08 1.154e-08 -7.854 -7.938 -0.084 - CaOH+ 4.858e-09 4.004e-09 -8.314 -8.398 -0.084 -H(0) 1.614e-34 - H2 8.072e-35 8.147e-35 -34.093 -34.089 0.004 -O(0) 2.635e-15 - O2 1.318e-15 1.330e-15 -14.880 -14.876 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -102.815 -102.904 -0.088 - H2S 0.000e+00 0.000e+00 -102.968 -102.964 0.004 - S-2 0.000e+00 0.000e+00 -107.936 -108.262 -0.326 -S(6) 1.593e-02 - SO4-2 1.004e-02 4.725e-03 -1.998 -2.326 -0.327 - CaSO4 5.892e-03 5.947e-03 -2.230 -2.226 0.004 - HSO4- 2.418e-07 1.993e-07 -6.616 -6.700 -0.084 - CaHSO4+ 1.400e-08 1.154e-08 -7.854 -7.938 -0.084 + OH- 4.844e-07 3.955e-07 -6.315 -6.403 -0.088 (0) + H+ 2.333e-07 1.995e-07 -6.632 -6.700 -0.068 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.29 +Ca 1.593e-02 + Ca+2 1.004e-02 4.816e-03 -1.998 -2.317 -0.319 -17.74 + CaSO4 5.892e-03 5.947e-03 -2.230 -2.226 0.004 (0) + CaHSO4+ 1.400e-08 1.154e-08 -7.854 -7.938 -0.084 (0) + CaOH+ 4.858e-09 4.004e-09 -8.314 -8.398 -0.084 (0) +H(0) 1.614e-34 + H2 8.072e-35 8.147e-35 -34.093 -34.089 0.004 (0) +O(0) 2.635e-15 + O2 1.318e-15 1.330e-15 -14.880 -14.876 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -102.815 -102.904 -0.088 (0) + H2S 0.000e+00 0.000e+00 -102.968 -102.964 0.004 (0) + S-2 0.000e+00 0.000e+00 -107.936 -108.262 -0.326 (0) +S(6) 1.593e-02 + SO4-2 1.004e-02 4.725e-03 -1.998 -2.326 -0.327 13.08 + CaSO4 5.892e-03 5.947e-03 -2.230 -2.226 0.004 (0) + HSO4- 2.418e-07 1.993e-07 -6.616 -6.700 -0.084 (0) + CaHSO4+ 1.400e-08 1.154e-08 -7.854 -7.938 -0.084 (0) ------------------------------Saturation indices------------------------------- @@ -2791,30 +2791,30 @@ Gypsum -0.00 -4.65 -4.65 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 5.008e-07 4.089e-07 -6.300 -6.388 -0.088 - H+ 2.383e-07 2.038e-07 -6.623 -6.691 -0.068 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.588e-02 - Ca+2 1.000e-02 4.794e-03 -2.000 -2.319 -0.319 - CaSO4 5.884e-03 5.939e-03 -2.230 -2.226 0.004 - CaHSO4+ 1.456e-08 1.200e-08 -7.837 -7.921 -0.084 - CaOH+ 4.735e-09 3.902e-09 -8.325 -8.409 -0.084 -H(0) 2.866e-34 - H2 1.433e-34 1.446e-34 -33.844 -33.840 0.004 -O(0) 1.530e-15 - O2 7.652e-16 7.723e-16 -15.116 -15.112 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -101.917 -102.005 -0.088 - H2S 0.000e+00 0.000e+00 -102.067 -102.063 0.004 - S-2 0.000e+00 0.000e+00 -107.023 -107.349 -0.326 -S(6) 1.588e-02 - SO4-2 9.999e-03 4.704e-03 -2.000 -2.328 -0.327 - CaSO4 5.884e-03 5.939e-03 -2.230 -2.226 0.004 - HSO4- 2.526e-07 2.081e-07 -6.598 -6.682 -0.084 - CaHSO4+ 1.456e-08 1.200e-08 -7.837 -7.921 -0.084 + OH- 5.008e-07 4.089e-07 -6.300 -6.388 -0.088 (0) + H+ 2.383e-07 2.038e-07 -6.623 -6.691 -0.068 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.30 +Ca 1.588e-02 + Ca+2 1.000e-02 4.794e-03 -2.000 -2.319 -0.319 -17.78 + CaSO4 5.884e-03 5.939e-03 -2.230 -2.226 0.004 (0) + CaHSO4+ 1.456e-08 1.200e-08 -7.837 -7.921 -0.084 (0) + CaOH+ 4.735e-09 3.902e-09 -8.325 -8.409 -0.084 (0) +H(0) 2.866e-34 + H2 1.433e-34 1.446e-34 -33.844 -33.840 0.004 (0) +O(0) 1.530e-15 + O2 7.652e-16 7.723e-16 -15.116 -15.112 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -101.917 -102.005 -0.088 (0) + H2S 0.000e+00 0.000e+00 -102.067 -102.063 0.004 (0) + S-2 0.000e+00 0.000e+00 -107.023 -107.349 -0.326 (0) +S(6) 1.588e-02 + SO4-2 9.999e-03 4.704e-03 -2.000 -2.328 -0.327 12.92 + CaSO4 5.884e-03 5.939e-03 -2.230 -2.226 0.004 (0) + HSO4- 2.526e-07 2.081e-07 -6.598 -6.682 -0.084 (0) + CaHSO4+ 1.456e-08 1.200e-08 -7.837 -7.921 -0.084 (0) ------------------------------Saturation indices------------------------------- @@ -2871,30 +2871,30 @@ Gypsum -0.01 -4.66 -4.65 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 5.158e-07 4.215e-07 -6.288 -6.375 -0.088 - H+ 2.438e-07 2.087e-07 -6.613 -6.681 -0.068 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.558e-02 - Ca+2 9.822e-03 4.724e-03 -2.008 -2.326 -0.318 - CaSO4 5.760e-03 5.812e-03 -2.240 -2.236 0.004 - CaHSO4+ 1.485e-08 1.225e-08 -7.828 -7.912 -0.084 - CaOH+ 4.554e-09 3.756e-09 -8.342 -8.425 -0.084 -H(0) 3.826e-34 - H2 1.913e-34 1.930e-34 -33.718 -33.714 0.004 -O(0) 1.567e-15 - O2 7.833e-16 7.905e-16 -15.106 -15.102 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -101.518 -101.606 -0.088 - H2S 0.000e+00 0.000e+00 -101.663 -101.659 0.004 - S-2 0.000e+00 0.000e+00 -106.611 -106.935 -0.324 -S(6) 1.558e-02 - SO4-2 9.822e-03 4.637e-03 -2.008 -2.334 -0.326 - CaSO4 5.760e-03 5.812e-03 -2.240 -2.236 0.004 - HSO4- 2.615e-07 2.157e-07 -6.582 -6.666 -0.084 - CaHSO4+ 1.485e-08 1.225e-08 -7.828 -7.912 -0.084 + OH- 5.158e-07 4.215e-07 -6.288 -6.375 -0.088 (0) + H+ 2.438e-07 2.087e-07 -6.613 -6.681 -0.068 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.31 +Ca 1.558e-02 + Ca+2 9.822e-03 4.724e-03 -2.008 -2.326 -0.318 -17.82 + CaSO4 5.760e-03 5.812e-03 -2.240 -2.236 0.004 (0) + CaHSO4+ 1.485e-08 1.225e-08 -7.828 -7.912 -0.084 (0) + CaOH+ 4.554e-09 3.756e-09 -8.342 -8.425 -0.084 (0) +H(0) 3.826e-34 + H2 1.913e-34 1.930e-34 -33.718 -33.714 0.004 (0) +O(0) 1.567e-15 + O2 7.833e-16 7.905e-16 -15.106 -15.102 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -101.518 -101.606 -0.088 (0) + H2S 0.000e+00 0.000e+00 -101.663 -101.659 0.004 (0) + S-2 0.000e+00 0.000e+00 -106.611 -106.935 -0.324 (0) +S(6) 1.558e-02 + SO4-2 9.822e-03 4.637e-03 -2.008 -2.334 -0.326 12.76 + CaSO4 5.760e-03 5.812e-03 -2.240 -2.236 0.004 (0) + HSO4- 2.615e-07 2.157e-07 -6.582 -6.666 -0.084 (0) + CaHSO4+ 1.485e-08 1.225e-08 -7.828 -7.912 -0.084 (0) ------------------------------Saturation indices------------------------------- @@ -2951,30 +2951,30 @@ Gypsum -0.02 -4.67 -4.65 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 5.310e-07 4.344e-07 -6.275 -6.362 -0.087 - H+ 2.494e-07 2.136e-07 -6.603 -6.670 -0.067 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.528e-02 - Ca+2 9.645e-03 4.654e-03 -2.016 -2.332 -0.316 - CaSO4 5.636e-03 5.686e-03 -2.249 -2.245 0.004 - CaHSO4+ 1.515e-08 1.250e-08 -7.820 -7.903 -0.083 - CaOH+ 4.379e-09 3.615e-09 -8.359 -8.442 -0.083 -H(0) 5.221e-34 - H2 2.611e-34 2.634e-34 -33.583 -33.579 0.004 -O(0) 1.529e-15 - O2 7.643e-16 7.711e-16 -15.117 -15.113 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -101.079 -101.167 -0.087 - H2S 0.000e+00 0.000e+00 -101.220 -101.216 0.004 - S-2 0.000e+00 0.000e+00 -106.160 -106.482 -0.323 -S(6) 1.528e-02 - SO4-2 9.644e-03 4.570e-03 -2.016 -2.340 -0.324 - CaSO4 5.636e-03 5.686e-03 -2.249 -2.245 0.004 - HSO4- 2.707e-07 2.234e-07 -6.568 -6.651 -0.083 - CaHSO4+ 1.515e-08 1.250e-08 -7.820 -7.903 -0.083 + OH- 5.310e-07 4.344e-07 -6.275 -6.362 -0.087 (0) + H+ 2.494e-07 2.136e-07 -6.603 -6.670 -0.067 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.32 +Ca 1.528e-02 + Ca+2 9.645e-03 4.654e-03 -2.016 -2.332 -0.316 -17.86 + CaSO4 5.636e-03 5.686e-03 -2.249 -2.245 0.004 (0) + CaHSO4+ 1.515e-08 1.250e-08 -7.820 -7.903 -0.083 (0) + CaOH+ 4.379e-09 3.615e-09 -8.359 -8.442 -0.083 (0) +H(0) 5.221e-34 + H2 2.611e-34 2.634e-34 -33.583 -33.579 0.004 (0) +O(0) 1.529e-15 + O2 7.643e-16 7.711e-16 -15.117 -15.113 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -101.079 -101.167 -0.087 (0) + H2S 0.000e+00 0.000e+00 -101.220 -101.216 0.004 (0) + S-2 0.000e+00 0.000e+00 -106.160 -106.482 -0.323 (0) +S(6) 1.528e-02 + SO4-2 9.644e-03 4.570e-03 -2.016 -2.340 -0.324 12.59 + CaSO4 5.636e-03 5.686e-03 -2.249 -2.245 0.004 (0) + HSO4- 2.707e-07 2.234e-07 -6.568 -6.651 -0.083 (0) + CaHSO4+ 1.515e-08 1.250e-08 -7.820 -7.903 -0.083 (0) ------------------------------Saturation indices------------------------------- @@ -3031,30 +3031,30 @@ Gypsum -0.03 -4.69 -4.66 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 5.465e-07 4.476e-07 -6.262 -6.349 -0.087 - H+ 2.551e-07 2.186e-07 -6.593 -6.660 -0.067 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.498e-02 - Ca+2 9.468e-03 4.584e-03 -2.024 -2.339 -0.315 - CaSO4 5.511e-03 5.559e-03 -2.259 -2.255 0.004 - CaHSO4+ 1.544e-08 1.275e-08 -7.811 -7.894 -0.083 - CaOH+ 4.211e-09 3.479e-09 -8.376 -8.459 -0.083 -H(0) 6.992e-34 - H2 3.496e-34 3.527e-34 -33.456 -33.453 0.004 -O(0) 1.544e-15 - O2 7.718e-16 7.786e-16 -15.112 -15.109 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -100.674 -100.760 -0.087 - H2S 0.000e+00 0.000e+00 -100.809 -100.805 0.004 - S-2 0.000e+00 0.000e+00 -105.741 -106.062 -0.321 -S(6) 1.498e-02 - SO4-2 9.467e-03 4.503e-03 -2.024 -2.347 -0.323 - CaSO4 5.511e-03 5.559e-03 -2.259 -2.255 0.004 - HSO4- 2.801e-07 2.314e-07 -6.553 -6.636 -0.083 - CaHSO4+ 1.544e-08 1.275e-08 -7.811 -7.894 -0.083 + OH- 5.465e-07 4.476e-07 -6.262 -6.349 -0.087 (0) + H+ 2.551e-07 2.186e-07 -6.593 -6.660 -0.067 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.33 +Ca 1.498e-02 + Ca+2 9.468e-03 4.584e-03 -2.024 -2.339 -0.315 -17.91 + CaSO4 5.511e-03 5.559e-03 -2.259 -2.255 0.004 (0) + CaHSO4+ 1.544e-08 1.275e-08 -7.811 -7.894 -0.083 (0) + CaOH+ 4.211e-09 3.479e-09 -8.376 -8.459 -0.083 (0) +H(0) 6.992e-34 + H2 3.496e-34 3.527e-34 -33.456 -33.453 0.004 (0) +O(0) 1.544e-15 + O2 7.718e-16 7.786e-16 -15.112 -15.109 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -100.674 -100.760 -0.087 (0) + H2S 0.000e+00 0.000e+00 -100.809 -100.805 0.004 (0) + S-2 0.000e+00 0.000e+00 -105.741 -106.062 -0.321 (0) +S(6) 1.498e-02 + SO4-2 9.467e-03 4.503e-03 -2.024 -2.347 -0.323 12.42 + CaSO4 5.511e-03 5.559e-03 -2.259 -2.255 0.004 (0) + HSO4- 2.801e-07 2.314e-07 -6.553 -6.636 -0.083 (0) + CaHSO4+ 1.544e-08 1.275e-08 -7.811 -7.894 -0.083 (0) ------------------------------Saturation indices------------------------------- @@ -3111,30 +3111,30 @@ Gypsum -0.04 -4.70 -4.66 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 5.623e-07 4.611e-07 -6.250 -6.336 -0.086 - H+ 2.608e-07 2.236e-07 -6.584 -6.650 -0.067 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.468e-02 - Ca+2 9.291e-03 4.514e-03 -2.032 -2.345 -0.314 - CaSO4 5.386e-03 5.433e-03 -2.269 -2.265 0.004 - CaHSO4+ 1.572e-08 1.300e-08 -7.803 -7.886 -0.083 - CaOH+ 4.049e-09 3.349e-09 -8.393 -8.475 -0.083 -H(0) 9.449e-34 - H2 4.724e-34 4.765e-34 -33.326 -33.322 0.004 -O(0) 1.525e-15 - O2 7.627e-16 7.693e-16 -15.118 -15.114 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -100.252 -100.338 -0.086 - H2S 0.000e+00 0.000e+00 -100.382 -100.378 0.004 - S-2 0.000e+00 0.000e+00 -105.306 -105.626 -0.320 -S(6) 1.468e-02 - SO4-2 9.291e-03 4.435e-03 -2.032 -2.353 -0.321 - CaSO4 5.386e-03 5.433e-03 -2.269 -2.265 0.004 - HSO4- 2.897e-07 2.396e-07 -6.538 -6.621 -0.083 - CaHSO4+ 1.572e-08 1.300e-08 -7.803 -7.886 -0.083 + OH- 5.623e-07 4.611e-07 -6.250 -6.336 -0.086 (0) + H+ 2.608e-07 2.236e-07 -6.584 -6.650 -0.067 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.34 +Ca 1.468e-02 + Ca+2 9.291e-03 4.514e-03 -2.032 -2.345 -0.314 -17.96 + CaSO4 5.386e-03 5.433e-03 -2.269 -2.265 0.004 (0) + CaHSO4+ 1.572e-08 1.300e-08 -7.803 -7.886 -0.083 (0) + CaOH+ 4.049e-09 3.349e-09 -8.393 -8.475 -0.083 (0) +H(0) 9.449e-34 + H2 4.724e-34 4.765e-34 -33.326 -33.322 0.004 (0) +O(0) 1.525e-15 + O2 7.627e-16 7.693e-16 -15.118 -15.114 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -100.252 -100.338 -0.086 (0) + H2S 0.000e+00 0.000e+00 -100.382 -100.378 0.004 (0) + S-2 0.000e+00 0.000e+00 -105.306 -105.626 -0.320 (0) +S(6) 1.468e-02 + SO4-2 9.291e-03 4.435e-03 -2.032 -2.353 -0.321 12.23 + CaSO4 5.386e-03 5.433e-03 -2.269 -2.265 0.004 (0) + HSO4- 2.897e-07 2.396e-07 -6.538 -6.621 -0.083 (0) + CaHSO4+ 1.572e-08 1.300e-08 -7.803 -7.886 -0.083 (0) ------------------------------Saturation indices------------------------------- @@ -3191,30 +3191,30 @@ Gypsum -0.05 -4.71 -4.67 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 5.784e-07 4.748e-07 -6.238 -6.324 -0.086 - H+ 2.666e-07 2.287e-07 -6.574 -6.641 -0.067 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.438e-02 - Ca+2 9.116e-03 4.444e-03 -2.040 -2.352 -0.312 - CaSO4 5.262e-03 5.307e-03 -2.279 -2.275 0.004 - CaHSO4+ 1.600e-08 1.325e-08 -7.796 -7.878 -0.082 - CaOH+ 3.894e-09 3.223e-09 -8.410 -8.492 -0.082 -H(0) 1.013e-33 - H2 5.064e-34 5.107e-34 -33.295 -33.292 0.004 -O(0) 2.387e-15 - O2 1.194e-15 1.204e-15 -14.923 -14.919 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -100.231 -100.317 -0.086 - H2S 0.000e+00 0.000e+00 -100.356 -100.353 0.004 - S-2 0.000e+00 0.000e+00 -105.274 -105.592 -0.318 -S(6) 1.438e-02 - SO4-2 9.115e-03 4.368e-03 -2.040 -2.360 -0.319 - CaSO4 5.262e-03 5.307e-03 -2.279 -2.275 0.004 - HSO4- 2.995e-07 2.479e-07 -6.524 -6.606 -0.082 - CaHSO4+ 1.600e-08 1.325e-08 -7.796 -7.878 -0.082 + OH- 5.784e-07 4.748e-07 -6.238 -6.324 -0.086 (0) + H+ 2.666e-07 2.287e-07 -6.574 -6.641 -0.067 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.35 +Ca 1.438e-02 + Ca+2 9.116e-03 4.444e-03 -2.040 -2.352 -0.312 -18.01 + CaSO4 5.262e-03 5.307e-03 -2.279 -2.275 0.004 (0) + CaHSO4+ 1.600e-08 1.325e-08 -7.796 -7.878 -0.082 (0) + CaOH+ 3.894e-09 3.223e-09 -8.410 -8.492 -0.082 (0) +H(0) 1.013e-33 + H2 5.064e-34 5.107e-34 -33.295 -33.292 0.004 (0) +O(0) 2.387e-15 + O2 1.194e-15 1.204e-15 -14.923 -14.919 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -100.231 -100.317 -0.086 (0) + H2S 0.000e+00 0.000e+00 -100.356 -100.353 0.004 (0) + S-2 0.000e+00 0.000e+00 -105.274 -105.592 -0.318 (0) +S(6) 1.438e-02 + SO4-2 9.115e-03 4.368e-03 -2.040 -2.360 -0.319 12.04 + CaSO4 5.262e-03 5.307e-03 -2.279 -2.275 0.004 (0) + HSO4- 2.995e-07 2.479e-07 -6.524 -6.606 -0.082 (0) + CaHSO4+ 1.600e-08 1.325e-08 -7.796 -7.878 -0.082 (0) ------------------------------Saturation indices------------------------------- @@ -3271,30 +3271,30 @@ Gypsum -0.06 -4.73 -4.67 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 5.948e-07 4.888e-07 -6.226 -6.311 -0.085 - H+ 2.725e-07 2.339e-07 -6.565 -6.631 -0.066 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.408e-02 - Ca+2 8.941e-03 4.374e-03 -2.049 -2.359 -0.310 - CaSO4 5.138e-03 5.181e-03 -2.289 -2.286 0.004 - CaHSO4+ 1.628e-08 1.349e-08 -7.788 -7.870 -0.082 - CaOH+ 3.744e-09 3.102e-09 -8.427 -8.508 -0.082 -H(0) 1.693e-33 - H2 8.464e-34 8.534e-34 -33.072 -33.069 0.004 -O(0) 1.532e-15 - O2 7.658e-16 7.722e-16 -15.116 -15.112 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -99.439 -99.525 -0.085 - H2S 0.000e+00 0.000e+00 -99.559 -99.556 0.004 - S-2 0.000e+00 0.000e+00 -104.469 -104.786 -0.316 -S(6) 1.408e-02 - SO4-2 8.941e-03 4.301e-03 -2.049 -2.366 -0.318 - CaSO4 5.138e-03 5.181e-03 -2.289 -2.286 0.004 - HSO4- 3.096e-07 2.565e-07 -6.509 -6.591 -0.082 - CaHSO4+ 1.628e-08 1.349e-08 -7.788 -7.870 -0.082 + OH- 5.948e-07 4.888e-07 -6.226 -6.311 -0.085 (0) + H+ 2.725e-07 2.339e-07 -6.565 -6.631 -0.066 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.36 +Ca 1.408e-02 + Ca+2 8.941e-03 4.374e-03 -2.049 -2.359 -0.310 -18.06 + CaSO4 5.138e-03 5.181e-03 -2.289 -2.286 0.004 (0) + CaHSO4+ 1.628e-08 1.349e-08 -7.788 -7.870 -0.082 (0) + CaOH+ 3.744e-09 3.102e-09 -8.427 -8.508 -0.082 (0) +H(0) 1.693e-33 + H2 8.464e-34 8.534e-34 -33.072 -33.069 0.004 (0) +O(0) 1.532e-15 + O2 7.658e-16 7.722e-16 -15.116 -15.112 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -99.439 -99.525 -0.085 (0) + H2S 0.000e+00 0.000e+00 -99.559 -99.556 0.004 (0) + S-2 0.000e+00 0.000e+00 -104.469 -104.786 -0.316 (0) +S(6) 1.408e-02 + SO4-2 8.941e-03 4.301e-03 -2.049 -2.366 -0.318 11.84 + CaSO4 5.138e-03 5.181e-03 -2.289 -2.286 0.004 (0) + HSO4- 3.096e-07 2.565e-07 -6.509 -6.591 -0.082 (0) + CaHSO4+ 1.628e-08 1.349e-08 -7.788 -7.870 -0.082 (0) ------------------------------Saturation indices------------------------------- @@ -3351,30 +3351,30 @@ Gypsum -0.07 -4.74 -4.67 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 6.114e-07 5.030e-07 -6.214 -6.298 -0.085 - H+ 2.785e-07 2.392e-07 -6.555 -6.621 -0.066 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.378e-02 - Ca+2 8.767e-03 4.305e-03 -2.057 -2.366 -0.309 - CaSO4 5.015e-03 5.056e-03 -2.300 -2.296 0.004 - CaHSO4+ 1.656e-08 1.373e-08 -7.781 -7.862 -0.081 - CaOH+ 3.600e-09 2.986e-09 -8.444 -8.525 -0.081 -H(0) 2.265e-33 - H2 1.132e-33 1.142e-33 -32.946 -32.943 0.004 -O(0) 1.528e-15 - O2 7.641e-16 7.703e-16 -15.117 -15.113 0.004 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -99.034 -99.118 -0.085 - H2S 0.000e+00 0.000e+00 -99.148 -99.144 0.004 - S-2 0.000e+00 0.000e+00 -104.051 -104.366 -0.315 -S(6) 1.378e-02 - SO4-2 8.767e-03 4.234e-03 -2.057 -2.373 -0.316 - CaSO4 5.015e-03 5.056e-03 -2.300 -2.296 0.004 - HSO4- 3.199e-07 2.653e-07 -6.495 -6.576 -0.081 - CaHSO4+ 1.656e-08 1.373e-08 -7.781 -7.862 -0.081 + OH- 6.114e-07 5.030e-07 -6.214 -6.298 -0.085 (0) + H+ 2.785e-07 2.392e-07 -6.555 -6.621 -0.066 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.37 +Ca 1.378e-02 + Ca+2 8.767e-03 4.305e-03 -2.057 -2.366 -0.309 -18.12 + CaSO4 5.015e-03 5.056e-03 -2.300 -2.296 0.004 (0) + CaHSO4+ 1.656e-08 1.373e-08 -7.781 -7.862 -0.081 (0) + CaOH+ 3.600e-09 2.986e-09 -8.444 -8.525 -0.081 (0) +H(0) 2.265e-33 + H2 1.132e-33 1.142e-33 -32.946 -32.943 0.004 (0) +O(0) 1.528e-15 + O2 7.641e-16 7.703e-16 -15.117 -15.113 0.004 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -99.034 -99.118 -0.085 (0) + H2S 0.000e+00 0.000e+00 -99.148 -99.144 0.004 (0) + S-2 0.000e+00 0.000e+00 -104.051 -104.366 -0.315 (0) +S(6) 1.378e-02 + SO4-2 8.767e-03 4.234e-03 -2.057 -2.373 -0.316 11.63 + CaSO4 5.015e-03 5.056e-03 -2.300 -2.296 0.004 (0) + HSO4- 3.199e-07 2.653e-07 -6.495 -6.576 -0.081 (0) + CaHSO4+ 1.656e-08 1.373e-08 -7.781 -7.862 -0.081 (0) ------------------------------Saturation indices------------------------------- @@ -3431,30 +3431,30 @@ Gypsum -0.08 -4.75 -4.68 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 6.283e-07 5.176e-07 -6.202 -6.286 -0.084 - H+ 2.845e-07 2.445e-07 -6.546 -6.612 -0.066 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.349e-02 - Ca+2 8.594e-03 4.236e-03 -2.066 -2.373 -0.307 - CaSO4 4.893e-03 4.931e-03 -2.310 -2.307 0.003 - CaHSO4+ 1.683e-08 1.397e-08 -7.774 -7.855 -0.081 - CaOH+ 3.462e-09 2.874e-09 -8.461 -8.541 -0.081 -H(0) 2.415e-33 - H2 1.208e-33 1.217e-33 -32.918 -32.915 0.003 -O(0) 2.392e-15 - O2 1.196e-15 1.205e-15 -14.922 -14.919 0.003 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -99.021 -99.106 -0.084 - H2S 0.000e+00 0.000e+00 -99.130 -99.127 0.003 - S-2 0.000e+00 0.000e+00 -104.027 -104.340 -0.313 -S(6) 1.349e-02 - SO4-2 8.594e-03 4.167e-03 -2.066 -2.380 -0.314 - CaSO4 4.893e-03 4.931e-03 -2.310 -2.307 0.003 - HSO4- 3.304e-07 2.743e-07 -6.481 -6.562 -0.081 - CaHSO4+ 1.683e-08 1.397e-08 -7.774 -7.855 -0.081 + OH- 6.283e-07 5.176e-07 -6.202 -6.286 -0.084 (0) + H+ 2.845e-07 2.445e-07 -6.546 -6.612 -0.066 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.38 +Ca 1.349e-02 + Ca+2 8.594e-03 4.236e-03 -2.066 -2.373 -0.307 -18.18 + CaSO4 4.893e-03 4.931e-03 -2.310 -2.307 0.003 (0) + CaHSO4+ 1.683e-08 1.397e-08 -7.774 -7.855 -0.081 (0) + CaOH+ 3.462e-09 2.874e-09 -8.461 -8.541 -0.081 (0) +H(0) 2.415e-33 + H2 1.208e-33 1.217e-33 -32.918 -32.915 0.003 (0) +O(0) 2.392e-15 + O2 1.196e-15 1.205e-15 -14.922 -14.919 0.003 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -99.021 -99.106 -0.084 (0) + H2S 0.000e+00 0.000e+00 -99.130 -99.127 0.003 (0) + S-2 0.000e+00 0.000e+00 -104.027 -104.340 -0.313 (0) +S(6) 1.349e-02 + SO4-2 8.594e-03 4.167e-03 -2.066 -2.380 -0.314 11.42 + CaSO4 4.893e-03 4.931e-03 -2.310 -2.307 0.003 (0) + HSO4- 3.304e-07 2.743e-07 -6.481 -6.562 -0.081 (0) + CaHSO4+ 1.683e-08 1.397e-08 -7.774 -7.855 -0.081 (0) ------------------------------Saturation indices------------------------------- @@ -3511,30 +3511,30 @@ Gypsum -0.09 -4.77 -4.68 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 6.456e-07 5.324e-07 -6.190 -6.274 -0.084 - H+ 2.905e-07 2.499e-07 -6.537 -6.602 -0.065 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.319e-02 - Ca+2 8.423e-03 4.167e-03 -2.075 -2.380 -0.306 - CaSO4 4.771e-03 4.808e-03 -2.321 -2.318 0.003 - CaHSO4+ 1.709e-08 1.420e-08 -7.767 -7.848 -0.080 - CaOH+ 3.329e-09 2.766e-09 -8.478 -8.558 -0.080 -H(0) 3.969e-33 - H2 1.985e-33 2.000e-33 -32.702 -32.699 0.003 -O(0) 1.570e-15 - O2 7.852e-16 7.913e-16 -15.105 -15.102 0.003 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -98.257 -98.341 -0.084 - H2S 0.000e+00 0.000e+00 -98.361 -98.357 0.003 - S-2 0.000e+00 0.000e+00 -103.250 -103.561 -0.311 -S(6) 1.319e-02 - SO4-2 8.422e-03 4.101e-03 -2.075 -2.387 -0.313 - CaSO4 4.771e-03 4.808e-03 -2.321 -2.318 0.003 - HSO4- 3.412e-07 2.835e-07 -6.467 -6.547 -0.080 - CaHSO4+ 1.709e-08 1.420e-08 -7.767 -7.848 -0.080 + OH- 6.456e-07 5.324e-07 -6.190 -6.274 -0.084 (0) + H+ 2.905e-07 2.499e-07 -6.537 -6.602 -0.065 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.39 +Ca 1.319e-02 + Ca+2 8.423e-03 4.167e-03 -2.075 -2.380 -0.306 -18.24 + CaSO4 4.771e-03 4.808e-03 -2.321 -2.318 0.003 (0) + CaHSO4+ 1.709e-08 1.420e-08 -7.767 -7.848 -0.080 (0) + CaOH+ 3.329e-09 2.766e-09 -8.478 -8.558 -0.080 (0) +H(0) 3.969e-33 + H2 1.985e-33 2.000e-33 -32.702 -32.699 0.003 (0) +O(0) 1.570e-15 + O2 7.852e-16 7.913e-16 -15.105 -15.102 0.003 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -98.257 -98.341 -0.084 (0) + H2S 0.000e+00 0.000e+00 -98.361 -98.357 0.003 (0) + S-2 0.000e+00 0.000e+00 -103.250 -103.561 -0.311 (0) +S(6) 1.319e-02 + SO4-2 8.422e-03 4.101e-03 -2.075 -2.387 -0.313 11.19 + CaSO4 4.771e-03 4.808e-03 -2.321 -2.318 0.003 (0) + HSO4- 3.412e-07 2.835e-07 -6.467 -6.547 -0.080 (0) + CaHSO4+ 1.709e-08 1.420e-08 -7.767 -7.848 -0.080 (0) ------------------------------Saturation indices------------------------------- @@ -3591,30 +3591,30 @@ Gypsum -0.10 -4.78 -4.69 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 6.631e-07 5.475e-07 -6.178 -6.262 -0.083 - H+ 2.966e-07 2.553e-07 -6.528 -6.593 -0.065 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.290e-02 - Ca+2 8.252e-03 4.098e-03 -2.083 -2.387 -0.304 - CaSO4 4.650e-03 4.685e-03 -2.333 -2.329 0.003 - CaHSO4+ 1.735e-08 1.443e-08 -7.761 -7.841 -0.080 - CaOH+ 3.201e-09 2.663e-09 -8.495 -8.575 -0.080 -H(0) 5.299e-33 - H2 2.650e-33 2.670e-33 -32.577 -32.574 0.003 -O(0) 1.558e-15 - O2 7.788e-16 7.847e-16 -15.109 -15.105 0.003 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -97.854 -97.937 -0.083 - H2S 0.000e+00 0.000e+00 -97.952 -97.948 0.003 - S-2 0.000e+00 0.000e+00 -102.834 -103.144 -0.309 -S(6) 1.290e-02 - SO4-2 8.252e-03 4.034e-03 -2.083 -2.394 -0.311 - CaSO4 4.650e-03 4.685e-03 -2.333 -2.329 0.003 - HSO4- 3.522e-07 2.929e-07 -6.453 -6.533 -0.080 - CaHSO4+ 1.735e-08 1.443e-08 -7.761 -7.841 -0.080 + OH- 6.631e-07 5.475e-07 -6.178 -6.262 -0.083 (0) + H+ 2.966e-07 2.553e-07 -6.528 -6.593 -0.065 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.40 +Ca 1.290e-02 + Ca+2 8.252e-03 4.098e-03 -2.083 -2.387 -0.304 -18.30 + CaSO4 4.650e-03 4.685e-03 -2.333 -2.329 0.003 (0) + CaHSO4+ 1.735e-08 1.443e-08 -7.761 -7.841 -0.080 (0) + CaOH+ 3.201e-09 2.663e-09 -8.495 -8.575 -0.080 (0) +H(0) 5.299e-33 + H2 2.650e-33 2.670e-33 -32.577 -32.574 0.003 (0) +O(0) 1.558e-15 + O2 7.788e-16 7.847e-16 -15.109 -15.105 0.003 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -97.854 -97.937 -0.083 (0) + H2S 0.000e+00 0.000e+00 -97.952 -97.948 0.003 (0) + S-2 0.000e+00 0.000e+00 -102.834 -103.144 -0.309 (0) +S(6) 1.290e-02 + SO4-2 8.252e-03 4.034e-03 -2.083 -2.394 -0.311 10.96 + CaSO4 4.650e-03 4.685e-03 -2.333 -2.329 0.003 (0) + HSO4- 3.522e-07 2.929e-07 -6.453 -6.533 -0.080 (0) + CaHSO4+ 1.735e-08 1.443e-08 -7.761 -7.841 -0.080 (0) ------------------------------Saturation indices------------------------------- @@ -3671,30 +3671,30 @@ Gypsum -0.11 -4.80 -4.69 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 6.808e-07 5.628e-07 -6.167 -6.250 -0.083 - H+ 3.028e-07 2.608e-07 -6.519 -6.584 -0.065 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Ca 1.261e-02 - Ca+2 8.083e-03 4.029e-03 -2.092 -2.395 -0.302 - CaSO4 4.530e-03 4.564e-03 -2.344 -2.341 0.003 - CaHSO4+ 1.760e-08 1.466e-08 -7.754 -7.834 -0.080 - CaOH+ 3.078e-09 2.563e-09 -8.512 -8.591 -0.080 -H(0) 7.047e-33 - H2 3.524e-33 3.550e-33 -32.453 -32.450 0.003 -O(0) 1.552e-15 - O2 7.759e-16 7.817e-16 -15.110 -15.107 0.003 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -97.456 -97.539 -0.083 - H2S 0.000e+00 0.000e+00 -97.549 -97.546 0.003 - S-2 0.000e+00 0.000e+00 -102.425 -102.733 -0.308 -S(6) 1.261e-02 - SO4-2 8.083e-03 3.968e-03 -2.092 -2.401 -0.309 - CaSO4 4.530e-03 4.564e-03 -2.344 -2.341 0.003 - HSO4- 3.634e-07 3.026e-07 -6.440 -6.519 -0.080 - CaHSO4+ 1.760e-08 1.466e-08 -7.754 -7.834 -0.080 + OH- 6.808e-07 5.628e-07 -6.167 -6.250 -0.083 (0) + H+ 3.028e-07 2.608e-07 -6.519 -6.584 -0.065 0.00 + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.41 +Ca 1.261e-02 + Ca+2 8.083e-03 4.029e-03 -2.092 -2.395 -0.302 -18.37 + CaSO4 4.530e-03 4.564e-03 -2.344 -2.341 0.003 (0) + CaHSO4+ 1.760e-08 1.466e-08 -7.754 -7.834 -0.080 (0) + CaOH+ 3.078e-09 2.563e-09 -8.512 -8.591 -0.080 (0) +H(0) 7.047e-33 + H2 3.524e-33 3.550e-33 -32.453 -32.450 0.003 (0) +O(0) 1.552e-15 + O2 7.759e-16 7.817e-16 -15.110 -15.107 0.003 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -97.456 -97.539 -0.083 (0) + H2S 0.000e+00 0.000e+00 -97.549 -97.546 0.003 (0) + S-2 0.000e+00 0.000e+00 -102.425 -102.733 -0.308 (0) +S(6) 1.261e-02 + SO4-2 8.083e-03 3.968e-03 -2.092 -2.401 -0.309 10.73 + CaSO4 4.530e-03 4.564e-03 -2.344 -2.341 0.003 (0) + HSO4- 3.634e-07 3.026e-07 -6.440 -6.519 -0.080 (0) + CaHSO4+ 1.760e-08 1.466e-08 -7.754 -7.834 -0.080 (0) ------------------------------Saturation indices------------------------------- @@ -3751,30 +3751,30 @@ Gypsum -0.12 -4.81 -4.69 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 6.989e-07 5.785e-07 -6.156 -6.238 -0.082 - H+ 3.091e-07 2.664e-07 -6.510 -6.574 -0.065 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -Ca 1.233e-02 - Ca+2 7.916e-03 3.961e-03 -2.101 -2.402 -0.301 - CaSO4 4.411e-03 4.444e-03 -2.355 -2.352 0.003 - CaHSO4+ 1.785e-08 1.488e-08 -7.748 -7.827 -0.079 - CaOH+ 2.959e-09 2.467e-09 -8.529 -8.608 -0.079 -H(0) 9.299e-33 - H2 4.649e-33 4.683e-33 -32.333 -32.329 0.003 -O(0) 1.565e-15 - O2 7.826e-16 7.884e-16 -15.106 -15.103 0.003 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -97.073 -97.155 -0.082 - H2S 0.000e+00 0.000e+00 -97.159 -97.156 0.003 - S-2 0.000e+00 0.000e+00 -102.029 -102.335 -0.306 -S(6) 1.233e-02 - SO4-2 7.916e-03 3.902e-03 -2.102 -2.409 -0.307 - CaSO4 4.411e-03 4.444e-03 -2.355 -2.352 0.003 - HSO4- 3.748e-07 3.125e-07 -6.426 -6.505 -0.079 - CaHSO4+ 1.785e-08 1.488e-08 -7.748 -7.827 -0.079 + OH- 6.989e-07 5.785e-07 -6.156 -6.238 -0.082 (0) + H+ 3.091e-07 2.664e-07 -6.510 -6.574 -0.065 0.00 + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.42 +Ca 1.233e-02 + Ca+2 7.916e-03 3.961e-03 -2.101 -2.402 -0.301 -18.44 + CaSO4 4.411e-03 4.444e-03 -2.355 -2.352 0.003 (0) + CaHSO4+ 1.785e-08 1.488e-08 -7.748 -7.827 -0.079 (0) + CaOH+ 2.959e-09 2.467e-09 -8.529 -8.608 -0.079 (0) +H(0) 9.299e-33 + H2 4.649e-33 4.683e-33 -32.333 -32.329 0.003 (0) +O(0) 1.565e-15 + O2 7.826e-16 7.884e-16 -15.106 -15.103 0.003 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -97.073 -97.155 -0.082 (0) + H2S 0.000e+00 0.000e+00 -97.159 -97.156 0.003 (0) + S-2 0.000e+00 0.000e+00 -102.029 -102.335 -0.306 (0) +S(6) 1.233e-02 + SO4-2 7.916e-03 3.902e-03 -2.102 -2.409 -0.307 10.48 + CaSO4 4.411e-03 4.444e-03 -2.355 -2.352 0.003 (0) + HSO4- 3.748e-07 3.125e-07 -6.426 -6.505 -0.079 (0) + CaHSO4+ 1.785e-08 1.488e-08 -7.748 -7.827 -0.079 (0) ------------------------------Saturation indices------------------------------- @@ -3831,30 +3831,30 @@ Gypsum -0.13 -4.83 -4.70 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 7.173e-07 5.944e-07 -6.144 -6.226 -0.082 - H+ 3.154e-07 2.720e-07 -6.501 -6.565 -0.064 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -Ca 1.204e-02 - Ca+2 7.750e-03 3.893e-03 -2.111 -2.410 -0.299 - CaSO4 4.294e-03 4.325e-03 -2.367 -2.364 0.003 - CaHSO4+ 1.809e-08 1.510e-08 -7.742 -7.821 -0.079 - CaOH+ 2.846e-09 2.375e-09 -8.546 -8.624 -0.079 -H(0) 1.233e-32 - H2 6.166e-33 6.210e-33 -32.210 -32.207 0.003 -O(0) 1.558e-15 - O2 7.788e-16 7.844e-16 -15.109 -15.105 0.003 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -96.680 -96.761 -0.082 - H2S 0.000e+00 0.000e+00 -96.760 -96.757 0.003 - S-2 0.000e+00 0.000e+00 -101.624 -101.928 -0.304 -S(6) 1.204e-02 - SO4-2 7.750e-03 3.837e-03 -2.111 -2.416 -0.305 - CaSO4 4.294e-03 4.325e-03 -2.367 -2.364 0.003 - HSO4- 3.865e-07 3.225e-07 -6.413 -6.491 -0.079 - CaHSO4+ 1.809e-08 1.510e-08 -7.742 -7.821 -0.079 + OH- 7.173e-07 5.944e-07 -6.144 -6.226 -0.082 (0) + H+ 3.154e-07 2.720e-07 -6.501 -6.565 -0.064 0.00 + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.44 +Ca 1.204e-02 + Ca+2 7.750e-03 3.893e-03 -2.111 -2.410 -0.299 -18.51 + CaSO4 4.294e-03 4.325e-03 -2.367 -2.364 0.003 (0) + CaHSO4+ 1.809e-08 1.510e-08 -7.742 -7.821 -0.079 (0) + CaOH+ 2.846e-09 2.375e-09 -8.546 -8.624 -0.079 (0) +H(0) 1.233e-32 + H2 6.166e-33 6.210e-33 -32.210 -32.207 0.003 (0) +O(0) 1.558e-15 + O2 7.788e-16 7.844e-16 -15.109 -15.105 0.003 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -96.680 -96.761 -0.082 (0) + H2S 0.000e+00 0.000e+00 -96.760 -96.757 0.003 (0) + S-2 0.000e+00 0.000e+00 -101.624 -101.928 -0.304 (0) +S(6) 1.204e-02 + SO4-2 7.750e-03 3.837e-03 -2.111 -2.416 -0.305 10.23 + CaSO4 4.294e-03 4.325e-03 -2.367 -2.364 0.003 (0) + HSO4- 3.865e-07 3.225e-07 -6.413 -6.491 -0.079 (0) + CaHSO4+ 1.809e-08 1.510e-08 -7.742 -7.821 -0.079 (0) ------------------------------Saturation indices------------------------------- @@ -3911,30 +3911,30 @@ Gypsum -0.14 -4.84 -4.70 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 7.359e-07 6.106e-07 -6.133 -6.214 -0.081 - H+ 3.218e-07 2.777e-07 -6.492 -6.556 -0.064 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -Ca 1.176e-02 - Ca+2 7.586e-03 3.826e-03 -2.120 -2.417 -0.297 - CaSO4 4.178e-03 4.207e-03 -2.379 -2.376 0.003 - CaHSO4+ 1.833e-08 1.531e-08 -7.737 -7.815 -0.078 - CaOH+ 2.736e-09 2.286e-09 -8.563 -8.641 -0.078 -H(0) 1.626e-32 - H2 8.130e-33 8.187e-33 -32.090 -32.087 0.003 -O(0) 1.563e-15 - O2 7.816e-16 7.871e-16 -15.107 -15.104 0.003 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -96.296 -96.377 -0.081 - H2S 0.000e+00 0.000e+00 -96.371 -96.368 0.003 - S-2 0.000e+00 0.000e+00 -101.229 -101.531 -0.302 -S(6) 1.176e-02 - SO4-2 7.585e-03 3.772e-03 -2.120 -2.423 -0.303 - CaSO4 4.178e-03 4.207e-03 -2.379 -2.376 0.003 - HSO4- 3.984e-07 3.328e-07 -6.400 -6.478 -0.078 - CaHSO4+ 1.833e-08 1.531e-08 -7.737 -7.815 -0.078 + OH- 7.359e-07 6.106e-07 -6.133 -6.214 -0.081 (0) + H+ 3.218e-07 2.777e-07 -6.492 -6.556 -0.064 0.00 + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.45 +Ca 1.176e-02 + Ca+2 7.586e-03 3.826e-03 -2.120 -2.417 -0.297 -18.58 + CaSO4 4.178e-03 4.207e-03 -2.379 -2.376 0.003 (0) + CaHSO4+ 1.833e-08 1.531e-08 -7.737 -7.815 -0.078 (0) + CaOH+ 2.736e-09 2.286e-09 -8.563 -8.641 -0.078 (0) +H(0) 1.626e-32 + H2 8.130e-33 8.187e-33 -32.090 -32.087 0.003 (0) +O(0) 1.563e-15 + O2 7.816e-16 7.871e-16 -15.107 -15.104 0.003 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -96.296 -96.377 -0.081 (0) + H2S 0.000e+00 0.000e+00 -96.371 -96.368 0.003 (0) + S-2 0.000e+00 0.000e+00 -101.229 -101.531 -0.302 (0) +S(6) 1.176e-02 + SO4-2 7.585e-03 3.772e-03 -2.120 -2.423 -0.303 9.97 + CaSO4 4.178e-03 4.207e-03 -2.379 -2.376 0.003 (0) + HSO4- 3.984e-07 3.328e-07 -6.400 -6.478 -0.078 (0) + CaHSO4+ 1.833e-08 1.531e-08 -7.737 -7.815 -0.078 (0) ------------------------------Saturation indices------------------------------- @@ -3991,30 +3991,30 @@ Gypsum -0.15 -4.86 -4.71 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 7.548e-07 6.271e-07 -6.122 -6.203 -0.081 - H+ 3.282e-07 2.835e-07 -6.484 -6.547 -0.064 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -Ca 1.149e-02 - Ca+2 7.423e-03 3.759e-03 -2.129 -2.425 -0.295 - CaSO4 4.063e-03 4.091e-03 -2.391 -2.388 0.003 - CaHSO4+ 1.856e-08 1.552e-08 -7.731 -7.809 -0.078 - CaOH+ 2.631e-09 2.200e-09 -8.580 -8.658 -0.078 -H(0) 2.166e-32 - H2 1.083e-32 1.090e-32 -31.965 -31.962 0.003 -O(0) 1.532e-15 - O2 7.660e-16 7.713e-16 -15.116 -15.113 0.003 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -95.895 -95.975 -0.081 - H2S 0.000e+00 0.000e+00 -95.964 -95.961 0.003 - S-2 0.000e+00 0.000e+00 -100.815 -101.116 -0.300 -S(6) 1.149e-02 - SO4-2 7.423e-03 3.707e-03 -2.129 -2.431 -0.302 - CaSO4 4.063e-03 4.091e-03 -2.391 -2.388 0.003 - HSO4- 4.106e-07 3.434e-07 -6.387 -6.464 -0.078 - CaHSO4+ 1.856e-08 1.552e-08 -7.731 -7.809 -0.078 + OH- 7.548e-07 6.271e-07 -6.122 -6.203 -0.081 (0) + H+ 3.282e-07 2.835e-07 -6.484 -6.547 -0.064 0.00 + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.46 +Ca 1.149e-02 + Ca+2 7.423e-03 3.759e-03 -2.129 -2.425 -0.295 -18.66 + CaSO4 4.063e-03 4.091e-03 -2.391 -2.388 0.003 (0) + CaHSO4+ 1.856e-08 1.552e-08 -7.731 -7.809 -0.078 (0) + CaOH+ 2.631e-09 2.200e-09 -8.580 -8.658 -0.078 (0) +H(0) 2.166e-32 + H2 1.083e-32 1.090e-32 -31.965 -31.962 0.003 (0) +O(0) 1.532e-15 + O2 7.660e-16 7.713e-16 -15.116 -15.113 0.003 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -95.895 -95.975 -0.081 (0) + H2S 0.000e+00 0.000e+00 -95.964 -95.961 0.003 (0) + S-2 0.000e+00 0.000e+00 -100.815 -101.116 -0.300 (0) +S(6) 1.149e-02 + SO4-2 7.423e-03 3.707e-03 -2.129 -2.431 -0.302 9.70 + CaSO4 4.063e-03 4.091e-03 -2.391 -2.388 0.003 (0) + HSO4- 4.106e-07 3.434e-07 -6.387 -6.464 -0.078 (0) + CaHSO4+ 1.856e-08 1.552e-08 -7.731 -7.809 -0.078 (0) ------------------------------Saturation indices------------------------------- @@ -4071,30 +4071,30 @@ Gypsum -0.16 -4.87 -4.71 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 7.741e-07 6.439e-07 -6.111 -6.191 -0.080 - H+ 3.347e-07 2.893e-07 -6.475 -6.539 -0.063 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -Ca 1.121e-02 - Ca+2 7.263e-03 3.693e-03 -2.139 -2.433 -0.294 - CaSO4 3.950e-03 3.976e-03 -2.403 -2.401 0.003 - CaHSO4+ 1.878e-08 1.572e-08 -7.726 -7.803 -0.077 - CaOH+ 2.530e-09 2.118e-09 -8.597 -8.674 -0.077 -H(0) 2.850e-32 - H2 1.425e-32 1.435e-32 -31.846 -31.843 0.003 -O(0) 1.534e-15 - O2 7.669e-16 7.721e-16 -15.115 -15.112 0.003 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -95.514 -95.594 -0.080 - H2S 0.000e+00 0.000e+00 -95.577 -95.574 0.003 - S-2 0.000e+00 0.000e+00 -100.423 -100.721 -0.299 -S(6) 1.121e-02 - SO4-2 7.262e-03 3.642e-03 -2.139 -2.439 -0.300 - CaSO4 3.950e-03 3.976e-03 -2.403 -2.401 0.003 - HSO4- 4.230e-07 3.541e-07 -6.374 -6.451 -0.077 - CaHSO4+ 1.878e-08 1.572e-08 -7.726 -7.803 -0.077 + OH- 7.741e-07 6.439e-07 -6.111 -6.191 -0.080 (0) + H+ 3.347e-07 2.893e-07 -6.475 -6.539 -0.063 0.00 + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.47 +Ca 1.121e-02 + Ca+2 7.263e-03 3.693e-03 -2.139 -2.433 -0.294 -18.74 + CaSO4 3.950e-03 3.976e-03 -2.403 -2.401 0.003 (0) + CaHSO4+ 1.878e-08 1.572e-08 -7.726 -7.803 -0.077 (0) + CaOH+ 2.530e-09 2.118e-09 -8.597 -8.674 -0.077 (0) +H(0) 2.850e-32 + H2 1.425e-32 1.435e-32 -31.846 -31.843 0.003 (0) +O(0) 1.534e-15 + O2 7.669e-16 7.721e-16 -15.115 -15.112 0.003 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -95.514 -95.594 -0.080 (0) + H2S 0.000e+00 0.000e+00 -95.577 -95.574 0.003 (0) + S-2 0.000e+00 0.000e+00 -100.423 -100.721 -0.299 (0) +S(6) 1.121e-02 + SO4-2 7.262e-03 3.642e-03 -2.139 -2.439 -0.300 9.42 + CaSO4 3.950e-03 3.976e-03 -2.403 -2.401 0.003 (0) + HSO4- 4.230e-07 3.541e-07 -6.374 -6.451 -0.077 (0) + CaHSO4+ 1.878e-08 1.572e-08 -7.726 -7.803 -0.077 (0) ------------------------------Saturation indices------------------------------- @@ -4151,30 +4151,30 @@ Gypsum -0.17 -4.89 -4.72 1.000e+00 0 -1.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 7.935e-07 6.609e-07 -6.100 -6.180 -0.079 - H+ 3.412e-07 2.952e-07 -6.467 -6.530 -0.063 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -Ca 1.094e-02 - Ca+2 7.104e-03 3.627e-03 -2.149 -2.440 -0.292 - CaSO4 3.838e-03 3.863e-03 -2.416 -2.413 0.003 - CaHSO4+ 1.900e-08 1.592e-08 -7.721 -7.798 -0.077 - CaOH+ 2.432e-09 2.039e-09 -8.614 -8.691 -0.077 -H(0) 3.755e-32 - H2 1.878e-32 1.890e-32 -31.726 -31.724 0.003 -O(0) 1.527e-15 - O2 7.635e-16 7.685e-16 -15.117 -15.114 0.003 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -95.131 -95.210 -0.079 - H2S 0.000e+00 0.000e+00 -95.188 -95.185 0.003 - S-2 0.000e+00 0.000e+00 -100.028 -100.324 -0.297 -S(6) 1.094e-02 - SO4-2 7.103e-03 3.579e-03 -2.149 -2.446 -0.298 - CaSO4 3.838e-03 3.863e-03 -2.416 -2.413 0.003 - HSO4- 4.356e-07 3.651e-07 -6.361 -6.438 -0.077 - CaHSO4+ 1.900e-08 1.592e-08 -7.721 -7.798 -0.077 + OH- 7.935e-07 6.609e-07 -6.100 -6.180 -0.079 (0) + H+ 3.412e-07 2.952e-07 -6.467 -6.530 -0.063 0.00 + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.48 +Ca 1.094e-02 + Ca+2 7.104e-03 3.627e-03 -2.149 -2.440 -0.292 -18.82 + CaSO4 3.838e-03 3.863e-03 -2.416 -2.413 0.003 (0) + CaHSO4+ 1.900e-08 1.592e-08 -7.721 -7.798 -0.077 (0) + CaOH+ 2.432e-09 2.039e-09 -8.614 -8.691 -0.077 (0) +H(0) 3.755e-32 + H2 1.878e-32 1.890e-32 -31.726 -31.724 0.003 (0) +O(0) 1.527e-15 + O2 7.635e-16 7.685e-16 -15.117 -15.114 0.003 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -95.131 -95.210 -0.079 (0) + H2S 0.000e+00 0.000e+00 -95.188 -95.185 0.003 (0) + S-2 0.000e+00 0.000e+00 -100.028 -100.324 -0.297 (0) +S(6) 1.094e-02 + SO4-2 7.103e-03 3.579e-03 -2.149 -2.446 -0.298 9.14 + CaSO4 3.838e-03 3.863e-03 -2.416 -2.413 0.003 (0) + HSO4- 4.356e-07 3.651e-07 -6.361 -6.438 -0.077 (0) + CaHSO4+ 1.900e-08 1.592e-08 -7.721 -7.798 -0.077 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex20a.out b/ex20a.out index 5fbaf353..c669dbe4 100644 --- a/ex20a.out +++ b/ex20a.out @@ -93,34 +93,34 @@ Initial solution 1. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.673e-06 1.586e-06 -5.776 -5.800 -0.023 - H3O+ 6.628e-09 6.310e-09 -8.179 -8.200 -0.021 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -77.792 -77.792 0.000 -C(4) 2.000e-03 - HCO3- 1.944e-03 1.844e-03 -2.711 -2.734 -0.023 - CO2 2.615e-05 2.616e-05 -4.583 -4.582 0.000 - CO3-2 1.693e-05 1.371e-05 -4.771 -4.863 -0.092 - CaHCO3+ 5.989e-06 5.687e-06 -5.223 -5.245 -0.022 - CaCO3 5.562e-06 5.565e-06 -5.255 -5.255 0.000 - NaHCO3 1.356e-06 1.356e-06 -5.868 -5.868 0.000 - NaCO3- 3.520e-07 3.339e-07 -6.453 -6.476 -0.023 -Ca 3.089e-04 - Ca+2 2.974e-04 2.417e-04 -3.527 -3.617 -0.090 - CaHCO3+ 5.989e-06 5.687e-06 -5.223 -5.245 -0.022 - CaCO3 5.562e-06 5.565e-06 -5.255 -5.255 0.000 -H(0) 5.634e-28 - H2 2.817e-28 2.819e-28 -27.550 -27.550 0.000 -Na 1.380e-03 - Na+ 1.379e-03 1.308e-03 -2.861 -2.883 -0.023 - NaHCO3 1.356e-06 1.356e-06 -5.868 -5.868 0.000 - NaCO3- 3.520e-07 3.339e-07 -6.453 -6.476 -0.023 -O(0) 1.049e-37 - O2 5.243e-38 5.246e-38 -37.280 -37.280 0.000 + OH- 1.673e-06 1.586e-06 -5.776 -5.800 -0.023 (0) + H3O+ 6.628e-09 6.310e-09 -8.179 -8.200 -0.021 (0) + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -77.792 -77.792 0.000 (0) +C(4) 2.000e-03 + HCO3- 1.944e-03 1.844e-03 -2.711 -2.734 -0.023 (0) + CO2 2.615e-05 2.616e-05 -4.583 -4.582 0.000 (0) + CO3-2 1.693e-05 1.371e-05 -4.771 -4.863 -0.092 (0) + CaHCO3+ 5.989e-06 5.687e-06 -5.223 -5.245 -0.022 (0) + CaCO3 5.562e-06 5.565e-06 -5.255 -5.255 0.000 (0) + NaHCO3 1.356e-06 1.356e-06 -5.868 -5.868 0.000 (0) + NaCO3- 3.520e-07 3.339e-07 -6.453 -6.476 -0.023 (0) +Ca 3.089e-04 + Ca+2 2.974e-04 2.417e-04 -3.527 -3.617 -0.090 (0) + CaHCO3+ 5.989e-06 5.687e-06 -5.223 -5.245 -0.022 (0) + CaCO3 5.562e-06 5.565e-06 -5.255 -5.255 0.000 (0) +H(0) 5.634e-28 + H2 2.817e-28 2.819e-28 -27.550 -27.550 0.000 (0) +Na 1.380e-03 + Na+ 1.379e-03 1.308e-03 -2.861 -2.883 -0.023 (0) + NaHCO3 1.356e-06 1.356e-06 -5.868 -5.868 0.000 (0) + NaCO3- 3.520e-07 3.339e-07 -6.453 -6.476 -0.023 (0) +O(0) 1.049e-37 + O2 5.243e-38 5.246e-38 -37.280 -37.280 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -289,113 +289,113 @@ Alpha 13C Calcite/CO2(aq) 1.0107 10.641 10.641 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.661e-06 1.575e-06 -5.780 -5.803 -0.023 - H3O+ 6.648e-09 6.328e-09 -8.177 -8.199 -0.021 - H2O 5.556e+01 9.977e-01 1.745 -0.001 0.000 -C(-4) 3.053e-24 - CH4 3.051e-24 3.053e-24 -23.515 -23.515 0.000 - CH3D 1.901e-27 1.902e-27 -26.721 -26.721 0.000 -C(4) 1.984e-03 - HCO3- 1.916e-03 1.818e-03 -2.718 -2.741 -0.023 - CO2 2.597e-05 2.598e-05 -4.586 -4.585 0.000 - CO3-2 1.661e-05 1.344e-05 -4.780 -4.872 -0.092 - CaHCO3+ 5.916e-06 5.618e-06 -5.228 -5.250 -0.023 - CaCO3 5.466e-06 5.469e-06 -5.262 -5.262 0.000 - HCO2[18O]- 3.842e-06 3.645e-06 -5.415 -5.438 -0.023 - HCO[18O]O- 3.842e-06 3.645e-06 -5.415 -5.438 -0.023 - HC[18O]O2- 3.842e-06 3.645e-06 -5.415 -5.438 -0.023 - NaHCO3 1.341e-06 1.341e-06 -5.873 -5.872 0.000 - NaCO3- 3.463e-07 3.285e-07 -6.460 -6.483 -0.023 - DCO3- 2.985e-07 2.831e-07 -6.525 -6.548 -0.023 - CO[18O] 1.085e-07 1.086e-07 -6.964 -6.964 0.000 - CO2[18O]-2 9.991e-08 8.087e-08 -7.000 -7.092 -0.092 - CaCO2[18O] 3.288e-08 3.290e-08 -7.483 -7.483 0.000 - CaHCO2[18O]+ 1.186e-08 1.126e-08 -7.926 -7.948 -0.023 - CaHCO[18O]O+ 1.186e-08 1.126e-08 -7.926 -7.948 -0.023 - CaHC[18O]O2+ 1.186e-08 1.126e-08 -7.926 -7.948 -0.023 - HCO[18O]2- 7.705e-09 7.308e-09 -8.113 -8.136 -0.023 - HC[18O]2O- 7.705e-09 7.308e-09 -8.113 -8.136 -0.023 - HC[18O]O[18O]- 7.705e-09 7.308e-09 -8.113 -8.136 -0.023 - NaHCO2[18O] 2.688e-09 2.690e-09 -8.571 -8.570 0.000 - NaHCO[18O]O 2.688e-09 2.690e-09 -8.571 -8.570 0.000 - NaHC[18O]O2 2.688e-09 2.690e-09 -8.571 -8.570 0.000 - NaCO2[18O]- 2.083e-09 1.976e-09 -8.681 -8.704 -0.023 -Ca 3.097e-04 - Ca+2 2.981e-04 2.422e-04 -3.526 -3.616 -0.090 - CaHCO3+ 5.916e-06 5.618e-06 -5.228 -5.250 -0.023 - CaCO3 5.466e-06 5.469e-06 -5.262 -5.262 0.000 - CaH[13C]O3+ 6.616e-08 6.281e-08 -7.179 -7.202 -0.023 - Ca[13C]O3 6.104e-08 6.107e-08 -7.214 -7.214 0.000 - CaCO2[18O] 3.288e-08 3.290e-08 -7.483 -7.483 0.000 - CaHCO2[18O]+ 1.186e-08 1.126e-08 -7.926 -7.948 -0.023 - CaHCO[18O]O+ 1.186e-08 1.126e-08 -7.926 -7.948 -0.023 - CaHC[18O]O2+ 1.186e-08 1.126e-08 -7.926 -7.948 -0.023 - CaDCO3+ 9.216e-10 8.750e-10 -9.035 -9.058 -0.023 - Ca[13C]O2[18O] 3.672e-10 3.674e-10 -9.435 -9.435 0.000 -D(0) 3.257e-18 - HD 3.256e-18 3.258e-18 -17.487 -17.487 0.000 - D2 2.536e-22 2.537e-22 -21.596 -21.596 0.000 -D(1) 1.734e-02 - HDO 1.731e-02 3.108e-04 -1.762 -3.507 -1.746 - HD[18O] 3.470e-05 6.233e-07 -4.460 -6.205 -1.746 - D2O 1.348e-06 2.421e-08 -5.870 -7.616 -1.746 - DCO3- 2.985e-07 2.831e-07 -6.525 -6.548 -0.023 -H(0) 2.091e-14 - H2 1.045e-14 1.046e-14 -13.981 -13.981 0.000 - HD 3.256e-18 3.258e-18 -17.487 -17.487 0.000 -Na 1.385e-03 - Na+ 1.383e-03 1.312e-03 -2.859 -2.882 -0.023 - NaHCO3 1.341e-06 1.341e-06 -5.873 -5.872 0.000 - NaCO3- 3.463e-07 3.285e-07 -6.460 -6.483 -0.023 - NaH[13C]O3 1.499e-08 1.500e-08 -7.824 -7.824 0.000 - Na[13C]O3- 3.867e-09 3.668e-09 -8.413 -8.436 -0.023 - NaHCO2[18O] 2.688e-09 2.690e-09 -8.571 -8.570 0.000 - NaHCO[18O]O 2.688e-09 2.690e-09 -8.571 -8.570 0.000 - NaHC[18O]O2 2.688e-09 2.690e-09 -8.571 -8.570 0.000 - NaCO2[18O]- 2.083e-09 1.976e-09 -8.681 -8.704 -0.023 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -64.421 -64.421 0.000 - O[18O] 0.000e+00 0.000e+00 -66.818 -66.818 0.000 -[13C](-4) 3.385e-26 - [13C]H4 3.383e-26 3.384e-26 -25.471 -25.471 0.000 - [13C]H3D 2.107e-29 2.109e-29 -28.676 -28.676 0.000 -[13C](4) 2.218e-05 - H[13C]O3- 2.143e-05 2.032e-05 -4.669 -4.692 -0.023 - [13C]O2 2.879e-07 2.880e-07 -6.541 -6.541 0.000 - [13C]O3-2 1.854e-07 1.501e-07 -6.732 -6.824 -0.092 - CaH[13C]O3+ 6.616e-08 6.281e-08 -7.179 -7.202 -0.023 - Ca[13C]O3 6.104e-08 6.107e-08 -7.214 -7.214 0.000 - H[13C]O2[18O]- 4.296e-08 4.075e-08 -7.367 -7.390 -0.023 - H[13C]O[18O]O- 4.296e-08 4.075e-08 -7.367 -7.390 -0.023 - H[13C][18O]O2- 4.296e-08 4.075e-08 -7.367 -7.390 -0.023 - NaH[13C]O3 1.499e-08 1.500e-08 -7.824 -7.824 0.000 - Na[13C]O3- 3.867e-09 3.668e-09 -8.413 -8.436 -0.023 - D[13C]O3- 3.337e-09 3.166e-09 -8.477 -8.500 -0.023 - [13C]O[18O] 1.203e-09 1.204e-09 -8.920 -8.919 0.000 - [13C]O2[18O]-2 1.116e-09 9.029e-10 -8.953 -9.044 -0.092 - Ca[13C]O2[18O] 3.672e-10 3.674e-10 -9.435 -9.435 0.000 - CaH[13C]O2[18O]+ 1.327e-10 1.260e-10 -9.877 -9.900 -0.023 - CaH[13C]O[18O]O+ 1.327e-10 1.260e-10 -9.877 -9.900 -0.023 - CaH[13C][18O]O2+ 1.327e-10 1.260e-10 -9.877 -9.900 -0.023 - H[13C]O[18O]2- 8.615e-11 8.172e-11 -10.065 -10.088 -0.023 - H[13C][18O]2O- 8.615e-11 8.172e-11 -10.065 -10.088 -0.023 - H[13C][18O]O[18O]- 8.615e-11 8.172e-11 -10.065 -10.088 -0.023 - NaH[13C]O2[18O] 3.006e-11 3.008e-11 -10.522 -10.522 0.000 - NaH[13C]O[18O]O 3.006e-11 3.008e-11 -10.522 -10.522 0.000 - NaH[13C][18O]O2 3.006e-11 3.008e-11 -10.522 -10.522 0.000 - Na[13C]O2[18O]- 2.326e-11 2.207e-11 -10.633 -10.656 -0.023 -[18O](-2) 1.114e-01 - H2[18O] 1.114e-01 2.001e-03 -0.953 -2.699 -1.746 - HD[18O] 3.470e-05 6.233e-07 -4.460 -6.205 -1.746 - HCO2[18O]- 3.842e-06 3.645e-06 -5.415 -5.438 -0.023 - HCO[18O]O- 3.842e-06 3.645e-06 -5.415 -5.438 -0.023 - HC[18O]O2- 3.842e-06 3.645e-06 -5.415 -5.438 -0.023 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -66.818 -66.818 0.000 - [18O]2 0.000e+00 0.000e+00 -69.817 -69.817 0.000 + OH- 1.661e-06 1.575e-06 -5.780 -5.803 -0.023 (0) + H3O+ 6.648e-09 6.328e-09 -8.177 -8.199 -0.021 (0) + H2O 5.556e+01 9.977e-01 1.745 -0.001 0.000 18.07 +C(-4) 3.053e-24 + CH4 3.051e-24 3.053e-24 -23.515 -23.515 0.000 (0) + CH3D 1.901e-27 1.902e-27 -26.721 -26.721 0.000 (0) +C(4) 1.984e-03 + HCO3- 1.916e-03 1.818e-03 -2.718 -2.741 -0.023 (0) + CO2 2.597e-05 2.598e-05 -4.586 -4.585 0.000 (0) + CO3-2 1.661e-05 1.344e-05 -4.780 -4.872 -0.092 (0) + CaHCO3+ 5.916e-06 5.618e-06 -5.228 -5.250 -0.023 (0) + CaCO3 5.466e-06 5.469e-06 -5.262 -5.262 0.000 (0) + HCO2[18O]- 3.842e-06 3.645e-06 -5.415 -5.438 -0.023 (0) + HCO[18O]O- 3.842e-06 3.645e-06 -5.415 -5.438 -0.023 (0) + HC[18O]O2- 3.842e-06 3.645e-06 -5.415 -5.438 -0.023 (0) + NaHCO3 1.341e-06 1.341e-06 -5.873 -5.872 0.000 (0) + NaCO3- 3.463e-07 3.285e-07 -6.460 -6.483 -0.023 (0) + DCO3- 2.985e-07 2.831e-07 -6.525 -6.548 -0.023 (0) + CO[18O] 1.085e-07 1.086e-07 -6.964 -6.964 0.000 (0) + CO2[18O]-2 9.991e-08 8.087e-08 -7.000 -7.092 -0.092 (0) + CaCO2[18O] 3.288e-08 3.290e-08 -7.483 -7.483 0.000 (0) + CaHCO2[18O]+ 1.186e-08 1.126e-08 -7.926 -7.948 -0.023 (0) + CaHCO[18O]O+ 1.186e-08 1.126e-08 -7.926 -7.948 -0.023 (0) + CaHC[18O]O2+ 1.186e-08 1.126e-08 -7.926 -7.948 -0.023 (0) + HCO[18O]2- 7.705e-09 7.308e-09 -8.113 -8.136 -0.023 (0) + HC[18O]2O- 7.705e-09 7.308e-09 -8.113 -8.136 -0.023 (0) + HC[18O]O[18O]- 7.705e-09 7.308e-09 -8.113 -8.136 -0.023 (0) + NaHCO2[18O] 2.688e-09 2.690e-09 -8.571 -8.570 0.000 (0) + NaHCO[18O]O 2.688e-09 2.690e-09 -8.571 -8.570 0.000 (0) + NaHC[18O]O2 2.688e-09 2.690e-09 -8.571 -8.570 0.000 (0) + NaCO2[18O]- 2.083e-09 1.976e-09 -8.681 -8.704 -0.023 (0) +Ca 3.097e-04 + Ca+2 2.981e-04 2.422e-04 -3.526 -3.616 -0.090 (0) + CaHCO3+ 5.916e-06 5.618e-06 -5.228 -5.250 -0.023 (0) + CaCO3 5.466e-06 5.469e-06 -5.262 -5.262 0.000 (0) + CaH[13C]O3+ 6.616e-08 6.281e-08 -7.179 -7.202 -0.023 (0) + Ca[13C]O3 6.104e-08 6.107e-08 -7.214 -7.214 0.000 (0) + CaCO2[18O] 3.288e-08 3.290e-08 -7.483 -7.483 0.000 (0) + CaHCO2[18O]+ 1.186e-08 1.126e-08 -7.926 -7.948 -0.023 (0) + CaHCO[18O]O+ 1.186e-08 1.126e-08 -7.926 -7.948 -0.023 (0) + CaHC[18O]O2+ 1.186e-08 1.126e-08 -7.926 -7.948 -0.023 (0) + CaDCO3+ 9.216e-10 8.750e-10 -9.035 -9.058 -0.023 (0) + Ca[13C]O2[18O] 3.672e-10 3.674e-10 -9.435 -9.435 0.000 (0) +D(0) 3.257e-18 + HD 3.256e-18 3.258e-18 -17.487 -17.487 0.000 (0) + D2 2.536e-22 2.537e-22 -21.596 -21.596 0.000 (0) +D(1) 1.734e-02 + HDO 1.731e-02 3.108e-04 -1.762 -3.507 -1.746 (0) + HD[18O] 3.470e-05 6.233e-07 -4.460 -6.205 -1.746 (0) + D2O 1.348e-06 2.421e-08 -5.870 -7.616 -1.746 (0) + DCO3- 2.985e-07 2.831e-07 -6.525 -6.548 -0.023 (0) +H(0) 2.091e-14 + H2 1.045e-14 1.046e-14 -13.981 -13.981 0.000 (0) + HD 3.256e-18 3.258e-18 -17.487 -17.487 0.000 (0) +Na 1.385e-03 + Na+ 1.383e-03 1.312e-03 -2.859 -2.882 -0.023 (0) + NaHCO3 1.341e-06 1.341e-06 -5.873 -5.872 0.000 (0) + NaCO3- 3.463e-07 3.285e-07 -6.460 -6.483 -0.023 (0) + NaH[13C]O3 1.499e-08 1.500e-08 -7.824 -7.824 0.000 (0) + Na[13C]O3- 3.867e-09 3.668e-09 -8.413 -8.436 -0.023 (0) + NaHCO2[18O] 2.688e-09 2.690e-09 -8.571 -8.570 0.000 (0) + NaHCO[18O]O 2.688e-09 2.690e-09 -8.571 -8.570 0.000 (0) + NaHC[18O]O2 2.688e-09 2.690e-09 -8.571 -8.570 0.000 (0) + NaCO2[18O]- 2.083e-09 1.976e-09 -8.681 -8.704 -0.023 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -64.421 -64.421 0.000 (0) + O[18O] 0.000e+00 0.000e+00 -66.818 -66.818 0.000 (0) +[13C](-4) 3.385e-26 + [13C]H4 3.383e-26 3.384e-26 -25.471 -25.471 0.000 (0) + [13C]H3D 2.107e-29 2.109e-29 -28.676 -28.676 0.000 (0) +[13C](4) 2.218e-05 + H[13C]O3- 2.143e-05 2.032e-05 -4.669 -4.692 -0.023 (0) + [13C]O2 2.879e-07 2.880e-07 -6.541 -6.541 0.000 (0) + [13C]O3-2 1.854e-07 1.501e-07 -6.732 -6.824 -0.092 (0) + CaH[13C]O3+ 6.616e-08 6.281e-08 -7.179 -7.202 -0.023 (0) + Ca[13C]O3 6.104e-08 6.107e-08 -7.214 -7.214 0.000 (0) + H[13C]O2[18O]- 4.296e-08 4.075e-08 -7.367 -7.390 -0.023 (0) + H[13C]O[18O]O- 4.296e-08 4.075e-08 -7.367 -7.390 -0.023 (0) + H[13C][18O]O2- 4.296e-08 4.075e-08 -7.367 -7.390 -0.023 (0) + NaH[13C]O3 1.499e-08 1.500e-08 -7.824 -7.824 0.000 (0) + Na[13C]O3- 3.867e-09 3.668e-09 -8.413 -8.436 -0.023 (0) + D[13C]O3- 3.337e-09 3.166e-09 -8.477 -8.500 -0.023 (0) + [13C]O[18O] 1.203e-09 1.204e-09 -8.920 -8.919 0.000 (0) + [13C]O2[18O]-2 1.116e-09 9.029e-10 -8.953 -9.044 -0.092 (0) + Ca[13C]O2[18O] 3.672e-10 3.674e-10 -9.435 -9.435 0.000 (0) + CaH[13C]O2[18O]+ 1.327e-10 1.260e-10 -9.877 -9.900 -0.023 (0) + CaH[13C]O[18O]O+ 1.327e-10 1.260e-10 -9.877 -9.900 -0.023 (0) + CaH[13C][18O]O2+ 1.327e-10 1.260e-10 -9.877 -9.900 -0.023 (0) + H[13C]O[18O]2- 8.615e-11 8.172e-11 -10.065 -10.088 -0.023 (0) + H[13C][18O]2O- 8.615e-11 8.172e-11 -10.065 -10.088 -0.023 (0) + H[13C][18O]O[18O]- 8.615e-11 8.172e-11 -10.065 -10.088 -0.023 (0) + NaH[13C]O2[18O] 3.006e-11 3.008e-11 -10.522 -10.522 0.000 (0) + NaH[13C]O[18O]O 3.006e-11 3.008e-11 -10.522 -10.522 0.000 (0) + NaH[13C][18O]O2 3.006e-11 3.008e-11 -10.522 -10.522 0.000 (0) + Na[13C]O2[18O]- 2.326e-11 2.207e-11 -10.633 -10.656 -0.023 (0) +[18O](-2) 1.114e-01 + H2[18O] 1.114e-01 2.001e-03 -0.953 -2.699 -1.746 (0) + HD[18O] 3.470e-05 6.233e-07 -4.460 -6.205 -1.746 (0) + HCO2[18O]- 3.842e-06 3.645e-06 -5.415 -5.438 -0.023 (0) + HCO[18O]O- 3.842e-06 3.645e-06 -5.415 -5.438 -0.023 (0) + HC[18O]O2- 3.842e-06 3.645e-06 -5.415 -5.438 -0.023 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -66.818 -66.818 0.000 (0) + [18O]2 0.000e+00 0.000e+00 -69.817 -69.817 0.000 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex20b.out b/ex20b.out index 031421d1..33d9607d 100644 --- a/ex20b.out +++ b/ex20b.out @@ -212,21 +212,21 @@ Calcite added: 0 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 3.919e-05 3.891e-05 -4.407 -4.410 -0.003 - OH- 2.591e-10 2.573e-10 -9.586 -9.590 -0.003 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -93.357 -93.357 0.000 -C(4) 3.444e-03 - CO2 3.405e-03 3.405e-03 -2.468 -2.468 0.000 - HCO3- 3.919e-05 3.890e-05 -4.407 -4.410 -0.003 -H(0) 2.144e-32 - H2 1.072e-32 1.072e-32 -31.970 -31.970 0.000 -O(0) 7.256e-29 - O2 3.628e-29 3.628e-29 -28.440 -28.440 0.000 + H3O+ 3.919e-05 3.891e-05 -4.407 -4.410 -0.003 (0) + OH- 2.591e-10 2.573e-10 -9.586 -9.590 -0.003 (0) + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -93.357 -93.357 0.000 (0) +C(4) 3.444e-03 + CO2 3.405e-03 3.405e-03 -2.468 -2.468 0.000 (0) + HCO3- 3.919e-05 3.890e-05 -4.407 -4.410 -0.003 (0) +H(0) 2.144e-32 + H2 1.072e-32 1.072e-32 -31.970 -31.970 0.000 (0) +O(0) 7.256e-29 + O2 3.628e-29 3.628e-29 -28.440 -28.440 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -388,89 +388,89 @@ Alpha 14C CH4(aq)/CO2(aq) 1 8.2157e-12 0 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.426e-06 1.369e-06 -5.846 -5.864 -0.018 - OH- 7.606e-09 7.283e-09 -8.119 -8.138 -0.019 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 8.991e-28 - CH4 8.991e-28 8.994e-28 -27.046 -27.046 0.000 -C(4) 3.912e-03 - CO2 2.907e-03 2.908e-03 -2.537 -2.536 0.000 - HCO3- 9.821e-04 9.406e-04 -3.008 -3.027 -0.019 - CO[18O] 1.209e-05 1.209e-05 -4.918 -4.918 0.000 - CaHCO3+ 5.242e-06 5.024e-06 -5.281 -5.299 -0.018 - HCO2[18O]- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 - HCO[18O]O- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 - HC[18O]O2- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 - CO3-2 3.822e-08 3.216e-08 -7.418 -7.493 -0.075 - CaCO3 2.261e-08 2.261e-08 -7.646 -7.646 0.000 - C[18O]2 1.257e-08 1.257e-08 -7.901 -7.901 0.000 - CaHCO2[18O]+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 - CaHCO[18O]O+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 - CaHC[18O]O2+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 -Ca 5.014e-04 - Ca+2 4.961e-04 4.185e-04 -3.304 -3.378 -0.074 - CaHCO3+ 5.242e-06 5.024e-06 -5.281 -5.299 -0.018 - CaH[13C]O3+ 5.771e-08 5.532e-08 -7.239 -7.257 -0.018 - CaCO3 2.261e-08 2.261e-08 -7.646 -7.646 0.000 - CaHCO2[18O]+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 - CaHCO[18O]O+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 - CaHC[18O]O2+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 -H(0) 8.423e-16 - H2 4.212e-16 4.213e-16 -15.376 -15.375 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -61.631 -61.631 0.000 - O[18O] 0.000e+00 0.000e+00 -64.030 -64.030 0.000 -[13C](-4) 9.814e-30 - [13C]H4 9.814e-30 9.817e-30 -29.008 -29.008 0.000 -[13C](4) 4.280e-05 - [13C]O2 3.173e-05 3.174e-05 -4.499 -4.498 0.000 - H[13C]O3- 1.081e-05 1.036e-05 -4.966 -4.985 -0.019 - [13C]O[18O] 1.319e-07 1.320e-07 -6.880 -6.879 0.000 - CaH[13C]O3+ 5.771e-08 5.532e-08 -7.239 -7.257 -0.018 - H[13C]O2[18O]- 2.157e-08 2.066e-08 -7.666 -7.685 -0.019 - H[13C]O[18O]O- 2.157e-08 2.066e-08 -7.666 -7.685 -0.019 - H[13C][18O]O2- 2.157e-08 2.066e-08 -7.666 -7.685 -0.019 - [13C]O3-2 4.202e-10 3.536e-10 -9.377 -9.451 -0.075 - Ca[13C]O3 2.485e-10 2.486e-10 -9.605 -9.604 0.000 - [13C][18O]2 1.372e-10 1.372e-10 -9.863 -9.863 0.000 - CaH[13C]O2[18O]+ 1.151e-10 1.104e-10 -9.939 -9.957 -0.018 - CaH[13C]O[18O]O+ 1.151e-10 1.104e-10 -9.939 -9.957 -0.018 - CaH[13C][18O]O2+ 1.151e-10 1.104e-10 -9.939 -9.957 -0.018 - H[13C]O[18O]2- 4.304e-11 4.123e-11 -10.366 -10.385 -0.019 - H[13C][18O]2O- 4.304e-11 4.123e-11 -10.366 -10.385 -0.019 - H[13C][18O]O[18O]- 4.304e-11 4.123e-11 -10.366 -10.385 -0.019 -[14C](-4) 9.292e-40 - [14C]H4 9.292e-40 9.295e-40 -39.032 -39.032 0.000 -[14C](4) 4.061e-15 - [14C]O2 3.004e-15 3.005e-15 -14.522 -14.522 0.000 - H[14C]O3- 1.033e-15 9.891e-16 -14.986 -15.005 -0.019 - [14C]O[18O] 1.249e-17 1.250e-17 -16.903 -16.903 0.000 - CaH[14C]O3+ 5.512e-18 5.283e-18 -17.259 -17.277 -0.018 - H[14C]O2[18O]- 2.060e-18 1.973e-18 -17.686 -17.705 -0.019 - H[14C]O[18O]O- 2.060e-18 1.973e-18 -17.686 -17.705 -0.019 - H[14C][18O]O2- 2.060e-18 1.973e-18 -17.686 -17.705 -0.019 - [14C]O3-2 4.007e-20 3.372e-20 -19.397 -19.472 -0.075 - Ca[14C]O3 2.370e-20 2.371e-20 -19.625 -19.625 0.000 - [14C][18O]2 1.299e-20 1.299e-20 -19.887 -19.886 0.000 - CaH[14C]O2[18O]+ 1.100e-20 1.054e-20 -19.959 -19.977 -0.018 - CaH[14C]O[18O]O+ 1.100e-20 1.054e-20 -19.959 -19.977 -0.018 - CaH[14C][18O]O2+ 1.100e-20 1.054e-20 -19.959 -19.977 -0.018 - H[14C]O[18O]2- 4.111e-21 3.937e-21 -20.386 -20.405 -0.019 - H[14C][18O]2O- 4.111e-21 3.937e-21 -20.386 -20.405 -0.019 - H[14C][18O]O[18O]- 4.111e-21 3.937e-21 -20.386 -20.405 -0.019 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - CO[18O] 1.209e-05 1.209e-05 -4.918 -4.918 0.000 - HCO2[18O]- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 - HCO[18O]O- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 - HC[18O]O2- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 - [13C]O[18O] 1.319e-07 1.320e-07 -6.880 -6.879 0.000 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -64.030 -64.030 0.000 - [18O]2 0.000e+00 0.000e+00 -67.031 -67.031 0.000 + H3O+ 1.426e-06 1.369e-06 -5.846 -5.864 -0.018 (0) + OH- 7.606e-09 7.283e-09 -8.119 -8.138 -0.019 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 8.991e-28 + CH4 8.991e-28 8.994e-28 -27.046 -27.046 0.000 (0) +C(4) 3.912e-03 + CO2 2.907e-03 2.908e-03 -2.537 -2.536 0.000 (0) + HCO3- 9.821e-04 9.406e-04 -3.008 -3.027 -0.019 (0) + CO[18O] 1.209e-05 1.209e-05 -4.918 -4.918 0.000 (0) + CaHCO3+ 5.242e-06 5.024e-06 -5.281 -5.299 -0.018 (0) + HCO2[18O]- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 (0) + HCO[18O]O- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 (0) + HC[18O]O2- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 (0) + CO3-2 3.822e-08 3.216e-08 -7.418 -7.493 -0.075 (0) + CaCO3 2.261e-08 2.261e-08 -7.646 -7.646 0.000 (0) + C[18O]2 1.257e-08 1.257e-08 -7.901 -7.901 0.000 (0) + CaHCO2[18O]+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 (0) + CaHCO[18O]O+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 (0) + CaHC[18O]O2+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 (0) +Ca 5.014e-04 + Ca+2 4.961e-04 4.185e-04 -3.304 -3.378 -0.074 (0) + CaHCO3+ 5.242e-06 5.024e-06 -5.281 -5.299 -0.018 (0) + CaH[13C]O3+ 5.771e-08 5.532e-08 -7.239 -7.257 -0.018 (0) + CaCO3 2.261e-08 2.261e-08 -7.646 -7.646 0.000 (0) + CaHCO2[18O]+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 (0) + CaHCO[18O]O+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 (0) + CaHC[18O]O2+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 (0) +H(0) 8.423e-16 + H2 4.212e-16 4.213e-16 -15.376 -15.375 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -61.631 -61.631 0.000 (0) + O[18O] 0.000e+00 0.000e+00 -64.030 -64.030 0.000 (0) +[13C](-4) 9.814e-30 + [13C]H4 9.814e-30 9.817e-30 -29.008 -29.008 0.000 (0) +[13C](4) 4.280e-05 + [13C]O2 3.173e-05 3.174e-05 -4.499 -4.498 0.000 (0) + H[13C]O3- 1.081e-05 1.036e-05 -4.966 -4.985 -0.019 (0) + [13C]O[18O] 1.319e-07 1.320e-07 -6.880 -6.879 0.000 (0) + CaH[13C]O3+ 5.771e-08 5.532e-08 -7.239 -7.257 -0.018 (0) + H[13C]O2[18O]- 2.157e-08 2.066e-08 -7.666 -7.685 -0.019 (0) + H[13C]O[18O]O- 2.157e-08 2.066e-08 -7.666 -7.685 -0.019 (0) + H[13C][18O]O2- 2.157e-08 2.066e-08 -7.666 -7.685 -0.019 (0) + [13C]O3-2 4.202e-10 3.536e-10 -9.377 -9.451 -0.075 (0) + Ca[13C]O3 2.485e-10 2.486e-10 -9.605 -9.604 0.000 (0) + [13C][18O]2 1.372e-10 1.372e-10 -9.863 -9.863 0.000 (0) + CaH[13C]O2[18O]+ 1.151e-10 1.104e-10 -9.939 -9.957 -0.018 (0) + CaH[13C]O[18O]O+ 1.151e-10 1.104e-10 -9.939 -9.957 -0.018 (0) + CaH[13C][18O]O2+ 1.151e-10 1.104e-10 -9.939 -9.957 -0.018 (0) + H[13C]O[18O]2- 4.304e-11 4.123e-11 -10.366 -10.385 -0.019 (0) + H[13C][18O]2O- 4.304e-11 4.123e-11 -10.366 -10.385 -0.019 (0) + H[13C][18O]O[18O]- 4.304e-11 4.123e-11 -10.366 -10.385 -0.019 (0) +[14C](-4) 9.292e-40 + [14C]H4 9.292e-40 9.295e-40 -39.032 -39.032 0.000 (0) +[14C](4) 4.061e-15 + [14C]O2 3.004e-15 3.005e-15 -14.522 -14.522 0.000 (0) + H[14C]O3- 1.033e-15 9.891e-16 -14.986 -15.005 -0.019 (0) + [14C]O[18O] 1.249e-17 1.250e-17 -16.903 -16.903 0.000 (0) + CaH[14C]O3+ 5.512e-18 5.283e-18 -17.259 -17.277 -0.018 (0) + H[14C]O2[18O]- 2.060e-18 1.973e-18 -17.686 -17.705 -0.019 (0) + H[14C]O[18O]O- 2.060e-18 1.973e-18 -17.686 -17.705 -0.019 (0) + H[14C][18O]O2- 2.060e-18 1.973e-18 -17.686 -17.705 -0.019 (0) + [14C]O3-2 4.007e-20 3.372e-20 -19.397 -19.472 -0.075 (0) + Ca[14C]O3 2.370e-20 2.371e-20 -19.625 -19.625 0.000 (0) + [14C][18O]2 1.299e-20 1.299e-20 -19.887 -19.886 0.000 (0) + CaH[14C]O2[18O]+ 1.100e-20 1.054e-20 -19.959 -19.977 -0.018 (0) + CaH[14C]O[18O]O+ 1.100e-20 1.054e-20 -19.959 -19.977 -0.018 (0) + CaH[14C][18O]O2+ 1.100e-20 1.054e-20 -19.959 -19.977 -0.018 (0) + H[14C]O[18O]2- 4.111e-21 3.937e-21 -20.386 -20.405 -0.019 (0) + H[14C][18O]2O- 4.111e-21 3.937e-21 -20.386 -20.405 -0.019 (0) + H[14C][18O]O[18O]- 4.111e-21 3.937e-21 -20.386 -20.405 -0.019 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + CO[18O] 1.209e-05 1.209e-05 -4.918 -4.918 0.000 (0) + HCO2[18O]- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 (0) + HCO[18O]O- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 (0) + HC[18O]O2- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 (0) + [13C]O[18O] 1.319e-07 1.320e-07 -6.880 -6.879 0.000 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -64.030 -64.030 0.000 (0) + [18O]2 0.000e+00 0.000e+00 -67.031 -67.031 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -644,93 +644,93 @@ Alpha 14C CO3-2/CO2(aq) 1.0146 14.452 14.452 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 6.145e-07 5.816e-07 -6.211 -6.235 -0.024 - OH- 1.821e-08 1.715e-08 -7.740 -7.766 -0.026 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -122.264 -122.263 0.000 -C(4) 4.408e-03 - CO2 2.414e-03 2.416e-03 -2.617 -2.617 0.000 - HCO3- 1.953e-03 1.840e-03 -2.709 -2.735 -0.026 - CaHCO3+ 1.937e-05 1.827e-05 -4.713 -4.738 -0.025 - CO[18O] 1.004e-05 1.005e-05 -4.998 -4.998 0.000 - HCO2[18O]- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 - HCO[18O]O- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 - HC[18O]O2- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 - CaCO3 1.935e-07 1.936e-07 -6.713 -6.713 0.000 - CO3-2 1.879e-07 1.481e-07 -6.726 -6.829 -0.103 - CaHCO2[18O]+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 - CaHCO[18O]O+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 - CaHC[18O]O2+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 - C[18O]2 1.044e-08 1.044e-08 -7.981 -7.981 0.000 - HCO[18O]2- 7.773e-09 7.323e-09 -8.109 -8.135 -0.026 - HC[18O]2O- 7.773e-09 7.323e-09 -8.109 -8.135 -0.026 - HC[18O]O[18O]- 7.773e-09 7.323e-09 -8.109 -8.135 -0.026 -Ca 1.003e-03 - Ca+2 9.830e-04 7.783e-04 -3.007 -3.109 -0.101 - CaHCO3+ 1.937e-05 1.827e-05 -4.713 -4.738 -0.025 - CaH[13C]O3+ 2.135e-07 2.014e-07 -6.671 -6.696 -0.025 - CaCO3 1.935e-07 1.936e-07 -6.713 -6.713 0.000 - CaHCO2[18O]+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 - CaHCO[18O]O+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 - CaHC[18O]O2+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 - Ca[13C]O3 2.129e-09 2.131e-09 -8.672 -8.671 0.000 - CaCO2[18O] 1.158e-09 1.159e-09 -8.936 -8.936 0.000 -H(0) 1.384e-39 - H2 6.920e-40 6.925e-40 -39.160 -39.160 0.000 -O(0) 1.738e-14 - O2 8.653e-15 8.659e-15 -14.063 -14.063 0.000 - O[18O] 3.453e-17 3.455e-17 -16.462 -16.462 0.000 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -124.225 -124.225 0.000 -[13C](4) 4.835e-05 - [13C]O2 2.638e-05 2.639e-05 -4.579 -4.578 0.000 - H[13C]O3- 2.152e-05 2.028e-05 -4.667 -4.693 -0.026 - CaH[13C]O3+ 2.135e-07 2.014e-07 -6.671 -6.696 -0.025 - [13C]O[18O] 1.097e-07 1.098e-07 -6.960 -6.960 0.000 - H[13C]O2[18O]- 4.294e-08 4.045e-08 -7.367 -7.393 -0.026 - H[13C]O[18O]O- 4.294e-08 4.045e-08 -7.367 -7.393 -0.026 - H[13C][18O]O2- 4.294e-08 4.045e-08 -7.367 -7.393 -0.026 - Ca[13C]O3 2.129e-09 2.131e-09 -8.672 -8.671 0.000 - [13C]O3-2 2.068e-09 1.630e-09 -8.684 -8.788 -0.103 - CaH[13C]O2[18O]+ 4.259e-10 4.018e-10 -9.371 -9.396 -0.025 - CaH[13C]O[18O]O+ 4.259e-10 4.018e-10 -9.371 -9.396 -0.025 - CaH[13C][18O]O2+ 4.259e-10 4.018e-10 -9.371 -9.396 -0.025 - [13C][18O]2 1.140e-10 1.141e-10 -9.943 -9.943 0.000 - H[13C]O[18O]2- 8.566e-11 8.071e-11 -10.067 -10.093 -0.026 - H[13C][18O]2O- 8.566e-11 8.071e-11 -10.067 -10.093 -0.026 - H[13C][18O]O[18O]- 8.566e-11 8.071e-11 -10.067 -10.093 -0.026 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -134.303 -134.302 0.000 -[14C](4) 4.061e-15 - [14C]O2 2.207e-15 2.208e-15 -14.656 -14.656 0.000 - H[14C]O3- 1.816e-15 1.711e-15 -14.741 -14.767 -0.026 - CaH[14C]O3+ 1.801e-17 1.699e-17 -16.744 -16.770 -0.025 - [14C]O[18O] 9.176e-18 9.182e-18 -17.037 -17.037 0.000 - H[14C]O2[18O]- 3.623e-18 3.414e-18 -17.441 -17.467 -0.026 - H[14C]O[18O]O- 3.623e-18 3.414e-18 -17.441 -17.467 -0.026 - H[14C][18O]O2- 3.623e-18 3.414e-18 -17.441 -17.467 -0.026 - Ca[14C]O3 1.794e-19 1.796e-19 -18.746 -18.746 0.000 - [14C]O3-2 1.743e-19 1.373e-19 -18.759 -18.862 -0.103 - CaH[14C]O2[18O]+ 3.594e-20 3.391e-20 -19.444 -19.470 -0.025 - CaH[14C]O[18O]O+ 3.594e-20 3.391e-20 -19.444 -19.470 -0.025 - CaH[14C][18O]O2+ 3.594e-20 3.391e-20 -19.444 -19.470 -0.025 - [14C][18O]2 9.539e-21 9.545e-21 -20.021 -20.020 0.000 - H[14C]O[18O]2- 7.229e-21 6.811e-21 -20.141 -20.167 -0.026 - H[14C][18O]2O- 7.229e-21 6.811e-21 -20.141 -20.167 -0.026 - H[14C][18O]O[18O]- 7.229e-21 6.811e-21 -20.141 -20.167 -0.026 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - CO[18O] 1.004e-05 1.005e-05 -4.998 -4.998 0.000 - HCO2[18O]- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 - HCO[18O]O- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 - HC[18O]O2- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 -[18O](0) 3.460e-17 - O[18O] 3.453e-17 3.455e-17 -16.462 -16.462 0.000 - [18O]2 3.444e-20 3.447e-20 -19.463 -19.463 0.000 + H3O+ 6.145e-07 5.816e-07 -6.211 -6.235 -0.024 (0) + OH- 1.821e-08 1.715e-08 -7.740 -7.766 -0.026 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -122.264 -122.263 0.000 (0) +C(4) 4.408e-03 + CO2 2.414e-03 2.416e-03 -2.617 -2.617 0.000 (0) + HCO3- 1.953e-03 1.840e-03 -2.709 -2.735 -0.026 (0) + CaHCO3+ 1.937e-05 1.827e-05 -4.713 -4.738 -0.025 (0) + CO[18O] 1.004e-05 1.005e-05 -4.998 -4.998 0.000 (0) + HCO2[18O]- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 (0) + HCO[18O]O- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 (0) + HC[18O]O2- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 (0) + CaCO3 1.935e-07 1.936e-07 -6.713 -6.713 0.000 (0) + CO3-2 1.879e-07 1.481e-07 -6.726 -6.829 -0.103 (0) + CaHCO2[18O]+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 (0) + CaHCO[18O]O+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 (0) + CaHC[18O]O2+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 (0) + C[18O]2 1.044e-08 1.044e-08 -7.981 -7.981 0.000 (0) + HCO[18O]2- 7.773e-09 7.323e-09 -8.109 -8.135 -0.026 (0) + HC[18O]2O- 7.773e-09 7.323e-09 -8.109 -8.135 -0.026 (0) + HC[18O]O[18O]- 7.773e-09 7.323e-09 -8.109 -8.135 -0.026 (0) +Ca 1.003e-03 + Ca+2 9.830e-04 7.783e-04 -3.007 -3.109 -0.101 (0) + CaHCO3+ 1.937e-05 1.827e-05 -4.713 -4.738 -0.025 (0) + CaH[13C]O3+ 2.135e-07 2.014e-07 -6.671 -6.696 -0.025 (0) + CaCO3 1.935e-07 1.936e-07 -6.713 -6.713 0.000 (0) + CaHCO2[18O]+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 (0) + CaHCO[18O]O+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 (0) + CaHC[18O]O2+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 (0) + Ca[13C]O3 2.129e-09 2.131e-09 -8.672 -8.671 0.000 (0) + CaCO2[18O] 1.158e-09 1.159e-09 -8.936 -8.936 0.000 (0) +H(0) 1.384e-39 + H2 6.920e-40 6.925e-40 -39.160 -39.160 0.000 (0) +O(0) 1.738e-14 + O2 8.653e-15 8.659e-15 -14.063 -14.063 0.000 (0) + O[18O] 3.453e-17 3.455e-17 -16.462 -16.462 0.000 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -124.225 -124.225 0.000 (0) +[13C](4) 4.835e-05 + [13C]O2 2.638e-05 2.639e-05 -4.579 -4.578 0.000 (0) + H[13C]O3- 2.152e-05 2.028e-05 -4.667 -4.693 -0.026 (0) + CaH[13C]O3+ 2.135e-07 2.014e-07 -6.671 -6.696 -0.025 (0) + [13C]O[18O] 1.097e-07 1.098e-07 -6.960 -6.960 0.000 (0) + H[13C]O2[18O]- 4.294e-08 4.045e-08 -7.367 -7.393 -0.026 (0) + H[13C]O[18O]O- 4.294e-08 4.045e-08 -7.367 -7.393 -0.026 (0) + H[13C][18O]O2- 4.294e-08 4.045e-08 -7.367 -7.393 -0.026 (0) + Ca[13C]O3 2.129e-09 2.131e-09 -8.672 -8.671 0.000 (0) + [13C]O3-2 2.068e-09 1.630e-09 -8.684 -8.788 -0.103 (0) + CaH[13C]O2[18O]+ 4.259e-10 4.018e-10 -9.371 -9.396 -0.025 (0) + CaH[13C]O[18O]O+ 4.259e-10 4.018e-10 -9.371 -9.396 -0.025 (0) + CaH[13C][18O]O2+ 4.259e-10 4.018e-10 -9.371 -9.396 -0.025 (0) + [13C][18O]2 1.140e-10 1.141e-10 -9.943 -9.943 0.000 (0) + H[13C]O[18O]2- 8.566e-11 8.071e-11 -10.067 -10.093 -0.026 (0) + H[13C][18O]2O- 8.566e-11 8.071e-11 -10.067 -10.093 -0.026 (0) + H[13C][18O]O[18O]- 8.566e-11 8.071e-11 -10.067 -10.093 -0.026 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -134.303 -134.302 0.000 (0) +[14C](4) 4.061e-15 + [14C]O2 2.207e-15 2.208e-15 -14.656 -14.656 0.000 (0) + H[14C]O3- 1.816e-15 1.711e-15 -14.741 -14.767 -0.026 (0) + CaH[14C]O3+ 1.801e-17 1.699e-17 -16.744 -16.770 -0.025 (0) + [14C]O[18O] 9.176e-18 9.182e-18 -17.037 -17.037 0.000 (0) + H[14C]O2[18O]- 3.623e-18 3.414e-18 -17.441 -17.467 -0.026 (0) + H[14C]O[18O]O- 3.623e-18 3.414e-18 -17.441 -17.467 -0.026 (0) + H[14C][18O]O2- 3.623e-18 3.414e-18 -17.441 -17.467 -0.026 (0) + Ca[14C]O3 1.794e-19 1.796e-19 -18.746 -18.746 0.000 (0) + [14C]O3-2 1.743e-19 1.373e-19 -18.759 -18.862 -0.103 (0) + CaH[14C]O2[18O]+ 3.594e-20 3.391e-20 -19.444 -19.470 -0.025 (0) + CaH[14C]O[18O]O+ 3.594e-20 3.391e-20 -19.444 -19.470 -0.025 (0) + CaH[14C][18O]O2+ 3.594e-20 3.391e-20 -19.444 -19.470 -0.025 (0) + [14C][18O]2 9.539e-21 9.545e-21 -20.021 -20.020 0.000 (0) + H[14C]O[18O]2- 7.229e-21 6.811e-21 -20.141 -20.167 -0.026 (0) + H[14C][18O]2O- 7.229e-21 6.811e-21 -20.141 -20.167 -0.026 (0) + H[14C][18O]O[18O]- 7.229e-21 6.811e-21 -20.141 -20.167 -0.026 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + CO[18O] 1.004e-05 1.005e-05 -4.998 -4.998 0.000 (0) + HCO2[18O]- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 (0) + HCO[18O]O- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 (0) + HC[18O]O2- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 (0) +[18O](0) 3.460e-17 + O[18O] 3.453e-17 3.455e-17 -16.462 -16.462 0.000 (0) + [18O]2 3.444e-20 3.447e-20 -19.463 -19.463 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -906,93 +906,93 @@ Alpha 14C CH4(aq)/CO2(aq) 1 1.7764e-12 0 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 3.351e-07 3.139e-07 -6.475 -6.503 -0.028 - OH- 3.415e-08 3.176e-08 -7.467 -7.498 -0.031 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 4.315e-22 - CH4 4.315e-22 4.320e-22 -21.365 -21.365 0.000 -C(4) 4.904e-03 - HCO3- 2.915e-03 2.713e-03 -2.535 -2.566 -0.031 - CO2 1.921e-03 1.923e-03 -2.716 -2.716 0.000 - CaHCO3+ 4.104e-05 3.827e-05 -4.387 -4.417 -0.030 - CO[18O] 7.989e-06 7.997e-06 -5.097 -5.097 0.000 - HCO2[18O]- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 - HCO[18O]O- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 - HC[18O]O2- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 - CaCO3 7.505e-07 7.513e-07 -6.125 -6.124 0.000 - CO3-2 5.389e-07 4.047e-07 -6.269 -6.393 -0.124 - CaHCO2[18O]+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 - CaHCO[18O]O+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 - CaHC[18O]O2+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 - HCO[18O]2- 1.160e-08 1.080e-08 -7.935 -7.967 -0.031 - HC[18O]2O- 1.160e-08 1.080e-08 -7.935 -7.967 -0.031 - HC[18O]O[18O]- 1.160e-08 1.080e-08 -7.935 -7.967 -0.031 - C[18O]2 8.305e-09 8.314e-09 -8.081 -8.080 0.000 -Ca 1.504e-03 - Ca+2 1.462e-03 1.105e-03 -2.835 -2.957 -0.121 - CaHCO3+ 4.104e-05 3.827e-05 -4.387 -4.417 -0.030 - CaCO3 7.505e-07 7.513e-07 -6.125 -6.124 0.000 - CaH[13C]O3+ 4.526e-07 4.221e-07 -6.344 -6.375 -0.030 - CaHCO2[18O]+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 - CaHCO[18O]O+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 - CaHC[18O]O2+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 - Ca[13C]O3 8.266e-09 8.275e-09 -8.083 -8.082 0.000 - CaCO2[18O] 4.492e-09 4.497e-09 -8.348 -8.347 0.000 -H(0) 2.457e-14 - H2 1.229e-14 1.230e-14 -13.911 -13.910 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -64.562 -64.561 0.000 - O[18O] 0.000e+00 0.000e+00 -66.961 -66.960 0.000 -[13C](-4) 4.719e-24 - [13C]H4 4.719e-24 4.724e-24 -23.326 -23.326 0.000 -[13C](4) 5.391e-05 - H[13C]O3- 3.215e-05 2.993e-05 -4.493 -4.524 -0.031 - [13C]O2 2.101e-05 2.103e-05 -4.678 -4.677 0.000 - CaH[13C]O3+ 4.526e-07 4.221e-07 -6.344 -6.375 -0.030 - [13C]O[18O] 8.736e-08 8.745e-08 -7.059 -7.058 0.000 - H[13C]O2[18O]- 6.415e-08 5.971e-08 -7.193 -7.224 -0.031 - H[13C]O[18O]O- 6.415e-08 5.971e-08 -7.193 -7.224 -0.031 - H[13C][18O]O2- 6.415e-08 5.971e-08 -7.193 -7.224 -0.031 - Ca[13C]O3 8.266e-09 8.275e-09 -8.083 -8.082 0.000 - [13C]O3-2 5.935e-09 4.457e-09 -8.227 -8.351 -0.124 - CaH[13C]O2[18O]+ 9.031e-10 8.422e-10 -9.044 -9.075 -0.030 - CaH[13C]O[18O]O+ 9.031e-10 8.422e-10 -9.044 -9.075 -0.030 - CaH[13C][18O]O2+ 9.031e-10 8.422e-10 -9.044 -9.075 -0.030 - H[13C]O[18O]2- 1.280e-10 1.191e-10 -9.893 -9.924 -0.031 - H[13C][18O]2O- 1.280e-10 1.191e-10 -9.893 -9.924 -0.031 - H[13C][18O]O[18O]- 1.280e-10 1.191e-10 -9.893 -9.924 -0.031 - [13C][18O]2 9.082e-11 9.091e-11 -10.042 -10.041 0.000 -[14C](-4) 3.536e-34 - [14C]H4 3.536e-34 3.540e-34 -33.451 -33.451 0.000 -[14C](4) 4.061e-15 - H[14C]O3- 2.430e-15 2.262e-15 -14.614 -14.645 -0.031 - [14C]O2 1.574e-15 1.576e-15 -14.803 -14.802 0.000 - CaH[14C]O3+ 3.421e-17 3.191e-17 -16.466 -16.496 -0.030 - [14C]O[18O] 6.547e-18 6.553e-18 -17.184 -17.184 0.000 - H[14C]O2[18O]- 4.849e-18 4.514e-18 -17.314 -17.345 -0.031 - H[14C]O[18O]O- 4.849e-18 4.514e-18 -17.314 -17.345 -0.031 - H[14C][18O]O2- 4.849e-18 4.514e-18 -17.314 -17.345 -0.031 - Ca[14C]O3 6.239e-19 6.246e-19 -18.205 -18.204 0.000 - [14C]O3-2 4.480e-19 3.364e-19 -18.349 -18.473 -0.124 - CaH[14C]O2[18O]+ 6.826e-20 6.366e-20 -19.166 -19.196 -0.030 - CaH[14C]O[18O]O+ 6.826e-20 6.366e-20 -19.166 -19.196 -0.030 - CaH[14C][18O]O2+ 6.826e-20 6.366e-20 -19.166 -19.196 -0.030 - H[14C]O[18O]2- 9.674e-21 9.006e-21 -20.014 -20.045 -0.031 - H[14C][18O]2O- 9.674e-21 9.006e-21 -20.014 -20.045 -0.031 - H[14C][18O]O[18O]- 9.674e-21 9.006e-21 -20.014 -20.045 -0.031 - [14C][18O]2 6.806e-21 6.813e-21 -20.167 -20.167 0.000 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - CO[18O] 7.989e-06 7.997e-06 -5.097 -5.097 0.000 - HCO2[18O]- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 - HCO[18O]O- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 - HC[18O]O2- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -66.961 -66.960 0.000 - [18O]2 0.000e+00 0.000e+00 -69.962 -69.961 0.000 + H3O+ 3.351e-07 3.139e-07 -6.475 -6.503 -0.028 (0) + OH- 3.415e-08 3.176e-08 -7.467 -7.498 -0.031 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 4.315e-22 + CH4 4.315e-22 4.320e-22 -21.365 -21.365 0.000 (0) +C(4) 4.904e-03 + HCO3- 2.915e-03 2.713e-03 -2.535 -2.566 -0.031 (0) + CO2 1.921e-03 1.923e-03 -2.716 -2.716 0.000 (0) + CaHCO3+ 4.104e-05 3.827e-05 -4.387 -4.417 -0.030 (0) + CO[18O] 7.989e-06 7.997e-06 -5.097 -5.097 0.000 (0) + HCO2[18O]- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 (0) + HCO[18O]O- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 (0) + HC[18O]O2- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 (0) + CaCO3 7.505e-07 7.513e-07 -6.125 -6.124 0.000 (0) + CO3-2 5.389e-07 4.047e-07 -6.269 -6.393 -0.124 (0) + CaHCO2[18O]+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 (0) + CaHCO[18O]O+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 (0) + CaHC[18O]O2+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 (0) + HCO[18O]2- 1.160e-08 1.080e-08 -7.935 -7.967 -0.031 (0) + HC[18O]2O- 1.160e-08 1.080e-08 -7.935 -7.967 -0.031 (0) + HC[18O]O[18O]- 1.160e-08 1.080e-08 -7.935 -7.967 -0.031 (0) + C[18O]2 8.305e-09 8.314e-09 -8.081 -8.080 0.000 (0) +Ca 1.504e-03 + Ca+2 1.462e-03 1.105e-03 -2.835 -2.957 -0.121 (0) + CaHCO3+ 4.104e-05 3.827e-05 -4.387 -4.417 -0.030 (0) + CaCO3 7.505e-07 7.513e-07 -6.125 -6.124 0.000 (0) + CaH[13C]O3+ 4.526e-07 4.221e-07 -6.344 -6.375 -0.030 (0) + CaHCO2[18O]+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 (0) + CaHCO[18O]O+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 (0) + CaHC[18O]O2+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 (0) + Ca[13C]O3 8.266e-09 8.275e-09 -8.083 -8.082 0.000 (0) + CaCO2[18O] 4.492e-09 4.497e-09 -8.348 -8.347 0.000 (0) +H(0) 2.457e-14 + H2 1.229e-14 1.230e-14 -13.911 -13.910 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -64.562 -64.561 0.000 (0) + O[18O] 0.000e+00 0.000e+00 -66.961 -66.960 0.000 (0) +[13C](-4) 4.719e-24 + [13C]H4 4.719e-24 4.724e-24 -23.326 -23.326 0.000 (0) +[13C](4) 5.391e-05 + H[13C]O3- 3.215e-05 2.993e-05 -4.493 -4.524 -0.031 (0) + [13C]O2 2.101e-05 2.103e-05 -4.678 -4.677 0.000 (0) + CaH[13C]O3+ 4.526e-07 4.221e-07 -6.344 -6.375 -0.030 (0) + [13C]O[18O] 8.736e-08 8.745e-08 -7.059 -7.058 0.000 (0) + H[13C]O2[18O]- 6.415e-08 5.971e-08 -7.193 -7.224 -0.031 (0) + H[13C]O[18O]O- 6.415e-08 5.971e-08 -7.193 -7.224 -0.031 (0) + H[13C][18O]O2- 6.415e-08 5.971e-08 -7.193 -7.224 -0.031 (0) + Ca[13C]O3 8.266e-09 8.275e-09 -8.083 -8.082 0.000 (0) + [13C]O3-2 5.935e-09 4.457e-09 -8.227 -8.351 -0.124 (0) + CaH[13C]O2[18O]+ 9.031e-10 8.422e-10 -9.044 -9.075 -0.030 (0) + CaH[13C]O[18O]O+ 9.031e-10 8.422e-10 -9.044 -9.075 -0.030 (0) + CaH[13C][18O]O2+ 9.031e-10 8.422e-10 -9.044 -9.075 -0.030 (0) + H[13C]O[18O]2- 1.280e-10 1.191e-10 -9.893 -9.924 -0.031 (0) + H[13C][18O]2O- 1.280e-10 1.191e-10 -9.893 -9.924 -0.031 (0) + H[13C][18O]O[18O]- 1.280e-10 1.191e-10 -9.893 -9.924 -0.031 (0) + [13C][18O]2 9.082e-11 9.091e-11 -10.042 -10.041 0.000 (0) +[14C](-4) 3.536e-34 + [14C]H4 3.536e-34 3.540e-34 -33.451 -33.451 0.000 (0) +[14C](4) 4.061e-15 + H[14C]O3- 2.430e-15 2.262e-15 -14.614 -14.645 -0.031 (0) + [14C]O2 1.574e-15 1.576e-15 -14.803 -14.802 0.000 (0) + CaH[14C]O3+ 3.421e-17 3.191e-17 -16.466 -16.496 -0.030 (0) + [14C]O[18O] 6.547e-18 6.553e-18 -17.184 -17.184 0.000 (0) + H[14C]O2[18O]- 4.849e-18 4.514e-18 -17.314 -17.345 -0.031 (0) + H[14C]O[18O]O- 4.849e-18 4.514e-18 -17.314 -17.345 -0.031 (0) + H[14C][18O]O2- 4.849e-18 4.514e-18 -17.314 -17.345 -0.031 (0) + Ca[14C]O3 6.239e-19 6.246e-19 -18.205 -18.204 0.000 (0) + [14C]O3-2 4.480e-19 3.364e-19 -18.349 -18.473 -0.124 (0) + CaH[14C]O2[18O]+ 6.826e-20 6.366e-20 -19.166 -19.196 -0.030 (0) + CaH[14C]O[18O]O+ 6.826e-20 6.366e-20 -19.166 -19.196 -0.030 (0) + CaH[14C][18O]O2+ 6.826e-20 6.366e-20 -19.166 -19.196 -0.030 (0) + H[14C]O[18O]2- 9.674e-21 9.006e-21 -20.014 -20.045 -0.031 (0) + H[14C][18O]2O- 9.674e-21 9.006e-21 -20.014 -20.045 -0.031 (0) + H[14C][18O]O[18O]- 9.674e-21 9.006e-21 -20.014 -20.045 -0.031 (0) + [14C][18O]2 6.806e-21 6.813e-21 -20.167 -20.167 0.000 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + CO[18O] 7.989e-06 7.997e-06 -5.097 -5.097 0.000 (0) + HCO2[18O]- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 (0) + HCO[18O]O- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 (0) + HC[18O]O2- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -66.961 -66.960 0.000 (0) + [18O]2 0.000e+00 0.000e+00 -69.962 -69.961 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -1168,102 +1168,102 @@ Alpha 14C CH4(aq)/CO2(aq) 1 6.8834e-12 0 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.913e-07 1.778e-07 -6.718 -6.750 -0.032 - OH- 6.090e-08 5.607e-08 -7.215 -7.251 -0.036 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.420e-21 - CH4 1.420e-21 1.422e-21 -20.848 -20.847 0.001 -C(4) 5.400e-03 - HCO3- 3.868e-03 3.566e-03 -2.413 -2.448 -0.035 - CO2 1.430e-03 1.432e-03 -2.845 -2.844 0.001 - CaHCO3+ 6.934e-05 6.406e-05 -4.159 -4.193 -0.034 - HCO2[18O]- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 - HCO[18O]O- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 - HC[18O]O2- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 - CO[18O] 5.945e-06 5.953e-06 -5.226 -5.225 0.001 - CaCO3 2.217e-06 2.220e-06 -5.654 -5.654 0.001 - CO3-2 1.300e-06 9.387e-07 -5.886 -6.027 -0.141 - CaHCO2[18O]+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 - CaHCO[18O]O+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 - CaHC[18O]O2+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 - HCO[18O]2- 1.540e-08 1.419e-08 -7.813 -7.848 -0.035 - HC[18O]2O- 1.540e-08 1.419e-08 -7.813 -7.848 -0.035 - HC[18O]O[18O]- 1.540e-08 1.419e-08 -7.813 -7.848 -0.035 - CaCO2[18O] 1.327e-08 1.329e-08 -7.877 -7.877 0.001 - CO2[18O]-2 7.781e-09 5.619e-09 -8.109 -8.250 -0.141 - C[18O]2 6.180e-09 6.189e-09 -8.209 -8.208 0.001 -Ca 2.006e-03 - Ca+2 1.933e-03 1.408e-03 -2.714 -2.851 -0.138 - CaHCO3+ 6.934e-05 6.406e-05 -4.159 -4.193 -0.034 - CaCO3 2.217e-06 2.220e-06 -5.654 -5.654 0.001 - CaH[13C]O3+ 7.653e-07 7.071e-07 -6.116 -6.151 -0.034 - CaHCO2[18O]+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 - CaHCO[18O]O+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 - CaHC[18O]O2+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 - Ca[13C]O3 2.444e-08 2.447e-08 -7.612 -7.611 0.001 - CaCO2[18O] 1.327e-08 1.329e-08 -7.877 -7.877 0.001 -H(0) 3.562e-14 - H2 1.781e-14 1.784e-14 -13.749 -13.749 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -64.885 -64.884 0.001 - O[18O] 0.000e+00 0.000e+00 -67.284 -67.283 0.001 -[13C](-4) 1.554e-23 - [13C]H4 1.554e-23 1.556e-23 -22.808 -22.808 0.001 -[13C](4) 5.947e-05 - H[13C]O3- 4.269e-05 3.935e-05 -4.370 -4.405 -0.035 - [13C]O2 1.564e-05 1.566e-05 -4.806 -4.805 0.001 - CaH[13C]O3+ 7.653e-07 7.071e-07 -6.116 -6.151 -0.034 - H[13C]O2[18O]- 8.518e-08 7.852e-08 -7.070 -7.105 -0.035 - H[13C]O[18O]O- 8.518e-08 7.852e-08 -7.070 -7.105 -0.035 - H[13C][18O]O2- 8.518e-08 7.852e-08 -7.070 -7.105 -0.035 - [13C]O[18O] 6.505e-08 6.514e-08 -7.187 -7.186 0.001 - Ca[13C]O3 2.444e-08 2.447e-08 -7.612 -7.611 0.001 - [13C]O3-2 1.433e-08 1.035e-08 -7.844 -7.985 -0.141 - CaH[13C]O2[18O]+ 1.527e-09 1.411e-09 -8.816 -8.851 -0.034 - CaH[13C]O[18O]O+ 1.527e-09 1.411e-09 -8.816 -8.851 -0.034 - CaH[13C][18O]O2+ 1.527e-09 1.411e-09 -8.816 -8.851 -0.034 - H[13C]O[18O]2- 1.699e-10 1.567e-10 -9.770 -9.805 -0.035 - H[13C][18O]2O- 1.699e-10 1.567e-10 -9.770 -9.805 -0.035 - H[13C][18O]O[18O]- 1.699e-10 1.567e-10 -9.770 -9.805 -0.035 - Ca[13C]O2[18O] 1.463e-10 1.465e-10 -9.835 -9.834 0.001 - [13C]O2[18O]-2 8.576e-11 6.193e-11 -10.067 -10.208 -0.141 - [13C][18O]2 6.763e-11 6.772e-11 -10.170 -10.169 0.001 -[14C](-4) 1.055e-33 - [14C]H4 1.055e-33 1.056e-33 -32.977 -32.976 0.001 -[14C](4) 4.061e-15 - H[14C]O3- 2.922e-15 2.694e-15 -14.534 -14.570 -0.035 - [14C]O2 1.062e-15 1.063e-15 -14.974 -14.973 0.001 - CaH[14C]O3+ 5.238e-17 4.840e-17 -16.281 -16.315 -0.034 - H[14C]O2[18O]- 5.831e-18 5.375e-18 -17.234 -17.270 -0.035 - H[14C]O[18O]O- 5.831e-18 5.375e-18 -17.234 -17.270 -0.035 - H[14C][18O]O2- 5.831e-18 5.375e-18 -17.234 -17.270 -0.035 - [14C]O[18O] 4.414e-18 4.420e-18 -17.355 -17.355 0.001 - Ca[14C]O3 1.670e-18 1.673e-18 -17.777 -17.777 0.001 - [14C]O3-2 9.793e-19 7.072e-19 -18.009 -18.150 -0.141 - CaH[14C]O2[18O]+ 1.045e-19 9.657e-20 -18.981 -19.015 -0.034 - CaH[14C]O[18O]O+ 1.045e-19 9.657e-20 -18.981 -19.015 -0.034 - CaH[14C][18O]O2+ 1.045e-19 9.657e-20 -18.981 -19.015 -0.034 - H[14C]O[18O]2- 1.163e-20 1.072e-20 -19.934 -19.970 -0.035 - H[14C][18O]2O- 1.163e-20 1.072e-20 -19.934 -19.970 -0.035 - H[14C][18O]O[18O]- 1.163e-20 1.072e-20 -19.934 -19.970 -0.035 - Ca[14C]O2[18O] 9.997e-21 1.001e-20 -20.000 -20.000 0.001 - [14C]O2[18O]-2 5.862e-21 4.233e-21 -20.232 -20.373 -0.141 - [14C][18O]2 4.589e-21 4.595e-21 -20.338 -20.338 0.001 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 - HCO[18O]O- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 - HC[18O]O2- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 - CO[18O] 5.945e-06 5.953e-06 -5.226 -5.225 0.001 - CaHCO2[18O]+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 - CaHCO[18O]O+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 - CaHC[18O]O2+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.284 -67.283 0.001 - [18O]2 0.000e+00 0.000e+00 -70.285 -70.284 0.001 + H3O+ 1.913e-07 1.778e-07 -6.718 -6.750 -0.032 (0) + OH- 6.090e-08 5.607e-08 -7.215 -7.251 -0.036 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.420e-21 + CH4 1.420e-21 1.422e-21 -20.848 -20.847 0.001 (0) +C(4) 5.400e-03 + HCO3- 3.868e-03 3.566e-03 -2.413 -2.448 -0.035 (0) + CO2 1.430e-03 1.432e-03 -2.845 -2.844 0.001 (0) + CaHCO3+ 6.934e-05 6.406e-05 -4.159 -4.193 -0.034 (0) + HCO2[18O]- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 (0) + HCO[18O]O- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 (0) + HC[18O]O2- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 (0) + CO[18O] 5.945e-06 5.953e-06 -5.226 -5.225 0.001 (0) + CaCO3 2.217e-06 2.220e-06 -5.654 -5.654 0.001 (0) + CO3-2 1.300e-06 9.387e-07 -5.886 -6.027 -0.141 (0) + CaHCO2[18O]+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) + CaHCO[18O]O+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) + CaHC[18O]O2+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) + HCO[18O]2- 1.540e-08 1.419e-08 -7.813 -7.848 -0.035 (0) + HC[18O]2O- 1.540e-08 1.419e-08 -7.813 -7.848 -0.035 (0) + HC[18O]O[18O]- 1.540e-08 1.419e-08 -7.813 -7.848 -0.035 (0) + CaCO2[18O] 1.327e-08 1.329e-08 -7.877 -7.877 0.001 (0) + CO2[18O]-2 7.781e-09 5.619e-09 -8.109 -8.250 -0.141 (0) + C[18O]2 6.180e-09 6.189e-09 -8.209 -8.208 0.001 (0) +Ca 2.006e-03 + Ca+2 1.933e-03 1.408e-03 -2.714 -2.851 -0.138 (0) + CaHCO3+ 6.934e-05 6.406e-05 -4.159 -4.193 -0.034 (0) + CaCO3 2.217e-06 2.220e-06 -5.654 -5.654 0.001 (0) + CaH[13C]O3+ 7.653e-07 7.071e-07 -6.116 -6.151 -0.034 (0) + CaHCO2[18O]+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) + CaHCO[18O]O+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) + CaHC[18O]O2+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) + Ca[13C]O3 2.444e-08 2.447e-08 -7.612 -7.611 0.001 (0) + CaCO2[18O] 1.327e-08 1.329e-08 -7.877 -7.877 0.001 (0) +H(0) 3.562e-14 + H2 1.781e-14 1.784e-14 -13.749 -13.749 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -64.885 -64.884 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.284 -67.283 0.001 (0) +[13C](-4) 1.554e-23 + [13C]H4 1.554e-23 1.556e-23 -22.808 -22.808 0.001 (0) +[13C](4) 5.947e-05 + H[13C]O3- 4.269e-05 3.935e-05 -4.370 -4.405 -0.035 (0) + [13C]O2 1.564e-05 1.566e-05 -4.806 -4.805 0.001 (0) + CaH[13C]O3+ 7.653e-07 7.071e-07 -6.116 -6.151 -0.034 (0) + H[13C]O2[18O]- 8.518e-08 7.852e-08 -7.070 -7.105 -0.035 (0) + H[13C]O[18O]O- 8.518e-08 7.852e-08 -7.070 -7.105 -0.035 (0) + H[13C][18O]O2- 8.518e-08 7.852e-08 -7.070 -7.105 -0.035 (0) + [13C]O[18O] 6.505e-08 6.514e-08 -7.187 -7.186 0.001 (0) + Ca[13C]O3 2.444e-08 2.447e-08 -7.612 -7.611 0.001 (0) + [13C]O3-2 1.433e-08 1.035e-08 -7.844 -7.985 -0.141 (0) + CaH[13C]O2[18O]+ 1.527e-09 1.411e-09 -8.816 -8.851 -0.034 (0) + CaH[13C]O[18O]O+ 1.527e-09 1.411e-09 -8.816 -8.851 -0.034 (0) + CaH[13C][18O]O2+ 1.527e-09 1.411e-09 -8.816 -8.851 -0.034 (0) + H[13C]O[18O]2- 1.699e-10 1.567e-10 -9.770 -9.805 -0.035 (0) + H[13C][18O]2O- 1.699e-10 1.567e-10 -9.770 -9.805 -0.035 (0) + H[13C][18O]O[18O]- 1.699e-10 1.567e-10 -9.770 -9.805 -0.035 (0) + Ca[13C]O2[18O] 1.463e-10 1.465e-10 -9.835 -9.834 0.001 (0) + [13C]O2[18O]-2 8.576e-11 6.193e-11 -10.067 -10.208 -0.141 (0) + [13C][18O]2 6.763e-11 6.772e-11 -10.170 -10.169 0.001 (0) +[14C](-4) 1.055e-33 + [14C]H4 1.055e-33 1.056e-33 -32.977 -32.976 0.001 (0) +[14C](4) 4.061e-15 + H[14C]O3- 2.922e-15 2.694e-15 -14.534 -14.570 -0.035 (0) + [14C]O2 1.062e-15 1.063e-15 -14.974 -14.973 0.001 (0) + CaH[14C]O3+ 5.238e-17 4.840e-17 -16.281 -16.315 -0.034 (0) + H[14C]O2[18O]- 5.831e-18 5.375e-18 -17.234 -17.270 -0.035 (0) + H[14C]O[18O]O- 5.831e-18 5.375e-18 -17.234 -17.270 -0.035 (0) + H[14C][18O]O2- 5.831e-18 5.375e-18 -17.234 -17.270 -0.035 (0) + [14C]O[18O] 4.414e-18 4.420e-18 -17.355 -17.355 0.001 (0) + Ca[14C]O3 1.670e-18 1.673e-18 -17.777 -17.777 0.001 (0) + [14C]O3-2 9.793e-19 7.072e-19 -18.009 -18.150 -0.141 (0) + CaH[14C]O2[18O]+ 1.045e-19 9.657e-20 -18.981 -19.015 -0.034 (0) + CaH[14C]O[18O]O+ 1.045e-19 9.657e-20 -18.981 -19.015 -0.034 (0) + CaH[14C][18O]O2+ 1.045e-19 9.657e-20 -18.981 -19.015 -0.034 (0) + H[14C]O[18O]2- 1.163e-20 1.072e-20 -19.934 -19.970 -0.035 (0) + H[14C][18O]2O- 1.163e-20 1.072e-20 -19.934 -19.970 -0.035 (0) + H[14C][18O]O[18O]- 1.163e-20 1.072e-20 -19.934 -19.970 -0.035 (0) + Ca[14C]O2[18O] 9.997e-21 1.001e-20 -20.000 -20.000 0.001 (0) + [14C]O2[18O]-2 5.862e-21 4.233e-21 -20.232 -20.373 -0.141 (0) + [14C][18O]2 4.589e-21 4.595e-21 -20.338 -20.338 0.001 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 (0) + HCO[18O]O- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 (0) + HC[18O]O2- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 (0) + CO[18O] 5.945e-06 5.953e-06 -5.226 -5.225 0.001 (0) + CaHCO2[18O]+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) + CaHCO[18O]O+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) + CaHC[18O]O2+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.284 -67.283 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.285 -70.284 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -1445,99 +1445,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.350e-20 - CH4 1.350e-20 1.352e-20 -19.870 -19.869 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.304e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.979e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.936e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.936e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.097e-06 1.007e-06 -5.960 -5.997 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.023e-08 6.033e-08 -7.220 -7.219 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 6.844e-14 - H2 3.422e-14 3.428e-14 -13.466 -13.465 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.452 -65.452 0.001 - O[18O] 0.000e+00 0.000e+00 -67.851 -67.851 0.001 -[13C](-4) 1.478e-22 - [13C]H4 1.478e-22 1.481e-22 -21.830 -21.830 0.001 -[13C](4) 6.440e-05 - H[13C]O3- 5.194e-05 4.753e-05 -4.284 -4.323 -0.039 - [13C]O2 1.091e-05 1.093e-05 -4.962 -4.962 0.001 - CaH[13C]O3+ 1.097e-06 1.007e-06 -5.960 -5.997 -0.037 - H[13C]O2[18O]- 1.036e-07 9.483e-08 -6.984 -7.023 -0.039 - H[13C]O[18O]O- 1.036e-07 9.483e-08 -6.984 -7.023 -0.039 - H[13C][18O]O2- 1.036e-07 9.483e-08 -6.984 -7.023 -0.039 - Ca[13C]O3 6.023e-08 6.033e-08 -7.220 -7.219 0.001 - [13C]O[18O] 4.536e-08 4.543e-08 -7.343 -7.343 0.001 - [13C]O3-2 3.087e-08 2.164e-08 -7.510 -7.665 -0.154 - CaH[13C]O2[18O]+ 2.189e-09 2.009e-09 -8.660 -8.697 -0.037 - CaH[13C]O[18O]O+ 2.189e-09 2.009e-09 -8.660 -8.697 -0.037 - CaH[13C][18O]O2+ 2.189e-09 2.009e-09 -8.660 -8.697 -0.037 - Ca[13C]O2[18O] 3.605e-10 3.611e-10 -9.443 -9.442 0.001 - H[13C]O[18O]2- 2.068e-10 1.892e-10 -9.685 -9.723 -0.039 - H[13C][18O]2O- 2.068e-10 1.892e-10 -9.685 -9.723 -0.039 - H[13C][18O]O[18O]- 2.068e-10 1.892e-10 -9.685 -9.723 -0.039 - [13C]O2[18O]-2 1.848e-10 1.295e-10 -9.733 -9.888 -0.154 -[14C](-4) 9.167e-33 - [14C]H4 9.167e-33 9.182e-33 -32.038 -32.037 0.001 -[14C](4) 4.023e-15 - H[14C]O3- 3.249e-15 2.973e-15 -14.488 -14.527 -0.039 - [14C]O2 6.764e-16 6.775e-16 -15.170 -15.169 0.001 - CaH[14C]O3+ 6.863e-17 6.297e-17 -16.163 -16.201 -0.037 - H[14C]O2[18O]- 6.483e-18 5.931e-18 -17.188 -17.227 -0.039 - H[14C]O[18O]O- 6.483e-18 5.931e-18 -17.188 -17.227 -0.039 - H[14C][18O]O2- 6.483e-18 5.931e-18 -17.188 -17.227 -0.039 - Ca[14C]O3 3.762e-18 3.768e-18 -17.425 -17.424 0.001 - [14C]O[18O] 2.813e-18 2.817e-18 -17.551 -17.550 0.001 - [14C]O3-2 1.928e-18 1.351e-18 -17.715 -17.869 -0.154 - CaH[14C]O2[18O]+ 1.369e-19 1.256e-19 -18.863 -18.901 -0.037 - CaH[14C]O[18O]O+ 1.369e-19 1.256e-19 -18.863 -18.901 -0.037 - CaH[14C][18O]O2+ 1.369e-19 1.256e-19 -18.863 -18.901 -0.037 - Ca[14C]O2[18O] 2.252e-20 2.255e-20 -19.648 -19.647 0.001 - H[14C]O[18O]2- 1.293e-20 1.183e-20 -19.888 -19.927 -0.039 - H[14C][18O]2O- 1.293e-20 1.183e-20 -19.888 -19.927 -0.039 - H[14C][18O]O[18O]- 1.293e-20 1.183e-20 -19.888 -19.927 -0.039 - [14C]O2[18O]-2 1.154e-20 8.089e-21 -19.938 -20.092 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.851 -67.851 0.001 - [18O]2 0.000e+00 0.000e+00 -70.853 -70.852 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.350e-20 + CH4 1.350e-20 1.352e-20 -19.870 -19.869 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.304e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.979e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.936e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.936e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.097e-06 1.007e-06 -5.960 -5.997 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.023e-08 6.033e-08 -7.220 -7.219 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 6.844e-14 + H2 3.422e-14 3.428e-14 -13.466 -13.465 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.452 -65.452 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.851 -67.851 0.001 (0) +[13C](-4) 1.478e-22 + [13C]H4 1.478e-22 1.481e-22 -21.830 -21.830 0.001 (0) +[13C](4) 6.440e-05 + H[13C]O3- 5.194e-05 4.753e-05 -4.284 -4.323 -0.039 (0) + [13C]O2 1.091e-05 1.093e-05 -4.962 -4.962 0.001 (0) + CaH[13C]O3+ 1.097e-06 1.007e-06 -5.960 -5.997 -0.037 (0) + H[13C]O2[18O]- 1.036e-07 9.483e-08 -6.984 -7.023 -0.039 (0) + H[13C]O[18O]O- 1.036e-07 9.483e-08 -6.984 -7.023 -0.039 (0) + H[13C][18O]O2- 1.036e-07 9.483e-08 -6.984 -7.023 -0.039 (0) + Ca[13C]O3 6.023e-08 6.033e-08 -7.220 -7.219 0.001 (0) + [13C]O[18O] 4.536e-08 4.543e-08 -7.343 -7.343 0.001 (0) + [13C]O3-2 3.087e-08 2.164e-08 -7.510 -7.665 -0.154 (0) + CaH[13C]O2[18O]+ 2.189e-09 2.009e-09 -8.660 -8.697 -0.037 (0) + CaH[13C]O[18O]O+ 2.189e-09 2.009e-09 -8.660 -8.697 -0.037 (0) + CaH[13C][18O]O2+ 2.189e-09 2.009e-09 -8.660 -8.697 -0.037 (0) + Ca[13C]O2[18O] 3.605e-10 3.611e-10 -9.443 -9.442 0.001 (0) + H[13C]O[18O]2- 2.068e-10 1.892e-10 -9.685 -9.723 -0.039 (0) + H[13C][18O]2O- 2.068e-10 1.892e-10 -9.685 -9.723 -0.039 (0) + H[13C][18O]O[18O]- 2.068e-10 1.892e-10 -9.685 -9.723 -0.039 (0) + [13C]O2[18O]-2 1.848e-10 1.295e-10 -9.733 -9.888 -0.154 (0) +[14C](-4) 9.167e-33 + [14C]H4 9.167e-33 9.182e-33 -32.038 -32.037 0.001 (0) +[14C](4) 4.023e-15 + H[14C]O3- 3.249e-15 2.973e-15 -14.488 -14.527 -0.039 (0) + [14C]O2 6.764e-16 6.775e-16 -15.170 -15.169 0.001 (0) + CaH[14C]O3+ 6.863e-17 6.297e-17 -16.163 -16.201 -0.037 (0) + H[14C]O2[18O]- 6.483e-18 5.931e-18 -17.188 -17.227 -0.039 (0) + H[14C]O[18O]O- 6.483e-18 5.931e-18 -17.188 -17.227 -0.039 (0) + H[14C][18O]O2- 6.483e-18 5.931e-18 -17.188 -17.227 -0.039 (0) + Ca[14C]O3 3.762e-18 3.768e-18 -17.425 -17.424 0.001 (0) + [14C]O[18O] 2.813e-18 2.817e-18 -17.551 -17.550 0.001 (0) + [14C]O3-2 1.928e-18 1.351e-18 -17.715 -17.869 -0.154 (0) + CaH[14C]O2[18O]+ 1.369e-19 1.256e-19 -18.863 -18.901 -0.037 (0) + CaH[14C]O[18O]O+ 1.369e-19 1.256e-19 -18.863 -18.901 -0.037 (0) + CaH[14C][18O]O2+ 1.369e-19 1.256e-19 -18.863 -18.901 -0.037 (0) + Ca[14C]O2[18O] 2.252e-20 2.255e-20 -19.648 -19.647 0.001 (0) + H[14C]O[18O]2- 1.293e-20 1.183e-20 -19.888 -19.927 -0.039 (0) + H[14C][18O]2O- 1.293e-20 1.183e-20 -19.888 -19.927 -0.039 (0) + H[14C][18O]O[18O]- 1.293e-20 1.183e-20 -19.888 -19.927 -0.039 (0) + [14C]O2[18O]-2 1.154e-20 8.089e-21 -19.938 -20.092 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.851 -67.851 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.853 -70.852 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -1719,99 +1719,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.073e-20 - CH4 1.073e-20 1.074e-20 -19.970 -19.969 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.304e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.979e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.098e-06 1.008e-06 -5.959 -5.997 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.028e-08 6.038e-08 -7.220 -7.219 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 6.461e-14 - H2 3.231e-14 3.236e-14 -13.491 -13.490 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.402 -65.402 0.001 - O[18O] 0.000e+00 0.000e+00 -67.801 -67.801 0.001 -[13C](-4) 1.175e-22 - [13C]H4 1.175e-22 1.177e-22 -21.930 -21.929 0.001 -[13C](4) 6.447e-05 - H[13C]O3- 5.199e-05 4.757e-05 -4.284 -4.323 -0.039 - [13C]O2 1.092e-05 1.094e-05 -4.962 -4.961 0.001 - CaH[13C]O3+ 1.098e-06 1.008e-06 -5.959 -5.997 -0.037 - H[13C]O2[18O]- 1.037e-07 9.492e-08 -6.984 -7.023 -0.039 - H[13C]O[18O]O- 1.037e-07 9.492e-08 -6.984 -7.023 -0.039 - H[13C][18O]O2- 1.037e-07 9.492e-08 -6.984 -7.023 -0.039 - Ca[13C]O3 6.028e-08 6.038e-08 -7.220 -7.219 0.001 - [13C]O[18O] 4.540e-08 4.548e-08 -7.343 -7.342 0.001 - [13C]O3-2 3.090e-08 2.166e-08 -7.510 -7.664 -0.154 - CaH[13C]O2[18O]+ 2.191e-09 2.010e-09 -8.659 -8.697 -0.037 - CaH[13C]O[18O]O+ 2.191e-09 2.010e-09 -8.659 -8.697 -0.037 - CaH[13C][18O]O2+ 2.191e-09 2.010e-09 -8.659 -8.697 -0.037 - Ca[13C]O2[18O] 3.608e-10 3.614e-10 -9.443 -9.442 0.001 - H[13C]O[18O]2- 2.070e-10 1.894e-10 -9.684 -9.723 -0.039 - H[13C][18O]2O- 2.070e-10 1.894e-10 -9.684 -9.723 -0.039 - H[13C][18O]O[18O]- 2.070e-10 1.894e-10 -9.684 -9.723 -0.039 - [13C]O2[18O]-2 1.849e-10 1.296e-10 -9.733 -9.887 -0.154 -[14C](-4) 6.708e-33 - [14C]H4 6.708e-33 6.720e-33 -32.173 -32.173 0.001 -[14C](4) 3.706e-15 - H[14C]O3- 2.993e-15 2.739e-15 -14.524 -14.562 -0.039 - [14C]O2 6.231e-16 6.241e-16 -15.205 -15.205 0.001 - CaH[14C]O3+ 6.323e-17 5.801e-17 -16.199 -16.237 -0.037 - H[14C]O2[18O]- 5.972e-18 5.464e-18 -17.224 -17.262 -0.039 - H[14C]O[18O]O- 5.972e-18 5.464e-18 -17.224 -17.262 -0.039 - H[14C][18O]O2- 5.972e-18 5.464e-18 -17.224 -17.262 -0.039 - Ca[14C]O3 3.465e-18 3.471e-18 -17.460 -17.460 0.001 - [14C]O[18O] 2.591e-18 2.595e-18 -17.587 -17.586 0.001 - [14C]O3-2 1.776e-18 1.245e-18 -17.751 -17.905 -0.154 - CaH[14C]O2[18O]+ 1.262e-19 1.157e-19 -18.899 -18.937 -0.037 - CaH[14C]O[18O]O+ 1.262e-19 1.157e-19 -18.899 -18.937 -0.037 - CaH[14C][18O]O2+ 1.262e-19 1.157e-19 -18.899 -18.937 -0.037 - Ca[14C]O2[18O] 2.074e-20 2.078e-20 -19.683 -19.682 0.001 - H[14C]O[18O]2- 1.191e-20 1.090e-20 -19.924 -19.962 -0.039 - H[14C][18O]2O- 1.191e-20 1.090e-20 -19.924 -19.962 -0.039 - H[14C][18O]O[18O]- 1.191e-20 1.090e-20 -19.924 -19.962 -0.039 - [14C]O2[18O]-2 1.063e-20 7.452e-21 -19.973 -20.128 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.801 -67.801 0.001 - [18O]2 0.000e+00 0.000e+00 -70.803 -70.802 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.073e-20 + CH4 1.073e-20 1.074e-20 -19.970 -19.969 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.304e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.979e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.098e-06 1.008e-06 -5.959 -5.997 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.028e-08 6.038e-08 -7.220 -7.219 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 6.461e-14 + H2 3.231e-14 3.236e-14 -13.491 -13.490 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.402 -65.402 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.801 -67.801 0.001 (0) +[13C](-4) 1.175e-22 + [13C]H4 1.175e-22 1.177e-22 -21.930 -21.929 0.001 (0) +[13C](4) 6.447e-05 + H[13C]O3- 5.199e-05 4.757e-05 -4.284 -4.323 -0.039 (0) + [13C]O2 1.092e-05 1.094e-05 -4.962 -4.961 0.001 (0) + CaH[13C]O3+ 1.098e-06 1.008e-06 -5.959 -5.997 -0.037 (0) + H[13C]O2[18O]- 1.037e-07 9.492e-08 -6.984 -7.023 -0.039 (0) + H[13C]O[18O]O- 1.037e-07 9.492e-08 -6.984 -7.023 -0.039 (0) + H[13C][18O]O2- 1.037e-07 9.492e-08 -6.984 -7.023 -0.039 (0) + Ca[13C]O3 6.028e-08 6.038e-08 -7.220 -7.219 0.001 (0) + [13C]O[18O] 4.540e-08 4.548e-08 -7.343 -7.342 0.001 (0) + [13C]O3-2 3.090e-08 2.166e-08 -7.510 -7.664 -0.154 (0) + CaH[13C]O2[18O]+ 2.191e-09 2.010e-09 -8.659 -8.697 -0.037 (0) + CaH[13C]O[18O]O+ 2.191e-09 2.010e-09 -8.659 -8.697 -0.037 (0) + CaH[13C][18O]O2+ 2.191e-09 2.010e-09 -8.659 -8.697 -0.037 (0) + Ca[13C]O2[18O] 3.608e-10 3.614e-10 -9.443 -9.442 0.001 (0) + H[13C]O[18O]2- 2.070e-10 1.894e-10 -9.684 -9.723 -0.039 (0) + H[13C][18O]2O- 2.070e-10 1.894e-10 -9.684 -9.723 -0.039 (0) + H[13C][18O]O[18O]- 2.070e-10 1.894e-10 -9.684 -9.723 -0.039 (0) + [13C]O2[18O]-2 1.849e-10 1.296e-10 -9.733 -9.887 -0.154 (0) +[14C](-4) 6.708e-33 + [14C]H4 6.708e-33 6.720e-33 -32.173 -32.173 0.001 (0) +[14C](4) 3.706e-15 + H[14C]O3- 2.993e-15 2.739e-15 -14.524 -14.562 -0.039 (0) + [14C]O2 6.231e-16 6.241e-16 -15.205 -15.205 0.001 (0) + CaH[14C]O3+ 6.323e-17 5.801e-17 -16.199 -16.237 -0.037 (0) + H[14C]O2[18O]- 5.972e-18 5.464e-18 -17.224 -17.262 -0.039 (0) + H[14C]O[18O]O- 5.972e-18 5.464e-18 -17.224 -17.262 -0.039 (0) + H[14C][18O]O2- 5.972e-18 5.464e-18 -17.224 -17.262 -0.039 (0) + Ca[14C]O3 3.465e-18 3.471e-18 -17.460 -17.460 0.001 (0) + [14C]O[18O] 2.591e-18 2.595e-18 -17.587 -17.586 0.001 (0) + [14C]O3-2 1.776e-18 1.245e-18 -17.751 -17.905 -0.154 (0) + CaH[14C]O2[18O]+ 1.262e-19 1.157e-19 -18.899 -18.937 -0.037 (0) + CaH[14C]O[18O]O+ 1.262e-19 1.157e-19 -18.899 -18.937 -0.037 (0) + CaH[14C][18O]O2+ 1.262e-19 1.157e-19 -18.899 -18.937 -0.037 (0) + Ca[14C]O2[18O] 2.074e-20 2.078e-20 -19.683 -19.682 0.001 (0) + H[14C]O[18O]2- 1.191e-20 1.090e-20 -19.924 -19.962 -0.039 (0) + H[14C][18O]2O- 1.191e-20 1.090e-20 -19.924 -19.962 -0.039 (0) + H[14C][18O]O[18O]- 1.191e-20 1.090e-20 -19.924 -19.962 -0.039 (0) + [14C]O2[18O]-2 1.063e-20 7.452e-21 -19.973 -20.128 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.801 -67.801 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.803 -70.802 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -1993,99 +1993,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 5.520e-21 - CH4 5.520e-21 5.529e-21 -20.258 -20.257 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.979e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.099e-06 1.009e-06 -5.959 -5.996 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.034e-08 6.044e-08 -7.219 -7.219 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 5.473e-14 - H2 2.736e-14 2.741e-14 -13.563 -13.562 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.258 -65.258 0.001 - O[18O] 0.000e+00 0.000e+00 -67.657 -67.657 0.001 -[13C](-4) 6.055e-23 - [13C]H4 6.055e-23 6.065e-23 -22.218 -22.217 0.001 -[13C](4) 6.452e-05 - H[13C]O3- 5.204e-05 4.762e-05 -4.284 -4.322 -0.039 - [13C]O2 1.093e-05 1.095e-05 -4.961 -4.961 0.001 - CaH[13C]O3+ 1.099e-06 1.009e-06 -5.959 -5.996 -0.037 - H[13C]O2[18O]- 1.038e-07 9.500e-08 -6.984 -7.022 -0.039 - H[13C]O[18O]O- 1.038e-07 9.500e-08 -6.984 -7.022 -0.039 - H[13C][18O]O2- 1.038e-07 9.500e-08 -6.984 -7.022 -0.039 - Ca[13C]O3 6.034e-08 6.044e-08 -7.219 -7.219 0.001 - [13C]O[18O] 4.544e-08 4.552e-08 -7.343 -7.342 0.001 - [13C]O3-2 3.093e-08 2.168e-08 -7.510 -7.664 -0.154 - CaH[13C]O2[18O]+ 2.193e-09 2.012e-09 -8.659 -8.696 -0.037 - CaH[13C]O[18O]O+ 2.193e-09 2.012e-09 -8.659 -8.696 -0.037 - CaH[13C][18O]O2+ 2.193e-09 2.012e-09 -8.659 -8.696 -0.037 - Ca[13C]O2[18O] 3.612e-10 3.618e-10 -9.442 -9.442 0.001 - H[13C]O[18O]2- 2.072e-10 1.895e-10 -9.684 -9.722 -0.039 - H[13C][18O]2O- 2.072e-10 1.895e-10 -9.684 -9.722 -0.039 - H[13C][18O]O[18O]- 2.072e-10 1.895e-10 -9.684 -9.722 -0.039 - [13C]O2[18O]-2 1.851e-10 1.297e-10 -9.733 -9.887 -0.154 -[14C](-4) 3.180e-33 - [14C]H4 3.180e-33 3.186e-33 -32.498 -32.497 0.001 -[14C](4) 3.414e-15 - H[14C]O3- 2.757e-15 2.523e-15 -14.560 -14.598 -0.039 - [14C]O2 5.740e-16 5.750e-16 -15.241 -15.240 0.001 - CaH[14C]O3+ 5.825e-17 5.344e-17 -16.235 -16.272 -0.037 - H[14C]O2[18O]- 5.501e-18 5.034e-18 -17.260 -17.298 -0.039 - H[14C]O[18O]O- 5.501e-18 5.034e-18 -17.260 -17.298 -0.039 - H[14C][18O]O2- 5.501e-18 5.034e-18 -17.260 -17.298 -0.039 - Ca[14C]O3 3.192e-18 3.198e-18 -17.496 -17.495 0.001 - [14C]O[18O] 2.387e-18 2.391e-18 -17.622 -17.621 0.001 - [14C]O3-2 1.636e-18 1.147e-18 -17.786 -17.940 -0.154 - CaH[14C]O2[18O]+ 1.162e-19 1.066e-19 -18.935 -18.972 -0.037 - CaH[14C]O[18O]O+ 1.162e-19 1.066e-19 -18.935 -18.972 -0.037 - CaH[14C][18O]O2+ 1.162e-19 1.066e-19 -18.935 -18.972 -0.037 - Ca[14C]O2[18O] 1.911e-20 1.914e-20 -19.719 -19.718 0.001 - H[14C]O[18O]2- 1.098e-20 1.004e-20 -19.960 -19.998 -0.039 - H[14C][18O]2O- 1.098e-20 1.004e-20 -19.960 -19.998 -0.039 - H[14C][18O]O[18O]- 1.098e-20 1.004e-20 -19.960 -19.998 -0.039 - [14C]O2[18O]-2 9.794e-21 6.865e-21 -20.009 -20.163 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.657 -67.657 0.001 - [18O]2 0.000e+00 0.000e+00 -70.658 -70.658 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 5.520e-21 + CH4 5.520e-21 5.529e-21 -20.258 -20.257 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.979e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.099e-06 1.009e-06 -5.959 -5.996 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.034e-08 6.044e-08 -7.219 -7.219 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 5.473e-14 + H2 2.736e-14 2.741e-14 -13.563 -13.562 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.258 -65.258 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.657 -67.657 0.001 (0) +[13C](-4) 6.055e-23 + [13C]H4 6.055e-23 6.065e-23 -22.218 -22.217 0.001 (0) +[13C](4) 6.452e-05 + H[13C]O3- 5.204e-05 4.762e-05 -4.284 -4.322 -0.039 (0) + [13C]O2 1.093e-05 1.095e-05 -4.961 -4.961 0.001 (0) + CaH[13C]O3+ 1.099e-06 1.009e-06 -5.959 -5.996 -0.037 (0) + H[13C]O2[18O]- 1.038e-07 9.500e-08 -6.984 -7.022 -0.039 (0) + H[13C]O[18O]O- 1.038e-07 9.500e-08 -6.984 -7.022 -0.039 (0) + H[13C][18O]O2- 1.038e-07 9.500e-08 -6.984 -7.022 -0.039 (0) + Ca[13C]O3 6.034e-08 6.044e-08 -7.219 -7.219 0.001 (0) + [13C]O[18O] 4.544e-08 4.552e-08 -7.343 -7.342 0.001 (0) + [13C]O3-2 3.093e-08 2.168e-08 -7.510 -7.664 -0.154 (0) + CaH[13C]O2[18O]+ 2.193e-09 2.012e-09 -8.659 -8.696 -0.037 (0) + CaH[13C]O[18O]O+ 2.193e-09 2.012e-09 -8.659 -8.696 -0.037 (0) + CaH[13C][18O]O2+ 2.193e-09 2.012e-09 -8.659 -8.696 -0.037 (0) + Ca[13C]O2[18O] 3.612e-10 3.618e-10 -9.442 -9.442 0.001 (0) + H[13C]O[18O]2- 2.072e-10 1.895e-10 -9.684 -9.722 -0.039 (0) + H[13C][18O]2O- 2.072e-10 1.895e-10 -9.684 -9.722 -0.039 (0) + H[13C][18O]O[18O]- 2.072e-10 1.895e-10 -9.684 -9.722 -0.039 (0) + [13C]O2[18O]-2 1.851e-10 1.297e-10 -9.733 -9.887 -0.154 (0) +[14C](-4) 3.180e-33 + [14C]H4 3.180e-33 3.186e-33 -32.498 -32.497 0.001 (0) +[14C](4) 3.414e-15 + H[14C]O3- 2.757e-15 2.523e-15 -14.560 -14.598 -0.039 (0) + [14C]O2 5.740e-16 5.750e-16 -15.241 -15.240 0.001 (0) + CaH[14C]O3+ 5.825e-17 5.344e-17 -16.235 -16.272 -0.037 (0) + H[14C]O2[18O]- 5.501e-18 5.034e-18 -17.260 -17.298 -0.039 (0) + H[14C]O[18O]O- 5.501e-18 5.034e-18 -17.260 -17.298 -0.039 (0) + H[14C][18O]O2- 5.501e-18 5.034e-18 -17.260 -17.298 -0.039 (0) + Ca[14C]O3 3.192e-18 3.198e-18 -17.496 -17.495 0.001 (0) + [14C]O[18O] 2.387e-18 2.391e-18 -17.622 -17.621 0.001 (0) + [14C]O3-2 1.636e-18 1.147e-18 -17.786 -17.940 -0.154 (0) + CaH[14C]O2[18O]+ 1.162e-19 1.066e-19 -18.935 -18.972 -0.037 (0) + CaH[14C]O[18O]O+ 1.162e-19 1.066e-19 -18.935 -18.972 -0.037 (0) + CaH[14C][18O]O2+ 1.162e-19 1.066e-19 -18.935 -18.972 -0.037 (0) + Ca[14C]O2[18O] 1.911e-20 1.914e-20 -19.719 -19.718 0.001 (0) + H[14C]O[18O]2- 1.098e-20 1.004e-20 -19.960 -19.998 -0.039 (0) + H[14C][18O]2O- 1.098e-20 1.004e-20 -19.960 -19.998 -0.039 (0) + H[14C][18O]O[18O]- 1.098e-20 1.004e-20 -19.960 -19.998 -0.039 (0) + [14C]O2[18O]-2 9.794e-21 6.865e-21 -20.009 -20.163 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.657 -67.657 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.658 -70.658 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -2267,99 +2267,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 9.081e-22 - CH4 9.081e-22 9.096e-22 -21.042 -21.041 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.100e-06 1.009e-06 -5.959 -5.996 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.039e-08 6.049e-08 -7.219 -7.218 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 3.485e-14 - H2 1.743e-14 1.746e-14 -13.759 -13.758 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -64.866 -64.866 0.001 - O[18O] 0.000e+00 0.000e+00 -67.265 -67.265 0.001 -[13C](-4) 9.969e-24 - [13C]H4 9.969e-24 9.985e-24 -23.001 -23.001 0.001 -[13C](4) 6.458e-05 - H[13C]O3- 5.208e-05 4.766e-05 -4.283 -4.322 -0.039 - [13C]O2 1.094e-05 1.095e-05 -4.961 -4.960 0.001 - CaH[13C]O3+ 1.100e-06 1.009e-06 -5.959 -5.996 -0.037 - H[13C]O2[18O]- 1.039e-07 9.508e-08 -6.983 -7.022 -0.039 - H[13C]O[18O]O- 1.039e-07 9.508e-08 -6.983 -7.022 -0.039 - H[13C][18O]O2- 1.039e-07 9.508e-08 -6.983 -7.022 -0.039 - Ca[13C]O3 6.039e-08 6.049e-08 -7.219 -7.218 0.001 - [13C]O[18O] 4.548e-08 4.555e-08 -7.342 -7.341 0.001 - [13C]O3-2 3.095e-08 2.169e-08 -7.509 -7.664 -0.154 - CaH[13C]O2[18O]+ 2.195e-09 2.014e-09 -8.659 -8.696 -0.037 - CaH[13C]O[18O]O+ 2.195e-09 2.014e-09 -8.659 -8.696 -0.037 - CaH[13C][18O]O2+ 2.195e-09 2.014e-09 -8.659 -8.696 -0.037 - Ca[13C]O2[18O] 3.615e-10 3.620e-10 -9.442 -9.441 0.001 - H[13C]O[18O]2- 2.073e-10 1.897e-10 -9.683 -9.722 -0.039 - H[13C][18O]2O- 2.073e-10 1.897e-10 -9.683 -9.722 -0.039 - H[13C][18O]O[18O]- 2.073e-10 1.897e-10 -9.683 -9.722 -0.039 - [13C]O2[18O]-2 1.853e-10 1.299e-10 -9.732 -9.887 -0.154 -[14C](-4) 4.820e-34 - [14C]H4 4.820e-34 4.828e-34 -33.317 -33.316 0.001 -[14C](4) 3.145e-15 - H[14C]O3- 2.540e-15 2.324e-15 -14.595 -14.634 -0.039 - [14C]O2 5.288e-16 5.297e-16 -15.277 -15.276 0.001 - CaH[14C]O3+ 5.366e-17 4.923e-17 -16.270 -16.308 -0.037 - H[14C]O2[18O]- 5.068e-18 4.637e-18 -17.295 -17.334 -0.039 - H[14C]O[18O]O- 5.068e-18 4.637e-18 -17.295 -17.334 -0.039 - H[14C][18O]O2- 5.068e-18 4.637e-18 -17.295 -17.334 -0.039 - Ca[14C]O3 2.941e-18 2.946e-18 -17.532 -17.531 0.001 - [14C]O[18O] 2.199e-18 2.202e-18 -17.658 -17.657 0.001 - [14C]O3-2 1.507e-18 1.057e-18 -17.822 -17.976 -0.154 - CaH[14C]O2[18O]+ 1.071e-19 9.822e-20 -18.970 -19.008 -0.037 - CaH[14C]O[18O]O+ 1.071e-19 9.822e-20 -18.970 -19.008 -0.037 - CaH[14C][18O]O2+ 1.071e-19 9.822e-20 -18.970 -19.008 -0.037 - Ca[14C]O2[18O] 1.760e-20 1.763e-20 -19.754 -19.754 0.001 - H[14C]O[18O]2- 1.011e-20 9.252e-21 -19.995 -20.034 -0.039 - H[14C][18O]2O- 1.011e-20 9.252e-21 -19.995 -20.034 -0.039 - H[14C][18O]O[18O]- 1.011e-20 9.252e-21 -19.995 -20.034 -0.039 - [14C]O2[18O]-2 9.022e-21 6.324e-21 -20.045 -20.199 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.265 -67.265 0.001 - [18O]2 0.000e+00 0.000e+00 -70.266 -70.266 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 9.081e-22 + CH4 9.081e-22 9.096e-22 -21.042 -21.041 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.100e-06 1.009e-06 -5.959 -5.996 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.039e-08 6.049e-08 -7.219 -7.218 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 3.485e-14 + H2 1.743e-14 1.746e-14 -13.759 -13.758 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -64.866 -64.866 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.265 -67.265 0.001 (0) +[13C](-4) 9.969e-24 + [13C]H4 9.969e-24 9.985e-24 -23.001 -23.001 0.001 (0) +[13C](4) 6.458e-05 + H[13C]O3- 5.208e-05 4.766e-05 -4.283 -4.322 -0.039 (0) + [13C]O2 1.094e-05 1.095e-05 -4.961 -4.960 0.001 (0) + CaH[13C]O3+ 1.100e-06 1.009e-06 -5.959 -5.996 -0.037 (0) + H[13C]O2[18O]- 1.039e-07 9.508e-08 -6.983 -7.022 -0.039 (0) + H[13C]O[18O]O- 1.039e-07 9.508e-08 -6.983 -7.022 -0.039 (0) + H[13C][18O]O2- 1.039e-07 9.508e-08 -6.983 -7.022 -0.039 (0) + Ca[13C]O3 6.039e-08 6.049e-08 -7.219 -7.218 0.001 (0) + [13C]O[18O] 4.548e-08 4.555e-08 -7.342 -7.341 0.001 (0) + [13C]O3-2 3.095e-08 2.169e-08 -7.509 -7.664 -0.154 (0) + CaH[13C]O2[18O]+ 2.195e-09 2.014e-09 -8.659 -8.696 -0.037 (0) + CaH[13C]O[18O]O+ 2.195e-09 2.014e-09 -8.659 -8.696 -0.037 (0) + CaH[13C][18O]O2+ 2.195e-09 2.014e-09 -8.659 -8.696 -0.037 (0) + Ca[13C]O2[18O] 3.615e-10 3.620e-10 -9.442 -9.441 0.001 (0) + H[13C]O[18O]2- 2.073e-10 1.897e-10 -9.683 -9.722 -0.039 (0) + H[13C][18O]2O- 2.073e-10 1.897e-10 -9.683 -9.722 -0.039 (0) + H[13C][18O]O[18O]- 2.073e-10 1.897e-10 -9.683 -9.722 -0.039 (0) + [13C]O2[18O]-2 1.853e-10 1.299e-10 -9.732 -9.887 -0.154 (0) +[14C](-4) 4.820e-34 + [14C]H4 4.820e-34 4.828e-34 -33.317 -33.316 0.001 (0) +[14C](4) 3.145e-15 + H[14C]O3- 2.540e-15 2.324e-15 -14.595 -14.634 -0.039 (0) + [14C]O2 5.288e-16 5.297e-16 -15.277 -15.276 0.001 (0) + CaH[14C]O3+ 5.366e-17 4.923e-17 -16.270 -16.308 -0.037 (0) + H[14C]O2[18O]- 5.068e-18 4.637e-18 -17.295 -17.334 -0.039 (0) + H[14C]O[18O]O- 5.068e-18 4.637e-18 -17.295 -17.334 -0.039 (0) + H[14C][18O]O2- 5.068e-18 4.637e-18 -17.295 -17.334 -0.039 (0) + Ca[14C]O3 2.941e-18 2.946e-18 -17.532 -17.531 0.001 (0) + [14C]O[18O] 2.199e-18 2.202e-18 -17.658 -17.657 0.001 (0) + [14C]O3-2 1.507e-18 1.057e-18 -17.822 -17.976 -0.154 (0) + CaH[14C]O2[18O]+ 1.071e-19 9.822e-20 -18.970 -19.008 -0.037 (0) + CaH[14C]O[18O]O+ 1.071e-19 9.822e-20 -18.970 -19.008 -0.037 (0) + CaH[14C][18O]O2+ 1.071e-19 9.822e-20 -18.970 -19.008 -0.037 (0) + Ca[14C]O2[18O] 1.760e-20 1.763e-20 -19.754 -19.754 0.001 (0) + H[14C]O[18O]2- 1.011e-20 9.252e-21 -19.995 -20.034 -0.039 (0) + H[14C][18O]2O- 1.011e-20 9.252e-21 -19.995 -20.034 -0.039 (0) + H[14C][18O]O[18O]- 1.011e-20 9.252e-21 -19.995 -20.034 -0.039 (0) + [14C]O2[18O]-2 9.022e-21 6.324e-21 -20.045 -20.199 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.265 -67.265 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.266 -70.266 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -2541,99 +2541,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 6.894e-21 - CH4 6.894e-21 6.905e-21 -20.162 -20.161 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.101e-06 1.010e-06 -5.958 -5.996 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.043e-08 6.053e-08 -7.219 -7.218 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 5.785e-14 - H2 2.893e-14 2.897e-14 -13.539 -13.538 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.307 -65.306 0.001 - O[18O] 0.000e+00 0.000e+00 -67.706 -67.705 0.001 -[13C](-4) 7.574e-23 - [13C]H4 7.574e-23 7.587e-23 -22.121 -22.120 0.001 -[13C](4) 6.462e-05 - H[13C]O3- 5.212e-05 4.769e-05 -4.283 -4.322 -0.039 - [13C]O2 1.094e-05 1.096e-05 -4.961 -4.960 0.001 - CaH[13C]O3+ 1.101e-06 1.010e-06 -5.958 -5.996 -0.037 - H[13C]O2[18O]- 1.040e-07 9.515e-08 -6.983 -7.022 -0.039 - H[13C]O[18O]O- 1.040e-07 9.515e-08 -6.983 -7.022 -0.039 - H[13C][18O]O2- 1.040e-07 9.515e-08 -6.983 -7.022 -0.039 - Ca[13C]O3 6.043e-08 6.053e-08 -7.219 -7.218 0.001 - [13C]O[18O] 4.551e-08 4.559e-08 -7.342 -7.341 0.001 - [13C]O3-2 3.097e-08 2.171e-08 -7.509 -7.663 -0.154 - CaH[13C]O2[18O]+ 2.197e-09 2.015e-09 -8.658 -8.696 -0.037 - CaH[13C]O[18O]O+ 2.197e-09 2.015e-09 -8.658 -8.696 -0.037 - CaH[13C][18O]O2+ 2.197e-09 2.015e-09 -8.658 -8.696 -0.037 - Ca[13C]O2[18O] 3.617e-10 3.623e-10 -9.442 -9.441 0.001 - H[13C]O[18O]2- 2.075e-10 1.898e-10 -9.683 -9.722 -0.039 - H[13C][18O]2O- 2.075e-10 1.898e-10 -9.683 -9.722 -0.039 - H[13C][18O]O[18O]- 2.075e-10 1.898e-10 -9.683 -9.722 -0.039 - [13C]O2[18O]-2 1.854e-10 1.299e-10 -9.732 -9.886 -0.154 -[14C](-4) 3.371e-33 - [14C]H4 3.371e-33 3.377e-33 -32.472 -32.472 0.001 -[14C](4) 2.897e-15 - H[14C]O3- 2.340e-15 2.141e-15 -14.631 -14.669 -0.039 - [14C]O2 4.871e-16 4.879e-16 -15.312 -15.312 0.001 - CaH[14C]O3+ 4.943e-17 4.535e-17 -16.306 -16.343 -0.037 - H[14C]O2[18O]- 4.669e-18 4.272e-18 -17.331 -17.369 -0.039 - H[14C]O[18O]O- 4.669e-18 4.272e-18 -17.331 -17.369 -0.039 - H[14C][18O]O2- 4.669e-18 4.272e-18 -17.331 -17.369 -0.039 - Ca[14C]O3 2.709e-18 2.714e-18 -17.567 -17.566 0.001 - [14C]O[18O] 2.026e-18 2.029e-18 -17.693 -17.693 0.001 - [14C]O3-2 1.389e-18 9.733e-19 -17.857 -18.012 -0.154 - CaH[14C]O2[18O]+ 9.862e-20 9.048e-20 -19.006 -19.043 -0.037 - CaH[14C]O[18O]O+ 9.862e-20 9.048e-20 -19.006 -19.043 -0.037 - CaH[14C][18O]O2+ 9.862e-20 9.048e-20 -19.006 -19.043 -0.037 - Ca[14C]O2[18O] 1.622e-20 1.624e-20 -19.790 -19.789 0.001 - H[14C]O[18O]2- 9.315e-21 8.523e-21 -20.031 -20.069 -0.039 - H[14C][18O]2O- 9.315e-21 8.523e-21 -20.031 -20.069 -0.039 - H[14C][18O]O[18O]- 9.315e-21 8.523e-21 -20.031 -20.069 -0.039 - [14C]O2[18O]-2 8.312e-21 5.826e-21 -20.080 -20.235 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.706 -67.705 0.001 - [18O]2 0.000e+00 0.000e+00 -70.707 -70.706 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 6.894e-21 + CH4 6.894e-21 6.905e-21 -20.162 -20.161 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.101e-06 1.010e-06 -5.958 -5.996 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.043e-08 6.053e-08 -7.219 -7.218 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 5.785e-14 + H2 2.893e-14 2.897e-14 -13.539 -13.538 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.307 -65.306 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.706 -67.705 0.001 (0) +[13C](-4) 7.574e-23 + [13C]H4 7.574e-23 7.587e-23 -22.121 -22.120 0.001 (0) +[13C](4) 6.462e-05 + H[13C]O3- 5.212e-05 4.769e-05 -4.283 -4.322 -0.039 (0) + [13C]O2 1.094e-05 1.096e-05 -4.961 -4.960 0.001 (0) + CaH[13C]O3+ 1.101e-06 1.010e-06 -5.958 -5.996 -0.037 (0) + H[13C]O2[18O]- 1.040e-07 9.515e-08 -6.983 -7.022 -0.039 (0) + H[13C]O[18O]O- 1.040e-07 9.515e-08 -6.983 -7.022 -0.039 (0) + H[13C][18O]O2- 1.040e-07 9.515e-08 -6.983 -7.022 -0.039 (0) + Ca[13C]O3 6.043e-08 6.053e-08 -7.219 -7.218 0.001 (0) + [13C]O[18O] 4.551e-08 4.559e-08 -7.342 -7.341 0.001 (0) + [13C]O3-2 3.097e-08 2.171e-08 -7.509 -7.663 -0.154 (0) + CaH[13C]O2[18O]+ 2.197e-09 2.015e-09 -8.658 -8.696 -0.037 (0) + CaH[13C]O[18O]O+ 2.197e-09 2.015e-09 -8.658 -8.696 -0.037 (0) + CaH[13C][18O]O2+ 2.197e-09 2.015e-09 -8.658 -8.696 -0.037 (0) + Ca[13C]O2[18O] 3.617e-10 3.623e-10 -9.442 -9.441 0.001 (0) + H[13C]O[18O]2- 2.075e-10 1.898e-10 -9.683 -9.722 -0.039 (0) + H[13C][18O]2O- 2.075e-10 1.898e-10 -9.683 -9.722 -0.039 (0) + H[13C][18O]O[18O]- 2.075e-10 1.898e-10 -9.683 -9.722 -0.039 (0) + [13C]O2[18O]-2 1.854e-10 1.299e-10 -9.732 -9.886 -0.154 (0) +[14C](-4) 3.371e-33 + [14C]H4 3.371e-33 3.377e-33 -32.472 -32.472 0.001 (0) +[14C](4) 2.897e-15 + H[14C]O3- 2.340e-15 2.141e-15 -14.631 -14.669 -0.039 (0) + [14C]O2 4.871e-16 4.879e-16 -15.312 -15.312 0.001 (0) + CaH[14C]O3+ 4.943e-17 4.535e-17 -16.306 -16.343 -0.037 (0) + H[14C]O2[18O]- 4.669e-18 4.272e-18 -17.331 -17.369 -0.039 (0) + H[14C]O[18O]O- 4.669e-18 4.272e-18 -17.331 -17.369 -0.039 (0) + H[14C][18O]O2- 4.669e-18 4.272e-18 -17.331 -17.369 -0.039 (0) + Ca[14C]O3 2.709e-18 2.714e-18 -17.567 -17.566 0.001 (0) + [14C]O[18O] 2.026e-18 2.029e-18 -17.693 -17.693 0.001 (0) + [14C]O3-2 1.389e-18 9.733e-19 -17.857 -18.012 -0.154 (0) + CaH[14C]O2[18O]+ 9.862e-20 9.048e-20 -19.006 -19.043 -0.037 (0) + CaH[14C]O[18O]O+ 9.862e-20 9.048e-20 -19.006 -19.043 -0.037 (0) + CaH[14C][18O]O2+ 9.862e-20 9.048e-20 -19.006 -19.043 -0.037 (0) + Ca[14C]O2[18O] 1.622e-20 1.624e-20 -19.790 -19.789 0.001 (0) + H[14C]O[18O]2- 9.315e-21 8.523e-21 -20.031 -20.069 -0.039 (0) + H[14C][18O]2O- 9.315e-21 8.523e-21 -20.031 -20.069 -0.039 (0) + H[14C][18O]O[18O]- 9.315e-21 8.523e-21 -20.031 -20.069 -0.039 (0) + [14C]O2[18O]-2 8.312e-21 5.826e-21 -20.080 -20.235 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.706 -67.705 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.707 -70.706 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -2815,99 +2815,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 2.064e-22 - CH4 2.064e-22 2.067e-22 -21.685 -21.685 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.102e-06 1.011e-06 -5.958 -5.995 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.048e-08 6.057e-08 -7.218 -7.218 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 2.406e-14 - H2 1.203e-14 1.205e-14 -13.920 -13.919 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -64.545 -64.544 0.001 - O[18O] 0.000e+00 0.000e+00 -66.944 -66.943 0.001 -[13C](-4) 2.269e-24 - [13C]H4 2.269e-24 2.273e-24 -23.644 -23.643 0.001 -[13C](4) 6.467e-05 - H[13C]O3- 5.216e-05 4.772e-05 -4.283 -4.321 -0.039 - [13C]O2 1.095e-05 1.097e-05 -4.960 -4.960 0.001 - CaH[13C]O3+ 1.102e-06 1.011e-06 -5.958 -5.995 -0.037 - H[13C]O2[18O]- 1.041e-07 9.522e-08 -6.983 -7.021 -0.039 - H[13C]O[18O]O- 1.041e-07 9.522e-08 -6.983 -7.021 -0.039 - H[13C][18O]O2- 1.041e-07 9.522e-08 -6.983 -7.021 -0.039 - Ca[13C]O3 6.048e-08 6.057e-08 -7.218 -7.218 0.001 - [13C]O[18O] 4.554e-08 4.562e-08 -7.342 -7.341 0.001 - [13C]O3-2 3.100e-08 2.173e-08 -7.509 -7.663 -0.154 - CaH[13C]O2[18O]+ 2.198e-09 2.017e-09 -8.658 -8.695 -0.037 - CaH[13C]O[18O]O+ 2.198e-09 2.017e-09 -8.658 -8.695 -0.037 - CaH[13C][18O]O2+ 2.198e-09 2.017e-09 -8.658 -8.695 -0.037 - Ca[13C]O2[18O] 3.620e-10 3.626e-10 -9.441 -9.441 0.001 - H[13C]O[18O]2- 2.076e-10 1.900e-10 -9.683 -9.721 -0.039 - H[13C][18O]2O- 2.076e-10 1.900e-10 -9.683 -9.721 -0.039 - H[13C][18O]O[18O]- 2.076e-10 1.900e-10 -9.683 -9.721 -0.039 - [13C]O2[18O]-2 1.855e-10 1.300e-10 -9.732 -9.886 -0.154 -[14C](-4) 9.297e-35 - [14C]H4 9.297e-35 9.312e-35 -34.032 -34.031 0.001 -[14C](4) 2.669e-15 - H[14C]O3- 2.156e-15 1.972e-15 -14.666 -14.705 -0.039 - [14C]O2 4.488e-16 4.495e-16 -15.348 -15.347 0.001 - CaH[14C]O3+ 4.554e-17 4.178e-17 -16.342 -16.379 -0.037 - H[14C]O2[18O]- 4.301e-18 3.935e-18 -17.366 -17.405 -0.039 - H[14C]O[18O]O- 4.301e-18 3.935e-18 -17.366 -17.405 -0.039 - H[14C][18O]O2- 4.301e-18 3.935e-18 -17.366 -17.405 -0.039 - Ca[14C]O3 2.496e-18 2.500e-18 -17.603 -17.602 0.001 - [14C]O[18O] 1.866e-18 1.869e-18 -17.729 -17.728 0.001 - [14C]O3-2 1.279e-18 8.966e-19 -17.893 -18.047 -0.154 - CaH[14C]O2[18O]+ 9.085e-20 8.335e-20 -19.042 -19.079 -0.037 - CaH[14C]O[18O]O+ 9.085e-20 8.335e-20 -19.042 -19.079 -0.037 - CaH[14C][18O]O2+ 9.085e-20 8.335e-20 -19.042 -19.079 -0.037 - Ca[14C]O2[18O] 1.494e-20 1.496e-20 -19.826 -19.825 0.001 - H[14C]O[18O]2- 8.581e-21 7.852e-21 -20.066 -20.105 -0.039 - H[14C][18O]2O- 8.581e-21 7.852e-21 -20.066 -20.105 -0.039 - H[14C][18O]O[18O]- 8.581e-21 7.852e-21 -20.066 -20.105 -0.039 - [14C]O2[18O]-2 7.657e-21 5.367e-21 -20.116 -20.270 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -66.944 -66.943 0.001 - [18O]2 0.000e+00 0.000e+00 -69.945 -69.944 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 2.064e-22 + CH4 2.064e-22 2.067e-22 -21.685 -21.685 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.102e-06 1.011e-06 -5.958 -5.995 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.048e-08 6.057e-08 -7.218 -7.218 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 2.406e-14 + H2 1.203e-14 1.205e-14 -13.920 -13.919 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -64.545 -64.544 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -66.944 -66.943 0.001 (0) +[13C](-4) 2.269e-24 + [13C]H4 2.269e-24 2.273e-24 -23.644 -23.643 0.001 (0) +[13C](4) 6.467e-05 + H[13C]O3- 5.216e-05 4.772e-05 -4.283 -4.321 -0.039 (0) + [13C]O2 1.095e-05 1.097e-05 -4.960 -4.960 0.001 (0) + CaH[13C]O3+ 1.102e-06 1.011e-06 -5.958 -5.995 -0.037 (0) + H[13C]O2[18O]- 1.041e-07 9.522e-08 -6.983 -7.021 -0.039 (0) + H[13C]O[18O]O- 1.041e-07 9.522e-08 -6.983 -7.021 -0.039 (0) + H[13C][18O]O2- 1.041e-07 9.522e-08 -6.983 -7.021 -0.039 (0) + Ca[13C]O3 6.048e-08 6.057e-08 -7.218 -7.218 0.001 (0) + [13C]O[18O] 4.554e-08 4.562e-08 -7.342 -7.341 0.001 (0) + [13C]O3-2 3.100e-08 2.173e-08 -7.509 -7.663 -0.154 (0) + CaH[13C]O2[18O]+ 2.198e-09 2.017e-09 -8.658 -8.695 -0.037 (0) + CaH[13C]O[18O]O+ 2.198e-09 2.017e-09 -8.658 -8.695 -0.037 (0) + CaH[13C][18O]O2+ 2.198e-09 2.017e-09 -8.658 -8.695 -0.037 (0) + Ca[13C]O2[18O] 3.620e-10 3.626e-10 -9.441 -9.441 0.001 (0) + H[13C]O[18O]2- 2.076e-10 1.900e-10 -9.683 -9.721 -0.039 (0) + H[13C][18O]2O- 2.076e-10 1.900e-10 -9.683 -9.721 -0.039 (0) + H[13C][18O]O[18O]- 2.076e-10 1.900e-10 -9.683 -9.721 -0.039 (0) + [13C]O2[18O]-2 1.855e-10 1.300e-10 -9.732 -9.886 -0.154 (0) +[14C](-4) 9.297e-35 + [14C]H4 9.297e-35 9.312e-35 -34.032 -34.031 0.001 (0) +[14C](4) 2.669e-15 + H[14C]O3- 2.156e-15 1.972e-15 -14.666 -14.705 -0.039 (0) + [14C]O2 4.488e-16 4.495e-16 -15.348 -15.347 0.001 (0) + CaH[14C]O3+ 4.554e-17 4.178e-17 -16.342 -16.379 -0.037 (0) + H[14C]O2[18O]- 4.301e-18 3.935e-18 -17.366 -17.405 -0.039 (0) + H[14C]O[18O]O- 4.301e-18 3.935e-18 -17.366 -17.405 -0.039 (0) + H[14C][18O]O2- 4.301e-18 3.935e-18 -17.366 -17.405 -0.039 (0) + Ca[14C]O3 2.496e-18 2.500e-18 -17.603 -17.602 0.001 (0) + [14C]O[18O] 1.866e-18 1.869e-18 -17.729 -17.728 0.001 (0) + [14C]O3-2 1.279e-18 8.966e-19 -17.893 -18.047 -0.154 (0) + CaH[14C]O2[18O]+ 9.085e-20 8.335e-20 -19.042 -19.079 -0.037 (0) + CaH[14C]O[18O]O+ 9.085e-20 8.335e-20 -19.042 -19.079 -0.037 (0) + CaH[14C][18O]O2+ 9.085e-20 8.335e-20 -19.042 -19.079 -0.037 (0) + Ca[14C]O2[18O] 1.494e-20 1.496e-20 -19.826 -19.825 0.001 (0) + H[14C]O[18O]2- 8.581e-21 7.852e-21 -20.066 -20.105 -0.039 (0) + H[14C][18O]2O- 8.581e-21 7.852e-21 -20.066 -20.105 -0.039 (0) + H[14C][18O]O[18O]- 8.581e-21 7.852e-21 -20.066 -20.105 -0.039 (0) + [14C]O2[18O]-2 7.657e-21 5.367e-21 -20.116 -20.270 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -66.944 -66.943 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -69.945 -69.944 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -3087,99 +3087,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -121.737 -121.737 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.103e-06 1.011e-06 -5.958 -5.995 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.051e-08 6.061e-08 -7.218 -7.217 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 2.335e-39 - H2 1.168e-39 1.170e-39 -38.933 -38.932 0.001 -O(0) 6.085e-15 - O2 3.030e-15 3.035e-15 -14.519 -14.518 0.001 - O[18O] 1.209e-17 1.211e-17 -16.918 -16.917 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -123.696 -123.695 0.001 -[13C](4) 6.471e-05 - H[13C]O3- 5.219e-05 4.775e-05 -4.282 -4.321 -0.039 - [13C]O2 1.096e-05 1.098e-05 -4.960 -4.959 0.001 - CaH[13C]O3+ 1.103e-06 1.011e-06 -5.958 -5.995 -0.037 - H[13C]O2[18O]- 1.041e-07 9.528e-08 -6.982 -7.021 -0.039 - H[13C]O[18O]O- 1.041e-07 9.528e-08 -6.982 -7.021 -0.039 - H[13C][18O]O2- 1.041e-07 9.528e-08 -6.982 -7.021 -0.039 - Ca[13C]O3 6.051e-08 6.061e-08 -7.218 -7.217 0.001 - [13C]O[18O] 4.557e-08 4.565e-08 -7.341 -7.341 0.001 - [13C]O3-2 3.102e-08 2.174e-08 -7.508 -7.663 -0.154 - CaH[13C]O2[18O]+ 2.200e-09 2.018e-09 -8.658 -8.695 -0.037 - CaH[13C]O[18O]O+ 2.200e-09 2.018e-09 -8.658 -8.695 -0.037 - CaH[13C][18O]O2+ 2.200e-09 2.018e-09 -8.658 -8.695 -0.037 - Ca[13C]O2[18O] 3.622e-10 3.628e-10 -9.441 -9.440 0.001 - H[13C]O[18O]2- 2.078e-10 1.901e-10 -9.682 -9.721 -0.039 - H[13C][18O]2O- 2.078e-10 1.901e-10 -9.682 -9.721 -0.039 - H[13C][18O]O[18O]- 2.078e-10 1.901e-10 -9.682 -9.721 -0.039 - [13C]O2[18O]-2 1.856e-10 1.301e-10 -9.731 -9.886 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -134.119 -134.119 0.001 -[14C](4) 2.459e-15 - H[14C]O3- 1.986e-15 1.817e-15 -14.702 -14.741 -0.039 - [14C]O2 4.134e-16 4.141e-16 -15.384 -15.383 0.001 - CaH[14C]O3+ 4.195e-17 3.849e-17 -16.377 -16.415 -0.037 - H[14C]O2[18O]- 3.962e-18 3.625e-18 -17.402 -17.441 -0.039 - H[14C]O[18O]O- 3.962e-18 3.625e-18 -17.402 -17.441 -0.039 - H[14C][18O]O2- 3.962e-18 3.625e-18 -17.402 -17.441 -0.039 - Ca[14C]O3 2.299e-18 2.303e-18 -17.638 -17.638 0.001 - [14C]O[18O] 1.719e-18 1.722e-18 -17.765 -17.764 0.001 - [14C]O3-2 1.178e-18 8.260e-19 -17.929 -18.083 -0.154 - CaH[14C]O2[18O]+ 8.370e-20 7.679e-20 -19.077 -19.115 -0.037 - CaH[14C]O[18O]O+ 8.370e-20 7.679e-20 -19.077 -19.115 -0.037 - CaH[14C][18O]O2+ 8.370e-20 7.679e-20 -19.077 -19.115 -0.037 - Ca[14C]O2[18O] 1.376e-20 1.378e-20 -19.861 -19.861 0.001 - H[14C]O[18O]2- 7.905e-21 7.233e-21 -20.102 -20.141 -0.039 - H[14C][18O]2O- 7.905e-21 7.233e-21 -20.102 -20.141 -0.039 - H[14C][18O]O[18O]- 7.905e-21 7.233e-21 -20.102 -20.141 -0.039 - [14C]O2[18O]-2 7.054e-21 4.944e-21 -20.152 -20.306 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 1.212e-17 - O[18O] 1.209e-17 1.211e-17 -16.918 -16.917 0.001 - [18O]2 1.206e-20 1.208e-20 -19.919 -19.918 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -121.737 -121.737 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.103e-06 1.011e-06 -5.958 -5.995 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.051e-08 6.061e-08 -7.218 -7.217 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 2.335e-39 + H2 1.168e-39 1.170e-39 -38.933 -38.932 0.001 (0) +O(0) 6.085e-15 + O2 3.030e-15 3.035e-15 -14.519 -14.518 0.001 (0) + O[18O] 1.209e-17 1.211e-17 -16.918 -16.917 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -123.696 -123.695 0.001 (0) +[13C](4) 6.471e-05 + H[13C]O3- 5.219e-05 4.775e-05 -4.282 -4.321 -0.039 (0) + [13C]O2 1.096e-05 1.098e-05 -4.960 -4.959 0.001 (0) + CaH[13C]O3+ 1.103e-06 1.011e-06 -5.958 -5.995 -0.037 (0) + H[13C]O2[18O]- 1.041e-07 9.528e-08 -6.982 -7.021 -0.039 (0) + H[13C]O[18O]O- 1.041e-07 9.528e-08 -6.982 -7.021 -0.039 (0) + H[13C][18O]O2- 1.041e-07 9.528e-08 -6.982 -7.021 -0.039 (0) + Ca[13C]O3 6.051e-08 6.061e-08 -7.218 -7.217 0.001 (0) + [13C]O[18O] 4.557e-08 4.565e-08 -7.341 -7.341 0.001 (0) + [13C]O3-2 3.102e-08 2.174e-08 -7.508 -7.663 -0.154 (0) + CaH[13C]O2[18O]+ 2.200e-09 2.018e-09 -8.658 -8.695 -0.037 (0) + CaH[13C]O[18O]O+ 2.200e-09 2.018e-09 -8.658 -8.695 -0.037 (0) + CaH[13C][18O]O2+ 2.200e-09 2.018e-09 -8.658 -8.695 -0.037 (0) + Ca[13C]O2[18O] 3.622e-10 3.628e-10 -9.441 -9.440 0.001 (0) + H[13C]O[18O]2- 2.078e-10 1.901e-10 -9.682 -9.721 -0.039 (0) + H[13C][18O]2O- 2.078e-10 1.901e-10 -9.682 -9.721 -0.039 (0) + H[13C][18O]O[18O]- 2.078e-10 1.901e-10 -9.682 -9.721 -0.039 (0) + [13C]O2[18O]-2 1.856e-10 1.301e-10 -9.731 -9.886 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -134.119 -134.119 0.001 (0) +[14C](4) 2.459e-15 + H[14C]O3- 1.986e-15 1.817e-15 -14.702 -14.741 -0.039 (0) + [14C]O2 4.134e-16 4.141e-16 -15.384 -15.383 0.001 (0) + CaH[14C]O3+ 4.195e-17 3.849e-17 -16.377 -16.415 -0.037 (0) + H[14C]O2[18O]- 3.962e-18 3.625e-18 -17.402 -17.441 -0.039 (0) + H[14C]O[18O]O- 3.962e-18 3.625e-18 -17.402 -17.441 -0.039 (0) + H[14C][18O]O2- 3.962e-18 3.625e-18 -17.402 -17.441 -0.039 (0) + Ca[14C]O3 2.299e-18 2.303e-18 -17.638 -17.638 0.001 (0) + [14C]O[18O] 1.719e-18 1.722e-18 -17.765 -17.764 0.001 (0) + [14C]O3-2 1.178e-18 8.260e-19 -17.929 -18.083 -0.154 (0) + CaH[14C]O2[18O]+ 8.370e-20 7.679e-20 -19.077 -19.115 -0.037 (0) + CaH[14C]O[18O]O+ 8.370e-20 7.679e-20 -19.077 -19.115 -0.037 (0) + CaH[14C][18O]O2+ 8.370e-20 7.679e-20 -19.077 -19.115 -0.037 (0) + Ca[14C]O2[18O] 1.376e-20 1.378e-20 -19.861 -19.861 0.001 (0) + H[14C]O[18O]2- 7.905e-21 7.233e-21 -20.102 -20.141 -0.039 (0) + H[14C][18O]2O- 7.905e-21 7.233e-21 -20.102 -20.141 -0.039 (0) + H[14C][18O]O[18O]- 7.905e-21 7.233e-21 -20.102 -20.141 -0.039 (0) + [14C]O2[18O]-2 7.054e-21 4.944e-21 -20.152 -20.306 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 1.212e-17 + O[18O] 1.209e-17 1.211e-17 -16.918 -16.917 0.001 (0) + [18O]2 1.206e-20 1.208e-20 -19.919 -19.918 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -3359,99 +3359,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -122.960 -122.959 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.103e-06 1.012e-06 -5.957 -5.995 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.055e-08 6.065e-08 -7.218 -7.217 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.155e-39 - H2 5.777e-40 5.787e-40 -39.238 -39.238 0.001 -O(0) 2.486e-14 - O2 1.238e-14 1.240e-14 -13.907 -13.907 0.001 - O[18O] 4.939e-17 4.947e-17 -16.306 -16.306 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -124.918 -124.917 0.001 -[13C](4) 6.475e-05 - H[13C]O3- 5.222e-05 4.778e-05 -4.282 -4.321 -0.039 - [13C]O2 1.097e-05 1.098e-05 -4.960 -4.959 0.001 - CaH[13C]O3+ 1.103e-06 1.012e-06 -5.957 -5.995 -0.037 - H[13C]O2[18O]- 1.042e-07 9.534e-08 -6.982 -7.021 -0.039 - H[13C]O[18O]O- 1.042e-07 9.534e-08 -6.982 -7.021 -0.039 - H[13C][18O]O2- 1.042e-07 9.534e-08 -6.982 -7.021 -0.039 - Ca[13C]O3 6.055e-08 6.065e-08 -7.218 -7.217 0.001 - [13C]O[18O] 4.560e-08 4.567e-08 -7.341 -7.340 0.001 - [13C]O3-2 3.103e-08 2.175e-08 -7.508 -7.662 -0.154 - CaH[13C]O2[18O]+ 2.201e-09 2.019e-09 -8.657 -8.695 -0.037 - CaH[13C]O[18O]O+ 2.201e-09 2.019e-09 -8.657 -8.695 -0.037 - CaH[13C][18O]O2+ 2.201e-09 2.019e-09 -8.657 -8.695 -0.037 - Ca[13C]O2[18O] 3.624e-10 3.630e-10 -9.441 -9.440 0.001 - H[13C]O[18O]2- 2.079e-10 1.902e-10 -9.682 -9.721 -0.039 - H[13C][18O]2O- 2.079e-10 1.902e-10 -9.682 -9.721 -0.039 - H[13C][18O]O[18O]- 2.079e-10 1.902e-10 -9.682 -9.721 -0.039 - [13C]O2[18O]-2 1.858e-10 1.302e-10 -9.731 -9.885 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -135.377 -135.377 0.001 -[14C](4) 2.265e-15 - H[14C]O3- 1.829e-15 1.674e-15 -14.738 -14.776 -0.039 - [14C]O2 3.808e-16 3.815e-16 -15.419 -15.419 0.001 - CaH[14C]O3+ 3.865e-17 3.545e-17 -16.413 -16.450 -0.037 - H[14C]O2[18O]- 3.650e-18 3.340e-18 -17.438 -17.476 -0.039 - H[14C]O[18O]O- 3.650e-18 3.340e-18 -17.438 -17.476 -0.039 - H[14C][18O]O2- 3.650e-18 3.340e-18 -17.438 -17.476 -0.039 - Ca[14C]O3 2.118e-18 2.122e-18 -17.674 -17.673 0.001 - [14C]O[18O] 1.584e-18 1.586e-18 -17.800 -17.800 0.001 - [14C]O3-2 1.086e-18 7.609e-19 -17.964 -18.119 -0.154 - CaH[14C]O2[18O]+ 7.710e-20 7.074e-20 -19.113 -19.150 -0.037 - CaH[14C]O[18O]O+ 7.710e-20 7.074e-20 -19.113 -19.150 -0.037 - CaH[14C][18O]O2+ 7.710e-20 7.074e-20 -19.113 -19.150 -0.037 - Ca[14C]O2[18O] 1.268e-20 1.270e-20 -19.897 -19.896 0.001 - H[14C]O[18O]2- 7.283e-21 6.663e-21 -20.138 -20.176 -0.039 - H[14C][18O]2O- 7.283e-21 6.663e-21 -20.138 -20.176 -0.039 - H[14C][18O]O[18O]- 7.283e-21 6.663e-21 -20.138 -20.176 -0.039 - [14C]O2[18O]-2 6.498e-21 4.555e-21 -20.187 -20.342 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 4.949e-17 - O[18O] 4.939e-17 4.947e-17 -16.306 -16.306 0.001 - [18O]2 4.927e-20 4.936e-20 -19.307 -19.307 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -122.960 -122.959 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.103e-06 1.012e-06 -5.957 -5.995 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.055e-08 6.065e-08 -7.218 -7.217 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.155e-39 + H2 5.777e-40 5.787e-40 -39.238 -39.238 0.001 (0) +O(0) 2.486e-14 + O2 1.238e-14 1.240e-14 -13.907 -13.907 0.001 (0) + O[18O] 4.939e-17 4.947e-17 -16.306 -16.306 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -124.918 -124.917 0.001 (0) +[13C](4) 6.475e-05 + H[13C]O3- 5.222e-05 4.778e-05 -4.282 -4.321 -0.039 (0) + [13C]O2 1.097e-05 1.098e-05 -4.960 -4.959 0.001 (0) + CaH[13C]O3+ 1.103e-06 1.012e-06 -5.957 -5.995 -0.037 (0) + H[13C]O2[18O]- 1.042e-07 9.534e-08 -6.982 -7.021 -0.039 (0) + H[13C]O[18O]O- 1.042e-07 9.534e-08 -6.982 -7.021 -0.039 (0) + H[13C][18O]O2- 1.042e-07 9.534e-08 -6.982 -7.021 -0.039 (0) + Ca[13C]O3 6.055e-08 6.065e-08 -7.218 -7.217 0.001 (0) + [13C]O[18O] 4.560e-08 4.567e-08 -7.341 -7.340 0.001 (0) + [13C]O3-2 3.103e-08 2.175e-08 -7.508 -7.662 -0.154 (0) + CaH[13C]O2[18O]+ 2.201e-09 2.019e-09 -8.657 -8.695 -0.037 (0) + CaH[13C]O[18O]O+ 2.201e-09 2.019e-09 -8.657 -8.695 -0.037 (0) + CaH[13C][18O]O2+ 2.201e-09 2.019e-09 -8.657 -8.695 -0.037 (0) + Ca[13C]O2[18O] 3.624e-10 3.630e-10 -9.441 -9.440 0.001 (0) + H[13C]O[18O]2- 2.079e-10 1.902e-10 -9.682 -9.721 -0.039 (0) + H[13C][18O]2O- 2.079e-10 1.902e-10 -9.682 -9.721 -0.039 (0) + H[13C][18O]O[18O]- 2.079e-10 1.902e-10 -9.682 -9.721 -0.039 (0) + [13C]O2[18O]-2 1.858e-10 1.302e-10 -9.731 -9.885 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -135.377 -135.377 0.001 (0) +[14C](4) 2.265e-15 + H[14C]O3- 1.829e-15 1.674e-15 -14.738 -14.776 -0.039 (0) + [14C]O2 3.808e-16 3.815e-16 -15.419 -15.419 0.001 (0) + CaH[14C]O3+ 3.865e-17 3.545e-17 -16.413 -16.450 -0.037 (0) + H[14C]O2[18O]- 3.650e-18 3.340e-18 -17.438 -17.476 -0.039 (0) + H[14C]O[18O]O- 3.650e-18 3.340e-18 -17.438 -17.476 -0.039 (0) + H[14C][18O]O2- 3.650e-18 3.340e-18 -17.438 -17.476 -0.039 (0) + Ca[14C]O3 2.118e-18 2.122e-18 -17.674 -17.673 0.001 (0) + [14C]O[18O] 1.584e-18 1.586e-18 -17.800 -17.800 0.001 (0) + [14C]O3-2 1.086e-18 7.609e-19 -17.964 -18.119 -0.154 (0) + CaH[14C]O2[18O]+ 7.710e-20 7.074e-20 -19.113 -19.150 -0.037 (0) + CaH[14C]O[18O]O+ 7.710e-20 7.074e-20 -19.113 -19.150 -0.037 (0) + CaH[14C][18O]O2+ 7.710e-20 7.074e-20 -19.113 -19.150 -0.037 (0) + Ca[14C]O2[18O] 1.268e-20 1.270e-20 -19.897 -19.896 0.001 (0) + H[14C]O[18O]2- 7.283e-21 6.663e-21 -20.138 -20.176 -0.039 (0) + H[14C][18O]2O- 7.283e-21 6.663e-21 -20.138 -20.176 -0.039 (0) + H[14C][18O]O[18O]- 7.283e-21 6.663e-21 -20.138 -20.176 -0.039 (0) + [14C]O2[18O]-2 6.498e-21 4.555e-21 -20.187 -20.342 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 4.949e-17 + O[18O] 4.939e-17 4.947e-17 -16.306 -16.306 0.001 (0) + [18O]2 4.927e-20 4.936e-20 -19.307 -19.307 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -3631,99 +3631,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.158 -123.157 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.995 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.058e-08 6.068e-08 -7.218 -7.217 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.031e-39 - H2 5.154e-40 5.162e-40 -39.288 -39.287 0.001 -O(0) 3.123e-14 - O2 1.555e-14 1.558e-14 -13.808 -13.807 0.001 - O[18O] 6.206e-17 6.216e-17 -16.207 -16.206 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.116 -125.116 0.001 -[13C](4) 6.478e-05 - H[13C]O3- 5.225e-05 4.781e-05 -4.282 -4.320 -0.039 - [13C]O2 1.097e-05 1.099e-05 -4.960 -4.959 0.001 - CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.995 -0.037 - H[13C]O2[18O]- 1.042e-07 9.539e-08 -6.982 -7.021 -0.039 - H[13C]O[18O]O- 1.042e-07 9.539e-08 -6.982 -7.021 -0.039 - H[13C][18O]O2- 1.042e-07 9.539e-08 -6.982 -7.021 -0.039 - Ca[13C]O3 6.058e-08 6.068e-08 -7.218 -7.217 0.001 - [13C]O[18O] 4.562e-08 4.570e-08 -7.341 -7.340 0.001 - [13C]O3-2 3.105e-08 2.176e-08 -7.508 -7.662 -0.154 - CaH[13C]O2[18O]+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 - CaH[13C]O[18O]O+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 - CaH[13C][18O]O2+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 - Ca[13C]O2[18O] 3.626e-10 3.632e-10 -9.441 -9.440 0.001 - H[13C]O[18O]2- 2.080e-10 1.903e-10 -9.682 -9.721 -0.039 - H[13C][18O]2O- 2.080e-10 1.903e-10 -9.682 -9.721 -0.039 - H[13C][18O]O[18O]- 2.080e-10 1.903e-10 -9.682 -9.721 -0.039 - [13C]O2[18O]-2 1.859e-10 1.303e-10 -9.731 -9.885 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -135.611 -135.611 0.001 -[14C](4) 2.087e-15 - H[14C]O3- 1.685e-15 1.542e-15 -14.773 -14.812 -0.039 - [14C]O2 3.508e-16 3.514e-16 -15.455 -15.454 0.001 - CaH[14C]O3+ 3.560e-17 3.266e-17 -16.449 -16.486 -0.037 - H[14C]O2[18O]- 3.363e-18 3.077e-18 -17.473 -17.512 -0.039 - H[14C]O[18O]O- 3.363e-18 3.077e-18 -17.473 -17.512 -0.039 - H[14C][18O]O2- 3.363e-18 3.077e-18 -17.473 -17.512 -0.039 - Ca[14C]O3 1.951e-18 1.954e-18 -17.710 -17.709 0.001 - [14C]O[18O] 1.459e-18 1.461e-18 -17.836 -17.835 0.001 - [14C]O3-2 1.000e-18 7.010e-19 -18.000 -18.154 -0.154 - CaH[14C]O2[18O]+ 7.103e-20 6.517e-20 -19.149 -19.186 -0.037 - CaH[14C]O[18O]O+ 7.103e-20 6.517e-20 -19.149 -19.186 -0.037 - CaH[14C][18O]O2+ 7.103e-20 6.517e-20 -19.149 -19.186 -0.037 - Ca[14C]O2[18O] 1.168e-20 1.170e-20 -19.933 -19.932 0.001 - H[14C]O[18O]2- 6.709e-21 6.139e-21 -20.173 -20.212 -0.039 - H[14C][18O]2O- 6.709e-21 6.139e-21 -20.173 -20.212 -0.039 - H[14C][18O]O[18O]- 6.709e-21 6.139e-21 -20.173 -20.212 -0.039 - [14C]O2[18O]-2 5.986e-21 4.196e-21 -20.223 -20.377 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 6.219e-17 - O[18O] 6.206e-17 6.216e-17 -16.207 -16.206 0.001 - [18O]2 6.191e-20 6.201e-20 -19.208 -19.208 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.158 -123.157 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.995 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.058e-08 6.068e-08 -7.218 -7.217 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.031e-39 + H2 5.154e-40 5.162e-40 -39.288 -39.287 0.001 (0) +O(0) 3.123e-14 + O2 1.555e-14 1.558e-14 -13.808 -13.807 0.001 (0) + O[18O] 6.206e-17 6.216e-17 -16.207 -16.206 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.116 -125.116 0.001 (0) +[13C](4) 6.478e-05 + H[13C]O3- 5.225e-05 4.781e-05 -4.282 -4.320 -0.039 (0) + [13C]O2 1.097e-05 1.099e-05 -4.960 -4.959 0.001 (0) + CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.995 -0.037 (0) + H[13C]O2[18O]- 1.042e-07 9.539e-08 -6.982 -7.021 -0.039 (0) + H[13C]O[18O]O- 1.042e-07 9.539e-08 -6.982 -7.021 -0.039 (0) + H[13C][18O]O2- 1.042e-07 9.539e-08 -6.982 -7.021 -0.039 (0) + Ca[13C]O3 6.058e-08 6.068e-08 -7.218 -7.217 0.001 (0) + [13C]O[18O] 4.562e-08 4.570e-08 -7.341 -7.340 0.001 (0) + [13C]O3-2 3.105e-08 2.176e-08 -7.508 -7.662 -0.154 (0) + CaH[13C]O2[18O]+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 (0) + CaH[13C]O[18O]O+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 (0) + CaH[13C][18O]O2+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 (0) + Ca[13C]O2[18O] 3.626e-10 3.632e-10 -9.441 -9.440 0.001 (0) + H[13C]O[18O]2- 2.080e-10 1.903e-10 -9.682 -9.721 -0.039 (0) + H[13C][18O]2O- 2.080e-10 1.903e-10 -9.682 -9.721 -0.039 (0) + H[13C][18O]O[18O]- 2.080e-10 1.903e-10 -9.682 -9.721 -0.039 (0) + [13C]O2[18O]-2 1.859e-10 1.303e-10 -9.731 -9.885 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -135.611 -135.611 0.001 (0) +[14C](4) 2.087e-15 + H[14C]O3- 1.685e-15 1.542e-15 -14.773 -14.812 -0.039 (0) + [14C]O2 3.508e-16 3.514e-16 -15.455 -15.454 0.001 (0) + CaH[14C]O3+ 3.560e-17 3.266e-17 -16.449 -16.486 -0.037 (0) + H[14C]O2[18O]- 3.363e-18 3.077e-18 -17.473 -17.512 -0.039 (0) + H[14C]O[18O]O- 3.363e-18 3.077e-18 -17.473 -17.512 -0.039 (0) + H[14C][18O]O2- 3.363e-18 3.077e-18 -17.473 -17.512 -0.039 (0) + Ca[14C]O3 1.951e-18 1.954e-18 -17.710 -17.709 0.001 (0) + [14C]O[18O] 1.459e-18 1.461e-18 -17.836 -17.835 0.001 (0) + [14C]O3-2 1.000e-18 7.010e-19 -18.000 -18.154 -0.154 (0) + CaH[14C]O2[18O]+ 7.103e-20 6.517e-20 -19.149 -19.186 -0.037 (0) + CaH[14C]O[18O]O+ 7.103e-20 6.517e-20 -19.149 -19.186 -0.037 (0) + CaH[14C][18O]O2+ 7.103e-20 6.517e-20 -19.149 -19.186 -0.037 (0) + Ca[14C]O2[18O] 1.168e-20 1.170e-20 -19.933 -19.932 0.001 (0) + H[14C]O[18O]2- 6.709e-21 6.139e-21 -20.173 -20.212 -0.039 (0) + H[14C][18O]2O- 6.709e-21 6.139e-21 -20.173 -20.212 -0.039 (0) + H[14C][18O]O[18O]- 6.709e-21 6.139e-21 -20.173 -20.212 -0.039 (0) + [14C]O2[18O]-2 5.986e-21 4.196e-21 -20.223 -20.377 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 6.219e-17 + O[18O] 6.206e-17 6.216e-17 -16.207 -16.206 0.001 (0) + [18O]2 6.191e-20 6.201e-20 -19.208 -19.208 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -3905,99 +3905,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 5.317e-25 - CH4 5.317e-25 5.325e-25 -24.274 -24.274 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.061e-08 6.071e-08 -7.217 -7.217 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 5.422e-15 - H2 2.711e-15 2.715e-15 -14.567 -14.566 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -63.250 -63.249 0.001 - O[18O] 0.000e+00 0.000e+00 -65.649 -65.648 0.001 -[13C](-4) 5.859e-27 - [13C]H4 5.859e-27 5.868e-27 -26.232 -26.231 0.001 -[13C](4) 6.482e-05 - H[13C]O3- 5.228e-05 4.783e-05 -4.282 -4.320 -0.039 - [13C]O2 1.098e-05 1.100e-05 -4.960 -4.959 0.001 - CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.994 -0.037 - H[13C]O2[18O]- 1.043e-07 9.543e-08 -6.982 -7.020 -0.039 - H[13C]O[18O]O- 1.043e-07 9.543e-08 -6.982 -7.020 -0.039 - H[13C][18O]O2- 1.043e-07 9.543e-08 -6.982 -7.020 -0.039 - Ca[13C]O3 6.061e-08 6.071e-08 -7.217 -7.217 0.001 - [13C]O[18O] 4.565e-08 4.572e-08 -7.341 -7.340 0.001 - [13C]O3-2 3.107e-08 2.177e-08 -7.508 -7.662 -0.154 - CaH[13C]O2[18O]+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 - CaH[13C][18O]O2+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 - Ca[13C]O2[18O] 3.628e-10 3.634e-10 -9.440 -9.440 0.001 - H[13C]O[18O]2- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 - H[13C][18O]2O- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 - H[13C][18O]O[18O]- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 - [13C]O2[18O]-2 1.859e-10 1.303e-10 -9.731 -9.885 -0.154 -[14C](-4) 1.725e-37 - [14C]H4 1.725e-37 1.728e-37 -36.763 -36.763 0.001 -[14C](4) 1.922e-15 - H[14C]O3- 1.553e-15 1.421e-15 -14.809 -14.848 -0.039 - [14C]O2 3.232e-16 3.237e-16 -15.491 -15.490 0.001 - CaH[14C]O3+ 3.280e-17 3.009e-17 -16.484 -16.522 -0.037 - H[14C]O2[18O]- 3.098e-18 2.834e-18 -17.509 -17.548 -0.039 - H[14C]O[18O]O- 3.098e-18 2.834e-18 -17.509 -17.548 -0.039 - H[14C][18O]O2- 3.098e-18 2.834e-18 -17.509 -17.548 -0.039 - Ca[14C]O3 1.798e-18 1.800e-18 -17.745 -17.745 0.001 - [14C]O[18O] 1.344e-18 1.346e-18 -17.872 -17.871 0.001 - [14C]O3-2 9.213e-19 6.458e-19 -18.036 -18.190 -0.154 - CaH[14C]O2[18O]+ 6.543e-20 6.003e-20 -19.184 -19.222 -0.037 - CaH[14C]O[18O]O+ 6.543e-20 6.003e-20 -19.184 -19.222 -0.037 - CaH[14C][18O]O2+ 6.543e-20 6.003e-20 -19.184 -19.222 -0.037 - Ca[14C]O2[18O] 1.076e-20 1.078e-20 -19.968 -19.968 0.001 - H[14C]O[18O]2- 6.180e-21 5.655e-21 -20.209 -20.248 -0.039 - H[14C][18O]2O- 6.180e-21 5.655e-21 -20.209 -20.248 -0.039 - H[14C][18O]O[18O]- 6.180e-21 5.655e-21 -20.209 -20.248 -0.039 - [14C]O2[18O]-2 5.515e-21 3.865e-21 -20.258 -20.413 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -65.649 -65.648 0.001 - [18O]2 0.000e+00 0.000e+00 -68.650 -68.649 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 5.317e-25 + CH4 5.317e-25 5.325e-25 -24.274 -24.274 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.061e-08 6.071e-08 -7.217 -7.217 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 5.422e-15 + H2 2.711e-15 2.715e-15 -14.567 -14.566 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -63.250 -63.249 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -65.649 -65.648 0.001 (0) +[13C](-4) 5.859e-27 + [13C]H4 5.859e-27 5.868e-27 -26.232 -26.231 0.001 (0) +[13C](4) 6.482e-05 + H[13C]O3- 5.228e-05 4.783e-05 -4.282 -4.320 -0.039 (0) + [13C]O2 1.098e-05 1.100e-05 -4.960 -4.959 0.001 (0) + CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.043e-07 9.543e-08 -6.982 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.043e-07 9.543e-08 -6.982 -7.020 -0.039 (0) + H[13C][18O]O2- 1.043e-07 9.543e-08 -6.982 -7.020 -0.039 (0) + Ca[13C]O3 6.061e-08 6.071e-08 -7.217 -7.217 0.001 (0) + [13C]O[18O] 4.565e-08 4.572e-08 -7.341 -7.340 0.001 (0) + [13C]O3-2 3.107e-08 2.177e-08 -7.508 -7.662 -0.154 (0) + CaH[13C]O2[18O]+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.628e-10 3.634e-10 -9.440 -9.440 0.001 (0) + H[13C]O[18O]2- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 (0) + H[13C][18O]2O- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.859e-10 1.303e-10 -9.731 -9.885 -0.154 (0) +[14C](-4) 1.725e-37 + [14C]H4 1.725e-37 1.728e-37 -36.763 -36.763 0.001 (0) +[14C](4) 1.922e-15 + H[14C]O3- 1.553e-15 1.421e-15 -14.809 -14.848 -0.039 (0) + [14C]O2 3.232e-16 3.237e-16 -15.491 -15.490 0.001 (0) + CaH[14C]O3+ 3.280e-17 3.009e-17 -16.484 -16.522 -0.037 (0) + H[14C]O2[18O]- 3.098e-18 2.834e-18 -17.509 -17.548 -0.039 (0) + H[14C]O[18O]O- 3.098e-18 2.834e-18 -17.509 -17.548 -0.039 (0) + H[14C][18O]O2- 3.098e-18 2.834e-18 -17.509 -17.548 -0.039 (0) + Ca[14C]O3 1.798e-18 1.800e-18 -17.745 -17.745 0.001 (0) + [14C]O[18O] 1.344e-18 1.346e-18 -17.872 -17.871 0.001 (0) + [14C]O3-2 9.213e-19 6.458e-19 -18.036 -18.190 -0.154 (0) + CaH[14C]O2[18O]+ 6.543e-20 6.003e-20 -19.184 -19.222 -0.037 (0) + CaH[14C]O[18O]O+ 6.543e-20 6.003e-20 -19.184 -19.222 -0.037 (0) + CaH[14C][18O]O2+ 6.543e-20 6.003e-20 -19.184 -19.222 -0.037 (0) + Ca[14C]O2[18O] 1.076e-20 1.078e-20 -19.968 -19.968 0.001 (0) + H[14C]O[18O]2- 6.180e-21 5.655e-21 -20.209 -20.248 -0.039 (0) + H[14C][18O]2O- 6.180e-21 5.655e-21 -20.209 -20.248 -0.039 (0) + H[14C][18O]O[18O]- 6.180e-21 5.655e-21 -20.209 -20.248 -0.039 (0) + [14C]O2[18O]-2 5.515e-21 3.865e-21 -20.258 -20.413 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -65.649 -65.648 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -68.650 -68.649 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -4179,99 +4179,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 8.400e-23 - CH4 8.400e-23 8.413e-23 -22.076 -22.075 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.064e-08 6.074e-08 -7.217 -7.217 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.922e-14 - H2 9.611e-15 9.627e-15 -14.017 -14.017 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -64.349 -64.349 0.001 - O[18O] 0.000e+00 0.000e+00 -66.748 -66.748 0.001 -[13C](-4) 9.260e-25 - [13C]H4 9.260e-25 9.275e-25 -24.033 -24.033 0.001 -[13C](4) 6.485e-05 - H[13C]O3- 5.230e-05 4.785e-05 -4.281 -4.320 -0.039 - [13C]O2 1.098e-05 1.100e-05 -4.959 -4.959 0.001 - CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 - H[13C]O2[18O]- 1.043e-07 9.548e-08 -6.982 -7.020 -0.039 - H[13C]O[18O]O- 1.043e-07 9.548e-08 -6.982 -7.020 -0.039 - H[13C][18O]O2- 1.043e-07 9.548e-08 -6.982 -7.020 -0.039 - Ca[13C]O3 6.064e-08 6.074e-08 -7.217 -7.217 0.001 - [13C]O[18O] 4.567e-08 4.574e-08 -7.340 -7.340 0.001 - [13C]O3-2 3.108e-08 2.178e-08 -7.508 -7.662 -0.154 - CaH[13C]O2[18O]+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 - CaH[13C][18O]O2+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 - Ca[13C]O2[18O] 3.630e-10 3.636e-10 -9.440 -9.439 0.001 - H[13C]O[18O]2- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 - H[13C][18O]2O- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 - H[13C][18O]O[18O]- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 - [13C]O2[18O]-2 1.860e-10 1.304e-10 -9.730 -9.885 -0.154 -[14C](-4) 2.511e-35 - [14C]H4 2.511e-35 2.515e-35 -34.600 -34.600 0.001 -[14C](4) 1.771e-15 - H[14C]O3- 1.430e-15 1.309e-15 -14.845 -14.883 -0.039 - [14C]O2 2.977e-16 2.982e-16 -15.526 -15.525 0.001 - CaH[14C]O3+ 3.021e-17 2.772e-17 -16.520 -16.557 -0.037 - H[14C]O2[18O]- 2.854e-18 2.611e-18 -17.545 -17.583 -0.039 - H[14C]O[18O]O- 2.854e-18 2.611e-18 -17.545 -17.583 -0.039 - H[14C][18O]O2- 2.854e-18 2.611e-18 -17.545 -17.583 -0.039 - Ca[14C]O3 1.656e-18 1.659e-18 -17.781 -17.780 0.001 - [14C]O[18O] 1.238e-18 1.240e-18 -17.907 -17.907 0.001 - [14C]O3-2 8.487e-19 5.949e-19 -18.071 -18.226 -0.154 - CaH[14C]O2[18O]+ 6.028e-20 5.530e-20 -19.220 -19.257 -0.037 - CaH[14C]O[18O]O+ 6.028e-20 5.530e-20 -19.220 -19.257 -0.037 - CaH[14C][18O]O2+ 6.028e-20 5.530e-20 -19.220 -19.257 -0.037 - Ca[14C]O2[18O] 9.912e-21 9.928e-21 -20.004 -20.003 0.001 - H[14C]O[18O]2- 5.693e-21 5.209e-21 -20.245 -20.283 -0.039 - H[14C][18O]2O- 5.693e-21 5.209e-21 -20.245 -20.283 -0.039 - H[14C][18O]O[18O]- 5.693e-21 5.209e-21 -20.245 -20.283 -0.039 - [14C]O2[18O]-2 5.080e-21 3.561e-21 -20.294 -20.448 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -66.748 -66.748 0.001 - [18O]2 0.000e+00 0.000e+00 -69.749 -69.749 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 8.400e-23 + CH4 8.400e-23 8.413e-23 -22.076 -22.075 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.064e-08 6.074e-08 -7.217 -7.217 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.922e-14 + H2 9.611e-15 9.627e-15 -14.017 -14.017 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -64.349 -64.349 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -66.748 -66.748 0.001 (0) +[13C](-4) 9.260e-25 + [13C]H4 9.260e-25 9.275e-25 -24.033 -24.033 0.001 (0) +[13C](4) 6.485e-05 + H[13C]O3- 5.230e-05 4.785e-05 -4.281 -4.320 -0.039 (0) + [13C]O2 1.098e-05 1.100e-05 -4.959 -4.959 0.001 (0) + CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.043e-07 9.548e-08 -6.982 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.043e-07 9.548e-08 -6.982 -7.020 -0.039 (0) + H[13C][18O]O2- 1.043e-07 9.548e-08 -6.982 -7.020 -0.039 (0) + Ca[13C]O3 6.064e-08 6.074e-08 -7.217 -7.217 0.001 (0) + [13C]O[18O] 4.567e-08 4.574e-08 -7.340 -7.340 0.001 (0) + [13C]O3-2 3.108e-08 2.178e-08 -7.508 -7.662 -0.154 (0) + CaH[13C]O2[18O]+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.630e-10 3.636e-10 -9.440 -9.439 0.001 (0) + H[13C]O[18O]2- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 (0) + H[13C][18O]2O- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.860e-10 1.304e-10 -9.730 -9.885 -0.154 (0) +[14C](-4) 2.511e-35 + [14C]H4 2.511e-35 2.515e-35 -34.600 -34.600 0.001 (0) +[14C](4) 1.771e-15 + H[14C]O3- 1.430e-15 1.309e-15 -14.845 -14.883 -0.039 (0) + [14C]O2 2.977e-16 2.982e-16 -15.526 -15.525 0.001 (0) + CaH[14C]O3+ 3.021e-17 2.772e-17 -16.520 -16.557 -0.037 (0) + H[14C]O2[18O]- 2.854e-18 2.611e-18 -17.545 -17.583 -0.039 (0) + H[14C]O[18O]O- 2.854e-18 2.611e-18 -17.545 -17.583 -0.039 (0) + H[14C][18O]O2- 2.854e-18 2.611e-18 -17.545 -17.583 -0.039 (0) + Ca[14C]O3 1.656e-18 1.659e-18 -17.781 -17.780 0.001 (0) + [14C]O[18O] 1.238e-18 1.240e-18 -17.907 -17.907 0.001 (0) + [14C]O3-2 8.487e-19 5.949e-19 -18.071 -18.226 -0.154 (0) + CaH[14C]O2[18O]+ 6.028e-20 5.530e-20 -19.220 -19.257 -0.037 (0) + CaH[14C]O[18O]O+ 6.028e-20 5.530e-20 -19.220 -19.257 -0.037 (0) + CaH[14C][18O]O2+ 6.028e-20 5.530e-20 -19.220 -19.257 -0.037 (0) + Ca[14C]O2[18O] 9.912e-21 9.928e-21 -20.004 -20.003 0.001 (0) + H[14C]O[18O]2- 5.693e-21 5.209e-21 -20.245 -20.283 -0.039 (0) + H[14C][18O]2O- 5.693e-21 5.209e-21 -20.245 -20.283 -0.039 (0) + H[14C][18O]O[18O]- 5.693e-21 5.209e-21 -20.245 -20.283 -0.039 (0) + [14C]O2[18O]-2 5.080e-21 3.561e-21 -20.294 -20.448 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -66.748 -66.748 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -69.749 -69.749 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -4453,99 +4453,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 9.764e-20 - CH4 9.764e-20 9.780e-20 -19.010 -19.010 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.067e-08 6.077e-08 -7.217 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.122e-13 - H2 5.612e-14 5.621e-14 -13.251 -13.250 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.882 -65.881 0.001 - O[18O] 0.000e+00 0.000e+00 -68.281 -68.280 0.001 -[13C](-4) 1.077e-21 - [13C]H4 1.077e-21 1.079e-21 -20.968 -20.967 0.001 -[13C](4) 6.487e-05 - H[13C]O3- 5.232e-05 4.787e-05 -4.281 -4.320 -0.039 - [13C]O2 1.099e-05 1.101e-05 -4.959 -4.958 0.001 - CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 - H[13C]O2[18O]- 1.044e-07 9.552e-08 -6.981 -7.020 -0.039 - H[13C]O[18O]O- 1.044e-07 9.552e-08 -6.981 -7.020 -0.039 - H[13C][18O]O2- 1.044e-07 9.552e-08 -6.981 -7.020 -0.039 - Ca[13C]O3 6.067e-08 6.077e-08 -7.217 -7.216 0.001 - [13C]O[18O] 4.569e-08 4.576e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.109e-08 2.179e-08 -7.507 -7.662 -0.154 - CaH[13C]O2[18O]+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 - CaH[13C][18O]O2+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 - Ca[13C]O2[18O] 3.631e-10 3.637e-10 -9.440 -9.439 0.001 - H[13C]O[18O]2- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 - H[13C][18O]2O- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 - H[13C][18O]O[18O]- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 - [13C]O2[18O]-2 1.861e-10 1.304e-10 -9.730 -9.885 -0.154 -[14C](-4) 2.688e-32 - [14C]H4 2.688e-32 2.693e-32 -31.570 -31.570 0.001 -[14C](4) 1.631e-15 - H[14C]O3- 1.318e-15 1.206e-15 -14.880 -14.919 -0.039 - [14C]O2 2.743e-16 2.747e-16 -15.562 -15.561 0.001 - CaH[14C]O3+ 2.783e-17 2.553e-17 -16.555 -16.593 -0.037 - H[14C]O2[18O]- 2.629e-18 2.405e-18 -17.580 -17.619 -0.039 - H[14C]O[18O]O- 2.629e-18 2.405e-18 -17.580 -17.619 -0.039 - H[14C][18O]O2- 2.629e-18 2.405e-18 -17.580 -17.619 -0.039 - Ca[14C]O3 1.525e-18 1.528e-18 -17.817 -17.816 0.001 - [14C]O[18O] 1.141e-18 1.142e-18 -17.943 -17.942 0.001 - [14C]O3-2 7.819e-19 5.480e-19 -18.107 -18.261 -0.154 - CaH[14C]O2[18O]+ 5.553e-20 5.095e-20 -19.255 -19.293 -0.037 - CaH[14C]O[18O]O+ 5.553e-20 5.095e-20 -19.255 -19.293 -0.037 - CaH[14C][18O]O2+ 5.553e-20 5.095e-20 -19.255 -19.293 -0.037 - Ca[14C]O2[18O] 9.131e-21 9.146e-21 -20.039 -20.039 0.001 - H[14C]O[18O]2- 5.245e-21 4.799e-21 -20.280 -20.319 -0.039 - H[14C][18O]2O- 5.245e-21 4.799e-21 -20.280 -20.319 -0.039 - H[14C][18O]O[18O]- 5.245e-21 4.799e-21 -20.280 -20.319 -0.039 - [14C]O2[18O]-2 4.680e-21 3.280e-21 -20.330 -20.484 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.281 -68.280 0.001 - [18O]2 0.000e+00 0.000e+00 -71.282 -71.281 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 9.764e-20 + CH4 9.764e-20 9.780e-20 -19.010 -19.010 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.067e-08 6.077e-08 -7.217 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.122e-13 + H2 5.612e-14 5.621e-14 -13.251 -13.250 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.882 -65.881 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.281 -68.280 0.001 (0) +[13C](-4) 1.077e-21 + [13C]H4 1.077e-21 1.079e-21 -20.968 -20.967 0.001 (0) +[13C](4) 6.487e-05 + H[13C]O3- 5.232e-05 4.787e-05 -4.281 -4.320 -0.039 (0) + [13C]O2 1.099e-05 1.101e-05 -4.959 -4.958 0.001 (0) + CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.044e-07 9.552e-08 -6.981 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.044e-07 9.552e-08 -6.981 -7.020 -0.039 (0) + H[13C][18O]O2- 1.044e-07 9.552e-08 -6.981 -7.020 -0.039 (0) + Ca[13C]O3 6.067e-08 6.077e-08 -7.217 -7.216 0.001 (0) + [13C]O[18O] 4.569e-08 4.576e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.109e-08 2.179e-08 -7.507 -7.662 -0.154 (0) + CaH[13C]O2[18O]+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.631e-10 3.637e-10 -9.440 -9.439 0.001 (0) + H[13C]O[18O]2- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]2O- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.861e-10 1.304e-10 -9.730 -9.885 -0.154 (0) +[14C](-4) 2.688e-32 + [14C]H4 2.688e-32 2.693e-32 -31.570 -31.570 0.001 (0) +[14C](4) 1.631e-15 + H[14C]O3- 1.318e-15 1.206e-15 -14.880 -14.919 -0.039 (0) + [14C]O2 2.743e-16 2.747e-16 -15.562 -15.561 0.001 (0) + CaH[14C]O3+ 2.783e-17 2.553e-17 -16.555 -16.593 -0.037 (0) + H[14C]O2[18O]- 2.629e-18 2.405e-18 -17.580 -17.619 -0.039 (0) + H[14C]O[18O]O- 2.629e-18 2.405e-18 -17.580 -17.619 -0.039 (0) + H[14C][18O]O2- 2.629e-18 2.405e-18 -17.580 -17.619 -0.039 (0) + Ca[14C]O3 1.525e-18 1.528e-18 -17.817 -17.816 0.001 (0) + [14C]O[18O] 1.141e-18 1.142e-18 -17.943 -17.942 0.001 (0) + [14C]O3-2 7.819e-19 5.480e-19 -18.107 -18.261 -0.154 (0) + CaH[14C]O2[18O]+ 5.553e-20 5.095e-20 -19.255 -19.293 -0.037 (0) + CaH[14C]O[18O]O+ 5.553e-20 5.095e-20 -19.255 -19.293 -0.037 (0) + CaH[14C][18O]O2+ 5.553e-20 5.095e-20 -19.255 -19.293 -0.037 (0) + Ca[14C]O2[18O] 9.131e-21 9.146e-21 -20.039 -20.039 0.001 (0) + H[14C]O[18O]2- 5.245e-21 4.799e-21 -20.280 -20.319 -0.039 (0) + H[14C][18O]2O- 5.245e-21 4.799e-21 -20.280 -20.319 -0.039 (0) + H[14C][18O]O[18O]- 5.245e-21 4.799e-21 -20.280 -20.319 -0.039 (0) + [14C]O2[18O]-2 4.680e-21 3.280e-21 -20.330 -20.484 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.281 -68.280 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.282 -71.281 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -4727,99 +4727,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 4.766e-19 - CH4 4.766e-19 4.774e-19 -18.322 -18.321 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.106e-06 1.014e-06 -5.956 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.069e-08 6.079e-08 -7.217 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.668e-13 - H2 8.341e-14 8.355e-14 -13.079 -13.078 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.226 -66.226 0.001 - O[18O] 0.000e+00 0.000e+00 -68.625 -68.625 0.001 -[13C](-4) 5.259e-21 - [13C]H4 5.259e-21 5.268e-21 -20.279 -20.278 0.001 -[13C](4) 6.490e-05 - H[13C]O3- 5.234e-05 4.789e-05 -4.281 -4.320 -0.039 - [13C]O2 1.099e-05 1.101e-05 -4.959 -4.958 0.001 - CaH[13C]O3+ 1.106e-06 1.014e-06 -5.956 -5.994 -0.037 - H[13C]O2[18O]- 1.044e-07 9.556e-08 -6.981 -7.020 -0.039 - H[13C]O[18O]O- 1.044e-07 9.556e-08 -6.981 -7.020 -0.039 - H[13C][18O]O2- 1.044e-07 9.556e-08 -6.981 -7.020 -0.039 - Ca[13C]O3 6.069e-08 6.079e-08 -7.217 -7.216 0.001 - [13C]O[18O] 4.571e-08 4.578e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.111e-08 2.180e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 - CaH[13C][18O]O2+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 - Ca[13C]O2[18O] 3.633e-10 3.639e-10 -9.440 -9.439 0.001 - H[13C]O[18O]2- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 - H[13C][18O]2O- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 - H[13C][18O]O[18O]- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 - [13C]O2[18O]-2 1.862e-10 1.305e-10 -9.730 -9.884 -0.154 -[14C](-4) 1.209e-31 - [14C]H4 1.209e-31 1.211e-31 -30.918 -30.917 0.001 -[14C](4) 1.503e-15 - H[14C]O3- 1.214e-15 1.111e-15 -14.916 -14.954 -0.039 - [14C]O2 2.527e-16 2.531e-16 -15.597 -15.597 0.001 - CaH[14C]O3+ 2.564e-17 2.352e-17 -16.591 -16.628 -0.037 - H[14C]O2[18O]- 2.422e-18 2.216e-18 -17.616 -17.654 -0.039 - H[14C]O[18O]O- 2.422e-18 2.216e-18 -17.616 -17.654 -0.039 - H[14C][18O]O2- 2.422e-18 2.216e-18 -17.616 -17.654 -0.039 - Ca[14C]O3 1.405e-18 1.408e-18 -17.852 -17.852 0.001 - [14C]O[18O] 1.051e-18 1.052e-18 -17.979 -17.978 0.001 - [14C]O3-2 7.203e-19 5.049e-19 -18.143 -18.297 -0.154 - CaH[14C]O2[18O]+ 5.116e-20 4.693e-20 -19.291 -19.329 -0.037 - CaH[14C]O[18O]O+ 5.116e-20 4.693e-20 -19.291 -19.329 -0.037 - CaH[14C][18O]O2+ 5.116e-20 4.693e-20 -19.291 -19.329 -0.037 - Ca[14C]O2[18O] 8.412e-21 8.425e-21 -20.075 -20.074 0.001 - H[14C]O[18O]2- 4.832e-21 4.421e-21 -20.316 -20.354 -0.039 - H[14C][18O]2O- 4.832e-21 4.421e-21 -20.316 -20.354 -0.039 - H[14C][18O]O[18O]- 4.832e-21 4.421e-21 -20.316 -20.354 -0.039 - [14C]O2[18O]-2 4.311e-21 3.022e-21 -20.365 -20.520 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.625 -68.625 0.001 - [18O]2 0.000e+00 0.000e+00 -71.626 -71.626 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 4.766e-19 + CH4 4.766e-19 4.774e-19 -18.322 -18.321 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.014e-06 -5.956 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.069e-08 6.079e-08 -7.217 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.668e-13 + H2 8.341e-14 8.355e-14 -13.079 -13.078 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.226 -66.226 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.625 -68.625 0.001 (0) +[13C](-4) 5.259e-21 + [13C]H4 5.259e-21 5.268e-21 -20.279 -20.278 0.001 (0) +[13C](4) 6.490e-05 + H[13C]O3- 5.234e-05 4.789e-05 -4.281 -4.320 -0.039 (0) + [13C]O2 1.099e-05 1.101e-05 -4.959 -4.958 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.014e-06 -5.956 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.044e-07 9.556e-08 -6.981 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.044e-07 9.556e-08 -6.981 -7.020 -0.039 (0) + H[13C][18O]O2- 1.044e-07 9.556e-08 -6.981 -7.020 -0.039 (0) + Ca[13C]O3 6.069e-08 6.079e-08 -7.217 -7.216 0.001 (0) + [13C]O[18O] 4.571e-08 4.578e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.111e-08 2.180e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.633e-10 3.639e-10 -9.440 -9.439 0.001 (0) + H[13C]O[18O]2- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]2O- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.862e-10 1.305e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 1.209e-31 + [14C]H4 1.209e-31 1.211e-31 -30.918 -30.917 0.001 (0) +[14C](4) 1.503e-15 + H[14C]O3- 1.214e-15 1.111e-15 -14.916 -14.954 -0.039 (0) + [14C]O2 2.527e-16 2.531e-16 -15.597 -15.597 0.001 (0) + CaH[14C]O3+ 2.564e-17 2.352e-17 -16.591 -16.628 -0.037 (0) + H[14C]O2[18O]- 2.422e-18 2.216e-18 -17.616 -17.654 -0.039 (0) + H[14C]O[18O]O- 2.422e-18 2.216e-18 -17.616 -17.654 -0.039 (0) + H[14C][18O]O2- 2.422e-18 2.216e-18 -17.616 -17.654 -0.039 (0) + Ca[14C]O3 1.405e-18 1.408e-18 -17.852 -17.852 0.001 (0) + [14C]O[18O] 1.051e-18 1.052e-18 -17.979 -17.978 0.001 (0) + [14C]O3-2 7.203e-19 5.049e-19 -18.143 -18.297 -0.154 (0) + CaH[14C]O2[18O]+ 5.116e-20 4.693e-20 -19.291 -19.329 -0.037 (0) + CaH[14C]O[18O]O+ 5.116e-20 4.693e-20 -19.291 -19.329 -0.037 (0) + CaH[14C][18O]O2+ 5.116e-20 4.693e-20 -19.291 -19.329 -0.037 (0) + Ca[14C]O2[18O] 8.412e-21 8.425e-21 -20.075 -20.074 0.001 (0) + H[14C]O[18O]2- 4.832e-21 4.421e-21 -20.316 -20.354 -0.039 (0) + H[14C][18O]2O- 4.832e-21 4.421e-21 -20.316 -20.354 -0.039 (0) + H[14C][18O]O[18O]- 4.832e-21 4.421e-21 -20.316 -20.354 -0.039 (0) + [14C]O2[18O]-2 4.311e-21 3.022e-21 -20.365 -20.520 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.625 -68.625 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.626 -71.626 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -5001,99 +5001,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 4.482e-19 - CH4 4.482e-19 4.489e-19 -18.349 -18.348 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.071e-08 6.081e-08 -7.217 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.643e-13 - H2 8.214e-14 8.227e-14 -13.085 -13.085 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.213 -66.212 0.001 - O[18O] 0.000e+00 0.000e+00 -68.612 -68.611 0.001 -[13C](-4) 4.947e-21 - [13C]H4 4.947e-21 4.955e-21 -20.306 -20.305 0.001 -[13C](4) 6.492e-05 - H[13C]O3- 5.236e-05 4.791e-05 -4.281 -4.320 -0.039 - [13C]O2 1.100e-05 1.101e-05 -4.959 -4.958 0.001 - CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 - H[13C]O2[18O]- 1.045e-07 9.559e-08 -6.981 -7.020 -0.039 - H[13C]O[18O]O- 1.045e-07 9.559e-08 -6.981 -7.020 -0.039 - H[13C][18O]O2- 1.045e-07 9.559e-08 -6.981 -7.020 -0.039 - Ca[13C]O3 6.071e-08 6.081e-08 -7.217 -7.216 0.001 - [13C]O[18O] 4.572e-08 4.580e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.112e-08 2.181e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 - CaH[13C][18O]O2+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 - Ca[13C]O2[18O] 3.634e-10 3.640e-10 -9.440 -9.439 0.001 - H[13C]O[18O]2- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 - H[13C][18O]2O- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 - H[13C][18O]O[18O]- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 - [13C]O2[18O]-2 1.863e-10 1.305e-10 -9.730 -9.884 -0.154 -[14C](-4) 1.047e-31 - [14C]H4 1.047e-31 1.049e-31 -30.980 -30.979 0.001 -[14C](4) 1.384e-15 - H[14C]O3- 1.118e-15 1.023e-15 -14.951 -14.990 -0.039 - [14C]O2 2.328e-16 2.332e-16 -15.633 -15.632 0.001 - CaH[14C]O3+ 2.362e-17 2.167e-17 -16.627 -16.664 -0.037 - H[14C]O2[18O]- 2.231e-18 2.041e-18 -17.652 -17.690 -0.039 - H[14C]O[18O]O- 2.231e-18 2.041e-18 -17.652 -17.690 -0.039 - H[14C][18O]O2- 2.231e-18 2.041e-18 -17.652 -17.690 -0.039 - Ca[14C]O3 1.295e-18 1.297e-18 -17.888 -17.887 0.001 - [14C]O[18O] 9.679e-19 9.695e-19 -18.014 -18.013 0.001 - [14C]O3-2 6.635e-19 4.651e-19 -18.178 -18.332 -0.154 - CaH[14C]O2[18O]+ 4.713e-20 4.324e-20 -19.327 -19.364 -0.037 - CaH[14C]O[18O]O+ 4.713e-20 4.324e-20 -19.327 -19.364 -0.037 - CaH[14C][18O]O2+ 4.713e-20 4.324e-20 -19.327 -19.364 -0.037 - Ca[14C]O2[18O] 7.749e-21 7.762e-21 -20.111 -20.110 0.001 - H[14C]O[18O]2- 4.451e-21 4.073e-21 -20.352 -20.390 -0.039 - H[14C][18O]2O- 4.451e-21 4.073e-21 -20.352 -20.390 -0.039 - H[14C][18O]O[18O]- 4.451e-21 4.073e-21 -20.352 -20.390 -0.039 - [14C]O2[18O]-2 3.972e-21 2.784e-21 -20.401 -20.555 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.612 -68.611 0.001 - [18O]2 0.000e+00 0.000e+00 -71.613 -71.612 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 4.482e-19 + CH4 4.482e-19 4.489e-19 -18.349 -18.348 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.071e-08 6.081e-08 -7.217 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.643e-13 + H2 8.214e-14 8.227e-14 -13.085 -13.085 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.213 -66.212 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.612 -68.611 0.001 (0) +[13C](-4) 4.947e-21 + [13C]H4 4.947e-21 4.955e-21 -20.306 -20.305 0.001 (0) +[13C](4) 6.492e-05 + H[13C]O3- 5.236e-05 4.791e-05 -4.281 -4.320 -0.039 (0) + [13C]O2 1.100e-05 1.101e-05 -4.959 -4.958 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.045e-07 9.559e-08 -6.981 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.045e-07 9.559e-08 -6.981 -7.020 -0.039 (0) + H[13C][18O]O2- 1.045e-07 9.559e-08 -6.981 -7.020 -0.039 (0) + Ca[13C]O3 6.071e-08 6.081e-08 -7.217 -7.216 0.001 (0) + [13C]O[18O] 4.572e-08 4.580e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.112e-08 2.181e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.634e-10 3.640e-10 -9.440 -9.439 0.001 (0) + H[13C]O[18O]2- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]2O- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.863e-10 1.305e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 1.047e-31 + [14C]H4 1.047e-31 1.049e-31 -30.980 -30.979 0.001 (0) +[14C](4) 1.384e-15 + H[14C]O3- 1.118e-15 1.023e-15 -14.951 -14.990 -0.039 (0) + [14C]O2 2.328e-16 2.332e-16 -15.633 -15.632 0.001 (0) + CaH[14C]O3+ 2.362e-17 2.167e-17 -16.627 -16.664 -0.037 (0) + H[14C]O2[18O]- 2.231e-18 2.041e-18 -17.652 -17.690 -0.039 (0) + H[14C]O[18O]O- 2.231e-18 2.041e-18 -17.652 -17.690 -0.039 (0) + H[14C][18O]O2- 2.231e-18 2.041e-18 -17.652 -17.690 -0.039 (0) + Ca[14C]O3 1.295e-18 1.297e-18 -17.888 -17.887 0.001 (0) + [14C]O[18O] 9.679e-19 9.695e-19 -18.014 -18.013 0.001 (0) + [14C]O3-2 6.635e-19 4.651e-19 -18.178 -18.332 -0.154 (0) + CaH[14C]O2[18O]+ 4.713e-20 4.324e-20 -19.327 -19.364 -0.037 (0) + CaH[14C]O[18O]O+ 4.713e-20 4.324e-20 -19.327 -19.364 -0.037 (0) + CaH[14C][18O]O2+ 4.713e-20 4.324e-20 -19.327 -19.364 -0.037 (0) + Ca[14C]O2[18O] 7.749e-21 7.762e-21 -20.111 -20.110 0.001 (0) + H[14C]O[18O]2- 4.451e-21 4.073e-21 -20.352 -20.390 -0.039 (0) + H[14C][18O]2O- 4.451e-21 4.073e-21 -20.352 -20.390 -0.039 (0) + H[14C][18O]O[18O]- 4.451e-21 4.073e-21 -20.352 -20.390 -0.039 (0) + [14C]O2[18O]-2 3.972e-21 2.784e-21 -20.401 -20.555 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.612 -68.611 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.613 -71.612 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -5275,99 +5275,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 2.949e-19 - CH4 2.949e-19 2.954e-19 -18.530 -18.530 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.073e-08 6.083e-08 -7.217 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.480e-13 - H2 7.398e-14 7.410e-14 -13.131 -13.130 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.122 -66.121 0.001 - O[18O] 0.000e+00 0.000e+00 -68.521 -68.520 0.001 -[13C](-4) 3.257e-21 - [13C]H4 3.257e-21 3.262e-21 -20.487 -20.487 0.001 -[13C](4) 6.494e-05 - H[13C]O3- 5.238e-05 4.793e-05 -4.281 -4.319 -0.039 - [13C]O2 1.100e-05 1.102e-05 -4.959 -4.958 0.001 - CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.045e-07 9.562e-08 -6.981 -7.019 -0.039 - H[13C]O[18O]O- 1.045e-07 9.562e-08 -6.981 -7.019 -0.039 - H[13C][18O]O2- 1.045e-07 9.562e-08 -6.981 -7.019 -0.039 - Ca[13C]O3 6.073e-08 6.083e-08 -7.217 -7.216 0.001 - [13C]O[18O] 4.574e-08 4.581e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.113e-08 2.182e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.208e-09 2.025e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.208e-09 2.025e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.208e-09 2.025e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.635e-10 3.641e-10 -9.439 -9.439 0.001 - H[13C]O[18O]2- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 - H[13C][18O]2O- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 - H[13C][18O]O[18O]- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 - [13C]O2[18O]-2 1.863e-10 1.306e-10 -9.730 -9.884 -0.154 -[14C](-4) 6.349e-32 - [14C]H4 6.349e-32 6.359e-32 -31.197 -31.197 0.001 -[14C](4) 1.275e-15 - H[14C]O3- 1.030e-15 9.425e-16 -14.987 -15.026 -0.039 - [14C]O2 2.144e-16 2.148e-16 -15.669 -15.668 0.001 - CaH[14C]O3+ 2.176e-17 1.996e-17 -16.662 -16.700 -0.037 - H[14C]O2[18O]- 2.055e-18 1.880e-18 -17.687 -17.726 -0.039 - H[14C]O[18O]O- 2.055e-18 1.880e-18 -17.687 -17.726 -0.039 - H[14C][18O]O2- 2.055e-18 1.880e-18 -17.687 -17.726 -0.039 - Ca[14C]O3 1.193e-18 1.195e-18 -17.923 -17.923 0.001 - [14C]O[18O] 8.917e-19 8.932e-19 -18.050 -18.049 0.001 - [14C]O3-2 6.113e-19 4.284e-19 -18.214 -18.368 -0.154 - CaH[14C]O2[18O]+ 4.341e-20 3.983e-20 -19.362 -19.400 -0.037 - CaH[14C]O[18O]O+ 4.341e-20 3.983e-20 -19.362 -19.400 -0.037 - CaH[14C][18O]O2+ 4.341e-20 3.983e-20 -19.362 -19.400 -0.037 - Ca[14C]O2[18O] 7.138e-21 7.150e-21 -20.146 -20.146 0.001 - H[14C]O[18O]2- 4.101e-21 3.752e-21 -20.387 -20.426 -0.039 - H[14C][18O]2O- 4.101e-21 3.752e-21 -20.387 -20.426 -0.039 - H[14C][18O]O[18O]- 4.101e-21 3.752e-21 -20.387 -20.426 -0.039 - [14C]O2[18O]-2 3.659e-21 2.564e-21 -20.437 -20.591 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.521 -68.520 0.001 - [18O]2 0.000e+00 0.000e+00 -71.522 -71.521 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 2.949e-19 + CH4 2.949e-19 2.954e-19 -18.530 -18.530 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.073e-08 6.083e-08 -7.217 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.480e-13 + H2 7.398e-14 7.410e-14 -13.131 -13.130 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.122 -66.121 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.521 -68.520 0.001 (0) +[13C](-4) 3.257e-21 + [13C]H4 3.257e-21 3.262e-21 -20.487 -20.487 0.001 (0) +[13C](4) 6.494e-05 + H[13C]O3- 5.238e-05 4.793e-05 -4.281 -4.319 -0.039 (0) + [13C]O2 1.100e-05 1.102e-05 -4.959 -4.958 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.045e-07 9.562e-08 -6.981 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.045e-07 9.562e-08 -6.981 -7.019 -0.039 (0) + H[13C][18O]O2- 1.045e-07 9.562e-08 -6.981 -7.019 -0.039 (0) + Ca[13C]O3 6.073e-08 6.083e-08 -7.217 -7.216 0.001 (0) + [13C]O[18O] 4.574e-08 4.581e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.113e-08 2.182e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.208e-09 2.025e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.208e-09 2.025e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.208e-09 2.025e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.635e-10 3.641e-10 -9.439 -9.439 0.001 (0) + H[13C]O[18O]2- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]2O- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.863e-10 1.306e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 6.349e-32 + [14C]H4 6.349e-32 6.359e-32 -31.197 -31.197 0.001 (0) +[14C](4) 1.275e-15 + H[14C]O3- 1.030e-15 9.425e-16 -14.987 -15.026 -0.039 (0) + [14C]O2 2.144e-16 2.148e-16 -15.669 -15.668 0.001 (0) + CaH[14C]O3+ 2.176e-17 1.996e-17 -16.662 -16.700 -0.037 (0) + H[14C]O2[18O]- 2.055e-18 1.880e-18 -17.687 -17.726 -0.039 (0) + H[14C]O[18O]O- 2.055e-18 1.880e-18 -17.687 -17.726 -0.039 (0) + H[14C][18O]O2- 2.055e-18 1.880e-18 -17.687 -17.726 -0.039 (0) + Ca[14C]O3 1.193e-18 1.195e-18 -17.923 -17.923 0.001 (0) + [14C]O[18O] 8.917e-19 8.932e-19 -18.050 -18.049 0.001 (0) + [14C]O3-2 6.113e-19 4.284e-19 -18.214 -18.368 -0.154 (0) + CaH[14C]O2[18O]+ 4.341e-20 3.983e-20 -19.362 -19.400 -0.037 (0) + CaH[14C]O[18O]O+ 4.341e-20 3.983e-20 -19.362 -19.400 -0.037 (0) + CaH[14C][18O]O2+ 4.341e-20 3.983e-20 -19.362 -19.400 -0.037 (0) + Ca[14C]O2[18O] 7.138e-21 7.150e-21 -20.146 -20.146 0.001 (0) + H[14C]O[18O]2- 4.101e-21 3.752e-21 -20.387 -20.426 -0.039 (0) + H[14C][18O]2O- 4.101e-21 3.752e-21 -20.387 -20.426 -0.039 (0) + H[14C][18O]O[18O]- 4.101e-21 3.752e-21 -20.387 -20.426 -0.039 (0) + [14C]O2[18O]-2 3.659e-21 2.564e-21 -20.437 -20.591 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.521 -68.520 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.522 -71.521 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -5549,99 +5549,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 2.696e-19 - CH4 2.696e-19 2.701e-19 -18.569 -18.569 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.075e-08 6.085e-08 -7.216 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.447e-13 - H2 7.234e-14 7.246e-14 -13.141 -13.140 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.103 -66.102 0.001 - O[18O] 0.000e+00 0.000e+00 -68.502 -68.501 0.001 -[13C](-4) 2.978e-21 - [13C]H4 2.978e-21 2.983e-21 -20.526 -20.525 0.001 -[13C](4) 6.496e-05 - H[13C]O3- 5.240e-05 4.794e-05 -4.281 -4.319 -0.039 - [13C]O2 1.100e-05 1.102e-05 -4.959 -4.958 0.001 - CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.045e-07 9.565e-08 -6.981 -7.019 -0.039 - H[13C]O[18O]O- 1.045e-07 9.565e-08 -6.981 -7.019 -0.039 - H[13C][18O]O2- 1.045e-07 9.565e-08 -6.981 -7.019 -0.039 - Ca[13C]O3 6.075e-08 6.085e-08 -7.216 -7.216 0.001 - [13C]O[18O] 4.575e-08 4.583e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.114e-08 2.182e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.636e-10 3.642e-10 -9.439 -9.439 0.001 - H[13C]O[18O]2- 2.086e-10 1.908e-10 -9.681 -9.719 -0.039 - H[13C][18O]2O- 2.086e-10 1.908e-10 -9.681 -9.719 -0.039 - H[13C][18O]O[18O]- 2.086e-10 1.908e-10 -9.681 -9.719 -0.039 - [13C]O2[18O]-2 1.864e-10 1.306e-10 -9.730 -9.884 -0.154 -[14C](-4) 5.347e-32 - [14C]H4 5.347e-32 5.356e-32 -31.272 -31.271 0.001 -[14C](4) 1.175e-15 - H[14C]O3- 9.489e-16 8.683e-16 -15.023 -15.061 -0.039 - [14C]O2 1.975e-16 1.979e-16 -15.704 -15.704 0.001 - CaH[14C]O3+ 2.005e-17 1.839e-17 -16.698 -16.735 -0.037 - H[14C]O2[18O]- 1.893e-18 1.732e-18 -17.723 -17.761 -0.039 - H[14C]O[18O]O- 1.893e-18 1.732e-18 -17.723 -17.761 -0.039 - H[14C][18O]O2- 1.893e-18 1.732e-18 -17.723 -17.761 -0.039 - Ca[14C]O3 1.099e-18 1.100e-18 -17.959 -17.958 0.001 - [14C]O[18O] 8.215e-19 8.228e-19 -18.085 -18.085 0.001 - [14C]O3-2 5.631e-19 3.947e-19 -18.249 -18.404 -0.154 - CaH[14C]O2[18O]+ 3.999e-20 3.669e-20 -19.398 -19.435 -0.037 - CaH[14C]O[18O]O+ 3.999e-20 3.669e-20 -19.398 -19.435 -0.037 - CaH[14C][18O]O2+ 3.999e-20 3.669e-20 -19.398 -19.435 -0.037 - Ca[14C]O2[18O] 6.576e-21 6.587e-21 -20.182 -20.181 0.001 - H[14C]O[18O]2- 3.777e-21 3.456e-21 -20.423 -20.461 -0.039 - H[14C][18O]2O- 3.777e-21 3.456e-21 -20.423 -20.461 -0.039 - H[14C][18O]O[18O]- 3.777e-21 3.456e-21 -20.423 -20.461 -0.039 - [14C]O2[18O]-2 3.371e-21 2.362e-21 -20.472 -20.627 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.502 -68.501 0.001 - [18O]2 0.000e+00 0.000e+00 -71.503 -71.502 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 2.696e-19 + CH4 2.696e-19 2.701e-19 -18.569 -18.569 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.075e-08 6.085e-08 -7.216 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.447e-13 + H2 7.234e-14 7.246e-14 -13.141 -13.140 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.103 -66.102 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.502 -68.501 0.001 (0) +[13C](-4) 2.978e-21 + [13C]H4 2.978e-21 2.983e-21 -20.526 -20.525 0.001 (0) +[13C](4) 6.496e-05 + H[13C]O3- 5.240e-05 4.794e-05 -4.281 -4.319 -0.039 (0) + [13C]O2 1.100e-05 1.102e-05 -4.959 -4.958 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.045e-07 9.565e-08 -6.981 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.045e-07 9.565e-08 -6.981 -7.019 -0.039 (0) + H[13C][18O]O2- 1.045e-07 9.565e-08 -6.981 -7.019 -0.039 (0) + Ca[13C]O3 6.075e-08 6.085e-08 -7.216 -7.216 0.001 (0) + [13C]O[18O] 4.575e-08 4.583e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.114e-08 2.182e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.636e-10 3.642e-10 -9.439 -9.439 0.001 (0) + H[13C]O[18O]2- 2.086e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]2O- 2.086e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.086e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.864e-10 1.306e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 5.347e-32 + [14C]H4 5.347e-32 5.356e-32 -31.272 -31.271 0.001 (0) +[14C](4) 1.175e-15 + H[14C]O3- 9.489e-16 8.683e-16 -15.023 -15.061 -0.039 (0) + [14C]O2 1.975e-16 1.979e-16 -15.704 -15.704 0.001 (0) + CaH[14C]O3+ 2.005e-17 1.839e-17 -16.698 -16.735 -0.037 (0) + H[14C]O2[18O]- 1.893e-18 1.732e-18 -17.723 -17.761 -0.039 (0) + H[14C]O[18O]O- 1.893e-18 1.732e-18 -17.723 -17.761 -0.039 (0) + H[14C][18O]O2- 1.893e-18 1.732e-18 -17.723 -17.761 -0.039 (0) + Ca[14C]O3 1.099e-18 1.100e-18 -17.959 -17.958 0.001 (0) + [14C]O[18O] 8.215e-19 8.228e-19 -18.085 -18.085 0.001 (0) + [14C]O3-2 5.631e-19 3.947e-19 -18.249 -18.404 -0.154 (0) + CaH[14C]O2[18O]+ 3.999e-20 3.669e-20 -19.398 -19.435 -0.037 (0) + CaH[14C]O[18O]O+ 3.999e-20 3.669e-20 -19.398 -19.435 -0.037 (0) + CaH[14C][18O]O2+ 3.999e-20 3.669e-20 -19.398 -19.435 -0.037 (0) + Ca[14C]O2[18O] 6.576e-21 6.587e-21 -20.182 -20.181 0.001 (0) + H[14C]O[18O]2- 3.777e-21 3.456e-21 -20.423 -20.461 -0.039 (0) + H[14C][18O]2O- 3.777e-21 3.456e-21 -20.423 -20.461 -0.039 (0) + H[14C][18O]O[18O]- 3.777e-21 3.456e-21 -20.423 -20.461 -0.039 (0) + [14C]O2[18O]-2 3.371e-21 2.362e-21 -20.472 -20.627 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.502 -68.501 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.503 -71.502 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -5823,99 +5823,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 9.624e-19 - CH4 9.624e-19 9.640e-19 -18.017 -18.016 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.077e-08 6.087e-08 -7.216 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.989e-13 - H2 9.943e-14 9.960e-14 -13.002 -13.002 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.379 -66.378 0.001 - O[18O] 0.000e+00 0.000e+00 -68.778 -68.777 0.001 -[13C](-4) 1.063e-20 - [13C]H4 1.063e-20 1.065e-20 -19.973 -19.973 0.001 -[13C](4) 6.498e-05 - H[13C]O3- 5.241e-05 4.795e-05 -4.281 -4.319 -0.039 - [13C]O2 1.101e-05 1.102e-05 -4.958 -4.958 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.568e-08 -6.981 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.568e-08 -6.981 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.568e-08 -6.981 -7.019 -0.039 - Ca[13C]O3 6.077e-08 6.087e-08 -7.216 -7.216 0.001 - [13C]O[18O] 4.576e-08 4.584e-08 -7.339 -7.339 0.001 - [13C]O3-2 3.115e-08 2.183e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.637e-10 3.643e-10 -9.439 -9.439 0.001 - H[13C]O[18O]2- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]2O- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]O[18O]- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - [13C]O2[18O]-2 1.864e-10 1.307e-10 -9.730 -9.884 -0.154 -[14C](-4) 1.758e-31 - [14C]H4 1.758e-31 1.761e-31 -30.755 -30.754 0.001 -[14C](4) 1.082e-15 - H[14C]O3- 8.742e-16 7.999e-16 -15.058 -15.097 -0.039 - [14C]O2 1.820e-16 1.823e-16 -15.740 -15.739 0.001 - CaH[14C]O3+ 1.847e-17 1.694e-17 -16.734 -16.771 -0.037 - H[14C]O2[18O]- 1.744e-18 1.596e-18 -17.758 -17.797 -0.039 - H[14C]O[18O]O- 1.744e-18 1.596e-18 -17.758 -17.797 -0.039 - H[14C][18O]O2- 1.744e-18 1.596e-18 -17.758 -17.797 -0.039 - Ca[14C]O3 1.012e-18 1.014e-18 -17.995 -17.994 0.001 - [14C]O[18O] 7.567e-19 7.580e-19 -18.121 -18.120 0.001 - [14C]O3-2 5.188e-19 3.636e-19 -18.285 -18.439 -0.154 - CaH[14C]O2[18O]+ 3.684e-20 3.380e-20 -19.434 -19.471 -0.037 - CaH[14C]O[18O]O+ 3.684e-20 3.380e-20 -19.434 -19.471 -0.037 - CaH[14C][18O]O2+ 3.684e-20 3.380e-20 -19.434 -19.471 -0.037 - Ca[14C]O2[18O] 6.058e-21 6.068e-21 -20.218 -20.217 0.001 - H[14C]O[18O]2- 3.480e-21 3.184e-21 -20.458 -20.497 -0.039 - H[14C][18O]2O- 3.480e-21 3.184e-21 -20.458 -20.497 -0.039 - H[14C][18O]O[18O]- 3.480e-21 3.184e-21 -20.458 -20.497 -0.039 - [14C]O2[18O]-2 3.105e-21 2.176e-21 -20.508 -20.662 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.778 -68.777 0.001 - [18O]2 0.000e+00 0.000e+00 -71.779 -71.778 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 9.624e-19 + CH4 9.624e-19 9.640e-19 -18.017 -18.016 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.077e-08 6.087e-08 -7.216 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.989e-13 + H2 9.943e-14 9.960e-14 -13.002 -13.002 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.379 -66.378 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.778 -68.777 0.001 (0) +[13C](-4) 1.063e-20 + [13C]H4 1.063e-20 1.065e-20 -19.973 -19.973 0.001 (0) +[13C](4) 6.498e-05 + H[13C]O3- 5.241e-05 4.795e-05 -4.281 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.102e-05 -4.958 -4.958 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.568e-08 -6.981 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.568e-08 -6.981 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.568e-08 -6.981 -7.019 -0.039 (0) + Ca[13C]O3 6.077e-08 6.087e-08 -7.216 -7.216 0.001 (0) + [13C]O[18O] 4.576e-08 4.584e-08 -7.339 -7.339 0.001 (0) + [13C]O3-2 3.115e-08 2.183e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.637e-10 3.643e-10 -9.439 -9.439 0.001 (0) + H[13C]O[18O]2- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]2O- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.864e-10 1.307e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 1.758e-31 + [14C]H4 1.758e-31 1.761e-31 -30.755 -30.754 0.001 (0) +[14C](4) 1.082e-15 + H[14C]O3- 8.742e-16 7.999e-16 -15.058 -15.097 -0.039 (0) + [14C]O2 1.820e-16 1.823e-16 -15.740 -15.739 0.001 (0) + CaH[14C]O3+ 1.847e-17 1.694e-17 -16.734 -16.771 -0.037 (0) + H[14C]O2[18O]- 1.744e-18 1.596e-18 -17.758 -17.797 -0.039 (0) + H[14C]O[18O]O- 1.744e-18 1.596e-18 -17.758 -17.797 -0.039 (0) + H[14C][18O]O2- 1.744e-18 1.596e-18 -17.758 -17.797 -0.039 (0) + Ca[14C]O3 1.012e-18 1.014e-18 -17.995 -17.994 0.001 (0) + [14C]O[18O] 7.567e-19 7.580e-19 -18.121 -18.120 0.001 (0) + [14C]O3-2 5.188e-19 3.636e-19 -18.285 -18.439 -0.154 (0) + CaH[14C]O2[18O]+ 3.684e-20 3.380e-20 -19.434 -19.471 -0.037 (0) + CaH[14C]O[18O]O+ 3.684e-20 3.380e-20 -19.434 -19.471 -0.037 (0) + CaH[14C][18O]O2+ 3.684e-20 3.380e-20 -19.434 -19.471 -0.037 (0) + Ca[14C]O2[18O] 6.058e-21 6.068e-21 -20.218 -20.217 0.001 (0) + H[14C]O[18O]2- 3.480e-21 3.184e-21 -20.458 -20.497 -0.039 (0) + H[14C][18O]2O- 3.480e-21 3.184e-21 -20.458 -20.497 -0.039 (0) + H[14C][18O]O[18O]- 3.480e-21 3.184e-21 -20.458 -20.497 -0.039 (0) + [14C]O2[18O]-2 3.105e-21 2.176e-21 -20.508 -20.662 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.778 -68.777 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.779 -71.778 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -6097,99 +6097,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.099e-18 - CH4 1.099e-18 1.101e-18 -17.959 -17.958 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.078e-08 6.088e-08 -7.216 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 2.056e-13 - H2 1.028e-13 1.030e-13 -12.988 -12.987 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.408 -66.407 0.001 - O[18O] 0.000e+00 0.000e+00 -68.807 -68.806 0.001 -[13C](-4) 1.214e-20 - [13C]H4 1.214e-20 1.216e-20 -19.916 -19.915 0.001 -[13C](4) 6.500e-05 - H[13C]O3- 5.242e-05 4.797e-05 -4.280 -4.319 -0.039 - [13C]O2 1.101e-05 1.103e-05 -4.958 -4.958 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.570e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.570e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.570e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.078e-08 6.088e-08 -7.216 -7.216 0.001 - [13C]O[18O] 4.578e-08 4.585e-08 -7.339 -7.339 0.001 - [13C]O3-2 3.115e-08 2.184e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.638e-10 3.644e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]2O- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]O[18O]- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 - [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 -[14C](-4) 1.849e-31 - [14C]H4 1.849e-31 1.852e-31 -30.733 -30.732 0.001 -[14C](4) 9.970e-16 - H[14C]O3- 8.053e-16 7.369e-16 -15.094 -15.133 -0.039 - [14C]O2 1.676e-16 1.679e-16 -15.776 -15.775 0.001 - CaH[14C]O3+ 1.701e-17 1.561e-17 -16.769 -16.807 -0.037 - H[14C]O2[18O]- 1.607e-18 1.470e-18 -17.794 -17.833 -0.039 - H[14C]O[18O]O- 1.607e-18 1.470e-18 -17.794 -17.833 -0.039 - H[14C][18O]O2- 1.607e-18 1.470e-18 -17.794 -17.833 -0.039 - Ca[14C]O3 9.324e-19 9.339e-19 -18.030 -18.030 0.001 - [14C]O[18O] 6.971e-19 6.983e-19 -18.157 -18.156 0.001 - [14C]O3-2 4.779e-19 3.350e-19 -18.321 -18.475 -0.154 - CaH[14C]O2[18O]+ 3.394e-20 3.114e-20 -19.469 -19.507 -0.037 - CaH[14C]O[18O]O+ 3.394e-20 3.114e-20 -19.469 -19.507 -0.037 - CaH[14C][18O]O2+ 3.394e-20 3.114e-20 -19.469 -19.507 -0.037 - Ca[14C]O2[18O] 5.581e-21 5.590e-21 -20.253 -20.253 0.001 - H[14C]O[18O]2- 3.206e-21 2.933e-21 -20.494 -20.533 -0.039 - H[14C][18O]2O- 3.206e-21 2.933e-21 -20.494 -20.533 -0.039 - H[14C][18O]O[18O]- 3.206e-21 2.933e-21 -20.494 -20.533 -0.039 - [14C]O2[18O]-2 2.860e-21 2.005e-21 -20.544 -20.698 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.807 -68.806 0.001 - [18O]2 0.000e+00 0.000e+00 -71.808 -71.807 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.099e-18 + CH4 1.099e-18 1.101e-18 -17.959 -17.958 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.078e-08 6.088e-08 -7.216 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 2.056e-13 + H2 1.028e-13 1.030e-13 -12.988 -12.987 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.408 -66.407 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.807 -68.806 0.001 (0) +[13C](-4) 1.214e-20 + [13C]H4 1.214e-20 1.216e-20 -19.916 -19.915 0.001 (0) +[13C](4) 6.500e-05 + H[13C]O3- 5.242e-05 4.797e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.103e-05 -4.958 -4.958 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.570e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.570e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.570e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.078e-08 6.088e-08 -7.216 -7.216 0.001 (0) + [13C]O[18O] 4.578e-08 4.585e-08 -7.339 -7.339 0.001 (0) + [13C]O3-2 3.115e-08 2.184e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.638e-10 3.644e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]2O- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 (0) +[14C](-4) 1.849e-31 + [14C]H4 1.849e-31 1.852e-31 -30.733 -30.732 0.001 (0) +[14C](4) 9.970e-16 + H[14C]O3- 8.053e-16 7.369e-16 -15.094 -15.133 -0.039 (0) + [14C]O2 1.676e-16 1.679e-16 -15.776 -15.775 0.001 (0) + CaH[14C]O3+ 1.701e-17 1.561e-17 -16.769 -16.807 -0.037 (0) + H[14C]O2[18O]- 1.607e-18 1.470e-18 -17.794 -17.833 -0.039 (0) + H[14C]O[18O]O- 1.607e-18 1.470e-18 -17.794 -17.833 -0.039 (0) + H[14C][18O]O2- 1.607e-18 1.470e-18 -17.794 -17.833 -0.039 (0) + Ca[14C]O3 9.324e-19 9.339e-19 -18.030 -18.030 0.001 (0) + [14C]O[18O] 6.971e-19 6.983e-19 -18.157 -18.156 0.001 (0) + [14C]O3-2 4.779e-19 3.350e-19 -18.321 -18.475 -0.154 (0) + CaH[14C]O2[18O]+ 3.394e-20 3.114e-20 -19.469 -19.507 -0.037 (0) + CaH[14C]O[18O]O+ 3.394e-20 3.114e-20 -19.469 -19.507 -0.037 (0) + CaH[14C][18O]O2+ 3.394e-20 3.114e-20 -19.469 -19.507 -0.037 (0) + Ca[14C]O2[18O] 5.581e-21 5.590e-21 -20.253 -20.253 0.001 (0) + H[14C]O[18O]2- 3.206e-21 2.933e-21 -20.494 -20.533 -0.039 (0) + H[14C][18O]2O- 3.206e-21 2.933e-21 -20.494 -20.533 -0.039 (0) + H[14C][18O]O[18O]- 3.206e-21 2.933e-21 -20.494 -20.533 -0.039 (0) + [14C]O2[18O]-2 2.860e-21 2.005e-21 -20.544 -20.698 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.807 -68.806 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.808 -71.807 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -6371,99 +6371,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 4.958e-19 - CH4 4.958e-19 4.966e-19 -18.305 -18.304 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.080e-08 6.090e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.685e-13 - H2 8.424e-14 8.438e-14 -13.074 -13.074 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.235 -66.234 0.001 - O[18O] 0.000e+00 0.000e+00 -68.634 -68.633 0.001 -[13C](-4) 5.480e-21 - [13C]H4 5.480e-21 5.489e-21 -20.261 -20.260 0.001 -[13C](4) 6.501e-05 - H[13C]O3- 5.244e-05 4.798e-05 -4.280 -4.319 -0.039 - [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.080e-08 6.090e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.579e-08 4.586e-08 -7.339 -7.339 0.001 - [13C]O3-2 3.116e-08 2.184e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.639e-10 3.645e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 -[14C](-4) 7.687e-32 - [14C]H4 7.687e-32 7.699e-32 -31.114 -31.114 0.001 -[14C](4) 9.185e-16 - H[14C]O3- 7.419e-16 6.788e-16 -15.130 -15.168 -0.039 - [14C]O2 1.544e-16 1.547e-16 -15.811 -15.811 0.001 - CaH[14C]O3+ 1.567e-17 1.438e-17 -16.805 -16.842 -0.037 - H[14C]O2[18O]- 1.480e-18 1.354e-18 -17.830 -17.868 -0.039 - H[14C]O[18O]O- 1.480e-18 1.354e-18 -17.830 -17.868 -0.039 - H[14C][18O]O2- 1.480e-18 1.354e-18 -17.830 -17.868 -0.039 - Ca[14C]O3 8.589e-19 8.604e-19 -18.066 -18.065 0.001 - [14C]O[18O] 6.422e-19 6.433e-19 -18.192 -18.192 0.001 - [14C]O3-2 4.402e-19 3.086e-19 -18.356 -18.511 -0.154 - CaH[14C]O2[18O]+ 3.127e-20 2.869e-20 -19.505 -19.542 -0.037 - CaH[14C]O[18O]O+ 3.127e-20 2.869e-20 -19.505 -19.542 -0.037 - CaH[14C][18O]O2+ 3.127e-20 2.869e-20 -19.505 -19.542 -0.037 - Ca[14C]O2[18O] 5.141e-21 5.150e-21 -20.289 -20.288 0.001 - H[14C]O[18O]2- 2.953e-21 2.702e-21 -20.530 -20.568 -0.039 - H[14C][18O]2O- 2.953e-21 2.702e-21 -20.530 -20.568 -0.039 - H[14C][18O]O[18O]- 2.953e-21 2.702e-21 -20.530 -20.568 -0.039 - [14C]O2[18O]-2 2.635e-21 1.847e-21 -20.579 -20.734 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.634 -68.633 0.001 - [18O]2 0.000e+00 0.000e+00 -71.635 -71.634 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 4.958e-19 + CH4 4.958e-19 4.966e-19 -18.305 -18.304 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.080e-08 6.090e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.685e-13 + H2 8.424e-14 8.438e-14 -13.074 -13.074 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.235 -66.234 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.634 -68.633 0.001 (0) +[13C](-4) 5.480e-21 + [13C]H4 5.480e-21 5.489e-21 -20.261 -20.260 0.001 (0) +[13C](4) 6.501e-05 + H[13C]O3- 5.244e-05 4.798e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.080e-08 6.090e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.579e-08 4.586e-08 -7.339 -7.339 0.001 (0) + [13C]O3-2 3.116e-08 2.184e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.639e-10 3.645e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 (0) +[14C](-4) 7.687e-32 + [14C]H4 7.687e-32 7.699e-32 -31.114 -31.114 0.001 (0) +[14C](4) 9.185e-16 + H[14C]O3- 7.419e-16 6.788e-16 -15.130 -15.168 -0.039 (0) + [14C]O2 1.544e-16 1.547e-16 -15.811 -15.811 0.001 (0) + CaH[14C]O3+ 1.567e-17 1.438e-17 -16.805 -16.842 -0.037 (0) + H[14C]O2[18O]- 1.480e-18 1.354e-18 -17.830 -17.868 -0.039 (0) + H[14C]O[18O]O- 1.480e-18 1.354e-18 -17.830 -17.868 -0.039 (0) + H[14C][18O]O2- 1.480e-18 1.354e-18 -17.830 -17.868 -0.039 (0) + Ca[14C]O3 8.589e-19 8.604e-19 -18.066 -18.065 0.001 (0) + [14C]O[18O] 6.422e-19 6.433e-19 -18.192 -18.192 0.001 (0) + [14C]O3-2 4.402e-19 3.086e-19 -18.356 -18.511 -0.154 (0) + CaH[14C]O2[18O]+ 3.127e-20 2.869e-20 -19.505 -19.542 -0.037 (0) + CaH[14C]O[18O]O+ 3.127e-20 2.869e-20 -19.505 -19.542 -0.037 (0) + CaH[14C][18O]O2+ 3.127e-20 2.869e-20 -19.505 -19.542 -0.037 (0) + Ca[14C]O2[18O] 5.141e-21 5.150e-21 -20.289 -20.288 0.001 (0) + H[14C]O[18O]2- 2.953e-21 2.702e-21 -20.530 -20.568 -0.039 (0) + H[14C][18O]2O- 2.953e-21 2.702e-21 -20.530 -20.568 -0.039 (0) + H[14C][18O]O[18O]- 2.953e-21 2.702e-21 -20.530 -20.568 -0.039 (0) + [14C]O2[18O]-2 2.635e-21 1.847e-21 -20.579 -20.734 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.634 -68.633 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.635 -71.634 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -6645,99 +6645,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 2.290e-18 - CH4 2.290e-18 2.294e-18 -17.640 -17.639 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.081e-08 6.091e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 2.470e-13 - H2 1.235e-13 1.237e-13 -12.908 -12.908 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.567 -66.567 0.001 - O[18O] 0.000e+00 0.000e+00 -68.966 -68.966 0.001 -[13C](-4) 2.532e-20 - [13C]H4 2.532e-20 2.536e-20 -19.596 -19.596 0.001 -[13C](4) 6.503e-05 - H[13C]O3- 5.245e-05 4.799e-05 -4.280 -4.319 -0.039 - [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.081e-08 6.091e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.580e-08 4.587e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.117e-08 2.185e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.640e-10 3.646e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.884 -0.154 -[14C](-4) 3.271e-31 - [14C]H4 3.271e-31 3.277e-31 -30.485 -30.485 0.001 -[14C](4) 8.461e-16 - H[14C]O3- 6.834e-16 6.253e-16 -15.165 -15.204 -0.039 - [14C]O2 1.423e-16 1.425e-16 -15.847 -15.846 0.001 - CaH[14C]O3+ 1.444e-17 1.325e-17 -16.841 -16.878 -0.037 - H[14C]O2[18O]- 1.364e-18 1.248e-18 -17.865 -17.904 -0.039 - H[14C]O[18O]O- 1.364e-18 1.248e-18 -17.865 -17.904 -0.039 - H[14C][18O]O2- 1.364e-18 1.248e-18 -17.865 -17.904 -0.039 - Ca[14C]O3 7.913e-19 7.926e-19 -18.102 -18.101 0.001 - [14C]O[18O] 5.916e-19 5.926e-19 -18.228 -18.227 0.001 - [14C]O3-2 4.056e-19 2.843e-19 -18.392 -18.546 -0.154 - CaH[14C]O2[18O]+ 2.880e-20 2.643e-20 -19.541 -19.578 -0.037 - CaH[14C]O[18O]O+ 2.880e-20 2.643e-20 -19.541 -19.578 -0.037 - CaH[14C][18O]O2+ 2.880e-20 2.643e-20 -19.541 -19.578 -0.037 - Ca[14C]O2[18O] 4.736e-21 4.744e-21 -20.325 -20.324 0.001 - H[14C]O[18O]2- 2.721e-21 2.489e-21 -20.565 -20.604 -0.039 - H[14C][18O]2O- 2.721e-21 2.489e-21 -20.565 -20.604 -0.039 - H[14C][18O]O[18O]- 2.721e-21 2.489e-21 -20.565 -20.604 -0.039 - [14C]O2[18O]-2 2.427e-21 1.701e-21 -20.615 -20.769 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.966 -68.966 0.001 - [18O]2 0.000e+00 0.000e+00 -71.967 -71.967 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 2.290e-18 + CH4 2.290e-18 2.294e-18 -17.640 -17.639 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.081e-08 6.091e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 2.470e-13 + H2 1.235e-13 1.237e-13 -12.908 -12.908 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.567 -66.567 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.966 -68.966 0.001 (0) +[13C](-4) 2.532e-20 + [13C]H4 2.532e-20 2.536e-20 -19.596 -19.596 0.001 (0) +[13C](4) 6.503e-05 + H[13C]O3- 5.245e-05 4.799e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.081e-08 6.091e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.580e-08 4.587e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.117e-08 2.185e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.640e-10 3.646e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.884 -0.154 (0) +[14C](-4) 3.271e-31 + [14C]H4 3.271e-31 3.277e-31 -30.485 -30.485 0.001 (0) +[14C](4) 8.461e-16 + H[14C]O3- 6.834e-16 6.253e-16 -15.165 -15.204 -0.039 (0) + [14C]O2 1.423e-16 1.425e-16 -15.847 -15.846 0.001 (0) + CaH[14C]O3+ 1.444e-17 1.325e-17 -16.841 -16.878 -0.037 (0) + H[14C]O2[18O]- 1.364e-18 1.248e-18 -17.865 -17.904 -0.039 (0) + H[14C]O[18O]O- 1.364e-18 1.248e-18 -17.865 -17.904 -0.039 (0) + H[14C][18O]O2- 1.364e-18 1.248e-18 -17.865 -17.904 -0.039 (0) + Ca[14C]O3 7.913e-19 7.926e-19 -18.102 -18.101 0.001 (0) + [14C]O[18O] 5.916e-19 5.926e-19 -18.228 -18.227 0.001 (0) + [14C]O3-2 4.056e-19 2.843e-19 -18.392 -18.546 -0.154 (0) + CaH[14C]O2[18O]+ 2.880e-20 2.643e-20 -19.541 -19.578 -0.037 (0) + CaH[14C]O[18O]O+ 2.880e-20 2.643e-20 -19.541 -19.578 -0.037 (0) + CaH[14C][18O]O2+ 2.880e-20 2.643e-20 -19.541 -19.578 -0.037 (0) + Ca[14C]O2[18O] 4.736e-21 4.744e-21 -20.325 -20.324 0.001 (0) + H[14C]O[18O]2- 2.721e-21 2.489e-21 -20.565 -20.604 -0.039 (0) + H[14C][18O]2O- 2.721e-21 2.489e-21 -20.565 -20.604 -0.039 (0) + H[14C][18O]O[18O]- 2.721e-21 2.489e-21 -20.565 -20.604 -0.039 (0) + [14C]O2[18O]-2 2.427e-21 1.701e-21 -20.615 -20.769 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.966 -68.966 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.967 -71.967 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -6919,99 +6919,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 5.008e-18 - CH4 5.008e-18 5.016e-18 -17.300 -17.300 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 3.004e-13 - H2 1.502e-13 1.504e-13 -12.823 -12.823 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.737 -66.736 0.001 - O[18O] 0.000e+00 0.000e+00 -69.136 -69.135 0.001 -[13C](-4) 5.538e-20 - [13C]H4 5.538e-20 5.547e-20 -19.257 -19.256 0.001 -[13C](4) 6.504e-05 - H[13C]O3- 5.246e-05 4.800e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.103e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.581e-08 4.588e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.117e-08 2.185e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 6.589e-31 - [14C]H4 6.589e-31 6.600e-31 -30.181 -30.180 0.001 -[14C](4) 7.795e-16 - H[14C]O3- 6.296e-16 5.761e-16 -15.201 -15.240 -0.039 - [14C]O2 1.311e-16 1.313e-16 -15.883 -15.882 0.001 - CaH[14C]O3+ 1.330e-17 1.220e-17 -16.876 -16.914 -0.037 - H[14C]O2[18O]- 1.256e-18 1.149e-18 -17.901 -17.940 -0.039 - H[14C]O[18O]O- 1.256e-18 1.149e-18 -17.901 -17.940 -0.039 - H[14C][18O]O2- 1.256e-18 1.149e-18 -17.901 -17.940 -0.039 - Ca[14C]O3 7.289e-19 7.301e-19 -18.137 -18.137 0.001 - [14C]O[18O] 5.450e-19 5.459e-19 -18.264 -18.263 0.001 - [14C]O3-2 3.736e-19 2.619e-19 -18.428 -18.582 -0.154 - CaH[14C]O2[18O]+ 2.654e-20 2.434e-20 -19.576 -19.614 -0.037 - CaH[14C]O[18O]O+ 2.654e-20 2.434e-20 -19.576 -19.614 -0.037 - CaH[14C][18O]O2+ 2.654e-20 2.434e-20 -19.576 -19.614 -0.037 - Ca[14C]O2[18O] 4.363e-21 4.370e-21 -20.360 -20.359 0.001 - H[14C]O[18O]2- 2.506e-21 2.293e-21 -20.601 -20.640 -0.039 - H[14C][18O]2O- 2.506e-21 2.293e-21 -20.601 -20.640 -0.039 - H[14C][18O]O[18O]- 2.506e-21 2.293e-21 -20.601 -20.640 -0.039 - [14C]O2[18O]-2 2.236e-21 1.567e-21 -20.650 -20.805 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -69.136 -69.135 0.001 - [18O]2 0.000e+00 0.000e+00 -72.137 -72.136 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 5.008e-18 + CH4 5.008e-18 5.016e-18 -17.300 -17.300 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 3.004e-13 + H2 1.502e-13 1.504e-13 -12.823 -12.823 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.737 -66.736 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -69.136 -69.135 0.001 (0) +[13C](-4) 5.538e-20 + [13C]H4 5.538e-20 5.547e-20 -19.257 -19.256 0.001 (0) +[13C](4) 6.504e-05 + H[13C]O3- 5.246e-05 4.800e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.103e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.581e-08 4.588e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.117e-08 2.185e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 6.589e-31 + [14C]H4 6.589e-31 6.600e-31 -30.181 -30.180 0.001 (0) +[14C](4) 7.795e-16 + H[14C]O3- 6.296e-16 5.761e-16 -15.201 -15.240 -0.039 (0) + [14C]O2 1.311e-16 1.313e-16 -15.883 -15.882 0.001 (0) + CaH[14C]O3+ 1.330e-17 1.220e-17 -16.876 -16.914 -0.037 (0) + H[14C]O2[18O]- 1.256e-18 1.149e-18 -17.901 -17.940 -0.039 (0) + H[14C]O[18O]O- 1.256e-18 1.149e-18 -17.901 -17.940 -0.039 (0) + H[14C][18O]O2- 1.256e-18 1.149e-18 -17.901 -17.940 -0.039 (0) + Ca[14C]O3 7.289e-19 7.301e-19 -18.137 -18.137 0.001 (0) + [14C]O[18O] 5.450e-19 5.459e-19 -18.264 -18.263 0.001 (0) + [14C]O3-2 3.736e-19 2.619e-19 -18.428 -18.582 -0.154 (0) + CaH[14C]O2[18O]+ 2.654e-20 2.434e-20 -19.576 -19.614 -0.037 (0) + CaH[14C]O[18O]O+ 2.654e-20 2.434e-20 -19.576 -19.614 -0.037 (0) + CaH[14C][18O]O2+ 2.654e-20 2.434e-20 -19.576 -19.614 -0.037 (0) + Ca[14C]O2[18O] 4.363e-21 4.370e-21 -20.360 -20.359 0.001 (0) + H[14C]O[18O]2- 2.506e-21 2.293e-21 -20.601 -20.640 -0.039 (0) + H[14C][18O]2O- 2.506e-21 2.293e-21 -20.601 -20.640 -0.039 (0) + H[14C][18O]O[18O]- 2.506e-21 2.293e-21 -20.601 -20.640 -0.039 (0) + [14C]O2[18O]-2 2.236e-21 1.567e-21 -20.650 -20.805 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -69.136 -69.135 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -72.137 -72.136 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -7193,99 +7193,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.477e-17 - CH4 1.477e-17 1.479e-17 -16.831 -16.830 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 3.936e-13 - H2 1.968e-13 1.971e-13 -12.706 -12.705 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.972 -66.971 0.001 - O[18O] 0.000e+00 0.000e+00 -69.371 -69.370 0.001 -[13C](-4) 1.633e-19 - [13C]H4 1.633e-19 1.636e-19 -18.787 -18.786 0.001 -[13C](4) 6.505e-05 - H[13C]O3- 5.247e-05 4.801e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.581e-08 4.589e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.118e-08 2.185e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 1.790e-30 - [14C]H4 1.790e-30 1.793e-30 -29.747 -29.746 0.001 -[14C](4) 7.181e-16 - H[14C]O3- 5.800e-16 5.307e-16 -15.237 -15.275 -0.039 - [14C]O2 1.207e-16 1.209e-16 -15.918 -15.917 0.001 - CaH[14C]O3+ 1.225e-17 1.124e-17 -16.912 -16.949 -0.037 - H[14C]O2[18O]- 1.157e-18 1.059e-18 -17.937 -17.975 -0.039 - H[14C]O[18O]O- 1.157e-18 1.059e-18 -17.937 -17.975 -0.039 - H[14C][18O]O2- 1.157e-18 1.059e-18 -17.937 -17.975 -0.039 - Ca[14C]O3 6.715e-19 6.726e-19 -18.173 -18.172 0.001 - [14C]O[18O] 5.021e-19 5.029e-19 -18.299 -18.299 0.001 - [14C]O3-2 3.442e-19 2.412e-19 -18.463 -18.618 -0.154 - CaH[14C]O2[18O]+ 2.444e-20 2.243e-20 -19.612 -19.649 -0.037 - CaH[14C]O[18O]O+ 2.444e-20 2.243e-20 -19.612 -19.649 -0.037 - CaH[14C][18O]O2+ 2.444e-20 2.243e-20 -19.612 -19.649 -0.037 - Ca[14C]O2[18O] 4.019e-21 4.026e-21 -20.396 -20.395 0.001 - H[14C]O[18O]2- 2.309e-21 2.113e-21 -20.637 -20.675 -0.039 - H[14C][18O]2O- 2.309e-21 2.113e-21 -20.637 -20.675 -0.039 - H[14C][18O]O[18O]- 2.309e-21 2.113e-21 -20.637 -20.675 -0.039 - [14C]O2[18O]-2 2.060e-21 1.444e-21 -20.686 -20.840 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -69.371 -69.370 0.001 - [18O]2 0.000e+00 0.000e+00 -72.372 -72.371 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.477e-17 + CH4 1.477e-17 1.479e-17 -16.831 -16.830 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 3.936e-13 + H2 1.968e-13 1.971e-13 -12.706 -12.705 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.972 -66.971 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -69.371 -69.370 0.001 (0) +[13C](-4) 1.633e-19 + [13C]H4 1.633e-19 1.636e-19 -18.787 -18.786 0.001 (0) +[13C](4) 6.505e-05 + H[13C]O3- 5.247e-05 4.801e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.581e-08 4.589e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.118e-08 2.185e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 1.790e-30 + [14C]H4 1.790e-30 1.793e-30 -29.747 -29.746 0.001 (0) +[14C](4) 7.181e-16 + H[14C]O3- 5.800e-16 5.307e-16 -15.237 -15.275 -0.039 (0) + [14C]O2 1.207e-16 1.209e-16 -15.918 -15.917 0.001 (0) + CaH[14C]O3+ 1.225e-17 1.124e-17 -16.912 -16.949 -0.037 (0) + H[14C]O2[18O]- 1.157e-18 1.059e-18 -17.937 -17.975 -0.039 (0) + H[14C]O[18O]O- 1.157e-18 1.059e-18 -17.937 -17.975 -0.039 (0) + H[14C][18O]O2- 1.157e-18 1.059e-18 -17.937 -17.975 -0.039 (0) + Ca[14C]O3 6.715e-19 6.726e-19 -18.173 -18.172 0.001 (0) + [14C]O[18O] 5.021e-19 5.029e-19 -18.299 -18.299 0.001 (0) + [14C]O3-2 3.442e-19 2.412e-19 -18.463 -18.618 -0.154 (0) + CaH[14C]O2[18O]+ 2.444e-20 2.243e-20 -19.612 -19.649 -0.037 (0) + CaH[14C]O[18O]O+ 2.444e-20 2.243e-20 -19.612 -19.649 -0.037 (0) + CaH[14C][18O]O2+ 2.444e-20 2.243e-20 -19.612 -19.649 -0.037 (0) + Ca[14C]O2[18O] 4.019e-21 4.026e-21 -20.396 -20.395 0.001 (0) + H[14C]O[18O]2- 2.309e-21 2.113e-21 -20.637 -20.675 -0.039 (0) + H[14C][18O]2O- 2.309e-21 2.113e-21 -20.637 -20.675 -0.039 (0) + H[14C][18O]O[18O]- 2.309e-21 2.113e-21 -20.637 -20.675 -0.039 (0) + [14C]O2[18O]-2 2.060e-21 1.444e-21 -20.686 -20.840 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -69.371 -69.370 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -72.372 -72.371 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -7467,99 +7467,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.201e-17 - CH4 1.201e-17 1.203e-17 -16.921 -16.920 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 3.737e-13 - H2 1.869e-13 1.872e-13 -12.728 -12.728 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.927 -66.926 0.001 - O[18O] 0.000e+00 0.000e+00 -69.326 -69.325 0.001 -[13C](-4) 1.328e-19 - [13C]H4 1.328e-19 1.330e-19 -18.877 -18.876 0.001 -[13C](4) 6.506e-05 - H[13C]O3- 5.248e-05 4.802e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.582e-08 4.590e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 1.341e-30 - [14C]H4 1.341e-30 1.343e-30 -29.873 -29.872 0.001 -[14C](4) 6.615e-16 - H[14C]O3- 5.343e-16 4.889e-16 -15.272 -15.311 -0.039 - [14C]O2 1.112e-16 1.114e-16 -15.954 -15.953 0.001 - CaH[14C]O3+ 1.129e-17 1.036e-17 -16.947 -16.985 -0.037 - H[14C]O2[18O]- 1.066e-18 9.754e-19 -17.972 -18.011 -0.039 - H[14C]O[18O]O- 1.066e-18 9.754e-19 -17.972 -18.011 -0.039 - H[14C][18O]O2- 1.066e-18 9.754e-19 -17.972 -18.011 -0.039 - Ca[14C]O3 6.186e-19 6.196e-19 -18.209 -18.208 0.001 - [14C]O[18O] 4.625e-19 4.633e-19 -18.335 -18.334 0.001 - [14C]O3-2 3.171e-19 2.222e-19 -18.499 -18.653 -0.154 - CaH[14C]O2[18O]+ 2.252e-20 2.066e-20 -19.647 -19.685 -0.037 - CaH[14C]O[18O]O+ 2.252e-20 2.066e-20 -19.647 -19.685 -0.037 - CaH[14C][18O]O2+ 2.252e-20 2.066e-20 -19.647 -19.685 -0.037 - Ca[14C]O2[18O] 3.703e-21 3.709e-21 -20.431 -20.431 0.001 - H[14C]O[18O]2- 2.127e-21 1.946e-21 -20.672 -20.711 -0.039 - H[14C][18O]2O- 2.127e-21 1.946e-21 -20.672 -20.711 -0.039 - H[14C][18O]O[18O]- 2.127e-21 1.946e-21 -20.672 -20.711 -0.039 - [14C]O2[18O]-2 1.898e-21 1.330e-21 -20.722 -20.876 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -69.326 -69.325 0.001 - [18O]2 0.000e+00 0.000e+00 -72.327 -72.326 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.201e-17 + CH4 1.201e-17 1.203e-17 -16.921 -16.920 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 3.737e-13 + H2 1.869e-13 1.872e-13 -12.728 -12.728 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.927 -66.926 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -69.326 -69.325 0.001 (0) +[13C](-4) 1.328e-19 + [13C]H4 1.328e-19 1.330e-19 -18.877 -18.876 0.001 (0) +[13C](4) 6.506e-05 + H[13C]O3- 5.248e-05 4.802e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.582e-08 4.590e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 1.341e-30 + [14C]H4 1.341e-30 1.343e-30 -29.873 -29.872 0.001 (0) +[14C](4) 6.615e-16 + H[14C]O3- 5.343e-16 4.889e-16 -15.272 -15.311 -0.039 (0) + [14C]O2 1.112e-16 1.114e-16 -15.954 -15.953 0.001 (0) + CaH[14C]O3+ 1.129e-17 1.036e-17 -16.947 -16.985 -0.037 (0) + H[14C]O2[18O]- 1.066e-18 9.754e-19 -17.972 -18.011 -0.039 (0) + H[14C]O[18O]O- 1.066e-18 9.754e-19 -17.972 -18.011 -0.039 (0) + H[14C][18O]O2- 1.066e-18 9.754e-19 -17.972 -18.011 -0.039 (0) + Ca[14C]O3 6.186e-19 6.196e-19 -18.209 -18.208 0.001 (0) + [14C]O[18O] 4.625e-19 4.633e-19 -18.335 -18.334 0.001 (0) + [14C]O3-2 3.171e-19 2.222e-19 -18.499 -18.653 -0.154 (0) + CaH[14C]O2[18O]+ 2.252e-20 2.066e-20 -19.647 -19.685 -0.037 (0) + CaH[14C]O[18O]O+ 2.252e-20 2.066e-20 -19.647 -19.685 -0.037 (0) + CaH[14C][18O]O2+ 2.252e-20 2.066e-20 -19.647 -19.685 -0.037 (0) + Ca[14C]O2[18O] 3.703e-21 3.709e-21 -20.431 -20.431 0.001 (0) + H[14C]O[18O]2- 2.127e-21 1.946e-21 -20.672 -20.711 -0.039 (0) + H[14C][18O]2O- 2.127e-21 1.946e-21 -20.672 -20.711 -0.039 (0) + H[14C][18O]O[18O]- 2.127e-21 1.946e-21 -20.672 -20.711 -0.039 (0) + [14C]O2[18O]-2 1.898e-21 1.330e-21 -20.722 -20.876 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -69.326 -69.325 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -72.327 -72.326 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -7741,99 +7741,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.617e-17 - CH4 1.617e-17 1.619e-17 -16.791 -16.791 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 4.026e-13 - H2 2.013e-13 2.016e-13 -12.696 -12.695 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.992 -66.991 0.001 - O[18O] 0.000e+00 0.000e+00 -69.391 -69.390 0.001 -[13C](-4) 1.789e-19 - [13C]H4 1.789e-19 1.792e-19 -18.747 -18.747 0.001 -[13C](4) 6.507e-05 - H[13C]O3- 5.249e-05 4.802e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.583e-08 4.590e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 1.663e-30 - [14C]H4 1.663e-30 1.666e-30 -29.779 -29.778 0.001 -[14C](4) 6.094e-16 - H[14C]O3- 4.922e-16 4.504e-16 -15.308 -15.346 -0.039 - [14C]O2 1.025e-16 1.026e-16 -15.989 -15.989 0.001 - CaH[14C]O3+ 1.040e-17 9.539e-18 -16.983 -17.020 -0.037 - H[14C]O2[18O]- 9.821e-19 8.986e-19 -18.008 -18.046 -0.039 - H[14C]O[18O]O- 9.821e-19 8.986e-19 -18.008 -18.046 -0.039 - H[14C][18O]O2- 9.821e-19 8.986e-19 -18.008 -18.046 -0.039 - Ca[14C]O3 5.699e-19 5.708e-19 -18.244 -18.243 0.001 - [14C]O[18O] 4.261e-19 4.268e-19 -18.370 -18.370 0.001 - [14C]O3-2 2.921e-19 2.047e-19 -18.534 -18.689 -0.154 - CaH[14C]O2[18O]+ 2.075e-20 1.903e-20 -19.683 -19.721 -0.037 - CaH[14C]O[18O]O+ 2.075e-20 1.903e-20 -19.683 -19.721 -0.037 - CaH[14C][18O]O2+ 2.075e-20 1.903e-20 -19.683 -19.721 -0.037 - Ca[14C]O2[18O] 3.411e-21 3.417e-21 -20.467 -20.466 0.001 - H[14C]O[18O]2- 1.959e-21 1.793e-21 -20.708 -20.746 -0.039 - H[14C][18O]2O- 1.959e-21 1.793e-21 -20.708 -20.746 -0.039 - H[14C][18O]O[18O]- 1.959e-21 1.793e-21 -20.708 -20.746 -0.039 - [14C]O2[18O]-2 1.748e-21 1.225e-21 -20.757 -20.912 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -69.391 -69.390 0.001 - [18O]2 0.000e+00 0.000e+00 -72.392 -72.391 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.617e-17 + CH4 1.617e-17 1.619e-17 -16.791 -16.791 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 4.026e-13 + H2 2.013e-13 2.016e-13 -12.696 -12.695 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.992 -66.991 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -69.391 -69.390 0.001 (0) +[13C](-4) 1.789e-19 + [13C]H4 1.789e-19 1.792e-19 -18.747 -18.747 0.001 (0) +[13C](4) 6.507e-05 + H[13C]O3- 5.249e-05 4.802e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.583e-08 4.590e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 1.663e-30 + [14C]H4 1.663e-30 1.666e-30 -29.779 -29.778 0.001 (0) +[14C](4) 6.094e-16 + H[14C]O3- 4.922e-16 4.504e-16 -15.308 -15.346 -0.039 (0) + [14C]O2 1.025e-16 1.026e-16 -15.989 -15.989 0.001 (0) + CaH[14C]O3+ 1.040e-17 9.539e-18 -16.983 -17.020 -0.037 (0) + H[14C]O2[18O]- 9.821e-19 8.986e-19 -18.008 -18.046 -0.039 (0) + H[14C]O[18O]O- 9.821e-19 8.986e-19 -18.008 -18.046 -0.039 (0) + H[14C][18O]O2- 9.821e-19 8.986e-19 -18.008 -18.046 -0.039 (0) + Ca[14C]O3 5.699e-19 5.708e-19 -18.244 -18.243 0.001 (0) + [14C]O[18O] 4.261e-19 4.268e-19 -18.370 -18.370 0.001 (0) + [14C]O3-2 2.921e-19 2.047e-19 -18.534 -18.689 -0.154 (0) + CaH[14C]O2[18O]+ 2.075e-20 1.903e-20 -19.683 -19.721 -0.037 (0) + CaH[14C]O[18O]O+ 2.075e-20 1.903e-20 -19.683 -19.721 -0.037 (0) + CaH[14C][18O]O2+ 2.075e-20 1.903e-20 -19.683 -19.721 -0.037 (0) + Ca[14C]O2[18O] 3.411e-21 3.417e-21 -20.467 -20.466 0.001 (0) + H[14C]O[18O]2- 1.959e-21 1.793e-21 -20.708 -20.746 -0.039 (0) + H[14C][18O]2O- 1.959e-21 1.793e-21 -20.708 -20.746 -0.039 (0) + H[14C][18O]O[18O]- 1.959e-21 1.793e-21 -20.708 -20.746 -0.039 (0) + [14C]O2[18O]-2 1.748e-21 1.225e-21 -20.757 -20.912 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -69.391 -69.390 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -72.392 -72.391 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -8015,99 +8015,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.053e-17 - CH4 1.053e-17 1.054e-17 -16.978 -16.977 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 3.617e-13 - H2 1.808e-13 1.811e-13 -12.743 -12.742 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.898 -66.898 0.001 - O[18O] 0.000e+00 0.000e+00 -69.297 -69.297 0.001 -[13C](-4) 1.165e-19 - [13C]H4 1.165e-19 1.167e-19 -18.934 -18.933 0.001 -[13C](4) 6.508e-05 - H[13C]O3- 5.249e-05 4.803e-05 -4.280 -4.318 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.584e-08 4.591e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 9.975e-31 - [14C]H4 9.975e-31 9.991e-31 -30.001 -30.000 0.001 -[14C](4) 5.614e-16 - H[14C]O3- 4.534e-16 4.149e-16 -15.343 -15.382 -0.039 - [14C]O2 9.440e-17 9.455e-17 -16.025 -16.024 0.001 - CaH[14C]O3+ 9.579e-18 8.788e-18 -17.019 -17.056 -0.037 - H[14C]O2[18O]- 9.047e-19 8.278e-19 -18.043 -18.082 -0.039 - H[14C]O[18O]O- 9.047e-19 8.278e-19 -18.043 -18.082 -0.039 - H[14C][18O]O2- 9.047e-19 8.278e-19 -18.043 -18.082 -0.039 - Ca[14C]O3 5.250e-19 5.259e-19 -18.280 -18.279 0.001 - [14C]O[18O] 3.925e-19 3.932e-19 -18.406 -18.405 0.001 - [14C]O3-2 2.691e-19 1.886e-19 -18.570 -18.724 -0.154 - CaH[14C]O2[18O]+ 1.911e-20 1.753e-20 -19.719 -19.756 -0.037 - CaH[14C]O[18O]O+ 1.911e-20 1.753e-20 -19.719 -19.756 -0.037 - CaH[14C][18O]O2+ 1.911e-20 1.753e-20 -19.719 -19.756 -0.037 - Ca[14C]O2[18O] 3.142e-21 3.148e-21 -20.503 -20.502 0.001 - H[14C]O[18O]2- 1.805e-21 1.652e-21 -20.744 -20.782 -0.039 - H[14C][18O]2O- 1.805e-21 1.652e-21 -20.744 -20.782 -0.039 - H[14C][18O]O[18O]- 1.805e-21 1.652e-21 -20.744 -20.782 -0.039 - [14C]O2[18O]-2 1.611e-21 1.129e-21 -20.793 -20.947 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -69.297 -69.297 0.001 - [18O]2 0.000e+00 0.000e+00 -72.298 -72.298 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.053e-17 + CH4 1.053e-17 1.054e-17 -16.978 -16.977 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 3.617e-13 + H2 1.808e-13 1.811e-13 -12.743 -12.742 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.898 -66.898 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -69.297 -69.297 0.001 (0) +[13C](-4) 1.165e-19 + [13C]H4 1.165e-19 1.167e-19 -18.934 -18.933 0.001 (0) +[13C](4) 6.508e-05 + H[13C]O3- 5.249e-05 4.803e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.584e-08 4.591e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 9.975e-31 + [14C]H4 9.975e-31 9.991e-31 -30.001 -30.000 0.001 (0) +[14C](4) 5.614e-16 + H[14C]O3- 4.534e-16 4.149e-16 -15.343 -15.382 -0.039 (0) + [14C]O2 9.440e-17 9.455e-17 -16.025 -16.024 0.001 (0) + CaH[14C]O3+ 9.579e-18 8.788e-18 -17.019 -17.056 -0.037 (0) + H[14C]O2[18O]- 9.047e-19 8.278e-19 -18.043 -18.082 -0.039 (0) + H[14C]O[18O]O- 9.047e-19 8.278e-19 -18.043 -18.082 -0.039 (0) + H[14C][18O]O2- 9.047e-19 8.278e-19 -18.043 -18.082 -0.039 (0) + Ca[14C]O3 5.250e-19 5.259e-19 -18.280 -18.279 0.001 (0) + [14C]O[18O] 3.925e-19 3.932e-19 -18.406 -18.405 0.001 (0) + [14C]O3-2 2.691e-19 1.886e-19 -18.570 -18.724 -0.154 (0) + CaH[14C]O2[18O]+ 1.911e-20 1.753e-20 -19.719 -19.756 -0.037 (0) + CaH[14C]O[18O]O+ 1.911e-20 1.753e-20 -19.719 -19.756 -0.037 (0) + CaH[14C][18O]O2+ 1.911e-20 1.753e-20 -19.719 -19.756 -0.037 (0) + Ca[14C]O2[18O] 3.142e-21 3.148e-21 -20.503 -20.502 0.001 (0) + H[14C]O[18O]2- 1.805e-21 1.652e-21 -20.744 -20.782 -0.039 (0) + H[14C][18O]2O- 1.805e-21 1.652e-21 -20.744 -20.782 -0.039 (0) + H[14C][18O]O[18O]- 1.805e-21 1.652e-21 -20.744 -20.782 -0.039 (0) + [14C]O2[18O]-2 1.611e-21 1.129e-21 -20.793 -20.947 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -69.297 -69.297 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -72.298 -72.298 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -8289,99 +8289,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 7.080e-18 - CH4 7.080e-18 7.091e-18 -17.150 -17.149 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 3.275e-13 - H2 1.638e-13 1.640e-13 -12.786 -12.785 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.812 -66.812 0.001 - O[18O] 0.000e+00 0.000e+00 -69.211 -69.211 0.001 -[13C](-4) 7.835e-20 - [13C]H4 7.835e-20 7.848e-20 -19.106 -19.105 0.001 -[13C](4) 6.509e-05 - H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.584e-08 4.592e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 6.180e-31 - [14C]H4 6.180e-31 6.190e-31 -30.209 -30.208 0.001 -[14C](4) 5.172e-16 - H[14C]O3- 4.177e-16 3.822e-16 -15.379 -15.418 -0.039 - [14C]O2 8.696e-17 8.710e-17 -16.061 -16.060 0.001 - CaH[14C]O3+ 8.824e-18 8.096e-18 -17.054 -17.092 -0.037 - H[14C]O2[18O]- 8.334e-19 7.626e-19 -18.079 -18.118 -0.039 - H[14C]O[18O]O- 8.334e-19 7.626e-19 -18.079 -18.118 -0.039 - H[14C][18O]O2- 8.334e-19 7.626e-19 -18.079 -18.118 -0.039 - Ca[14C]O3 4.836e-19 4.844e-19 -18.315 -18.315 0.001 - [14C]O[18O] 3.616e-19 3.622e-19 -18.442 -18.441 0.001 - [14C]O3-2 2.479e-19 1.737e-19 -18.606 -18.760 -0.154 - CaH[14C]O2[18O]+ 1.761e-20 1.615e-20 -19.754 -19.792 -0.037 - CaH[14C]O[18O]O+ 1.761e-20 1.615e-20 -19.754 -19.792 -0.037 - CaH[14C][18O]O2+ 1.761e-20 1.615e-20 -19.754 -19.792 -0.037 - Ca[14C]O2[18O] 2.895e-21 2.900e-21 -20.538 -20.538 0.001 - H[14C]O[18O]2- 1.663e-21 1.521e-21 -20.779 -20.818 -0.039 - H[14C][18O]2O- 1.663e-21 1.521e-21 -20.779 -20.818 -0.039 - H[14C][18O]O[18O]- 1.663e-21 1.521e-21 -20.779 -20.818 -0.039 - [14C]O2[18O]-2 1.484e-21 1.040e-21 -20.829 -20.983 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -69.211 -69.211 0.001 - [18O]2 0.000e+00 0.000e+00 -72.212 -72.212 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 7.080e-18 + CH4 7.080e-18 7.091e-18 -17.150 -17.149 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 3.275e-13 + H2 1.638e-13 1.640e-13 -12.786 -12.785 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.812 -66.812 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -69.211 -69.211 0.001 (0) +[13C](-4) 7.835e-20 + [13C]H4 7.835e-20 7.848e-20 -19.106 -19.105 0.001 (0) +[13C](4) 6.509e-05 + H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.584e-08 4.592e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 6.180e-31 + [14C]H4 6.180e-31 6.190e-31 -30.209 -30.208 0.001 (0) +[14C](4) 5.172e-16 + H[14C]O3- 4.177e-16 3.822e-16 -15.379 -15.418 -0.039 (0) + [14C]O2 8.696e-17 8.710e-17 -16.061 -16.060 0.001 (0) + CaH[14C]O3+ 8.824e-18 8.096e-18 -17.054 -17.092 -0.037 (0) + H[14C]O2[18O]- 8.334e-19 7.626e-19 -18.079 -18.118 -0.039 (0) + H[14C]O[18O]O- 8.334e-19 7.626e-19 -18.079 -18.118 -0.039 (0) + H[14C][18O]O2- 8.334e-19 7.626e-19 -18.079 -18.118 -0.039 (0) + Ca[14C]O3 4.836e-19 4.844e-19 -18.315 -18.315 0.001 (0) + [14C]O[18O] 3.616e-19 3.622e-19 -18.442 -18.441 0.001 (0) + [14C]O3-2 2.479e-19 1.737e-19 -18.606 -18.760 -0.154 (0) + CaH[14C]O2[18O]+ 1.761e-20 1.615e-20 -19.754 -19.792 -0.037 (0) + CaH[14C]O[18O]O+ 1.761e-20 1.615e-20 -19.754 -19.792 -0.037 (0) + CaH[14C][18O]O2+ 1.761e-20 1.615e-20 -19.754 -19.792 -0.037 (0) + Ca[14C]O2[18O] 2.895e-21 2.900e-21 -20.538 -20.538 0.001 (0) + H[14C]O[18O]2- 1.663e-21 1.521e-21 -20.779 -20.818 -0.039 (0) + H[14C][18O]2O- 1.663e-21 1.521e-21 -20.779 -20.818 -0.039 (0) + H[14C][18O]O[18O]- 1.663e-21 1.521e-21 -20.779 -20.818 -0.039 (0) + [14C]O2[18O]-2 1.484e-21 1.040e-21 -20.829 -20.983 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -69.211 -69.211 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -72.212 -72.212 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -8563,99 +8563,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.783e-18 - CH4 1.783e-18 1.786e-18 -17.749 -17.748 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 2.320e-13 - H2 1.160e-13 1.162e-13 -12.935 -12.935 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.513 -66.512 0.001 - O[18O] 0.000e+00 0.000e+00 -68.912 -68.911 0.001 -[13C](-4) 1.974e-20 - [13C]H4 1.974e-20 1.977e-20 -19.705 -19.704 0.001 -[13C](4) 6.510e-05 - H[13C]O3- 5.251e-05 4.804e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.585e-08 4.592e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 1.434e-31 - [14C]H4 1.434e-31 1.437e-31 -30.843 -30.843 0.001 -[14C](4) 4.764e-16 - H[14C]O3- 3.848e-16 3.521e-16 -15.415 -15.453 -0.039 - [14C]O2 8.011e-17 8.024e-17 -16.096 -16.096 0.001 - CaH[14C]O3+ 8.129e-18 7.458e-18 -17.090 -17.127 -0.037 - H[14C]O2[18O]- 7.678e-19 7.025e-19 -18.115 -18.153 -0.039 - H[14C]O[18O]O- 7.678e-19 7.025e-19 -18.115 -18.153 -0.039 - H[14C][18O]O2- 7.678e-19 7.025e-19 -18.115 -18.153 -0.039 - Ca[14C]O3 4.455e-19 4.463e-19 -18.351 -18.350 0.001 - [14C]O[18O] 3.331e-19 3.337e-19 -18.477 -18.477 0.001 - [14C]O3-2 2.284e-19 1.601e-19 -18.641 -18.796 -0.154 - CaH[14C]O2[18O]+ 1.622e-20 1.488e-20 -19.790 -19.827 -0.037 - CaH[14C]O[18O]O+ 1.622e-20 1.488e-20 -19.790 -19.827 -0.037 - CaH[14C][18O]O2+ 1.622e-20 1.488e-20 -19.790 -19.827 -0.037 - Ca[14C]O2[18O] 2.667e-21 2.671e-21 -20.574 -20.573 0.001 - H[14C]O[18O]2- 1.532e-21 1.402e-21 -20.815 -20.853 -0.039 - H[14C][18O]2O- 1.532e-21 1.402e-21 -20.815 -20.853 -0.039 - H[14C][18O]O[18O]- 1.532e-21 1.402e-21 -20.815 -20.853 -0.039 - [14C]O2[18O]-2 1.367e-21 9.580e-22 -20.864 -21.019 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.912 -68.911 0.001 - [18O]2 0.000e+00 0.000e+00 -71.913 -71.912 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.783e-18 + CH4 1.783e-18 1.786e-18 -17.749 -17.748 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 2.320e-13 + H2 1.160e-13 1.162e-13 -12.935 -12.935 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.513 -66.512 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.912 -68.911 0.001 (0) +[13C](-4) 1.974e-20 + [13C]H4 1.974e-20 1.977e-20 -19.705 -19.704 0.001 (0) +[13C](4) 6.510e-05 + H[13C]O3- 5.251e-05 4.804e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.585e-08 4.592e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 1.434e-31 + [14C]H4 1.434e-31 1.437e-31 -30.843 -30.843 0.001 (0) +[14C](4) 4.764e-16 + H[14C]O3- 3.848e-16 3.521e-16 -15.415 -15.453 -0.039 (0) + [14C]O2 8.011e-17 8.024e-17 -16.096 -16.096 0.001 (0) + CaH[14C]O3+ 8.129e-18 7.458e-18 -17.090 -17.127 -0.037 (0) + H[14C]O2[18O]- 7.678e-19 7.025e-19 -18.115 -18.153 -0.039 (0) + H[14C]O[18O]O- 7.678e-19 7.025e-19 -18.115 -18.153 -0.039 (0) + H[14C][18O]O2- 7.678e-19 7.025e-19 -18.115 -18.153 -0.039 (0) + Ca[14C]O3 4.455e-19 4.463e-19 -18.351 -18.350 0.001 (0) + [14C]O[18O] 3.331e-19 3.337e-19 -18.477 -18.477 0.001 (0) + [14C]O3-2 2.284e-19 1.601e-19 -18.641 -18.796 -0.154 (0) + CaH[14C]O2[18O]+ 1.622e-20 1.488e-20 -19.790 -19.827 -0.037 (0) + CaH[14C]O[18O]O+ 1.622e-20 1.488e-20 -19.790 -19.827 -0.037 (0) + CaH[14C][18O]O2+ 1.622e-20 1.488e-20 -19.790 -19.827 -0.037 (0) + Ca[14C]O2[18O] 2.667e-21 2.671e-21 -20.574 -20.573 0.001 (0) + H[14C]O[18O]2- 1.532e-21 1.402e-21 -20.815 -20.853 -0.039 (0) + H[14C][18O]2O- 1.532e-21 1.402e-21 -20.815 -20.853 -0.039 (0) + H[14C][18O]O[18O]- 1.532e-21 1.402e-21 -20.815 -20.853 -0.039 (0) + [14C]O2[18O]-2 1.367e-21 9.580e-22 -20.864 -21.019 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.912 -68.911 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.913 -71.912 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -8837,99 +8837,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 2.287e-18 - CH4 2.287e-18 2.291e-18 -17.641 -17.640 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.089e-08 6.099e-08 -7.215 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 2.469e-13 - H2 1.235e-13 1.237e-13 -12.908 -12.908 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.567 -66.566 0.001 - O[18O] 0.000e+00 0.000e+00 -68.966 -68.965 0.001 -[13C](-4) 2.532e-20 - [13C]H4 2.532e-20 2.536e-20 -19.597 -19.596 0.001 -[13C](4) 6.511e-05 - H[13C]O3- 5.251e-05 4.805e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.105e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.587e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.587e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.587e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.089e-08 6.099e-08 -7.215 -7.215 0.001 - [13C]O[18O] 4.585e-08 4.593e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.121e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.031e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.031e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.031e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 1.694e-31 - [14C]H4 1.694e-31 1.697e-31 -30.771 -30.770 0.001 -[14C](4) 4.389e-16 - H[14C]O3- 3.545e-16 3.244e-16 -15.450 -15.489 -0.039 - [14C]O2 7.380e-17 7.392e-17 -16.132 -16.131 0.001 - CaH[14C]O3+ 7.489e-18 6.870e-18 -17.126 -17.163 -0.037 - H[14C]O2[18O]- 7.073e-19 6.472e-19 -18.150 -18.189 -0.039 - H[14C]O[18O]O- 7.073e-19 6.472e-19 -18.150 -18.189 -0.039 - H[14C][18O]O2- 7.073e-19 6.472e-19 -18.150 -18.189 -0.039 - Ca[14C]O3 4.104e-19 4.111e-19 -18.387 -18.386 0.001 - [14C]O[18O] 3.069e-19 3.074e-19 -18.513 -18.512 0.001 - [14C]O3-2 2.104e-19 1.474e-19 -18.677 -18.831 -0.154 - CaH[14C]O2[18O]+ 1.494e-20 1.371e-20 -19.826 -19.863 -0.037 - CaH[14C]O[18O]O+ 1.494e-20 1.371e-20 -19.826 -19.863 -0.037 - CaH[14C][18O]O2+ 1.494e-20 1.371e-20 -19.826 -19.863 -0.037 - Ca[14C]O2[18O] 2.457e-21 2.461e-21 -20.610 -20.609 0.001 - H[14C]O[18O]2- 1.411e-21 1.291e-21 -20.850 -20.889 -0.039 - H[14C][18O]2O- 1.411e-21 1.291e-21 -20.850 -20.889 -0.039 - H[14C][18O]O[18O]- 1.411e-21 1.291e-21 -20.850 -20.889 -0.039 - [14C]O2[18O]-2 1.259e-21 8.826e-22 -20.900 -21.054 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.966 -68.965 0.001 - [18O]2 0.000e+00 0.000e+00 -71.967 -71.966 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 2.287e-18 + CH4 2.287e-18 2.291e-18 -17.641 -17.640 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.089e-08 6.099e-08 -7.215 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 2.469e-13 + H2 1.235e-13 1.237e-13 -12.908 -12.908 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.567 -66.566 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.966 -68.965 0.001 (0) +[13C](-4) 2.532e-20 + [13C]H4 2.532e-20 2.536e-20 -19.597 -19.596 0.001 (0) +[13C](4) 6.511e-05 + H[13C]O3- 5.251e-05 4.805e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.105e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.587e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.587e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.587e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.089e-08 6.099e-08 -7.215 -7.215 0.001 (0) + [13C]O[18O] 4.585e-08 4.593e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.121e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 1.694e-31 + [14C]H4 1.694e-31 1.697e-31 -30.771 -30.770 0.001 (0) +[14C](4) 4.389e-16 + H[14C]O3- 3.545e-16 3.244e-16 -15.450 -15.489 -0.039 (0) + [14C]O2 7.380e-17 7.392e-17 -16.132 -16.131 0.001 (0) + CaH[14C]O3+ 7.489e-18 6.870e-18 -17.126 -17.163 -0.037 (0) + H[14C]O2[18O]- 7.073e-19 6.472e-19 -18.150 -18.189 -0.039 (0) + H[14C]O[18O]O- 7.073e-19 6.472e-19 -18.150 -18.189 -0.039 (0) + H[14C][18O]O2- 7.073e-19 6.472e-19 -18.150 -18.189 -0.039 (0) + Ca[14C]O3 4.104e-19 4.111e-19 -18.387 -18.386 0.001 (0) + [14C]O[18O] 3.069e-19 3.074e-19 -18.513 -18.512 0.001 (0) + [14C]O3-2 2.104e-19 1.474e-19 -18.677 -18.831 -0.154 (0) + CaH[14C]O2[18O]+ 1.494e-20 1.371e-20 -19.826 -19.863 -0.037 (0) + CaH[14C]O[18O]O+ 1.494e-20 1.371e-20 -19.826 -19.863 -0.037 (0) + CaH[14C][18O]O2+ 1.494e-20 1.371e-20 -19.826 -19.863 -0.037 (0) + Ca[14C]O2[18O] 2.457e-21 2.461e-21 -20.610 -20.609 0.001 (0) + H[14C]O[18O]2- 1.411e-21 1.291e-21 -20.850 -20.889 -0.039 (0) + H[14C][18O]2O- 1.411e-21 1.291e-21 -20.850 -20.889 -0.039 (0) + H[14C][18O]O[18O]- 1.411e-21 1.291e-21 -20.850 -20.889 -0.039 (0) + [14C]O2[18O]-2 1.259e-21 8.826e-22 -20.900 -21.054 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.966 -68.965 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.967 -71.966 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -9111,99 +9111,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 2.756e-18 - CH4 2.756e-18 2.760e-18 -17.560 -17.559 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.089e-08 6.099e-08 -7.215 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 2.587e-13 - H2 1.293e-13 1.296e-13 -12.888 -12.888 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.607 -66.607 0.001 - O[18O] 0.000e+00 0.000e+00 -69.006 -69.006 0.001 -[13C](-4) 3.051e-20 - [13C]H4 3.051e-20 3.056e-20 -19.516 -19.515 0.001 -[13C](4) 6.512e-05 - H[13C]O3- 5.252e-05 4.805e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.105e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.588e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.588e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.588e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.089e-08 6.099e-08 -7.215 -7.215 0.001 - [13C]O[18O] 4.586e-08 4.593e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.121e-08 2.188e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.031e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.031e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.031e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.645e-10 3.651e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 1.881e-31 - [14C]H4 1.881e-31 1.884e-31 -30.726 -30.725 0.001 -[14C](4) 4.043e-16 - H[14C]O3- 3.266e-16 2.988e-16 -15.486 -15.525 -0.039 - [14C]O2 6.798e-17 6.810e-17 -16.168 -16.167 0.001 - CaH[14C]O3+ 6.899e-18 6.329e-18 -17.161 -17.199 -0.037 - H[14C]O2[18O]- 6.516e-19 5.962e-19 -18.186 -18.225 -0.039 - H[14C]O[18O]O- 6.516e-19 5.962e-19 -18.186 -18.225 -0.039 - H[14C][18O]O2- 6.516e-19 5.962e-19 -18.186 -18.225 -0.039 - Ca[14C]O3 3.781e-19 3.787e-19 -18.422 -18.422 0.001 - [14C]O[18O] 2.827e-19 2.832e-19 -18.549 -18.548 0.001 - [14C]O3-2 1.938e-19 1.358e-19 -18.713 -18.867 -0.154 - CaH[14C]O2[18O]+ 1.376e-20 1.263e-20 -19.861 -19.899 -0.037 - CaH[14C]O[18O]O+ 1.376e-20 1.263e-20 -19.861 -19.899 -0.037 - CaH[14C][18O]O2+ 1.376e-20 1.263e-20 -19.861 -19.899 -0.037 - Ca[14C]O2[18O] 2.263e-21 2.267e-21 -20.645 -20.645 0.001 - H[14C]O[18O]2- 1.300e-21 1.190e-21 -20.886 -20.925 -0.039 - H[14C][18O]2O- 1.300e-21 1.190e-21 -20.886 -20.925 -0.039 - H[14C][18O]O[18O]- 1.300e-21 1.190e-21 -20.886 -20.925 -0.039 - [14C]O2[18O]-2 1.160e-21 8.130e-22 -20.936 -21.090 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -69.006 -69.006 0.001 - [18O]2 0.000e+00 0.000e+00 -72.007 -72.007 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 2.756e-18 + CH4 2.756e-18 2.760e-18 -17.560 -17.559 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.089e-08 6.099e-08 -7.215 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 2.587e-13 + H2 1.293e-13 1.296e-13 -12.888 -12.888 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.607 -66.607 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -69.006 -69.006 0.001 (0) +[13C](-4) 3.051e-20 + [13C]H4 3.051e-20 3.056e-20 -19.516 -19.515 0.001 (0) +[13C](4) 6.512e-05 + H[13C]O3- 5.252e-05 4.805e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.105e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.588e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.588e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.588e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.089e-08 6.099e-08 -7.215 -7.215 0.001 (0) + [13C]O[18O] 4.586e-08 4.593e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.121e-08 2.188e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.645e-10 3.651e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 1.881e-31 + [14C]H4 1.881e-31 1.884e-31 -30.726 -30.725 0.001 (0) +[14C](4) 4.043e-16 + H[14C]O3- 3.266e-16 2.988e-16 -15.486 -15.525 -0.039 (0) + [14C]O2 6.798e-17 6.810e-17 -16.168 -16.167 0.001 (0) + CaH[14C]O3+ 6.899e-18 6.329e-18 -17.161 -17.199 -0.037 (0) + H[14C]O2[18O]- 6.516e-19 5.962e-19 -18.186 -18.225 -0.039 (0) + H[14C]O[18O]O- 6.516e-19 5.962e-19 -18.186 -18.225 -0.039 (0) + H[14C][18O]O2- 6.516e-19 5.962e-19 -18.186 -18.225 -0.039 (0) + Ca[14C]O3 3.781e-19 3.787e-19 -18.422 -18.422 0.001 (0) + [14C]O[18O] 2.827e-19 2.832e-19 -18.549 -18.548 0.001 (0) + [14C]O3-2 1.938e-19 1.358e-19 -18.713 -18.867 -0.154 (0) + CaH[14C]O2[18O]+ 1.376e-20 1.263e-20 -19.861 -19.899 -0.037 (0) + CaH[14C]O[18O]O+ 1.376e-20 1.263e-20 -19.861 -19.899 -0.037 (0) + CaH[14C][18O]O2+ 1.376e-20 1.263e-20 -19.861 -19.899 -0.037 (0) + Ca[14C]O2[18O] 2.263e-21 2.267e-21 -20.645 -20.645 0.001 (0) + H[14C]O[18O]2- 1.300e-21 1.190e-21 -20.886 -20.925 -0.039 (0) + H[14C][18O]2O- 1.300e-21 1.190e-21 -20.886 -20.925 -0.039 (0) + H[14C][18O]O[18O]- 1.300e-21 1.190e-21 -20.886 -20.925 -0.039 (0) + [14C]O2[18O]-2 1.160e-21 8.130e-22 -20.936 -21.090 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -69.006 -69.006 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -72.007 -72.007 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -9385,99 +9385,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 2.879e-18 - CH4 2.879e-18 2.884e-18 -17.541 -17.540 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.090e-08 6.100e-08 -7.215 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 2.615e-13 - H2 1.308e-13 1.310e-13 -12.883 -12.883 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.617 -66.616 0.001 - O[18O] 0.000e+00 0.000e+00 -69.016 -69.015 0.001 -[13C](-4) 3.187e-20 - [13C]H4 3.187e-20 3.193e-20 -19.497 -19.496 0.001 -[13C](4) 6.512e-05 - H[13C]O3- 5.252e-05 4.806e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.105e-05 -4.957 -4.957 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.588e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.588e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.588e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.090e-08 6.100e-08 -7.215 -7.215 0.001 - [13C]O[18O] 4.586e-08 4.594e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.121e-08 2.188e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.645e-10 3.651e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 1.810e-31 - [14C]H4 1.810e-31 1.813e-31 -30.742 -30.742 0.001 -[14C](4) 3.725e-16 - H[14C]O3- 3.008e-16 2.753e-16 -15.522 -15.560 -0.039 - [14C]O2 6.263e-17 6.273e-17 -16.203 -16.203 0.001 - CaH[14C]O3+ 6.355e-18 5.831e-18 -17.197 -17.234 -0.037 - H[14C]O2[18O]- 6.002e-19 5.492e-19 -18.222 -18.260 -0.039 - H[14C]O[18O]O- 6.002e-19 5.492e-19 -18.222 -18.260 -0.039 - H[14C][18O]O2- 6.002e-19 5.492e-19 -18.222 -18.260 -0.039 - Ca[14C]O3 3.483e-19 3.489e-19 -18.458 -18.457 0.001 - [14C]O[18O] 2.604e-19 2.609e-19 -18.584 -18.584 0.001 - [14C]O3-2 1.785e-19 1.251e-19 -18.748 -18.903 -0.154 - CaH[14C]O2[18O]+ 1.268e-20 1.163e-20 -19.897 -19.934 -0.037 - CaH[14C]O[18O]O+ 1.268e-20 1.163e-20 -19.897 -19.934 -0.037 - CaH[14C][18O]O2+ 1.268e-20 1.163e-20 -19.897 -19.934 -0.037 - Ca[14C]O2[18O] 2.085e-21 2.088e-21 -20.681 -20.680 0.001 - H[14C]O[18O]2- 1.198e-21 1.096e-21 -20.922 -20.960 -0.039 - H[14C][18O]2O- 1.198e-21 1.096e-21 -20.922 -20.960 -0.039 - H[14C][18O]O[18O]- 1.198e-21 1.096e-21 -20.922 -20.960 -0.039 - [14C]O2[18O]-2 1.069e-21 7.490e-22 -20.971 -21.126 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -69.016 -69.015 0.001 - [18O]2 0.000e+00 0.000e+00 -72.017 -72.016 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 2.879e-18 + CH4 2.879e-18 2.884e-18 -17.541 -17.540 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.090e-08 6.100e-08 -7.215 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 2.615e-13 + H2 1.308e-13 1.310e-13 -12.883 -12.883 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.617 -66.616 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -69.016 -69.015 0.001 (0) +[13C](-4) 3.187e-20 + [13C]H4 3.187e-20 3.193e-20 -19.497 -19.496 0.001 (0) +[13C](4) 6.512e-05 + H[13C]O3- 5.252e-05 4.806e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.105e-05 -4.957 -4.957 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.588e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.588e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.588e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.090e-08 6.100e-08 -7.215 -7.215 0.001 (0) + [13C]O[18O] 4.586e-08 4.594e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.121e-08 2.188e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.645e-10 3.651e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 1.810e-31 + [14C]H4 1.810e-31 1.813e-31 -30.742 -30.742 0.001 (0) +[14C](4) 3.725e-16 + H[14C]O3- 3.008e-16 2.753e-16 -15.522 -15.560 -0.039 (0) + [14C]O2 6.263e-17 6.273e-17 -16.203 -16.203 0.001 (0) + CaH[14C]O3+ 6.355e-18 5.831e-18 -17.197 -17.234 -0.037 (0) + H[14C]O2[18O]- 6.002e-19 5.492e-19 -18.222 -18.260 -0.039 (0) + H[14C]O[18O]O- 6.002e-19 5.492e-19 -18.222 -18.260 -0.039 (0) + H[14C][18O]O2- 6.002e-19 5.492e-19 -18.222 -18.260 -0.039 (0) + Ca[14C]O3 3.483e-19 3.489e-19 -18.458 -18.457 0.001 (0) + [14C]O[18O] 2.604e-19 2.609e-19 -18.584 -18.584 0.001 (0) + [14C]O3-2 1.785e-19 1.251e-19 -18.748 -18.903 -0.154 (0) + CaH[14C]O2[18O]+ 1.268e-20 1.163e-20 -19.897 -19.934 -0.037 (0) + CaH[14C]O[18O]O+ 1.268e-20 1.163e-20 -19.897 -19.934 -0.037 (0) + CaH[14C][18O]O2+ 1.268e-20 1.163e-20 -19.897 -19.934 -0.037 (0) + Ca[14C]O2[18O] 2.085e-21 2.088e-21 -20.681 -20.680 0.001 (0) + H[14C]O[18O]2- 1.198e-21 1.096e-21 -20.922 -20.960 -0.039 (0) + H[14C][18O]2O- 1.198e-21 1.096e-21 -20.922 -20.960 -0.039 (0) + H[14C][18O]O[18O]- 1.198e-21 1.096e-21 -20.922 -20.960 -0.039 (0) + [14C]O2[18O]-2 1.069e-21 7.490e-22 -20.971 -21.126 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -69.016 -69.015 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -72.017 -72.016 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -9659,99 +9659,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.029e-18 - CH4 1.029e-18 1.030e-18 -17.988 -17.987 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.090e-08 6.100e-08 -7.215 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 2.022e-13 - H2 1.011e-13 1.013e-13 -12.995 -12.995 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.393 -66.393 0.001 - O[18O] 0.000e+00 0.000e+00 -68.792 -68.792 0.001 -[13C](-4) 1.139e-20 - [13C]H4 1.139e-20 1.141e-20 -19.943 -19.943 0.001 -[13C](4) 6.513e-05 - H[13C]O3- 5.253e-05 4.806e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.105e-05 -4.957 -4.957 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.589e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.589e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.589e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.090e-08 6.100e-08 -7.215 -7.215 0.001 - [13C]O[18O] 4.587e-08 4.594e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.122e-08 2.188e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.645e-10 3.651e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.310e-10 -9.729 -9.883 -0.154 -[14C](-4) 5.958e-32 - [14C]H4 5.958e-32 5.967e-32 -31.225 -31.224 0.001 -[14C](4) 3.431e-16 - H[14C]O3- 2.771e-16 2.536e-16 -15.557 -15.596 -0.039 - [14C]O2 5.770e-17 5.779e-17 -16.239 -16.238 0.001 - CaH[14C]O3+ 5.855e-18 5.371e-18 -17.233 -17.270 -0.037 - H[14C]O2[18O]- 5.530e-19 5.060e-19 -18.257 -18.296 -0.039 - H[14C]O[18O]O- 5.530e-19 5.060e-19 -18.257 -18.296 -0.039 - H[14C][18O]O2- 5.530e-19 5.060e-19 -18.257 -18.296 -0.039 - Ca[14C]O3 3.209e-19 3.214e-19 -18.494 -18.493 0.001 - [14C]O[18O] 2.399e-19 2.403e-19 -18.620 -18.619 0.001 - [14C]O3-2 1.645e-19 1.153e-19 -18.784 -18.938 -0.154 - CaH[14C]O2[18O]+ 1.168e-20 1.072e-20 -19.933 -19.970 -0.037 - CaH[14C]O[18O]O+ 1.168e-20 1.072e-20 -19.933 -19.970 -0.037 - CaH[14C][18O]O2+ 1.168e-20 1.072e-20 -19.933 -19.970 -0.037 - Ca[14C]O2[18O] 1.921e-21 1.924e-21 -20.717 -20.716 0.001 - H[14C]O[18O]2- 1.103e-21 1.009e-21 -20.957 -20.996 -0.039 - H[14C][18O]2O- 1.103e-21 1.009e-21 -20.957 -20.996 -0.039 - H[14C][18O]O[18O]- 1.103e-21 1.009e-21 -20.957 -20.996 -0.039 - [14C]O2[18O]-2 9.844e-22 6.900e-22 -21.007 -21.161 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.792 -68.792 0.001 - [18O]2 0.000e+00 0.000e+00 -71.793 -71.793 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.029e-18 + CH4 1.029e-18 1.030e-18 -17.988 -17.987 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.090e-08 6.100e-08 -7.215 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 2.022e-13 + H2 1.011e-13 1.013e-13 -12.995 -12.995 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.393 -66.393 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.792 -68.792 0.001 (0) +[13C](-4) 1.139e-20 + [13C]H4 1.139e-20 1.141e-20 -19.943 -19.943 0.001 (0) +[13C](4) 6.513e-05 + H[13C]O3- 5.253e-05 4.806e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.105e-05 -4.957 -4.957 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.589e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.589e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.589e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.090e-08 6.100e-08 -7.215 -7.215 0.001 (0) + [13C]O[18O] 4.587e-08 4.594e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.122e-08 2.188e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.645e-10 3.651e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.310e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 5.958e-32 + [14C]H4 5.958e-32 5.967e-32 -31.225 -31.224 0.001 (0) +[14C](4) 3.431e-16 + H[14C]O3- 2.771e-16 2.536e-16 -15.557 -15.596 -0.039 (0) + [14C]O2 5.770e-17 5.779e-17 -16.239 -16.238 0.001 (0) + CaH[14C]O3+ 5.855e-18 5.371e-18 -17.233 -17.270 -0.037 (0) + H[14C]O2[18O]- 5.530e-19 5.060e-19 -18.257 -18.296 -0.039 (0) + H[14C]O[18O]O- 5.530e-19 5.060e-19 -18.257 -18.296 -0.039 (0) + H[14C][18O]O2- 5.530e-19 5.060e-19 -18.257 -18.296 -0.039 (0) + Ca[14C]O3 3.209e-19 3.214e-19 -18.494 -18.493 0.001 (0) + [14C]O[18O] 2.399e-19 2.403e-19 -18.620 -18.619 0.001 (0) + [14C]O3-2 1.645e-19 1.153e-19 -18.784 -18.938 -0.154 (0) + CaH[14C]O2[18O]+ 1.168e-20 1.072e-20 -19.933 -19.970 -0.037 (0) + CaH[14C]O[18O]O+ 1.168e-20 1.072e-20 -19.933 -19.970 -0.037 (0) + CaH[14C][18O]O2+ 1.168e-20 1.072e-20 -19.933 -19.970 -0.037 (0) + Ca[14C]O2[18O] 1.921e-21 1.924e-21 -20.717 -20.716 0.001 (0) + H[14C]O[18O]2- 1.103e-21 1.009e-21 -20.957 -20.996 -0.039 (0) + H[14C][18O]2O- 1.103e-21 1.009e-21 -20.957 -20.996 -0.039 (0) + H[14C][18O]O[18O]- 1.103e-21 1.009e-21 -20.957 -20.996 -0.039 (0) + [14C]O2[18O]-2 9.844e-22 6.900e-22 -21.007 -21.161 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.792 -68.792 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.793 -71.793 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -9933,99 +9933,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 8.622e-19 - CH4 8.622e-19 8.636e-19 -18.064 -18.064 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.091e-08 6.101e-08 -7.215 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.935e-13 - H2 9.674e-14 9.690e-14 -13.014 -13.014 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.355 -66.354 0.001 - O[18O] 0.000e+00 0.000e+00 -68.754 -68.753 0.001 -[13C](-4) 9.548e-21 - [13C]H4 9.548e-21 9.564e-21 -20.020 -20.019 0.001 -[13C](4) 6.513e-05 - H[13C]O3- 5.253e-05 4.807e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.105e-05 -4.957 -4.957 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.590e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.590e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.590e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.091e-08 6.101e-08 -7.215 -7.215 0.001 - [13C]O[18O] 4.587e-08 4.595e-08 -7.338 -7.338 0.001 - [13C]O3-2 3.122e-08 2.188e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.646e-10 3.652e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 -[14C](-4) 4.600e-32 - [14C]H4 4.600e-32 4.608e-32 -31.337 -31.336 0.001 -[14C](4) 3.161e-16 - H[14C]O3- 2.553e-16 2.336e-16 -15.593 -15.632 -0.039 - [14C]O2 5.315e-17 5.324e-17 -16.274 -16.274 0.001 - CaH[14C]O3+ 5.393e-18 4.948e-18 -17.268 -17.306 -0.037 - H[14C]O2[18O]- 5.094e-19 4.661e-19 -18.293 -18.332 -0.039 - H[14C]O[18O]O- 5.094e-19 4.661e-19 -18.293 -18.332 -0.039 - H[14C][18O]O2- 5.094e-19 4.661e-19 -18.293 -18.332 -0.039 - Ca[14C]O3 2.956e-19 2.961e-19 -18.529 -18.529 0.001 - [14C]O[18O] 2.210e-19 2.214e-19 -18.656 -18.655 0.001 - [14C]O3-2 1.515e-19 1.062e-19 -18.820 -18.974 -0.154 - CaH[14C]O2[18O]+ 1.076e-20 9.872e-21 -19.968 -20.006 -0.037 - CaH[14C]O[18O]O+ 1.076e-20 9.872e-21 -19.968 -20.006 -0.037 - CaH[14C][18O]O2+ 1.076e-20 9.872e-21 -19.968 -20.006 -0.037 - Ca[14C]O2[18O] 1.769e-21 1.772e-21 -20.752 -20.751 0.001 - H[14C]O[18O]2- 1.016e-21 9.300e-22 -20.993 -21.032 -0.039 - H[14C][18O]2O- 1.016e-21 9.300e-22 -20.993 -21.032 -0.039 - H[14C][18O]O[18O]- 1.016e-21 9.300e-22 -20.993 -21.032 -0.039 - [14C]O2[18O]-2 9.069e-22 6.356e-22 -21.042 -21.197 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.754 -68.753 0.001 - [18O]2 0.000e+00 0.000e+00 -71.755 -71.754 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 8.622e-19 + CH4 8.622e-19 8.636e-19 -18.064 -18.064 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.091e-08 6.101e-08 -7.215 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.935e-13 + H2 9.674e-14 9.690e-14 -13.014 -13.014 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.355 -66.354 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.754 -68.753 0.001 (0) +[13C](-4) 9.548e-21 + [13C]H4 9.548e-21 9.564e-21 -20.020 -20.019 0.001 (0) +[13C](4) 6.513e-05 + H[13C]O3- 5.253e-05 4.807e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.105e-05 -4.957 -4.957 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.590e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.590e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.590e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.091e-08 6.101e-08 -7.215 -7.215 0.001 (0) + [13C]O[18O] 4.587e-08 4.595e-08 -7.338 -7.338 0.001 (0) + [13C]O3-2 3.122e-08 2.188e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.646e-10 3.652e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.091e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 4.600e-32 + [14C]H4 4.600e-32 4.608e-32 -31.337 -31.336 0.001 (0) +[14C](4) 3.161e-16 + H[14C]O3- 2.553e-16 2.336e-16 -15.593 -15.632 -0.039 (0) + [14C]O2 5.315e-17 5.324e-17 -16.274 -16.274 0.001 (0) + CaH[14C]O3+ 5.393e-18 4.948e-18 -17.268 -17.306 -0.037 (0) + H[14C]O2[18O]- 5.094e-19 4.661e-19 -18.293 -18.332 -0.039 (0) + H[14C]O[18O]O- 5.094e-19 4.661e-19 -18.293 -18.332 -0.039 (0) + H[14C][18O]O2- 5.094e-19 4.661e-19 -18.293 -18.332 -0.039 (0) + Ca[14C]O3 2.956e-19 2.961e-19 -18.529 -18.529 0.001 (0) + [14C]O[18O] 2.210e-19 2.214e-19 -18.656 -18.655 0.001 (0) + [14C]O3-2 1.515e-19 1.062e-19 -18.820 -18.974 -0.154 (0) + CaH[14C]O2[18O]+ 1.076e-20 9.872e-21 -19.968 -20.006 -0.037 (0) + CaH[14C]O[18O]O+ 1.076e-20 9.872e-21 -19.968 -20.006 -0.037 (0) + CaH[14C][18O]O2+ 1.076e-20 9.872e-21 -19.968 -20.006 -0.037 (0) + Ca[14C]O2[18O] 1.769e-21 1.772e-21 -20.752 -20.751 0.001 (0) + H[14C]O[18O]2- 1.016e-21 9.300e-22 -20.993 -21.032 -0.039 (0) + H[14C][18O]2O- 1.016e-21 9.300e-22 -20.993 -21.032 -0.039 (0) + H[14C][18O]O[18O]- 1.016e-21 9.300e-22 -20.993 -21.032 -0.039 (0) + [14C]O2[18O]-2 9.069e-22 6.356e-22 -21.042 -21.197 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.754 -68.753 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.755 -71.754 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -10207,99 +10207,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 7.639e-19 - CH4 7.639e-19 7.652e-19 -18.117 -18.116 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.091e-08 6.101e-08 -7.215 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.877e-13 - H2 9.386e-14 9.401e-14 -13.028 -13.027 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.329 -66.328 0.001 - O[18O] 0.000e+00 0.000e+00 -68.728 -68.727 0.001 -[13C](-4) 8.460e-21 - [13C]H4 8.460e-21 8.474e-21 -20.073 -20.072 0.001 -[13C](4) 6.514e-05 - H[13C]O3- 5.254e-05 4.807e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.105e-05 -4.957 -4.957 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.591e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.591e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.591e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.091e-08 6.101e-08 -7.215 -7.215 0.001 - [13C]O[18O] 4.587e-08 4.595e-08 -7.338 -7.338 0.001 - [13C]O3-2 3.122e-08 2.188e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.646e-10 3.652e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.091e-10 1.914e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.091e-10 1.914e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.091e-10 1.914e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 -[14C](-4) 3.755e-32 - [14C]H4 3.755e-32 3.761e-32 -31.425 -31.425 0.001 -[14C](4) 2.912e-16 - H[14C]O3- 2.352e-16 2.152e-16 -15.629 -15.667 -0.039 - [14C]O2 4.896e-17 4.904e-17 -16.310 -16.309 0.001 - CaH[14C]O3+ 4.968e-18 4.558e-18 -17.304 -17.341 -0.037 - H[14C]O2[18O]- 4.693e-19 4.294e-19 -18.329 -18.367 -0.039 - H[14C]O[18O]O- 4.693e-19 4.294e-19 -18.329 -18.367 -0.039 - H[14C][18O]O2- 4.693e-19 4.294e-19 -18.329 -18.367 -0.039 - Ca[14C]O3 2.723e-19 2.728e-19 -18.565 -18.564 0.001 - [14C]O[18O] 2.036e-19 2.039e-19 -18.691 -18.690 0.001 - [14C]O3-2 1.396e-19 9.783e-20 -18.855 -19.010 -0.154 - CaH[14C]O2[18O]+ 9.913e-21 9.095e-21 -20.004 -20.041 -0.037 - CaH[14C]O[18O]O+ 9.913e-21 9.095e-21 -20.004 -20.041 -0.037 - CaH[14C][18O]O2+ 9.913e-21 9.095e-21 -20.004 -20.041 -0.037 - Ca[14C]O2[18O] 1.630e-21 1.633e-21 -20.788 -20.787 0.001 - H[14C]O[18O]2- 9.363e-22 8.567e-22 -21.029 -21.067 -0.039 - H[14C][18O]2O- 9.363e-22 8.567e-22 -21.029 -21.067 -0.039 - H[14C][18O]O[18O]- 9.363e-22 8.567e-22 -21.029 -21.067 -0.039 - [14C]O2[18O]-2 8.354e-22 5.856e-22 -21.078 -21.232 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.728 -68.727 0.001 - [18O]2 0.000e+00 0.000e+00 -71.729 -71.728 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 7.639e-19 + CH4 7.639e-19 7.652e-19 -18.117 -18.116 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.091e-08 6.101e-08 -7.215 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.877e-13 + H2 9.386e-14 9.401e-14 -13.028 -13.027 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.329 -66.328 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.728 -68.727 0.001 (0) +[13C](-4) 8.460e-21 + [13C]H4 8.460e-21 8.474e-21 -20.073 -20.072 0.001 (0) +[13C](4) 6.514e-05 + H[13C]O3- 5.254e-05 4.807e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.105e-05 -4.957 -4.957 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.591e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.591e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.591e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.091e-08 6.101e-08 -7.215 -7.215 0.001 (0) + [13C]O[18O] 4.587e-08 4.595e-08 -7.338 -7.338 0.001 (0) + [13C]O3-2 3.122e-08 2.188e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.214e-09 2.031e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.646e-10 3.652e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.091e-10 1.914e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.091e-10 1.914e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.091e-10 1.914e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 3.755e-32 + [14C]H4 3.755e-32 3.761e-32 -31.425 -31.425 0.001 (0) +[14C](4) 2.912e-16 + H[14C]O3- 2.352e-16 2.152e-16 -15.629 -15.667 -0.039 (0) + [14C]O2 4.896e-17 4.904e-17 -16.310 -16.309 0.001 (0) + CaH[14C]O3+ 4.968e-18 4.558e-18 -17.304 -17.341 -0.037 (0) + H[14C]O2[18O]- 4.693e-19 4.294e-19 -18.329 -18.367 -0.039 (0) + H[14C]O[18O]O- 4.693e-19 4.294e-19 -18.329 -18.367 -0.039 (0) + H[14C][18O]O2- 4.693e-19 4.294e-19 -18.329 -18.367 -0.039 (0) + Ca[14C]O3 2.723e-19 2.728e-19 -18.565 -18.564 0.001 (0) + [14C]O[18O] 2.036e-19 2.039e-19 -18.691 -18.690 0.001 (0) + [14C]O3-2 1.396e-19 9.783e-20 -18.855 -19.010 -0.154 (0) + CaH[14C]O2[18O]+ 9.913e-21 9.095e-21 -20.004 -20.041 -0.037 (0) + CaH[14C]O[18O]O+ 9.913e-21 9.095e-21 -20.004 -20.041 -0.037 (0) + CaH[14C][18O]O2+ 9.913e-21 9.095e-21 -20.004 -20.041 -0.037 (0) + Ca[14C]O2[18O] 1.630e-21 1.633e-21 -20.788 -20.787 0.001 (0) + H[14C]O[18O]2- 9.363e-22 8.567e-22 -21.029 -21.067 -0.039 (0) + H[14C][18O]2O- 9.363e-22 8.567e-22 -21.029 -21.067 -0.039 (0) + H[14C][18O]O[18O]- 9.363e-22 8.567e-22 -21.029 -21.067 -0.039 (0) + [14C]O2[18O]-2 8.354e-22 5.856e-22 -21.078 -21.232 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.728 -68.727 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.729 -71.728 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -10481,99 +10481,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 7.224e-19 - CH4 7.224e-19 7.235e-19 -18.141 -18.141 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.092e-08 6.102e-08 -7.215 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.851e-13 - H2 9.255e-14 9.270e-14 -13.034 -13.033 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.317 -66.316 0.001 - O[18O] 0.000e+00 0.000e+00 -68.716 -68.715 0.001 -[13C](-4) 8.001e-21 - [13C]H4 8.001e-21 8.014e-21 -20.097 -20.096 0.001 -[13C](4) 6.514e-05 - H[13C]O3- 5.254e-05 4.807e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.105e-05 -4.957 -4.957 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.592e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.592e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.592e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.092e-08 6.102e-08 -7.215 -7.215 0.001 - [13C]O[18O] 4.588e-08 4.595e-08 -7.338 -7.338 0.001 - [13C]O3-2 3.122e-08 2.188e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.214e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.214e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.214e-09 2.032e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.646e-10 3.652e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.091e-10 1.914e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.091e-10 1.914e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.091e-10 1.914e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 -[14C](-4) 3.271e-32 - [14C]H4 3.271e-32 3.276e-32 -31.485 -31.485 0.001 -[14C](4) 2.683e-16 - H[14C]O3- 2.167e-16 1.983e-16 -15.664 -15.703 -0.039 - [14C]O2 4.511e-17 4.518e-17 -16.346 -16.345 0.001 - CaH[14C]O3+ 4.577e-18 4.199e-18 -17.339 -17.377 -0.037 - H[14C]O2[18O]- 4.323e-19 3.956e-19 -18.364 -18.403 -0.039 - H[14C]O[18O]O- 4.323e-19 3.956e-19 -18.364 -18.403 -0.039 - H[14C][18O]O2- 4.323e-19 3.956e-19 -18.364 -18.403 -0.039 - Ca[14C]O3 2.509e-19 2.513e-19 -18.601 -18.600 0.001 - [14C]O[18O] 1.876e-19 1.879e-19 -18.727 -18.726 0.001 - [14C]O3-2 1.286e-19 9.012e-20 -18.891 -19.045 -0.154 - CaH[14C]O2[18O]+ 9.132e-21 8.378e-21 -20.039 -20.077 -0.037 - CaH[14C]O[18O]O+ 9.132e-21 8.378e-21 -20.039 -20.077 -0.037 - CaH[14C][18O]O2+ 9.132e-21 8.378e-21 -20.039 -20.077 -0.037 - Ca[14C]O2[18O] 1.502e-21 1.504e-21 -20.823 -20.823 0.001 - H[14C]O[18O]2- 8.625e-22 7.892e-22 -21.064 -21.103 -0.039 - H[14C][18O]2O- 8.625e-22 7.892e-22 -21.064 -21.103 -0.039 - H[14C][18O]O[18O]- 8.625e-22 7.892e-22 -21.064 -21.103 -0.039 - [14C]O2[18O]-2 7.696e-22 5.394e-22 -21.114 -21.268 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.716 -68.715 0.001 - [18O]2 0.000e+00 0.000e+00 -71.717 -71.716 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 7.224e-19 + CH4 7.224e-19 7.235e-19 -18.141 -18.141 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.092e-08 6.102e-08 -7.215 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.851e-13 + H2 9.255e-14 9.270e-14 -13.034 -13.033 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.317 -66.316 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.716 -68.715 0.001 (0) +[13C](-4) 8.001e-21 + [13C]H4 8.001e-21 8.014e-21 -20.097 -20.096 0.001 (0) +[13C](4) 6.514e-05 + H[13C]O3- 5.254e-05 4.807e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.105e-05 -4.957 -4.957 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.592e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.592e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.592e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.092e-08 6.102e-08 -7.215 -7.215 0.001 (0) + [13C]O[18O] 4.588e-08 4.595e-08 -7.338 -7.338 0.001 (0) + [13C]O3-2 3.122e-08 2.188e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.214e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.214e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.214e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.646e-10 3.652e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.091e-10 1.914e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.091e-10 1.914e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.091e-10 1.914e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 3.271e-32 + [14C]H4 3.271e-32 3.276e-32 -31.485 -31.485 0.001 (0) +[14C](4) 2.683e-16 + H[14C]O3- 2.167e-16 1.983e-16 -15.664 -15.703 -0.039 (0) + [14C]O2 4.511e-17 4.518e-17 -16.346 -16.345 0.001 (0) + CaH[14C]O3+ 4.577e-18 4.199e-18 -17.339 -17.377 -0.037 (0) + H[14C]O2[18O]- 4.323e-19 3.956e-19 -18.364 -18.403 -0.039 (0) + H[14C]O[18O]O- 4.323e-19 3.956e-19 -18.364 -18.403 -0.039 (0) + H[14C][18O]O2- 4.323e-19 3.956e-19 -18.364 -18.403 -0.039 (0) + Ca[14C]O3 2.509e-19 2.513e-19 -18.601 -18.600 0.001 (0) + [14C]O[18O] 1.876e-19 1.879e-19 -18.727 -18.726 0.001 (0) + [14C]O3-2 1.286e-19 9.012e-20 -18.891 -19.045 -0.154 (0) + CaH[14C]O2[18O]+ 9.132e-21 8.378e-21 -20.039 -20.077 -0.037 (0) + CaH[14C]O[18O]O+ 9.132e-21 8.378e-21 -20.039 -20.077 -0.037 (0) + CaH[14C][18O]O2+ 9.132e-21 8.378e-21 -20.039 -20.077 -0.037 (0) + Ca[14C]O2[18O] 1.502e-21 1.504e-21 -20.823 -20.823 0.001 (0) + H[14C]O[18O]2- 8.625e-22 7.892e-22 -21.064 -21.103 -0.039 (0) + H[14C][18O]2O- 8.625e-22 7.892e-22 -21.064 -21.103 -0.039 (0) + H[14C][18O]O[18O]- 8.625e-22 7.892e-22 -21.064 -21.103 -0.039 (0) + [14C]O2[18O]-2 7.696e-22 5.394e-22 -21.114 -21.268 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.716 -68.715 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.717 -71.716 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -10755,99 +10755,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.438e-18 - CH4 1.438e-18 1.440e-18 -17.842 -17.842 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.092e-08 6.102e-08 -7.215 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 2.199e-13 - H2 1.099e-13 1.101e-13 -12.959 -12.958 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.466 -66.465 0.001 - O[18O] 0.000e+00 0.000e+00 -68.865 -68.864 0.001 -[13C](-4) 1.593e-20 - [13C]H4 1.593e-20 1.595e-20 -19.798 -19.797 0.001 -[13C](4) 6.515e-05 - H[13C]O3- 5.254e-05 4.808e-05 -4.279 -4.318 -0.039 - [13C]O2 1.103e-05 1.105e-05 -4.957 -4.957 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.592e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.592e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.592e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.092e-08 6.102e-08 -7.215 -7.215 0.001 - [13C]O[18O] 4.588e-08 4.596e-08 -7.338 -7.338 0.001 - [13C]O3-2 3.122e-08 2.189e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.646e-10 3.652e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.092e-10 1.914e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.092e-10 1.914e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.092e-10 1.914e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 -[14C](-4) 5.998e-32 - [14C]H4 5.998e-32 6.008e-32 -31.222 -31.221 0.001 -[14C](4) 2.471e-16 - H[14C]O3- 1.996e-16 1.826e-16 -15.700 -15.738 -0.039 - [14C]O2 4.155e-17 4.162e-17 -16.381 -16.381 0.001 - CaH[14C]O3+ 4.216e-18 3.868e-18 -17.375 -17.412 -0.037 - H[14C]O2[18O]- 3.983e-19 3.644e-19 -18.400 -18.438 -0.039 - H[14C]O[18O]O- 3.983e-19 3.644e-19 -18.400 -18.438 -0.039 - H[14C][18O]O2- 3.983e-19 3.644e-19 -18.400 -18.438 -0.039 - Ca[14C]O3 2.311e-19 2.315e-19 -18.636 -18.635 0.001 - [14C]O[18O] 1.728e-19 1.731e-19 -18.762 -18.762 0.001 - [14C]O3-2 1.184e-19 8.302e-20 -18.926 -19.081 -0.154 - CaH[14C]O2[18O]+ 8.413e-21 7.718e-21 -20.075 -20.112 -0.037 - CaH[14C]O[18O]O+ 8.413e-21 7.718e-21 -20.075 -20.112 -0.037 - CaH[14C][18O]O2+ 8.413e-21 7.718e-21 -20.075 -20.112 -0.037 - Ca[14C]O2[18O] 1.383e-21 1.386e-21 -20.859 -20.858 0.001 - H[14C]O[18O]2- 7.946e-22 7.270e-22 -21.100 -21.138 -0.039 - H[14C][18O]2O- 7.946e-22 7.270e-22 -21.100 -21.138 -0.039 - H[14C][18O]O[18O]- 7.946e-22 7.270e-22 -21.100 -21.138 -0.039 - [14C]O2[18O]-2 7.090e-22 4.969e-22 -21.149 -21.304 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.865 -68.864 0.001 - [18O]2 0.000e+00 0.000e+00 -71.866 -71.865 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.438e-18 + CH4 1.438e-18 1.440e-18 -17.842 -17.842 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.092e-08 6.102e-08 -7.215 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 2.199e-13 + H2 1.099e-13 1.101e-13 -12.959 -12.958 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.466 -66.465 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.865 -68.864 0.001 (0) +[13C](-4) 1.593e-20 + [13C]H4 1.593e-20 1.595e-20 -19.798 -19.797 0.001 (0) +[13C](4) 6.515e-05 + H[13C]O3- 5.254e-05 4.808e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.105e-05 -4.957 -4.957 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.592e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.592e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.592e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.092e-08 6.102e-08 -7.215 -7.215 0.001 (0) + [13C]O[18O] 4.588e-08 4.596e-08 -7.338 -7.338 0.001 (0) + [13C]O3-2 3.122e-08 2.189e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.646e-10 3.652e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.092e-10 1.914e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.092e-10 1.914e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.092e-10 1.914e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 5.998e-32 + [14C]H4 5.998e-32 6.008e-32 -31.222 -31.221 0.001 (0) +[14C](4) 2.471e-16 + H[14C]O3- 1.996e-16 1.826e-16 -15.700 -15.738 -0.039 (0) + [14C]O2 4.155e-17 4.162e-17 -16.381 -16.381 0.001 (0) + CaH[14C]O3+ 4.216e-18 3.868e-18 -17.375 -17.412 -0.037 (0) + H[14C]O2[18O]- 3.983e-19 3.644e-19 -18.400 -18.438 -0.039 (0) + H[14C]O[18O]O- 3.983e-19 3.644e-19 -18.400 -18.438 -0.039 (0) + H[14C][18O]O2- 3.983e-19 3.644e-19 -18.400 -18.438 -0.039 (0) + Ca[14C]O3 2.311e-19 2.315e-19 -18.636 -18.635 0.001 (0) + [14C]O[18O] 1.728e-19 1.731e-19 -18.762 -18.762 0.001 (0) + [14C]O3-2 1.184e-19 8.302e-20 -18.926 -19.081 -0.154 (0) + CaH[14C]O2[18O]+ 8.413e-21 7.718e-21 -20.075 -20.112 -0.037 (0) + CaH[14C]O[18O]O+ 8.413e-21 7.718e-21 -20.075 -20.112 -0.037 (0) + CaH[14C][18O]O2+ 8.413e-21 7.718e-21 -20.075 -20.112 -0.037 (0) + Ca[14C]O2[18O] 1.383e-21 1.386e-21 -20.859 -20.858 0.001 (0) + H[14C]O[18O]2- 7.946e-22 7.270e-22 -21.100 -21.138 -0.039 (0) + H[14C][18O]2O- 7.946e-22 7.270e-22 -21.100 -21.138 -0.039 (0) + H[14C][18O]O[18O]- 7.946e-22 7.270e-22 -21.100 -21.138 -0.039 (0) + [14C]O2[18O]-2 7.090e-22 4.969e-22 -21.149 -21.304 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.865 -68.864 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.866 -71.865 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -11029,99 +11029,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 4.069e-19 - CH4 4.069e-19 4.076e-19 -18.391 -18.390 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.092e-08 6.102e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.604e-13 - H2 8.018e-14 8.031e-14 -13.096 -13.095 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.192 -66.191 0.001 - O[18O] 0.000e+00 0.000e+00 -68.591 -68.590 0.001 -[13C](-4) 4.507e-21 - [13C]H4 4.507e-21 4.515e-21 -20.346 -20.345 0.001 -[13C](4) 6.515e-05 - H[13C]O3- 5.255e-05 4.808e-05 -4.279 -4.318 -0.039 - [13C]O2 1.103e-05 1.105e-05 -4.957 -4.957 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.593e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.593e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.593e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.092e-08 6.102e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.588e-08 4.596e-08 -7.338 -7.338 0.001 - [13C]O3-2 3.123e-08 2.189e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.647e-10 3.653e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 -[14C](-4) 1.564e-32 - [14C]H4 1.564e-32 1.566e-32 -31.806 -31.805 0.001 -[14C](4) 2.277e-16 - H[14C]O3- 1.839e-16 1.682e-16 -15.735 -15.774 -0.039 - [14C]O2 3.828e-17 3.834e-17 -16.417 -16.416 0.001 - CaH[14C]O3+ 3.884e-18 3.564e-18 -17.411 -17.448 -0.037 - H[14C]O2[18O]- 3.669e-19 3.357e-19 -18.435 -18.474 -0.039 - H[14C]O[18O]O- 3.669e-19 3.357e-19 -18.435 -18.474 -0.039 - H[14C][18O]O2- 3.669e-19 3.357e-19 -18.435 -18.474 -0.039 - Ca[14C]O3 2.129e-19 2.132e-19 -18.672 -18.671 0.001 - [14C]O[18O] 1.592e-19 1.594e-19 -18.798 -18.797 0.001 - [14C]O3-2 1.091e-19 7.648e-20 -18.962 -19.116 -0.154 - CaH[14C]O2[18O]+ 7.750e-21 7.110e-21 -20.111 -20.148 -0.037 - CaH[14C]O[18O]O+ 7.750e-21 7.110e-21 -20.111 -20.148 -0.037 - CaH[14C][18O]O2+ 7.750e-21 7.110e-21 -20.111 -20.148 -0.037 - Ca[14C]O2[18O] 1.274e-21 1.276e-21 -20.895 -20.894 0.001 - H[14C]O[18O]2- 7.320e-22 6.698e-22 -21.135 -21.174 -0.039 - H[14C][18O]2O- 7.320e-22 6.698e-22 -21.135 -21.174 -0.039 - H[14C][18O]O[18O]- 7.320e-22 6.698e-22 -21.135 -21.174 -0.039 - [14C]O2[18O]-2 6.531e-22 4.578e-22 -21.185 -21.339 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.591 -68.590 0.001 - [18O]2 0.000e+00 0.000e+00 -71.592 -71.591 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 4.069e-19 + CH4 4.069e-19 4.076e-19 -18.391 -18.390 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.092e-08 6.102e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.604e-13 + H2 8.018e-14 8.031e-14 -13.096 -13.095 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.192 -66.191 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.591 -68.590 0.001 (0) +[13C](-4) 4.507e-21 + [13C]H4 4.507e-21 4.515e-21 -20.346 -20.345 0.001 (0) +[13C](4) 6.515e-05 + H[13C]O3- 5.255e-05 4.808e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.105e-05 -4.957 -4.957 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.593e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.593e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.593e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.092e-08 6.102e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.588e-08 4.596e-08 -7.338 -7.338 0.001 (0) + [13C]O3-2 3.123e-08 2.189e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.647e-10 3.653e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 1.564e-32 + [14C]H4 1.564e-32 1.566e-32 -31.806 -31.805 0.001 (0) +[14C](4) 2.277e-16 + H[14C]O3- 1.839e-16 1.682e-16 -15.735 -15.774 -0.039 (0) + [14C]O2 3.828e-17 3.834e-17 -16.417 -16.416 0.001 (0) + CaH[14C]O3+ 3.884e-18 3.564e-18 -17.411 -17.448 -0.037 (0) + H[14C]O2[18O]- 3.669e-19 3.357e-19 -18.435 -18.474 -0.039 (0) + H[14C]O[18O]O- 3.669e-19 3.357e-19 -18.435 -18.474 -0.039 (0) + H[14C][18O]O2- 3.669e-19 3.357e-19 -18.435 -18.474 -0.039 (0) + Ca[14C]O3 2.129e-19 2.132e-19 -18.672 -18.671 0.001 (0) + [14C]O[18O] 1.592e-19 1.594e-19 -18.798 -18.797 0.001 (0) + [14C]O3-2 1.091e-19 7.648e-20 -18.962 -19.116 -0.154 (0) + CaH[14C]O2[18O]+ 7.750e-21 7.110e-21 -20.111 -20.148 -0.037 (0) + CaH[14C]O[18O]O+ 7.750e-21 7.110e-21 -20.111 -20.148 -0.037 (0) + CaH[14C][18O]O2+ 7.750e-21 7.110e-21 -20.111 -20.148 -0.037 (0) + Ca[14C]O2[18O] 1.274e-21 1.276e-21 -20.895 -20.894 0.001 (0) + H[14C]O[18O]2- 7.320e-22 6.698e-22 -21.135 -21.174 -0.039 (0) + H[14C][18O]2O- 7.320e-22 6.698e-22 -21.135 -21.174 -0.039 (0) + H[14C][18O]O[18O]- 7.320e-22 6.698e-22 -21.135 -21.174 -0.039 (0) + [14C]O2[18O]-2 6.531e-22 4.578e-22 -21.185 -21.339 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.591 -68.590 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.592 -71.591 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -11303,99 +11303,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 9.000e-20 - CH4 9.000e-20 9.015e-20 -19.046 -19.045 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.093e-08 6.103e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.100e-13 - H2 5.499e-14 5.508e-14 -13.260 -13.259 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.864 -65.864 0.001 - O[18O] 0.000e+00 0.000e+00 -68.263 -68.263 0.001 -[13C](-4) 9.970e-22 - [13C]H4 9.970e-22 9.987e-22 -21.001 -21.001 0.001 -[13C](4) 6.515e-05 - H[13C]O3- 5.255e-05 4.808e-05 -4.279 -4.318 -0.039 - [13C]O2 1.103e-05 1.105e-05 -4.957 -4.957 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.593e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.593e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.593e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.093e-08 6.103e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.589e-08 4.596e-08 -7.338 -7.338 0.001 - [13C]O3-2 3.123e-08 2.189e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.647e-10 3.653e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 -[14C](-4) 3.186e-33 - [14C]H4 3.186e-33 3.191e-33 -32.497 -32.496 0.001 -[14C](4) 2.097e-16 - H[14C]O3- 1.694e-16 1.550e-16 -15.771 -15.810 -0.039 - [14C]O2 3.526e-17 3.532e-17 -16.453 -16.452 0.001 - CaH[14C]O3+ 3.578e-18 3.283e-18 -17.446 -17.484 -0.037 - H[14C]O2[18O]- 3.380e-19 3.092e-19 -18.471 -18.510 -0.039 - H[14C]O[18O]O- 3.380e-19 3.092e-19 -18.471 -18.510 -0.039 - H[14C][18O]O2- 3.380e-19 3.092e-19 -18.471 -18.510 -0.039 - Ca[14C]O3 1.961e-19 1.964e-19 -18.707 -18.707 0.001 - [14C]O[18O] 1.466e-19 1.469e-19 -18.834 -18.833 0.001 - [14C]O3-2 1.005e-19 7.046e-20 -18.998 -19.152 -0.154 - CaH[14C]O2[18O]+ 7.139e-21 6.550e-21 -20.146 -20.184 -0.037 - CaH[14C]O[18O]O+ 7.139e-21 6.550e-21 -20.146 -20.184 -0.037 - CaH[14C][18O]O2+ 7.139e-21 6.550e-21 -20.146 -20.184 -0.037 - Ca[14C]O2[18O] 1.174e-21 1.176e-21 -20.930 -20.930 0.001 - H[14C]O[18O]2- 6.743e-22 6.170e-22 -21.171 -21.210 -0.039 - H[14C][18O]2O- 6.743e-22 6.170e-22 -21.171 -21.210 -0.039 - H[14C][18O]O[18O]- 6.743e-22 6.170e-22 -21.171 -21.210 -0.039 - [14C]O2[18O]-2 6.017e-22 4.217e-22 -21.221 -21.375 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.263 -68.263 0.001 - [18O]2 0.000e+00 0.000e+00 -71.264 -71.264 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 9.000e-20 + CH4 9.000e-20 9.015e-20 -19.046 -19.045 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.093e-08 6.103e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.100e-13 + H2 5.499e-14 5.508e-14 -13.260 -13.259 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.864 -65.864 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.263 -68.263 0.001 (0) +[13C](-4) 9.970e-22 + [13C]H4 9.970e-22 9.987e-22 -21.001 -21.001 0.001 (0) +[13C](4) 6.515e-05 + H[13C]O3- 5.255e-05 4.808e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.105e-05 -4.957 -4.957 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.593e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.593e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.593e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.093e-08 6.103e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.589e-08 4.596e-08 -7.338 -7.338 0.001 (0) + [13C]O3-2 3.123e-08 2.189e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.647e-10 3.653e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 3.186e-33 + [14C]H4 3.186e-33 3.191e-33 -32.497 -32.496 0.001 (0) +[14C](4) 2.097e-16 + H[14C]O3- 1.694e-16 1.550e-16 -15.771 -15.810 -0.039 (0) + [14C]O2 3.526e-17 3.532e-17 -16.453 -16.452 0.001 (0) + CaH[14C]O3+ 3.578e-18 3.283e-18 -17.446 -17.484 -0.037 (0) + H[14C]O2[18O]- 3.380e-19 3.092e-19 -18.471 -18.510 -0.039 (0) + H[14C]O[18O]O- 3.380e-19 3.092e-19 -18.471 -18.510 -0.039 (0) + H[14C][18O]O2- 3.380e-19 3.092e-19 -18.471 -18.510 -0.039 (0) + Ca[14C]O3 1.961e-19 1.964e-19 -18.707 -18.707 0.001 (0) + [14C]O[18O] 1.466e-19 1.469e-19 -18.834 -18.833 0.001 (0) + [14C]O3-2 1.005e-19 7.046e-20 -18.998 -19.152 -0.154 (0) + CaH[14C]O2[18O]+ 7.139e-21 6.550e-21 -20.146 -20.184 -0.037 (0) + CaH[14C]O[18O]O+ 7.139e-21 6.550e-21 -20.146 -20.184 -0.037 (0) + CaH[14C][18O]O2+ 7.139e-21 6.550e-21 -20.146 -20.184 -0.037 (0) + Ca[14C]O2[18O] 1.174e-21 1.176e-21 -20.930 -20.930 0.001 (0) + H[14C]O[18O]2- 6.743e-22 6.170e-22 -21.171 -21.210 -0.039 (0) + H[14C][18O]2O- 6.743e-22 6.170e-22 -21.171 -21.210 -0.039 (0) + H[14C][18O]O[18O]- 6.743e-22 6.170e-22 -21.171 -21.210 -0.039 (0) + [14C]O2[18O]-2 6.017e-22 4.217e-22 -21.221 -21.375 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.263 -68.263 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.264 -71.264 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -11577,99 +11577,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 4.295e-21 - CH4 4.295e-21 4.302e-21 -20.367 -20.366 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.093e-08 6.103e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 5.140e-14 - H2 2.570e-14 2.574e-14 -13.590 -13.589 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.204 -65.203 0.001 - O[18O] 0.000e+00 0.000e+00 -67.603 -67.602 0.001 -[13C](-4) 4.758e-23 - [13C]H4 4.758e-23 4.766e-23 -22.323 -22.322 0.001 -[13C](4) 6.516e-05 - H[13C]O3- 5.255e-05 4.808e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.105e-05 -4.957 -4.957 0.001 - CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.594e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.594e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.594e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.093e-08 6.103e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.589e-08 4.596e-08 -7.338 -7.338 0.001 - [13C]O3-2 3.123e-08 2.189e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.647e-10 3.653e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 -[14C](-4) 1.401e-34 - [14C]H4 1.401e-34 1.403e-34 -33.854 -33.853 0.001 -[14C](4) 1.932e-16 - H[14C]O3- 1.561e-16 1.428e-16 -15.807 -15.845 -0.039 - [14C]O2 3.249e-17 3.254e-17 -16.488 -16.488 0.001 - CaH[14C]O3+ 3.296e-18 3.024e-18 -17.482 -17.519 -0.037 - H[14C]O2[18O]- 3.114e-19 2.849e-19 -18.507 -18.545 -0.039 - H[14C]O[18O]O- 3.114e-19 2.849e-19 -18.507 -18.545 -0.039 - H[14C][18O]O2- 3.114e-19 2.849e-19 -18.507 -18.545 -0.039 - Ca[14C]O3 1.807e-19 1.810e-19 -18.743 -18.742 0.001 - [14C]O[18O] 1.351e-19 1.353e-19 -18.869 -18.869 0.001 - [14C]O3-2 9.260e-20 6.491e-20 -19.033 -19.188 -0.154 - CaH[14C]O2[18O]+ 6.577e-21 6.034e-21 -20.182 -20.219 -0.037 - CaH[14C]O[18O]O+ 6.577e-21 6.034e-21 -20.182 -20.219 -0.037 - CaH[14C][18O]O2+ 6.577e-21 6.034e-21 -20.182 -20.219 -0.037 - Ca[14C]O2[18O] 1.081e-21 1.083e-21 -20.966 -20.965 0.001 - H[14C]O[18O]2- 6.212e-22 5.684e-22 -21.207 -21.245 -0.039 - H[14C][18O]2O- 6.212e-22 5.684e-22 -21.207 -21.245 -0.039 - H[14C][18O]O[18O]- 6.212e-22 5.684e-22 -21.207 -21.245 -0.039 - [14C]O2[18O]-2 5.543e-22 3.885e-22 -21.256 -21.411 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.603 -67.602 0.001 - [18O]2 0.000e+00 0.000e+00 -70.604 -70.603 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 4.295e-21 + CH4 4.295e-21 4.302e-21 -20.367 -20.366 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.093e-08 6.103e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 5.140e-14 + H2 2.570e-14 2.574e-14 -13.590 -13.589 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.204 -65.203 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.603 -67.602 0.001 (0) +[13C](-4) 4.758e-23 + [13C]H4 4.758e-23 4.766e-23 -22.323 -22.322 0.001 (0) +[13C](4) 6.516e-05 + H[13C]O3- 5.255e-05 4.808e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.105e-05 -4.957 -4.957 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.594e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.594e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.594e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.093e-08 6.103e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.589e-08 4.596e-08 -7.338 -7.338 0.001 (0) + [13C]O3-2 3.123e-08 2.189e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.647e-10 3.653e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 1.401e-34 + [14C]H4 1.401e-34 1.403e-34 -33.854 -33.853 0.001 (0) +[14C](4) 1.932e-16 + H[14C]O3- 1.561e-16 1.428e-16 -15.807 -15.845 -0.039 (0) + [14C]O2 3.249e-17 3.254e-17 -16.488 -16.488 0.001 (0) + CaH[14C]O3+ 3.296e-18 3.024e-18 -17.482 -17.519 -0.037 (0) + H[14C]O2[18O]- 3.114e-19 2.849e-19 -18.507 -18.545 -0.039 (0) + H[14C]O[18O]O- 3.114e-19 2.849e-19 -18.507 -18.545 -0.039 (0) + H[14C][18O]O2- 3.114e-19 2.849e-19 -18.507 -18.545 -0.039 (0) + Ca[14C]O3 1.807e-19 1.810e-19 -18.743 -18.742 0.001 (0) + [14C]O[18O] 1.351e-19 1.353e-19 -18.869 -18.869 0.001 (0) + [14C]O3-2 9.260e-20 6.491e-20 -19.033 -19.188 -0.154 (0) + CaH[14C]O2[18O]+ 6.577e-21 6.034e-21 -20.182 -20.219 -0.037 (0) + CaH[14C]O[18O]O+ 6.577e-21 6.034e-21 -20.182 -20.219 -0.037 (0) + CaH[14C][18O]O2+ 6.577e-21 6.034e-21 -20.182 -20.219 -0.037 (0) + Ca[14C]O2[18O] 1.081e-21 1.083e-21 -20.966 -20.965 0.001 (0) + H[14C]O[18O]2- 6.212e-22 5.684e-22 -21.207 -21.245 -0.039 (0) + H[14C][18O]2O- 6.212e-22 5.684e-22 -21.207 -21.245 -0.039 (0) + H[14C][18O]O[18O]- 6.212e-22 5.684e-22 -21.207 -21.245 -0.039 (0) + [14C]O2[18O]-2 5.543e-22 3.885e-22 -21.256 -21.411 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.603 -67.602 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.604 -70.603 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -11851,99 +11851,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 2.787e-21 - CH4 2.787e-21 2.792e-21 -20.555 -20.554 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.093e-08 6.103e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 4.613e-14 - H2 2.307e-14 2.310e-14 -13.637 -13.636 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.110 -65.109 0.001 - O[18O] 0.000e+00 0.000e+00 -67.509 -67.508 0.001 -[13C](-4) 3.088e-23 - [13C]H4 3.088e-23 3.093e-23 -22.510 -22.510 0.001 -[13C](4) 6.516e-05 - H[13C]O3- 5.255e-05 4.809e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.105e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.594e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.594e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.594e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.093e-08 6.103e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.589e-08 4.597e-08 -7.338 -7.338 0.001 - [13C]O3-2 3.123e-08 2.189e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.647e-10 3.653e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 -[14C](-4) 8.374e-35 - [14C]H4 8.374e-35 8.387e-35 -34.077 -34.076 0.001 -[14C](4) 1.780e-16 - H[14C]O3- 1.438e-16 1.315e-16 -15.842 -15.881 -0.039 - [14C]O2 2.993e-17 2.998e-17 -16.524 -16.523 0.001 - CaH[14C]O3+ 3.037e-18 2.786e-18 -17.518 -17.555 -0.037 - H[14C]O2[18O]- 2.868e-19 2.624e-19 -18.542 -18.581 -0.039 - H[14C]O[18O]O- 2.868e-19 2.624e-19 -18.542 -18.581 -0.039 - H[14C][18O]O2- 2.868e-19 2.624e-19 -18.542 -18.581 -0.039 - Ca[14C]O3 1.664e-19 1.667e-19 -18.779 -18.778 0.001 - [14C]O[18O] 1.244e-19 1.247e-19 -18.905 -18.904 0.001 - [14C]O3-2 8.531e-20 5.979e-20 -19.069 -19.223 -0.154 - CaH[14C]O2[18O]+ 6.059e-21 5.559e-21 -20.218 -20.255 -0.037 - CaH[14C]O[18O]O+ 6.059e-21 5.559e-21 -20.218 -20.255 -0.037 - CaH[14C][18O]O2+ 6.059e-21 5.559e-21 -20.218 -20.255 -0.037 - Ca[14C]O2[18O] 9.963e-22 9.979e-22 -21.002 -21.001 0.001 - H[14C]O[18O]2- 5.723e-22 5.236e-22 -21.242 -21.281 -0.039 - H[14C][18O]2O- 5.723e-22 5.236e-22 -21.242 -21.281 -0.039 - H[14C][18O]O[18O]- 5.723e-22 5.236e-22 -21.242 -21.281 -0.039 - [14C]O2[18O]-2 5.106e-22 3.579e-22 -21.292 -21.446 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.509 -67.508 0.001 - [18O]2 0.000e+00 0.000e+00 -70.510 -70.509 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 2.787e-21 + CH4 2.787e-21 2.792e-21 -20.555 -20.554 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.093e-08 6.103e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 4.613e-14 + H2 2.307e-14 2.310e-14 -13.637 -13.636 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.110 -65.109 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.509 -67.508 0.001 (0) +[13C](-4) 3.088e-23 + [13C]H4 3.088e-23 3.093e-23 -22.510 -22.510 0.001 (0) +[13C](4) 6.516e-05 + H[13C]O3- 5.255e-05 4.809e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.105e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.594e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.594e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.594e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.093e-08 6.103e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.589e-08 4.597e-08 -7.338 -7.338 0.001 (0) + [13C]O3-2 3.123e-08 2.189e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.647e-10 3.653e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 8.374e-35 + [14C]H4 8.374e-35 8.387e-35 -34.077 -34.076 0.001 (0) +[14C](4) 1.780e-16 + H[14C]O3- 1.438e-16 1.315e-16 -15.842 -15.881 -0.039 (0) + [14C]O2 2.993e-17 2.998e-17 -16.524 -16.523 0.001 (0) + CaH[14C]O3+ 3.037e-18 2.786e-18 -17.518 -17.555 -0.037 (0) + H[14C]O2[18O]- 2.868e-19 2.624e-19 -18.542 -18.581 -0.039 (0) + H[14C]O[18O]O- 2.868e-19 2.624e-19 -18.542 -18.581 -0.039 (0) + H[14C][18O]O2- 2.868e-19 2.624e-19 -18.542 -18.581 -0.039 (0) + Ca[14C]O3 1.664e-19 1.667e-19 -18.779 -18.778 0.001 (0) + [14C]O[18O] 1.244e-19 1.247e-19 -18.905 -18.904 0.001 (0) + [14C]O3-2 8.531e-20 5.979e-20 -19.069 -19.223 -0.154 (0) + CaH[14C]O2[18O]+ 6.059e-21 5.559e-21 -20.218 -20.255 -0.037 (0) + CaH[14C]O[18O]O+ 6.059e-21 5.559e-21 -20.218 -20.255 -0.037 (0) + CaH[14C][18O]O2+ 6.059e-21 5.559e-21 -20.218 -20.255 -0.037 (0) + Ca[14C]O2[18O] 9.963e-22 9.979e-22 -21.002 -21.001 0.001 (0) + H[14C]O[18O]2- 5.723e-22 5.236e-22 -21.242 -21.281 -0.039 (0) + H[14C][18O]2O- 5.723e-22 5.236e-22 -21.242 -21.281 -0.039 (0) + H[14C][18O]O[18O]- 5.723e-22 5.236e-22 -21.242 -21.281 -0.039 (0) + [14C]O2[18O]-2 5.106e-22 3.579e-22 -21.292 -21.446 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.509 -67.508 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.510 -70.509 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -12125,99 +12125,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 4.470e-20 - CH4 4.470e-20 4.478e-20 -19.350 -19.349 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.094e-08 6.104e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 9.232e-14 - H2 4.616e-14 4.624e-14 -13.336 -13.335 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.712 -65.712 0.001 - O[18O] 0.000e+00 0.000e+00 -68.111 -68.111 0.001 -[13C](-4) 4.953e-22 - [13C]H4 4.953e-22 4.961e-22 -21.305 -21.304 0.001 -[13C](4) 6.516e-05 - H[13C]O3- 5.256e-05 4.809e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.105e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.094e-08 6.104e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.589e-08 4.597e-08 -7.338 -7.338 0.001 - [13C]O3-2 3.123e-08 2.189e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.647e-10 3.653e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 -[14C](-4) 1.237e-33 - [14C]H4 1.237e-33 1.239e-33 -32.908 -32.907 0.001 -[14C](4) 1.640e-16 - H[14C]O3- 1.324e-16 1.212e-16 -15.878 -15.917 -0.039 - [14C]O2 2.757e-17 2.761e-17 -16.560 -16.559 0.001 - CaH[14C]O3+ 2.798e-18 2.567e-18 -17.553 -17.591 -0.037 - H[14C]O2[18O]- 2.642e-19 2.418e-19 -18.578 -18.617 -0.039 - H[14C]O[18O]O- 2.642e-19 2.418e-19 -18.578 -18.617 -0.039 - H[14C][18O]O2- 2.642e-19 2.418e-19 -18.578 -18.617 -0.039 - Ca[14C]O3 1.533e-19 1.536e-19 -18.814 -18.814 0.001 - [14C]O[18O] 1.146e-19 1.148e-19 -18.941 -18.940 0.001 - [14C]O3-2 7.859e-20 5.508e-20 -19.105 -19.259 -0.154 - CaH[14C]O2[18O]+ 5.582e-21 5.121e-21 -20.253 -20.291 -0.037 - CaH[14C]O[18O]O+ 5.582e-21 5.121e-21 -20.253 -20.291 -0.037 - CaH[14C][18O]O2+ 5.582e-21 5.121e-21 -20.253 -20.291 -0.037 - Ca[14C]O2[18O] 9.178e-22 9.193e-22 -21.037 -21.037 0.001 - H[14C]O[18O]2- 5.272e-22 4.824e-22 -21.278 -21.317 -0.039 - H[14C][18O]2O- 5.272e-22 4.824e-22 -21.278 -21.317 -0.039 - H[14C][18O]O[18O]- 5.272e-22 4.824e-22 -21.278 -21.317 -0.039 - [14C]O2[18O]-2 4.704e-22 3.297e-22 -21.328 -21.482 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.111 -68.111 0.001 - [18O]2 0.000e+00 0.000e+00 -71.112 -71.112 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 4.470e-20 + CH4 4.470e-20 4.478e-20 -19.350 -19.349 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.094e-08 6.104e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 9.232e-14 + H2 4.616e-14 4.624e-14 -13.336 -13.335 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.712 -65.712 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.111 -68.111 0.001 (0) +[13C](-4) 4.953e-22 + [13C]H4 4.953e-22 4.961e-22 -21.305 -21.304 0.001 (0) +[13C](4) 6.516e-05 + H[13C]O3- 5.256e-05 4.809e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.105e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.094e-08 6.104e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.589e-08 4.597e-08 -7.338 -7.338 0.001 (0) + [13C]O3-2 3.123e-08 2.189e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.647e-10 3.653e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.869e-10 1.310e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 1.237e-33 + [14C]H4 1.237e-33 1.239e-33 -32.908 -32.907 0.001 (0) +[14C](4) 1.640e-16 + H[14C]O3- 1.324e-16 1.212e-16 -15.878 -15.917 -0.039 (0) + [14C]O2 2.757e-17 2.761e-17 -16.560 -16.559 0.001 (0) + CaH[14C]O3+ 2.798e-18 2.567e-18 -17.553 -17.591 -0.037 (0) + H[14C]O2[18O]- 2.642e-19 2.418e-19 -18.578 -18.617 -0.039 (0) + H[14C]O[18O]O- 2.642e-19 2.418e-19 -18.578 -18.617 -0.039 (0) + H[14C][18O]O2- 2.642e-19 2.418e-19 -18.578 -18.617 -0.039 (0) + Ca[14C]O3 1.533e-19 1.536e-19 -18.814 -18.814 0.001 (0) + [14C]O[18O] 1.146e-19 1.148e-19 -18.941 -18.940 0.001 (0) + [14C]O3-2 7.859e-20 5.508e-20 -19.105 -19.259 -0.154 (0) + CaH[14C]O2[18O]+ 5.582e-21 5.121e-21 -20.253 -20.291 -0.037 (0) + CaH[14C]O[18O]O+ 5.582e-21 5.121e-21 -20.253 -20.291 -0.037 (0) + CaH[14C][18O]O2+ 5.582e-21 5.121e-21 -20.253 -20.291 -0.037 (0) + Ca[14C]O2[18O] 9.178e-22 9.193e-22 -21.037 -21.037 0.001 (0) + H[14C]O[18O]2- 5.272e-22 4.824e-22 -21.278 -21.317 -0.039 (0) + H[14C][18O]2O- 5.272e-22 4.824e-22 -21.278 -21.317 -0.039 (0) + H[14C][18O]O[18O]- 5.272e-22 4.824e-22 -21.278 -21.317 -0.039 (0) + [14C]O2[18O]-2 4.704e-22 3.297e-22 -21.328 -21.482 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.111 -68.111 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.112 -71.112 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -12399,99 +12399,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 3.016e-20 - CH4 3.016e-20 3.021e-20 -19.521 -19.520 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.094e-08 6.104e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 8.367e-14 - H2 4.184e-14 4.190e-14 -13.378 -13.378 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.627 -65.626 0.001 - O[18O] 0.000e+00 0.000e+00 -68.026 -68.025 0.001 -[13C](-4) 3.341e-22 - [13C]H4 3.341e-22 3.347e-22 -21.476 -21.475 0.001 -[13C](4) 6.517e-05 - H[13C]O3- 5.256e-05 4.809e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.105e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.094e-08 6.104e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.589e-08 4.597e-08 -7.338 -7.338 0.001 - [13C]O3-2 3.123e-08 2.189e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.310e-10 -9.728 -9.883 -0.154 -[14C](-4) 7.689e-34 - [14C]H4 7.689e-34 7.702e-34 -33.114 -33.113 0.001 -[14C](4) 1.510e-16 - H[14C]O3- 1.220e-16 1.116e-16 -15.914 -15.952 -0.039 - [14C]O2 2.540e-17 2.544e-17 -16.595 -16.594 0.001 - CaH[14C]O3+ 2.577e-18 2.364e-18 -17.589 -17.626 -0.037 - H[14C]O2[18O]- 2.434e-19 2.227e-19 -18.614 -18.652 -0.039 - H[14C]O[18O]O- 2.434e-19 2.227e-19 -18.614 -18.652 -0.039 - H[14C][18O]O2- 2.434e-19 2.227e-19 -18.614 -18.652 -0.039 - Ca[14C]O3 1.413e-19 1.415e-19 -18.850 -18.849 0.001 - [14C]O[18O] 1.056e-19 1.058e-19 -18.976 -18.976 0.001 - [14C]O3-2 7.240e-20 5.074e-20 -19.140 -19.295 -0.154 - CaH[14C]O2[18O]+ 5.142e-21 4.717e-21 -20.289 -20.326 -0.037 - CaH[14C]O[18O]O+ 5.142e-21 4.717e-21 -20.289 -20.326 -0.037 - CaH[14C][18O]O2+ 5.142e-21 4.717e-21 -20.289 -20.326 -0.037 - Ca[14C]O2[18O] 8.455e-22 8.469e-22 -21.073 -21.072 0.001 - H[14C]O[18O]2- 4.857e-22 4.444e-22 -21.314 -21.352 -0.039 - H[14C][18O]2O- 4.857e-22 4.444e-22 -21.314 -21.352 -0.039 - H[14C][18O]O[18O]- 4.857e-22 4.444e-22 -21.314 -21.352 -0.039 - [14C]O2[18O]-2 4.333e-22 3.037e-22 -21.363 -21.518 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.026 -68.025 0.001 - [18O]2 0.000e+00 0.000e+00 -71.027 -71.026 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 3.016e-20 + CH4 3.016e-20 3.021e-20 -19.521 -19.520 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.094e-08 6.104e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 8.367e-14 + H2 4.184e-14 4.190e-14 -13.378 -13.378 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.627 -65.626 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.026 -68.025 0.001 (0) +[13C](-4) 3.341e-22 + [13C]H4 3.341e-22 3.347e-22 -21.476 -21.475 0.001 (0) +[13C](4) 6.517e-05 + H[13C]O3- 5.256e-05 4.809e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.105e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.094e-08 6.104e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.589e-08 4.597e-08 -7.338 -7.338 0.001 (0) + [13C]O3-2 3.123e-08 2.189e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.310e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 7.689e-34 + [14C]H4 7.689e-34 7.702e-34 -33.114 -33.113 0.001 (0) +[14C](4) 1.510e-16 + H[14C]O3- 1.220e-16 1.116e-16 -15.914 -15.952 -0.039 (0) + [14C]O2 2.540e-17 2.544e-17 -16.595 -16.594 0.001 (0) + CaH[14C]O3+ 2.577e-18 2.364e-18 -17.589 -17.626 -0.037 (0) + H[14C]O2[18O]- 2.434e-19 2.227e-19 -18.614 -18.652 -0.039 (0) + H[14C]O[18O]O- 2.434e-19 2.227e-19 -18.614 -18.652 -0.039 (0) + H[14C][18O]O2- 2.434e-19 2.227e-19 -18.614 -18.652 -0.039 (0) + Ca[14C]O3 1.413e-19 1.415e-19 -18.850 -18.849 0.001 (0) + [14C]O[18O] 1.056e-19 1.058e-19 -18.976 -18.976 0.001 (0) + [14C]O3-2 7.240e-20 5.074e-20 -19.140 -19.295 -0.154 (0) + CaH[14C]O2[18O]+ 5.142e-21 4.717e-21 -20.289 -20.326 -0.037 (0) + CaH[14C]O[18O]O+ 5.142e-21 4.717e-21 -20.289 -20.326 -0.037 (0) + CaH[14C][18O]O2+ 5.142e-21 4.717e-21 -20.289 -20.326 -0.037 (0) + Ca[14C]O2[18O] 8.455e-22 8.469e-22 -21.073 -21.072 0.001 (0) + H[14C]O[18O]2- 4.857e-22 4.444e-22 -21.314 -21.352 -0.039 (0) + H[14C][18O]2O- 4.857e-22 4.444e-22 -21.314 -21.352 -0.039 (0) + H[14C][18O]O[18O]- 4.857e-22 4.444e-22 -21.314 -21.352 -0.039 (0) + [14C]O2[18O]-2 4.333e-22 3.037e-22 -21.363 -21.518 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.026 -68.025 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.027 -71.026 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -12673,99 +12673,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.362e-19 - CH4 1.362e-19 1.364e-19 -18.866 -18.865 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.094e-08 6.104e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.220e-13 - H2 6.099e-14 6.109e-14 -13.215 -13.214 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.954 -65.954 0.001 - O[18O] 0.000e+00 0.000e+00 -68.353 -68.353 0.001 -[13C](-4) 1.509e-21 - [13C]H4 1.509e-21 1.512e-21 -20.821 -20.821 0.001 -[13C](4) 6.517e-05 - H[13C]O3- 5.256e-05 4.809e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.094e-08 6.104e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.590e-08 4.597e-08 -7.338 -7.338 0.001 - [13C]O3-2 3.123e-08 2.189e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.310e-10 -9.728 -9.883 -0.154 -[14C](-4) 3.199e-33 - [14C]H4 3.199e-33 3.205e-33 -32.495 -32.494 0.001 -[14C](4) 1.391e-16 - H[14C]O3- 1.124e-16 1.028e-16 -15.949 -15.988 -0.039 - [14C]O2 2.340e-17 2.344e-17 -16.631 -16.630 0.001 - CaH[14C]O3+ 2.374e-18 2.178e-18 -17.624 -17.662 -0.037 - H[14C]O2[18O]- 2.242e-19 2.052e-19 -18.649 -18.688 -0.039 - H[14C]O[18O]O- 2.242e-19 2.052e-19 -18.649 -18.688 -0.039 - H[14C][18O]O2- 2.242e-19 2.052e-19 -18.649 -18.688 -0.039 - Ca[14C]O3 1.301e-19 1.303e-19 -18.886 -18.885 0.001 - [14C]O[18O] 9.729e-20 9.745e-20 -19.012 -19.011 0.001 - [14C]O3-2 6.669e-20 4.675e-20 -19.176 -19.330 -0.154 - CaH[14C]O2[18O]+ 4.737e-21 4.346e-21 -20.325 -20.362 -0.037 - CaH[14C]O[18O]O+ 4.737e-21 4.346e-21 -20.325 -20.362 -0.037 - CaH[14C][18O]O2+ 4.737e-21 4.346e-21 -20.325 -20.362 -0.037 - Ca[14C]O2[18O] 7.789e-22 7.801e-22 -21.109 -21.108 0.001 - H[14C]O[18O]2- 4.474e-22 4.094e-22 -21.349 -21.388 -0.039 - H[14C][18O]2O- 4.474e-22 4.094e-22 -21.349 -21.388 -0.039 - H[14C][18O]O[18O]- 4.474e-22 4.094e-22 -21.349 -21.388 -0.039 - [14C]O2[18O]-2 3.992e-22 2.798e-22 -21.399 -21.553 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.353 -68.353 0.001 - [18O]2 0.000e+00 0.000e+00 -71.354 -71.354 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.362e-19 + CH4 1.362e-19 1.364e-19 -18.866 -18.865 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.094e-08 6.104e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.220e-13 + H2 6.099e-14 6.109e-14 -13.215 -13.214 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.954 -65.954 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.353 -68.353 0.001 (0) +[13C](-4) 1.509e-21 + [13C]H4 1.509e-21 1.512e-21 -20.821 -20.821 0.001 (0) +[13C](4) 6.517e-05 + H[13C]O3- 5.256e-05 4.809e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.595e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.094e-08 6.104e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.590e-08 4.597e-08 -7.338 -7.338 0.001 (0) + [13C]O3-2 3.123e-08 2.189e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.092e-10 1.914e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.310e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 3.199e-33 + [14C]H4 3.199e-33 3.205e-33 -32.495 -32.494 0.001 (0) +[14C](4) 1.391e-16 + H[14C]O3- 1.124e-16 1.028e-16 -15.949 -15.988 -0.039 (0) + [14C]O2 2.340e-17 2.344e-17 -16.631 -16.630 0.001 (0) + CaH[14C]O3+ 2.374e-18 2.178e-18 -17.624 -17.662 -0.037 (0) + H[14C]O2[18O]- 2.242e-19 2.052e-19 -18.649 -18.688 -0.039 (0) + H[14C]O[18O]O- 2.242e-19 2.052e-19 -18.649 -18.688 -0.039 (0) + H[14C][18O]O2- 2.242e-19 2.052e-19 -18.649 -18.688 -0.039 (0) + Ca[14C]O3 1.301e-19 1.303e-19 -18.886 -18.885 0.001 (0) + [14C]O[18O] 9.729e-20 9.745e-20 -19.012 -19.011 0.001 (0) + [14C]O3-2 6.669e-20 4.675e-20 -19.176 -19.330 -0.154 (0) + CaH[14C]O2[18O]+ 4.737e-21 4.346e-21 -20.325 -20.362 -0.037 (0) + CaH[14C]O[18O]O+ 4.737e-21 4.346e-21 -20.325 -20.362 -0.037 (0) + CaH[14C][18O]O2+ 4.737e-21 4.346e-21 -20.325 -20.362 -0.037 (0) + Ca[14C]O2[18O] 7.789e-22 7.801e-22 -21.109 -21.108 0.001 (0) + H[14C]O[18O]2- 4.474e-22 4.094e-22 -21.349 -21.388 -0.039 (0) + H[14C][18O]2O- 4.474e-22 4.094e-22 -21.349 -21.388 -0.039 (0) + H[14C][18O]O[18O]- 4.474e-22 4.094e-22 -21.349 -21.388 -0.039 (0) + [14C]O2[18O]-2 3.992e-22 2.798e-22 -21.399 -21.553 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.353 -68.353 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.354 -71.354 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -12947,99 +12947,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 9.459e-21 - CH4 9.459e-21 9.474e-21 -20.024 -20.023 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.094e-08 6.104e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 6.262e-14 - H2 3.131e-14 3.136e-14 -13.504 -13.504 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.375 -65.375 0.001 - O[18O] 0.000e+00 0.000e+00 -67.774 -67.773 0.001 -[13C](-4) 1.048e-22 - [13C]H4 1.048e-22 1.050e-22 -21.980 -21.979 0.001 -[13C](4) 6.517e-05 - H[13C]O3- 5.256e-05 4.809e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.094e-08 6.104e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.590e-08 4.597e-08 -7.338 -7.338 0.001 - [13C]O3-2 3.124e-08 2.189e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.092e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.092e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.092e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.310e-10 -9.728 -9.883 -0.154 -[14C](-4) 2.047e-34 - [14C]H4 2.047e-34 2.050e-34 -33.689 -33.688 0.001 -[14C](4) 1.282e-16 - H[14C]O3- 1.035e-16 9.473e-17 -15.985 -16.023 -0.039 - [14C]O2 2.155e-17 2.159e-17 -16.666 -16.666 0.001 - CaH[14C]O3+ 2.187e-18 2.007e-18 -17.660 -17.698 -0.037 - H[14C]O2[18O]- 2.066e-19 1.890e-19 -18.685 -18.724 -0.039 - H[14C]O[18O]O- 2.066e-19 1.890e-19 -18.685 -18.724 -0.039 - H[14C][18O]O2- 2.066e-19 1.890e-19 -18.685 -18.724 -0.039 - Ca[14C]O3 1.199e-19 1.201e-19 -18.921 -18.921 0.001 - [14C]O[18O] 8.963e-20 8.977e-20 -19.048 -19.047 0.001 - [14C]O3-2 6.144e-20 4.306e-20 -19.212 -19.366 -0.154 - CaH[14C]O2[18O]+ 4.364e-21 4.003e-21 -20.360 -20.398 -0.037 - CaH[14C]O[18O]O+ 4.364e-21 4.003e-21 -20.360 -20.398 -0.037 - CaH[14C][18O]O2+ 4.364e-21 4.003e-21 -20.360 -20.398 -0.037 - Ca[14C]O2[18O] 7.175e-22 7.187e-22 -21.144 -21.143 0.001 - H[14C]O[18O]2- 4.122e-22 3.771e-22 -21.385 -21.424 -0.039 - H[14C][18O]2O- 4.122e-22 3.771e-22 -21.385 -21.424 -0.039 - H[14C][18O]O[18O]- 4.122e-22 3.771e-22 -21.385 -21.424 -0.039 - [14C]O2[18O]-2 3.678e-22 2.578e-22 -21.434 -21.589 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.774 -67.773 0.001 - [18O]2 0.000e+00 0.000e+00 -70.775 -70.775 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 9.459e-21 + CH4 9.459e-21 9.474e-21 -20.024 -20.023 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.094e-08 6.104e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 6.262e-14 + H2 3.131e-14 3.136e-14 -13.504 -13.504 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.375 -65.375 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.774 -67.773 0.001 (0) +[13C](-4) 1.048e-22 + [13C]H4 1.048e-22 1.050e-22 -21.980 -21.979 0.001 (0) +[13C](4) 6.517e-05 + H[13C]O3- 5.256e-05 4.809e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.094e-08 6.104e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.590e-08 4.597e-08 -7.338 -7.338 0.001 (0) + [13C]O3-2 3.124e-08 2.189e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.092e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.092e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.092e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.310e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 2.047e-34 + [14C]H4 2.047e-34 2.050e-34 -33.689 -33.688 0.001 (0) +[14C](4) 1.282e-16 + H[14C]O3- 1.035e-16 9.473e-17 -15.985 -16.023 -0.039 (0) + [14C]O2 2.155e-17 2.159e-17 -16.666 -16.666 0.001 (0) + CaH[14C]O3+ 2.187e-18 2.007e-18 -17.660 -17.698 -0.037 (0) + H[14C]O2[18O]- 2.066e-19 1.890e-19 -18.685 -18.724 -0.039 (0) + H[14C]O[18O]O- 2.066e-19 1.890e-19 -18.685 -18.724 -0.039 (0) + H[14C][18O]O2- 2.066e-19 1.890e-19 -18.685 -18.724 -0.039 (0) + Ca[14C]O3 1.199e-19 1.201e-19 -18.921 -18.921 0.001 (0) + [14C]O[18O] 8.963e-20 8.977e-20 -19.048 -19.047 0.001 (0) + [14C]O3-2 6.144e-20 4.306e-20 -19.212 -19.366 -0.154 (0) + CaH[14C]O2[18O]+ 4.364e-21 4.003e-21 -20.360 -20.398 -0.037 (0) + CaH[14C]O[18O]O+ 4.364e-21 4.003e-21 -20.360 -20.398 -0.037 (0) + CaH[14C][18O]O2+ 4.364e-21 4.003e-21 -20.360 -20.398 -0.037 (0) + Ca[14C]O2[18O] 7.175e-22 7.187e-22 -21.144 -21.143 0.001 (0) + H[14C]O[18O]2- 4.122e-22 3.771e-22 -21.385 -21.424 -0.039 (0) + H[14C][18O]2O- 4.122e-22 3.771e-22 -21.385 -21.424 -0.039 (0) + H[14C][18O]O[18O]- 4.122e-22 3.771e-22 -21.385 -21.424 -0.039 (0) + [14C]O2[18O]-2 3.678e-22 2.578e-22 -21.434 -21.589 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.774 -67.773 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.775 -70.775 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -13219,99 +13219,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -120.213 -120.212 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 5.618e-39 - H2 2.809e-39 2.814e-39 -38.551 -38.551 0.001 -O(0) 1.051e-15 - O2 5.236e-16 5.245e-16 -15.281 -15.280 0.001 - O[18O] 2.089e-18 2.093e-18 -17.680 -17.679 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -122.168 -122.167 0.001 -[13C](4) 6.517e-05 - H[13C]O3- 5.256e-05 4.810e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.590e-08 4.597e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.124e-08 2.189e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.092e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.092e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.092e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.310e-10 -9.728 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -133.913 -133.912 0.001 -[14C](4) 1.181e-16 - H[14C]O3- 9.538e-17 8.727e-17 -16.021 -16.059 -0.039 - [14C]O2 1.986e-17 1.989e-17 -16.702 -16.701 0.001 - CaH[14C]O3+ 2.015e-18 1.848e-18 -17.696 -17.733 -0.037 - H[14C]O2[18O]- 1.903e-19 1.741e-19 -18.721 -18.759 -0.039 - H[14C]O[18O]O- 1.903e-19 1.741e-19 -18.721 -18.759 -0.039 - H[14C][18O]O2- 1.903e-19 1.741e-19 -18.721 -18.759 -0.039 - Ca[14C]O3 1.104e-19 1.106e-19 -18.957 -18.956 0.001 - [14C]O[18O] 8.257e-20 8.270e-20 -19.083 -19.082 0.001 - [14C]O3-2 5.660e-20 3.967e-20 -19.247 -19.402 -0.154 - CaH[14C]O2[18O]+ 4.020e-21 3.688e-21 -20.396 -20.433 -0.037 - CaH[14C]O[18O]O+ 4.020e-21 3.688e-21 -20.396 -20.433 -0.037 - CaH[14C][18O]O2+ 4.020e-21 3.688e-21 -20.396 -20.433 -0.037 - Ca[14C]O2[18O] 6.610e-22 6.621e-22 -21.180 -21.179 0.001 - H[14C]O[18O]2- 3.797e-22 3.474e-22 -21.421 -21.459 -0.039 - H[14C][18O]2O- 3.797e-22 3.474e-22 -21.421 -21.459 -0.039 - H[14C][18O]O[18O]- 3.797e-22 3.474e-22 -21.421 -21.459 -0.039 - [14C]O2[18O]-2 3.388e-22 2.375e-22 -21.470 -21.624 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.094e-18 - O[18O] 2.089e-18 2.093e-18 -17.680 -17.679 0.001 - [18O]2 2.084e-21 2.088e-21 -20.681 -20.680 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -120.213 -120.212 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 5.618e-39 + H2 2.809e-39 2.814e-39 -38.551 -38.551 0.001 (0) +O(0) 1.051e-15 + O2 5.236e-16 5.245e-16 -15.281 -15.280 0.001 (0) + O[18O] 2.089e-18 2.093e-18 -17.680 -17.679 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -122.168 -122.167 0.001 (0) +[13C](4) 6.517e-05 + H[13C]O3- 5.256e-05 4.810e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.590e-08 4.597e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.124e-08 2.189e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.215e-09 2.032e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.092e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.092e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.092e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.310e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -133.913 -133.912 0.001 (0) +[14C](4) 1.181e-16 + H[14C]O3- 9.538e-17 8.727e-17 -16.021 -16.059 -0.039 (0) + [14C]O2 1.986e-17 1.989e-17 -16.702 -16.701 0.001 (0) + CaH[14C]O3+ 2.015e-18 1.848e-18 -17.696 -17.733 -0.037 (0) + H[14C]O2[18O]- 1.903e-19 1.741e-19 -18.721 -18.759 -0.039 (0) + H[14C]O[18O]O- 1.903e-19 1.741e-19 -18.721 -18.759 -0.039 (0) + H[14C][18O]O2- 1.903e-19 1.741e-19 -18.721 -18.759 -0.039 (0) + Ca[14C]O3 1.104e-19 1.106e-19 -18.957 -18.956 0.001 (0) + [14C]O[18O] 8.257e-20 8.270e-20 -19.083 -19.082 0.001 (0) + [14C]O3-2 5.660e-20 3.967e-20 -19.247 -19.402 -0.154 (0) + CaH[14C]O2[18O]+ 4.020e-21 3.688e-21 -20.396 -20.433 -0.037 (0) + CaH[14C]O[18O]O+ 4.020e-21 3.688e-21 -20.396 -20.433 -0.037 (0) + CaH[14C][18O]O2+ 4.020e-21 3.688e-21 -20.396 -20.433 -0.037 (0) + Ca[14C]O2[18O] 6.610e-22 6.621e-22 -21.180 -21.179 0.001 (0) + H[14C]O[18O]2- 3.797e-22 3.474e-22 -21.421 -21.459 -0.039 (0) + H[14C][18O]2O- 3.797e-22 3.474e-22 -21.421 -21.459 -0.039 (0) + H[14C][18O]O[18O]- 3.797e-22 3.474e-22 -21.421 -21.459 -0.039 (0) + [14C]O2[18O]-2 3.388e-22 2.375e-22 -21.470 -21.624 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.094e-18 + O[18O] 2.089e-18 2.093e-18 -17.680 -17.679 0.001 (0) + [18O]2 2.084e-21 2.088e-21 -20.681 -20.680 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -13493,99 +13493,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.073e-25 - CH4 1.073e-25 1.075e-25 -24.969 -24.969 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 3.634e-15 - H2 1.817e-15 1.820e-15 -14.741 -14.740 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -62.903 -62.902 0.001 - O[18O] 0.000e+00 0.000e+00 -65.302 -65.301 0.001 -[13C](-4) 1.189e-27 - [13C]H4 1.189e-27 1.191e-27 -26.925 -26.924 0.001 -[13C](4) 6.517e-05 - H[13C]O3- 5.256e-05 4.810e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.590e-08 4.597e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.124e-08 2.189e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.215e-09 2.033e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.215e-09 2.033e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.215e-09 2.033e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.883 -0.154 -[14C](-4) 1.970e-39 - [14C]H4 1.970e-39 1.974e-39 -38.705 -38.705 0.001 -[14C](4) 1.088e-16 - H[14C]O3- 8.787e-17 8.040e-17 -16.056 -16.095 -0.039 - [14C]O2 1.829e-17 1.832e-17 -16.738 -16.737 0.001 - CaH[14C]O3+ 1.856e-18 1.703e-18 -17.731 -17.769 -0.037 - H[14C]O2[18O]- 1.753e-19 1.604e-19 -18.756 -18.795 -0.039 - H[14C]O[18O]O- 1.753e-19 1.604e-19 -18.756 -18.795 -0.039 - H[14C][18O]O2- 1.753e-19 1.604e-19 -18.756 -18.795 -0.039 - Ca[14C]O3 1.017e-19 1.019e-19 -18.993 -18.992 0.001 - [14C]O[18O] 7.606e-20 7.619e-20 -19.119 -19.118 0.001 - [14C]O3-2 5.214e-20 3.655e-20 -19.283 -19.437 -0.154 - CaH[14C]O2[18O]+ 3.703e-21 3.398e-21 -20.431 -20.469 -0.037 - CaH[14C]O[18O]O+ 3.703e-21 3.398e-21 -20.431 -20.469 -0.037 - CaH[14C][18O]O2+ 3.703e-21 3.398e-21 -20.431 -20.469 -0.037 - Ca[14C]O2[18O] 6.089e-22 6.099e-22 -21.215 -21.215 0.001 - H[14C]O[18O]2- 3.498e-22 3.200e-22 -21.456 -21.495 -0.039 - H[14C][18O]2O- 3.498e-22 3.200e-22 -21.456 -21.495 -0.039 - H[14C][18O]O[18O]- 3.498e-22 3.200e-22 -21.456 -21.495 -0.039 - [14C]O2[18O]-2 3.121e-22 2.188e-22 -21.506 -21.660 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -65.302 -65.301 0.001 - [18O]2 0.000e+00 0.000e+00 -68.303 -68.302 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.073e-25 + CH4 1.073e-25 1.075e-25 -24.969 -24.969 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 3.634e-15 + H2 1.817e-15 1.820e-15 -14.741 -14.740 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -62.903 -62.902 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -65.302 -65.301 0.001 (0) +[13C](-4) 1.189e-27 + [13C]H4 1.189e-27 1.191e-27 -26.925 -26.924 0.001 (0) +[13C](4) 6.517e-05 + H[13C]O3- 5.256e-05 4.810e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.590e-08 4.597e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.124e-08 2.189e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.215e-09 2.033e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.215e-09 2.033e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.215e-09 2.033e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 1.970e-39 + [14C]H4 1.970e-39 1.974e-39 -38.705 -38.705 0.001 (0) +[14C](4) 1.088e-16 + H[14C]O3- 8.787e-17 8.040e-17 -16.056 -16.095 -0.039 (0) + [14C]O2 1.829e-17 1.832e-17 -16.738 -16.737 0.001 (0) + CaH[14C]O3+ 1.856e-18 1.703e-18 -17.731 -17.769 -0.037 (0) + H[14C]O2[18O]- 1.753e-19 1.604e-19 -18.756 -18.795 -0.039 (0) + H[14C]O[18O]O- 1.753e-19 1.604e-19 -18.756 -18.795 -0.039 (0) + H[14C][18O]O2- 1.753e-19 1.604e-19 -18.756 -18.795 -0.039 (0) + Ca[14C]O3 1.017e-19 1.019e-19 -18.993 -18.992 0.001 (0) + [14C]O[18O] 7.606e-20 7.619e-20 -19.119 -19.118 0.001 (0) + [14C]O3-2 5.214e-20 3.655e-20 -19.283 -19.437 -0.154 (0) + CaH[14C]O2[18O]+ 3.703e-21 3.398e-21 -20.431 -20.469 -0.037 (0) + CaH[14C]O[18O]O+ 3.703e-21 3.398e-21 -20.431 -20.469 -0.037 (0) + CaH[14C][18O]O2+ 3.703e-21 3.398e-21 -20.431 -20.469 -0.037 (0) + Ca[14C]O2[18O] 6.089e-22 6.099e-22 -21.215 -21.215 0.001 (0) + H[14C]O[18O]2- 3.498e-22 3.200e-22 -21.456 -21.495 -0.039 (0) + H[14C][18O]2O- 3.498e-22 3.200e-22 -21.456 -21.495 -0.039 (0) + H[14C][18O]O[18O]- 3.498e-22 3.200e-22 -21.456 -21.495 -0.039 (0) + [14C]O2[18O]-2 3.121e-22 2.188e-22 -21.506 -21.660 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -65.302 -65.301 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -68.303 -68.302 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -13767,99 +13767,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 2.567e-24 - CH4 2.567e-24 2.571e-24 -23.591 -23.590 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 8.037e-15 - H2 4.018e-15 4.025e-15 -14.396 -14.395 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -63.592 -63.591 0.001 - O[18O] 0.000e+00 0.000e+00 -65.991 -65.990 0.001 -[13C](-4) 2.845e-26 - [13C]H4 2.845e-26 2.849e-26 -25.546 -25.545 0.001 -[13C](4) 6.518e-05 - H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.590e-08 4.598e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.883 -0.154 -[14C](-4) 4.343e-38 - [14C]H4 4.343e-38 4.350e-38 -37.362 -37.362 0.001 -[14C](4) 1.002e-16 - H[14C]O3- 8.094e-17 7.406e-17 -16.092 -16.130 -0.039 - [14C]O2 1.685e-17 1.688e-17 -16.773 -16.773 0.001 - CaH[14C]O3+ 1.710e-18 1.569e-18 -17.767 -17.804 -0.037 - H[14C]O2[18O]- 1.615e-19 1.478e-19 -18.792 -18.830 -0.039 - H[14C]O[18O]O- 1.615e-19 1.478e-19 -18.792 -18.830 -0.039 - H[14C][18O]O2- 1.615e-19 1.478e-19 -18.792 -18.830 -0.039 - Ca[14C]O3 9.372e-20 9.387e-20 -19.028 -19.027 0.001 - [14C]O[18O] 7.007e-20 7.019e-20 -19.154 -19.154 0.001 - [14C]O3-2 4.803e-20 3.367e-20 -19.318 -19.473 -0.154 - CaH[14C]O2[18O]+ 3.412e-21 3.130e-21 -20.467 -20.504 -0.037 - CaH[14C]O[18O]O+ 3.412e-21 3.130e-21 -20.467 -20.504 -0.037 - CaH[14C][18O]O2+ 3.412e-21 3.130e-21 -20.467 -20.504 -0.037 - Ca[14C]O2[18O] 5.610e-22 5.619e-22 -21.251 -21.250 0.001 - H[14C]O[18O]2- 3.222e-22 2.948e-22 -21.492 -21.530 -0.039 - H[14C][18O]2O- 3.222e-22 2.948e-22 -21.492 -21.530 -0.039 - H[14C][18O]O[18O]- 3.222e-22 2.948e-22 -21.492 -21.530 -0.039 - [14C]O2[18O]-2 2.875e-22 2.015e-22 -21.541 -21.696 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -65.991 -65.990 0.001 - [18O]2 0.000e+00 0.000e+00 -68.992 -68.991 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 2.567e-24 + CH4 2.567e-24 2.571e-24 -23.591 -23.590 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 8.037e-15 + H2 4.018e-15 4.025e-15 -14.396 -14.395 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -63.592 -63.591 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -65.991 -65.990 0.001 (0) +[13C](-4) 2.845e-26 + [13C]H4 2.845e-26 2.849e-26 -25.546 -25.545 0.001 (0) +[13C](4) 6.518e-05 + H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.596e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.590e-08 4.598e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 4.343e-38 + [14C]H4 4.343e-38 4.350e-38 -37.362 -37.362 0.001 (0) +[14C](4) 1.002e-16 + H[14C]O3- 8.094e-17 7.406e-17 -16.092 -16.130 -0.039 (0) + [14C]O2 1.685e-17 1.688e-17 -16.773 -16.773 0.001 (0) + CaH[14C]O3+ 1.710e-18 1.569e-18 -17.767 -17.804 -0.037 (0) + H[14C]O2[18O]- 1.615e-19 1.478e-19 -18.792 -18.830 -0.039 (0) + H[14C]O[18O]O- 1.615e-19 1.478e-19 -18.792 -18.830 -0.039 (0) + H[14C][18O]O2- 1.615e-19 1.478e-19 -18.792 -18.830 -0.039 (0) + Ca[14C]O3 9.372e-20 9.387e-20 -19.028 -19.027 0.001 (0) + [14C]O[18O] 7.007e-20 7.019e-20 -19.154 -19.154 0.001 (0) + [14C]O3-2 4.803e-20 3.367e-20 -19.318 -19.473 -0.154 (0) + CaH[14C]O2[18O]+ 3.412e-21 3.130e-21 -20.467 -20.504 -0.037 (0) + CaH[14C]O[18O]O+ 3.412e-21 3.130e-21 -20.467 -20.504 -0.037 (0) + CaH[14C][18O]O2+ 3.412e-21 3.130e-21 -20.467 -20.504 -0.037 (0) + Ca[14C]O2[18O] 5.610e-22 5.619e-22 -21.251 -21.250 0.001 (0) + H[14C]O[18O]2- 3.222e-22 2.948e-22 -21.492 -21.530 -0.039 (0) + H[14C][18O]2O- 3.222e-22 2.948e-22 -21.492 -21.530 -0.039 (0) + H[14C][18O]O[18O]- 3.222e-22 2.948e-22 -21.492 -21.530 -0.039 (0) + [14C]O2[18O]-2 2.875e-22 2.015e-22 -21.541 -21.696 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -65.991 -65.990 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -68.992 -68.991 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -14041,99 +14041,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 2.311e-24 - CH4 2.311e-24 2.315e-24 -23.636 -23.636 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 7.828e-15 - H2 3.914e-15 3.921e-15 -14.407 -14.407 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -63.569 -63.568 0.001 - O[18O] 0.000e+00 0.000e+00 -65.968 -65.967 0.001 -[13C](-4) 2.561e-26 - [13C]H4 2.561e-26 2.565e-26 -25.592 -25.591 0.001 -[13C](4) 6.518e-05 - H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.590e-08 4.598e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.883 -0.154 -[14C](-4) 3.601e-38 - [14C]H4 3.601e-38 3.607e-38 -37.444 -37.443 0.001 -[14C](4) 9.232e-17 - H[14C]O3- 7.457e-17 6.823e-17 -16.127 -16.166 -0.039 - [14C]O2 1.552e-17 1.555e-17 -16.809 -16.808 0.001 - CaH[14C]O3+ 1.575e-18 1.445e-18 -17.803 -17.840 -0.037 - H[14C]O2[18O]- 1.488e-19 1.361e-19 -18.827 -18.866 -0.039 - H[14C]O[18O]O- 1.488e-19 1.361e-19 -18.827 -18.866 -0.039 - H[14C][18O]O2- 1.488e-19 1.361e-19 -18.827 -18.866 -0.039 - Ca[14C]O3 8.633e-20 8.648e-20 -19.064 -19.063 0.001 - [14C]O[18O] 6.455e-20 6.466e-20 -19.190 -19.189 0.001 - [14C]O3-2 4.425e-20 3.102e-20 -19.354 -19.508 -0.154 - CaH[14C]O2[18O]+ 3.143e-21 2.883e-21 -20.503 -20.540 -0.037 - CaH[14C]O[18O]O+ 3.143e-21 2.883e-21 -20.503 -20.540 -0.037 - CaH[14C][18O]O2+ 3.143e-21 2.883e-21 -20.503 -20.540 -0.037 - Ca[14C]O2[18O] 5.168e-22 5.176e-22 -21.287 -21.286 0.001 - H[14C]O[18O]2- 2.968e-22 2.716e-22 -21.527 -21.566 -0.039 - H[14C][18O]2O- 2.968e-22 2.716e-22 -21.527 -21.566 -0.039 - H[14C][18O]O[18O]- 2.968e-22 2.716e-22 -21.527 -21.566 -0.039 - [14C]O2[18O]-2 2.649e-22 1.856e-22 -21.577 -21.731 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -65.968 -65.967 0.001 - [18O]2 0.000e+00 0.000e+00 -68.969 -68.969 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 2.311e-24 + CH4 2.311e-24 2.315e-24 -23.636 -23.636 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 7.828e-15 + H2 3.914e-15 3.921e-15 -14.407 -14.407 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -63.569 -63.568 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -65.968 -65.967 0.001 (0) +[13C](-4) 2.561e-26 + [13C]H4 2.561e-26 2.565e-26 -25.592 -25.591 0.001 (0) +[13C](4) 6.518e-05 + H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.590e-08 4.598e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 3.601e-38 + [14C]H4 3.601e-38 3.607e-38 -37.444 -37.443 0.001 (0) +[14C](4) 9.232e-17 + H[14C]O3- 7.457e-17 6.823e-17 -16.127 -16.166 -0.039 (0) + [14C]O2 1.552e-17 1.555e-17 -16.809 -16.808 0.001 (0) + CaH[14C]O3+ 1.575e-18 1.445e-18 -17.803 -17.840 -0.037 (0) + H[14C]O2[18O]- 1.488e-19 1.361e-19 -18.827 -18.866 -0.039 (0) + H[14C]O[18O]O- 1.488e-19 1.361e-19 -18.827 -18.866 -0.039 (0) + H[14C][18O]O2- 1.488e-19 1.361e-19 -18.827 -18.866 -0.039 (0) + Ca[14C]O3 8.633e-20 8.648e-20 -19.064 -19.063 0.001 (0) + [14C]O[18O] 6.455e-20 6.466e-20 -19.190 -19.189 0.001 (0) + [14C]O3-2 4.425e-20 3.102e-20 -19.354 -19.508 -0.154 (0) + CaH[14C]O2[18O]+ 3.143e-21 2.883e-21 -20.503 -20.540 -0.037 (0) + CaH[14C]O[18O]O+ 3.143e-21 2.883e-21 -20.503 -20.540 -0.037 (0) + CaH[14C][18O]O2+ 3.143e-21 2.883e-21 -20.503 -20.540 -0.037 (0) + Ca[14C]O2[18O] 5.168e-22 5.176e-22 -21.287 -21.286 0.001 (0) + H[14C]O[18O]2- 2.968e-22 2.716e-22 -21.527 -21.566 -0.039 (0) + H[14C][18O]2O- 2.968e-22 2.716e-22 -21.527 -21.566 -0.039 (0) + H[14C][18O]O[18O]- 2.968e-22 2.716e-22 -21.527 -21.566 -0.039 (0) + [14C]O2[18O]-2 2.649e-22 1.856e-22 -21.577 -21.731 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -65.968 -65.967 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -68.969 -68.969 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -14313,99 +14313,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.128 -123.127 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.049e-39 - H2 5.244e-40 5.252e-40 -39.280 -39.280 0.001 -O(0) 3.017e-14 - O2 1.502e-14 1.505e-14 -13.823 -13.822 0.001 - O[18O] 5.995e-17 6.005e-17 -16.222 -16.221 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.084 -125.083 0.001 -[13C](4) 6.518e-05 - H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.590e-08 4.598e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -136.971 -136.970 0.001 -[14C](4) 8.505e-17 - H[14C]O3- 6.869e-17 6.285e-17 -16.163 -16.202 -0.039 - [14C]O2 1.430e-17 1.432e-17 -16.845 -16.844 0.001 - CaH[14C]O3+ 1.451e-18 1.331e-18 -17.838 -17.876 -0.037 - H[14C]O2[18O]- 1.371e-19 1.254e-19 -18.863 -18.902 -0.039 - H[14C]O[18O]O- 1.371e-19 1.254e-19 -18.863 -18.902 -0.039 - H[14C][18O]O2- 1.371e-19 1.254e-19 -18.863 -18.902 -0.039 - Ca[14C]O3 7.953e-20 7.966e-20 -19.099 -19.099 0.001 - [14C]O[18O] 5.947e-20 5.956e-20 -19.226 -19.225 0.001 - [14C]O3-2 4.076e-20 2.857e-20 -19.390 -19.544 -0.154 - CaH[14C]O2[18O]+ 2.895e-21 2.656e-21 -20.538 -20.576 -0.037 - CaH[14C]O[18O]O+ 2.895e-21 2.656e-21 -20.538 -20.576 -0.037 - CaH[14C][18O]O2+ 2.895e-21 2.656e-21 -20.538 -20.576 -0.037 - Ca[14C]O2[18O] 4.761e-22 4.768e-22 -21.322 -21.322 0.001 - H[14C]O[18O]2- 2.735e-22 2.502e-22 -21.563 -21.602 -0.039 - H[14C][18O]2O- 2.735e-22 2.502e-22 -21.563 -21.602 -0.039 - H[14C][18O]O[18O]- 2.735e-22 2.502e-22 -21.563 -21.602 -0.039 - [14C]O2[18O]-2 2.440e-22 1.710e-22 -21.613 -21.767 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 6.007e-17 - O[18O] 5.995e-17 6.005e-17 -16.222 -16.221 0.001 - [18O]2 5.981e-20 5.991e-20 -19.223 -19.223 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.128 -123.127 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.049e-39 + H2 5.244e-40 5.252e-40 -39.280 -39.280 0.001 (0) +O(0) 3.017e-14 + O2 1.502e-14 1.505e-14 -13.823 -13.822 0.001 (0) + O[18O] 5.995e-17 6.005e-17 -16.222 -16.221 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.084 -125.083 0.001 (0) +[13C](4) 6.518e-05 + H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.590e-08 4.598e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -136.971 -136.970 0.001 (0) +[14C](4) 8.505e-17 + H[14C]O3- 6.869e-17 6.285e-17 -16.163 -16.202 -0.039 (0) + [14C]O2 1.430e-17 1.432e-17 -16.845 -16.844 0.001 (0) + CaH[14C]O3+ 1.451e-18 1.331e-18 -17.838 -17.876 -0.037 (0) + H[14C]O2[18O]- 1.371e-19 1.254e-19 -18.863 -18.902 -0.039 (0) + H[14C]O[18O]O- 1.371e-19 1.254e-19 -18.863 -18.902 -0.039 (0) + H[14C][18O]O2- 1.371e-19 1.254e-19 -18.863 -18.902 -0.039 (0) + Ca[14C]O3 7.953e-20 7.966e-20 -19.099 -19.099 0.001 (0) + [14C]O[18O] 5.947e-20 5.956e-20 -19.226 -19.225 0.001 (0) + [14C]O3-2 4.076e-20 2.857e-20 -19.390 -19.544 -0.154 (0) + CaH[14C]O2[18O]+ 2.895e-21 2.656e-21 -20.538 -20.576 -0.037 (0) + CaH[14C]O[18O]O+ 2.895e-21 2.656e-21 -20.538 -20.576 -0.037 (0) + CaH[14C][18O]O2+ 2.895e-21 2.656e-21 -20.538 -20.576 -0.037 (0) + Ca[14C]O2[18O] 4.761e-22 4.768e-22 -21.322 -21.322 0.001 (0) + H[14C]O[18O]2- 2.735e-22 2.502e-22 -21.563 -21.602 -0.039 (0) + H[14C][18O]2O- 2.735e-22 2.502e-22 -21.563 -21.602 -0.039 (0) + H[14C][18O]O[18O]- 2.735e-22 2.502e-22 -21.563 -21.602 -0.039 (0) + [14C]O2[18O]-2 2.440e-22 1.710e-22 -21.613 -21.767 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 6.007e-17 + O[18O] 5.995e-17 6.005e-17 -16.222 -16.221 0.001 (0) + [18O]2 5.981e-20 5.991e-20 -19.223 -19.223 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -14585,99 +14585,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -122.948 -122.947 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.163e-39 - H2 5.817e-40 5.827e-40 -39.235 -39.235 0.001 -O(0) 2.451e-14 - O2 1.221e-14 1.223e-14 -13.913 -13.913 0.001 - O[18O] 4.872e-17 4.880e-17 -16.312 -16.312 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -124.903 -124.903 0.001 -[13C](4) 6.518e-05 - H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.110e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.590e-08 4.598e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -136.827 -136.826 0.001 -[14C](4) 7.835e-17 - H[14C]O3- 6.328e-17 5.790e-17 -16.199 -16.237 -0.039 - [14C]O2 1.317e-17 1.320e-17 -16.880 -16.880 0.001 - CaH[14C]O3+ 1.337e-18 1.226e-18 -17.874 -17.911 -0.037 - H[14C]O2[18O]- 1.263e-19 1.155e-19 -18.899 -18.937 -0.039 - H[14C]O[18O]O- 1.263e-19 1.155e-19 -18.899 -18.937 -0.039 - H[14C][18O]O2- 1.263e-19 1.155e-19 -18.899 -18.937 -0.039 - Ca[14C]O3 7.327e-20 7.339e-20 -19.135 -19.134 0.001 - [14C]O[18O] 5.478e-20 5.487e-20 -19.261 -19.261 0.001 - [14C]O3-2 3.755e-20 2.632e-20 -19.425 -19.580 -0.154 - CaH[14C]O2[18O]+ 2.667e-21 2.447e-21 -20.574 -20.611 -0.037 - CaH[14C]O[18O]O+ 2.667e-21 2.447e-21 -20.574 -20.611 -0.037 - CaH[14C][18O]O2+ 2.667e-21 2.447e-21 -20.574 -20.611 -0.037 - Ca[14C]O2[18O] 4.386e-22 4.393e-22 -21.358 -21.357 0.001 - H[14C]O[18O]2- 2.519e-22 2.305e-22 -21.599 -21.637 -0.039 - H[14C][18O]2O- 2.519e-22 2.305e-22 -21.599 -21.637 -0.039 - H[14C][18O]O[18O]- 2.519e-22 2.305e-22 -21.599 -21.637 -0.039 - [14C]O2[18O]-2 2.248e-22 1.575e-22 -21.648 -21.803 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 4.881e-17 - O[18O] 4.872e-17 4.880e-17 -16.312 -16.312 0.001 - [18O]2 4.860e-20 4.868e-20 -19.313 -19.313 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -122.948 -122.947 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.163e-39 + H2 5.817e-40 5.827e-40 -39.235 -39.235 0.001 (0) +O(0) 2.451e-14 + O2 1.221e-14 1.223e-14 -13.913 -13.913 0.001 (0) + O[18O] 4.872e-17 4.880e-17 -16.312 -16.312 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -124.903 -124.903 0.001 (0) +[13C](4) 6.518e-05 + H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.110e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.590e-08 4.598e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -136.827 -136.826 0.001 (0) +[14C](4) 7.835e-17 + H[14C]O3- 6.328e-17 5.790e-17 -16.199 -16.237 -0.039 (0) + [14C]O2 1.317e-17 1.320e-17 -16.880 -16.880 0.001 (0) + CaH[14C]O3+ 1.337e-18 1.226e-18 -17.874 -17.911 -0.037 (0) + H[14C]O2[18O]- 1.263e-19 1.155e-19 -18.899 -18.937 -0.039 (0) + H[14C]O[18O]O- 1.263e-19 1.155e-19 -18.899 -18.937 -0.039 (0) + H[14C][18O]O2- 1.263e-19 1.155e-19 -18.899 -18.937 -0.039 (0) + Ca[14C]O3 7.327e-20 7.339e-20 -19.135 -19.134 0.001 (0) + [14C]O[18O] 5.478e-20 5.487e-20 -19.261 -19.261 0.001 (0) + [14C]O3-2 3.755e-20 2.632e-20 -19.425 -19.580 -0.154 (0) + CaH[14C]O2[18O]+ 2.667e-21 2.447e-21 -20.574 -20.611 -0.037 (0) + CaH[14C]O[18O]O+ 2.667e-21 2.447e-21 -20.574 -20.611 -0.037 (0) + CaH[14C][18O]O2+ 2.667e-21 2.447e-21 -20.574 -20.611 -0.037 (0) + Ca[14C]O2[18O] 4.386e-22 4.393e-22 -21.358 -21.357 0.001 (0) + H[14C]O[18O]2- 2.519e-22 2.305e-22 -21.599 -21.637 -0.039 (0) + H[14C][18O]2O- 2.519e-22 2.305e-22 -21.599 -21.637 -0.039 (0) + H[14C][18O]O[18O]- 2.519e-22 2.305e-22 -21.599 -21.637 -0.039 (0) + [14C]O2[18O]-2 2.248e-22 1.575e-22 -21.648 -21.803 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 4.881e-17 + O[18O] 4.872e-17 4.880e-17 -16.312 -16.312 0.001 (0) + [18O]2 4.860e-20 4.868e-20 -19.313 -19.313 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -14857,99 +14857,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -121.824 -121.823 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 2.222e-39 - H2 1.111e-39 1.113e-39 -38.954 -38.954 0.001 -O(0) 6.722e-15 - O2 3.348e-15 3.353e-15 -14.475 -14.475 0.001 - O[18O] 1.336e-17 1.338e-17 -16.874 -16.874 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -123.780 -123.779 0.001 -[13C](4) 6.518e-05 - H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.590e-08 4.598e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -135.738 -135.738 0.001 -[14C](4) 7.218e-17 - H[14C]O3- 5.830e-17 5.334e-17 -16.234 -16.273 -0.039 - [14C]O2 1.214e-17 1.216e-17 -16.916 -16.915 0.001 - CaH[14C]O3+ 1.231e-18 1.130e-18 -17.910 -17.947 -0.037 - H[14C]O2[18O]- 1.163e-19 1.064e-19 -18.934 -18.973 -0.039 - H[14C]O[18O]O- 1.163e-19 1.064e-19 -18.934 -18.973 -0.039 - H[14C][18O]O2- 1.163e-19 1.064e-19 -18.934 -18.973 -0.039 - Ca[14C]O3 6.750e-20 6.761e-20 -19.171 -19.170 0.001 - [14C]O[18O] 5.047e-20 5.055e-20 -19.297 -19.296 0.001 - [14C]O3-2 3.459e-20 2.425e-20 -19.461 -19.615 -0.154 - CaH[14C]O2[18O]+ 2.457e-21 2.254e-21 -20.610 -20.647 -0.037 - CaH[14C]O[18O]O+ 2.457e-21 2.254e-21 -20.610 -20.647 -0.037 - CaH[14C][18O]O2+ 2.457e-21 2.254e-21 -20.610 -20.647 -0.037 - Ca[14C]O2[18O] 4.040e-22 4.047e-22 -21.394 -21.393 0.001 - H[14C]O[18O]2- 2.321e-22 2.123e-22 -21.634 -21.673 -0.039 - H[14C][18O]2O- 2.321e-22 2.123e-22 -21.634 -21.673 -0.039 - H[14C][18O]O[18O]- 2.321e-22 2.123e-22 -21.634 -21.673 -0.039 - [14C]O2[18O]-2 2.071e-22 1.451e-22 -21.684 -21.838 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 1.339e-17 - O[18O] 1.336e-17 1.338e-17 -16.874 -16.874 0.001 - [18O]2 1.333e-20 1.335e-20 -19.875 -19.875 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -121.824 -121.823 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 2.222e-39 + H2 1.111e-39 1.113e-39 -38.954 -38.954 0.001 (0) +O(0) 6.722e-15 + O2 3.348e-15 3.353e-15 -14.475 -14.475 0.001 (0) + O[18O] 1.336e-17 1.338e-17 -16.874 -16.874 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -123.780 -123.779 0.001 (0) +[13C](4) 6.518e-05 + H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.590e-08 4.598e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -135.738 -135.738 0.001 (0) +[14C](4) 7.218e-17 + H[14C]O3- 5.830e-17 5.334e-17 -16.234 -16.273 -0.039 (0) + [14C]O2 1.214e-17 1.216e-17 -16.916 -16.915 0.001 (0) + CaH[14C]O3+ 1.231e-18 1.130e-18 -17.910 -17.947 -0.037 (0) + H[14C]O2[18O]- 1.163e-19 1.064e-19 -18.934 -18.973 -0.039 (0) + H[14C]O[18O]O- 1.163e-19 1.064e-19 -18.934 -18.973 -0.039 (0) + H[14C][18O]O2- 1.163e-19 1.064e-19 -18.934 -18.973 -0.039 (0) + Ca[14C]O3 6.750e-20 6.761e-20 -19.171 -19.170 0.001 (0) + [14C]O[18O] 5.047e-20 5.055e-20 -19.297 -19.296 0.001 (0) + [14C]O3-2 3.459e-20 2.425e-20 -19.461 -19.615 -0.154 (0) + CaH[14C]O2[18O]+ 2.457e-21 2.254e-21 -20.610 -20.647 -0.037 (0) + CaH[14C]O[18O]O+ 2.457e-21 2.254e-21 -20.610 -20.647 -0.037 (0) + CaH[14C][18O]O2+ 2.457e-21 2.254e-21 -20.610 -20.647 -0.037 (0) + Ca[14C]O2[18O] 4.040e-22 4.047e-22 -21.394 -21.393 0.001 (0) + H[14C]O[18O]2- 2.321e-22 2.123e-22 -21.634 -21.673 -0.039 (0) + H[14C][18O]2O- 2.321e-22 2.123e-22 -21.634 -21.673 -0.039 (0) + H[14C][18O]O[18O]- 2.321e-22 2.123e-22 -21.634 -21.673 -0.039 (0) + [14C]O2[18O]-2 2.071e-22 1.451e-22 -21.684 -21.838 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 1.339e-17 + O[18O] 1.336e-17 1.338e-17 -16.874 -16.874 0.001 (0) + [18O]2 1.333e-20 1.335e-20 -19.875 -19.875 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -15129,99 +15129,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.529 -123.528 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 8.329e-40 - H2 4.164e-40 4.171e-40 -39.380 -39.380 0.001 -O(0) 4.784e-14 - O2 2.382e-14 2.386e-14 -13.623 -13.622 0.001 - O[18O] 9.507e-17 9.522e-17 -16.022 -16.021 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.484 -125.483 0.001 -[13C](4) 6.518e-05 - H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.598e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -137.478 -137.478 0.001 -[14C](4) 6.649e-17 - H[14C]O3- 5.370e-17 4.914e-17 -16.270 -16.309 -0.039 - [14C]O2 1.118e-17 1.120e-17 -16.952 -16.951 0.001 - CaH[14C]O3+ 1.134e-18 1.041e-18 -17.945 -17.983 -0.037 - H[14C]O2[18O]- 1.072e-19 9.804e-20 -18.970 -19.009 -0.039 - H[14C]O[18O]O- 1.072e-19 9.804e-20 -18.970 -19.009 -0.039 - H[14C][18O]O2- 1.072e-19 9.804e-20 -18.970 -19.009 -0.039 - Ca[14C]O3 6.218e-20 6.228e-20 -19.206 -19.206 0.001 - [14C]O[18O] 4.649e-20 4.657e-20 -19.333 -19.332 0.001 - [14C]O3-2 3.187e-20 2.234e-20 -19.497 -19.651 -0.154 - CaH[14C]O2[18O]+ 2.263e-21 2.077e-21 -20.645 -20.683 -0.037 - CaH[14C]O[18O]O+ 2.263e-21 2.077e-21 -20.645 -20.683 -0.037 - CaH[14C][18O]O2+ 2.263e-21 2.077e-21 -20.645 -20.683 -0.037 - Ca[14C]O2[18O] 3.722e-22 3.728e-22 -21.429 -21.429 0.001 - H[14C]O[18O]2- 2.138e-22 1.956e-22 -21.670 -21.709 -0.039 - H[14C][18O]2O- 2.138e-22 1.956e-22 -21.670 -21.709 -0.039 - H[14C][18O]O[18O]- 2.138e-22 1.956e-22 -21.670 -21.709 -0.039 - [14C]O2[18O]-2 1.908e-22 1.337e-22 -21.720 -21.874 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 9.526e-17 - O[18O] 9.507e-17 9.522e-17 -16.022 -16.021 0.001 - [18O]2 9.484e-20 9.499e-20 -19.023 -19.022 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.529 -123.528 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 8.329e-40 + H2 4.164e-40 4.171e-40 -39.380 -39.380 0.001 (0) +O(0) 4.784e-14 + O2 2.382e-14 2.386e-14 -13.623 -13.622 0.001 (0) + O[18O] 9.507e-17 9.522e-17 -16.022 -16.021 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.484 -125.483 0.001 (0) +[13C](4) 6.518e-05 + H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.597e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.095e-08 6.105e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.598e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.648e-10 3.654e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -137.478 -137.478 0.001 (0) +[14C](4) 6.649e-17 + H[14C]O3- 5.370e-17 4.914e-17 -16.270 -16.309 -0.039 (0) + [14C]O2 1.118e-17 1.120e-17 -16.952 -16.951 0.001 (0) + CaH[14C]O3+ 1.134e-18 1.041e-18 -17.945 -17.983 -0.037 (0) + H[14C]O2[18O]- 1.072e-19 9.804e-20 -18.970 -19.009 -0.039 (0) + H[14C]O[18O]O- 1.072e-19 9.804e-20 -18.970 -19.009 -0.039 (0) + H[14C][18O]O2- 1.072e-19 9.804e-20 -18.970 -19.009 -0.039 (0) + Ca[14C]O3 6.218e-20 6.228e-20 -19.206 -19.206 0.001 (0) + [14C]O[18O] 4.649e-20 4.657e-20 -19.333 -19.332 0.001 (0) + [14C]O3-2 3.187e-20 2.234e-20 -19.497 -19.651 -0.154 (0) + CaH[14C]O2[18O]+ 2.263e-21 2.077e-21 -20.645 -20.683 -0.037 (0) + CaH[14C]O[18O]O+ 2.263e-21 2.077e-21 -20.645 -20.683 -0.037 (0) + CaH[14C][18O]O2+ 2.263e-21 2.077e-21 -20.645 -20.683 -0.037 (0) + Ca[14C]O2[18O] 3.722e-22 3.728e-22 -21.429 -21.429 0.001 (0) + H[14C]O[18O]2- 2.138e-22 1.956e-22 -21.670 -21.709 -0.039 (0) + H[14C][18O]2O- 2.138e-22 1.956e-22 -21.670 -21.709 -0.039 (0) + H[14C][18O]O[18O]- 2.138e-22 1.956e-22 -21.670 -21.709 -0.039 (0) + [14C]O2[18O]-2 1.908e-22 1.337e-22 -21.720 -21.874 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 9.526e-17 + O[18O] 9.507e-17 9.522e-17 -16.022 -16.021 0.001 (0) + [18O]2 9.484e-20 9.499e-20 -19.023 -19.022 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -15401,99 +15401,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.557 -123.556 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 8.194e-40 - H2 4.097e-40 4.104e-40 -39.388 -39.387 0.001 -O(0) 4.942e-14 - O2 2.461e-14 2.465e-14 -13.609 -13.608 0.001 - O[18O] 9.822e-17 9.838e-17 -16.008 -16.007 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.512 -125.512 0.001 -[13C](4) 6.518e-05 - H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.598e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -137.542 -137.542 0.001 -[14C](4) 6.125e-17 - H[14C]O3- 4.947e-17 4.527e-17 -16.306 -16.344 -0.039 - [14C]O2 1.030e-17 1.032e-17 -16.987 -16.986 0.001 - CaH[14C]O3+ 1.045e-18 9.588e-19 -17.981 -18.018 -0.037 - H[14C]O2[18O]- 9.871e-20 9.032e-20 -19.006 -19.044 -0.039 - H[14C]O[18O]O- 9.871e-20 9.032e-20 -19.006 -19.044 -0.039 - H[14C][18O]O2- 9.871e-20 9.032e-20 -19.006 -19.044 -0.039 - Ca[14C]O3 5.728e-20 5.737e-20 -19.242 -19.241 0.001 - [14C]O[18O] 4.283e-20 4.290e-20 -19.368 -19.368 0.001 - [14C]O3-2 2.936e-20 2.058e-20 -19.532 -19.687 -0.154 - CaH[14C]O2[18O]+ 2.085e-21 1.913e-21 -20.681 -20.718 -0.037 - CaH[14C]O[18O]O+ 2.085e-21 1.913e-21 -20.681 -20.718 -0.037 - CaH[14C][18O]O2+ 2.085e-21 1.913e-21 -20.681 -20.718 -0.037 - Ca[14C]O2[18O] 3.429e-22 3.434e-22 -21.465 -21.464 0.001 - H[14C]O[18O]2- 1.969e-22 1.802e-22 -21.706 -21.744 -0.039 - H[14C][18O]2O- 1.969e-22 1.802e-22 -21.706 -21.744 -0.039 - H[14C][18O]O[18O]- 1.969e-22 1.802e-22 -21.706 -21.744 -0.039 - [14C]O2[18O]-2 1.757e-22 1.232e-22 -21.755 -21.909 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 9.841e-17 - O[18O] 9.822e-17 9.838e-17 -16.008 -16.007 0.001 - [18O]2 9.798e-20 9.814e-20 -19.009 -19.008 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.557 -123.556 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 8.194e-40 + H2 4.097e-40 4.104e-40 -39.388 -39.387 0.001 (0) +O(0) 4.942e-14 + O2 2.461e-14 2.465e-14 -13.609 -13.608 0.001 (0) + O[18O] 9.822e-17 9.838e-17 -16.008 -16.007 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.512 -125.512 0.001 (0) +[13C](4) 6.518e-05 + H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.598e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -137.542 -137.542 0.001 (0) +[14C](4) 6.125e-17 + H[14C]O3- 4.947e-17 4.527e-17 -16.306 -16.344 -0.039 (0) + [14C]O2 1.030e-17 1.032e-17 -16.987 -16.986 0.001 (0) + CaH[14C]O3+ 1.045e-18 9.588e-19 -17.981 -18.018 -0.037 (0) + H[14C]O2[18O]- 9.871e-20 9.032e-20 -19.006 -19.044 -0.039 (0) + H[14C]O[18O]O- 9.871e-20 9.032e-20 -19.006 -19.044 -0.039 (0) + H[14C][18O]O2- 9.871e-20 9.032e-20 -19.006 -19.044 -0.039 (0) + Ca[14C]O3 5.728e-20 5.737e-20 -19.242 -19.241 0.001 (0) + [14C]O[18O] 4.283e-20 4.290e-20 -19.368 -19.368 0.001 (0) + [14C]O3-2 2.936e-20 2.058e-20 -19.532 -19.687 -0.154 (0) + CaH[14C]O2[18O]+ 2.085e-21 1.913e-21 -20.681 -20.718 -0.037 (0) + CaH[14C]O[18O]O+ 2.085e-21 1.913e-21 -20.681 -20.718 -0.037 (0) + CaH[14C][18O]O2+ 2.085e-21 1.913e-21 -20.681 -20.718 -0.037 (0) + Ca[14C]O2[18O] 3.429e-22 3.434e-22 -21.465 -21.464 0.001 (0) + H[14C]O[18O]2- 1.969e-22 1.802e-22 -21.706 -21.744 -0.039 (0) + H[14C][18O]2O- 1.969e-22 1.802e-22 -21.706 -21.744 -0.039 (0) + H[14C][18O]O[18O]- 1.969e-22 1.802e-22 -21.706 -21.744 -0.039 (0) + [14C]O2[18O]-2 1.757e-22 1.232e-22 -21.755 -21.909 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 9.841e-17 + O[18O] 9.822e-17 9.838e-17 -16.008 -16.007 0.001 (0) + [18O]2 9.798e-20 9.814e-20 -19.009 -19.008 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -15673,99 +15673,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.060 -123.060 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.091e-39 - H2 5.453e-40 5.462e-40 -39.263 -39.263 0.001 -O(0) 2.790e-14 - O2 1.390e-14 1.392e-14 -13.857 -13.856 0.001 - O[18O] 5.545e-17 5.554e-17 -16.256 -16.255 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.016 -125.015 0.001 -[13C](4) 6.518e-05 - H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.598e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -137.082 -137.081 0.001 -[14C](4) 5.643e-17 - H[14C]O3- 4.558e-17 4.170e-17 -16.341 -16.380 -0.039 - [14C]O2 9.488e-18 9.504e-18 -17.023 -17.022 0.001 - CaH[14C]O3+ 9.628e-19 8.833e-19 -18.016 -18.054 -0.037 - H[14C]O2[18O]- 9.093e-20 8.320e-20 -19.041 -19.080 -0.039 - H[14C]O[18O]O- 9.093e-20 8.320e-20 -19.041 -19.080 -0.039 - H[14C][18O]O2- 9.093e-20 8.320e-20 -19.041 -19.080 -0.039 - Ca[14C]O3 5.277e-20 5.286e-20 -19.278 -19.277 0.001 - [14C]O[18O] 3.945e-20 3.952e-20 -19.404 -19.403 0.001 - [14C]O3-2 2.705e-20 1.896e-20 -19.568 -19.722 -0.154 - CaH[14C]O2[18O]+ 1.921e-21 1.762e-21 -20.716 -20.754 -0.037 - CaH[14C]O[18O]O+ 1.921e-21 1.762e-21 -20.716 -20.754 -0.037 - CaH[14C][18O]O2+ 1.921e-21 1.762e-21 -20.716 -20.754 -0.037 - Ca[14C]O2[18O] 3.158e-22 3.164e-22 -21.501 -21.500 0.001 - H[14C]O[18O]2- 1.814e-22 1.660e-22 -21.741 -21.780 -0.039 - H[14C][18O]2O- 1.814e-22 1.660e-22 -21.741 -21.780 -0.039 - H[14C][18O]O[18O]- 1.814e-22 1.660e-22 -21.741 -21.780 -0.039 - [14C]O2[18O]-2 1.619e-22 1.135e-22 -21.791 -21.945 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 5.556e-17 - O[18O] 5.545e-17 5.554e-17 -16.256 -16.255 0.001 - [18O]2 5.532e-20 5.541e-20 -19.257 -19.256 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.060 -123.060 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.091e-39 + H2 5.453e-40 5.462e-40 -39.263 -39.263 0.001 (0) +O(0) 2.790e-14 + O2 1.390e-14 1.392e-14 -13.857 -13.856 0.001 (0) + O[18O] 5.545e-17 5.554e-17 -16.256 -16.255 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.016 -125.015 0.001 (0) +[13C](4) 6.518e-05 + H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.598e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -137.082 -137.081 0.001 (0) +[14C](4) 5.643e-17 + H[14C]O3- 4.558e-17 4.170e-17 -16.341 -16.380 -0.039 (0) + [14C]O2 9.488e-18 9.504e-18 -17.023 -17.022 0.001 (0) + CaH[14C]O3+ 9.628e-19 8.833e-19 -18.016 -18.054 -0.037 (0) + H[14C]O2[18O]- 9.093e-20 8.320e-20 -19.041 -19.080 -0.039 (0) + H[14C]O[18O]O- 9.093e-20 8.320e-20 -19.041 -19.080 -0.039 (0) + H[14C][18O]O2- 9.093e-20 8.320e-20 -19.041 -19.080 -0.039 (0) + Ca[14C]O3 5.277e-20 5.286e-20 -19.278 -19.277 0.001 (0) + [14C]O[18O] 3.945e-20 3.952e-20 -19.404 -19.403 0.001 (0) + [14C]O3-2 2.705e-20 1.896e-20 -19.568 -19.722 -0.154 (0) + CaH[14C]O2[18O]+ 1.921e-21 1.762e-21 -20.716 -20.754 -0.037 (0) + CaH[14C]O[18O]O+ 1.921e-21 1.762e-21 -20.716 -20.754 -0.037 (0) + CaH[14C][18O]O2+ 1.921e-21 1.762e-21 -20.716 -20.754 -0.037 (0) + Ca[14C]O2[18O] 3.158e-22 3.164e-22 -21.501 -21.500 0.001 (0) + H[14C]O[18O]2- 1.814e-22 1.660e-22 -21.741 -21.780 -0.039 (0) + H[14C][18O]2O- 1.814e-22 1.660e-22 -21.741 -21.780 -0.039 (0) + H[14C][18O]O[18O]- 1.814e-22 1.660e-22 -21.741 -21.780 -0.039 (0) + [14C]O2[18O]-2 1.619e-22 1.135e-22 -21.791 -21.945 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 5.556e-17 + O[18O] 5.545e-17 5.554e-17 -16.256 -16.255 0.001 (0) + [18O]2 5.532e-20 5.541e-20 -19.257 -19.256 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -15945,99 +15945,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -119.775 -119.775 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 7.226e-39 - H2 3.613e-39 3.619e-39 -38.442 -38.441 0.001 -O(0) 6.354e-16 - O2 3.165e-16 3.170e-16 -15.500 -15.499 0.001 - O[18O] 1.263e-18 1.265e-18 -17.899 -17.898 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -121.731 -121.730 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.598e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -133.832 -133.831 0.001 -[14C](4) 5.198e-17 - H[14C]O3- 4.199e-17 3.842e-17 -16.377 -16.415 -0.039 - [14C]O2 8.741e-18 8.755e-18 -17.058 -17.058 0.001 - CaH[14C]O3+ 8.869e-19 8.137e-19 -18.052 -18.090 -0.037 - H[14C]O2[18O]- 8.377e-20 7.665e-20 -19.077 -19.115 -0.039 - H[14C]O[18O]O- 8.377e-20 7.665e-20 -19.077 -19.115 -0.039 - H[14C][18O]O2- 8.377e-20 7.665e-20 -19.077 -19.115 -0.039 - Ca[14C]O3 4.861e-20 4.869e-20 -19.313 -19.313 0.001 - [14C]O[18O] 3.635e-20 3.641e-20 -19.440 -19.439 0.001 - [14C]O3-2 2.492e-20 1.746e-20 -19.604 -19.758 -0.154 - CaH[14C]O2[18O]+ 1.770e-21 1.623e-21 -20.752 -20.790 -0.037 - CaH[14C]O[18O]O+ 1.770e-21 1.623e-21 -20.752 -20.790 -0.037 - CaH[14C][18O]O2+ 1.770e-21 1.623e-21 -20.752 -20.790 -0.037 - Ca[14C]O2[18O] 2.910e-22 2.914e-22 -21.536 -21.535 0.001 - H[14C]O[18O]2- 1.671e-22 1.529e-22 -21.777 -21.816 -0.039 - H[14C][18O]2O- 1.671e-22 1.529e-22 -21.777 -21.816 -0.039 - H[14C][18O]O[18O]- 1.671e-22 1.529e-22 -21.777 -21.816 -0.039 - [14C]O2[18O]-2 1.491e-22 1.045e-22 -21.826 -21.981 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 1.265e-18 - O[18O] 1.263e-18 1.265e-18 -17.899 -17.898 0.001 - [18O]2 1.260e-21 1.262e-21 -20.900 -20.899 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -119.775 -119.775 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 7.226e-39 + H2 3.613e-39 3.619e-39 -38.442 -38.441 0.001 (0) +O(0) 6.354e-16 + O2 3.165e-16 3.170e-16 -15.500 -15.499 0.001 (0) + O[18O] 1.263e-18 1.265e-18 -17.899 -17.898 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -121.731 -121.730 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.257e-05 4.810e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.598e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -133.832 -133.831 0.001 (0) +[14C](4) 5.198e-17 + H[14C]O3- 4.199e-17 3.842e-17 -16.377 -16.415 -0.039 (0) + [14C]O2 8.741e-18 8.755e-18 -17.058 -17.058 0.001 (0) + CaH[14C]O3+ 8.869e-19 8.137e-19 -18.052 -18.090 -0.037 (0) + H[14C]O2[18O]- 8.377e-20 7.665e-20 -19.077 -19.115 -0.039 (0) + H[14C]O[18O]O- 8.377e-20 7.665e-20 -19.077 -19.115 -0.039 (0) + H[14C][18O]O2- 8.377e-20 7.665e-20 -19.077 -19.115 -0.039 (0) + Ca[14C]O3 4.861e-20 4.869e-20 -19.313 -19.313 0.001 (0) + [14C]O[18O] 3.635e-20 3.641e-20 -19.440 -19.439 0.001 (0) + [14C]O3-2 2.492e-20 1.746e-20 -19.604 -19.758 -0.154 (0) + CaH[14C]O2[18O]+ 1.770e-21 1.623e-21 -20.752 -20.790 -0.037 (0) + CaH[14C]O[18O]O+ 1.770e-21 1.623e-21 -20.752 -20.790 -0.037 (0) + CaH[14C][18O]O2+ 1.770e-21 1.623e-21 -20.752 -20.790 -0.037 (0) + Ca[14C]O2[18O] 2.910e-22 2.914e-22 -21.536 -21.535 0.001 (0) + H[14C]O[18O]2- 1.671e-22 1.529e-22 -21.777 -21.816 -0.039 (0) + H[14C][18O]2O- 1.671e-22 1.529e-22 -21.777 -21.816 -0.039 (0) + H[14C][18O]O[18O]- 1.671e-22 1.529e-22 -21.777 -21.816 -0.039 (0) + [14C]O2[18O]-2 1.491e-22 1.045e-22 -21.826 -21.981 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 1.265e-18 + O[18O] 1.263e-18 1.265e-18 -17.899 -17.898 0.001 (0) + [18O]2 1.260e-21 1.262e-21 -20.900 -20.899 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -16217,99 +16217,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.087 -123.086 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.074e-39 - H2 5.371e-40 5.379e-40 -39.270 -39.269 0.001 -O(0) 2.876e-14 - O2 1.432e-14 1.435e-14 -13.844 -13.843 0.001 - O[18O] 5.716e-17 5.725e-17 -16.243 -16.242 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.042 -125.041 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.257e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.598e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -137.179 -137.178 0.001 -[14C](4) 4.789e-17 - H[14C]O3- 3.868e-17 3.539e-17 -16.413 -16.451 -0.039 - [14C]O2 8.052e-18 8.065e-18 -17.094 -17.093 0.001 - CaH[14C]O3+ 8.171e-19 7.496e-19 -18.088 -18.125 -0.037 - H[14C]O2[18O]- 7.717e-20 7.061e-20 -19.113 -19.151 -0.039 - H[14C]O[18O]O- 7.717e-20 7.061e-20 -19.113 -19.151 -0.039 - H[14C][18O]O2- 7.717e-20 7.061e-20 -19.113 -19.151 -0.039 - Ca[14C]O3 4.478e-20 4.486e-20 -19.349 -19.348 0.001 - [14C]O[18O] 3.348e-20 3.354e-20 -19.475 -19.474 0.001 - [14C]O3-2 2.295e-20 1.609e-20 -19.639 -19.794 -0.154 - CaH[14C]O2[18O]+ 1.630e-21 1.496e-21 -20.788 -20.825 -0.037 - CaH[14C]O[18O]O+ 1.630e-21 1.496e-21 -20.788 -20.825 -0.037 - CaH[14C][18O]O2+ 1.630e-21 1.496e-21 -20.788 -20.825 -0.037 - Ca[14C]O2[18O] 2.680e-22 2.685e-22 -21.572 -21.571 0.001 - H[14C]O[18O]2- 1.540e-22 1.409e-22 -21.813 -21.851 -0.039 - H[14C][18O]2O- 1.540e-22 1.409e-22 -21.813 -21.851 -0.039 - H[14C][18O]O[18O]- 1.540e-22 1.409e-22 -21.813 -21.851 -0.039 - [14C]O2[18O]-2 1.374e-22 9.629e-23 -21.862 -22.016 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 5.727e-17 - O[18O] 5.716e-17 5.725e-17 -16.243 -16.242 0.001 - [18O]2 5.702e-20 5.711e-20 -19.244 -19.243 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.087 -123.086 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.074e-39 + H2 5.371e-40 5.379e-40 -39.270 -39.269 0.001 (0) +O(0) 2.876e-14 + O2 1.432e-14 1.435e-14 -13.844 -13.843 0.001 (0) + O[18O] 5.716e-17 5.725e-17 -16.243 -16.242 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.042 -125.041 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.257e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.598e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -137.179 -137.178 0.001 (0) +[14C](4) 4.789e-17 + H[14C]O3- 3.868e-17 3.539e-17 -16.413 -16.451 -0.039 (0) + [14C]O2 8.052e-18 8.065e-18 -17.094 -17.093 0.001 (0) + CaH[14C]O3+ 8.171e-19 7.496e-19 -18.088 -18.125 -0.037 (0) + H[14C]O2[18O]- 7.717e-20 7.061e-20 -19.113 -19.151 -0.039 (0) + H[14C]O[18O]O- 7.717e-20 7.061e-20 -19.113 -19.151 -0.039 (0) + H[14C][18O]O2- 7.717e-20 7.061e-20 -19.113 -19.151 -0.039 (0) + Ca[14C]O3 4.478e-20 4.486e-20 -19.349 -19.348 0.001 (0) + [14C]O[18O] 3.348e-20 3.354e-20 -19.475 -19.474 0.001 (0) + [14C]O3-2 2.295e-20 1.609e-20 -19.639 -19.794 -0.154 (0) + CaH[14C]O2[18O]+ 1.630e-21 1.496e-21 -20.788 -20.825 -0.037 (0) + CaH[14C]O[18O]O+ 1.630e-21 1.496e-21 -20.788 -20.825 -0.037 (0) + CaH[14C][18O]O2+ 1.630e-21 1.496e-21 -20.788 -20.825 -0.037 (0) + Ca[14C]O2[18O] 2.680e-22 2.685e-22 -21.572 -21.571 0.001 (0) + H[14C]O[18O]2- 1.540e-22 1.409e-22 -21.813 -21.851 -0.039 (0) + H[14C][18O]2O- 1.540e-22 1.409e-22 -21.813 -21.851 -0.039 (0) + H[14C][18O]O[18O]- 1.540e-22 1.409e-22 -21.813 -21.851 -0.039 (0) + [14C]O2[18O]-2 1.374e-22 9.629e-23 -21.862 -22.016 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 5.727e-17 + O[18O] 5.716e-17 5.725e-17 -16.243 -16.242 0.001 (0) + [18O]2 5.702e-20 5.711e-20 -19.244 -19.243 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -16489,99 +16489,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.164 -123.164 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.027e-39 - H2 5.136e-40 5.145e-40 -39.289 -39.289 0.001 -O(0) 3.145e-14 - O2 1.566e-14 1.569e-14 -13.805 -13.804 0.001 - O[18O] 6.249e-17 6.260e-17 -16.204 -16.203 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.120 -125.119 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.598e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -137.292 -137.292 0.001 -[14C](4) 4.411e-17 - H[14C]O3- 3.563e-17 3.260e-17 -16.448 -16.487 -0.039 - [14C]O2 7.418e-18 7.430e-18 -17.130 -17.129 0.001 - CaH[14C]O3+ 7.527e-19 6.906e-19 -18.123 -18.161 -0.037 - H[14C]O2[18O]- 7.109e-20 6.505e-20 -19.148 -19.187 -0.039 - H[14C]O[18O]O- 7.109e-20 6.505e-20 -19.148 -19.187 -0.039 - H[14C][18O]O2- 7.109e-20 6.505e-20 -19.148 -19.187 -0.039 - Ca[14C]O3 4.125e-20 4.132e-20 -19.385 -19.384 0.001 - [14C]O[18O] 3.085e-20 3.090e-20 -19.511 -19.510 0.001 - [14C]O3-2 2.114e-20 1.482e-20 -19.675 -19.829 -0.154 - CaH[14C]O2[18O]+ 1.502e-21 1.378e-21 -20.823 -20.861 -0.037 - CaH[14C]O[18O]O+ 1.502e-21 1.378e-21 -20.823 -20.861 -0.037 - CaH[14C][18O]O2+ 1.502e-21 1.378e-21 -20.823 -20.861 -0.037 - Ca[14C]O2[18O] 2.469e-22 2.473e-22 -21.607 -21.607 0.001 - H[14C]O[18O]2- 1.418e-22 1.298e-22 -21.848 -21.887 -0.039 - H[14C][18O]2O- 1.418e-22 1.298e-22 -21.848 -21.887 -0.039 - H[14C][18O]O[18O]- 1.418e-22 1.298e-22 -21.848 -21.887 -0.039 - [14C]O2[18O]-2 1.266e-22 8.871e-23 -21.898 -22.052 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 6.262e-17 - O[18O] 6.249e-17 6.260e-17 -16.204 -16.203 0.001 - [18O]2 6.234e-20 6.245e-20 -19.205 -19.204 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.164 -123.164 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.027e-39 + H2 5.136e-40 5.145e-40 -39.289 -39.289 0.001 (0) +O(0) 3.145e-14 + O2 1.566e-14 1.569e-14 -13.805 -13.804 0.001 (0) + O[18O] 6.249e-17 6.260e-17 -16.204 -16.203 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.120 -125.119 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.598e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -137.292 -137.292 0.001 (0) +[14C](4) 4.411e-17 + H[14C]O3- 3.563e-17 3.260e-17 -16.448 -16.487 -0.039 (0) + [14C]O2 7.418e-18 7.430e-18 -17.130 -17.129 0.001 (0) + CaH[14C]O3+ 7.527e-19 6.906e-19 -18.123 -18.161 -0.037 (0) + H[14C]O2[18O]- 7.109e-20 6.505e-20 -19.148 -19.187 -0.039 (0) + H[14C]O[18O]O- 7.109e-20 6.505e-20 -19.148 -19.187 -0.039 (0) + H[14C][18O]O2- 7.109e-20 6.505e-20 -19.148 -19.187 -0.039 (0) + Ca[14C]O3 4.125e-20 4.132e-20 -19.385 -19.384 0.001 (0) + [14C]O[18O] 3.085e-20 3.090e-20 -19.511 -19.510 0.001 (0) + [14C]O3-2 2.114e-20 1.482e-20 -19.675 -19.829 -0.154 (0) + CaH[14C]O2[18O]+ 1.502e-21 1.378e-21 -20.823 -20.861 -0.037 (0) + CaH[14C]O[18O]O+ 1.502e-21 1.378e-21 -20.823 -20.861 -0.037 (0) + CaH[14C][18O]O2+ 1.502e-21 1.378e-21 -20.823 -20.861 -0.037 (0) + Ca[14C]O2[18O] 2.469e-22 2.473e-22 -21.607 -21.607 0.001 (0) + H[14C]O[18O]2- 1.418e-22 1.298e-22 -21.848 -21.887 -0.039 (0) + H[14C][18O]2O- 1.418e-22 1.298e-22 -21.848 -21.887 -0.039 (0) + H[14C][18O]O[18O]- 1.418e-22 1.298e-22 -21.848 -21.887 -0.039 (0) + [14C]O2[18O]-2 1.266e-22 8.871e-23 -21.898 -22.052 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 6.262e-17 + O[18O] 6.249e-17 6.260e-17 -16.204 -16.203 0.001 (0) + [18O]2 6.234e-20 6.245e-20 -19.205 -19.204 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -16761,99 +16761,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.082 -123.081 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.077e-39 - H2 5.386e-40 5.395e-40 -39.269 -39.268 0.001 -O(0) 2.860e-14 - O2 1.424e-14 1.427e-14 -13.846 -13.846 0.001 - O[18O] 5.683e-17 5.692e-17 -16.245 -16.245 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.037 -125.036 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.598e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -137.245 -137.245 0.001 -[14C](4) 4.064e-17 - H[14C]O3- 3.282e-17 3.003e-17 -16.484 -16.522 -0.039 - [14C]O2 6.833e-18 6.845e-18 -17.165 -17.165 0.001 - CaH[14C]O3+ 6.934e-19 6.362e-19 -18.159 -18.196 -0.037 - H[14C]O2[18O]- 6.549e-20 5.992e-20 -19.184 -19.222 -0.039 - H[14C]O[18O]O- 6.549e-20 5.992e-20 -19.184 -19.222 -0.039 - H[14C][18O]O2- 6.549e-20 5.992e-20 -19.184 -19.222 -0.039 - Ca[14C]O3 3.800e-20 3.807e-20 -19.420 -19.419 0.001 - [14C]O[18O] 2.842e-20 2.846e-20 -19.546 -19.546 0.001 - [14C]O3-2 1.948e-20 1.365e-20 -19.710 -19.865 -0.154 - CaH[14C]O2[18O]+ 1.383e-21 1.269e-21 -20.859 -20.896 -0.037 - CaH[14C]O[18O]O+ 1.383e-21 1.269e-21 -20.859 -20.896 -0.037 - CaH[14C][18O]O2+ 1.383e-21 1.269e-21 -20.859 -20.896 -0.037 - Ca[14C]O2[18O] 2.275e-22 2.279e-22 -21.643 -21.642 0.001 - H[14C]O[18O]2- 1.307e-22 1.196e-22 -21.884 -21.922 -0.039 - H[14C][18O]2O- 1.307e-22 1.196e-22 -21.884 -21.922 -0.039 - H[14C][18O]O[18O]- 1.307e-22 1.196e-22 -21.884 -21.922 -0.039 - [14C]O2[18O]-2 1.166e-22 8.172e-23 -21.933 -22.088 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 5.694e-17 - O[18O] 5.683e-17 5.692e-17 -16.245 -16.245 0.001 - [18O]2 5.669e-20 5.679e-20 -19.246 -19.246 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.082 -123.081 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.077e-39 + H2 5.386e-40 5.395e-40 -39.269 -39.268 0.001 (0) +O(0) 2.860e-14 + O2 1.424e-14 1.427e-14 -13.846 -13.846 0.001 (0) + O[18O] 5.683e-17 5.692e-17 -16.245 -16.245 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.037 -125.036 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.598e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -137.245 -137.245 0.001 (0) +[14C](4) 4.064e-17 + H[14C]O3- 3.282e-17 3.003e-17 -16.484 -16.522 -0.039 (0) + [14C]O2 6.833e-18 6.845e-18 -17.165 -17.165 0.001 (0) + CaH[14C]O3+ 6.934e-19 6.362e-19 -18.159 -18.196 -0.037 (0) + H[14C]O2[18O]- 6.549e-20 5.992e-20 -19.184 -19.222 -0.039 (0) + H[14C]O[18O]O- 6.549e-20 5.992e-20 -19.184 -19.222 -0.039 (0) + H[14C][18O]O2- 6.549e-20 5.992e-20 -19.184 -19.222 -0.039 (0) + Ca[14C]O3 3.800e-20 3.807e-20 -19.420 -19.419 0.001 (0) + [14C]O[18O] 2.842e-20 2.846e-20 -19.546 -19.546 0.001 (0) + [14C]O3-2 1.948e-20 1.365e-20 -19.710 -19.865 -0.154 (0) + CaH[14C]O2[18O]+ 1.383e-21 1.269e-21 -20.859 -20.896 -0.037 (0) + CaH[14C]O[18O]O+ 1.383e-21 1.269e-21 -20.859 -20.896 -0.037 (0) + CaH[14C][18O]O2+ 1.383e-21 1.269e-21 -20.859 -20.896 -0.037 (0) + Ca[14C]O2[18O] 2.275e-22 2.279e-22 -21.643 -21.642 0.001 (0) + H[14C]O[18O]2- 1.307e-22 1.196e-22 -21.884 -21.922 -0.039 (0) + H[14C][18O]2O- 1.307e-22 1.196e-22 -21.884 -21.922 -0.039 (0) + H[14C][18O]O[18O]- 1.307e-22 1.196e-22 -21.884 -21.922 -0.039 (0) + [14C]O2[18O]-2 1.166e-22 8.172e-23 -21.933 -22.088 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 5.694e-17 + O[18O] 5.683e-17 5.692e-17 -16.245 -16.245 0.001 (0) + [18O]2 5.669e-20 5.679e-20 -19.246 -19.246 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -17033,99 +17033,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.380 -123.379 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 9.074e-40 - H2 4.537e-40 4.544e-40 -39.343 -39.343 0.001 -O(0) 4.030e-14 - O2 2.007e-14 2.011e-14 -13.697 -13.697 0.001 - O[18O] 8.010e-17 8.023e-17 -16.096 -16.096 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.335 -125.334 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.598e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -137.579 -137.578 0.001 -[14C](4) 3.744e-17 - H[14C]O3- 3.024e-17 2.767e-17 -16.519 -16.558 -0.039 - [14C]O2 6.295e-18 6.305e-18 -17.201 -17.200 0.001 - CaH[14C]O3+ 6.388e-19 5.860e-19 -18.195 -18.232 -0.037 - H[14C]O2[18O]- 6.033e-20 5.520e-20 -19.219 -19.258 -0.039 - H[14C]O[18O]O- 6.033e-20 5.520e-20 -19.219 -19.258 -0.039 - H[14C][18O]O2- 6.033e-20 5.520e-20 -19.219 -19.258 -0.039 - Ca[14C]O3 3.501e-20 3.507e-20 -19.456 -19.455 0.001 - [14C]O[18O] 2.618e-20 2.622e-20 -19.582 -19.581 0.001 - [14C]O3-2 1.794e-20 1.258e-20 -19.746 -19.900 -0.154 - CaH[14C]O2[18O]+ 1.274e-21 1.169e-21 -20.895 -20.932 -0.037 - CaH[14C]O[18O]O+ 1.274e-21 1.169e-21 -20.895 -20.932 -0.037 - CaH[14C][18O]O2+ 1.274e-21 1.169e-21 -20.895 -20.932 -0.037 - Ca[14C]O2[18O] 2.096e-22 2.099e-22 -21.679 -21.678 0.001 - H[14C]O[18O]2- 1.204e-22 1.101e-22 -21.919 -21.958 -0.039 - H[14C][18O]2O- 1.204e-22 1.101e-22 -21.919 -21.958 -0.039 - H[14C][18O]O[18O]- 1.204e-22 1.101e-22 -21.919 -21.958 -0.039 - [14C]O2[18O]-2 1.074e-22 7.528e-23 -21.969 -22.123 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 8.025e-17 - O[18O] 8.010e-17 8.023e-17 -16.096 -16.096 0.001 - [18O]2 7.990e-20 8.003e-20 -19.097 -19.097 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.380 -123.379 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 9.074e-40 + H2 4.537e-40 4.544e-40 -39.343 -39.343 0.001 (0) +O(0) 4.030e-14 + O2 2.007e-14 2.011e-14 -13.697 -13.697 0.001 (0) + O[18O] 8.010e-17 8.023e-17 -16.096 -16.096 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.335 -125.334 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.598e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -137.579 -137.578 0.001 (0) +[14C](4) 3.744e-17 + H[14C]O3- 3.024e-17 2.767e-17 -16.519 -16.558 -0.039 (0) + [14C]O2 6.295e-18 6.305e-18 -17.201 -17.200 0.001 (0) + CaH[14C]O3+ 6.388e-19 5.860e-19 -18.195 -18.232 -0.037 (0) + H[14C]O2[18O]- 6.033e-20 5.520e-20 -19.219 -19.258 -0.039 (0) + H[14C]O[18O]O- 6.033e-20 5.520e-20 -19.219 -19.258 -0.039 (0) + H[14C][18O]O2- 6.033e-20 5.520e-20 -19.219 -19.258 -0.039 (0) + Ca[14C]O3 3.501e-20 3.507e-20 -19.456 -19.455 0.001 (0) + [14C]O[18O] 2.618e-20 2.622e-20 -19.582 -19.581 0.001 (0) + [14C]O3-2 1.794e-20 1.258e-20 -19.746 -19.900 -0.154 (0) + CaH[14C]O2[18O]+ 1.274e-21 1.169e-21 -20.895 -20.932 -0.037 (0) + CaH[14C]O[18O]O+ 1.274e-21 1.169e-21 -20.895 -20.932 -0.037 (0) + CaH[14C][18O]O2+ 1.274e-21 1.169e-21 -20.895 -20.932 -0.037 (0) + Ca[14C]O2[18O] 2.096e-22 2.099e-22 -21.679 -21.678 0.001 (0) + H[14C]O[18O]2- 1.204e-22 1.101e-22 -21.919 -21.958 -0.039 (0) + H[14C][18O]2O- 1.204e-22 1.101e-22 -21.919 -21.958 -0.039 (0) + H[14C][18O]O[18O]- 1.204e-22 1.101e-22 -21.919 -21.958 -0.039 (0) + [14C]O2[18O]-2 1.074e-22 7.528e-23 -21.969 -22.123 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 8.025e-17 + O[18O] 8.010e-17 8.023e-17 -16.096 -16.096 0.001 (0) + [18O]2 7.990e-20 8.003e-20 -19.097 -19.097 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -17305,99 +17305,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -122.648 -122.648 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.382e-39 - H2 6.912e-40 6.924e-40 -39.160 -39.160 0.001 -O(0) 1.736e-14 - O2 8.647e-15 8.661e-15 -14.063 -14.062 0.001 - O[18O] 3.450e-17 3.456e-17 -16.462 -16.461 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -124.604 -124.603 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -136.883 -136.883 0.001 -[14C](4) 3.449e-17 - H[14C]O3- 2.786e-17 2.549e-17 -16.555 -16.594 -0.039 - [14C]O2 5.799e-18 5.809e-18 -17.237 -17.236 0.001 - CaH[14C]O3+ 5.885e-19 5.399e-19 -18.230 -18.268 -0.037 - H[14C]O2[18O]- 5.558e-20 5.086e-20 -19.255 -19.294 -0.039 - H[14C]O[18O]O- 5.558e-20 5.086e-20 -19.255 -19.294 -0.039 - H[14C][18O]O2- 5.558e-20 5.086e-20 -19.255 -19.294 -0.039 - Ca[14C]O3 3.225e-20 3.231e-20 -19.491 -19.491 0.001 - [14C]O[18O] 2.411e-20 2.415e-20 -19.618 -19.617 0.001 - [14C]O3-2 1.653e-20 1.159e-20 -19.782 -19.936 -0.154 - CaH[14C]O2[18O]+ 1.174e-21 1.077e-21 -20.930 -20.968 -0.037 - CaH[14C]O[18O]O+ 1.174e-21 1.077e-21 -20.930 -20.968 -0.037 - CaH[14C][18O]O2+ 1.174e-21 1.077e-21 -20.930 -20.968 -0.037 - Ca[14C]O2[18O] 1.931e-22 1.934e-22 -21.714 -21.714 0.001 - H[14C]O[18O]2- 1.109e-22 1.015e-22 -21.955 -21.994 -0.039 - H[14C][18O]2O- 1.109e-22 1.015e-22 -21.955 -21.994 -0.039 - H[14C][18O]O[18O]- 1.109e-22 1.015e-22 -21.955 -21.994 -0.039 - [14C]O2[18O]-2 9.895e-23 6.935e-23 -22.005 -22.159 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.457e-17 - O[18O] 3.450e-17 3.456e-17 -16.462 -16.461 0.001 - [18O]2 3.442e-20 3.448e-20 -19.463 -19.462 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -122.648 -122.648 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.382e-39 + H2 6.912e-40 6.924e-40 -39.160 -39.160 0.001 (0) +O(0) 1.736e-14 + O2 8.647e-15 8.661e-15 -14.063 -14.062 0.001 (0) + O[18O] 3.450e-17 3.456e-17 -16.462 -16.461 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -124.604 -124.603 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -136.883 -136.883 0.001 (0) +[14C](4) 3.449e-17 + H[14C]O3- 2.786e-17 2.549e-17 -16.555 -16.594 -0.039 (0) + [14C]O2 5.799e-18 5.809e-18 -17.237 -17.236 0.001 (0) + CaH[14C]O3+ 5.885e-19 5.399e-19 -18.230 -18.268 -0.037 (0) + H[14C]O2[18O]- 5.558e-20 5.086e-20 -19.255 -19.294 -0.039 (0) + H[14C]O[18O]O- 5.558e-20 5.086e-20 -19.255 -19.294 -0.039 (0) + H[14C][18O]O2- 5.558e-20 5.086e-20 -19.255 -19.294 -0.039 (0) + Ca[14C]O3 3.225e-20 3.231e-20 -19.491 -19.491 0.001 (0) + [14C]O[18O] 2.411e-20 2.415e-20 -19.618 -19.617 0.001 (0) + [14C]O3-2 1.653e-20 1.159e-20 -19.782 -19.936 -0.154 (0) + CaH[14C]O2[18O]+ 1.174e-21 1.077e-21 -20.930 -20.968 -0.037 (0) + CaH[14C]O[18O]O+ 1.174e-21 1.077e-21 -20.930 -20.968 -0.037 (0) + CaH[14C][18O]O2+ 1.174e-21 1.077e-21 -20.930 -20.968 -0.037 (0) + Ca[14C]O2[18O] 1.931e-22 1.934e-22 -21.714 -21.714 0.001 (0) + H[14C]O[18O]2- 1.109e-22 1.015e-22 -21.955 -21.994 -0.039 (0) + H[14C][18O]2O- 1.109e-22 1.015e-22 -21.955 -21.994 -0.039 (0) + H[14C][18O]O[18O]- 1.109e-22 1.015e-22 -21.955 -21.994 -0.039 (0) + [14C]O2[18O]-2 9.895e-23 6.935e-23 -22.005 -22.159 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.457e-17 + O[18O] 3.450e-17 3.456e-17 -16.462 -16.461 0.001 (0) + [18O]2 3.442e-20 3.448e-20 -19.463 -19.462 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -17577,99 +17577,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.472 -123.471 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 8.604e-40 - H2 4.302e-40 4.309e-40 -39.366 -39.366 0.001 -O(0) 4.482e-14 - O2 2.232e-14 2.236e-14 -13.651 -13.651 0.001 - O[18O] 8.908e-17 8.922e-17 -16.050 -16.050 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.427 -125.427 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -137.743 -137.742 0.001 -[14C](4) 3.177e-17 - H[14C]O3- 2.566e-17 2.348e-17 -16.591 -16.629 -0.039 - [14C]O2 5.342e-18 5.351e-18 -17.272 -17.272 0.001 - CaH[14C]O3+ 5.421e-19 4.973e-19 -18.266 -18.303 -0.037 - H[14C]O2[18O]- 5.120e-20 4.685e-20 -19.291 -19.329 -0.039 - H[14C]O[18O]O- 5.120e-20 4.685e-20 -19.291 -19.329 -0.039 - H[14C][18O]O2- 5.120e-20 4.685e-20 -19.291 -19.329 -0.039 - Ca[14C]O3 2.971e-20 2.976e-20 -19.527 -19.526 0.001 - [14C]O[18O] 2.222e-20 2.225e-20 -19.653 -19.653 0.001 - [14C]O3-2 1.523e-20 1.067e-20 -19.817 -19.972 -0.154 - CaH[14C]O2[18O]+ 1.082e-21 9.923e-22 -20.966 -21.003 -0.037 - CaH[14C]O[18O]O+ 1.082e-21 9.923e-22 -20.966 -21.003 -0.037 - CaH[14C][18O]O2+ 1.082e-21 9.923e-22 -20.966 -21.003 -0.037 - Ca[14C]O2[18O] 1.778e-22 1.781e-22 -21.750 -21.749 0.001 - H[14C]O[18O]2- 1.022e-22 9.347e-23 -21.991 -22.029 -0.039 - H[14C][18O]2O- 1.022e-22 9.347e-23 -21.991 -22.029 -0.039 - H[14C][18O]O[18O]- 1.022e-22 9.347e-23 -21.991 -22.029 -0.039 - [14C]O2[18O]-2 9.115e-23 6.389e-23 -22.040 -22.195 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 8.926e-17 - O[18O] 8.908e-17 8.922e-17 -16.050 -16.050 0.001 - [18O]2 8.886e-20 8.901e-20 -19.051 -19.051 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.472 -123.471 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 8.604e-40 + H2 4.302e-40 4.309e-40 -39.366 -39.366 0.001 (0) +O(0) 4.482e-14 + O2 2.232e-14 2.236e-14 -13.651 -13.651 0.001 (0) + O[18O] 8.908e-17 8.922e-17 -16.050 -16.050 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.427 -125.427 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.598e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.124e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -137.743 -137.742 0.001 (0) +[14C](4) 3.177e-17 + H[14C]O3- 2.566e-17 2.348e-17 -16.591 -16.629 -0.039 (0) + [14C]O2 5.342e-18 5.351e-18 -17.272 -17.272 0.001 (0) + CaH[14C]O3+ 5.421e-19 4.973e-19 -18.266 -18.303 -0.037 (0) + H[14C]O2[18O]- 5.120e-20 4.685e-20 -19.291 -19.329 -0.039 (0) + H[14C]O[18O]O- 5.120e-20 4.685e-20 -19.291 -19.329 -0.039 (0) + H[14C][18O]O2- 5.120e-20 4.685e-20 -19.291 -19.329 -0.039 (0) + Ca[14C]O3 2.971e-20 2.976e-20 -19.527 -19.526 0.001 (0) + [14C]O[18O] 2.222e-20 2.225e-20 -19.653 -19.653 0.001 (0) + [14C]O3-2 1.523e-20 1.067e-20 -19.817 -19.972 -0.154 (0) + CaH[14C]O2[18O]+ 1.082e-21 9.923e-22 -20.966 -21.003 -0.037 (0) + CaH[14C]O[18O]O+ 1.082e-21 9.923e-22 -20.966 -21.003 -0.037 (0) + CaH[14C][18O]O2+ 1.082e-21 9.923e-22 -20.966 -21.003 -0.037 (0) + Ca[14C]O2[18O] 1.778e-22 1.781e-22 -21.750 -21.749 0.001 (0) + H[14C]O[18O]2- 1.022e-22 9.347e-23 -21.991 -22.029 -0.039 (0) + H[14C][18O]2O- 1.022e-22 9.347e-23 -21.991 -22.029 -0.039 (0) + H[14C][18O]O[18O]- 1.022e-22 9.347e-23 -21.991 -22.029 -0.039 (0) + [14C]O2[18O]-2 9.115e-23 6.389e-23 -22.040 -22.195 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 8.926e-17 + O[18O] 8.908e-17 8.922e-17 -16.050 -16.050 0.001 (0) + [18O]2 8.886e-20 8.901e-20 -19.051 -19.051 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -17849,99 +17849,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.162 -123.161 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.029e-39 - H2 5.144e-40 5.153e-40 -39.289 -39.288 0.001 -O(0) 3.135e-14 - O2 1.561e-14 1.564e-14 -13.807 -13.806 0.001 - O[18O] 6.230e-17 6.240e-17 -16.206 -16.205 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.117 -125.116 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -137.468 -137.467 0.001 -[14C](4) 2.927e-17 - H[14C]O3- 2.364e-17 2.163e-17 -16.626 -16.665 -0.039 - [14C]O2 4.921e-18 4.930e-18 -17.308 -17.307 0.001 - CaH[14C]O3+ 4.994e-19 4.582e-19 -18.302 -18.339 -0.037 - H[14C]O2[18O]- 4.717e-20 4.316e-20 -19.326 -19.365 -0.039 - H[14C]O[18O]O- 4.717e-20 4.316e-20 -19.326 -19.365 -0.039 - H[14C][18O]O2- 4.717e-20 4.316e-20 -19.326 -19.365 -0.039 - Ca[14C]O3 2.737e-20 2.742e-20 -19.563 -19.562 0.001 - [14C]O[18O] 2.046e-20 2.050e-20 -19.689 -19.688 0.001 - [14C]O3-2 1.403e-20 9.833e-21 -19.853 -20.007 -0.154 - CaH[14C]O2[18O]+ 9.964e-22 9.141e-22 -21.002 -21.039 -0.037 - CaH[14C]O[18O]O+ 9.964e-22 9.141e-22 -21.002 -21.039 -0.037 - CaH[14C][18O]O2+ 9.964e-22 9.141e-22 -21.002 -21.039 -0.037 - Ca[14C]O2[18O] 1.638e-22 1.641e-22 -21.786 -21.785 0.001 - H[14C]O[18O]2- 9.411e-23 8.611e-23 -22.026 -22.065 -0.039 - H[14C][18O]2O- 9.411e-23 8.611e-23 -22.026 -22.065 -0.039 - H[14C][18O]O[18O]- 9.411e-23 8.611e-23 -22.026 -22.065 -0.039 - [14C]O2[18O]-2 8.397e-23 5.886e-23 -22.076 -22.230 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 6.242e-17 - O[18O] 6.230e-17 6.240e-17 -16.206 -16.205 0.001 - [18O]2 6.215e-20 6.225e-20 -19.207 -19.206 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.162 -123.161 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.029e-39 + H2 5.144e-40 5.153e-40 -39.289 -39.288 0.001 (0) +O(0) 3.135e-14 + O2 1.561e-14 1.564e-14 -13.807 -13.806 0.001 (0) + O[18O] 6.230e-17 6.240e-17 -16.206 -16.205 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.117 -125.116 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -137.468 -137.467 0.001 (0) +[14C](4) 2.927e-17 + H[14C]O3- 2.364e-17 2.163e-17 -16.626 -16.665 -0.039 (0) + [14C]O2 4.921e-18 4.930e-18 -17.308 -17.307 0.001 (0) + CaH[14C]O3+ 4.994e-19 4.582e-19 -18.302 -18.339 -0.037 (0) + H[14C]O2[18O]- 4.717e-20 4.316e-20 -19.326 -19.365 -0.039 (0) + H[14C]O[18O]O- 4.717e-20 4.316e-20 -19.326 -19.365 -0.039 (0) + H[14C][18O]O2- 4.717e-20 4.316e-20 -19.326 -19.365 -0.039 (0) + Ca[14C]O3 2.737e-20 2.742e-20 -19.563 -19.562 0.001 (0) + [14C]O[18O] 2.046e-20 2.050e-20 -19.689 -19.688 0.001 (0) + [14C]O3-2 1.403e-20 9.833e-21 -19.853 -20.007 -0.154 (0) + CaH[14C]O2[18O]+ 9.964e-22 9.141e-22 -21.002 -21.039 -0.037 (0) + CaH[14C]O[18O]O+ 9.964e-22 9.141e-22 -21.002 -21.039 -0.037 (0) + CaH[14C][18O]O2+ 9.964e-22 9.141e-22 -21.002 -21.039 -0.037 (0) + Ca[14C]O2[18O] 1.638e-22 1.641e-22 -21.786 -21.785 0.001 (0) + H[14C]O[18O]2- 9.411e-23 8.611e-23 -22.026 -22.065 -0.039 (0) + H[14C][18O]2O- 9.411e-23 8.611e-23 -22.026 -22.065 -0.039 (0) + H[14C][18O]O[18O]- 9.411e-23 8.611e-23 -22.026 -22.065 -0.039 (0) + [14C]O2[18O]-2 8.397e-23 5.886e-23 -22.076 -22.230 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 6.242e-17 + O[18O] 6.230e-17 6.240e-17 -16.206 -16.205 0.001 (0) + [18O]2 6.215e-20 6.225e-20 -19.207 -19.206 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -18121,99 +18121,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.777 -123.777 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 7.218e-40 - H2 3.609e-40 3.615e-40 -39.443 -39.442 0.001 -O(0) 6.370e-14 - O2 3.172e-14 3.178e-14 -13.499 -13.498 0.001 - O[18O] 1.266e-16 1.268e-16 -15.898 -15.897 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.733 -125.732 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -138.119 -138.118 0.001 -[14C](4) 2.696e-17 - H[14C]O3- 2.178e-17 1.993e-17 -16.662 -16.701 -0.039 - [14C]O2 4.534e-18 4.541e-18 -17.344 -17.343 0.001 - CaH[14C]O3+ 4.601e-19 4.221e-19 -18.337 -18.375 -0.037 - H[14C]O2[18O]- 4.345e-20 3.976e-20 -19.362 -19.401 -0.039 - H[14C]O[18O]O- 4.345e-20 3.976e-20 -19.362 -19.401 -0.039 - H[14C][18O]O2- 4.345e-20 3.976e-20 -19.362 -19.401 -0.039 - Ca[14C]O3 2.522e-20 2.526e-20 -19.598 -19.598 0.001 - [14C]O[18O] 1.885e-20 1.888e-20 -19.725 -19.724 0.001 - [14C]O3-2 1.292e-20 9.058e-21 -19.889 -20.043 -0.154 - CaH[14C]O2[18O]+ 9.179e-22 8.421e-22 -21.037 -21.075 -0.037 - CaH[14C]O[18O]O+ 9.179e-22 8.421e-22 -21.037 -21.075 -0.037 - CaH[14C][18O]O2+ 9.179e-22 8.421e-22 -21.037 -21.075 -0.037 - Ca[14C]O2[18O] 1.509e-22 1.512e-22 -21.821 -21.821 0.001 - H[14C]O[18O]2- 8.670e-23 7.933e-23 -22.062 -22.101 -0.039 - H[14C][18O]2O- 8.670e-23 7.933e-23 -22.062 -22.101 -0.039 - H[14C][18O]O[18O]- 8.670e-23 7.933e-23 -22.062 -22.101 -0.039 - [14C]O2[18O]-2 7.736e-23 5.422e-23 -22.112 -22.266 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 1.268e-16 - O[18O] 1.266e-16 1.268e-16 -15.898 -15.897 0.001 - [18O]2 1.263e-19 1.265e-19 -18.899 -18.898 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.777 -123.777 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 7.218e-40 + H2 3.609e-40 3.615e-40 -39.443 -39.442 0.001 (0) +O(0) 6.370e-14 + O2 3.172e-14 3.178e-14 -13.499 -13.498 0.001 (0) + O[18O] 1.266e-16 1.268e-16 -15.898 -15.897 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.733 -125.732 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -138.119 -138.118 0.001 (0) +[14C](4) 2.696e-17 + H[14C]O3- 2.178e-17 1.993e-17 -16.662 -16.701 -0.039 (0) + [14C]O2 4.534e-18 4.541e-18 -17.344 -17.343 0.001 (0) + CaH[14C]O3+ 4.601e-19 4.221e-19 -18.337 -18.375 -0.037 (0) + H[14C]O2[18O]- 4.345e-20 3.976e-20 -19.362 -19.401 -0.039 (0) + H[14C]O[18O]O- 4.345e-20 3.976e-20 -19.362 -19.401 -0.039 (0) + H[14C][18O]O2- 4.345e-20 3.976e-20 -19.362 -19.401 -0.039 (0) + Ca[14C]O3 2.522e-20 2.526e-20 -19.598 -19.598 0.001 (0) + [14C]O[18O] 1.885e-20 1.888e-20 -19.725 -19.724 0.001 (0) + [14C]O3-2 1.292e-20 9.058e-21 -19.889 -20.043 -0.154 (0) + CaH[14C]O2[18O]+ 9.179e-22 8.421e-22 -21.037 -21.075 -0.037 (0) + CaH[14C]O[18O]O+ 9.179e-22 8.421e-22 -21.037 -21.075 -0.037 (0) + CaH[14C][18O]O2+ 9.179e-22 8.421e-22 -21.037 -21.075 -0.037 (0) + Ca[14C]O2[18O] 1.509e-22 1.512e-22 -21.821 -21.821 0.001 (0) + H[14C]O[18O]2- 8.670e-23 7.933e-23 -22.062 -22.101 -0.039 (0) + H[14C][18O]2O- 8.670e-23 7.933e-23 -22.062 -22.101 -0.039 (0) + H[14C][18O]O[18O]- 8.670e-23 7.933e-23 -22.062 -22.101 -0.039 (0) + [14C]O2[18O]-2 7.736e-23 5.422e-23 -22.112 -22.266 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 1.268e-16 + O[18O] 1.266e-16 1.268e-16 -15.898 -15.897 0.001 (0) + [18O]2 1.263e-19 1.265e-19 -18.899 -18.898 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -18393,99 +18393,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.584 -123.584 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 8.066e-40 - H2 4.033e-40 4.039e-40 -39.394 -39.394 0.001 -O(0) 5.101e-14 - O2 2.540e-14 2.545e-14 -13.595 -13.594 0.001 - O[18O] 1.014e-16 1.015e-16 -15.994 -15.993 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.540 -125.539 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -137.962 -137.961 0.001 -[14C](4) 2.484e-17 - H[14C]O3- 2.006e-17 1.836e-17 -16.698 -16.736 -0.039 - [14C]O2 4.177e-18 4.183e-18 -17.379 -17.378 0.001 - CaH[14C]O3+ 4.238e-19 3.888e-19 -18.373 -18.410 -0.037 - H[14C]O2[18O]- 4.003e-20 3.663e-20 -19.398 -19.436 -0.039 - H[14C]O[18O]O- 4.003e-20 3.663e-20 -19.398 -19.436 -0.039 - H[14C][18O]O2- 4.003e-20 3.663e-20 -19.398 -19.436 -0.039 - Ca[14C]O3 2.323e-20 2.327e-20 -19.634 -19.633 0.001 - [14C]O[18O] 1.737e-20 1.740e-20 -19.760 -19.760 0.001 - [14C]O3-2 1.191e-20 8.345e-21 -19.924 -20.079 -0.154 - CaH[14C]O2[18O]+ 8.456e-22 7.758e-22 -21.073 -21.110 -0.037 - CaH[14C]O[18O]O+ 8.456e-22 7.758e-22 -21.073 -21.110 -0.037 - CaH[14C][18O]O2+ 8.456e-22 7.758e-22 -21.073 -21.110 -0.037 - Ca[14C]O2[18O] 1.390e-22 1.393e-22 -21.857 -21.856 0.001 - H[14C]O[18O]2- 7.987e-23 7.308e-23 -22.098 -22.136 -0.039 - H[14C][18O]2O- 7.987e-23 7.308e-23 -22.098 -22.136 -0.039 - H[14C][18O]O[18O]- 7.987e-23 7.308e-23 -22.098 -22.136 -0.039 - [14C]O2[18O]-2 7.126e-23 4.995e-23 -22.147 -22.301 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 1.016e-16 - O[18O] 1.014e-16 1.015e-16 -15.994 -15.993 0.001 - [18O]2 1.011e-19 1.013e-19 -18.995 -18.994 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.584 -123.584 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 8.066e-40 + H2 4.033e-40 4.039e-40 -39.394 -39.394 0.001 (0) +O(0) 5.101e-14 + O2 2.540e-14 2.545e-14 -13.595 -13.594 0.001 (0) + O[18O] 1.014e-16 1.015e-16 -15.994 -15.993 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.540 -125.539 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -137.962 -137.961 0.001 (0) +[14C](4) 2.484e-17 + H[14C]O3- 2.006e-17 1.836e-17 -16.698 -16.736 -0.039 (0) + [14C]O2 4.177e-18 4.183e-18 -17.379 -17.378 0.001 (0) + CaH[14C]O3+ 4.238e-19 3.888e-19 -18.373 -18.410 -0.037 (0) + H[14C]O2[18O]- 4.003e-20 3.663e-20 -19.398 -19.436 -0.039 (0) + H[14C]O[18O]O- 4.003e-20 3.663e-20 -19.398 -19.436 -0.039 (0) + H[14C][18O]O2- 4.003e-20 3.663e-20 -19.398 -19.436 -0.039 (0) + Ca[14C]O3 2.323e-20 2.327e-20 -19.634 -19.633 0.001 (0) + [14C]O[18O] 1.737e-20 1.740e-20 -19.760 -19.760 0.001 (0) + [14C]O3-2 1.191e-20 8.345e-21 -19.924 -20.079 -0.154 (0) + CaH[14C]O2[18O]+ 8.456e-22 7.758e-22 -21.073 -21.110 -0.037 (0) + CaH[14C]O[18O]O+ 8.456e-22 7.758e-22 -21.073 -21.110 -0.037 (0) + CaH[14C][18O]O2+ 8.456e-22 7.758e-22 -21.073 -21.110 -0.037 (0) + Ca[14C]O2[18O] 1.390e-22 1.393e-22 -21.857 -21.856 0.001 (0) + H[14C]O[18O]2- 7.987e-23 7.308e-23 -22.098 -22.136 -0.039 (0) + H[14C][18O]2O- 7.987e-23 7.308e-23 -22.098 -22.136 -0.039 (0) + H[14C][18O]O[18O]- 7.987e-23 7.308e-23 -22.098 -22.136 -0.039 (0) + [14C]O2[18O]-2 7.126e-23 4.995e-23 -22.147 -22.301 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 1.016e-16 + O[18O] 1.014e-16 1.015e-16 -15.994 -15.993 0.001 (0) + [18O]2 1.011e-19 1.013e-19 -18.995 -18.994 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -18665,99 +18665,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -122.619 -122.619 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.406e-39 - H2 7.028e-40 7.040e-40 -39.153 -39.152 0.001 -O(0) 1.680e-14 - O2 8.364e-15 8.378e-15 -14.078 -14.077 0.001 - O[18O] 3.338e-17 3.343e-17 -16.477 -16.476 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -124.575 -124.574 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -137.033 -137.032 0.001 -[14C](4) 2.288e-17 - H[14C]O3- 1.848e-17 1.691e-17 -16.733 -16.772 -0.039 - [14C]O2 3.848e-18 3.854e-18 -17.415 -17.414 0.001 - CaH[14C]O3+ 3.904e-19 3.582e-19 -18.408 -18.446 -0.037 - H[14C]O2[18O]- 3.688e-20 3.374e-20 -19.433 -19.472 -0.039 - H[14C]O[18O]O- 3.688e-20 3.374e-20 -19.433 -19.472 -0.039 - H[14C][18O]O2- 3.688e-20 3.374e-20 -19.433 -19.472 -0.039 - Ca[14C]O3 2.140e-20 2.143e-20 -19.670 -19.669 0.001 - [14C]O[18O] 1.600e-20 1.603e-20 -19.796 -19.795 0.001 - [14C]O3-2 1.097e-20 7.687e-21 -19.960 -20.114 -0.154 - CaH[14C]O2[18O]+ 7.790e-22 7.147e-22 -21.108 -21.146 -0.037 - CaH[14C]O[18O]O+ 7.790e-22 7.147e-22 -21.108 -21.146 -0.037 - CaH[14C][18O]O2+ 7.790e-22 7.147e-22 -21.108 -21.146 -0.037 - Ca[14C]O2[18O] 1.281e-22 1.283e-22 -21.893 -21.892 0.001 - H[14C]O[18O]2- 7.358e-23 6.732e-23 -22.133 -22.172 -0.039 - H[14C][18O]2O- 7.358e-23 6.732e-23 -22.133 -22.172 -0.039 - H[14C][18O]O[18O]- 7.358e-23 6.732e-23 -22.133 -22.172 -0.039 - [14C]O2[18O]-2 6.565e-23 4.601e-23 -22.183 -22.337 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.344e-17 - O[18O] 3.338e-17 3.343e-17 -16.477 -16.476 0.001 - [18O]2 3.330e-20 3.335e-20 -19.478 -19.477 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -122.619 -122.619 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.406e-39 + H2 7.028e-40 7.040e-40 -39.153 -39.152 0.001 (0) +O(0) 1.680e-14 + O2 8.364e-15 8.378e-15 -14.078 -14.077 0.001 (0) + O[18O] 3.338e-17 3.343e-17 -16.477 -16.476 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -124.575 -124.574 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -137.033 -137.032 0.001 (0) +[14C](4) 2.288e-17 + H[14C]O3- 1.848e-17 1.691e-17 -16.733 -16.772 -0.039 (0) + [14C]O2 3.848e-18 3.854e-18 -17.415 -17.414 0.001 (0) + CaH[14C]O3+ 3.904e-19 3.582e-19 -18.408 -18.446 -0.037 (0) + H[14C]O2[18O]- 3.688e-20 3.374e-20 -19.433 -19.472 -0.039 (0) + H[14C]O[18O]O- 3.688e-20 3.374e-20 -19.433 -19.472 -0.039 (0) + H[14C][18O]O2- 3.688e-20 3.374e-20 -19.433 -19.472 -0.039 (0) + Ca[14C]O3 2.140e-20 2.143e-20 -19.670 -19.669 0.001 (0) + [14C]O[18O] 1.600e-20 1.603e-20 -19.796 -19.795 0.001 (0) + [14C]O3-2 1.097e-20 7.687e-21 -19.960 -20.114 -0.154 (0) + CaH[14C]O2[18O]+ 7.790e-22 7.147e-22 -21.108 -21.146 -0.037 (0) + CaH[14C]O[18O]O+ 7.790e-22 7.147e-22 -21.108 -21.146 -0.037 (0) + CaH[14C][18O]O2+ 7.790e-22 7.147e-22 -21.108 -21.146 -0.037 (0) + Ca[14C]O2[18O] 1.281e-22 1.283e-22 -21.893 -21.892 0.001 (0) + H[14C]O[18O]2- 7.358e-23 6.732e-23 -22.133 -22.172 -0.039 (0) + H[14C][18O]2O- 7.358e-23 6.732e-23 -22.133 -22.172 -0.039 (0) + H[14C][18O]O[18O]- 7.358e-23 6.732e-23 -22.133 -22.172 -0.039 (0) + [14C]O2[18O]-2 6.565e-23 4.601e-23 -22.183 -22.337 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.344e-17 + O[18O] 3.338e-17 3.343e-17 -16.477 -16.476 0.001 (0) + [18O]2 3.330e-20 3.335e-20 -19.478 -19.477 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -18939,99 +18939,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 8.937e-28 - CH4 8.937e-28 8.952e-28 -27.049 -27.048 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.098e-15 - H2 5.489e-16 5.498e-16 -15.261 -15.260 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -61.863 -61.862 0.001 - O[18O] 0.000e+00 0.000e+00 -64.262 -64.261 0.001 -[13C](-4) 9.906e-30 - [13C]H4 9.906e-30 9.922e-30 -29.004 -29.003 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -41.498 -41.497 0.001 -[14C](4) 2.108e-17 - H[14C]O3- 1.703e-17 1.558e-17 -16.769 -16.807 -0.039 - [14C]O2 3.544e-18 3.550e-18 -17.450 -17.450 0.001 - CaH[14C]O3+ 3.597e-19 3.300e-19 -18.444 -18.482 -0.037 - H[14C]O2[18O]- 3.397e-20 3.108e-20 -19.469 -19.507 -0.039 - H[14C]O[18O]O- 3.397e-20 3.108e-20 -19.469 -19.507 -0.039 - H[14C][18O]O2- 3.397e-20 3.108e-20 -19.469 -19.507 -0.039 - Ca[14C]O3 1.971e-20 1.975e-20 -19.705 -19.705 0.001 - [14C]O[18O] 1.474e-20 1.476e-20 -19.832 -19.831 0.001 - [14C]O3-2 1.010e-20 7.082e-21 -19.996 -20.150 -0.154 - CaH[14C]O2[18O]+ 7.176e-22 6.584e-22 -21.144 -21.182 -0.037 - CaH[14C]O[18O]O+ 7.176e-22 6.584e-22 -21.144 -21.182 -0.037 - CaH[14C][18O]O2+ 7.176e-22 6.584e-22 -21.144 -21.182 -0.037 - Ca[14C]O2[18O] 1.180e-22 1.182e-22 -21.928 -21.927 0.001 - H[14C]O[18O]2- 6.778e-23 6.202e-23 -22.169 -22.207 -0.039 - H[14C][18O]2O- 6.778e-23 6.202e-23 -22.169 -22.207 -0.039 - H[14C][18O]O[18O]- 6.778e-23 6.202e-23 -22.169 -22.207 -0.039 - [14C]O2[18O]-2 6.048e-23 4.239e-23 -22.218 -22.373 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -64.262 -64.261 0.001 - [18O]2 0.000e+00 0.000e+00 -67.263 -67.262 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 8.937e-28 + CH4 8.937e-28 8.952e-28 -27.049 -27.048 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.098e-15 + H2 5.489e-16 5.498e-16 -15.261 -15.260 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -61.863 -61.862 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -64.262 -64.261 0.001 (0) +[13C](-4) 9.906e-30 + [13C]H4 9.906e-30 9.922e-30 -29.004 -29.003 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -41.498 -41.497 0.001 (0) +[14C](4) 2.108e-17 + H[14C]O3- 1.703e-17 1.558e-17 -16.769 -16.807 -0.039 (0) + [14C]O2 3.544e-18 3.550e-18 -17.450 -17.450 0.001 (0) + CaH[14C]O3+ 3.597e-19 3.300e-19 -18.444 -18.482 -0.037 (0) + H[14C]O2[18O]- 3.397e-20 3.108e-20 -19.469 -19.507 -0.039 (0) + H[14C]O[18O]O- 3.397e-20 3.108e-20 -19.469 -19.507 -0.039 (0) + H[14C][18O]O2- 3.397e-20 3.108e-20 -19.469 -19.507 -0.039 (0) + Ca[14C]O3 1.971e-20 1.975e-20 -19.705 -19.705 0.001 (0) + [14C]O[18O] 1.474e-20 1.476e-20 -19.832 -19.831 0.001 (0) + [14C]O3-2 1.010e-20 7.082e-21 -19.996 -20.150 -0.154 (0) + CaH[14C]O2[18O]+ 7.176e-22 6.584e-22 -21.144 -21.182 -0.037 (0) + CaH[14C]O[18O]O+ 7.176e-22 6.584e-22 -21.144 -21.182 -0.037 (0) + CaH[14C][18O]O2+ 7.176e-22 6.584e-22 -21.144 -21.182 -0.037 (0) + Ca[14C]O2[18O] 1.180e-22 1.182e-22 -21.928 -21.927 0.001 (0) + H[14C]O[18O]2- 6.778e-23 6.202e-23 -22.169 -22.207 -0.039 (0) + H[14C][18O]2O- 6.778e-23 6.202e-23 -22.169 -22.207 -0.039 (0) + H[14C][18O]O[18O]- 6.778e-23 6.202e-23 -22.169 -22.207 -0.039 (0) + [14C]O2[18O]-2 6.048e-23 4.239e-23 -22.218 -22.373 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -64.262 -64.261 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -67.263 -67.262 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -19211,99 +19211,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -120.784 -120.783 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 4.043e-39 - H2 2.021e-39 2.025e-39 -38.694 -38.694 0.001 -O(0) 2.030e-15 - O2 1.011e-15 1.013e-15 -14.995 -14.995 0.001 - O[18O] 4.035e-18 4.041e-18 -17.394 -17.393 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -122.739 -122.739 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -135.269 -135.268 0.001 -[14C](4) 1.942e-17 - H[14C]O3- 1.569e-17 1.435e-17 -16.805 -16.843 -0.039 - [14C]O2 3.265e-18 3.271e-18 -17.486 -17.485 0.001 - CaH[14C]O3+ 3.313e-19 3.040e-19 -18.480 -18.517 -0.037 - H[14C]O2[18O]- 3.129e-20 2.863e-20 -19.505 -19.543 -0.039 - H[14C]O[18O]O- 3.129e-20 2.863e-20 -19.505 -19.543 -0.039 - H[14C][18O]O2- 3.129e-20 2.863e-20 -19.505 -19.543 -0.039 - Ca[14C]O3 1.816e-20 1.819e-20 -19.741 -19.740 0.001 - [14C]O[18O] 1.358e-20 1.360e-20 -19.867 -19.866 0.001 - [14C]O3-2 9.308e-21 6.524e-21 -20.031 -20.185 -0.154 - CaH[14C]O2[18O]+ 6.611e-22 6.065e-22 -21.180 -21.217 -0.037 - CaH[14C]O[18O]O+ 6.611e-22 6.065e-22 -21.180 -21.217 -0.037 - CaH[14C][18O]O2+ 6.611e-22 6.065e-22 -21.180 -21.217 -0.037 - Ca[14C]O2[18O] 1.087e-22 1.089e-22 -21.964 -21.963 0.001 - H[14C]O[18O]2- 6.244e-23 5.713e-23 -22.205 -22.243 -0.039 - H[14C][18O]2O- 6.244e-23 5.713e-23 -22.205 -22.243 -0.039 - H[14C][18O]O[18O]- 6.244e-23 5.713e-23 -22.205 -22.243 -0.039 - [14C]O2[18O]-2 5.571e-23 3.905e-23 -22.254 -22.408 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 4.043e-18 - O[18O] 4.035e-18 4.041e-18 -17.394 -17.393 0.001 - [18O]2 4.025e-21 4.031e-21 -20.395 -20.395 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -120.784 -120.783 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 4.043e-39 + H2 2.021e-39 2.025e-39 -38.694 -38.694 0.001 (0) +O(0) 2.030e-15 + O2 1.011e-15 1.013e-15 -14.995 -14.995 0.001 (0) + O[18O] 4.035e-18 4.041e-18 -17.394 -17.393 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -122.739 -122.739 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -135.269 -135.268 0.001 (0) +[14C](4) 1.942e-17 + H[14C]O3- 1.569e-17 1.435e-17 -16.805 -16.843 -0.039 (0) + [14C]O2 3.265e-18 3.271e-18 -17.486 -17.485 0.001 (0) + CaH[14C]O3+ 3.313e-19 3.040e-19 -18.480 -18.517 -0.037 (0) + H[14C]O2[18O]- 3.129e-20 2.863e-20 -19.505 -19.543 -0.039 (0) + H[14C]O[18O]O- 3.129e-20 2.863e-20 -19.505 -19.543 -0.039 (0) + H[14C][18O]O2- 3.129e-20 2.863e-20 -19.505 -19.543 -0.039 (0) + Ca[14C]O3 1.816e-20 1.819e-20 -19.741 -19.740 0.001 (0) + [14C]O[18O] 1.358e-20 1.360e-20 -19.867 -19.866 0.001 (0) + [14C]O3-2 9.308e-21 6.524e-21 -20.031 -20.185 -0.154 (0) + CaH[14C]O2[18O]+ 6.611e-22 6.065e-22 -21.180 -21.217 -0.037 (0) + CaH[14C]O[18O]O+ 6.611e-22 6.065e-22 -21.180 -21.217 -0.037 (0) + CaH[14C][18O]O2+ 6.611e-22 6.065e-22 -21.180 -21.217 -0.037 (0) + Ca[14C]O2[18O] 1.087e-22 1.089e-22 -21.964 -21.963 0.001 (0) + H[14C]O[18O]2- 6.244e-23 5.713e-23 -22.205 -22.243 -0.039 (0) + H[14C][18O]2O- 6.244e-23 5.713e-23 -22.205 -22.243 -0.039 (0) + H[14C][18O]O[18O]- 6.244e-23 5.713e-23 -22.205 -22.243 -0.039 (0) + [14C]O2[18O]-2 5.571e-23 3.905e-23 -22.254 -22.408 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 4.043e-18 + O[18O] 4.035e-18 4.041e-18 -17.394 -17.393 0.001 (0) + [18O]2 4.025e-21 4.031e-21 -20.395 -20.395 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -19483,99 +19483,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -121.282 -121.281 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 3.035e-39 - H2 1.518e-39 1.520e-39 -38.819 -38.818 0.001 -O(0) 3.602e-15 - O2 1.794e-15 1.797e-15 -14.746 -14.746 0.001 - O[18O] 7.157e-18 7.169e-18 -17.145 -17.145 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -123.237 -123.237 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -135.802 -135.801 0.001 -[14C](4) 1.789e-17 - H[14C]O3- 1.445e-17 1.322e-17 -16.840 -16.879 -0.039 - [14C]O2 3.008e-18 3.013e-18 -17.522 -17.521 0.001 - CaH[14C]O3+ 3.052e-19 2.800e-19 -18.515 -18.553 -0.037 - H[14C]O2[18O]- 2.883e-20 2.638e-20 -19.540 -19.579 -0.039 - H[14C]O[18O]O- 2.883e-20 2.638e-20 -19.540 -19.579 -0.039 - H[14C][18O]O2- 2.883e-20 2.638e-20 -19.540 -19.579 -0.039 - Ca[14C]O3 1.673e-20 1.676e-20 -19.777 -19.776 0.001 - [14C]O[18O] 1.251e-20 1.253e-20 -19.903 -19.902 0.001 - [14C]O3-2 8.575e-21 6.010e-21 -20.067 -20.221 -0.154 - CaH[14C]O2[18O]+ 6.090e-22 5.587e-22 -21.215 -21.253 -0.037 - CaH[14C]O[18O]O+ 6.090e-22 5.587e-22 -21.215 -21.253 -0.037 - CaH[14C][18O]O2+ 6.090e-22 5.587e-22 -21.215 -21.253 -0.037 - Ca[14C]O2[18O] 1.001e-22 1.003e-22 -21.999 -21.999 0.001 - H[14C]O[18O]2- 5.752e-23 5.263e-23 -22.240 -22.279 -0.039 - H[14C][18O]2O- 5.752e-23 5.263e-23 -22.240 -22.279 -0.039 - H[14C][18O]O[18O]- 5.752e-23 5.263e-23 -22.240 -22.279 -0.039 - [14C]O2[18O]-2 5.132e-23 3.597e-23 -22.290 -22.444 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 7.172e-18 - O[18O] 7.157e-18 7.169e-18 -17.145 -17.145 0.001 - [18O]2 7.140e-21 7.152e-21 -20.146 -20.146 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -121.282 -121.281 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 3.035e-39 + H2 1.518e-39 1.520e-39 -38.819 -38.818 0.001 (0) +O(0) 3.602e-15 + O2 1.794e-15 1.797e-15 -14.746 -14.746 0.001 (0) + O[18O] 7.157e-18 7.169e-18 -17.145 -17.145 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -123.237 -123.237 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -135.802 -135.801 0.001 (0) +[14C](4) 1.789e-17 + H[14C]O3- 1.445e-17 1.322e-17 -16.840 -16.879 -0.039 (0) + [14C]O2 3.008e-18 3.013e-18 -17.522 -17.521 0.001 (0) + CaH[14C]O3+ 3.052e-19 2.800e-19 -18.515 -18.553 -0.037 (0) + H[14C]O2[18O]- 2.883e-20 2.638e-20 -19.540 -19.579 -0.039 (0) + H[14C]O[18O]O- 2.883e-20 2.638e-20 -19.540 -19.579 -0.039 (0) + H[14C][18O]O2- 2.883e-20 2.638e-20 -19.540 -19.579 -0.039 (0) + Ca[14C]O3 1.673e-20 1.676e-20 -19.777 -19.776 0.001 (0) + [14C]O[18O] 1.251e-20 1.253e-20 -19.903 -19.902 0.001 (0) + [14C]O3-2 8.575e-21 6.010e-21 -20.067 -20.221 -0.154 (0) + CaH[14C]O2[18O]+ 6.090e-22 5.587e-22 -21.215 -21.253 -0.037 (0) + CaH[14C]O[18O]O+ 6.090e-22 5.587e-22 -21.215 -21.253 -0.037 (0) + CaH[14C][18O]O2+ 6.090e-22 5.587e-22 -21.215 -21.253 -0.037 (0) + Ca[14C]O2[18O] 1.001e-22 1.003e-22 -21.999 -21.999 0.001 (0) + H[14C]O[18O]2- 5.752e-23 5.263e-23 -22.240 -22.279 -0.039 (0) + H[14C][18O]2O- 5.752e-23 5.263e-23 -22.240 -22.279 -0.039 (0) + H[14C][18O]O[18O]- 5.752e-23 5.263e-23 -22.240 -22.279 -0.039 (0) + [14C]O2[18O]-2 5.132e-23 3.597e-23 -22.290 -22.444 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 7.172e-18 + O[18O] 7.157e-18 7.169e-18 -17.145 -17.145 0.001 (0) + [18O]2 7.140e-21 7.152e-21 -20.146 -20.146 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -19755,99 +19755,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -122.407 -122.407 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.588e-39 - H2 7.941e-40 7.954e-40 -39.100 -39.099 0.001 -O(0) 1.316e-14 - O2 6.551e-15 6.562e-15 -14.184 -14.183 0.001 - O[18O] 2.614e-17 2.619e-17 -16.583 -16.582 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -124.363 -124.362 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -136.963 -136.962 0.001 -[14C](4) 1.648e-17 - H[14C]O3- 1.331e-17 1.218e-17 -16.876 -16.914 -0.039 - [14C]O2 2.771e-18 2.776e-18 -17.557 -17.557 0.001 - CaH[14C]O3+ 2.812e-19 2.580e-19 -18.551 -18.588 -0.037 - H[14C]O2[18O]- 2.656e-20 2.430e-20 -19.576 -19.614 -0.039 - H[14C]O[18O]O- 2.656e-20 2.430e-20 -19.576 -19.614 -0.039 - H[14C][18O]O2- 2.656e-20 2.430e-20 -19.576 -19.614 -0.039 - Ca[14C]O3 1.541e-20 1.544e-20 -19.812 -19.811 0.001 - [14C]O[18O] 1.152e-20 1.154e-20 -19.938 -19.938 0.001 - [14C]O3-2 7.899e-21 5.537e-21 -20.102 -20.257 -0.154 - CaH[14C]O2[18O]+ 5.610e-22 5.147e-22 -21.251 -21.288 -0.037 - CaH[14C]O[18O]O+ 5.610e-22 5.147e-22 -21.251 -21.288 -0.037 - CaH[14C][18O]O2+ 5.610e-22 5.147e-22 -21.251 -21.288 -0.037 - Ca[14C]O2[18O] 9.225e-23 9.240e-23 -22.035 -22.034 0.001 - H[14C]O[18O]2- 5.299e-23 4.849e-23 -22.276 -22.314 -0.039 - H[14C][18O]2O- 5.299e-23 4.849e-23 -22.276 -22.314 -0.039 - H[14C][18O]O[18O]- 5.299e-23 4.849e-23 -22.276 -22.314 -0.039 - [14C]O2[18O]-2 4.728e-23 3.314e-23 -22.325 -22.480 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.620e-17 - O[18O] 2.614e-17 2.619e-17 -16.583 -16.582 0.001 - [18O]2 2.608e-20 2.612e-20 -19.584 -19.583 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -122.407 -122.407 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.588e-39 + H2 7.941e-40 7.954e-40 -39.100 -39.099 0.001 (0) +O(0) 1.316e-14 + O2 6.551e-15 6.562e-15 -14.184 -14.183 0.001 (0) + O[18O] 2.614e-17 2.619e-17 -16.583 -16.582 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -124.363 -124.362 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -136.963 -136.962 0.001 (0) +[14C](4) 1.648e-17 + H[14C]O3- 1.331e-17 1.218e-17 -16.876 -16.914 -0.039 (0) + [14C]O2 2.771e-18 2.776e-18 -17.557 -17.557 0.001 (0) + CaH[14C]O3+ 2.812e-19 2.580e-19 -18.551 -18.588 -0.037 (0) + H[14C]O2[18O]- 2.656e-20 2.430e-20 -19.576 -19.614 -0.039 (0) + H[14C]O[18O]O- 2.656e-20 2.430e-20 -19.576 -19.614 -0.039 (0) + H[14C][18O]O2- 2.656e-20 2.430e-20 -19.576 -19.614 -0.039 (0) + Ca[14C]O3 1.541e-20 1.544e-20 -19.812 -19.811 0.001 (0) + [14C]O[18O] 1.152e-20 1.154e-20 -19.938 -19.938 0.001 (0) + [14C]O3-2 7.899e-21 5.537e-21 -20.102 -20.257 -0.154 (0) + CaH[14C]O2[18O]+ 5.610e-22 5.147e-22 -21.251 -21.288 -0.037 (0) + CaH[14C]O[18O]O+ 5.610e-22 5.147e-22 -21.251 -21.288 -0.037 (0) + CaH[14C][18O]O2+ 5.610e-22 5.147e-22 -21.251 -21.288 -0.037 (0) + Ca[14C]O2[18O] 9.225e-23 9.240e-23 -22.035 -22.034 0.001 (0) + H[14C]O[18O]2- 5.299e-23 4.849e-23 -22.276 -22.314 -0.039 (0) + H[14C][18O]2O- 5.299e-23 4.849e-23 -22.276 -22.314 -0.039 (0) + H[14C][18O]O[18O]- 5.299e-23 4.849e-23 -22.276 -22.314 -0.039 (0) + [14C]O2[18O]-2 4.728e-23 3.314e-23 -22.325 -22.480 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.620e-17 + O[18O] 2.614e-17 2.619e-17 -16.583 -16.582 0.001 (0) + [18O]2 2.608e-20 2.612e-20 -19.584 -19.583 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -20027,99 +20027,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.352 -123.352 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 9.218e-40 - H2 4.609e-40 4.616e-40 -39.336 -39.336 0.001 -O(0) 3.905e-14 - O2 1.945e-14 1.948e-14 -13.711 -13.710 0.001 - O[18O] 7.761e-17 7.774e-17 -16.110 -16.109 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.308 -125.307 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -137.944 -137.943 0.001 -[14C](4) 1.518e-17 - H[14C]O3- 1.226e-17 1.122e-17 -16.911 -16.950 -0.039 - [14C]O2 2.553e-18 2.557e-18 -17.593 -17.592 0.001 - CaH[14C]O3+ 2.590e-19 2.377e-19 -18.587 -18.624 -0.037 - H[14C]O2[18O]- 2.447e-20 2.239e-20 -19.611 -19.650 -0.039 - H[14C]O[18O]O- 2.447e-20 2.239e-20 -19.611 -19.650 -0.039 - H[14C][18O]O2- 2.447e-20 2.239e-20 -19.611 -19.650 -0.039 - Ca[14C]O3 1.420e-20 1.422e-20 -19.848 -19.847 0.001 - [14C]O[18O] 1.062e-20 1.063e-20 -19.974 -19.973 0.001 - [14C]O3-2 7.277e-21 5.100e-21 -20.138 -20.292 -0.154 - CaH[14C]O2[18O]+ 5.168e-22 4.742e-22 -21.287 -21.324 -0.037 - CaH[14C]O[18O]O+ 5.168e-22 4.742e-22 -21.287 -21.324 -0.037 - CaH[14C][18O]O2+ 5.168e-22 4.742e-22 -21.287 -21.324 -0.037 - Ca[14C]O2[18O] 8.498e-23 8.512e-23 -22.071 -22.070 0.001 - H[14C]O[18O]2- 4.882e-23 4.467e-23 -22.311 -22.350 -0.039 - H[14C][18O]2O- 4.882e-23 4.467e-23 -22.311 -22.350 -0.039 - H[14C][18O]O[18O]- 4.882e-23 4.467e-23 -22.311 -22.350 -0.039 - [14C]O2[18O]-2 4.356e-23 3.053e-23 -22.361 -22.515 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 7.777e-17 - O[18O] 7.761e-17 7.774e-17 -16.110 -16.109 0.001 - [18O]2 7.743e-20 7.755e-20 -19.111 -19.110 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.352 -123.352 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 9.218e-40 + H2 4.609e-40 4.616e-40 -39.336 -39.336 0.001 (0) +O(0) 3.905e-14 + O2 1.945e-14 1.948e-14 -13.711 -13.710 0.001 (0) + O[18O] 7.761e-17 7.774e-17 -16.110 -16.109 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.308 -125.307 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -137.944 -137.943 0.001 (0) +[14C](4) 1.518e-17 + H[14C]O3- 1.226e-17 1.122e-17 -16.911 -16.950 -0.039 (0) + [14C]O2 2.553e-18 2.557e-18 -17.593 -17.592 0.001 (0) + CaH[14C]O3+ 2.590e-19 2.377e-19 -18.587 -18.624 -0.037 (0) + H[14C]O2[18O]- 2.447e-20 2.239e-20 -19.611 -19.650 -0.039 (0) + H[14C]O[18O]O- 2.447e-20 2.239e-20 -19.611 -19.650 -0.039 (0) + H[14C][18O]O2- 2.447e-20 2.239e-20 -19.611 -19.650 -0.039 (0) + Ca[14C]O3 1.420e-20 1.422e-20 -19.848 -19.847 0.001 (0) + [14C]O[18O] 1.062e-20 1.063e-20 -19.974 -19.973 0.001 (0) + [14C]O3-2 7.277e-21 5.100e-21 -20.138 -20.292 -0.154 (0) + CaH[14C]O2[18O]+ 5.168e-22 4.742e-22 -21.287 -21.324 -0.037 (0) + CaH[14C]O[18O]O+ 5.168e-22 4.742e-22 -21.287 -21.324 -0.037 (0) + CaH[14C][18O]O2+ 5.168e-22 4.742e-22 -21.287 -21.324 -0.037 (0) + Ca[14C]O2[18O] 8.498e-23 8.512e-23 -22.071 -22.070 0.001 (0) + H[14C]O[18O]2- 4.882e-23 4.467e-23 -22.311 -22.350 -0.039 (0) + H[14C][18O]2O- 4.882e-23 4.467e-23 -22.311 -22.350 -0.039 (0) + H[14C][18O]O[18O]- 4.882e-23 4.467e-23 -22.311 -22.350 -0.039 (0) + [14C]O2[18O]-2 4.356e-23 3.053e-23 -22.361 -22.515 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 7.777e-17 + O[18O] 7.761e-17 7.774e-17 -16.110 -16.109 0.001 (0) + [18O]2 7.743e-20 7.755e-20 -19.111 -19.110 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -20299,99 +20299,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.076 -123.076 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.081e-39 - H2 5.403e-40 5.412e-40 -39.267 -39.267 0.001 -O(0) 2.842e-14 - O2 1.415e-14 1.418e-14 -13.849 -13.848 0.001 - O[18O] 5.648e-17 5.657e-17 -16.248 -16.247 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.032 -125.031 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -137.703 -137.703 0.001 -[14C](4) 1.399e-17 - H[14C]O3- 1.130e-17 1.034e-17 -16.947 -16.986 -0.039 - [14C]O2 2.352e-18 2.356e-18 -17.629 -17.628 0.001 - CaH[14C]O3+ 2.386e-19 2.189e-19 -18.622 -18.660 -0.037 - H[14C]O2[18O]- 2.254e-20 2.062e-20 -19.647 -19.686 -0.039 - H[14C]O[18O]O- 2.254e-20 2.062e-20 -19.647 -19.686 -0.039 - H[14C][18O]O2- 2.254e-20 2.062e-20 -19.647 -19.686 -0.039 - Ca[14C]O3 1.308e-20 1.310e-20 -19.883 -19.883 0.001 - [14C]O[18O] 9.779e-21 9.795e-21 -20.010 -20.009 0.001 - [14C]O3-2 6.704e-21 4.699e-21 -20.174 -20.328 -0.154 - CaH[14C]O2[18O]+ 4.761e-22 4.368e-22 -21.322 -21.360 -0.037 - CaH[14C]O[18O]O+ 4.761e-22 4.368e-22 -21.322 -21.360 -0.037 - CaH[14C][18O]O2+ 4.761e-22 4.368e-22 -21.322 -21.360 -0.037 - Ca[14C]O2[18O] 7.829e-23 7.842e-23 -22.106 -22.106 0.001 - H[14C]O[18O]2- 4.497e-23 4.115e-23 -22.347 -22.386 -0.039 - H[14C][18O]2O- 4.497e-23 4.115e-23 -22.347 -22.386 -0.039 - H[14C][18O]O[18O]- 4.497e-23 4.115e-23 -22.347 -22.386 -0.039 - [14C]O2[18O]-2 4.012e-23 2.812e-23 -22.397 -22.551 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 5.659e-17 - O[18O] 5.648e-17 5.657e-17 -16.248 -16.247 0.001 - [18O]2 5.634e-20 5.644e-20 -19.249 -19.248 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.076 -123.076 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.081e-39 + H2 5.403e-40 5.412e-40 -39.267 -39.267 0.001 (0) +O(0) 2.842e-14 + O2 1.415e-14 1.418e-14 -13.849 -13.848 0.001 (0) + O[18O] 5.648e-17 5.657e-17 -16.248 -16.247 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.032 -125.031 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -137.703 -137.703 0.001 (0) +[14C](4) 1.399e-17 + H[14C]O3- 1.130e-17 1.034e-17 -16.947 -16.986 -0.039 (0) + [14C]O2 2.352e-18 2.356e-18 -17.629 -17.628 0.001 (0) + CaH[14C]O3+ 2.386e-19 2.189e-19 -18.622 -18.660 -0.037 (0) + H[14C]O2[18O]- 2.254e-20 2.062e-20 -19.647 -19.686 -0.039 (0) + H[14C]O[18O]O- 2.254e-20 2.062e-20 -19.647 -19.686 -0.039 (0) + H[14C][18O]O2- 2.254e-20 2.062e-20 -19.647 -19.686 -0.039 (0) + Ca[14C]O3 1.308e-20 1.310e-20 -19.883 -19.883 0.001 (0) + [14C]O[18O] 9.779e-21 9.795e-21 -20.010 -20.009 0.001 (0) + [14C]O3-2 6.704e-21 4.699e-21 -20.174 -20.328 -0.154 (0) + CaH[14C]O2[18O]+ 4.761e-22 4.368e-22 -21.322 -21.360 -0.037 (0) + CaH[14C]O[18O]O+ 4.761e-22 4.368e-22 -21.322 -21.360 -0.037 (0) + CaH[14C][18O]O2+ 4.761e-22 4.368e-22 -21.322 -21.360 -0.037 (0) + Ca[14C]O2[18O] 7.829e-23 7.842e-23 -22.106 -22.106 0.001 (0) + H[14C]O[18O]2- 4.497e-23 4.115e-23 -22.347 -22.386 -0.039 (0) + H[14C][18O]2O- 4.497e-23 4.115e-23 -22.347 -22.386 -0.039 (0) + H[14C][18O]O[18O]- 4.497e-23 4.115e-23 -22.347 -22.386 -0.039 (0) + [14C]O2[18O]-2 4.012e-23 2.812e-23 -22.397 -22.551 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 5.659e-17 + O[18O] 5.648e-17 5.657e-17 -16.248 -16.247 0.001 (0) + [18O]2 5.634e-20 5.644e-20 -19.249 -19.248 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -20571,99 +20571,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.679 -123.678 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 7.640e-40 - H2 3.820e-40 3.826e-40 -39.418 -39.417 0.001 -O(0) 5.685e-14 - O2 2.831e-14 2.836e-14 -13.548 -13.547 0.001 - O[18O] 1.130e-16 1.132e-16 -15.947 -15.946 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.634 -125.633 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -138.341 -138.340 0.001 -[14C](4) 1.288e-17 - H[14C]O3- 1.041e-17 9.522e-18 -16.983 -17.021 -0.039 - [14C]O2 2.166e-18 2.170e-18 -17.664 -17.664 0.001 - CaH[14C]O3+ 2.198e-19 2.017e-19 -18.658 -18.695 -0.037 - H[14C]O2[18O]- 2.076e-20 1.900e-20 -19.683 -19.721 -0.039 - H[14C]O[18O]O- 2.076e-20 1.900e-20 -19.683 -19.721 -0.039 - H[14C][18O]O2- 2.076e-20 1.900e-20 -19.683 -19.721 -0.039 - Ca[14C]O3 1.205e-20 1.207e-20 -19.919 -19.918 0.001 - [14C]O[18O] 9.009e-21 9.024e-21 -20.045 -20.045 0.001 - [14C]O3-2 6.175e-21 4.328e-21 -20.209 -20.364 -0.154 - CaH[14C]O2[18O]+ 4.386e-22 4.024e-22 -21.358 -21.395 -0.037 - CaH[14C]O[18O]O+ 4.386e-22 4.024e-22 -21.358 -21.395 -0.037 - CaH[14C][18O]O2+ 4.386e-22 4.024e-22 -21.358 -21.395 -0.037 - Ca[14C]O2[18O] 7.212e-23 7.224e-23 -22.142 -22.141 0.001 - H[14C]O[18O]2- 4.143e-23 3.791e-23 -22.383 -22.421 -0.039 - H[14C][18O]2O- 4.143e-23 3.791e-23 -22.383 -22.421 -0.039 - H[14C][18O]O[18O]- 4.143e-23 3.791e-23 -22.383 -22.421 -0.039 - [14C]O2[18O]-2 3.696e-23 2.591e-23 -22.432 -22.587 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 1.132e-16 - O[18O] 1.130e-16 1.132e-16 -15.947 -15.946 0.001 - [18O]2 1.127e-19 1.129e-19 -18.948 -18.947 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.679 -123.678 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 7.640e-40 + H2 3.820e-40 3.826e-40 -39.418 -39.417 0.001 (0) +O(0) 5.685e-14 + O2 2.831e-14 2.836e-14 -13.548 -13.547 0.001 (0) + O[18O] 1.130e-16 1.132e-16 -15.947 -15.946 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.634 -125.633 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.106e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -138.341 -138.340 0.001 (0) +[14C](4) 1.288e-17 + H[14C]O3- 1.041e-17 9.522e-18 -16.983 -17.021 -0.039 (0) + [14C]O2 2.166e-18 2.170e-18 -17.664 -17.664 0.001 (0) + CaH[14C]O3+ 2.198e-19 2.017e-19 -18.658 -18.695 -0.037 (0) + H[14C]O2[18O]- 2.076e-20 1.900e-20 -19.683 -19.721 -0.039 (0) + H[14C]O[18O]O- 2.076e-20 1.900e-20 -19.683 -19.721 -0.039 (0) + H[14C][18O]O2- 2.076e-20 1.900e-20 -19.683 -19.721 -0.039 (0) + Ca[14C]O3 1.205e-20 1.207e-20 -19.919 -19.918 0.001 (0) + [14C]O[18O] 9.009e-21 9.024e-21 -20.045 -20.045 0.001 (0) + [14C]O3-2 6.175e-21 4.328e-21 -20.209 -20.364 -0.154 (0) + CaH[14C]O2[18O]+ 4.386e-22 4.024e-22 -21.358 -21.395 -0.037 (0) + CaH[14C]O[18O]O+ 4.386e-22 4.024e-22 -21.358 -21.395 -0.037 (0) + CaH[14C][18O]O2+ 4.386e-22 4.024e-22 -21.358 -21.395 -0.037 (0) + Ca[14C]O2[18O] 7.212e-23 7.224e-23 -22.142 -22.141 0.001 (0) + H[14C]O[18O]2- 4.143e-23 3.791e-23 -22.383 -22.421 -0.039 (0) + H[14C][18O]2O- 4.143e-23 3.791e-23 -22.383 -22.421 -0.039 (0) + H[14C][18O]O[18O]- 4.143e-23 3.791e-23 -22.383 -22.421 -0.039 (0) + [14C]O2[18O]-2 3.696e-23 2.591e-23 -22.432 -22.587 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 1.132e-16 + O[18O] 1.130e-16 1.132e-16 -15.947 -15.946 0.001 (0) + [18O]2 1.127e-19 1.129e-19 -18.948 -18.947 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -20843,99 +20843,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.570 -123.569 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.096e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 8.132e-40 - H2 4.066e-40 4.073e-40 -39.391 -39.390 0.001 -O(0) 5.018e-14 - O2 2.499e-14 2.503e-14 -13.602 -13.602 0.001 - O[18O] 9.972e-17 9.988e-17 -16.001 -16.001 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.525 -125.525 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.096e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -138.268 -138.268 0.001 -[14C](4) 1.187e-17 - H[14C]O3- 9.587e-18 8.772e-18 -17.018 -17.057 -0.039 - [14C]O2 1.996e-18 1.999e-18 -17.700 -17.699 0.001 - CaH[14C]O3+ 2.025e-19 1.858e-19 -18.694 -18.731 -0.037 - H[14C]O2[18O]- 1.913e-20 1.750e-20 -19.718 -19.757 -0.039 - H[14C]O[18O]O- 1.913e-20 1.750e-20 -19.718 -19.757 -0.039 - H[14C][18O]O2- 1.913e-20 1.750e-20 -19.718 -19.757 -0.039 - Ca[14C]O3 1.110e-20 1.112e-20 -19.955 -19.954 0.001 - [14C]O[18O] 8.299e-21 8.313e-21 -20.081 -20.080 0.001 - [14C]O3-2 5.689e-21 3.988e-21 -20.245 -20.399 -0.154 - CaH[14C]O2[18O]+ 4.041e-22 3.707e-22 -21.394 -21.431 -0.037 - CaH[14C]O[18O]O+ 4.041e-22 3.707e-22 -21.394 -21.431 -0.037 - CaH[14C][18O]O2+ 4.041e-22 3.707e-22 -21.394 -21.431 -0.037 - Ca[14C]O2[18O] 6.644e-23 6.655e-23 -22.178 -22.177 0.001 - H[14C]O[18O]2- 3.816e-23 3.492e-23 -22.418 -22.457 -0.039 - H[14C][18O]2O- 3.816e-23 3.492e-23 -22.418 -22.457 -0.039 - H[14C][18O]O[18O]- 3.816e-23 3.492e-23 -22.418 -22.457 -0.039 - [14C]O2[18O]-2 3.405e-23 2.387e-23 -22.468 -22.622 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 9.992e-17 - O[18O] 9.972e-17 9.988e-17 -16.001 -16.001 0.001 - [18O]2 9.948e-20 9.964e-20 -19.002 -19.002 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.570 -123.569 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.096e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 8.132e-40 + H2 4.066e-40 4.073e-40 -39.391 -39.390 0.001 (0) +O(0) 5.018e-14 + O2 2.499e-14 2.503e-14 -13.602 -13.602 0.001 (0) + O[18O] 9.972e-17 9.988e-17 -16.001 -16.001 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.525 -125.525 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.096e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -138.268 -138.268 0.001 (0) +[14C](4) 1.187e-17 + H[14C]O3- 9.587e-18 8.772e-18 -17.018 -17.057 -0.039 (0) + [14C]O2 1.996e-18 1.999e-18 -17.700 -17.699 0.001 (0) + CaH[14C]O3+ 2.025e-19 1.858e-19 -18.694 -18.731 -0.037 (0) + H[14C]O2[18O]- 1.913e-20 1.750e-20 -19.718 -19.757 -0.039 (0) + H[14C]O[18O]O- 1.913e-20 1.750e-20 -19.718 -19.757 -0.039 (0) + H[14C][18O]O2- 1.913e-20 1.750e-20 -19.718 -19.757 -0.039 (0) + Ca[14C]O3 1.110e-20 1.112e-20 -19.955 -19.954 0.001 (0) + [14C]O[18O] 8.299e-21 8.313e-21 -20.081 -20.080 0.001 (0) + [14C]O3-2 5.689e-21 3.988e-21 -20.245 -20.399 -0.154 (0) + CaH[14C]O2[18O]+ 4.041e-22 3.707e-22 -21.394 -21.431 -0.037 (0) + CaH[14C]O[18O]O+ 4.041e-22 3.707e-22 -21.394 -21.431 -0.037 (0) + CaH[14C][18O]O2+ 4.041e-22 3.707e-22 -21.394 -21.431 -0.037 (0) + Ca[14C]O2[18O] 6.644e-23 6.655e-23 -22.178 -22.177 0.001 (0) + H[14C]O[18O]2- 3.816e-23 3.492e-23 -22.418 -22.457 -0.039 (0) + H[14C][18O]2O- 3.816e-23 3.492e-23 -22.418 -22.457 -0.039 (0) + H[14C][18O]O[18O]- 3.816e-23 3.492e-23 -22.418 -22.457 -0.039 (0) + [14C]O2[18O]-2 3.405e-23 2.387e-23 -22.468 -22.622 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 9.992e-17 + O[18O] 9.972e-17 9.988e-17 -16.001 -16.001 0.001 (0) + [18O]2 9.948e-20 9.964e-20 -19.002 -19.002 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -21115,99 +21115,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.679 -123.678 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 7.640e-40 - H2 3.820e-40 3.826e-40 -39.418 -39.417 0.001 -O(0) 5.685e-14 - O2 2.831e-14 2.836e-14 -13.548 -13.547 0.001 - O[18O] 1.130e-16 1.132e-16 -15.947 -15.946 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.634 -125.633 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -138.412 -138.412 0.001 -[14C](4) 1.093e-17 - H[14C]O3- 8.832e-18 8.081e-18 -17.054 -17.093 -0.039 - [14C]O2 1.839e-18 1.842e-18 -17.736 -17.735 0.001 - CaH[14C]O3+ 1.866e-19 1.712e-19 -18.729 -18.767 -0.037 - H[14C]O2[18O]- 1.762e-20 1.612e-20 -19.754 -19.793 -0.039 - H[14C]O[18O]O- 1.762e-20 1.612e-20 -19.754 -19.793 -0.039 - H[14C][18O]O2- 1.762e-20 1.612e-20 -19.754 -19.793 -0.039 - Ca[14C]O3 1.023e-20 1.024e-20 -19.990 -19.990 0.001 - [14C]O[18O] 7.645e-21 7.658e-21 -20.117 -20.116 0.001 - [14C]O3-2 5.241e-21 3.673e-21 -20.281 -20.435 -0.154 - CaH[14C]O2[18O]+ 3.722e-22 3.415e-22 -21.429 -21.467 -0.037 - CaH[14C]O[18O]O+ 3.722e-22 3.415e-22 -21.429 -21.467 -0.037 - CaH[14C][18O]O2+ 3.722e-22 3.415e-22 -21.429 -21.467 -0.037 - Ca[14C]O2[18O] 6.120e-23 6.130e-23 -22.213 -22.213 0.001 - H[14C]O[18O]2- 3.516e-23 3.217e-23 -22.454 -22.493 -0.039 - H[14C][18O]2O- 3.516e-23 3.217e-23 -22.454 -22.493 -0.039 - H[14C][18O]O[18O]- 3.516e-23 3.217e-23 -22.454 -22.493 -0.039 - [14C]O2[18O]-2 3.137e-23 2.199e-23 -22.503 -22.658 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 1.132e-16 - O[18O] 1.130e-16 1.132e-16 -15.947 -15.946 0.001 - [18O]2 1.127e-19 1.129e-19 -18.948 -18.947 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.679 -123.678 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 7.640e-40 + H2 3.820e-40 3.826e-40 -39.418 -39.417 0.001 (0) +O(0) 5.685e-14 + O2 2.831e-14 2.836e-14 -13.548 -13.547 0.001 (0) + O[18O] 1.130e-16 1.132e-16 -15.947 -15.946 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.634 -125.633 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -138.412 -138.412 0.001 (0) +[14C](4) 1.093e-17 + H[14C]O3- 8.832e-18 8.081e-18 -17.054 -17.093 -0.039 (0) + [14C]O2 1.839e-18 1.842e-18 -17.736 -17.735 0.001 (0) + CaH[14C]O3+ 1.866e-19 1.712e-19 -18.729 -18.767 -0.037 (0) + H[14C]O2[18O]- 1.762e-20 1.612e-20 -19.754 -19.793 -0.039 (0) + H[14C]O[18O]O- 1.762e-20 1.612e-20 -19.754 -19.793 -0.039 (0) + H[14C][18O]O2- 1.762e-20 1.612e-20 -19.754 -19.793 -0.039 (0) + Ca[14C]O3 1.023e-20 1.024e-20 -19.990 -19.990 0.001 (0) + [14C]O[18O] 7.645e-21 7.658e-21 -20.117 -20.116 0.001 (0) + [14C]O3-2 5.241e-21 3.673e-21 -20.281 -20.435 -0.154 (0) + CaH[14C]O2[18O]+ 3.722e-22 3.415e-22 -21.429 -21.467 -0.037 (0) + CaH[14C]O[18O]O+ 3.722e-22 3.415e-22 -21.429 -21.467 -0.037 (0) + CaH[14C][18O]O2+ 3.722e-22 3.415e-22 -21.429 -21.467 -0.037 (0) + Ca[14C]O2[18O] 6.120e-23 6.130e-23 -22.213 -22.213 0.001 (0) + H[14C]O[18O]2- 3.516e-23 3.217e-23 -22.454 -22.493 -0.039 (0) + H[14C][18O]2O- 3.516e-23 3.217e-23 -22.454 -22.493 -0.039 (0) + H[14C][18O]O[18O]- 3.516e-23 3.217e-23 -22.454 -22.493 -0.039 (0) + [14C]O2[18O]-2 3.137e-23 2.199e-23 -22.503 -22.658 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 1.132e-16 + O[18O] 1.130e-16 1.132e-16 -15.947 -15.946 0.001 (0) + [18O]2 1.127e-19 1.129e-19 -18.948 -18.947 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -21387,99 +21387,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.987 -123.987 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 6.396e-40 - H2 3.198e-40 3.203e-40 -39.495 -39.494 0.001 -O(0) 8.112e-14 - O2 4.040e-14 4.047e-14 -13.394 -13.393 0.001 - O[18O] 1.612e-16 1.615e-16 -15.793 -15.792 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.943 -125.942 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -138.757 -138.756 0.001 -[14C](4) 1.007e-17 - H[14C]O3- 8.136e-18 7.444e-18 -17.090 -17.128 -0.039 - [14C]O2 1.694e-18 1.696e-18 -17.771 -17.770 0.001 - CaH[14C]O3+ 1.719e-19 1.577e-19 -18.765 -18.802 -0.037 - H[14C]O2[18O]- 1.623e-20 1.485e-20 -19.790 -19.828 -0.039 - H[14C]O[18O]O- 1.623e-20 1.485e-20 -19.790 -19.828 -0.039 - H[14C][18O]O2- 1.623e-20 1.485e-20 -19.790 -19.828 -0.039 - Ca[14C]O3 9.420e-21 9.435e-21 -20.026 -20.025 0.001 - [14C]O[18O] 7.043e-21 7.055e-21 -20.152 -20.152 0.001 - [14C]O3-2 4.828e-21 3.384e-21 -20.316 -20.471 -0.154 - CaH[14C]O2[18O]+ 3.429e-22 3.146e-22 -21.465 -21.502 -0.037 - CaH[14C]O[18O]O+ 3.429e-22 3.146e-22 -21.465 -21.502 -0.037 - CaH[14C][18O]O2+ 3.429e-22 3.146e-22 -21.465 -21.502 -0.037 - Ca[14C]O2[18O] 5.638e-23 5.648e-23 -22.249 -22.248 0.001 - H[14C]O[18O]2- 3.239e-23 2.963e-23 -22.490 -22.528 -0.039 - H[14C][18O]2O- 3.239e-23 2.963e-23 -22.490 -22.528 -0.039 - H[14C][18O]O[18O]- 3.239e-23 2.963e-23 -22.490 -22.528 -0.039 - [14C]O2[18O]-2 2.890e-23 2.026e-23 -22.539 -22.693 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 1.615e-16 - O[18O] 1.612e-16 1.615e-16 -15.793 -15.792 0.001 - [18O]2 1.608e-19 1.611e-19 -18.794 -18.793 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.987 -123.987 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 6.396e-40 + H2 3.198e-40 3.203e-40 -39.495 -39.494 0.001 (0) +O(0) 8.112e-14 + O2 4.040e-14 4.047e-14 -13.394 -13.393 0.001 (0) + O[18O] 1.612e-16 1.615e-16 -15.793 -15.792 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.943 -125.942 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -138.757 -138.756 0.001 (0) +[14C](4) 1.007e-17 + H[14C]O3- 8.136e-18 7.444e-18 -17.090 -17.128 -0.039 (0) + [14C]O2 1.694e-18 1.696e-18 -17.771 -17.770 0.001 (0) + CaH[14C]O3+ 1.719e-19 1.577e-19 -18.765 -18.802 -0.037 (0) + H[14C]O2[18O]- 1.623e-20 1.485e-20 -19.790 -19.828 -0.039 (0) + H[14C]O[18O]O- 1.623e-20 1.485e-20 -19.790 -19.828 -0.039 (0) + H[14C][18O]O2- 1.623e-20 1.485e-20 -19.790 -19.828 -0.039 (0) + Ca[14C]O3 9.420e-21 9.435e-21 -20.026 -20.025 0.001 (0) + [14C]O[18O] 7.043e-21 7.055e-21 -20.152 -20.152 0.001 (0) + [14C]O3-2 4.828e-21 3.384e-21 -20.316 -20.471 -0.154 (0) + CaH[14C]O2[18O]+ 3.429e-22 3.146e-22 -21.465 -21.502 -0.037 (0) + CaH[14C]O[18O]O+ 3.429e-22 3.146e-22 -21.465 -21.502 -0.037 (0) + CaH[14C][18O]O2+ 3.429e-22 3.146e-22 -21.465 -21.502 -0.037 (0) + Ca[14C]O2[18O] 5.638e-23 5.648e-23 -22.249 -22.248 0.001 (0) + H[14C]O[18O]2- 3.239e-23 2.963e-23 -22.490 -22.528 -0.039 (0) + H[14C][18O]2O- 3.239e-23 2.963e-23 -22.490 -22.528 -0.039 (0) + H[14C][18O]O[18O]- 3.239e-23 2.963e-23 -22.490 -22.528 -0.039 (0) + [14C]O2[18O]-2 2.890e-23 2.026e-23 -22.539 -22.693 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 1.615e-16 + O[18O] 1.612e-16 1.615e-16 -15.793 -15.792 0.001 (0) + [18O]2 1.608e-19 1.611e-19 -18.794 -18.793 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -21659,99 +21659,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -124.034 -124.033 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 6.227e-40 - H2 3.114e-40 3.119e-40 -39.507 -39.506 0.001 -O(0) 8.558e-14 - O2 4.262e-14 4.269e-14 -13.370 -13.370 0.001 - O[18O] 1.701e-16 1.703e-16 -15.769 -15.769 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.989 -125.988 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -138.839 -138.838 0.001 -[14C](4) 9.279e-18 - H[14C]O3- 7.495e-18 6.858e-18 -17.125 -17.164 -0.039 - [14C]O2 1.560e-18 1.563e-18 -17.807 -17.806 0.001 - CaH[14C]O3+ 1.583e-19 1.453e-19 -18.800 -18.838 -0.037 - H[14C]O2[18O]- 1.495e-20 1.368e-20 -19.825 -19.864 -0.039 - H[14C]O[18O]O- 1.495e-20 1.368e-20 -19.825 -19.864 -0.039 - H[14C][18O]O2- 1.495e-20 1.368e-20 -19.825 -19.864 -0.039 - Ca[14C]O3 8.678e-21 8.692e-21 -20.062 -20.061 0.001 - [14C]O[18O] 6.488e-21 6.499e-21 -20.188 -20.187 0.001 - [14C]O3-2 4.448e-21 3.117e-21 -20.352 -20.506 -0.154 - CaH[14C]O2[18O]+ 3.159e-22 2.898e-22 -21.500 -21.538 -0.037 - CaH[14C]O[18O]O+ 3.159e-22 2.898e-22 -21.500 -21.538 -0.037 - CaH[14C][18O]O2+ 3.159e-22 2.898e-22 -21.500 -21.538 -0.037 - Ca[14C]O2[18O] 5.194e-23 5.203e-23 -22.284 -22.284 0.001 - H[14C]O[18O]2- 2.984e-23 2.730e-23 -22.525 -22.564 -0.039 - H[14C][18O]2O- 2.984e-23 2.730e-23 -22.525 -22.564 -0.039 - H[14C][18O]O[18O]- 2.984e-23 2.730e-23 -22.525 -22.564 -0.039 - [14C]O2[18O]-2 2.662e-23 1.866e-23 -22.575 -22.729 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 1.704e-16 - O[18O] 1.701e-16 1.703e-16 -15.769 -15.769 0.001 - [18O]2 1.697e-19 1.699e-19 -18.770 -18.770 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -124.034 -124.033 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 6.227e-40 + H2 3.114e-40 3.119e-40 -39.507 -39.506 0.001 (0) +O(0) 8.558e-14 + O2 4.262e-14 4.269e-14 -13.370 -13.370 0.001 (0) + O[18O] 1.701e-16 1.703e-16 -15.769 -15.769 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.989 -125.988 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -138.839 -138.838 0.001 (0) +[14C](4) 9.279e-18 + H[14C]O3- 7.495e-18 6.858e-18 -17.125 -17.164 -0.039 (0) + [14C]O2 1.560e-18 1.563e-18 -17.807 -17.806 0.001 (0) + CaH[14C]O3+ 1.583e-19 1.453e-19 -18.800 -18.838 -0.037 (0) + H[14C]O2[18O]- 1.495e-20 1.368e-20 -19.825 -19.864 -0.039 (0) + H[14C]O[18O]O- 1.495e-20 1.368e-20 -19.825 -19.864 -0.039 (0) + H[14C][18O]O2- 1.495e-20 1.368e-20 -19.825 -19.864 -0.039 (0) + Ca[14C]O3 8.678e-21 8.692e-21 -20.062 -20.061 0.001 (0) + [14C]O[18O] 6.488e-21 6.499e-21 -20.188 -20.187 0.001 (0) + [14C]O3-2 4.448e-21 3.117e-21 -20.352 -20.506 -0.154 (0) + CaH[14C]O2[18O]+ 3.159e-22 2.898e-22 -21.500 -21.538 -0.037 (0) + CaH[14C]O[18O]O+ 3.159e-22 2.898e-22 -21.500 -21.538 -0.037 (0) + CaH[14C][18O]O2+ 3.159e-22 2.898e-22 -21.500 -21.538 -0.037 (0) + Ca[14C]O2[18O] 5.194e-23 5.203e-23 -22.284 -22.284 0.001 (0) + H[14C]O[18O]2- 2.984e-23 2.730e-23 -22.525 -22.564 -0.039 (0) + H[14C][18O]2O- 2.984e-23 2.730e-23 -22.525 -22.564 -0.039 (0) + H[14C][18O]O[18O]- 2.984e-23 2.730e-23 -22.525 -22.564 -0.039 (0) + [14C]O2[18O]-2 2.662e-23 1.866e-23 -22.575 -22.729 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 1.704e-16 + O[18O] 1.701e-16 1.703e-16 -15.769 -15.769 0.001 (0) + [18O]2 1.697e-19 1.699e-19 -18.770 -18.770 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -21931,99 +21931,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.926 -123.925 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 6.625e-40 - H2 3.313e-40 3.318e-40 -39.480 -39.479 0.001 -O(0) 7.560e-14 - O2 3.765e-14 3.771e-14 -13.424 -13.424 0.001 - O[18O] 1.502e-16 1.505e-16 -15.823 -15.823 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.881 -125.881 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -138.767 -138.766 0.001 -[14C](4) 8.548e-18 - H[14C]O3- 6.905e-18 6.318e-18 -17.161 -17.199 -0.039 - [14C]O2 1.437e-18 1.440e-18 -17.842 -17.842 0.001 - CaH[14C]O3+ 1.459e-19 1.338e-19 -18.836 -18.874 -0.037 - H[14C]O2[18O]- 1.378e-20 1.260e-20 -19.861 -19.899 -0.039 - H[14C]O[18O]O- 1.378e-20 1.260e-20 -19.861 -19.899 -0.039 - H[14C][18O]O2- 1.378e-20 1.260e-20 -19.861 -19.899 -0.039 - Ca[14C]O3 7.994e-21 8.007e-21 -20.097 -20.097 0.001 - [14C]O[18O] 5.977e-21 5.987e-21 -20.224 -20.223 0.001 - [14C]O3-2 4.097e-21 2.872e-21 -20.388 -20.542 -0.154 - CaH[14C]O2[18O]+ 2.910e-22 2.670e-22 -21.536 -21.574 -0.037 - CaH[14C]O[18O]O+ 2.910e-22 2.670e-22 -21.536 -21.574 -0.037 - CaH[14C][18O]O2+ 2.910e-22 2.670e-22 -21.536 -21.574 -0.037 - Ca[14C]O2[18O] 4.785e-23 4.793e-23 -22.320 -22.319 0.001 - H[14C]O[18O]2- 2.749e-23 2.515e-23 -22.561 -22.599 -0.039 - H[14C][18O]2O- 2.749e-23 2.515e-23 -22.561 -22.599 -0.039 - H[14C][18O]O[18O]- 2.749e-23 2.515e-23 -22.561 -22.599 -0.039 - [14C]O2[18O]-2 2.452e-23 1.719e-23 -22.610 -22.765 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 1.505e-16 - O[18O] 1.502e-16 1.505e-16 -15.823 -15.823 0.001 - [18O]2 1.499e-19 1.501e-19 -18.824 -18.824 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.926 -123.925 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 6.625e-40 + H2 3.313e-40 3.318e-40 -39.480 -39.479 0.001 (0) +O(0) 7.560e-14 + O2 3.765e-14 3.771e-14 -13.424 -13.424 0.001 (0) + O[18O] 1.502e-16 1.505e-16 -15.823 -15.823 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.881 -125.881 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -138.767 -138.766 0.001 (0) +[14C](4) 8.548e-18 + H[14C]O3- 6.905e-18 6.318e-18 -17.161 -17.199 -0.039 (0) + [14C]O2 1.437e-18 1.440e-18 -17.842 -17.842 0.001 (0) + CaH[14C]O3+ 1.459e-19 1.338e-19 -18.836 -18.874 -0.037 (0) + H[14C]O2[18O]- 1.378e-20 1.260e-20 -19.861 -19.899 -0.039 (0) + H[14C]O[18O]O- 1.378e-20 1.260e-20 -19.861 -19.899 -0.039 (0) + H[14C][18O]O2- 1.378e-20 1.260e-20 -19.861 -19.899 -0.039 (0) + Ca[14C]O3 7.994e-21 8.007e-21 -20.097 -20.097 0.001 (0) + [14C]O[18O] 5.977e-21 5.987e-21 -20.224 -20.223 0.001 (0) + [14C]O3-2 4.097e-21 2.872e-21 -20.388 -20.542 -0.154 (0) + CaH[14C]O2[18O]+ 2.910e-22 2.670e-22 -21.536 -21.574 -0.037 (0) + CaH[14C]O[18O]O+ 2.910e-22 2.670e-22 -21.536 -21.574 -0.037 (0) + CaH[14C][18O]O2+ 2.910e-22 2.670e-22 -21.536 -21.574 -0.037 (0) + Ca[14C]O2[18O] 4.785e-23 4.793e-23 -22.320 -22.319 0.001 (0) + H[14C]O[18O]2- 2.749e-23 2.515e-23 -22.561 -22.599 -0.039 (0) + H[14C][18O]2O- 2.749e-23 2.515e-23 -22.561 -22.599 -0.039 (0) + H[14C][18O]O[18O]- 2.749e-23 2.515e-23 -22.561 -22.599 -0.039 (0) + [14C]O2[18O]-2 2.452e-23 1.719e-23 -22.610 -22.765 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 1.505e-16 + O[18O] 1.502e-16 1.505e-16 -15.823 -15.823 0.001 (0) + [18O]2 1.499e-19 1.501e-19 -18.824 -18.824 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -22203,99 +22203,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -124.003 -124.002 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 6.338e-40 - H2 3.169e-40 3.174e-40 -39.499 -39.498 0.001 -O(0) 8.260e-14 - O2 4.114e-14 4.121e-14 -13.386 -13.385 0.001 - O[18O] 1.642e-16 1.644e-16 -15.785 -15.784 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.958 -125.958 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -138.879 -138.879 0.001 -[14C](4) 7.875e-18 - H[14C]O3- 6.361e-18 5.820e-18 -17.196 -17.235 -0.039 - [14C]O2 1.324e-18 1.326e-18 -17.878 -17.877 0.001 - CaH[14C]O3+ 1.344e-19 1.233e-19 -18.872 -18.909 -0.037 - H[14C]O2[18O]- 1.269e-20 1.161e-20 -19.897 -19.935 -0.039 - H[14C]O[18O]O- 1.269e-20 1.161e-20 -19.897 -19.935 -0.039 - H[14C][18O]O2- 1.269e-20 1.161e-20 -19.897 -19.935 -0.039 - Ca[14C]O3 7.364e-21 7.376e-21 -20.133 -20.132 0.001 - [14C]O[18O] 5.506e-21 5.515e-21 -20.259 -20.258 0.001 - [14C]O3-2 3.775e-21 2.646e-21 -20.423 -20.577 -0.154 - CaH[14C]O2[18O]+ 2.681e-22 2.460e-22 -21.572 -21.609 -0.037 - CaH[14C]O[18O]O+ 2.681e-22 2.460e-22 -21.572 -21.609 -0.037 - CaH[14C][18O]O2+ 2.681e-22 2.460e-22 -21.572 -21.609 -0.037 - Ca[14C]O2[18O] 4.408e-23 4.415e-23 -22.356 -22.355 0.001 - H[14C]O[18O]2- 2.532e-23 2.317e-23 -22.597 -22.635 -0.039 - H[14C][18O]2O- 2.532e-23 2.317e-23 -22.597 -22.635 -0.039 - H[14C][18O]O[18O]- 2.532e-23 2.317e-23 -22.597 -22.635 -0.039 - [14C]O2[18O]-2 2.259e-23 1.584e-23 -22.646 -22.800 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 1.645e-16 - O[18O] 1.642e-16 1.644e-16 -15.785 -15.784 0.001 - [18O]2 1.638e-19 1.640e-19 -18.786 -18.785 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -124.003 -124.002 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 6.338e-40 + H2 3.169e-40 3.174e-40 -39.499 -39.498 0.001 (0) +O(0) 8.260e-14 + O2 4.114e-14 4.121e-14 -13.386 -13.385 0.001 (0) + O[18O] 1.642e-16 1.644e-16 -15.785 -15.784 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.958 -125.958 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -138.879 -138.879 0.001 (0) +[14C](4) 7.875e-18 + H[14C]O3- 6.361e-18 5.820e-18 -17.196 -17.235 -0.039 (0) + [14C]O2 1.324e-18 1.326e-18 -17.878 -17.877 0.001 (0) + CaH[14C]O3+ 1.344e-19 1.233e-19 -18.872 -18.909 -0.037 (0) + H[14C]O2[18O]- 1.269e-20 1.161e-20 -19.897 -19.935 -0.039 (0) + H[14C]O[18O]O- 1.269e-20 1.161e-20 -19.897 -19.935 -0.039 (0) + H[14C][18O]O2- 1.269e-20 1.161e-20 -19.897 -19.935 -0.039 (0) + Ca[14C]O3 7.364e-21 7.376e-21 -20.133 -20.132 0.001 (0) + [14C]O[18O] 5.506e-21 5.515e-21 -20.259 -20.258 0.001 (0) + [14C]O3-2 3.775e-21 2.646e-21 -20.423 -20.577 -0.154 (0) + CaH[14C]O2[18O]+ 2.681e-22 2.460e-22 -21.572 -21.609 -0.037 (0) + CaH[14C]O[18O]O+ 2.681e-22 2.460e-22 -21.572 -21.609 -0.037 (0) + CaH[14C][18O]O2+ 2.681e-22 2.460e-22 -21.572 -21.609 -0.037 (0) + Ca[14C]O2[18O] 4.408e-23 4.415e-23 -22.356 -22.355 0.001 (0) + H[14C]O[18O]2- 2.532e-23 2.317e-23 -22.597 -22.635 -0.039 (0) + H[14C][18O]2O- 2.532e-23 2.317e-23 -22.597 -22.635 -0.039 (0) + H[14C][18O]O[18O]- 2.532e-23 2.317e-23 -22.597 -22.635 -0.039 (0) + [14C]O2[18O]-2 2.259e-23 1.584e-23 -22.646 -22.800 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 1.645e-16 + O[18O] 1.642e-16 1.644e-16 -15.785 -15.784 0.001 (0) + [18O]2 1.638e-19 1.640e-19 -18.786 -18.785 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -22475,99 +22475,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -124.222 -124.221 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 5.588e-40 - H2 2.794e-40 2.799e-40 -39.554 -39.553 0.001 -O(0) 1.063e-13 - O2 5.292e-14 5.301e-14 -13.276 -13.276 0.001 - O[18O] 2.112e-16 2.115e-16 -15.675 -15.675 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -126.177 -126.176 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.134 -139.133 0.001 -[14C](4) 7.255e-18 - H[14C]O3- 5.860e-18 5.361e-18 -17.232 -17.271 -0.039 - [14C]O2 1.220e-18 1.222e-18 -17.914 -17.913 0.001 - CaH[14C]O3+ 1.238e-19 1.136e-19 -18.907 -18.945 -0.037 - H[14C]O2[18O]- 1.169e-20 1.070e-20 -19.932 -19.971 -0.039 - H[14C]O[18O]O- 1.169e-20 1.070e-20 -19.932 -19.971 -0.039 - H[14C][18O]O2- 1.169e-20 1.070e-20 -19.932 -19.971 -0.039 - Ca[14C]O3 6.784e-21 6.795e-21 -20.169 -20.168 0.001 - [14C]O[18O] 5.072e-21 5.081e-21 -20.295 -20.294 0.001 - [14C]O3-2 3.477e-21 2.437e-21 -20.459 -20.613 -0.154 - CaH[14C]O2[18O]+ 2.470e-22 2.266e-22 -21.607 -21.645 -0.037 - CaH[14C]O[18O]O+ 2.470e-22 2.266e-22 -21.607 -21.645 -0.037 - CaH[14C][18O]O2+ 2.470e-22 2.266e-22 -21.607 -21.645 -0.037 - Ca[14C]O2[18O] 4.061e-23 4.067e-23 -22.391 -22.391 0.001 - H[14C]O[18O]2- 2.333e-23 2.134e-23 -22.632 -22.671 -0.039 - H[14C][18O]2O- 2.333e-23 2.134e-23 -22.632 -22.671 -0.039 - H[14C][18O]O[18O]- 2.333e-23 2.134e-23 -22.632 -22.671 -0.039 - [14C]O2[18O]-2 2.081e-23 1.459e-23 -22.682 -22.836 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.116e-16 - O[18O] 2.112e-16 2.115e-16 -15.675 -15.675 0.001 - [18O]2 2.107e-19 2.110e-19 -18.676 -18.676 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -124.222 -124.221 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 5.588e-40 + H2 2.794e-40 2.799e-40 -39.554 -39.553 0.001 (0) +O(0) 1.063e-13 + O2 5.292e-14 5.301e-14 -13.276 -13.276 0.001 (0) + O[18O] 2.112e-16 2.115e-16 -15.675 -15.675 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -126.177 -126.176 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.134 -139.133 0.001 (0) +[14C](4) 7.255e-18 + H[14C]O3- 5.860e-18 5.361e-18 -17.232 -17.271 -0.039 (0) + [14C]O2 1.220e-18 1.222e-18 -17.914 -17.913 0.001 (0) + CaH[14C]O3+ 1.238e-19 1.136e-19 -18.907 -18.945 -0.037 (0) + H[14C]O2[18O]- 1.169e-20 1.070e-20 -19.932 -19.971 -0.039 (0) + H[14C]O[18O]O- 1.169e-20 1.070e-20 -19.932 -19.971 -0.039 (0) + H[14C][18O]O2- 1.169e-20 1.070e-20 -19.932 -19.971 -0.039 (0) + Ca[14C]O3 6.784e-21 6.795e-21 -20.169 -20.168 0.001 (0) + [14C]O[18O] 5.072e-21 5.081e-21 -20.295 -20.294 0.001 (0) + [14C]O3-2 3.477e-21 2.437e-21 -20.459 -20.613 -0.154 (0) + CaH[14C]O2[18O]+ 2.470e-22 2.266e-22 -21.607 -21.645 -0.037 (0) + CaH[14C]O[18O]O+ 2.470e-22 2.266e-22 -21.607 -21.645 -0.037 (0) + CaH[14C][18O]O2+ 2.470e-22 2.266e-22 -21.607 -21.645 -0.037 (0) + Ca[14C]O2[18O] 4.061e-23 4.067e-23 -22.391 -22.391 0.001 (0) + H[14C]O[18O]2- 2.333e-23 2.134e-23 -22.632 -22.671 -0.039 (0) + H[14C][18O]2O- 2.333e-23 2.134e-23 -22.632 -22.671 -0.039 (0) + H[14C][18O]O[18O]- 2.333e-23 2.134e-23 -22.632 -22.671 -0.039 (0) + [14C]O2[18O]-2 2.081e-23 1.459e-23 -22.682 -22.836 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.116e-16 + O[18O] 2.112e-16 2.115e-16 -15.675 -15.675 0.001 (0) + [18O]2 2.107e-19 2.110e-19 -18.676 -18.676 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -22747,99 +22747,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -124.194 -124.193 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 5.679e-40 - H2 2.840e-40 2.844e-40 -39.547 -39.546 0.001 -O(0) 1.029e-13 - O2 5.124e-14 5.132e-14 -13.290 -13.290 0.001 - O[18O] 2.045e-16 2.048e-16 -15.689 -15.689 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -126.149 -126.148 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.141 -139.141 0.001 -[14C](4) 6.683e-18 - H[14C]O3- 5.398e-18 4.939e-18 -17.268 -17.306 -0.039 - [14C]O2 1.124e-18 1.126e-18 -17.949 -17.949 0.001 - CaH[14C]O3+ 1.140e-19 1.046e-19 -18.943 -18.980 -0.037 - H[14C]O2[18O]- 1.077e-20 9.855e-21 -19.968 -20.006 -0.039 - H[14C]O[18O]O- 1.077e-20 9.855e-21 -19.968 -20.006 -0.039 - H[14C][18O]O2- 1.077e-20 9.855e-21 -19.968 -20.006 -0.039 - Ca[14C]O3 6.250e-21 6.260e-21 -20.204 -20.203 0.001 - [14C]O[18O] 4.673e-21 4.681e-21 -20.330 -20.330 0.001 - [14C]O3-2 3.203e-21 2.245e-21 -20.494 -20.649 -0.154 - CaH[14C]O2[18O]+ 2.275e-22 2.087e-22 -21.643 -21.680 -0.037 - CaH[14C]O[18O]O+ 2.275e-22 2.087e-22 -21.643 -21.680 -0.037 - CaH[14C][18O]O2+ 2.275e-22 2.087e-22 -21.643 -21.680 -0.037 - Ca[14C]O2[18O] 3.741e-23 3.747e-23 -22.427 -22.426 0.001 - H[14C]O[18O]2- 2.149e-23 1.966e-23 -22.668 -22.706 -0.039 - H[14C][18O]2O- 2.149e-23 1.966e-23 -22.668 -22.706 -0.039 - H[14C][18O]O[18O]- 2.149e-23 1.966e-23 -22.668 -22.706 -0.039 - [14C]O2[18O]-2 1.917e-23 1.344e-23 -22.717 -22.872 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.049e-16 - O[18O] 2.045e-16 2.048e-16 -15.689 -15.689 0.001 - [18O]2 2.040e-19 2.043e-19 -18.690 -18.690 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -124.194 -124.193 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 5.679e-40 + H2 2.840e-40 2.844e-40 -39.547 -39.546 0.001 (0) +O(0) 1.029e-13 + O2 5.124e-14 5.132e-14 -13.290 -13.290 0.001 (0) + O[18O] 2.045e-16 2.048e-16 -15.689 -15.689 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -126.149 -126.148 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.141 -139.141 0.001 (0) +[14C](4) 6.683e-18 + H[14C]O3- 5.398e-18 4.939e-18 -17.268 -17.306 -0.039 (0) + [14C]O2 1.124e-18 1.126e-18 -17.949 -17.949 0.001 (0) + CaH[14C]O3+ 1.140e-19 1.046e-19 -18.943 -18.980 -0.037 (0) + H[14C]O2[18O]- 1.077e-20 9.855e-21 -19.968 -20.006 -0.039 (0) + H[14C]O[18O]O- 1.077e-20 9.855e-21 -19.968 -20.006 -0.039 (0) + H[14C][18O]O2- 1.077e-20 9.855e-21 -19.968 -20.006 -0.039 (0) + Ca[14C]O3 6.250e-21 6.260e-21 -20.204 -20.203 0.001 (0) + [14C]O[18O] 4.673e-21 4.681e-21 -20.330 -20.330 0.001 (0) + [14C]O3-2 3.203e-21 2.245e-21 -20.494 -20.649 -0.154 (0) + CaH[14C]O2[18O]+ 2.275e-22 2.087e-22 -21.643 -21.680 -0.037 (0) + CaH[14C]O[18O]O+ 2.275e-22 2.087e-22 -21.643 -21.680 -0.037 (0) + CaH[14C][18O]O2+ 2.275e-22 2.087e-22 -21.643 -21.680 -0.037 (0) + Ca[14C]O2[18O] 3.741e-23 3.747e-23 -22.427 -22.426 0.001 (0) + H[14C]O[18O]2- 2.149e-23 1.966e-23 -22.668 -22.706 -0.039 (0) + H[14C][18O]2O- 2.149e-23 1.966e-23 -22.668 -22.706 -0.039 (0) + H[14C][18O]O[18O]- 2.149e-23 1.966e-23 -22.668 -22.706 -0.039 (0) + [14C]O2[18O]-2 1.917e-23 1.344e-23 -22.717 -22.872 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.049e-16 + O[18O] 2.045e-16 2.048e-16 -15.689 -15.689 0.001 (0) + [18O]2 2.040e-19 2.043e-19 -18.690 -18.690 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -23019,99 +23019,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -124.150 -124.150 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 5.823e-40 - H2 2.912e-40 2.916e-40 -39.536 -39.535 0.001 -O(0) 9.786e-14 - O2 4.874e-14 4.882e-14 -13.312 -13.311 0.001 - O[18O] 1.945e-16 1.948e-16 -15.711 -15.710 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -126.106 -126.105 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.134 -139.133 0.001 -[14C](4) 6.157e-18 - H[14C]O3- 4.973e-18 4.550e-18 -17.303 -17.342 -0.039 - [14C]O2 1.035e-18 1.037e-18 -17.985 -17.984 0.001 - CaH[14C]O3+ 1.050e-19 9.637e-20 -18.979 -19.016 -0.037 - H[14C]O2[18O]- 9.922e-21 9.078e-21 -20.003 -20.042 -0.039 - H[14C]O[18O]O- 9.922e-21 9.078e-21 -20.003 -20.042 -0.039 - H[14C][18O]O2- 9.922e-21 9.078e-21 -20.003 -20.042 -0.039 - Ca[14C]O3 5.757e-21 5.767e-21 -20.240 -20.239 0.001 - [14C]O[18O] 4.305e-21 4.312e-21 -20.366 -20.365 0.001 - [14C]O3-2 2.951e-21 2.068e-21 -20.530 -20.684 -0.154 - CaH[14C]O2[18O]+ 2.096e-22 1.923e-22 -21.679 -21.716 -0.037 - CaH[14C]O[18O]O+ 2.096e-22 1.923e-22 -21.679 -21.716 -0.037 - CaH[14C][18O]O2+ 2.096e-22 1.923e-22 -21.679 -21.716 -0.037 - Ca[14C]O2[18O] 3.446e-23 3.452e-23 -22.463 -22.462 0.001 - H[14C]O[18O]2- 1.980e-23 1.811e-23 -22.703 -22.742 -0.039 - H[14C][18O]2O- 1.980e-23 1.811e-23 -22.703 -22.742 -0.039 - H[14C][18O]O[18O]- 1.980e-23 1.811e-23 -22.703 -22.742 -0.039 - [14C]O2[18O]-2 1.766e-23 1.238e-23 -22.753 -22.907 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 1.949e-16 - O[18O] 1.945e-16 1.948e-16 -15.711 -15.710 0.001 - [18O]2 1.940e-19 1.943e-19 -18.712 -18.711 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -124.150 -124.150 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 5.823e-40 + H2 2.912e-40 2.916e-40 -39.536 -39.535 0.001 (0) +O(0) 9.786e-14 + O2 4.874e-14 4.882e-14 -13.312 -13.311 0.001 (0) + O[18O] 1.945e-16 1.948e-16 -15.711 -15.710 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -126.106 -126.105 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.134 -139.133 0.001 (0) +[14C](4) 6.157e-18 + H[14C]O3- 4.973e-18 4.550e-18 -17.303 -17.342 -0.039 (0) + [14C]O2 1.035e-18 1.037e-18 -17.985 -17.984 0.001 (0) + CaH[14C]O3+ 1.050e-19 9.637e-20 -18.979 -19.016 -0.037 (0) + H[14C]O2[18O]- 9.922e-21 9.078e-21 -20.003 -20.042 -0.039 (0) + H[14C]O[18O]O- 9.922e-21 9.078e-21 -20.003 -20.042 -0.039 (0) + H[14C][18O]O2- 9.922e-21 9.078e-21 -20.003 -20.042 -0.039 (0) + Ca[14C]O3 5.757e-21 5.767e-21 -20.240 -20.239 0.001 (0) + [14C]O[18O] 4.305e-21 4.312e-21 -20.366 -20.365 0.001 (0) + [14C]O3-2 2.951e-21 2.068e-21 -20.530 -20.684 -0.154 (0) + CaH[14C]O2[18O]+ 2.096e-22 1.923e-22 -21.679 -21.716 -0.037 (0) + CaH[14C]O[18O]O+ 2.096e-22 1.923e-22 -21.679 -21.716 -0.037 (0) + CaH[14C][18O]O2+ 2.096e-22 1.923e-22 -21.679 -21.716 -0.037 (0) + Ca[14C]O2[18O] 3.446e-23 3.452e-23 -22.463 -22.462 0.001 (0) + H[14C]O[18O]2- 1.980e-23 1.811e-23 -22.703 -22.742 -0.039 (0) + H[14C][18O]2O- 1.980e-23 1.811e-23 -22.703 -22.742 -0.039 (0) + H[14C][18O]O[18O]- 1.980e-23 1.811e-23 -22.703 -22.742 -0.039 (0) + [14C]O2[18O]-2 1.766e-23 1.238e-23 -22.753 -22.907 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 1.949e-16 + O[18O] 1.945e-16 1.948e-16 -15.711 -15.710 0.001 (0) + [18O]2 1.940e-19 1.943e-19 -18.712 -18.711 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -23291,99 +23291,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -124.282 -124.281 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 5.398e-40 - H2 2.699e-40 2.703e-40 -39.569 -39.568 0.001 -O(0) 1.139e-13 - O2 5.672e-14 5.681e-14 -13.246 -13.246 0.001 - O[18O] 2.263e-16 2.267e-16 -15.645 -15.645 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -126.237 -126.237 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.301 -139.300 0.001 -[14C](4) 5.672e-18 - H[14C]O3- 4.581e-18 4.192e-18 -17.339 -17.378 -0.039 - [14C]O2 9.537e-19 9.552e-19 -18.021 -18.020 0.001 - CaH[14C]O3+ 9.677e-20 8.878e-20 -19.014 -19.052 -0.037 - H[14C]O2[18O]- 9.140e-21 8.363e-21 -20.039 -20.078 -0.039 - H[14C]O[18O]O- 9.140e-21 8.363e-21 -20.039 -20.078 -0.039 - H[14C][18O]O2- 9.140e-21 8.363e-21 -20.039 -20.078 -0.039 - Ca[14C]O3 5.304e-21 5.313e-21 -20.275 -20.275 0.001 - [14C]O[18O] 3.966e-21 3.972e-21 -20.402 -20.401 0.001 - [14C]O3-2 2.718e-21 1.905e-21 -20.566 -20.720 -0.154 - CaH[14C]O2[18O]+ 1.931e-22 1.771e-22 -21.714 -21.752 -0.037 - CaH[14C]O[18O]O+ 1.931e-22 1.771e-22 -21.714 -21.752 -0.037 - CaH[14C][18O]O2+ 1.931e-22 1.771e-22 -21.714 -21.752 -0.037 - Ca[14C]O2[18O] 3.175e-23 3.180e-23 -22.498 -22.498 0.001 - H[14C]O[18O]2- 1.824e-23 1.669e-23 -22.739 -22.778 -0.039 - H[14C][18O]2O- 1.824e-23 1.669e-23 -22.739 -22.778 -0.039 - H[14C][18O]O[18O]- 1.824e-23 1.669e-23 -22.739 -22.778 -0.039 - [14C]O2[18O]-2 1.627e-23 1.141e-23 -22.789 -22.943 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.268e-16 - O[18O] 2.263e-16 2.267e-16 -15.645 -15.645 0.001 - [18O]2 2.258e-19 2.262e-19 -18.646 -18.646 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -124.282 -124.281 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 5.398e-40 + H2 2.699e-40 2.703e-40 -39.569 -39.568 0.001 (0) +O(0) 1.139e-13 + O2 5.672e-14 5.681e-14 -13.246 -13.246 0.001 (0) + O[18O] 2.263e-16 2.267e-16 -15.645 -15.645 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -126.237 -126.237 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.301 -139.300 0.001 (0) +[14C](4) 5.672e-18 + H[14C]O3- 4.581e-18 4.192e-18 -17.339 -17.378 -0.039 (0) + [14C]O2 9.537e-19 9.552e-19 -18.021 -18.020 0.001 (0) + CaH[14C]O3+ 9.677e-20 8.878e-20 -19.014 -19.052 -0.037 (0) + H[14C]O2[18O]- 9.140e-21 8.363e-21 -20.039 -20.078 -0.039 (0) + H[14C]O[18O]O- 9.140e-21 8.363e-21 -20.039 -20.078 -0.039 (0) + H[14C][18O]O2- 9.140e-21 8.363e-21 -20.039 -20.078 -0.039 (0) + Ca[14C]O3 5.304e-21 5.313e-21 -20.275 -20.275 0.001 (0) + [14C]O[18O] 3.966e-21 3.972e-21 -20.402 -20.401 0.001 (0) + [14C]O3-2 2.718e-21 1.905e-21 -20.566 -20.720 -0.154 (0) + CaH[14C]O2[18O]+ 1.931e-22 1.771e-22 -21.714 -21.752 -0.037 (0) + CaH[14C]O[18O]O+ 1.931e-22 1.771e-22 -21.714 -21.752 -0.037 (0) + CaH[14C][18O]O2+ 1.931e-22 1.771e-22 -21.714 -21.752 -0.037 (0) + Ca[14C]O2[18O] 3.175e-23 3.180e-23 -22.498 -22.498 0.001 (0) + H[14C]O[18O]2- 1.824e-23 1.669e-23 -22.739 -22.778 -0.039 (0) + H[14C][18O]2O- 1.824e-23 1.669e-23 -22.739 -22.778 -0.039 (0) + H[14C][18O]O[18O]- 1.824e-23 1.669e-23 -22.739 -22.778 -0.039 (0) + [14C]O2[18O]-2 1.627e-23 1.141e-23 -22.789 -22.943 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.268e-16 + O[18O] 2.263e-16 2.267e-16 -15.645 -15.645 0.001 (0) + [18O]2 2.258e-19 2.262e-19 -18.646 -18.646 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -23563,99 +23563,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -124.169 -124.168 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 5.761e-40 - H2 2.881e-40 2.885e-40 -39.540 -39.540 0.001 -O(0) 9.997e-14 - O2 4.978e-14 4.987e-14 -13.303 -13.302 0.001 - O[18O] 1.987e-16 1.990e-16 -15.702 -15.701 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -126.124 -126.123 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.223 -139.223 0.001 -[14C](4) 5.225e-18 - H[14C]O3- 4.220e-18 3.861e-18 -17.375 -17.413 -0.039 - [14C]O2 8.785e-19 8.800e-19 -18.056 -18.056 0.001 - CaH[14C]O3+ 8.915e-20 8.179e-20 -19.050 -19.087 -0.037 - H[14C]O2[18O]- 8.420e-21 7.704e-21 -20.075 -20.113 -0.039 - H[14C]O[18O]O- 8.420e-21 7.704e-21 -20.075 -20.113 -0.039 - H[14C][18O]O2- 8.420e-21 7.704e-21 -20.075 -20.113 -0.039 - Ca[14C]O3 4.886e-21 4.894e-21 -20.311 -20.310 0.001 - [14C]O[18O] 3.653e-21 3.659e-21 -20.437 -20.437 0.001 - [14C]O3-2 2.504e-21 1.755e-21 -20.601 -20.756 -0.154 - CaH[14C]O2[18O]+ 1.779e-22 1.632e-22 -21.750 -21.787 -0.037 - CaH[14C]O[18O]O+ 1.779e-22 1.632e-22 -21.750 -21.787 -0.037 - CaH[14C][18O]O2+ 1.779e-22 1.632e-22 -21.750 -21.787 -0.037 - Ca[14C]O2[18O] 2.925e-23 2.929e-23 -22.534 -22.533 0.001 - H[14C]O[18O]2- 1.680e-23 1.537e-23 -22.775 -22.813 -0.039 - H[14C][18O]2O- 1.680e-23 1.537e-23 -22.775 -22.813 -0.039 - H[14C][18O]O[18O]- 1.680e-23 1.537e-23 -22.775 -22.813 -0.039 - [14C]O2[18O]-2 1.499e-23 1.051e-23 -22.824 -22.979 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 1.991e-16 - O[18O] 1.987e-16 1.990e-16 -15.702 -15.701 0.001 - [18O]2 1.982e-19 1.985e-19 -18.703 -18.702 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -124.169 -124.168 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 5.761e-40 + H2 2.881e-40 2.885e-40 -39.540 -39.540 0.001 (0) +O(0) 9.997e-14 + O2 4.978e-14 4.987e-14 -13.303 -13.302 0.001 (0) + O[18O] 1.987e-16 1.990e-16 -15.702 -15.701 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -126.124 -126.123 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.223 -139.223 0.001 (0) +[14C](4) 5.225e-18 + H[14C]O3- 4.220e-18 3.861e-18 -17.375 -17.413 -0.039 (0) + [14C]O2 8.785e-19 8.800e-19 -18.056 -18.056 0.001 (0) + CaH[14C]O3+ 8.915e-20 8.179e-20 -19.050 -19.087 -0.037 (0) + H[14C]O2[18O]- 8.420e-21 7.704e-21 -20.075 -20.113 -0.039 (0) + H[14C]O[18O]O- 8.420e-21 7.704e-21 -20.075 -20.113 -0.039 (0) + H[14C][18O]O2- 8.420e-21 7.704e-21 -20.075 -20.113 -0.039 (0) + Ca[14C]O3 4.886e-21 4.894e-21 -20.311 -20.310 0.001 (0) + [14C]O[18O] 3.653e-21 3.659e-21 -20.437 -20.437 0.001 (0) + [14C]O3-2 2.504e-21 1.755e-21 -20.601 -20.756 -0.154 (0) + CaH[14C]O2[18O]+ 1.779e-22 1.632e-22 -21.750 -21.787 -0.037 (0) + CaH[14C]O[18O]O+ 1.779e-22 1.632e-22 -21.750 -21.787 -0.037 (0) + CaH[14C][18O]O2+ 1.779e-22 1.632e-22 -21.750 -21.787 -0.037 (0) + Ca[14C]O2[18O] 2.925e-23 2.929e-23 -22.534 -22.533 0.001 (0) + H[14C]O[18O]2- 1.680e-23 1.537e-23 -22.775 -22.813 -0.039 (0) + H[14C][18O]2O- 1.680e-23 1.537e-23 -22.775 -22.813 -0.039 (0) + H[14C][18O]O[18O]- 1.680e-23 1.537e-23 -22.775 -22.813 -0.039 (0) + [14C]O2[18O]-2 1.499e-23 1.051e-23 -22.824 -22.979 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 1.991e-16 + O[18O] 1.987e-16 1.990e-16 -15.702 -15.701 0.001 (0) + [18O]2 1.982e-19 1.985e-19 -18.703 -18.702 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -23835,99 +23835,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -124.372 -124.371 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 5.126e-40 - H2 2.563e-40 2.567e-40 -39.591 -39.591 0.001 -O(0) 1.263e-13 - O2 6.290e-14 6.300e-14 -13.201 -13.201 0.001 - O[18O] 2.510e-16 2.514e-16 -15.600 -15.600 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -126.327 -126.326 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.462 -139.461 0.001 -[14C](4) 4.813e-18 - H[14C]O3- 3.888e-18 3.557e-18 -17.410 -17.449 -0.039 - [14C]O2 8.093e-19 8.107e-19 -18.092 -18.091 0.001 - CaH[14C]O3+ 8.212e-20 7.534e-20 -19.086 -19.123 -0.037 - H[14C]O2[18O]- 7.757e-21 7.097e-21 -20.110 -20.149 -0.039 - H[14C]O[18O]O- 7.757e-21 7.097e-21 -20.110 -20.149 -0.039 - H[14C][18O]O2- 7.757e-21 7.097e-21 -20.110 -20.149 -0.039 - Ca[14C]O3 4.501e-21 4.509e-21 -20.347 -20.346 0.001 - [14C]O[18O] 3.365e-21 3.371e-21 -20.473 -20.472 0.001 - [14C]O3-2 2.307e-21 1.617e-21 -20.637 -20.791 -0.154 - CaH[14C]O2[18O]+ 1.639e-22 1.503e-22 -21.786 -21.823 -0.037 - CaH[14C]O[18O]O+ 1.639e-22 1.503e-22 -21.786 -21.823 -0.037 - CaH[14C][18O]O2+ 1.639e-22 1.503e-22 -21.786 -21.823 -0.037 - Ca[14C]O2[18O] 2.694e-23 2.699e-23 -22.570 -22.569 0.001 - H[14C]O[18O]2- 1.548e-23 1.416e-23 -22.810 -22.849 -0.039 - H[14C][18O]2O- 1.548e-23 1.416e-23 -22.810 -22.849 -0.039 - H[14C][18O]O[18O]- 1.548e-23 1.416e-23 -22.810 -22.849 -0.039 - [14C]O2[18O]-2 1.381e-23 9.679e-24 -22.860 -23.014 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.515e-16 - O[18O] 2.510e-16 2.514e-16 -15.600 -15.600 0.001 - [18O]2 2.504e-19 2.508e-19 -18.601 -18.601 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -124.372 -124.371 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 5.126e-40 + H2 2.563e-40 2.567e-40 -39.591 -39.591 0.001 (0) +O(0) 1.263e-13 + O2 6.290e-14 6.300e-14 -13.201 -13.201 0.001 (0) + O[18O] 2.510e-16 2.514e-16 -15.600 -15.600 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -126.327 -126.326 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.462 -139.461 0.001 (0) +[14C](4) 4.813e-18 + H[14C]O3- 3.888e-18 3.557e-18 -17.410 -17.449 -0.039 (0) + [14C]O2 8.093e-19 8.107e-19 -18.092 -18.091 0.001 (0) + CaH[14C]O3+ 8.212e-20 7.534e-20 -19.086 -19.123 -0.037 (0) + H[14C]O2[18O]- 7.757e-21 7.097e-21 -20.110 -20.149 -0.039 (0) + H[14C]O[18O]O- 7.757e-21 7.097e-21 -20.110 -20.149 -0.039 (0) + H[14C][18O]O2- 7.757e-21 7.097e-21 -20.110 -20.149 -0.039 (0) + Ca[14C]O3 4.501e-21 4.509e-21 -20.347 -20.346 0.001 (0) + [14C]O[18O] 3.365e-21 3.371e-21 -20.473 -20.472 0.001 (0) + [14C]O3-2 2.307e-21 1.617e-21 -20.637 -20.791 -0.154 (0) + CaH[14C]O2[18O]+ 1.639e-22 1.503e-22 -21.786 -21.823 -0.037 (0) + CaH[14C]O[18O]O+ 1.639e-22 1.503e-22 -21.786 -21.823 -0.037 (0) + CaH[14C][18O]O2+ 1.639e-22 1.503e-22 -21.786 -21.823 -0.037 (0) + Ca[14C]O2[18O] 2.694e-23 2.699e-23 -22.570 -22.569 0.001 (0) + H[14C]O[18O]2- 1.548e-23 1.416e-23 -22.810 -22.849 -0.039 (0) + H[14C][18O]2O- 1.548e-23 1.416e-23 -22.810 -22.849 -0.039 (0) + H[14C][18O]O[18O]- 1.548e-23 1.416e-23 -22.810 -22.849 -0.039 (0) + [14C]O2[18O]-2 1.381e-23 9.679e-24 -22.860 -23.014 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.515e-16 + O[18O] 2.510e-16 2.514e-16 -15.600 -15.600 0.001 (0) + [18O]2 2.504e-19 2.508e-19 -18.601 -18.601 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -24107,99 +24107,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -124.596 -124.595 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 4.505e-40 - H2 2.252e-40 2.256e-40 -39.647 -39.647 0.001 -O(0) 1.635e-13 - O2 8.143e-14 8.156e-14 -13.089 -13.089 0.001 - O[18O] 3.249e-16 3.255e-16 -15.488 -15.487 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -126.551 -126.551 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.722 -139.721 0.001 -[14C](4) 4.434e-18 - H[14C]O3- 3.581e-18 3.277e-18 -17.446 -17.485 -0.039 - [14C]O2 7.456e-19 7.468e-19 -18.128 -18.127 0.001 - CaH[14C]O3+ 7.566e-20 6.941e-20 -19.121 -19.159 -0.037 - H[14C]O2[18O]- 7.146e-21 6.538e-21 -20.146 -20.185 -0.039 - H[14C]O[18O]O- 7.146e-21 6.538e-21 -20.146 -20.185 -0.039 - H[14C][18O]O2- 7.146e-21 6.538e-21 -20.146 -20.185 -0.039 - Ca[14C]O3 4.147e-21 4.153e-21 -20.382 -20.382 0.001 - [14C]O[18O] 3.100e-21 3.105e-21 -20.509 -20.508 0.001 - [14C]O3-2 2.125e-21 1.490e-21 -20.673 -20.827 -0.154 - CaH[14C]O2[18O]+ 1.509e-22 1.385e-22 -21.821 -21.859 -0.037 - CaH[14C]O[18O]O+ 1.509e-22 1.385e-22 -21.821 -21.859 -0.037 - CaH[14C][18O]O2+ 1.509e-22 1.385e-22 -21.821 -21.859 -0.037 - Ca[14C]O2[18O] 2.482e-23 2.486e-23 -22.605 -22.604 0.001 - H[14C]O[18O]2- 1.426e-23 1.305e-23 -22.846 -22.885 -0.039 - H[14C][18O]2O- 1.426e-23 1.305e-23 -22.846 -22.885 -0.039 - H[14C][18O]O[18O]- 1.426e-23 1.305e-23 -22.846 -22.885 -0.039 - [14C]O2[18O]-2 1.272e-23 8.916e-24 -22.895 -23.050 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.256e-16 - O[18O] 3.249e-16 3.255e-16 -15.488 -15.487 0.001 - [18O]2 3.242e-19 3.247e-19 -18.489 -18.489 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -124.596 -124.595 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 4.505e-40 + H2 2.252e-40 2.256e-40 -39.647 -39.647 0.001 (0) +O(0) 1.635e-13 + O2 8.143e-14 8.156e-14 -13.089 -13.089 0.001 (0) + O[18O] 3.249e-16 3.255e-16 -15.488 -15.487 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -126.551 -126.551 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.722 -139.721 0.001 (0) +[14C](4) 4.434e-18 + H[14C]O3- 3.581e-18 3.277e-18 -17.446 -17.485 -0.039 (0) + [14C]O2 7.456e-19 7.468e-19 -18.128 -18.127 0.001 (0) + CaH[14C]O3+ 7.566e-20 6.941e-20 -19.121 -19.159 -0.037 (0) + H[14C]O2[18O]- 7.146e-21 6.538e-21 -20.146 -20.185 -0.039 (0) + H[14C]O[18O]O- 7.146e-21 6.538e-21 -20.146 -20.185 -0.039 (0) + H[14C][18O]O2- 7.146e-21 6.538e-21 -20.146 -20.185 -0.039 (0) + Ca[14C]O3 4.147e-21 4.153e-21 -20.382 -20.382 0.001 (0) + [14C]O[18O] 3.100e-21 3.105e-21 -20.509 -20.508 0.001 (0) + [14C]O3-2 2.125e-21 1.490e-21 -20.673 -20.827 -0.154 (0) + CaH[14C]O2[18O]+ 1.509e-22 1.385e-22 -21.821 -21.859 -0.037 (0) + CaH[14C]O[18O]O+ 1.509e-22 1.385e-22 -21.821 -21.859 -0.037 (0) + CaH[14C][18O]O2+ 1.509e-22 1.385e-22 -21.821 -21.859 -0.037 (0) + Ca[14C]O2[18O] 2.482e-23 2.486e-23 -22.605 -22.604 0.001 (0) + H[14C]O[18O]2- 1.426e-23 1.305e-23 -22.846 -22.885 -0.039 (0) + H[14C][18O]2O- 1.426e-23 1.305e-23 -22.846 -22.885 -0.039 (0) + H[14C][18O]O[18O]- 1.426e-23 1.305e-23 -22.846 -22.885 -0.039 (0) + [14C]O2[18O]-2 1.272e-23 8.916e-24 -22.895 -23.050 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.256e-16 + O[18O] 3.249e-16 3.255e-16 -15.488 -15.487 0.001 (0) + [18O]2 3.242e-19 3.247e-19 -18.489 -18.489 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -24379,99 +24379,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -124.365 -124.364 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 5.146e-40 - H2 2.573e-40 2.577e-40 -39.590 -39.589 0.001 -O(0) 1.253e-13 - O2 6.241e-14 6.251e-14 -13.205 -13.204 0.001 - O[18O] 2.490e-16 2.495e-16 -15.604 -15.603 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -126.320 -126.320 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.527 -139.526 0.001 -[14C](4) 4.085e-18 - H[14C]O3- 3.299e-18 3.019e-18 -17.482 -17.520 -0.039 - [14C]O2 6.868e-19 6.880e-19 -18.163 -18.162 0.001 - CaH[14C]O3+ 6.970e-20 6.394e-20 -19.157 -19.194 -0.037 - H[14C]O2[18O]- 6.583e-21 6.023e-21 -20.182 -20.220 -0.039 - H[14C]O[18O]O- 6.583e-21 6.023e-21 -20.182 -20.220 -0.039 - H[14C][18O]O2- 6.583e-21 6.023e-21 -20.182 -20.220 -0.039 - Ca[14C]O3 3.820e-21 3.826e-21 -20.418 -20.417 0.001 - [14C]O[18O] 2.856e-21 2.861e-21 -20.544 -20.544 0.001 - [14C]O3-2 1.958e-21 1.372e-21 -20.708 -20.863 -0.154 - CaH[14C]O2[18O]+ 1.391e-22 1.276e-22 -21.857 -21.894 -0.037 - CaH[14C]O[18O]O+ 1.391e-22 1.276e-22 -21.857 -21.894 -0.037 - CaH[14C][18O]O2+ 1.391e-22 1.276e-22 -21.857 -21.894 -0.037 - Ca[14C]O2[18O] 2.286e-23 2.290e-23 -22.641 -22.640 0.001 - H[14C]O[18O]2- 1.313e-23 1.202e-23 -22.882 -22.920 -0.039 - H[14C][18O]2O- 1.313e-23 1.202e-23 -22.882 -22.920 -0.039 - H[14C][18O]O[18O]- 1.313e-23 1.202e-23 -22.882 -22.920 -0.039 - [14C]O2[18O]-2 1.172e-23 8.214e-24 -22.931 -23.085 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.495e-16 - O[18O] 2.490e-16 2.495e-16 -15.604 -15.603 0.001 - [18O]2 2.484e-19 2.489e-19 -18.605 -18.604 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -124.365 -124.364 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 5.146e-40 + H2 2.573e-40 2.577e-40 -39.590 -39.589 0.001 (0) +O(0) 1.253e-13 + O2 6.241e-14 6.251e-14 -13.205 -13.204 0.001 (0) + O[18O] 2.490e-16 2.495e-16 -15.604 -15.603 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -126.320 -126.320 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.527 -139.526 0.001 (0) +[14C](4) 4.085e-18 + H[14C]O3- 3.299e-18 3.019e-18 -17.482 -17.520 -0.039 (0) + [14C]O2 6.868e-19 6.880e-19 -18.163 -18.162 0.001 (0) + CaH[14C]O3+ 6.970e-20 6.394e-20 -19.157 -19.194 -0.037 (0) + H[14C]O2[18O]- 6.583e-21 6.023e-21 -20.182 -20.220 -0.039 (0) + H[14C]O[18O]O- 6.583e-21 6.023e-21 -20.182 -20.220 -0.039 (0) + H[14C][18O]O2- 6.583e-21 6.023e-21 -20.182 -20.220 -0.039 (0) + Ca[14C]O3 3.820e-21 3.826e-21 -20.418 -20.417 0.001 (0) + [14C]O[18O] 2.856e-21 2.861e-21 -20.544 -20.544 0.001 (0) + [14C]O3-2 1.958e-21 1.372e-21 -20.708 -20.863 -0.154 (0) + CaH[14C]O2[18O]+ 1.391e-22 1.276e-22 -21.857 -21.894 -0.037 (0) + CaH[14C]O[18O]O+ 1.391e-22 1.276e-22 -21.857 -21.894 -0.037 (0) + CaH[14C][18O]O2+ 1.391e-22 1.276e-22 -21.857 -21.894 -0.037 (0) + Ca[14C]O2[18O] 2.286e-23 2.290e-23 -22.641 -22.640 0.001 (0) + H[14C]O[18O]2- 1.313e-23 1.202e-23 -22.882 -22.920 -0.039 (0) + H[14C][18O]2O- 1.313e-23 1.202e-23 -22.882 -22.920 -0.039 (0) + H[14C][18O]O[18O]- 1.313e-23 1.202e-23 -22.882 -22.920 -0.039 (0) + [14C]O2[18O]-2 1.172e-23 8.214e-24 -22.931 -23.085 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.495e-16 + O[18O] 2.490e-16 2.495e-16 -15.604 -15.603 0.001 (0) + [18O]2 2.484e-19 2.489e-19 -18.605 -18.604 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -24651,99 +24651,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -124.255 -124.254 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 5.482e-40 - H2 2.741e-40 2.746e-40 -39.562 -39.561 0.001 -O(0) 1.104e-13 - O2 5.499e-14 5.508e-14 -13.260 -13.259 0.001 - O[18O] 2.194e-16 2.198e-16 -15.659 -15.658 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -126.210 -126.210 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.452 -139.452 0.001 -[14C](4) 3.763e-18 - H[14C]O3- 3.039e-18 2.781e-18 -17.517 -17.556 -0.039 - [14C]O2 6.327e-19 6.338e-19 -18.199 -18.198 0.001 - CaH[14C]O3+ 6.421e-20 5.890e-20 -19.192 -19.230 -0.037 - H[14C]O2[18O]- 6.064e-21 5.549e-21 -20.217 -20.256 -0.039 - H[14C]O[18O]O- 6.064e-21 5.549e-21 -20.217 -20.256 -0.039 - H[14C][18O]O2- 6.064e-21 5.549e-21 -20.217 -20.256 -0.039 - Ca[14C]O3 3.519e-21 3.525e-21 -20.454 -20.453 0.001 - [14C]O[18O] 2.631e-21 2.635e-21 -20.580 -20.579 0.001 - [14C]O3-2 1.804e-21 1.264e-21 -20.744 -20.898 -0.154 - CaH[14C]O2[18O]+ 1.281e-22 1.175e-22 -21.892 -21.930 -0.037 - CaH[14C]O[18O]O+ 1.281e-22 1.175e-22 -21.892 -21.930 -0.037 - CaH[14C][18O]O2+ 1.281e-22 1.175e-22 -21.892 -21.930 -0.037 - Ca[14C]O2[18O] 2.106e-23 2.110e-23 -22.676 -22.676 0.001 - H[14C]O[18O]2- 1.210e-23 1.107e-23 -22.917 -22.956 -0.039 - H[14C][18O]2O- 1.210e-23 1.107e-23 -22.917 -22.956 -0.039 - H[14C][18O]O[18O]- 1.210e-23 1.107e-23 -22.917 -22.956 -0.039 - [14C]O2[18O]-2 1.080e-23 7.567e-24 -22.967 -23.121 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.199e-16 - O[18O] 2.194e-16 2.198e-16 -15.659 -15.658 0.001 - [18O]2 2.189e-19 2.193e-19 -18.660 -18.659 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -124.255 -124.254 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 5.482e-40 + H2 2.741e-40 2.746e-40 -39.562 -39.561 0.001 (0) +O(0) 1.104e-13 + O2 5.499e-14 5.508e-14 -13.260 -13.259 0.001 (0) + O[18O] 2.194e-16 2.198e-16 -15.659 -15.658 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -126.210 -126.210 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.452 -139.452 0.001 (0) +[14C](4) 3.763e-18 + H[14C]O3- 3.039e-18 2.781e-18 -17.517 -17.556 -0.039 (0) + [14C]O2 6.327e-19 6.338e-19 -18.199 -18.198 0.001 (0) + CaH[14C]O3+ 6.421e-20 5.890e-20 -19.192 -19.230 -0.037 (0) + H[14C]O2[18O]- 6.064e-21 5.549e-21 -20.217 -20.256 -0.039 (0) + H[14C]O[18O]O- 6.064e-21 5.549e-21 -20.217 -20.256 -0.039 (0) + H[14C][18O]O2- 6.064e-21 5.549e-21 -20.217 -20.256 -0.039 (0) + Ca[14C]O3 3.519e-21 3.525e-21 -20.454 -20.453 0.001 (0) + [14C]O[18O] 2.631e-21 2.635e-21 -20.580 -20.579 0.001 (0) + [14C]O3-2 1.804e-21 1.264e-21 -20.744 -20.898 -0.154 (0) + CaH[14C]O2[18O]+ 1.281e-22 1.175e-22 -21.892 -21.930 -0.037 (0) + CaH[14C]O[18O]O+ 1.281e-22 1.175e-22 -21.892 -21.930 -0.037 (0) + CaH[14C][18O]O2+ 1.281e-22 1.175e-22 -21.892 -21.930 -0.037 (0) + Ca[14C]O2[18O] 2.106e-23 2.110e-23 -22.676 -22.676 0.001 (0) + H[14C]O[18O]2- 1.210e-23 1.107e-23 -22.917 -22.956 -0.039 (0) + H[14C][18O]2O- 1.210e-23 1.107e-23 -22.917 -22.956 -0.039 (0) + H[14C][18O]O[18O]- 1.210e-23 1.107e-23 -22.917 -22.956 -0.039 (0) + [14C]O2[18O]-2 1.080e-23 7.567e-24 -22.967 -23.121 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.199e-16 + O[18O] 2.194e-16 2.198e-16 -15.659 -15.658 0.001 (0) + [18O]2 2.189e-19 2.193e-19 -18.660 -18.659 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -24923,99 +24923,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -124.004 -124.004 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 6.334e-40 - H2 3.167e-40 3.172e-40 -39.499 -39.499 0.001 -O(0) 8.272e-14 - O2 4.120e-14 4.127e-14 -13.385 -13.384 0.001 - O[18O] 1.644e-16 1.647e-16 -15.784 -15.783 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.960 -125.959 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.237 -139.236 0.001 -[14C](4) 3.467e-18 - H[14C]O3- 2.800e-18 2.562e-18 -17.553 -17.591 -0.039 - [14C]O2 5.829e-19 5.838e-19 -18.234 -18.234 0.001 - CaH[14C]O3+ 5.915e-20 5.426e-20 -19.228 -19.265 -0.037 - H[14C]O2[18O]- 5.587e-21 5.112e-21 -20.253 -20.291 -0.039 - H[14C]O[18O]O- 5.587e-21 5.112e-21 -20.253 -20.291 -0.039 - H[14C][18O]O2- 5.587e-21 5.112e-21 -20.253 -20.291 -0.039 - Ca[14C]O3 3.242e-21 3.247e-21 -20.489 -20.489 0.001 - [14C]O[18O] 2.424e-21 2.428e-21 -20.615 -20.615 0.001 - [14C]O3-2 1.662e-21 1.165e-21 -20.779 -20.934 -0.154 - CaH[14C]O2[18O]+ 1.180e-22 1.083e-22 -21.928 -21.965 -0.037 - CaH[14C]O[18O]O+ 1.180e-22 1.083e-22 -21.928 -21.965 -0.037 - CaH[14C][18O]O2+ 1.180e-22 1.083e-22 -21.928 -21.965 -0.037 - Ca[14C]O2[18O] 1.940e-23 1.944e-23 -22.712 -22.711 0.001 - H[14C]O[18O]2- 1.115e-23 1.020e-23 -22.953 -22.991 -0.039 - H[14C][18O]2O- 1.115e-23 1.020e-23 -22.953 -22.991 -0.039 - H[14C][18O]O[18O]- 1.115e-23 1.020e-23 -22.953 -22.991 -0.039 - [14C]O2[18O]-2 9.945e-24 6.971e-24 -23.002 -23.157 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 1.647e-16 - O[18O] 1.644e-16 1.647e-16 -15.784 -15.783 0.001 - [18O]2 1.640e-19 1.643e-19 -18.785 -18.784 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -124.004 -124.004 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 6.334e-40 + H2 3.167e-40 3.172e-40 -39.499 -39.499 0.001 (0) +O(0) 8.272e-14 + O2 4.120e-14 4.127e-14 -13.385 -13.384 0.001 (0) + O[18O] 1.644e-16 1.647e-16 -15.784 -15.783 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.960 -125.959 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.237 -139.236 0.001 (0) +[14C](4) 3.467e-18 + H[14C]O3- 2.800e-18 2.562e-18 -17.553 -17.591 -0.039 (0) + [14C]O2 5.829e-19 5.838e-19 -18.234 -18.234 0.001 (0) + CaH[14C]O3+ 5.915e-20 5.426e-20 -19.228 -19.265 -0.037 (0) + H[14C]O2[18O]- 5.587e-21 5.112e-21 -20.253 -20.291 -0.039 (0) + H[14C]O[18O]O- 5.587e-21 5.112e-21 -20.253 -20.291 -0.039 (0) + H[14C][18O]O2- 5.587e-21 5.112e-21 -20.253 -20.291 -0.039 (0) + Ca[14C]O3 3.242e-21 3.247e-21 -20.489 -20.489 0.001 (0) + [14C]O[18O] 2.424e-21 2.428e-21 -20.615 -20.615 0.001 (0) + [14C]O3-2 1.662e-21 1.165e-21 -20.779 -20.934 -0.154 (0) + CaH[14C]O2[18O]+ 1.180e-22 1.083e-22 -21.928 -21.965 -0.037 (0) + CaH[14C]O[18O]O+ 1.180e-22 1.083e-22 -21.928 -21.965 -0.037 (0) + CaH[14C][18O]O2+ 1.180e-22 1.083e-22 -21.928 -21.965 -0.037 (0) + Ca[14C]O2[18O] 1.940e-23 1.944e-23 -22.712 -22.711 0.001 (0) + H[14C]O[18O]2- 1.115e-23 1.020e-23 -22.953 -22.991 -0.039 (0) + H[14C][18O]2O- 1.115e-23 1.020e-23 -22.953 -22.991 -0.039 (0) + H[14C][18O]O[18O]- 1.115e-23 1.020e-23 -22.953 -22.991 -0.039 (0) + [14C]O2[18O]-2 9.945e-24 6.971e-24 -23.002 -23.157 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 1.647e-16 + O[18O] 1.644e-16 1.647e-16 -15.784 -15.783 0.001 (0) + [18O]2 1.640e-19 1.643e-19 -18.785 -18.784 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -25195,99 +25195,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.540 -123.540 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 8.273e-40 - H2 4.136e-40 4.143e-40 -39.383 -39.383 0.001 -O(0) 4.849e-14 - O2 2.415e-14 2.419e-14 -13.617 -13.616 0.001 - O[18O] 9.636e-17 9.651e-17 -16.016 -16.015 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.496 -125.495 0.001 -[13C](4) 6.519e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -138.809 -138.808 0.001 -[14C](4) 3.193e-18 - H[14C]O3- 2.579e-18 2.360e-18 -17.588 -17.627 -0.039 - [14C]O2 5.370e-19 5.379e-19 -18.270 -18.269 0.001 - CaH[14C]O3+ 5.449e-20 4.999e-20 -19.264 -19.301 -0.037 - H[14C]O2[18O]- 5.146e-21 4.709e-21 -20.288 -20.327 -0.039 - H[14C]O[18O]O- 5.146e-21 4.709e-21 -20.288 -20.327 -0.039 - H[14C][18O]O2- 5.146e-21 4.709e-21 -20.288 -20.327 -0.039 - Ca[14C]O3 2.986e-21 2.991e-21 -20.525 -20.524 0.001 - [14C]O[18O] 2.233e-21 2.237e-21 -20.651 -20.650 0.001 - [14C]O3-2 1.531e-21 1.073e-21 -20.815 -20.969 -0.154 - CaH[14C]O2[18O]+ 1.087e-22 9.974e-23 -21.964 -22.001 -0.037 - CaH[14C]O[18O]O+ 1.087e-22 9.974e-23 -21.964 -22.001 -0.037 - CaH[14C][18O]O2+ 1.087e-22 9.974e-23 -21.964 -22.001 -0.037 - Ca[14C]O2[18O] 1.788e-23 1.790e-23 -22.748 -22.747 0.001 - H[14C]O[18O]2- 1.027e-23 9.395e-24 -22.989 -23.027 -0.039 - H[14C][18O]2O- 1.027e-23 9.395e-24 -22.989 -23.027 -0.039 - H[14C][18O]O[18O]- 1.027e-23 9.395e-24 -22.989 -23.027 -0.039 - [14C]O2[18O]-2 9.162e-24 6.422e-24 -23.038 -23.192 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 9.655e-17 - O[18O] 9.636e-17 9.651e-17 -16.016 -16.015 0.001 - [18O]2 9.612e-20 9.628e-20 -19.017 -19.016 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.540 -123.540 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 8.273e-40 + H2 4.136e-40 4.143e-40 -39.383 -39.383 0.001 (0) +O(0) 4.849e-14 + O2 2.415e-14 2.419e-14 -13.617 -13.616 0.001 (0) + O[18O] 9.636e-17 9.651e-17 -16.016 -16.015 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.496 -125.495 0.001 (0) +[13C](4) 6.519e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -138.809 -138.808 0.001 (0) +[14C](4) 3.193e-18 + H[14C]O3- 2.579e-18 2.360e-18 -17.588 -17.627 -0.039 (0) + [14C]O2 5.370e-19 5.379e-19 -18.270 -18.269 0.001 (0) + CaH[14C]O3+ 5.449e-20 4.999e-20 -19.264 -19.301 -0.037 (0) + H[14C]O2[18O]- 5.146e-21 4.709e-21 -20.288 -20.327 -0.039 (0) + H[14C]O[18O]O- 5.146e-21 4.709e-21 -20.288 -20.327 -0.039 (0) + H[14C][18O]O2- 5.146e-21 4.709e-21 -20.288 -20.327 -0.039 (0) + Ca[14C]O3 2.986e-21 2.991e-21 -20.525 -20.524 0.001 (0) + [14C]O[18O] 2.233e-21 2.237e-21 -20.651 -20.650 0.001 (0) + [14C]O3-2 1.531e-21 1.073e-21 -20.815 -20.969 -0.154 (0) + CaH[14C]O2[18O]+ 1.087e-22 9.974e-23 -21.964 -22.001 -0.037 (0) + CaH[14C]O[18O]O+ 1.087e-22 9.974e-23 -21.964 -22.001 -0.037 (0) + CaH[14C][18O]O2+ 1.087e-22 9.974e-23 -21.964 -22.001 -0.037 (0) + Ca[14C]O2[18O] 1.788e-23 1.790e-23 -22.748 -22.747 0.001 (0) + H[14C]O[18O]2- 1.027e-23 9.395e-24 -22.989 -23.027 -0.039 (0) + H[14C][18O]2O- 1.027e-23 9.395e-24 -22.989 -23.027 -0.039 (0) + H[14C][18O]O[18O]- 1.027e-23 9.395e-24 -22.989 -23.027 -0.039 (0) + [14C]O2[18O]-2 9.162e-24 6.422e-24 -23.038 -23.192 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 9.655e-17 + O[18O] 9.636e-17 9.651e-17 -16.016 -16.015 0.001 (0) + [18O]2 9.612e-20 9.628e-20 -19.017 -19.016 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -25467,99 +25467,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -123.167 -123.166 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.026e-39 - H2 5.128e-40 5.136e-40 -39.290 -39.289 0.001 -O(0) 3.155e-14 - O2 1.571e-14 1.574e-14 -13.804 -13.803 0.001 - O[18O] 6.269e-17 6.280e-17 -16.203 -16.202 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -125.122 -125.122 0.001 -[13C](4) 6.520e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -138.471 -138.470 0.001 -[14C](4) 2.942e-18 - H[14C]O3- 2.376e-18 2.174e-18 -17.624 -17.663 -0.039 - [14C]O2 4.947e-19 4.955e-19 -18.306 -18.305 0.001 - CaH[14C]O3+ 5.020e-20 4.605e-20 -19.299 -19.337 -0.037 - H[14C]O2[18O]- 4.741e-21 4.338e-21 -20.324 -20.363 -0.039 - H[14C]O[18O]O- 4.741e-21 4.338e-21 -20.324 -20.363 -0.039 - H[14C][18O]O2- 4.741e-21 4.338e-21 -20.324 -20.363 -0.039 - Ca[14C]O3 2.751e-21 2.756e-21 -20.560 -20.560 0.001 - [14C]O[18O] 2.057e-21 2.060e-21 -20.687 -20.686 0.001 - [14C]O3-2 1.410e-21 9.883e-22 -20.851 -21.005 -0.154 - CaH[14C]O2[18O]+ 1.002e-22 9.188e-23 -21.999 -22.037 -0.037 - CaH[14C]O[18O]O+ 1.002e-22 9.188e-23 -21.999 -22.037 -0.037 - CaH[14C][18O]O2+ 1.002e-22 9.188e-23 -21.999 -22.037 -0.037 - Ca[14C]O2[18O] 1.647e-23 1.649e-23 -22.783 -22.783 0.001 - H[14C]O[18O]2- 9.459e-24 8.655e-24 -23.024 -23.063 -0.039 - H[14C][18O]2O- 9.459e-24 8.655e-24 -23.024 -23.063 -0.039 - H[14C][18O]O[18O]- 9.459e-24 8.655e-24 -23.024 -23.063 -0.039 - [14C]O2[18O]-2 8.440e-24 5.916e-24 -23.074 -23.228 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 6.282e-17 - O[18O] 6.269e-17 6.280e-17 -16.203 -16.202 0.001 - [18O]2 6.254e-20 6.265e-20 -19.204 -19.203 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -123.167 -123.166 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.026e-39 + H2 5.128e-40 5.136e-40 -39.290 -39.289 0.001 (0) +O(0) 3.155e-14 + O2 1.571e-14 1.574e-14 -13.804 -13.803 0.001 (0) + O[18O] 6.269e-17 6.280e-17 -16.203 -16.202 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -125.122 -125.122 0.001 (0) +[13C](4) 6.520e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -138.471 -138.470 0.001 (0) +[14C](4) 2.942e-18 + H[14C]O3- 2.376e-18 2.174e-18 -17.624 -17.663 -0.039 (0) + [14C]O2 4.947e-19 4.955e-19 -18.306 -18.305 0.001 (0) + CaH[14C]O3+ 5.020e-20 4.605e-20 -19.299 -19.337 -0.037 (0) + H[14C]O2[18O]- 4.741e-21 4.338e-21 -20.324 -20.363 -0.039 (0) + H[14C]O[18O]O- 4.741e-21 4.338e-21 -20.324 -20.363 -0.039 (0) + H[14C][18O]O2- 4.741e-21 4.338e-21 -20.324 -20.363 -0.039 (0) + Ca[14C]O3 2.751e-21 2.756e-21 -20.560 -20.560 0.001 (0) + [14C]O[18O] 2.057e-21 2.060e-21 -20.687 -20.686 0.001 (0) + [14C]O3-2 1.410e-21 9.883e-22 -20.851 -21.005 -0.154 (0) + CaH[14C]O2[18O]+ 1.002e-22 9.188e-23 -21.999 -22.037 -0.037 (0) + CaH[14C]O[18O]O+ 1.002e-22 9.188e-23 -21.999 -22.037 -0.037 (0) + CaH[14C][18O]O2+ 1.002e-22 9.188e-23 -21.999 -22.037 -0.037 (0) + Ca[14C]O2[18O] 1.647e-23 1.649e-23 -22.783 -22.783 0.001 (0) + H[14C]O[18O]2- 9.459e-24 8.655e-24 -23.024 -23.063 -0.039 (0) + H[14C][18O]2O- 9.459e-24 8.655e-24 -23.024 -23.063 -0.039 (0) + H[14C][18O]O[18O]- 9.459e-24 8.655e-24 -23.024 -23.063 -0.039 (0) + [14C]O2[18O]-2 8.440e-24 5.916e-24 -23.074 -23.228 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 6.282e-17 + O[18O] 6.269e-17 6.280e-17 -16.203 -16.202 0.001 (0) + [18O]2 6.254e-20 6.265e-20 -19.204 -19.203 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -25739,99 +25739,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -122.254 -122.254 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.734e-39 - H2 8.672e-40 8.686e-40 -39.062 -39.061 0.001 -O(0) 1.103e-14 - O2 5.494e-15 5.503e-15 -14.260 -14.259 0.001 - O[18O] 2.192e-17 2.196e-17 -16.659 -16.658 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -124.210 -124.209 0.001 -[13C](4) 6.520e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -137.594 -137.593 0.001 -[14C](4) 2.710e-18 - H[14C]O3- 2.189e-18 2.003e-18 -17.660 -17.698 -0.039 - [14C]O2 4.557e-19 4.564e-19 -18.341 -18.341 0.001 - CaH[14C]O3+ 4.624e-20 4.242e-20 -19.335 -19.372 -0.037 - H[14C]O2[18O]- 4.368e-21 3.996e-21 -20.360 -20.398 -0.039 - H[14C]O[18O]O- 4.368e-21 3.996e-21 -20.360 -20.398 -0.039 - H[14C][18O]O2- 4.368e-21 3.996e-21 -20.360 -20.398 -0.039 - Ca[14C]O3 2.534e-21 2.539e-21 -20.596 -20.595 0.001 - [14C]O[18O] 1.895e-21 1.898e-21 -20.722 -20.722 0.001 - [14C]O3-2 1.299e-21 9.105e-22 -20.886 -21.041 -0.154 - CaH[14C]O2[18O]+ 9.226e-23 8.464e-23 -22.035 -22.072 -0.037 - CaH[14C]O[18O]O+ 9.226e-23 8.464e-23 -22.035 -22.072 -0.037 - CaH[14C][18O]O2+ 9.226e-23 8.464e-23 -22.035 -22.072 -0.037 - Ca[14C]O2[18O] 1.517e-23 1.520e-23 -22.819 -22.818 0.001 - H[14C]O[18O]2- 8.714e-24 7.973e-24 -23.060 -23.098 -0.039 - H[14C][18O]2O- 8.714e-24 7.973e-24 -23.060 -23.098 -0.039 - H[14C][18O]O[18O]- 8.714e-24 7.973e-24 -23.060 -23.098 -0.039 - [14C]O2[18O]-2 7.775e-24 5.450e-24 -23.109 -23.264 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.197e-17 - O[18O] 2.192e-17 2.196e-17 -16.659 -16.658 0.001 - [18O]2 2.187e-20 2.190e-20 -19.660 -19.659 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -122.254 -122.254 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.734e-39 + H2 8.672e-40 8.686e-40 -39.062 -39.061 0.001 (0) +O(0) 1.103e-14 + O2 5.494e-15 5.503e-15 -14.260 -14.259 0.001 (0) + O[18O] 2.192e-17 2.196e-17 -16.659 -16.658 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -124.210 -124.209 0.001 (0) +[13C](4) 6.520e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -137.594 -137.593 0.001 (0) +[14C](4) 2.710e-18 + H[14C]O3- 2.189e-18 2.003e-18 -17.660 -17.698 -0.039 (0) + [14C]O2 4.557e-19 4.564e-19 -18.341 -18.341 0.001 (0) + CaH[14C]O3+ 4.624e-20 4.242e-20 -19.335 -19.372 -0.037 (0) + H[14C]O2[18O]- 4.368e-21 3.996e-21 -20.360 -20.398 -0.039 (0) + H[14C]O[18O]O- 4.368e-21 3.996e-21 -20.360 -20.398 -0.039 (0) + H[14C][18O]O2- 4.368e-21 3.996e-21 -20.360 -20.398 -0.039 (0) + Ca[14C]O3 2.534e-21 2.539e-21 -20.596 -20.595 0.001 (0) + [14C]O[18O] 1.895e-21 1.898e-21 -20.722 -20.722 0.001 (0) + [14C]O3-2 1.299e-21 9.105e-22 -20.886 -21.041 -0.154 (0) + CaH[14C]O2[18O]+ 9.226e-23 8.464e-23 -22.035 -22.072 -0.037 (0) + CaH[14C]O[18O]O+ 9.226e-23 8.464e-23 -22.035 -22.072 -0.037 (0) + CaH[14C][18O]O2+ 9.226e-23 8.464e-23 -22.035 -22.072 -0.037 (0) + Ca[14C]O2[18O] 1.517e-23 1.520e-23 -22.819 -22.818 0.001 (0) + H[14C]O[18O]2- 8.714e-24 7.973e-24 -23.060 -23.098 -0.039 (0) + H[14C][18O]2O- 8.714e-24 7.973e-24 -23.060 -23.098 -0.039 (0) + H[14C][18O]O[18O]- 8.714e-24 7.973e-24 -23.060 -23.098 -0.039 (0) + [14C]O2[18O]-2 7.775e-24 5.450e-24 -23.109 -23.264 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.197e-17 + O[18O] 2.192e-17 2.196e-17 -16.659 -16.658 0.001 (0) + [18O]2 2.187e-20 2.190e-20 -19.660 -19.659 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -26013,99 +26013,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 3.714e-21 - CH4 3.714e-21 3.720e-21 -20.430 -20.429 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 4.957e-14 - H2 2.478e-14 2.482e-14 -13.606 -13.605 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.172 -65.171 0.001 - O[18O] 0.000e+00 0.000e+00 -67.571 -67.570 0.001 -[13C](-4) 4.116e-23 - [13C]H4 4.116e-23 4.123e-23 -22.385 -22.385 0.001 -[13C](4) 6.520e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 1.565e-36 - [14C]H4 1.565e-36 1.568e-36 -35.805 -35.805 0.001 -[14C](4) 2.497e-18 - H[14C]O3- 2.017e-18 1.845e-18 -17.695 -17.734 -0.039 - [14C]O2 4.198e-19 4.205e-19 -18.377 -18.376 0.001 - CaH[14C]O3+ 4.260e-20 3.908e-20 -19.371 -19.408 -0.037 - H[14C]O2[18O]- 4.023e-21 3.681e-21 -20.395 -20.434 -0.039 - H[14C]O[18O]O- 4.023e-21 3.681e-21 -20.395 -20.434 -0.039 - H[14C][18O]O2- 4.023e-21 3.681e-21 -20.395 -20.434 -0.039 - Ca[14C]O3 2.335e-21 2.339e-21 -20.632 -20.631 0.001 - [14C]O[18O] 1.746e-21 1.749e-21 -20.758 -20.757 0.001 - [14C]O3-2 1.197e-21 8.388e-22 -20.922 -21.076 -0.154 - CaH[14C]O2[18O]+ 8.499e-23 7.798e-23 -22.071 -22.108 -0.037 - CaH[14C]O[18O]O+ 8.499e-23 7.798e-23 -22.071 -22.108 -0.037 - CaH[14C][18O]O2+ 8.499e-23 7.798e-23 -22.071 -22.108 -0.037 - Ca[14C]O2[18O] 1.398e-23 1.400e-23 -22.855 -22.854 0.001 - H[14C]O[18O]2- 8.028e-24 7.345e-24 -23.095 -23.134 -0.039 - H[14C][18O]2O- 8.028e-24 7.345e-24 -23.095 -23.134 -0.039 - H[14C][18O]O[18O]- 8.028e-24 7.345e-24 -23.095 -23.134 -0.039 - [14C]O2[18O]-2 7.163e-24 5.020e-24 -23.145 -23.299 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.571 -67.570 0.001 - [18O]2 0.000e+00 0.000e+00 -70.572 -70.572 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 3.714e-21 + CH4 3.714e-21 3.720e-21 -20.430 -20.429 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 4.957e-14 + H2 2.478e-14 2.482e-14 -13.606 -13.605 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.172 -65.171 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.571 -67.570 0.001 (0) +[13C](-4) 4.116e-23 + [13C]H4 4.116e-23 4.123e-23 -22.385 -22.385 0.001 (0) +[13C](4) 6.520e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 1.565e-36 + [14C]H4 1.565e-36 1.568e-36 -35.805 -35.805 0.001 (0) +[14C](4) 2.497e-18 + H[14C]O3- 2.017e-18 1.845e-18 -17.695 -17.734 -0.039 (0) + [14C]O2 4.198e-19 4.205e-19 -18.377 -18.376 0.001 (0) + CaH[14C]O3+ 4.260e-20 3.908e-20 -19.371 -19.408 -0.037 (0) + H[14C]O2[18O]- 4.023e-21 3.681e-21 -20.395 -20.434 -0.039 (0) + H[14C]O[18O]O- 4.023e-21 3.681e-21 -20.395 -20.434 -0.039 (0) + H[14C][18O]O2- 4.023e-21 3.681e-21 -20.395 -20.434 -0.039 (0) + Ca[14C]O3 2.335e-21 2.339e-21 -20.632 -20.631 0.001 (0) + [14C]O[18O] 1.746e-21 1.749e-21 -20.758 -20.757 0.001 (0) + [14C]O3-2 1.197e-21 8.388e-22 -20.922 -21.076 -0.154 (0) + CaH[14C]O2[18O]+ 8.499e-23 7.798e-23 -22.071 -22.108 -0.037 (0) + CaH[14C]O[18O]O+ 8.499e-23 7.798e-23 -22.071 -22.108 -0.037 (0) + CaH[14C][18O]O2+ 8.499e-23 7.798e-23 -22.071 -22.108 -0.037 (0) + Ca[14C]O2[18O] 1.398e-23 1.400e-23 -22.855 -22.854 0.001 (0) + H[14C]O[18O]2- 8.028e-24 7.345e-24 -23.095 -23.134 -0.039 (0) + H[14C][18O]2O- 8.028e-24 7.345e-24 -23.095 -23.134 -0.039 (0) + H[14C][18O]O[18O]- 8.028e-24 7.345e-24 -23.095 -23.134 -0.039 (0) + [14C]O2[18O]-2 7.163e-24 5.020e-24 -23.145 -23.299 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.571 -67.570 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.572 -70.572 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -26287,99 +26287,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 9.073e-20 - CH4 9.073e-20 9.088e-20 -19.042 -19.042 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.102e-13 - H2 5.510e-14 5.519e-14 -13.259 -13.258 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.866 -65.865 0.001 - O[18O] 0.000e+00 0.000e+00 -68.265 -68.264 0.001 -[13C](-4) 1.006e-21 - [13C]H4 1.006e-21 1.007e-21 -20.998 -20.997 0.001 -[13C](4) 6.520e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 3.523e-35 - [14C]H4 3.523e-35 3.528e-35 -34.453 -34.452 0.001 -[14C](4) 2.300e-18 - H[14C]O3- 1.858e-18 1.700e-18 -17.731 -17.770 -0.039 - [14C]O2 3.867e-19 3.874e-19 -18.413 -18.412 0.001 - CaH[14C]O3+ 3.924e-20 3.600e-20 -19.406 -19.444 -0.037 - H[14C]O2[18O]- 3.707e-21 3.391e-21 -20.431 -20.470 -0.039 - H[14C]O[18O]O- 3.707e-21 3.391e-21 -20.431 -20.470 -0.039 - H[14C][18O]O2- 3.707e-21 3.391e-21 -20.431 -20.470 -0.039 - Ca[14C]O3 2.151e-21 2.154e-21 -20.667 -20.667 0.001 - [14C]O[18O] 1.608e-21 1.611e-21 -20.794 -20.793 0.001 - [14C]O3-2 1.102e-21 7.727e-22 -20.958 -21.112 -0.154 - CaH[14C]O2[18O]+ 7.830e-23 7.183e-23 -22.106 -22.144 -0.037 - CaH[14C]O[18O]O+ 7.830e-23 7.183e-23 -22.106 -22.144 -0.037 - CaH[14C][18O]O2+ 7.830e-23 7.183e-23 -22.106 -22.144 -0.037 - Ca[14C]O2[18O] 1.287e-23 1.290e-23 -22.890 -22.890 0.001 - H[14C]O[18O]2- 7.395e-24 6.767e-24 -23.131 -23.170 -0.039 - H[14C][18O]2O- 7.395e-24 6.767e-24 -23.131 -23.170 -0.039 - H[14C][18O]O[18O]- 7.395e-24 6.767e-24 -23.131 -23.170 -0.039 - [14C]O2[18O]-2 6.599e-24 4.625e-24 -23.181 -23.335 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.265 -68.264 0.001 - [18O]2 0.000e+00 0.000e+00 -71.266 -71.265 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 9.073e-20 + CH4 9.073e-20 9.088e-20 -19.042 -19.042 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.102e-13 + H2 5.510e-14 5.519e-14 -13.259 -13.258 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.866 -65.865 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.265 -68.264 0.001 (0) +[13C](-4) 1.006e-21 + [13C]H4 1.006e-21 1.007e-21 -20.998 -20.997 0.001 (0) +[13C](4) 6.520e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 3.523e-35 + [14C]H4 3.523e-35 3.528e-35 -34.453 -34.452 0.001 (0) +[14C](4) 2.300e-18 + H[14C]O3- 1.858e-18 1.700e-18 -17.731 -17.770 -0.039 (0) + [14C]O2 3.867e-19 3.874e-19 -18.413 -18.412 0.001 (0) + CaH[14C]O3+ 3.924e-20 3.600e-20 -19.406 -19.444 -0.037 (0) + H[14C]O2[18O]- 3.707e-21 3.391e-21 -20.431 -20.470 -0.039 (0) + H[14C]O[18O]O- 3.707e-21 3.391e-21 -20.431 -20.470 -0.039 (0) + H[14C][18O]O2- 3.707e-21 3.391e-21 -20.431 -20.470 -0.039 (0) + Ca[14C]O3 2.151e-21 2.154e-21 -20.667 -20.667 0.001 (0) + [14C]O[18O] 1.608e-21 1.611e-21 -20.794 -20.793 0.001 (0) + [14C]O3-2 1.102e-21 7.727e-22 -20.958 -21.112 -0.154 (0) + CaH[14C]O2[18O]+ 7.830e-23 7.183e-23 -22.106 -22.144 -0.037 (0) + CaH[14C]O[18O]O+ 7.830e-23 7.183e-23 -22.106 -22.144 -0.037 (0) + CaH[14C][18O]O2+ 7.830e-23 7.183e-23 -22.106 -22.144 -0.037 (0) + Ca[14C]O2[18O] 1.287e-23 1.290e-23 -22.890 -22.890 0.001 (0) + H[14C]O[18O]2- 7.395e-24 6.767e-24 -23.131 -23.170 -0.039 (0) + H[14C][18O]2O- 7.395e-24 6.767e-24 -23.131 -23.170 -0.039 (0) + H[14C][18O]O[18O]- 7.395e-24 6.767e-24 -23.131 -23.170 -0.039 (0) + [14C]O2[18O]-2 6.599e-24 4.625e-24 -23.181 -23.335 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.265 -68.264 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.266 -71.265 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -26561,99 +26561,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.169e-19 - CH4 1.169e-19 1.171e-19 -18.932 -18.932 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.174e-13 - H2 5.870e-14 5.879e-14 -13.231 -13.231 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.921 -65.920 0.001 - O[18O] 0.000e+00 0.000e+00 -68.320 -68.319 0.001 -[13C](-4) 1.295e-21 - [13C]H4 1.295e-21 1.298e-21 -20.888 -20.887 0.001 -[13C](4) 6.520e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 4.180e-35 - [14C]H4 4.180e-35 4.187e-35 -34.379 -34.378 0.001 -[14C](4) 2.119e-18 - H[14C]O3- 1.711e-18 1.566e-18 -17.767 -17.805 -0.039 - [14C]O2 3.563e-19 3.569e-19 -18.448 -18.448 0.001 - CaH[14C]O3+ 3.615e-20 3.317e-20 -19.442 -19.479 -0.037 - H[14C]O2[18O]- 3.415e-21 3.124e-21 -20.467 -20.505 -0.039 - H[14C]O[18O]O- 3.415e-21 3.124e-21 -20.467 -20.505 -0.039 - H[14C][18O]O2- 3.415e-21 3.124e-21 -20.467 -20.505 -0.039 - Ca[14C]O3 1.981e-21 1.985e-21 -20.703 -20.702 0.001 - [14C]O[18O] 1.481e-21 1.484e-21 -20.829 -20.829 0.001 - [14C]O3-2 1.016e-21 7.118e-22 -20.993 -21.148 -0.154 - CaH[14C]O2[18O]+ 7.213e-23 6.617e-23 -22.142 -22.179 -0.037 - CaH[14C]O[18O]O+ 7.213e-23 6.617e-23 -22.142 -22.179 -0.037 - CaH[14C][18O]O2+ 7.213e-23 6.617e-23 -22.142 -22.179 -0.037 - Ca[14C]O2[18O] 1.186e-23 1.188e-23 -22.926 -22.925 0.001 - H[14C]O[18O]2- 6.813e-24 6.234e-24 -23.167 -23.205 -0.039 - H[14C][18O]2O- 6.813e-24 6.234e-24 -23.167 -23.205 -0.039 - H[14C][18O]O[18O]- 6.813e-24 6.234e-24 -23.167 -23.205 -0.039 - [14C]O2[18O]-2 6.079e-24 4.261e-24 -23.216 -23.371 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.320 -68.319 0.001 - [18O]2 0.000e+00 0.000e+00 -71.321 -71.320 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.169e-19 + CH4 1.169e-19 1.171e-19 -18.932 -18.932 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.174e-13 + H2 5.870e-14 5.879e-14 -13.231 -13.231 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.921 -65.920 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.320 -68.319 0.001 (0) +[13C](-4) 1.295e-21 + [13C]H4 1.295e-21 1.298e-21 -20.888 -20.887 0.001 (0) +[13C](4) 6.520e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 4.180e-35 + [14C]H4 4.180e-35 4.187e-35 -34.379 -34.378 0.001 (0) +[14C](4) 2.119e-18 + H[14C]O3- 1.711e-18 1.566e-18 -17.767 -17.805 -0.039 (0) + [14C]O2 3.563e-19 3.569e-19 -18.448 -18.448 0.001 (0) + CaH[14C]O3+ 3.615e-20 3.317e-20 -19.442 -19.479 -0.037 (0) + H[14C]O2[18O]- 3.415e-21 3.124e-21 -20.467 -20.505 -0.039 (0) + H[14C]O[18O]O- 3.415e-21 3.124e-21 -20.467 -20.505 -0.039 (0) + H[14C][18O]O2- 3.415e-21 3.124e-21 -20.467 -20.505 -0.039 (0) + Ca[14C]O3 1.981e-21 1.985e-21 -20.703 -20.702 0.001 (0) + [14C]O[18O] 1.481e-21 1.484e-21 -20.829 -20.829 0.001 (0) + [14C]O3-2 1.016e-21 7.118e-22 -20.993 -21.148 -0.154 (0) + CaH[14C]O2[18O]+ 7.213e-23 6.617e-23 -22.142 -22.179 -0.037 (0) + CaH[14C]O[18O]O+ 7.213e-23 6.617e-23 -22.142 -22.179 -0.037 (0) + CaH[14C][18O]O2+ 7.213e-23 6.617e-23 -22.142 -22.179 -0.037 (0) + Ca[14C]O2[18O] 1.186e-23 1.188e-23 -22.926 -22.925 0.001 (0) + H[14C]O[18O]2- 6.813e-24 6.234e-24 -23.167 -23.205 -0.039 (0) + H[14C][18O]2O- 6.813e-24 6.234e-24 -23.167 -23.205 -0.039 (0) + H[14C][18O]O[18O]- 6.813e-24 6.234e-24 -23.167 -23.205 -0.039 (0) + [14C]O2[18O]-2 6.079e-24 4.261e-24 -23.216 -23.371 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.320 -68.319 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.321 -71.320 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -26835,99 +26835,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 2.649e-19 - CH4 2.649e-19 2.653e-19 -18.577 -18.576 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.440e-13 - H2 7.202e-14 7.214e-14 -13.143 -13.142 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.099 -66.098 0.001 - O[18O] 0.000e+00 0.000e+00 -68.498 -68.497 0.001 -[13C](-4) 2.936e-21 - [13C]H4 2.936e-21 2.941e-21 -20.532 -20.532 0.001 -[13C](4) 6.520e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 8.727e-35 - [14C]H4 8.727e-35 8.742e-35 -34.059 -34.058 0.001 -[14C](4) 1.952e-18 - H[14C]O3- 1.577e-18 1.443e-18 -17.802 -17.841 -0.039 - [14C]O2 3.282e-19 3.287e-19 -18.484 -18.483 0.001 - CaH[14C]O3+ 3.330e-20 3.055e-20 -19.478 -19.515 -0.037 - H[14C]O2[18O]- 3.146e-21 2.878e-21 -20.502 -20.541 -0.039 - H[14C]O[18O]O- 3.146e-21 2.878e-21 -20.502 -20.541 -0.039 - H[14C][18O]O2- 3.146e-21 2.878e-21 -20.502 -20.541 -0.039 - Ca[14C]O3 1.825e-21 1.828e-21 -20.739 -20.738 0.001 - [14C]O[18O] 1.365e-21 1.367e-21 -20.865 -20.864 0.001 - [14C]O3-2 9.355e-22 6.557e-22 -21.029 -21.183 -0.154 - CaH[14C]O2[18O]+ 6.645e-23 6.096e-23 -22.178 -22.215 -0.037 - CaH[14C]O[18O]O+ 6.645e-23 6.096e-23 -22.178 -22.215 -0.037 - CaH[14C][18O]O2+ 6.645e-23 6.096e-23 -22.178 -22.215 -0.037 - Ca[14C]O2[18O] 1.093e-23 1.094e-23 -22.962 -22.961 0.001 - H[14C]O[18O]2- 6.276e-24 5.743e-24 -23.202 -23.241 -0.039 - H[14C][18O]2O- 6.276e-24 5.743e-24 -23.202 -23.241 -0.039 - H[14C][18O]O[18O]- 6.276e-24 5.743e-24 -23.202 -23.241 -0.039 - [14C]O2[18O]-2 5.600e-24 3.925e-24 -23.252 -23.406 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.498 -68.497 0.001 - [18O]2 0.000e+00 0.000e+00 -71.499 -71.498 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 2.649e-19 + CH4 2.649e-19 2.653e-19 -18.577 -18.576 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.440e-13 + H2 7.202e-14 7.214e-14 -13.143 -13.142 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.099 -66.098 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.498 -68.497 0.001 (0) +[13C](-4) 2.936e-21 + [13C]H4 2.936e-21 2.941e-21 -20.532 -20.532 0.001 (0) +[13C](4) 6.520e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 8.727e-35 + [14C]H4 8.727e-35 8.742e-35 -34.059 -34.058 0.001 (0) +[14C](4) 1.952e-18 + H[14C]O3- 1.577e-18 1.443e-18 -17.802 -17.841 -0.039 (0) + [14C]O2 3.282e-19 3.287e-19 -18.484 -18.483 0.001 (0) + CaH[14C]O3+ 3.330e-20 3.055e-20 -19.478 -19.515 -0.037 (0) + H[14C]O2[18O]- 3.146e-21 2.878e-21 -20.502 -20.541 -0.039 (0) + H[14C]O[18O]O- 3.146e-21 2.878e-21 -20.502 -20.541 -0.039 (0) + H[14C][18O]O2- 3.146e-21 2.878e-21 -20.502 -20.541 -0.039 (0) + Ca[14C]O3 1.825e-21 1.828e-21 -20.739 -20.738 0.001 (0) + [14C]O[18O] 1.365e-21 1.367e-21 -20.865 -20.864 0.001 (0) + [14C]O3-2 9.355e-22 6.557e-22 -21.029 -21.183 -0.154 (0) + CaH[14C]O2[18O]+ 6.645e-23 6.096e-23 -22.178 -22.215 -0.037 (0) + CaH[14C]O[18O]O+ 6.645e-23 6.096e-23 -22.178 -22.215 -0.037 (0) + CaH[14C][18O]O2+ 6.645e-23 6.096e-23 -22.178 -22.215 -0.037 (0) + Ca[14C]O2[18O] 1.093e-23 1.094e-23 -22.962 -22.961 0.001 (0) + H[14C]O[18O]2- 6.276e-24 5.743e-24 -23.202 -23.241 -0.039 (0) + H[14C][18O]2O- 6.276e-24 5.743e-24 -23.202 -23.241 -0.039 (0) + H[14C][18O]O[18O]- 6.276e-24 5.743e-24 -23.202 -23.241 -0.039 (0) + [14C]O2[18O]-2 5.600e-24 3.925e-24 -23.252 -23.406 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.498 -68.497 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.499 -71.498 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -27109,99 +27109,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 8.063e-19 - CH4 8.063e-19 8.076e-19 -18.094 -18.093 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 1.903e-13 - H2 9.513e-14 9.529e-14 -13.022 -13.021 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.341 -66.340 0.001 - O[18O] 0.000e+00 0.000e+00 -68.740 -68.739 0.001 -[13C](-4) 8.938e-21 - [13C]H4 8.938e-21 8.952e-21 -20.049 -20.048 0.001 -[13C](4) 6.520e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 2.447e-34 - [14C]H4 2.447e-34 2.451e-34 -33.611 -33.611 0.001 -[14C](4) 1.798e-18 - H[14C]O3- 1.452e-18 1.329e-18 -17.838 -17.877 -0.039 - [14C]O2 3.023e-19 3.028e-19 -18.519 -18.519 0.001 - CaH[14C]O3+ 3.068e-20 2.815e-20 -19.513 -19.551 -0.037 - H[14C]O2[18O]- 2.898e-21 2.651e-21 -20.538 -20.577 -0.039 - H[14C]O[18O]O- 2.898e-21 2.651e-21 -20.538 -20.577 -0.039 - H[14C][18O]O2- 2.898e-21 2.651e-21 -20.538 -20.577 -0.039 - Ca[14C]O3 1.682e-21 1.684e-21 -20.774 -20.774 0.001 - [14C]O[18O] 1.257e-21 1.259e-21 -20.901 -20.900 0.001 - [14C]O3-2 8.619e-22 6.041e-22 -21.065 -21.219 -0.154 - CaH[14C]O2[18O]+ 6.121e-23 5.616e-23 -22.213 -22.251 -0.037 - CaH[14C]O[18O]O+ 6.121e-23 5.616e-23 -22.213 -22.251 -0.037 - CaH[14C][18O]O2+ 6.121e-23 5.616e-23 -22.213 -22.251 -0.037 - Ca[14C]O2[18O] 1.007e-23 1.008e-23 -22.997 -22.996 0.001 - H[14C]O[18O]2- 5.782e-24 5.290e-24 -23.238 -23.277 -0.039 - H[14C][18O]2O- 5.782e-24 5.290e-24 -23.238 -23.277 -0.039 - H[14C][18O]O[18O]- 5.782e-24 5.290e-24 -23.238 -23.277 -0.039 - [14C]O2[18O]-2 5.159e-24 3.616e-24 -23.287 -23.442 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -68.740 -68.739 0.001 - [18O]2 0.000e+00 0.000e+00 -71.741 -71.740 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 8.063e-19 + CH4 8.063e-19 8.076e-19 -18.094 -18.093 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 1.903e-13 + H2 9.513e-14 9.529e-14 -13.022 -13.021 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.341 -66.340 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -68.740 -68.739 0.001 (0) +[13C](-4) 8.938e-21 + [13C]H4 8.938e-21 8.952e-21 -20.049 -20.048 0.001 (0) +[13C](4) 6.520e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 2.447e-34 + [14C]H4 2.447e-34 2.451e-34 -33.611 -33.611 0.001 (0) +[14C](4) 1.798e-18 + H[14C]O3- 1.452e-18 1.329e-18 -17.838 -17.877 -0.039 (0) + [14C]O2 3.023e-19 3.028e-19 -18.519 -18.519 0.001 (0) + CaH[14C]O3+ 3.068e-20 2.815e-20 -19.513 -19.551 -0.037 (0) + H[14C]O2[18O]- 2.898e-21 2.651e-21 -20.538 -20.577 -0.039 (0) + H[14C]O[18O]O- 2.898e-21 2.651e-21 -20.538 -20.577 -0.039 (0) + H[14C][18O]O2- 2.898e-21 2.651e-21 -20.538 -20.577 -0.039 (0) + Ca[14C]O3 1.682e-21 1.684e-21 -20.774 -20.774 0.001 (0) + [14C]O[18O] 1.257e-21 1.259e-21 -20.901 -20.900 0.001 (0) + [14C]O3-2 8.619e-22 6.041e-22 -21.065 -21.219 -0.154 (0) + CaH[14C]O2[18O]+ 6.121e-23 5.616e-23 -22.213 -22.251 -0.037 (0) + CaH[14C]O[18O]O+ 6.121e-23 5.616e-23 -22.213 -22.251 -0.037 (0) + CaH[14C][18O]O2+ 6.121e-23 5.616e-23 -22.213 -22.251 -0.037 (0) + Ca[14C]O2[18O] 1.007e-23 1.008e-23 -22.997 -22.996 0.001 (0) + H[14C]O[18O]2- 5.782e-24 5.290e-24 -23.238 -23.277 -0.039 (0) + H[14C][18O]2O- 5.782e-24 5.290e-24 -23.238 -23.277 -0.039 (0) + H[14C][18O]O[18O]- 5.782e-24 5.290e-24 -23.238 -23.277 -0.039 (0) + [14C]O2[18O]-2 5.159e-24 3.616e-24 -23.287 -23.442 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -68.740 -68.739 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -71.741 -71.740 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -27383,99 +27383,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 3.343e-18 - CH4 3.343e-18 3.348e-18 -17.476 -17.475 0.001 -C(4) 5.839e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 2.715e-13 - H2 1.357e-13 1.360e-13 -12.867 -12.867 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.649 -66.649 0.001 - O[18O] 0.000e+00 0.000e+00 -69.048 -69.048 0.001 -[13C](-4) 3.705e-20 - [13C]H4 3.705e-20 3.711e-20 -19.431 -19.430 0.001 -[13C](4) 6.520e-05 - H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 - [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 - CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 - H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 - Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 - [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 - [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 - Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 - H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 - [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 -[14C](-4) 9.346e-34 - [14C]H4 9.346e-34 9.362e-34 -33.029 -33.029 0.001 -[14C](4) 1.656e-18 - H[14C]O3- 1.338e-18 1.224e-18 -17.874 -17.912 -0.039 - [14C]O2 2.785e-19 2.790e-19 -18.555 -18.554 0.001 - CaH[14C]O3+ 2.826e-20 2.593e-20 -19.549 -19.586 -0.037 - H[14C]O2[18O]- 2.669e-21 2.443e-21 -20.574 -20.612 -0.039 - H[14C]O[18O]O- 2.669e-21 2.443e-21 -20.574 -20.612 -0.039 - H[14C][18O]O2- 2.669e-21 2.443e-21 -20.574 -20.612 -0.039 - Ca[14C]O3 1.549e-21 1.552e-21 -20.810 -20.809 0.001 - [14C]O[18O] 1.158e-21 1.160e-21 -20.936 -20.935 0.001 - [14C]O3-2 7.940e-22 5.565e-22 -21.100 -21.255 -0.154 - CaH[14C]O2[18O]+ 5.639e-23 5.174e-23 -22.249 -22.286 -0.037 - CaH[14C]O[18O]O+ 5.639e-23 5.174e-23 -22.249 -22.286 -0.037 - CaH[14C][18O]O2+ 5.639e-23 5.174e-23 -22.249 -22.286 -0.037 - Ca[14C]O2[18O] 9.272e-24 9.287e-24 -23.033 -23.032 0.001 - H[14C]O[18O]2- 5.326e-24 4.873e-24 -23.274 -23.312 -0.039 - H[14C][18O]2O- 5.326e-24 4.873e-24 -23.274 -23.312 -0.039 - H[14C][18O]O[18O]- 5.326e-24 4.873e-24 -23.274 -23.312 -0.039 - [14C]O2[18O]-2 4.752e-24 3.331e-24 -23.323 -23.477 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -69.048 -69.048 0.001 - [18O]2 0.000e+00 0.000e+00 -72.049 -72.049 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 3.343e-18 + CH4 3.343e-18 3.348e-18 -17.476 -17.475 0.001 (0) +C(4) 5.839e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.977e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.460e-06 5.469e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 2.715e-13 + H2 1.357e-13 1.360e-13 -12.867 -12.867 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.649 -66.649 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -69.048 -69.048 0.001 (0) +[13C](-4) 3.705e-20 + [13C]H4 3.705e-20 3.711e-20 -19.431 -19.430 0.001 (0) +[13C](4) 6.520e-05 + H[13C]O3- 5.258e-05 4.811e-05 -4.279 -4.318 -0.039 (0) + [13C]O2 1.104e-05 1.106e-05 -4.957 -4.956 0.001 (0) + CaH[13C]O3+ 1.111e-06 1.019e-06 -5.954 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + H[13C][18O]O2- 1.049e-07 9.599e-08 -6.979 -7.018 -0.039 (0) + Ca[13C]O3 6.097e-08 6.107e-08 -7.215 -7.214 0.001 (0) + [13C]O[18O] 4.591e-08 4.599e-08 -7.338 -7.337 0.001 (0) + [13C]O3-2 3.125e-08 2.190e-08 -7.505 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.216e-09 2.033e-09 -8.654 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.649e-10 3.655e-10 -9.438 -9.437 0.001 (0) + H[13C]O[18O]2- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]2O- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.093e-10 1.915e-10 -9.679 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.870e-10 1.311e-10 -9.728 -9.882 -0.154 (0) +[14C](-4) 9.346e-34 + [14C]H4 9.346e-34 9.362e-34 -33.029 -33.029 0.001 (0) +[14C](4) 1.656e-18 + H[14C]O3- 1.338e-18 1.224e-18 -17.874 -17.912 -0.039 (0) + [14C]O2 2.785e-19 2.790e-19 -18.555 -18.554 0.001 (0) + CaH[14C]O3+ 2.826e-20 2.593e-20 -19.549 -19.586 -0.037 (0) + H[14C]O2[18O]- 2.669e-21 2.443e-21 -20.574 -20.612 -0.039 (0) + H[14C]O[18O]O- 2.669e-21 2.443e-21 -20.574 -20.612 -0.039 (0) + H[14C][18O]O2- 2.669e-21 2.443e-21 -20.574 -20.612 -0.039 (0) + Ca[14C]O3 1.549e-21 1.552e-21 -20.810 -20.809 0.001 (0) + [14C]O[18O] 1.158e-21 1.160e-21 -20.936 -20.935 0.001 (0) + [14C]O3-2 7.940e-22 5.565e-22 -21.100 -21.255 -0.154 (0) + CaH[14C]O2[18O]+ 5.639e-23 5.174e-23 -22.249 -22.286 -0.037 (0) + CaH[14C]O[18O]O+ 5.639e-23 5.174e-23 -22.249 -22.286 -0.037 (0) + CaH[14C][18O]O2+ 5.639e-23 5.174e-23 -22.249 -22.286 -0.037 (0) + Ca[14C]O2[18O] 9.272e-24 9.287e-24 -23.033 -23.032 0.001 (0) + H[14C]O[18O]2- 5.326e-24 4.873e-24 -23.274 -23.312 -0.039 (0) + H[14C][18O]2O- 5.326e-24 4.873e-24 -23.274 -23.312 -0.039 (0) + H[14C][18O]O[18O]- 5.326e-24 4.873e-24 -23.274 -23.312 -0.039 (0) + [14C]O2[18O]-2 4.752e-24 3.331e-24 -23.323 -23.477 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -69.048 -69.048 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -72.049 -72.049 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -27631,21 +27631,21 @@ Calcite added: 0 0 0 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 3.919e-05 3.891e-05 -4.407 -4.410 -0.003 - OH- 2.591e-10 2.573e-10 -9.586 -9.590 -0.003 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -93.357 -93.357 0.000 -C(4) 3.444e-03 - CO2 3.405e-03 3.405e-03 -2.468 -2.468 0.000 - HCO3- 3.919e-05 3.890e-05 -4.407 -4.410 -0.003 -H(0) 2.144e-32 - H2 1.072e-32 1.072e-32 -31.970 -31.970 0.000 -O(0) 7.256e-29 - O2 3.628e-29 3.628e-29 -28.440 -28.440 0.000 + H3O+ 3.919e-05 3.891e-05 -4.407 -4.410 -0.003 (0) + OH- 2.591e-10 2.573e-10 -9.586 -9.590 -0.003 (0) + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -93.357 -93.357 0.000 (0) +C(4) 3.444e-03 + CO2 3.405e-03 3.405e-03 -2.468 -2.468 0.000 (0) + HCO3- 3.919e-05 3.890e-05 -4.407 -4.410 -0.003 (0) +H(0) 2.144e-32 + H2 1.072e-32 1.072e-32 -31.970 -31.970 0.000 (0) +O(0) 7.256e-29 + O2 3.628e-29 3.628e-29 -28.440 -28.440 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -27809,89 +27809,89 @@ Alpha 14C CH4(aq)/CO2(aq) 1 8.2157e-12 0 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.426e-06 1.369e-06 -5.846 -5.864 -0.018 - OH- 7.606e-09 7.283e-09 -8.119 -8.138 -0.019 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 8.991e-28 - CH4 8.991e-28 8.994e-28 -27.046 -27.046 0.000 -C(4) 3.912e-03 - CO2 2.907e-03 2.908e-03 -2.537 -2.536 0.000 - HCO3- 9.821e-04 9.406e-04 -3.008 -3.027 -0.019 - CO[18O] 1.209e-05 1.209e-05 -4.918 -4.918 0.000 - CaHCO3+ 5.242e-06 5.024e-06 -5.281 -5.299 -0.018 - HCO2[18O]- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 - HCO[18O]O- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 - HC[18O]O2- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 - CO3-2 3.822e-08 3.216e-08 -7.418 -7.493 -0.075 - CaCO3 2.261e-08 2.261e-08 -7.646 -7.646 0.000 - C[18O]2 1.257e-08 1.257e-08 -7.901 -7.901 0.000 - CaHCO2[18O]+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 - CaHCO[18O]O+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 - CaHC[18O]O2+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 -Ca 5.014e-04 - Ca+2 4.961e-04 4.185e-04 -3.304 -3.378 -0.074 - CaHCO3+ 5.242e-06 5.024e-06 -5.281 -5.299 -0.018 - CaH[13C]O3+ 5.771e-08 5.532e-08 -7.239 -7.257 -0.018 - CaCO3 2.261e-08 2.261e-08 -7.646 -7.646 0.000 - CaHCO2[18O]+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 - CaHCO[18O]O+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 - CaHC[18O]O2+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 -H(0) 8.423e-16 - H2 4.212e-16 4.213e-16 -15.376 -15.375 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -61.631 -61.631 0.000 - O[18O] 0.000e+00 0.000e+00 -64.030 -64.030 0.000 -[13C](-4) 9.814e-30 - [13C]H4 9.814e-30 9.817e-30 -29.008 -29.008 0.000 -[13C](4) 4.280e-05 - [13C]O2 3.173e-05 3.174e-05 -4.499 -4.498 0.000 - H[13C]O3- 1.081e-05 1.036e-05 -4.966 -4.985 -0.019 - [13C]O[18O] 1.319e-07 1.320e-07 -6.880 -6.879 0.000 - CaH[13C]O3+ 5.771e-08 5.532e-08 -7.239 -7.257 -0.018 - H[13C]O2[18O]- 2.157e-08 2.066e-08 -7.666 -7.685 -0.019 - H[13C]O[18O]O- 2.157e-08 2.066e-08 -7.666 -7.685 -0.019 - H[13C][18O]O2- 2.157e-08 2.066e-08 -7.666 -7.685 -0.019 - [13C]O3-2 4.202e-10 3.536e-10 -9.377 -9.451 -0.075 - Ca[13C]O3 2.485e-10 2.486e-10 -9.605 -9.604 0.000 - [13C][18O]2 1.372e-10 1.372e-10 -9.863 -9.863 0.000 - CaH[13C]O2[18O]+ 1.151e-10 1.104e-10 -9.939 -9.957 -0.018 - CaH[13C]O[18O]O+ 1.151e-10 1.104e-10 -9.939 -9.957 -0.018 - CaH[13C][18O]O2+ 1.151e-10 1.104e-10 -9.939 -9.957 -0.018 - H[13C]O[18O]2- 4.304e-11 4.123e-11 -10.366 -10.385 -0.019 - H[13C][18O]2O- 4.304e-11 4.123e-11 -10.366 -10.385 -0.019 - H[13C][18O]O[18O]- 4.304e-11 4.123e-11 -10.366 -10.385 -0.019 -[14C](-4) 9.292e-40 - [14C]H4 9.292e-40 9.295e-40 -39.032 -39.032 0.000 -[14C](4) 4.061e-15 - [14C]O2 3.004e-15 3.005e-15 -14.522 -14.522 0.000 - H[14C]O3- 1.033e-15 9.891e-16 -14.986 -15.005 -0.019 - [14C]O[18O] 1.249e-17 1.250e-17 -16.903 -16.903 0.000 - CaH[14C]O3+ 5.512e-18 5.283e-18 -17.259 -17.277 -0.018 - H[14C]O2[18O]- 2.060e-18 1.973e-18 -17.686 -17.705 -0.019 - H[14C]O[18O]O- 2.060e-18 1.973e-18 -17.686 -17.705 -0.019 - H[14C][18O]O2- 2.060e-18 1.973e-18 -17.686 -17.705 -0.019 - [14C]O3-2 4.007e-20 3.372e-20 -19.397 -19.472 -0.075 - Ca[14C]O3 2.370e-20 2.371e-20 -19.625 -19.625 0.000 - [14C][18O]2 1.299e-20 1.299e-20 -19.887 -19.886 0.000 - CaH[14C]O2[18O]+ 1.100e-20 1.054e-20 -19.959 -19.977 -0.018 - CaH[14C]O[18O]O+ 1.100e-20 1.054e-20 -19.959 -19.977 -0.018 - CaH[14C][18O]O2+ 1.100e-20 1.054e-20 -19.959 -19.977 -0.018 - H[14C]O[18O]2- 4.111e-21 3.937e-21 -20.386 -20.405 -0.019 - H[14C][18O]2O- 4.111e-21 3.937e-21 -20.386 -20.405 -0.019 - H[14C][18O]O[18O]- 4.111e-21 3.937e-21 -20.386 -20.405 -0.019 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - CO[18O] 1.209e-05 1.209e-05 -4.918 -4.918 0.000 - HCO2[18O]- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 - HCO[18O]O- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 - HC[18O]O2- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 - [13C]O[18O] 1.319e-07 1.320e-07 -6.880 -6.879 0.000 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -64.030 -64.030 0.000 - [18O]2 0.000e+00 0.000e+00 -67.031 -67.031 0.000 + H3O+ 1.426e-06 1.369e-06 -5.846 -5.864 -0.018 (0) + OH- 7.606e-09 7.283e-09 -8.119 -8.138 -0.019 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 8.991e-28 + CH4 8.991e-28 8.994e-28 -27.046 -27.046 0.000 (0) +C(4) 3.912e-03 + CO2 2.907e-03 2.908e-03 -2.537 -2.536 0.000 (0) + HCO3- 9.821e-04 9.406e-04 -3.008 -3.027 -0.019 (0) + CO[18O] 1.209e-05 1.209e-05 -4.918 -4.918 0.000 (0) + CaHCO3+ 5.242e-06 5.024e-06 -5.281 -5.299 -0.018 (0) + HCO2[18O]- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 (0) + HCO[18O]O- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 (0) + HC[18O]O2- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 (0) + CO3-2 3.822e-08 3.216e-08 -7.418 -7.493 -0.075 (0) + CaCO3 2.261e-08 2.261e-08 -7.646 -7.646 0.000 (0) + C[18O]2 1.257e-08 1.257e-08 -7.901 -7.901 0.000 (0) + CaHCO2[18O]+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 (0) + CaHCO[18O]O+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 (0) + CaHC[18O]O2+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 (0) +Ca 5.014e-04 + Ca+2 4.961e-04 4.185e-04 -3.304 -3.378 -0.074 (0) + CaHCO3+ 5.242e-06 5.024e-06 -5.281 -5.299 -0.018 (0) + CaH[13C]O3+ 5.771e-08 5.532e-08 -7.239 -7.257 -0.018 (0) + CaCO3 2.261e-08 2.261e-08 -7.646 -7.646 0.000 (0) + CaHCO2[18O]+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 (0) + CaHCO[18O]O+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 (0) + CaHC[18O]O2+ 1.046e-08 1.002e-08 -7.981 -7.999 -0.018 (0) +H(0) 8.423e-16 + H2 4.212e-16 4.213e-16 -15.376 -15.375 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -61.631 -61.631 0.000 (0) + O[18O] 0.000e+00 0.000e+00 -64.030 -64.030 0.000 (0) +[13C](-4) 9.814e-30 + [13C]H4 9.814e-30 9.817e-30 -29.008 -29.008 0.000 (0) +[13C](4) 4.280e-05 + [13C]O2 3.173e-05 3.174e-05 -4.499 -4.498 0.000 (0) + H[13C]O3- 1.081e-05 1.036e-05 -4.966 -4.985 -0.019 (0) + [13C]O[18O] 1.319e-07 1.320e-07 -6.880 -6.879 0.000 (0) + CaH[13C]O3+ 5.771e-08 5.532e-08 -7.239 -7.257 -0.018 (0) + H[13C]O2[18O]- 2.157e-08 2.066e-08 -7.666 -7.685 -0.019 (0) + H[13C]O[18O]O- 2.157e-08 2.066e-08 -7.666 -7.685 -0.019 (0) + H[13C][18O]O2- 2.157e-08 2.066e-08 -7.666 -7.685 -0.019 (0) + [13C]O3-2 4.202e-10 3.536e-10 -9.377 -9.451 -0.075 (0) + Ca[13C]O3 2.485e-10 2.486e-10 -9.605 -9.604 0.000 (0) + [13C][18O]2 1.372e-10 1.372e-10 -9.863 -9.863 0.000 (0) + CaH[13C]O2[18O]+ 1.151e-10 1.104e-10 -9.939 -9.957 -0.018 (0) + CaH[13C]O[18O]O+ 1.151e-10 1.104e-10 -9.939 -9.957 -0.018 (0) + CaH[13C][18O]O2+ 1.151e-10 1.104e-10 -9.939 -9.957 -0.018 (0) + H[13C]O[18O]2- 4.304e-11 4.123e-11 -10.366 -10.385 -0.019 (0) + H[13C][18O]2O- 4.304e-11 4.123e-11 -10.366 -10.385 -0.019 (0) + H[13C][18O]O[18O]- 4.304e-11 4.123e-11 -10.366 -10.385 -0.019 (0) +[14C](-4) 9.292e-40 + [14C]H4 9.292e-40 9.295e-40 -39.032 -39.032 0.000 (0) +[14C](4) 4.061e-15 + [14C]O2 3.004e-15 3.005e-15 -14.522 -14.522 0.000 (0) + H[14C]O3- 1.033e-15 9.891e-16 -14.986 -15.005 -0.019 (0) + [14C]O[18O] 1.249e-17 1.250e-17 -16.903 -16.903 0.000 (0) + CaH[14C]O3+ 5.512e-18 5.283e-18 -17.259 -17.277 -0.018 (0) + H[14C]O2[18O]- 2.060e-18 1.973e-18 -17.686 -17.705 -0.019 (0) + H[14C]O[18O]O- 2.060e-18 1.973e-18 -17.686 -17.705 -0.019 (0) + H[14C][18O]O2- 2.060e-18 1.973e-18 -17.686 -17.705 -0.019 (0) + [14C]O3-2 4.007e-20 3.372e-20 -19.397 -19.472 -0.075 (0) + Ca[14C]O3 2.370e-20 2.371e-20 -19.625 -19.625 0.000 (0) + [14C][18O]2 1.299e-20 1.299e-20 -19.887 -19.886 0.000 (0) + CaH[14C]O2[18O]+ 1.100e-20 1.054e-20 -19.959 -19.977 -0.018 (0) + CaH[14C]O[18O]O+ 1.100e-20 1.054e-20 -19.959 -19.977 -0.018 (0) + CaH[14C][18O]O2+ 1.100e-20 1.054e-20 -19.959 -19.977 -0.018 (0) + H[14C]O[18O]2- 4.111e-21 3.937e-21 -20.386 -20.405 -0.019 (0) + H[14C][18O]2O- 4.111e-21 3.937e-21 -20.386 -20.405 -0.019 (0) + H[14C][18O]O[18O]- 4.111e-21 3.937e-21 -20.386 -20.405 -0.019 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + CO[18O] 1.209e-05 1.209e-05 -4.918 -4.918 0.000 (0) + HCO2[18O]- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 (0) + HCO[18O]O- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 (0) + HC[18O]O2- 1.959e-06 1.877e-06 -5.708 -5.727 -0.019 (0) + [13C]O[18O] 1.319e-07 1.320e-07 -6.880 -6.879 0.000 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -64.030 -64.030 0.000 (0) + [18O]2 0.000e+00 0.000e+00 -67.031 -67.031 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -28048,93 +28048,93 @@ Alpha 14C CO3-2/CO2(aq) 1.0146 14.452 14.452 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 6.145e-07 5.816e-07 -6.211 -6.235 -0.024 - OH- 1.821e-08 1.715e-08 -7.740 -7.766 -0.026 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -122.264 -122.263 0.000 -C(4) 4.408e-03 - CO2 2.414e-03 2.416e-03 -2.617 -2.617 0.000 - HCO3- 1.953e-03 1.840e-03 -2.709 -2.735 -0.026 - CaHCO3+ 1.937e-05 1.827e-05 -4.713 -4.738 -0.025 - CO[18O] 1.004e-05 1.005e-05 -4.998 -4.998 0.000 - HCO2[18O]- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 - HCO[18O]O- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 - HC[18O]O2- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 - CaCO3 1.935e-07 1.936e-07 -6.713 -6.713 0.000 - CO3-2 1.879e-07 1.481e-07 -6.726 -6.829 -0.103 - CaHCO2[18O]+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 - CaHCO[18O]O+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 - CaHC[18O]O2+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 - C[18O]2 1.044e-08 1.044e-08 -7.981 -7.981 0.000 - HCO[18O]2- 7.773e-09 7.323e-09 -8.109 -8.135 -0.026 - HC[18O]2O- 7.773e-09 7.323e-09 -8.109 -8.135 -0.026 - HC[18O]O[18O]- 7.773e-09 7.323e-09 -8.109 -8.135 -0.026 -Ca 1.003e-03 - Ca+2 9.830e-04 7.783e-04 -3.007 -3.109 -0.101 - CaHCO3+ 1.937e-05 1.827e-05 -4.713 -4.738 -0.025 - CaH[13C]O3+ 2.135e-07 2.014e-07 -6.671 -6.696 -0.025 - CaCO3 1.935e-07 1.936e-07 -6.713 -6.713 0.000 - CaHCO2[18O]+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 - CaHCO[18O]O+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 - CaHC[18O]O2+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 - Ca[13C]O3 2.129e-09 2.131e-09 -8.672 -8.671 0.000 - CaCO2[18O] 1.158e-09 1.159e-09 -8.936 -8.936 0.000 -H(0) 1.384e-39 - H2 6.920e-40 6.925e-40 -39.160 -39.160 0.000 -O(0) 1.738e-14 - O2 8.653e-15 8.659e-15 -14.063 -14.063 0.000 - O[18O] 3.453e-17 3.455e-17 -16.462 -16.462 0.000 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -124.225 -124.225 0.000 -[13C](4) 4.835e-05 - [13C]O2 2.638e-05 2.639e-05 -4.579 -4.578 0.000 - H[13C]O3- 2.152e-05 2.028e-05 -4.667 -4.693 -0.026 - CaH[13C]O3+ 2.135e-07 2.014e-07 -6.671 -6.696 -0.025 - [13C]O[18O] 1.097e-07 1.098e-07 -6.960 -6.960 0.000 - H[13C]O2[18O]- 4.294e-08 4.045e-08 -7.367 -7.393 -0.026 - H[13C]O[18O]O- 4.294e-08 4.045e-08 -7.367 -7.393 -0.026 - H[13C][18O]O2- 4.294e-08 4.045e-08 -7.367 -7.393 -0.026 - Ca[13C]O3 2.129e-09 2.131e-09 -8.672 -8.671 0.000 - [13C]O3-2 2.068e-09 1.630e-09 -8.684 -8.788 -0.103 - CaH[13C]O2[18O]+ 4.259e-10 4.018e-10 -9.371 -9.396 -0.025 - CaH[13C]O[18O]O+ 4.259e-10 4.018e-10 -9.371 -9.396 -0.025 - CaH[13C][18O]O2+ 4.259e-10 4.018e-10 -9.371 -9.396 -0.025 - [13C][18O]2 1.140e-10 1.141e-10 -9.943 -9.943 0.000 - H[13C]O[18O]2- 8.566e-11 8.071e-11 -10.067 -10.093 -0.026 - H[13C][18O]2O- 8.566e-11 8.071e-11 -10.067 -10.093 -0.026 - H[13C][18O]O[18O]- 8.566e-11 8.071e-11 -10.067 -10.093 -0.026 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -134.303 -134.302 0.000 -[14C](4) 4.061e-15 - [14C]O2 2.207e-15 2.208e-15 -14.656 -14.656 0.000 - H[14C]O3- 1.816e-15 1.711e-15 -14.741 -14.767 -0.026 - CaH[14C]O3+ 1.801e-17 1.699e-17 -16.744 -16.770 -0.025 - [14C]O[18O] 9.176e-18 9.182e-18 -17.037 -17.037 0.000 - H[14C]O2[18O]- 3.623e-18 3.414e-18 -17.441 -17.467 -0.026 - H[14C]O[18O]O- 3.623e-18 3.414e-18 -17.441 -17.467 -0.026 - H[14C][18O]O2- 3.623e-18 3.414e-18 -17.441 -17.467 -0.026 - Ca[14C]O3 1.794e-19 1.796e-19 -18.746 -18.746 0.000 - [14C]O3-2 1.743e-19 1.373e-19 -18.759 -18.862 -0.103 - CaH[14C]O2[18O]+ 3.594e-20 3.391e-20 -19.444 -19.470 -0.025 - CaH[14C]O[18O]O+ 3.594e-20 3.391e-20 -19.444 -19.470 -0.025 - CaH[14C][18O]O2+ 3.594e-20 3.391e-20 -19.444 -19.470 -0.025 - [14C][18O]2 9.539e-21 9.545e-21 -20.021 -20.020 0.000 - H[14C]O[18O]2- 7.229e-21 6.811e-21 -20.141 -20.167 -0.026 - H[14C][18O]2O- 7.229e-21 6.811e-21 -20.141 -20.167 -0.026 - H[14C][18O]O[18O]- 7.229e-21 6.811e-21 -20.141 -20.167 -0.026 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - CO[18O] 1.004e-05 1.005e-05 -4.998 -4.998 0.000 - HCO2[18O]- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 - HCO[18O]O- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 - HC[18O]O2- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 -[18O](0) 3.460e-17 - O[18O] 3.453e-17 3.455e-17 -16.462 -16.462 0.000 - [18O]2 3.444e-20 3.447e-20 -19.463 -19.463 0.000 + H3O+ 6.145e-07 5.816e-07 -6.211 -6.235 -0.024 (0) + OH- 1.821e-08 1.715e-08 -7.740 -7.766 -0.026 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -122.264 -122.263 0.000 (0) +C(4) 4.408e-03 + CO2 2.414e-03 2.416e-03 -2.617 -2.617 0.000 (0) + HCO3- 1.953e-03 1.840e-03 -2.709 -2.735 -0.026 (0) + CaHCO3+ 1.937e-05 1.827e-05 -4.713 -4.738 -0.025 (0) + CO[18O] 1.004e-05 1.005e-05 -4.998 -4.998 0.000 (0) + HCO2[18O]- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 (0) + HCO[18O]O- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 (0) + HC[18O]O2- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 (0) + CaCO3 1.935e-07 1.936e-07 -6.713 -6.713 0.000 (0) + CO3-2 1.879e-07 1.481e-07 -6.726 -6.829 -0.103 (0) + CaHCO2[18O]+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 (0) + CaHCO[18O]O+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 (0) + CaHC[18O]O2+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 (0) + C[18O]2 1.044e-08 1.044e-08 -7.981 -7.981 0.000 (0) + HCO[18O]2- 7.773e-09 7.323e-09 -8.109 -8.135 -0.026 (0) + HC[18O]2O- 7.773e-09 7.323e-09 -8.109 -8.135 -0.026 (0) + HC[18O]O[18O]- 7.773e-09 7.323e-09 -8.109 -8.135 -0.026 (0) +Ca 1.003e-03 + Ca+2 9.830e-04 7.783e-04 -3.007 -3.109 -0.101 (0) + CaHCO3+ 1.937e-05 1.827e-05 -4.713 -4.738 -0.025 (0) + CaH[13C]O3+ 2.135e-07 2.014e-07 -6.671 -6.696 -0.025 (0) + CaCO3 1.935e-07 1.936e-07 -6.713 -6.713 0.000 (0) + CaHCO2[18O]+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 (0) + CaHCO[18O]O+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 (0) + CaHC[18O]O2+ 3.864e-08 3.646e-08 -7.413 -7.438 -0.025 (0) + Ca[13C]O3 2.129e-09 2.131e-09 -8.672 -8.671 0.000 (0) + CaCO2[18O] 1.158e-09 1.159e-09 -8.936 -8.936 0.000 (0) +H(0) 1.384e-39 + H2 6.920e-40 6.925e-40 -39.160 -39.160 0.000 (0) +O(0) 1.738e-14 + O2 8.653e-15 8.659e-15 -14.063 -14.063 0.000 (0) + O[18O] 3.453e-17 3.455e-17 -16.462 -16.462 0.000 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -124.225 -124.225 0.000 (0) +[13C](4) 4.835e-05 + [13C]O2 2.638e-05 2.639e-05 -4.579 -4.578 0.000 (0) + H[13C]O3- 2.152e-05 2.028e-05 -4.667 -4.693 -0.026 (0) + CaH[13C]O3+ 2.135e-07 2.014e-07 -6.671 -6.696 -0.025 (0) + [13C]O[18O] 1.097e-07 1.098e-07 -6.960 -6.960 0.000 (0) + H[13C]O2[18O]- 4.294e-08 4.045e-08 -7.367 -7.393 -0.026 (0) + H[13C]O[18O]O- 4.294e-08 4.045e-08 -7.367 -7.393 -0.026 (0) + H[13C][18O]O2- 4.294e-08 4.045e-08 -7.367 -7.393 -0.026 (0) + Ca[13C]O3 2.129e-09 2.131e-09 -8.672 -8.671 0.000 (0) + [13C]O3-2 2.068e-09 1.630e-09 -8.684 -8.788 -0.103 (0) + CaH[13C]O2[18O]+ 4.259e-10 4.018e-10 -9.371 -9.396 -0.025 (0) + CaH[13C]O[18O]O+ 4.259e-10 4.018e-10 -9.371 -9.396 -0.025 (0) + CaH[13C][18O]O2+ 4.259e-10 4.018e-10 -9.371 -9.396 -0.025 (0) + [13C][18O]2 1.140e-10 1.141e-10 -9.943 -9.943 0.000 (0) + H[13C]O[18O]2- 8.566e-11 8.071e-11 -10.067 -10.093 -0.026 (0) + H[13C][18O]2O- 8.566e-11 8.071e-11 -10.067 -10.093 -0.026 (0) + H[13C][18O]O[18O]- 8.566e-11 8.071e-11 -10.067 -10.093 -0.026 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -134.303 -134.302 0.000 (0) +[14C](4) 4.061e-15 + [14C]O2 2.207e-15 2.208e-15 -14.656 -14.656 0.000 (0) + H[14C]O3- 1.816e-15 1.711e-15 -14.741 -14.767 -0.026 (0) + CaH[14C]O3+ 1.801e-17 1.699e-17 -16.744 -16.770 -0.025 (0) + [14C]O[18O] 9.176e-18 9.182e-18 -17.037 -17.037 0.000 (0) + H[14C]O2[18O]- 3.623e-18 3.414e-18 -17.441 -17.467 -0.026 (0) + H[14C]O[18O]O- 3.623e-18 3.414e-18 -17.441 -17.467 -0.026 (0) + H[14C][18O]O2- 3.623e-18 3.414e-18 -17.441 -17.467 -0.026 (0) + Ca[14C]O3 1.794e-19 1.796e-19 -18.746 -18.746 0.000 (0) + [14C]O3-2 1.743e-19 1.373e-19 -18.759 -18.862 -0.103 (0) + CaH[14C]O2[18O]+ 3.594e-20 3.391e-20 -19.444 -19.470 -0.025 (0) + CaH[14C]O[18O]O+ 3.594e-20 3.391e-20 -19.444 -19.470 -0.025 (0) + CaH[14C][18O]O2+ 3.594e-20 3.391e-20 -19.444 -19.470 -0.025 (0) + [14C][18O]2 9.539e-21 9.545e-21 -20.021 -20.020 0.000 (0) + H[14C]O[18O]2- 7.229e-21 6.811e-21 -20.141 -20.167 -0.026 (0) + H[14C][18O]2O- 7.229e-21 6.811e-21 -20.141 -20.167 -0.026 (0) + H[14C][18O]O[18O]- 7.229e-21 6.811e-21 -20.141 -20.167 -0.026 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + CO[18O] 1.004e-05 1.005e-05 -4.998 -4.998 0.000 (0) + HCO2[18O]- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 (0) + HCO[18O]O- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 (0) + HC[18O]O2- 3.896e-06 3.670e-06 -5.409 -5.435 -0.026 (0) +[18O](0) 3.460e-17 + O[18O] 3.453e-17 3.455e-17 -16.462 -16.462 0.000 (0) + [18O]2 3.444e-20 3.447e-20 -19.463 -19.463 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -28293,93 +28293,93 @@ Alpha 14C CH4(aq)/CO2(aq) 1 1.7764e-12 0 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 3.351e-07 3.139e-07 -6.475 -6.503 -0.028 - OH- 3.415e-08 3.176e-08 -7.467 -7.498 -0.031 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 4.315e-22 - CH4 4.315e-22 4.320e-22 -21.365 -21.365 0.000 -C(4) 4.904e-03 - HCO3- 2.915e-03 2.713e-03 -2.535 -2.566 -0.031 - CO2 1.921e-03 1.923e-03 -2.716 -2.716 0.000 - CaHCO3+ 4.104e-05 3.827e-05 -4.387 -4.417 -0.030 - CO[18O] 7.989e-06 7.997e-06 -5.097 -5.097 0.000 - HCO2[18O]- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 - HCO[18O]O- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 - HC[18O]O2- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 - CaCO3 7.505e-07 7.513e-07 -6.125 -6.124 0.000 - CO3-2 5.389e-07 4.047e-07 -6.269 -6.393 -0.124 - CaHCO2[18O]+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 - CaHCO[18O]O+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 - CaHC[18O]O2+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 - HCO[18O]2- 1.160e-08 1.080e-08 -7.935 -7.967 -0.031 - HC[18O]2O- 1.160e-08 1.080e-08 -7.935 -7.967 -0.031 - HC[18O]O[18O]- 1.160e-08 1.080e-08 -7.935 -7.967 -0.031 - C[18O]2 8.305e-09 8.314e-09 -8.081 -8.080 0.000 -Ca 1.504e-03 - Ca+2 1.462e-03 1.105e-03 -2.835 -2.957 -0.121 - CaHCO3+ 4.104e-05 3.827e-05 -4.387 -4.417 -0.030 - CaCO3 7.505e-07 7.513e-07 -6.125 -6.124 0.000 - CaH[13C]O3+ 4.526e-07 4.221e-07 -6.344 -6.375 -0.030 - CaHCO2[18O]+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 - CaHCO[18O]O+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 - CaHC[18O]O2+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 - Ca[13C]O3 8.266e-09 8.275e-09 -8.083 -8.082 0.000 - CaCO2[18O] 4.492e-09 4.497e-09 -8.348 -8.347 0.000 -H(0) 2.457e-14 - H2 1.229e-14 1.230e-14 -13.911 -13.910 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -64.562 -64.561 0.000 - O[18O] 0.000e+00 0.000e+00 -66.961 -66.960 0.000 -[13C](-4) 4.719e-24 - [13C]H4 4.719e-24 4.724e-24 -23.326 -23.326 0.000 -[13C](4) 5.391e-05 - H[13C]O3- 3.215e-05 2.993e-05 -4.493 -4.524 -0.031 - [13C]O2 2.101e-05 2.103e-05 -4.678 -4.677 0.000 - CaH[13C]O3+ 4.526e-07 4.221e-07 -6.344 -6.375 -0.030 - [13C]O[18O] 8.736e-08 8.745e-08 -7.059 -7.058 0.000 - H[13C]O2[18O]- 6.415e-08 5.971e-08 -7.193 -7.224 -0.031 - H[13C]O[18O]O- 6.415e-08 5.971e-08 -7.193 -7.224 -0.031 - H[13C][18O]O2- 6.415e-08 5.971e-08 -7.193 -7.224 -0.031 - Ca[13C]O3 8.266e-09 8.275e-09 -8.083 -8.082 0.000 - [13C]O3-2 5.935e-09 4.457e-09 -8.227 -8.351 -0.124 - CaH[13C]O2[18O]+ 9.031e-10 8.422e-10 -9.044 -9.075 -0.030 - CaH[13C]O[18O]O+ 9.031e-10 8.422e-10 -9.044 -9.075 -0.030 - CaH[13C][18O]O2+ 9.031e-10 8.422e-10 -9.044 -9.075 -0.030 - H[13C]O[18O]2- 1.280e-10 1.191e-10 -9.893 -9.924 -0.031 - H[13C][18O]2O- 1.280e-10 1.191e-10 -9.893 -9.924 -0.031 - H[13C][18O]O[18O]- 1.280e-10 1.191e-10 -9.893 -9.924 -0.031 - [13C][18O]2 9.082e-11 9.091e-11 -10.042 -10.041 0.000 -[14C](-4) 3.536e-34 - [14C]H4 3.536e-34 3.540e-34 -33.451 -33.451 0.000 -[14C](4) 4.061e-15 - H[14C]O3- 2.430e-15 2.262e-15 -14.614 -14.645 -0.031 - [14C]O2 1.574e-15 1.576e-15 -14.803 -14.802 0.000 - CaH[14C]O3+ 3.421e-17 3.191e-17 -16.466 -16.496 -0.030 - [14C]O[18O] 6.547e-18 6.553e-18 -17.184 -17.184 0.000 - H[14C]O2[18O]- 4.849e-18 4.514e-18 -17.314 -17.345 -0.031 - H[14C]O[18O]O- 4.849e-18 4.514e-18 -17.314 -17.345 -0.031 - H[14C][18O]O2- 4.849e-18 4.514e-18 -17.314 -17.345 -0.031 - Ca[14C]O3 6.239e-19 6.246e-19 -18.205 -18.204 0.000 - [14C]O3-2 4.480e-19 3.364e-19 -18.349 -18.473 -0.124 - CaH[14C]O2[18O]+ 6.826e-20 6.366e-20 -19.166 -19.196 -0.030 - CaH[14C]O[18O]O+ 6.826e-20 6.366e-20 -19.166 -19.196 -0.030 - CaH[14C][18O]O2+ 6.826e-20 6.366e-20 -19.166 -19.196 -0.030 - H[14C]O[18O]2- 9.674e-21 9.006e-21 -20.014 -20.045 -0.031 - H[14C][18O]2O- 9.674e-21 9.006e-21 -20.014 -20.045 -0.031 - H[14C][18O]O[18O]- 9.674e-21 9.006e-21 -20.014 -20.045 -0.031 - [14C][18O]2 6.806e-21 6.813e-21 -20.167 -20.167 0.000 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - CO[18O] 7.989e-06 7.997e-06 -5.097 -5.097 0.000 - HCO2[18O]- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 - HCO[18O]O- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 - HC[18O]O2- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -66.961 -66.960 0.000 - [18O]2 0.000e+00 0.000e+00 -69.962 -69.961 0.000 + H3O+ 3.351e-07 3.139e-07 -6.475 -6.503 -0.028 (0) + OH- 3.415e-08 3.176e-08 -7.467 -7.498 -0.031 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 4.315e-22 + CH4 4.315e-22 4.320e-22 -21.365 -21.365 0.000 (0) +C(4) 4.904e-03 + HCO3- 2.915e-03 2.713e-03 -2.535 -2.566 -0.031 (0) + CO2 1.921e-03 1.923e-03 -2.716 -2.716 0.000 (0) + CaHCO3+ 4.104e-05 3.827e-05 -4.387 -4.417 -0.030 (0) + CO[18O] 7.989e-06 7.997e-06 -5.097 -5.097 0.000 (0) + HCO2[18O]- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 (0) + HCO[18O]O- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 (0) + HC[18O]O2- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 (0) + CaCO3 7.505e-07 7.513e-07 -6.125 -6.124 0.000 (0) + CO3-2 5.389e-07 4.047e-07 -6.269 -6.393 -0.124 (0) + CaHCO2[18O]+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 (0) + CaHCO[18O]O+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 (0) + CaHC[18O]O2+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 (0) + HCO[18O]2- 1.160e-08 1.080e-08 -7.935 -7.967 -0.031 (0) + HC[18O]2O- 1.160e-08 1.080e-08 -7.935 -7.967 -0.031 (0) + HC[18O]O[18O]- 1.160e-08 1.080e-08 -7.935 -7.967 -0.031 (0) + C[18O]2 8.305e-09 8.314e-09 -8.081 -8.080 0.000 (0) +Ca 1.504e-03 + Ca+2 1.462e-03 1.105e-03 -2.835 -2.957 -0.121 (0) + CaHCO3+ 4.104e-05 3.827e-05 -4.387 -4.417 -0.030 (0) + CaCO3 7.505e-07 7.513e-07 -6.125 -6.124 0.000 (0) + CaH[13C]O3+ 4.526e-07 4.221e-07 -6.344 -6.375 -0.030 (0) + CaHCO2[18O]+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 (0) + CaHCO[18O]O+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 (0) + CaHC[18O]O2+ 8.187e-08 7.635e-08 -7.087 -7.117 -0.030 (0) + Ca[13C]O3 8.266e-09 8.275e-09 -8.083 -8.082 0.000 (0) + CaCO2[18O] 4.492e-09 4.497e-09 -8.348 -8.347 0.000 (0) +H(0) 2.457e-14 + H2 1.229e-14 1.230e-14 -13.911 -13.910 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -64.562 -64.561 0.000 (0) + O[18O] 0.000e+00 0.000e+00 -66.961 -66.960 0.000 (0) +[13C](-4) 4.719e-24 + [13C]H4 4.719e-24 4.724e-24 -23.326 -23.326 0.000 (0) +[13C](4) 5.391e-05 + H[13C]O3- 3.215e-05 2.993e-05 -4.493 -4.524 -0.031 (0) + [13C]O2 2.101e-05 2.103e-05 -4.678 -4.677 0.000 (0) + CaH[13C]O3+ 4.526e-07 4.221e-07 -6.344 -6.375 -0.030 (0) + [13C]O[18O] 8.736e-08 8.745e-08 -7.059 -7.058 0.000 (0) + H[13C]O2[18O]- 6.415e-08 5.971e-08 -7.193 -7.224 -0.031 (0) + H[13C]O[18O]O- 6.415e-08 5.971e-08 -7.193 -7.224 -0.031 (0) + H[13C][18O]O2- 6.415e-08 5.971e-08 -7.193 -7.224 -0.031 (0) + Ca[13C]O3 8.266e-09 8.275e-09 -8.083 -8.082 0.000 (0) + [13C]O3-2 5.935e-09 4.457e-09 -8.227 -8.351 -0.124 (0) + CaH[13C]O2[18O]+ 9.031e-10 8.422e-10 -9.044 -9.075 -0.030 (0) + CaH[13C]O[18O]O+ 9.031e-10 8.422e-10 -9.044 -9.075 -0.030 (0) + CaH[13C][18O]O2+ 9.031e-10 8.422e-10 -9.044 -9.075 -0.030 (0) + H[13C]O[18O]2- 1.280e-10 1.191e-10 -9.893 -9.924 -0.031 (0) + H[13C][18O]2O- 1.280e-10 1.191e-10 -9.893 -9.924 -0.031 (0) + H[13C][18O]O[18O]- 1.280e-10 1.191e-10 -9.893 -9.924 -0.031 (0) + [13C][18O]2 9.082e-11 9.091e-11 -10.042 -10.041 0.000 (0) +[14C](-4) 3.536e-34 + [14C]H4 3.536e-34 3.540e-34 -33.451 -33.451 0.000 (0) +[14C](4) 4.061e-15 + H[14C]O3- 2.430e-15 2.262e-15 -14.614 -14.645 -0.031 (0) + [14C]O2 1.574e-15 1.576e-15 -14.803 -14.802 0.000 (0) + CaH[14C]O3+ 3.421e-17 3.191e-17 -16.466 -16.496 -0.030 (0) + [14C]O[18O] 6.547e-18 6.553e-18 -17.184 -17.184 0.000 (0) + H[14C]O2[18O]- 4.849e-18 4.514e-18 -17.314 -17.345 -0.031 (0) + H[14C]O[18O]O- 4.849e-18 4.514e-18 -17.314 -17.345 -0.031 (0) + H[14C][18O]O2- 4.849e-18 4.514e-18 -17.314 -17.345 -0.031 (0) + Ca[14C]O3 6.239e-19 6.246e-19 -18.205 -18.204 0.000 (0) + [14C]O3-2 4.480e-19 3.364e-19 -18.349 -18.473 -0.124 (0) + CaH[14C]O2[18O]+ 6.826e-20 6.366e-20 -19.166 -19.196 -0.030 (0) + CaH[14C]O[18O]O+ 6.826e-20 6.366e-20 -19.166 -19.196 -0.030 (0) + CaH[14C][18O]O2+ 6.826e-20 6.366e-20 -19.166 -19.196 -0.030 (0) + H[14C]O[18O]2- 9.674e-21 9.006e-21 -20.014 -20.045 -0.031 (0) + H[14C][18O]2O- 9.674e-21 9.006e-21 -20.014 -20.045 -0.031 (0) + H[14C][18O]O[18O]- 9.674e-21 9.006e-21 -20.014 -20.045 -0.031 (0) + [14C][18O]2 6.806e-21 6.813e-21 -20.167 -20.167 0.000 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + CO[18O] 7.989e-06 7.997e-06 -5.097 -5.097 0.000 (0) + HCO2[18O]- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 (0) + HCO[18O]O- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 (0) + HC[18O]O2- 5.816e-06 5.414e-06 -5.235 -5.267 -0.031 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -66.961 -66.960 0.000 (0) + [18O]2 0.000e+00 0.000e+00 -69.962 -69.961 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -28538,102 +28538,102 @@ Alpha 14C CH4(aq)/CO2(aq) 1 6.8834e-12 0 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.913e-07 1.778e-07 -6.718 -6.750 -0.032 - OH- 6.090e-08 5.607e-08 -7.215 -7.251 -0.036 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.420e-21 - CH4 1.420e-21 1.422e-21 -20.848 -20.847 0.001 -C(4) 5.400e-03 - HCO3- 3.868e-03 3.566e-03 -2.413 -2.448 -0.035 - CO2 1.430e-03 1.432e-03 -2.845 -2.844 0.001 - CaHCO3+ 6.934e-05 6.406e-05 -4.159 -4.193 -0.034 - HCO2[18O]- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 - HCO[18O]O- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 - HC[18O]O2- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 - CO[18O] 5.945e-06 5.953e-06 -5.226 -5.225 0.001 - CaCO3 2.217e-06 2.220e-06 -5.654 -5.654 0.001 - CO3-2 1.300e-06 9.387e-07 -5.886 -6.027 -0.141 - CaHCO2[18O]+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 - CaHCO[18O]O+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 - CaHC[18O]O2+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 - HCO[18O]2- 1.540e-08 1.419e-08 -7.813 -7.848 -0.035 - HC[18O]2O- 1.540e-08 1.419e-08 -7.813 -7.848 -0.035 - HC[18O]O[18O]- 1.540e-08 1.419e-08 -7.813 -7.848 -0.035 - CaCO2[18O] 1.327e-08 1.329e-08 -7.877 -7.877 0.001 - CO2[18O]-2 7.781e-09 5.619e-09 -8.109 -8.250 -0.141 - C[18O]2 6.180e-09 6.189e-09 -8.209 -8.208 0.001 -Ca 2.006e-03 - Ca+2 1.933e-03 1.408e-03 -2.714 -2.851 -0.138 - CaHCO3+ 6.934e-05 6.406e-05 -4.159 -4.193 -0.034 - CaCO3 2.217e-06 2.220e-06 -5.654 -5.654 0.001 - CaH[13C]O3+ 7.653e-07 7.071e-07 -6.116 -6.151 -0.034 - CaHCO2[18O]+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 - CaHCO[18O]O+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 - CaHC[18O]O2+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 - Ca[13C]O3 2.444e-08 2.447e-08 -7.612 -7.611 0.001 - CaCO2[18O] 1.327e-08 1.329e-08 -7.877 -7.877 0.001 -H(0) 3.562e-14 - H2 1.781e-14 1.784e-14 -13.749 -13.749 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -64.885 -64.884 0.001 - O[18O] 0.000e+00 0.000e+00 -67.284 -67.283 0.001 -[13C](-4) 1.554e-23 - [13C]H4 1.554e-23 1.556e-23 -22.808 -22.808 0.001 -[13C](4) 5.947e-05 - H[13C]O3- 4.269e-05 3.935e-05 -4.370 -4.405 -0.035 - [13C]O2 1.564e-05 1.566e-05 -4.806 -4.805 0.001 - CaH[13C]O3+ 7.653e-07 7.071e-07 -6.116 -6.151 -0.034 - H[13C]O2[18O]- 8.518e-08 7.852e-08 -7.070 -7.105 -0.035 - H[13C]O[18O]O- 8.518e-08 7.852e-08 -7.070 -7.105 -0.035 - H[13C][18O]O2- 8.518e-08 7.852e-08 -7.070 -7.105 -0.035 - [13C]O[18O] 6.505e-08 6.514e-08 -7.187 -7.186 0.001 - Ca[13C]O3 2.444e-08 2.447e-08 -7.612 -7.611 0.001 - [13C]O3-2 1.433e-08 1.035e-08 -7.844 -7.985 -0.141 - CaH[13C]O2[18O]+ 1.527e-09 1.411e-09 -8.816 -8.851 -0.034 - CaH[13C]O[18O]O+ 1.527e-09 1.411e-09 -8.816 -8.851 -0.034 - CaH[13C][18O]O2+ 1.527e-09 1.411e-09 -8.816 -8.851 -0.034 - H[13C]O[18O]2- 1.699e-10 1.567e-10 -9.770 -9.805 -0.035 - H[13C][18O]2O- 1.699e-10 1.567e-10 -9.770 -9.805 -0.035 - H[13C][18O]O[18O]- 1.699e-10 1.567e-10 -9.770 -9.805 -0.035 - Ca[13C]O2[18O] 1.463e-10 1.465e-10 -9.835 -9.834 0.001 - [13C]O2[18O]-2 8.576e-11 6.193e-11 -10.067 -10.208 -0.141 - [13C][18O]2 6.763e-11 6.772e-11 -10.170 -10.169 0.001 -[14C](-4) 1.055e-33 - [14C]H4 1.055e-33 1.056e-33 -32.977 -32.976 0.001 -[14C](4) 4.061e-15 - H[14C]O3- 2.922e-15 2.694e-15 -14.534 -14.570 -0.035 - [14C]O2 1.062e-15 1.063e-15 -14.974 -14.973 0.001 - CaH[14C]O3+ 5.238e-17 4.840e-17 -16.281 -16.315 -0.034 - H[14C]O2[18O]- 5.831e-18 5.375e-18 -17.234 -17.270 -0.035 - H[14C]O[18O]O- 5.831e-18 5.375e-18 -17.234 -17.270 -0.035 - H[14C][18O]O2- 5.831e-18 5.375e-18 -17.234 -17.270 -0.035 - [14C]O[18O] 4.414e-18 4.420e-18 -17.355 -17.355 0.001 - Ca[14C]O3 1.670e-18 1.673e-18 -17.777 -17.777 0.001 - [14C]O3-2 9.793e-19 7.072e-19 -18.009 -18.150 -0.141 - CaH[14C]O2[18O]+ 1.045e-19 9.657e-20 -18.981 -19.015 -0.034 - CaH[14C]O[18O]O+ 1.045e-19 9.657e-20 -18.981 -19.015 -0.034 - CaH[14C][18O]O2+ 1.045e-19 9.657e-20 -18.981 -19.015 -0.034 - H[14C]O[18O]2- 1.163e-20 1.072e-20 -19.934 -19.970 -0.035 - H[14C][18O]2O- 1.163e-20 1.072e-20 -19.934 -19.970 -0.035 - H[14C][18O]O[18O]- 1.163e-20 1.072e-20 -19.934 -19.970 -0.035 - Ca[14C]O2[18O] 9.997e-21 1.001e-20 -20.000 -20.000 0.001 - [14C]O2[18O]-2 5.862e-21 4.233e-21 -20.232 -20.373 -0.141 - [14C][18O]2 4.589e-21 4.595e-21 -20.338 -20.338 0.001 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 - HCO[18O]O- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 - HC[18O]O2- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 - CO[18O] 5.945e-06 5.953e-06 -5.226 -5.225 0.001 - CaHCO2[18O]+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 - CaHCO[18O]O+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 - CaHC[18O]O2+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.284 -67.283 0.001 - [18O]2 0.000e+00 0.000e+00 -70.285 -70.284 0.001 + H3O+ 1.913e-07 1.778e-07 -6.718 -6.750 -0.032 (0) + OH- 6.090e-08 5.607e-08 -7.215 -7.251 -0.036 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.420e-21 + CH4 1.420e-21 1.422e-21 -20.848 -20.847 0.001 (0) +C(4) 5.400e-03 + HCO3- 3.868e-03 3.566e-03 -2.413 -2.448 -0.035 (0) + CO2 1.430e-03 1.432e-03 -2.845 -2.844 0.001 (0) + CaHCO3+ 6.934e-05 6.406e-05 -4.159 -4.193 -0.034 (0) + HCO2[18O]- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 (0) + HCO[18O]O- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 (0) + HC[18O]O2- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 (0) + CO[18O] 5.945e-06 5.953e-06 -5.226 -5.225 0.001 (0) + CaCO3 2.217e-06 2.220e-06 -5.654 -5.654 0.001 (0) + CO3-2 1.300e-06 9.387e-07 -5.886 -6.027 -0.141 (0) + CaHCO2[18O]+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) + CaHCO[18O]O+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) + CaHC[18O]O2+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) + HCO[18O]2- 1.540e-08 1.419e-08 -7.813 -7.848 -0.035 (0) + HC[18O]2O- 1.540e-08 1.419e-08 -7.813 -7.848 -0.035 (0) + HC[18O]O[18O]- 1.540e-08 1.419e-08 -7.813 -7.848 -0.035 (0) + CaCO2[18O] 1.327e-08 1.329e-08 -7.877 -7.877 0.001 (0) + CO2[18O]-2 7.781e-09 5.619e-09 -8.109 -8.250 -0.141 (0) + C[18O]2 6.180e-09 6.189e-09 -8.209 -8.208 0.001 (0) +Ca 2.006e-03 + Ca+2 1.933e-03 1.408e-03 -2.714 -2.851 -0.138 (0) + CaHCO3+ 6.934e-05 6.406e-05 -4.159 -4.193 -0.034 (0) + CaCO3 2.217e-06 2.220e-06 -5.654 -5.654 0.001 (0) + CaH[13C]O3+ 7.653e-07 7.071e-07 -6.116 -6.151 -0.034 (0) + CaHCO2[18O]+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) + CaHCO[18O]O+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) + CaHC[18O]O2+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) + Ca[13C]O3 2.444e-08 2.447e-08 -7.612 -7.611 0.001 (0) + CaCO2[18O] 1.327e-08 1.329e-08 -7.877 -7.877 0.001 (0) +H(0) 3.562e-14 + H2 1.781e-14 1.784e-14 -13.749 -13.749 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -64.885 -64.884 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.284 -67.283 0.001 (0) +[13C](-4) 1.554e-23 + [13C]H4 1.554e-23 1.556e-23 -22.808 -22.808 0.001 (0) +[13C](4) 5.947e-05 + H[13C]O3- 4.269e-05 3.935e-05 -4.370 -4.405 -0.035 (0) + [13C]O2 1.564e-05 1.566e-05 -4.806 -4.805 0.001 (0) + CaH[13C]O3+ 7.653e-07 7.071e-07 -6.116 -6.151 -0.034 (0) + H[13C]O2[18O]- 8.518e-08 7.852e-08 -7.070 -7.105 -0.035 (0) + H[13C]O[18O]O- 8.518e-08 7.852e-08 -7.070 -7.105 -0.035 (0) + H[13C][18O]O2- 8.518e-08 7.852e-08 -7.070 -7.105 -0.035 (0) + [13C]O[18O] 6.505e-08 6.514e-08 -7.187 -7.186 0.001 (0) + Ca[13C]O3 2.444e-08 2.447e-08 -7.612 -7.611 0.001 (0) + [13C]O3-2 1.433e-08 1.035e-08 -7.844 -7.985 -0.141 (0) + CaH[13C]O2[18O]+ 1.527e-09 1.411e-09 -8.816 -8.851 -0.034 (0) + CaH[13C]O[18O]O+ 1.527e-09 1.411e-09 -8.816 -8.851 -0.034 (0) + CaH[13C][18O]O2+ 1.527e-09 1.411e-09 -8.816 -8.851 -0.034 (0) + H[13C]O[18O]2- 1.699e-10 1.567e-10 -9.770 -9.805 -0.035 (0) + H[13C][18O]2O- 1.699e-10 1.567e-10 -9.770 -9.805 -0.035 (0) + H[13C][18O]O[18O]- 1.699e-10 1.567e-10 -9.770 -9.805 -0.035 (0) + Ca[13C]O2[18O] 1.463e-10 1.465e-10 -9.835 -9.834 0.001 (0) + [13C]O2[18O]-2 8.576e-11 6.193e-11 -10.067 -10.208 -0.141 (0) + [13C][18O]2 6.763e-11 6.772e-11 -10.170 -10.169 0.001 (0) +[14C](-4) 1.055e-33 + [14C]H4 1.055e-33 1.056e-33 -32.977 -32.976 0.001 (0) +[14C](4) 4.061e-15 + H[14C]O3- 2.922e-15 2.694e-15 -14.534 -14.570 -0.035 (0) + [14C]O2 1.062e-15 1.063e-15 -14.974 -14.973 0.001 (0) + CaH[14C]O3+ 5.238e-17 4.840e-17 -16.281 -16.315 -0.034 (0) + H[14C]O2[18O]- 5.831e-18 5.375e-18 -17.234 -17.270 -0.035 (0) + H[14C]O[18O]O- 5.831e-18 5.375e-18 -17.234 -17.270 -0.035 (0) + H[14C][18O]O2- 5.831e-18 5.375e-18 -17.234 -17.270 -0.035 (0) + [14C]O[18O] 4.414e-18 4.420e-18 -17.355 -17.355 0.001 (0) + Ca[14C]O3 1.670e-18 1.673e-18 -17.777 -17.777 0.001 (0) + [14C]O3-2 9.793e-19 7.072e-19 -18.009 -18.150 -0.141 (0) + CaH[14C]O2[18O]+ 1.045e-19 9.657e-20 -18.981 -19.015 -0.034 (0) + CaH[14C]O[18O]O+ 1.045e-19 9.657e-20 -18.981 -19.015 -0.034 (0) + CaH[14C][18O]O2+ 1.045e-19 9.657e-20 -18.981 -19.015 -0.034 (0) + H[14C]O[18O]2- 1.163e-20 1.072e-20 -19.934 -19.970 -0.035 (0) + H[14C][18O]2O- 1.163e-20 1.072e-20 -19.934 -19.970 -0.035 (0) + H[14C][18O]O[18O]- 1.163e-20 1.072e-20 -19.934 -19.970 -0.035 (0) + Ca[14C]O2[18O] 9.997e-21 1.001e-20 -20.000 -20.000 0.001 (0) + [14C]O2[18O]-2 5.862e-21 4.233e-21 -20.232 -20.373 -0.141 (0) + [14C][18O]2 4.589e-21 4.595e-21 -20.338 -20.338 0.001 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 (0) + HCO[18O]O- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 (0) + HC[18O]O2- 7.717e-06 7.114e-06 -5.113 -5.148 -0.035 (0) + CO[18O] 5.945e-06 5.953e-06 -5.226 -5.225 0.001 (0) + CaHCO2[18O]+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) + CaHCO[18O]O+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) + CaHC[18O]O2+ 1.383e-07 1.278e-07 -6.859 -6.893 -0.034 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.284 -67.283 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.285 -70.284 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -28798,99 +28798,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.345e-20 - CH4 1.345e-20 1.347e-20 -19.871 -19.871 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.304e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.979e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.936e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.936e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.097e-06 1.007e-06 -5.960 -5.997 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.023e-08 6.033e-08 -7.220 -7.219 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 6.837e-14 - H2 3.419e-14 3.424e-14 -13.466 -13.465 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.452 -65.451 0.001 - O[18O] 0.000e+00 0.000e+00 -67.851 -67.850 0.001 -[13C](-4) 1.472e-22 - [13C]H4 1.472e-22 1.475e-22 -21.832 -21.831 0.001 -[13C](4) 6.440e-05 - H[13C]O3- 5.194e-05 4.753e-05 -4.284 -4.323 -0.039 - [13C]O2 1.091e-05 1.093e-05 -4.962 -4.962 0.001 - CaH[13C]O3+ 1.097e-06 1.007e-06 -5.960 -5.997 -0.037 - H[13C]O2[18O]- 1.036e-07 9.483e-08 -6.984 -7.023 -0.039 - H[13C]O[18O]O- 1.036e-07 9.483e-08 -6.984 -7.023 -0.039 - H[13C][18O]O2- 1.036e-07 9.483e-08 -6.984 -7.023 -0.039 - Ca[13C]O3 6.023e-08 6.033e-08 -7.220 -7.219 0.001 - [13C]O[18O] 4.536e-08 4.543e-08 -7.343 -7.343 0.001 - [13C]O3-2 3.087e-08 2.164e-08 -7.510 -7.665 -0.154 - CaH[13C]O2[18O]+ 2.189e-09 2.009e-09 -8.660 -8.697 -0.037 - CaH[13C]O[18O]O+ 2.189e-09 2.009e-09 -8.660 -8.697 -0.037 - CaH[13C][18O]O2+ 2.189e-09 2.009e-09 -8.660 -8.697 -0.037 - Ca[13C]O2[18O] 3.605e-10 3.611e-10 -9.443 -9.442 0.001 - H[13C]O[18O]2- 2.068e-10 1.892e-10 -9.685 -9.723 -0.039 - H[13C][18O]2O- 2.068e-10 1.892e-10 -9.685 -9.723 -0.039 - H[13C][18O]O[18O]- 2.068e-10 1.892e-10 -9.685 -9.723 -0.039 - [13C]O2[18O]-2 1.848e-10 1.295e-10 -9.733 -9.888 -0.154 -[14C](-4) 9.130e-33 - [14C]H4 9.130e-33 9.145e-33 -32.040 -32.039 0.001 -[14C](4) 4.023e-15 - H[14C]O3- 3.249e-15 2.973e-15 -14.488 -14.527 -0.039 - [14C]O2 6.764e-16 6.775e-16 -15.170 -15.169 0.001 - CaH[14C]O3+ 6.863e-17 6.297e-17 -16.163 -16.201 -0.037 - H[14C]O2[18O]- 6.483e-18 5.931e-18 -17.188 -17.227 -0.039 - H[14C]O[18O]O- 6.483e-18 5.931e-18 -17.188 -17.227 -0.039 - H[14C][18O]O2- 6.483e-18 5.931e-18 -17.188 -17.227 -0.039 - Ca[14C]O3 3.762e-18 3.768e-18 -17.425 -17.424 0.001 - [14C]O[18O] 2.813e-18 2.817e-18 -17.551 -17.550 0.001 - [14C]O3-2 1.928e-18 1.351e-18 -17.715 -17.869 -0.154 - CaH[14C]O2[18O]+ 1.369e-19 1.256e-19 -18.863 -18.901 -0.037 - CaH[14C]O[18O]O+ 1.369e-19 1.256e-19 -18.863 -18.901 -0.037 - CaH[14C][18O]O2+ 1.369e-19 1.256e-19 -18.863 -18.901 -0.037 - Ca[14C]O2[18O] 2.252e-20 2.255e-20 -19.648 -19.647 0.001 - H[14C]O[18O]2- 1.293e-20 1.183e-20 -19.888 -19.927 -0.039 - H[14C][18O]2O- 1.293e-20 1.183e-20 -19.888 -19.927 -0.039 - H[14C][18O]O[18O]- 1.293e-20 1.183e-20 -19.888 -19.927 -0.039 - [14C]O2[18O]-2 1.154e-20 8.089e-21 -19.938 -20.092 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.851 -67.850 0.001 - [18O]2 0.000e+00 0.000e+00 -70.852 -70.851 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.345e-20 + CH4 1.345e-20 1.347e-20 -19.871 -19.871 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.304e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.979e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.936e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.936e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.097e-06 1.007e-06 -5.960 -5.997 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.023e-08 6.033e-08 -7.220 -7.219 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 6.837e-14 + H2 3.419e-14 3.424e-14 -13.466 -13.465 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.452 -65.451 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.851 -67.850 0.001 (0) +[13C](-4) 1.472e-22 + [13C]H4 1.472e-22 1.475e-22 -21.832 -21.831 0.001 (0) +[13C](4) 6.440e-05 + H[13C]O3- 5.194e-05 4.753e-05 -4.284 -4.323 -0.039 (0) + [13C]O2 1.091e-05 1.093e-05 -4.962 -4.962 0.001 (0) + CaH[13C]O3+ 1.097e-06 1.007e-06 -5.960 -5.997 -0.037 (0) + H[13C]O2[18O]- 1.036e-07 9.483e-08 -6.984 -7.023 -0.039 (0) + H[13C]O[18O]O- 1.036e-07 9.483e-08 -6.984 -7.023 -0.039 (0) + H[13C][18O]O2- 1.036e-07 9.483e-08 -6.984 -7.023 -0.039 (0) + Ca[13C]O3 6.023e-08 6.033e-08 -7.220 -7.219 0.001 (0) + [13C]O[18O] 4.536e-08 4.543e-08 -7.343 -7.343 0.001 (0) + [13C]O3-2 3.087e-08 2.164e-08 -7.510 -7.665 -0.154 (0) + CaH[13C]O2[18O]+ 2.189e-09 2.009e-09 -8.660 -8.697 -0.037 (0) + CaH[13C]O[18O]O+ 2.189e-09 2.009e-09 -8.660 -8.697 -0.037 (0) + CaH[13C][18O]O2+ 2.189e-09 2.009e-09 -8.660 -8.697 -0.037 (0) + Ca[13C]O2[18O] 3.605e-10 3.611e-10 -9.443 -9.442 0.001 (0) + H[13C]O[18O]2- 2.068e-10 1.892e-10 -9.685 -9.723 -0.039 (0) + H[13C][18O]2O- 2.068e-10 1.892e-10 -9.685 -9.723 -0.039 (0) + H[13C][18O]O[18O]- 2.068e-10 1.892e-10 -9.685 -9.723 -0.039 (0) + [13C]O2[18O]-2 1.848e-10 1.295e-10 -9.733 -9.888 -0.154 (0) +[14C](-4) 9.130e-33 + [14C]H4 9.130e-33 9.145e-33 -32.040 -32.039 0.001 (0) +[14C](4) 4.023e-15 + H[14C]O3- 3.249e-15 2.973e-15 -14.488 -14.527 -0.039 (0) + [14C]O2 6.764e-16 6.775e-16 -15.170 -15.169 0.001 (0) + CaH[14C]O3+ 6.863e-17 6.297e-17 -16.163 -16.201 -0.037 (0) + H[14C]O2[18O]- 6.483e-18 5.931e-18 -17.188 -17.227 -0.039 (0) + H[14C]O[18O]O- 6.483e-18 5.931e-18 -17.188 -17.227 -0.039 (0) + H[14C][18O]O2- 6.483e-18 5.931e-18 -17.188 -17.227 -0.039 (0) + Ca[14C]O3 3.762e-18 3.768e-18 -17.425 -17.424 0.001 (0) + [14C]O[18O] 2.813e-18 2.817e-18 -17.551 -17.550 0.001 (0) + [14C]O3-2 1.928e-18 1.351e-18 -17.715 -17.869 -0.154 (0) + CaH[14C]O2[18O]+ 1.369e-19 1.256e-19 -18.863 -18.901 -0.037 (0) + CaH[14C]O[18O]O+ 1.369e-19 1.256e-19 -18.863 -18.901 -0.037 (0) + CaH[14C][18O]O2+ 1.369e-19 1.256e-19 -18.863 -18.901 -0.037 (0) + Ca[14C]O2[18O] 2.252e-20 2.255e-20 -19.648 -19.647 0.001 (0) + H[14C]O[18O]2- 1.293e-20 1.183e-20 -19.888 -19.927 -0.039 (0) + H[14C][18O]2O- 1.293e-20 1.183e-20 -19.888 -19.927 -0.039 (0) + H[14C][18O]O[18O]- 1.293e-20 1.183e-20 -19.888 -19.927 -0.039 (0) + [14C]O2[18O]-2 1.154e-20 8.089e-21 -19.938 -20.092 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.851 -67.850 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.852 -70.851 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -29055,99 +29055,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.079e-20 - CH4 1.079e-20 1.081e-20 -19.967 -19.966 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.304e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.979e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.098e-06 1.008e-06 -5.959 -5.997 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.028e-08 6.038e-08 -7.220 -7.219 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 6.472e-14 - H2 3.236e-14 3.241e-14 -13.490 -13.489 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.404 -65.403 0.001 - O[18O] 0.000e+00 0.000e+00 -67.803 -67.802 0.001 -[13C](-4) 1.183e-22 - [13C]H4 1.183e-22 1.185e-22 -21.927 -21.926 0.001 -[13C](4) 6.447e-05 - H[13C]O3- 5.199e-05 4.757e-05 -4.284 -4.323 -0.039 - [13C]O2 1.092e-05 1.094e-05 -4.962 -4.961 0.001 - CaH[13C]O3+ 1.098e-06 1.008e-06 -5.959 -5.997 -0.037 - H[13C]O2[18O]- 1.037e-07 9.492e-08 -6.984 -7.023 -0.039 - H[13C]O[18O]O- 1.037e-07 9.492e-08 -6.984 -7.023 -0.039 - H[13C][18O]O2- 1.037e-07 9.492e-08 -6.984 -7.023 -0.039 - Ca[13C]O3 6.028e-08 6.038e-08 -7.220 -7.219 0.001 - [13C]O[18O] 4.540e-08 4.547e-08 -7.343 -7.342 0.001 - [13C]O3-2 3.090e-08 2.166e-08 -7.510 -7.664 -0.154 - CaH[13C]O2[18O]+ 2.191e-09 2.010e-09 -8.659 -8.697 -0.037 - CaH[13C]O[18O]O+ 2.191e-09 2.010e-09 -8.659 -8.697 -0.037 - CaH[13C][18O]O2+ 2.191e-09 2.010e-09 -8.659 -8.697 -0.037 - Ca[13C]O2[18O] 3.608e-10 3.614e-10 -9.443 -9.442 0.001 - H[13C]O[18O]2- 2.070e-10 1.894e-10 -9.684 -9.723 -0.039 - H[13C][18O]2O- 2.070e-10 1.894e-10 -9.684 -9.723 -0.039 - H[13C][18O]O[18O]- 2.070e-10 1.894e-10 -9.684 -9.723 -0.039 - [13C]O2[18O]-2 1.849e-10 1.296e-10 -9.733 -9.887 -0.154 -[14C](-4) 6.756e-33 - [14C]H4 6.756e-33 6.768e-33 -32.170 -32.170 0.001 -[14C](4) 3.708e-15 - H[14C]O3- 2.995e-15 2.741e-15 -14.524 -14.562 -0.039 - [14C]O2 6.236e-16 6.246e-16 -15.205 -15.204 0.001 - CaH[14C]O3+ 6.328e-17 5.805e-17 -16.199 -16.236 -0.037 - H[14C]O2[18O]- 5.976e-18 5.468e-18 -17.224 -17.262 -0.039 - H[14C]O[18O]O- 5.976e-18 5.468e-18 -17.224 -17.262 -0.039 - H[14C][18O]O2- 5.976e-18 5.468e-18 -17.224 -17.262 -0.039 - Ca[14C]O3 3.468e-18 3.474e-18 -17.460 -17.459 0.001 - [14C]O[18O] 2.593e-18 2.597e-18 -17.586 -17.585 0.001 - [14C]O3-2 1.777e-18 1.246e-18 -17.750 -17.905 -0.154 - CaH[14C]O2[18O]+ 1.262e-19 1.158e-19 -18.899 -18.936 -0.037 - CaH[14C]O[18O]O+ 1.262e-19 1.158e-19 -18.899 -18.936 -0.037 - CaH[14C][18O]O2+ 1.262e-19 1.158e-19 -18.899 -18.936 -0.037 - Ca[14C]O2[18O] 2.076e-20 2.079e-20 -19.683 -19.682 0.001 - H[14C]O[18O]2- 1.192e-20 1.091e-20 -19.924 -19.962 -0.039 - H[14C][18O]2O- 1.192e-20 1.091e-20 -19.924 -19.962 -0.039 - H[14C][18O]O[18O]- 1.192e-20 1.091e-20 -19.924 -19.962 -0.039 - [14C]O2[18O]-2 1.064e-20 7.457e-21 -19.973 -20.127 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.803 -67.802 0.001 - [18O]2 0.000e+00 0.000e+00 -70.804 -70.803 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.079e-20 + CH4 1.079e-20 1.081e-20 -19.967 -19.966 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.304e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.979e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.098e-06 1.008e-06 -5.959 -5.997 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.028e-08 6.038e-08 -7.220 -7.219 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 6.472e-14 + H2 3.236e-14 3.241e-14 -13.490 -13.489 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.404 -65.403 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.803 -67.802 0.001 (0) +[13C](-4) 1.183e-22 + [13C]H4 1.183e-22 1.185e-22 -21.927 -21.926 0.001 (0) +[13C](4) 6.447e-05 + H[13C]O3- 5.199e-05 4.757e-05 -4.284 -4.323 -0.039 (0) + [13C]O2 1.092e-05 1.094e-05 -4.962 -4.961 0.001 (0) + CaH[13C]O3+ 1.098e-06 1.008e-06 -5.959 -5.997 -0.037 (0) + H[13C]O2[18O]- 1.037e-07 9.492e-08 -6.984 -7.023 -0.039 (0) + H[13C]O[18O]O- 1.037e-07 9.492e-08 -6.984 -7.023 -0.039 (0) + H[13C][18O]O2- 1.037e-07 9.492e-08 -6.984 -7.023 -0.039 (0) + Ca[13C]O3 6.028e-08 6.038e-08 -7.220 -7.219 0.001 (0) + [13C]O[18O] 4.540e-08 4.547e-08 -7.343 -7.342 0.001 (0) + [13C]O3-2 3.090e-08 2.166e-08 -7.510 -7.664 -0.154 (0) + CaH[13C]O2[18O]+ 2.191e-09 2.010e-09 -8.659 -8.697 -0.037 (0) + CaH[13C]O[18O]O+ 2.191e-09 2.010e-09 -8.659 -8.697 -0.037 (0) + CaH[13C][18O]O2+ 2.191e-09 2.010e-09 -8.659 -8.697 -0.037 (0) + Ca[13C]O2[18O] 3.608e-10 3.614e-10 -9.443 -9.442 0.001 (0) + H[13C]O[18O]2- 2.070e-10 1.894e-10 -9.684 -9.723 -0.039 (0) + H[13C][18O]2O- 2.070e-10 1.894e-10 -9.684 -9.723 -0.039 (0) + H[13C][18O]O[18O]- 2.070e-10 1.894e-10 -9.684 -9.723 -0.039 (0) + [13C]O2[18O]-2 1.849e-10 1.296e-10 -9.733 -9.887 -0.154 (0) +[14C](-4) 6.756e-33 + [14C]H4 6.756e-33 6.768e-33 -32.170 -32.170 0.001 (0) +[14C](4) 3.708e-15 + H[14C]O3- 2.995e-15 2.741e-15 -14.524 -14.562 -0.039 (0) + [14C]O2 6.236e-16 6.246e-16 -15.205 -15.204 0.001 (0) + CaH[14C]O3+ 6.328e-17 5.805e-17 -16.199 -16.236 -0.037 (0) + H[14C]O2[18O]- 5.976e-18 5.468e-18 -17.224 -17.262 -0.039 (0) + H[14C]O[18O]O- 5.976e-18 5.468e-18 -17.224 -17.262 -0.039 (0) + H[14C][18O]O2- 5.976e-18 5.468e-18 -17.224 -17.262 -0.039 (0) + Ca[14C]O3 3.468e-18 3.474e-18 -17.460 -17.459 0.001 (0) + [14C]O[18O] 2.593e-18 2.597e-18 -17.586 -17.585 0.001 (0) + [14C]O3-2 1.777e-18 1.246e-18 -17.750 -17.905 -0.154 (0) + CaH[14C]O2[18O]+ 1.262e-19 1.158e-19 -18.899 -18.936 -0.037 (0) + CaH[14C]O[18O]O+ 1.262e-19 1.158e-19 -18.899 -18.936 -0.037 (0) + CaH[14C][18O]O2+ 1.262e-19 1.158e-19 -18.899 -18.936 -0.037 (0) + Ca[14C]O2[18O] 2.076e-20 2.079e-20 -19.683 -19.682 0.001 (0) + H[14C]O[18O]2- 1.192e-20 1.091e-20 -19.924 -19.962 -0.039 (0) + H[14C][18O]2O- 1.192e-20 1.091e-20 -19.924 -19.962 -0.039 (0) + H[14C][18O]O[18O]- 1.192e-20 1.091e-20 -19.924 -19.962 -0.039 (0) + [14C]O2[18O]-2 1.064e-20 7.457e-21 -19.973 -20.127 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.803 -67.802 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.804 -70.803 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -29312,99 +29312,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.278e-20 - CH4 1.278e-20 1.281e-20 -19.893 -19.893 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.979e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.099e-06 1.008e-06 -5.959 -5.996 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.033e-08 6.043e-08 -7.219 -7.219 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 6.751e-14 - H2 3.376e-14 3.381e-14 -13.472 -13.471 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.441 -65.440 0.001 - O[18O] 0.000e+00 0.000e+00 -67.840 -67.839 0.001 -[13C](-4) 1.402e-22 - [13C]H4 1.402e-22 1.405e-22 -21.853 -21.852 0.001 -[13C](4) 6.452e-05 - H[13C]O3- 5.204e-05 4.761e-05 -4.284 -4.322 -0.039 - [13C]O2 1.093e-05 1.094e-05 -4.962 -4.961 0.001 - CaH[13C]O3+ 1.099e-06 1.008e-06 -5.959 -5.996 -0.037 - H[13C]O2[18O]- 1.038e-07 9.500e-08 -6.984 -7.022 -0.039 - H[13C]O[18O]O- 1.038e-07 9.500e-08 -6.984 -7.022 -0.039 - H[13C][18O]O2- 1.038e-07 9.500e-08 -6.984 -7.022 -0.039 - Ca[13C]O3 6.033e-08 6.043e-08 -7.219 -7.219 0.001 - [13C]O[18O] 4.544e-08 4.551e-08 -7.343 -7.342 0.001 - [13C]O3-2 3.092e-08 2.167e-08 -7.510 -7.664 -0.154 - CaH[13C]O2[18O]+ 2.193e-09 2.012e-09 -8.659 -8.696 -0.037 - CaH[13C]O[18O]O+ 2.193e-09 2.012e-09 -8.659 -8.696 -0.037 - CaH[13C][18O]O2+ 2.193e-09 2.012e-09 -8.659 -8.696 -0.037 - Ca[13C]O2[18O] 3.611e-10 3.617e-10 -9.442 -9.442 0.001 - H[13C]O[18O]2- 2.071e-10 1.895e-10 -9.684 -9.722 -0.039 - H[13C][18O]2O- 2.071e-10 1.895e-10 -9.684 -9.722 -0.039 - H[13C][18O]O[18O]- 2.071e-10 1.895e-10 -9.684 -9.722 -0.039 - [13C]O2[18O]-2 1.851e-10 1.297e-10 -9.733 -9.887 -0.154 -[14C](-4) 7.423e-33 - [14C]H4 7.423e-33 7.435e-33 -32.129 -32.129 0.001 -[14C](4) 3.440e-15 - H[14C]O3- 2.778e-15 2.542e-15 -14.556 -14.595 -0.039 - [14C]O2 5.784e-16 5.794e-16 -15.238 -15.237 0.001 - CaH[14C]O3+ 5.869e-17 5.385e-17 -16.231 -16.269 -0.037 - H[14C]O2[18O]- 5.543e-18 5.072e-18 -17.256 -17.295 -0.039 - H[14C]O[18O]O- 5.543e-18 5.072e-18 -17.256 -17.295 -0.039 - H[14C][18O]O2- 5.543e-18 5.072e-18 -17.256 -17.295 -0.039 - Ca[14C]O3 3.217e-18 3.222e-18 -17.493 -17.492 0.001 - [14C]O[18O] 2.405e-18 2.409e-18 -17.619 -17.618 0.001 - [14C]O3-2 1.649e-18 1.156e-18 -17.783 -17.937 -0.154 - CaH[14C]O2[18O]+ 1.171e-19 1.074e-19 -18.931 -18.969 -0.037 - CaH[14C]O[18O]O+ 1.171e-19 1.074e-19 -18.931 -18.969 -0.037 - CaH[14C][18O]O2+ 1.171e-19 1.074e-19 -18.931 -18.969 -0.037 - Ca[14C]O2[18O] 1.925e-20 1.929e-20 -19.715 -19.715 0.001 - H[14C]O[18O]2- 1.106e-20 1.012e-20 -19.956 -19.995 -0.039 - H[14C][18O]2O- 1.106e-20 1.012e-20 -19.956 -19.995 -0.039 - H[14C][18O]O[18O]- 1.106e-20 1.012e-20 -19.956 -19.995 -0.039 - [14C]O2[18O]-2 9.869e-21 6.917e-21 -20.006 -20.160 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.840 -67.839 0.001 - [18O]2 0.000e+00 0.000e+00 -70.841 -70.840 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.278e-20 + CH4 1.278e-20 1.281e-20 -19.893 -19.893 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.979e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.099e-06 1.008e-06 -5.959 -5.996 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.033e-08 6.043e-08 -7.219 -7.219 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 6.751e-14 + H2 3.376e-14 3.381e-14 -13.472 -13.471 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.441 -65.440 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.840 -67.839 0.001 (0) +[13C](-4) 1.402e-22 + [13C]H4 1.402e-22 1.405e-22 -21.853 -21.852 0.001 (0) +[13C](4) 6.452e-05 + H[13C]O3- 5.204e-05 4.761e-05 -4.284 -4.322 -0.039 (0) + [13C]O2 1.093e-05 1.094e-05 -4.962 -4.961 0.001 (0) + CaH[13C]O3+ 1.099e-06 1.008e-06 -5.959 -5.996 -0.037 (0) + H[13C]O2[18O]- 1.038e-07 9.500e-08 -6.984 -7.022 -0.039 (0) + H[13C]O[18O]O- 1.038e-07 9.500e-08 -6.984 -7.022 -0.039 (0) + H[13C][18O]O2- 1.038e-07 9.500e-08 -6.984 -7.022 -0.039 (0) + Ca[13C]O3 6.033e-08 6.043e-08 -7.219 -7.219 0.001 (0) + [13C]O[18O] 4.544e-08 4.551e-08 -7.343 -7.342 0.001 (0) + [13C]O3-2 3.092e-08 2.167e-08 -7.510 -7.664 -0.154 (0) + CaH[13C]O2[18O]+ 2.193e-09 2.012e-09 -8.659 -8.696 -0.037 (0) + CaH[13C]O[18O]O+ 2.193e-09 2.012e-09 -8.659 -8.696 -0.037 (0) + CaH[13C][18O]O2+ 2.193e-09 2.012e-09 -8.659 -8.696 -0.037 (0) + Ca[13C]O2[18O] 3.611e-10 3.617e-10 -9.442 -9.442 0.001 (0) + H[13C]O[18O]2- 2.071e-10 1.895e-10 -9.684 -9.722 -0.039 (0) + H[13C][18O]2O- 2.071e-10 1.895e-10 -9.684 -9.722 -0.039 (0) + H[13C][18O]O[18O]- 2.071e-10 1.895e-10 -9.684 -9.722 -0.039 (0) + [13C]O2[18O]-2 1.851e-10 1.297e-10 -9.733 -9.887 -0.154 (0) +[14C](-4) 7.423e-33 + [14C]H4 7.423e-33 7.435e-33 -32.129 -32.129 0.001 (0) +[14C](4) 3.440e-15 + H[14C]O3- 2.778e-15 2.542e-15 -14.556 -14.595 -0.039 (0) + [14C]O2 5.784e-16 5.794e-16 -15.238 -15.237 0.001 (0) + CaH[14C]O3+ 5.869e-17 5.385e-17 -16.231 -16.269 -0.037 (0) + H[14C]O2[18O]- 5.543e-18 5.072e-18 -17.256 -17.295 -0.039 (0) + H[14C]O[18O]O- 5.543e-18 5.072e-18 -17.256 -17.295 -0.039 (0) + H[14C][18O]O2- 5.543e-18 5.072e-18 -17.256 -17.295 -0.039 (0) + Ca[14C]O3 3.217e-18 3.222e-18 -17.493 -17.492 0.001 (0) + [14C]O[18O] 2.405e-18 2.409e-18 -17.619 -17.618 0.001 (0) + [14C]O3-2 1.649e-18 1.156e-18 -17.783 -17.937 -0.154 (0) + CaH[14C]O2[18O]+ 1.171e-19 1.074e-19 -18.931 -18.969 -0.037 (0) + CaH[14C]O[18O]O+ 1.171e-19 1.074e-19 -18.931 -18.969 -0.037 (0) + CaH[14C][18O]O2+ 1.171e-19 1.074e-19 -18.931 -18.969 -0.037 (0) + Ca[14C]O2[18O] 1.925e-20 1.929e-20 -19.715 -19.715 0.001 (0) + H[14C]O[18O]2- 1.106e-20 1.012e-20 -19.956 -19.995 -0.039 (0) + H[14C][18O]2O- 1.106e-20 1.012e-20 -19.956 -19.995 -0.039 (0) + H[14C][18O]O[18O]- 1.106e-20 1.012e-20 -19.956 -19.995 -0.039 (0) + [14C]O2[18O]-2 9.869e-21 6.917e-21 -20.006 -20.160 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.840 -67.839 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.841 -70.840 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -29569,99 +29569,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 1.062e-21 - CH4 1.062e-21 1.063e-21 -20.974 -20.973 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.979e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.100e-06 1.009e-06 -5.959 -5.996 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.038e-08 6.048e-08 -7.219 -7.218 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 3.624e-14 - H2 1.812e-14 1.815e-14 -13.742 -13.741 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -64.900 -64.900 0.001 - O[18O] 0.000e+00 0.000e+00 -67.299 -67.299 0.001 -[13C](-4) 1.165e-23 - [13C]H4 1.165e-23 1.167e-23 -22.934 -22.933 0.001 -[13C](4) 6.456e-05 - H[13C]O3- 5.207e-05 4.765e-05 -4.283 -4.322 -0.039 - [13C]O2 1.093e-05 1.095e-05 -4.961 -4.960 0.001 - CaH[13C]O3+ 1.100e-06 1.009e-06 -5.959 -5.996 -0.037 - H[13C]O2[18O]- 1.039e-07 9.506e-08 -6.983 -7.022 -0.039 - H[13C]O[18O]O- 1.039e-07 9.506e-08 -6.983 -7.022 -0.039 - H[13C][18O]O2- 1.039e-07 9.506e-08 -6.983 -7.022 -0.039 - Ca[13C]O3 6.038e-08 6.048e-08 -7.219 -7.218 0.001 - [13C]O[18O] 4.547e-08 4.554e-08 -7.342 -7.342 0.001 - [13C]O3-2 3.095e-08 2.169e-08 -7.509 -7.664 -0.154 - CaH[13C]O2[18O]+ 2.195e-09 2.014e-09 -8.659 -8.696 -0.037 - CaH[13C]O[18O]O+ 2.195e-09 2.014e-09 -8.659 -8.696 -0.037 - CaH[13C][18O]O2+ 2.195e-09 2.014e-09 -8.659 -8.696 -0.037 - Ca[13C]O2[18O] 3.614e-10 3.620e-10 -9.442 -9.441 0.001 - H[13C]O[18O]2- 2.073e-10 1.897e-10 -9.683 -9.722 -0.039 - H[13C][18O]2O- 2.073e-10 1.897e-10 -9.683 -9.722 -0.039 - H[13C][18O]O[18O]- 2.073e-10 1.897e-10 -9.683 -9.722 -0.039 - [13C]O2[18O]-2 1.852e-10 1.298e-10 -9.732 -9.887 -0.154 -[14C](-4) 5.747e-34 - [14C]H4 5.747e-34 5.756e-34 -33.241 -33.240 0.001 -[14C](4) 3.208e-15 - H[14C]O3- 2.591e-15 2.371e-15 -14.587 -14.625 -0.039 - [14C]O2 5.393e-16 5.402e-16 -15.268 -15.267 0.001 - CaH[14C]O3+ 5.473e-17 5.021e-17 -16.262 -16.299 -0.037 - H[14C]O2[18O]- 5.169e-18 4.730e-18 -17.287 -17.325 -0.039 - H[14C]O[18O]O- 5.169e-18 4.730e-18 -17.287 -17.325 -0.039 - H[14C][18O]O2- 5.169e-18 4.730e-18 -17.287 -17.325 -0.039 - Ca[14C]O3 3.000e-18 3.005e-18 -17.523 -17.522 0.001 - [14C]O[18O] 2.243e-18 2.246e-18 -17.649 -17.649 0.001 - [14C]O3-2 1.537e-18 1.078e-18 -17.813 -17.968 -0.154 - CaH[14C]O2[18O]+ 1.092e-19 1.002e-19 -18.962 -18.999 -0.037 - CaH[14C]O[18O]O+ 1.092e-19 1.002e-19 -18.962 -18.999 -0.037 - CaH[14C][18O]O2+ 1.092e-19 1.002e-19 -18.962 -18.999 -0.037 - Ca[14C]O2[18O] 1.795e-20 1.798e-20 -19.746 -19.745 0.001 - H[14C]O[18O]2- 1.031e-20 9.437e-21 -19.987 -20.025 -0.039 - H[14C][18O]2O- 1.031e-20 9.437e-21 -19.987 -20.025 -0.039 - H[14C][18O]O[18O]- 1.031e-20 9.437e-21 -19.987 -20.025 -0.039 - [14C]O2[18O]-2 9.202e-21 6.450e-21 -20.036 -20.190 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.299 -67.299 0.001 - [18O]2 0.000e+00 0.000e+00 -70.300 -70.300 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 1.062e-21 + CH4 1.062e-21 1.063e-21 -20.974 -20.973 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.979e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.100e-06 1.009e-06 -5.959 -5.996 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.038e-08 6.048e-08 -7.219 -7.218 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 3.624e-14 + H2 1.812e-14 1.815e-14 -13.742 -13.741 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -64.900 -64.900 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.299 -67.299 0.001 (0) +[13C](-4) 1.165e-23 + [13C]H4 1.165e-23 1.167e-23 -22.934 -22.933 0.001 (0) +[13C](4) 6.456e-05 + H[13C]O3- 5.207e-05 4.765e-05 -4.283 -4.322 -0.039 (0) + [13C]O2 1.093e-05 1.095e-05 -4.961 -4.960 0.001 (0) + CaH[13C]O3+ 1.100e-06 1.009e-06 -5.959 -5.996 -0.037 (0) + H[13C]O2[18O]- 1.039e-07 9.506e-08 -6.983 -7.022 -0.039 (0) + H[13C]O[18O]O- 1.039e-07 9.506e-08 -6.983 -7.022 -0.039 (0) + H[13C][18O]O2- 1.039e-07 9.506e-08 -6.983 -7.022 -0.039 (0) + Ca[13C]O3 6.038e-08 6.048e-08 -7.219 -7.218 0.001 (0) + [13C]O[18O] 4.547e-08 4.554e-08 -7.342 -7.342 0.001 (0) + [13C]O3-2 3.095e-08 2.169e-08 -7.509 -7.664 -0.154 (0) + CaH[13C]O2[18O]+ 2.195e-09 2.014e-09 -8.659 -8.696 -0.037 (0) + CaH[13C]O[18O]O+ 2.195e-09 2.014e-09 -8.659 -8.696 -0.037 (0) + CaH[13C][18O]O2+ 2.195e-09 2.014e-09 -8.659 -8.696 -0.037 (0) + Ca[13C]O2[18O] 3.614e-10 3.620e-10 -9.442 -9.441 0.001 (0) + H[13C]O[18O]2- 2.073e-10 1.897e-10 -9.683 -9.722 -0.039 (0) + H[13C][18O]2O- 2.073e-10 1.897e-10 -9.683 -9.722 -0.039 (0) + H[13C][18O]O[18O]- 2.073e-10 1.897e-10 -9.683 -9.722 -0.039 (0) + [13C]O2[18O]-2 1.852e-10 1.298e-10 -9.732 -9.887 -0.154 (0) +[14C](-4) 5.747e-34 + [14C]H4 5.747e-34 5.756e-34 -33.241 -33.240 0.001 (0) +[14C](4) 3.208e-15 + H[14C]O3- 2.591e-15 2.371e-15 -14.587 -14.625 -0.039 (0) + [14C]O2 5.393e-16 5.402e-16 -15.268 -15.267 0.001 (0) + CaH[14C]O3+ 5.473e-17 5.021e-17 -16.262 -16.299 -0.037 (0) + H[14C]O2[18O]- 5.169e-18 4.730e-18 -17.287 -17.325 -0.039 (0) + H[14C]O[18O]O- 5.169e-18 4.730e-18 -17.287 -17.325 -0.039 (0) + H[14C][18O]O2- 5.169e-18 4.730e-18 -17.287 -17.325 -0.039 (0) + Ca[14C]O3 3.000e-18 3.005e-18 -17.523 -17.522 0.001 (0) + [14C]O[18O] 2.243e-18 2.246e-18 -17.649 -17.649 0.001 (0) + [14C]O3-2 1.537e-18 1.078e-18 -17.813 -17.968 -0.154 (0) + CaH[14C]O2[18O]+ 1.092e-19 1.002e-19 -18.962 -18.999 -0.037 (0) + CaH[14C]O[18O]O+ 1.092e-19 1.002e-19 -18.962 -18.999 -0.037 (0) + CaH[14C][18O]O2+ 1.092e-19 1.002e-19 -18.962 -18.999 -0.037 (0) + Ca[14C]O2[18O] 1.795e-20 1.798e-20 -19.746 -19.745 0.001 (0) + H[14C]O[18O]2- 1.031e-20 9.437e-21 -19.987 -20.025 -0.039 (0) + H[14C][18O]2O- 1.031e-20 9.437e-21 -19.987 -20.025 -0.039 (0) + H[14C][18O]O[18O]- 1.031e-20 9.437e-21 -19.987 -20.025 -0.039 (0) + [14C]O2[18O]-2 9.202e-21 6.450e-21 -20.036 -20.190 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.299 -67.299 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.300 -70.300 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -29826,99 +29826,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 6.047e-22 - CH4 6.047e-22 6.057e-22 -21.218 -21.218 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.101e-06 1.010e-06 -5.958 -5.996 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.041e-08 6.051e-08 -7.219 -7.218 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 3.148e-14 - H2 1.574e-14 1.577e-14 -13.803 -13.802 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -64.778 -64.777 0.001 - O[18O] 0.000e+00 0.000e+00 -67.177 -67.176 0.001 -[13C](-4) 6.641e-24 - [13C]H4 6.641e-24 6.652e-24 -23.178 -23.177 0.001 -[13C](4) 6.460e-05 - H[13C]O3- 5.211e-05 4.768e-05 -4.283 -4.322 -0.039 - [13C]O2 1.094e-05 1.096e-05 -4.961 -4.960 0.001 - CaH[13C]O3+ 1.101e-06 1.010e-06 -5.958 -5.996 -0.037 - H[13C]O2[18O]- 1.040e-07 9.512e-08 -6.983 -7.022 -0.039 - H[13C]O[18O]O- 1.040e-07 9.512e-08 -6.983 -7.022 -0.039 - H[13C][18O]O2- 1.040e-07 9.512e-08 -6.983 -7.022 -0.039 - Ca[13C]O3 6.041e-08 6.051e-08 -7.219 -7.218 0.001 - [13C]O[18O] 4.550e-08 4.557e-08 -7.342 -7.341 0.001 - [13C]O3-2 3.096e-08 2.170e-08 -7.509 -7.663 -0.154 - CaH[13C]O2[18O]+ 2.196e-09 2.015e-09 -8.658 -8.696 -0.037 - CaH[13C]O[18O]O+ 2.196e-09 2.015e-09 -8.658 -8.696 -0.037 - CaH[13C][18O]O2+ 2.196e-09 2.015e-09 -8.658 -8.696 -0.037 - Ca[13C]O2[18O] 3.616e-10 3.622e-10 -9.442 -9.441 0.001 - H[13C]O[18O]2- 2.074e-10 1.898e-10 -9.683 -9.722 -0.039 - H[13C][18O]2O- 2.074e-10 1.898e-10 -9.683 -9.722 -0.039 - H[13C][18O]O[18O]- 2.074e-10 1.898e-10 -9.683 -9.722 -0.039 - [13C]O2[18O]-2 1.853e-10 1.299e-10 -9.732 -9.886 -0.154 -[14C](-4) 3.067e-34 - [14C]H4 3.067e-34 3.072e-34 -33.513 -33.513 0.001 -[14C](4) 3.005e-15 - H[14C]O3- 2.427e-15 2.221e-15 -14.615 -14.654 -0.039 - [14C]O2 5.052e-16 5.060e-16 -15.297 -15.296 0.001 - CaH[14C]O3+ 5.127e-17 4.703e-17 -16.290 -16.328 -0.037 - H[14C]O2[18O]- 4.842e-18 4.430e-18 -17.315 -17.354 -0.039 - H[14C]O[18O]O- 4.842e-18 4.430e-18 -17.315 -17.354 -0.039 - H[14C][18O]O2- 4.842e-18 4.430e-18 -17.315 -17.354 -0.039 - Ca[14C]O3 2.810e-18 2.814e-18 -17.551 -17.551 0.001 - [14C]O[18O] 2.101e-18 2.104e-18 -17.678 -17.677 0.001 - [14C]O3-2 1.440e-18 1.009e-18 -17.842 -17.996 -0.154 - CaH[14C]O2[18O]+ 1.023e-19 9.384e-20 -18.990 -19.028 -0.037 - CaH[14C]O[18O]O+ 1.023e-19 9.384e-20 -18.990 -19.028 -0.037 - CaH[14C][18O]O2+ 1.023e-19 9.384e-20 -18.990 -19.028 -0.037 - Ca[14C]O2[18O] 1.682e-20 1.685e-20 -19.774 -19.774 0.001 - H[14C]O[18O]2- 9.661e-21 8.840e-21 -20.015 -20.054 -0.039 - H[14C][18O]2O- 9.661e-21 8.840e-21 -20.015 -20.054 -0.039 - H[14C][18O]O[18O]- 9.661e-21 8.840e-21 -20.015 -20.054 -0.039 - [14C]O2[18O]-2 8.620e-21 6.042e-21 -20.064 -20.219 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.177 -67.176 0.001 - [18O]2 0.000e+00 0.000e+00 -70.178 -70.177 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 6.047e-22 + CH4 6.047e-22 6.057e-22 -21.218 -21.218 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.101e-06 1.010e-06 -5.958 -5.996 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.041e-08 6.051e-08 -7.219 -7.218 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 3.148e-14 + H2 1.574e-14 1.577e-14 -13.803 -13.802 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -64.778 -64.777 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.177 -67.176 0.001 (0) +[13C](-4) 6.641e-24 + [13C]H4 6.641e-24 6.652e-24 -23.178 -23.177 0.001 (0) +[13C](4) 6.460e-05 + H[13C]O3- 5.211e-05 4.768e-05 -4.283 -4.322 -0.039 (0) + [13C]O2 1.094e-05 1.096e-05 -4.961 -4.960 0.001 (0) + CaH[13C]O3+ 1.101e-06 1.010e-06 -5.958 -5.996 -0.037 (0) + H[13C]O2[18O]- 1.040e-07 9.512e-08 -6.983 -7.022 -0.039 (0) + H[13C]O[18O]O- 1.040e-07 9.512e-08 -6.983 -7.022 -0.039 (0) + H[13C][18O]O2- 1.040e-07 9.512e-08 -6.983 -7.022 -0.039 (0) + Ca[13C]O3 6.041e-08 6.051e-08 -7.219 -7.218 0.001 (0) + [13C]O[18O] 4.550e-08 4.557e-08 -7.342 -7.341 0.001 (0) + [13C]O3-2 3.096e-08 2.170e-08 -7.509 -7.663 -0.154 (0) + CaH[13C]O2[18O]+ 2.196e-09 2.015e-09 -8.658 -8.696 -0.037 (0) + CaH[13C]O[18O]O+ 2.196e-09 2.015e-09 -8.658 -8.696 -0.037 (0) + CaH[13C][18O]O2+ 2.196e-09 2.015e-09 -8.658 -8.696 -0.037 (0) + Ca[13C]O2[18O] 3.616e-10 3.622e-10 -9.442 -9.441 0.001 (0) + H[13C]O[18O]2- 2.074e-10 1.898e-10 -9.683 -9.722 -0.039 (0) + H[13C][18O]2O- 2.074e-10 1.898e-10 -9.683 -9.722 -0.039 (0) + H[13C][18O]O[18O]- 2.074e-10 1.898e-10 -9.683 -9.722 -0.039 (0) + [13C]O2[18O]-2 1.853e-10 1.299e-10 -9.732 -9.886 -0.154 (0) +[14C](-4) 3.067e-34 + [14C]H4 3.067e-34 3.072e-34 -33.513 -33.513 0.001 (0) +[14C](4) 3.005e-15 + H[14C]O3- 2.427e-15 2.221e-15 -14.615 -14.654 -0.039 (0) + [14C]O2 5.052e-16 5.060e-16 -15.297 -15.296 0.001 (0) + CaH[14C]O3+ 5.127e-17 4.703e-17 -16.290 -16.328 -0.037 (0) + H[14C]O2[18O]- 4.842e-18 4.430e-18 -17.315 -17.354 -0.039 (0) + H[14C]O[18O]O- 4.842e-18 4.430e-18 -17.315 -17.354 -0.039 (0) + H[14C][18O]O2- 4.842e-18 4.430e-18 -17.315 -17.354 -0.039 (0) + Ca[14C]O3 2.810e-18 2.814e-18 -17.551 -17.551 0.001 (0) + [14C]O[18O] 2.101e-18 2.104e-18 -17.678 -17.677 0.001 (0) + [14C]O3-2 1.440e-18 1.009e-18 -17.842 -17.996 -0.154 (0) + CaH[14C]O2[18O]+ 1.023e-19 9.384e-20 -18.990 -19.028 -0.037 (0) + CaH[14C]O[18O]O+ 1.023e-19 9.384e-20 -18.990 -19.028 -0.037 (0) + CaH[14C][18O]O2+ 1.023e-19 9.384e-20 -18.990 -19.028 -0.037 (0) + Ca[14C]O2[18O] 1.682e-20 1.685e-20 -19.774 -19.774 0.001 (0) + H[14C]O[18O]2- 9.661e-21 8.840e-21 -20.015 -20.054 -0.039 (0) + H[14C][18O]2O- 9.661e-21 8.840e-21 -20.015 -20.054 -0.039 (0) + H[14C][18O]O[18O]- 9.661e-21 8.840e-21 -20.015 -20.054 -0.039 (0) + [14C]O2[18O]-2 8.620e-21 6.042e-21 -20.064 -20.219 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.143e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.177 -67.176 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.178 -70.177 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -30083,99 +30083,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 9.674e-21 - CH4 9.674e-21 9.690e-21 -20.014 -20.014 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.101e-06 1.010e-06 -5.958 -5.996 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.045e-08 6.055e-08 -7.219 -7.218 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 6.297e-14 - H2 3.148e-14 3.154e-14 -13.502 -13.501 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.380 -65.379 0.001 - O[18O] 0.000e+00 0.000e+00 -67.779 -67.778 0.001 -[13C](-4) 1.063e-22 - [13C]H4 1.063e-22 1.065e-22 -21.973 -21.973 0.001 -[13C](4) 6.464e-05 - H[13C]O3- 5.213e-05 4.770e-05 -4.283 -4.321 -0.039 - [13C]O2 1.095e-05 1.097e-05 -4.961 -4.960 0.001 - CaH[13C]O3+ 1.101e-06 1.010e-06 -5.958 -5.996 -0.037 - H[13C]O2[18O]- 1.040e-07 9.517e-08 -6.983 -7.021 -0.039 - H[13C]O[18O]O- 1.040e-07 9.517e-08 -6.983 -7.021 -0.039 - H[13C][18O]O2- 1.040e-07 9.517e-08 -6.983 -7.021 -0.039 - Ca[13C]O3 6.045e-08 6.055e-08 -7.219 -7.218 0.001 - [13C]O[18O] 4.552e-08 4.560e-08 -7.342 -7.341 0.001 - [13C]O3-2 3.098e-08 2.172e-08 -7.509 -7.663 -0.154 - CaH[13C]O2[18O]+ 2.197e-09 2.016e-09 -8.658 -8.696 -0.037 - CaH[13C]O[18O]O+ 2.197e-09 2.016e-09 -8.658 -8.696 -0.037 - CaH[13C][18O]O2+ 2.197e-09 2.016e-09 -8.658 -8.696 -0.037 - Ca[13C]O2[18O] 3.618e-10 3.624e-10 -9.442 -9.441 0.001 - H[13C]O[18O]2- 2.075e-10 1.899e-10 -9.683 -9.722 -0.039 - H[13C][18O]2O- 2.075e-10 1.899e-10 -9.683 -9.722 -0.039 - H[13C][18O]O[18O]- 2.075e-10 1.899e-10 -9.683 -9.722 -0.039 - [13C]O2[18O]-2 1.854e-10 1.300e-10 -9.732 -9.886 -0.154 -[14C](-4) 4.614e-33 - [14C]H4 4.614e-33 4.622e-33 -32.336 -32.335 0.001 -[14C](4) 2.826e-15 - H[14C]O3- 2.282e-15 2.088e-15 -14.642 -14.680 -0.039 - [14C]O2 4.752e-16 4.759e-16 -15.323 -15.322 0.001 - CaH[14C]O3+ 4.822e-17 4.424e-17 -16.317 -16.354 -0.037 - H[14C]O2[18O]- 4.554e-18 4.167e-18 -17.342 -17.380 -0.039 - H[14C]O[18O]O- 4.554e-18 4.167e-18 -17.342 -17.380 -0.039 - H[14C][18O]O2- 4.554e-18 4.167e-18 -17.342 -17.380 -0.039 - Ca[14C]O3 2.643e-18 2.647e-18 -17.578 -17.577 0.001 - [14C]O[18O] 1.976e-18 1.979e-18 -17.704 -17.704 0.001 - [14C]O3-2 1.354e-18 9.494e-19 -17.868 -18.023 -0.154 - CaH[14C]O2[18O]+ 9.620e-20 8.826e-20 -19.017 -19.054 -0.037 - CaH[14C]O[18O]O+ 9.620e-20 8.826e-20 -19.017 -19.054 -0.037 - CaH[14C][18O]O2+ 9.620e-20 8.826e-20 -19.017 -19.054 -0.037 - Ca[14C]O2[18O] 1.582e-20 1.584e-20 -19.801 -19.800 0.001 - H[14C]O[18O]2- 9.086e-21 8.314e-21 -20.042 -20.080 -0.039 - H[14C][18O]2O- 9.086e-21 8.314e-21 -20.042 -20.080 -0.039 - H[14C][18O]O[18O]- 9.086e-21 8.314e-21 -20.042 -20.080 -0.039 - [14C]O2[18O]-2 8.107e-21 5.682e-21 -20.091 -20.245 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.779 -67.778 0.001 - [18O]2 0.000e+00 0.000e+00 -70.780 -70.779 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 9.674e-21 + CH4 9.674e-21 9.690e-21 -20.014 -20.014 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.101e-06 1.010e-06 -5.958 -5.996 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.045e-08 6.055e-08 -7.219 -7.218 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 6.297e-14 + H2 3.148e-14 3.154e-14 -13.502 -13.501 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.380 -65.379 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.779 -67.778 0.001 (0) +[13C](-4) 1.063e-22 + [13C]H4 1.063e-22 1.065e-22 -21.973 -21.973 0.001 (0) +[13C](4) 6.464e-05 + H[13C]O3- 5.213e-05 4.770e-05 -4.283 -4.321 -0.039 (0) + [13C]O2 1.095e-05 1.097e-05 -4.961 -4.960 0.001 (0) + CaH[13C]O3+ 1.101e-06 1.010e-06 -5.958 -5.996 -0.037 (0) + H[13C]O2[18O]- 1.040e-07 9.517e-08 -6.983 -7.021 -0.039 (0) + H[13C]O[18O]O- 1.040e-07 9.517e-08 -6.983 -7.021 -0.039 (0) + H[13C][18O]O2- 1.040e-07 9.517e-08 -6.983 -7.021 -0.039 (0) + Ca[13C]O3 6.045e-08 6.055e-08 -7.219 -7.218 0.001 (0) + [13C]O[18O] 4.552e-08 4.560e-08 -7.342 -7.341 0.001 (0) + [13C]O3-2 3.098e-08 2.172e-08 -7.509 -7.663 -0.154 (0) + CaH[13C]O2[18O]+ 2.197e-09 2.016e-09 -8.658 -8.696 -0.037 (0) + CaH[13C]O[18O]O+ 2.197e-09 2.016e-09 -8.658 -8.696 -0.037 (0) + CaH[13C][18O]O2+ 2.197e-09 2.016e-09 -8.658 -8.696 -0.037 (0) + Ca[13C]O2[18O] 3.618e-10 3.624e-10 -9.442 -9.441 0.001 (0) + H[13C]O[18O]2- 2.075e-10 1.899e-10 -9.683 -9.722 -0.039 (0) + H[13C][18O]2O- 2.075e-10 1.899e-10 -9.683 -9.722 -0.039 (0) + H[13C][18O]O[18O]- 2.075e-10 1.899e-10 -9.683 -9.722 -0.039 (0) + [13C]O2[18O]-2 1.854e-10 1.300e-10 -9.732 -9.886 -0.154 (0) +[14C](-4) 4.614e-33 + [14C]H4 4.614e-33 4.622e-33 -32.336 -32.335 0.001 (0) +[14C](4) 2.826e-15 + H[14C]O3- 2.282e-15 2.088e-15 -14.642 -14.680 -0.039 (0) + [14C]O2 4.752e-16 4.759e-16 -15.323 -15.322 0.001 (0) + CaH[14C]O3+ 4.822e-17 4.424e-17 -16.317 -16.354 -0.037 (0) + H[14C]O2[18O]- 4.554e-18 4.167e-18 -17.342 -17.380 -0.039 (0) + H[14C]O[18O]O- 4.554e-18 4.167e-18 -17.342 -17.380 -0.039 (0) + H[14C][18O]O2- 4.554e-18 4.167e-18 -17.342 -17.380 -0.039 (0) + Ca[14C]O3 2.643e-18 2.647e-18 -17.578 -17.577 0.001 (0) + [14C]O[18O] 1.976e-18 1.979e-18 -17.704 -17.704 0.001 (0) + [14C]O3-2 1.354e-18 9.494e-19 -17.868 -18.023 -0.154 (0) + CaH[14C]O2[18O]+ 9.620e-20 8.826e-20 -19.017 -19.054 -0.037 (0) + CaH[14C]O[18O]O+ 9.620e-20 8.826e-20 -19.017 -19.054 -0.037 (0) + CaH[14C][18O]O2+ 9.620e-20 8.826e-20 -19.017 -19.054 -0.037 (0) + Ca[14C]O2[18O] 1.582e-20 1.584e-20 -19.801 -19.800 0.001 (0) + H[14C]O[18O]2- 9.086e-21 8.314e-21 -20.042 -20.080 -0.039 (0) + H[14C][18O]2O- 9.086e-21 8.314e-21 -20.042 -20.080 -0.039 (0) + H[14C][18O]O[18O]- 9.086e-21 8.314e-21 -20.042 -20.080 -0.039 (0) + [14C]O2[18O]-2 8.107e-21 5.682e-21 -20.091 -20.245 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.779 -67.778 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.780 -70.779 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -30340,99 +30340,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 3.094e-29 - CH4 3.094e-29 3.099e-29 -28.509 -28.509 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.102e-06 1.011e-06 -5.958 -5.995 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.048e-08 6.058e-08 -7.218 -7.218 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 4.735e-16 - H2 2.368e-16 2.372e-16 -15.626 -15.625 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -61.133 -61.132 0.001 - O[18O] 0.000e+00 0.000e+00 -63.532 -63.531 0.001 -[13C](-4) 3.402e-31 - [13C]H4 3.402e-31 3.407e-31 -30.468 -30.468 0.001 -[13C](4) 6.467e-05 - H[13C]O3- 5.216e-05 4.772e-05 -4.283 -4.321 -0.039 - [13C]O2 1.095e-05 1.097e-05 -4.960 -4.960 0.001 - CaH[13C]O3+ 1.102e-06 1.011e-06 -5.958 -5.995 -0.037 - H[13C]O2[18O]- 1.041e-07 9.522e-08 -6.983 -7.021 -0.039 - H[13C]O[18O]O- 1.041e-07 9.522e-08 -6.983 -7.021 -0.039 - H[13C][18O]O2- 1.041e-07 9.522e-08 -6.983 -7.021 -0.039 - Ca[13C]O3 6.048e-08 6.058e-08 -7.218 -7.218 0.001 - [13C]O[18O] 4.554e-08 4.562e-08 -7.342 -7.341 0.001 - [13C]O3-2 3.100e-08 2.173e-08 -7.509 -7.663 -0.154 - CaH[13C]O2[18O]+ 2.198e-09 2.017e-09 -8.658 -8.695 -0.037 - CaH[13C]O[18O]O+ 2.198e-09 2.017e-09 -8.658 -8.695 -0.037 - CaH[13C][18O]O2+ 2.198e-09 2.017e-09 -8.658 -8.695 -0.037 - Ca[13C]O2[18O] 3.620e-10 3.626e-10 -9.441 -9.441 0.001 - H[13C]O[18O]2- 2.076e-10 1.900e-10 -9.683 -9.721 -0.039 - H[13C][18O]2O- 2.076e-10 1.900e-10 -9.683 -9.721 -0.039 - H[13C][18O]O[18O]- 2.076e-10 1.900e-10 -9.683 -9.721 -0.039 - [13C]O2[18O]-2 1.855e-10 1.300e-10 -9.732 -9.886 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -40.856 -40.855 0.001 -[14C](4) 2.667e-15 - H[14C]O3- 2.154e-15 1.971e-15 -14.667 -14.705 -0.039 - [14C]O2 4.485e-16 4.492e-16 -15.348 -15.348 0.001 - CaH[14C]O3+ 4.551e-17 4.175e-17 -16.342 -16.379 -0.037 - H[14C]O2[18O]- 4.298e-18 3.933e-18 -17.367 -17.405 -0.039 - H[14C]O[18O]O- 4.298e-18 3.933e-18 -17.367 -17.405 -0.039 - H[14C][18O]O2- 4.298e-18 3.933e-18 -17.367 -17.405 -0.039 - Ca[14C]O3 2.494e-18 2.498e-18 -17.603 -17.602 0.001 - [14C]O[18O] 1.865e-18 1.868e-18 -17.729 -17.729 0.001 - [14C]O3-2 1.278e-18 8.960e-19 -17.893 -18.048 -0.154 - CaH[14C]O2[18O]+ 9.080e-20 8.330e-20 -19.042 -19.079 -0.037 - CaH[14C]O[18O]O+ 9.080e-20 8.330e-20 -19.042 -19.079 -0.037 - CaH[14C][18O]O2+ 9.080e-20 8.330e-20 -19.042 -19.079 -0.037 - Ca[14C]O2[18O] 1.493e-20 1.495e-20 -19.826 -19.825 0.001 - H[14C]O[18O]2- 8.576e-21 7.847e-21 -20.067 -20.105 -0.039 - H[14C][18O]2O- 8.576e-21 7.847e-21 -20.067 -20.105 -0.039 - H[14C][18O]O[18O]- 8.576e-21 7.847e-21 -20.067 -20.105 -0.039 - [14C]O2[18O]-2 7.652e-21 5.363e-21 -20.116 -20.271 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -63.532 -63.531 0.001 - [18O]2 0.000e+00 0.000e+00 -66.533 -66.532 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 3.094e-29 + CH4 3.094e-29 3.099e-29 -28.509 -28.509 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.102e-06 1.011e-06 -5.958 -5.995 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.048e-08 6.058e-08 -7.218 -7.218 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 4.735e-16 + H2 2.368e-16 2.372e-16 -15.626 -15.625 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -61.133 -61.132 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -63.532 -63.531 0.001 (0) +[13C](-4) 3.402e-31 + [13C]H4 3.402e-31 3.407e-31 -30.468 -30.468 0.001 (0) +[13C](4) 6.467e-05 + H[13C]O3- 5.216e-05 4.772e-05 -4.283 -4.321 -0.039 (0) + [13C]O2 1.095e-05 1.097e-05 -4.960 -4.960 0.001 (0) + CaH[13C]O3+ 1.102e-06 1.011e-06 -5.958 -5.995 -0.037 (0) + H[13C]O2[18O]- 1.041e-07 9.522e-08 -6.983 -7.021 -0.039 (0) + H[13C]O[18O]O- 1.041e-07 9.522e-08 -6.983 -7.021 -0.039 (0) + H[13C][18O]O2- 1.041e-07 9.522e-08 -6.983 -7.021 -0.039 (0) + Ca[13C]O3 6.048e-08 6.058e-08 -7.218 -7.218 0.001 (0) + [13C]O[18O] 4.554e-08 4.562e-08 -7.342 -7.341 0.001 (0) + [13C]O3-2 3.100e-08 2.173e-08 -7.509 -7.663 -0.154 (0) + CaH[13C]O2[18O]+ 2.198e-09 2.017e-09 -8.658 -8.695 -0.037 (0) + CaH[13C]O[18O]O+ 2.198e-09 2.017e-09 -8.658 -8.695 -0.037 (0) + CaH[13C][18O]O2+ 2.198e-09 2.017e-09 -8.658 -8.695 -0.037 (0) + Ca[13C]O2[18O] 3.620e-10 3.626e-10 -9.441 -9.441 0.001 (0) + H[13C]O[18O]2- 2.076e-10 1.900e-10 -9.683 -9.721 -0.039 (0) + H[13C][18O]2O- 2.076e-10 1.900e-10 -9.683 -9.721 -0.039 (0) + H[13C][18O]O[18O]- 2.076e-10 1.900e-10 -9.683 -9.721 -0.039 (0) + [13C]O2[18O]-2 1.855e-10 1.300e-10 -9.732 -9.886 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -40.856 -40.855 0.001 (0) +[14C](4) 2.667e-15 + H[14C]O3- 2.154e-15 1.971e-15 -14.667 -14.705 -0.039 (0) + [14C]O2 4.485e-16 4.492e-16 -15.348 -15.348 0.001 (0) + CaH[14C]O3+ 4.551e-17 4.175e-17 -16.342 -16.379 -0.037 (0) + H[14C]O2[18O]- 4.298e-18 3.933e-18 -17.367 -17.405 -0.039 (0) + H[14C]O[18O]O- 4.298e-18 3.933e-18 -17.367 -17.405 -0.039 (0) + H[14C][18O]O2- 4.298e-18 3.933e-18 -17.367 -17.405 -0.039 (0) + Ca[14C]O3 2.494e-18 2.498e-18 -17.603 -17.602 0.001 (0) + [14C]O[18O] 1.865e-18 1.868e-18 -17.729 -17.729 0.001 (0) + [14C]O3-2 1.278e-18 8.960e-19 -17.893 -18.048 -0.154 (0) + CaH[14C]O2[18O]+ 9.080e-20 8.330e-20 -19.042 -19.079 -0.037 (0) + CaH[14C]O[18O]O+ 9.080e-20 8.330e-20 -19.042 -19.079 -0.037 (0) + CaH[14C][18O]O2+ 9.080e-20 8.330e-20 -19.042 -19.079 -0.037 (0) + Ca[14C]O2[18O] 1.493e-20 1.495e-20 -19.826 -19.825 0.001 (0) + H[14C]O[18O]2- 8.576e-21 7.847e-21 -20.067 -20.105 -0.039 (0) + H[14C][18O]2O- 8.576e-21 7.847e-21 -20.067 -20.105 -0.039 (0) + H[14C][18O]O[18O]- 8.576e-21 7.847e-21 -20.067 -20.105 -0.039 (0) + [14C]O2[18O]-2 7.652e-21 5.363e-21 -20.116 -20.271 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -63.532 -63.531 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -66.533 -66.532 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -30597,99 +30597,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 2.277e-20 - CH4 2.277e-20 2.280e-20 -19.643 -19.642 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.102e-06 1.011e-06 -5.958 -5.995 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.050e-08 6.060e-08 -7.218 -7.218 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 7.799e-14 - H2 3.900e-14 3.906e-14 -13.409 -13.408 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -65.566 -65.565 0.001 - O[18O] 0.000e+00 0.000e+00 -67.965 -67.964 0.001 -[13C](-4) 2.504e-22 - [13C]H4 2.504e-22 2.508e-22 -21.601 -21.601 0.001 -[13C](4) 6.470e-05 - H[13C]O3- 5.218e-05 4.775e-05 -4.282 -4.321 -0.039 - [13C]O2 1.096e-05 1.098e-05 -4.960 -4.960 0.001 - CaH[13C]O3+ 1.102e-06 1.011e-06 -5.958 -5.995 -0.037 - H[13C]O2[18O]- 1.041e-07 9.526e-08 -6.983 -7.021 -0.039 - H[13C]O[18O]O- 1.041e-07 9.526e-08 -6.983 -7.021 -0.039 - H[13C][18O]O2- 1.041e-07 9.526e-08 -6.983 -7.021 -0.039 - Ca[13C]O3 6.050e-08 6.060e-08 -7.218 -7.218 0.001 - [13C]O[18O] 4.556e-08 4.564e-08 -7.341 -7.341 0.001 - [13C]O3-2 3.101e-08 2.174e-08 -7.509 -7.663 -0.154 - CaH[13C]O2[18O]+ 2.199e-09 2.018e-09 -8.658 -8.695 -0.037 - CaH[13C]O[18O]O+ 2.199e-09 2.018e-09 -8.658 -8.695 -0.037 - CaH[13C][18O]O2+ 2.199e-09 2.018e-09 -8.658 -8.695 -0.037 - Ca[13C]O2[18O] 3.621e-10 3.627e-10 -9.441 -9.440 0.001 - H[13C]O[18O]2- 2.077e-10 1.901e-10 -9.683 -9.721 -0.039 - H[13C][18O]2O- 2.077e-10 1.901e-10 -9.683 -9.721 -0.039 - H[13C][18O]O[18O]- 2.077e-10 1.901e-10 -9.683 -9.721 -0.039 - [13C]O2[18O]-2 1.856e-10 1.301e-10 -9.731 -9.886 -0.154 -[14C](-4) 9.704e-33 - [14C]H4 9.704e-33 9.720e-33 -32.013 -32.012 0.001 -[14C](4) 2.525e-15 - H[14C]O3- 2.040e-15 1.866e-15 -14.690 -14.729 -0.039 - [14C]O2 4.246e-16 4.253e-16 -15.372 -15.371 0.001 - CaH[14C]O3+ 4.309e-17 3.953e-17 -16.366 -16.403 -0.037 - H[14C]O2[18O]- 4.070e-18 3.724e-18 -17.390 -17.429 -0.039 - H[14C]O[18O]O- 4.070e-18 3.724e-18 -17.390 -17.429 -0.039 - H[14C][18O]O2- 4.070e-18 3.724e-18 -17.390 -17.429 -0.039 - Ca[14C]O3 2.362e-18 2.365e-18 -17.627 -17.626 0.001 - [14C]O[18O] 1.766e-18 1.769e-18 -17.753 -17.752 0.001 - [14C]O3-2 1.210e-18 8.484e-19 -17.917 -18.071 -0.154 - CaH[14C]O2[18O]+ 8.597e-20 7.887e-20 -19.066 -19.103 -0.037 - CaH[14C]O[18O]O+ 8.597e-20 7.887e-20 -19.066 -19.103 -0.037 - CaH[14C][18O]O2+ 8.597e-20 7.887e-20 -19.066 -19.103 -0.037 - Ca[14C]O2[18O] 1.414e-20 1.416e-20 -19.850 -19.849 0.001 - H[14C]O[18O]2- 8.120e-21 7.429e-21 -20.090 -20.129 -0.039 - H[14C][18O]2O- 8.120e-21 7.429e-21 -20.090 -20.129 -0.039 - H[14C][18O]O[18O]- 8.120e-21 7.429e-21 -20.090 -20.129 -0.039 - [14C]O2[18O]-2 7.245e-21 5.078e-21 -20.140 -20.294 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 0.000e+00 - O[18O] 0.000e+00 0.000e+00 -67.965 -67.964 0.001 - [18O]2 0.000e+00 0.000e+00 -70.966 -70.965 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 2.277e-20 + CH4 2.277e-20 2.280e-20 -19.643 -19.642 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.102e-06 1.011e-06 -5.958 -5.995 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.050e-08 6.060e-08 -7.218 -7.218 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 7.799e-14 + H2 3.900e-14 3.906e-14 -13.409 -13.408 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -65.566 -65.565 0.001 (0) + O[18O] 0.000e+00 0.000e+00 -67.965 -67.964 0.001 (0) +[13C](-4) 2.504e-22 + [13C]H4 2.504e-22 2.508e-22 -21.601 -21.601 0.001 (0) +[13C](4) 6.470e-05 + H[13C]O3- 5.218e-05 4.775e-05 -4.282 -4.321 -0.039 (0) + [13C]O2 1.096e-05 1.098e-05 -4.960 -4.960 0.001 (0) + CaH[13C]O3+ 1.102e-06 1.011e-06 -5.958 -5.995 -0.037 (0) + H[13C]O2[18O]- 1.041e-07 9.526e-08 -6.983 -7.021 -0.039 (0) + H[13C]O[18O]O- 1.041e-07 9.526e-08 -6.983 -7.021 -0.039 (0) + H[13C][18O]O2- 1.041e-07 9.526e-08 -6.983 -7.021 -0.039 (0) + Ca[13C]O3 6.050e-08 6.060e-08 -7.218 -7.218 0.001 (0) + [13C]O[18O] 4.556e-08 4.564e-08 -7.341 -7.341 0.001 (0) + [13C]O3-2 3.101e-08 2.174e-08 -7.509 -7.663 -0.154 (0) + CaH[13C]O2[18O]+ 2.199e-09 2.018e-09 -8.658 -8.695 -0.037 (0) + CaH[13C]O[18O]O+ 2.199e-09 2.018e-09 -8.658 -8.695 -0.037 (0) + CaH[13C][18O]O2+ 2.199e-09 2.018e-09 -8.658 -8.695 -0.037 (0) + Ca[13C]O2[18O] 3.621e-10 3.627e-10 -9.441 -9.440 0.001 (0) + H[13C]O[18O]2- 2.077e-10 1.901e-10 -9.683 -9.721 -0.039 (0) + H[13C][18O]2O- 2.077e-10 1.901e-10 -9.683 -9.721 -0.039 (0) + H[13C][18O]O[18O]- 2.077e-10 1.901e-10 -9.683 -9.721 -0.039 (0) + [13C]O2[18O]-2 1.856e-10 1.301e-10 -9.731 -9.886 -0.154 (0) +[14C](-4) 9.704e-33 + [14C]H4 9.704e-33 9.720e-33 -32.013 -32.012 0.001 (0) +[14C](4) 2.525e-15 + H[14C]O3- 2.040e-15 1.866e-15 -14.690 -14.729 -0.039 (0) + [14C]O2 4.246e-16 4.253e-16 -15.372 -15.371 0.001 (0) + CaH[14C]O3+ 4.309e-17 3.953e-17 -16.366 -16.403 -0.037 (0) + H[14C]O2[18O]- 4.070e-18 3.724e-18 -17.390 -17.429 -0.039 (0) + H[14C]O[18O]O- 4.070e-18 3.724e-18 -17.390 -17.429 -0.039 (0) + H[14C][18O]O2- 4.070e-18 3.724e-18 -17.390 -17.429 -0.039 (0) + Ca[14C]O3 2.362e-18 2.365e-18 -17.627 -17.626 0.001 (0) + [14C]O[18O] 1.766e-18 1.769e-18 -17.753 -17.752 0.001 (0) + [14C]O3-2 1.210e-18 8.484e-19 -17.917 -18.071 -0.154 (0) + CaH[14C]O2[18O]+ 8.597e-20 7.887e-20 -19.066 -19.103 -0.037 (0) + CaH[14C]O[18O]O+ 8.597e-20 7.887e-20 -19.066 -19.103 -0.037 (0) + CaH[14C][18O]O2+ 8.597e-20 7.887e-20 -19.066 -19.103 -0.037 (0) + Ca[14C]O2[18O] 1.414e-20 1.416e-20 -19.850 -19.849 0.001 (0) + H[14C]O[18O]2- 8.120e-21 7.429e-21 -20.090 -20.129 -0.039 (0) + H[14C][18O]2O- 8.120e-21 7.429e-21 -20.090 -20.129 -0.039 (0) + H[14C][18O]O[18O]- 8.120e-21 7.429e-21 -20.090 -20.129 -0.039 (0) + [14C]O2[18O]-2 7.245e-21 5.078e-21 -20.140 -20.294 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 0.000e+00 + O[18O] 0.000e+00 0.000e+00 -67.965 -67.964 0.001 (0) + [18O]2 0.000e+00 0.000e+00 -70.966 -70.965 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -30852,99 +30852,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.510 -126.510 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.103e-06 1.012e-06 -5.958 -5.995 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.053e-08 6.062e-08 -7.218 -7.217 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.126 -40.125 0.001 -O(0) 1.481e-12 - O2 7.378e-13 7.390e-13 -12.132 -12.131 0.001 - O[18O] 2.944e-15 2.949e-15 -14.531 -14.530 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.469 -128.468 0.001 -[13C](4) 6.472e-05 - H[13C]O3- 5.220e-05 4.776e-05 -4.282 -4.321 -0.039 - [13C]O2 1.096e-05 1.098e-05 -4.960 -4.959 0.001 - CaH[13C]O3+ 1.103e-06 1.012e-06 -5.958 -5.995 -0.037 - H[13C]O2[18O]- 1.042e-07 9.530e-08 -6.982 -7.021 -0.039 - H[13C]O[18O]O- 1.042e-07 9.530e-08 -6.982 -7.021 -0.039 - H[13C][18O]O2- 1.042e-07 9.530e-08 -6.982 -7.021 -0.039 - Ca[13C]O3 6.053e-08 6.062e-08 -7.218 -7.217 0.001 - [13C]O[18O] 4.558e-08 4.566e-08 -7.341 -7.340 0.001 - [13C]O3-2 3.102e-08 2.174e-08 -7.508 -7.663 -0.154 - CaH[13C]O2[18O]+ 2.200e-09 2.018e-09 -8.658 -8.695 -0.037 - CaH[13C]O[18O]O+ 2.200e-09 2.018e-09 -8.658 -8.695 -0.037 - CaH[13C][18O]O2+ 2.200e-09 2.018e-09 -8.658 -8.695 -0.037 - Ca[13C]O2[18O] 3.623e-10 3.629e-10 -9.441 -9.440 0.001 - H[13C]O[18O]2- 2.078e-10 1.901e-10 -9.682 -9.721 -0.039 - H[13C][18O]2O- 2.078e-10 1.901e-10 -9.682 -9.721 -0.039 - H[13C][18O]O[18O]- 2.078e-10 1.901e-10 -9.682 -9.721 -0.039 - [13C]O2[18O]-2 1.857e-10 1.301e-10 -9.731 -9.886 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -138.903 -138.903 0.001 -[14C](4) 2.398e-15 - H[14C]O3- 1.937e-15 1.772e-15 -14.713 -14.752 -0.039 - [14C]O2 4.032e-16 4.039e-16 -15.394 -15.394 0.001 - CaH[14C]O3+ 4.091e-17 3.754e-17 -16.388 -16.426 -0.037 - H[14C]O2[18O]- 3.864e-18 3.536e-18 -17.413 -17.452 -0.039 - H[14C]O[18O]O- 3.864e-18 3.536e-18 -17.413 -17.452 -0.039 - H[14C][18O]O2- 3.864e-18 3.536e-18 -17.413 -17.452 -0.039 - Ca[14C]O3 2.242e-18 2.246e-18 -17.649 -17.649 0.001 - [14C]O[18O] 1.677e-18 1.679e-18 -17.776 -17.775 0.001 - [14C]O3-2 1.149e-18 8.056e-19 -17.940 -18.094 -0.154 - CaH[14C]O2[18O]+ 8.163e-20 7.489e-20 -19.088 -19.126 -0.037 - CaH[14C]O[18O]O+ 8.163e-20 7.489e-20 -19.088 -19.126 -0.037 - CaH[14C][18O]O2+ 8.163e-20 7.489e-20 -19.088 -19.126 -0.037 - Ca[14C]O2[18O] 1.342e-20 1.344e-20 -19.872 -19.871 0.001 - H[14C]O[18O]2- 7.710e-21 7.054e-21 -20.113 -20.152 -0.039 - H[14C][18O]2O- 7.710e-21 7.054e-21 -20.113 -20.152 -0.039 - H[14C][18O]O[18O]- 7.710e-21 7.054e-21 -20.113 -20.152 -0.039 - [14C]O2[18O]-2 6.879e-21 4.822e-21 -20.162 -20.317 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 2.950e-15 - O[18O] 2.944e-15 2.949e-15 -14.531 -14.530 0.001 - [18O]2 2.937e-18 2.942e-18 -17.532 -17.531 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.510 -126.510 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.103e-06 1.012e-06 -5.958 -5.995 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.053e-08 6.062e-08 -7.218 -7.217 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.126 -40.125 0.001 (0) +O(0) 1.481e-12 + O2 7.378e-13 7.390e-13 -12.132 -12.131 0.001 (0) + O[18O] 2.944e-15 2.949e-15 -14.531 -14.530 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.469 -128.468 0.001 (0) +[13C](4) 6.472e-05 + H[13C]O3- 5.220e-05 4.776e-05 -4.282 -4.321 -0.039 (0) + [13C]O2 1.096e-05 1.098e-05 -4.960 -4.959 0.001 (0) + CaH[13C]O3+ 1.103e-06 1.012e-06 -5.958 -5.995 -0.037 (0) + H[13C]O2[18O]- 1.042e-07 9.530e-08 -6.982 -7.021 -0.039 (0) + H[13C]O[18O]O- 1.042e-07 9.530e-08 -6.982 -7.021 -0.039 (0) + H[13C][18O]O2- 1.042e-07 9.530e-08 -6.982 -7.021 -0.039 (0) + Ca[13C]O3 6.053e-08 6.062e-08 -7.218 -7.217 0.001 (0) + [13C]O[18O] 4.558e-08 4.566e-08 -7.341 -7.340 0.001 (0) + [13C]O3-2 3.102e-08 2.174e-08 -7.508 -7.663 -0.154 (0) + CaH[13C]O2[18O]+ 2.200e-09 2.018e-09 -8.658 -8.695 -0.037 (0) + CaH[13C]O[18O]O+ 2.200e-09 2.018e-09 -8.658 -8.695 -0.037 (0) + CaH[13C][18O]O2+ 2.200e-09 2.018e-09 -8.658 -8.695 -0.037 (0) + Ca[13C]O2[18O] 3.623e-10 3.629e-10 -9.441 -9.440 0.001 (0) + H[13C]O[18O]2- 2.078e-10 1.901e-10 -9.682 -9.721 -0.039 (0) + H[13C][18O]2O- 2.078e-10 1.901e-10 -9.682 -9.721 -0.039 (0) + H[13C][18O]O[18O]- 2.078e-10 1.901e-10 -9.682 -9.721 -0.039 (0) + [13C]O2[18O]-2 1.857e-10 1.301e-10 -9.731 -9.886 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -138.903 -138.903 0.001 (0) +[14C](4) 2.398e-15 + H[14C]O3- 1.937e-15 1.772e-15 -14.713 -14.752 -0.039 (0) + [14C]O2 4.032e-16 4.039e-16 -15.394 -15.394 0.001 (0) + CaH[14C]O3+ 4.091e-17 3.754e-17 -16.388 -16.426 -0.037 (0) + H[14C]O2[18O]- 3.864e-18 3.536e-18 -17.413 -17.452 -0.039 (0) + H[14C]O[18O]O- 3.864e-18 3.536e-18 -17.413 -17.452 -0.039 (0) + H[14C][18O]O2- 3.864e-18 3.536e-18 -17.413 -17.452 -0.039 (0) + Ca[14C]O3 2.242e-18 2.246e-18 -17.649 -17.649 0.001 (0) + [14C]O[18O] 1.677e-18 1.679e-18 -17.776 -17.775 0.001 (0) + [14C]O3-2 1.149e-18 8.056e-19 -17.940 -18.094 -0.154 (0) + CaH[14C]O2[18O]+ 8.163e-20 7.489e-20 -19.088 -19.126 -0.037 (0) + CaH[14C]O[18O]O+ 8.163e-20 7.489e-20 -19.088 -19.126 -0.037 (0) + CaH[14C][18O]O2+ 8.163e-20 7.489e-20 -19.088 -19.126 -0.037 (0) + Ca[14C]O2[18O] 1.342e-20 1.344e-20 -19.872 -19.871 0.001 (0) + H[14C]O[18O]2- 7.710e-21 7.054e-21 -20.113 -20.152 -0.039 (0) + H[14C][18O]2O- 7.710e-21 7.054e-21 -20.113 -20.152 -0.039 (0) + H[14C][18O]O[18O]- 7.710e-21 7.054e-21 -20.113 -20.152 -0.039 (0) + [14C]O2[18O]-2 6.879e-21 4.822e-21 -20.162 -20.317 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.950e-15 + O[18O] 2.944e-15 2.949e-15 -14.531 -14.530 0.001 (0) + [18O]2 2.937e-18 2.942e-18 -17.532 -17.531 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -31107,99 +31107,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.523 -126.522 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.103e-06 1.012e-06 -5.957 -5.995 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.055e-08 6.065e-08 -7.218 -7.217 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.129 -40.128 0.001 -O(0) 1.503e-12 - O2 7.484e-13 7.496e-13 -12.126 -12.125 0.001 - O[18O] 2.986e-15 2.991e-15 -14.525 -14.524 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.481 -128.480 0.001 -[13C](4) 6.475e-05 - H[13C]O3- 5.222e-05 4.778e-05 -4.282 -4.321 -0.039 - [13C]O2 1.097e-05 1.098e-05 -4.960 -4.959 0.001 - CaH[13C]O3+ 1.103e-06 1.012e-06 -5.957 -5.995 -0.037 - H[13C]O2[18O]- 1.042e-07 9.533e-08 -6.982 -7.021 -0.039 - H[13C]O[18O]O- 1.042e-07 9.533e-08 -6.982 -7.021 -0.039 - H[13C][18O]O2- 1.042e-07 9.533e-08 -6.982 -7.021 -0.039 - Ca[13C]O3 6.055e-08 6.065e-08 -7.218 -7.217 0.001 - [13C]O[18O] 4.560e-08 4.567e-08 -7.341 -7.340 0.001 - [13C]O3-2 3.103e-08 2.175e-08 -7.508 -7.663 -0.154 - CaH[13C]O2[18O]+ 2.201e-09 2.019e-09 -8.657 -8.695 -0.037 - CaH[13C]O[18O]O+ 2.201e-09 2.019e-09 -8.657 -8.695 -0.037 - CaH[13C][18O]O2+ 2.201e-09 2.019e-09 -8.657 -8.695 -0.037 - Ca[13C]O2[18O] 3.624e-10 3.630e-10 -9.441 -9.440 0.001 - H[13C]O[18O]2- 2.079e-10 1.902e-10 -9.682 -9.721 -0.039 - H[13C][18O]2O- 2.079e-10 1.902e-10 -9.682 -9.721 -0.039 - H[13C][18O]O[18O]- 2.079e-10 1.902e-10 -9.682 -9.721 -0.039 - [13C]O2[18O]-2 1.857e-10 1.302e-10 -9.731 -9.885 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -138.937 -138.936 0.001 -[14C](4) 2.283e-15 - H[14C]O3- 1.844e-15 1.687e-15 -14.734 -14.773 -0.039 - [14C]O2 3.838e-16 3.844e-16 -15.416 -15.415 0.001 - CaH[14C]O3+ 3.895e-17 3.573e-17 -16.410 -16.447 -0.037 - H[14C]O2[18O]- 3.678e-18 3.366e-18 -17.434 -17.473 -0.039 - H[14C]O[18O]O- 3.678e-18 3.366e-18 -17.434 -17.473 -0.039 - H[14C][18O]O2- 3.678e-18 3.366e-18 -17.434 -17.473 -0.039 - Ca[14C]O3 2.135e-18 2.138e-18 -17.671 -17.670 0.001 - [14C]O[18O] 1.596e-18 1.599e-18 -17.797 -17.796 0.001 - [14C]O3-2 1.094e-18 7.669e-19 -17.961 -18.115 -0.154 - CaH[14C]O2[18O]+ 7.771e-20 7.129e-20 -19.110 -19.147 -0.037 - CaH[14C]O[18O]O+ 7.771e-20 7.129e-20 -19.110 -19.147 -0.037 - CaH[14C][18O]O2+ 7.771e-20 7.129e-20 -19.110 -19.147 -0.037 - Ca[14C]O2[18O] 1.278e-20 1.280e-20 -19.894 -19.893 0.001 - H[14C]O[18O]2- 7.339e-21 6.715e-21 -20.134 -20.173 -0.039 - H[14C][18O]2O- 7.339e-21 6.715e-21 -20.134 -20.173 -0.039 - H[14C][18O]O[18O]- 7.339e-21 6.715e-21 -20.134 -20.173 -0.039 - [14C]O2[18O]-2 6.549e-21 4.590e-21 -20.184 -20.338 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 2.992e-15 - O[18O] 2.986e-15 2.991e-15 -14.525 -14.524 0.001 - [18O]2 2.979e-18 2.984e-18 -17.526 -17.525 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.523 -126.522 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.103e-06 1.012e-06 -5.957 -5.995 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.055e-08 6.065e-08 -7.218 -7.217 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.129 -40.128 0.001 (0) +O(0) 1.503e-12 + O2 7.484e-13 7.496e-13 -12.126 -12.125 0.001 (0) + O[18O] 2.986e-15 2.991e-15 -14.525 -14.524 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.481 -128.480 0.001 (0) +[13C](4) 6.475e-05 + H[13C]O3- 5.222e-05 4.778e-05 -4.282 -4.321 -0.039 (0) + [13C]O2 1.097e-05 1.098e-05 -4.960 -4.959 0.001 (0) + CaH[13C]O3+ 1.103e-06 1.012e-06 -5.957 -5.995 -0.037 (0) + H[13C]O2[18O]- 1.042e-07 9.533e-08 -6.982 -7.021 -0.039 (0) + H[13C]O[18O]O- 1.042e-07 9.533e-08 -6.982 -7.021 -0.039 (0) + H[13C][18O]O2- 1.042e-07 9.533e-08 -6.982 -7.021 -0.039 (0) + Ca[13C]O3 6.055e-08 6.065e-08 -7.218 -7.217 0.001 (0) + [13C]O[18O] 4.560e-08 4.567e-08 -7.341 -7.340 0.001 (0) + [13C]O3-2 3.103e-08 2.175e-08 -7.508 -7.663 -0.154 (0) + CaH[13C]O2[18O]+ 2.201e-09 2.019e-09 -8.657 -8.695 -0.037 (0) + CaH[13C]O[18O]O+ 2.201e-09 2.019e-09 -8.657 -8.695 -0.037 (0) + CaH[13C][18O]O2+ 2.201e-09 2.019e-09 -8.657 -8.695 -0.037 (0) + Ca[13C]O2[18O] 3.624e-10 3.630e-10 -9.441 -9.440 0.001 (0) + H[13C]O[18O]2- 2.079e-10 1.902e-10 -9.682 -9.721 -0.039 (0) + H[13C][18O]2O- 2.079e-10 1.902e-10 -9.682 -9.721 -0.039 (0) + H[13C][18O]O[18O]- 2.079e-10 1.902e-10 -9.682 -9.721 -0.039 (0) + [13C]O2[18O]-2 1.857e-10 1.302e-10 -9.731 -9.885 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -138.937 -138.936 0.001 (0) +[14C](4) 2.283e-15 + H[14C]O3- 1.844e-15 1.687e-15 -14.734 -14.773 -0.039 (0) + [14C]O2 3.838e-16 3.844e-16 -15.416 -15.415 0.001 (0) + CaH[14C]O3+ 3.895e-17 3.573e-17 -16.410 -16.447 -0.037 (0) + H[14C]O2[18O]- 3.678e-18 3.366e-18 -17.434 -17.473 -0.039 (0) + H[14C]O[18O]O- 3.678e-18 3.366e-18 -17.434 -17.473 -0.039 (0) + H[14C][18O]O2- 3.678e-18 3.366e-18 -17.434 -17.473 -0.039 (0) + Ca[14C]O3 2.135e-18 2.138e-18 -17.671 -17.670 0.001 (0) + [14C]O[18O] 1.596e-18 1.599e-18 -17.797 -17.796 0.001 (0) + [14C]O3-2 1.094e-18 7.669e-19 -17.961 -18.115 -0.154 (0) + CaH[14C]O2[18O]+ 7.771e-20 7.129e-20 -19.110 -19.147 -0.037 (0) + CaH[14C]O[18O]O+ 7.771e-20 7.129e-20 -19.110 -19.147 -0.037 (0) + CaH[14C][18O]O2+ 7.771e-20 7.129e-20 -19.110 -19.147 -0.037 (0) + Ca[14C]O2[18O] 1.278e-20 1.280e-20 -19.894 -19.893 0.001 (0) + H[14C]O[18O]2- 7.339e-21 6.715e-21 -20.134 -20.173 -0.039 (0) + H[14C][18O]2O- 7.339e-21 6.715e-21 -20.134 -20.173 -0.039 (0) + H[14C][18O]O[18O]- 7.339e-21 6.715e-21 -20.134 -20.173 -0.039 (0) + [14C]O2[18O]-2 6.549e-21 4.590e-21 -20.184 -20.338 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.992e-15 + O[18O] 2.986e-15 2.991e-15 -14.525 -14.524 0.001 (0) + [18O]2 2.979e-18 2.984e-18 -17.526 -17.525 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -31362,99 +31362,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.503 -126.502 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.103e-06 1.012e-06 -5.957 -5.995 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.057e-08 6.067e-08 -7.218 -7.217 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.124 -40.123 0.001 -O(0) 1.469e-12 - O2 7.315e-13 7.327e-13 -12.136 -12.135 0.001 - O[18O] 2.919e-15 2.924e-15 -14.535 -14.534 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.461 -128.460 0.001 -[13C](4) 6.477e-05 - H[13C]O3- 5.224e-05 4.780e-05 -4.282 -4.321 -0.039 - [13C]O2 1.097e-05 1.099e-05 -4.960 -4.959 0.001 - CaH[13C]O3+ 1.103e-06 1.012e-06 -5.957 -5.995 -0.037 - H[13C]O2[18O]- 1.042e-07 9.536e-08 -6.982 -7.021 -0.039 - H[13C]O[18O]O- 1.042e-07 9.536e-08 -6.982 -7.021 -0.039 - H[13C][18O]O2- 1.042e-07 9.536e-08 -6.982 -7.021 -0.039 - Ca[13C]O3 6.057e-08 6.067e-08 -7.218 -7.217 0.001 - [13C]O[18O] 4.561e-08 4.569e-08 -7.341 -7.340 0.001 - [13C]O3-2 3.104e-08 2.176e-08 -7.508 -7.662 -0.154 - CaH[13C]O2[18O]+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 - CaH[13C]O[18O]O+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 - CaH[13C][18O]O2+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 - Ca[13C]O2[18O] 3.625e-10 3.631e-10 -9.441 -9.440 0.001 - H[13C]O[18O]2- 2.079e-10 1.903e-10 -9.682 -9.721 -0.039 - H[13C][18O]2O- 2.079e-10 1.903e-10 -9.682 -9.721 -0.039 - H[13C][18O]O[18O]- 2.079e-10 1.903e-10 -9.682 -9.721 -0.039 - [13C]O2[18O]-2 1.858e-10 1.302e-10 -9.731 -9.885 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -138.938 -138.937 0.001 -[14C](4) 2.178e-15 - H[14C]O3- 1.759e-15 1.610e-15 -14.755 -14.793 -0.039 - [14C]O2 3.662e-16 3.668e-16 -15.436 -15.436 0.001 - CaH[14C]O3+ 3.716e-17 3.409e-17 -16.430 -16.467 -0.037 - H[14C]O2[18O]- 3.510e-18 3.211e-18 -17.455 -17.493 -0.039 - H[14C]O[18O]O- 3.510e-18 3.211e-18 -17.455 -17.493 -0.039 - H[14C][18O]O2- 3.510e-18 3.211e-18 -17.455 -17.493 -0.039 - Ca[14C]O3 2.037e-18 2.040e-18 -17.691 -17.690 0.001 - [14C]O[18O] 1.523e-18 1.525e-18 -17.817 -17.817 0.001 - [14C]O3-2 1.044e-18 7.317e-19 -17.981 -18.136 -0.154 - CaH[14C]O2[18O]+ 7.414e-20 6.802e-20 -19.130 -19.167 -0.037 - CaH[14C]O[18O]O+ 7.414e-20 6.802e-20 -19.130 -19.167 -0.037 - CaH[14C][18O]O2+ 7.414e-20 6.802e-20 -19.130 -19.167 -0.037 - Ca[14C]O2[18O] 1.219e-20 1.221e-20 -19.914 -19.913 0.001 - H[14C]O[18O]2- 7.003e-21 6.407e-21 -20.155 -20.193 -0.039 - H[14C][18O]2O- 7.003e-21 6.407e-21 -20.155 -20.193 -0.039 - H[14C][18O]O[18O]- 7.003e-21 6.407e-21 -20.155 -20.193 -0.039 - [14C]O2[18O]-2 6.248e-21 4.380e-21 -20.204 -20.359 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 2.925e-15 - O[18O] 2.919e-15 2.924e-15 -14.535 -14.534 0.001 - [18O]2 2.912e-18 2.917e-18 -17.536 -17.535 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.503 -126.502 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.103e-06 1.012e-06 -5.957 -5.995 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.057e-08 6.067e-08 -7.218 -7.217 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.124 -40.123 0.001 (0) +O(0) 1.469e-12 + O2 7.315e-13 7.327e-13 -12.136 -12.135 0.001 (0) + O[18O] 2.919e-15 2.924e-15 -14.535 -14.534 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.461 -128.460 0.001 (0) +[13C](4) 6.477e-05 + H[13C]O3- 5.224e-05 4.780e-05 -4.282 -4.321 -0.039 (0) + [13C]O2 1.097e-05 1.099e-05 -4.960 -4.959 0.001 (0) + CaH[13C]O3+ 1.103e-06 1.012e-06 -5.957 -5.995 -0.037 (0) + H[13C]O2[18O]- 1.042e-07 9.536e-08 -6.982 -7.021 -0.039 (0) + H[13C]O[18O]O- 1.042e-07 9.536e-08 -6.982 -7.021 -0.039 (0) + H[13C][18O]O2- 1.042e-07 9.536e-08 -6.982 -7.021 -0.039 (0) + Ca[13C]O3 6.057e-08 6.067e-08 -7.218 -7.217 0.001 (0) + [13C]O[18O] 4.561e-08 4.569e-08 -7.341 -7.340 0.001 (0) + [13C]O3-2 3.104e-08 2.176e-08 -7.508 -7.662 -0.154 (0) + CaH[13C]O2[18O]+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 (0) + CaH[13C]O[18O]O+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 (0) + CaH[13C][18O]O2+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 (0) + Ca[13C]O2[18O] 3.625e-10 3.631e-10 -9.441 -9.440 0.001 (0) + H[13C]O[18O]2- 2.079e-10 1.903e-10 -9.682 -9.721 -0.039 (0) + H[13C][18O]2O- 2.079e-10 1.903e-10 -9.682 -9.721 -0.039 (0) + H[13C][18O]O[18O]- 2.079e-10 1.903e-10 -9.682 -9.721 -0.039 (0) + [13C]O2[18O]-2 1.858e-10 1.302e-10 -9.731 -9.885 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -138.938 -138.937 0.001 (0) +[14C](4) 2.178e-15 + H[14C]O3- 1.759e-15 1.610e-15 -14.755 -14.793 -0.039 (0) + [14C]O2 3.662e-16 3.668e-16 -15.436 -15.436 0.001 (0) + CaH[14C]O3+ 3.716e-17 3.409e-17 -16.430 -16.467 -0.037 (0) + H[14C]O2[18O]- 3.510e-18 3.211e-18 -17.455 -17.493 -0.039 (0) + H[14C]O[18O]O- 3.510e-18 3.211e-18 -17.455 -17.493 -0.039 (0) + H[14C][18O]O2- 3.510e-18 3.211e-18 -17.455 -17.493 -0.039 (0) + Ca[14C]O3 2.037e-18 2.040e-18 -17.691 -17.690 0.001 (0) + [14C]O[18O] 1.523e-18 1.525e-18 -17.817 -17.817 0.001 (0) + [14C]O3-2 1.044e-18 7.317e-19 -17.981 -18.136 -0.154 (0) + CaH[14C]O2[18O]+ 7.414e-20 6.802e-20 -19.130 -19.167 -0.037 (0) + CaH[14C]O[18O]O+ 7.414e-20 6.802e-20 -19.130 -19.167 -0.037 (0) + CaH[14C][18O]O2+ 7.414e-20 6.802e-20 -19.130 -19.167 -0.037 (0) + Ca[14C]O2[18O] 1.219e-20 1.221e-20 -19.914 -19.913 0.001 (0) + H[14C]O[18O]2- 7.003e-21 6.407e-21 -20.155 -20.193 -0.039 (0) + H[14C][18O]2O- 7.003e-21 6.407e-21 -20.155 -20.193 -0.039 (0) + H[14C][18O]O[18O]- 7.003e-21 6.407e-21 -20.155 -20.193 -0.039 (0) + [14C]O2[18O]-2 6.248e-21 4.380e-21 -20.204 -20.359 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.925e-15 + O[18O] 2.919e-15 2.924e-15 -14.535 -14.534 0.001 (0) + [18O]2 2.912e-18 2.917e-18 -17.536 -17.535 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -31617,99 +31617,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.499 -126.498 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.995 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.058e-08 6.068e-08 -7.218 -7.217 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.123 -40.122 0.001 -O(0) 1.462e-12 - O2 7.283e-13 7.295e-13 -12.138 -12.137 0.001 - O[18O] 2.906e-15 2.911e-15 -14.537 -14.536 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.457 -128.457 0.001 -[13C](4) 6.479e-05 - H[13C]O3- 5.225e-05 4.781e-05 -4.282 -4.320 -0.039 - [13C]O2 1.097e-05 1.099e-05 -4.960 -4.959 0.001 - CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.995 -0.037 - H[13C]O2[18O]- 1.043e-07 9.539e-08 -6.982 -7.021 -0.039 - H[13C]O[18O]O- 1.043e-07 9.539e-08 -6.982 -7.021 -0.039 - H[13C][18O]O2- 1.043e-07 9.539e-08 -6.982 -7.021 -0.039 - Ca[13C]O3 6.058e-08 6.068e-08 -7.218 -7.217 0.001 - [13C]O[18O] 4.563e-08 4.570e-08 -7.341 -7.340 0.001 - [13C]O3-2 3.105e-08 2.176e-08 -7.508 -7.662 -0.154 - CaH[13C]O2[18O]+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 - CaH[13C]O[18O]O+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 - CaH[13C][18O]O2+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 - Ca[13C]O2[18O] 3.626e-10 3.632e-10 -9.441 -9.440 0.001 - H[13C]O[18O]2- 2.080e-10 1.903e-10 -9.682 -9.721 -0.039 - H[13C][18O]2O- 2.080e-10 1.903e-10 -9.682 -9.721 -0.039 - H[13C][18O]O[18O]- 2.080e-10 1.903e-10 -9.682 -9.721 -0.039 - [13C]O2[18O]-2 1.859e-10 1.303e-10 -9.731 -9.885 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -138.953 -138.953 0.001 -[14C](4) 2.082e-15 - H[14C]O3- 1.682e-15 1.539e-15 -14.774 -14.813 -0.039 - [14C]O2 3.502e-16 3.507e-16 -15.456 -15.455 0.001 - CaH[14C]O3+ 3.553e-17 3.260e-17 -16.449 -16.487 -0.037 - H[14C]O2[18O]- 3.356e-18 3.071e-18 -17.474 -17.513 -0.039 - H[14C]O[18O]O- 3.356e-18 3.071e-18 -17.474 -17.513 -0.039 - H[14C][18O]O2- 3.356e-18 3.071e-18 -17.474 -17.513 -0.039 - Ca[14C]O3 1.947e-18 1.951e-18 -17.711 -17.710 0.001 - [14C]O[18O] 1.456e-18 1.458e-18 -17.837 -17.836 0.001 - [14C]O3-2 9.981e-19 6.996e-19 -18.001 -18.155 -0.154 - CaH[14C]O2[18O]+ 7.089e-20 6.504e-20 -19.149 -19.187 -0.037 - CaH[14C]O[18O]O+ 7.089e-20 6.504e-20 -19.149 -19.187 -0.037 - CaH[14C][18O]O2+ 7.089e-20 6.504e-20 -19.149 -19.187 -0.037 - Ca[14C]O2[18O] 1.166e-20 1.168e-20 -19.933 -19.933 0.001 - H[14C]O[18O]2- 6.696e-21 6.126e-21 -20.174 -20.213 -0.039 - H[14C][18O]2O- 6.696e-21 6.126e-21 -20.174 -20.213 -0.039 - H[14C][18O]O[18O]- 6.696e-21 6.126e-21 -20.174 -20.213 -0.039 - [14C]O2[18O]-2 5.974e-21 4.188e-21 -20.224 -20.378 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 2.912e-15 - O[18O] 2.906e-15 2.911e-15 -14.537 -14.536 0.001 - [18O]2 2.899e-18 2.904e-18 -17.538 -17.537 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.499 -126.498 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.995 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.058e-08 6.068e-08 -7.218 -7.217 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.123 -40.122 0.001 (0) +O(0) 1.462e-12 + O2 7.283e-13 7.295e-13 -12.138 -12.137 0.001 (0) + O[18O] 2.906e-15 2.911e-15 -14.537 -14.536 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.457 -128.457 0.001 (0) +[13C](4) 6.479e-05 + H[13C]O3- 5.225e-05 4.781e-05 -4.282 -4.320 -0.039 (0) + [13C]O2 1.097e-05 1.099e-05 -4.960 -4.959 0.001 (0) + CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.995 -0.037 (0) + H[13C]O2[18O]- 1.043e-07 9.539e-08 -6.982 -7.021 -0.039 (0) + H[13C]O[18O]O- 1.043e-07 9.539e-08 -6.982 -7.021 -0.039 (0) + H[13C][18O]O2- 1.043e-07 9.539e-08 -6.982 -7.021 -0.039 (0) + Ca[13C]O3 6.058e-08 6.068e-08 -7.218 -7.217 0.001 (0) + [13C]O[18O] 4.563e-08 4.570e-08 -7.341 -7.340 0.001 (0) + [13C]O3-2 3.105e-08 2.176e-08 -7.508 -7.662 -0.154 (0) + CaH[13C]O2[18O]+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 (0) + CaH[13C]O[18O]O+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 (0) + CaH[13C][18O]O2+ 2.202e-09 2.020e-09 -8.657 -8.695 -0.037 (0) + Ca[13C]O2[18O] 3.626e-10 3.632e-10 -9.441 -9.440 0.001 (0) + H[13C]O[18O]2- 2.080e-10 1.903e-10 -9.682 -9.721 -0.039 (0) + H[13C][18O]2O- 2.080e-10 1.903e-10 -9.682 -9.721 -0.039 (0) + H[13C][18O]O[18O]- 2.080e-10 1.903e-10 -9.682 -9.721 -0.039 (0) + [13C]O2[18O]-2 1.859e-10 1.303e-10 -9.731 -9.885 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -138.953 -138.953 0.001 (0) +[14C](4) 2.082e-15 + H[14C]O3- 1.682e-15 1.539e-15 -14.774 -14.813 -0.039 (0) + [14C]O2 3.502e-16 3.507e-16 -15.456 -15.455 0.001 (0) + CaH[14C]O3+ 3.553e-17 3.260e-17 -16.449 -16.487 -0.037 (0) + H[14C]O2[18O]- 3.356e-18 3.071e-18 -17.474 -17.513 -0.039 (0) + H[14C]O[18O]O- 3.356e-18 3.071e-18 -17.474 -17.513 -0.039 (0) + H[14C][18O]O2- 3.356e-18 3.071e-18 -17.474 -17.513 -0.039 (0) + Ca[14C]O3 1.947e-18 1.951e-18 -17.711 -17.710 0.001 (0) + [14C]O[18O] 1.456e-18 1.458e-18 -17.837 -17.836 0.001 (0) + [14C]O3-2 9.981e-19 6.996e-19 -18.001 -18.155 -0.154 (0) + CaH[14C]O2[18O]+ 7.089e-20 6.504e-20 -19.149 -19.187 -0.037 (0) + CaH[14C]O[18O]O+ 7.089e-20 6.504e-20 -19.149 -19.187 -0.037 (0) + CaH[14C][18O]O2+ 7.089e-20 6.504e-20 -19.149 -19.187 -0.037 (0) + Ca[14C]O2[18O] 1.166e-20 1.168e-20 -19.933 -19.933 0.001 (0) + H[14C]O[18O]2- 6.696e-21 6.126e-21 -20.174 -20.213 -0.039 (0) + H[14C][18O]2O- 6.696e-21 6.126e-21 -20.174 -20.213 -0.039 (0) + H[14C][18O]O[18O]- 6.696e-21 6.126e-21 -20.174 -20.213 -0.039 (0) + [14C]O2[18O]-2 5.974e-21 4.188e-21 -20.224 -20.378 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.384e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.912e-15 + O[18O] 2.906e-15 2.911e-15 -14.537 -14.536 0.001 (0) + [18O]2 2.899e-18 2.904e-18 -17.538 -17.537 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -31872,99 +31872,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.504 -126.503 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.060e-08 6.070e-08 -7.218 -7.217 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.124 -40.124 0.001 -O(0) 1.470e-12 - O2 7.320e-13 7.332e-13 -12.135 -12.135 0.001 - O[18O] 2.921e-15 2.926e-15 -14.534 -14.534 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.462 -128.461 0.001 -[13C](4) 6.480e-05 - H[13C]O3- 5.227e-05 4.782e-05 -4.282 -4.320 -0.039 - [13C]O2 1.098e-05 1.099e-05 -4.960 -4.959 0.001 - CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.994 -0.037 - H[13C]O2[18O]- 1.043e-07 9.541e-08 -6.982 -7.020 -0.039 - H[13C]O[18O]O- 1.043e-07 9.541e-08 -6.982 -7.020 -0.039 - H[13C][18O]O2- 1.043e-07 9.541e-08 -6.982 -7.020 -0.039 - Ca[13C]O3 6.060e-08 6.070e-08 -7.218 -7.217 0.001 - [13C]O[18O] 4.564e-08 4.571e-08 -7.341 -7.340 0.001 - [13C]O3-2 3.106e-08 2.177e-08 -7.508 -7.662 -0.154 - CaH[13C]O2[18O]+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 - CaH[13C][18O]O2+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 - Ca[13C]O2[18O] 3.627e-10 3.633e-10 -9.440 -9.440 0.001 - H[13C]O[18O]2- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 - H[13C][18O]2O- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 - H[13C][18O]O[18O]- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 - [13C]O2[18O]-2 1.859e-10 1.303e-10 -9.731 -9.885 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -138.976 -138.976 0.001 -[14C](4) 1.995e-15 - H[14C]O3- 1.611e-15 1.474e-15 -14.793 -14.831 -0.039 - [14C]O2 3.354e-16 3.360e-16 -15.474 -15.474 0.001 - CaH[14C]O3+ 3.404e-17 3.123e-17 -16.468 -16.505 -0.037 - H[14C]O2[18O]- 3.215e-18 2.942e-18 -17.493 -17.531 -0.039 - H[14C]O[18O]O- 3.215e-18 2.942e-18 -17.493 -17.531 -0.039 - H[14C][18O]O2- 3.215e-18 2.942e-18 -17.493 -17.531 -0.039 - Ca[14C]O3 1.866e-18 1.869e-18 -17.729 -17.728 0.001 - [14C]O[18O] 1.395e-18 1.397e-18 -17.855 -17.855 0.001 - [14C]O3-2 9.562e-19 6.702e-19 -18.019 -18.174 -0.154 - CaH[14C]O2[18O]+ 6.791e-20 6.231e-20 -19.168 -19.205 -0.037 - CaH[14C]O[18O]O+ 6.791e-20 6.231e-20 -19.168 -19.205 -0.037 - CaH[14C][18O]O2+ 6.791e-20 6.231e-20 -19.168 -19.205 -0.037 - Ca[14C]O2[18O] 1.117e-20 1.119e-20 -19.952 -19.951 0.001 - H[14C]O[18O]2- 6.414e-21 5.869e-21 -20.193 -20.231 -0.039 - H[14C][18O]2O- 6.414e-21 5.869e-21 -20.193 -20.231 -0.039 - H[14C][18O]O[18O]- 6.414e-21 5.869e-21 -20.193 -20.231 -0.039 - [14C]O2[18O]-2 5.723e-21 4.012e-21 -20.242 -20.397 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 2.927e-15 - O[18O] 2.921e-15 2.926e-15 -14.534 -14.534 0.001 - [18O]2 2.914e-18 2.919e-18 -17.535 -17.535 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.504 -126.503 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.060e-08 6.070e-08 -7.218 -7.217 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.124 -40.124 0.001 (0) +O(0) 1.470e-12 + O2 7.320e-13 7.332e-13 -12.135 -12.135 0.001 (0) + O[18O] 2.921e-15 2.926e-15 -14.534 -14.534 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.462 -128.461 0.001 (0) +[13C](4) 6.480e-05 + H[13C]O3- 5.227e-05 4.782e-05 -4.282 -4.320 -0.039 (0) + [13C]O2 1.098e-05 1.099e-05 -4.960 -4.959 0.001 (0) + CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.043e-07 9.541e-08 -6.982 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.043e-07 9.541e-08 -6.982 -7.020 -0.039 (0) + H[13C][18O]O2- 1.043e-07 9.541e-08 -6.982 -7.020 -0.039 (0) + Ca[13C]O3 6.060e-08 6.070e-08 -7.218 -7.217 0.001 (0) + [13C]O[18O] 4.564e-08 4.571e-08 -7.341 -7.340 0.001 (0) + [13C]O3-2 3.106e-08 2.177e-08 -7.508 -7.662 -0.154 (0) + CaH[13C]O2[18O]+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.627e-10 3.633e-10 -9.440 -9.440 0.001 (0) + H[13C]O[18O]2- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 (0) + H[13C][18O]2O- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.859e-10 1.303e-10 -9.731 -9.885 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -138.976 -138.976 0.001 (0) +[14C](4) 1.995e-15 + H[14C]O3- 1.611e-15 1.474e-15 -14.793 -14.831 -0.039 (0) + [14C]O2 3.354e-16 3.360e-16 -15.474 -15.474 0.001 (0) + CaH[14C]O3+ 3.404e-17 3.123e-17 -16.468 -16.505 -0.037 (0) + H[14C]O2[18O]- 3.215e-18 2.942e-18 -17.493 -17.531 -0.039 (0) + H[14C]O[18O]O- 3.215e-18 2.942e-18 -17.493 -17.531 -0.039 (0) + H[14C][18O]O2- 3.215e-18 2.942e-18 -17.493 -17.531 -0.039 (0) + Ca[14C]O3 1.866e-18 1.869e-18 -17.729 -17.728 0.001 (0) + [14C]O[18O] 1.395e-18 1.397e-18 -17.855 -17.855 0.001 (0) + [14C]O3-2 9.562e-19 6.702e-19 -18.019 -18.174 -0.154 (0) + CaH[14C]O2[18O]+ 6.791e-20 6.231e-20 -19.168 -19.205 -0.037 (0) + CaH[14C]O[18O]O+ 6.791e-20 6.231e-20 -19.168 -19.205 -0.037 (0) + CaH[14C][18O]O2+ 6.791e-20 6.231e-20 -19.168 -19.205 -0.037 (0) + Ca[14C]O2[18O] 1.117e-20 1.119e-20 -19.952 -19.951 0.001 (0) + H[14C]O[18O]2- 6.414e-21 5.869e-21 -20.193 -20.231 -0.039 (0) + H[14C][18O]2O- 6.414e-21 5.869e-21 -20.193 -20.231 -0.039 (0) + H[14C][18O]O[18O]- 6.414e-21 5.869e-21 -20.193 -20.231 -0.039 (0) + [14C]O2[18O]-2 5.723e-21 4.012e-21 -20.242 -20.397 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.927e-15 + O[18O] 2.921e-15 2.926e-15 -14.534 -14.534 0.001 (0) + [18O]2 2.914e-18 2.919e-18 -17.535 -17.535 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -32127,99 +32127,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.479 -126.479 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.061e-08 6.071e-08 -7.217 -7.217 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.118 -40.117 0.001 -O(0) 1.429e-12 - O2 7.118e-13 7.130e-13 -12.148 -12.147 0.001 - O[18O] 2.841e-15 2.845e-15 -14.547 -14.546 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.437 -128.436 0.001 -[13C](4) 6.482e-05 - H[13C]O3- 5.228e-05 4.783e-05 -4.282 -4.320 -0.039 - [13C]O2 1.098e-05 1.100e-05 -4.959 -4.959 0.001 - CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.994 -0.037 - H[13C]O2[18O]- 1.043e-07 9.544e-08 -6.982 -7.020 -0.039 - H[13C]O[18O]O- 1.043e-07 9.544e-08 -6.982 -7.020 -0.039 - H[13C][18O]O2- 1.043e-07 9.544e-08 -6.982 -7.020 -0.039 - Ca[13C]O3 6.061e-08 6.071e-08 -7.217 -7.217 0.001 - [13C]O[18O] 4.565e-08 4.572e-08 -7.341 -7.340 0.001 - [13C]O3-2 3.107e-08 2.178e-08 -7.508 -7.662 -0.154 - CaH[13C]O2[18O]+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 - CaH[13C][18O]O2+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 - Ca[13C]O2[18O] 3.628e-10 3.634e-10 -9.440 -9.440 0.001 - H[13C]O[18O]2- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 - H[13C][18O]2O- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 - H[13C][18O]O[18O]- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 - [13C]O2[18O]-2 1.860e-10 1.303e-10 -9.731 -9.885 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -138.970 -138.969 0.001 -[14C](4) 1.915e-15 - H[14C]O3- 1.546e-15 1.415e-15 -14.811 -14.849 -0.039 - [14C]O2 3.219e-16 3.225e-16 -15.492 -15.492 0.001 - CaH[14C]O3+ 3.267e-17 2.997e-17 -16.486 -16.523 -0.037 - H[14C]O2[18O]- 3.085e-18 2.823e-18 -17.511 -17.549 -0.039 - H[14C]O[18O]O- 3.085e-18 2.823e-18 -17.511 -17.549 -0.039 - H[14C][18O]O2- 3.085e-18 2.823e-18 -17.511 -17.549 -0.039 - Ca[14C]O3 1.790e-18 1.793e-18 -17.747 -17.746 0.001 - [14C]O[18O] 1.339e-18 1.341e-18 -17.873 -17.873 0.001 - [14C]O3-2 9.177e-19 6.432e-19 -18.037 -18.192 -0.154 - CaH[14C]O2[18O]+ 6.518e-20 5.979e-20 -19.186 -19.223 -0.037 - CaH[14C]O[18O]O+ 6.518e-20 5.979e-20 -19.186 -19.223 -0.037 - CaH[14C][18O]O2+ 6.518e-20 5.979e-20 -19.186 -19.223 -0.037 - Ca[14C]O2[18O] 1.072e-20 1.073e-20 -19.970 -19.969 0.001 - H[14C]O[18O]2- 6.156e-21 5.633e-21 -20.211 -20.249 -0.039 - H[14C][18O]2O- 6.156e-21 5.633e-21 -20.211 -20.249 -0.039 - H[14C][18O]O[18O]- 6.156e-21 5.633e-21 -20.211 -20.249 -0.039 - [14C]O2[18O]-2 5.493e-21 3.850e-21 -20.260 -20.415 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 2.846e-15 - O[18O] 2.841e-15 2.845e-15 -14.547 -14.546 0.001 - [18O]2 2.834e-18 2.838e-18 -17.548 -17.547 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.479 -126.479 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.061e-08 6.071e-08 -7.217 -7.217 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.118 -40.117 0.001 (0) +O(0) 1.429e-12 + O2 7.118e-13 7.130e-13 -12.148 -12.147 0.001 (0) + O[18O] 2.841e-15 2.845e-15 -14.547 -14.546 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.437 -128.436 0.001 (0) +[13C](4) 6.482e-05 + H[13C]O3- 5.228e-05 4.783e-05 -4.282 -4.320 -0.039 (0) + [13C]O2 1.098e-05 1.100e-05 -4.959 -4.959 0.001 (0) + CaH[13C]O3+ 1.104e-06 1.013e-06 -5.957 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.043e-07 9.544e-08 -6.982 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.043e-07 9.544e-08 -6.982 -7.020 -0.039 (0) + H[13C][18O]O2- 1.043e-07 9.544e-08 -6.982 -7.020 -0.039 (0) + Ca[13C]O3 6.061e-08 6.071e-08 -7.217 -7.217 0.001 (0) + [13C]O[18O] 4.565e-08 4.572e-08 -7.341 -7.340 0.001 (0) + [13C]O3-2 3.107e-08 2.178e-08 -7.508 -7.662 -0.154 (0) + CaH[13C]O2[18O]+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.203e-09 2.021e-09 -8.657 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.628e-10 3.634e-10 -9.440 -9.440 0.001 (0) + H[13C]O[18O]2- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 (0) + H[13C][18O]2O- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.081e-10 1.904e-10 -9.682 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.860e-10 1.303e-10 -9.731 -9.885 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -138.970 -138.969 0.001 (0) +[14C](4) 1.915e-15 + H[14C]O3- 1.546e-15 1.415e-15 -14.811 -14.849 -0.039 (0) + [14C]O2 3.219e-16 3.225e-16 -15.492 -15.492 0.001 (0) + CaH[14C]O3+ 3.267e-17 2.997e-17 -16.486 -16.523 -0.037 (0) + H[14C]O2[18O]- 3.085e-18 2.823e-18 -17.511 -17.549 -0.039 (0) + H[14C]O[18O]O- 3.085e-18 2.823e-18 -17.511 -17.549 -0.039 (0) + H[14C][18O]O2- 3.085e-18 2.823e-18 -17.511 -17.549 -0.039 (0) + Ca[14C]O3 1.790e-18 1.793e-18 -17.747 -17.746 0.001 (0) + [14C]O[18O] 1.339e-18 1.341e-18 -17.873 -17.873 0.001 (0) + [14C]O3-2 9.177e-19 6.432e-19 -18.037 -18.192 -0.154 (0) + CaH[14C]O2[18O]+ 6.518e-20 5.979e-20 -19.186 -19.223 -0.037 (0) + CaH[14C]O[18O]O+ 6.518e-20 5.979e-20 -19.186 -19.223 -0.037 (0) + CaH[14C][18O]O2+ 6.518e-20 5.979e-20 -19.186 -19.223 -0.037 (0) + Ca[14C]O2[18O] 1.072e-20 1.073e-20 -19.970 -19.969 0.001 (0) + H[14C]O[18O]2- 6.156e-21 5.633e-21 -20.211 -20.249 -0.039 (0) + H[14C][18O]2O- 6.156e-21 5.633e-21 -20.211 -20.249 -0.039 (0) + H[14C][18O]O[18O]- 6.156e-21 5.633e-21 -20.211 -20.249 -0.039 (0) + [14C]O2[18O]-2 5.493e-21 3.850e-21 -20.260 -20.415 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.846e-15 + O[18O] 2.841e-15 2.845e-15 -14.547 -14.546 0.001 (0) + [18O]2 2.834e-18 2.838e-18 -17.548 -17.547 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -32382,99 +32382,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.496 -126.496 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.105e-06 1.013e-06 -5.957 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.063e-08 6.073e-08 -7.217 -7.217 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.122 -40.122 0.001 -O(0) 1.458e-12 - O2 7.260e-13 7.272e-13 -12.139 -12.138 0.001 - O[18O] 2.897e-15 2.902e-15 -14.538 -14.537 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.454 -128.453 0.001 -[13C](4) 6.483e-05 - H[13C]O3- 5.229e-05 4.784e-05 -4.282 -4.320 -0.039 - [13C]O2 1.098e-05 1.100e-05 -4.959 -4.959 0.001 - CaH[13C]O3+ 1.105e-06 1.013e-06 -5.957 -5.994 -0.037 - H[13C]O2[18O]- 1.043e-07 9.546e-08 -6.982 -7.020 -0.039 - H[13C]O[18O]O- 1.043e-07 9.546e-08 -6.982 -7.020 -0.039 - H[13C][18O]O2- 1.043e-07 9.546e-08 -6.982 -7.020 -0.039 - Ca[13C]O3 6.063e-08 6.073e-08 -7.217 -7.217 0.001 - [13C]O[18O] 4.566e-08 4.573e-08 -7.340 -7.340 0.001 - [13C]O3-2 3.107e-08 2.178e-08 -7.508 -7.662 -0.154 - CaH[13C]O2[18O]+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 - CaH[13C][18O]O2+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 - Ca[13C]O2[18O] 3.629e-10 3.635e-10 -9.440 -9.440 0.001 - H[13C]O[18O]2- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 - H[13C][18O]2O- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 - H[13C][18O]O[18O]- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 - [13C]O2[18O]-2 1.860e-10 1.304e-10 -9.730 -9.885 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.004 -139.003 0.001 -[14C](4) 1.840e-15 - H[14C]O3- 1.486e-15 1.360e-15 -14.828 -14.866 -0.039 - [14C]O2 3.094e-16 3.100e-16 -15.509 -15.509 0.001 - CaH[14C]O3+ 3.140e-17 2.881e-17 -16.503 -16.540 -0.037 - H[14C]O2[18O]- 2.966e-18 2.714e-18 -17.528 -17.566 -0.039 - H[14C]O[18O]O- 2.966e-18 2.714e-18 -17.528 -17.566 -0.039 - H[14C][18O]O2- 2.966e-18 2.714e-18 -17.528 -17.566 -0.039 - Ca[14C]O3 1.721e-18 1.724e-18 -17.764 -17.763 0.001 - [14C]O[18O] 1.287e-18 1.289e-18 -17.890 -17.890 0.001 - [14C]O3-2 8.821e-19 6.183e-19 -18.054 -18.209 -0.154 - CaH[14C]O2[18O]+ 6.265e-20 5.748e-20 -19.203 -19.240 -0.037 - CaH[14C]O[18O]O+ 6.265e-20 5.748e-20 -19.203 -19.240 -0.037 - CaH[14C][18O]O2+ 6.265e-20 5.748e-20 -19.203 -19.240 -0.037 - Ca[14C]O2[18O] 1.030e-20 1.032e-20 -19.987 -19.986 0.001 - H[14C]O[18O]2- 5.917e-21 5.414e-21 -20.228 -20.266 -0.039 - H[14C][18O]2O- 5.917e-21 5.414e-21 -20.228 -20.266 -0.039 - H[14C][18O]O[18O]- 5.917e-21 5.414e-21 -20.228 -20.266 -0.039 - [14C]O2[18O]-2 5.280e-21 3.701e-21 -20.277 -20.432 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 2.903e-15 - O[18O] 2.897e-15 2.902e-15 -14.538 -14.537 0.001 - [18O]2 2.890e-18 2.895e-18 -17.539 -17.538 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.496 -126.496 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.105e-06 1.013e-06 -5.957 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.063e-08 6.073e-08 -7.217 -7.217 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.122 -40.122 0.001 (0) +O(0) 1.458e-12 + O2 7.260e-13 7.272e-13 -12.139 -12.138 0.001 (0) + O[18O] 2.897e-15 2.902e-15 -14.538 -14.537 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.454 -128.453 0.001 (0) +[13C](4) 6.483e-05 + H[13C]O3- 5.229e-05 4.784e-05 -4.282 -4.320 -0.039 (0) + [13C]O2 1.098e-05 1.100e-05 -4.959 -4.959 0.001 (0) + CaH[13C]O3+ 1.105e-06 1.013e-06 -5.957 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.043e-07 9.546e-08 -6.982 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.043e-07 9.546e-08 -6.982 -7.020 -0.039 (0) + H[13C][18O]O2- 1.043e-07 9.546e-08 -6.982 -7.020 -0.039 (0) + Ca[13C]O3 6.063e-08 6.073e-08 -7.217 -7.217 0.001 (0) + [13C]O[18O] 4.566e-08 4.573e-08 -7.340 -7.340 0.001 (0) + [13C]O3-2 3.107e-08 2.178e-08 -7.508 -7.662 -0.154 (0) + CaH[13C]O2[18O]+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.629e-10 3.635e-10 -9.440 -9.440 0.001 (0) + H[13C]O[18O]2- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 (0) + H[13C][18O]2O- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.860e-10 1.304e-10 -9.730 -9.885 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.004 -139.003 0.001 (0) +[14C](4) 1.840e-15 + H[14C]O3- 1.486e-15 1.360e-15 -14.828 -14.866 -0.039 (0) + [14C]O2 3.094e-16 3.100e-16 -15.509 -15.509 0.001 (0) + CaH[14C]O3+ 3.140e-17 2.881e-17 -16.503 -16.540 -0.037 (0) + H[14C]O2[18O]- 2.966e-18 2.714e-18 -17.528 -17.566 -0.039 (0) + H[14C]O[18O]O- 2.966e-18 2.714e-18 -17.528 -17.566 -0.039 (0) + H[14C][18O]O2- 2.966e-18 2.714e-18 -17.528 -17.566 -0.039 (0) + Ca[14C]O3 1.721e-18 1.724e-18 -17.764 -17.763 0.001 (0) + [14C]O[18O] 1.287e-18 1.289e-18 -17.890 -17.890 0.001 (0) + [14C]O3-2 8.821e-19 6.183e-19 -18.054 -18.209 -0.154 (0) + CaH[14C]O2[18O]+ 6.265e-20 5.748e-20 -19.203 -19.240 -0.037 (0) + CaH[14C]O[18O]O+ 6.265e-20 5.748e-20 -19.203 -19.240 -0.037 (0) + CaH[14C][18O]O2+ 6.265e-20 5.748e-20 -19.203 -19.240 -0.037 (0) + Ca[14C]O2[18O] 1.030e-20 1.032e-20 -19.987 -19.986 0.001 (0) + H[14C]O[18O]2- 5.917e-21 5.414e-21 -20.228 -20.266 -0.039 (0) + H[14C][18O]2O- 5.917e-21 5.414e-21 -20.228 -20.266 -0.039 (0) + H[14C][18O]O[18O]- 5.917e-21 5.414e-21 -20.228 -20.266 -0.039 (0) + [14C]O2[18O]-2 5.280e-21 3.701e-21 -20.277 -20.432 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.903e-15 + O[18O] 2.897e-15 2.902e-15 -14.538 -14.537 0.001 (0) + [18O]2 2.890e-18 2.895e-18 -17.539 -17.538 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -32637,99 +32637,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.499 -126.499 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.064e-08 6.074e-08 -7.217 -7.217 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.123 -40.122 0.001 -O(0) 1.463e-12 - O2 7.285e-13 7.297e-13 -12.138 -12.137 0.001 - O[18O] 2.907e-15 2.912e-15 -14.537 -14.536 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.457 -128.456 0.001 -[13C](4) 6.485e-05 - H[13C]O3- 5.230e-05 4.785e-05 -4.281 -4.320 -0.039 - [13C]O2 1.098e-05 1.100e-05 -4.959 -4.959 0.001 - CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 - H[13C]O2[18O]- 1.043e-07 9.548e-08 -6.982 -7.020 -0.039 - H[13C]O[18O]O- 1.043e-07 9.548e-08 -6.982 -7.020 -0.039 - H[13C][18O]O2- 1.043e-07 9.548e-08 -6.982 -7.020 -0.039 - Ca[13C]O3 6.064e-08 6.074e-08 -7.217 -7.217 0.001 - [13C]O[18O] 4.567e-08 4.574e-08 -7.340 -7.340 0.001 - [13C]O3-2 3.108e-08 2.178e-08 -7.508 -7.662 -0.154 - CaH[13C]O2[18O]+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 - CaH[13C][18O]O2+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 - Ca[13C]O2[18O] 3.630e-10 3.636e-10 -9.440 -9.439 0.001 - H[13C]O[18O]2- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 - H[13C][18O]2O- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 - H[13C][18O]O[18O]- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 - [13C]O2[18O]-2 1.860e-10 1.304e-10 -9.730 -9.885 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.024 -139.023 0.001 -[14C](4) 1.772e-15 - H[14C]O3- 1.431e-15 1.309e-15 -14.844 -14.883 -0.039 - [14C]O2 2.979e-16 2.984e-16 -15.526 -15.525 0.001 - CaH[14C]O3+ 3.023e-17 2.773e-17 -16.520 -16.557 -0.037 - H[14C]O2[18O]- 2.855e-18 2.612e-18 -17.544 -17.583 -0.039 - H[14C]O[18O]O- 2.855e-18 2.612e-18 -17.544 -17.583 -0.039 - H[14C][18O]O2- 2.855e-18 2.612e-18 -17.544 -17.583 -0.039 - Ca[14C]O3 1.657e-18 1.660e-18 -17.781 -17.780 0.001 - [14C]O[18O] 1.239e-18 1.241e-18 -17.907 -17.906 0.001 - [14C]O3-2 8.492e-19 5.952e-19 -18.071 -18.225 -0.154 - CaH[14C]O2[18O]+ 6.031e-20 5.533e-20 -19.220 -19.257 -0.037 - CaH[14C]O[18O]O+ 6.031e-20 5.533e-20 -19.220 -19.257 -0.037 - CaH[14C][18O]O2+ 6.031e-20 5.533e-20 -19.220 -19.257 -0.037 - Ca[14C]O2[18O] 9.917e-21 9.933e-21 -20.004 -20.003 0.001 - H[14C]O[18O]2- 5.697e-21 5.212e-21 -20.244 -20.283 -0.039 - H[14C][18O]2O- 5.697e-21 5.212e-21 -20.244 -20.283 -0.039 - H[14C][18O]O[18O]- 5.697e-21 5.212e-21 -20.244 -20.283 -0.039 - [14C]O2[18O]-2 5.083e-21 3.563e-21 -20.294 -20.448 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 2.913e-15 - O[18O] 2.907e-15 2.912e-15 -14.537 -14.536 0.001 - [18O]2 2.900e-18 2.905e-18 -17.538 -17.537 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.499 -126.499 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.064e-08 6.074e-08 -7.217 -7.217 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.123 -40.122 0.001 (0) +O(0) 1.463e-12 + O2 7.285e-13 7.297e-13 -12.138 -12.137 0.001 (0) + O[18O] 2.907e-15 2.912e-15 -14.537 -14.536 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.457 -128.456 0.001 (0) +[13C](4) 6.485e-05 + H[13C]O3- 5.230e-05 4.785e-05 -4.281 -4.320 -0.039 (0) + [13C]O2 1.098e-05 1.100e-05 -4.959 -4.959 0.001 (0) + CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.043e-07 9.548e-08 -6.982 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.043e-07 9.548e-08 -6.982 -7.020 -0.039 (0) + H[13C][18O]O2- 1.043e-07 9.548e-08 -6.982 -7.020 -0.039 (0) + Ca[13C]O3 6.064e-08 6.074e-08 -7.217 -7.217 0.001 (0) + [13C]O[18O] 4.567e-08 4.574e-08 -7.340 -7.340 0.001 (0) + [13C]O3-2 3.108e-08 2.178e-08 -7.508 -7.662 -0.154 (0) + CaH[13C]O2[18O]+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.204e-09 2.022e-09 -8.657 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.630e-10 3.636e-10 -9.440 -9.439 0.001 (0) + H[13C]O[18O]2- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 (0) + H[13C][18O]2O- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.082e-10 1.905e-10 -9.682 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.860e-10 1.304e-10 -9.730 -9.885 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.024 -139.023 0.001 (0) +[14C](4) 1.772e-15 + H[14C]O3- 1.431e-15 1.309e-15 -14.844 -14.883 -0.039 (0) + [14C]O2 2.979e-16 2.984e-16 -15.526 -15.525 0.001 (0) + CaH[14C]O3+ 3.023e-17 2.773e-17 -16.520 -16.557 -0.037 (0) + H[14C]O2[18O]- 2.855e-18 2.612e-18 -17.544 -17.583 -0.039 (0) + H[14C]O[18O]O- 2.855e-18 2.612e-18 -17.544 -17.583 -0.039 (0) + H[14C][18O]O2- 2.855e-18 2.612e-18 -17.544 -17.583 -0.039 (0) + Ca[14C]O3 1.657e-18 1.660e-18 -17.781 -17.780 0.001 (0) + [14C]O[18O] 1.239e-18 1.241e-18 -17.907 -17.906 0.001 (0) + [14C]O3-2 8.492e-19 5.952e-19 -18.071 -18.225 -0.154 (0) + CaH[14C]O2[18O]+ 6.031e-20 5.533e-20 -19.220 -19.257 -0.037 (0) + CaH[14C]O[18O]O+ 6.031e-20 5.533e-20 -19.220 -19.257 -0.037 (0) + CaH[14C][18O]O2+ 6.031e-20 5.533e-20 -19.220 -19.257 -0.037 (0) + Ca[14C]O2[18O] 9.917e-21 9.933e-21 -20.004 -20.003 0.001 (0) + H[14C]O[18O]2- 5.697e-21 5.212e-21 -20.244 -20.283 -0.039 (0) + H[14C][18O]2O- 5.697e-21 5.212e-21 -20.244 -20.283 -0.039 (0) + H[14C][18O]O[18O]- 5.697e-21 5.212e-21 -20.244 -20.283 -0.039 (0) + [14C]O2[18O]-2 5.083e-21 3.563e-21 -20.294 -20.448 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.913e-15 + O[18O] 2.907e-15 2.912e-15 -14.537 -14.536 0.001 (0) + [18O]2 2.900e-18 2.905e-18 -17.538 -17.537 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -32892,99 +32892,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.503 -126.502 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.065e-08 6.075e-08 -7.217 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.124 -40.123 0.001 -O(0) 1.469e-12 - O2 7.314e-13 7.326e-13 -12.136 -12.135 0.001 - O[18O] 2.918e-15 2.923e-15 -14.535 -14.534 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.460 -128.460 0.001 -[13C](4) 6.486e-05 - H[13C]O3- 5.231e-05 4.786e-05 -4.281 -4.320 -0.039 - [13C]O2 1.098e-05 1.100e-05 -4.959 -4.959 0.001 - CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 - H[13C]O2[18O]- 1.044e-07 9.550e-08 -6.981 -7.020 -0.039 - H[13C]O[18O]O- 1.044e-07 9.550e-08 -6.981 -7.020 -0.039 - H[13C][18O]O2- 1.044e-07 9.550e-08 -6.981 -7.020 -0.039 - Ca[13C]O3 6.065e-08 6.075e-08 -7.217 -7.216 0.001 - [13C]O[18O] 4.568e-08 4.575e-08 -7.340 -7.340 0.001 - [13C]O3-2 3.109e-08 2.179e-08 -7.507 -7.662 -0.154 - CaH[13C]O2[18O]+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 - CaH[13C][18O]O2+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 - Ca[13C]O2[18O] 3.630e-10 3.636e-10 -9.440 -9.439 0.001 - H[13C]O[18O]2- 2.082e-10 1.905e-10 -9.681 -9.720 -0.039 - H[13C][18O]2O- 2.082e-10 1.905e-10 -9.681 -9.720 -0.039 - H[13C][18O]O[18O]- 2.082e-10 1.905e-10 -9.681 -9.720 -0.039 - [13C]O2[18O]-2 1.861e-10 1.304e-10 -9.730 -9.885 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.043 -139.042 0.001 -[14C](4) 1.708e-15 - H[14C]O3- 1.380e-15 1.262e-15 -14.860 -14.899 -0.039 - [14C]O2 2.872e-16 2.877e-16 -15.542 -15.541 0.001 - CaH[14C]O3+ 2.914e-17 2.674e-17 -16.535 -16.573 -0.037 - H[14C]O2[18O]- 2.752e-18 2.518e-18 -17.560 -17.599 -0.039 - H[14C]O[18O]O- 2.752e-18 2.518e-18 -17.560 -17.599 -0.039 - H[14C][18O]O2- 2.752e-18 2.518e-18 -17.560 -17.599 -0.039 - Ca[14C]O3 1.597e-18 1.600e-18 -17.797 -17.796 0.001 - [14C]O[18O] 1.194e-18 1.196e-18 -17.923 -17.922 0.001 - [14C]O3-2 8.187e-19 5.738e-19 -18.087 -18.241 -0.154 - CaH[14C]O2[18O]+ 5.814e-20 5.334e-20 -19.235 -19.273 -0.037 - CaH[14C]O[18O]O+ 5.814e-20 5.334e-20 -19.235 -19.273 -0.037 - CaH[14C][18O]O2+ 5.814e-20 5.334e-20 -19.235 -19.273 -0.037 - Ca[14C]O2[18O] 9.560e-21 9.576e-21 -20.020 -20.019 0.001 - H[14C]O[18O]2- 5.492e-21 5.025e-21 -20.260 -20.299 -0.039 - H[14C][18O]2O- 5.492e-21 5.025e-21 -20.260 -20.299 -0.039 - H[14C][18O]O[18O]- 5.492e-21 5.025e-21 -20.260 -20.299 -0.039 - [14C]O2[18O]-2 4.900e-21 3.435e-21 -20.310 -20.464 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 2.924e-15 - O[18O] 2.918e-15 2.923e-15 -14.535 -14.534 0.001 - [18O]2 2.911e-18 2.916e-18 -17.536 -17.535 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.503 -126.502 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.065e-08 6.075e-08 -7.217 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.124 -40.123 0.001 (0) +O(0) 1.469e-12 + O2 7.314e-13 7.326e-13 -12.136 -12.135 0.001 (0) + O[18O] 2.918e-15 2.923e-15 -14.535 -14.534 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.460 -128.460 0.001 (0) +[13C](4) 6.486e-05 + H[13C]O3- 5.231e-05 4.786e-05 -4.281 -4.320 -0.039 (0) + [13C]O2 1.098e-05 1.100e-05 -4.959 -4.959 0.001 (0) + CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.044e-07 9.550e-08 -6.981 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.044e-07 9.550e-08 -6.981 -7.020 -0.039 (0) + H[13C][18O]O2- 1.044e-07 9.550e-08 -6.981 -7.020 -0.039 (0) + Ca[13C]O3 6.065e-08 6.075e-08 -7.217 -7.216 0.001 (0) + [13C]O[18O] 4.568e-08 4.575e-08 -7.340 -7.340 0.001 (0) + [13C]O3-2 3.109e-08 2.179e-08 -7.507 -7.662 -0.154 (0) + CaH[13C]O2[18O]+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.630e-10 3.636e-10 -9.440 -9.439 0.001 (0) + H[13C]O[18O]2- 2.082e-10 1.905e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]2O- 2.082e-10 1.905e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.082e-10 1.905e-10 -9.681 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.861e-10 1.304e-10 -9.730 -9.885 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.043 -139.042 0.001 (0) +[14C](4) 1.708e-15 + H[14C]O3- 1.380e-15 1.262e-15 -14.860 -14.899 -0.039 (0) + [14C]O2 2.872e-16 2.877e-16 -15.542 -15.541 0.001 (0) + CaH[14C]O3+ 2.914e-17 2.674e-17 -16.535 -16.573 -0.037 (0) + H[14C]O2[18O]- 2.752e-18 2.518e-18 -17.560 -17.599 -0.039 (0) + H[14C]O[18O]O- 2.752e-18 2.518e-18 -17.560 -17.599 -0.039 (0) + H[14C][18O]O2- 2.752e-18 2.518e-18 -17.560 -17.599 -0.039 (0) + Ca[14C]O3 1.597e-18 1.600e-18 -17.797 -17.796 0.001 (0) + [14C]O[18O] 1.194e-18 1.196e-18 -17.923 -17.922 0.001 (0) + [14C]O3-2 8.187e-19 5.738e-19 -18.087 -18.241 -0.154 (0) + CaH[14C]O2[18O]+ 5.814e-20 5.334e-20 -19.235 -19.273 -0.037 (0) + CaH[14C]O[18O]O+ 5.814e-20 5.334e-20 -19.235 -19.273 -0.037 (0) + CaH[14C][18O]O2+ 5.814e-20 5.334e-20 -19.235 -19.273 -0.037 (0) + Ca[14C]O2[18O] 9.560e-21 9.576e-21 -20.020 -20.019 0.001 (0) + H[14C]O[18O]2- 5.492e-21 5.025e-21 -20.260 -20.299 -0.039 (0) + H[14C][18O]2O- 5.492e-21 5.025e-21 -20.260 -20.299 -0.039 (0) + H[14C][18O]O[18O]- 5.492e-21 5.025e-21 -20.260 -20.299 -0.039 (0) + [14C]O2[18O]-2 4.900e-21 3.435e-21 -20.310 -20.464 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.924e-15 + O[18O] 2.918e-15 2.923e-15 -14.535 -14.534 0.001 (0) + [18O]2 2.911e-18 2.916e-18 -17.536 -17.535 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -33147,99 +33147,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.493 -126.493 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.066e-08 6.076e-08 -7.217 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.122 -40.121 0.001 -O(0) 1.452e-12 - O2 7.233e-13 7.245e-13 -12.141 -12.140 0.001 - O[18O] 2.886e-15 2.891e-15 -14.540 -14.539 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.451 -128.450 0.001 -[13C](4) 6.487e-05 - H[13C]O3- 5.232e-05 4.787e-05 -4.281 -4.320 -0.039 - [13C]O2 1.099e-05 1.100e-05 -4.959 -4.958 0.001 - CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 - H[13C]O2[18O]- 1.044e-07 9.551e-08 -6.981 -7.020 -0.039 - H[13C]O[18O]O- 1.044e-07 9.551e-08 -6.981 -7.020 -0.039 - H[13C][18O]O2- 1.044e-07 9.551e-08 -6.981 -7.020 -0.039 - Ca[13C]O3 6.066e-08 6.076e-08 -7.217 -7.216 0.001 - [13C]O[18O] 4.569e-08 4.576e-08 -7.340 -7.340 0.001 - [13C]O3-2 3.109e-08 2.179e-08 -7.507 -7.662 -0.154 - CaH[13C]O2[18O]+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 - CaH[13C][18O]O2+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 - Ca[13C]O2[18O] 3.631e-10 3.637e-10 -9.440 -9.439 0.001 - H[13C]O[18O]2- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 - H[13C][18O]2O- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 - H[13C][18O]O[18O]- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 - [13C]O2[18O]-2 1.861e-10 1.304e-10 -9.730 -9.885 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.049 -139.048 0.001 -[14C](4) 1.649e-15 - H[14C]O3- 1.332e-15 1.218e-15 -14.876 -14.914 -0.039 - [14C]O2 2.772e-16 2.777e-16 -15.557 -15.556 0.001 - CaH[14C]O3+ 2.813e-17 2.581e-17 -16.551 -16.588 -0.037 - H[14C]O2[18O]- 2.657e-18 2.431e-18 -17.576 -17.614 -0.039 - H[14C]O[18O]O- 2.657e-18 2.431e-18 -17.576 -17.614 -0.039 - H[14C][18O]O2- 2.657e-18 2.431e-18 -17.576 -17.614 -0.039 - Ca[14C]O3 1.542e-18 1.544e-18 -17.812 -17.811 0.001 - [14C]O[18O] 1.153e-18 1.155e-18 -17.938 -17.938 0.001 - [14C]O3-2 7.902e-19 5.539e-19 -18.102 -18.257 -0.154 - CaH[14C]O2[18O]+ 5.613e-20 5.149e-20 -19.251 -19.288 -0.037 - CaH[14C]O[18O]O+ 5.613e-20 5.149e-20 -19.251 -19.288 -0.037 - CaH[14C][18O]O2+ 5.613e-20 5.149e-20 -19.251 -19.288 -0.037 - Ca[14C]O2[18O] 9.229e-21 9.244e-21 -20.035 -20.034 0.001 - H[14C]O[18O]2- 5.301e-21 4.850e-21 -20.276 -20.314 -0.039 - H[14C][18O]2O- 5.301e-21 4.850e-21 -20.276 -20.314 -0.039 - H[14C][18O]O[18O]- 5.301e-21 4.850e-21 -20.276 -20.314 -0.039 - [14C]O2[18O]-2 4.730e-21 3.315e-21 -20.325 -20.479 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 2.892e-15 - O[18O] 2.886e-15 2.891e-15 -14.540 -14.539 0.001 - [18O]2 2.879e-18 2.884e-18 -17.541 -17.540 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.493 -126.493 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.066e-08 6.076e-08 -7.217 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.122 -40.121 0.001 (0) +O(0) 1.452e-12 + O2 7.233e-13 7.245e-13 -12.141 -12.140 0.001 (0) + O[18O] 2.886e-15 2.891e-15 -14.540 -14.539 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.451 -128.450 0.001 (0) +[13C](4) 6.487e-05 + H[13C]O3- 5.232e-05 4.787e-05 -4.281 -4.320 -0.039 (0) + [13C]O2 1.099e-05 1.100e-05 -4.959 -4.958 0.001 (0) + CaH[13C]O3+ 1.105e-06 1.014e-06 -5.957 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.044e-07 9.551e-08 -6.981 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.044e-07 9.551e-08 -6.981 -7.020 -0.039 (0) + H[13C][18O]O2- 1.044e-07 9.551e-08 -6.981 -7.020 -0.039 (0) + Ca[13C]O3 6.066e-08 6.076e-08 -7.217 -7.216 0.001 (0) + [13C]O[18O] 4.569e-08 4.576e-08 -7.340 -7.340 0.001 (0) + [13C]O3-2 3.109e-08 2.179e-08 -7.507 -7.662 -0.154 (0) + CaH[13C]O2[18O]+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.205e-09 2.023e-09 -8.657 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.631e-10 3.637e-10 -9.440 -9.439 0.001 (0) + H[13C]O[18O]2- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]2O- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.861e-10 1.304e-10 -9.730 -9.885 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.049 -139.048 0.001 (0) +[14C](4) 1.649e-15 + H[14C]O3- 1.332e-15 1.218e-15 -14.876 -14.914 -0.039 (0) + [14C]O2 2.772e-16 2.777e-16 -15.557 -15.556 0.001 (0) + CaH[14C]O3+ 2.813e-17 2.581e-17 -16.551 -16.588 -0.037 (0) + H[14C]O2[18O]- 2.657e-18 2.431e-18 -17.576 -17.614 -0.039 (0) + H[14C]O[18O]O- 2.657e-18 2.431e-18 -17.576 -17.614 -0.039 (0) + H[14C][18O]O2- 2.657e-18 2.431e-18 -17.576 -17.614 -0.039 (0) + Ca[14C]O3 1.542e-18 1.544e-18 -17.812 -17.811 0.001 (0) + [14C]O[18O] 1.153e-18 1.155e-18 -17.938 -17.938 0.001 (0) + [14C]O3-2 7.902e-19 5.539e-19 -18.102 -18.257 -0.154 (0) + CaH[14C]O2[18O]+ 5.613e-20 5.149e-20 -19.251 -19.288 -0.037 (0) + CaH[14C]O[18O]O+ 5.613e-20 5.149e-20 -19.251 -19.288 -0.037 (0) + CaH[14C][18O]O2+ 5.613e-20 5.149e-20 -19.251 -19.288 -0.037 (0) + Ca[14C]O2[18O] 9.229e-21 9.244e-21 -20.035 -20.034 0.001 (0) + H[14C]O[18O]2- 5.301e-21 4.850e-21 -20.276 -20.314 -0.039 (0) + H[14C][18O]2O- 5.301e-21 4.850e-21 -20.276 -20.314 -0.039 (0) + H[14C][18O]O[18O]- 5.301e-21 4.850e-21 -20.276 -20.314 -0.039 (0) + [14C]O2[18O]-2 4.730e-21 3.315e-21 -20.325 -20.479 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.892e-15 + O[18O] 2.886e-15 2.891e-15 -14.540 -14.539 0.001 (0) + [18O]2 2.879e-18 2.884e-18 -17.541 -17.540 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -33402,99 +33402,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.485 -126.484 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.105e-06 1.014e-06 -5.956 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.067e-08 6.077e-08 -7.217 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.120 -40.119 0.001 -O(0) 1.439e-12 - O2 7.165e-13 7.177e-13 -12.145 -12.144 0.001 - O[18O] 2.859e-15 2.864e-15 -14.544 -14.543 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.442 -128.442 0.001 -[13C](4) 6.488e-05 - H[13C]O3- 5.233e-05 4.788e-05 -4.281 -4.320 -0.039 - [13C]O2 1.099e-05 1.101e-05 -4.959 -4.958 0.001 - CaH[13C]O3+ 1.105e-06 1.014e-06 -5.956 -5.994 -0.037 - H[13C]O2[18O]- 1.044e-07 9.553e-08 -6.981 -7.020 -0.039 - H[13C]O[18O]O- 1.044e-07 9.553e-08 -6.981 -7.020 -0.039 - H[13C][18O]O2- 1.044e-07 9.553e-08 -6.981 -7.020 -0.039 - Ca[13C]O3 6.067e-08 6.077e-08 -7.217 -7.216 0.001 - [13C]O[18O] 4.569e-08 4.577e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.110e-08 2.180e-08 -7.507 -7.662 -0.154 - CaH[13C]O2[18O]+ 2.205e-09 2.023e-09 -8.656 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.205e-09 2.023e-09 -8.656 -8.694 -0.037 - CaH[13C][18O]O2+ 2.205e-09 2.023e-09 -8.656 -8.694 -0.037 - Ca[13C]O2[18O] 3.632e-10 3.638e-10 -9.440 -9.439 0.001 - H[13C]O[18O]2- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 - H[13C][18O]2O- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 - H[13C][18O]O[18O]- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 - [13C]O2[18O]-2 1.861e-10 1.305e-10 -9.730 -9.885 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.055 -139.055 0.001 -[14C](4) 1.593e-15 - H[14C]O3- 1.287e-15 1.178e-15 -14.890 -14.929 -0.039 - [14C]O2 2.679e-16 2.684e-16 -15.572 -15.571 0.001 - CaH[14C]O3+ 2.719e-17 2.494e-17 -16.566 -16.603 -0.037 - H[14C]O2[18O]- 2.568e-18 2.350e-18 -17.590 -17.629 -0.039 - H[14C]O[18O]O- 2.568e-18 2.350e-18 -17.590 -17.629 -0.039 - H[14C][18O]O2- 2.568e-18 2.350e-18 -17.590 -17.629 -0.039 - Ca[14C]O3 1.490e-18 1.493e-18 -17.827 -17.826 0.001 - [14C]O[18O] 1.114e-18 1.116e-18 -17.953 -17.952 0.001 - [14C]O3-2 7.637e-19 5.353e-19 -18.117 -18.271 -0.154 - CaH[14C]O2[18O]+ 5.424e-20 4.976e-20 -19.266 -19.303 -0.037 - CaH[14C]O[18O]O+ 5.424e-20 4.976e-20 -19.266 -19.303 -0.037 - CaH[14C][18O]O2+ 5.424e-20 4.976e-20 -19.266 -19.303 -0.037 - Ca[14C]O2[18O] 8.919e-21 8.934e-21 -20.050 -20.049 0.001 - H[14C]O[18O]2- 5.123e-21 4.688e-21 -20.290 -20.329 -0.039 - H[14C][18O]2O- 5.123e-21 4.688e-21 -20.290 -20.329 -0.039 - H[14C][18O]O[18O]- 5.123e-21 4.688e-21 -20.290 -20.329 -0.039 - [14C]O2[18O]-2 4.571e-21 3.204e-21 -20.340 -20.494 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 2.865e-15 - O[18O] 2.859e-15 2.864e-15 -14.544 -14.543 0.001 - [18O]2 2.852e-18 2.857e-18 -17.545 -17.544 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.485 -126.484 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.105e-06 1.014e-06 -5.956 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.067e-08 6.077e-08 -7.217 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.120 -40.119 0.001 (0) +O(0) 1.439e-12 + O2 7.165e-13 7.177e-13 -12.145 -12.144 0.001 (0) + O[18O] 2.859e-15 2.864e-15 -14.544 -14.543 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.442 -128.442 0.001 (0) +[13C](4) 6.488e-05 + H[13C]O3- 5.233e-05 4.788e-05 -4.281 -4.320 -0.039 (0) + [13C]O2 1.099e-05 1.101e-05 -4.959 -4.958 0.001 (0) + CaH[13C]O3+ 1.105e-06 1.014e-06 -5.956 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.044e-07 9.553e-08 -6.981 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.044e-07 9.553e-08 -6.981 -7.020 -0.039 (0) + H[13C][18O]O2- 1.044e-07 9.553e-08 -6.981 -7.020 -0.039 (0) + Ca[13C]O3 6.067e-08 6.077e-08 -7.217 -7.216 0.001 (0) + [13C]O[18O] 4.569e-08 4.577e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.110e-08 2.180e-08 -7.507 -7.662 -0.154 (0) + CaH[13C]O2[18O]+ 2.205e-09 2.023e-09 -8.656 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.205e-09 2.023e-09 -8.656 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.205e-09 2.023e-09 -8.656 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.632e-10 3.638e-10 -9.440 -9.439 0.001 (0) + H[13C]O[18O]2- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]2O- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.861e-10 1.305e-10 -9.730 -9.885 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.055 -139.055 0.001 (0) +[14C](4) 1.593e-15 + H[14C]O3- 1.287e-15 1.178e-15 -14.890 -14.929 -0.039 (0) + [14C]O2 2.679e-16 2.684e-16 -15.572 -15.571 0.001 (0) + CaH[14C]O3+ 2.719e-17 2.494e-17 -16.566 -16.603 -0.037 (0) + H[14C]O2[18O]- 2.568e-18 2.350e-18 -17.590 -17.629 -0.039 (0) + H[14C]O[18O]O- 2.568e-18 2.350e-18 -17.590 -17.629 -0.039 (0) + H[14C][18O]O2- 2.568e-18 2.350e-18 -17.590 -17.629 -0.039 (0) + Ca[14C]O3 1.490e-18 1.493e-18 -17.827 -17.826 0.001 (0) + [14C]O[18O] 1.114e-18 1.116e-18 -17.953 -17.952 0.001 (0) + [14C]O3-2 7.637e-19 5.353e-19 -18.117 -18.271 -0.154 (0) + CaH[14C]O2[18O]+ 5.424e-20 4.976e-20 -19.266 -19.303 -0.037 (0) + CaH[14C]O[18O]O+ 5.424e-20 4.976e-20 -19.266 -19.303 -0.037 (0) + CaH[14C][18O]O2+ 5.424e-20 4.976e-20 -19.266 -19.303 -0.037 (0) + Ca[14C]O2[18O] 8.919e-21 8.934e-21 -20.050 -20.049 0.001 (0) + H[14C]O[18O]2- 5.123e-21 4.688e-21 -20.290 -20.329 -0.039 (0) + H[14C][18O]2O- 5.123e-21 4.688e-21 -20.290 -20.329 -0.039 (0) + H[14C][18O]O[18O]- 5.123e-21 4.688e-21 -20.290 -20.329 -0.039 (0) + [14C]O2[18O]-2 4.571e-21 3.204e-21 -20.340 -20.494 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.865e-15 + O[18O] 2.859e-15 2.864e-15 -14.544 -14.543 0.001 (0) + [18O]2 2.852e-18 2.857e-18 -17.545 -17.544 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -33657,99 +33657,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.463 -126.462 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.106e-06 1.014e-06 -5.956 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.068e-08 6.078e-08 -7.217 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.114 -40.113 0.001 -O(0) 1.402e-12 - O2 6.983e-13 6.994e-13 -12.156 -12.155 0.001 - O[18O] 2.786e-15 2.791e-15 -14.555 -14.554 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.420 -128.419 0.001 -[13C](4) 6.489e-05 - H[13C]O3- 5.234e-05 4.789e-05 -4.281 -4.320 -0.039 - [13C]O2 1.099e-05 1.101e-05 -4.959 -4.958 0.001 - CaH[13C]O3+ 1.106e-06 1.014e-06 -5.956 -5.994 -0.037 - H[13C]O2[18O]- 1.044e-07 9.555e-08 -6.981 -7.020 -0.039 - H[13C]O[18O]O- 1.044e-07 9.555e-08 -6.981 -7.020 -0.039 - H[13C][18O]O2- 1.044e-07 9.555e-08 -6.981 -7.020 -0.039 - Ca[13C]O3 6.068e-08 6.078e-08 -7.217 -7.216 0.001 - [13C]O[18O] 4.570e-08 4.578e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.110e-08 2.180e-08 -7.507 -7.662 -0.154 - CaH[13C]O2[18O]+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 - CaH[13C][18O]O2+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 - Ca[13C]O2[18O] 3.632e-10 3.638e-10 -9.440 -9.439 0.001 - H[13C]O[18O]2- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 - H[13C][18O]2O- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 - H[13C][18O]O[18O]- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 - [13C]O2[18O]-2 1.862e-10 1.305e-10 -9.730 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.047 -139.047 0.001 -[14C](4) 1.542e-15 - H[14C]O3- 1.245e-15 1.139e-15 -14.905 -14.943 -0.039 - [14C]O2 2.592e-16 2.597e-16 -15.586 -15.586 0.001 - CaH[14C]O3+ 2.630e-17 2.413e-17 -16.580 -16.617 -0.037 - H[14C]O2[18O]- 2.484e-18 2.273e-18 -17.605 -17.643 -0.039 - H[14C]O[18O]O- 2.484e-18 2.273e-18 -17.605 -17.643 -0.039 - H[14C][18O]O2- 2.484e-18 2.273e-18 -17.605 -17.643 -0.039 - Ca[14C]O3 1.442e-18 1.444e-18 -17.841 -17.840 0.001 - [14C]O[18O] 1.078e-18 1.080e-18 -17.967 -17.967 0.001 - [14C]O3-2 7.389e-19 5.179e-19 -18.131 -18.286 -0.154 - CaH[14C]O2[18O]+ 5.248e-20 4.815e-20 -19.280 -19.317 -0.037 - CaH[14C]O[18O]O+ 5.248e-20 4.815e-20 -19.280 -19.317 -0.037 - CaH[14C][18O]O2+ 5.248e-20 4.815e-20 -19.280 -19.317 -0.037 - Ca[14C]O2[18O] 8.629e-21 8.644e-21 -20.064 -20.063 0.001 - H[14C]O[18O]2- 4.957e-21 4.536e-21 -20.305 -20.343 -0.039 - H[14C][18O]2O- 4.957e-21 4.536e-21 -20.305 -20.343 -0.039 - H[14C][18O]O[18O]- 4.957e-21 4.536e-21 -20.305 -20.343 -0.039 - [14C]O2[18O]-2 4.423e-21 3.100e-21 -20.354 -20.509 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 2.792e-15 - O[18O] 2.786e-15 2.791e-15 -14.555 -14.554 0.001 - [18O]2 2.780e-18 2.784e-18 -17.556 -17.555 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.463 -126.462 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.115e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.014e-06 -5.956 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.068e-08 6.078e-08 -7.217 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.114 -40.113 0.001 (0) +O(0) 1.402e-12 + O2 6.983e-13 6.994e-13 -12.156 -12.155 0.001 (0) + O[18O] 2.786e-15 2.791e-15 -14.555 -14.554 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.420 -128.419 0.001 (0) +[13C](4) 6.489e-05 + H[13C]O3- 5.234e-05 4.789e-05 -4.281 -4.320 -0.039 (0) + [13C]O2 1.099e-05 1.101e-05 -4.959 -4.958 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.014e-06 -5.956 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.044e-07 9.555e-08 -6.981 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.044e-07 9.555e-08 -6.981 -7.020 -0.039 (0) + H[13C][18O]O2- 1.044e-07 9.555e-08 -6.981 -7.020 -0.039 (0) + Ca[13C]O3 6.068e-08 6.078e-08 -7.217 -7.216 0.001 (0) + [13C]O[18O] 4.570e-08 4.578e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.110e-08 2.180e-08 -7.507 -7.662 -0.154 (0) + CaH[13C]O2[18O]+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.632e-10 3.638e-10 -9.440 -9.439 0.001 (0) + H[13C]O[18O]2- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]2O- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.083e-10 1.906e-10 -9.681 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.862e-10 1.305e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.047 -139.047 0.001 (0) +[14C](4) 1.542e-15 + H[14C]O3- 1.245e-15 1.139e-15 -14.905 -14.943 -0.039 (0) + [14C]O2 2.592e-16 2.597e-16 -15.586 -15.586 0.001 (0) + CaH[14C]O3+ 2.630e-17 2.413e-17 -16.580 -16.617 -0.037 (0) + H[14C]O2[18O]- 2.484e-18 2.273e-18 -17.605 -17.643 -0.039 (0) + H[14C]O[18O]O- 2.484e-18 2.273e-18 -17.605 -17.643 -0.039 (0) + H[14C][18O]O2- 2.484e-18 2.273e-18 -17.605 -17.643 -0.039 (0) + Ca[14C]O3 1.442e-18 1.444e-18 -17.841 -17.840 0.001 (0) + [14C]O[18O] 1.078e-18 1.080e-18 -17.967 -17.967 0.001 (0) + [14C]O3-2 7.389e-19 5.179e-19 -18.131 -18.286 -0.154 (0) + CaH[14C]O2[18O]+ 5.248e-20 4.815e-20 -19.280 -19.317 -0.037 (0) + CaH[14C]O[18O]O+ 5.248e-20 4.815e-20 -19.280 -19.317 -0.037 (0) + CaH[14C][18O]O2+ 5.248e-20 4.815e-20 -19.280 -19.317 -0.037 (0) + Ca[14C]O2[18O] 8.629e-21 8.644e-21 -20.064 -20.063 0.001 (0) + H[14C]O[18O]2- 4.957e-21 4.536e-21 -20.305 -20.343 -0.039 (0) + H[14C][18O]2O- 4.957e-21 4.536e-21 -20.305 -20.343 -0.039 (0) + H[14C][18O]O[18O]- 4.957e-21 4.536e-21 -20.305 -20.343 -0.039 (0) + [14C]O2[18O]-2 4.423e-21 3.100e-21 -20.354 -20.509 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.792e-15 + O[18O] 2.786e-15 2.791e-15 -14.555 -14.554 0.001 (0) + [18O]2 2.780e-18 2.784e-18 -17.556 -17.555 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -33912,99 +33912,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.452 -126.452 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.106e-06 1.014e-06 -5.956 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.069e-08 6.079e-08 -7.217 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.111 -40.111 0.001 -O(0) 1.385e-12 - O2 6.900e-13 6.911e-13 -12.161 -12.160 0.001 - O[18O] 2.753e-15 2.758e-15 -14.560 -14.559 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.409 -128.409 0.001 -[13C](4) 6.490e-05 - H[13C]O3- 5.234e-05 4.790e-05 -4.281 -4.320 -0.039 - [13C]O2 1.099e-05 1.101e-05 -4.959 -4.958 0.001 - CaH[13C]O3+ 1.106e-06 1.014e-06 -5.956 -5.994 -0.037 - H[13C]O2[18O]- 1.044e-07 9.556e-08 -6.981 -7.020 -0.039 - H[13C]O[18O]O- 1.044e-07 9.556e-08 -6.981 -7.020 -0.039 - H[13C][18O]O2- 1.044e-07 9.556e-08 -6.981 -7.020 -0.039 - Ca[13C]O3 6.069e-08 6.079e-08 -7.217 -7.216 0.001 - [13C]O[18O] 4.571e-08 4.578e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.111e-08 2.180e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 - CaH[13C][18O]O2+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 - Ca[13C]O2[18O] 3.633e-10 3.639e-10 -9.440 -9.439 0.001 - H[13C]O[18O]2- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 - H[13C][18O]2O- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 - H[13C][18O]O[18O]- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 - [13C]O2[18O]-2 1.862e-10 1.305e-10 -9.730 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.051 -139.050 0.001 -[14C](4) 1.493e-15 - H[14C]O3- 1.206e-15 1.104e-15 -14.919 -14.957 -0.039 - [14C]O2 2.511e-16 2.515e-16 -15.600 -15.599 0.001 - CaH[14C]O3+ 2.548e-17 2.337e-17 -16.594 -16.631 -0.037 - H[14C]O2[18O]- 2.406e-18 2.202e-18 -17.619 -17.657 -0.039 - H[14C]O[18O]O- 2.406e-18 2.202e-18 -17.619 -17.657 -0.039 - H[14C][18O]O2- 2.406e-18 2.202e-18 -17.619 -17.657 -0.039 - Ca[14C]O3 1.396e-18 1.399e-18 -17.855 -17.854 0.001 - [14C]O[18O] 1.044e-18 1.046e-18 -17.981 -17.981 0.001 - [14C]O3-2 7.157e-19 5.016e-19 -18.145 -18.300 -0.154 - CaH[14C]O2[18O]+ 5.083e-20 4.664e-20 -19.294 -19.331 -0.037 - CaH[14C]O[18O]O+ 5.083e-20 4.664e-20 -19.294 -19.331 -0.037 - CaH[14C][18O]O2+ 5.083e-20 4.664e-20 -19.294 -19.331 -0.037 - Ca[14C]O2[18O] 8.358e-21 8.372e-21 -20.078 -20.077 0.001 - H[14C]O[18O]2- 4.801e-21 4.393e-21 -20.319 -20.357 -0.039 - H[14C][18O]2O- 4.801e-21 4.393e-21 -20.319 -20.357 -0.039 - H[14C][18O]O[18O]- 4.801e-21 4.393e-21 -20.319 -20.357 -0.039 - [14C]O2[18O]-2 4.284e-21 3.003e-21 -20.368 -20.522 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 2.759e-15 - O[18O] 2.753e-15 2.758e-15 -14.560 -14.559 0.001 - [18O]2 2.747e-18 2.751e-18 -17.561 -17.560 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.452 -126.452 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.014e-06 -5.956 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.069e-08 6.079e-08 -7.217 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.111 -40.111 0.001 (0) +O(0) 1.385e-12 + O2 6.900e-13 6.911e-13 -12.161 -12.160 0.001 (0) + O[18O] 2.753e-15 2.758e-15 -14.560 -14.559 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.409 -128.409 0.001 (0) +[13C](4) 6.490e-05 + H[13C]O3- 5.234e-05 4.790e-05 -4.281 -4.320 -0.039 (0) + [13C]O2 1.099e-05 1.101e-05 -4.959 -4.958 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.014e-06 -5.956 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.044e-07 9.556e-08 -6.981 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.044e-07 9.556e-08 -6.981 -7.020 -0.039 (0) + H[13C][18O]O2- 1.044e-07 9.556e-08 -6.981 -7.020 -0.039 (0) + Ca[13C]O3 6.069e-08 6.079e-08 -7.217 -7.216 0.001 (0) + [13C]O[18O] 4.571e-08 4.578e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.111e-08 2.180e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.633e-10 3.639e-10 -9.440 -9.439 0.001 (0) + H[13C]O[18O]2- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]2O- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.862e-10 1.305e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.051 -139.050 0.001 (0) +[14C](4) 1.493e-15 + H[14C]O3- 1.206e-15 1.104e-15 -14.919 -14.957 -0.039 (0) + [14C]O2 2.511e-16 2.515e-16 -15.600 -15.599 0.001 (0) + CaH[14C]O3+ 2.548e-17 2.337e-17 -16.594 -16.631 -0.037 (0) + H[14C]O2[18O]- 2.406e-18 2.202e-18 -17.619 -17.657 -0.039 (0) + H[14C]O[18O]O- 2.406e-18 2.202e-18 -17.619 -17.657 -0.039 (0) + H[14C][18O]O2- 2.406e-18 2.202e-18 -17.619 -17.657 -0.039 (0) + Ca[14C]O3 1.396e-18 1.399e-18 -17.855 -17.854 0.001 (0) + [14C]O[18O] 1.044e-18 1.046e-18 -17.981 -17.981 0.001 (0) + [14C]O3-2 7.157e-19 5.016e-19 -18.145 -18.300 -0.154 (0) + CaH[14C]O2[18O]+ 5.083e-20 4.664e-20 -19.294 -19.331 -0.037 (0) + CaH[14C]O[18O]O+ 5.083e-20 4.664e-20 -19.294 -19.331 -0.037 (0) + CaH[14C][18O]O2+ 5.083e-20 4.664e-20 -19.294 -19.331 -0.037 (0) + Ca[14C]O2[18O] 8.358e-21 8.372e-21 -20.078 -20.077 0.001 (0) + H[14C]O[18O]2- 4.801e-21 4.393e-21 -20.319 -20.357 -0.039 (0) + H[14C][18O]2O- 4.801e-21 4.393e-21 -20.319 -20.357 -0.039 (0) + H[14C][18O]O[18O]- 4.801e-21 4.393e-21 -20.319 -20.357 -0.039 (0) + [14C]O2[18O]-2 4.284e-21 3.003e-21 -20.368 -20.522 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.759e-15 + O[18O] 2.753e-15 2.758e-15 -14.560 -14.559 0.001 (0) + [18O]2 2.747e-18 2.751e-18 -17.561 -17.560 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -34167,99 +34167,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.450 -126.450 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.070e-08 6.080e-08 -7.217 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.111 -40.110 0.001 -O(0) 1.382e-12 - O2 6.884e-13 6.895e-13 -12.162 -12.161 0.001 - O[18O] 2.747e-15 2.751e-15 -14.561 -14.560 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.407 -128.407 0.001 -[13C](4) 6.491e-05 - H[13C]O3- 5.235e-05 4.790e-05 -4.281 -4.320 -0.039 - [13C]O2 1.099e-05 1.101e-05 -4.959 -4.958 0.001 - CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 - H[13C]O2[18O]- 1.045e-07 9.557e-08 -6.981 -7.020 -0.039 - H[13C]O[18O]O- 1.045e-07 9.557e-08 -6.981 -7.020 -0.039 - H[13C][18O]O2- 1.045e-07 9.557e-08 -6.981 -7.020 -0.039 - Ca[13C]O3 6.070e-08 6.080e-08 -7.217 -7.216 0.001 - [13C]O[18O] 4.571e-08 4.579e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.111e-08 2.181e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 - CaH[13C][18O]O2+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 - Ca[13C]O2[18O] 3.633e-10 3.639e-10 -9.440 -9.439 0.001 - H[13C]O[18O]2- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 - H[13C][18O]2O- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 - H[13C][18O]O[18O]- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 - [13C]O2[18O]-2 1.862e-10 1.305e-10 -9.730 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.062 -139.062 0.001 -[14C](4) 1.448e-15 - H[14C]O3- 1.169e-15 1.070e-15 -14.932 -14.971 -0.039 - [14C]O2 2.434e-16 2.438e-16 -15.614 -15.613 0.001 - CaH[14C]O3+ 2.470e-17 2.266e-17 -16.607 -16.645 -0.037 - H[14C]O2[18O]- 2.333e-18 2.135e-18 -17.632 -17.671 -0.039 - H[14C]O[18O]O- 2.333e-18 2.135e-18 -17.632 -17.671 -0.039 - H[14C][18O]O2- 2.333e-18 2.135e-18 -17.632 -17.671 -0.039 - Ca[14C]O3 1.354e-18 1.356e-18 -17.868 -17.868 0.001 - [14C]O[18O] 1.012e-18 1.014e-18 -17.995 -17.994 0.001 - [14C]O3-2 6.939e-19 4.864e-19 -18.159 -18.313 -0.154 - CaH[14C]O2[18O]+ 4.928e-20 4.521e-20 -19.307 -19.345 -0.037 - CaH[14C]O[18O]O+ 4.928e-20 4.521e-20 -19.307 -19.345 -0.037 - CaH[14C][18O]O2+ 4.928e-20 4.521e-20 -19.307 -19.345 -0.037 - Ca[14C]O2[18O] 8.103e-21 8.117e-21 -20.091 -20.091 0.001 - H[14C]O[18O]2- 4.655e-21 4.259e-21 -20.332 -20.371 -0.039 - H[14C][18O]2O- 4.655e-21 4.259e-21 -20.332 -20.371 -0.039 - H[14C][18O]O[18O]- 4.655e-21 4.259e-21 -20.332 -20.371 -0.039 - [14C]O2[18O]-2 4.153e-21 2.911e-21 -20.382 -20.536 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 2.752e-15 - O[18O] 2.747e-15 2.751e-15 -14.561 -14.560 0.001 - [18O]2 2.740e-18 2.745e-18 -17.562 -17.561 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.450 -126.450 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.070e-08 6.080e-08 -7.217 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.111 -40.110 0.001 (0) +O(0) 1.382e-12 + O2 6.884e-13 6.895e-13 -12.162 -12.161 0.001 (0) + O[18O] 2.747e-15 2.751e-15 -14.561 -14.560 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.407 -128.407 0.001 (0) +[13C](4) 6.491e-05 + H[13C]O3- 5.235e-05 4.790e-05 -4.281 -4.320 -0.039 (0) + [13C]O2 1.099e-05 1.101e-05 -4.959 -4.958 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.045e-07 9.557e-08 -6.981 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.045e-07 9.557e-08 -6.981 -7.020 -0.039 (0) + H[13C][18O]O2- 1.045e-07 9.557e-08 -6.981 -7.020 -0.039 (0) + Ca[13C]O3 6.070e-08 6.080e-08 -7.217 -7.216 0.001 (0) + [13C]O[18O] 4.571e-08 4.579e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.111e-08 2.181e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.206e-09 2.024e-09 -8.656 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.633e-10 3.639e-10 -9.440 -9.439 0.001 (0) + H[13C]O[18O]2- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]2O- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.862e-10 1.305e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.062 -139.062 0.001 (0) +[14C](4) 1.448e-15 + H[14C]O3- 1.169e-15 1.070e-15 -14.932 -14.971 -0.039 (0) + [14C]O2 2.434e-16 2.438e-16 -15.614 -15.613 0.001 (0) + CaH[14C]O3+ 2.470e-17 2.266e-17 -16.607 -16.645 -0.037 (0) + H[14C]O2[18O]- 2.333e-18 2.135e-18 -17.632 -17.671 -0.039 (0) + H[14C]O[18O]O- 2.333e-18 2.135e-18 -17.632 -17.671 -0.039 (0) + H[14C][18O]O2- 2.333e-18 2.135e-18 -17.632 -17.671 -0.039 (0) + Ca[14C]O3 1.354e-18 1.356e-18 -17.868 -17.868 0.001 (0) + [14C]O[18O] 1.012e-18 1.014e-18 -17.995 -17.994 0.001 (0) + [14C]O3-2 6.939e-19 4.864e-19 -18.159 -18.313 -0.154 (0) + CaH[14C]O2[18O]+ 4.928e-20 4.521e-20 -19.307 -19.345 -0.037 (0) + CaH[14C]O[18O]O+ 4.928e-20 4.521e-20 -19.307 -19.345 -0.037 (0) + CaH[14C][18O]O2+ 4.928e-20 4.521e-20 -19.307 -19.345 -0.037 (0) + Ca[14C]O2[18O] 8.103e-21 8.117e-21 -20.091 -20.091 0.001 (0) + H[14C]O[18O]2- 4.655e-21 4.259e-21 -20.332 -20.371 -0.039 (0) + H[14C][18O]2O- 4.655e-21 4.259e-21 -20.332 -20.371 -0.039 (0) + H[14C][18O]O[18O]- 4.655e-21 4.259e-21 -20.332 -20.371 -0.039 (0) + [14C]O2[18O]-2 4.153e-21 2.911e-21 -20.382 -20.536 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.752e-15 + O[18O] 2.747e-15 2.751e-15 -14.561 -14.560 0.001 (0) + [18O]2 2.740e-18 2.745e-18 -17.562 -17.561 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -34422,99 +34422,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.452 -126.451 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.071e-08 6.081e-08 -7.217 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.111 -40.111 0.001 -O(0) 1.385e-12 - O2 6.899e-13 6.911e-13 -12.161 -12.160 0.001 - O[18O] 2.753e-15 2.758e-15 -14.560 -14.559 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.409 -128.409 0.001 -[13C](4) 6.492e-05 - H[13C]O3- 5.236e-05 4.791e-05 -4.281 -4.320 -0.039 - [13C]O2 1.099e-05 1.101e-05 -4.959 -4.958 0.001 - CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 - H[13C]O2[18O]- 1.045e-07 9.559e-08 -6.981 -7.020 -0.039 - H[13C]O[18O]O- 1.045e-07 9.559e-08 -6.981 -7.020 -0.039 - H[13C][18O]O2- 1.045e-07 9.559e-08 -6.981 -7.020 -0.039 - Ca[13C]O3 6.071e-08 6.081e-08 -7.217 -7.216 0.001 - [13C]O[18O] 4.572e-08 4.579e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.112e-08 2.181e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 - CaH[13C][18O]O2+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 - Ca[13C]O2[18O] 3.634e-10 3.640e-10 -9.440 -9.439 0.001 - H[13C]O[18O]2- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 - H[13C][18O]2O- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 - H[13C][18O]O[18O]- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 - [13C]O2[18O]-2 1.862e-10 1.305e-10 -9.730 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.077 -139.076 0.001 -[14C](4) 1.405e-15 - H[14C]O3- 1.135e-15 1.038e-15 -14.945 -14.984 -0.039 - [14C]O2 2.362e-16 2.366e-16 -15.627 -15.626 0.001 - CaH[14C]O3+ 2.397e-17 2.199e-17 -16.620 -16.658 -0.037 - H[14C]O2[18O]- 2.264e-18 2.072e-18 -17.645 -17.684 -0.039 - H[14C]O[18O]O- 2.264e-18 2.072e-18 -17.645 -17.684 -0.039 - H[14C][18O]O2- 2.264e-18 2.072e-18 -17.645 -17.684 -0.039 - Ca[14C]O3 1.314e-18 1.316e-18 -17.881 -17.881 0.001 - [14C]O[18O] 9.823e-19 9.839e-19 -18.008 -18.007 0.001 - [14C]O3-2 6.734e-19 4.720e-19 -18.172 -18.326 -0.154 - CaH[14C]O2[18O]+ 4.782e-20 4.388e-20 -19.320 -19.358 -0.037 - CaH[14C]O[18O]O+ 4.782e-20 4.388e-20 -19.320 -19.358 -0.037 - CaH[14C][18O]O2+ 4.782e-20 4.388e-20 -19.320 -19.358 -0.037 - Ca[14C]O2[18O] 7.864e-21 7.877e-21 -20.104 -20.104 0.001 - H[14C]O[18O]2- 4.517e-21 4.133e-21 -20.345 -20.384 -0.039 - H[14C][18O]2O- 4.517e-21 4.133e-21 -20.345 -20.384 -0.039 - H[14C][18O]O[18O]- 4.517e-21 4.133e-21 -20.345 -20.384 -0.039 - [14C]O2[18O]-2 4.030e-21 2.825e-21 -20.395 -20.549 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 2.759e-15 - O[18O] 2.753e-15 2.758e-15 -14.560 -14.559 0.001 - [18O]2 2.746e-18 2.751e-18 -17.561 -17.561 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.452 -126.451 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.071e-08 6.081e-08 -7.217 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.111 -40.111 0.001 (0) +O(0) 1.385e-12 + O2 6.899e-13 6.911e-13 -12.161 -12.160 0.001 (0) + O[18O] 2.753e-15 2.758e-15 -14.560 -14.559 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.409 -128.409 0.001 (0) +[13C](4) 6.492e-05 + H[13C]O3- 5.236e-05 4.791e-05 -4.281 -4.320 -0.039 (0) + [13C]O2 1.099e-05 1.101e-05 -4.959 -4.958 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.045e-07 9.559e-08 -6.981 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.045e-07 9.559e-08 -6.981 -7.020 -0.039 (0) + H[13C][18O]O2- 1.045e-07 9.559e-08 -6.981 -7.020 -0.039 (0) + Ca[13C]O3 6.071e-08 6.081e-08 -7.217 -7.216 0.001 (0) + [13C]O[18O] 4.572e-08 4.579e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.112e-08 2.181e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.634e-10 3.640e-10 -9.440 -9.439 0.001 (0) + H[13C]O[18O]2- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]2O- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.084e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.862e-10 1.305e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.077 -139.076 0.001 (0) +[14C](4) 1.405e-15 + H[14C]O3- 1.135e-15 1.038e-15 -14.945 -14.984 -0.039 (0) + [14C]O2 2.362e-16 2.366e-16 -15.627 -15.626 0.001 (0) + CaH[14C]O3+ 2.397e-17 2.199e-17 -16.620 -16.658 -0.037 (0) + H[14C]O2[18O]- 2.264e-18 2.072e-18 -17.645 -17.684 -0.039 (0) + H[14C]O[18O]O- 2.264e-18 2.072e-18 -17.645 -17.684 -0.039 (0) + H[14C][18O]O2- 2.264e-18 2.072e-18 -17.645 -17.684 -0.039 (0) + Ca[14C]O3 1.314e-18 1.316e-18 -17.881 -17.881 0.001 (0) + [14C]O[18O] 9.823e-19 9.839e-19 -18.008 -18.007 0.001 (0) + [14C]O3-2 6.734e-19 4.720e-19 -18.172 -18.326 -0.154 (0) + CaH[14C]O2[18O]+ 4.782e-20 4.388e-20 -19.320 -19.358 -0.037 (0) + CaH[14C]O[18O]O+ 4.782e-20 4.388e-20 -19.320 -19.358 -0.037 (0) + CaH[14C][18O]O2+ 4.782e-20 4.388e-20 -19.320 -19.358 -0.037 (0) + Ca[14C]O2[18O] 7.864e-21 7.877e-21 -20.104 -20.104 0.001 (0) + H[14C]O[18O]2- 4.517e-21 4.133e-21 -20.345 -20.384 -0.039 (0) + H[14C][18O]2O- 4.517e-21 4.133e-21 -20.345 -20.384 -0.039 (0) + H[14C][18O]O[18O]- 4.517e-21 4.133e-21 -20.345 -20.384 -0.039 (0) + [14C]O2[18O]-2 4.030e-21 2.825e-21 -20.395 -20.549 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.759e-15 + O[18O] 2.753e-15 2.758e-15 -14.560 -14.559 0.001 (0) + [18O]2 2.746e-18 2.751e-18 -17.561 -17.561 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -34677,99 +34677,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.447 -126.446 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.072e-08 6.082e-08 -7.217 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.110 -40.109 0.001 -O(0) 1.377e-12 - O2 6.856e-13 6.867e-13 -12.164 -12.163 0.001 - O[18O] 2.736e-15 2.740e-15 -14.563 -14.562 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.404 -128.403 0.001 -[13C](4) 6.493e-05 - H[13C]O3- 5.237e-05 4.791e-05 -4.281 -4.320 -0.039 - [13C]O2 1.100e-05 1.101e-05 -4.959 -4.958 0.001 - CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 - H[13C]O2[18O]- 1.045e-07 9.560e-08 -6.981 -7.020 -0.039 - H[13C]O[18O]O- 1.045e-07 9.560e-08 -6.981 -7.020 -0.039 - H[13C][18O]O2- 1.045e-07 9.560e-08 -6.981 -7.020 -0.039 - Ca[13C]O3 6.072e-08 6.082e-08 -7.217 -7.216 0.001 - [13C]O[18O] 4.572e-08 4.580e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.112e-08 2.181e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 - CaH[13C][18O]O2+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 - Ca[13C]O2[18O] 3.634e-10 3.640e-10 -9.440 -9.439 0.001 - H[13C]O[18O]2- 2.085e-10 1.907e-10 -9.681 -9.720 -0.039 - H[13C][18O]2O- 2.085e-10 1.907e-10 -9.681 -9.720 -0.039 - H[13C][18O]O[18O]- 2.085e-10 1.907e-10 -9.681 -9.720 -0.039 - [13C]O2[18O]-2 1.863e-10 1.306e-10 -9.730 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.084 -139.084 0.001 -[14C](4) 1.364e-15 - H[14C]O3- 1.102e-15 1.008e-15 -14.958 -14.996 -0.039 - [14C]O2 2.294e-16 2.298e-16 -15.639 -15.639 0.001 - CaH[14C]O3+ 2.328e-17 2.136e-17 -16.633 -16.670 -0.037 - H[14C]O2[18O]- 2.199e-18 2.012e-18 -17.658 -17.696 -0.039 - H[14C]O[18O]O- 2.199e-18 2.012e-18 -17.658 -17.696 -0.039 - H[14C][18O]O2- 2.199e-18 2.012e-18 -17.658 -17.696 -0.039 - Ca[14C]O3 1.276e-18 1.278e-18 -17.894 -17.893 0.001 - [14C]O[18O] 9.541e-19 9.556e-19 -18.020 -18.020 0.001 - [14C]O3-2 6.540e-19 4.584e-19 -18.184 -18.339 -0.154 - CaH[14C]O2[18O]+ 4.645e-20 4.262e-20 -19.333 -19.370 -0.037 - CaH[14C]O[18O]O+ 4.645e-20 4.262e-20 -19.333 -19.370 -0.037 - CaH[14C][18O]O2+ 4.645e-20 4.262e-20 -19.333 -19.370 -0.037 - Ca[14C]O2[18O] 7.638e-21 7.650e-21 -20.117 -20.116 0.001 - H[14C]O[18O]2- 4.387e-21 4.014e-21 -20.358 -20.396 -0.039 - H[14C][18O]2O- 4.387e-21 4.014e-21 -20.358 -20.396 -0.039 - H[14C][18O]O[18O]- 4.387e-21 4.014e-21 -20.358 -20.396 -0.039 - [14C]O2[18O]-2 3.915e-21 2.744e-21 -20.407 -20.562 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 2.741e-15 - O[18O] 2.736e-15 2.740e-15 -14.563 -14.562 0.001 - [18O]2 2.729e-18 2.734e-18 -17.564 -17.563 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.447 -126.446 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.072e-08 6.082e-08 -7.217 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.110 -40.109 0.001 (0) +O(0) 1.377e-12 + O2 6.856e-13 6.867e-13 -12.164 -12.163 0.001 (0) + O[18O] 2.736e-15 2.740e-15 -14.563 -14.562 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.404 -128.403 0.001 (0) +[13C](4) 6.493e-05 + H[13C]O3- 5.237e-05 4.791e-05 -4.281 -4.320 -0.039 (0) + [13C]O2 1.100e-05 1.101e-05 -4.959 -4.958 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.045e-07 9.560e-08 -6.981 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.045e-07 9.560e-08 -6.981 -7.020 -0.039 (0) + H[13C][18O]O2- 1.045e-07 9.560e-08 -6.981 -7.020 -0.039 (0) + Ca[13C]O3 6.072e-08 6.082e-08 -7.217 -7.216 0.001 (0) + [13C]O[18O] 4.572e-08 4.580e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.112e-08 2.181e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.634e-10 3.640e-10 -9.440 -9.439 0.001 (0) + H[13C]O[18O]2- 2.085e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]2O- 2.085e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.085e-10 1.907e-10 -9.681 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.863e-10 1.306e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.084 -139.084 0.001 (0) +[14C](4) 1.364e-15 + H[14C]O3- 1.102e-15 1.008e-15 -14.958 -14.996 -0.039 (0) + [14C]O2 2.294e-16 2.298e-16 -15.639 -15.639 0.001 (0) + CaH[14C]O3+ 2.328e-17 2.136e-17 -16.633 -16.670 -0.037 (0) + H[14C]O2[18O]- 2.199e-18 2.012e-18 -17.658 -17.696 -0.039 (0) + H[14C]O[18O]O- 2.199e-18 2.012e-18 -17.658 -17.696 -0.039 (0) + H[14C][18O]O2- 2.199e-18 2.012e-18 -17.658 -17.696 -0.039 (0) + Ca[14C]O3 1.276e-18 1.278e-18 -17.894 -17.893 0.001 (0) + [14C]O[18O] 9.541e-19 9.556e-19 -18.020 -18.020 0.001 (0) + [14C]O3-2 6.540e-19 4.584e-19 -18.184 -18.339 -0.154 (0) + CaH[14C]O2[18O]+ 4.645e-20 4.262e-20 -19.333 -19.370 -0.037 (0) + CaH[14C]O[18O]O+ 4.645e-20 4.262e-20 -19.333 -19.370 -0.037 (0) + CaH[14C][18O]O2+ 4.645e-20 4.262e-20 -19.333 -19.370 -0.037 (0) + Ca[14C]O2[18O] 7.638e-21 7.650e-21 -20.117 -20.116 0.001 (0) + H[14C]O[18O]2- 4.387e-21 4.014e-21 -20.358 -20.396 -0.039 (0) + H[14C][18O]2O- 4.387e-21 4.014e-21 -20.358 -20.396 -0.039 (0) + H[14C][18O]O[18O]- 4.387e-21 4.014e-21 -20.358 -20.396 -0.039 (0) + [14C]O2[18O]-2 3.915e-21 2.744e-21 -20.407 -20.562 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.741e-15 + O[18O] 2.736e-15 2.740e-15 -14.563 -14.562 0.001 (0) + [18O]2 2.729e-18 2.734e-18 -17.564 -17.563 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -34932,99 +34932,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.451 -126.450 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.072e-08 6.082e-08 -7.217 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.111 -40.110 0.001 -O(0) 1.383e-12 - O2 6.889e-13 6.900e-13 -12.162 -12.161 0.001 - O[18O] 2.749e-15 2.753e-15 -14.561 -14.560 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.408 -128.407 0.001 -[13C](4) 6.493e-05 - H[13C]O3- 5.237e-05 4.792e-05 -4.281 -4.319 -0.039 - [13C]O2 1.100e-05 1.102e-05 -4.959 -4.958 0.001 - CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 - H[13C]O2[18O]- 1.045e-07 9.561e-08 -6.981 -7.020 -0.039 - H[13C]O[18O]O- 1.045e-07 9.561e-08 -6.981 -7.020 -0.039 - H[13C][18O]O2- 1.045e-07 9.561e-08 -6.981 -7.020 -0.039 - Ca[13C]O3 6.072e-08 6.082e-08 -7.217 -7.216 0.001 - [13C]O[18O] 4.573e-08 4.581e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.112e-08 2.181e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 - CaH[13C][18O]O2+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 - Ca[13C]O2[18O] 3.635e-10 3.641e-10 -9.440 -9.439 0.001 - H[13C]O[18O]2- 2.085e-10 1.908e-10 -9.681 -9.720 -0.039 - H[13C][18O]2O- 2.085e-10 1.908e-10 -9.681 -9.720 -0.039 - H[13C][18O]O[18O]- 2.085e-10 1.908e-10 -9.681 -9.720 -0.039 - [13C]O2[18O]-2 1.863e-10 1.306e-10 -9.730 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.101 -139.100 0.001 -[14C](4) 1.326e-15 - H[14C]O3- 1.071e-15 9.803e-16 -14.970 -15.009 -0.039 - [14C]O2 2.230e-16 2.234e-16 -15.652 -15.651 0.001 - CaH[14C]O3+ 2.263e-17 2.076e-17 -16.645 -16.683 -0.037 - H[14C]O2[18O]- 2.138e-18 1.956e-18 -17.670 -17.709 -0.039 - H[14C]O[18O]O- 2.138e-18 1.956e-18 -17.670 -17.709 -0.039 - H[14C][18O]O2- 2.138e-18 1.956e-18 -17.670 -17.709 -0.039 - Ca[14C]O3 1.240e-18 1.242e-18 -17.906 -17.906 0.001 - [14C]O[18O] 9.274e-19 9.289e-19 -18.033 -18.032 0.001 - [14C]O3-2 6.357e-19 4.456e-19 -18.197 -18.351 -0.154 - CaH[14C]O2[18O]+ 4.515e-20 4.143e-20 -19.345 -19.383 -0.037 - CaH[14C]O[18O]O+ 4.515e-20 4.143e-20 -19.345 -19.383 -0.037 - CaH[14C][18O]O2+ 4.515e-20 4.143e-20 -19.345 -19.383 -0.037 - Ca[14C]O2[18O] 7.424e-21 7.437e-21 -20.129 -20.129 0.001 - H[14C]O[18O]2- 4.265e-21 3.902e-21 -20.370 -20.409 -0.039 - H[14C][18O]2O- 4.265e-21 3.902e-21 -20.370 -20.409 -0.039 - H[14C][18O]O[18O]- 4.265e-21 3.902e-21 -20.370 -20.409 -0.039 - [14C]O2[18O]-2 3.805e-21 2.667e-21 -20.420 -20.574 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 -[18O](0) 2.754e-15 - O[18O] 2.749e-15 2.753e-15 -14.561 -14.560 0.001 - [18O]2 2.742e-18 2.747e-18 -17.562 -17.561 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.451 -126.450 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.962e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.072e-08 6.082e-08 -7.217 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.111 -40.110 0.001 (0) +O(0) 1.383e-12 + O2 6.889e-13 6.900e-13 -12.162 -12.161 0.001 (0) + O[18O] 2.749e-15 2.753e-15 -14.561 -14.560 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.408 -128.407 0.001 (0) +[13C](4) 6.493e-05 + H[13C]O3- 5.237e-05 4.792e-05 -4.281 -4.319 -0.039 (0) + [13C]O2 1.100e-05 1.102e-05 -4.959 -4.958 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.994 -0.037 (0) + H[13C]O2[18O]- 1.045e-07 9.561e-08 -6.981 -7.020 -0.039 (0) + H[13C]O[18O]O- 1.045e-07 9.561e-08 -6.981 -7.020 -0.039 (0) + H[13C][18O]O2- 1.045e-07 9.561e-08 -6.981 -7.020 -0.039 (0) + Ca[13C]O3 6.072e-08 6.082e-08 -7.217 -7.216 0.001 (0) + [13C]O[18O] 4.573e-08 4.581e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.112e-08 2.181e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.207e-09 2.025e-09 -8.656 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.635e-10 3.641e-10 -9.440 -9.439 0.001 (0) + H[13C]O[18O]2- 2.085e-10 1.908e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]2O- 2.085e-10 1.908e-10 -9.681 -9.720 -0.039 (0) + H[13C][18O]O[18O]- 2.085e-10 1.908e-10 -9.681 -9.720 -0.039 (0) + [13C]O2[18O]-2 1.863e-10 1.306e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.101 -139.100 0.001 (0) +[14C](4) 1.326e-15 + H[14C]O3- 1.071e-15 9.803e-16 -14.970 -15.009 -0.039 (0) + [14C]O2 2.230e-16 2.234e-16 -15.652 -15.651 0.001 (0) + CaH[14C]O3+ 2.263e-17 2.076e-17 -16.645 -16.683 -0.037 (0) + H[14C]O2[18O]- 2.138e-18 1.956e-18 -17.670 -17.709 -0.039 (0) + H[14C]O[18O]O- 2.138e-18 1.956e-18 -17.670 -17.709 -0.039 (0) + H[14C][18O]O2- 2.138e-18 1.956e-18 -17.670 -17.709 -0.039 (0) + Ca[14C]O3 1.240e-18 1.242e-18 -17.906 -17.906 0.001 (0) + [14C]O[18O] 9.274e-19 9.289e-19 -18.033 -18.032 0.001 (0) + [14C]O3-2 6.357e-19 4.456e-19 -18.197 -18.351 -0.154 (0) + CaH[14C]O2[18O]+ 4.515e-20 4.143e-20 -19.345 -19.383 -0.037 (0) + CaH[14C]O[18O]O+ 4.515e-20 4.143e-20 -19.345 -19.383 -0.037 (0) + CaH[14C][18O]O2+ 4.515e-20 4.143e-20 -19.345 -19.383 -0.037 (0) + Ca[14C]O2[18O] 7.424e-21 7.437e-21 -20.129 -20.129 0.001 (0) + H[14C]O[18O]2- 4.265e-21 3.902e-21 -20.370 -20.409 -0.039 (0) + H[14C][18O]2O- 4.265e-21 3.902e-21 -20.370 -20.409 -0.039 (0) + H[14C][18O]O[18O]- 4.265e-21 3.902e-21 -20.370 -20.409 -0.039 (0) + [14C]O2[18O]-2 3.805e-21 2.667e-21 -20.420 -20.574 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.819e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.754e-15 + O[18O] 2.749e-15 2.753e-15 -14.561 -14.560 0.001 (0) + [18O]2 2.742e-18 2.747e-18 -17.562 -17.561 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -35187,99 +35187,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.433 -126.432 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.073e-08 6.083e-08 -7.217 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.107 -40.106 0.001 -O(0) 1.355e-12 - O2 6.748e-13 6.759e-13 -12.171 -12.170 0.001 - O[18O] 2.693e-15 2.697e-15 -14.570 -14.569 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.390 -128.389 0.001 -[13C](4) 6.494e-05 - H[13C]O3- 5.238e-05 4.792e-05 -4.281 -4.319 -0.039 - [13C]O2 1.100e-05 1.102e-05 -4.959 -4.958 0.001 - CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.045e-07 9.562e-08 -6.981 -7.019 -0.039 - H[13C]O[18O]O- 1.045e-07 9.562e-08 -6.981 -7.019 -0.039 - H[13C][18O]O2- 1.045e-07 9.562e-08 -6.981 -7.019 -0.039 - Ca[13C]O3 6.073e-08 6.083e-08 -7.217 -7.216 0.001 - [13C]O[18O] 4.574e-08 4.581e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.113e-08 2.182e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.208e-09 2.025e-09 -8.656 -8.694 -0.037 - CaH[13C]O[18O]O+ 2.208e-09 2.025e-09 -8.656 -8.694 -0.037 - CaH[13C][18O]O2+ 2.208e-09 2.025e-09 -8.656 -8.694 -0.037 - Ca[13C]O2[18O] 3.635e-10 3.641e-10 -9.439 -9.439 0.001 - H[13C]O[18O]2- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 - H[13C][18O]2O- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 - H[13C][18O]O[18O]- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 - [13C]O2[18O]-2 1.863e-10 1.306e-10 -9.730 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.095 -139.094 0.001 -[14C](4) 1.290e-15 - H[14C]O3- 1.042e-15 9.536e-16 -14.982 -15.021 -0.039 - [14C]O2 2.170e-16 2.173e-16 -15.664 -15.663 0.001 - CaH[14C]O3+ 2.202e-17 2.020e-17 -16.657 -16.695 -0.037 - H[14C]O2[18O]- 2.079e-18 1.903e-18 -17.682 -17.721 -0.039 - H[14C]O[18O]O- 2.079e-18 1.903e-18 -17.682 -17.721 -0.039 - H[14C][18O]O2- 2.079e-18 1.903e-18 -17.682 -17.721 -0.039 - Ca[14C]O3 1.207e-18 1.209e-18 -17.918 -17.918 0.001 - [14C]O[18O] 9.022e-19 9.037e-19 -18.045 -18.044 0.001 - [14C]O3-2 6.185e-19 4.335e-19 -18.209 -18.363 -0.154 - CaH[14C]O2[18O]+ 4.393e-20 4.030e-20 -19.357 -19.395 -0.037 - CaH[14C]O[18O]O+ 4.393e-20 4.030e-20 -19.357 -19.395 -0.037 - CaH[14C][18O]O2+ 4.393e-20 4.030e-20 -19.357 -19.395 -0.037 - Ca[14C]O2[18O] 7.223e-21 7.235e-21 -20.141 -20.141 0.001 - H[14C]O[18O]2- 4.149e-21 3.796e-21 -20.382 -20.421 -0.039 - H[14C][18O]2O- 4.149e-21 3.796e-21 -20.382 -20.421 -0.039 - H[14C][18O]O[18O]- 4.149e-21 3.796e-21 -20.382 -20.421 -0.039 - [14C]O2[18O]-2 3.702e-21 2.595e-21 -20.432 -20.586 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.698e-15 - O[18O] 2.693e-15 2.697e-15 -14.570 -14.569 0.001 - [18O]2 2.686e-18 2.690e-18 -17.571 -17.570 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.433 -126.432 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.073e-08 6.083e-08 -7.217 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.107 -40.106 0.001 (0) +O(0) 1.355e-12 + O2 6.748e-13 6.759e-13 -12.171 -12.170 0.001 (0) + O[18O] 2.693e-15 2.697e-15 -14.570 -14.569 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.390 -128.389 0.001 (0) +[13C](4) 6.494e-05 + H[13C]O3- 5.238e-05 4.792e-05 -4.281 -4.319 -0.039 (0) + [13C]O2 1.100e-05 1.102e-05 -4.959 -4.958 0.001 (0) + CaH[13C]O3+ 1.106e-06 1.015e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.045e-07 9.562e-08 -6.981 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.045e-07 9.562e-08 -6.981 -7.019 -0.039 (0) + H[13C][18O]O2- 1.045e-07 9.562e-08 -6.981 -7.019 -0.039 (0) + Ca[13C]O3 6.073e-08 6.083e-08 -7.217 -7.216 0.001 (0) + [13C]O[18O] 4.574e-08 4.581e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.113e-08 2.182e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.208e-09 2.025e-09 -8.656 -8.694 -0.037 (0) + CaH[13C]O[18O]O+ 2.208e-09 2.025e-09 -8.656 -8.694 -0.037 (0) + CaH[13C][18O]O2+ 2.208e-09 2.025e-09 -8.656 -8.694 -0.037 (0) + Ca[13C]O2[18O] 3.635e-10 3.641e-10 -9.439 -9.439 0.001 (0) + H[13C]O[18O]2- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]2O- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.863e-10 1.306e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.095 -139.094 0.001 (0) +[14C](4) 1.290e-15 + H[14C]O3- 1.042e-15 9.536e-16 -14.982 -15.021 -0.039 (0) + [14C]O2 2.170e-16 2.173e-16 -15.664 -15.663 0.001 (0) + CaH[14C]O3+ 2.202e-17 2.020e-17 -16.657 -16.695 -0.037 (0) + H[14C]O2[18O]- 2.079e-18 1.903e-18 -17.682 -17.721 -0.039 (0) + H[14C]O[18O]O- 2.079e-18 1.903e-18 -17.682 -17.721 -0.039 (0) + H[14C][18O]O2- 2.079e-18 1.903e-18 -17.682 -17.721 -0.039 (0) + Ca[14C]O3 1.207e-18 1.209e-18 -17.918 -17.918 0.001 (0) + [14C]O[18O] 9.022e-19 9.037e-19 -18.045 -18.044 0.001 (0) + [14C]O3-2 6.185e-19 4.335e-19 -18.209 -18.363 -0.154 (0) + CaH[14C]O2[18O]+ 4.393e-20 4.030e-20 -19.357 -19.395 -0.037 (0) + CaH[14C]O[18O]O+ 4.393e-20 4.030e-20 -19.357 -19.395 -0.037 (0) + CaH[14C][18O]O2+ 4.393e-20 4.030e-20 -19.357 -19.395 -0.037 (0) + Ca[14C]O2[18O] 7.223e-21 7.235e-21 -20.141 -20.141 0.001 (0) + H[14C]O[18O]2- 4.149e-21 3.796e-21 -20.382 -20.421 -0.039 (0) + H[14C][18O]2O- 4.149e-21 3.796e-21 -20.382 -20.421 -0.039 (0) + H[14C][18O]O[18O]- 4.149e-21 3.796e-21 -20.382 -20.421 -0.039 (0) + [14C]O2[18O]-2 3.702e-21 2.595e-21 -20.432 -20.586 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.698e-15 + O[18O] 2.693e-15 2.697e-15 -14.570 -14.569 0.001 (0) + [18O]2 2.686e-18 2.690e-18 -17.571 -17.570 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -35442,99 +35442,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.415 -126.414 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.074e-08 6.084e-08 -7.217 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.102 -40.101 0.001 -O(0) 1.327e-12 - O2 6.608e-13 6.619e-13 -12.180 -12.179 0.001 - O[18O] 2.637e-15 2.641e-15 -14.579 -14.578 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.372 -128.371 0.001 -[13C](4) 6.495e-05 - H[13C]O3- 5.238e-05 4.793e-05 -4.281 -4.319 -0.039 - [13C]O2 1.100e-05 1.102e-05 -4.959 -4.958 0.001 - CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.045e-07 9.563e-08 -6.981 -7.019 -0.039 - H[13C]O[18O]O- 1.045e-07 9.563e-08 -6.981 -7.019 -0.039 - H[13C][18O]O2- 1.045e-07 9.563e-08 -6.981 -7.019 -0.039 - Ca[13C]O3 6.074e-08 6.084e-08 -7.217 -7.216 0.001 - [13C]O[18O] 4.574e-08 4.582e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.113e-08 2.182e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.208e-09 2.025e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.208e-09 2.025e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.208e-09 2.025e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.635e-10 3.641e-10 -9.439 -9.439 0.001 - H[13C]O[18O]2- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 - H[13C][18O]2O- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 - H[13C][18O]O[18O]- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 - [13C]O2[18O]-2 1.863e-10 1.306e-10 -9.730 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.088 -139.088 0.001 -[14C](4) 1.256e-15 - H[14C]O3- 1.015e-15 9.284e-16 -14.994 -15.032 -0.039 - [14C]O2 2.112e-16 2.116e-16 -15.675 -15.675 0.001 - CaH[14C]O3+ 2.143e-17 1.966e-17 -16.669 -16.706 -0.037 - H[14C]O2[18O]- 2.024e-18 1.852e-18 -17.694 -17.732 -0.039 - H[14C]O[18O]O- 2.024e-18 1.852e-18 -17.694 -17.732 -0.039 - H[14C][18O]O2- 2.024e-18 1.852e-18 -17.694 -17.732 -0.039 - Ca[14C]O3 1.175e-18 1.177e-18 -17.930 -17.929 0.001 - [14C]O[18O] 8.784e-19 8.798e-19 -18.056 -18.056 0.001 - [14C]O3-2 6.021e-19 4.220e-19 -18.220 -18.375 -0.154 - CaH[14C]O2[18O]+ 4.276e-20 3.923e-20 -19.369 -19.406 -0.037 - CaH[14C]O[18O]O+ 4.276e-20 3.923e-20 -19.369 -19.406 -0.037 - CaH[14C][18O]O2+ 4.276e-20 3.923e-20 -19.369 -19.406 -0.037 - Ca[14C]O2[18O] 7.032e-21 7.043e-21 -20.153 -20.152 0.001 - H[14C]O[18O]2- 4.039e-21 3.696e-21 -20.394 -20.432 -0.039 - H[14C][18O]2O- 4.039e-21 3.696e-21 -20.394 -20.432 -0.039 - H[14C][18O]O[18O]- 4.039e-21 3.696e-21 -20.394 -20.432 -0.039 - [14C]O2[18O]-2 3.604e-21 2.526e-21 -20.443 -20.598 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.642e-15 - O[18O] 2.637e-15 2.641e-15 -14.579 -14.578 0.001 - [18O]2 2.630e-18 2.635e-18 -17.580 -17.579 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.415 -126.414 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.074e-08 6.084e-08 -7.217 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.102 -40.101 0.001 (0) +O(0) 1.327e-12 + O2 6.608e-13 6.619e-13 -12.180 -12.179 0.001 (0) + O[18O] 2.637e-15 2.641e-15 -14.579 -14.578 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.372 -128.371 0.001 (0) +[13C](4) 6.495e-05 + H[13C]O3- 5.238e-05 4.793e-05 -4.281 -4.319 -0.039 (0) + [13C]O2 1.100e-05 1.102e-05 -4.959 -4.958 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.045e-07 9.563e-08 -6.981 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.045e-07 9.563e-08 -6.981 -7.019 -0.039 (0) + H[13C][18O]O2- 1.045e-07 9.563e-08 -6.981 -7.019 -0.039 (0) + Ca[13C]O3 6.074e-08 6.084e-08 -7.217 -7.216 0.001 (0) + [13C]O[18O] 4.574e-08 4.582e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.113e-08 2.182e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.208e-09 2.025e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.208e-09 2.025e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.208e-09 2.025e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.635e-10 3.641e-10 -9.439 -9.439 0.001 (0) + H[13C]O[18O]2- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]2O- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.863e-10 1.306e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.088 -139.088 0.001 (0) +[14C](4) 1.256e-15 + H[14C]O3- 1.015e-15 9.284e-16 -14.994 -15.032 -0.039 (0) + [14C]O2 2.112e-16 2.116e-16 -15.675 -15.675 0.001 (0) + CaH[14C]O3+ 2.143e-17 1.966e-17 -16.669 -16.706 -0.037 (0) + H[14C]O2[18O]- 2.024e-18 1.852e-18 -17.694 -17.732 -0.039 (0) + H[14C]O[18O]O- 2.024e-18 1.852e-18 -17.694 -17.732 -0.039 (0) + H[14C][18O]O2- 2.024e-18 1.852e-18 -17.694 -17.732 -0.039 (0) + Ca[14C]O3 1.175e-18 1.177e-18 -17.930 -17.929 0.001 (0) + [14C]O[18O] 8.784e-19 8.798e-19 -18.056 -18.056 0.001 (0) + [14C]O3-2 6.021e-19 4.220e-19 -18.220 -18.375 -0.154 (0) + CaH[14C]O2[18O]+ 4.276e-20 3.923e-20 -19.369 -19.406 -0.037 (0) + CaH[14C]O[18O]O+ 4.276e-20 3.923e-20 -19.369 -19.406 -0.037 (0) + CaH[14C][18O]O2+ 4.276e-20 3.923e-20 -19.369 -19.406 -0.037 (0) + Ca[14C]O2[18O] 7.032e-21 7.043e-21 -20.153 -20.152 0.001 (0) + H[14C]O[18O]2- 4.039e-21 3.696e-21 -20.394 -20.432 -0.039 (0) + H[14C][18O]2O- 4.039e-21 3.696e-21 -20.394 -20.432 -0.039 (0) + H[14C][18O]O[18O]- 4.039e-21 3.696e-21 -20.394 -20.432 -0.039 (0) + [14C]O2[18O]-2 3.604e-21 2.526e-21 -20.443 -20.598 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.642e-15 + O[18O] 2.637e-15 2.641e-15 -14.579 -14.578 0.001 (0) + [18O]2 2.630e-18 2.635e-18 -17.580 -17.579 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -35697,99 +35697,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.414 -126.413 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.074e-08 6.084e-08 -7.217 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.102 -40.101 0.001 -O(0) 1.326e-12 - O2 6.603e-13 6.614e-13 -12.180 -12.180 0.001 - O[18O] 2.635e-15 2.639e-15 -14.579 -14.579 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.371 -128.370 0.001 -[13C](4) 6.495e-05 - H[13C]O3- 5.239e-05 4.793e-05 -4.281 -4.319 -0.039 - [13C]O2 1.100e-05 1.102e-05 -4.959 -4.958 0.001 - CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.045e-07 9.564e-08 -6.981 -7.019 -0.039 - H[13C]O[18O]O- 1.045e-07 9.564e-08 -6.981 -7.019 -0.039 - H[13C][18O]O2- 1.045e-07 9.564e-08 -6.981 -7.019 -0.039 - Ca[13C]O3 6.074e-08 6.084e-08 -7.217 -7.216 0.001 - [13C]O[18O] 4.574e-08 4.582e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.113e-08 2.182e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.636e-10 3.642e-10 -9.439 -9.439 0.001 - H[13C]O[18O]2- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 - H[13C][18O]2O- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 - H[13C][18O]O[18O]- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 - [13C]O2[18O]-2 1.863e-10 1.306e-10 -9.730 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.099 -139.098 0.001 -[14C](4) 1.224e-15 - H[14C]O3- 9.885e-16 9.045e-16 -15.005 -15.044 -0.039 - [14C]O2 2.058e-16 2.061e-16 -15.687 -15.686 0.001 - CaH[14C]O3+ 2.088e-17 1.916e-17 -16.680 -16.718 -0.037 - H[14C]O2[18O]- 1.972e-18 1.805e-18 -17.705 -17.744 -0.039 - H[14C]O[18O]O- 1.972e-18 1.805e-18 -17.705 -17.744 -0.039 - H[14C][18O]O2- 1.972e-18 1.805e-18 -17.705 -17.744 -0.039 - Ca[14C]O3 1.144e-18 1.146e-18 -17.941 -17.941 0.001 - [14C]O[18O] 8.557e-19 8.571e-19 -18.068 -18.067 0.001 - [14C]O3-2 5.866e-19 4.112e-19 -18.232 -18.386 -0.154 - CaH[14C]O2[18O]+ 4.166e-20 3.822e-20 -19.380 -19.418 -0.037 - CaH[14C]O[18O]O+ 4.166e-20 3.822e-20 -19.380 -19.418 -0.037 - CaH[14C][18O]O2+ 4.166e-20 3.822e-20 -19.380 -19.418 -0.037 - Ca[14C]O2[18O] 6.850e-21 6.862e-21 -20.164 -20.164 0.001 - H[14C]O[18O]2- 3.935e-21 3.601e-21 -20.405 -20.444 -0.039 - H[14C][18O]2O- 3.935e-21 3.601e-21 -20.405 -20.444 -0.039 - H[14C][18O]O[18O]- 3.935e-21 3.601e-21 -20.405 -20.444 -0.039 - [14C]O2[18O]-2 3.511e-21 2.461e-21 -20.455 -20.609 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.640e-15 - O[18O] 2.635e-15 2.639e-15 -14.579 -14.579 0.001 - [18O]2 2.629e-18 2.633e-18 -17.580 -17.580 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.414 -126.413 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.074e-08 6.084e-08 -7.217 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.102 -40.101 0.001 (0) +O(0) 1.326e-12 + O2 6.603e-13 6.614e-13 -12.180 -12.180 0.001 (0) + O[18O] 2.635e-15 2.639e-15 -14.579 -14.579 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.371 -128.370 0.001 (0) +[13C](4) 6.495e-05 + H[13C]O3- 5.239e-05 4.793e-05 -4.281 -4.319 -0.039 (0) + [13C]O2 1.100e-05 1.102e-05 -4.959 -4.958 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.045e-07 9.564e-08 -6.981 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.045e-07 9.564e-08 -6.981 -7.019 -0.039 (0) + H[13C][18O]O2- 1.045e-07 9.564e-08 -6.981 -7.019 -0.039 (0) + Ca[13C]O3 6.074e-08 6.084e-08 -7.217 -7.216 0.001 (0) + [13C]O[18O] 4.574e-08 4.582e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.113e-08 2.182e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.636e-10 3.642e-10 -9.439 -9.439 0.001 (0) + H[13C]O[18O]2- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]2O- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.085e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.863e-10 1.306e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.099 -139.098 0.001 (0) +[14C](4) 1.224e-15 + H[14C]O3- 9.885e-16 9.045e-16 -15.005 -15.044 -0.039 (0) + [14C]O2 2.058e-16 2.061e-16 -15.687 -15.686 0.001 (0) + CaH[14C]O3+ 2.088e-17 1.916e-17 -16.680 -16.718 -0.037 (0) + H[14C]O2[18O]- 1.972e-18 1.805e-18 -17.705 -17.744 -0.039 (0) + H[14C]O[18O]O- 1.972e-18 1.805e-18 -17.705 -17.744 -0.039 (0) + H[14C][18O]O2- 1.972e-18 1.805e-18 -17.705 -17.744 -0.039 (0) + Ca[14C]O3 1.144e-18 1.146e-18 -17.941 -17.941 0.001 (0) + [14C]O[18O] 8.557e-19 8.571e-19 -18.068 -18.067 0.001 (0) + [14C]O3-2 5.866e-19 4.112e-19 -18.232 -18.386 -0.154 (0) + CaH[14C]O2[18O]+ 4.166e-20 3.822e-20 -19.380 -19.418 -0.037 (0) + CaH[14C]O[18O]O+ 4.166e-20 3.822e-20 -19.380 -19.418 -0.037 (0) + CaH[14C][18O]O2+ 4.166e-20 3.822e-20 -19.380 -19.418 -0.037 (0) + Ca[14C]O2[18O] 6.850e-21 6.862e-21 -20.164 -20.164 0.001 (0) + H[14C]O[18O]2- 3.935e-21 3.601e-21 -20.405 -20.444 -0.039 (0) + H[14C][18O]2O- 3.935e-21 3.601e-21 -20.405 -20.444 -0.039 (0) + H[14C][18O]O[18O]- 3.935e-21 3.601e-21 -20.405 -20.444 -0.039 (0) + [14C]O2[18O]-2 3.511e-21 2.461e-21 -20.455 -20.609 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.640e-15 + O[18O] 2.635e-15 2.639e-15 -14.579 -14.579 0.001 (0) + [18O]2 2.629e-18 2.633e-18 -17.580 -17.580 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -35952,99 +35952,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.410 -126.410 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.075e-08 6.085e-08 -7.216 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.101 -40.100 0.001 -O(0) 1.320e-12 - O2 6.575e-13 6.586e-13 -12.182 -12.181 0.001 - O[18O] 2.624e-15 2.628e-15 -14.581 -14.580 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.367 -128.367 0.001 -[13C](4) 6.496e-05 - H[13C]O3- 5.239e-05 4.794e-05 -4.281 -4.319 -0.039 - [13C]O2 1.100e-05 1.102e-05 -4.959 -4.958 0.001 - CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.045e-07 9.565e-08 -6.981 -7.019 -0.039 - H[13C]O[18O]O- 1.045e-07 9.565e-08 -6.981 -7.019 -0.039 - H[13C][18O]O2- 1.045e-07 9.565e-08 -6.981 -7.019 -0.039 - Ca[13C]O3 6.075e-08 6.085e-08 -7.216 -7.216 0.001 - [13C]O[18O] 4.575e-08 4.582e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.114e-08 2.182e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.636e-10 3.642e-10 -9.439 -9.439 0.001 - H[13C]O[18O]2- 2.086e-10 1.908e-10 -9.681 -9.719 -0.039 - H[13C][18O]2O- 2.086e-10 1.908e-10 -9.681 -9.719 -0.039 - H[13C][18O]O[18O]- 2.086e-10 1.908e-10 -9.681 -9.719 -0.039 - [13C]O2[18O]-2 1.864e-10 1.306e-10 -9.730 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.106 -139.106 0.001 -[14C](4) 1.193e-15 - H[14C]O3- 9.637e-16 8.818e-16 -15.016 -15.055 -0.039 - [14C]O2 2.006e-16 2.009e-16 -15.698 -15.697 0.001 - CaH[14C]O3+ 2.036e-17 1.868e-17 -16.691 -16.729 -0.037 - H[14C]O2[18O]- 1.923e-18 1.759e-18 -17.716 -17.755 -0.039 - H[14C]O[18O]O- 1.923e-18 1.759e-18 -17.716 -17.755 -0.039 - H[14C][18O]O2- 1.923e-18 1.759e-18 -17.716 -17.755 -0.039 - Ca[14C]O3 1.116e-18 1.118e-18 -17.952 -17.952 0.001 - [14C]O[18O] 8.342e-19 8.356e-19 -18.079 -18.078 0.001 - [14C]O3-2 5.719e-19 4.008e-19 -18.243 -18.397 -0.154 - CaH[14C]O2[18O]+ 4.062e-20 3.726e-20 -19.391 -19.429 -0.037 - CaH[14C]O[18O]O+ 4.062e-20 3.726e-20 -19.391 -19.429 -0.037 - CaH[14C][18O]O2+ 4.062e-20 3.726e-20 -19.391 -19.429 -0.037 - Ca[14C]O2[18O] 6.678e-21 6.689e-21 -20.175 -20.175 0.001 - H[14C]O[18O]2- 3.836e-21 3.510e-21 -20.416 -20.455 -0.039 - H[14C][18O]2O- 3.836e-21 3.510e-21 -20.416 -20.455 -0.039 - H[14C][18O]O[18O]- 3.836e-21 3.510e-21 -20.416 -20.455 -0.039 - [14C]O2[18O]-2 3.423e-21 2.399e-21 -20.466 -20.620 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.629e-15 - O[18O] 2.624e-15 2.628e-15 -14.581 -14.580 0.001 - [18O]2 2.617e-18 2.622e-18 -17.582 -17.581 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.410 -126.410 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.075e-08 6.085e-08 -7.216 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.101 -40.100 0.001 (0) +O(0) 1.320e-12 + O2 6.575e-13 6.586e-13 -12.182 -12.181 0.001 (0) + O[18O] 2.624e-15 2.628e-15 -14.581 -14.580 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.367 -128.367 0.001 (0) +[13C](4) 6.496e-05 + H[13C]O3- 5.239e-05 4.794e-05 -4.281 -4.319 -0.039 (0) + [13C]O2 1.100e-05 1.102e-05 -4.959 -4.958 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.045e-07 9.565e-08 -6.981 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.045e-07 9.565e-08 -6.981 -7.019 -0.039 (0) + H[13C][18O]O2- 1.045e-07 9.565e-08 -6.981 -7.019 -0.039 (0) + Ca[13C]O3 6.075e-08 6.085e-08 -7.216 -7.216 0.001 (0) + [13C]O[18O] 4.575e-08 4.582e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.114e-08 2.182e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.636e-10 3.642e-10 -9.439 -9.439 0.001 (0) + H[13C]O[18O]2- 2.086e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]2O- 2.086e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.086e-10 1.908e-10 -9.681 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.864e-10 1.306e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.106 -139.106 0.001 (0) +[14C](4) 1.193e-15 + H[14C]O3- 9.637e-16 8.818e-16 -15.016 -15.055 -0.039 (0) + [14C]O2 2.006e-16 2.009e-16 -15.698 -15.697 0.001 (0) + CaH[14C]O3+ 2.036e-17 1.868e-17 -16.691 -16.729 -0.037 (0) + H[14C]O2[18O]- 1.923e-18 1.759e-18 -17.716 -17.755 -0.039 (0) + H[14C]O[18O]O- 1.923e-18 1.759e-18 -17.716 -17.755 -0.039 (0) + H[14C][18O]O2- 1.923e-18 1.759e-18 -17.716 -17.755 -0.039 (0) + Ca[14C]O3 1.116e-18 1.118e-18 -17.952 -17.952 0.001 (0) + [14C]O[18O] 8.342e-19 8.356e-19 -18.079 -18.078 0.001 (0) + [14C]O3-2 5.719e-19 4.008e-19 -18.243 -18.397 -0.154 (0) + CaH[14C]O2[18O]+ 4.062e-20 3.726e-20 -19.391 -19.429 -0.037 (0) + CaH[14C]O[18O]O+ 4.062e-20 3.726e-20 -19.391 -19.429 -0.037 (0) + CaH[14C][18O]O2+ 4.062e-20 3.726e-20 -19.391 -19.429 -0.037 (0) + Ca[14C]O2[18O] 6.678e-21 6.689e-21 -20.175 -20.175 0.001 (0) + H[14C]O[18O]2- 3.836e-21 3.510e-21 -20.416 -20.455 -0.039 (0) + H[14C][18O]2O- 3.836e-21 3.510e-21 -20.416 -20.455 -0.039 (0) + H[14C][18O]O[18O]- 3.836e-21 3.510e-21 -20.416 -20.455 -0.039 (0) + [14C]O2[18O]-2 3.423e-21 2.399e-21 -20.466 -20.620 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.629e-15 + O[18O] 2.624e-15 2.628e-15 -14.581 -14.580 0.001 (0) + [18O]2 2.617e-18 2.622e-18 -17.582 -17.581 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -36207,99 +36207,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.418 -126.418 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.075e-08 6.085e-08 -7.216 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.103 -40.102 0.001 -O(0) 1.333e-12 - O2 6.636e-13 6.647e-13 -12.178 -12.177 0.001 - O[18O] 2.648e-15 2.652e-15 -14.577 -14.576 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.375 -128.375 0.001 -[13C](4) 6.497e-05 - H[13C]O3- 5.240e-05 4.794e-05 -4.281 -4.319 -0.039 - [13C]O2 1.100e-05 1.102e-05 -4.958 -4.958 0.001 - CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.045e-07 9.566e-08 -6.981 -7.019 -0.039 - H[13C]O[18O]O- 1.045e-07 9.566e-08 -6.981 -7.019 -0.039 - H[13C][18O]O2- 1.045e-07 9.566e-08 -6.981 -7.019 -0.039 - Ca[13C]O3 6.075e-08 6.085e-08 -7.216 -7.216 0.001 - [13C]O[18O] 4.575e-08 4.583e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.114e-08 2.183e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.636e-10 3.642e-10 -9.439 -9.439 0.001 - H[13C]O[18O]2- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]2O- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]O[18O]- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - [13C]O2[18O]-2 1.864e-10 1.306e-10 -9.730 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.125 -139.124 0.001 -[14C](4) 1.164e-15 - H[14C]O3- 9.401e-16 8.602e-16 -15.027 -15.065 -0.039 - [14C]O2 1.957e-16 1.960e-16 -15.708 -15.708 0.001 - CaH[14C]O3+ 1.986e-17 1.822e-17 -16.702 -16.739 -0.037 - H[14C]O2[18O]- 1.876e-18 1.716e-18 -17.727 -17.765 -0.039 - H[14C]O[18O]O- 1.876e-18 1.716e-18 -17.727 -17.765 -0.039 - H[14C][18O]O2- 1.876e-18 1.716e-18 -17.727 -17.765 -0.039 - Ca[14C]O3 1.088e-18 1.090e-18 -17.963 -17.962 0.001 - [14C]O[18O] 8.138e-19 8.151e-19 -18.089 -18.089 0.001 - [14C]O3-2 5.578e-19 3.910e-19 -18.253 -18.408 -0.154 - CaH[14C]O2[18O]+ 3.962e-20 3.635e-20 -19.402 -19.439 -0.037 - CaH[14C]O[18O]O+ 3.962e-20 3.635e-20 -19.402 -19.439 -0.037 - CaH[14C][18O]O2+ 3.962e-20 3.635e-20 -19.402 -19.439 -0.037 - Ca[14C]O2[18O] 6.515e-21 6.525e-21 -20.186 -20.185 0.001 - H[14C]O[18O]2- 3.742e-21 3.424e-21 -20.427 -20.465 -0.039 - H[14C][18O]2O- 3.742e-21 3.424e-21 -20.427 -20.465 -0.039 - H[14C][18O]O[18O]- 3.742e-21 3.424e-21 -20.427 -20.465 -0.039 - [14C]O2[18O]-2 3.339e-21 2.340e-21 -20.476 -20.631 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.653e-15 - O[18O] 2.648e-15 2.652e-15 -14.577 -14.576 0.001 - [18O]2 2.642e-18 2.646e-18 -17.578 -17.577 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.418 -126.418 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.075e-08 6.085e-08 -7.216 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.103 -40.102 0.001 (0) +O(0) 1.333e-12 + O2 6.636e-13 6.647e-13 -12.178 -12.177 0.001 (0) + O[18O] 2.648e-15 2.652e-15 -14.577 -14.576 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.375 -128.375 0.001 (0) +[13C](4) 6.497e-05 + H[13C]O3- 5.240e-05 4.794e-05 -4.281 -4.319 -0.039 (0) + [13C]O2 1.100e-05 1.102e-05 -4.958 -4.958 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.015e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.045e-07 9.566e-08 -6.981 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.045e-07 9.566e-08 -6.981 -7.019 -0.039 (0) + H[13C][18O]O2- 1.045e-07 9.566e-08 -6.981 -7.019 -0.039 (0) + Ca[13C]O3 6.075e-08 6.085e-08 -7.216 -7.216 0.001 (0) + [13C]O[18O] 4.575e-08 4.583e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.114e-08 2.183e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.208e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.636e-10 3.642e-10 -9.439 -9.439 0.001 (0) + H[13C]O[18O]2- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]2O- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.864e-10 1.306e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.125 -139.124 0.001 (0) +[14C](4) 1.164e-15 + H[14C]O3- 9.401e-16 8.602e-16 -15.027 -15.065 -0.039 (0) + [14C]O2 1.957e-16 1.960e-16 -15.708 -15.708 0.001 (0) + CaH[14C]O3+ 1.986e-17 1.822e-17 -16.702 -16.739 -0.037 (0) + H[14C]O2[18O]- 1.876e-18 1.716e-18 -17.727 -17.765 -0.039 (0) + H[14C]O[18O]O- 1.876e-18 1.716e-18 -17.727 -17.765 -0.039 (0) + H[14C][18O]O2- 1.876e-18 1.716e-18 -17.727 -17.765 -0.039 (0) + Ca[14C]O3 1.088e-18 1.090e-18 -17.963 -17.962 0.001 (0) + [14C]O[18O] 8.138e-19 8.151e-19 -18.089 -18.089 0.001 (0) + [14C]O3-2 5.578e-19 3.910e-19 -18.253 -18.408 -0.154 (0) + CaH[14C]O2[18O]+ 3.962e-20 3.635e-20 -19.402 -19.439 -0.037 (0) + CaH[14C]O[18O]O+ 3.962e-20 3.635e-20 -19.402 -19.439 -0.037 (0) + CaH[14C][18O]O2+ 3.962e-20 3.635e-20 -19.402 -19.439 -0.037 (0) + Ca[14C]O2[18O] 6.515e-21 6.525e-21 -20.186 -20.185 0.001 (0) + H[14C]O[18O]2- 3.742e-21 3.424e-21 -20.427 -20.465 -0.039 (0) + H[14C][18O]2O- 3.742e-21 3.424e-21 -20.427 -20.465 -0.039 (0) + H[14C][18O]O[18O]- 3.742e-21 3.424e-21 -20.427 -20.465 -0.039 (0) + [14C]O2[18O]-2 3.339e-21 2.340e-21 -20.476 -20.631 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.653e-15 + O[18O] 2.648e-15 2.652e-15 -14.577 -14.576 0.001 (0) + [18O]2 2.642e-18 2.646e-18 -17.578 -17.577 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -36462,99 +36462,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.423 -126.422 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.076e-08 6.086e-08 -7.216 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.104 -40.103 0.001 -O(0) 1.340e-12 - O2 6.671e-13 6.682e-13 -12.176 -12.175 0.001 - O[18O] 2.662e-15 2.666e-15 -14.575 -14.574 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.380 -128.379 0.001 -[13C](4) 6.497e-05 - H[13C]O3- 5.240e-05 4.795e-05 -4.281 -4.319 -0.039 - [13C]O2 1.100e-05 1.102e-05 -4.958 -4.958 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.566e-08 -6.981 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.566e-08 -6.981 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.566e-08 -6.981 -7.019 -0.039 - Ca[13C]O3 6.076e-08 6.086e-08 -7.216 -7.216 0.001 - [13C]O[18O] 4.576e-08 4.583e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.114e-08 2.183e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.209e-09 2.026e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.209e-09 2.026e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.209e-09 2.026e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.637e-10 3.643e-10 -9.439 -9.439 0.001 - H[13C]O[18O]2- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]2O- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]O[18O]- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - [13C]O2[18O]-2 1.864e-10 1.306e-10 -9.730 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.140 -139.140 0.001 -[14C](4) 1.136e-15 - H[14C]O3- 9.176e-16 8.396e-16 -15.037 -15.076 -0.039 - [14C]O2 1.910e-16 1.913e-16 -15.719 -15.718 0.001 - CaH[14C]O3+ 1.938e-17 1.778e-17 -16.713 -16.750 -0.037 - H[14C]O2[18O]- 1.831e-18 1.675e-18 -17.737 -17.776 -0.039 - H[14C]O[18O]O- 1.831e-18 1.675e-18 -17.737 -17.776 -0.039 - H[14C][18O]O2- 1.831e-18 1.675e-18 -17.737 -17.776 -0.039 - Ca[14C]O3 1.062e-18 1.064e-18 -17.974 -17.973 0.001 - [14C]O[18O] 7.943e-19 7.956e-19 -18.100 -18.099 0.001 - [14C]O3-2 5.445e-19 3.817e-19 -18.264 -18.418 -0.154 - CaH[14C]O2[18O]+ 3.867e-20 3.548e-20 -19.413 -19.450 -0.037 - CaH[14C]O[18O]O+ 3.867e-20 3.548e-20 -19.413 -19.450 -0.037 - CaH[14C][18O]O2+ 3.867e-20 3.548e-20 -19.413 -19.450 -0.037 - Ca[14C]O2[18O] 6.359e-21 6.369e-21 -20.197 -20.196 0.001 - H[14C]O[18O]2- 3.653e-21 3.342e-21 -20.437 -20.476 -0.039 - H[14C][18O]2O- 3.653e-21 3.342e-21 -20.437 -20.476 -0.039 - H[14C][18O]O[18O]- 3.653e-21 3.342e-21 -20.437 -20.476 -0.039 - [14C]O2[18O]-2 3.259e-21 2.284e-21 -20.487 -20.641 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.667e-15 - O[18O] 2.662e-15 2.666e-15 -14.575 -14.574 0.001 - [18O]2 2.656e-18 2.660e-18 -17.576 -17.575 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.423 -126.422 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.076e-08 6.086e-08 -7.216 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.104 -40.103 0.001 (0) +O(0) 1.340e-12 + O2 6.671e-13 6.682e-13 -12.176 -12.175 0.001 (0) + O[18O] 2.662e-15 2.666e-15 -14.575 -14.574 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.380 -128.379 0.001 (0) +[13C](4) 6.497e-05 + H[13C]O3- 5.240e-05 4.795e-05 -4.281 -4.319 -0.039 (0) + [13C]O2 1.100e-05 1.102e-05 -4.958 -4.958 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.566e-08 -6.981 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.566e-08 -6.981 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.566e-08 -6.981 -7.019 -0.039 (0) + Ca[13C]O3 6.076e-08 6.086e-08 -7.216 -7.216 0.001 (0) + [13C]O[18O] 4.576e-08 4.583e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.114e-08 2.183e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.209e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.209e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.209e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.637e-10 3.643e-10 -9.439 -9.439 0.001 (0) + H[13C]O[18O]2- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]2O- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.864e-10 1.306e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.140 -139.140 0.001 (0) +[14C](4) 1.136e-15 + H[14C]O3- 9.176e-16 8.396e-16 -15.037 -15.076 -0.039 (0) + [14C]O2 1.910e-16 1.913e-16 -15.719 -15.718 0.001 (0) + CaH[14C]O3+ 1.938e-17 1.778e-17 -16.713 -16.750 -0.037 (0) + H[14C]O2[18O]- 1.831e-18 1.675e-18 -17.737 -17.776 -0.039 (0) + H[14C]O[18O]O- 1.831e-18 1.675e-18 -17.737 -17.776 -0.039 (0) + H[14C][18O]O2- 1.831e-18 1.675e-18 -17.737 -17.776 -0.039 (0) + Ca[14C]O3 1.062e-18 1.064e-18 -17.974 -17.973 0.001 (0) + [14C]O[18O] 7.943e-19 7.956e-19 -18.100 -18.099 0.001 (0) + [14C]O3-2 5.445e-19 3.817e-19 -18.264 -18.418 -0.154 (0) + CaH[14C]O2[18O]+ 3.867e-20 3.548e-20 -19.413 -19.450 -0.037 (0) + CaH[14C]O[18O]O+ 3.867e-20 3.548e-20 -19.413 -19.450 -0.037 (0) + CaH[14C][18O]O2+ 3.867e-20 3.548e-20 -19.413 -19.450 -0.037 (0) + Ca[14C]O2[18O] 6.359e-21 6.369e-21 -20.197 -20.196 0.001 (0) + H[14C]O[18O]2- 3.653e-21 3.342e-21 -20.437 -20.476 -0.039 (0) + H[14C][18O]2O- 3.653e-21 3.342e-21 -20.437 -20.476 -0.039 (0) + H[14C][18O]O[18O]- 3.653e-21 3.342e-21 -20.437 -20.476 -0.039 (0) + [14C]O2[18O]-2 3.259e-21 2.284e-21 -20.487 -20.641 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.667e-15 + O[18O] 2.662e-15 2.666e-15 -14.575 -14.574 0.001 (0) + [18O]2 2.656e-18 2.660e-18 -17.576 -17.575 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -36717,99 +36717,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.416 -126.415 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.076e-08 6.086e-08 -7.216 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.102 -40.102 0.001 -O(0) 1.329e-12 - O2 6.619e-13 6.629e-13 -12.179 -12.179 0.001 - O[18O] 2.641e-15 2.645e-15 -14.578 -14.578 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.373 -128.372 0.001 -[13C](4) 6.498e-05 - H[13C]O3- 5.241e-05 4.795e-05 -4.281 -4.319 -0.039 - [13C]O2 1.100e-05 1.102e-05 -4.958 -4.958 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.567e-08 -6.981 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.567e-08 -6.981 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.567e-08 -6.981 -7.019 -0.039 - Ca[13C]O3 6.076e-08 6.086e-08 -7.216 -7.216 0.001 - [13C]O[18O] 4.576e-08 4.584e-08 -7.340 -7.339 0.001 - [13C]O3-2 3.114e-08 2.183e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.209e-09 2.026e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.209e-09 2.026e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.209e-09 2.026e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.637e-10 3.643e-10 -9.439 -9.439 0.001 - H[13C]O[18O]2- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]2O- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]O[18O]- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - [13C]O2[18O]-2 1.864e-10 1.307e-10 -9.730 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.144 -139.143 0.001 -[14C](4) 1.109e-15 - H[14C]O3- 8.961e-16 8.200e-16 -15.048 -15.086 -0.039 - [14C]O2 1.866e-16 1.869e-16 -15.729 -15.728 0.001 - CaH[14C]O3+ 1.893e-17 1.737e-17 -16.723 -16.760 -0.037 - H[14C]O2[18O]- 1.788e-18 1.636e-18 -17.748 -17.786 -0.039 - H[14C]O[18O]O- 1.788e-18 1.636e-18 -17.748 -17.786 -0.039 - H[14C][18O]O2- 1.788e-18 1.636e-18 -17.748 -17.786 -0.039 - Ca[14C]O3 1.038e-18 1.039e-18 -17.984 -17.983 0.001 - [14C]O[18O] 7.758e-19 7.770e-19 -18.110 -18.110 0.001 - [14C]O3-2 5.318e-19 3.727e-19 -18.274 -18.429 -0.154 - CaH[14C]O2[18O]+ 3.777e-20 3.465e-20 -19.423 -19.460 -0.037 - CaH[14C]O[18O]O+ 3.777e-20 3.465e-20 -19.423 -19.460 -0.037 - CaH[14C][18O]O2+ 3.777e-20 3.465e-20 -19.423 -19.460 -0.037 - Ca[14C]O2[18O] 6.210e-21 6.221e-21 -20.207 -20.206 0.001 - H[14C]O[18O]2- 3.567e-21 3.264e-21 -20.448 -20.486 -0.039 - H[14C][18O]2O- 3.567e-21 3.264e-21 -20.448 -20.486 -0.039 - H[14C][18O]O[18O]- 3.567e-21 3.264e-21 -20.448 -20.486 -0.039 - [14C]O2[18O]-2 3.183e-21 2.231e-21 -20.497 -20.651 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.646e-15 - O[18O] 2.641e-15 2.645e-15 -14.578 -14.578 0.001 - [18O]2 2.635e-18 2.639e-18 -17.579 -17.579 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.416 -126.415 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.076e-08 6.086e-08 -7.216 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.102 -40.102 0.001 (0) +O(0) 1.329e-12 + O2 6.619e-13 6.629e-13 -12.179 -12.179 0.001 (0) + O[18O] 2.641e-15 2.645e-15 -14.578 -14.578 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.373 -128.372 0.001 (0) +[13C](4) 6.498e-05 + H[13C]O3- 5.241e-05 4.795e-05 -4.281 -4.319 -0.039 (0) + [13C]O2 1.100e-05 1.102e-05 -4.958 -4.958 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.567e-08 -6.981 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.567e-08 -6.981 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.567e-08 -6.981 -7.019 -0.039 (0) + Ca[13C]O3 6.076e-08 6.086e-08 -7.216 -7.216 0.001 (0) + [13C]O[18O] 4.576e-08 4.584e-08 -7.340 -7.339 0.001 (0) + [13C]O3-2 3.114e-08 2.183e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.209e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.209e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.209e-09 2.026e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.637e-10 3.643e-10 -9.439 -9.439 0.001 (0) + H[13C]O[18O]2- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]2O- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.864e-10 1.307e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.144 -139.143 0.001 (0) +[14C](4) 1.109e-15 + H[14C]O3- 8.961e-16 8.200e-16 -15.048 -15.086 -0.039 (0) + [14C]O2 1.866e-16 1.869e-16 -15.729 -15.728 0.001 (0) + CaH[14C]O3+ 1.893e-17 1.737e-17 -16.723 -16.760 -0.037 (0) + H[14C]O2[18O]- 1.788e-18 1.636e-18 -17.748 -17.786 -0.039 (0) + H[14C]O[18O]O- 1.788e-18 1.636e-18 -17.748 -17.786 -0.039 (0) + H[14C][18O]O2- 1.788e-18 1.636e-18 -17.748 -17.786 -0.039 (0) + Ca[14C]O3 1.038e-18 1.039e-18 -17.984 -17.983 0.001 (0) + [14C]O[18O] 7.758e-19 7.770e-19 -18.110 -18.110 0.001 (0) + [14C]O3-2 5.318e-19 3.727e-19 -18.274 -18.429 -0.154 (0) + CaH[14C]O2[18O]+ 3.777e-20 3.465e-20 -19.423 -19.460 -0.037 (0) + CaH[14C]O[18O]O+ 3.777e-20 3.465e-20 -19.423 -19.460 -0.037 (0) + CaH[14C][18O]O2+ 3.777e-20 3.465e-20 -19.423 -19.460 -0.037 (0) + Ca[14C]O2[18O] 6.210e-21 6.221e-21 -20.207 -20.206 0.001 (0) + H[14C]O[18O]2- 3.567e-21 3.264e-21 -20.448 -20.486 -0.039 (0) + H[14C][18O]2O- 3.567e-21 3.264e-21 -20.448 -20.486 -0.039 (0) + H[14C][18O]O[18O]- 3.567e-21 3.264e-21 -20.448 -20.486 -0.039 (0) + [14C]O2[18O]-2 3.183e-21 2.231e-21 -20.497 -20.651 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.646e-15 + O[18O] 2.641e-15 2.645e-15 -14.578 -14.578 0.001 (0) + [18O]2 2.635e-18 2.639e-18 -17.579 -17.579 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -36972,99 +36972,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.396 -126.395 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.077e-08 6.087e-08 -7.216 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.097 -40.097 0.001 -O(0) 1.299e-12 - O2 6.468e-13 6.478e-13 -12.189 -12.189 0.001 - O[18O] 2.581e-15 2.585e-15 -14.588 -14.588 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.353 -128.352 0.001 -[13C](4) 6.498e-05 - H[13C]O3- 5.241e-05 4.795e-05 -4.281 -4.319 -0.039 - [13C]O2 1.101e-05 1.102e-05 -4.958 -4.958 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.568e-08 -6.981 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.568e-08 -6.981 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.568e-08 -6.981 -7.019 -0.039 - Ca[13C]O3 6.077e-08 6.087e-08 -7.216 -7.216 0.001 - [13C]O[18O] 4.576e-08 4.584e-08 -7.339 -7.339 0.001 - [13C]O3-2 3.115e-08 2.183e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.637e-10 3.643e-10 -9.439 -9.439 0.001 - H[13C]O[18O]2- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]2O- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]O[18O]- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - [13C]O2[18O]-2 1.864e-10 1.307e-10 -9.730 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.134 -139.133 0.001 -[14C](4) 1.084e-15 - H[14C]O3- 8.757e-16 8.012e-16 -15.058 -15.096 -0.039 - [14C]O2 1.823e-16 1.826e-16 -15.739 -15.739 0.001 - CaH[14C]O3+ 1.850e-17 1.697e-17 -16.733 -16.770 -0.037 - H[14C]O2[18O]- 1.747e-18 1.599e-18 -17.758 -17.796 -0.039 - H[14C]O[18O]O- 1.747e-18 1.599e-18 -17.758 -17.796 -0.039 - H[14C][18O]O2- 1.747e-18 1.599e-18 -17.758 -17.796 -0.039 - Ca[14C]O3 1.014e-18 1.016e-18 -17.994 -17.993 0.001 - [14C]O[18O] 7.580e-19 7.593e-19 -18.120 -18.120 0.001 - [14C]O3-2 5.196e-19 3.642e-19 -18.284 -18.439 -0.154 - CaH[14C]O2[18O]+ 3.691e-20 3.386e-20 -19.433 -19.470 -0.037 - CaH[14C]O[18O]O+ 3.691e-20 3.386e-20 -19.433 -19.470 -0.037 - CaH[14C][18O]O2+ 3.691e-20 3.386e-20 -19.433 -19.470 -0.037 - Ca[14C]O2[18O] 6.069e-21 6.079e-21 -20.217 -20.216 0.001 - H[14C]O[18O]2- 3.486e-21 3.190e-21 -20.458 -20.496 -0.039 - H[14C][18O]2O- 3.486e-21 3.190e-21 -20.458 -20.496 -0.039 - H[14C][18O]O[18O]- 3.486e-21 3.190e-21 -20.458 -20.496 -0.039 - [14C]O2[18O]-2 3.110e-21 2.180e-21 -20.507 -20.662 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.586e-15 - O[18O] 2.581e-15 2.585e-15 -14.588 -14.588 0.001 - [18O]2 2.575e-18 2.579e-18 -17.589 -17.589 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.396 -126.395 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.077e-08 6.087e-08 -7.216 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.097 -40.097 0.001 (0) +O(0) 1.299e-12 + O2 6.468e-13 6.478e-13 -12.189 -12.189 0.001 (0) + O[18O] 2.581e-15 2.585e-15 -14.588 -14.588 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.353 -128.352 0.001 (0) +[13C](4) 6.498e-05 + H[13C]O3- 5.241e-05 4.795e-05 -4.281 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.102e-05 -4.958 -4.958 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.568e-08 -6.981 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.568e-08 -6.981 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.568e-08 -6.981 -7.019 -0.039 (0) + Ca[13C]O3 6.077e-08 6.087e-08 -7.216 -7.216 0.001 (0) + [13C]O[18O] 4.576e-08 4.584e-08 -7.339 -7.339 0.001 (0) + [13C]O3-2 3.115e-08 2.183e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.637e-10 3.643e-10 -9.439 -9.439 0.001 (0) + H[13C]O[18O]2- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]2O- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.864e-10 1.307e-10 -9.730 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.134 -139.133 0.001 (0) +[14C](4) 1.084e-15 + H[14C]O3- 8.757e-16 8.012e-16 -15.058 -15.096 -0.039 (0) + [14C]O2 1.823e-16 1.826e-16 -15.739 -15.739 0.001 (0) + CaH[14C]O3+ 1.850e-17 1.697e-17 -16.733 -16.770 -0.037 (0) + H[14C]O2[18O]- 1.747e-18 1.599e-18 -17.758 -17.796 -0.039 (0) + H[14C]O[18O]O- 1.747e-18 1.599e-18 -17.758 -17.796 -0.039 (0) + H[14C][18O]O2- 1.747e-18 1.599e-18 -17.758 -17.796 -0.039 (0) + Ca[14C]O3 1.014e-18 1.016e-18 -17.994 -17.993 0.001 (0) + [14C]O[18O] 7.580e-19 7.593e-19 -18.120 -18.120 0.001 (0) + [14C]O3-2 5.196e-19 3.642e-19 -18.284 -18.439 -0.154 (0) + CaH[14C]O2[18O]+ 3.691e-20 3.386e-20 -19.433 -19.470 -0.037 (0) + CaH[14C]O[18O]O+ 3.691e-20 3.386e-20 -19.433 -19.470 -0.037 (0) + CaH[14C][18O]O2+ 3.691e-20 3.386e-20 -19.433 -19.470 -0.037 (0) + Ca[14C]O2[18O] 6.069e-21 6.079e-21 -20.217 -20.216 0.001 (0) + H[14C]O[18O]2- 3.486e-21 3.190e-21 -20.458 -20.496 -0.039 (0) + H[14C][18O]2O- 3.486e-21 3.190e-21 -20.458 -20.496 -0.039 (0) + H[14C][18O]O[18O]- 3.486e-21 3.190e-21 -20.458 -20.496 -0.039 (0) + [14C]O2[18O]-2 3.110e-21 2.180e-21 -20.507 -20.662 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.586e-15 + O[18O] 2.581e-15 2.585e-15 -14.588 -14.588 0.001 (0) + [18O]2 2.575e-18 2.579e-18 -17.589 -17.589 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -37227,99 +37227,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.420 -126.419 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.077e-08 6.087e-08 -7.216 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.103 -40.103 0.001 -O(0) 1.335e-12 - O2 6.647e-13 6.658e-13 -12.177 -12.177 0.001 - O[18O] 2.652e-15 2.657e-15 -14.576 -14.576 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.376 -128.376 0.001 -[13C](4) 6.499e-05 - H[13C]O3- 5.241e-05 4.796e-05 -4.281 -4.319 -0.039 - [13C]O2 1.101e-05 1.102e-05 -4.958 -4.958 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.569e-08 -6.981 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.569e-08 -6.981 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.569e-08 -6.981 -7.019 -0.039 - Ca[13C]O3 6.077e-08 6.087e-08 -7.216 -7.216 0.001 - [13C]O[18O] 4.577e-08 4.584e-08 -7.339 -7.339 0.001 - [13C]O3-2 3.115e-08 2.183e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.638e-10 3.644e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]2O- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]O[18O]- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 - [13C]O2[18O]-2 1.864e-10 1.307e-10 -9.729 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.167 -139.166 0.001 -[14C](4) 1.060e-15 - H[14C]O3- 8.561e-16 7.834e-16 -15.067 -15.106 -0.039 - [14C]O2 1.782e-16 1.785e-16 -15.749 -15.748 0.001 - CaH[14C]O3+ 1.809e-17 1.659e-17 -16.743 -16.780 -0.037 - H[14C]O2[18O]- 1.708e-18 1.563e-18 -17.767 -17.806 -0.039 - H[14C]O[18O]O- 1.708e-18 1.563e-18 -17.767 -17.806 -0.039 - H[14C][18O]O2- 1.708e-18 1.563e-18 -17.767 -17.806 -0.039 - Ca[14C]O3 9.912e-19 9.929e-19 -18.004 -18.003 0.001 - [14C]O[18O] 7.411e-19 7.424e-19 -18.130 -18.129 0.001 - [14C]O3-2 5.080e-19 3.561e-19 -18.294 -18.448 -0.154 - CaH[14C]O2[18O]+ 3.608e-20 3.310e-20 -19.443 -19.480 -0.037 - CaH[14C]O[18O]O+ 3.608e-20 3.310e-20 -19.443 -19.480 -0.037 - CaH[14C][18O]O2+ 3.608e-20 3.310e-20 -19.443 -19.480 -0.037 - Ca[14C]O2[18O] 5.933e-21 5.943e-21 -20.227 -20.226 0.001 - H[14C]O[18O]2- 3.408e-21 3.118e-21 -20.467 -20.506 -0.039 - H[14C][18O]2O- 3.408e-21 3.118e-21 -20.467 -20.506 -0.039 - H[14C][18O]O[18O]- 3.408e-21 3.118e-21 -20.467 -20.506 -0.039 - [14C]O2[18O]-2 3.041e-21 2.131e-21 -20.517 -20.671 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.658e-15 - O[18O] 2.652e-15 2.657e-15 -14.576 -14.576 0.001 - [18O]2 2.646e-18 2.650e-18 -17.577 -17.577 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.420 -126.419 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.077e-08 6.087e-08 -7.216 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.103 -40.103 0.001 (0) +O(0) 1.335e-12 + O2 6.647e-13 6.658e-13 -12.177 -12.177 0.001 (0) + O[18O] 2.652e-15 2.657e-15 -14.576 -14.576 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.376 -128.376 0.001 (0) +[13C](4) 6.499e-05 + H[13C]O3- 5.241e-05 4.796e-05 -4.281 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.102e-05 -4.958 -4.958 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.569e-08 -6.981 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.569e-08 -6.981 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.569e-08 -6.981 -7.019 -0.039 (0) + Ca[13C]O3 6.077e-08 6.087e-08 -7.216 -7.216 0.001 (0) + [13C]O[18O] 4.577e-08 4.584e-08 -7.339 -7.339 0.001 (0) + [13C]O3-2 3.115e-08 2.183e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.638e-10 3.644e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]2O- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.086e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.864e-10 1.307e-10 -9.729 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.167 -139.166 0.001 (0) +[14C](4) 1.060e-15 + H[14C]O3- 8.561e-16 7.834e-16 -15.067 -15.106 -0.039 (0) + [14C]O2 1.782e-16 1.785e-16 -15.749 -15.748 0.001 (0) + CaH[14C]O3+ 1.809e-17 1.659e-17 -16.743 -16.780 -0.037 (0) + H[14C]O2[18O]- 1.708e-18 1.563e-18 -17.767 -17.806 -0.039 (0) + H[14C]O[18O]O- 1.708e-18 1.563e-18 -17.767 -17.806 -0.039 (0) + H[14C][18O]O2- 1.708e-18 1.563e-18 -17.767 -17.806 -0.039 (0) + Ca[14C]O3 9.912e-19 9.929e-19 -18.004 -18.003 0.001 (0) + [14C]O[18O] 7.411e-19 7.424e-19 -18.130 -18.129 0.001 (0) + [14C]O3-2 5.080e-19 3.561e-19 -18.294 -18.448 -0.154 (0) + CaH[14C]O2[18O]+ 3.608e-20 3.310e-20 -19.443 -19.480 -0.037 (0) + CaH[14C]O[18O]O+ 3.608e-20 3.310e-20 -19.443 -19.480 -0.037 (0) + CaH[14C][18O]O2+ 3.608e-20 3.310e-20 -19.443 -19.480 -0.037 (0) + Ca[14C]O2[18O] 5.933e-21 5.943e-21 -20.227 -20.226 0.001 (0) + H[14C]O[18O]2- 3.408e-21 3.118e-21 -20.467 -20.506 -0.039 (0) + H[14C][18O]2O- 3.408e-21 3.118e-21 -20.467 -20.506 -0.039 (0) + H[14C][18O]O[18O]- 3.408e-21 3.118e-21 -20.467 -20.506 -0.039 (0) + [14C]O2[18O]-2 3.041e-21 2.131e-21 -20.517 -20.671 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.658e-15 + O[18O] 2.652e-15 2.657e-15 -14.576 -14.576 0.001 (0) + [18O]2 2.646e-18 2.650e-18 -17.577 -17.577 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -37482,99 +37482,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.433 -126.432 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.078e-08 6.088e-08 -7.216 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.106 -40.106 0.001 -O(0) 1.354e-12 - O2 6.745e-13 6.757e-13 -12.171 -12.170 0.001 - O[18O] 2.692e-15 2.696e-15 -14.570 -14.569 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.389 -128.389 0.001 -[13C](4) 6.499e-05 - H[13C]O3- 5.242e-05 4.796e-05 -4.281 -4.319 -0.039 - [13C]O2 1.101e-05 1.103e-05 -4.958 -4.958 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.569e-08 -6.981 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.569e-08 -6.981 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.569e-08 -6.981 -7.019 -0.039 - Ca[13C]O3 6.078e-08 6.088e-08 -7.216 -7.216 0.001 - [13C]O[18O] 4.577e-08 4.585e-08 -7.339 -7.339 0.001 - [13C]O3-2 3.115e-08 2.183e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.638e-10 3.644e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]2O- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]O[18O]- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 - [13C]O2[18O]-2 1.864e-10 1.307e-10 -9.729 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.190 -139.189 0.001 -[14C](4) 1.037e-15 - H[14C]O3- 8.375e-16 7.663e-16 -15.077 -15.116 -0.039 - [14C]O2 1.743e-16 1.746e-16 -15.759 -15.758 0.001 - CaH[14C]O3+ 1.769e-17 1.623e-17 -16.752 -16.790 -0.037 - H[14C]O2[18O]- 1.671e-18 1.529e-18 -17.777 -17.816 -0.039 - H[14C]O[18O]O- 1.671e-18 1.529e-18 -17.777 -17.816 -0.039 - H[14C][18O]O2- 1.671e-18 1.529e-18 -17.777 -17.816 -0.039 - Ca[14C]O3 9.696e-19 9.712e-19 -18.013 -18.013 0.001 - [14C]O[18O] 7.250e-19 7.261e-19 -18.140 -18.139 0.001 - [14C]O3-2 4.970e-19 3.483e-19 -18.304 -18.458 -0.154 - CaH[14C]O2[18O]+ 3.530e-20 3.238e-20 -19.452 -19.490 -0.037 - CaH[14C]O[18O]O+ 3.530e-20 3.238e-20 -19.452 -19.490 -0.037 - CaH[14C][18O]O2+ 3.530e-20 3.238e-20 -19.452 -19.490 -0.037 - Ca[14C]O2[18O] 5.804e-21 5.813e-21 -20.236 -20.236 0.001 - H[14C]O[18O]2- 3.334e-21 3.050e-21 -20.477 -20.516 -0.039 - H[14C][18O]2O- 3.334e-21 3.050e-21 -20.477 -20.516 -0.039 - H[14C][18O]O[18O]- 3.334e-21 3.050e-21 -20.477 -20.516 -0.039 - [14C]O2[18O]-2 2.975e-21 2.085e-21 -20.527 -20.681 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.697e-15 - O[18O] 2.692e-15 2.696e-15 -14.570 -14.569 0.001 - [18O]2 2.685e-18 2.690e-18 -17.571 -17.570 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.433 -126.432 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.078e-08 6.088e-08 -7.216 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.106 -40.106 0.001 (0) +O(0) 1.354e-12 + O2 6.745e-13 6.757e-13 -12.171 -12.170 0.001 (0) + O[18O] 2.692e-15 2.696e-15 -14.570 -14.569 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.389 -128.389 0.001 (0) +[13C](4) 6.499e-05 + H[13C]O3- 5.242e-05 4.796e-05 -4.281 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.103e-05 -4.958 -4.958 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.569e-08 -6.981 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.569e-08 -6.981 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.569e-08 -6.981 -7.019 -0.039 (0) + Ca[13C]O3 6.078e-08 6.088e-08 -7.216 -7.216 0.001 (0) + [13C]O[18O] 4.577e-08 4.585e-08 -7.339 -7.339 0.001 (0) + [13C]O3-2 3.115e-08 2.183e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.638e-10 3.644e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]2O- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.864e-10 1.307e-10 -9.729 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.190 -139.189 0.001 (0) +[14C](4) 1.037e-15 + H[14C]O3- 8.375e-16 7.663e-16 -15.077 -15.116 -0.039 (0) + [14C]O2 1.743e-16 1.746e-16 -15.759 -15.758 0.001 (0) + CaH[14C]O3+ 1.769e-17 1.623e-17 -16.752 -16.790 -0.037 (0) + H[14C]O2[18O]- 1.671e-18 1.529e-18 -17.777 -17.816 -0.039 (0) + H[14C]O[18O]O- 1.671e-18 1.529e-18 -17.777 -17.816 -0.039 (0) + H[14C][18O]O2- 1.671e-18 1.529e-18 -17.777 -17.816 -0.039 (0) + Ca[14C]O3 9.696e-19 9.712e-19 -18.013 -18.013 0.001 (0) + [14C]O[18O] 7.250e-19 7.261e-19 -18.140 -18.139 0.001 (0) + [14C]O3-2 4.970e-19 3.483e-19 -18.304 -18.458 -0.154 (0) + CaH[14C]O2[18O]+ 3.530e-20 3.238e-20 -19.452 -19.490 -0.037 (0) + CaH[14C]O[18O]O+ 3.530e-20 3.238e-20 -19.452 -19.490 -0.037 (0) + CaH[14C][18O]O2+ 3.530e-20 3.238e-20 -19.452 -19.490 -0.037 (0) + Ca[14C]O2[18O] 5.804e-21 5.813e-21 -20.236 -20.236 0.001 (0) + H[14C]O[18O]2- 3.334e-21 3.050e-21 -20.477 -20.516 -0.039 (0) + H[14C][18O]2O- 3.334e-21 3.050e-21 -20.477 -20.516 -0.039 (0) + H[14C][18O]O[18O]- 3.334e-21 3.050e-21 -20.477 -20.516 -0.039 (0) + [14C]O2[18O]-2 2.975e-21 2.085e-21 -20.527 -20.681 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.697e-15 + O[18O] 2.692e-15 2.696e-15 -14.570 -14.569 0.001 (0) + [18O]2 2.685e-18 2.690e-18 -17.571 -17.570 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -37737,99 +37737,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.416 -126.415 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.078e-08 6.088e-08 -7.216 -7.216 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.102 -40.101 0.001 -O(0) 1.328e-12 - O2 6.615e-13 6.626e-13 -12.179 -12.179 0.001 - O[18O] 2.640e-15 2.644e-15 -14.578 -14.578 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.372 -128.372 0.001 -[13C](4) 6.500e-05 - H[13C]O3- 5.242e-05 4.796e-05 -4.280 -4.319 -0.039 - [13C]O2 1.101e-05 1.103e-05 -4.958 -4.958 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.570e-08 -6.981 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.570e-08 -6.981 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.570e-08 -6.981 -7.019 -0.039 - Ca[13C]O3 6.078e-08 6.088e-08 -7.216 -7.216 0.001 - [13C]O[18O] 4.577e-08 4.585e-08 -7.339 -7.339 0.001 - [13C]O3-2 3.115e-08 2.183e-08 -7.507 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.638e-10 3.644e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]2O- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 - H[13C][18O]O[18O]- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 - [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.182 -139.181 0.001 -[14C](4) 1.015e-15 - H[14C]O3- 8.196e-16 7.499e-16 -15.086 -15.125 -0.039 - [14C]O2 1.706e-16 1.709e-16 -15.768 -15.767 0.001 - CaH[14C]O3+ 1.731e-17 1.588e-17 -16.762 -16.799 -0.037 - H[14C]O2[18O]- 1.635e-18 1.496e-18 -17.786 -17.825 -0.039 - H[14C]O[18O]O- 1.635e-18 1.496e-18 -17.786 -17.825 -0.039 - H[14C][18O]O2- 1.635e-18 1.496e-18 -17.786 -17.825 -0.039 - Ca[14C]O3 9.489e-19 9.504e-19 -18.023 -18.022 0.001 - [14C]O[18O] 7.095e-19 7.106e-19 -18.149 -18.148 0.001 - [14C]O3-2 4.863e-19 3.409e-19 -18.313 -18.467 -0.154 - CaH[14C]O2[18O]+ 3.454e-20 3.169e-20 -19.462 -19.499 -0.037 - CaH[14C]O[18O]O+ 3.454e-20 3.169e-20 -19.462 -19.499 -0.037 - CaH[14C][18O]O2+ 3.454e-20 3.169e-20 -19.462 -19.499 -0.037 - Ca[14C]O2[18O] 5.680e-21 5.689e-21 -20.246 -20.245 0.001 - H[14C]O[18O]2- 3.263e-21 2.985e-21 -20.486 -20.525 -0.039 - H[14C][18O]2O- 3.263e-21 2.985e-21 -20.486 -20.525 -0.039 - H[14C][18O]O[18O]- 3.263e-21 2.985e-21 -20.486 -20.525 -0.039 - [14C]O2[18O]-2 2.911e-21 2.040e-21 -20.536 -20.690 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.645e-15 - O[18O] 2.640e-15 2.644e-15 -14.578 -14.578 0.001 - [18O]2 2.633e-18 2.637e-18 -17.580 -17.579 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.416 -126.415 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.078e-08 6.088e-08 -7.216 -7.216 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.102 -40.101 0.001 (0) +O(0) 1.328e-12 + O2 6.615e-13 6.626e-13 -12.179 -12.179 0.001 (0) + O[18O] 2.640e-15 2.644e-15 -14.578 -14.578 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.372 -128.372 0.001 (0) +[13C](4) 6.500e-05 + H[13C]O3- 5.242e-05 4.796e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.103e-05 -4.958 -4.958 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.570e-08 -6.981 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.570e-08 -6.981 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.570e-08 -6.981 -7.019 -0.039 (0) + Ca[13C]O3 6.078e-08 6.088e-08 -7.216 -7.216 0.001 (0) + [13C]O[18O] 4.577e-08 4.585e-08 -7.339 -7.339 0.001 (0) + [13C]O3-2 3.115e-08 2.183e-08 -7.507 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.209e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.638e-10 3.644e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]2O- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.087e-10 1.909e-10 -9.681 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.182 -139.181 0.001 (0) +[14C](4) 1.015e-15 + H[14C]O3- 8.196e-16 7.499e-16 -15.086 -15.125 -0.039 (0) + [14C]O2 1.706e-16 1.709e-16 -15.768 -15.767 0.001 (0) + CaH[14C]O3+ 1.731e-17 1.588e-17 -16.762 -16.799 -0.037 (0) + H[14C]O2[18O]- 1.635e-18 1.496e-18 -17.786 -17.825 -0.039 (0) + H[14C]O[18O]O- 1.635e-18 1.496e-18 -17.786 -17.825 -0.039 (0) + H[14C][18O]O2- 1.635e-18 1.496e-18 -17.786 -17.825 -0.039 (0) + Ca[14C]O3 9.489e-19 9.504e-19 -18.023 -18.022 0.001 (0) + [14C]O[18O] 7.095e-19 7.106e-19 -18.149 -18.148 0.001 (0) + [14C]O3-2 4.863e-19 3.409e-19 -18.313 -18.467 -0.154 (0) + CaH[14C]O2[18O]+ 3.454e-20 3.169e-20 -19.462 -19.499 -0.037 (0) + CaH[14C]O[18O]O+ 3.454e-20 3.169e-20 -19.462 -19.499 -0.037 (0) + CaH[14C][18O]O2+ 3.454e-20 3.169e-20 -19.462 -19.499 -0.037 (0) + Ca[14C]O2[18O] 5.680e-21 5.689e-21 -20.246 -20.245 0.001 (0) + H[14C]O[18O]2- 3.263e-21 2.985e-21 -20.486 -20.525 -0.039 (0) + H[14C][18O]2O- 3.263e-21 2.985e-21 -20.486 -20.525 -0.039 (0) + H[14C][18O]O[18O]- 3.263e-21 2.985e-21 -20.486 -20.525 -0.039 (0) + [14C]O2[18O]-2 2.911e-21 2.040e-21 -20.536 -20.690 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.645e-15 + O[18O] 2.640e-15 2.644e-15 -14.578 -14.578 0.001 (0) + [18O]2 2.633e-18 2.637e-18 -17.580 -17.579 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -37992,99 +37992,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.424 -126.423 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.078e-08 6.088e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.104 -40.104 0.001 -O(0) 1.341e-12 - O2 6.679e-13 6.690e-13 -12.175 -12.175 0.001 - O[18O] 2.665e-15 2.670e-15 -14.574 -14.574 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.381 -128.380 0.001 -[13C](4) 6.500e-05 - H[13C]O3- 5.242e-05 4.797e-05 -4.280 -4.319 -0.039 - [13C]O2 1.101e-05 1.103e-05 -4.958 -4.958 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.570e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.570e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.570e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.078e-08 6.088e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.578e-08 4.585e-08 -7.339 -7.339 0.001 - [13C]O3-2 3.115e-08 2.184e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.638e-10 3.644e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.087e-10 1.909e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.087e-10 1.909e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.087e-10 1.909e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.200 -139.199 0.001 -[14C](4) 9.934e-16 - H[14C]O3- 8.024e-16 7.342e-16 -15.096 -15.134 -0.039 - [14C]O2 1.670e-16 1.673e-16 -15.777 -15.776 0.001 - CaH[14C]O3+ 1.695e-17 1.555e-17 -16.771 -16.808 -0.037 - H[14C]O2[18O]- 1.601e-18 1.465e-18 -17.796 -17.834 -0.039 - H[14C]O[18O]O- 1.601e-18 1.465e-18 -17.796 -17.834 -0.039 - H[14C][18O]O2- 1.601e-18 1.465e-18 -17.796 -17.834 -0.039 - Ca[14C]O3 9.290e-19 9.306e-19 -18.032 -18.031 0.001 - [14C]O[18O] 6.946e-19 6.958e-19 -18.158 -18.158 0.001 - [14C]O3-2 4.762e-19 3.338e-19 -18.322 -18.477 -0.154 - CaH[14C]O2[18O]+ 3.382e-20 3.103e-20 -19.471 -19.508 -0.037 - CaH[14C]O[18O]O+ 3.382e-20 3.103e-20 -19.471 -19.508 -0.037 - CaH[14C][18O]O2+ 3.382e-20 3.103e-20 -19.471 -19.508 -0.037 - Ca[14C]O2[18O] 5.561e-21 5.570e-21 -20.255 -20.254 0.001 - H[14C]O[18O]2- 3.194e-21 2.923e-21 -20.496 -20.534 -0.039 - H[14C][18O]2O- 3.194e-21 2.923e-21 -20.496 -20.534 -0.039 - H[14C][18O]O[18O]- 3.194e-21 2.923e-21 -20.496 -20.534 -0.039 - [14C]O2[18O]-2 2.850e-21 1.998e-21 -20.545 -20.699 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.671e-15 - O[18O] 2.665e-15 2.670e-15 -14.574 -14.574 0.001 - [18O]2 2.659e-18 2.663e-18 -17.575 -17.575 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.424 -126.423 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.935e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.078e-08 6.088e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.104 -40.104 0.001 (0) +O(0) 1.341e-12 + O2 6.679e-13 6.690e-13 -12.175 -12.175 0.001 (0) + O[18O] 2.665e-15 2.670e-15 -14.574 -14.574 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.381 -128.380 0.001 (0) +[13C](4) 6.500e-05 + H[13C]O3- 5.242e-05 4.797e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.103e-05 -4.958 -4.958 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.570e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.570e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.570e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.078e-08 6.088e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.578e-08 4.585e-08 -7.339 -7.339 0.001 (0) + [13C]O3-2 3.115e-08 2.184e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.638e-10 3.644e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.087e-10 1.909e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.087e-10 1.909e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.087e-10 1.909e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.200 -139.199 0.001 (0) +[14C](4) 9.934e-16 + H[14C]O3- 8.024e-16 7.342e-16 -15.096 -15.134 -0.039 (0) + [14C]O2 1.670e-16 1.673e-16 -15.777 -15.776 0.001 (0) + CaH[14C]O3+ 1.695e-17 1.555e-17 -16.771 -16.808 -0.037 (0) + H[14C]O2[18O]- 1.601e-18 1.465e-18 -17.796 -17.834 -0.039 (0) + H[14C]O[18O]O- 1.601e-18 1.465e-18 -17.796 -17.834 -0.039 (0) + H[14C][18O]O2- 1.601e-18 1.465e-18 -17.796 -17.834 -0.039 (0) + Ca[14C]O3 9.290e-19 9.306e-19 -18.032 -18.031 0.001 (0) + [14C]O[18O] 6.946e-19 6.958e-19 -18.158 -18.158 0.001 (0) + [14C]O3-2 4.762e-19 3.338e-19 -18.322 -18.477 -0.154 (0) + CaH[14C]O2[18O]+ 3.382e-20 3.103e-20 -19.471 -19.508 -0.037 (0) + CaH[14C]O[18O]O+ 3.382e-20 3.103e-20 -19.471 -19.508 -0.037 (0) + CaH[14C][18O]O2+ 3.382e-20 3.103e-20 -19.471 -19.508 -0.037 (0) + Ca[14C]O2[18O] 5.561e-21 5.570e-21 -20.255 -20.254 0.001 (0) + H[14C]O[18O]2- 3.194e-21 2.923e-21 -20.496 -20.534 -0.039 (0) + H[14C][18O]2O- 3.194e-21 2.923e-21 -20.496 -20.534 -0.039 (0) + H[14C][18O]O[18O]- 3.194e-21 2.923e-21 -20.496 -20.534 -0.039 (0) + [14C]O2[18O]-2 2.850e-21 1.998e-21 -20.545 -20.699 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.671e-15 + O[18O] 2.665e-15 2.670e-15 -14.574 -14.574 0.001 (0) + [18O]2 2.659e-18 2.663e-18 -17.575 -17.575 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -38247,99 +38247,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.450 -126.449 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.079e-08 6.089e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.111 -40.110 0.001 -O(0) 1.381e-12 - O2 6.879e-13 6.891e-13 -12.162 -12.162 0.001 - O[18O] 2.745e-15 2.750e-15 -14.561 -14.561 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.406 -128.406 0.001 -[13C](4) 6.500e-05 - H[13C]O3- 5.243e-05 4.797e-05 -4.280 -4.319 -0.039 - [13C]O2 1.101e-05 1.103e-05 -4.958 -4.958 0.001 - CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.571e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.571e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.571e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.079e-08 6.089e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.578e-08 4.585e-08 -7.339 -7.339 0.001 - [13C]O3-2 3.116e-08 2.184e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.638e-10 3.644e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.234 -139.233 0.001 -[14C](4) 9.731e-16 - H[14C]O3- 7.860e-16 7.192e-16 -15.105 -15.143 -0.039 - [14C]O2 1.636e-16 1.639e-16 -15.786 -15.785 0.001 - CaH[14C]O3+ 1.660e-17 1.523e-17 -16.780 -16.817 -0.037 - H[14C]O2[18O]- 1.568e-18 1.435e-18 -17.805 -17.843 -0.039 - H[14C]O[18O]O- 1.568e-18 1.435e-18 -17.805 -17.843 -0.039 - H[14C][18O]O2- 1.568e-18 1.435e-18 -17.805 -17.843 -0.039 - Ca[14C]O3 9.100e-19 9.115e-19 -18.041 -18.040 0.001 - [14C]O[18O] 6.804e-19 6.815e-19 -18.167 -18.167 0.001 - [14C]O3-2 4.664e-19 3.269e-19 -18.331 -18.486 -0.154 - CaH[14C]O2[18O]+ 3.313e-20 3.039e-20 -19.480 -19.517 -0.037 - CaH[14C]O[18O]O+ 3.313e-20 3.039e-20 -19.480 -19.517 -0.037 - CaH[14C][18O]O2+ 3.313e-20 3.039e-20 -19.480 -19.517 -0.037 - Ca[14C]O2[18O] 5.447e-21 5.456e-21 -20.264 -20.263 0.001 - H[14C]O[18O]2- 3.129e-21 2.863e-21 -20.505 -20.543 -0.039 - H[14C][18O]2O- 3.129e-21 2.863e-21 -20.505 -20.543 -0.039 - H[14C][18O]O[18O]- 3.129e-21 2.863e-21 -20.505 -20.543 -0.039 - [14C]O2[18O]-2 2.792e-21 1.957e-21 -20.554 -20.708 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.751e-15 - O[18O] 2.745e-15 2.750e-15 -14.561 -14.561 0.001 - [18O]2 2.738e-18 2.743e-18 -17.562 -17.562 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.450 -126.449 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.079e-08 6.089e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.111 -40.110 0.001 (0) +O(0) 1.381e-12 + O2 6.879e-13 6.891e-13 -12.162 -12.162 0.001 (0) + O[18O] 2.745e-15 2.750e-15 -14.561 -14.561 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.406 -128.406 0.001 (0) +[13C](4) 6.500e-05 + H[13C]O3- 5.243e-05 4.797e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.103e-05 -4.958 -4.958 0.001 (0) + CaH[13C]O3+ 1.107e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.571e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.571e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.571e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.079e-08 6.089e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.578e-08 4.585e-08 -7.339 -7.339 0.001 (0) + [13C]O3-2 3.116e-08 2.184e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.638e-10 3.644e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.234 -139.233 0.001 (0) +[14C](4) 9.731e-16 + H[14C]O3- 7.860e-16 7.192e-16 -15.105 -15.143 -0.039 (0) + [14C]O2 1.636e-16 1.639e-16 -15.786 -15.785 0.001 (0) + CaH[14C]O3+ 1.660e-17 1.523e-17 -16.780 -16.817 -0.037 (0) + H[14C]O2[18O]- 1.568e-18 1.435e-18 -17.805 -17.843 -0.039 (0) + H[14C]O[18O]O- 1.568e-18 1.435e-18 -17.805 -17.843 -0.039 (0) + H[14C][18O]O2- 1.568e-18 1.435e-18 -17.805 -17.843 -0.039 (0) + Ca[14C]O3 9.100e-19 9.115e-19 -18.041 -18.040 0.001 (0) + [14C]O[18O] 6.804e-19 6.815e-19 -18.167 -18.167 0.001 (0) + [14C]O3-2 4.664e-19 3.269e-19 -18.331 -18.486 -0.154 (0) + CaH[14C]O2[18O]+ 3.313e-20 3.039e-20 -19.480 -19.517 -0.037 (0) + CaH[14C]O[18O]O+ 3.313e-20 3.039e-20 -19.480 -19.517 -0.037 (0) + CaH[14C][18O]O2+ 3.313e-20 3.039e-20 -19.480 -19.517 -0.037 (0) + Ca[14C]O2[18O] 5.447e-21 5.456e-21 -20.264 -20.263 0.001 (0) + H[14C]O[18O]2- 3.129e-21 2.863e-21 -20.505 -20.543 -0.039 (0) + H[14C][18O]2O- 3.129e-21 2.863e-21 -20.505 -20.543 -0.039 (0) + H[14C][18O]O[18O]- 3.129e-21 2.863e-21 -20.505 -20.543 -0.039 (0) + [14C]O2[18O]-2 2.792e-21 1.957e-21 -20.554 -20.708 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.751e-15 + O[18O] 2.745e-15 2.750e-15 -14.561 -14.561 0.001 (0) + [18O]2 2.738e-18 2.743e-18 -17.562 -17.562 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -38502,99 +38502,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.463 -126.462 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.079e-08 6.089e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.114 -40.113 0.001 -O(0) 1.402e-12 - O2 6.984e-13 6.996e-13 -12.156 -12.155 0.001 - O[18O] 2.787e-15 2.792e-15 -14.555 -14.554 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.419 -128.419 0.001 -[13C](4) 6.501e-05 - H[13C]O3- 5.243e-05 4.797e-05 -4.280 -4.319 -0.039 - [13C]O2 1.101e-05 1.103e-05 -4.958 -4.958 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.572e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.572e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.572e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.079e-08 6.089e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.578e-08 4.586e-08 -7.339 -7.339 0.001 - [13C]O3-2 3.116e-08 2.184e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.639e-10 3.645e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.256 -139.255 0.001 -[14C](4) 9.535e-16 - H[14C]O3- 7.702e-16 7.047e-16 -15.113 -15.152 -0.039 - [14C]O2 1.603e-16 1.606e-16 -15.795 -15.794 0.001 - CaH[14C]O3+ 1.627e-17 1.493e-17 -16.789 -16.826 -0.037 - H[14C]O2[18O]- 1.537e-18 1.406e-18 -17.813 -17.852 -0.039 - H[14C]O[18O]O- 1.537e-18 1.406e-18 -17.813 -17.852 -0.039 - H[14C][18O]O2- 1.537e-18 1.406e-18 -17.813 -17.852 -0.039 - Ca[14C]O3 8.917e-19 8.932e-19 -18.050 -18.049 0.001 - [14C]O[18O] 6.667e-19 6.678e-19 -18.176 -18.175 0.001 - [14C]O3-2 4.570e-19 3.204e-19 -18.340 -18.494 -0.154 - CaH[14C]O2[18O]+ 3.246e-20 2.978e-20 -19.489 -19.526 -0.037 - CaH[14C]O[18O]O+ 3.246e-20 2.978e-20 -19.489 -19.526 -0.037 - CaH[14C][18O]O2+ 3.246e-20 2.978e-20 -19.489 -19.526 -0.037 - Ca[14C]O2[18O] 5.338e-21 5.346e-21 -20.273 -20.272 0.001 - H[14C]O[18O]2- 3.066e-21 2.805e-21 -20.513 -20.552 -0.039 - H[14C][18O]2O- 3.066e-21 2.805e-21 -20.513 -20.552 -0.039 - H[14C][18O]O[18O]- 3.066e-21 2.805e-21 -20.513 -20.552 -0.039 - [14C]O2[18O]-2 2.736e-21 1.917e-21 -20.563 -20.717 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.793e-15 - O[18O] 2.787e-15 2.792e-15 -14.555 -14.554 0.001 - [18O]2 2.780e-18 2.785e-18 -17.556 -17.555 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.463 -126.462 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.079e-08 6.089e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.114 -40.113 0.001 (0) +O(0) 1.402e-12 + O2 6.984e-13 6.996e-13 -12.156 -12.155 0.001 (0) + O[18O] 2.787e-15 2.792e-15 -14.555 -14.554 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.419 -128.419 0.001 (0) +[13C](4) 6.501e-05 + H[13C]O3- 5.243e-05 4.797e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.103e-05 -4.958 -4.958 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.572e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.572e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.572e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.079e-08 6.089e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.578e-08 4.586e-08 -7.339 -7.339 0.001 (0) + [13C]O3-2 3.116e-08 2.184e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.639e-10 3.645e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.256 -139.255 0.001 (0) +[14C](4) 9.535e-16 + H[14C]O3- 7.702e-16 7.047e-16 -15.113 -15.152 -0.039 (0) + [14C]O2 1.603e-16 1.606e-16 -15.795 -15.794 0.001 (0) + CaH[14C]O3+ 1.627e-17 1.493e-17 -16.789 -16.826 -0.037 (0) + H[14C]O2[18O]- 1.537e-18 1.406e-18 -17.813 -17.852 -0.039 (0) + H[14C]O[18O]O- 1.537e-18 1.406e-18 -17.813 -17.852 -0.039 (0) + H[14C][18O]O2- 1.537e-18 1.406e-18 -17.813 -17.852 -0.039 (0) + Ca[14C]O3 8.917e-19 8.932e-19 -18.050 -18.049 0.001 (0) + [14C]O[18O] 6.667e-19 6.678e-19 -18.176 -18.175 0.001 (0) + [14C]O3-2 4.570e-19 3.204e-19 -18.340 -18.494 -0.154 (0) + CaH[14C]O2[18O]+ 3.246e-20 2.978e-20 -19.489 -19.526 -0.037 (0) + CaH[14C]O[18O]O+ 3.246e-20 2.978e-20 -19.489 -19.526 -0.037 (0) + CaH[14C][18O]O2+ 3.246e-20 2.978e-20 -19.489 -19.526 -0.037 (0) + Ca[14C]O2[18O] 5.338e-21 5.346e-21 -20.273 -20.272 0.001 (0) + H[14C]O[18O]2- 3.066e-21 2.805e-21 -20.513 -20.552 -0.039 (0) + H[14C][18O]2O- 3.066e-21 2.805e-21 -20.513 -20.552 -0.039 (0) + H[14C][18O]O[18O]- 3.066e-21 2.805e-21 -20.513 -20.552 -0.039 (0) + [14C]O2[18O]-2 2.736e-21 1.917e-21 -20.563 -20.717 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.793e-15 + O[18O] 2.787e-15 2.792e-15 -14.555 -14.554 0.001 (0) + [18O]2 2.780e-18 2.785e-18 -17.556 -17.555 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -38757,99 +38757,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.471 -126.471 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.079e-08 6.089e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.116 -40.115 0.001 -O(0) 1.416e-12 - O2 7.054e-13 7.066e-13 -12.152 -12.151 0.001 - O[18O] 2.815e-15 2.819e-15 -14.551 -14.550 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.428 -128.427 0.001 -[13C](4) 6.501e-05 - H[13C]O3- 5.243e-05 4.798e-05 -4.280 -4.319 -0.039 - [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.572e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.572e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.572e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.079e-08 6.089e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.578e-08 4.586e-08 -7.339 -7.339 0.001 - [13C]O3-2 3.116e-08 2.184e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.639e-10 3.645e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.273 -139.273 0.001 -[14C](4) 9.348e-16 - H[14C]O3- 7.550e-16 6.909e-16 -15.122 -15.161 -0.039 - [14C]O2 1.572e-16 1.574e-16 -15.804 -15.803 0.001 - CaH[14C]O3+ 1.595e-17 1.463e-17 -16.797 -16.835 -0.037 - H[14C]O2[18O]- 1.506e-18 1.378e-18 -17.822 -17.861 -0.039 - H[14C]O[18O]O- 1.506e-18 1.378e-18 -17.822 -17.861 -0.039 - H[14C][18O]O2- 1.506e-18 1.378e-18 -17.822 -17.861 -0.039 - Ca[14C]O3 8.742e-19 8.756e-19 -18.058 -18.058 0.001 - [14C]O[18O] 6.536e-19 6.547e-19 -18.185 -18.184 0.001 - [14C]O3-2 4.481e-19 3.140e-19 -18.349 -18.503 -0.154 - CaH[14C]O2[18O]+ 3.182e-20 2.920e-20 -19.497 -19.535 -0.037 - CaH[14C]O[18O]O+ 3.182e-20 2.920e-20 -19.497 -19.535 -0.037 - CaH[14C][18O]O2+ 3.182e-20 2.920e-20 -19.497 -19.535 -0.037 - Ca[14C]O2[18O] 5.232e-21 5.241e-21 -20.281 -20.281 0.001 - H[14C]O[18O]2- 3.006e-21 2.750e-21 -20.522 -20.561 -0.039 - H[14C][18O]2O- 3.006e-21 2.750e-21 -20.522 -20.561 -0.039 - H[14C][18O]O[18O]- 3.006e-21 2.750e-21 -20.522 -20.561 -0.039 - [14C]O2[18O]-2 2.682e-21 1.880e-21 -20.572 -20.726 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.820e-15 - O[18O] 2.815e-15 2.819e-15 -14.551 -14.550 0.001 - [18O]2 2.808e-18 2.813e-18 -17.552 -17.551 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.471 -126.471 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.079e-08 6.089e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.116 -40.115 0.001 (0) +O(0) 1.416e-12 + O2 7.054e-13 7.066e-13 -12.152 -12.151 0.001 (0) + O[18O] 2.815e-15 2.819e-15 -14.551 -14.550 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.428 -128.427 0.001 (0) +[13C](4) 6.501e-05 + H[13C]O3- 5.243e-05 4.798e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.572e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.572e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.572e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.079e-08 6.089e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.578e-08 4.586e-08 -7.339 -7.339 0.001 (0) + [13C]O3-2 3.116e-08 2.184e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.210e-09 2.027e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.639e-10 3.645e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.273 -139.273 0.001 (0) +[14C](4) 9.348e-16 + H[14C]O3- 7.550e-16 6.909e-16 -15.122 -15.161 -0.039 (0) + [14C]O2 1.572e-16 1.574e-16 -15.804 -15.803 0.001 (0) + CaH[14C]O3+ 1.595e-17 1.463e-17 -16.797 -16.835 -0.037 (0) + H[14C]O2[18O]- 1.506e-18 1.378e-18 -17.822 -17.861 -0.039 (0) + H[14C]O[18O]O- 1.506e-18 1.378e-18 -17.822 -17.861 -0.039 (0) + H[14C][18O]O2- 1.506e-18 1.378e-18 -17.822 -17.861 -0.039 (0) + Ca[14C]O3 8.742e-19 8.756e-19 -18.058 -18.058 0.001 (0) + [14C]O[18O] 6.536e-19 6.547e-19 -18.185 -18.184 0.001 (0) + [14C]O3-2 4.481e-19 3.140e-19 -18.349 -18.503 -0.154 (0) + CaH[14C]O2[18O]+ 3.182e-20 2.920e-20 -19.497 -19.535 -0.037 (0) + CaH[14C]O[18O]O+ 3.182e-20 2.920e-20 -19.497 -19.535 -0.037 (0) + CaH[14C][18O]O2+ 3.182e-20 2.920e-20 -19.497 -19.535 -0.037 (0) + Ca[14C]O2[18O] 5.232e-21 5.241e-21 -20.281 -20.281 0.001 (0) + H[14C]O[18O]2- 3.006e-21 2.750e-21 -20.522 -20.561 -0.039 (0) + H[14C][18O]2O- 3.006e-21 2.750e-21 -20.522 -20.561 -0.039 (0) + H[14C][18O]O[18O]- 3.006e-21 2.750e-21 -20.522 -20.561 -0.039 (0) + [14C]O2[18O]-2 2.682e-21 1.880e-21 -20.572 -20.726 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.820e-15 + O[18O] 2.815e-15 2.819e-15 -14.551 -14.550 0.001 (0) + [18O]2 2.808e-18 2.813e-18 -17.552 -17.551 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -39012,99 +39012,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.466 -126.466 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.080e-08 6.090e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.115 -40.114 0.001 -O(0) 1.408e-12 - O2 7.014e-13 7.025e-13 -12.154 -12.153 0.001 - O[18O] 2.799e-15 2.803e-15 -14.553 -14.552 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.423 -128.422 0.001 -[13C](4) 6.501e-05 - H[13C]O3- 5.244e-05 4.798e-05 -4.280 -4.319 -0.039 - [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.080e-08 6.090e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.579e-08 4.586e-08 -7.339 -7.339 0.001 - [13C]O3-2 3.116e-08 2.184e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.639e-10 3.645e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.277 -139.276 0.001 -[14C](4) 9.167e-16 - H[14C]O3- 7.405e-16 6.775e-16 -15.130 -15.169 -0.039 - [14C]O2 1.541e-16 1.544e-16 -15.812 -15.811 0.001 - CaH[14C]O3+ 1.564e-17 1.435e-17 -16.806 -16.843 -0.037 - H[14C]O2[18O]- 1.477e-18 1.352e-18 -17.831 -17.869 -0.039 - H[14C]O[18O]O- 1.477e-18 1.352e-18 -17.831 -17.869 -0.039 - H[14C][18O]O2- 1.477e-18 1.352e-18 -17.831 -17.869 -0.039 - Ca[14C]O3 8.573e-19 8.587e-19 -18.067 -18.066 0.001 - [14C]O[18O] 6.410e-19 6.420e-19 -18.193 -18.192 0.001 - [14C]O3-2 4.394e-19 3.080e-19 -18.357 -18.511 -0.154 - CaH[14C]O2[18O]+ 3.121e-20 2.863e-20 -19.506 -19.543 -0.037 - CaH[14C]O[18O]O+ 3.121e-20 2.863e-20 -19.506 -19.543 -0.037 - CaH[14C][18O]O2+ 3.121e-20 2.863e-20 -19.506 -19.543 -0.037 - Ca[14C]O2[18O] 5.131e-21 5.140e-21 -20.290 -20.289 0.001 - H[14C]O[18O]2- 2.948e-21 2.697e-21 -20.531 -20.569 -0.039 - H[14C][18O]2O- 2.948e-21 2.697e-21 -20.531 -20.569 -0.039 - H[14C][18O]O[18O]- 2.948e-21 2.697e-21 -20.531 -20.569 -0.039 - [14C]O2[18O]-2 2.630e-21 1.843e-21 -20.580 -20.734 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.804e-15 - O[18O] 2.799e-15 2.803e-15 -14.553 -14.552 0.001 - [18O]2 2.792e-18 2.797e-18 -17.554 -17.553 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.466 -126.466 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.080e-08 6.090e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.115 -40.114 0.001 (0) +O(0) 1.408e-12 + O2 7.014e-13 7.025e-13 -12.154 -12.153 0.001 (0) + O[18O] 2.799e-15 2.803e-15 -14.553 -14.552 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.423 -128.422 0.001 (0) +[13C](4) 6.501e-05 + H[13C]O3- 5.244e-05 4.798e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.080e-08 6.090e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.579e-08 4.586e-08 -7.339 -7.339 0.001 (0) + [13C]O3-2 3.116e-08 2.184e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.639e-10 3.645e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.277 -139.276 0.001 (0) +[14C](4) 9.167e-16 + H[14C]O3- 7.405e-16 6.775e-16 -15.130 -15.169 -0.039 (0) + [14C]O2 1.541e-16 1.544e-16 -15.812 -15.811 0.001 (0) + CaH[14C]O3+ 1.564e-17 1.435e-17 -16.806 -16.843 -0.037 (0) + H[14C]O2[18O]- 1.477e-18 1.352e-18 -17.831 -17.869 -0.039 (0) + H[14C]O[18O]O- 1.477e-18 1.352e-18 -17.831 -17.869 -0.039 (0) + H[14C][18O]O2- 1.477e-18 1.352e-18 -17.831 -17.869 -0.039 (0) + Ca[14C]O3 8.573e-19 8.587e-19 -18.067 -18.066 0.001 (0) + [14C]O[18O] 6.410e-19 6.420e-19 -18.193 -18.192 0.001 (0) + [14C]O3-2 4.394e-19 3.080e-19 -18.357 -18.511 -0.154 (0) + CaH[14C]O2[18O]+ 3.121e-20 2.863e-20 -19.506 -19.543 -0.037 (0) + CaH[14C]O[18O]O+ 3.121e-20 2.863e-20 -19.506 -19.543 -0.037 (0) + CaH[14C][18O]O2+ 3.121e-20 2.863e-20 -19.506 -19.543 -0.037 (0) + Ca[14C]O2[18O] 5.131e-21 5.140e-21 -20.290 -20.289 0.001 (0) + H[14C]O[18O]2- 2.948e-21 2.697e-21 -20.531 -20.569 -0.039 (0) + H[14C][18O]2O- 2.948e-21 2.697e-21 -20.531 -20.569 -0.039 (0) + H[14C][18O]O[18O]- 2.948e-21 2.697e-21 -20.531 -20.569 -0.039 (0) + [14C]O2[18O]-2 2.630e-21 1.843e-21 -20.580 -20.734 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.804e-15 + O[18O] 2.799e-15 2.803e-15 -14.553 -14.552 0.001 (0) + [18O]2 2.792e-18 2.797e-18 -17.554 -17.553 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -39267,99 +39267,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.461 -126.460 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.080e-08 6.090e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.114 -40.113 0.001 -O(0) 1.400e-12 - O2 6.971e-13 6.983e-13 -12.157 -12.156 0.001 - O[18O] 2.782e-15 2.786e-15 -14.556 -14.555 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.418 -128.417 0.001 -[13C](4) 6.502e-05 - H[13C]O3- 5.244e-05 4.798e-05 -4.280 -4.319 -0.039 - [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.080e-08 6.090e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.579e-08 4.586e-08 -7.339 -7.339 0.001 - [13C]O3-2 3.116e-08 2.184e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.639e-10 3.645e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.280 -139.279 0.001 -[14C](4) 8.994e-16 - H[14C]O3- 7.264e-16 6.647e-16 -15.139 -15.177 -0.039 - [14C]O2 1.512e-16 1.515e-16 -15.820 -15.820 0.001 - CaH[14C]O3+ 1.535e-17 1.408e-17 -16.814 -16.851 -0.037 - H[14C]O2[18O]- 1.449e-18 1.326e-18 -17.839 -17.877 -0.039 - H[14C]O[18O]O- 1.449e-18 1.326e-18 -17.839 -17.877 -0.039 - H[14C][18O]O2- 1.449e-18 1.326e-18 -17.839 -17.877 -0.039 - Ca[14C]O3 8.411e-19 8.425e-19 -18.075 -18.074 0.001 - [14C]O[18O] 6.289e-19 6.299e-19 -18.201 -18.201 0.001 - [14C]O3-2 4.311e-19 3.022e-19 -18.365 -18.520 -0.154 - CaH[14C]O2[18O]+ 3.062e-20 2.809e-20 -19.514 -19.551 -0.037 - CaH[14C]O[18O]O+ 3.062e-20 2.809e-20 -19.514 -19.551 -0.037 - CaH[14C][18O]O2+ 3.062e-20 2.809e-20 -19.514 -19.551 -0.037 - Ca[14C]O2[18O] 5.034e-21 5.043e-21 -20.298 -20.297 0.001 - H[14C]O[18O]2- 2.892e-21 2.646e-21 -20.539 -20.577 -0.039 - H[14C][18O]2O- 2.892e-21 2.646e-21 -20.539 -20.577 -0.039 - H[14C][18O]O[18O]- 2.892e-21 2.646e-21 -20.539 -20.577 -0.039 - [14C]O2[18O]-2 2.580e-21 1.809e-21 -20.588 -20.743 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.787e-15 - O[18O] 2.782e-15 2.786e-15 -14.556 -14.555 0.001 - [18O]2 2.775e-18 2.780e-18 -17.557 -17.556 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.461 -126.460 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.080e-08 6.090e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.114 -40.113 0.001 (0) +O(0) 1.400e-12 + O2 6.971e-13 6.983e-13 -12.157 -12.156 0.001 (0) + O[18O] 2.782e-15 2.786e-15 -14.556 -14.555 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.418 -128.417 0.001 (0) +[13C](4) 6.502e-05 + H[13C]O3- 5.244e-05 4.798e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.573e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.080e-08 6.090e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.579e-08 4.586e-08 -7.339 -7.339 0.001 (0) + [13C]O3-2 3.116e-08 2.184e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.639e-10 3.645e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.087e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.280 -139.279 0.001 (0) +[14C](4) 8.994e-16 + H[14C]O3- 7.264e-16 6.647e-16 -15.139 -15.177 -0.039 (0) + [14C]O2 1.512e-16 1.515e-16 -15.820 -15.820 0.001 (0) + CaH[14C]O3+ 1.535e-17 1.408e-17 -16.814 -16.851 -0.037 (0) + H[14C]O2[18O]- 1.449e-18 1.326e-18 -17.839 -17.877 -0.039 (0) + H[14C]O[18O]O- 1.449e-18 1.326e-18 -17.839 -17.877 -0.039 (0) + H[14C][18O]O2- 1.449e-18 1.326e-18 -17.839 -17.877 -0.039 (0) + Ca[14C]O3 8.411e-19 8.425e-19 -18.075 -18.074 0.001 (0) + [14C]O[18O] 6.289e-19 6.299e-19 -18.201 -18.201 0.001 (0) + [14C]O3-2 4.311e-19 3.022e-19 -18.365 -18.520 -0.154 (0) + CaH[14C]O2[18O]+ 3.062e-20 2.809e-20 -19.514 -19.551 -0.037 (0) + CaH[14C]O[18O]O+ 3.062e-20 2.809e-20 -19.514 -19.551 -0.037 (0) + CaH[14C][18O]O2+ 3.062e-20 2.809e-20 -19.514 -19.551 -0.037 (0) + Ca[14C]O2[18O] 5.034e-21 5.043e-21 -20.298 -20.297 0.001 (0) + H[14C]O[18O]2- 2.892e-21 2.646e-21 -20.539 -20.577 -0.039 (0) + H[14C][18O]2O- 2.892e-21 2.646e-21 -20.539 -20.577 -0.039 (0) + H[14C][18O]O[18O]- 2.892e-21 2.646e-21 -20.539 -20.577 -0.039 (0) + [14C]O2[18O]-2 2.580e-21 1.809e-21 -20.588 -20.743 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.787e-15 + O[18O] 2.782e-15 2.786e-15 -14.556 -14.555 0.001 (0) + [18O]2 2.775e-18 2.780e-18 -17.557 -17.556 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -39522,99 +39522,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.457 -126.456 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.080e-08 6.090e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.112 -40.112 0.001 -O(0) 1.392e-12 - O2 6.935e-13 6.946e-13 -12.159 -12.158 0.001 - O[18O] 2.767e-15 2.772e-15 -14.558 -14.557 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.413 -128.412 0.001 -[13C](4) 6.502e-05 - H[13C]O3- 5.244e-05 4.798e-05 -4.280 -4.319 -0.039 - [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.574e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.574e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.574e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.080e-08 6.090e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.579e-08 4.587e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.116e-08 2.184e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.639e-10 3.645e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.283 -139.283 0.001 -[14C](4) 8.827e-16 - H[14C]O3- 7.129e-16 6.523e-16 -15.147 -15.186 -0.039 - [14C]O2 1.484e-16 1.487e-16 -15.829 -15.828 0.001 - CaH[14C]O3+ 1.506e-17 1.382e-17 -16.822 -16.860 -0.037 - H[14C]O2[18O]- 1.422e-18 1.302e-18 -17.847 -17.886 -0.039 - H[14C]O[18O]O- 1.422e-18 1.302e-18 -17.847 -17.886 -0.039 - H[14C][18O]O2- 1.422e-18 1.302e-18 -17.847 -17.886 -0.039 - Ca[14C]O3 8.254e-19 8.268e-19 -18.083 -18.083 0.001 - [14C]O[18O] 6.172e-19 6.182e-19 -18.210 -18.209 0.001 - [14C]O3-2 4.231e-19 2.965e-19 -18.374 -18.528 -0.154 - CaH[14C]O2[18O]+ 3.005e-20 2.757e-20 -19.522 -19.560 -0.037 - CaH[14C]O[18O]O+ 3.005e-20 2.757e-20 -19.522 -19.560 -0.037 - CaH[14C][18O]O2+ 3.005e-20 2.757e-20 -19.522 -19.560 -0.037 - Ca[14C]O2[18O] 4.941e-21 4.949e-21 -20.306 -20.305 0.001 - H[14C]O[18O]2- 2.838e-21 2.597e-21 -20.547 -20.586 -0.039 - H[14C][18O]2O- 2.838e-21 2.597e-21 -20.547 -20.586 -0.039 - H[14C][18O]O[18O]- 2.838e-21 2.597e-21 -20.547 -20.586 -0.039 - [14C]O2[18O]-2 2.532e-21 1.775e-21 -20.596 -20.751 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.773e-15 - O[18O] 2.767e-15 2.772e-15 -14.558 -14.557 0.001 - [18O]2 2.761e-18 2.765e-18 -17.559 -17.558 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.457 -126.456 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.080e-08 6.090e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.269e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.112 -40.112 0.001 (0) +O(0) 1.392e-12 + O2 6.935e-13 6.946e-13 -12.159 -12.158 0.001 (0) + O[18O] 2.767e-15 2.772e-15 -14.558 -14.557 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.413 -128.412 0.001 (0) +[13C](4) 6.502e-05 + H[13C]O3- 5.244e-05 4.798e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.574e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.574e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.574e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.080e-08 6.090e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.579e-08 4.587e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.116e-08 2.184e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.639e-10 3.645e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.865e-10 1.307e-10 -9.729 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.283 -139.283 0.001 (0) +[14C](4) 8.827e-16 + H[14C]O3- 7.129e-16 6.523e-16 -15.147 -15.186 -0.039 (0) + [14C]O2 1.484e-16 1.487e-16 -15.829 -15.828 0.001 (0) + CaH[14C]O3+ 1.506e-17 1.382e-17 -16.822 -16.860 -0.037 (0) + H[14C]O2[18O]- 1.422e-18 1.302e-18 -17.847 -17.886 -0.039 (0) + H[14C]O[18O]O- 1.422e-18 1.302e-18 -17.847 -17.886 -0.039 (0) + H[14C][18O]O2- 1.422e-18 1.302e-18 -17.847 -17.886 -0.039 (0) + Ca[14C]O3 8.254e-19 8.268e-19 -18.083 -18.083 0.001 (0) + [14C]O[18O] 6.172e-19 6.182e-19 -18.210 -18.209 0.001 (0) + [14C]O3-2 4.231e-19 2.965e-19 -18.374 -18.528 -0.154 (0) + CaH[14C]O2[18O]+ 3.005e-20 2.757e-20 -19.522 -19.560 -0.037 (0) + CaH[14C]O[18O]O+ 3.005e-20 2.757e-20 -19.522 -19.560 -0.037 (0) + CaH[14C][18O]O2+ 3.005e-20 2.757e-20 -19.522 -19.560 -0.037 (0) + Ca[14C]O2[18O] 4.941e-21 4.949e-21 -20.306 -20.305 0.001 (0) + H[14C]O[18O]2- 2.838e-21 2.597e-21 -20.547 -20.586 -0.039 (0) + H[14C][18O]2O- 2.838e-21 2.597e-21 -20.547 -20.586 -0.039 (0) + H[14C][18O]O[18O]- 2.838e-21 2.597e-21 -20.547 -20.586 -0.039 (0) + [14C]O2[18O]-2 2.532e-21 1.775e-21 -20.596 -20.751 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.773e-15 + O[18O] 2.767e-15 2.772e-15 -14.558 -14.557 0.001 (0) + [18O]2 2.761e-18 2.765e-18 -17.559 -17.558 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -39777,99 +39777,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.450 -126.449 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.081e-08 6.091e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.111 -40.110 0.001 -O(0) 1.381e-12 - O2 6.880e-13 6.891e-13 -12.162 -12.162 0.001 - O[18O] 2.745e-15 2.750e-15 -14.561 -14.561 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.406 -128.405 0.001 -[13C](4) 6.502e-05 - H[13C]O3- 5.244e-05 4.799e-05 -4.280 -4.319 -0.039 - [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.574e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.574e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.574e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.081e-08 6.091e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.579e-08 4.587e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.117e-08 2.184e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.640e-10 3.646e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.865e-10 1.308e-10 -9.729 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.285 -139.284 0.001 -[14C](4) 8.666e-16 - H[14C]O3- 6.999e-16 6.404e-16 -15.155 -15.194 -0.039 - [14C]O2 1.457e-16 1.459e-16 -15.837 -15.836 0.001 - CaH[14C]O3+ 1.479e-17 1.356e-17 -16.830 -16.868 -0.037 - H[14C]O2[18O]- 1.397e-18 1.278e-18 -17.855 -17.894 -0.039 - H[14C]O[18O]O- 1.397e-18 1.278e-18 -17.855 -17.894 -0.039 - H[14C][18O]O2- 1.397e-18 1.278e-18 -17.855 -17.894 -0.039 - Ca[14C]O3 8.104e-19 8.117e-19 -18.091 -18.091 0.001 - [14C]O[18O] 6.059e-19 6.069e-19 -18.218 -18.217 0.001 - [14C]O3-2 4.154e-19 2.911e-19 -18.382 -18.536 -0.154 - CaH[14C]O2[18O]+ 2.950e-20 2.706e-20 -19.530 -19.568 -0.037 - CaH[14C]O[18O]O+ 2.950e-20 2.706e-20 -19.530 -19.568 -0.037 - CaH[14C][18O]O2+ 2.950e-20 2.706e-20 -19.530 -19.568 -0.037 - Ca[14C]O2[18O] 4.851e-21 4.859e-21 -20.314 -20.313 0.001 - H[14C]O[18O]2- 2.786e-21 2.549e-21 -20.555 -20.594 -0.039 - H[14C][18O]2O- 2.786e-21 2.549e-21 -20.555 -20.594 -0.039 - H[14C][18O]O[18O]- 2.786e-21 2.549e-21 -20.555 -20.594 -0.039 - [14C]O2[18O]-2 2.486e-21 1.743e-21 -20.604 -20.759 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.751e-15 - O[18O] 2.745e-15 2.750e-15 -14.561 -14.561 0.001 - [18O]2 2.739e-18 2.743e-18 -17.562 -17.562 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.450 -126.449 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.081e-08 6.091e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.111 -40.110 0.001 (0) +O(0) 1.381e-12 + O2 6.880e-13 6.891e-13 -12.162 -12.162 0.001 (0) + O[18O] 2.745e-15 2.750e-15 -14.561 -14.561 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.406 -128.405 0.001 (0) +[13C](4) 6.502e-05 + H[13C]O3- 5.244e-05 4.799e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.956 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.574e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.574e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.574e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.081e-08 6.091e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.579e-08 4.587e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.117e-08 2.184e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.640e-10 3.646e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.865e-10 1.308e-10 -9.729 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.285 -139.284 0.001 (0) +[14C](4) 8.666e-16 + H[14C]O3- 6.999e-16 6.404e-16 -15.155 -15.194 -0.039 (0) + [14C]O2 1.457e-16 1.459e-16 -15.837 -15.836 0.001 (0) + CaH[14C]O3+ 1.479e-17 1.356e-17 -16.830 -16.868 -0.037 (0) + H[14C]O2[18O]- 1.397e-18 1.278e-18 -17.855 -17.894 -0.039 (0) + H[14C]O[18O]O- 1.397e-18 1.278e-18 -17.855 -17.894 -0.039 (0) + H[14C][18O]O2- 1.397e-18 1.278e-18 -17.855 -17.894 -0.039 (0) + Ca[14C]O3 8.104e-19 8.117e-19 -18.091 -18.091 0.001 (0) + [14C]O[18O] 6.059e-19 6.069e-19 -18.218 -18.217 0.001 (0) + [14C]O3-2 4.154e-19 2.911e-19 -18.382 -18.536 -0.154 (0) + CaH[14C]O2[18O]+ 2.950e-20 2.706e-20 -19.530 -19.568 -0.037 (0) + CaH[14C]O[18O]O+ 2.950e-20 2.706e-20 -19.530 -19.568 -0.037 (0) + CaH[14C][18O]O2+ 2.950e-20 2.706e-20 -19.530 -19.568 -0.037 (0) + Ca[14C]O2[18O] 4.851e-21 4.859e-21 -20.314 -20.313 0.001 (0) + H[14C]O[18O]2- 2.786e-21 2.549e-21 -20.555 -20.594 -0.039 (0) + H[14C][18O]2O- 2.786e-21 2.549e-21 -20.555 -20.594 -0.039 (0) + H[14C][18O]O[18O]- 2.786e-21 2.549e-21 -20.555 -20.594 -0.039 (0) + [14C]O2[18O]-2 2.486e-21 1.743e-21 -20.604 -20.759 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.751e-15 + O[18O] 2.745e-15 2.750e-15 -14.561 -14.561 0.001 (0) + [18O]2 2.739e-18 2.743e-18 -17.562 -17.562 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -40032,99 +40032,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.469 -126.468 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.081e-08 6.091e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.116 -40.115 0.001 -O(0) 1.413e-12 - O2 7.035e-13 7.046e-13 -12.153 -12.152 0.001 - O[18O] 2.807e-15 2.812e-15 -14.552 -14.551 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.425 -128.425 0.001 -[13C](4) 6.503e-05 - H[13C]O3- 5.245e-05 4.799e-05 -4.280 -4.319 -0.039 - [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.081e-08 6.091e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.580e-08 4.587e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.117e-08 2.185e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - CaH[13C][18O]O2+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 - Ca[13C]O2[18O] 3.640e-10 3.646e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.312 -139.311 0.001 -[14C](4) 8.510e-16 - H[14C]O3- 6.874e-16 6.290e-16 -15.163 -15.201 -0.039 - [14C]O2 1.431e-16 1.433e-16 -15.844 -15.844 0.001 - CaH[14C]O3+ 1.452e-17 1.332e-17 -16.838 -16.875 -0.037 - H[14C]O2[18O]- 1.371e-18 1.255e-18 -17.863 -17.901 -0.039 - H[14C]O[18O]O- 1.371e-18 1.255e-18 -17.863 -17.901 -0.039 - H[14C][18O]O2- 1.371e-18 1.255e-18 -17.863 -17.901 -0.039 - Ca[14C]O3 7.959e-19 7.972e-19 -18.099 -18.098 0.001 - [14C]O[18O] 5.950e-19 5.960e-19 -18.225 -18.225 0.001 - [14C]O3-2 4.079e-19 2.859e-19 -18.389 -18.544 -0.154 - CaH[14C]O2[18O]+ 2.897e-20 2.658e-20 -19.538 -19.575 -0.037 - CaH[14C]O[18O]O+ 2.897e-20 2.658e-20 -19.538 -19.575 -0.037 - CaH[14C][18O]O2+ 2.897e-20 2.658e-20 -19.538 -19.575 -0.037 - Ca[14C]O2[18O] 4.764e-21 4.772e-21 -20.322 -20.321 0.001 - H[14C]O[18O]2- 2.736e-21 2.504e-21 -20.563 -20.601 -0.039 - H[14C][18O]2O- 2.736e-21 2.504e-21 -20.563 -20.601 -0.039 - H[14C][18O]O[18O]- 2.736e-21 2.504e-21 -20.563 -20.601 -0.039 - [14C]O2[18O]-2 2.442e-21 1.711e-21 -20.612 -20.767 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.813e-15 - O[18O] 2.807e-15 2.812e-15 -14.552 -14.551 0.001 - [18O]2 2.800e-18 2.805e-18 -17.553 -17.552 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.469 -126.468 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.081e-08 6.091e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.116 -40.115 0.001 (0) +O(0) 1.413e-12 + O2 7.035e-13 7.046e-13 -12.153 -12.152 0.001 (0) + O[18O] 2.807e-15 2.812e-15 -14.552 -14.551 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.425 -128.425 0.001 (0) +[13C](4) 6.503e-05 + H[13C]O3- 5.245e-05 4.799e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.081e-08 6.091e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.580e-08 4.587e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.117e-08 2.185e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.210e-09 2.028e-09 -8.656 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.640e-10 3.646e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.312 -139.311 0.001 (0) +[14C](4) 8.510e-16 + H[14C]O3- 6.874e-16 6.290e-16 -15.163 -15.201 -0.039 (0) + [14C]O2 1.431e-16 1.433e-16 -15.844 -15.844 0.001 (0) + CaH[14C]O3+ 1.452e-17 1.332e-17 -16.838 -16.875 -0.037 (0) + H[14C]O2[18O]- 1.371e-18 1.255e-18 -17.863 -17.901 -0.039 (0) + H[14C]O[18O]O- 1.371e-18 1.255e-18 -17.863 -17.901 -0.039 (0) + H[14C][18O]O2- 1.371e-18 1.255e-18 -17.863 -17.901 -0.039 (0) + Ca[14C]O3 7.959e-19 7.972e-19 -18.099 -18.098 0.001 (0) + [14C]O[18O] 5.950e-19 5.960e-19 -18.225 -18.225 0.001 (0) + [14C]O3-2 4.079e-19 2.859e-19 -18.389 -18.544 -0.154 (0) + CaH[14C]O2[18O]+ 2.897e-20 2.658e-20 -19.538 -19.575 -0.037 (0) + CaH[14C]O[18O]O+ 2.897e-20 2.658e-20 -19.538 -19.575 -0.037 (0) + CaH[14C][18O]O2+ 2.897e-20 2.658e-20 -19.538 -19.575 -0.037 (0) + Ca[14C]O2[18O] 4.764e-21 4.772e-21 -20.322 -20.321 0.001 (0) + H[14C]O[18O]2- 2.736e-21 2.504e-21 -20.563 -20.601 -0.039 (0) + H[14C][18O]2O- 2.736e-21 2.504e-21 -20.563 -20.601 -0.039 (0) + H[14C][18O]O[18O]- 2.736e-21 2.504e-21 -20.563 -20.601 -0.039 (0) + [14C]O2[18O]-2 2.442e-21 1.711e-21 -20.612 -20.767 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.586e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.813e-15 + O[18O] 2.807e-15 2.812e-15 -14.552 -14.551 0.001 (0) + [18O]2 2.800e-18 2.805e-18 -17.553 -17.552 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -40287,99 +40287,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.455 -126.454 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.081e-08 6.091e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.112 -40.111 0.001 -O(0) 1.390e-12 - O2 6.923e-13 6.935e-13 -12.160 -12.159 0.001 - O[18O] 2.763e-15 2.767e-15 -14.559 -14.558 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.412 -128.411 0.001 -[13C](4) 6.503e-05 - H[13C]O3- 5.245e-05 4.799e-05 -4.280 -4.319 -0.039 - [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.016e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.081e-08 6.091e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.580e-08 4.587e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.117e-08 2.185e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.640e-10 3.646e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.884 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.306 -139.305 0.001 -[14C](4) 8.360e-16 - H[14C]O3- 6.753e-16 6.179e-16 -15.171 -15.209 -0.039 - [14C]O2 1.406e-16 1.408e-16 -15.852 -15.851 0.001 - CaH[14C]O3+ 1.427e-17 1.309e-17 -16.846 -16.883 -0.037 - H[14C]O2[18O]- 1.347e-18 1.233e-18 -17.871 -17.909 -0.039 - H[14C]O[18O]O- 1.347e-18 1.233e-18 -17.871 -17.909 -0.039 - H[14C][18O]O2- 1.347e-18 1.233e-18 -17.871 -17.909 -0.039 - Ca[14C]O3 7.818e-19 7.831e-19 -18.107 -18.106 0.001 - [14C]O[18O] 5.846e-19 5.855e-19 -18.233 -18.232 0.001 - [14C]O3-2 4.007e-19 2.809e-19 -18.397 -18.551 -0.154 - CaH[14C]O2[18O]+ 2.846e-20 2.611e-20 -19.546 -19.583 -0.037 - CaH[14C]O[18O]O+ 2.846e-20 2.611e-20 -19.546 -19.583 -0.037 - CaH[14C][18O]O2+ 2.846e-20 2.611e-20 -19.546 -19.583 -0.037 - Ca[14C]O2[18O] 4.680e-21 4.688e-21 -20.330 -20.329 0.001 - H[14C]O[18O]2- 2.688e-21 2.460e-21 -20.571 -20.609 -0.039 - H[14C][18O]2O- 2.688e-21 2.460e-21 -20.571 -20.609 -0.039 - H[14C][18O]O[18O]- 2.688e-21 2.460e-21 -20.571 -20.609 -0.039 - [14C]O2[18O]-2 2.399e-21 1.681e-21 -20.620 -20.774 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.768e-15 - O[18O] 2.763e-15 2.767e-15 -14.559 -14.558 0.001 - [18O]2 2.756e-18 2.761e-18 -17.560 -17.559 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.455 -126.454 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.081e-08 6.091e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.112 -40.111 0.001 (0) +O(0) 1.390e-12 + O2 6.923e-13 6.935e-13 -12.160 -12.159 0.001 (0) + O[18O] 2.763e-15 2.767e-15 -14.559 -14.558 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.412 -128.411 0.001 (0) +[13C](4) 6.503e-05 + H[13C]O3- 5.245e-05 4.799e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.016e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.046e-07 9.575e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.081e-08 6.091e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.580e-08 4.587e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.117e-08 2.185e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.640e-10 3.646e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.884 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.306 -139.305 0.001 (0) +[14C](4) 8.360e-16 + H[14C]O3- 6.753e-16 6.179e-16 -15.171 -15.209 -0.039 (0) + [14C]O2 1.406e-16 1.408e-16 -15.852 -15.851 0.001 (0) + CaH[14C]O3+ 1.427e-17 1.309e-17 -16.846 -16.883 -0.037 (0) + H[14C]O2[18O]- 1.347e-18 1.233e-18 -17.871 -17.909 -0.039 (0) + H[14C]O[18O]O- 1.347e-18 1.233e-18 -17.871 -17.909 -0.039 (0) + H[14C][18O]O2- 1.347e-18 1.233e-18 -17.871 -17.909 -0.039 (0) + Ca[14C]O3 7.818e-19 7.831e-19 -18.107 -18.106 0.001 (0) + [14C]O[18O] 5.846e-19 5.855e-19 -18.233 -18.232 0.001 (0) + [14C]O3-2 4.007e-19 2.809e-19 -18.397 -18.551 -0.154 (0) + CaH[14C]O2[18O]+ 2.846e-20 2.611e-20 -19.546 -19.583 -0.037 (0) + CaH[14C]O[18O]O+ 2.846e-20 2.611e-20 -19.546 -19.583 -0.037 (0) + CaH[14C][18O]O2+ 2.846e-20 2.611e-20 -19.546 -19.583 -0.037 (0) + Ca[14C]O2[18O] 4.680e-21 4.688e-21 -20.330 -20.329 0.001 (0) + H[14C]O[18O]2- 2.688e-21 2.460e-21 -20.571 -20.609 -0.039 (0) + H[14C][18O]2O- 2.688e-21 2.460e-21 -20.571 -20.609 -0.039 (0) + H[14C][18O]O[18O]- 2.688e-21 2.460e-21 -20.571 -20.609 -0.039 (0) + [14C]O2[18O]-2 2.399e-21 1.681e-21 -20.620 -20.774 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.768e-15 + O[18O] 2.763e-15 2.767e-15 -14.559 -14.558 0.001 (0) + [18O]2 2.756e-18 2.761e-18 -17.560 -17.559 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -40542,99 +40542,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.460 -126.459 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.113 -40.113 0.001 -O(0) 1.398e-12 - O2 6.960e-13 6.972e-13 -12.157 -12.157 0.001 - O[18O] 2.777e-15 2.782e-15 -14.556 -14.556 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.416 -128.415 0.001 -[13C](4) 6.503e-05 - H[13C]O3- 5.245e-05 4.799e-05 -4.280 -4.319 -0.039 - [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.575e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.575e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.575e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.580e-08 4.588e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.117e-08 2.185e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.640e-10 3.646e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.318 -139.317 0.001 -[14C](4) 8.216e-16 - H[14C]O3- 6.636e-16 6.072e-16 -15.178 -15.217 -0.039 - [14C]O2 1.381e-16 1.384e-16 -15.860 -15.859 0.001 - CaH[14C]O3+ 1.402e-17 1.286e-17 -16.853 -16.891 -0.037 - H[14C]O2[18O]- 1.324e-18 1.211e-18 -17.878 -17.917 -0.039 - H[14C]O[18O]O- 1.324e-18 1.211e-18 -17.878 -17.917 -0.039 - H[14C][18O]O2- 1.324e-18 1.211e-18 -17.878 -17.917 -0.039 - Ca[14C]O3 7.683e-19 7.696e-19 -18.114 -18.114 0.001 - [14C]O[18O] 5.745e-19 5.754e-19 -18.241 -18.240 0.001 - [14C]O3-2 3.938e-19 2.760e-19 -18.405 -18.559 -0.154 - CaH[14C]O2[18O]+ 2.797e-20 2.566e-20 -19.553 -19.591 -0.037 - CaH[14C]O[18O]O+ 2.797e-20 2.566e-20 -19.553 -19.591 -0.037 - CaH[14C][18O]O2+ 2.797e-20 2.566e-20 -19.553 -19.591 -0.037 - Ca[14C]O2[18O] 4.599e-21 4.606e-21 -20.337 -20.337 0.001 - H[14C]O[18O]2- 2.642e-21 2.417e-21 -20.578 -20.617 -0.039 - H[14C][18O]2O- 2.642e-21 2.417e-21 -20.578 -20.617 -0.039 - H[14C][18O]O[18O]- 2.642e-21 2.417e-21 -20.578 -20.617 -0.039 - [14C]O2[18O]-2 2.357e-21 1.652e-21 -20.628 -20.782 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.783e-15 - O[18O] 2.777e-15 2.782e-15 -14.556 -14.556 0.001 - [18O]2 2.771e-18 2.775e-18 -17.557 -17.557 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.460 -126.459 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.113 -40.113 0.001 (0) +O(0) 1.398e-12 + O2 6.960e-13 6.972e-13 -12.157 -12.157 0.001 (0) + O[18O] 2.777e-15 2.782e-15 -14.556 -14.556 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.416 -128.415 0.001 (0) +[13C](4) 6.503e-05 + H[13C]O3- 5.245e-05 4.799e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.575e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.575e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.575e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.580e-08 4.588e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.117e-08 2.185e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.640e-10 3.646e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.088e-10 1.910e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.318 -139.317 0.001 (0) +[14C](4) 8.216e-16 + H[14C]O3- 6.636e-16 6.072e-16 -15.178 -15.217 -0.039 (0) + [14C]O2 1.381e-16 1.384e-16 -15.860 -15.859 0.001 (0) + CaH[14C]O3+ 1.402e-17 1.286e-17 -16.853 -16.891 -0.037 (0) + H[14C]O2[18O]- 1.324e-18 1.211e-18 -17.878 -17.917 -0.039 (0) + H[14C]O[18O]O- 1.324e-18 1.211e-18 -17.878 -17.917 -0.039 (0) + H[14C][18O]O2- 1.324e-18 1.211e-18 -17.878 -17.917 -0.039 (0) + Ca[14C]O3 7.683e-19 7.696e-19 -18.114 -18.114 0.001 (0) + [14C]O[18O] 5.745e-19 5.754e-19 -18.241 -18.240 0.001 (0) + [14C]O3-2 3.938e-19 2.760e-19 -18.405 -18.559 -0.154 (0) + CaH[14C]O2[18O]+ 2.797e-20 2.566e-20 -19.553 -19.591 -0.037 (0) + CaH[14C]O[18O]O+ 2.797e-20 2.566e-20 -19.553 -19.591 -0.037 (0) + CaH[14C][18O]O2+ 2.797e-20 2.566e-20 -19.553 -19.591 -0.037 (0) + Ca[14C]O2[18O] 4.599e-21 4.606e-21 -20.337 -20.337 0.001 (0) + H[14C]O[18O]2- 2.642e-21 2.417e-21 -20.578 -20.617 -0.039 (0) + H[14C][18O]2O- 2.642e-21 2.417e-21 -20.578 -20.617 -0.039 (0) + H[14C][18O]O[18O]- 2.642e-21 2.417e-21 -20.578 -20.617 -0.039 (0) + [14C]O2[18O]-2 2.357e-21 1.652e-21 -20.628 -20.782 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.783e-15 + O[18O] 2.777e-15 2.782e-15 -14.556 -14.556 0.001 (0) + [18O]2 2.771e-18 2.775e-18 -17.557 -17.557 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -40797,99 +40797,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.482 -126.481 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.119 -40.118 0.001 -O(0) 1.433e-12 - O2 7.137e-13 7.149e-13 -12.146 -12.146 0.001 - O[18O] 2.848e-15 2.853e-15 -14.545 -14.545 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.438 -128.437 0.001 -[13C](4) 6.504e-05 - H[13C]O3- 5.245e-05 4.799e-05 -4.280 -4.319 -0.039 - [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.576e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.576e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.576e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.580e-08 4.588e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.117e-08 2.185e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.640e-10 3.646e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.347 -139.346 0.001 -[14C](4) 8.076e-16 - H[14C]O3- 6.523e-16 5.969e-16 -15.186 -15.224 -0.039 - [14C]O2 1.358e-16 1.360e-16 -15.867 -15.866 0.001 - CaH[14C]O3+ 1.378e-17 1.264e-17 -16.861 -16.898 -0.037 - H[14C]O2[18O]- 1.302e-18 1.191e-18 -17.886 -17.924 -0.039 - H[14C]O[18O]O- 1.302e-18 1.191e-18 -17.886 -17.924 -0.039 - H[14C][18O]O2- 1.302e-18 1.191e-18 -17.886 -17.924 -0.039 - Ca[14C]O3 7.553e-19 7.565e-19 -18.122 -18.121 0.001 - [14C]O[18O] 5.647e-19 5.656e-19 -18.248 -18.247 0.001 - [14C]O3-2 3.871e-19 2.713e-19 -18.412 -18.567 -0.154 - CaH[14C]O2[18O]+ 2.749e-20 2.522e-20 -19.561 -19.598 -0.037 - CaH[14C]O[18O]O+ 2.749e-20 2.522e-20 -19.561 -19.598 -0.037 - CaH[14C][18O]O2+ 2.749e-20 2.522e-20 -19.561 -19.598 -0.037 - Ca[14C]O2[18O] 4.521e-21 4.528e-21 -20.345 -20.344 0.001 - H[14C]O[18O]2- 2.597e-21 2.376e-21 -20.586 -20.624 -0.039 - H[14C][18O]2O- 2.597e-21 2.376e-21 -20.586 -20.624 -0.039 - H[14C][18O]O[18O]- 2.597e-21 2.376e-21 -20.586 -20.624 -0.039 - [14C]O2[18O]-2 2.317e-21 1.624e-21 -20.635 -20.789 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.854e-15 - O[18O] 2.848e-15 2.853e-15 -14.545 -14.545 0.001 - [18O]2 2.841e-18 2.846e-18 -17.547 -17.546 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.482 -126.481 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.119 -40.118 0.001 (0) +O(0) 1.433e-12 + O2 7.137e-13 7.149e-13 -12.146 -12.146 0.001 (0) + O[18O] 2.848e-15 2.853e-15 -14.545 -14.545 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.438 -128.437 0.001 (0) +[13C](4) 6.504e-05 + H[13C]O3- 5.245e-05 4.799e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.101e-05 1.103e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.576e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.576e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.576e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.580e-08 4.588e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.117e-08 2.185e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.640e-10 3.646e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.347 -139.346 0.001 (0) +[14C](4) 8.076e-16 + H[14C]O3- 6.523e-16 5.969e-16 -15.186 -15.224 -0.039 (0) + [14C]O2 1.358e-16 1.360e-16 -15.867 -15.866 0.001 (0) + CaH[14C]O3+ 1.378e-17 1.264e-17 -16.861 -16.898 -0.037 (0) + H[14C]O2[18O]- 1.302e-18 1.191e-18 -17.886 -17.924 -0.039 (0) + H[14C]O[18O]O- 1.302e-18 1.191e-18 -17.886 -17.924 -0.039 (0) + H[14C][18O]O2- 1.302e-18 1.191e-18 -17.886 -17.924 -0.039 (0) + Ca[14C]O3 7.553e-19 7.565e-19 -18.122 -18.121 0.001 (0) + [14C]O[18O] 5.647e-19 5.656e-19 -18.248 -18.247 0.001 (0) + [14C]O3-2 3.871e-19 2.713e-19 -18.412 -18.567 -0.154 (0) + CaH[14C]O2[18O]+ 2.749e-20 2.522e-20 -19.561 -19.598 -0.037 (0) + CaH[14C]O[18O]O+ 2.749e-20 2.522e-20 -19.561 -19.598 -0.037 (0) + CaH[14C][18O]O2+ 2.749e-20 2.522e-20 -19.561 -19.598 -0.037 (0) + Ca[14C]O2[18O] 4.521e-21 4.528e-21 -20.345 -20.344 0.001 (0) + H[14C]O[18O]2- 2.597e-21 2.376e-21 -20.586 -20.624 -0.039 (0) + H[14C][18O]2O- 2.597e-21 2.376e-21 -20.586 -20.624 -0.039 (0) + H[14C][18O]O[18O]- 2.597e-21 2.376e-21 -20.586 -20.624 -0.039 (0) + [14C]O2[18O]-2 2.317e-21 1.624e-21 -20.635 -20.789 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.854e-15 + O[18O] 2.848e-15 2.853e-15 -14.545 -14.545 0.001 (0) + [18O]2 2.841e-18 2.846e-18 -17.547 -17.546 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -41052,99 +41052,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.480 -126.480 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.118 -40.118 0.001 -O(0) 1.431e-12 - O2 7.127e-13 7.139e-13 -12.147 -12.146 0.001 - O[18O] 2.844e-15 2.849e-15 -14.546 -14.545 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.437 -128.436 0.001 -[13C](4) 6.504e-05 - H[13C]O3- 5.246e-05 4.800e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.103e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.576e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.576e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.576e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.580e-08 4.588e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.117e-08 2.185e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.640e-10 3.646e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.353 -139.352 0.001 -[14C](4) 7.941e-16 - H[14C]O3- 6.414e-16 5.869e-16 -15.193 -15.231 -0.039 - [14C]O2 1.335e-16 1.337e-16 -15.874 -15.874 0.001 - CaH[14C]O3+ 1.355e-17 1.243e-17 -16.868 -16.905 -0.037 - H[14C]O2[18O]- 1.280e-18 1.171e-18 -17.893 -17.931 -0.039 - H[14C]O[18O]O- 1.280e-18 1.171e-18 -17.893 -17.931 -0.039 - H[14C][18O]O2- 1.280e-18 1.171e-18 -17.893 -17.931 -0.039 - Ca[14C]O3 7.426e-19 7.439e-19 -18.129 -18.129 0.001 - [14C]O[18O] 5.553e-19 5.562e-19 -18.256 -18.255 0.001 - [14C]O3-2 3.806e-19 2.668e-19 -18.420 -18.574 -0.154 - CaH[14C]O2[18O]+ 2.703e-20 2.480e-20 -19.568 -19.606 -0.037 - CaH[14C]O[18O]O+ 2.703e-20 2.480e-20 -19.568 -19.606 -0.037 - CaH[14C][18O]O2+ 2.703e-20 2.480e-20 -19.568 -19.606 -0.037 - Ca[14C]O2[18O] 4.445e-21 4.452e-21 -20.352 -20.351 0.001 - H[14C]O[18O]2- 2.553e-21 2.336e-21 -20.593 -20.631 -0.039 - H[14C][18O]2O- 2.553e-21 2.336e-21 -20.593 -20.631 -0.039 - H[14C][18O]O[18O]- 2.553e-21 2.336e-21 -20.593 -20.631 -0.039 - [14C]O2[18O]-2 2.278e-21 1.597e-21 -20.642 -20.797 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.850e-15 - O[18O] 2.844e-15 2.849e-15 -14.546 -14.545 0.001 - [18O]2 2.837e-18 2.842e-18 -17.547 -17.546 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.480 -126.480 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.118 -40.118 0.001 (0) +O(0) 1.431e-12 + O2 7.127e-13 7.139e-13 -12.147 -12.146 0.001 (0) + O[18O] 2.844e-15 2.849e-15 -14.546 -14.545 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.437 -128.436 0.001 (0) +[13C](4) 6.504e-05 + H[13C]O3- 5.246e-05 4.800e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.103e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.576e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.576e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.576e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.580e-08 4.588e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.117e-08 2.185e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.640e-10 3.646e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.353 -139.352 0.001 (0) +[14C](4) 7.941e-16 + H[14C]O3- 6.414e-16 5.869e-16 -15.193 -15.231 -0.039 (0) + [14C]O2 1.335e-16 1.337e-16 -15.874 -15.874 0.001 (0) + CaH[14C]O3+ 1.355e-17 1.243e-17 -16.868 -16.905 -0.037 (0) + H[14C]O2[18O]- 1.280e-18 1.171e-18 -17.893 -17.931 -0.039 (0) + H[14C]O[18O]O- 1.280e-18 1.171e-18 -17.893 -17.931 -0.039 (0) + H[14C][18O]O2- 1.280e-18 1.171e-18 -17.893 -17.931 -0.039 (0) + Ca[14C]O3 7.426e-19 7.439e-19 -18.129 -18.129 0.001 (0) + [14C]O[18O] 5.553e-19 5.562e-19 -18.256 -18.255 0.001 (0) + [14C]O3-2 3.806e-19 2.668e-19 -18.420 -18.574 -0.154 (0) + CaH[14C]O2[18O]+ 2.703e-20 2.480e-20 -19.568 -19.606 -0.037 (0) + CaH[14C]O[18O]O+ 2.703e-20 2.480e-20 -19.568 -19.606 -0.037 (0) + CaH[14C][18O]O2+ 2.703e-20 2.480e-20 -19.568 -19.606 -0.037 (0) + Ca[14C]O2[18O] 4.445e-21 4.452e-21 -20.352 -20.351 0.001 (0) + H[14C]O[18O]2- 2.553e-21 2.336e-21 -20.593 -20.631 -0.039 (0) + H[14C][18O]2O- 2.553e-21 2.336e-21 -20.593 -20.631 -0.039 (0) + H[14C][18O]O[18O]- 2.553e-21 2.336e-21 -20.593 -20.631 -0.039 (0) + [14C]O2[18O]-2 2.278e-21 1.597e-21 -20.642 -20.797 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.850e-15 + O[18O] 2.844e-15 2.849e-15 -14.546 -14.545 0.001 (0) + [18O]2 2.837e-18 2.842e-18 -17.547 -17.546 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -41307,99 +41307,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.491 -126.490 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.121 -40.120 0.001 -O(0) 1.449e-12 - O2 7.214e-13 7.226e-13 -12.142 -12.141 0.001 - O[18O] 2.879e-15 2.883e-15 -14.541 -14.540 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.447 -128.447 0.001 -[13C](4) 6.504e-05 - H[13C]O3- 5.246e-05 4.800e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.103e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.581e-08 4.588e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.117e-08 2.185e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.371 -139.370 0.001 -[14C](4) 7.811e-16 - H[14C]O3- 6.309e-16 5.772e-16 -15.200 -15.239 -0.039 - [14C]O2 1.313e-16 1.315e-16 -15.882 -15.881 0.001 - CaH[14C]O3+ 1.333e-17 1.223e-17 -16.875 -16.913 -0.037 - H[14C]O2[18O]- 1.259e-18 1.152e-18 -17.900 -17.939 -0.039 - H[14C]O[18O]O- 1.259e-18 1.152e-18 -17.900 -17.939 -0.039 - H[14C][18O]O2- 1.259e-18 1.152e-18 -17.900 -17.939 -0.039 - Ca[14C]O3 7.304e-19 7.316e-19 -18.136 -18.136 0.001 - [14C]O[18O] 5.461e-19 5.470e-19 -18.263 -18.262 0.001 - [14C]O3-2 3.744e-19 2.624e-19 -18.427 -18.581 -0.154 - CaH[14C]O2[18O]+ 2.659e-20 2.439e-20 -19.575 -19.613 -0.037 - CaH[14C]O[18O]O+ 2.659e-20 2.439e-20 -19.575 -19.613 -0.037 - CaH[14C][18O]O2+ 2.659e-20 2.439e-20 -19.575 -19.613 -0.037 - Ca[14C]O2[18O] 4.372e-21 4.379e-21 -20.359 -20.359 0.001 - H[14C]O[18O]2- 2.511e-21 2.298e-21 -20.600 -20.639 -0.039 - H[14C][18O]2O- 2.511e-21 2.298e-21 -20.600 -20.639 -0.039 - H[14C][18O]O[18O]- 2.511e-21 2.298e-21 -20.600 -20.639 -0.039 - [14C]O2[18O]-2 2.241e-21 1.571e-21 -20.650 -20.804 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.884e-15 - O[18O] 2.879e-15 2.883e-15 -14.541 -14.540 0.001 - [18O]2 2.872e-18 2.876e-18 -17.542 -17.541 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.491 -126.490 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.121 -40.120 0.001 (0) +O(0) 1.449e-12 + O2 7.214e-13 7.226e-13 -12.142 -12.141 0.001 (0) + O[18O] 2.879e-15 2.883e-15 -14.541 -14.540 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.447 -128.447 0.001 (0) +[13C](4) 6.504e-05 + H[13C]O3- 5.246e-05 4.800e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.103e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.082e-08 6.092e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.581e-08 4.588e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.117e-08 2.185e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.371 -139.370 0.001 (0) +[14C](4) 7.811e-16 + H[14C]O3- 6.309e-16 5.772e-16 -15.200 -15.239 -0.039 (0) + [14C]O2 1.313e-16 1.315e-16 -15.882 -15.881 0.001 (0) + CaH[14C]O3+ 1.333e-17 1.223e-17 -16.875 -16.913 -0.037 (0) + H[14C]O2[18O]- 1.259e-18 1.152e-18 -17.900 -17.939 -0.039 (0) + H[14C]O[18O]O- 1.259e-18 1.152e-18 -17.900 -17.939 -0.039 (0) + H[14C][18O]O2- 1.259e-18 1.152e-18 -17.900 -17.939 -0.039 (0) + Ca[14C]O3 7.304e-19 7.316e-19 -18.136 -18.136 0.001 (0) + [14C]O[18O] 5.461e-19 5.470e-19 -18.263 -18.262 0.001 (0) + [14C]O3-2 3.744e-19 2.624e-19 -18.427 -18.581 -0.154 (0) + CaH[14C]O2[18O]+ 2.659e-20 2.439e-20 -19.575 -19.613 -0.037 (0) + CaH[14C]O[18O]O+ 2.659e-20 2.439e-20 -19.575 -19.613 -0.037 (0) + CaH[14C][18O]O2+ 2.659e-20 2.439e-20 -19.575 -19.613 -0.037 (0) + Ca[14C]O2[18O] 4.372e-21 4.379e-21 -20.359 -20.359 0.001 (0) + H[14C]O[18O]2- 2.511e-21 2.298e-21 -20.600 -20.639 -0.039 (0) + H[14C][18O]2O- 2.511e-21 2.298e-21 -20.600 -20.639 -0.039 (0) + H[14C][18O]O[18O]- 2.511e-21 2.298e-21 -20.600 -20.639 -0.039 (0) + [14C]O2[18O]-2 2.241e-21 1.571e-21 -20.650 -20.804 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.884e-15 + O[18O] 2.879e-15 2.883e-15 -14.541 -14.540 0.001 (0) + [18O]2 2.872e-18 2.876e-18 -17.542 -17.541 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -41562,99 +41562,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.508 -126.507 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.125 -40.125 0.001 -O(0) 1.477e-12 - O2 7.356e-13 7.368e-13 -12.133 -12.133 0.001 - O[18O] 2.935e-15 2.940e-15 -14.532 -14.532 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.464 -128.463 0.001 -[13C](4) 6.504e-05 - H[13C]O3- 5.246e-05 4.800e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.103e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.581e-08 4.588e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.118e-08 2.185e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.395 -139.394 0.001 -[14C](4) 7.684e-16 - H[14C]O3- 6.207e-16 5.679e-16 -15.207 -15.246 -0.039 - [14C]O2 1.292e-16 1.294e-16 -15.889 -15.888 0.001 - CaH[14C]O3+ 1.311e-17 1.203e-17 -16.882 -16.920 -0.037 - H[14C]O2[18O]- 1.238e-18 1.133e-18 -17.907 -17.946 -0.039 - H[14C]O[18O]O- 1.238e-18 1.133e-18 -17.907 -17.946 -0.039 - H[14C][18O]O2- 1.238e-18 1.133e-18 -17.907 -17.946 -0.039 - Ca[14C]O3 7.186e-19 7.198e-19 -18.144 -18.143 0.001 - [14C]O[18O] 5.373e-19 5.382e-19 -18.270 -18.269 0.001 - [14C]O3-2 3.683e-19 2.582e-19 -18.434 -18.588 -0.154 - CaH[14C]O2[18O]+ 2.616e-20 2.400e-20 -19.582 -19.620 -0.037 - CaH[14C]O[18O]O+ 2.616e-20 2.400e-20 -19.582 -19.620 -0.037 - CaH[14C][18O]O2+ 2.616e-20 2.400e-20 -19.582 -19.620 -0.037 - Ca[14C]O2[18O] 4.301e-21 4.308e-21 -20.366 -20.366 0.001 - H[14C]O[18O]2- 2.471e-21 2.261e-21 -20.607 -20.646 -0.039 - H[14C][18O]2O- 2.471e-21 2.261e-21 -20.607 -20.646 -0.039 - H[14C][18O]O[18O]- 2.471e-21 2.261e-21 -20.607 -20.646 -0.039 - [14C]O2[18O]-2 2.205e-21 1.545e-21 -20.657 -20.811 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.941e-15 - O[18O] 2.935e-15 2.940e-15 -14.532 -14.532 0.001 - [18O]2 2.928e-18 2.933e-18 -17.533 -17.533 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.508 -126.507 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.125 -40.125 0.001 (0) +O(0) 1.477e-12 + O2 7.356e-13 7.368e-13 -12.133 -12.133 0.001 (0) + O[18O] 2.935e-15 2.940e-15 -14.532 -14.532 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.464 -128.463 0.001 (0) +[13C](4) 6.504e-05 + H[13C]O3- 5.246e-05 4.800e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.103e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.581e-08 4.588e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.118e-08 2.185e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.211e-09 2.028e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.395 -139.394 0.001 (0) +[14C](4) 7.684e-16 + H[14C]O3- 6.207e-16 5.679e-16 -15.207 -15.246 -0.039 (0) + [14C]O2 1.292e-16 1.294e-16 -15.889 -15.888 0.001 (0) + CaH[14C]O3+ 1.311e-17 1.203e-17 -16.882 -16.920 -0.037 (0) + H[14C]O2[18O]- 1.238e-18 1.133e-18 -17.907 -17.946 -0.039 (0) + H[14C]O[18O]O- 1.238e-18 1.133e-18 -17.907 -17.946 -0.039 (0) + H[14C][18O]O2- 1.238e-18 1.133e-18 -17.907 -17.946 -0.039 (0) + Ca[14C]O3 7.186e-19 7.198e-19 -18.144 -18.143 0.001 (0) + [14C]O[18O] 5.373e-19 5.382e-19 -18.270 -18.269 0.001 (0) + [14C]O3-2 3.683e-19 2.582e-19 -18.434 -18.588 -0.154 (0) + CaH[14C]O2[18O]+ 2.616e-20 2.400e-20 -19.582 -19.620 -0.037 (0) + CaH[14C]O[18O]O+ 2.616e-20 2.400e-20 -19.582 -19.620 -0.037 (0) + CaH[14C][18O]O2+ 2.616e-20 2.400e-20 -19.582 -19.620 -0.037 (0) + Ca[14C]O2[18O] 4.301e-21 4.308e-21 -20.366 -20.366 0.001 (0) + H[14C]O[18O]2- 2.471e-21 2.261e-21 -20.607 -20.646 -0.039 (0) + H[14C][18O]2O- 2.471e-21 2.261e-21 -20.607 -20.646 -0.039 (0) + H[14C][18O]O[18O]- 2.471e-21 2.261e-21 -20.607 -20.646 -0.039 (0) + [14C]O2[18O]-2 2.205e-21 1.545e-21 -20.657 -20.811 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.941e-15 + O[18O] 2.935e-15 2.940e-15 -14.532 -14.532 0.001 (0) + [18O]2 2.928e-18 2.933e-18 -17.533 -17.533 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -41817,99 +41817,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.507 -126.506 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.125 -40.124 0.001 -O(0) 1.476e-12 - O2 7.348e-13 7.360e-13 -12.134 -12.133 0.001 - O[18O] 2.932e-15 2.937e-15 -14.533 -14.532 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.463 -128.463 0.001 -[13C](4) 6.505e-05 - H[13C]O3- 5.246e-05 4.800e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.103e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.581e-08 4.588e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.118e-08 2.185e-08 -7.506 -7.661 -0.154 - CaH[13C]O2[18O]+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.401 -139.400 0.001 -[14C](4) 7.562e-16 - H[14C]O3- 6.108e-16 5.589e-16 -15.214 -15.253 -0.039 - [14C]O2 1.271e-16 1.274e-16 -15.896 -15.895 0.001 - CaH[14C]O3+ 1.290e-17 1.184e-17 -16.889 -16.927 -0.037 - H[14C]O2[18O]- 1.219e-18 1.115e-18 -17.914 -17.953 -0.039 - H[14C]O[18O]O- 1.219e-18 1.115e-18 -17.914 -17.953 -0.039 - H[14C][18O]O2- 1.219e-18 1.115e-18 -17.914 -17.953 -0.039 - Ca[14C]O3 7.072e-19 7.083e-19 -18.150 -18.150 0.001 - [14C]O[18O] 5.287e-19 5.296e-19 -18.277 -18.276 0.001 - [14C]O3-2 3.624e-19 2.540e-19 -18.441 -18.595 -0.154 - CaH[14C]O2[18O]+ 2.574e-20 2.362e-20 -19.589 -19.627 -0.037 - CaH[14C]O[18O]O+ 2.574e-20 2.362e-20 -19.589 -19.627 -0.037 - CaH[14C][18O]O2+ 2.574e-20 2.362e-20 -19.589 -19.627 -0.037 - Ca[14C]O2[18O] 4.233e-21 4.240e-21 -20.373 -20.373 0.001 - H[14C]O[18O]2- 2.431e-21 2.225e-21 -20.614 -20.653 -0.039 - H[14C][18O]2O- 2.431e-21 2.225e-21 -20.614 -20.653 -0.039 - H[14C][18O]O[18O]- 2.431e-21 2.225e-21 -20.614 -20.653 -0.039 - [14C]O2[18O]-2 2.169e-21 1.521e-21 -20.664 -20.818 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.938e-15 - O[18O] 2.932e-15 2.937e-15 -14.533 -14.532 0.001 - [18O]2 2.925e-18 2.930e-18 -17.534 -17.533 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.507 -126.506 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.125 -40.124 0.001 (0) +O(0) 1.476e-12 + O2 7.348e-13 7.360e-13 -12.134 -12.133 0.001 (0) + O[18O] 2.932e-15 2.937e-15 -14.533 -14.532 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.463 -128.463 0.001 (0) +[13C](4) 6.505e-05 + H[13C]O3- 5.246e-05 4.800e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.103e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.577e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.581e-08 4.588e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.118e-08 2.185e-08 -7.506 -7.661 -0.154 (0) + CaH[13C]O2[18O]+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.401 -139.400 0.001 (0) +[14C](4) 7.562e-16 + H[14C]O3- 6.108e-16 5.589e-16 -15.214 -15.253 -0.039 (0) + [14C]O2 1.271e-16 1.274e-16 -15.896 -15.895 0.001 (0) + CaH[14C]O3+ 1.290e-17 1.184e-17 -16.889 -16.927 -0.037 (0) + H[14C]O2[18O]- 1.219e-18 1.115e-18 -17.914 -17.953 -0.039 (0) + H[14C]O[18O]O- 1.219e-18 1.115e-18 -17.914 -17.953 -0.039 (0) + H[14C][18O]O2- 1.219e-18 1.115e-18 -17.914 -17.953 -0.039 (0) + Ca[14C]O3 7.072e-19 7.083e-19 -18.150 -18.150 0.001 (0) + [14C]O[18O] 5.287e-19 5.296e-19 -18.277 -18.276 0.001 (0) + [14C]O3-2 3.624e-19 2.540e-19 -18.441 -18.595 -0.154 (0) + CaH[14C]O2[18O]+ 2.574e-20 2.362e-20 -19.589 -19.627 -0.037 (0) + CaH[14C]O[18O]O+ 2.574e-20 2.362e-20 -19.589 -19.627 -0.037 (0) + CaH[14C][18O]O2+ 2.574e-20 2.362e-20 -19.589 -19.627 -0.037 (0) + Ca[14C]O2[18O] 4.233e-21 4.240e-21 -20.373 -20.373 0.001 (0) + H[14C]O[18O]2- 2.431e-21 2.225e-21 -20.614 -20.653 -0.039 (0) + H[14C][18O]2O- 2.431e-21 2.225e-21 -20.614 -20.653 -0.039 (0) + H[14C][18O]O[18O]- 2.431e-21 2.225e-21 -20.614 -20.653 -0.039 (0) + [14C]O2[18O]-2 2.169e-21 1.521e-21 -20.664 -20.818 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.938e-15 + O[18O] 2.932e-15 2.937e-15 -14.533 -14.532 0.001 (0) + [18O]2 2.925e-18 2.930e-18 -17.534 -17.533 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -42072,99 +42072,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.510 -126.509 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.126 -40.125 0.001 -O(0) 1.480e-12 - O2 7.370e-13 7.382e-13 -12.133 -12.132 0.001 - O[18O] 2.941e-15 2.946e-15 -14.532 -14.531 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.466 -128.465 0.001 -[13C](4) 6.505e-05 - H[13C]O3- 5.246e-05 4.800e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.103e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.581e-08 4.589e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.118e-08 2.185e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.410 -139.410 0.001 -[14C](4) 7.443e-16 - H[14C]O3- 6.012e-16 5.501e-16 -15.221 -15.260 -0.039 - [14C]O2 1.252e-16 1.254e-16 -15.903 -15.902 0.001 - CaH[14C]O3+ 1.270e-17 1.165e-17 -16.896 -16.934 -0.037 - H[14C]O2[18O]- 1.200e-18 1.098e-18 -17.921 -17.960 -0.039 - H[14C]O[18O]O- 1.200e-18 1.098e-18 -17.921 -17.960 -0.039 - H[14C][18O]O2- 1.200e-18 1.098e-18 -17.921 -17.960 -0.039 - Ca[14C]O3 6.961e-19 6.972e-19 -18.157 -18.157 0.001 - [14C]O[18O] 5.204e-19 5.213e-19 -18.284 -18.283 0.001 - [14C]O3-2 3.568e-19 2.501e-19 -18.448 -18.602 -0.154 - CaH[14C]O2[18O]+ 2.534e-20 2.325e-20 -19.596 -19.634 -0.037 - CaH[14C]O[18O]O+ 2.534e-20 2.325e-20 -19.596 -19.634 -0.037 - CaH[14C][18O]O2+ 2.534e-20 2.325e-20 -19.596 -19.634 -0.037 - Ca[14C]O2[18O] 4.166e-21 4.173e-21 -20.380 -20.380 0.001 - H[14C]O[18O]2- 2.393e-21 2.190e-21 -20.621 -20.660 -0.039 - H[14C][18O]2O- 2.393e-21 2.190e-21 -20.621 -20.660 -0.039 - H[14C][18O]O[18O]- 2.393e-21 2.190e-21 -20.621 -20.660 -0.039 - [14C]O2[18O]-2 2.135e-21 1.497e-21 -20.671 -20.825 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.947e-15 - O[18O] 2.941e-15 2.946e-15 -14.532 -14.531 0.001 - [18O]2 2.934e-18 2.939e-18 -17.533 -17.532 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.510 -126.509 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.126 -40.125 0.001 (0) +O(0) 1.480e-12 + O2 7.370e-13 7.382e-13 -12.133 -12.132 0.001 (0) + O[18O] 2.941e-15 2.946e-15 -14.532 -14.531 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.466 -128.465 0.001 (0) +[13C](4) 6.505e-05 + H[13C]O3- 5.246e-05 4.800e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.103e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.581e-08 4.589e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.118e-08 2.185e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.088e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.410 -139.410 0.001 (0) +[14C](4) 7.443e-16 + H[14C]O3- 6.012e-16 5.501e-16 -15.221 -15.260 -0.039 (0) + [14C]O2 1.252e-16 1.254e-16 -15.903 -15.902 0.001 (0) + CaH[14C]O3+ 1.270e-17 1.165e-17 -16.896 -16.934 -0.037 (0) + H[14C]O2[18O]- 1.200e-18 1.098e-18 -17.921 -17.960 -0.039 (0) + H[14C]O[18O]O- 1.200e-18 1.098e-18 -17.921 -17.960 -0.039 (0) + H[14C][18O]O2- 1.200e-18 1.098e-18 -17.921 -17.960 -0.039 (0) + Ca[14C]O3 6.961e-19 6.972e-19 -18.157 -18.157 0.001 (0) + [14C]O[18O] 5.204e-19 5.213e-19 -18.284 -18.283 0.001 (0) + [14C]O3-2 3.568e-19 2.501e-19 -18.448 -18.602 -0.154 (0) + CaH[14C]O2[18O]+ 2.534e-20 2.325e-20 -19.596 -19.634 -0.037 (0) + CaH[14C]O[18O]O+ 2.534e-20 2.325e-20 -19.596 -19.634 -0.037 (0) + CaH[14C][18O]O2+ 2.534e-20 2.325e-20 -19.596 -19.634 -0.037 (0) + Ca[14C]O2[18O] 4.166e-21 4.173e-21 -20.380 -20.380 0.001 (0) + H[14C]O[18O]2- 2.393e-21 2.190e-21 -20.621 -20.660 -0.039 (0) + H[14C][18O]2O- 2.393e-21 2.190e-21 -20.621 -20.660 -0.039 (0) + H[14C][18O]O[18O]- 2.393e-21 2.190e-21 -20.621 -20.660 -0.039 (0) + [14C]O2[18O]-2 2.135e-21 1.497e-21 -20.671 -20.825 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.947e-15 + O[18O] 2.941e-15 2.946e-15 -14.532 -14.531 0.001 (0) + [18O]2 2.934e-18 2.939e-18 -17.533 -17.532 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -42327,99 +42327,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.517 -126.516 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.127 -40.127 0.001 -O(0) 1.492e-12 - O2 7.430e-13 7.442e-13 -12.129 -12.128 0.001 - O[18O] 2.965e-15 2.970e-15 -14.528 -14.527 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.473 -128.472 0.001 -[13C](4) 6.505e-05 - H[13C]O3- 5.247e-05 4.801e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.581e-08 4.589e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.118e-08 2.185e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.424 -139.423 0.001 -[14C](4) 7.328e-16 - H[14C]O3- 5.919e-16 5.416e-16 -15.228 -15.266 -0.039 - [14C]O2 1.232e-16 1.234e-16 -15.909 -15.909 0.001 - CaH[14C]O3+ 1.250e-17 1.147e-17 -16.903 -16.940 -0.037 - H[14C]O2[18O]- 1.181e-18 1.081e-18 -17.928 -17.966 -0.039 - H[14C]O[18O]O- 1.181e-18 1.081e-18 -17.928 -17.966 -0.039 - H[14C][18O]O2- 1.181e-18 1.081e-18 -17.928 -17.966 -0.039 - Ca[14C]O3 6.853e-19 6.865e-19 -18.164 -18.163 0.001 - [14C]O[18O] 5.124e-19 5.133e-19 -18.290 -18.290 0.001 - [14C]O3-2 3.513e-19 2.462e-19 -18.454 -18.609 -0.154 - CaH[14C]O2[18O]+ 2.495e-20 2.289e-20 -19.603 -19.640 -0.037 - CaH[14C]O[18O]O+ 2.495e-20 2.289e-20 -19.603 -19.640 -0.037 - CaH[14C][18O]O2+ 2.495e-20 2.289e-20 -19.603 -19.640 -0.037 - Ca[14C]O2[18O] 4.102e-21 4.109e-21 -20.387 -20.386 0.001 - H[14C]O[18O]2- 2.356e-21 2.156e-21 -20.628 -20.666 -0.039 - H[14C][18O]2O- 2.356e-21 2.156e-21 -20.628 -20.666 -0.039 - H[14C][18O]O[18O]- 2.356e-21 2.156e-21 -20.628 -20.666 -0.039 - [14C]O2[18O]-2 2.102e-21 1.474e-21 -20.677 -20.832 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.971e-15 - O[18O] 2.965e-15 2.970e-15 -14.528 -14.527 0.001 - [18O]2 2.958e-18 2.962e-18 -17.529 -17.528 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.517 -126.516 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.127 -40.127 0.001 (0) +O(0) 1.492e-12 + O2 7.430e-13 7.442e-13 -12.129 -12.128 0.001 (0) + O[18O] 2.965e-15 2.970e-15 -14.528 -14.527 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.473 -128.472 0.001 (0) +[13C](4) 6.505e-05 + H[13C]O3- 5.247e-05 4.801e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.581e-08 4.589e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.118e-08 2.185e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.424 -139.423 0.001 (0) +[14C](4) 7.328e-16 + H[14C]O3- 5.919e-16 5.416e-16 -15.228 -15.266 -0.039 (0) + [14C]O2 1.232e-16 1.234e-16 -15.909 -15.909 0.001 (0) + CaH[14C]O3+ 1.250e-17 1.147e-17 -16.903 -16.940 -0.037 (0) + H[14C]O2[18O]- 1.181e-18 1.081e-18 -17.928 -17.966 -0.039 (0) + H[14C]O[18O]O- 1.181e-18 1.081e-18 -17.928 -17.966 -0.039 (0) + H[14C][18O]O2- 1.181e-18 1.081e-18 -17.928 -17.966 -0.039 (0) + Ca[14C]O3 6.853e-19 6.865e-19 -18.164 -18.163 0.001 (0) + [14C]O[18O] 5.124e-19 5.133e-19 -18.290 -18.290 0.001 (0) + [14C]O3-2 3.513e-19 2.462e-19 -18.454 -18.609 -0.154 (0) + CaH[14C]O2[18O]+ 2.495e-20 2.289e-20 -19.603 -19.640 -0.037 (0) + CaH[14C]O[18O]O+ 2.495e-20 2.289e-20 -19.603 -19.640 -0.037 (0) + CaH[14C][18O]O2+ 2.495e-20 2.289e-20 -19.603 -19.640 -0.037 (0) + Ca[14C]O2[18O] 4.102e-21 4.109e-21 -20.387 -20.386 0.001 (0) + H[14C]O[18O]2- 2.356e-21 2.156e-21 -20.628 -20.666 -0.039 (0) + H[14C][18O]2O- 2.356e-21 2.156e-21 -20.628 -20.666 -0.039 (0) + H[14C][18O]O[18O]- 2.356e-21 2.156e-21 -20.628 -20.666 -0.039 (0) + [14C]O2[18O]-2 2.102e-21 1.474e-21 -20.677 -20.832 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.971e-15 + O[18O] 2.965e-15 2.970e-15 -14.528 -14.527 0.001 (0) + [18O]2 2.958e-18 2.962e-18 -17.529 -17.528 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -42582,99 +42582,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.529 -126.528 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.130 -40.130 0.001 -O(0) 1.513e-12 - O2 7.534e-13 7.546e-13 -12.123 -12.122 0.001 - O[18O] 3.006e-15 3.011e-15 -14.522 -14.521 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.485 -128.484 0.001 -[13C](4) 6.505e-05 - H[13C]O3- 5.247e-05 4.801e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.581e-08 4.589e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.118e-08 2.185e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.443 -139.442 0.001 -[14C](4) 7.217e-16 - H[14C]O3- 5.829e-16 5.334e-16 -15.234 -15.273 -0.039 - [14C]O2 1.214e-16 1.216e-16 -15.916 -15.915 0.001 - CaH[14C]O3+ 1.231e-17 1.130e-17 -16.910 -16.947 -0.037 - H[14C]O2[18O]- 1.163e-18 1.064e-18 -17.934 -17.973 -0.039 - H[14C]O[18O]O- 1.163e-18 1.064e-18 -17.934 -17.973 -0.039 - H[14C][18O]O2- 1.163e-18 1.064e-18 -17.934 -17.973 -0.039 - Ca[14C]O3 6.749e-19 6.760e-19 -18.171 -18.170 0.001 - [14C]O[18O] 5.046e-19 5.055e-19 -18.297 -18.296 0.001 - [14C]O3-2 3.459e-19 2.425e-19 -18.461 -18.615 -0.154 - CaH[14C]O2[18O]+ 2.457e-20 2.254e-20 -19.610 -19.647 -0.037 - CaH[14C]O[18O]O+ 2.457e-20 2.254e-20 -19.610 -19.647 -0.037 - CaH[14C][18O]O2+ 2.457e-20 2.254e-20 -19.610 -19.647 -0.037 - Ca[14C]O2[18O] 4.040e-21 4.046e-21 -20.394 -20.393 0.001 - H[14C]O[18O]2- 2.321e-21 2.123e-21 -20.634 -20.673 -0.039 - H[14C][18O]2O- 2.321e-21 2.123e-21 -20.634 -20.673 -0.039 - H[14C][18O]O[18O]- 2.321e-21 2.123e-21 -20.634 -20.673 -0.039 - [14C]O2[18O]-2 2.071e-21 1.451e-21 -20.684 -20.838 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.012e-15 - O[18O] 3.006e-15 3.011e-15 -14.522 -14.521 0.001 - [18O]2 2.999e-18 3.004e-18 -17.523 -17.522 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.529 -126.528 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.130 -40.130 0.001 (0) +O(0) 1.513e-12 + O2 7.534e-13 7.546e-13 -12.123 -12.122 0.001 (0) + O[18O] 3.006e-15 3.011e-15 -14.522 -14.521 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.485 -128.484 0.001 (0) +[13C](4) 6.505e-05 + H[13C]O3- 5.247e-05 4.801e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.578e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.083e-08 6.093e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.581e-08 4.589e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.118e-08 2.185e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.443 -139.442 0.001 (0) +[14C](4) 7.217e-16 + H[14C]O3- 5.829e-16 5.334e-16 -15.234 -15.273 -0.039 (0) + [14C]O2 1.214e-16 1.216e-16 -15.916 -15.915 0.001 (0) + CaH[14C]O3+ 1.231e-17 1.130e-17 -16.910 -16.947 -0.037 (0) + H[14C]O2[18O]- 1.163e-18 1.064e-18 -17.934 -17.973 -0.039 (0) + H[14C]O[18O]O- 1.163e-18 1.064e-18 -17.934 -17.973 -0.039 (0) + H[14C][18O]O2- 1.163e-18 1.064e-18 -17.934 -17.973 -0.039 (0) + Ca[14C]O3 6.749e-19 6.760e-19 -18.171 -18.170 0.001 (0) + [14C]O[18O] 5.046e-19 5.055e-19 -18.297 -18.296 0.001 (0) + [14C]O3-2 3.459e-19 2.425e-19 -18.461 -18.615 -0.154 (0) + CaH[14C]O2[18O]+ 2.457e-20 2.254e-20 -19.610 -19.647 -0.037 (0) + CaH[14C]O[18O]O+ 2.457e-20 2.254e-20 -19.610 -19.647 -0.037 (0) + CaH[14C][18O]O2+ 2.457e-20 2.254e-20 -19.610 -19.647 -0.037 (0) + Ca[14C]O2[18O] 4.040e-21 4.046e-21 -20.394 -20.393 0.001 (0) + H[14C]O[18O]2- 2.321e-21 2.123e-21 -20.634 -20.673 -0.039 (0) + H[14C][18O]2O- 2.321e-21 2.123e-21 -20.634 -20.673 -0.039 (0) + H[14C][18O]O[18O]- 2.321e-21 2.123e-21 -20.634 -20.673 -0.039 (0) + [14C]O2[18O]-2 2.071e-21 1.451e-21 -20.684 -20.838 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.012e-15 + O[18O] 3.006e-15 3.011e-15 -14.522 -14.521 0.001 (0) + [18O]2 2.999e-18 3.004e-18 -17.523 -17.522 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -42837,99 +42837,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.531 -126.530 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.131 -40.130 0.001 -O(0) 1.516e-12 - O2 7.552e-13 7.564e-13 -12.122 -12.121 0.001 - O[18O] 3.013e-15 3.018e-15 -14.521 -14.520 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.487 -128.486 0.001 -[13C](4) 6.506e-05 - H[13C]O3- 5.247e-05 4.801e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.582e-08 4.589e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.118e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.452 -139.451 0.001 -[14C](4) 7.109e-16 - H[14C]O3- 5.742e-16 5.254e-16 -15.241 -15.280 -0.039 - [14C]O2 1.195e-16 1.197e-16 -15.922 -15.922 0.001 - CaH[14C]O3+ 1.213e-17 1.113e-17 -16.916 -16.954 -0.037 - H[14C]O2[18O]- 1.146e-18 1.048e-18 -17.941 -17.980 -0.039 - H[14C]O[18O]O- 1.146e-18 1.048e-18 -17.941 -17.980 -0.039 - H[14C][18O]O2- 1.146e-18 1.048e-18 -17.941 -17.980 -0.039 - Ca[14C]O3 6.648e-19 6.659e-19 -18.177 -18.177 0.001 - [14C]O[18O] 4.971e-19 4.979e-19 -18.304 -18.303 0.001 - [14C]O3-2 3.407e-19 2.388e-19 -18.468 -18.622 -0.154 - CaH[14C]O2[18O]+ 2.420e-20 2.220e-20 -19.616 -19.654 -0.037 - CaH[14C]O[18O]O+ 2.420e-20 2.220e-20 -19.616 -19.654 -0.037 - CaH[14C][18O]O2+ 2.420e-20 2.220e-20 -19.616 -19.654 -0.037 - Ca[14C]O2[18O] 3.979e-21 3.986e-21 -20.400 -20.399 0.001 - H[14C]O[18O]2- 2.286e-21 2.092e-21 -20.641 -20.680 -0.039 - H[14C][18O]2O- 2.286e-21 2.092e-21 -20.641 -20.680 -0.039 - H[14C][18O]O[18O]- 2.286e-21 2.092e-21 -20.641 -20.680 -0.039 - [14C]O2[18O]-2 2.040e-21 1.430e-21 -20.690 -20.845 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.019e-15 - O[18O] 3.013e-15 3.018e-15 -14.521 -14.520 0.001 - [18O]2 3.006e-18 3.011e-18 -17.522 -17.521 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.531 -126.530 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.131 -40.130 0.001 (0) +O(0) 1.516e-12 + O2 7.552e-13 7.564e-13 -12.122 -12.121 0.001 (0) + O[18O] 3.013e-15 3.018e-15 -14.521 -14.520 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.487 -128.486 0.001 (0) +[13C](4) 6.506e-05 + H[13C]O3- 5.247e-05 4.801e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.582e-08 4.589e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.118e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.452 -139.451 0.001 (0) +[14C](4) 7.109e-16 + H[14C]O3- 5.742e-16 5.254e-16 -15.241 -15.280 -0.039 (0) + [14C]O2 1.195e-16 1.197e-16 -15.922 -15.922 0.001 (0) + CaH[14C]O3+ 1.213e-17 1.113e-17 -16.916 -16.954 -0.037 (0) + H[14C]O2[18O]- 1.146e-18 1.048e-18 -17.941 -17.980 -0.039 (0) + H[14C]O[18O]O- 1.146e-18 1.048e-18 -17.941 -17.980 -0.039 (0) + H[14C][18O]O2- 1.146e-18 1.048e-18 -17.941 -17.980 -0.039 (0) + Ca[14C]O3 6.648e-19 6.659e-19 -18.177 -18.177 0.001 (0) + [14C]O[18O] 4.971e-19 4.979e-19 -18.304 -18.303 0.001 (0) + [14C]O3-2 3.407e-19 2.388e-19 -18.468 -18.622 -0.154 (0) + CaH[14C]O2[18O]+ 2.420e-20 2.220e-20 -19.616 -19.654 -0.037 (0) + CaH[14C]O[18O]O+ 2.420e-20 2.220e-20 -19.616 -19.654 -0.037 (0) + CaH[14C][18O]O2+ 2.420e-20 2.220e-20 -19.616 -19.654 -0.037 (0) + Ca[14C]O2[18O] 3.979e-21 3.986e-21 -20.400 -20.399 0.001 (0) + H[14C]O[18O]2- 2.286e-21 2.092e-21 -20.641 -20.680 -0.039 (0) + H[14C][18O]2O- 2.286e-21 2.092e-21 -20.641 -20.680 -0.039 (0) + H[14C][18O]O[18O]- 2.286e-21 2.092e-21 -20.641 -20.680 -0.039 (0) + [14C]O2[18O]-2 2.040e-21 1.430e-21 -20.690 -20.845 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.019e-15 + O[18O] 3.013e-15 3.018e-15 -14.521 -14.520 0.001 (0) + [18O]2 3.006e-18 3.011e-18 -17.522 -17.521 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -43092,99 +43092,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.524 -126.523 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.129 -40.129 0.001 -O(0) 1.505e-12 - O2 7.494e-13 7.507e-13 -12.125 -12.125 0.001 - O[18O] 2.990e-15 2.995e-15 -14.524 -14.524 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.480 -128.480 0.001 -[13C](4) 6.506e-05 - H[13C]O3- 5.247e-05 4.801e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.582e-08 4.589e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.118e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.451 -139.451 0.001 -[14C](4) 7.004e-16 - H[14C]O3- 5.657e-16 5.176e-16 -15.247 -15.286 -0.039 - [14C]O2 1.178e-16 1.180e-16 -15.929 -15.928 0.001 - CaH[14C]O3+ 1.195e-17 1.096e-17 -16.923 -16.960 -0.037 - H[14C]O2[18O]- 1.129e-18 1.033e-18 -17.947 -17.986 -0.039 - H[14C]O[18O]O- 1.129e-18 1.033e-18 -17.947 -17.986 -0.039 - H[14C][18O]O2- 1.129e-18 1.033e-18 -17.947 -17.986 -0.039 - Ca[14C]O3 6.550e-19 6.561e-19 -18.184 -18.183 0.001 - [14C]O[18O] 4.897e-19 4.905e-19 -18.310 -18.309 0.001 - [14C]O3-2 3.357e-19 2.353e-19 -18.474 -18.628 -0.154 - CaH[14C]O2[18O]+ 2.384e-20 2.188e-20 -19.623 -19.660 -0.037 - CaH[14C]O[18O]O+ 2.384e-20 2.188e-20 -19.623 -19.660 -0.037 - CaH[14C][18O]O2+ 2.384e-20 2.188e-20 -19.623 -19.660 -0.037 - Ca[14C]O2[18O] 3.921e-21 3.927e-21 -20.407 -20.406 0.001 - H[14C]O[18O]2- 2.252e-21 2.061e-21 -20.647 -20.686 -0.039 - H[14C][18O]2O- 2.252e-21 2.061e-21 -20.647 -20.686 -0.039 - H[14C][18O]O[18O]- 2.252e-21 2.061e-21 -20.647 -20.686 -0.039 - [14C]O2[18O]-2 2.009e-21 1.408e-21 -20.697 -20.851 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.996e-15 - O[18O] 2.990e-15 2.995e-15 -14.524 -14.524 0.001 - [18O]2 2.983e-18 2.988e-18 -17.525 -17.525 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.524 -126.523 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.129 -40.129 0.001 (0) +O(0) 1.505e-12 + O2 7.494e-13 7.507e-13 -12.125 -12.125 0.001 (0) + O[18O] 2.990e-15 2.995e-15 -14.524 -14.524 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.480 -128.480 0.001 (0) +[13C](4) 6.506e-05 + H[13C]O3- 5.247e-05 4.801e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.582e-08 4.589e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.118e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.211e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.641e-10 3.647e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.451 -139.451 0.001 (0) +[14C](4) 7.004e-16 + H[14C]O3- 5.657e-16 5.176e-16 -15.247 -15.286 -0.039 (0) + [14C]O2 1.178e-16 1.180e-16 -15.929 -15.928 0.001 (0) + CaH[14C]O3+ 1.195e-17 1.096e-17 -16.923 -16.960 -0.037 (0) + H[14C]O2[18O]- 1.129e-18 1.033e-18 -17.947 -17.986 -0.039 (0) + H[14C]O[18O]O- 1.129e-18 1.033e-18 -17.947 -17.986 -0.039 (0) + H[14C][18O]O2- 1.129e-18 1.033e-18 -17.947 -17.986 -0.039 (0) + Ca[14C]O3 6.550e-19 6.561e-19 -18.184 -18.183 0.001 (0) + [14C]O[18O] 4.897e-19 4.905e-19 -18.310 -18.309 0.001 (0) + [14C]O3-2 3.357e-19 2.353e-19 -18.474 -18.628 -0.154 (0) + CaH[14C]O2[18O]+ 2.384e-20 2.188e-20 -19.623 -19.660 -0.037 (0) + CaH[14C]O[18O]O+ 2.384e-20 2.188e-20 -19.623 -19.660 -0.037 (0) + CaH[14C][18O]O2+ 2.384e-20 2.188e-20 -19.623 -19.660 -0.037 (0) + Ca[14C]O2[18O] 3.921e-21 3.927e-21 -20.407 -20.406 0.001 (0) + H[14C]O[18O]2- 2.252e-21 2.061e-21 -20.647 -20.686 -0.039 (0) + H[14C][18O]2O- 2.252e-21 2.061e-21 -20.647 -20.686 -0.039 (0) + H[14C][18O]O[18O]- 2.252e-21 2.061e-21 -20.647 -20.686 -0.039 (0) + [14C]O2[18O]-2 2.009e-21 1.408e-21 -20.697 -20.851 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.996e-15 + O[18O] 2.990e-15 2.995e-15 -14.524 -14.524 0.001 (0) + [18O]2 2.983e-18 2.988e-18 -17.525 -17.525 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -43347,99 +43347,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.543 -126.542 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.134 -40.133 0.001 -O(0) 1.538e-12 - O2 7.657e-13 7.670e-13 -12.116 -12.115 0.001 - O[18O] 3.056e-15 3.061e-15 -14.515 -14.514 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.499 -128.498 0.001 -[13C](4) 6.506e-05 - H[13C]O3- 5.247e-05 4.801e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.582e-08 4.589e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.118e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.476 -139.476 0.001 -[14C](4) 6.902e-16 - H[14C]O3- 5.575e-16 5.101e-16 -15.254 -15.292 -0.039 - [14C]O2 1.161e-16 1.163e-16 -15.935 -15.935 0.001 - CaH[14C]O3+ 1.178e-17 1.080e-17 -16.929 -16.966 -0.037 - H[14C]O2[18O]- 1.112e-18 1.018e-18 -17.954 -17.992 -0.039 - H[14C]O[18O]O- 1.112e-18 1.018e-18 -17.954 -17.992 -0.039 - H[14C][18O]O2- 1.112e-18 1.018e-18 -17.954 -17.992 -0.039 - Ca[14C]O3 6.455e-19 6.466e-19 -18.190 -18.189 0.001 - [14C]O[18O] 4.826e-19 4.834e-19 -18.316 -18.316 0.001 - [14C]O3-2 3.308e-19 2.319e-19 -18.480 -18.635 -0.154 - CaH[14C]O2[18O]+ 2.350e-20 2.156e-20 -19.629 -19.666 -0.037 - CaH[14C]O[18O]O+ 2.350e-20 2.156e-20 -19.629 -19.666 -0.037 - CaH[14C][18O]O2+ 2.350e-20 2.156e-20 -19.629 -19.666 -0.037 - Ca[14C]O2[18O] 3.864e-21 3.870e-21 -20.413 -20.412 0.001 - H[14C]O[18O]2- 2.219e-21 2.031e-21 -20.654 -20.692 -0.039 - H[14C][18O]2O- 2.219e-21 2.031e-21 -20.654 -20.692 -0.039 - H[14C][18O]O[18O]- 2.219e-21 2.031e-21 -20.654 -20.692 -0.039 - [14C]O2[18O]-2 1.980e-21 1.388e-21 -20.703 -20.858 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.062e-15 - O[18O] 3.056e-15 3.061e-15 -14.515 -14.514 0.001 - [18O]2 3.048e-18 3.053e-18 -17.516 -17.515 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.543 -126.542 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.134 -40.133 0.001 (0) +O(0) 1.538e-12 + O2 7.657e-13 7.670e-13 -12.116 -12.115 0.001 (0) + O[18O] 3.056e-15 3.061e-15 -14.515 -14.514 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.499 -128.498 0.001 (0) +[13C](4) 6.506e-05 + H[13C]O3- 5.247e-05 4.801e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.579e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.582e-08 4.589e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.118e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.866e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.476 -139.476 0.001 (0) +[14C](4) 6.902e-16 + H[14C]O3- 5.575e-16 5.101e-16 -15.254 -15.292 -0.039 (0) + [14C]O2 1.161e-16 1.163e-16 -15.935 -15.935 0.001 (0) + CaH[14C]O3+ 1.178e-17 1.080e-17 -16.929 -16.966 -0.037 (0) + H[14C]O2[18O]- 1.112e-18 1.018e-18 -17.954 -17.992 -0.039 (0) + H[14C]O[18O]O- 1.112e-18 1.018e-18 -17.954 -17.992 -0.039 (0) + H[14C][18O]O2- 1.112e-18 1.018e-18 -17.954 -17.992 -0.039 (0) + Ca[14C]O3 6.455e-19 6.466e-19 -18.190 -18.189 0.001 (0) + [14C]O[18O] 4.826e-19 4.834e-19 -18.316 -18.316 0.001 (0) + [14C]O3-2 3.308e-19 2.319e-19 -18.480 -18.635 -0.154 (0) + CaH[14C]O2[18O]+ 2.350e-20 2.156e-20 -19.629 -19.666 -0.037 (0) + CaH[14C]O[18O]O+ 2.350e-20 2.156e-20 -19.629 -19.666 -0.037 (0) + CaH[14C][18O]O2+ 2.350e-20 2.156e-20 -19.629 -19.666 -0.037 (0) + Ca[14C]O2[18O] 3.864e-21 3.870e-21 -20.413 -20.412 0.001 (0) + H[14C]O[18O]2- 2.219e-21 2.031e-21 -20.654 -20.692 -0.039 (0) + H[14C][18O]2O- 2.219e-21 2.031e-21 -20.654 -20.692 -0.039 (0) + H[14C][18O]O[18O]- 2.219e-21 2.031e-21 -20.654 -20.692 -0.039 (0) + [14C]O2[18O]-2 1.980e-21 1.388e-21 -20.703 -20.858 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.062e-15 + O[18O] 3.056e-15 3.061e-15 -14.515 -14.514 0.001 (0) + [18O]2 3.048e-18 3.053e-18 -17.516 -17.515 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -43602,99 +43602,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.531 -126.531 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.131 -40.130 0.001 -O(0) 1.518e-12 - O2 7.558e-13 7.571e-13 -12.122 -12.121 0.001 - O[18O] 3.016e-15 3.021e-15 -14.521 -14.520 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.488 -128.487 0.001 -[13C](4) 6.506e-05 - H[13C]O3- 5.247e-05 4.801e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.582e-08 4.590e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.118e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.471 -139.471 0.001 -[14C](4) 6.804e-16 - H[14C]O3- 5.495e-16 5.028e-16 -15.260 -15.299 -0.039 - [14C]O2 1.144e-16 1.146e-16 -15.942 -15.941 0.001 - CaH[14C]O3+ 1.161e-17 1.065e-17 -16.935 -16.973 -0.037 - H[14C]O2[18O]- 1.096e-18 1.003e-18 -17.960 -17.999 -0.039 - H[14C]O[18O]O- 1.096e-18 1.003e-18 -17.960 -17.999 -0.039 - H[14C][18O]O2- 1.096e-18 1.003e-18 -17.960 -17.999 -0.039 - Ca[14C]O3 6.362e-19 6.373e-19 -18.196 -18.196 0.001 - [14C]O[18O] 4.757e-19 4.765e-19 -18.323 -18.322 0.001 - [14C]O3-2 3.261e-19 2.286e-19 -18.487 -18.641 -0.154 - CaH[14C]O2[18O]+ 2.316e-20 2.125e-20 -19.635 -19.673 -0.037 - CaH[14C]O[18O]O+ 2.316e-20 2.125e-20 -19.635 -19.673 -0.037 - CaH[14C][18O]O2+ 2.316e-20 2.125e-20 -19.635 -19.673 -0.037 - Ca[14C]O2[18O] 3.808e-21 3.815e-21 -20.419 -20.419 0.001 - H[14C]O[18O]2- 2.188e-21 2.002e-21 -20.660 -20.699 -0.039 - H[14C][18O]2O- 2.188e-21 2.002e-21 -20.660 -20.699 -0.039 - H[14C][18O]O[18O]- 2.188e-21 2.002e-21 -20.660 -20.699 -0.039 - [14C]O2[18O]-2 1.952e-21 1.368e-21 -20.710 -20.864 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.022e-15 - O[18O] 3.016e-15 3.021e-15 -14.521 -14.520 0.001 - [18O]2 3.009e-18 3.014e-18 -17.522 -17.521 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.531 -126.531 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.131 -40.130 0.001 (0) +O(0) 1.518e-12 + O2 7.558e-13 7.571e-13 -12.122 -12.121 0.001 (0) + O[18O] 3.016e-15 3.021e-15 -14.521 -14.520 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.488 -128.487 0.001 (0) +[13C](4) 6.506e-05 + H[13C]O3- 5.247e-05 4.801e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.108e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.582e-08 4.590e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.118e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.471 -139.471 0.001 (0) +[14C](4) 6.804e-16 + H[14C]O3- 5.495e-16 5.028e-16 -15.260 -15.299 -0.039 (0) + [14C]O2 1.144e-16 1.146e-16 -15.942 -15.941 0.001 (0) + CaH[14C]O3+ 1.161e-17 1.065e-17 -16.935 -16.973 -0.037 (0) + H[14C]O2[18O]- 1.096e-18 1.003e-18 -17.960 -17.999 -0.039 (0) + H[14C]O[18O]O- 1.096e-18 1.003e-18 -17.960 -17.999 -0.039 (0) + H[14C][18O]O2- 1.096e-18 1.003e-18 -17.960 -17.999 -0.039 (0) + Ca[14C]O3 6.362e-19 6.373e-19 -18.196 -18.196 0.001 (0) + [14C]O[18O] 4.757e-19 4.765e-19 -18.323 -18.322 0.001 (0) + [14C]O3-2 3.261e-19 2.286e-19 -18.487 -18.641 -0.154 (0) + CaH[14C]O2[18O]+ 2.316e-20 2.125e-20 -19.635 -19.673 -0.037 (0) + CaH[14C]O[18O]O+ 2.316e-20 2.125e-20 -19.635 -19.673 -0.037 (0) + CaH[14C][18O]O2+ 2.316e-20 2.125e-20 -19.635 -19.673 -0.037 (0) + Ca[14C]O2[18O] 3.808e-21 3.815e-21 -20.419 -20.419 0.001 (0) + H[14C]O[18O]2- 2.188e-21 2.002e-21 -20.660 -20.699 -0.039 (0) + H[14C][18O]2O- 2.188e-21 2.002e-21 -20.660 -20.699 -0.039 (0) + H[14C][18O]O[18O]- 2.188e-21 2.002e-21 -20.660 -20.699 -0.039 (0) + [14C]O2[18O]-2 1.952e-21 1.368e-21 -20.710 -20.864 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.022e-15 + O[18O] 3.016e-15 3.021e-15 -14.521 -14.520 0.001 (0) + [18O]2 3.009e-18 3.014e-18 -17.522 -17.521 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -43857,99 +43857,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.541 -126.540 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.133 -40.133 0.001 -O(0) 1.534e-12 - O2 7.639e-13 7.652e-13 -12.117 -12.116 0.001 - O[18O] 3.048e-15 3.053e-15 -14.516 -14.515 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.497 -128.496 0.001 -[13C](4) 6.506e-05 - H[13C]O3- 5.248e-05 4.801e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.582e-08 4.590e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.118e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.487 -139.486 0.001 -[14C](4) 6.707e-16 - H[14C]O3- 5.418e-16 4.957e-16 -15.266 -15.305 -0.039 - [14C]O2 1.128e-16 1.130e-16 -15.948 -15.947 0.001 - CaH[14C]O3+ 1.144e-17 1.050e-17 -16.941 -16.979 -0.037 - H[14C]O2[18O]- 1.081e-18 9.891e-19 -17.966 -18.005 -0.039 - H[14C]O[18O]O- 1.081e-18 9.891e-19 -17.966 -18.005 -0.039 - H[14C][18O]O2- 1.081e-18 9.891e-19 -17.966 -18.005 -0.039 - Ca[14C]O3 6.273e-19 6.283e-19 -18.203 -18.202 0.001 - [14C]O[18O] 4.690e-19 4.698e-19 -18.329 -18.328 0.001 - [14C]O3-2 3.215e-19 2.253e-19 -18.493 -18.647 -0.154 - CaH[14C]O2[18O]+ 2.283e-20 2.095e-20 -19.641 -19.679 -0.037 - CaH[14C]O[18O]O+ 2.283e-20 2.095e-20 -19.641 -19.679 -0.037 - CaH[14C][18O]O2+ 2.283e-20 2.095e-20 -19.641 -19.679 -0.037 - Ca[14C]O2[18O] 3.755e-21 3.761e-21 -20.425 -20.425 0.001 - H[14C]O[18O]2- 2.157e-21 1.973e-21 -20.666 -20.705 -0.039 - H[14C][18O]2O- 2.157e-21 1.973e-21 -20.666 -20.705 -0.039 - H[14C][18O]O[18O]- 2.157e-21 1.973e-21 -20.666 -20.705 -0.039 - [14C]O2[18O]-2 1.924e-21 1.349e-21 -20.716 -20.870 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.055e-15 - O[18O] 3.048e-15 3.053e-15 -14.516 -14.515 0.001 - [18O]2 3.041e-18 3.046e-18 -17.517 -17.516 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.541 -126.540 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.133 -40.133 0.001 (0) +O(0) 1.534e-12 + O2 7.639e-13 7.652e-13 -12.117 -12.116 0.001 (0) + O[18O] 3.048e-15 3.053e-15 -14.516 -14.515 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.497 -128.496 0.001 (0) +[13C](4) 6.506e-05 + H[13C]O3- 5.248e-05 4.801e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.084e-08 6.094e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.582e-08 4.590e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.118e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.487 -139.486 0.001 (0) +[14C](4) 6.707e-16 + H[14C]O3- 5.418e-16 4.957e-16 -15.266 -15.305 -0.039 (0) + [14C]O2 1.128e-16 1.130e-16 -15.948 -15.947 0.001 (0) + CaH[14C]O3+ 1.144e-17 1.050e-17 -16.941 -16.979 -0.037 (0) + H[14C]O2[18O]- 1.081e-18 9.891e-19 -17.966 -18.005 -0.039 (0) + H[14C]O[18O]O- 1.081e-18 9.891e-19 -17.966 -18.005 -0.039 (0) + H[14C][18O]O2- 1.081e-18 9.891e-19 -17.966 -18.005 -0.039 (0) + Ca[14C]O3 6.273e-19 6.283e-19 -18.203 -18.202 0.001 (0) + [14C]O[18O] 4.690e-19 4.698e-19 -18.329 -18.328 0.001 (0) + [14C]O3-2 3.215e-19 2.253e-19 -18.493 -18.647 -0.154 (0) + CaH[14C]O2[18O]+ 2.283e-20 2.095e-20 -19.641 -19.679 -0.037 (0) + CaH[14C]O[18O]O+ 2.283e-20 2.095e-20 -19.641 -19.679 -0.037 (0) + CaH[14C][18O]O2+ 2.283e-20 2.095e-20 -19.641 -19.679 -0.037 (0) + Ca[14C]O2[18O] 3.755e-21 3.761e-21 -20.425 -20.425 0.001 (0) + H[14C]O[18O]2- 2.157e-21 1.973e-21 -20.666 -20.705 -0.039 (0) + H[14C][18O]2O- 2.157e-21 1.973e-21 -20.666 -20.705 -0.039 (0) + H[14C][18O]O[18O]- 2.157e-21 1.973e-21 -20.666 -20.705 -0.039 (0) + [14C]O2[18O]-2 1.924e-21 1.349e-21 -20.716 -20.870 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.055e-15 + O[18O] 3.048e-15 3.053e-15 -14.516 -14.515 0.001 (0) + [18O]2 3.041e-18 3.046e-18 -17.517 -17.516 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -44112,99 +44112,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.552 -126.551 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.084e-08 6.095e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.136 -40.136 0.001 -O(0) 1.554e-12 - O2 7.739e-13 7.751e-13 -12.111 -12.111 0.001 - O[18O] 3.088e-15 3.093e-15 -14.510 -14.510 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.508 -128.507 0.001 -[13C](4) 6.507e-05 - H[13C]O3- 5.248e-05 4.802e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.084e-08 6.095e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.582e-08 4.590e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.504 -139.503 0.001 -[14C](4) 6.614e-16 - H[14C]O3- 5.342e-16 4.888e-16 -15.272 -15.311 -0.039 - [14C]O2 1.112e-16 1.114e-16 -15.954 -15.953 0.001 - CaH[14C]O3+ 1.129e-17 1.035e-17 -16.947 -16.985 -0.037 - H[14C]O2[18O]- 1.066e-18 9.753e-19 -17.972 -18.011 -0.039 - H[14C]O[18O]O- 1.066e-18 9.753e-19 -17.972 -18.011 -0.039 - H[14C][18O]O2- 1.066e-18 9.753e-19 -17.972 -18.011 -0.039 - Ca[14C]O3 6.185e-19 6.195e-19 -18.209 -18.208 0.001 - [14C]O[18O] 4.625e-19 4.632e-19 -18.335 -18.334 0.001 - [14C]O3-2 3.170e-19 2.222e-19 -18.499 -18.653 -0.154 - CaH[14C]O2[18O]+ 2.252e-20 2.066e-20 -19.648 -19.685 -0.037 - CaH[14C]O[18O]O+ 2.252e-20 2.066e-20 -19.648 -19.685 -0.037 - CaH[14C][18O]O2+ 2.252e-20 2.066e-20 -19.648 -19.685 -0.037 - Ca[14C]O2[18O] 3.702e-21 3.708e-21 -20.432 -20.431 0.001 - H[14C]O[18O]2- 2.127e-21 1.946e-21 -20.672 -20.711 -0.039 - H[14C][18O]2O- 2.127e-21 1.946e-21 -20.672 -20.711 -0.039 - H[14C][18O]O[18O]- 2.127e-21 1.946e-21 -20.672 -20.711 -0.039 - [14C]O2[18O]-2 1.898e-21 1.330e-21 -20.722 -20.876 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.094e-15 - O[18O] 3.088e-15 3.093e-15 -14.510 -14.510 0.001 - [18O]2 3.081e-18 3.086e-18 -17.511 -17.511 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.552 -126.551 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.084e-08 6.095e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.136 -40.136 0.001 (0) +O(0) 1.554e-12 + O2 7.739e-13 7.751e-13 -12.111 -12.111 0.001 (0) + O[18O] 3.088e-15 3.093e-15 -14.510 -14.510 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.508 -128.507 0.001 (0) +[13C](4) 6.507e-05 + H[13C]O3- 5.248e-05 4.802e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.084e-08 6.095e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.582e-08 4.590e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.504 -139.503 0.001 (0) +[14C](4) 6.614e-16 + H[14C]O3- 5.342e-16 4.888e-16 -15.272 -15.311 -0.039 (0) + [14C]O2 1.112e-16 1.114e-16 -15.954 -15.953 0.001 (0) + CaH[14C]O3+ 1.129e-17 1.035e-17 -16.947 -16.985 -0.037 (0) + H[14C]O2[18O]- 1.066e-18 9.753e-19 -17.972 -18.011 -0.039 (0) + H[14C]O[18O]O- 1.066e-18 9.753e-19 -17.972 -18.011 -0.039 (0) + H[14C][18O]O2- 1.066e-18 9.753e-19 -17.972 -18.011 -0.039 (0) + Ca[14C]O3 6.185e-19 6.195e-19 -18.209 -18.208 0.001 (0) + [14C]O[18O] 4.625e-19 4.632e-19 -18.335 -18.334 0.001 (0) + [14C]O3-2 3.170e-19 2.222e-19 -18.499 -18.653 -0.154 (0) + CaH[14C]O2[18O]+ 2.252e-20 2.066e-20 -19.648 -19.685 -0.037 (0) + CaH[14C]O[18O]O+ 2.252e-20 2.066e-20 -19.648 -19.685 -0.037 (0) + CaH[14C][18O]O2+ 2.252e-20 2.066e-20 -19.648 -19.685 -0.037 (0) + Ca[14C]O2[18O] 3.702e-21 3.708e-21 -20.432 -20.431 0.001 (0) + H[14C]O[18O]2- 2.127e-21 1.946e-21 -20.672 -20.711 -0.039 (0) + H[14C][18O]2O- 2.127e-21 1.946e-21 -20.672 -20.711 -0.039 (0) + H[14C][18O]O[18O]- 2.127e-21 1.946e-21 -20.672 -20.711 -0.039 (0) + [14C]O2[18O]-2 1.898e-21 1.330e-21 -20.722 -20.876 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.094e-15 + O[18O] 3.088e-15 3.093e-15 -14.510 -14.510 0.001 (0) + [18O]2 3.081e-18 3.086e-18 -17.511 -17.511 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -44367,99 +44367,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.563 -126.562 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.139 -40.138 0.001 -O(0) 1.574e-12 - O2 7.839e-13 7.852e-13 -12.106 -12.105 0.001 - O[18O] 3.128e-15 3.133e-15 -14.505 -14.504 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.519 -128.519 0.001 -[13C](4) 6.507e-05 - H[13C]O3- 5.248e-05 4.802e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.582e-08 4.590e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.521 -139.521 0.001 -[14C](4) 6.523e-16 - H[14C]O3- 5.269e-16 4.821e-16 -15.278 -15.317 -0.039 - [14C]O2 1.097e-16 1.099e-16 -15.960 -15.959 0.001 - CaH[14C]O3+ 1.113e-17 1.021e-17 -16.953 -16.991 -0.037 - H[14C]O2[18O]- 1.051e-18 9.619e-19 -17.978 -18.017 -0.039 - H[14C]O[18O]O- 1.051e-18 9.619e-19 -17.978 -18.017 -0.039 - H[14C][18O]O2- 1.051e-18 9.619e-19 -17.978 -18.017 -0.039 - Ca[14C]O3 6.100e-19 6.110e-19 -18.215 -18.214 0.001 - [14C]O[18O] 4.561e-19 4.569e-19 -18.341 -18.340 0.001 - [14C]O3-2 3.127e-19 2.192e-19 -18.505 -18.659 -0.154 - CaH[14C]O2[18O]+ 2.221e-20 2.037e-20 -19.654 -19.691 -0.037 - CaH[14C]O[18O]O+ 2.221e-20 2.037e-20 -19.654 -19.691 -0.037 - CaH[14C][18O]O2+ 2.221e-20 2.037e-20 -19.654 -19.691 -0.037 - Ca[14C]O2[18O] 3.651e-21 3.657e-21 -20.438 -20.437 0.001 - H[14C]O[18O]2- 2.097e-21 1.919e-21 -20.678 -20.717 -0.039 - H[14C][18O]2O- 2.097e-21 1.919e-21 -20.678 -20.717 -0.039 - H[14C][18O]O[18O]- 2.097e-21 1.919e-21 -20.678 -20.717 -0.039 - [14C]O2[18O]-2 1.871e-21 1.312e-21 -20.728 -20.882 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.134e-15 - O[18O] 3.128e-15 3.133e-15 -14.505 -14.504 0.001 - [18O]2 3.121e-18 3.126e-18 -17.506 -17.505 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.563 -126.562 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.139 -40.138 0.001 (0) +O(0) 1.574e-12 + O2 7.839e-13 7.852e-13 -12.106 -12.105 0.001 (0) + O[18O] 3.128e-15 3.133e-15 -14.505 -14.504 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.519 -128.519 0.001 (0) +[13C](4) 6.507e-05 + H[13C]O3- 5.248e-05 4.802e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.580e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.582e-08 4.590e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.911e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.521 -139.521 0.001 (0) +[14C](4) 6.523e-16 + H[14C]O3- 5.269e-16 4.821e-16 -15.278 -15.317 -0.039 (0) + [14C]O2 1.097e-16 1.099e-16 -15.960 -15.959 0.001 (0) + CaH[14C]O3+ 1.113e-17 1.021e-17 -16.953 -16.991 -0.037 (0) + H[14C]O2[18O]- 1.051e-18 9.619e-19 -17.978 -18.017 -0.039 (0) + H[14C]O[18O]O- 1.051e-18 9.619e-19 -17.978 -18.017 -0.039 (0) + H[14C][18O]O2- 1.051e-18 9.619e-19 -17.978 -18.017 -0.039 (0) + Ca[14C]O3 6.100e-19 6.110e-19 -18.215 -18.214 0.001 (0) + [14C]O[18O] 4.561e-19 4.569e-19 -18.341 -18.340 0.001 (0) + [14C]O3-2 3.127e-19 2.192e-19 -18.505 -18.659 -0.154 (0) + CaH[14C]O2[18O]+ 2.221e-20 2.037e-20 -19.654 -19.691 -0.037 (0) + CaH[14C]O[18O]O+ 2.221e-20 2.037e-20 -19.654 -19.691 -0.037 (0) + CaH[14C][18O]O2+ 2.221e-20 2.037e-20 -19.654 -19.691 -0.037 (0) + Ca[14C]O2[18O] 3.651e-21 3.657e-21 -20.438 -20.437 0.001 (0) + H[14C]O[18O]2- 2.097e-21 1.919e-21 -20.678 -20.717 -0.039 (0) + H[14C][18O]2O- 2.097e-21 1.919e-21 -20.678 -20.717 -0.039 (0) + H[14C][18O]O[18O]- 2.097e-21 1.919e-21 -20.678 -20.717 -0.039 (0) + [14C]O2[18O]-2 1.871e-21 1.312e-21 -20.728 -20.882 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.134e-15 + O[18O] 3.128e-15 3.133e-15 -14.505 -14.504 0.001 (0) + [18O]2 3.121e-18 3.126e-18 -17.506 -17.505 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -44622,99 +44622,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.549 -126.548 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.135 -40.135 0.001 -O(0) 1.548e-12 - O2 7.710e-13 7.723e-13 -12.113 -12.112 0.001 - O[18O] 3.077e-15 3.082e-15 -14.512 -14.511 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.505 -128.504 0.001 -[13C](4) 6.507e-05 - H[13C]O3- 5.248e-05 4.802e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.583e-08 4.590e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.513 -139.512 0.001 -[14C](4) 6.435e-16 - H[14C]O3- 5.198e-16 4.756e-16 -15.284 -15.323 -0.039 - [14C]O2 1.082e-16 1.084e-16 -15.966 -15.965 0.001 - CaH[14C]O3+ 1.098e-17 1.007e-17 -16.959 -16.997 -0.037 - H[14C]O2[18O]- 1.037e-18 9.489e-19 -17.984 -18.023 -0.039 - H[14C]O[18O]O- 1.037e-18 9.489e-19 -17.984 -18.023 -0.039 - H[14C][18O]O2- 1.037e-18 9.489e-19 -17.984 -18.023 -0.039 - Ca[14C]O3 6.018e-19 6.028e-19 -18.221 -18.220 0.001 - [14C]O[18O] 4.499e-19 4.507e-19 -18.347 -18.346 0.001 - [14C]O3-2 3.084e-19 2.162e-19 -18.511 -18.665 -0.154 - CaH[14C]O2[18O]+ 2.191e-20 2.010e-20 -19.659 -19.697 -0.037 - CaH[14C]O[18O]O+ 2.191e-20 2.010e-20 -19.659 -19.697 -0.037 - CaH[14C][18O]O2+ 2.191e-20 2.010e-20 -19.659 -19.697 -0.037 - Ca[14C]O2[18O] 3.602e-21 3.608e-21 -20.443 -20.443 0.001 - H[14C]O[18O]2- 2.069e-21 1.893e-21 -20.684 -20.723 -0.039 - H[14C][18O]2O- 2.069e-21 1.893e-21 -20.684 -20.723 -0.039 - H[14C][18O]O[18O]- 2.069e-21 1.893e-21 -20.684 -20.723 -0.039 - [14C]O2[18O]-2 1.846e-21 1.294e-21 -20.734 -20.888 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.083e-15 - O[18O] 3.077e-15 3.082e-15 -14.512 -14.511 0.001 - [18O]2 3.069e-18 3.074e-18 -17.513 -17.512 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.549 -126.548 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.135 -40.135 0.001 (0) +O(0) 1.548e-12 + O2 7.710e-13 7.723e-13 -12.113 -12.112 0.001 (0) + O[18O] 3.077e-15 3.082e-15 -14.512 -14.511 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.505 -128.504 0.001 (0) +[13C](4) 6.507e-05 + H[13C]O3- 5.248e-05 4.802e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.583e-08 4.590e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.513 -139.512 0.001 (0) +[14C](4) 6.435e-16 + H[14C]O3- 5.198e-16 4.756e-16 -15.284 -15.323 -0.039 (0) + [14C]O2 1.082e-16 1.084e-16 -15.966 -15.965 0.001 (0) + CaH[14C]O3+ 1.098e-17 1.007e-17 -16.959 -16.997 -0.037 (0) + H[14C]O2[18O]- 1.037e-18 9.489e-19 -17.984 -18.023 -0.039 (0) + H[14C]O[18O]O- 1.037e-18 9.489e-19 -17.984 -18.023 -0.039 (0) + H[14C][18O]O2- 1.037e-18 9.489e-19 -17.984 -18.023 -0.039 (0) + Ca[14C]O3 6.018e-19 6.028e-19 -18.221 -18.220 0.001 (0) + [14C]O[18O] 4.499e-19 4.507e-19 -18.347 -18.346 0.001 (0) + [14C]O3-2 3.084e-19 2.162e-19 -18.511 -18.665 -0.154 (0) + CaH[14C]O2[18O]+ 2.191e-20 2.010e-20 -19.659 -19.697 -0.037 (0) + CaH[14C]O[18O]O+ 2.191e-20 2.010e-20 -19.659 -19.697 -0.037 (0) + CaH[14C][18O]O2+ 2.191e-20 2.010e-20 -19.659 -19.697 -0.037 (0) + Ca[14C]O2[18O] 3.602e-21 3.608e-21 -20.443 -20.443 0.001 (0) + H[14C]O[18O]2- 2.069e-21 1.893e-21 -20.684 -20.723 -0.039 (0) + H[14C][18O]2O- 2.069e-21 1.893e-21 -20.684 -20.723 -0.039 (0) + H[14C][18O]O[18O]- 2.069e-21 1.893e-21 -20.684 -20.723 -0.039 (0) + [14C]O2[18O]-2 1.846e-21 1.294e-21 -20.734 -20.888 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.083e-15 + O[18O] 3.077e-15 3.082e-15 -14.512 -14.511 0.001 (0) + [18O]2 3.069e-18 3.074e-18 -17.513 -17.512 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -44877,99 +44877,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.563 -126.562 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.139 -40.138 0.001 -O(0) 1.573e-12 - O2 7.834e-13 7.847e-13 -12.106 -12.105 0.001 - O[18O] 3.126e-15 3.131e-15 -14.505 -14.504 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.519 -128.518 0.001 -[13C](4) 6.507e-05 - H[13C]O3- 5.248e-05 4.802e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.583e-08 4.590e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.532 -139.532 0.001 -[14C](4) 6.349e-16 - H[14C]O3- 5.128e-16 4.692e-16 -15.290 -15.329 -0.039 - [14C]O2 1.068e-16 1.069e-16 -15.972 -15.971 0.001 - CaH[14C]O3+ 1.083e-17 9.938e-18 -16.965 -17.003 -0.037 - H[14C]O2[18O]- 1.023e-18 9.362e-19 -17.990 -18.029 -0.039 - H[14C]O[18O]O- 1.023e-18 9.362e-19 -17.990 -18.029 -0.039 - H[14C][18O]O2- 1.023e-18 9.362e-19 -17.990 -18.029 -0.039 - Ca[14C]O3 5.937e-19 5.947e-19 -18.226 -18.226 0.001 - [14C]O[18O] 4.439e-19 4.446e-19 -18.353 -18.352 0.001 - [14C]O3-2 3.043e-19 2.133e-19 -18.517 -18.671 -0.154 - CaH[14C]O2[18O]+ 2.161e-20 1.983e-20 -19.665 -19.703 -0.037 - CaH[14C]O[18O]O+ 2.161e-20 1.983e-20 -19.665 -19.703 -0.037 - CaH[14C][18O]O2+ 2.161e-20 1.983e-20 -19.665 -19.703 -0.037 - Ca[14C]O2[18O] 3.554e-21 3.560e-21 -20.449 -20.449 0.001 - H[14C]O[18O]2- 2.041e-21 1.868e-21 -20.690 -20.729 -0.039 - H[14C][18O]2O- 2.041e-21 1.868e-21 -20.690 -20.729 -0.039 - H[14C][18O]O[18O]- 2.041e-21 1.868e-21 -20.690 -20.729 -0.039 - [14C]O2[18O]-2 1.821e-21 1.277e-21 -20.740 -20.894 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.132e-15 - O[18O] 3.126e-15 3.131e-15 -14.505 -14.504 0.001 - [18O]2 3.118e-18 3.124e-18 -17.506 -17.505 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.563 -126.562 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.139 -40.138 0.001 (0) +O(0) 1.573e-12 + O2 7.834e-13 7.847e-13 -12.106 -12.105 0.001 (0) + O[18O] 3.126e-15 3.131e-15 -14.505 -14.504 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.519 -128.518 0.001 (0) +[13C](4) 6.507e-05 + H[13C]O3- 5.248e-05 4.802e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.583e-08 4.590e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.532 -139.532 0.001 (0) +[14C](4) 6.349e-16 + H[14C]O3- 5.128e-16 4.692e-16 -15.290 -15.329 -0.039 (0) + [14C]O2 1.068e-16 1.069e-16 -15.972 -15.971 0.001 (0) + CaH[14C]O3+ 1.083e-17 9.938e-18 -16.965 -17.003 -0.037 (0) + H[14C]O2[18O]- 1.023e-18 9.362e-19 -17.990 -18.029 -0.039 (0) + H[14C]O[18O]O- 1.023e-18 9.362e-19 -17.990 -18.029 -0.039 (0) + H[14C][18O]O2- 1.023e-18 9.362e-19 -17.990 -18.029 -0.039 (0) + Ca[14C]O3 5.937e-19 5.947e-19 -18.226 -18.226 0.001 (0) + [14C]O[18O] 4.439e-19 4.446e-19 -18.353 -18.352 0.001 (0) + [14C]O3-2 3.043e-19 2.133e-19 -18.517 -18.671 -0.154 (0) + CaH[14C]O2[18O]+ 2.161e-20 1.983e-20 -19.665 -19.703 -0.037 (0) + CaH[14C]O[18O]O+ 2.161e-20 1.983e-20 -19.665 -19.703 -0.037 (0) + CaH[14C][18O]O2+ 2.161e-20 1.983e-20 -19.665 -19.703 -0.037 (0) + Ca[14C]O2[18O] 3.554e-21 3.560e-21 -20.449 -20.449 0.001 (0) + H[14C]O[18O]2- 2.041e-21 1.868e-21 -20.690 -20.729 -0.039 (0) + H[14C][18O]2O- 2.041e-21 1.868e-21 -20.690 -20.729 -0.039 (0) + H[14C][18O]O[18O]- 2.041e-21 1.868e-21 -20.690 -20.729 -0.039 (0) + [14C]O2[18O]-2 1.821e-21 1.277e-21 -20.740 -20.894 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.132e-15 + O[18O] 3.126e-15 3.131e-15 -14.505 -14.504 0.001 (0) + [18O]2 3.118e-18 3.124e-18 -17.506 -17.505 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -45132,99 +45132,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.579 -126.578 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.143 -40.142 0.001 -O(0) 1.602e-12 - O2 7.981e-13 7.994e-13 -12.098 -12.097 0.001 - O[18O] 3.185e-15 3.190e-15 -14.497 -14.496 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.535 -128.534 0.001 -[13C](4) 6.507e-05 - H[13C]O3- 5.248e-05 4.802e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.583e-08 4.590e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.308e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.554 -139.554 0.001 -[14C](4) 6.265e-16 - H[14C]O3- 5.060e-16 4.630e-16 -15.296 -15.334 -0.039 - [14C]O2 1.053e-16 1.055e-16 -15.977 -15.977 0.001 - CaH[14C]O3+ 1.069e-17 9.807e-18 -16.971 -17.008 -0.037 - H[14C]O2[18O]- 1.010e-18 9.238e-19 -17.996 -18.034 -0.039 - H[14C]O[18O]O- 1.010e-18 9.238e-19 -17.996 -18.034 -0.039 - H[14C][18O]O2- 1.010e-18 9.238e-19 -17.996 -18.034 -0.039 - Ca[14C]O3 5.859e-19 5.869e-19 -18.232 -18.231 0.001 - [14C]O[18O] 4.381e-19 4.388e-19 -18.358 -18.358 0.001 - [14C]O3-2 3.003e-19 2.105e-19 -18.522 -18.677 -0.154 - CaH[14C]O2[18O]+ 2.133e-20 1.957e-20 -19.671 -19.708 -0.037 - CaH[14C]O[18O]O+ 2.133e-20 1.957e-20 -19.671 -19.708 -0.037 - CaH[14C][18O]O2+ 2.133e-20 1.957e-20 -19.671 -19.708 -0.037 - Ca[14C]O2[18O] 3.507e-21 3.513e-21 -20.455 -20.454 0.001 - H[14C]O[18O]2- 2.014e-21 1.843e-21 -20.696 -20.734 -0.039 - H[14C][18O]2O- 2.014e-21 1.843e-21 -20.696 -20.734 -0.039 - H[14C][18O]O[18O]- 2.014e-21 1.843e-21 -20.696 -20.734 -0.039 - [14C]O2[18O]-2 1.797e-21 1.260e-21 -20.745 -20.900 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.191e-15 - O[18O] 3.185e-15 3.190e-15 -14.497 -14.496 0.001 - [18O]2 3.177e-18 3.182e-18 -17.498 -17.497 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.579 -126.578 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.143 -40.142 0.001 (0) +O(0) 1.602e-12 + O2 7.981e-13 7.994e-13 -12.098 -12.097 0.001 (0) + O[18O] 3.185e-15 3.190e-15 -14.497 -14.496 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.535 -128.534 0.001 (0) +[13C](4) 6.507e-05 + H[13C]O3- 5.248e-05 4.802e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.583e-08 4.590e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.308e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.554 -139.554 0.001 (0) +[14C](4) 6.265e-16 + H[14C]O3- 5.060e-16 4.630e-16 -15.296 -15.334 -0.039 (0) + [14C]O2 1.053e-16 1.055e-16 -15.977 -15.977 0.001 (0) + CaH[14C]O3+ 1.069e-17 9.807e-18 -16.971 -17.008 -0.037 (0) + H[14C]O2[18O]- 1.010e-18 9.238e-19 -17.996 -18.034 -0.039 (0) + H[14C]O[18O]O- 1.010e-18 9.238e-19 -17.996 -18.034 -0.039 (0) + H[14C][18O]O2- 1.010e-18 9.238e-19 -17.996 -18.034 -0.039 (0) + Ca[14C]O3 5.859e-19 5.869e-19 -18.232 -18.231 0.001 (0) + [14C]O[18O] 4.381e-19 4.388e-19 -18.358 -18.358 0.001 (0) + [14C]O3-2 3.003e-19 2.105e-19 -18.522 -18.677 -0.154 (0) + CaH[14C]O2[18O]+ 2.133e-20 1.957e-20 -19.671 -19.708 -0.037 (0) + CaH[14C]O[18O]O+ 2.133e-20 1.957e-20 -19.671 -19.708 -0.037 (0) + CaH[14C][18O]O2+ 2.133e-20 1.957e-20 -19.671 -19.708 -0.037 (0) + Ca[14C]O2[18O] 3.507e-21 3.513e-21 -20.455 -20.454 0.001 (0) + H[14C]O[18O]2- 2.014e-21 1.843e-21 -20.696 -20.734 -0.039 (0) + H[14C][18O]2O- 2.014e-21 1.843e-21 -20.696 -20.734 -0.039 (0) + H[14C][18O]O[18O]- 2.014e-21 1.843e-21 -20.696 -20.734 -0.039 (0) + [14C]O2[18O]-2 1.797e-21 1.260e-21 -20.745 -20.900 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.191e-15 + O[18O] 3.185e-15 3.190e-15 -14.497 -14.496 0.001 (0) + [18O]2 3.177e-18 3.182e-18 -17.498 -17.497 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -45387,99 +45387,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.588 -126.587 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.145 -40.145 0.001 -O(0) 1.620e-12 - O2 8.066e-13 8.080e-13 -12.093 -12.093 0.001 - O[18O] 3.219e-15 3.224e-15 -14.492 -14.492 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.544 -128.543 0.001 -[13C](4) 6.507e-05 - H[13C]O3- 5.248e-05 4.802e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.583e-08 4.590e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.569 -139.569 0.001 -[14C](4) 6.183e-16 - H[14C]O3- 4.995e-16 4.570e-16 -15.302 -15.340 -0.039 - [14C]O2 1.040e-16 1.041e-16 -15.983 -15.982 0.001 - CaH[14C]O3+ 1.055e-17 9.679e-18 -16.977 -17.014 -0.037 - H[14C]O2[18O]- 9.965e-19 9.118e-19 -18.002 -18.040 -0.039 - H[14C]O[18O]O- 9.965e-19 9.118e-19 -18.002 -18.040 -0.039 - H[14C][18O]O2- 9.965e-19 9.118e-19 -18.002 -18.040 -0.039 - Ca[14C]O3 5.783e-19 5.792e-19 -18.238 -18.237 0.001 - [14C]O[18O] 4.324e-19 4.331e-19 -18.364 -18.363 0.001 - [14C]O3-2 2.964e-19 2.077e-19 -18.528 -18.682 -0.154 - CaH[14C]O2[18O]+ 2.105e-20 1.931e-20 -19.677 -19.714 -0.037 - CaH[14C]O[18O]O+ 2.105e-20 1.931e-20 -19.677 -19.714 -0.037 - CaH[14C][18O]O2+ 2.105e-20 1.931e-20 -19.677 -19.714 -0.037 - Ca[14C]O2[18O] 3.461e-21 3.467e-21 -20.461 -20.460 0.001 - H[14C]O[18O]2- 1.988e-21 1.819e-21 -20.702 -20.740 -0.039 - H[14C][18O]2O- 1.988e-21 1.819e-21 -20.702 -20.740 -0.039 - H[14C][18O]O[18O]- 1.988e-21 1.819e-21 -20.702 -20.740 -0.039 - [14C]O2[18O]-2 1.774e-21 1.243e-21 -20.751 -20.905 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.225e-15 - O[18O] 3.219e-15 3.224e-15 -14.492 -14.492 0.001 - [18O]2 3.211e-18 3.216e-18 -17.493 -17.493 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.588 -126.587 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.145 -40.145 0.001 (0) +O(0) 1.620e-12 + O2 8.066e-13 8.080e-13 -12.093 -12.093 0.001 (0) + O[18O] 3.219e-15 3.224e-15 -14.492 -14.492 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.544 -128.543 0.001 (0) +[13C](4) 6.507e-05 + H[13C]O3- 5.248e-05 4.802e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.581e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.583e-08 4.590e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.569 -139.569 0.001 (0) +[14C](4) 6.183e-16 + H[14C]O3- 4.995e-16 4.570e-16 -15.302 -15.340 -0.039 (0) + [14C]O2 1.040e-16 1.041e-16 -15.983 -15.982 0.001 (0) + CaH[14C]O3+ 1.055e-17 9.679e-18 -16.977 -17.014 -0.037 (0) + H[14C]O2[18O]- 9.965e-19 9.118e-19 -18.002 -18.040 -0.039 (0) + H[14C]O[18O]O- 9.965e-19 9.118e-19 -18.002 -18.040 -0.039 (0) + H[14C][18O]O2- 9.965e-19 9.118e-19 -18.002 -18.040 -0.039 (0) + Ca[14C]O3 5.783e-19 5.792e-19 -18.238 -18.237 0.001 (0) + [14C]O[18O] 4.324e-19 4.331e-19 -18.364 -18.363 0.001 (0) + [14C]O3-2 2.964e-19 2.077e-19 -18.528 -18.682 -0.154 (0) + CaH[14C]O2[18O]+ 2.105e-20 1.931e-20 -19.677 -19.714 -0.037 (0) + CaH[14C]O[18O]O+ 2.105e-20 1.931e-20 -19.677 -19.714 -0.037 (0) + CaH[14C][18O]O2+ 2.105e-20 1.931e-20 -19.677 -19.714 -0.037 (0) + Ca[14C]O2[18O] 3.461e-21 3.467e-21 -20.461 -20.460 0.001 (0) + H[14C]O[18O]2- 1.988e-21 1.819e-21 -20.702 -20.740 -0.039 (0) + H[14C][18O]2O- 1.988e-21 1.819e-21 -20.702 -20.740 -0.039 (0) + H[14C][18O]O[18O]- 1.988e-21 1.819e-21 -20.702 -20.740 -0.039 (0) + [14C]O2[18O]-2 1.774e-21 1.243e-21 -20.751 -20.905 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.225e-15 + O[18O] 3.219e-15 3.224e-15 -14.492 -14.492 0.001 (0) + [18O]2 3.211e-18 3.216e-18 -17.493 -17.493 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -45642,99 +45642,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.597 -126.596 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.147 -40.147 0.001 -O(0) 1.636e-12 - O2 8.148e-13 8.161e-13 -12.089 -12.088 0.001 - O[18O] 3.251e-15 3.257e-15 -14.488 -14.487 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.553 -128.552 0.001 -[13C](4) 6.508e-05 - H[13C]O3- 5.249e-05 4.802e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.583e-08 4.591e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.584 -139.583 0.001 -[14C](4) 6.104e-16 - H[14C]O3- 4.930e-16 4.511e-16 -15.307 -15.346 -0.039 - [14C]O2 1.026e-16 1.028e-16 -15.989 -15.988 0.001 - CaH[14C]O3+ 1.041e-17 9.555e-18 -16.982 -17.020 -0.037 - H[14C]O2[18O]- 9.837e-19 9.001e-19 -18.007 -18.046 -0.039 - H[14C]O[18O]O- 9.837e-19 9.001e-19 -18.007 -18.046 -0.039 - H[14C][18O]O2- 9.837e-19 9.001e-19 -18.007 -18.046 -0.039 - Ca[14C]O3 5.708e-19 5.718e-19 -18.243 -18.243 0.001 - [14C]O[18O] 4.268e-19 4.275e-19 -18.370 -18.369 0.001 - [14C]O3-2 2.926e-19 2.051e-19 -18.534 -18.688 -0.154 - CaH[14C]O2[18O]+ 2.078e-20 1.906e-20 -19.682 -19.720 -0.037 - CaH[14C]O[18O]O+ 2.078e-20 1.906e-20 -19.682 -19.720 -0.037 - CaH[14C][18O]O2+ 2.078e-20 1.906e-20 -19.682 -19.720 -0.037 - Ca[14C]O2[18O] 3.417e-21 3.422e-21 -20.466 -20.466 0.001 - H[14C]O[18O]2- 1.963e-21 1.796e-21 -20.707 -20.746 -0.039 - H[14C][18O]2O- 1.963e-21 1.796e-21 -20.707 -20.746 -0.039 - H[14C][18O]O[18O]- 1.963e-21 1.796e-21 -20.707 -20.746 -0.039 - [14C]O2[18O]-2 1.751e-21 1.227e-21 -20.757 -20.911 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.258e-15 - O[18O] 3.251e-15 3.257e-15 -14.488 -14.487 0.001 - [18O]2 3.243e-18 3.249e-18 -17.489 -17.488 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.597 -126.596 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.147 -40.147 0.001 (0) +O(0) 1.636e-12 + O2 8.148e-13 8.161e-13 -12.089 -12.088 0.001 (0) + O[18O] 3.251e-15 3.257e-15 -14.488 -14.487 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.553 -128.552 0.001 (0) +[13C](4) 6.508e-05 + H[13C]O3- 5.249e-05 4.802e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.085e-08 6.095e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.583e-08 4.591e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.029e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.642e-10 3.648e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.584 -139.583 0.001 (0) +[14C](4) 6.104e-16 + H[14C]O3- 4.930e-16 4.511e-16 -15.307 -15.346 -0.039 (0) + [14C]O2 1.026e-16 1.028e-16 -15.989 -15.988 0.001 (0) + CaH[14C]O3+ 1.041e-17 9.555e-18 -16.982 -17.020 -0.037 (0) + H[14C]O2[18O]- 9.837e-19 9.001e-19 -18.007 -18.046 -0.039 (0) + H[14C]O[18O]O- 9.837e-19 9.001e-19 -18.007 -18.046 -0.039 (0) + H[14C][18O]O2- 9.837e-19 9.001e-19 -18.007 -18.046 -0.039 (0) + Ca[14C]O3 5.708e-19 5.718e-19 -18.243 -18.243 0.001 (0) + [14C]O[18O] 4.268e-19 4.275e-19 -18.370 -18.369 0.001 (0) + [14C]O3-2 2.926e-19 2.051e-19 -18.534 -18.688 -0.154 (0) + CaH[14C]O2[18O]+ 2.078e-20 1.906e-20 -19.682 -19.720 -0.037 (0) + CaH[14C]O[18O]O+ 2.078e-20 1.906e-20 -19.682 -19.720 -0.037 (0) + CaH[14C][18O]O2+ 2.078e-20 1.906e-20 -19.682 -19.720 -0.037 (0) + Ca[14C]O2[18O] 3.417e-21 3.422e-21 -20.466 -20.466 0.001 (0) + H[14C]O[18O]2- 1.963e-21 1.796e-21 -20.707 -20.746 -0.039 (0) + H[14C][18O]2O- 1.963e-21 1.796e-21 -20.707 -20.746 -0.039 (0) + H[14C][18O]O[18O]- 1.963e-21 1.796e-21 -20.707 -20.746 -0.039 (0) + [14C]O2[18O]-2 1.751e-21 1.227e-21 -20.757 -20.911 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.258e-15 + O[18O] 3.251e-15 3.257e-15 -14.488 -14.487 0.001 (0) + [18O]2 3.243e-18 3.249e-18 -17.489 -17.488 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -45897,99 +45897,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.600 -126.599 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.148 -40.148 0.001 -O(0) 1.642e-12 - O2 8.177e-13 8.190e-13 -12.087 -12.087 0.001 - O[18O] 3.263e-15 3.268e-15 -14.486 -14.486 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.556 -128.555 0.001 -[13C](4) 6.508e-05 - H[13C]O3- 5.249e-05 4.802e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.583e-08 4.591e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.592 -139.592 0.001 -[14C](4) 6.027e-16 - H[14C]O3- 4.868e-16 4.454e-16 -15.313 -15.351 -0.039 - [14C]O2 1.013e-16 1.015e-16 -15.994 -15.994 0.001 - CaH[14C]O3+ 1.028e-17 9.434e-18 -16.988 -17.025 -0.037 - H[14C]O2[18O]- 9.712e-19 8.887e-19 -18.013 -18.051 -0.039 - H[14C]O[18O]O- 9.712e-19 8.887e-19 -18.013 -18.051 -0.039 - H[14C][18O]O2- 9.712e-19 8.887e-19 -18.013 -18.051 -0.039 - Ca[14C]O3 5.636e-19 5.645e-19 -18.249 -18.248 0.001 - [14C]O[18O] 4.214e-19 4.221e-19 -18.375 -18.375 0.001 - [14C]O3-2 2.889e-19 2.025e-19 -18.539 -18.694 -0.154 - CaH[14C]O2[18O]+ 2.052e-20 1.882e-20 -19.688 -19.725 -0.037 - CaH[14C]O[18O]O+ 2.052e-20 1.882e-20 -19.688 -19.725 -0.037 - CaH[14C][18O]O2+ 2.052e-20 1.882e-20 -19.688 -19.725 -0.037 - Ca[14C]O2[18O] 3.373e-21 3.379e-21 -20.472 -20.471 0.001 - H[14C]O[18O]2- 1.938e-21 1.773e-21 -20.713 -20.751 -0.039 - H[14C][18O]2O- 1.938e-21 1.773e-21 -20.713 -20.751 -0.039 - H[14C][18O]O[18O]- 1.938e-21 1.773e-21 -20.713 -20.751 -0.039 - [14C]O2[18O]-2 1.729e-21 1.212e-21 -20.762 -20.917 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.269e-15 - O[18O] 3.263e-15 3.268e-15 -14.486 -14.486 0.001 - [18O]2 3.255e-18 3.260e-18 -17.487 -17.487 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.600 -126.599 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.148 -40.148 0.001 (0) +O(0) 1.642e-12 + O2 8.177e-13 8.190e-13 -12.087 -12.087 0.001 (0) + O[18O] 3.263e-15 3.268e-15 -14.486 -14.486 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.556 -128.555 0.001 (0) +[13C](4) 6.508e-05 + H[13C]O3- 5.249e-05 4.802e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.583e-08 4.591e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.592 -139.592 0.001 (0) +[14C](4) 6.027e-16 + H[14C]O3- 4.868e-16 4.454e-16 -15.313 -15.351 -0.039 (0) + [14C]O2 1.013e-16 1.015e-16 -15.994 -15.994 0.001 (0) + CaH[14C]O3+ 1.028e-17 9.434e-18 -16.988 -17.025 -0.037 (0) + H[14C]O2[18O]- 9.712e-19 8.887e-19 -18.013 -18.051 -0.039 (0) + H[14C]O[18O]O- 9.712e-19 8.887e-19 -18.013 -18.051 -0.039 (0) + H[14C][18O]O2- 9.712e-19 8.887e-19 -18.013 -18.051 -0.039 (0) + Ca[14C]O3 5.636e-19 5.645e-19 -18.249 -18.248 0.001 (0) + [14C]O[18O] 4.214e-19 4.221e-19 -18.375 -18.375 0.001 (0) + [14C]O3-2 2.889e-19 2.025e-19 -18.539 -18.694 -0.154 (0) + CaH[14C]O2[18O]+ 2.052e-20 1.882e-20 -19.688 -19.725 -0.037 (0) + CaH[14C]O[18O]O+ 2.052e-20 1.882e-20 -19.688 -19.725 -0.037 (0) + CaH[14C][18O]O2+ 2.052e-20 1.882e-20 -19.688 -19.725 -0.037 (0) + Ca[14C]O2[18O] 3.373e-21 3.379e-21 -20.472 -20.471 0.001 (0) + H[14C]O[18O]2- 1.938e-21 1.773e-21 -20.713 -20.751 -0.039 (0) + H[14C][18O]2O- 1.938e-21 1.773e-21 -20.713 -20.751 -0.039 (0) + H[14C][18O]O[18O]- 1.938e-21 1.773e-21 -20.713 -20.751 -0.039 (0) + [14C]O2[18O]-2 1.729e-21 1.212e-21 -20.762 -20.917 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.269e-15 + O[18O] 3.263e-15 3.268e-15 -14.486 -14.486 0.001 (0) + [18O]2 3.255e-18 3.260e-18 -17.487 -17.487 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -46152,99 +46152,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.604 -126.603 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.149 -40.148 0.001 -O(0) 1.649e-12 - O2 8.213e-13 8.226e-13 -12.086 -12.085 0.001 - O[18O] 3.277e-15 3.283e-15 -14.484 -14.484 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.560 -128.559 0.001 -[13C](4) 6.508e-05 - H[13C]O3- 5.249e-05 4.803e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.583e-08 4.591e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.602 -139.601 0.001 -[14C](4) 5.951e-16 - H[14C]O3- 4.807e-16 4.398e-16 -15.318 -15.357 -0.039 - [14C]O2 1.001e-16 1.002e-16 -16.000 -15.999 0.001 - CaH[14C]O3+ 1.015e-17 9.316e-18 -16.993 -17.031 -0.037 - H[14C]O2[18O]- 9.590e-19 8.775e-19 -18.018 -18.057 -0.039 - H[14C]O[18O]O- 9.590e-19 8.775e-19 -18.018 -18.057 -0.039 - H[14C][18O]O2- 9.590e-19 8.775e-19 -18.018 -18.057 -0.039 - Ca[14C]O3 5.565e-19 5.574e-19 -18.255 -18.254 0.001 - [14C]O[18O] 4.161e-19 4.168e-19 -18.381 -18.380 0.001 - [14C]O3-2 2.852e-19 1.999e-19 -18.545 -18.699 -0.154 - CaH[14C]O2[18O]+ 2.026e-20 1.859e-20 -19.693 -19.731 -0.037 - CaH[14C]O[18O]O+ 2.026e-20 1.859e-20 -19.693 -19.731 -0.037 - CaH[14C][18O]O2+ 2.026e-20 1.859e-20 -19.693 -19.731 -0.037 - Ca[14C]O2[18O] 3.331e-21 3.337e-21 -20.477 -20.477 0.001 - H[14C]O[18O]2- 1.913e-21 1.751e-21 -20.718 -20.757 -0.039 - H[14C][18O]2O- 1.913e-21 1.751e-21 -20.718 -20.757 -0.039 - H[14C][18O]O[18O]- 1.913e-21 1.751e-21 -20.718 -20.757 -0.039 - [14C]O2[18O]-2 1.707e-21 1.197e-21 -20.768 -20.922 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.284e-15 - O[18O] 3.277e-15 3.283e-15 -14.484 -14.484 0.001 - [18O]2 3.269e-18 3.275e-18 -17.486 -17.485 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.604 -126.603 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.149 -40.148 0.001 (0) +O(0) 1.649e-12 + O2 8.213e-13 8.226e-13 -12.086 -12.085 0.001 (0) + O[18O] 3.277e-15 3.283e-15 -14.484 -14.484 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.560 -128.559 0.001 (0) +[13C](4) 6.508e-05 + H[13C]O3- 5.249e-05 4.803e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.583e-08 4.591e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.602 -139.601 0.001 (0) +[14C](4) 5.951e-16 + H[14C]O3- 4.807e-16 4.398e-16 -15.318 -15.357 -0.039 (0) + [14C]O2 1.001e-16 1.002e-16 -16.000 -15.999 0.001 (0) + CaH[14C]O3+ 1.015e-17 9.316e-18 -16.993 -17.031 -0.037 (0) + H[14C]O2[18O]- 9.590e-19 8.775e-19 -18.018 -18.057 -0.039 (0) + H[14C]O[18O]O- 9.590e-19 8.775e-19 -18.018 -18.057 -0.039 (0) + H[14C][18O]O2- 9.590e-19 8.775e-19 -18.018 -18.057 -0.039 (0) + Ca[14C]O3 5.565e-19 5.574e-19 -18.255 -18.254 0.001 (0) + [14C]O[18O] 4.161e-19 4.168e-19 -18.381 -18.380 0.001 (0) + [14C]O3-2 2.852e-19 1.999e-19 -18.545 -18.699 -0.154 (0) + CaH[14C]O2[18O]+ 2.026e-20 1.859e-20 -19.693 -19.731 -0.037 (0) + CaH[14C]O[18O]O+ 2.026e-20 1.859e-20 -19.693 -19.731 -0.037 (0) + CaH[14C][18O]O2+ 2.026e-20 1.859e-20 -19.693 -19.731 -0.037 (0) + Ca[14C]O2[18O] 3.331e-21 3.337e-21 -20.477 -20.477 0.001 (0) + H[14C]O[18O]2- 1.913e-21 1.751e-21 -20.718 -20.757 -0.039 (0) + H[14C][18O]2O- 1.913e-21 1.751e-21 -20.718 -20.757 -0.039 (0) + H[14C][18O]O[18O]- 1.913e-21 1.751e-21 -20.718 -20.757 -0.039 (0) + [14C]O2[18O]-2 1.707e-21 1.197e-21 -20.768 -20.922 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.284e-15 + O[18O] 3.277e-15 3.283e-15 -14.484 -14.484 0.001 (0) + [18O]2 3.269e-18 3.275e-18 -17.486 -17.485 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -46407,99 +46407,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.611 -126.610 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.151 -40.150 0.001 -O(0) 1.662e-12 - O2 8.279e-13 8.292e-13 -12.082 -12.081 0.001 - O[18O] 3.304e-15 3.309e-15 -14.481 -14.480 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.567 -128.566 0.001 -[13C](4) 6.508e-05 - H[13C]O3- 5.249e-05 4.803e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.583e-08 4.591e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.614 -139.613 0.001 -[14C](4) 5.877e-16 - H[14C]O3- 4.747e-16 4.344e-16 -15.324 -15.362 -0.039 - [14C]O2 9.883e-17 9.899e-17 -16.005 -16.004 0.001 - CaH[14C]O3+ 1.003e-17 9.200e-18 -16.999 -17.036 -0.037 - H[14C]O2[18O]- 9.472e-19 8.667e-19 -18.024 -18.062 -0.039 - H[14C]O[18O]O- 9.472e-19 8.667e-19 -18.024 -18.062 -0.039 - H[14C][18O]O2- 9.472e-19 8.667e-19 -18.024 -18.062 -0.039 - Ca[14C]O3 5.496e-19 5.505e-19 -18.260 -18.259 0.001 - [14C]O[18O] 4.110e-19 4.116e-19 -18.386 -18.385 0.001 - [14C]O3-2 2.817e-19 1.975e-19 -18.550 -18.705 -0.154 - CaH[14C]O2[18O]+ 2.001e-20 1.836e-20 -19.699 -19.736 -0.037 - CaH[14C]O[18O]O+ 2.001e-20 1.836e-20 -19.699 -19.736 -0.037 - CaH[14C][18O]O2+ 2.001e-20 1.836e-20 -19.699 -19.736 -0.037 - Ca[14C]O2[18O] 3.290e-21 3.295e-21 -20.483 -20.482 0.001 - H[14C]O[18O]2- 1.890e-21 1.729e-21 -20.724 -20.762 -0.039 - H[14C][18O]2O- 1.890e-21 1.729e-21 -20.724 -20.762 -0.039 - H[14C][18O]O[18O]- 1.890e-21 1.729e-21 -20.724 -20.762 -0.039 - [14C]O2[18O]-2 1.686e-21 1.182e-21 -20.773 -20.927 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.310e-15 - O[18O] 3.304e-15 3.309e-15 -14.481 -14.480 0.001 - [18O]2 3.296e-18 3.301e-18 -17.482 -17.481 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.611 -126.610 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.151 -40.150 0.001 (0) +O(0) 1.662e-12 + O2 8.279e-13 8.292e-13 -12.082 -12.081 0.001 (0) + O[18O] 3.304e-15 3.309e-15 -14.481 -14.480 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.567 -128.566 0.001 (0) +[13C](4) 6.508e-05 + H[13C]O3- 5.249e-05 4.803e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.582e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.583e-08 4.591e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.089e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.614 -139.613 0.001 (0) +[14C](4) 5.877e-16 + H[14C]O3- 4.747e-16 4.344e-16 -15.324 -15.362 -0.039 (0) + [14C]O2 9.883e-17 9.899e-17 -16.005 -16.004 0.001 (0) + CaH[14C]O3+ 1.003e-17 9.200e-18 -16.999 -17.036 -0.037 (0) + H[14C]O2[18O]- 9.472e-19 8.667e-19 -18.024 -18.062 -0.039 (0) + H[14C]O[18O]O- 9.472e-19 8.667e-19 -18.024 -18.062 -0.039 (0) + H[14C][18O]O2- 9.472e-19 8.667e-19 -18.024 -18.062 -0.039 (0) + Ca[14C]O3 5.496e-19 5.505e-19 -18.260 -18.259 0.001 (0) + [14C]O[18O] 4.110e-19 4.116e-19 -18.386 -18.385 0.001 (0) + [14C]O3-2 2.817e-19 1.975e-19 -18.550 -18.705 -0.154 (0) + CaH[14C]O2[18O]+ 2.001e-20 1.836e-20 -19.699 -19.736 -0.037 (0) + CaH[14C]O[18O]O+ 2.001e-20 1.836e-20 -19.699 -19.736 -0.037 (0) + CaH[14C][18O]O2+ 2.001e-20 1.836e-20 -19.699 -19.736 -0.037 (0) + Ca[14C]O2[18O] 3.290e-21 3.295e-21 -20.483 -20.482 0.001 (0) + H[14C]O[18O]2- 1.890e-21 1.729e-21 -20.724 -20.762 -0.039 (0) + H[14C][18O]2O- 1.890e-21 1.729e-21 -20.724 -20.762 -0.039 (0) + H[14C][18O]O[18O]- 1.890e-21 1.729e-21 -20.724 -20.762 -0.039 (0) + [14C]O2[18O]-2 1.686e-21 1.182e-21 -20.773 -20.927 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.310e-15 + O[18O] 3.304e-15 3.309e-15 -14.481 -14.480 0.001 (0) + [18O]2 3.296e-18 3.301e-18 -17.482 -17.481 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -46662,99 +46662,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.612 -126.611 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.151 -40.151 0.001 -O(0) 1.665e-12 - O2 8.294e-13 8.307e-13 -12.081 -12.081 0.001 - O[18O] 3.310e-15 3.315e-15 -14.480 -14.480 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.568 -128.567 0.001 -[13C](4) 6.508e-05 - H[13C]O3- 5.249e-05 4.803e-05 -4.280 -4.319 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.583e-08 4.591e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.621 -139.620 0.001 -[14C](4) 5.806e-16 - H[14C]O3- 4.689e-16 4.291e-16 -15.329 -15.367 -0.039 - [14C]O2 9.762e-17 9.778e-17 -16.010 -16.010 0.001 - CaH[14C]O3+ 9.906e-18 9.088e-18 -17.004 -17.042 -0.037 - H[14C]O2[18O]- 9.356e-19 8.561e-19 -18.029 -18.067 -0.039 - H[14C]O[18O]O- 9.356e-19 8.561e-19 -18.029 -18.067 -0.039 - H[14C][18O]O2- 9.356e-19 8.561e-19 -18.029 -18.067 -0.039 - Ca[14C]O3 5.429e-19 5.438e-19 -18.265 -18.265 0.001 - [14C]O[18O] 4.059e-19 4.066e-19 -18.392 -18.391 0.001 - [14C]O3-2 2.783e-19 1.950e-19 -18.556 -18.710 -0.154 - CaH[14C]O2[18O]+ 1.976e-20 1.813e-20 -19.704 -19.742 -0.037 - CaH[14C]O[18O]O+ 1.976e-20 1.813e-20 -19.704 -19.742 -0.037 - CaH[14C][18O]O2+ 1.976e-20 1.813e-20 -19.704 -19.742 -0.037 - Ca[14C]O2[18O] 3.250e-21 3.255e-21 -20.488 -20.487 0.001 - H[14C]O[18O]2- 1.867e-21 1.708e-21 -20.729 -20.768 -0.039 - H[14C][18O]2O- 1.867e-21 1.708e-21 -20.729 -20.768 -0.039 - H[14C][18O]O[18O]- 1.867e-21 1.708e-21 -20.729 -20.768 -0.039 - [14C]O2[18O]-2 1.666e-21 1.167e-21 -20.778 -20.933 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.316e-15 - O[18O] 3.310e-15 3.315e-15 -14.480 -14.480 0.001 - [18O]2 3.302e-18 3.307e-18 -17.481 -17.481 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.612 -126.611 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.151 -40.151 0.001 (0) +O(0) 1.665e-12 + O2 8.294e-13 8.307e-13 -12.081 -12.081 0.001 (0) + O[18O] 3.310e-15 3.315e-15 -14.480 -14.480 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.568 -128.567 0.001 (0) +[13C](4) 6.508e-05 + H[13C]O3- 5.249e-05 4.803e-05 -4.280 -4.319 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.583e-08 4.591e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.621 -139.620 0.001 (0) +[14C](4) 5.806e-16 + H[14C]O3- 4.689e-16 4.291e-16 -15.329 -15.367 -0.039 (0) + [14C]O2 9.762e-17 9.778e-17 -16.010 -16.010 0.001 (0) + CaH[14C]O3+ 9.906e-18 9.088e-18 -17.004 -17.042 -0.037 (0) + H[14C]O2[18O]- 9.356e-19 8.561e-19 -18.029 -18.067 -0.039 (0) + H[14C]O[18O]O- 9.356e-19 8.561e-19 -18.029 -18.067 -0.039 (0) + H[14C][18O]O2- 9.356e-19 8.561e-19 -18.029 -18.067 -0.039 (0) + Ca[14C]O3 5.429e-19 5.438e-19 -18.265 -18.265 0.001 (0) + [14C]O[18O] 4.059e-19 4.066e-19 -18.392 -18.391 0.001 (0) + [14C]O3-2 2.783e-19 1.950e-19 -18.556 -18.710 -0.154 (0) + CaH[14C]O2[18O]+ 1.976e-20 1.813e-20 -19.704 -19.742 -0.037 (0) + CaH[14C]O[18O]O+ 1.976e-20 1.813e-20 -19.704 -19.742 -0.037 (0) + CaH[14C][18O]O2+ 1.976e-20 1.813e-20 -19.704 -19.742 -0.037 (0) + Ca[14C]O2[18O] 3.250e-21 3.255e-21 -20.488 -20.487 0.001 (0) + H[14C]O[18O]2- 1.867e-21 1.708e-21 -20.729 -20.768 -0.039 (0) + H[14C][18O]2O- 1.867e-21 1.708e-21 -20.729 -20.768 -0.039 (0) + H[14C][18O]O[18O]- 1.867e-21 1.708e-21 -20.729 -20.768 -0.039 (0) + [14C]O2[18O]-2 1.666e-21 1.167e-21 -20.778 -20.933 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.316e-15 + O[18O] 3.310e-15 3.315e-15 -14.480 -14.480 0.001 (0) + [18O]2 3.302e-18 3.307e-18 -17.481 -17.481 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -46917,99 +46917,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.600 -126.599 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.148 -40.147 0.001 -O(0) 1.642e-12 - O2 8.176e-13 8.189e-13 -12.087 -12.087 0.001 - O[18O] 3.262e-15 3.268e-15 -14.486 -14.486 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.556 -128.555 0.001 -[13C](4) 6.508e-05 - H[13C]O3- 5.249e-05 4.803e-05 -4.280 -4.318 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.583e-08 4.591e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.614 -139.613 0.001 -[14C](4) 5.735e-16 - H[14C]O3- 4.633e-16 4.239e-16 -15.334 -15.373 -0.039 - [14C]O2 9.644e-17 9.660e-17 -16.016 -16.015 0.001 - CaH[14C]O3+ 9.786e-18 8.978e-18 -17.009 -17.047 -0.037 - H[14C]O2[18O]- 9.243e-19 8.457e-19 -18.034 -18.073 -0.039 - H[14C]O[18O]O- 9.243e-19 8.457e-19 -18.034 -18.073 -0.039 - H[14C][18O]O2- 9.243e-19 8.457e-19 -18.034 -18.073 -0.039 - Ca[14C]O3 5.364e-19 5.372e-19 -18.271 -18.270 0.001 - [14C]O[18O] 4.010e-19 4.017e-19 -18.397 -18.396 0.001 - [14C]O3-2 2.749e-19 1.927e-19 -18.561 -18.715 -0.154 - CaH[14C]O2[18O]+ 1.953e-20 1.791e-20 -19.709 -19.747 -0.037 - CaH[14C]O[18O]O+ 1.953e-20 1.791e-20 -19.709 -19.747 -0.037 - CaH[14C][18O]O2+ 1.953e-20 1.791e-20 -19.709 -19.747 -0.037 - Ca[14C]O2[18O] 3.210e-21 3.216e-21 -20.493 -20.493 0.001 - H[14C]O[18O]2- 1.844e-21 1.687e-21 -20.734 -20.773 -0.039 - H[14C][18O]2O- 1.844e-21 1.687e-21 -20.734 -20.773 -0.039 - H[14C][18O]O[18O]- 1.844e-21 1.687e-21 -20.734 -20.773 -0.039 - [14C]O2[18O]-2 1.645e-21 1.153e-21 -20.784 -20.938 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.269e-15 - O[18O] 3.262e-15 3.268e-15 -14.486 -14.486 0.001 - [18O]2 3.255e-18 3.260e-18 -17.488 -17.487 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.600 -126.599 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.148 -40.147 0.001 (0) +O(0) 1.642e-12 + O2 8.176e-13 8.189e-13 -12.087 -12.087 0.001 (0) + O[18O] 3.262e-15 3.268e-15 -14.486 -14.486 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.556 -128.555 0.001 (0) +[13C](4) 6.508e-05 + H[13C]O3- 5.249e-05 4.803e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.583e-08 4.591e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.614 -139.613 0.001 (0) +[14C](4) 5.735e-16 + H[14C]O3- 4.633e-16 4.239e-16 -15.334 -15.373 -0.039 (0) + [14C]O2 9.644e-17 9.660e-17 -16.016 -16.015 0.001 (0) + CaH[14C]O3+ 9.786e-18 8.978e-18 -17.009 -17.047 -0.037 (0) + H[14C]O2[18O]- 9.243e-19 8.457e-19 -18.034 -18.073 -0.039 (0) + H[14C]O[18O]O- 9.243e-19 8.457e-19 -18.034 -18.073 -0.039 (0) + H[14C][18O]O2- 9.243e-19 8.457e-19 -18.034 -18.073 -0.039 (0) + Ca[14C]O3 5.364e-19 5.372e-19 -18.271 -18.270 0.001 (0) + [14C]O[18O] 4.010e-19 4.017e-19 -18.397 -18.396 0.001 (0) + [14C]O3-2 2.749e-19 1.927e-19 -18.561 -18.715 -0.154 (0) + CaH[14C]O2[18O]+ 1.953e-20 1.791e-20 -19.709 -19.747 -0.037 (0) + CaH[14C]O[18O]O+ 1.953e-20 1.791e-20 -19.709 -19.747 -0.037 (0) + CaH[14C][18O]O2+ 1.953e-20 1.791e-20 -19.709 -19.747 -0.037 (0) + Ca[14C]O2[18O] 3.210e-21 3.216e-21 -20.493 -20.493 0.001 (0) + H[14C]O[18O]2- 1.844e-21 1.687e-21 -20.734 -20.773 -0.039 (0) + H[14C][18O]2O- 1.844e-21 1.687e-21 -20.734 -20.773 -0.039 (0) + H[14C][18O]O[18O]- 1.844e-21 1.687e-21 -20.734 -20.773 -0.039 (0) + [14C]O2[18O]-2 1.645e-21 1.153e-21 -20.784 -20.938 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.269e-15 + O[18O] 3.262e-15 3.268e-15 -14.486 -14.486 0.001 (0) + [18O]2 3.255e-18 3.260e-18 -17.488 -17.487 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -47172,99 +47172,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.591 -126.590 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.146 -40.145 0.001 -O(0) 1.625e-12 - O2 8.093e-13 8.106e-13 -12.092 -12.091 0.001 - O[18O] 3.229e-15 3.235e-15 -14.491 -14.490 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.547 -128.546 0.001 -[13C](4) 6.508e-05 - H[13C]O3- 5.249e-05 4.803e-05 -4.280 -4.318 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 - H[13C]O[18O]O- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 - H[13C][18O]O2- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.584e-08 4.591e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.610 -139.609 0.001 -[14C](4) 5.667e-16 - H[14C]O3- 4.577e-16 4.188e-16 -15.339 -15.378 -0.039 - [14C]O2 9.529e-17 9.545e-17 -16.021 -16.020 0.001 - CaH[14C]O3+ 9.669e-18 8.871e-18 -17.015 -17.052 -0.037 - H[14C]O2[18O]- 9.133e-19 8.356e-19 -18.039 -18.078 -0.039 - H[14C]O[18O]O- 9.133e-19 8.356e-19 -18.039 -18.078 -0.039 - H[14C][18O]O2- 9.133e-19 8.356e-19 -18.039 -18.078 -0.039 - Ca[14C]O3 5.300e-19 5.308e-19 -18.276 -18.275 0.001 - [14C]O[18O] 3.962e-19 3.969e-19 -18.402 -18.401 0.001 - [14C]O3-2 2.716e-19 1.904e-19 -18.566 -18.720 -0.154 - CaH[14C]O2[18O]+ 1.929e-20 1.770e-20 -19.715 -19.752 -0.037 - CaH[14C]O[18O]O+ 1.929e-20 1.770e-20 -19.715 -19.752 -0.037 - CaH[14C][18O]O2+ 1.929e-20 1.770e-20 -19.715 -19.752 -0.037 - Ca[14C]O2[18O] 3.172e-21 3.177e-21 -20.499 -20.498 0.001 - H[14C]O[18O]2- 1.822e-21 1.667e-21 -20.739 -20.778 -0.039 - H[14C][18O]2O- 1.822e-21 1.667e-21 -20.739 -20.778 -0.039 - H[14C][18O]O[18O]- 1.822e-21 1.667e-21 -20.739 -20.778 -0.039 - [14C]O2[18O]-2 1.626e-21 1.140e-21 -20.789 -20.943 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.236e-15 - O[18O] 3.229e-15 3.235e-15 -14.491 -14.490 0.001 - [18O]2 3.222e-18 3.227e-18 -17.492 -17.491 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.591 -126.590 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.146 -40.145 0.001 (0) +O(0) 1.625e-12 + O2 8.093e-13 8.106e-13 -12.092 -12.091 0.001 (0) + O[18O] 3.229e-15 3.235e-15 -14.491 -14.490 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.547 -128.546 0.001 (0) +[13C](4) 6.508e-05 + H[13C]O3- 5.249e-05 4.803e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.583e-08 -6.980 -7.019 -0.039 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.584e-08 4.591e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.119e-08 2.186e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.610 -139.609 0.001 (0) +[14C](4) 5.667e-16 + H[14C]O3- 4.577e-16 4.188e-16 -15.339 -15.378 -0.039 (0) + [14C]O2 9.529e-17 9.545e-17 -16.021 -16.020 0.001 (0) + CaH[14C]O3+ 9.669e-18 8.871e-18 -17.015 -17.052 -0.037 (0) + H[14C]O2[18O]- 9.133e-19 8.356e-19 -18.039 -18.078 -0.039 (0) + H[14C]O[18O]O- 9.133e-19 8.356e-19 -18.039 -18.078 -0.039 (0) + H[14C][18O]O2- 9.133e-19 8.356e-19 -18.039 -18.078 -0.039 (0) + Ca[14C]O3 5.300e-19 5.308e-19 -18.276 -18.275 0.001 (0) + [14C]O[18O] 3.962e-19 3.969e-19 -18.402 -18.401 0.001 (0) + [14C]O3-2 2.716e-19 1.904e-19 -18.566 -18.720 -0.154 (0) + CaH[14C]O2[18O]+ 1.929e-20 1.770e-20 -19.715 -19.752 -0.037 (0) + CaH[14C]O[18O]O+ 1.929e-20 1.770e-20 -19.715 -19.752 -0.037 (0) + CaH[14C][18O]O2+ 1.929e-20 1.770e-20 -19.715 -19.752 -0.037 (0) + Ca[14C]O2[18O] 3.172e-21 3.177e-21 -20.499 -20.498 0.001 (0) + H[14C]O[18O]2- 1.822e-21 1.667e-21 -20.739 -20.778 -0.039 (0) + H[14C][18O]2O- 1.822e-21 1.667e-21 -20.739 -20.778 -0.039 (0) + H[14C][18O]O[18O]- 1.822e-21 1.667e-21 -20.739 -20.778 -0.039 (0) + [14C]O2[18O]-2 1.626e-21 1.140e-21 -20.789 -20.943 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.236e-15 + O[18O] 3.229e-15 3.235e-15 -14.491 -14.490 0.001 (0) + [18O]2 3.222e-18 3.227e-18 -17.492 -17.491 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -47427,99 +47427,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.585 -126.584 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.144 -40.144 0.001 -O(0) 1.613e-12 - O2 8.035e-13 8.049e-13 -12.095 -12.094 0.001 - O[18O] 3.206e-15 3.212e-15 -14.494 -14.493 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.541 -128.540 0.001 -[13C](4) 6.509e-05 - H[13C]O3- 5.249e-05 4.803e-05 -4.280 -4.318 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.584e-08 4.591e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.119e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.609 -139.608 0.001 -[14C](4) 5.600e-16 - H[14C]O3- 4.523e-16 4.139e-16 -15.345 -15.383 -0.039 - [14C]O2 9.417e-17 9.432e-17 -16.026 -16.025 0.001 - CaH[14C]O3+ 9.555e-18 8.766e-18 -17.020 -17.057 -0.037 - H[14C]O2[18O]- 9.025e-19 8.258e-19 -18.045 -18.083 -0.039 - H[14C]O[18O]O- 9.025e-19 8.258e-19 -18.045 -18.083 -0.039 - H[14C][18O]O2- 9.025e-19 8.258e-19 -18.045 -18.083 -0.039 - Ca[14C]O3 5.237e-19 5.246e-19 -18.281 -18.280 0.001 - [14C]O[18O] 3.916e-19 3.922e-19 -18.407 -18.406 0.001 - [14C]O3-2 2.684e-19 1.881e-19 -18.571 -18.726 -0.154 - CaH[14C]O2[18O]+ 1.906e-20 1.749e-20 -19.720 -19.757 -0.037 - CaH[14C]O[18O]O+ 1.906e-20 1.749e-20 -19.720 -19.757 -0.037 - CaH[14C][18O]O2+ 1.906e-20 1.749e-20 -19.720 -19.757 -0.037 - Ca[14C]O2[18O] 3.135e-21 3.140e-21 -20.504 -20.503 0.001 - H[14C]O[18O]2- 1.801e-21 1.648e-21 -20.745 -20.783 -0.039 - H[14C][18O]2O- 1.801e-21 1.648e-21 -20.745 -20.783 -0.039 - H[14C][18O]O[18O]- 1.801e-21 1.648e-21 -20.745 -20.783 -0.039 - [14C]O2[18O]-2 1.607e-21 1.126e-21 -20.794 -20.948 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.213e-15 - O[18O] 3.206e-15 3.212e-15 -14.494 -14.493 0.001 - [18O]2 3.199e-18 3.204e-18 -17.495 -17.494 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.585 -126.584 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.144 -40.144 0.001 (0) +O(0) 1.613e-12 + O2 8.035e-13 8.049e-13 -12.095 -12.094 0.001 (0) + O[18O] 3.206e-15 3.212e-15 -14.494 -14.493 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.541 -128.540 0.001 (0) +[13C](4) 6.509e-05 + H[13C]O3- 5.249e-05 4.803e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.584e-08 4.591e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.119e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.719 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.609 -139.608 0.001 (0) +[14C](4) 5.600e-16 + H[14C]O3- 4.523e-16 4.139e-16 -15.345 -15.383 -0.039 (0) + [14C]O2 9.417e-17 9.432e-17 -16.026 -16.025 0.001 (0) + CaH[14C]O3+ 9.555e-18 8.766e-18 -17.020 -17.057 -0.037 (0) + H[14C]O2[18O]- 9.025e-19 8.258e-19 -18.045 -18.083 -0.039 (0) + H[14C]O[18O]O- 9.025e-19 8.258e-19 -18.045 -18.083 -0.039 (0) + H[14C][18O]O2- 9.025e-19 8.258e-19 -18.045 -18.083 -0.039 (0) + Ca[14C]O3 5.237e-19 5.246e-19 -18.281 -18.280 0.001 (0) + [14C]O[18O] 3.916e-19 3.922e-19 -18.407 -18.406 0.001 (0) + [14C]O3-2 2.684e-19 1.881e-19 -18.571 -18.726 -0.154 (0) + CaH[14C]O2[18O]+ 1.906e-20 1.749e-20 -19.720 -19.757 -0.037 (0) + CaH[14C]O[18O]O+ 1.906e-20 1.749e-20 -19.720 -19.757 -0.037 (0) + CaH[14C][18O]O2+ 1.906e-20 1.749e-20 -19.720 -19.757 -0.037 (0) + Ca[14C]O2[18O] 3.135e-21 3.140e-21 -20.504 -20.503 0.001 (0) + H[14C]O[18O]2- 1.801e-21 1.648e-21 -20.745 -20.783 -0.039 (0) + H[14C][18O]2O- 1.801e-21 1.648e-21 -20.745 -20.783 -0.039 (0) + H[14C][18O]O[18O]- 1.801e-21 1.648e-21 -20.745 -20.783 -0.039 (0) + [14C]O2[18O]-2 1.607e-21 1.126e-21 -20.794 -20.948 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.213e-15 + O[18O] 3.206e-15 3.212e-15 -14.494 -14.493 0.001 (0) + [18O]2 3.199e-18 3.204e-18 -17.495 -17.494 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -47682,99 +47682,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.576 -126.576 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.142 -40.142 0.001 -O(0) 1.598e-12 - O2 7.959e-13 7.972e-13 -12.099 -12.098 0.001 - O[18O] 3.176e-15 3.181e-15 -14.498 -14.497 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.532 -128.532 0.001 -[13C](4) 6.509e-05 - H[13C]O3- 5.249e-05 4.803e-05 -4.280 -4.318 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.584e-08 4.591e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.606 -139.605 0.001 -[14C](4) 5.535e-16 - H[14C]O3- 4.471e-16 4.091e-16 -15.350 -15.388 -0.039 - [14C]O2 9.307e-17 9.322e-17 -16.031 -16.030 0.001 - CaH[14C]O3+ 9.444e-18 8.664e-18 -17.025 -17.062 -0.037 - H[14C]O2[18O]- 8.920e-19 8.162e-19 -18.050 -18.088 -0.039 - H[14C]O[18O]O- 8.920e-19 8.162e-19 -18.050 -18.088 -0.039 - H[14C][18O]O2- 8.920e-19 8.162e-19 -18.050 -18.088 -0.039 - Ca[14C]O3 5.176e-19 5.185e-19 -18.286 -18.285 0.001 - [14C]O[18O] 3.870e-19 3.876e-19 -18.412 -18.412 0.001 - [14C]O3-2 2.653e-19 1.859e-19 -18.576 -18.731 -0.154 - CaH[14C]O2[18O]+ 1.884e-20 1.729e-20 -19.725 -19.762 -0.037 - CaH[14C]O[18O]O+ 1.884e-20 1.729e-20 -19.725 -19.762 -0.037 - CaH[14C][18O]O2+ 1.884e-20 1.729e-20 -19.725 -19.762 -0.037 - Ca[14C]O2[18O] 3.098e-21 3.103e-21 -20.509 -20.508 0.001 - H[14C]O[18O]2- 1.780e-21 1.628e-21 -20.750 -20.788 -0.039 - H[14C][18O]2O- 1.780e-21 1.628e-21 -20.750 -20.788 -0.039 - H[14C][18O]O[18O]- 1.780e-21 1.628e-21 -20.750 -20.788 -0.039 - [14C]O2[18O]-2 1.588e-21 1.113e-21 -20.799 -20.953 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.182e-15 - O[18O] 3.176e-15 3.181e-15 -14.498 -14.497 0.001 - [18O]2 3.168e-18 3.174e-18 -17.499 -17.498 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.576 -126.576 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.142 -40.142 0.001 (0) +O(0) 1.598e-12 + O2 7.959e-13 7.972e-13 -12.099 -12.098 0.001 (0) + O[18O] 3.176e-15 3.181e-15 -14.498 -14.497 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.532 -128.532 0.001 (0) +[13C](4) 6.509e-05 + H[13C]O3- 5.249e-05 4.803e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.086e-08 6.096e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.584e-08 4.591e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.212e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.606 -139.605 0.001 (0) +[14C](4) 5.535e-16 + H[14C]O3- 4.471e-16 4.091e-16 -15.350 -15.388 -0.039 (0) + [14C]O2 9.307e-17 9.322e-17 -16.031 -16.030 0.001 (0) + CaH[14C]O3+ 9.444e-18 8.664e-18 -17.025 -17.062 -0.037 (0) + H[14C]O2[18O]- 8.920e-19 8.162e-19 -18.050 -18.088 -0.039 (0) + H[14C]O[18O]O- 8.920e-19 8.162e-19 -18.050 -18.088 -0.039 (0) + H[14C][18O]O2- 8.920e-19 8.162e-19 -18.050 -18.088 -0.039 (0) + Ca[14C]O3 5.176e-19 5.185e-19 -18.286 -18.285 0.001 (0) + [14C]O[18O] 3.870e-19 3.876e-19 -18.412 -18.412 0.001 (0) + [14C]O3-2 2.653e-19 1.859e-19 -18.576 -18.731 -0.154 (0) + CaH[14C]O2[18O]+ 1.884e-20 1.729e-20 -19.725 -19.762 -0.037 (0) + CaH[14C]O[18O]O+ 1.884e-20 1.729e-20 -19.725 -19.762 -0.037 (0) + CaH[14C][18O]O2+ 1.884e-20 1.729e-20 -19.725 -19.762 -0.037 (0) + Ca[14C]O2[18O] 3.098e-21 3.103e-21 -20.509 -20.508 0.001 (0) + H[14C]O[18O]2- 1.780e-21 1.628e-21 -20.750 -20.788 -0.039 (0) + H[14C][18O]2O- 1.780e-21 1.628e-21 -20.750 -20.788 -0.039 (0) + H[14C][18O]O[18O]- 1.780e-21 1.628e-21 -20.750 -20.788 -0.039 (0) + [14C]O2[18O]-2 1.588e-21 1.113e-21 -20.799 -20.953 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.182e-15 + O[18O] 3.176e-15 3.181e-15 -14.498 -14.497 0.001 (0) + [18O]2 3.168e-18 3.174e-18 -17.499 -17.498 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -47937,99 +47937,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.569 -126.568 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.141 -40.140 0.001 -O(0) 1.585e-12 - O2 7.892e-13 7.905e-13 -12.103 -12.102 0.001 - O[18O] 3.149e-15 3.154e-15 -14.502 -14.501 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.525 -128.524 0.001 -[13C](4) 6.509e-05 - H[13C]O3- 5.250e-05 4.803e-05 -4.280 -4.318 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.584e-08 4.591e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.603 -139.603 0.001 -[14C](4) 5.471e-16 - H[14C]O3- 4.419e-16 4.043e-16 -15.355 -15.393 -0.039 - [14C]O2 9.200e-17 9.215e-17 -16.036 -16.036 0.001 - CaH[14C]O3+ 9.335e-18 8.564e-18 -17.030 -17.067 -0.037 - H[14C]O2[18O]- 8.817e-19 8.068e-19 -18.055 -18.093 -0.039 - H[14C]O[18O]O- 8.817e-19 8.068e-19 -18.055 -18.093 -0.039 - H[14C][18O]O2- 8.817e-19 8.068e-19 -18.055 -18.093 -0.039 - Ca[14C]O3 5.116e-19 5.125e-19 -18.291 -18.290 0.001 - [14C]O[18O] 3.825e-19 3.832e-19 -18.417 -18.417 0.001 - [14C]O3-2 2.622e-19 1.838e-19 -18.581 -18.736 -0.154 - CaH[14C]O2[18O]+ 1.863e-20 1.709e-20 -19.730 -19.767 -0.037 - CaH[14C]O[18O]O+ 1.863e-20 1.709e-20 -19.730 -19.767 -0.037 - CaH[14C][18O]O2+ 1.863e-20 1.709e-20 -19.730 -19.767 -0.037 - Ca[14C]O2[18O] 3.063e-21 3.068e-21 -20.514 -20.513 0.001 - H[14C]O[18O]2- 1.759e-21 1.610e-21 -20.755 -20.793 -0.039 - H[14C][18O]2O- 1.759e-21 1.610e-21 -20.755 -20.793 -0.039 - H[14C][18O]O[18O]- 1.759e-21 1.610e-21 -20.755 -20.793 -0.039 - [14C]O2[18O]-2 1.570e-21 1.100e-21 -20.804 -20.959 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.155e-15 - O[18O] 3.149e-15 3.154e-15 -14.502 -14.501 0.001 - [18O]2 3.142e-18 3.147e-18 -17.503 -17.502 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.569 -126.568 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.141 -40.140 0.001 (0) +O(0) 1.585e-12 + O2 7.892e-13 7.905e-13 -12.103 -12.102 0.001 (0) + O[18O] 3.149e-15 3.154e-15 -14.502 -14.501 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.525 -128.524 0.001 (0) +[13C](4) 6.509e-05 + H[13C]O3- 5.250e-05 4.803e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.583e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.584e-08 4.591e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.603 -139.603 0.001 (0) +[14C](4) 5.471e-16 + H[14C]O3- 4.419e-16 4.043e-16 -15.355 -15.393 -0.039 (0) + [14C]O2 9.200e-17 9.215e-17 -16.036 -16.036 0.001 (0) + CaH[14C]O3+ 9.335e-18 8.564e-18 -17.030 -17.067 -0.037 (0) + H[14C]O2[18O]- 8.817e-19 8.068e-19 -18.055 -18.093 -0.039 (0) + H[14C]O[18O]O- 8.817e-19 8.068e-19 -18.055 -18.093 -0.039 (0) + H[14C][18O]O2- 8.817e-19 8.068e-19 -18.055 -18.093 -0.039 (0) + Ca[14C]O3 5.116e-19 5.125e-19 -18.291 -18.290 0.001 (0) + [14C]O[18O] 3.825e-19 3.832e-19 -18.417 -18.417 0.001 (0) + [14C]O3-2 2.622e-19 1.838e-19 -18.581 -18.736 -0.154 (0) + CaH[14C]O2[18O]+ 1.863e-20 1.709e-20 -19.730 -19.767 -0.037 (0) + CaH[14C]O[18O]O+ 1.863e-20 1.709e-20 -19.730 -19.767 -0.037 (0) + CaH[14C][18O]O2+ 1.863e-20 1.709e-20 -19.730 -19.767 -0.037 (0) + Ca[14C]O2[18O] 3.063e-21 3.068e-21 -20.514 -20.513 0.001 (0) + H[14C]O[18O]2- 1.759e-21 1.610e-21 -20.755 -20.793 -0.039 (0) + H[14C][18O]2O- 1.759e-21 1.610e-21 -20.755 -20.793 -0.039 (0) + H[14C][18O]O[18O]- 1.759e-21 1.610e-21 -20.755 -20.793 -0.039 (0) + [14C]O2[18O]-2 1.570e-21 1.100e-21 -20.804 -20.959 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.155e-15 + O[18O] 3.149e-15 3.154e-15 -14.502 -14.501 0.001 (0) + [18O]2 3.142e-18 3.147e-18 -17.503 -17.502 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -48192,99 +48192,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.565 -126.565 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.140 -40.139 0.001 -O(0) 1.578e-12 - O2 7.859e-13 7.872e-13 -12.105 -12.104 0.001 - O[18O] 3.136e-15 3.141e-15 -14.504 -14.503 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.521 -128.521 0.001 -[13C](4) 6.509e-05 - H[13C]O3- 5.250e-05 4.803e-05 -4.280 -4.318 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.584e-08 4.591e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.605 -139.604 0.001 -[14C](4) 5.409e-16 - H[14C]O3- 4.369e-16 3.997e-16 -15.360 -15.398 -0.039 - [14C]O2 9.095e-17 9.110e-17 -16.041 -16.040 0.001 - CaH[14C]O3+ 9.229e-18 8.467e-18 -17.035 -17.072 -0.037 - H[14C]O2[18O]- 8.717e-19 7.976e-19 -18.060 -18.098 -0.039 - H[14C]O[18O]O- 8.717e-19 7.976e-19 -18.060 -18.098 -0.039 - H[14C][18O]O2- 8.717e-19 7.976e-19 -18.060 -18.098 -0.039 - Ca[14C]O3 5.058e-19 5.067e-19 -18.296 -18.295 0.001 - [14C]O[18O] 3.782e-19 3.788e-19 -18.422 -18.422 0.001 - [14C]O3-2 2.593e-19 1.817e-19 -18.586 -18.741 -0.154 - CaH[14C]O2[18O]+ 1.841e-20 1.689e-20 -19.735 -19.772 -0.037 - CaH[14C]O[18O]O+ 1.841e-20 1.689e-20 -19.735 -19.772 -0.037 - CaH[14C][18O]O2+ 1.841e-20 1.689e-20 -19.735 -19.772 -0.037 - Ca[14C]O2[18O] 3.028e-21 3.033e-21 -20.519 -20.518 0.001 - H[14C]O[18O]2- 1.739e-21 1.591e-21 -20.760 -20.798 -0.039 - H[14C][18O]2O- 1.739e-21 1.591e-21 -20.760 -20.798 -0.039 - H[14C][18O]O[18O]- 1.739e-21 1.591e-21 -20.760 -20.798 -0.039 - [14C]O2[18O]-2 1.552e-21 1.088e-21 -20.809 -20.964 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.142e-15 - O[18O] 3.136e-15 3.141e-15 -14.504 -14.503 0.001 - [18O]2 3.129e-18 3.134e-18 -17.505 -17.504 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.565 -126.565 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.140 -40.139 0.001 (0) +O(0) 1.578e-12 + O2 7.859e-13 7.872e-13 -12.105 -12.104 0.001 (0) + O[18O] 3.136e-15 3.141e-15 -14.504 -14.503 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.521 -128.521 0.001 (0) +[13C](4) 6.509e-05 + H[13C]O3- 5.250e-05 4.803e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.584e-08 4.591e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.605 -139.604 0.001 (0) +[14C](4) 5.409e-16 + H[14C]O3- 4.369e-16 3.997e-16 -15.360 -15.398 -0.039 (0) + [14C]O2 9.095e-17 9.110e-17 -16.041 -16.040 0.001 (0) + CaH[14C]O3+ 9.229e-18 8.467e-18 -17.035 -17.072 -0.037 (0) + H[14C]O2[18O]- 8.717e-19 7.976e-19 -18.060 -18.098 -0.039 (0) + H[14C]O[18O]O- 8.717e-19 7.976e-19 -18.060 -18.098 -0.039 (0) + H[14C][18O]O2- 8.717e-19 7.976e-19 -18.060 -18.098 -0.039 (0) + Ca[14C]O3 5.058e-19 5.067e-19 -18.296 -18.295 0.001 (0) + [14C]O[18O] 3.782e-19 3.788e-19 -18.422 -18.422 0.001 (0) + [14C]O3-2 2.593e-19 1.817e-19 -18.586 -18.741 -0.154 (0) + CaH[14C]O2[18O]+ 1.841e-20 1.689e-20 -19.735 -19.772 -0.037 (0) + CaH[14C]O[18O]O+ 1.841e-20 1.689e-20 -19.735 -19.772 -0.037 (0) + CaH[14C][18O]O2+ 1.841e-20 1.689e-20 -19.735 -19.772 -0.037 (0) + Ca[14C]O2[18O] 3.028e-21 3.033e-21 -20.519 -20.518 0.001 (0) + H[14C]O[18O]2- 1.739e-21 1.591e-21 -20.760 -20.798 -0.039 (0) + H[14C][18O]2O- 1.739e-21 1.591e-21 -20.760 -20.798 -0.039 (0) + H[14C][18O]O[18O]- 1.739e-21 1.591e-21 -20.760 -20.798 -0.039 (0) + [14C]O2[18O]-2 1.552e-21 1.088e-21 -20.809 -20.964 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.142e-15 + O[18O] 3.136e-15 3.141e-15 -14.504 -14.503 0.001 (0) + [18O]2 3.129e-18 3.134e-18 -17.505 -17.504 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -48447,99 +48447,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.557 -126.556 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.138 -40.137 0.001 -O(0) 1.563e-12 - O2 7.784e-13 7.797e-13 -12.109 -12.108 0.001 - O[18O] 3.106e-15 3.111e-15 -14.508 -14.507 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.513 -128.512 0.001 -[13C](4) 6.509e-05 - H[13C]O3- 5.250e-05 4.803e-05 -4.280 -4.318 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 - H[13C]O2[18O]- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.584e-08 4.592e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.601 -139.601 0.001 -[14C](4) 5.348e-16 - H[14C]O3- 4.320e-16 3.952e-16 -15.365 -15.403 -0.039 - [14C]O2 8.992e-17 9.007e-17 -16.046 -16.045 0.001 - CaH[14C]O3+ 9.125e-18 8.372e-18 -17.040 -17.077 -0.037 - H[14C]O2[18O]- 8.619e-19 7.886e-19 -18.065 -18.103 -0.039 - H[14C]O[18O]O- 8.619e-19 7.886e-19 -18.065 -18.103 -0.039 - H[14C][18O]O2- 8.619e-19 7.886e-19 -18.065 -18.103 -0.039 - Ca[14C]O3 5.001e-19 5.009e-19 -18.301 -18.300 0.001 - [14C]O[18O] 3.739e-19 3.745e-19 -18.427 -18.426 0.001 - [14C]O3-2 2.563e-19 1.797e-19 -18.591 -18.746 -0.154 - CaH[14C]O2[18O]+ 1.821e-20 1.670e-20 -19.740 -19.777 -0.037 - CaH[14C]O[18O]O+ 1.821e-20 1.670e-20 -19.740 -19.777 -0.037 - CaH[14C][18O]O2+ 1.821e-20 1.670e-20 -19.740 -19.777 -0.037 - Ca[14C]O2[18O] 2.994e-21 2.998e-21 -20.524 -20.523 0.001 - H[14C]O[18O]2- 1.720e-21 1.573e-21 -20.765 -20.803 -0.039 - H[14C][18O]2O- 1.720e-21 1.573e-21 -20.765 -20.803 -0.039 - H[14C][18O]O[18O]- 1.720e-21 1.573e-21 -20.765 -20.803 -0.039 - [14C]O2[18O]-2 1.534e-21 1.075e-21 -20.814 -20.968 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.112e-15 - O[18O] 3.106e-15 3.111e-15 -14.508 -14.507 0.001 - [18O]2 3.099e-18 3.104e-18 -17.509 -17.508 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.557 -126.556 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.138 -40.137 0.001 (0) +O(0) 1.563e-12 + O2 7.784e-13 7.797e-13 -12.109 -12.108 0.001 (0) + O[18O] 3.106e-15 3.111e-15 -14.508 -14.507 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.513 -128.512 0.001 (0) +[13C](4) 6.509e-05 + H[13C]O3- 5.250e-05 4.803e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.993 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.584e-08 4.592e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.439 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.601 -139.601 0.001 (0) +[14C](4) 5.348e-16 + H[14C]O3- 4.320e-16 3.952e-16 -15.365 -15.403 -0.039 (0) + [14C]O2 8.992e-17 9.007e-17 -16.046 -16.045 0.001 (0) + CaH[14C]O3+ 9.125e-18 8.372e-18 -17.040 -17.077 -0.037 (0) + H[14C]O2[18O]- 8.619e-19 7.886e-19 -18.065 -18.103 -0.039 (0) + H[14C]O[18O]O- 8.619e-19 7.886e-19 -18.065 -18.103 -0.039 (0) + H[14C][18O]O2- 8.619e-19 7.886e-19 -18.065 -18.103 -0.039 (0) + Ca[14C]O3 5.001e-19 5.009e-19 -18.301 -18.300 0.001 (0) + [14C]O[18O] 3.739e-19 3.745e-19 -18.427 -18.426 0.001 (0) + [14C]O3-2 2.563e-19 1.797e-19 -18.591 -18.746 -0.154 (0) + CaH[14C]O2[18O]+ 1.821e-20 1.670e-20 -19.740 -19.777 -0.037 (0) + CaH[14C]O[18O]O+ 1.821e-20 1.670e-20 -19.740 -19.777 -0.037 (0) + CaH[14C][18O]O2+ 1.821e-20 1.670e-20 -19.740 -19.777 -0.037 (0) + Ca[14C]O2[18O] 2.994e-21 2.998e-21 -20.524 -20.523 0.001 (0) + H[14C]O[18O]2- 1.720e-21 1.573e-21 -20.765 -20.803 -0.039 (0) + H[14C][18O]2O- 1.720e-21 1.573e-21 -20.765 -20.803 -0.039 (0) + H[14C][18O]O[18O]- 1.720e-21 1.573e-21 -20.765 -20.803 -0.039 (0) + [14C]O2[18O]-2 1.534e-21 1.075e-21 -20.814 -20.968 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.112e-15 + O[18O] 3.106e-15 3.111e-15 -14.508 -14.507 0.001 (0) + [18O]2 3.099e-18 3.104e-18 -17.509 -17.508 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -48702,99 +48702,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.551 -126.550 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.136 -40.135 0.001 -O(0) 1.552e-12 - O2 7.729e-13 7.742e-13 -12.112 -12.111 0.001 - O[18O] 3.084e-15 3.089e-15 -14.511 -14.510 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.507 -128.506 0.001 -[13C](4) 6.509e-05 - H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.584e-08 4.592e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.600 -139.599 0.001 -[14C](4) 5.288e-16 - H[14C]O3- 4.272e-16 3.908e-16 -15.369 -15.408 -0.039 - [14C]O2 8.892e-17 8.907e-17 -16.051 -16.050 0.001 - CaH[14C]O3+ 9.023e-18 8.278e-18 -17.045 -17.082 -0.037 - H[14C]O2[18O]- 8.523e-19 7.798e-19 -18.069 -18.108 -0.039 - H[14C]O[18O]O- 8.523e-19 7.798e-19 -18.069 -18.108 -0.039 - H[14C][18O]O2- 8.523e-19 7.798e-19 -18.069 -18.108 -0.039 - Ca[14C]O3 4.946e-19 4.954e-19 -18.306 -18.305 0.001 - [14C]O[18O] 3.698e-19 3.704e-19 -18.432 -18.431 0.001 - [14C]O3-2 2.535e-19 1.777e-19 -18.596 -18.750 -0.154 - CaH[14C]O2[18O]+ 1.800e-20 1.652e-20 -19.745 -19.782 -0.037 - CaH[14C]O[18O]O+ 1.800e-20 1.652e-20 -19.745 -19.782 -0.037 - CaH[14C][18O]O2+ 1.800e-20 1.652e-20 -19.745 -19.782 -0.037 - Ca[14C]O2[18O] 2.960e-21 2.965e-21 -20.529 -20.528 0.001 - H[14C]O[18O]2- 1.700e-21 1.556e-21 -20.769 -20.808 -0.039 - H[14C][18O]2O- 1.700e-21 1.556e-21 -20.769 -20.808 -0.039 - H[14C][18O]O[18O]- 1.700e-21 1.556e-21 -20.769 -20.808 -0.039 - [14C]O2[18O]-2 1.517e-21 1.063e-21 -20.819 -20.973 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.090e-15 - O[18O] 3.084e-15 3.089e-15 -14.511 -14.510 0.001 - [18O]2 3.077e-18 3.082e-18 -17.512 -17.511 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.551 -126.550 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.136 -40.135 0.001 (0) +O(0) 1.552e-12 + O2 7.729e-13 7.742e-13 -12.112 -12.111 0.001 (0) + O[18O] 3.084e-15 3.089e-15 -14.511 -14.510 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.507 -128.506 0.001 (0) +[13C](4) 6.509e-05 + H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.584e-08 4.592e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.600 -139.599 0.001 (0) +[14C](4) 5.288e-16 + H[14C]O3- 4.272e-16 3.908e-16 -15.369 -15.408 -0.039 (0) + [14C]O2 8.892e-17 8.907e-17 -16.051 -16.050 0.001 (0) + CaH[14C]O3+ 9.023e-18 8.278e-18 -17.045 -17.082 -0.037 (0) + H[14C]O2[18O]- 8.523e-19 7.798e-19 -18.069 -18.108 -0.039 (0) + H[14C]O[18O]O- 8.523e-19 7.798e-19 -18.069 -18.108 -0.039 (0) + H[14C][18O]O2- 8.523e-19 7.798e-19 -18.069 -18.108 -0.039 (0) + Ca[14C]O3 4.946e-19 4.954e-19 -18.306 -18.305 0.001 (0) + [14C]O[18O] 3.698e-19 3.704e-19 -18.432 -18.431 0.001 (0) + [14C]O3-2 2.535e-19 1.777e-19 -18.596 -18.750 -0.154 (0) + CaH[14C]O2[18O]+ 1.800e-20 1.652e-20 -19.745 -19.782 -0.037 (0) + CaH[14C]O[18O]O+ 1.800e-20 1.652e-20 -19.745 -19.782 -0.037 (0) + CaH[14C][18O]O2+ 1.800e-20 1.652e-20 -19.745 -19.782 -0.037 (0) + Ca[14C]O2[18O] 2.960e-21 2.965e-21 -20.529 -20.528 0.001 (0) + H[14C]O[18O]2- 1.700e-21 1.556e-21 -20.769 -20.808 -0.039 (0) + H[14C][18O]2O- 1.700e-21 1.556e-21 -20.769 -20.808 -0.039 (0) + H[14C][18O]O[18O]- 1.700e-21 1.556e-21 -20.769 -20.808 -0.039 (0) + [14C]O2[18O]-2 1.517e-21 1.063e-21 -20.819 -20.973 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.090e-15 + O[18O] 3.084e-15 3.089e-15 -14.511 -14.510 0.001 (0) + [18O]2 3.077e-18 3.082e-18 -17.512 -17.511 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -48957,99 +48957,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.550 -126.549 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.136 -40.135 0.001 -O(0) 1.551e-12 - O2 7.722e-13 7.735e-13 -12.112 -12.112 0.001 - O[18O] 3.082e-15 3.087e-15 -14.511 -14.511 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.506 -128.505 0.001 -[13C](4) 6.509e-05 - H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.584e-08 4.592e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 - Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.604 -139.603 0.001 -[14C](4) 5.230e-16 - H[14C]O3- 4.224e-16 3.865e-16 -15.374 -15.413 -0.039 - [14C]O2 8.794e-17 8.809e-17 -16.056 -16.055 0.001 - CaH[14C]O3+ 8.924e-18 8.187e-18 -17.049 -17.087 -0.037 - H[14C]O2[18O]- 8.429e-19 7.712e-19 -18.074 -18.113 -0.039 - H[14C]O[18O]O- 8.429e-19 7.712e-19 -18.074 -18.113 -0.039 - H[14C][18O]O2- 8.429e-19 7.712e-19 -18.074 -18.113 -0.039 - Ca[14C]O3 4.891e-19 4.899e-19 -18.311 -18.310 0.001 - [14C]O[18O] 3.657e-19 3.663e-19 -18.437 -18.436 0.001 - [14C]O3-2 2.507e-19 1.757e-19 -18.601 -18.755 -0.154 - CaH[14C]O2[18O]+ 1.780e-20 1.634e-20 -19.749 -19.787 -0.037 - CaH[14C]O[18O]O+ 1.780e-20 1.634e-20 -19.749 -19.787 -0.037 - CaH[14C][18O]O2+ 1.780e-20 1.634e-20 -19.749 -19.787 -0.037 - Ca[14C]O2[18O] 2.928e-21 2.932e-21 -20.533 -20.533 0.001 - H[14C]O[18O]2- 1.682e-21 1.539e-21 -20.774 -20.813 -0.039 - H[14C][18O]2O- 1.682e-21 1.539e-21 -20.774 -20.813 -0.039 - H[14C][18O]O[18O]- 1.682e-21 1.539e-21 -20.774 -20.813 -0.039 - [14C]O2[18O]-2 1.501e-21 1.052e-21 -20.824 -20.978 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.088e-15 - O[18O] 3.082e-15 3.087e-15 -14.511 -14.511 0.001 - [18O]2 3.074e-18 3.079e-18 -17.512 -17.512 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.550 -126.549 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.136 -40.135 0.001 (0) +O(0) 1.551e-12 + O2 7.722e-13 7.735e-13 -12.112 -12.112 0.001 (0) + O[18O] 3.082e-15 3.087e-15 -14.511 -14.511 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.506 -128.505 0.001 (0) +[13C](4) 6.509e-05 + H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.584e-08 4.592e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.693 -0.037 (0) + Ca[13C]O2[18O] 3.643e-10 3.649e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.604 -139.603 0.001 (0) +[14C](4) 5.230e-16 + H[14C]O3- 4.224e-16 3.865e-16 -15.374 -15.413 -0.039 (0) + [14C]O2 8.794e-17 8.809e-17 -16.056 -16.055 0.001 (0) + CaH[14C]O3+ 8.924e-18 8.187e-18 -17.049 -17.087 -0.037 (0) + H[14C]O2[18O]- 8.429e-19 7.712e-19 -18.074 -18.113 -0.039 (0) + H[14C]O[18O]O- 8.429e-19 7.712e-19 -18.074 -18.113 -0.039 (0) + H[14C][18O]O2- 8.429e-19 7.712e-19 -18.074 -18.113 -0.039 (0) + Ca[14C]O3 4.891e-19 4.899e-19 -18.311 -18.310 0.001 (0) + [14C]O[18O] 3.657e-19 3.663e-19 -18.437 -18.436 0.001 (0) + [14C]O3-2 2.507e-19 1.757e-19 -18.601 -18.755 -0.154 (0) + CaH[14C]O2[18O]+ 1.780e-20 1.634e-20 -19.749 -19.787 -0.037 (0) + CaH[14C]O[18O]O+ 1.780e-20 1.634e-20 -19.749 -19.787 -0.037 (0) + CaH[14C][18O]O2+ 1.780e-20 1.634e-20 -19.749 -19.787 -0.037 (0) + Ca[14C]O2[18O] 2.928e-21 2.932e-21 -20.533 -20.533 0.001 (0) + H[14C]O[18O]2- 1.682e-21 1.539e-21 -20.774 -20.813 -0.039 (0) + H[14C][18O]2O- 1.682e-21 1.539e-21 -20.774 -20.813 -0.039 (0) + H[14C][18O]O[18O]- 1.682e-21 1.539e-21 -20.774 -20.813 -0.039 (0) + [14C]O2[18O]-2 1.501e-21 1.052e-21 -20.824 -20.978 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.088e-15 + O[18O] 3.082e-15 3.087e-15 -14.511 -14.511 0.001 (0) + [18O]2 3.074e-18 3.079e-18 -17.512 -17.512 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -49212,99 +49212,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.570 -126.569 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.141 -40.140 0.001 -O(0) 1.586e-12 - O2 7.900e-13 7.913e-13 -12.102 -12.102 0.001 - O[18O] 3.153e-15 3.158e-15 -14.501 -14.501 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.526 -128.525 0.001 -[13C](4) 6.509e-05 - H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.584e-08 4.592e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.629 -139.628 0.001 -[14C](4) 5.173e-16 - H[14C]O3- 4.178e-16 3.823e-16 -15.379 -15.418 -0.039 - [14C]O2 8.699e-17 8.713e-17 -16.061 -16.060 0.001 - CaH[14C]O3+ 8.827e-18 8.098e-18 -17.054 -17.092 -0.037 - H[14C]O2[18O]- 8.337e-19 7.628e-19 -18.079 -18.118 -0.039 - H[14C]O[18O]O- 8.337e-19 7.628e-19 -18.079 -18.118 -0.039 - H[14C][18O]O2- 8.337e-19 7.628e-19 -18.079 -18.118 -0.039 - Ca[14C]O3 4.838e-19 4.846e-19 -18.315 -18.315 0.001 - [14C]O[18O] 3.617e-19 3.623e-19 -18.442 -18.441 0.001 - [14C]O3-2 2.480e-19 1.738e-19 -18.606 -18.760 -0.154 - CaH[14C]O2[18O]+ 1.761e-20 1.616e-20 -19.754 -19.792 -0.037 - CaH[14C]O[18O]O+ 1.761e-20 1.616e-20 -19.754 -19.792 -0.037 - CaH[14C][18O]O2+ 1.761e-20 1.616e-20 -19.754 -19.792 -0.037 - Ca[14C]O2[18O] 2.896e-21 2.900e-21 -20.538 -20.538 0.001 - H[14C]O[18O]2- 1.663e-21 1.522e-21 -20.779 -20.818 -0.039 - H[14C][18O]2O- 1.663e-21 1.522e-21 -20.779 -20.818 -0.039 - H[14C][18O]O[18O]- 1.663e-21 1.522e-21 -20.779 -20.818 -0.039 - [14C]O2[18O]-2 1.484e-21 1.040e-21 -20.829 -20.983 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.159e-15 - O[18O] 3.153e-15 3.158e-15 -14.501 -14.501 0.001 - [18O]2 3.145e-18 3.150e-18 -17.502 -17.502 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.570 -126.569 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.141 -40.140 0.001 (0) +O(0) 1.586e-12 + O2 7.900e-13 7.913e-13 -12.102 -12.102 0.001 (0) + O[18O] 3.153e-15 3.158e-15 -14.501 -14.501 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.526 -128.525 0.001 (0) +[13C](4) 6.509e-05 + H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.047e-07 9.584e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.584e-08 4.592e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.629 -139.628 0.001 (0) +[14C](4) 5.173e-16 + H[14C]O3- 4.178e-16 3.823e-16 -15.379 -15.418 -0.039 (0) + [14C]O2 8.699e-17 8.713e-17 -16.061 -16.060 0.001 (0) + CaH[14C]O3+ 8.827e-18 8.098e-18 -17.054 -17.092 -0.037 (0) + H[14C]O2[18O]- 8.337e-19 7.628e-19 -18.079 -18.118 -0.039 (0) + H[14C]O[18O]O- 8.337e-19 7.628e-19 -18.079 -18.118 -0.039 (0) + H[14C][18O]O2- 8.337e-19 7.628e-19 -18.079 -18.118 -0.039 (0) + Ca[14C]O3 4.838e-19 4.846e-19 -18.315 -18.315 0.001 (0) + [14C]O[18O] 3.617e-19 3.623e-19 -18.442 -18.441 0.001 (0) + [14C]O3-2 2.480e-19 1.738e-19 -18.606 -18.760 -0.154 (0) + CaH[14C]O2[18O]+ 1.761e-20 1.616e-20 -19.754 -19.792 -0.037 (0) + CaH[14C]O[18O]O+ 1.761e-20 1.616e-20 -19.754 -19.792 -0.037 (0) + CaH[14C][18O]O2+ 1.761e-20 1.616e-20 -19.754 -19.792 -0.037 (0) + Ca[14C]O2[18O] 2.896e-21 2.900e-21 -20.538 -20.538 0.001 (0) + H[14C]O[18O]2- 1.663e-21 1.522e-21 -20.779 -20.818 -0.039 (0) + H[14C][18O]2O- 1.663e-21 1.522e-21 -20.779 -20.818 -0.039 (0) + H[14C][18O]O[18O]- 1.663e-21 1.522e-21 -20.779 -20.818 -0.039 (0) + [14C]O2[18O]-2 1.484e-21 1.040e-21 -20.829 -20.983 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.159e-15 + O[18O] 3.153e-15 3.158e-15 -14.501 -14.501 0.001 (0) + [18O]2 3.145e-18 3.150e-18 -17.502 -17.502 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -49467,99 +49467,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.570 -126.569 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.141 -40.140 0.001 -O(0) 1.587e-12 - O2 7.903e-13 7.916e-13 -12.102 -12.102 0.001 - O[18O] 3.153e-15 3.159e-15 -14.501 -14.500 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.526 -128.525 0.001 -[13C](4) 6.509e-05 - H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.584e-08 4.592e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.634 -139.633 0.001 -[14C](4) 5.117e-16 - H[14C]O3- 4.133e-16 3.782e-16 -15.384 -15.422 -0.039 - [14C]O2 8.605e-17 8.619e-17 -16.065 -16.065 0.001 - CaH[14C]O3+ 8.732e-18 8.011e-18 -17.059 -17.096 -0.037 - H[14C]O2[18O]- 8.247e-19 7.546e-19 -18.084 -18.122 -0.039 - H[14C]O[18O]O- 8.247e-19 7.546e-19 -18.084 -18.122 -0.039 - H[14C][18O]O2- 8.247e-19 7.546e-19 -18.084 -18.122 -0.039 - Ca[14C]O3 4.786e-19 4.794e-19 -18.320 -18.319 0.001 - [14C]O[18O] 3.578e-19 3.584e-19 -18.446 -18.446 0.001 - [14C]O3-2 2.453e-19 1.719e-19 -18.610 -18.765 -0.154 - CaH[14C]O2[18O]+ 1.742e-20 1.598e-20 -19.759 -19.796 -0.037 - CaH[14C]O[18O]O+ 1.742e-20 1.598e-20 -19.759 -19.796 -0.037 - CaH[14C][18O]O2+ 1.742e-20 1.598e-20 -19.759 -19.796 -0.037 - Ca[14C]O2[18O] 2.865e-21 2.869e-21 -20.543 -20.542 0.001 - H[14C]O[18O]2- 1.645e-21 1.506e-21 -20.784 -20.822 -0.039 - H[14C][18O]2O- 1.645e-21 1.506e-21 -20.784 -20.822 -0.039 - H[14C][18O]O[18O]- 1.645e-21 1.506e-21 -20.784 -20.822 -0.039 - [14C]O2[18O]-2 1.468e-21 1.029e-21 -20.833 -20.988 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.160e-15 - O[18O] 3.153e-15 3.159e-15 -14.501 -14.500 0.001 - [18O]2 3.146e-18 3.151e-18 -17.502 -17.502 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.570 -126.569 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.141 -40.140 0.001 (0) +O(0) 1.587e-12 + O2 7.903e-13 7.916e-13 -12.102 -12.102 0.001 (0) + O[18O] 3.153e-15 3.159e-15 -14.501 -14.500 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.526 -128.525 0.001 (0) +[13C](4) 6.509e-05 + H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.584e-08 4.592e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.867e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.634 -139.633 0.001 (0) +[14C](4) 5.117e-16 + H[14C]O3- 4.133e-16 3.782e-16 -15.384 -15.422 -0.039 (0) + [14C]O2 8.605e-17 8.619e-17 -16.065 -16.065 0.001 (0) + CaH[14C]O3+ 8.732e-18 8.011e-18 -17.059 -17.096 -0.037 (0) + H[14C]O2[18O]- 8.247e-19 7.546e-19 -18.084 -18.122 -0.039 (0) + H[14C]O[18O]O- 8.247e-19 7.546e-19 -18.084 -18.122 -0.039 (0) + H[14C][18O]O2- 8.247e-19 7.546e-19 -18.084 -18.122 -0.039 (0) + Ca[14C]O3 4.786e-19 4.794e-19 -18.320 -18.319 0.001 (0) + [14C]O[18O] 3.578e-19 3.584e-19 -18.446 -18.446 0.001 (0) + [14C]O3-2 2.453e-19 1.719e-19 -18.610 -18.765 -0.154 (0) + CaH[14C]O2[18O]+ 1.742e-20 1.598e-20 -19.759 -19.796 -0.037 (0) + CaH[14C]O[18O]O+ 1.742e-20 1.598e-20 -19.759 -19.796 -0.037 (0) + CaH[14C][18O]O2+ 1.742e-20 1.598e-20 -19.759 -19.796 -0.037 (0) + Ca[14C]O2[18O] 2.865e-21 2.869e-21 -20.543 -20.542 0.001 (0) + H[14C]O[18O]2- 1.645e-21 1.506e-21 -20.784 -20.822 -0.039 (0) + H[14C][18O]2O- 1.645e-21 1.506e-21 -20.784 -20.822 -0.039 (0) + H[14C][18O]O[18O]- 1.645e-21 1.506e-21 -20.784 -20.822 -0.039 (0) + [14C]O2[18O]-2 1.468e-21 1.029e-21 -20.833 -20.988 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.160e-15 + O[18O] 3.153e-15 3.159e-15 -14.501 -14.500 0.001 (0) + [18O]2 3.146e-18 3.151e-18 -17.502 -17.502 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -49722,99 +49722,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.581 -126.581 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.144 -40.143 0.001 -O(0) 1.607e-12 - O2 8.005e-13 8.019e-13 -12.097 -12.096 0.001 - O[18O] 3.194e-15 3.200e-15 -14.496 -14.495 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.537 -128.537 0.001 -[13C](4) 6.510e-05 - H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.584e-08 4.592e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.650 -139.649 0.001 -[14C](4) 5.063e-16 - H[14C]O3- 4.089e-16 3.742e-16 -15.388 -15.427 -0.039 - [14C]O2 8.513e-17 8.527e-17 -16.070 -16.069 0.001 - CaH[14C]O3+ 8.638e-18 7.925e-18 -17.064 -17.101 -0.037 - H[14C]O2[18O]- 8.159e-19 7.466e-19 -18.088 -18.127 -0.039 - H[14C]O[18O]O- 8.159e-19 7.466e-19 -18.088 -18.127 -0.039 - H[14C][18O]O2- 8.159e-19 7.466e-19 -18.088 -18.127 -0.039 - Ca[14C]O3 4.735e-19 4.742e-19 -18.325 -18.324 0.001 - [14C]O[18O] 3.540e-19 3.546e-19 -18.451 -18.450 0.001 - [14C]O3-2 2.427e-19 1.701e-19 -18.615 -18.769 -0.154 - CaH[14C]O2[18O]+ 1.724e-20 1.581e-20 -19.764 -19.801 -0.037 - CaH[14C]O[18O]O+ 1.724e-20 1.581e-20 -19.764 -19.801 -0.037 - CaH[14C][18O]O2+ 1.724e-20 1.581e-20 -19.764 -19.801 -0.037 - Ca[14C]O2[18O] 2.834e-21 2.839e-21 -20.548 -20.547 0.001 - H[14C]O[18O]2- 1.628e-21 1.490e-21 -20.788 -20.827 -0.039 - H[14C][18O]2O- 1.628e-21 1.490e-21 -20.788 -20.827 -0.039 - H[14C][18O]O[18O]- 1.628e-21 1.490e-21 -20.788 -20.827 -0.039 - [14C]O2[18O]-2 1.453e-21 1.018e-21 -20.838 -20.992 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.201e-15 - O[18O] 3.194e-15 3.200e-15 -14.496 -14.495 0.001 - [18O]2 3.187e-18 3.192e-18 -17.497 -17.496 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.581 -126.581 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.144 -40.143 0.001 (0) +O(0) 1.607e-12 + O2 8.005e-13 8.019e-13 -12.097 -12.096 0.001 (0) + O[18O] 3.194e-15 3.200e-15 -14.496 -14.495 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.537 -128.537 0.001 (0) +[13C](4) 6.510e-05 + H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.017e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.584e-08 4.592e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.650 -139.649 0.001 (0) +[14C](4) 5.063e-16 + H[14C]O3- 4.089e-16 3.742e-16 -15.388 -15.427 -0.039 (0) + [14C]O2 8.513e-17 8.527e-17 -16.070 -16.069 0.001 (0) + CaH[14C]O3+ 8.638e-18 7.925e-18 -17.064 -17.101 -0.037 (0) + H[14C]O2[18O]- 8.159e-19 7.466e-19 -18.088 -18.127 -0.039 (0) + H[14C]O[18O]O- 8.159e-19 7.466e-19 -18.088 -18.127 -0.039 (0) + H[14C][18O]O2- 8.159e-19 7.466e-19 -18.088 -18.127 -0.039 (0) + Ca[14C]O3 4.735e-19 4.742e-19 -18.325 -18.324 0.001 (0) + [14C]O[18O] 3.540e-19 3.546e-19 -18.451 -18.450 0.001 (0) + [14C]O3-2 2.427e-19 1.701e-19 -18.615 -18.769 -0.154 (0) + CaH[14C]O2[18O]+ 1.724e-20 1.581e-20 -19.764 -19.801 -0.037 (0) + CaH[14C]O[18O]O+ 1.724e-20 1.581e-20 -19.764 -19.801 -0.037 (0) + CaH[14C][18O]O2+ 1.724e-20 1.581e-20 -19.764 -19.801 -0.037 (0) + Ca[14C]O2[18O] 2.834e-21 2.839e-21 -20.548 -20.547 0.001 (0) + H[14C]O[18O]2- 1.628e-21 1.490e-21 -20.788 -20.827 -0.039 (0) + H[14C][18O]2O- 1.628e-21 1.490e-21 -20.788 -20.827 -0.039 (0) + H[14C][18O]O[18O]- 1.628e-21 1.490e-21 -20.788 -20.827 -0.039 (0) + [14C]O2[18O]-2 1.453e-21 1.018e-21 -20.838 -20.992 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.201e-15 + O[18O] 3.194e-15 3.200e-15 -14.496 -14.495 0.001 (0) + [18O]2 3.187e-18 3.192e-18 -17.497 -17.496 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -49977,99 +49977,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.560 -126.559 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.138 -40.138 0.001 -O(0) 1.569e-12 - O2 7.813e-13 7.826e-13 -12.107 -12.106 0.001 - O[18O] 3.118e-15 3.123e-15 -14.506 -14.505 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.516 -128.515 0.001 -[13C](4) 6.510e-05 - H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 - [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.585e-08 4.592e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.633 -139.632 0.001 -[14C](4) 5.009e-16 - H[14C]O3- 4.046e-16 3.702e-16 -15.393 -15.432 -0.039 - [14C]O2 8.423e-17 8.437e-17 -16.075 -16.074 0.001 - CaH[14C]O3+ 8.547e-18 7.842e-18 -17.068 -17.106 -0.037 - H[14C]O2[18O]- 8.073e-19 7.387e-19 -18.093 -18.132 -0.039 - H[14C]O[18O]O- 8.073e-19 7.387e-19 -18.093 -18.132 -0.039 - H[14C][18O]O2- 8.073e-19 7.387e-19 -18.093 -18.132 -0.039 - Ca[14C]O3 4.685e-19 4.692e-19 -18.329 -18.329 0.001 - [14C]O[18O] 3.503e-19 3.508e-19 -18.456 -18.455 0.001 - [14C]O3-2 2.401e-19 1.683e-19 -18.620 -18.774 -0.154 - CaH[14C]O2[18O]+ 1.705e-20 1.565e-20 -19.768 -19.806 -0.037 - CaH[14C]O[18O]O+ 1.705e-20 1.565e-20 -19.768 -19.806 -0.037 - CaH[14C][18O]O2+ 1.705e-20 1.565e-20 -19.768 -19.806 -0.037 - Ca[14C]O2[18O] 2.804e-21 2.809e-21 -20.552 -20.551 0.001 - H[14C]O[18O]2- 1.611e-21 1.474e-21 -20.793 -20.832 -0.039 - H[14C][18O]2O- 1.611e-21 1.474e-21 -20.793 -20.832 -0.039 - H[14C][18O]O[18O]- 1.611e-21 1.474e-21 -20.793 -20.832 -0.039 - [14C]O2[18O]-2 1.437e-21 1.007e-21 -20.842 -20.997 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.124e-15 - O[18O] 3.118e-15 3.123e-15 -14.506 -14.505 0.001 - [18O]2 3.110e-18 3.115e-18 -17.507 -17.507 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.560 -126.559 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.138 -40.138 0.001 (0) +O(0) 1.569e-12 + O2 7.813e-13 7.826e-13 -12.107 -12.106 0.001 (0) + O[18O] 3.118e-15 3.123e-15 -14.506 -14.505 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.516 -128.515 0.001 (0) +[13C](4) 6.510e-05 + H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.102e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.087e-08 6.097e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.585e-08 4.592e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.633 -139.632 0.001 (0) +[14C](4) 5.009e-16 + H[14C]O3- 4.046e-16 3.702e-16 -15.393 -15.432 -0.039 (0) + [14C]O2 8.423e-17 8.437e-17 -16.075 -16.074 0.001 (0) + CaH[14C]O3+ 8.547e-18 7.842e-18 -17.068 -17.106 -0.037 (0) + H[14C]O2[18O]- 8.073e-19 7.387e-19 -18.093 -18.132 -0.039 (0) + H[14C]O[18O]O- 8.073e-19 7.387e-19 -18.093 -18.132 -0.039 (0) + H[14C][18O]O2- 8.073e-19 7.387e-19 -18.093 -18.132 -0.039 (0) + Ca[14C]O3 4.685e-19 4.692e-19 -18.329 -18.329 0.001 (0) + [14C]O[18O] 3.503e-19 3.508e-19 -18.456 -18.455 0.001 (0) + [14C]O3-2 2.401e-19 1.683e-19 -18.620 -18.774 -0.154 (0) + CaH[14C]O2[18O]+ 1.705e-20 1.565e-20 -19.768 -19.806 -0.037 (0) + CaH[14C]O[18O]O+ 1.705e-20 1.565e-20 -19.768 -19.806 -0.037 (0) + CaH[14C][18O]O2+ 1.705e-20 1.565e-20 -19.768 -19.806 -0.037 (0) + Ca[14C]O2[18O] 2.804e-21 2.809e-21 -20.552 -20.551 0.001 (0) + H[14C]O[18O]2- 1.611e-21 1.474e-21 -20.793 -20.832 -0.039 (0) + H[14C][18O]2O- 1.611e-21 1.474e-21 -20.793 -20.832 -0.039 (0) + H[14C][18O]O[18O]- 1.611e-21 1.474e-21 -20.793 -20.832 -0.039 (0) + [14C]O2[18O]-2 1.437e-21 1.007e-21 -20.842 -20.997 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.124e-15 + O[18O] 3.118e-15 3.123e-15 -14.506 -14.505 0.001 (0) + [18O]2 3.110e-18 3.115e-18 -17.507 -17.507 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -50232,99 +50232,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.541 -126.540 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.133 -40.133 0.001 -O(0) 1.534e-12 - O2 7.639e-13 7.651e-13 -12.117 -12.116 0.001 - O[18O] 3.048e-15 3.053e-15 -14.516 -14.515 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.497 -128.496 0.001 -[13C](4) 6.510e-05 - H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.585e-08 4.592e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.618 -139.617 0.001 -[14C](4) 4.957e-16 - H[14C]O3- 4.004e-16 3.664e-16 -15.398 -15.436 -0.039 - [14C]O2 8.335e-17 8.349e-17 -16.079 -16.078 0.001 - CaH[14C]O3+ 8.458e-18 7.760e-18 -17.073 -17.110 -0.037 - H[14C]O2[18O]- 7.989e-19 7.310e-19 -18.098 -18.136 -0.039 - H[14C]O[18O]O- 7.989e-19 7.310e-19 -18.098 -18.136 -0.039 - H[14C][18O]O2- 7.989e-19 7.310e-19 -18.098 -18.136 -0.039 - Ca[14C]O3 4.636e-19 4.643e-19 -18.334 -18.333 0.001 - [14C]O[18O] 3.466e-19 3.472e-19 -18.460 -18.459 0.001 - [14C]O3-2 2.376e-19 1.665e-19 -18.624 -18.778 -0.154 - CaH[14C]O2[18O]+ 1.688e-20 1.548e-20 -19.773 -19.810 -0.037 - CaH[14C]O[18O]O+ 1.688e-20 1.548e-20 -19.773 -19.810 -0.037 - CaH[14C][18O]O2+ 1.688e-20 1.548e-20 -19.773 -19.810 -0.037 - Ca[14C]O2[18O] 2.775e-21 2.779e-21 -20.557 -20.556 0.001 - H[14C]O[18O]2- 1.594e-21 1.458e-21 -20.798 -20.836 -0.039 - H[14C][18O]2O- 1.594e-21 1.458e-21 -20.798 -20.836 -0.039 - H[14C][18O]O[18O]- 1.594e-21 1.458e-21 -20.798 -20.836 -0.039 - [14C]O2[18O]-2 1.422e-21 9.968e-22 -20.847 -21.001 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.054e-15 - O[18O] 3.048e-15 3.053e-15 -14.516 -14.515 0.001 - [18O]2 3.041e-18 3.046e-18 -17.517 -17.516 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.541 -126.540 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.133 -40.133 0.001 (0) +O(0) 1.534e-12 + O2 7.639e-13 7.651e-13 -12.117 -12.116 0.001 (0) + O[18O] 3.048e-15 3.053e-15 -14.516 -14.515 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.497 -128.496 0.001 (0) +[13C](4) 6.510e-05 + H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.585e-08 4.592e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.618 -139.617 0.001 (0) +[14C](4) 4.957e-16 + H[14C]O3- 4.004e-16 3.664e-16 -15.398 -15.436 -0.039 (0) + [14C]O2 8.335e-17 8.349e-17 -16.079 -16.078 0.001 (0) + CaH[14C]O3+ 8.458e-18 7.760e-18 -17.073 -17.110 -0.037 (0) + H[14C]O2[18O]- 7.989e-19 7.310e-19 -18.098 -18.136 -0.039 (0) + H[14C]O[18O]O- 7.989e-19 7.310e-19 -18.098 -18.136 -0.039 (0) + H[14C][18O]O2- 7.989e-19 7.310e-19 -18.098 -18.136 -0.039 (0) + Ca[14C]O3 4.636e-19 4.643e-19 -18.334 -18.333 0.001 (0) + [14C]O[18O] 3.466e-19 3.472e-19 -18.460 -18.459 0.001 (0) + [14C]O3-2 2.376e-19 1.665e-19 -18.624 -18.778 -0.154 (0) + CaH[14C]O2[18O]+ 1.688e-20 1.548e-20 -19.773 -19.810 -0.037 (0) + CaH[14C]O[18O]O+ 1.688e-20 1.548e-20 -19.773 -19.810 -0.037 (0) + CaH[14C][18O]O2+ 1.688e-20 1.548e-20 -19.773 -19.810 -0.037 (0) + Ca[14C]O2[18O] 2.775e-21 2.779e-21 -20.557 -20.556 0.001 (0) + H[14C]O[18O]2- 1.594e-21 1.458e-21 -20.798 -20.836 -0.039 (0) + H[14C][18O]2O- 1.594e-21 1.458e-21 -20.798 -20.836 -0.039 (0) + H[14C][18O]O[18O]- 1.594e-21 1.458e-21 -20.798 -20.836 -0.039 (0) + [14C]O2[18O]-2 1.422e-21 9.968e-22 -20.847 -21.001 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.054e-15 + O[18O] 3.048e-15 3.053e-15 -14.516 -14.515 0.001 (0) + [18O]2 3.041e-18 3.046e-18 -17.517 -17.516 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -50487,99 +50487,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.530 -126.530 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.131 -40.130 0.001 -O(0) 1.516e-12 - O2 7.549e-13 7.561e-13 -12.122 -12.121 0.001 - O[18O] 3.012e-15 3.017e-15 -14.521 -14.520 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.486 -128.486 0.001 -[13C](4) 6.510e-05 - H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.585e-08 4.592e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.612 -139.612 0.001 -[14C](4) 4.906e-16 - H[14C]O3- 3.963e-16 3.626e-16 -15.402 -15.441 -0.039 - [14C]O2 8.249e-17 8.263e-17 -16.084 -16.083 0.001 - CaH[14C]O3+ 8.371e-18 7.680e-18 -17.077 -17.115 -0.037 - H[14C]O2[18O]- 7.906e-19 7.234e-19 -18.102 -18.141 -0.039 - H[14C]O[18O]O- 7.906e-19 7.234e-19 -18.102 -18.141 -0.039 - H[14C][18O]O2- 7.906e-19 7.234e-19 -18.102 -18.141 -0.039 - Ca[14C]O3 4.588e-19 4.595e-19 -18.338 -18.338 0.001 - [14C]O[18O] 3.430e-19 3.436e-19 -18.465 -18.464 0.001 - [14C]O3-2 2.351e-19 1.648e-19 -18.629 -18.783 -0.154 - CaH[14C]O2[18O]+ 1.670e-20 1.532e-20 -19.777 -19.815 -0.037 - CaH[14C]O[18O]O+ 1.670e-20 1.532e-20 -19.777 -19.815 -0.037 - CaH[14C][18O]O2+ 1.670e-20 1.532e-20 -19.777 -19.815 -0.037 - Ca[14C]O2[18O] 2.746e-21 2.751e-21 -20.561 -20.561 0.001 - H[14C]O[18O]2- 1.577e-21 1.443e-21 -20.802 -20.841 -0.039 - H[14C][18O]2O- 1.577e-21 1.443e-21 -20.802 -20.841 -0.039 - H[14C][18O]O[18O]- 1.577e-21 1.443e-21 -20.802 -20.841 -0.039 - [14C]O2[18O]-2 1.408e-21 9.865e-22 -20.852 -21.006 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 3.018e-15 - O[18O] 3.012e-15 3.017e-15 -14.521 -14.520 0.001 - [18O]2 3.005e-18 3.010e-18 -17.522 -17.521 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.530 -126.530 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.131 -40.130 0.001 (0) +O(0) 1.516e-12 + O2 7.549e-13 7.561e-13 -12.122 -12.121 0.001 (0) + O[18O] 3.012e-15 3.017e-15 -14.521 -14.520 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.486 -128.486 0.001 (0) +[13C](4) 6.510e-05 + H[13C]O3- 5.250e-05 4.804e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.585e-08 4.592e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.612 -139.612 0.001 (0) +[14C](4) 4.906e-16 + H[14C]O3- 3.963e-16 3.626e-16 -15.402 -15.441 -0.039 (0) + [14C]O2 8.249e-17 8.263e-17 -16.084 -16.083 0.001 (0) + CaH[14C]O3+ 8.371e-18 7.680e-18 -17.077 -17.115 -0.037 (0) + H[14C]O2[18O]- 7.906e-19 7.234e-19 -18.102 -18.141 -0.039 (0) + H[14C]O[18O]O- 7.906e-19 7.234e-19 -18.102 -18.141 -0.039 (0) + H[14C][18O]O2- 7.906e-19 7.234e-19 -18.102 -18.141 -0.039 (0) + Ca[14C]O3 4.588e-19 4.595e-19 -18.338 -18.338 0.001 (0) + [14C]O[18O] 3.430e-19 3.436e-19 -18.465 -18.464 0.001 (0) + [14C]O3-2 2.351e-19 1.648e-19 -18.629 -18.783 -0.154 (0) + CaH[14C]O2[18O]+ 1.670e-20 1.532e-20 -19.777 -19.815 -0.037 (0) + CaH[14C]O[18O]O+ 1.670e-20 1.532e-20 -19.777 -19.815 -0.037 (0) + CaH[14C][18O]O2+ 1.670e-20 1.532e-20 -19.777 -19.815 -0.037 (0) + Ca[14C]O2[18O] 2.746e-21 2.751e-21 -20.561 -20.561 0.001 (0) + H[14C]O[18O]2- 1.577e-21 1.443e-21 -20.802 -20.841 -0.039 (0) + H[14C][18O]2O- 1.577e-21 1.443e-21 -20.802 -20.841 -0.039 (0) + H[14C][18O]O[18O]- 1.577e-21 1.443e-21 -20.802 -20.841 -0.039 (0) + [14C]O2[18O]-2 1.408e-21 9.865e-22 -20.852 -21.006 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 3.018e-15 + O[18O] 3.012e-15 3.017e-15 -14.521 -14.520 0.001 (0) + [18O]2 3.005e-18 3.010e-18 -17.522 -17.521 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -50742,99 +50742,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.521 -126.520 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.129 -40.128 0.001 -O(0) 1.499e-12 - O2 7.467e-13 7.480e-13 -12.127 -12.126 0.001 - O[18O] 2.980e-15 2.985e-15 -14.526 -14.525 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.477 -128.476 0.001 -[13C](4) 6.510e-05 - H[13C]O3- 5.251e-05 4.804e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.585e-08 4.592e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.607 -139.607 0.001 -[14C](4) 4.856e-16 - H[14C]O3- 3.922e-16 3.589e-16 -15.406 -15.445 -0.039 - [14C]O2 8.165e-17 8.178e-17 -16.088 -16.087 0.001 - CaH[14C]O3+ 8.285e-18 7.601e-18 -17.082 -17.119 -0.037 - H[14C]O2[18O]- 7.825e-19 7.160e-19 -18.106 -18.145 -0.039 - H[14C]O[18O]O- 7.825e-19 7.160e-19 -18.106 -18.145 -0.039 - H[14C][18O]O2- 7.825e-19 7.160e-19 -18.106 -18.145 -0.039 - Ca[14C]O3 4.541e-19 4.548e-19 -18.343 -18.342 0.001 - [14C]O[18O] 3.395e-19 3.401e-19 -18.469 -18.468 0.001 - [14C]O3-2 2.327e-19 1.631e-19 -18.633 -18.787 -0.154 - CaH[14C]O2[18O]+ 1.653e-20 1.517e-20 -19.782 -19.819 -0.037 - CaH[14C]O[18O]O+ 1.653e-20 1.517e-20 -19.782 -19.819 -0.037 - CaH[14C][18O]O2+ 1.653e-20 1.517e-20 -19.782 -19.819 -0.037 - Ca[14C]O2[18O] 2.718e-21 2.723e-21 -20.566 -20.565 0.001 - H[14C]O[18O]2- 1.561e-21 1.429e-21 -20.807 -20.845 -0.039 - H[14C][18O]2O- 1.561e-21 1.429e-21 -20.807 -20.845 -0.039 - H[14C][18O]O[18O]- 1.561e-21 1.429e-21 -20.807 -20.845 -0.039 - [14C]O2[18O]-2 1.393e-21 9.765e-22 -20.856 -21.010 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.986e-15 - O[18O] 2.980e-15 2.985e-15 -14.526 -14.525 0.001 - [18O]2 2.973e-18 2.977e-18 -17.527 -17.526 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.521 -126.520 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.129 -40.128 0.001 (0) +O(0) 1.499e-12 + O2 7.467e-13 7.480e-13 -12.127 -12.126 0.001 (0) + O[18O] 2.980e-15 2.985e-15 -14.526 -14.525 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.477 -128.476 0.001 (0) +[13C](4) 6.510e-05 + H[13C]O3- 5.251e-05 4.804e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.585e-08 4.592e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.607 -139.607 0.001 (0) +[14C](4) 4.856e-16 + H[14C]O3- 3.922e-16 3.589e-16 -15.406 -15.445 -0.039 (0) + [14C]O2 8.165e-17 8.178e-17 -16.088 -16.087 0.001 (0) + CaH[14C]O3+ 8.285e-18 7.601e-18 -17.082 -17.119 -0.037 (0) + H[14C]O2[18O]- 7.825e-19 7.160e-19 -18.106 -18.145 -0.039 (0) + H[14C]O[18O]O- 7.825e-19 7.160e-19 -18.106 -18.145 -0.039 (0) + H[14C][18O]O2- 7.825e-19 7.160e-19 -18.106 -18.145 -0.039 (0) + Ca[14C]O3 4.541e-19 4.548e-19 -18.343 -18.342 0.001 (0) + [14C]O[18O] 3.395e-19 3.401e-19 -18.469 -18.468 0.001 (0) + [14C]O3-2 2.327e-19 1.631e-19 -18.633 -18.787 -0.154 (0) + CaH[14C]O2[18O]+ 1.653e-20 1.517e-20 -19.782 -19.819 -0.037 (0) + CaH[14C]O[18O]O+ 1.653e-20 1.517e-20 -19.782 -19.819 -0.037 (0) + CaH[14C][18O]O2+ 1.653e-20 1.517e-20 -19.782 -19.819 -0.037 (0) + Ca[14C]O2[18O] 2.718e-21 2.723e-21 -20.566 -20.565 0.001 (0) + H[14C]O[18O]2- 1.561e-21 1.429e-21 -20.807 -20.845 -0.039 (0) + H[14C][18O]2O- 1.561e-21 1.429e-21 -20.807 -20.845 -0.039 (0) + H[14C][18O]O[18O]- 1.561e-21 1.429e-21 -20.807 -20.845 -0.039 (0) + [14C]O2[18O]-2 1.393e-21 9.765e-22 -20.856 -21.010 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.986e-15 + O[18O] 2.980e-15 2.985e-15 -14.526 -14.525 0.001 (0) + [18O]2 2.973e-18 2.977e-18 -17.527 -17.526 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -50997,99 +50997,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.516 -126.515 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.127 -40.127 0.001 -O(0) 1.491e-12 - O2 7.425e-13 7.437e-13 -12.129 -12.129 0.001 - O[18O] 2.963e-15 2.968e-15 -14.528 -14.528 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.472 -128.471 0.001 -[13C](4) 6.510e-05 - H[13C]O3- 5.251e-05 4.804e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.585e-08 4.592e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.607 -139.606 0.001 -[14C](4) 4.807e-16 - H[14C]O3- 3.882e-16 3.552e-16 -15.411 -15.449 -0.039 - [14C]O2 8.082e-17 8.096e-17 -16.092 -16.092 0.001 - CaH[14C]O3+ 8.201e-18 7.524e-18 -17.086 -17.124 -0.037 - H[14C]O2[18O]- 7.746e-19 7.088e-19 -18.111 -18.149 -0.039 - H[14C]O[18O]O- 7.746e-19 7.088e-19 -18.111 -18.149 -0.039 - H[14C][18O]O2- 7.746e-19 7.088e-19 -18.111 -18.149 -0.039 - Ca[14C]O3 4.495e-19 4.502e-19 -18.347 -18.347 0.001 - [14C]O[18O] 3.361e-19 3.366e-19 -18.474 -18.473 0.001 - [14C]O3-2 2.304e-19 1.615e-19 -18.638 -18.792 -0.154 - CaH[14C]O2[18O]+ 1.636e-20 1.501e-20 -19.786 -19.824 -0.037 - CaH[14C]O[18O]O+ 1.636e-20 1.501e-20 -19.786 -19.824 -0.037 - CaH[14C][18O]O2+ 1.636e-20 1.501e-20 -19.786 -19.824 -0.037 - Ca[14C]O2[18O] 2.691e-21 2.695e-21 -20.570 -20.569 0.001 - H[14C]O[18O]2- 1.546e-21 1.414e-21 -20.811 -20.850 -0.039 - H[14C][18O]2O- 1.546e-21 1.414e-21 -20.811 -20.850 -0.039 - H[14C][18O]O[18O]- 1.546e-21 1.414e-21 -20.811 -20.850 -0.039 - [14C]O2[18O]-2 1.379e-21 9.666e-22 -20.860 -21.015 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.969e-15 - O[18O] 2.963e-15 2.968e-15 -14.528 -14.528 0.001 - [18O]2 2.956e-18 2.961e-18 -17.529 -17.529 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.516 -126.515 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.127 -40.127 0.001 (0) +O(0) 1.491e-12 + O2 7.425e-13 7.437e-13 -12.129 -12.129 0.001 (0) + O[18O] 2.963e-15 2.968e-15 -14.528 -14.528 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.472 -128.471 0.001 (0) +[13C](4) 6.510e-05 + H[13C]O3- 5.251e-05 4.804e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.585e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.585e-08 4.592e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.912e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.607 -139.606 0.001 (0) +[14C](4) 4.807e-16 + H[14C]O3- 3.882e-16 3.552e-16 -15.411 -15.449 -0.039 (0) + [14C]O2 8.082e-17 8.096e-17 -16.092 -16.092 0.001 (0) + CaH[14C]O3+ 8.201e-18 7.524e-18 -17.086 -17.124 -0.037 (0) + H[14C]O2[18O]- 7.746e-19 7.088e-19 -18.111 -18.149 -0.039 (0) + H[14C]O[18O]O- 7.746e-19 7.088e-19 -18.111 -18.149 -0.039 (0) + H[14C][18O]O2- 7.746e-19 7.088e-19 -18.111 -18.149 -0.039 (0) + Ca[14C]O3 4.495e-19 4.502e-19 -18.347 -18.347 0.001 (0) + [14C]O[18O] 3.361e-19 3.366e-19 -18.474 -18.473 0.001 (0) + [14C]O3-2 2.304e-19 1.615e-19 -18.638 -18.792 -0.154 (0) + CaH[14C]O2[18O]+ 1.636e-20 1.501e-20 -19.786 -19.824 -0.037 (0) + CaH[14C]O[18O]O+ 1.636e-20 1.501e-20 -19.786 -19.824 -0.037 (0) + CaH[14C][18O]O2+ 1.636e-20 1.501e-20 -19.786 -19.824 -0.037 (0) + Ca[14C]O2[18O] 2.691e-21 2.695e-21 -20.570 -20.569 0.001 (0) + H[14C]O[18O]2- 1.546e-21 1.414e-21 -20.811 -20.850 -0.039 (0) + H[14C][18O]2O- 1.546e-21 1.414e-21 -20.811 -20.850 -0.039 (0) + H[14C][18O]O[18O]- 1.546e-21 1.414e-21 -20.811 -20.850 -0.039 (0) + [14C]O2[18O]-2 1.379e-21 9.666e-22 -20.860 -21.015 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.969e-15 + O[18O] 2.963e-15 2.968e-15 -14.528 -14.528 0.001 (0) + [18O]2 2.956e-18 2.961e-18 -17.529 -17.529 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -51252,99 +51252,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.507 -126.506 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.125 -40.124 0.001 -O(0) 1.475e-12 - O2 7.346e-13 7.358e-13 -12.134 -12.133 0.001 - O[18O] 2.931e-15 2.936e-15 -14.533 -14.532 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.463 -128.462 0.001 -[13C](4) 6.510e-05 - H[13C]O3- 5.251e-05 4.804e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.585e-08 4.592e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.602 -139.601 0.001 -[14C](4) 4.759e-16 - H[14C]O3- 3.844e-16 3.517e-16 -15.415 -15.454 -0.039 - [14C]O2 8.001e-17 8.014e-17 -16.097 -16.096 0.001 - CaH[14C]O3+ 8.119e-18 7.449e-18 -17.090 -17.128 -0.037 - H[14C]O2[18O]- 7.669e-19 7.017e-19 -18.115 -18.154 -0.039 - H[14C]O[18O]O- 7.669e-19 7.017e-19 -18.115 -18.154 -0.039 - H[14C][18O]O2- 7.669e-19 7.017e-19 -18.115 -18.154 -0.039 - Ca[14C]O3 4.450e-19 4.457e-19 -18.352 -18.351 0.001 - [14C]O[18O] 3.327e-19 3.333e-19 -18.478 -18.477 0.001 - [14C]O3-2 2.281e-19 1.599e-19 -18.642 -18.796 -0.154 - CaH[14C]O2[18O]+ 1.620e-20 1.486e-20 -19.791 -19.828 -0.037 - CaH[14C]O[18O]O+ 1.620e-20 1.486e-20 -19.791 -19.828 -0.037 - CaH[14C][18O]O2+ 1.620e-20 1.486e-20 -19.791 -19.828 -0.037 - Ca[14C]O2[18O] 2.664e-21 2.668e-21 -20.575 -20.574 0.001 - H[14C]O[18O]2- 1.530e-21 1.400e-21 -20.815 -20.854 -0.039 - H[14C][18O]2O- 1.530e-21 1.400e-21 -20.815 -20.854 -0.039 - H[14C][18O]O[18O]- 1.530e-21 1.400e-21 -20.815 -20.854 -0.039 - [14C]O2[18O]-2 1.365e-21 9.569e-22 -20.865 -21.019 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.937e-15 - O[18O] 2.931e-15 2.936e-15 -14.533 -14.532 0.001 - [18O]2 2.924e-18 2.929e-18 -17.534 -17.533 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.507 -126.506 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.125 -40.124 0.001 (0) +O(0) 1.475e-12 + O2 7.346e-13 7.358e-13 -12.134 -12.133 0.001 (0) + O[18O] 2.931e-15 2.936e-15 -14.533 -14.532 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.463 -128.462 0.001 (0) +[13C](4) 6.510e-05 + H[13C]O3- 5.251e-05 4.804e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.585e-08 4.592e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.602 -139.601 0.001 (0) +[14C](4) 4.759e-16 + H[14C]O3- 3.844e-16 3.517e-16 -15.415 -15.454 -0.039 (0) + [14C]O2 8.001e-17 8.014e-17 -16.097 -16.096 0.001 (0) + CaH[14C]O3+ 8.119e-18 7.449e-18 -17.090 -17.128 -0.037 (0) + H[14C]O2[18O]- 7.669e-19 7.017e-19 -18.115 -18.154 -0.039 (0) + H[14C]O[18O]O- 7.669e-19 7.017e-19 -18.115 -18.154 -0.039 (0) + H[14C][18O]O2- 7.669e-19 7.017e-19 -18.115 -18.154 -0.039 (0) + Ca[14C]O3 4.450e-19 4.457e-19 -18.352 -18.351 0.001 (0) + [14C]O[18O] 3.327e-19 3.333e-19 -18.478 -18.477 0.001 (0) + [14C]O3-2 2.281e-19 1.599e-19 -18.642 -18.796 -0.154 (0) + CaH[14C]O2[18O]+ 1.620e-20 1.486e-20 -19.791 -19.828 -0.037 (0) + CaH[14C]O[18O]O+ 1.620e-20 1.486e-20 -19.791 -19.828 -0.037 (0) + CaH[14C][18O]O2+ 1.620e-20 1.486e-20 -19.791 -19.828 -0.037 (0) + Ca[14C]O2[18O] 2.664e-21 2.668e-21 -20.575 -20.574 0.001 (0) + H[14C]O[18O]2- 1.530e-21 1.400e-21 -20.815 -20.854 -0.039 (0) + H[14C][18O]2O- 1.530e-21 1.400e-21 -20.815 -20.854 -0.039 (0) + H[14C][18O]O[18O]- 1.530e-21 1.400e-21 -20.815 -20.854 -0.039 (0) + [14C]O2[18O]-2 1.365e-21 9.569e-22 -20.865 -21.019 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.937e-15 + O[18O] 2.931e-15 2.936e-15 -14.533 -14.532 0.001 (0) + [18O]2 2.924e-18 2.929e-18 -17.534 -17.533 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -51507,99 +51507,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.509 -126.508 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.126 -40.125 0.001 -O(0) 1.479e-12 - O2 7.367e-13 7.379e-13 -12.133 -12.132 0.001 - O[18O] 2.940e-15 2.945e-15 -14.532 -14.531 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.465 -128.464 0.001 -[13C](4) 6.510e-05 - H[13C]O3- 5.251e-05 4.804e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.585e-08 4.592e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.609 -139.608 0.001 -[14C](4) 4.711e-16 - H[14C]O3- 3.805e-16 3.482e-16 -15.420 -15.458 -0.039 - [14C]O2 7.922e-17 7.935e-17 -16.101 -16.100 0.001 - CaH[14C]O3+ 8.039e-18 7.375e-18 -17.095 -17.132 -0.037 - H[14C]O2[18O]- 7.593e-19 6.947e-19 -18.120 -18.158 -0.039 - H[14C]O[18O]O- 7.593e-19 6.947e-19 -18.120 -18.158 -0.039 - H[14C][18O]O2- 7.593e-19 6.947e-19 -18.120 -18.158 -0.039 - Ca[14C]O3 4.406e-19 4.413e-19 -18.356 -18.355 0.001 - [14C]O[18O] 3.294e-19 3.300e-19 -18.482 -18.482 0.001 - [14C]O3-2 2.258e-19 1.583e-19 -18.646 -18.801 -0.154 - CaH[14C]O2[18O]+ 1.604e-20 1.471e-20 -19.795 -19.832 -0.037 - CaH[14C]O[18O]O+ 1.604e-20 1.471e-20 -19.795 -19.832 -0.037 - CaH[14C][18O]O2+ 1.604e-20 1.471e-20 -19.795 -19.832 -0.037 - Ca[14C]O2[18O] 2.637e-21 2.642e-21 -20.579 -20.578 0.001 - H[14C]O[18O]2- 1.515e-21 1.386e-21 -20.820 -20.858 -0.039 - H[14C][18O]2O- 1.515e-21 1.386e-21 -20.820 -20.858 -0.039 - H[14C][18O]O[18O]- 1.515e-21 1.386e-21 -20.820 -20.858 -0.039 - [14C]O2[18O]-2 1.352e-21 9.474e-22 -20.869 -21.023 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.946e-15 - O[18O] 2.940e-15 2.945e-15 -14.532 -14.531 0.001 - [18O]2 2.933e-18 2.938e-18 -17.533 -17.532 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.509 -126.508 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.126 -40.125 0.001 (0) +O(0) 1.479e-12 + O2 7.367e-13 7.379e-13 -12.133 -12.132 0.001 (0) + O[18O] 2.940e-15 2.945e-15 -14.532 -14.531 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.465 -128.464 0.001 (0) +[13C](4) 6.510e-05 + H[13C]O3- 5.251e-05 4.804e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.585e-08 4.592e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.609 -139.608 0.001 (0) +[14C](4) 4.711e-16 + H[14C]O3- 3.805e-16 3.482e-16 -15.420 -15.458 -0.039 (0) + [14C]O2 7.922e-17 7.935e-17 -16.101 -16.100 0.001 (0) + CaH[14C]O3+ 8.039e-18 7.375e-18 -17.095 -17.132 -0.037 (0) + H[14C]O2[18O]- 7.593e-19 6.947e-19 -18.120 -18.158 -0.039 (0) + H[14C]O[18O]O- 7.593e-19 6.947e-19 -18.120 -18.158 -0.039 (0) + H[14C][18O]O2- 7.593e-19 6.947e-19 -18.120 -18.158 -0.039 (0) + Ca[14C]O3 4.406e-19 4.413e-19 -18.356 -18.355 0.001 (0) + [14C]O[18O] 3.294e-19 3.300e-19 -18.482 -18.482 0.001 (0) + [14C]O3-2 2.258e-19 1.583e-19 -18.646 -18.801 -0.154 (0) + CaH[14C]O2[18O]+ 1.604e-20 1.471e-20 -19.795 -19.832 -0.037 (0) + CaH[14C]O[18O]O+ 1.604e-20 1.471e-20 -19.795 -19.832 -0.037 (0) + CaH[14C][18O]O2+ 1.604e-20 1.471e-20 -19.795 -19.832 -0.037 (0) + Ca[14C]O2[18O] 2.637e-21 2.642e-21 -20.579 -20.578 0.001 (0) + H[14C]O[18O]2- 1.515e-21 1.386e-21 -20.820 -20.858 -0.039 (0) + H[14C][18O]2O- 1.515e-21 1.386e-21 -20.820 -20.858 -0.039 (0) + H[14C][18O]O[18O]- 1.515e-21 1.386e-21 -20.820 -20.858 -0.039 (0) + [14C]O2[18O]-2 1.352e-21 9.474e-22 -20.869 -21.023 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.946e-15 + O[18O] 2.940e-15 2.945e-15 -14.532 -14.531 0.001 (0) + [18O]2 2.933e-18 2.938e-18 -17.533 -17.532 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -51762,99 +51762,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.494 -126.493 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.122 -40.121 0.001 -O(0) 1.453e-12 - O2 7.237e-13 7.249e-13 -12.140 -12.140 0.001 - O[18O] 2.888e-15 2.893e-15 -14.539 -14.539 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.450 -128.449 0.001 -[13C](4) 6.510e-05 - H[13C]O3- 5.251e-05 4.804e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.585e-08 4.593e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.597 -139.597 0.001 -[14C](4) 4.665e-16 - H[14C]O3- 3.768e-16 3.448e-16 -15.424 -15.462 -0.039 - [14C]O2 7.844e-17 7.857e-17 -16.105 -16.105 0.001 - CaH[14C]O3+ 7.960e-18 7.303e-18 -17.099 -17.137 -0.037 - H[14C]O2[18O]- 7.518e-19 6.879e-19 -18.124 -18.162 -0.039 - H[14C]O[18O]O- 7.518e-19 6.879e-19 -18.124 -18.162 -0.039 - H[14C][18O]O2- 7.518e-19 6.879e-19 -18.124 -18.162 -0.039 - Ca[14C]O3 4.363e-19 4.370e-19 -18.360 -18.360 0.001 - [14C]O[18O] 3.262e-19 3.267e-19 -18.487 -18.486 0.001 - [14C]O3-2 2.236e-19 1.567e-19 -18.651 -18.805 -0.154 - CaH[14C]O2[18O]+ 1.588e-20 1.457e-20 -19.799 -19.837 -0.037 - CaH[14C]O[18O]O+ 1.588e-20 1.457e-20 -19.799 -19.837 -0.037 - CaH[14C][18O]O2+ 1.588e-20 1.457e-20 -19.799 -19.837 -0.037 - Ca[14C]O2[18O] 2.611e-21 2.616e-21 -20.583 -20.582 0.001 - H[14C]O[18O]2- 1.500e-21 1.372e-21 -20.824 -20.862 -0.039 - H[14C][18O]2O- 1.500e-21 1.372e-21 -20.824 -20.862 -0.039 - H[14C][18O]O[18O]- 1.500e-21 1.372e-21 -20.824 -20.862 -0.039 - [14C]O2[18O]-2 1.338e-21 9.381e-22 -20.873 -21.028 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.894e-15 - O[18O] 2.888e-15 2.893e-15 -14.539 -14.539 0.001 - [18O]2 2.881e-18 2.886e-18 -17.540 -17.540 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.494 -126.493 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.122 -40.121 0.001 (0) +O(0) 1.453e-12 + O2 7.237e-13 7.249e-13 -12.140 -12.140 0.001 (0) + O[18O] 2.888e-15 2.893e-15 -14.539 -14.539 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.450 -128.449 0.001 (0) +[13C](4) 6.510e-05 + H[13C]O3- 5.251e-05 4.804e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.585e-08 4.593e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.597 -139.597 0.001 (0) +[14C](4) 4.665e-16 + H[14C]O3- 3.768e-16 3.448e-16 -15.424 -15.462 -0.039 (0) + [14C]O2 7.844e-17 7.857e-17 -16.105 -16.105 0.001 (0) + CaH[14C]O3+ 7.960e-18 7.303e-18 -17.099 -17.137 -0.037 (0) + H[14C]O2[18O]- 7.518e-19 6.879e-19 -18.124 -18.162 -0.039 (0) + H[14C]O[18O]O- 7.518e-19 6.879e-19 -18.124 -18.162 -0.039 (0) + H[14C][18O]O2- 7.518e-19 6.879e-19 -18.124 -18.162 -0.039 (0) + Ca[14C]O3 4.363e-19 4.370e-19 -18.360 -18.360 0.001 (0) + [14C]O[18O] 3.262e-19 3.267e-19 -18.487 -18.486 0.001 (0) + [14C]O3-2 2.236e-19 1.567e-19 -18.651 -18.805 -0.154 (0) + CaH[14C]O2[18O]+ 1.588e-20 1.457e-20 -19.799 -19.837 -0.037 (0) + CaH[14C]O[18O]O+ 1.588e-20 1.457e-20 -19.799 -19.837 -0.037 (0) + CaH[14C][18O]O2+ 1.588e-20 1.457e-20 -19.799 -19.837 -0.037 (0) + Ca[14C]O2[18O] 2.611e-21 2.616e-21 -20.583 -20.582 0.001 (0) + H[14C]O[18O]2- 1.500e-21 1.372e-21 -20.824 -20.862 -0.039 (0) + H[14C][18O]2O- 1.500e-21 1.372e-21 -20.824 -20.862 -0.039 (0) + H[14C][18O]O[18O]- 1.500e-21 1.372e-21 -20.824 -20.862 -0.039 (0) + [14C]O2[18O]-2 1.338e-21 9.381e-22 -20.873 -21.028 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.894e-15 + O[18O] 2.888e-15 2.893e-15 -14.539 -14.539 0.001 (0) + [18O]2 2.881e-18 2.886e-18 -17.540 -17.540 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -52017,99 +52017,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.476 -126.476 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.117 -40.117 0.001 -O(0) 1.424e-12 - O2 7.093e-13 7.105e-13 -12.149 -12.148 0.001 - O[18O] 2.830e-15 2.835e-15 -14.548 -14.547 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.432 -128.431 0.001 -[13C](4) 6.510e-05 - H[13C]O3- 5.251e-05 4.805e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.585e-08 4.593e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.584 -139.584 0.001 -[14C](4) 4.620e-16 - H[14C]O3- 3.731e-16 3.414e-16 -15.428 -15.467 -0.039 - [14C]O2 7.768e-17 7.781e-17 -16.110 -16.109 0.001 - CaH[14C]O3+ 7.882e-18 7.232e-18 -17.103 -17.141 -0.037 - H[14C]O2[18O]- 7.445e-19 6.812e-19 -18.128 -18.167 -0.039 - H[14C]O[18O]O- 7.445e-19 6.812e-19 -18.128 -18.167 -0.039 - H[14C][18O]O2- 7.445e-19 6.812e-19 -18.128 -18.167 -0.039 - Ca[14C]O3 4.320e-19 4.327e-19 -18.364 -18.364 0.001 - [14C]O[18O] 3.230e-19 3.235e-19 -18.491 -18.490 0.001 - [14C]O3-2 2.214e-19 1.552e-19 -18.655 -18.809 -0.154 - CaH[14C]O2[18O]+ 1.573e-20 1.443e-20 -19.803 -19.841 -0.037 - CaH[14C]O[18O]O+ 1.573e-20 1.443e-20 -19.803 -19.841 -0.037 - CaH[14C][18O]O2+ 1.573e-20 1.443e-20 -19.803 -19.841 -0.037 - Ca[14C]O2[18O] 2.586e-21 2.590e-21 -20.587 -20.587 0.001 - H[14C]O[18O]2- 1.485e-21 1.359e-21 -20.828 -20.867 -0.039 - H[14C][18O]2O- 1.485e-21 1.359e-21 -20.828 -20.867 -0.039 - H[14C][18O]O[18O]- 1.485e-21 1.359e-21 -20.828 -20.867 -0.039 - [14C]O2[18O]-2 1.325e-21 9.290e-22 -20.878 -21.032 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.836e-15 - O[18O] 2.830e-15 2.835e-15 -14.548 -14.547 0.001 - [18O]2 2.824e-18 2.828e-18 -17.549 -17.548 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.476 -126.476 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.117 -40.117 0.001 (0) +O(0) 1.424e-12 + O2 7.093e-13 7.105e-13 -12.149 -12.148 0.001 (0) + O[18O] 2.830e-15 2.835e-15 -14.548 -14.547 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.432 -128.431 0.001 (0) +[13C](4) 6.510e-05 + H[13C]O3- 5.251e-05 4.805e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.585e-08 4.593e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.584 -139.584 0.001 (0) +[14C](4) 4.620e-16 + H[14C]O3- 3.731e-16 3.414e-16 -15.428 -15.467 -0.039 (0) + [14C]O2 7.768e-17 7.781e-17 -16.110 -16.109 0.001 (0) + CaH[14C]O3+ 7.882e-18 7.232e-18 -17.103 -17.141 -0.037 (0) + H[14C]O2[18O]- 7.445e-19 6.812e-19 -18.128 -18.167 -0.039 (0) + H[14C]O[18O]O- 7.445e-19 6.812e-19 -18.128 -18.167 -0.039 (0) + H[14C][18O]O2- 7.445e-19 6.812e-19 -18.128 -18.167 -0.039 (0) + Ca[14C]O3 4.320e-19 4.327e-19 -18.364 -18.364 0.001 (0) + [14C]O[18O] 3.230e-19 3.235e-19 -18.491 -18.490 0.001 (0) + [14C]O3-2 2.214e-19 1.552e-19 -18.655 -18.809 -0.154 (0) + CaH[14C]O2[18O]+ 1.573e-20 1.443e-20 -19.803 -19.841 -0.037 (0) + CaH[14C]O[18O]O+ 1.573e-20 1.443e-20 -19.803 -19.841 -0.037 (0) + CaH[14C][18O]O2+ 1.573e-20 1.443e-20 -19.803 -19.841 -0.037 (0) + Ca[14C]O2[18O] 2.586e-21 2.590e-21 -20.587 -20.587 0.001 (0) + H[14C]O[18O]2- 1.485e-21 1.359e-21 -20.828 -20.867 -0.039 (0) + H[14C][18O]2O- 1.485e-21 1.359e-21 -20.828 -20.867 -0.039 (0) + H[14C][18O]O[18O]- 1.485e-21 1.359e-21 -20.828 -20.867 -0.039 (0) + [14C]O2[18O]-2 1.325e-21 9.290e-22 -20.878 -21.032 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.836e-15 + O[18O] 2.830e-15 2.835e-15 -14.548 -14.547 0.001 (0) + [18O]2 2.824e-18 2.828e-18 -17.549 -17.548 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -52272,99 +52272,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.465 -126.464 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.115 -40.114 0.001 -O(0) 1.406e-12 - O2 7.002e-13 7.014e-13 -12.155 -12.154 0.001 - O[18O] 2.794e-15 2.799e-15 -14.554 -14.553 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.421 -128.420 0.001 -[13C](4) 6.511e-05 - H[13C]O3- 5.251e-05 4.805e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.585e-08 4.593e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.577 -139.577 0.001 -[14C](4) 4.575e-16 - H[14C]O3- 3.695e-16 3.381e-16 -15.432 -15.471 -0.039 - [14C]O2 7.693e-17 7.706e-17 -16.114 -16.113 0.001 - CaH[14C]O3+ 7.806e-18 7.162e-18 -17.108 -17.145 -0.037 - H[14C]O2[18O]- 7.373e-19 6.746e-19 -18.132 -18.171 -0.039 - H[14C]O[18O]O- 7.373e-19 6.746e-19 -18.132 -18.171 -0.039 - H[14C][18O]O2- 7.373e-19 6.746e-19 -18.132 -18.171 -0.039 - Ca[14C]O3 4.279e-19 4.286e-19 -18.369 -18.368 0.001 - [14C]O[18O] 3.199e-19 3.204e-19 -18.495 -18.494 0.001 - [14C]O3-2 2.193e-19 1.537e-19 -18.659 -18.813 -0.154 - CaH[14C]O2[18O]+ 1.558e-20 1.429e-20 -19.808 -19.845 -0.037 - CaH[14C]O[18O]O+ 1.558e-20 1.429e-20 -19.808 -19.845 -0.037 - CaH[14C][18O]O2+ 1.558e-20 1.429e-20 -19.808 -19.845 -0.037 - Ca[14C]O2[18O] 2.561e-21 2.565e-21 -20.592 -20.591 0.001 - H[14C]O[18O]2- 1.471e-21 1.346e-21 -20.832 -20.871 -0.039 - H[14C][18O]2O- 1.471e-21 1.346e-21 -20.832 -20.871 -0.039 - H[14C][18O]O[18O]- 1.471e-21 1.346e-21 -20.832 -20.871 -0.039 - [14C]O2[18O]-2 1.313e-21 9.200e-22 -20.882 -21.036 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.800e-15 - O[18O] 2.794e-15 2.799e-15 -14.554 -14.553 0.001 - [18O]2 2.788e-18 2.792e-18 -17.555 -17.554 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.465 -126.464 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.115 -40.114 0.001 (0) +O(0) 1.406e-12 + O2 7.002e-13 7.014e-13 -12.155 -12.154 0.001 (0) + O[18O] 2.794e-15 2.799e-15 -14.554 -14.553 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.421 -128.420 0.001 (0) +[13C](4) 6.511e-05 + H[13C]O3- 5.251e-05 4.805e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.585e-08 4.593e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.120e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.577 -139.577 0.001 (0) +[14C](4) 4.575e-16 + H[14C]O3- 3.695e-16 3.381e-16 -15.432 -15.471 -0.039 (0) + [14C]O2 7.693e-17 7.706e-17 -16.114 -16.113 0.001 (0) + CaH[14C]O3+ 7.806e-18 7.162e-18 -17.108 -17.145 -0.037 (0) + H[14C]O2[18O]- 7.373e-19 6.746e-19 -18.132 -18.171 -0.039 (0) + H[14C]O[18O]O- 7.373e-19 6.746e-19 -18.132 -18.171 -0.039 (0) + H[14C][18O]O2- 7.373e-19 6.746e-19 -18.132 -18.171 -0.039 (0) + Ca[14C]O3 4.279e-19 4.286e-19 -18.369 -18.368 0.001 (0) + [14C]O[18O] 3.199e-19 3.204e-19 -18.495 -18.494 0.001 (0) + [14C]O3-2 2.193e-19 1.537e-19 -18.659 -18.813 -0.154 (0) + CaH[14C]O2[18O]+ 1.558e-20 1.429e-20 -19.808 -19.845 -0.037 (0) + CaH[14C]O[18O]O+ 1.558e-20 1.429e-20 -19.808 -19.845 -0.037 (0) + CaH[14C][18O]O2+ 1.558e-20 1.429e-20 -19.808 -19.845 -0.037 (0) + Ca[14C]O2[18O] 2.561e-21 2.565e-21 -20.592 -20.591 0.001 (0) + H[14C]O[18O]2- 1.471e-21 1.346e-21 -20.832 -20.871 -0.039 (0) + H[14C][18O]2O- 1.471e-21 1.346e-21 -20.832 -20.871 -0.039 (0) + H[14C][18O]O[18O]- 1.471e-21 1.346e-21 -20.832 -20.871 -0.039 (0) + [14C]O2[18O]-2 1.313e-21 9.200e-22 -20.882 -21.036 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.800e-15 + O[18O] 2.794e-15 2.799e-15 -14.554 -14.553 0.001 (0) + [18O]2 2.788e-18 2.792e-18 -17.555 -17.554 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -52527,99 +52527,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.486 -126.485 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.120 -40.119 0.001 -O(0) 1.440e-12 - O2 7.174e-13 7.186e-13 -12.144 -12.144 0.001 - O[18O] 2.863e-15 2.867e-15 -14.543 -14.543 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.442 -128.441 0.001 -[13C](4) 6.511e-05 - H[13C]O3- 5.251e-05 4.805e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 - [13C]O[18O] 4.585e-08 4.593e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.121e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.602 -139.602 0.001 -[14C](4) 4.531e-16 - H[14C]O3- 3.660e-16 3.349e-16 -15.436 -15.475 -0.039 - [14C]O2 7.620e-17 7.632e-17 -16.118 -16.117 0.001 - CaH[14C]O3+ 7.732e-18 7.094e-18 -17.112 -17.149 -0.037 - H[14C]O2[18O]- 7.303e-19 6.682e-19 -18.137 -18.175 -0.039 - H[14C]O[18O]O- 7.303e-19 6.682e-19 -18.137 -18.175 -0.039 - H[14C][18O]O2- 7.303e-19 6.682e-19 -18.137 -18.175 -0.039 - Ca[14C]O3 4.238e-19 4.245e-19 -18.373 -18.372 0.001 - [14C]O[18O] 3.168e-19 3.174e-19 -18.499 -18.498 0.001 - [14C]O3-2 2.172e-19 1.522e-19 -18.663 -18.817 -0.154 - CaH[14C]O2[18O]+ 1.543e-20 1.415e-20 -19.812 -19.849 -0.037 - CaH[14C]O[18O]O+ 1.543e-20 1.415e-20 -19.812 -19.849 -0.037 - CaH[14C][18O]O2+ 1.543e-20 1.415e-20 -19.812 -19.849 -0.037 - Ca[14C]O2[18O] 2.537e-21 2.541e-21 -20.596 -20.595 0.001 - H[14C]O[18O]2- 1.457e-21 1.333e-21 -20.837 -20.875 -0.039 - H[14C][18O]2O- 1.457e-21 1.333e-21 -20.837 -20.875 -0.039 - H[14C][18O]O[18O]- 1.457e-21 1.333e-21 -20.837 -20.875 -0.039 - [14C]O2[18O]-2 1.300e-21 9.112e-22 -20.886 -21.040 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.868e-15 - O[18O] 2.863e-15 2.867e-15 -14.543 -14.543 0.001 - [18O]2 2.856e-18 2.860e-18 -17.544 -17.544 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.486 -126.485 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.120 -40.119 0.001 (0) +O(0) 1.440e-12 + O2 7.174e-13 7.186e-13 -12.144 -12.144 0.001 (0) + O[18O] 2.863e-15 2.867e-15 -14.543 -14.543 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.442 -128.441 0.001 (0) +[13C](4) 6.511e-05 + H[13C]O3- 5.251e-05 4.805e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.216 -7.215 0.001 (0) + [13C]O[18O] 4.585e-08 4.593e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.121e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.602 -139.602 0.001 (0) +[14C](4) 4.531e-16 + H[14C]O3- 3.660e-16 3.349e-16 -15.436 -15.475 -0.039 (0) + [14C]O2 7.620e-17 7.632e-17 -16.118 -16.117 0.001 (0) + CaH[14C]O3+ 7.732e-18 7.094e-18 -17.112 -17.149 -0.037 (0) + H[14C]O2[18O]- 7.303e-19 6.682e-19 -18.137 -18.175 -0.039 (0) + H[14C]O[18O]O- 7.303e-19 6.682e-19 -18.137 -18.175 -0.039 (0) + H[14C][18O]O2- 7.303e-19 6.682e-19 -18.137 -18.175 -0.039 (0) + Ca[14C]O3 4.238e-19 4.245e-19 -18.373 -18.372 0.001 (0) + [14C]O[18O] 3.168e-19 3.174e-19 -18.499 -18.498 0.001 (0) + [14C]O3-2 2.172e-19 1.522e-19 -18.663 -18.817 -0.154 (0) + CaH[14C]O2[18O]+ 1.543e-20 1.415e-20 -19.812 -19.849 -0.037 (0) + CaH[14C]O[18O]O+ 1.543e-20 1.415e-20 -19.812 -19.849 -0.037 (0) + CaH[14C][18O]O2+ 1.543e-20 1.415e-20 -19.812 -19.849 -0.037 (0) + Ca[14C]O2[18O] 2.537e-21 2.541e-21 -20.596 -20.595 0.001 (0) + H[14C]O[18O]2- 1.457e-21 1.333e-21 -20.837 -20.875 -0.039 (0) + H[14C][18O]2O- 1.457e-21 1.333e-21 -20.837 -20.875 -0.039 (0) + H[14C][18O]O[18O]- 1.457e-21 1.333e-21 -20.837 -20.875 -0.039 (0) + [14C]O2[18O]-2 1.300e-21 9.112e-22 -20.886 -21.040 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.868e-15 + O[18O] 2.863e-15 2.867e-15 -14.543 -14.543 0.001 (0) + [18O]2 2.856e-18 2.860e-18 -17.544 -17.544 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -52782,99 +52782,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.465 -126.464 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.088e-08 6.098e-08 -7.215 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.115 -40.114 0.001 -O(0) 1.406e-12 - O2 7.001e-13 7.012e-13 -12.155 -12.154 0.001 - O[18O] 2.794e-15 2.798e-15 -14.554 -14.553 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.421 -128.420 0.001 -[13C](4) 6.511e-05 - H[13C]O3- 5.251e-05 4.805e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.088e-08 6.098e-08 -7.215 -7.215 0.001 - [13C]O[18O] 4.585e-08 4.593e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.121e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.585 -139.585 0.001 -[14C](4) 4.489e-16 - H[14C]O3- 3.626e-16 3.317e-16 -15.441 -15.479 -0.039 - [14C]O2 7.548e-17 7.560e-17 -16.122 -16.121 0.001 - CaH[14C]O3+ 7.659e-18 7.026e-18 -17.116 -17.153 -0.037 - H[14C]O2[18O]- 7.234e-19 6.619e-19 -18.141 -18.179 -0.039 - H[14C]O[18O]O- 7.234e-19 6.619e-19 -18.141 -18.179 -0.039 - H[14C][18O]O2- 7.234e-19 6.619e-19 -18.141 -18.179 -0.039 - Ca[14C]O3 4.198e-19 4.205e-19 -18.377 -18.376 0.001 - [14C]O[18O] 3.139e-19 3.144e-19 -18.503 -18.503 0.001 - [14C]O3-2 2.151e-19 1.508e-19 -18.667 -18.822 -0.154 - CaH[14C]O2[18O]+ 1.528e-20 1.402e-20 -19.816 -19.853 -0.037 - CaH[14C]O[18O]O+ 1.528e-20 1.402e-20 -19.816 -19.853 -0.037 - CaH[14C][18O]O2+ 1.528e-20 1.402e-20 -19.816 -19.853 -0.037 - Ca[14C]O2[18O] 2.513e-21 2.517e-21 -20.600 -20.599 0.001 - H[14C]O[18O]2- 1.443e-21 1.321e-21 -20.841 -20.879 -0.039 - H[14C][18O]2O- 1.443e-21 1.321e-21 -20.841 -20.879 -0.039 - H[14C][18O]O[18O]- 1.443e-21 1.321e-21 -20.841 -20.879 -0.039 - [14C]O2[18O]-2 1.288e-21 9.026e-22 -20.890 -21.044 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.799e-15 - O[18O] 2.794e-15 2.798e-15 -14.554 -14.553 0.001 - [18O]2 2.787e-18 2.792e-18 -17.555 -17.554 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.465 -126.464 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.215 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.115 -40.114 0.001 (0) +O(0) 1.406e-12 + O2 7.001e-13 7.012e-13 -12.155 -12.154 0.001 (0) + O[18O] 2.794e-15 2.798e-15 -14.554 -14.553 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.421 -128.420 0.001 (0) +[13C](4) 6.511e-05 + H[13C]O3- 5.251e-05 4.805e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.586e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.088e-08 6.098e-08 -7.215 -7.215 0.001 (0) + [13C]O[18O] 4.585e-08 4.593e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.121e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.585 -139.585 0.001 (0) +[14C](4) 4.489e-16 + H[14C]O3- 3.626e-16 3.317e-16 -15.441 -15.479 -0.039 (0) + [14C]O2 7.548e-17 7.560e-17 -16.122 -16.121 0.001 (0) + CaH[14C]O3+ 7.659e-18 7.026e-18 -17.116 -17.153 -0.037 (0) + H[14C]O2[18O]- 7.234e-19 6.619e-19 -18.141 -18.179 -0.039 (0) + H[14C]O[18O]O- 7.234e-19 6.619e-19 -18.141 -18.179 -0.039 (0) + H[14C][18O]O2- 7.234e-19 6.619e-19 -18.141 -18.179 -0.039 (0) + Ca[14C]O3 4.198e-19 4.205e-19 -18.377 -18.376 0.001 (0) + [14C]O[18O] 3.139e-19 3.144e-19 -18.503 -18.503 0.001 (0) + [14C]O3-2 2.151e-19 1.508e-19 -18.667 -18.822 -0.154 (0) + CaH[14C]O2[18O]+ 1.528e-20 1.402e-20 -19.816 -19.853 -0.037 (0) + CaH[14C]O[18O]O+ 1.528e-20 1.402e-20 -19.816 -19.853 -0.037 (0) + CaH[14C][18O]O2+ 1.528e-20 1.402e-20 -19.816 -19.853 -0.037 (0) + Ca[14C]O2[18O] 2.513e-21 2.517e-21 -20.600 -20.599 0.001 (0) + H[14C]O[18O]2- 1.443e-21 1.321e-21 -20.841 -20.879 -0.039 (0) + H[14C][18O]2O- 1.443e-21 1.321e-21 -20.841 -20.879 -0.039 (0) + H[14C][18O]O[18O]- 1.443e-21 1.321e-21 -20.841 -20.879 -0.039 (0) + [14C]O2[18O]-2 1.288e-21 9.026e-22 -20.890 -21.044 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.799e-15 + O[18O] 2.794e-15 2.798e-15 -14.554 -14.553 0.001 (0) + [18O]2 2.787e-18 2.792e-18 -17.555 -17.554 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -53037,99 +53037,99 @@ Alpha 14C Calcite/CO2(aq) 1.0215 21.282 21.282 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 - OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 - H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -126.479 -126.479 0.001 -C(4) 5.840e-03 - HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 - CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 - HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 - CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 -Ca 2.451e-03 - Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 - CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 - CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - Ca[13C]O3 6.088e-08 6.099e-08 -7.215 -7.215 0.001 - CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.118 -40.117 0.001 -O(0) 1.429e-12 - O2 7.118e-13 7.130e-13 -12.148 -12.147 0.001 - O[18O] 2.840e-15 2.845e-15 -14.547 -14.546 0.001 -[13C](-4) 0.000e+00 - [13C]H4 0.000e+00 0.000e+00 -128.435 -128.434 0.001 -[13C](4) 6.511e-05 - H[13C]O3- 5.251e-05 4.805e-05 -4.280 -4.318 -0.039 - [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 - CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 - H[13C]O2[18O]- 1.048e-07 9.587e-08 -6.980 -7.018 -0.039 - H[13C]O[18O]O- 1.048e-07 9.587e-08 -6.980 -7.018 -0.039 - H[13C][18O]O2- 1.048e-07 9.587e-08 -6.980 -7.018 -0.039 - Ca[13C]O3 6.088e-08 6.099e-08 -7.215 -7.215 0.001 - [13C]O[18O] 4.585e-08 4.593e-08 -7.339 -7.338 0.001 - [13C]O3-2 3.121e-08 2.187e-08 -7.506 -7.660 -0.154 - CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 - Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 - H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 - [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 -[14C](-4) 0.000e+00 - [14C]H4 0.000e+00 0.000e+00 -139.604 -139.603 0.001 -[14C](4) 4.447e-16 - H[14C]O3- 3.592e-16 3.286e-16 -15.445 -15.483 -0.039 - [14C]O2 7.477e-17 7.489e-17 -16.126 -16.126 0.001 - CaH[14C]O3+ 7.587e-18 6.961e-18 -17.120 -17.157 -0.037 - H[14C]O2[18O]- 7.166e-19 6.557e-19 -18.145 -18.183 -0.039 - H[14C]O[18O]O- 7.166e-19 6.557e-19 -18.145 -18.183 -0.039 - H[14C][18O]O2- 7.166e-19 6.557e-19 -18.145 -18.183 -0.039 - Ca[14C]O3 4.158e-19 4.165e-19 -18.381 -18.380 0.001 - [14C]O[18O] 3.109e-19 3.114e-19 -18.507 -18.507 0.001 - [14C]O3-2 2.131e-19 1.494e-19 -18.671 -18.826 -0.154 - CaH[14C]O2[18O]+ 1.514e-20 1.389e-20 -19.820 -19.857 -0.037 - CaH[14C]O[18O]O+ 1.514e-20 1.389e-20 -19.820 -19.857 -0.037 - CaH[14C][18O]O2+ 1.514e-20 1.389e-20 -19.820 -19.857 -0.037 - Ca[14C]O2[18O] 2.489e-21 2.493e-21 -20.604 -20.603 0.001 - H[14C]O[18O]2- 1.430e-21 1.308e-21 -20.845 -20.883 -0.039 - H[14C][18O]2O- 1.430e-21 1.308e-21 -20.845 -20.883 -0.039 - H[14C][18O]O[18O]- 1.430e-21 1.308e-21 -20.845 -20.883 -0.039 - [14C]O2[18O]-2 1.276e-21 8.942e-22 -20.894 -21.049 -0.154 -[18O](-2) 1.109e-01 - H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 - HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 - CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 - CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 - CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 -[18O](0) 2.846e-15 - O[18O] 2.840e-15 2.845e-15 -14.547 -14.546 0.001 - [18O]2 2.834e-18 2.838e-18 -17.548 -17.547 0.001 + H3O+ 1.112e-07 1.027e-07 -6.954 -6.988 -0.034 (0) + OH- 1.063e-07 9.709e-08 -6.974 -7.013 -0.039 (0) + H2O 5.556e+01 9.980e-01 1.745 -0.001 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -126.479 -126.479 0.001 (0) +C(4) 5.840e-03 + HCO3- 4.703e-03 4.303e-03 -2.328 -2.366 -0.039 (0) + CO2 9.961e-04 9.978e-04 -3.002 -3.001 0.001 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CO3-2 2.799e-06 1.962e-06 -5.553 -5.707 -0.154 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) + HCO[18O]2- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]2O- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + HC[18O]O[18O]- 1.872e-08 1.713e-08 -7.728 -7.766 -0.039 (0) + CO2[18O]-2 1.675e-08 1.174e-08 -7.776 -7.930 -0.154 (0) +Ca 2.451e-03 + Ca+2 2.344e-03 1.660e-03 -2.630 -2.780 -0.150 (0) + CaHCO3+ 9.934e-05 9.114e-05 -4.003 -4.040 -0.037 (0) + CaCO3 5.461e-06 5.470e-06 -5.263 -5.262 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + Ca[13C]O3 6.088e-08 6.099e-08 -7.215 -7.215 0.001 (0) + CaCO2[18O] 3.268e-08 3.274e-08 -7.486 -7.485 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.118 -40.117 0.001 (0) +O(0) 1.429e-12 + O2 7.118e-13 7.130e-13 -12.148 -12.147 0.001 (0) + O[18O] 2.840e-15 2.845e-15 -14.547 -14.546 0.001 (0) +[13C](-4) 0.000e+00 + [13C]H4 0.000e+00 0.000e+00 -128.435 -128.434 0.001 (0) +[13C](4) 6.511e-05 + H[13C]O3- 5.251e-05 4.805e-05 -4.280 -4.318 -0.039 (0) + [13C]O2 1.103e-05 1.104e-05 -4.958 -4.957 0.001 (0) + CaH[13C]O3+ 1.109e-06 1.018e-06 -5.955 -5.992 -0.037 (0) + H[13C]O2[18O]- 1.048e-07 9.587e-08 -6.980 -7.018 -0.039 (0) + H[13C]O[18O]O- 1.048e-07 9.587e-08 -6.980 -7.018 -0.039 (0) + H[13C][18O]O2- 1.048e-07 9.587e-08 -6.980 -7.018 -0.039 (0) + Ca[13C]O3 6.088e-08 6.099e-08 -7.215 -7.215 0.001 (0) + [13C]O[18O] 4.585e-08 4.593e-08 -7.339 -7.338 0.001 (0) + [13C]O3-2 3.121e-08 2.187e-08 -7.506 -7.660 -0.154 (0) + CaH[13C]O2[18O]+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C]O[18O]O+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + CaH[13C][18O]O2+ 2.213e-09 2.030e-09 -8.655 -8.692 -0.037 (0) + Ca[13C]O2[18O] 3.644e-10 3.650e-10 -9.438 -9.438 0.001 (0) + H[13C]O[18O]2- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]2O- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + H[13C][18O]O[18O]- 2.090e-10 1.913e-10 -9.680 -9.718 -0.039 (0) + [13C]O2[18O]-2 1.868e-10 1.309e-10 -9.729 -9.883 -0.154 (0) +[14C](-4) 0.000e+00 + [14C]H4 0.000e+00 0.000e+00 -139.604 -139.603 0.001 (0) +[14C](4) 4.447e-16 + H[14C]O3- 3.592e-16 3.286e-16 -15.445 -15.483 -0.039 (0) + [14C]O2 7.477e-17 7.489e-17 -16.126 -16.126 0.001 (0) + CaH[14C]O3+ 7.587e-18 6.961e-18 -17.120 -17.157 -0.037 (0) + H[14C]O2[18O]- 7.166e-19 6.557e-19 -18.145 -18.183 -0.039 (0) + H[14C]O[18O]O- 7.166e-19 6.557e-19 -18.145 -18.183 -0.039 (0) + H[14C][18O]O2- 7.166e-19 6.557e-19 -18.145 -18.183 -0.039 (0) + Ca[14C]O3 4.158e-19 4.165e-19 -18.381 -18.380 0.001 (0) + [14C]O[18O] 3.109e-19 3.114e-19 -18.507 -18.507 0.001 (0) + [14C]O3-2 2.131e-19 1.494e-19 -18.671 -18.826 -0.154 (0) + CaH[14C]O2[18O]+ 1.514e-20 1.389e-20 -19.820 -19.857 -0.037 (0) + CaH[14C]O[18O]O+ 1.514e-20 1.389e-20 -19.820 -19.857 -0.037 (0) + CaH[14C][18O]O2+ 1.514e-20 1.389e-20 -19.820 -19.857 -0.037 (0) + Ca[14C]O2[18O] 2.489e-21 2.493e-21 -20.604 -20.603 0.001 (0) + H[14C]O[18O]2- 1.430e-21 1.308e-21 -20.845 -20.883 -0.039 (0) + H[14C][18O]2O- 1.430e-21 1.308e-21 -20.845 -20.883 -0.039 (0) + H[14C][18O]O[18O]- 1.430e-21 1.308e-21 -20.845 -20.883 -0.039 (0) + [14C]O2[18O]-2 1.276e-21 8.942e-22 -20.894 -21.049 -0.154 (0) +[18O](-2) 1.109e-01 + H2[18O] 1.108e-01 1.991e-03 -0.955 -2.701 -1.746 (0) + HCO2[18O]- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HCO[18O]O- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + HC[18O]O2- 9.383e-06 8.585e-06 -5.028 -5.066 -0.039 (0) + CO[18O] 4.142e-06 4.149e-06 -5.383 -5.382 0.001 (0) + CaHCO2[18O]+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHCO[18O]O+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) + CaHC[18O]O2+ 1.982e-07 1.818e-07 -6.703 -6.740 -0.037 (0) +[18O](0) 2.846e-15 + O[18O] 2.840e-15 2.845e-15 -14.547 -14.546 0.001 (0) + [18O]2 2.834e-18 2.838e-18 -17.548 -17.547 0.001 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex21_radial.out b/ex21_radial.out index d52503c4..7d41fbd4 100644 --- a/ex21_radial.out +++ b/ex21_radial.out @@ -122,21 +122,21 @@ Initial solution 0. column with only cell 1, two boundary solutions 0 and 2. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 - H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Cl 1.000e-03 - Cl- 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 -H(0) 1.416e-25 - H2 7.078e-26 7.079e-26 -25.150 -25.150 0.000 -Na 1.000e-03 - Na+ 1.000e-03 9.652e-04 -3.000 -3.015 -0.015 - NaOH 6.375e-11 6.377e-11 -10.196 -10.195 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 + OH- 1.038e-07 1.001e-07 -6.984 -7.000 -0.016 (0) + H+ 1.034e-07 1.000e-07 -6.985 -7.000 -0.015 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Cl 1.000e-03 + Cl- 1.000e-03 9.649e-04 -3.000 -3.016 -0.016 17.82 +H(0) 1.416e-25 + H2 7.078e-26 7.079e-26 -25.150 -25.150 0.000 (0) +Na 1.000e-03 + Na+ 1.000e-03 9.652e-04 -3.000 -3.015 -0.015 -1.21 + NaOH 6.375e-11 6.377e-11 -10.196 -10.195 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -453,70 +453,70 @@ WARNING: USER_PUNCH: Headings count doesn't match number of calls to PUNCH. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 5.138e-07 3.386e-07 -6.289 -6.470 -0.181 - H+ 3.237e-08 2.512e-08 -7.490 -7.600 -0.110 - H2O 5.551e+01 9.899e-01 1.744 -0.004 0.000 -C(4) 4.788e-04 - HCO3- 3.789e-04 2.694e-04 -3.421 -3.570 -0.148 - CaHCO3+ 3.068e-05 2.182e-05 -4.513 -4.661 -0.148 - NaHCO3 2.379e-05 2.588e-05 -4.624 -4.587 0.037 - MgHCO3+ 1.977e-05 1.447e-05 -4.704 -4.840 -0.136 - CO2 1.450e-05 1.577e-05 -4.839 -4.802 0.037 - CaCO3 4.698e-06 5.110e-06 -5.328 -5.292 0.037 - MgCO3 1.900e-06 2.067e-06 -5.721 -5.685 0.037 - NaCO3- 1.895e-06 1.387e-06 -5.722 -5.858 -0.136 - CO3-2 1.889e-06 4.825e-07 -5.724 -6.316 -0.593 - SrHCO3+ 6.950e-07 4.941e-07 -6.158 -6.306 -0.148 - SrCO3 3.428e-08 3.729e-08 -7.465 -7.428 0.037 -Ca 2.580e-02 - Ca+2 2.357e-02 6.553e-03 -1.628 -2.184 -0.556 - CaSO4 2.192e-03 2.384e-03 -2.659 -2.623 0.037 - CaHCO3+ 3.068e-05 2.182e-05 -4.513 -4.661 -0.148 - CaCO3 4.698e-06 5.110e-06 -5.328 -5.292 0.037 - CaOH+ 5.856e-08 4.286e-08 -7.232 -7.368 -0.136 - CaHSO4+ 4.678e-10 3.423e-10 -9.330 -9.466 -0.136 -Cl 3.000e-01 - Cl- 3.000e-01 2.002e-01 -0.523 -0.699 -0.176 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.617 -44.580 0.037 -Hto 1.140e-06 - Hto 1.140e-06 1.140e-06 -5.943 -5.943 0.000 -K 1.610e-03 - K+ 1.592e-03 1.062e-03 -2.798 -2.974 -0.176 - KSO4- 1.830e-05 1.339e-05 -4.738 -4.873 -0.136 - KOH 1.334e-10 1.452e-10 -9.875 -9.838 0.037 -Mg 1.690e-02 - Mg+2 1.512e-02 4.629e-03 -1.821 -2.335 -0.514 - MgSO4 1.760e-03 1.914e-03 -2.754 -2.718 0.037 - MgHCO3+ 1.977e-05 1.447e-05 -4.704 -4.840 -0.136 - MgCO3 1.900e-06 2.067e-06 -5.721 -5.685 0.037 - MgOH+ 7.546e-07 5.522e-07 -6.122 -6.258 -0.136 -Na 2.400e-01 - Na+ 2.378e-01 1.708e-01 -0.624 -0.767 -0.144 - NaSO4- 2.146e-03 1.571e-03 -2.668 -2.804 -0.136 - NaHCO3 2.379e-05 2.588e-05 -4.624 -4.587 0.037 - NaCO3- 1.895e-06 1.387e-06 -5.722 -5.858 -0.136 - NaOH 4.089e-08 4.448e-08 -7.388 -7.352 0.037 -O(0) 2.437e-04 - O2 1.219e-04 1.325e-04 -3.914 -3.878 0.037 -S(6) 1.410e-02 - SO4-2 7.942e-03 1.858e-03 -2.100 -2.731 -0.631 - CaSO4 2.192e-03 2.384e-03 -2.659 -2.623 0.037 - NaSO4- 2.146e-03 1.571e-03 -2.668 -2.804 -0.136 - MgSO4 1.760e-03 1.914e-03 -2.754 -2.718 0.037 - SrSO4 4.177e-05 4.543e-05 -4.379 -4.343 0.037 - KSO4- 1.830e-05 1.339e-05 -4.738 -4.873 -0.136 - HSO4- 5.938e-09 4.346e-09 -8.226 -8.362 -0.136 - CaHSO4+ 4.678e-10 3.423e-10 -9.330 -9.466 -0.136 -Sr 5.050e-04 - Sr+2 4.625e-04 1.284e-04 -3.335 -3.891 -0.557 - SrSO4 4.177e-05 4.543e-05 -4.379 -4.343 0.037 - SrHCO3+ 6.950e-07 4.941e-07 -6.158 -6.306 -0.148 - SrCO3 3.428e-08 3.729e-08 -7.465 -7.428 0.037 - SrOH+ 3.701e-10 2.595e-10 -9.432 -9.586 -0.154 + OH- 5.138e-07 3.386e-07 -6.289 -6.470 -0.181 (0) + H+ 3.237e-08 2.512e-08 -7.490 -7.600 -0.110 0.00 + H2O 5.551e+01 9.899e-01 1.744 -0.004 0.000 18.06 +C(4) 4.788e-04 + HCO3- 3.789e-04 2.694e-04 -3.421 -3.570 -0.148 24.15 + CaHCO3+ 3.068e-05 2.182e-05 -4.513 -4.661 -0.148 (0) + NaHCO3 2.379e-05 2.588e-05 -4.624 -4.587 0.037 (0) + MgHCO3+ 1.977e-05 1.447e-05 -4.704 -4.840 -0.136 (0) + CO2 1.450e-05 1.577e-05 -4.839 -4.802 0.037 (0) + CaCO3 4.698e-06 5.110e-06 -5.328 -5.292 0.037 (0) + MgCO3 1.900e-06 2.067e-06 -5.721 -5.685 0.037 (0) + NaCO3- 1.895e-06 1.387e-06 -5.722 -5.858 -0.136 (0) + CO3-2 1.889e-06 4.825e-07 -5.724 -6.316 -0.593 -3.93 + SrHCO3+ 6.950e-07 4.941e-07 -6.158 -6.306 -0.148 (0) + SrCO3 3.428e-08 3.729e-08 -7.465 -7.428 0.037 (0) +Ca 2.580e-02 + Ca+2 2.357e-02 6.553e-03 -1.628 -2.184 -0.556 -17.86 + CaSO4 2.192e-03 2.384e-03 -2.659 -2.623 0.037 (0) + CaHCO3+ 3.068e-05 2.182e-05 -4.513 -4.661 -0.148 (0) + CaCO3 4.698e-06 5.110e-06 -5.328 -5.292 0.037 (0) + CaOH+ 5.856e-08 4.286e-08 -7.232 -7.368 -0.136 (0) + CaHSO4+ 4.678e-10 3.423e-10 -9.330 -9.466 -0.136 (0) +Cl 3.000e-01 + Cl- 3.000e-01 2.002e-01 -0.523 -0.699 -0.176 17.78 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.617 -44.580 0.037 (0) +Hto 1.140e-06 + Hto 1.140e-06 1.140e-06 -5.943 -5.943 0.000 (0) +K 1.610e-03 + K+ 1.592e-03 1.062e-03 -2.798 -2.974 -0.176 8.94 + KSO4- 1.830e-05 1.339e-05 -4.738 -4.873 -0.136 (0) + KOH 1.334e-10 1.452e-10 -9.875 -9.838 0.037 (0) +Mg 1.690e-02 + Mg+2 1.512e-02 4.629e-03 -1.821 -2.335 -0.514 -21.11 + MgSO4 1.760e-03 1.914e-03 -2.754 -2.718 0.037 (0) + MgHCO3+ 1.977e-05 1.447e-05 -4.704 -4.840 -0.136 (0) + MgCO3 1.900e-06 2.067e-06 -5.721 -5.685 0.037 (0) + MgOH+ 7.546e-07 5.522e-07 -6.122 -6.258 -0.136 (0) +Na 2.400e-01 + Na+ 2.378e-01 1.708e-01 -0.624 -0.767 -0.144 -1.34 + NaSO4- 2.146e-03 1.571e-03 -2.668 -2.804 -0.136 (0) + NaHCO3 2.379e-05 2.588e-05 -4.624 -4.587 0.037 (0) + NaCO3- 1.895e-06 1.387e-06 -5.722 -5.858 -0.136 (0) + NaOH 4.089e-08 4.448e-08 -7.388 -7.352 0.037 (0) +O(0) 2.437e-04 + O2 1.219e-04 1.325e-04 -3.914 -3.878 0.037 (0) +S(6) 1.410e-02 + SO4-2 7.942e-03 1.858e-03 -2.100 -2.731 -0.631 13.84 + CaSO4 2.192e-03 2.384e-03 -2.659 -2.623 0.037 (0) + NaSO4- 2.146e-03 1.571e-03 -2.668 -2.804 -0.136 (0) + MgSO4 1.760e-03 1.914e-03 -2.754 -2.718 0.037 (0) + SrSO4 4.177e-05 4.543e-05 -4.379 -4.343 0.037 (0) + KSO4- 1.830e-05 1.339e-05 -4.738 -4.873 -0.136 (0) + HSO4- 5.938e-09 4.346e-09 -8.226 -8.362 -0.136 (0) + CaHSO4+ 4.678e-10 3.423e-10 -9.330 -9.466 -0.136 (0) +Sr 5.050e-04 + Sr+2 4.625e-04 1.284e-04 -3.335 -3.891 -0.557 -18.51 + SrSO4 4.177e-05 4.543e-05 -4.379 -4.343 0.037 (0) + SrHCO3+ 6.950e-07 4.941e-07 -6.158 -6.306 -0.148 (0) + SrCO3 3.428e-08 3.729e-08 -7.465 -7.428 0.037 (0) + SrOH+ 3.701e-10 2.595e-10 -9.432 -9.586 -0.154 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex3.out b/ex3.out index 207a87f6..01e64343 100644 --- a/ex3.out +++ b/ex3.out @@ -67,16 +67,16 @@ Initial solution 1. Pure water ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.002e-07 1.001e-07 -6.999 -6.999 -0.000 - H+ 1.001e-07 1.000e-07 -7.000 -7.000 -0.000 - H2O 5.551e+01 1.000e+00 1.744 0.000 0.000 -H(0) 1.416e-25 - H2 7.079e-26 7.079e-26 -25.150 -25.150 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 + OH- 1.002e-07 1.001e-07 -6.999 -6.999 -0.000 (0) + H+ 1.001e-07 1.000e-07 -7.000 -7.000 -0.000 0.00 + H2O 5.551e+01 1.000e+00 1.744 0.000 0.000 18.07 +H(0) 1.416e-25 + H2 7.079e-26 7.079e-26 -25.150 -25.150 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -131,29 +131,29 @@ Calcite 0.00 -8.48 -8.48 1.000e+01 9.998e+00 -1.646e-03 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.137e-07 1.982e-07 -6.670 -6.703 -0.033 - H+ 5.403e-08 5.050e-08 -7.267 -7.297 -0.029 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -C(-4) 6.287e-25 - CH4 6.287e-25 6.294e-25 -24.202 -24.201 0.000 -C(4) 3.622e-03 - HCO3- 3.224e-03 2.998e-03 -2.492 -2.523 -0.032 - CO2 3.401e-04 3.405e-04 -3.468 -3.468 0.000 - CaHCO3+ 4.894e-05 4.551e-05 -4.310 -4.342 -0.032 - CaCO3 5.559e-06 5.565e-06 -5.255 -5.255 0.000 - CO3-2 3.721e-06 2.784e-06 -5.429 -5.555 -0.126 -Ca 1.646e-03 - Ca+2 1.591e-03 1.190e-03 -2.798 -2.925 -0.126 - CaHCO3+ 4.894e-05 4.551e-05 -4.310 -4.342 -0.032 - CaCO3 5.559e-06 5.565e-06 -5.255 -5.255 0.000 - CaOH+ 4.212e-09 3.910e-09 -8.376 -8.408 -0.032 -H(0) 7.408e-15 - H2 3.704e-15 3.708e-15 -14.431 -14.431 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -63.519 -63.518 0.000 + OH- 2.137e-07 1.982e-07 -6.670 -6.703 -0.033 (0) + H+ 5.403e-08 5.050e-08 -7.267 -7.297 -0.029 0.00 + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +C(-4) 6.287e-25 + CH4 6.287e-25 6.294e-25 -24.202 -24.201 0.000 (0) +C(4) 3.622e-03 + HCO3- 3.224e-03 2.998e-03 -2.492 -2.523 -0.032 24.29 + CO2 3.401e-04 3.405e-04 -3.468 -3.468 0.000 (0) + CaHCO3+ 4.894e-05 4.551e-05 -4.310 -4.342 -0.032 (0) + CaCO3 5.559e-06 5.565e-06 -5.255 -5.255 0.000 (0) + CO3-2 3.721e-06 2.784e-06 -5.429 -5.555 -0.126 -3.78 +Ca 1.646e-03 + Ca+2 1.591e-03 1.190e-03 -2.798 -2.925 -0.126 -17.83 + CaHCO3+ 4.894e-05 4.551e-05 -4.310 -4.342 -0.032 (0) + CaCO3 5.559e-06 5.565e-06 -5.255 -5.255 0.000 (0) + CaOH+ 4.212e-09 3.910e-09 -8.376 -8.408 -0.032 (0) +H(0) 7.408e-15 + H2 3.704e-15 3.708e-15 -14.431 -14.431 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -63.519 -63.518 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -237,63 +237,63 @@ Initial solution 2. Seawater ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.674e-06 1.629e-06 -5.573 -5.788 -0.215 - H+ 7.981e-09 6.026e-09 -8.098 -8.220 -0.122 - H2O 5.551e+01 9.806e-01 1.744 -0.009 0.000 -C(4) 2.180e-03 - HCO3- 1.514e-03 1.023e-03 -2.820 -2.990 -0.170 - MgHCO3+ 2.196e-04 1.640e-04 -3.658 -3.785 -0.127 - NaHCO3 1.668e-04 1.948e-04 -3.778 -3.710 0.067 - MgCO3 8.914e-05 1.041e-04 -4.050 -3.982 0.067 - NaCO3- 6.719e-05 5.020e-05 -4.173 -4.299 -0.127 - CaHCO3+ 4.598e-05 3.106e-05 -4.337 -4.508 -0.170 - CO3-2 3.821e-05 7.960e-06 -4.418 -5.099 -0.681 - CaCO3 2.725e-05 3.183e-05 -4.565 -4.497 0.067 - CO2 1.210e-05 1.413e-05 -4.917 -4.850 0.067 -Ca 1.066e-02 - Ca+2 9.504e-03 2.380e-03 -2.022 -2.623 -0.601 - CaSO4 1.083e-03 1.266e-03 -2.965 -2.898 0.067 - CaHCO3+ 4.598e-05 3.106e-05 -4.337 -4.508 -0.170 - CaCO3 2.725e-05 3.183e-05 -4.565 -4.497 0.067 - CaOH+ 8.604e-08 6.429e-08 -7.065 -7.192 -0.127 - CaHSO4+ 5.979e-11 4.467e-11 -10.223 -10.350 -0.127 -Cl 5.657e-01 - Cl- 5.657e-01 3.528e-01 -0.247 -0.452 -0.205 -H(0) 5.515e-37 - H2 2.757e-37 3.221e-37 -36.559 -36.492 0.067 -K 1.058e-02 - K+ 1.041e-02 6.495e-03 -1.982 -2.187 -0.205 - KSO4- 1.627e-04 1.216e-04 -3.789 -3.915 -0.127 - KOH 3.137e-09 3.665e-09 -8.503 -8.436 0.067 -Mg 5.507e-02 - Mg+2 4.742e-02 1.371e-02 -1.324 -1.863 -0.539 - MgSO4 7.330e-03 8.562e-03 -2.135 -2.067 0.067 - MgHCO3+ 2.196e-04 1.640e-04 -3.658 -3.785 -0.127 - MgCO3 8.914e-05 1.041e-04 -4.050 -3.982 0.067 - MgOH+ 1.084e-05 8.100e-06 -4.965 -5.092 -0.127 -Na 4.854e-01 - Na+ 4.791e-01 3.387e-01 -0.320 -0.470 -0.151 - NaSO4- 6.053e-03 4.523e-03 -2.218 -2.345 -0.127 - NaHCO3 1.668e-04 1.948e-04 -3.778 -3.710 0.067 - NaCO3- 6.719e-05 5.020e-05 -4.173 -4.299 -0.127 - NaOH 3.117e-07 3.641e-07 -6.506 -6.439 0.067 -O(0) 6.614e-20 - O2 3.307e-20 3.863e-20 -19.481 -19.413 0.067 -S(6) 2.926e-02 - SO4-2 1.463e-02 2.664e-03 -1.835 -2.574 -0.740 - MgSO4 7.330e-03 8.562e-03 -2.135 -2.067 0.067 - NaSO4- 6.053e-03 4.523e-03 -2.218 -2.345 -0.127 - CaSO4 1.083e-03 1.266e-03 -2.965 -2.898 0.067 - KSO4- 1.627e-04 1.216e-04 -3.789 -3.915 -0.127 - HSO4- 2.089e-09 1.561e-09 -8.680 -8.807 -0.127 - CaHSO4+ 5.979e-11 4.467e-11 -10.223 -10.350 -0.127 -Si 7.382e-05 - H4SiO4 7.110e-05 8.306e-05 -4.148 -4.081 0.067 - H3SiO4- 2.720e-06 2.032e-06 -5.565 -5.692 -0.127 - H2SiO4-2 7.362e-11 2.294e-11 -10.133 -10.639 -0.506 + OH- 2.674e-06 1.629e-06 -5.573 -5.788 -0.215 (0) + H+ 7.981e-09 6.026e-09 -8.098 -8.220 -0.122 0.00 + H2O 5.551e+01 9.806e-01 1.744 -0.009 0.000 18.07 +C(4) 2.180e-03 + HCO3- 1.514e-03 1.023e-03 -2.820 -2.990 -0.170 24.32 + MgHCO3+ 2.196e-04 1.640e-04 -3.658 -3.785 -0.127 (0) + NaHCO3 1.668e-04 1.948e-04 -3.778 -3.710 0.067 (0) + MgCO3 8.914e-05 1.041e-04 -4.050 -3.982 0.067 (0) + NaCO3- 6.719e-05 5.020e-05 -4.173 -4.299 -0.127 (0) + CaHCO3+ 4.598e-05 3.106e-05 -4.337 -4.508 -0.170 (0) + CO3-2 3.821e-05 7.960e-06 -4.418 -5.099 -0.681 -3.65 + CaCO3 2.725e-05 3.183e-05 -4.565 -4.497 0.067 (0) + CO2 1.210e-05 1.413e-05 -4.917 -4.850 0.067 (0) +Ca 1.066e-02 + Ca+2 9.504e-03 2.380e-03 -2.022 -2.623 -0.601 -17.70 + CaSO4 1.083e-03 1.266e-03 -2.965 -2.898 0.067 (0) + CaHCO3+ 4.598e-05 3.106e-05 -4.337 -4.508 -0.170 (0) + CaCO3 2.725e-05 3.183e-05 -4.565 -4.497 0.067 (0) + CaOH+ 8.604e-08 6.429e-08 -7.065 -7.192 -0.127 (0) + CaHSO4+ 5.979e-11 4.467e-11 -10.223 -10.350 -0.127 (0) +Cl 5.657e-01 + Cl- 5.657e-01 3.528e-01 -0.247 -0.452 -0.205 17.85 +H(0) 5.515e-37 + H2 2.757e-37 3.221e-37 -36.559 -36.492 0.067 (0) +K 1.058e-02 + K+ 1.041e-02 6.495e-03 -1.982 -2.187 -0.205 9.06 + KSO4- 1.627e-04 1.216e-04 -3.789 -3.915 -0.127 (0) + KOH 3.137e-09 3.665e-09 -8.503 -8.436 0.067 (0) +Mg 5.507e-02 + Mg+2 4.742e-02 1.371e-02 -1.324 -1.863 -0.539 -21.02 + MgSO4 7.330e-03 8.562e-03 -2.135 -2.067 0.067 (0) + MgHCO3+ 2.196e-04 1.640e-04 -3.658 -3.785 -0.127 (0) + MgCO3 8.914e-05 1.041e-04 -4.050 -3.982 0.067 (0) + MgOH+ 1.084e-05 8.100e-06 -4.965 -5.092 -0.127 (0) +Na 4.854e-01 + Na+ 4.791e-01 3.387e-01 -0.320 -0.470 -0.151 -1.18 + NaSO4- 6.053e-03 4.523e-03 -2.218 -2.345 -0.127 (0) + NaHCO3 1.668e-04 1.948e-04 -3.778 -3.710 0.067 (0) + NaCO3- 6.719e-05 5.020e-05 -4.173 -4.299 -0.127 (0) + NaOH 3.117e-07 3.641e-07 -6.506 -6.439 0.067 (0) +O(0) 6.614e-20 + O2 3.307e-20 3.863e-20 -19.481 -19.413 0.067 (0) +S(6) 2.926e-02 + SO4-2 1.463e-02 2.664e-03 -1.835 -2.574 -0.740 14.11 + MgSO4 7.330e-03 8.562e-03 -2.135 -2.067 0.067 (0) + NaSO4- 6.053e-03 4.523e-03 -2.218 -2.345 -0.127 (0) + CaSO4 1.083e-03 1.266e-03 -2.965 -2.898 0.067 (0) + KSO4- 1.627e-04 1.216e-04 -3.789 -3.915 -0.127 (0) + HSO4- 2.089e-09 1.561e-09 -8.680 -8.807 -0.127 (0) + CaHSO4+ 5.979e-11 4.467e-11 -10.223 -10.350 -0.127 (0) +Si 7.382e-05 + H4SiO4 7.110e-05 8.306e-05 -4.148 -4.081 0.067 56.00 + H3SiO4- 2.720e-06 2.032e-06 -5.565 -5.692 -0.127 (0) + H2SiO4-2 7.362e-11 2.294e-11 -10.133 -10.639 -0.506 (0) ------------------------------Saturation indices------------------------------- @@ -384,69 +384,69 @@ Mixture 1. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 3.170e-07 2.231e-07 -6.499 -6.651 -0.153 - H+ 5.603e-08 4.460e-08 -7.252 -7.351 -0.099 - H2O 5.551e+01 9.941e-01 1.744 -0.003 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -121.550 -121.529 0.021 -C(4) 3.189e-03 - HCO3- 2.662e-03 1.980e-03 -2.575 -2.703 -0.129 - CO2 1.904e-04 1.998e-04 -3.720 -3.699 0.021 - MgHCO3+ 1.545e-04 1.151e-04 -3.811 -3.939 -0.128 - NaHCO3 1.137e-04 1.192e-04 -3.944 -3.924 0.021 - CaHCO3+ 4.245e-05 3.158e-05 -4.372 -4.501 -0.129 - MgCO3 9.408e-06 9.871e-06 -5.027 -5.006 0.021 - CO3-2 6.803e-06 2.082e-06 -5.167 -5.682 -0.514 - NaCO3- 5.572e-06 4.151e-06 -5.254 -5.382 -0.128 - CaCO3 4.166e-06 4.371e-06 -5.380 -5.359 0.021 -Ca 4.350e-03 - Ca+2 3.928e-03 1.250e-03 -2.406 -2.903 -0.497 - CaSO4 3.753e-04 3.938e-04 -3.426 -3.405 0.021 - CaHCO3+ 4.245e-05 3.158e-05 -4.372 -4.501 -0.129 - CaCO3 4.166e-06 4.371e-06 -5.380 -5.359 0.021 - CaOH+ 6.204e-09 4.622e-09 -8.207 -8.335 -0.128 - CaHSO4+ 1.381e-10 1.029e-10 -9.860 -9.988 -0.128 -Cl 1.697e-01 - Cl- 1.697e-01 1.203e-01 -0.770 -0.920 -0.149 -H(0) 3.749e-39 - H2 1.874e-39 1.967e-39 -38.727 -38.706 0.021 -K 3.173e-03 - K+ 3.140e-03 2.226e-03 -2.503 -2.652 -0.149 - KSO4- 3.316e-05 2.470e-05 -4.479 -4.607 -0.128 - KOH 1.639e-10 1.720e-10 -9.785 -9.764 0.021 -Mg 1.652e-02 - Mg+2 1.460e-02 4.968e-03 -1.836 -2.304 -0.468 - MgSO4 1.753e-03 1.839e-03 -2.756 -2.735 0.021 - MgHCO3+ 1.545e-04 1.151e-04 -3.811 -3.939 -0.128 - MgCO3 9.408e-06 9.871e-06 -5.027 -5.006 0.021 - MgOH+ 5.396e-07 4.020e-07 -6.268 -6.396 -0.128 -Na 1.456e-01 - Na+ 1.444e-01 1.071e-01 -0.841 -0.970 -0.130 - NaSO4- 1.138e-03 8.476e-04 -2.944 -3.072 -0.128 - NaHCO3 1.137e-04 1.192e-04 -3.944 -3.924 0.021 - NaCO3- 5.572e-06 4.151e-06 -5.254 -5.382 -0.128 - NaOH 1.503e-08 1.577e-08 -7.823 -7.802 0.021 -O(0) 2.031e-15 - O2 1.015e-15 1.065e-15 -14.993 -14.973 0.021 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -118.564 -118.717 -0.153 - H2S 0.000e+00 0.000e+00 -119.147 -119.126 0.021 - S-2 0.000e+00 0.000e+00 -123.753 -124.284 -0.532 -S(6) 8.777e-03 - SO4-2 5.478e-03 1.579e-03 -2.261 -2.802 -0.540 - MgSO4 1.753e-03 1.839e-03 -2.756 -2.735 0.021 - NaSO4- 1.138e-03 8.476e-04 -2.944 -3.072 -0.128 - CaSO4 3.753e-04 3.938e-04 -3.426 -3.405 0.021 - KSO4- 3.316e-05 2.470e-05 -4.479 -4.607 -0.128 - HSO4- 9.193e-09 6.849e-09 -8.037 -8.164 -0.128 - CaHSO4+ 1.381e-10 1.029e-10 -9.860 -9.988 -0.128 -Si 2.215e-05 - H4SiO4 2.204e-05 2.313e-05 -4.657 -4.636 0.021 - H3SiO4- 1.026e-07 7.646e-08 -6.989 -7.117 -0.128 - H2SiO4-2 3.784e-13 1.166e-13 -12.422 -12.933 -0.511 + OH- 3.170e-07 2.231e-07 -6.499 -6.651 -0.153 (0) + H+ 5.603e-08 4.460e-08 -7.252 -7.351 -0.099 0.00 + H2O 5.551e+01 9.941e-01 1.744 -0.003 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -121.550 -121.529 0.021 (0) +C(4) 3.189e-03 + HCO3- 2.662e-03 1.980e-03 -2.575 -2.703 -0.129 24.50 + CO2 1.904e-04 1.998e-04 -3.720 -3.699 0.021 (0) + MgHCO3+ 1.545e-04 1.151e-04 -3.811 -3.939 -0.128 (0) + NaHCO3 1.137e-04 1.192e-04 -3.944 -3.924 0.021 (0) + CaHCO3+ 4.245e-05 3.158e-05 -4.372 -4.501 -0.129 (0) + MgCO3 9.408e-06 9.871e-06 -5.027 -5.006 0.021 (0) + CO3-2 6.803e-06 2.082e-06 -5.167 -5.682 -0.514 -2.93 + NaCO3- 5.572e-06 4.151e-06 -5.254 -5.382 -0.128 (0) + CaCO3 4.166e-06 4.371e-06 -5.380 -5.359 0.021 (0) +Ca 4.350e-03 + Ca+2 3.928e-03 1.250e-03 -2.406 -2.903 -0.497 -16.98 + CaSO4 3.753e-04 3.938e-04 -3.426 -3.405 0.021 (0) + CaHCO3+ 4.245e-05 3.158e-05 -4.372 -4.501 -0.129 (0) + CaCO3 4.166e-06 4.371e-06 -5.380 -5.359 0.021 (0) + CaOH+ 6.204e-09 4.622e-09 -8.207 -8.335 -0.128 (0) + CaHSO4+ 1.381e-10 1.029e-10 -9.860 -9.988 -0.128 (0) +Cl 1.697e-01 + Cl- 1.697e-01 1.203e-01 -0.770 -0.920 -0.149 18.03 +H(0) 3.749e-39 + H2 1.874e-39 1.967e-39 -38.727 -38.706 0.021 (0) +K 3.173e-03 + K+ 3.140e-03 2.226e-03 -2.503 -2.652 -0.149 9.24 + KSO4- 3.316e-05 2.470e-05 -4.479 -4.607 -0.128 (0) + KOH 1.639e-10 1.720e-10 -9.785 -9.764 0.021 (0) +Mg 1.652e-02 + Mg+2 1.460e-02 4.968e-03 -1.836 -2.304 -0.468 -20.30 + MgSO4 1.753e-03 1.839e-03 -2.756 -2.735 0.021 (0) + MgHCO3+ 1.545e-04 1.151e-04 -3.811 -3.939 -0.128 (0) + MgCO3 9.408e-06 9.871e-06 -5.027 -5.006 0.021 (0) + MgOH+ 5.396e-07 4.020e-07 -6.268 -6.396 -0.128 (0) +Na 1.456e-01 + Na+ 1.444e-01 1.071e-01 -0.841 -0.970 -0.130 -1.00 + NaSO4- 1.138e-03 8.476e-04 -2.944 -3.072 -0.128 (0) + NaHCO3 1.137e-04 1.192e-04 -3.944 -3.924 0.021 (0) + NaCO3- 5.572e-06 4.151e-06 -5.254 -5.382 -0.128 (0) + NaOH 1.503e-08 1.577e-08 -7.823 -7.802 0.021 (0) +O(0) 2.031e-15 + O2 1.015e-15 1.065e-15 -14.993 -14.973 0.021 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -118.564 -118.717 -0.153 (0) + H2S 0.000e+00 0.000e+00 -119.147 -119.126 0.021 (0) + S-2 0.000e+00 0.000e+00 -123.753 -124.284 -0.532 (0) +S(6) 8.777e-03 + SO4-2 5.478e-03 1.579e-03 -2.261 -2.802 -0.540 14.83 + MgSO4 1.753e-03 1.839e-03 -2.756 -2.735 0.021 (0) + NaSO4- 1.138e-03 8.476e-04 -2.944 -3.072 -0.128 (0) + CaSO4 3.753e-04 3.938e-04 -3.426 -3.405 0.021 (0) + KSO4- 3.316e-05 2.470e-05 -4.479 -4.607 -0.128 (0) + HSO4- 9.193e-09 6.849e-09 -8.037 -8.164 -0.128 (0) + CaHSO4+ 1.381e-10 1.029e-10 -9.860 -9.988 -0.128 (0) +Si 2.215e-05 + H4SiO4 2.204e-05 2.313e-05 -4.657 -4.636 0.021 56.00 + H3SiO4- 1.026e-07 7.646e-08 -6.989 -7.117 -0.128 (0) + H2SiO4-2 3.784e-13 1.166e-13 -12.422 -12.933 -0.511 (0) ------------------------------Saturation indices------------------------------- @@ -544,69 +544,69 @@ Dolomite 0.00 -17.09 -17.09 1.000e+01 1.001e+01 7.935e-03 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.609e-07 1.132e-07 -6.793 -6.946 -0.153 - H+ 1.104e-07 8.788e-08 -6.957 -7.056 -0.099 - H2O 5.551e+01 9.941e-01 1.744 -0.003 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -121.312 -121.291 0.021 -C(4) 3.029e-03 - HCO3- 2.397e-03 1.783e-03 -2.620 -2.749 -0.129 - CO2 3.377e-04 3.543e-04 -3.471 -3.451 0.021 - CaHCO3+ 1.065e-04 7.920e-05 -3.973 -4.101 -0.129 - NaHCO3 1.023e-04 1.073e-04 -3.990 -3.969 0.021 - MgHCO3+ 7.221e-05 5.380e-05 -4.141 -4.269 -0.128 - CaCO3 5.304e-06 5.565e-06 -5.275 -5.255 0.021 - CO3-2 3.109e-06 9.513e-07 -5.507 -6.022 -0.514 - NaCO3- 2.546e-06 1.897e-06 -5.594 -5.722 -0.128 - MgCO3 2.232e-06 2.341e-06 -5.651 -5.631 0.021 -Ca 1.213e-02 - Ca+2 1.095e-02 3.482e-03 -1.961 -2.458 -0.497 - CaSO4 1.067e-03 1.119e-03 -2.972 -2.951 0.021 - CaHCO3+ 1.065e-04 7.920e-05 -3.973 -4.101 -0.129 - CaCO3 5.304e-06 5.565e-06 -5.275 -5.255 0.021 - CaOH+ 8.774e-09 6.537e-09 -8.057 -8.185 -0.128 - CaHSO4+ 7.734e-10 5.762e-10 -9.112 -9.239 -0.128 -Cl 1.697e-01 - Cl- 1.697e-01 1.203e-01 -0.770 -0.920 -0.149 -H(0) 3.726e-39 - H2 1.863e-39 1.955e-39 -38.730 -38.709 0.021 -K 3.173e-03 - K+ 3.140e-03 2.225e-03 -2.503 -2.653 -0.149 - KSO4- 3.381e-05 2.519e-05 -4.471 -4.599 -0.128 - KOH 8.319e-11 8.729e-11 -10.080 -10.059 0.021 -Mg 8.585e-03 - Mg+2 7.582e-03 2.579e-03 -2.120 -2.588 -0.468 - MgSO4 9.283e-04 9.740e-04 -3.032 -3.011 0.021 - MgHCO3+ 7.221e-05 5.380e-05 -4.141 -4.269 -0.128 - MgCO3 2.232e-06 2.341e-06 -5.651 -5.631 0.021 - MgOH+ 1.422e-07 1.059e-07 -6.847 -6.975 -0.128 -Na 1.456e-01 - Na+ 1.444e-01 1.071e-01 -0.841 -0.970 -0.130 - NaSO4- 1.160e-03 8.644e-04 -2.935 -3.063 -0.128 - NaHCO3 1.023e-04 1.073e-04 -3.990 -3.969 0.021 - NaCO3- 2.546e-06 1.897e-06 -5.594 -5.722 -0.128 - NaOH 7.627e-09 8.002e-09 -8.118 -8.097 0.021 -O(0) 2.055e-15 - O2 1.027e-15 1.078e-15 -14.988 -14.967 0.021 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -118.272 -118.424 -0.153 - H2S 0.000e+00 0.000e+00 -118.560 -118.539 0.021 - S-2 0.000e+00 0.000e+00 -123.754 -124.286 -0.532 -S(6) 8.777e-03 - SO4-2 5.588e-03 1.611e-03 -2.253 -2.793 -0.540 - NaSO4- 1.160e-03 8.644e-04 -2.935 -3.063 -0.128 - CaSO4 1.067e-03 1.119e-03 -2.972 -2.951 0.021 - MgSO4 9.283e-04 9.740e-04 -3.032 -3.011 0.021 - KSO4- 3.381e-05 2.519e-05 -4.471 -4.599 -0.128 - HSO4- 1.847e-08 1.376e-08 -7.733 -7.861 -0.128 - CaHSO4+ 7.734e-10 5.762e-10 -9.112 -9.239 -0.128 -Si 2.215e-05 - H4SiO4 2.210e-05 2.318e-05 -4.656 -4.635 0.021 - H3SiO4- 5.221e-08 3.890e-08 -7.282 -7.410 -0.128 - H2SiO4-2 9.772e-14 3.011e-14 -13.010 -13.521 -0.511 + OH- 1.609e-07 1.132e-07 -6.793 -6.946 -0.153 (0) + H+ 1.104e-07 8.788e-08 -6.957 -7.056 -0.099 0.00 + H2O 5.551e+01 9.941e-01 1.744 -0.003 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -121.312 -121.291 0.021 (0) +C(4) 3.029e-03 + HCO3- 2.397e-03 1.783e-03 -2.620 -2.749 -0.129 24.50 + CO2 3.377e-04 3.543e-04 -3.471 -3.451 0.021 (0) + CaHCO3+ 1.065e-04 7.920e-05 -3.973 -4.101 -0.129 (0) + NaHCO3 1.023e-04 1.073e-04 -3.990 -3.969 0.021 (0) + MgHCO3+ 7.221e-05 5.380e-05 -4.141 -4.269 -0.128 (0) + CaCO3 5.304e-06 5.565e-06 -5.275 -5.255 0.021 (0) + CO3-2 3.109e-06 9.513e-07 -5.507 -6.022 -0.514 -2.93 + NaCO3- 2.546e-06 1.897e-06 -5.594 -5.722 -0.128 (0) + MgCO3 2.232e-06 2.341e-06 -5.651 -5.631 0.021 (0) +Ca 1.213e-02 + Ca+2 1.095e-02 3.482e-03 -1.961 -2.458 -0.497 -16.98 + CaSO4 1.067e-03 1.119e-03 -2.972 -2.951 0.021 (0) + CaHCO3+ 1.065e-04 7.920e-05 -3.973 -4.101 -0.129 (0) + CaCO3 5.304e-06 5.565e-06 -5.275 -5.255 0.021 (0) + CaOH+ 8.774e-09 6.537e-09 -8.057 -8.185 -0.128 (0) + CaHSO4+ 7.734e-10 5.762e-10 -9.112 -9.239 -0.128 (0) +Cl 1.697e-01 + Cl- 1.697e-01 1.203e-01 -0.770 -0.920 -0.149 18.03 +H(0) 3.726e-39 + H2 1.863e-39 1.955e-39 -38.730 -38.709 0.021 (0) +K 3.173e-03 + K+ 3.140e-03 2.225e-03 -2.503 -2.653 -0.149 9.24 + KSO4- 3.381e-05 2.519e-05 -4.471 -4.599 -0.128 (0) + KOH 8.319e-11 8.729e-11 -10.080 -10.059 0.021 (0) +Mg 8.585e-03 + Mg+2 7.582e-03 2.579e-03 -2.120 -2.588 -0.468 -20.30 + MgSO4 9.283e-04 9.740e-04 -3.032 -3.011 0.021 (0) + MgHCO3+ 7.221e-05 5.380e-05 -4.141 -4.269 -0.128 (0) + MgCO3 2.232e-06 2.341e-06 -5.651 -5.631 0.021 (0) + MgOH+ 1.422e-07 1.059e-07 -6.847 -6.975 -0.128 (0) +Na 1.456e-01 + Na+ 1.444e-01 1.071e-01 -0.841 -0.970 -0.130 -1.00 + NaSO4- 1.160e-03 8.644e-04 -2.935 -3.063 -0.128 (0) + NaHCO3 1.023e-04 1.073e-04 -3.990 -3.969 0.021 (0) + NaCO3- 2.546e-06 1.897e-06 -5.594 -5.722 -0.128 (0) + NaOH 7.627e-09 8.002e-09 -8.118 -8.097 0.021 (0) +O(0) 2.055e-15 + O2 1.027e-15 1.078e-15 -14.988 -14.967 0.021 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -118.272 -118.424 -0.153 (0) + H2S 0.000e+00 0.000e+00 -118.560 -118.539 0.021 (0) + S-2 0.000e+00 0.000e+00 -123.754 -124.286 -0.532 (0) +S(6) 8.777e-03 + SO4-2 5.588e-03 1.611e-03 -2.253 -2.793 -0.540 14.83 + NaSO4- 1.160e-03 8.644e-04 -2.935 -3.063 -0.128 (0) + CaSO4 1.067e-03 1.119e-03 -2.972 -2.951 0.021 (0) + MgSO4 9.283e-04 9.740e-04 -3.032 -3.011 0.021 (0) + KSO4- 3.381e-05 2.519e-05 -4.471 -4.599 -0.128 (0) + HSO4- 1.847e-08 1.376e-08 -7.733 -7.861 -0.128 (0) + CaHSO4+ 7.734e-10 5.762e-10 -9.112 -9.239 -0.128 (0) +Si 2.215e-05 + H4SiO4 2.210e-05 2.318e-05 -4.656 -4.635 0.021 56.00 + H3SiO4- 5.221e-08 3.890e-08 -7.282 -7.410 -0.128 (0) + H2SiO4-2 9.772e-14 3.011e-14 -13.010 -13.521 -0.511 (0) ------------------------------Saturation indices------------------------------- @@ -702,69 +702,69 @@ Calcite -0.00 -8.48 -8.48 1.000e+01 1.000e+01 -3.992e-05 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 3.915e-07 2.755e-07 -6.407 -6.560 -0.153 - H+ 4.537e-08 3.612e-08 -7.343 -7.442 -0.099 - H2O 5.551e+01 9.941e-01 1.744 -0.003 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -121.635 -121.614 0.021 -C(4) 3.229e-03 - HCO3- 2.721e-03 2.024e-03 -2.565 -2.694 -0.129 - MgHCO3+ 1.579e-04 1.176e-04 -3.802 -3.930 -0.128 - CO2 1.576e-04 1.653e-04 -3.803 -3.782 0.021 - NaHCO3 1.161e-04 1.219e-04 -3.935 -3.914 0.021 - CaHCO3+ 4.376e-05 3.255e-05 -4.359 -4.487 -0.129 - MgCO3 1.187e-05 1.245e-05 -4.926 -4.905 0.021 - CO3-2 8.587e-06 2.628e-06 -5.066 -5.580 -0.514 - NaCO3- 7.033e-06 5.240e-06 -5.153 -5.281 -0.128 - CaCO3 5.304e-06 5.565e-06 -5.275 -5.255 0.021 -Ca 4.390e-03 - Ca+2 3.963e-03 1.261e-03 -2.402 -2.899 -0.497 - CaSO4 3.784e-04 3.971e-04 -3.422 -3.401 0.021 - CaHCO3+ 4.376e-05 3.255e-05 -4.359 -4.487 -0.129 - CaCO3 5.304e-06 5.565e-06 -5.275 -5.255 0.021 - CaOH+ 7.728e-09 5.758e-09 -8.112 -8.240 -0.128 - CaHSO4+ 1.128e-10 8.402e-11 -9.948 -10.076 -0.128 -Cl 1.697e-01 - Cl- 1.697e-01 1.203e-01 -0.770 -0.920 -0.149 -H(0) 3.743e-39 - H2 1.871e-39 1.963e-39 -38.728 -38.707 0.021 -K 3.173e-03 - K+ 3.140e-03 2.226e-03 -2.503 -2.652 -0.149 - KSO4- 3.314e-05 2.469e-05 -4.480 -4.607 -0.128 - KOH 2.025e-10 2.124e-10 -9.694 -9.673 0.021 -Mg 1.652e-02 - Mg+2 1.460e-02 4.966e-03 -1.836 -2.304 -0.468 - MgSO4 1.752e-03 1.838e-03 -2.757 -2.736 0.021 - MgHCO3+ 1.579e-04 1.176e-04 -3.802 -3.930 -0.128 - MgCO3 1.187e-05 1.245e-05 -4.926 -4.905 0.021 - MgOH+ 6.661e-07 4.963e-07 -6.176 -6.304 -0.128 -Na 1.456e-01 - Na+ 1.444e-01 1.071e-01 -0.841 -0.970 -0.130 - NaSO4- 1.137e-03 8.472e-04 -2.944 -3.072 -0.128 - NaHCO3 1.161e-04 1.219e-04 -3.935 -3.914 0.021 - NaCO3- 7.033e-06 5.240e-06 -5.153 -5.281 -0.128 - NaOH 1.856e-08 1.947e-08 -7.731 -7.711 0.021 -O(0) 2.037e-15 - O2 1.018e-15 1.069e-15 -14.992 -14.971 0.021 -S(-2) 0.000e+00 - HS- 0.000e+00 0.000e+00 -118.659 -118.812 -0.153 - H2S 0.000e+00 0.000e+00 -119.333 -119.312 0.021 - S-2 0.000e+00 0.000e+00 -123.755 -124.287 -0.532 -S(6) 8.777e-03 - SO4-2 5.477e-03 1.579e-03 -2.261 -2.802 -0.540 - MgSO4 1.752e-03 1.838e-03 -2.757 -2.736 0.021 - NaSO4- 1.137e-03 8.472e-04 -2.944 -3.072 -0.128 - CaSO4 3.784e-04 3.971e-04 -3.422 -3.401 0.021 - KSO4- 3.314e-05 2.469e-05 -4.480 -4.607 -0.128 - HSO4- 7.441e-09 5.544e-09 -8.128 -8.256 -0.128 - CaHSO4+ 1.128e-10 8.402e-11 -9.948 -10.076 -0.128 -Si 2.215e-05 - H4SiO4 2.202e-05 2.311e-05 -4.657 -4.636 0.021 - H3SiO4- 1.266e-07 9.432e-08 -6.898 -7.025 -0.128 - H2SiO4-2 5.766e-13 1.776e-13 -12.239 -12.750 -0.511 + OH- 3.915e-07 2.755e-07 -6.407 -6.560 -0.153 (0) + H+ 4.537e-08 3.612e-08 -7.343 -7.442 -0.099 0.00 + H2O 5.551e+01 9.941e-01 1.744 -0.003 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -121.635 -121.614 0.021 (0) +C(4) 3.229e-03 + HCO3- 2.721e-03 2.024e-03 -2.565 -2.694 -0.129 24.50 + MgHCO3+ 1.579e-04 1.176e-04 -3.802 -3.930 -0.128 (0) + CO2 1.576e-04 1.653e-04 -3.803 -3.782 0.021 (0) + NaHCO3 1.161e-04 1.219e-04 -3.935 -3.914 0.021 (0) + CaHCO3+ 4.376e-05 3.255e-05 -4.359 -4.487 -0.129 (0) + MgCO3 1.187e-05 1.245e-05 -4.926 -4.905 0.021 (0) + CO3-2 8.587e-06 2.628e-06 -5.066 -5.580 -0.514 -2.93 + NaCO3- 7.033e-06 5.240e-06 -5.153 -5.281 -0.128 (0) + CaCO3 5.304e-06 5.565e-06 -5.275 -5.255 0.021 (0) +Ca 4.390e-03 + Ca+2 3.963e-03 1.261e-03 -2.402 -2.899 -0.497 -16.98 + CaSO4 3.784e-04 3.971e-04 -3.422 -3.401 0.021 (0) + CaHCO3+ 4.376e-05 3.255e-05 -4.359 -4.487 -0.129 (0) + CaCO3 5.304e-06 5.565e-06 -5.275 -5.255 0.021 (0) + CaOH+ 7.728e-09 5.758e-09 -8.112 -8.240 -0.128 (0) + CaHSO4+ 1.128e-10 8.402e-11 -9.948 -10.076 -0.128 (0) +Cl 1.697e-01 + Cl- 1.697e-01 1.203e-01 -0.770 -0.920 -0.149 18.03 +H(0) 3.743e-39 + H2 1.871e-39 1.963e-39 -38.728 -38.707 0.021 (0) +K 3.173e-03 + K+ 3.140e-03 2.226e-03 -2.503 -2.652 -0.149 9.24 + KSO4- 3.314e-05 2.469e-05 -4.480 -4.607 -0.128 (0) + KOH 2.025e-10 2.124e-10 -9.694 -9.673 0.021 (0) +Mg 1.652e-02 + Mg+2 1.460e-02 4.966e-03 -1.836 -2.304 -0.468 -20.30 + MgSO4 1.752e-03 1.838e-03 -2.757 -2.736 0.021 (0) + MgHCO3+ 1.579e-04 1.176e-04 -3.802 -3.930 -0.128 (0) + MgCO3 1.187e-05 1.245e-05 -4.926 -4.905 0.021 (0) + MgOH+ 6.661e-07 4.963e-07 -6.176 -6.304 -0.128 (0) +Na 1.456e-01 + Na+ 1.444e-01 1.071e-01 -0.841 -0.970 -0.130 -1.00 + NaSO4- 1.137e-03 8.472e-04 -2.944 -3.072 -0.128 (0) + NaHCO3 1.161e-04 1.219e-04 -3.935 -3.914 0.021 (0) + NaCO3- 7.033e-06 5.240e-06 -5.153 -5.281 -0.128 (0) + NaOH 1.856e-08 1.947e-08 -7.731 -7.711 0.021 (0) +O(0) 2.037e-15 + O2 1.018e-15 1.069e-15 -14.992 -14.971 0.021 (0) +S(-2) 0.000e+00 + HS- 0.000e+00 0.000e+00 -118.659 -118.812 -0.153 (0) + H2S 0.000e+00 0.000e+00 -119.333 -119.312 0.021 (0) + S-2 0.000e+00 0.000e+00 -123.755 -124.287 -0.532 (0) +S(6) 8.777e-03 + SO4-2 5.477e-03 1.579e-03 -2.261 -2.802 -0.540 14.83 + MgSO4 1.752e-03 1.838e-03 -2.757 -2.736 0.021 (0) + NaSO4- 1.137e-03 8.472e-04 -2.944 -3.072 -0.128 (0) + CaSO4 3.784e-04 3.971e-04 -3.422 -3.401 0.021 (0) + KSO4- 3.314e-05 2.469e-05 -4.480 -4.607 -0.128 (0) + HSO4- 7.441e-09 5.544e-09 -8.128 -8.256 -0.128 (0) + CaHSO4+ 1.128e-10 8.402e-11 -9.948 -10.076 -0.128 (0) +Si 2.215e-05 + H4SiO4 2.202e-05 2.311e-05 -4.657 -4.636 0.021 56.00 + H3SiO4- 1.266e-07 9.432e-08 -6.898 -7.025 -0.128 (0) + H2SiO4-2 5.766e-13 1.776e-13 -12.239 -12.750 -0.511 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex4.out b/ex4.out index 65d17eab..a0829a96 100644 --- a/ex4.out +++ b/ex4.out @@ -90,66 +90,66 @@ Initial solution 1. Precipitation from Central Oklahoma ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 3.196e-05 3.162e-05 -4.495 -4.500 -0.005 - OH- 3.200e-10 3.166e-10 -9.495 -9.500 -0.005 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -C(4) 1.092e-05 - CO2 1.077e-05 1.077e-05 -4.968 -4.968 0.000 - HCO3- 1.531e-07 1.514e-07 -6.815 -6.820 -0.005 - CaHCO3+ 1.787e-11 1.768e-11 -10.748 -10.753 -0.005 - MgHCO3+ 3.025e-12 2.992e-12 -11.519 -11.524 -0.005 - NaHCO3 5.166e-13 5.166e-13 -12.287 -12.287 0.000 - CO3-2 2.345e-13 2.246e-13 -12.630 -12.649 -0.019 - CaCO3 3.452e-15 3.452e-15 -14.462 -14.462 0.000 - MgCO3 3.619e-16 3.619e-16 -15.441 -15.441 0.000 - NaCO3- 2.565e-17 2.537e-17 -16.591 -16.596 -0.005 -Ca 9.581e-06 - Ca+2 9.557e-06 9.151e-06 -5.020 -5.039 -0.019 - CaSO4 2.353e-08 2.353e-08 -7.628 -7.628 0.000 - CaHCO3+ 1.787e-11 1.768e-11 -10.748 -10.753 -0.005 - CaHSO4+ 4.408e-12 4.360e-12 -11.356 -11.361 -0.005 - CaOH+ 4.855e-14 4.803e-14 -13.314 -13.319 -0.005 - CaCO3 3.452e-15 3.452e-15 -14.462 -14.462 0.000 -Cl 6.657e-06 - Cl- 6.657e-06 6.585e-06 -5.177 -5.181 -0.005 -H(0) 1.416e-20 - H2 7.079e-21 7.079e-21 -20.150 -20.150 0.000 -K 9.207e-07 - K+ 9.206e-07 9.106e-07 -6.036 -6.041 -0.005 - KSO4- 8.337e-11 8.247e-11 -10.079 -10.084 -0.005 - KOH 9.984e-17 9.985e-17 -16.001 -16.001 0.000 -Mg 1.769e-06 - Mg+2 1.764e-06 1.689e-06 -5.754 -5.772 -0.019 - MgSO4 5.103e-09 5.103e-09 -8.292 -8.292 0.000 - MgHCO3+ 3.025e-12 2.992e-12 -11.519 -11.524 -0.005 - MgOH+ 1.960e-13 1.939e-13 -12.708 -12.712 -0.005 - MgCO3 3.619e-16 3.619e-16 -15.441 -15.441 0.000 -N(-3) 1.485e-05 - NH4+ 1.485e-05 1.469e-05 -4.828 -4.833 -0.005 - NH4SO4- 2.465e-09 2.438e-09 -8.608 -8.613 -0.005 - NH3 2.646e-10 2.647e-10 -9.577 -9.577 0.000 -N(5) 1.692e-05 - NO3- 1.692e-05 1.674e-05 -4.772 -4.776 -0.005 -Na 6.133e-06 - Na+ 6.133e-06 6.066e-06 -5.212 -5.217 -0.005 - NaSO4- 3.962e-10 3.919e-10 -9.402 -9.407 -0.005 - NaHCO3 5.166e-13 5.166e-13 -12.287 -12.287 0.000 - NaOH 1.267e-15 1.267e-15 -14.897 -14.897 0.000 - NaCO3- 2.565e-17 2.537e-17 -16.591 -16.596 -0.005 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -52.080 -52.080 0.000 -S(6) 1.353e-05 - SO4-2 1.346e-05 1.289e-05 -4.871 -4.890 -0.019 - HSO4- 4.006e-08 3.963e-08 -7.397 -7.402 -0.005 - CaSO4 2.353e-08 2.353e-08 -7.628 -7.628 0.000 - MgSO4 5.103e-09 5.103e-09 -8.292 -8.292 0.000 - NH4SO4- 2.465e-09 2.438e-09 -8.608 -8.613 -0.005 - NaSO4- 3.962e-10 3.919e-10 -9.402 -9.407 -0.005 - KSO4- 8.337e-11 8.247e-11 -10.079 -10.084 -0.005 - CaHSO4+ 4.408e-12 4.360e-12 -11.356 -11.361 -0.005 + H+ 3.196e-05 3.162e-05 -4.495 -4.500 -0.005 0.00 + OH- 3.200e-10 3.166e-10 -9.495 -9.500 -0.005 (0) + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +C(4) 1.092e-05 + CO2 1.077e-05 1.077e-05 -4.968 -4.968 0.000 (0) + HCO3- 1.531e-07 1.514e-07 -6.815 -6.820 -0.005 24.29 + CaHCO3+ 1.787e-11 1.768e-11 -10.748 -10.753 -0.005 (0) + MgHCO3+ 3.025e-12 2.992e-12 -11.519 -11.524 -0.005 (0) + NaHCO3 5.166e-13 5.166e-13 -12.287 -12.287 0.000 (0) + CO3-2 2.345e-13 2.246e-13 -12.630 -12.649 -0.019 -3.78 + CaCO3 3.452e-15 3.452e-15 -14.462 -14.462 0.000 (0) + MgCO3 3.619e-16 3.619e-16 -15.441 -15.441 0.000 (0) + NaCO3- 2.565e-17 2.537e-17 -16.591 -16.596 -0.005 (0) +Ca 9.581e-06 + Ca+2 9.557e-06 9.151e-06 -5.020 -5.039 -0.019 -17.83 + CaSO4 2.353e-08 2.353e-08 -7.628 -7.628 0.000 (0) + CaHCO3+ 1.787e-11 1.768e-11 -10.748 -10.753 -0.005 (0) + CaHSO4+ 4.408e-12 4.360e-12 -11.356 -11.361 -0.005 (0) + CaOH+ 4.855e-14 4.803e-14 -13.314 -13.319 -0.005 (0) + CaCO3 3.452e-15 3.452e-15 -14.462 -14.462 0.000 (0) +Cl 6.657e-06 + Cl- 6.657e-06 6.585e-06 -5.177 -5.181 -0.005 17.82 +H(0) 1.416e-20 + H2 7.079e-21 7.079e-21 -20.150 -20.150 0.000 (0) +K 9.207e-07 + K+ 9.206e-07 9.106e-07 -6.036 -6.041 -0.005 9.03 + KSO4- 8.337e-11 8.247e-11 -10.079 -10.084 -0.005 (0) + KOH 9.984e-17 9.985e-17 -16.001 -16.001 0.000 (0) +Mg 1.769e-06 + Mg+2 1.764e-06 1.689e-06 -5.754 -5.772 -0.019 -21.15 + MgSO4 5.103e-09 5.103e-09 -8.292 -8.292 0.000 (0) + MgHCO3+ 3.025e-12 2.992e-12 -11.519 -11.524 -0.005 (0) + MgOH+ 1.960e-13 1.939e-13 -12.708 -12.712 -0.005 (0) + MgCO3 3.619e-16 3.619e-16 -15.441 -15.441 0.000 (0) +N(-3) 1.485e-05 + NH4+ 1.485e-05 1.469e-05 -4.828 -4.833 -0.005 17.86 + NH4SO4- 2.465e-09 2.438e-09 -8.608 -8.613 -0.005 (0) + NH3 2.646e-10 2.647e-10 -9.577 -9.577 0.000 (0) +N(5) 1.692e-05 + NO3- 1.692e-05 1.674e-05 -4.772 -4.776 -0.005 28.99 +Na 6.133e-06 + Na+ 6.133e-06 6.066e-06 -5.212 -5.217 -0.005 -1.21 + NaSO4- 3.962e-10 3.919e-10 -9.402 -9.407 -0.005 (0) + NaHCO3 5.166e-13 5.166e-13 -12.287 -12.287 0.000 (0) + NaOH 1.267e-15 1.267e-15 -14.897 -14.897 0.000 (0) + NaCO3- 2.565e-17 2.537e-17 -16.591 -16.596 -0.005 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -52.080 -52.080 0.000 (0) +S(6) 1.353e-05 + SO4-2 1.346e-05 1.289e-05 -4.871 -4.890 -0.019 13.98 + HSO4- 4.006e-08 3.963e-08 -7.397 -7.402 -0.005 (0) + CaSO4 2.353e-08 2.353e-08 -7.628 -7.628 0.000 (0) + MgSO4 5.103e-09 5.103e-09 -8.292 -8.292 0.000 (0) + NH4SO4- 2.465e-09 2.438e-09 -8.608 -8.613 -0.005 (0) + NaSO4- 3.962e-10 3.919e-10 -9.402 -9.407 -0.005 (0) + KSO4- 8.337e-11 8.247e-11 -10.079 -10.084 -0.005 (0) + CaHSO4+ 4.408e-12 4.360e-12 -11.356 -11.361 -0.005 (0) ------------------------------Saturation indices------------------------------- @@ -224,76 +224,76 @@ Reaction 1. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 7.406e-04 7.108e-04 -3.130 -3.148 -0.018 - OH- 1.472e-11 1.408e-11 -10.832 -10.851 -0.019 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -136.693 -136.693 0.000 -C(4) 2.183e-04 - CO2 2.182e-04 2.182e-04 -3.661 -3.661 0.000 - HCO3- 1.425e-07 1.366e-07 -6.846 -6.865 -0.019 - CaHCO3+ 2.834e-10 2.715e-10 -9.548 -9.566 -0.019 - MgHCO3+ 4.780e-11 4.576e-11 -10.321 -10.340 -0.019 - NaHCO3 9.005e-12 9.008e-12 -11.046 -11.045 0.000 - CO3-2 1.070e-14 9.010e-15 -13.971 -14.045 -0.074 - CaCO3 2.358e-15 2.359e-15 -14.627 -14.627 0.000 - MgCO3 2.461e-16 2.462e-16 -15.609 -15.609 0.000 - NaCO3- 2.056e-17 1.968e-17 -16.687 -16.706 -0.019 -Ca 1.916e-04 - Ca+2 1.851e-04 1.559e-04 -3.733 -3.807 -0.075 - CaSO4 6.474e-06 6.477e-06 -5.189 -5.189 0.000 - CaHSO4+ 2.817e-08 2.697e-08 -7.550 -7.569 -0.019 - CaHCO3+ 2.834e-10 2.715e-10 -9.548 -9.566 -0.019 - CaOH+ 3.801e-14 3.639e-14 -13.420 -13.439 -0.019 - CaCO3 2.358e-15 2.359e-15 -14.627 -14.627 0.000 -Cl 1.331e-04 - Cl- 1.331e-04 1.274e-04 -3.876 -3.895 -0.019 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.506 -42.506 0.000 -K 1.841e-05 - K+ 1.838e-05 1.759e-05 -4.736 -4.755 -0.019 - KSO4- 2.689e-08 2.575e-08 -7.570 -7.589 -0.019 - KOH 8.579e-17 8.582e-17 -16.067 -16.066 0.000 -Mg 3.536e-05 - Mg+2 3.396e-05 2.864e-05 -4.469 -4.543 -0.074 - MgSO4 1.398e-06 1.398e-06 -5.855 -5.854 0.000 - MgHCO3+ 4.780e-11 4.576e-11 -10.321 -10.340 -0.019 - MgOH+ 1.528e-13 1.463e-13 -12.816 -12.835 -0.019 - MgCO3 2.461e-16 2.462e-16 -15.609 -15.609 0.000 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -48.438 -48.457 -0.019 - NH4SO4- 0.000e+00 0.000e+00 -51.009 -51.028 -0.019 - NH3 0.000e+00 0.000e+00 -54.553 -54.553 0.000 -N(0) 4.751e-04 - N2 2.375e-04 2.376e-04 -3.624 -3.624 0.000 -N(3) 2.623e-15 - NO2- 2.623e-15 2.510e-15 -14.581 -14.600 -0.019 -N(5) 1.601e-04 - NO3- 1.601e-04 1.532e-04 -3.796 -3.815 -0.019 -Na 1.226e-04 - Na+ 1.225e-04 1.173e-04 -3.912 -3.931 -0.019 - NaSO4- 1.279e-07 1.224e-07 -6.893 -6.912 -0.019 - NaHCO3 9.005e-12 9.008e-12 -11.046 -11.045 0.000 - NaOH 1.090e-15 1.090e-15 -14.963 -14.962 0.000 - NaCO3- 2.056e-17 1.968e-17 -16.687 -16.706 -0.019 -O(0) 8.553e-08 - O2 4.277e-08 4.278e-08 -7.369 -7.369 0.000 -S(-2) 0.000e+00 - H2S 0.000e+00 0.000e+00 -126.809 -126.809 0.000 - HS- 0.000e+00 0.000e+00 -130.583 -130.602 -0.019 - S-2 0.000e+00 0.000e+00 -140.297 -140.372 -0.075 -S(6) 2.706e-04 - SO4-2 2.475e-04 2.083e-04 -3.606 -3.681 -0.075 - HSO4- 1.503e-05 1.439e-05 -4.823 -4.842 -0.019 - CaSO4 6.474e-06 6.477e-06 -5.189 -5.189 0.000 - MgSO4 1.398e-06 1.398e-06 -5.855 -5.854 0.000 - NaSO4- 1.279e-07 1.224e-07 -6.893 -6.912 -0.019 - CaHSO4+ 2.817e-08 2.697e-08 -7.550 -7.569 -0.019 - KSO4- 2.689e-08 2.575e-08 -7.570 -7.589 -0.019 - NH4SO4- 0.000e+00 0.000e+00 -51.009 -51.028 -0.019 + H+ 7.406e-04 7.108e-04 -3.130 -3.148 -0.018 0.00 + OH- 1.472e-11 1.408e-11 -10.832 -10.851 -0.019 (0) + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -136.693 -136.693 0.000 (0) +C(4) 2.183e-04 + CO2 2.182e-04 2.182e-04 -3.661 -3.661 0.000 (0) + HCO3- 1.425e-07 1.366e-07 -6.846 -6.865 -0.019 24.29 + CaHCO3+ 2.834e-10 2.715e-10 -9.548 -9.566 -0.019 (0) + MgHCO3+ 4.780e-11 4.576e-11 -10.321 -10.340 -0.019 (0) + NaHCO3 9.005e-12 9.008e-12 -11.046 -11.045 0.000 (0) + CO3-2 1.070e-14 9.010e-15 -13.971 -14.045 -0.074 -3.77 + CaCO3 2.358e-15 2.359e-15 -14.627 -14.627 0.000 (0) + MgCO3 2.461e-16 2.462e-16 -15.609 -15.609 0.000 (0) + NaCO3- 2.056e-17 1.968e-17 -16.687 -16.706 -0.019 (0) +Ca 1.916e-04 + Ca+2 1.851e-04 1.559e-04 -3.733 -3.807 -0.075 -17.82 + CaSO4 6.474e-06 6.477e-06 -5.189 -5.189 0.000 (0) + CaHSO4+ 2.817e-08 2.697e-08 -7.550 -7.569 -0.019 (0) + CaHCO3+ 2.834e-10 2.715e-10 -9.548 -9.566 -0.019 (0) + CaOH+ 3.801e-14 3.639e-14 -13.420 -13.439 -0.019 (0) + CaCO3 2.358e-15 2.359e-15 -14.627 -14.627 0.000 (0) +Cl 1.331e-04 + Cl- 1.331e-04 1.274e-04 -3.876 -3.895 -0.019 17.82 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.506 -42.506 0.000 (0) +K 1.841e-05 + K+ 1.838e-05 1.759e-05 -4.736 -4.755 -0.019 9.03 + KSO4- 2.689e-08 2.575e-08 -7.570 -7.589 -0.019 (0) + KOH 8.579e-17 8.582e-17 -16.067 -16.066 0.000 (0) +Mg 3.536e-05 + Mg+2 3.396e-05 2.864e-05 -4.469 -4.543 -0.074 -21.14 + MgSO4 1.398e-06 1.398e-06 -5.855 -5.854 0.000 (0) + MgHCO3+ 4.780e-11 4.576e-11 -10.321 -10.340 -0.019 (0) + MgOH+ 1.528e-13 1.463e-13 -12.816 -12.835 -0.019 (0) + MgCO3 2.461e-16 2.462e-16 -15.609 -15.609 0.000 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -48.438 -48.457 -0.019 17.86 + NH4SO4- 0.000e+00 0.000e+00 -51.009 -51.028 -0.019 (0) + NH3 0.000e+00 0.000e+00 -54.553 -54.553 0.000 (0) +N(0) 4.751e-04 + N2 2.375e-04 2.376e-04 -3.624 -3.624 0.000 (0) +N(3) 2.623e-15 + NO2- 2.623e-15 2.510e-15 -14.581 -14.600 -0.019 (0) +N(5) 1.601e-04 + NO3- 1.601e-04 1.532e-04 -3.796 -3.815 -0.019 28.99 +Na 1.226e-04 + Na+ 1.225e-04 1.173e-04 -3.912 -3.931 -0.019 -1.21 + NaSO4- 1.279e-07 1.224e-07 -6.893 -6.912 -0.019 (0) + NaHCO3 9.005e-12 9.008e-12 -11.046 -11.045 0.000 (0) + NaOH 1.090e-15 1.090e-15 -14.963 -14.962 0.000 (0) + NaCO3- 2.056e-17 1.968e-17 -16.687 -16.706 -0.019 (0) +O(0) 8.553e-08 + O2 4.277e-08 4.278e-08 -7.369 -7.369 0.000 (0) +S(-2) 0.000e+00 + H2S 0.000e+00 0.000e+00 -126.809 -126.809 0.000 (0) + HS- 0.000e+00 0.000e+00 -130.583 -130.602 -0.019 (0) + S-2 0.000e+00 0.000e+00 -140.297 -140.372 -0.075 (0) +S(6) 2.706e-04 + SO4-2 2.475e-04 2.083e-04 -3.606 -3.681 -0.075 13.99 + HSO4- 1.503e-05 1.439e-05 -4.823 -4.842 -0.019 (0) + CaSO4 6.474e-06 6.477e-06 -5.189 -5.189 0.000 (0) + MgSO4 1.398e-06 1.398e-06 -5.855 -5.854 0.000 (0) + NaSO4- 1.279e-07 1.224e-07 -6.893 -6.912 -0.019 (0) + CaHSO4+ 2.817e-08 2.697e-08 -7.550 -7.569 -0.019 (0) + KSO4- 2.689e-08 2.575e-08 -7.570 -7.589 -0.019 (0) + NH4SO4- 0.000e+00 0.000e+00 -51.009 -51.028 -0.019 (0) ------------------------------Saturation indices------------------------------- @@ -380,76 +380,76 @@ Mixture 1. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 7.406e-04 7.108e-04 -3.130 -3.148 -0.018 - OH- 1.472e-11 1.408e-11 -10.832 -10.851 -0.019 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -C(-4) 0.000e+00 - CH4 0.000e+00 0.000e+00 -136.693 -136.693 0.000 -C(4) 2.183e-04 - CO2 2.182e-04 2.182e-04 -3.661 -3.661 0.000 - HCO3- 1.425e-07 1.366e-07 -6.846 -6.865 -0.019 - CaHCO3+ 2.834e-10 2.715e-10 -9.548 -9.566 -0.019 - MgHCO3+ 4.780e-11 4.576e-11 -10.321 -10.340 -0.019 - NaHCO3 9.005e-12 9.008e-12 -11.046 -11.045 0.000 - CO3-2 1.070e-14 9.010e-15 -13.971 -14.045 -0.074 - CaCO3 2.358e-15 2.359e-15 -14.627 -14.627 0.000 - MgCO3 2.461e-16 2.462e-16 -15.609 -15.609 0.000 - NaCO3- 2.056e-17 1.968e-17 -16.687 -16.706 -0.019 -Ca 1.916e-04 - Ca+2 1.851e-04 1.559e-04 -3.733 -3.807 -0.075 - CaSO4 6.474e-06 6.477e-06 -5.189 -5.189 0.000 - CaHSO4+ 2.817e-08 2.697e-08 -7.550 -7.569 -0.019 - CaHCO3+ 2.834e-10 2.715e-10 -9.548 -9.566 -0.019 - CaOH+ 3.801e-14 3.639e-14 -13.420 -13.439 -0.019 - CaCO3 2.358e-15 2.359e-15 -14.627 -14.627 0.000 -Cl 1.331e-04 - Cl- 1.331e-04 1.274e-04 -3.876 -3.895 -0.019 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.506 -42.506 0.000 -K 1.841e-05 - K+ 1.838e-05 1.759e-05 -4.736 -4.755 -0.019 - KSO4- 2.689e-08 2.575e-08 -7.570 -7.589 -0.019 - KOH 8.579e-17 8.582e-17 -16.067 -16.066 0.000 -Mg 3.536e-05 - Mg+2 3.396e-05 2.864e-05 -4.469 -4.543 -0.074 - MgSO4 1.398e-06 1.398e-06 -5.855 -5.854 0.000 - MgHCO3+ 4.780e-11 4.576e-11 -10.321 -10.340 -0.019 - MgOH+ 1.528e-13 1.463e-13 -12.816 -12.835 -0.019 - MgCO3 2.461e-16 2.462e-16 -15.609 -15.609 0.000 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -48.438 -48.457 -0.019 - NH4SO4- 0.000e+00 0.000e+00 -51.009 -51.028 -0.019 - NH3 0.000e+00 0.000e+00 -54.553 -54.553 0.000 -N(0) 4.751e-04 - N2 2.375e-04 2.376e-04 -3.624 -3.624 0.000 -N(3) 2.623e-15 - NO2- 2.623e-15 2.510e-15 -14.581 -14.600 -0.019 -N(5) 1.601e-04 - NO3- 1.601e-04 1.532e-04 -3.796 -3.815 -0.019 -Na 1.226e-04 - Na+ 1.225e-04 1.173e-04 -3.912 -3.931 -0.019 - NaSO4- 1.279e-07 1.224e-07 -6.893 -6.912 -0.019 - NaHCO3 9.005e-12 9.008e-12 -11.046 -11.045 0.000 - NaOH 1.090e-15 1.090e-15 -14.963 -14.962 0.000 - NaCO3- 2.056e-17 1.968e-17 -16.687 -16.706 -0.019 -O(0) 8.553e-08 - O2 4.277e-08 4.278e-08 -7.369 -7.369 0.000 -S(-2) 0.000e+00 - H2S 0.000e+00 0.000e+00 -126.809 -126.809 0.000 - HS- 0.000e+00 0.000e+00 -130.583 -130.602 -0.019 - S-2 0.000e+00 0.000e+00 -140.297 -140.372 -0.075 -S(6) 2.706e-04 - SO4-2 2.475e-04 2.083e-04 -3.606 -3.681 -0.075 - HSO4- 1.503e-05 1.439e-05 -4.823 -4.842 -0.019 - CaSO4 6.474e-06 6.477e-06 -5.189 -5.189 0.000 - MgSO4 1.398e-06 1.398e-06 -5.855 -5.854 0.000 - NaSO4- 1.279e-07 1.224e-07 -6.893 -6.912 -0.019 - CaHSO4+ 2.817e-08 2.697e-08 -7.550 -7.569 -0.019 - KSO4- 2.689e-08 2.575e-08 -7.570 -7.589 -0.019 - NH4SO4- 0.000e+00 0.000e+00 -51.009 -51.028 -0.019 + H+ 7.406e-04 7.108e-04 -3.130 -3.148 -0.018 0.00 + OH- 1.472e-11 1.408e-11 -10.832 -10.851 -0.019 (0) + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +C(-4) 0.000e+00 + CH4 0.000e+00 0.000e+00 -136.693 -136.693 0.000 (0) +C(4) 2.183e-04 + CO2 2.182e-04 2.182e-04 -3.661 -3.661 0.000 (0) + HCO3- 1.425e-07 1.366e-07 -6.846 -6.865 -0.019 24.29 + CaHCO3+ 2.834e-10 2.715e-10 -9.548 -9.566 -0.019 (0) + MgHCO3+ 4.780e-11 4.576e-11 -10.321 -10.340 -0.019 (0) + NaHCO3 9.005e-12 9.008e-12 -11.046 -11.045 0.000 (0) + CO3-2 1.070e-14 9.010e-15 -13.971 -14.045 -0.074 -3.77 + CaCO3 2.358e-15 2.359e-15 -14.627 -14.627 0.000 (0) + MgCO3 2.461e-16 2.462e-16 -15.609 -15.609 0.000 (0) + NaCO3- 2.056e-17 1.968e-17 -16.687 -16.706 -0.019 (0) +Ca 1.916e-04 + Ca+2 1.851e-04 1.559e-04 -3.733 -3.807 -0.075 -17.82 + CaSO4 6.474e-06 6.477e-06 -5.189 -5.189 0.000 (0) + CaHSO4+ 2.817e-08 2.697e-08 -7.550 -7.569 -0.019 (0) + CaHCO3+ 2.834e-10 2.715e-10 -9.548 -9.566 -0.019 (0) + CaOH+ 3.801e-14 3.639e-14 -13.420 -13.439 -0.019 (0) + CaCO3 2.358e-15 2.359e-15 -14.627 -14.627 0.000 (0) +Cl 1.331e-04 + Cl- 1.331e-04 1.274e-04 -3.876 -3.895 -0.019 17.82 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.506 -42.506 0.000 (0) +K 1.841e-05 + K+ 1.838e-05 1.759e-05 -4.736 -4.755 -0.019 9.03 + KSO4- 2.689e-08 2.575e-08 -7.570 -7.589 -0.019 (0) + KOH 8.579e-17 8.582e-17 -16.067 -16.066 0.000 (0) +Mg 3.536e-05 + Mg+2 3.396e-05 2.864e-05 -4.469 -4.543 -0.074 -21.14 + MgSO4 1.398e-06 1.398e-06 -5.855 -5.854 0.000 (0) + MgHCO3+ 4.780e-11 4.576e-11 -10.321 -10.340 -0.019 (0) + MgOH+ 1.528e-13 1.463e-13 -12.816 -12.835 -0.019 (0) + MgCO3 2.461e-16 2.462e-16 -15.609 -15.609 0.000 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -48.438 -48.457 -0.019 17.86 + NH4SO4- 0.000e+00 0.000e+00 -51.009 -51.028 -0.019 (0) + NH3 0.000e+00 0.000e+00 -54.553 -54.553 0.000 (0) +N(0) 4.751e-04 + N2 2.375e-04 2.376e-04 -3.624 -3.624 0.000 (0) +N(3) 2.623e-15 + NO2- 2.623e-15 2.510e-15 -14.581 -14.600 -0.019 (0) +N(5) 1.601e-04 + NO3- 1.601e-04 1.532e-04 -3.796 -3.815 -0.019 28.99 +Na 1.226e-04 + Na+ 1.225e-04 1.173e-04 -3.912 -3.931 -0.019 -1.21 + NaSO4- 1.279e-07 1.224e-07 -6.893 -6.912 -0.019 (0) + NaHCO3 9.005e-12 9.008e-12 -11.046 -11.045 0.000 (0) + NaOH 1.090e-15 1.090e-15 -14.963 -14.962 0.000 (0) + NaCO3- 2.056e-17 1.968e-17 -16.687 -16.706 -0.019 (0) +O(0) 8.553e-08 + O2 4.277e-08 4.278e-08 -7.369 -7.369 0.000 (0) +S(-2) 0.000e+00 + H2S 0.000e+00 0.000e+00 -126.809 -126.809 0.000 (0) + HS- 0.000e+00 0.000e+00 -130.583 -130.602 -0.019 (0) + S-2 0.000e+00 0.000e+00 -140.297 -140.372 -0.075 (0) +S(6) 2.706e-04 + SO4-2 2.475e-04 2.083e-04 -3.606 -3.681 -0.075 13.99 + HSO4- 1.503e-05 1.439e-05 -4.823 -4.842 -0.019 (0) + CaSO4 6.474e-06 6.477e-06 -5.189 -5.189 0.000 (0) + MgSO4 1.398e-06 1.398e-06 -5.855 -5.854 0.000 (0) + NaSO4- 1.279e-07 1.224e-07 -6.893 -6.912 -0.019 (0) + CaHSO4+ 2.817e-08 2.697e-08 -7.550 -7.569 -0.019 (0) + KSO4- 2.689e-08 2.575e-08 -7.570 -7.589 -0.019 (0) + NH4SO4- 0.000e+00 0.000e+00 -51.009 -51.028 -0.019 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex5.out b/ex5.out index 09c6f804..8acffaa4 100644 --- a/ex5.out +++ b/ex5.out @@ -89,16 +89,16 @@ Initial solution 1. PURE WATER ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.002e-07 1.001e-07 -6.999 -6.999 -0.000 - H+ 1.001e-07 1.000e-07 -7.000 -7.000 -0.000 - H2O 5.551e+01 1.000e+00 1.744 0.000 0.000 -H(0) 1.416e-25 - H2 7.079e-26 7.079e-26 -25.150 -25.150 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 + OH- 1.002e-07 1.001e-07 -6.999 -6.999 -0.000 (0) + H+ 1.001e-07 1.000e-07 -7.000 -7.000 -0.000 0.00 + H2O 5.551e+01 1.000e+00 1.744 0.000 0.000 18.07 +H(0) 1.416e-25 + H2 7.079e-26 7.079e-26 -25.150 -25.150 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -175,69 +175,69 @@ Pyrite 0.00 -18.48 -18.48 1.000e+01 1.000e+01 -3.154e-08 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.987e-06 1.903e-06 -5.702 -5.720 -0.019 - H+ 5.476e-09 5.260e-09 -8.262 -8.279 -0.018 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -C(-4) 5.403e-08 - CH4 5.403e-08 5.405e-08 -7.267 -7.267 0.000 -C(4) 9.803e-04 - HCO3- 9.494e-04 9.104e-04 -3.023 -3.041 -0.018 - CO2 1.076e-05 1.077e-05 -4.968 -4.968 0.000 - CO3-2 9.603e-06 8.117e-06 -5.018 -5.091 -0.073 - CaCO3 5.563e-06 5.565e-06 -5.255 -5.255 0.000 - CaHCO3+ 4.943e-06 4.740e-06 -5.306 -5.324 -0.018 - FeCO3 2.600e-09 2.601e-09 -8.585 -8.585 0.000 - FeHCO3+ 1.269e-09 1.216e-09 -8.896 -8.915 -0.019 -Ca 4.934e-04 - Ca+2 4.829e-04 4.081e-04 -3.316 -3.389 -0.073 - CaCO3 5.563e-06 5.565e-06 -5.255 -5.255 0.000 - CaHCO3+ 4.943e-06 4.740e-06 -5.306 -5.324 -0.018 - CaOH+ 1.344e-08 1.288e-08 -7.872 -7.890 -0.019 - CaSO4 3.896e-09 3.897e-09 -8.409 -8.409 0.000 - CaHSO4+ 1.253e-16 1.201e-16 -15.902 -15.920 -0.019 -Fe(2) 2.049e-08 - Fe+2 1.578e-08 1.336e-08 -7.802 -7.874 -0.072 - FeCO3 2.600e-09 2.601e-09 -8.585 -8.585 0.000 - FeHCO3+ 1.269e-09 1.216e-09 -8.896 -8.915 -0.019 - FeOH+ 8.381e-10 8.031e-10 -9.077 -9.095 -0.019 - FeSO4 1.137e-13 1.137e-13 -12.944 -12.944 0.000 - Fe(HS)2 6.287e-17 6.289e-17 -16.202 -16.201 0.000 - FeHSO4+ 4.102e-21 3.931e-21 -20.387 -20.406 -0.019 - Fe(HS)3- 1.643e-23 1.574e-23 -22.784 -22.803 -0.019 -Fe(3) 3.369e-14 - Fe(OH)3 2.753e-14 2.754e-14 -13.560 -13.560 0.000 - Fe(OH)4- 4.984e-15 4.776e-15 -14.302 -14.321 -0.019 - Fe(OH)2+ 1.174e-15 1.124e-15 -14.931 -14.949 -0.019 - FeOH+2 2.119e-20 1.786e-20 -19.674 -19.748 -0.074 - Fe+3 2.091e-26 1.455e-26 -25.680 -25.837 -0.158 - FeSO4+ 7.970e-30 7.637e-30 -29.099 -29.117 -0.019 - Fe(SO4)2- 8.346e-36 7.997e-36 -35.079 -35.097 -0.019 - FeHSO4+2 1.276e-37 1.076e-37 -36.894 -36.968 -0.074 - Fe2(OH)2+4 1.700e-38 8.587e-39 -37.769 -38.066 -0.297 - Fe3(OH)4+5 0.000e+00 0.000e+00 -50.232 -50.695 -0.464 -H(0) 3.009e-10 - H2 1.505e-10 1.505e-10 -9.823 -9.822 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -72.735 -72.735 0.000 -S(-2) 2.505e-09 - HS- 2.399e-09 2.298e-09 -8.620 -8.639 -0.019 - H2S 1.057e-10 1.057e-10 -9.976 -9.976 0.000 - S-2 6.249e-14 5.278e-14 -13.204 -13.278 -0.073 - Fe(HS)2 6.287e-17 6.289e-17 -16.202 -16.201 0.000 - Fe(HS)3- 1.643e-23 1.574e-23 -22.784 -22.803 -0.019 -S(6) 6.057e-08 - SO4-2 5.668e-08 4.786e-08 -7.247 -7.320 -0.073 - CaSO4 3.896e-09 3.897e-09 -8.409 -8.409 0.000 - FeSO4 1.137e-13 1.137e-13 -12.944 -12.944 0.000 - HSO4- 2.554e-14 2.448e-14 -13.593 -13.611 -0.019 - CaHSO4+ 1.253e-16 1.201e-16 -15.902 -15.920 -0.019 - FeHSO4+ 4.102e-21 3.931e-21 -20.387 -20.406 -0.019 - FeSO4+ 7.970e-30 7.637e-30 -29.099 -29.117 -0.019 - Fe(SO4)2- 8.346e-36 7.997e-36 -35.079 -35.097 -0.019 - FeHSO4+2 1.276e-37 1.076e-37 -36.894 -36.968 -0.074 + OH- 1.987e-06 1.903e-06 -5.702 -5.720 -0.019 (0) + H+ 5.476e-09 5.260e-09 -8.262 -8.279 -0.018 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +C(-4) 5.403e-08 + CH4 5.403e-08 5.405e-08 -7.267 -7.267 0.000 (0) +C(4) 9.803e-04 + HCO3- 9.494e-04 9.104e-04 -3.023 -3.041 -0.018 24.29 + CO2 1.076e-05 1.077e-05 -4.968 -4.968 0.000 (0) + CO3-2 9.603e-06 8.117e-06 -5.018 -5.091 -0.073 -3.78 + CaCO3 5.563e-06 5.565e-06 -5.255 -5.255 0.000 (0) + CaHCO3+ 4.943e-06 4.740e-06 -5.306 -5.324 -0.018 (0) + FeCO3 2.600e-09 2.601e-09 -8.585 -8.585 0.000 (0) + FeHCO3+ 1.269e-09 1.216e-09 -8.896 -8.915 -0.019 (0) +Ca 4.934e-04 + Ca+2 4.829e-04 4.081e-04 -3.316 -3.389 -0.073 -17.83 + CaCO3 5.563e-06 5.565e-06 -5.255 -5.255 0.000 (0) + CaHCO3+ 4.943e-06 4.740e-06 -5.306 -5.324 -0.018 (0) + CaOH+ 1.344e-08 1.288e-08 -7.872 -7.890 -0.019 (0) + CaSO4 3.896e-09 3.897e-09 -8.409 -8.409 0.000 (0) + CaHSO4+ 1.253e-16 1.201e-16 -15.902 -15.920 -0.019 (0) +Fe(2) 2.049e-08 + Fe+2 1.578e-08 1.336e-08 -7.802 -7.874 -0.072 (0) + FeCO3 2.600e-09 2.601e-09 -8.585 -8.585 0.000 (0) + FeHCO3+ 1.269e-09 1.216e-09 -8.896 -8.915 -0.019 (0) + FeOH+ 8.381e-10 8.031e-10 -9.077 -9.095 -0.019 (0) + FeSO4 1.137e-13 1.137e-13 -12.944 -12.944 0.000 (0) + Fe(HS)2 6.287e-17 6.289e-17 -16.202 -16.201 0.000 (0) + FeHSO4+ 4.102e-21 3.931e-21 -20.387 -20.406 -0.019 (0) + Fe(HS)3- 1.643e-23 1.574e-23 -22.784 -22.803 -0.019 (0) +Fe(3) 3.369e-14 + Fe(OH)3 2.753e-14 2.754e-14 -13.560 -13.560 0.000 (0) + Fe(OH)4- 4.984e-15 4.776e-15 -14.302 -14.321 -0.019 (0) + Fe(OH)2+ 1.174e-15 1.124e-15 -14.931 -14.949 -0.019 (0) + FeOH+2 2.119e-20 1.786e-20 -19.674 -19.748 -0.074 (0) + Fe+3 2.091e-26 1.455e-26 -25.680 -25.837 -0.158 (0) + FeSO4+ 7.970e-30 7.637e-30 -29.099 -29.117 -0.019 (0) + Fe(SO4)2- 8.346e-36 7.997e-36 -35.079 -35.097 -0.019 (0) + FeHSO4+2 1.276e-37 1.076e-37 -36.894 -36.968 -0.074 (0) + Fe2(OH)2+4 1.700e-38 8.587e-39 -37.769 -38.066 -0.297 (0) + Fe3(OH)4+5 0.000e+00 0.000e+00 -50.232 -50.695 -0.464 (0) +H(0) 3.009e-10 + H2 1.505e-10 1.505e-10 -9.823 -9.822 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -72.735 -72.735 0.000 (0) +S(-2) 2.505e-09 + HS- 2.399e-09 2.298e-09 -8.620 -8.639 -0.019 (0) + H2S 1.057e-10 1.057e-10 -9.976 -9.976 0.000 (0) + S-2 6.249e-14 5.278e-14 -13.204 -13.278 -0.073 (0) + Fe(HS)2 6.287e-17 6.289e-17 -16.202 -16.201 0.000 (0) + Fe(HS)3- 1.643e-23 1.574e-23 -22.784 -22.803 -0.019 (0) +S(6) 6.057e-08 + SO4-2 5.668e-08 4.786e-08 -7.247 -7.320 -0.073 13.98 + CaSO4 3.896e-09 3.897e-09 -8.409 -8.409 0.000 (0) + FeSO4 1.137e-13 1.137e-13 -12.944 -12.944 0.000 (0) + HSO4- 2.554e-14 2.448e-14 -13.593 -13.611 -0.019 (0) + CaHSO4+ 1.253e-16 1.201e-16 -15.902 -15.920 -0.019 (0) + FeHSO4+ 4.102e-21 3.931e-21 -20.387 -20.406 -0.019 (0) + FeSO4+ 7.970e-30 7.637e-30 -29.099 -29.117 -0.019 (0) + Fe(SO4)2- 8.346e-36 7.997e-36 -35.079 -35.097 -0.019 (0) + FeHSO4+2 1.276e-37 1.076e-37 -36.894 -36.968 -0.074 (0) ------------------------------Saturation indices------------------------------- @@ -328,88 +328,88 @@ Pyrite -0.00 -18.48 -18.48 1.000e+01 1.000e+01 -2.667e-04 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.585e-06 1.484e-06 -5.800 -5.829 -0.029 - H+ 7.160e-09 6.745e-09 -8.145 -8.171 -0.026 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -C(-4) 2.240e-12 - CH4 2.240e-12 2.242e-12 -11.650 -11.649 0.000 -C(4) 7.859e-04 - HCO3- 7.565e-04 7.099e-04 -3.121 -3.149 -0.028 - CO2 1.076e-05 1.077e-05 -4.968 -4.968 0.000 - CaHCO3+ 6.477e-06 6.078e-06 -5.189 -5.216 -0.028 - CO3-2 6.364e-06 4.936e-06 -5.196 -5.307 -0.110 - CaCO3 5.560e-06 5.565e-06 -5.255 -5.255 0.000 - NaHCO3 1.865e-07 1.867e-07 -6.729 -6.729 0.000 - NaCO3- 4.587e-08 4.298e-08 -7.338 -7.367 -0.028 - FeCO3 7.363e-10 7.369e-10 -9.133 -9.133 0.000 - FeHCO3+ 4.715e-10 4.418e-10 -9.327 -9.355 -0.028 -Ca 9.277e-04 - Ca+2 8.657e-04 6.711e-04 -3.063 -3.173 -0.111 - CaSO4 4.996e-05 5.000e-05 -4.301 -4.301 0.000 - CaHCO3+ 6.477e-06 6.078e-06 -5.189 -5.216 -0.028 - CaCO3 5.560e-06 5.565e-06 -5.255 -5.255 0.000 - CaOH+ 1.762e-08 1.651e-08 -7.754 -7.782 -0.028 - CaHSO4+ 2.108e-12 1.976e-12 -11.676 -11.704 -0.028 -Cl 5.000e-04 - Cl- 5.000e-04 4.682e-04 -3.301 -3.330 -0.029 - FeCl+ 4.293e-12 4.023e-12 -11.367 -11.396 -0.028 - FeCl+2 5.629e-28 4.339e-28 -27.250 -27.363 -0.113 - FeCl2+ 9.686e-31 9.076e-31 -30.014 -30.042 -0.028 - FeCl3 4.246e-35 4.250e-35 -34.372 -34.372 0.000 -Fe(2) 9.939e-09 - Fe+2 8.002e-09 6.223e-09 -8.097 -8.206 -0.109 - FeCO3 7.363e-10 7.369e-10 -9.133 -9.133 0.000 - FeHCO3+ 4.715e-10 4.418e-10 -9.327 -9.355 -0.028 - FeSO4 4.129e-10 4.132e-10 -9.384 -9.384 0.000 - FeOH+ 3.114e-10 2.918e-10 -9.507 -9.535 -0.028 - FeCl+ 4.293e-12 4.023e-12 -11.367 -11.396 -0.028 - FeHSO4+ 1.955e-17 1.832e-17 -16.709 -16.737 -0.028 - Fe(HS)2 5.043e-18 5.047e-18 -17.297 -17.297 0.000 - Fe(HS)3- 5.596e-25 5.243e-25 -24.252 -24.280 -0.028 -Fe(3) 3.303e-14 - Fe(OH)3 2.752e-14 2.754e-14 -13.560 -13.560 0.000 - Fe(OH)4- 3.974e-15 3.724e-15 -14.401 -14.429 -0.028 - Fe(OH)2+ 1.539e-15 1.442e-15 -14.813 -14.841 -0.028 - FeOH+2 3.810e-20 2.937e-20 -19.419 -19.532 -0.113 - FeSO4+ 1.341e-25 1.256e-25 -24.873 -24.901 -0.028 - Fe+3 5.252e-26 3.069e-26 -25.280 -25.513 -0.233 - Fe(SO4)2- 1.095e-27 1.026e-27 -26.960 -26.989 -0.028 - FeCl+2 5.629e-28 4.339e-28 -27.250 -27.363 -0.113 - FeCl2+ 9.686e-31 9.076e-31 -30.014 -30.042 -0.028 - FeHSO4+2 2.943e-33 2.269e-33 -32.531 -32.644 -0.113 - FeCl3 4.246e-35 4.250e-35 -34.372 -34.372 0.000 - Fe2(OH)2+4 6.575e-38 2.322e-38 -37.182 -37.634 -0.452 - Fe3(OH)4+5 0.000e+00 0.000e+00 -49.449 -50.155 -0.706 -H(0) 2.414e-11 - H2 1.207e-11 1.208e-11 -10.918 -10.918 0.000 -Na 5.000e-04 - Na+ 4.988e-04 4.677e-04 -3.302 -3.330 -0.028 - NaSO4- 9.340e-07 8.752e-07 -6.030 -6.058 -0.028 - NaHCO3 1.865e-07 1.867e-07 -6.729 -6.729 0.000 - NaCO3- 4.587e-08 4.298e-08 -7.338 -7.367 -0.028 - NaOH 4.577e-10 4.581e-10 -9.339 -9.339 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -70.545 -70.544 0.000 -S(-2) 1.075e-09 - HS- 1.019e-09 9.540e-10 -8.992 -9.020 -0.029 - H2S 5.621e-11 5.626e-11 -10.250 -10.250 0.000 - S-2 2.207e-14 1.708e-14 -13.656 -13.767 -0.111 - Fe(HS)2 5.043e-18 5.047e-18 -17.297 -17.297 0.000 - Fe(HS)3- 5.596e-25 5.243e-25 -24.252 -24.280 -0.028 -S(6) 5.333e-04 - SO4-2 4.824e-04 3.734e-04 -3.317 -3.428 -0.111 - CaSO4 4.996e-05 5.000e-05 -4.301 -4.301 0.000 - NaSO4- 9.340e-07 8.752e-07 -6.030 -6.058 -0.028 - FeSO4 4.129e-10 4.132e-10 -9.384 -9.384 0.000 - HSO4- 2.613e-10 2.449e-10 -9.583 -9.611 -0.028 - CaHSO4+ 2.108e-12 1.976e-12 -11.676 -11.704 -0.028 - FeHSO4+ 1.955e-17 1.832e-17 -16.709 -16.737 -0.028 - FeSO4+ 1.341e-25 1.256e-25 -24.873 -24.901 -0.028 - Fe(SO4)2- 1.095e-27 1.026e-27 -26.960 -26.989 -0.028 - FeHSO4+2 2.943e-33 2.269e-33 -32.531 -32.644 -0.113 + OH- 1.585e-06 1.484e-06 -5.800 -5.829 -0.029 (0) + H+ 7.160e-09 6.745e-09 -8.145 -8.171 -0.026 0.00 + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +C(-4) 2.240e-12 + CH4 2.240e-12 2.242e-12 -11.650 -11.649 0.000 (0) +C(4) 7.859e-04 + HCO3- 7.565e-04 7.099e-04 -3.121 -3.149 -0.028 24.29 + CO2 1.076e-05 1.077e-05 -4.968 -4.968 0.000 (0) + CaHCO3+ 6.477e-06 6.078e-06 -5.189 -5.216 -0.028 (0) + CO3-2 6.364e-06 4.936e-06 -5.196 -5.307 -0.110 -3.78 + CaCO3 5.560e-06 5.565e-06 -5.255 -5.255 0.000 (0) + NaHCO3 1.865e-07 1.867e-07 -6.729 -6.729 0.000 (0) + NaCO3- 4.587e-08 4.298e-08 -7.338 -7.367 -0.028 (0) + FeCO3 7.363e-10 7.369e-10 -9.133 -9.133 0.000 (0) + FeHCO3+ 4.715e-10 4.418e-10 -9.327 -9.355 -0.028 (0) +Ca 9.277e-04 + Ca+2 8.657e-04 6.711e-04 -3.063 -3.173 -0.111 -17.83 + CaSO4 4.996e-05 5.000e-05 -4.301 -4.301 0.000 (0) + CaHCO3+ 6.477e-06 6.078e-06 -5.189 -5.216 -0.028 (0) + CaCO3 5.560e-06 5.565e-06 -5.255 -5.255 0.000 (0) + CaOH+ 1.762e-08 1.651e-08 -7.754 -7.782 -0.028 (0) + CaHSO4+ 2.108e-12 1.976e-12 -11.676 -11.704 -0.028 (0) +Cl 5.000e-04 + Cl- 5.000e-04 4.682e-04 -3.301 -3.330 -0.029 17.82 + FeCl+ 4.293e-12 4.023e-12 -11.367 -11.396 -0.028 (0) + FeCl+2 5.629e-28 4.339e-28 -27.250 -27.363 -0.113 (0) + FeCl2+ 9.686e-31 9.076e-31 -30.014 -30.042 -0.028 (0) + FeCl3 4.246e-35 4.250e-35 -34.372 -34.372 0.000 (0) +Fe(2) 9.939e-09 + Fe+2 8.002e-09 6.223e-09 -8.097 -8.206 -0.109 (0) + FeCO3 7.363e-10 7.369e-10 -9.133 -9.133 0.000 (0) + FeHCO3+ 4.715e-10 4.418e-10 -9.327 -9.355 -0.028 (0) + FeSO4 4.129e-10 4.132e-10 -9.384 -9.384 0.000 (0) + FeOH+ 3.114e-10 2.918e-10 -9.507 -9.535 -0.028 (0) + FeCl+ 4.293e-12 4.023e-12 -11.367 -11.396 -0.028 (0) + FeHSO4+ 1.955e-17 1.832e-17 -16.709 -16.737 -0.028 (0) + Fe(HS)2 5.043e-18 5.047e-18 -17.297 -17.297 0.000 (0) + Fe(HS)3- 5.596e-25 5.243e-25 -24.252 -24.280 -0.028 (0) +Fe(3) 3.303e-14 + Fe(OH)3 2.752e-14 2.754e-14 -13.560 -13.560 0.000 (0) + Fe(OH)4- 3.974e-15 3.724e-15 -14.401 -14.429 -0.028 (0) + Fe(OH)2+ 1.539e-15 1.442e-15 -14.813 -14.841 -0.028 (0) + FeOH+2 3.810e-20 2.937e-20 -19.419 -19.532 -0.113 (0) + FeSO4+ 1.341e-25 1.256e-25 -24.873 -24.901 -0.028 (0) + Fe+3 5.252e-26 3.069e-26 -25.280 -25.513 -0.233 (0) + Fe(SO4)2- 1.095e-27 1.026e-27 -26.960 -26.989 -0.028 (0) + FeCl+2 5.629e-28 4.339e-28 -27.250 -27.363 -0.113 (0) + FeCl2+ 9.686e-31 9.076e-31 -30.014 -30.042 -0.028 (0) + FeHSO4+2 2.943e-33 2.269e-33 -32.531 -32.644 -0.113 (0) + FeCl3 4.246e-35 4.250e-35 -34.372 -34.372 0.000 (0) + Fe2(OH)2+4 6.575e-38 2.322e-38 -37.182 -37.634 -0.452 (0) + Fe3(OH)4+5 0.000e+00 0.000e+00 -49.449 -50.155 -0.706 (0) +H(0) 2.414e-11 + H2 1.207e-11 1.208e-11 -10.918 -10.918 0.000 (0) +Na 5.000e-04 + Na+ 4.988e-04 4.677e-04 -3.302 -3.330 -0.028 -1.21 + NaSO4- 9.340e-07 8.752e-07 -6.030 -6.058 -0.028 (0) + NaHCO3 1.865e-07 1.867e-07 -6.729 -6.729 0.000 (0) + NaCO3- 4.587e-08 4.298e-08 -7.338 -7.367 -0.028 (0) + NaOH 4.577e-10 4.581e-10 -9.339 -9.339 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -70.545 -70.544 0.000 (0) +S(-2) 1.075e-09 + HS- 1.019e-09 9.540e-10 -8.992 -9.020 -0.029 (0) + H2S 5.621e-11 5.626e-11 -10.250 -10.250 0.000 (0) + S-2 2.207e-14 1.708e-14 -13.656 -13.767 -0.111 (0) + Fe(HS)2 5.043e-18 5.047e-18 -17.297 -17.297 0.000 (0) + Fe(HS)3- 5.596e-25 5.243e-25 -24.252 -24.280 -0.028 (0) +S(6) 5.333e-04 + SO4-2 4.824e-04 3.734e-04 -3.317 -3.428 -0.111 13.98 + CaSO4 4.996e-05 5.000e-05 -4.301 -4.301 0.000 (0) + NaSO4- 9.340e-07 8.752e-07 -6.030 -6.058 -0.028 (0) + FeSO4 4.129e-10 4.132e-10 -9.384 -9.384 0.000 (0) + HSO4- 2.613e-10 2.449e-10 -9.583 -9.611 -0.028 (0) + CaHSO4+ 2.108e-12 1.976e-12 -11.676 -11.704 -0.028 (0) + FeHSO4+ 1.955e-17 1.832e-17 -16.709 -16.737 -0.028 (0) + FeSO4+ 1.341e-25 1.256e-25 -24.873 -24.901 -0.028 (0) + Fe(SO4)2- 1.095e-27 1.026e-27 -26.960 -26.989 -0.028 (0) + FeHSO4+2 2.943e-33 2.269e-33 -32.531 -32.644 -0.113 (0) ------------------------------Saturation indices------------------------------- @@ -501,88 +501,88 @@ Pyrite 0.00 -18.48 -18.48 1.000e+01 9.999e+00 -1.333e-03 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.077e-06 9.604e-07 -5.968 -6.018 -0.050 - H+ 1.149e-08 1.042e-08 -7.940 -7.982 -0.042 - H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 -C(-4) 2.129e-13 - CH4 2.129e-13 2.135e-13 -12.672 -12.671 0.001 -C(4) 5.424e-04 - HCO3- 5.118e-04 4.594e-04 -3.291 -3.338 -0.047 - CO2 1.074e-05 1.077e-05 -4.969 -4.968 0.001 - CaHCO3+ 1.046e-05 9.392e-06 -4.980 -5.027 -0.047 - CaCO3 5.549e-06 5.565e-06 -5.256 -5.255 0.001 - CO3-2 3.184e-06 2.067e-06 -5.497 -5.685 -0.188 - NaHCO3 5.724e-07 5.740e-07 -6.242 -6.241 0.001 - NaCO3- 9.566e-08 8.553e-08 -7.019 -7.068 -0.049 - FeHCO3+ 5.691e-10 5.088e-10 -9.245 -9.293 -0.049 - FeCO3 5.477e-10 5.493e-10 -9.261 -9.260 0.001 -Ca 2.937e-03 - Ca+2 2.469e-03 1.602e-03 -2.607 -2.795 -0.188 - CaSO4 4.520e-04 4.532e-04 -3.345 -3.344 0.001 - CaHCO3+ 1.046e-05 9.392e-06 -4.980 -5.027 -0.047 - CaCO3 5.549e-06 5.565e-06 -5.256 -5.255 0.001 - CaOH+ 2.854e-08 2.551e-08 -7.545 -7.593 -0.049 - CaHSO4+ 3.095e-11 2.767e-11 -10.509 -10.558 -0.049 -Cl 2.500e-03 - Cl- 2.500e-03 2.230e-03 -2.602 -2.652 -0.050 - FeCl+ 3.814e-11 3.410e-11 -10.419 -10.467 -0.049 - FeCl+2 1.194e-26 7.627e-27 -25.923 -26.118 -0.194 - FeCl2+ 8.499e-29 7.599e-29 -28.071 -28.119 -0.049 - FeCl3 1.690e-32 1.695e-32 -31.772 -31.771 0.001 -Fe(2) 2.124e-08 - Fe+2 1.693e-08 1.108e-08 -7.771 -7.956 -0.184 - FeSO4 2.784e-09 2.792e-09 -8.555 -8.554 0.001 - FeHCO3+ 5.691e-10 5.088e-10 -9.245 -9.293 -0.049 - FeCO3 5.477e-10 5.493e-10 -9.261 -9.260 0.001 - FeOH+ 3.758e-10 3.360e-10 -9.425 -9.474 -0.049 - FeCl+ 3.814e-11 3.410e-11 -10.419 -10.467 -0.049 - FeHSO4+ 2.139e-16 1.913e-16 -15.670 -15.718 -0.049 - Fe(HS)2 2.796e-18 2.804e-18 -17.553 -17.552 0.001 - Fe(HS)3- 1.820e-25 1.627e-25 -24.740 -24.789 -0.049 -Fe(3) 3.265e-14 - Fe(OH)3 2.746e-14 2.754e-14 -13.561 -13.560 0.001 - Fe(OH)4- 2.695e-15 2.409e-15 -14.569 -14.618 -0.049 - Fe(OH)2+ 2.492e-15 2.228e-15 -14.603 -14.652 -0.049 - FeOH+2 1.098e-19 7.014e-20 -18.960 -19.154 -0.194 - FeSO4+ 1.968e-24 1.760e-24 -23.706 -23.755 -0.049 - Fe+3 2.720e-25 1.132e-25 -24.566 -24.946 -0.381 - Fe(SO4)2- 6.105e-26 5.458e-26 -25.214 -25.263 -0.049 - FeCl+2 1.194e-26 7.627e-27 -25.923 -26.118 -0.194 - FeCl2+ 8.499e-29 7.599e-29 -28.071 -28.119 -0.049 - FeHSO4+2 7.686e-32 4.911e-32 -31.114 -31.309 -0.194 - FeCl3 1.690e-32 1.695e-32 -31.772 -31.771 0.001 - Fe2(OH)2+4 7.941e-37 1.324e-37 -36.100 -36.878 -0.778 - Fe3(OH)4+5 0.000e+00 0.000e+00 -47.995 -49.210 -1.216 -H(0) 1.338e-11 - H2 6.691e-12 6.710e-12 -11.174 -11.173 0.001 -Na 2.500e-03 - Na+ 2.482e-03 2.222e-03 -2.605 -2.653 -0.048 - NaSO4- 1.766e-05 1.579e-05 -4.753 -4.802 -0.049 - NaHCO3 5.724e-07 5.740e-07 -6.242 -6.241 0.001 - NaCO3- 9.566e-08 8.553e-08 -7.019 -7.068 -0.049 - NaOH 1.404e-09 1.408e-09 -8.853 -8.851 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -70.035 -70.034 0.001 -S(-2) 6.460e-10 - HS- 5.976e-10 5.329e-10 -9.224 -9.273 -0.050 - H2S 4.843e-11 4.856e-11 -10.315 -10.314 0.001 - S-2 9.562e-15 6.176e-15 -14.019 -14.209 -0.190 - Fe(HS)2 2.796e-18 2.804e-18 -17.553 -17.552 0.001 - Fe(HS)3- 1.820e-25 1.627e-25 -24.740 -24.789 -0.049 -S(6) 2.667e-03 - SO4-2 2.197e-03 1.418e-03 -2.658 -2.848 -0.190 - CaSO4 4.520e-04 4.532e-04 -3.345 -3.344 0.001 - NaSO4- 1.766e-05 1.579e-05 -4.753 -4.802 -0.049 - FeSO4 2.784e-09 2.792e-09 -8.555 -8.554 0.001 - HSO4- 1.606e-09 1.436e-09 -8.794 -8.843 -0.049 - CaHSO4+ 3.095e-11 2.767e-11 -10.509 -10.558 -0.049 - FeHSO4+ 2.139e-16 1.913e-16 -15.670 -15.718 -0.049 - FeSO4+ 1.968e-24 1.760e-24 -23.706 -23.755 -0.049 - Fe(SO4)2- 6.105e-26 5.458e-26 -25.214 -25.263 -0.049 - FeHSO4+2 7.686e-32 4.911e-32 -31.114 -31.309 -0.194 + OH- 1.077e-06 9.604e-07 -5.968 -6.018 -0.050 (0) + H+ 1.149e-08 1.042e-08 -7.940 -7.982 -0.042 0.00 + H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 18.07 +C(-4) 2.129e-13 + CH4 2.129e-13 2.135e-13 -12.672 -12.671 0.001 (0) +C(4) 5.424e-04 + HCO3- 5.118e-04 4.594e-04 -3.291 -3.338 -0.047 24.29 + CO2 1.074e-05 1.077e-05 -4.969 -4.968 0.001 (0) + CaHCO3+ 1.046e-05 9.392e-06 -4.980 -5.027 -0.047 (0) + CaCO3 5.549e-06 5.565e-06 -5.256 -5.255 0.001 (0) + CO3-2 3.184e-06 2.067e-06 -5.497 -5.685 -0.188 -3.78 + NaHCO3 5.724e-07 5.740e-07 -6.242 -6.241 0.001 (0) + NaCO3- 9.566e-08 8.553e-08 -7.019 -7.068 -0.049 (0) + FeHCO3+ 5.691e-10 5.088e-10 -9.245 -9.293 -0.049 (0) + FeCO3 5.477e-10 5.493e-10 -9.261 -9.260 0.001 (0) +Ca 2.937e-03 + Ca+2 2.469e-03 1.602e-03 -2.607 -2.795 -0.188 -17.83 + CaSO4 4.520e-04 4.532e-04 -3.345 -3.344 0.001 (0) + CaHCO3+ 1.046e-05 9.392e-06 -4.980 -5.027 -0.047 (0) + CaCO3 5.549e-06 5.565e-06 -5.256 -5.255 0.001 (0) + CaOH+ 2.854e-08 2.551e-08 -7.545 -7.593 -0.049 (0) + CaHSO4+ 3.095e-11 2.767e-11 -10.509 -10.558 -0.049 (0) +Cl 2.500e-03 + Cl- 2.500e-03 2.230e-03 -2.602 -2.652 -0.050 17.82 + FeCl+ 3.814e-11 3.410e-11 -10.419 -10.467 -0.049 (0) + FeCl+2 1.194e-26 7.627e-27 -25.923 -26.118 -0.194 (0) + FeCl2+ 8.499e-29 7.599e-29 -28.071 -28.119 -0.049 (0) + FeCl3 1.690e-32 1.695e-32 -31.772 -31.771 0.001 (0) +Fe(2) 2.124e-08 + Fe+2 1.693e-08 1.108e-08 -7.771 -7.956 -0.184 (0) + FeSO4 2.784e-09 2.792e-09 -8.555 -8.554 0.001 (0) + FeHCO3+ 5.691e-10 5.088e-10 -9.245 -9.293 -0.049 (0) + FeCO3 5.477e-10 5.493e-10 -9.261 -9.260 0.001 (0) + FeOH+ 3.758e-10 3.360e-10 -9.425 -9.474 -0.049 (0) + FeCl+ 3.814e-11 3.410e-11 -10.419 -10.467 -0.049 (0) + FeHSO4+ 2.139e-16 1.913e-16 -15.670 -15.718 -0.049 (0) + Fe(HS)2 2.796e-18 2.804e-18 -17.553 -17.552 0.001 (0) + Fe(HS)3- 1.820e-25 1.627e-25 -24.740 -24.789 -0.049 (0) +Fe(3) 3.265e-14 + Fe(OH)3 2.746e-14 2.754e-14 -13.561 -13.560 0.001 (0) + Fe(OH)4- 2.695e-15 2.409e-15 -14.569 -14.618 -0.049 (0) + Fe(OH)2+ 2.492e-15 2.228e-15 -14.603 -14.652 -0.049 (0) + FeOH+2 1.098e-19 7.014e-20 -18.960 -19.154 -0.194 (0) + FeSO4+ 1.968e-24 1.760e-24 -23.706 -23.755 -0.049 (0) + Fe+3 2.720e-25 1.132e-25 -24.566 -24.946 -0.381 (0) + Fe(SO4)2- 6.105e-26 5.458e-26 -25.214 -25.263 -0.049 (0) + FeCl+2 1.194e-26 7.627e-27 -25.923 -26.118 -0.194 (0) + FeCl2+ 8.499e-29 7.599e-29 -28.071 -28.119 -0.049 (0) + FeHSO4+2 7.686e-32 4.911e-32 -31.114 -31.309 -0.194 (0) + FeCl3 1.690e-32 1.695e-32 -31.772 -31.771 0.001 (0) + Fe2(OH)2+4 7.941e-37 1.324e-37 -36.100 -36.878 -0.778 (0) + Fe3(OH)4+5 0.000e+00 0.000e+00 -47.995 -49.210 -1.216 (0) +H(0) 1.338e-11 + H2 6.691e-12 6.710e-12 -11.174 -11.173 0.001 (0) +Na 2.500e-03 + Na+ 2.482e-03 2.222e-03 -2.605 -2.653 -0.048 -1.21 + NaSO4- 1.766e-05 1.579e-05 -4.753 -4.802 -0.049 (0) + NaHCO3 5.724e-07 5.740e-07 -6.242 -6.241 0.001 (0) + NaCO3- 9.566e-08 8.553e-08 -7.019 -7.068 -0.049 (0) + NaOH 1.404e-09 1.408e-09 -8.853 -8.851 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -70.035 -70.034 0.001 (0) +S(-2) 6.460e-10 + HS- 5.976e-10 5.329e-10 -9.224 -9.273 -0.050 (0) + H2S 4.843e-11 4.856e-11 -10.315 -10.314 0.001 (0) + S-2 9.562e-15 6.176e-15 -14.019 -14.209 -0.190 (0) + Fe(HS)2 2.796e-18 2.804e-18 -17.553 -17.552 0.001 (0) + Fe(HS)3- 1.820e-25 1.627e-25 -24.740 -24.789 -0.049 (0) +S(6) 2.667e-03 + SO4-2 2.197e-03 1.418e-03 -2.658 -2.848 -0.190 13.98 + CaSO4 4.520e-04 4.532e-04 -3.345 -3.344 0.001 (0) + NaSO4- 1.766e-05 1.579e-05 -4.753 -4.802 -0.049 (0) + FeSO4 2.784e-09 2.792e-09 -8.555 -8.554 0.001 (0) + HSO4- 1.606e-09 1.436e-09 -8.794 -8.843 -0.049 (0) + CaHSO4+ 3.095e-11 2.767e-11 -10.509 -10.558 -0.049 (0) + FeHSO4+ 2.139e-16 1.913e-16 -15.670 -15.718 -0.049 (0) + FeSO4+ 1.968e-24 1.760e-24 -23.706 -23.755 -0.049 (0) + Fe(SO4)2- 6.105e-26 5.458e-26 -25.214 -25.263 -0.049 (0) + FeHSO4+2 7.686e-32 4.911e-32 -31.114 -31.309 -0.194 (0) ------------------------------Saturation indices------------------------------- @@ -674,88 +674,88 @@ Pyrite -0.00 -18.48 -18.48 1.000e+01 9.997e+00 -2.667e-03 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 8.898e-07 7.665e-07 -6.051 -6.115 -0.065 - H+ 1.474e-08 1.306e-08 -7.832 -7.884 -0.053 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -C(-4) 7.696e-14 - CH4 7.696e-14 7.735e-14 -13.114 -13.112 0.002 -C(4) 4.540e-04 - HCO3- 4.210e-04 3.666e-04 -3.376 -3.436 -0.060 - CaHCO3+ 1.351e-05 1.177e-05 -4.869 -4.929 -0.060 - CO2 1.071e-05 1.077e-05 -4.970 -4.968 0.002 - CaCO3 5.536e-06 5.565e-06 -5.257 -5.255 0.002 - CO3-2 2.289e-06 1.317e-06 -5.640 -5.880 -0.240 - NaHCO3 8.791e-07 8.836e-07 -6.056 -6.054 0.002 - NaCO3- 1.214e-07 1.051e-07 -6.916 -6.978 -0.063 - FeHCO3+ 6.487e-10 5.616e-10 -9.188 -9.251 -0.063 - FeCO3 4.814e-10 4.839e-10 -9.317 -9.315 0.002 -Ca 5.560e-03 - Ca+2 4.373e-03 2.515e-03 -2.359 -2.599 -0.240 - CaSO4 1.168e-03 1.174e-03 -2.933 -2.930 0.002 - CaHCO3+ 1.351e-05 1.177e-05 -4.869 -4.929 -0.060 - CaCO3 5.536e-06 5.565e-06 -5.257 -5.255 0.002 - CaOH+ 3.692e-08 3.196e-08 -7.433 -7.495 -0.063 - CaHSO4+ 1.037e-10 8.977e-11 -9.984 -10.047 -0.063 -Cl 5.000e-03 - Cl- 5.000e-03 4.311e-03 -2.301 -2.365 -0.064 - FeCl+ 1.053e-10 9.114e-11 -9.978 -10.040 -0.063 - FeCl+2 5.162e-26 2.899e-26 -25.287 -25.538 -0.251 - FeCl2+ 6.449e-28 5.583e-28 -27.191 -27.253 -0.063 - FeCl3 2.394e-31 2.406e-31 -30.621 -30.619 0.002 -Fe(2) 3.429e-08 - Fe+2 2.629e-08 1.532e-08 -7.580 -7.815 -0.235 - FeSO4 6.337e-09 6.369e-09 -8.198 -8.196 0.002 - FeHCO3+ 6.487e-10 5.616e-10 -9.188 -9.251 -0.063 - FeCO3 4.814e-10 4.839e-10 -9.317 -9.315 0.002 - FeOH+ 4.284e-10 3.708e-10 -9.368 -9.431 -0.063 - FeCl+ 1.053e-10 9.114e-11 -9.978 -10.040 -0.063 - FeHSO4+ 6.314e-16 5.466e-16 -15.200 -15.262 -0.063 - Fe(HS)2 2.164e-18 2.175e-18 -17.665 -17.663 0.002 - Fe(HS)3- 1.092e-25 9.454e-26 -24.962 -25.024 -0.063 -Fe(3) 3.284e-14 - Fe(OH)3 2.739e-14 2.753e-14 -13.562 -13.560 0.002 - Fe(OH)2+ 3.224e-15 2.791e-15 -14.492 -14.554 -0.063 - Fe(OH)4- 2.221e-15 1.923e-15 -14.653 -14.716 -0.063 - FeOH+2 1.960e-19 1.101e-19 -18.708 -18.958 -0.251 - FeSO4+ 6.596e-24 5.710e-24 -23.181 -23.243 -0.063 - Fe+3 6.635e-25 2.227e-25 -24.178 -24.652 -0.474 - Fe(SO4)2- 3.374e-25 2.921e-25 -24.472 -24.534 -0.063 - FeCl+2 5.162e-26 2.899e-26 -25.287 -25.538 -0.251 - FeCl2+ 6.449e-28 5.583e-28 -27.191 -27.253 -0.063 - FeHSO4+2 3.555e-31 1.996e-31 -30.449 -30.700 -0.251 - FeCl3 2.394e-31 2.406e-31 -30.621 -30.619 0.002 - Fe2(OH)2+4 3.279e-36 3.263e-37 -35.484 -36.486 -1.002 - Fe3(OH)4+5 0.000e+00 0.000e+00 -47.155 -48.721 -1.566 -H(0) 1.036e-11 - H2 5.179e-12 5.205e-12 -11.286 -11.284 0.002 -Na 5.000e-03 - Na+ 4.941e-03 4.286e-03 -2.306 -2.368 -0.062 - NaSO4- 5.802e-05 5.023e-05 -4.236 -4.299 -0.063 - NaHCO3 8.791e-07 8.836e-07 -6.056 -6.054 0.002 - NaCO3- 1.214e-07 1.051e-07 -6.916 -6.978 -0.063 - NaOH 2.157e-09 2.168e-09 -8.666 -8.664 0.002 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -69.815 -69.813 0.002 -S(-2) 5.087e-10 - HS- 4.634e-10 3.992e-10 -9.334 -9.399 -0.065 - H2S 4.533e-11 4.557e-11 -10.344 -10.341 0.002 - S-2 6.474e-15 3.693e-15 -14.189 -14.433 -0.244 - Fe(HS)2 2.164e-18 2.175e-18 -17.665 -17.663 0.002 - Fe(HS)3- 1.092e-25 9.454e-26 -24.962 -25.024 -0.063 -S(6) 5.333e-03 - SO4-2 4.108e-03 2.338e-03 -2.386 -2.631 -0.245 - CaSO4 1.168e-03 1.174e-03 -2.933 -2.930 0.002 - NaSO4- 5.802e-05 5.023e-05 -4.236 -4.299 -0.063 - FeSO4 6.337e-09 6.369e-09 -8.198 -8.196 0.002 - HSO4- 3.429e-09 2.968e-09 -8.465 -8.527 -0.063 - CaHSO4+ 1.037e-10 8.977e-11 -9.984 -10.047 -0.063 - FeHSO4+ 6.314e-16 5.466e-16 -15.200 -15.262 -0.063 - FeSO4+ 6.596e-24 5.710e-24 -23.181 -23.243 -0.063 - Fe(SO4)2- 3.374e-25 2.921e-25 -24.472 -24.534 -0.063 - FeHSO4+2 3.555e-31 1.996e-31 -30.449 -30.700 -0.251 + OH- 8.898e-07 7.665e-07 -6.051 -6.115 -0.065 (0) + H+ 1.474e-08 1.306e-08 -7.832 -7.884 -0.053 0.00 + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.07 +C(-4) 7.696e-14 + CH4 7.696e-14 7.735e-14 -13.114 -13.112 0.002 (0) +C(4) 4.540e-04 + HCO3- 4.210e-04 3.666e-04 -3.376 -3.436 -0.060 24.29 + CaHCO3+ 1.351e-05 1.177e-05 -4.869 -4.929 -0.060 (0) + CO2 1.071e-05 1.077e-05 -4.970 -4.968 0.002 (0) + CaCO3 5.536e-06 5.565e-06 -5.257 -5.255 0.002 (0) + CO3-2 2.289e-06 1.317e-06 -5.640 -5.880 -0.240 -3.78 + NaHCO3 8.791e-07 8.836e-07 -6.056 -6.054 0.002 (0) + NaCO3- 1.214e-07 1.051e-07 -6.916 -6.978 -0.063 (0) + FeHCO3+ 6.487e-10 5.616e-10 -9.188 -9.251 -0.063 (0) + FeCO3 4.814e-10 4.839e-10 -9.317 -9.315 0.002 (0) +Ca 5.560e-03 + Ca+2 4.373e-03 2.515e-03 -2.359 -2.599 -0.240 -17.83 + CaSO4 1.168e-03 1.174e-03 -2.933 -2.930 0.002 (0) + CaHCO3+ 1.351e-05 1.177e-05 -4.869 -4.929 -0.060 (0) + CaCO3 5.536e-06 5.565e-06 -5.257 -5.255 0.002 (0) + CaOH+ 3.692e-08 3.196e-08 -7.433 -7.495 -0.063 (0) + CaHSO4+ 1.037e-10 8.977e-11 -9.984 -10.047 -0.063 (0) +Cl 5.000e-03 + Cl- 5.000e-03 4.311e-03 -2.301 -2.365 -0.064 17.82 + FeCl+ 1.053e-10 9.114e-11 -9.978 -10.040 -0.063 (0) + FeCl+2 5.162e-26 2.899e-26 -25.287 -25.538 -0.251 (0) + FeCl2+ 6.449e-28 5.583e-28 -27.191 -27.253 -0.063 (0) + FeCl3 2.394e-31 2.406e-31 -30.621 -30.619 0.002 (0) +Fe(2) 3.429e-08 + Fe+2 2.629e-08 1.532e-08 -7.580 -7.815 -0.235 (0) + FeSO4 6.337e-09 6.369e-09 -8.198 -8.196 0.002 (0) + FeHCO3+ 6.487e-10 5.616e-10 -9.188 -9.251 -0.063 (0) + FeCO3 4.814e-10 4.839e-10 -9.317 -9.315 0.002 (0) + FeOH+ 4.284e-10 3.708e-10 -9.368 -9.431 -0.063 (0) + FeCl+ 1.053e-10 9.114e-11 -9.978 -10.040 -0.063 (0) + FeHSO4+ 6.314e-16 5.466e-16 -15.200 -15.262 -0.063 (0) + Fe(HS)2 2.164e-18 2.175e-18 -17.665 -17.663 0.002 (0) + Fe(HS)3- 1.092e-25 9.454e-26 -24.962 -25.024 -0.063 (0) +Fe(3) 3.284e-14 + Fe(OH)3 2.739e-14 2.753e-14 -13.562 -13.560 0.002 (0) + Fe(OH)2+ 3.224e-15 2.791e-15 -14.492 -14.554 -0.063 (0) + Fe(OH)4- 2.221e-15 1.923e-15 -14.653 -14.716 -0.063 (0) + FeOH+2 1.960e-19 1.101e-19 -18.708 -18.958 -0.251 (0) + FeSO4+ 6.596e-24 5.710e-24 -23.181 -23.243 -0.063 (0) + Fe+3 6.635e-25 2.227e-25 -24.178 -24.652 -0.474 (0) + Fe(SO4)2- 3.374e-25 2.921e-25 -24.472 -24.534 -0.063 (0) + FeCl+2 5.162e-26 2.899e-26 -25.287 -25.538 -0.251 (0) + FeCl2+ 6.449e-28 5.583e-28 -27.191 -27.253 -0.063 (0) + FeHSO4+2 3.555e-31 1.996e-31 -30.449 -30.700 -0.251 (0) + FeCl3 2.394e-31 2.406e-31 -30.621 -30.619 0.002 (0) + Fe2(OH)2+4 3.279e-36 3.263e-37 -35.484 -36.486 -1.002 (0) + Fe3(OH)4+5 0.000e+00 0.000e+00 -47.155 -48.721 -1.566 (0) +H(0) 1.036e-11 + H2 5.179e-12 5.205e-12 -11.286 -11.284 0.002 (0) +Na 5.000e-03 + Na+ 4.941e-03 4.286e-03 -2.306 -2.368 -0.062 -1.21 + NaSO4- 5.802e-05 5.023e-05 -4.236 -4.299 -0.063 (0) + NaHCO3 8.791e-07 8.836e-07 -6.056 -6.054 0.002 (0) + NaCO3- 1.214e-07 1.051e-07 -6.916 -6.978 -0.063 (0) + NaOH 2.157e-09 2.168e-09 -8.666 -8.664 0.002 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -69.815 -69.813 0.002 (0) +S(-2) 5.087e-10 + HS- 4.634e-10 3.992e-10 -9.334 -9.399 -0.065 (0) + H2S 4.533e-11 4.557e-11 -10.344 -10.341 0.002 (0) + S-2 6.474e-15 3.693e-15 -14.189 -14.433 -0.244 (0) + Fe(HS)2 2.164e-18 2.175e-18 -17.665 -17.663 0.002 (0) + Fe(HS)3- 1.092e-25 9.454e-26 -24.962 -25.024 -0.063 (0) +S(6) 5.333e-03 + SO4-2 4.108e-03 2.338e-03 -2.386 -2.631 -0.245 13.98 + CaSO4 1.168e-03 1.174e-03 -2.933 -2.930 0.002 (0) + NaSO4- 5.802e-05 5.023e-05 -4.236 -4.299 -0.063 (0) + FeSO4 6.337e-09 6.369e-09 -8.198 -8.196 0.002 (0) + HSO4- 3.429e-09 2.968e-09 -8.465 -8.527 -0.063 (0) + CaHSO4+ 1.037e-10 8.977e-11 -9.984 -10.047 -0.063 (0) + FeHSO4+ 6.314e-16 5.466e-16 -15.200 -15.262 -0.063 (0) + FeSO4+ 6.596e-24 5.710e-24 -23.181 -23.243 -0.063 (0) + Fe(SO4)2- 3.374e-25 2.921e-25 -24.472 -24.534 -0.063 (0) + FeHSO4+2 3.555e-31 1.996e-31 -30.449 -30.700 -0.251 (0) ------------------------------Saturation indices------------------------------- @@ -847,88 +847,88 @@ Pyrite 0.00 -18.48 -18.48 1.000e+01 9.992e+00 -8.000e-03 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 6.713e-07 5.368e-07 -6.173 -6.270 -0.097 - H+ 2.200e-08 1.863e-08 -7.658 -7.730 -0.072 - H2O 5.551e+01 9.990e-01 1.744 -0.000 0.000 -C(-4) 1.669e-14 - CH4 1.669e-14 1.693e-14 -13.777 -13.771 0.006 -C(4) 3.535e-04 - HCO3- 3.135e-04 2.568e-04 -3.504 -3.590 -0.087 - CaHCO3+ 2.050e-05 1.679e-05 -4.688 -4.775 -0.087 - CO2 1.062e-05 1.077e-05 -4.974 -4.968 0.006 - CaCO3 5.489e-06 5.565e-06 -5.261 -5.255 0.006 - NaHCO3 1.697e-06 1.721e-06 -5.770 -5.764 0.006 - CO3-2 1.437e-06 6.464e-07 -5.843 -6.190 -0.347 - NaCO3- 1.768e-07 1.434e-07 -6.753 -6.843 -0.091 - FeHCO3+ 8.172e-10 6.630e-10 -9.088 -9.178 -0.091 - FeCO3 3.949e-10 4.003e-10 -9.404 -9.398 0.006 -Ca 1.618e-02 - Ca+2 1.135e-02 5.125e-03 -1.945 -2.290 -0.345 - CaSO4 4.805e-03 4.871e-03 -2.318 -2.312 0.006 - CaHCO3+ 2.050e-05 1.679e-05 -4.688 -4.775 -0.087 - CaCO3 5.489e-06 5.565e-06 -5.261 -5.255 0.006 - CaOH+ 5.622e-08 4.561e-08 -7.250 -7.341 -0.091 - CaHSO4+ 6.553e-10 5.316e-10 -9.184 -9.274 -0.091 -Cl 1.500e-02 - Cl- 1.500e-02 1.202e-02 -1.824 -1.920 -0.096 - FeCl+ 5.281e-10 4.285e-10 -9.277 -9.368 -0.091 - FeCl+2 5.429e-25 2.352e-25 -24.265 -24.629 -0.363 - FeCl2+ 1.557e-26 1.263e-26 -25.808 -25.899 -0.091 - FeCl3 1.498e-29 1.518e-29 -28.825 -28.819 0.006 -Fe(2) 7.979e-08 - Fe+2 5.594e-08 2.582e-08 -7.252 -7.588 -0.336 - FeSO4 2.157e-08 2.187e-08 -7.666 -7.660 0.006 - FeHCO3+ 8.172e-10 6.630e-10 -9.088 -9.178 -0.091 - FeOH+ 5.397e-10 4.378e-10 -9.268 -9.359 -0.091 - FeCl+ 5.281e-10 4.285e-10 -9.277 -9.368 -0.091 - FeCO3 3.949e-10 4.003e-10 -9.404 -9.398 0.006 - FeHSO4+ 3.301e-15 2.678e-15 -14.481 -14.572 -0.091 - Fe(HS)2 1.467e-18 1.487e-18 -17.834 -17.828 0.006 - Fe(HS)3- 5.074e-26 4.116e-26 -25.295 -25.385 -0.091 -Fe(3) 3.371e-14 - Fe(OH)3 2.714e-14 2.752e-14 -13.566 -13.560 0.006 - Fe(OH)2+ 4.909e-15 3.983e-15 -14.309 -14.400 -0.091 - Fe(OH)4- 1.659e-15 1.346e-15 -14.780 -14.871 -0.091 - FeOH+2 5.177e-19 2.243e-19 -18.286 -18.649 -0.363 - FeSO4+ 4.171e-23 3.384e-23 -22.380 -22.471 -0.091 - Fe(SO4)2- 4.347e-24 3.527e-24 -23.362 -23.453 -0.091 - Fe+3 2.894e-24 6.479e-25 -23.539 -24.188 -0.650 - FeCl+2 5.429e-25 2.352e-25 -24.265 -24.629 -0.363 - FeCl2+ 1.557e-26 1.263e-26 -25.808 -25.899 -0.091 - FeCl3 1.498e-29 1.518e-29 -28.825 -28.819 0.006 - FeHSO4+2 3.896e-30 1.688e-30 -29.409 -29.773 -0.363 - Fe2(OH)2+4 3.843e-35 1.354e-36 -34.415 -35.868 -1.453 - Fe3(OH)4+5 0.000e+00 0.000e+00 -45.678 -47.948 -2.270 -H(0) 7.021e-12 - H2 3.511e-12 3.559e-12 -11.455 -11.449 0.006 -Na 1.500e-02 - Na+ 1.465e-02 1.192e-02 -1.834 -1.924 -0.090 - NaSO4- 3.506e-04 2.845e-04 -3.455 -3.546 -0.091 - NaHCO3 1.697e-06 1.721e-06 -5.770 -5.764 0.006 - NaCO3- 1.768e-07 1.434e-07 -6.753 -6.843 -0.091 - NaOH 4.164e-09 4.222e-09 -8.380 -8.375 0.006 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -69.489 -69.484 0.006 -S(-2) 3.587e-10 - HS- 3.179e-10 2.542e-10 -9.498 -9.595 -0.097 - H2S 4.084e-11 4.141e-11 -10.389 -10.383 0.006 - S-2 3.732e-15 1.648e-15 -14.428 -14.783 -0.355 - Fe(HS)2 1.467e-18 1.487e-18 -17.834 -17.828 0.006 - Fe(HS)3- 5.074e-26 4.116e-26 -25.295 -25.385 -0.091 -S(6) 1.600e-02 - SO4-2 1.085e-02 4.763e-03 -1.965 -2.322 -0.357 - CaSO4 4.805e-03 4.871e-03 -2.318 -2.312 0.006 - NaSO4- 3.506e-04 2.845e-04 -3.455 -3.546 -0.091 - FeSO4 2.157e-08 2.187e-08 -7.666 -7.660 0.006 - HSO4- 1.063e-08 8.628e-09 -7.973 -8.064 -0.091 - CaHSO4+ 6.553e-10 5.316e-10 -9.184 -9.274 -0.091 - FeHSO4+ 3.301e-15 2.678e-15 -14.481 -14.572 -0.091 - FeSO4+ 4.171e-23 3.384e-23 -22.380 -22.471 -0.091 - Fe(SO4)2- 4.347e-24 3.527e-24 -23.362 -23.453 -0.091 - FeHSO4+2 3.896e-30 1.688e-30 -29.409 -29.773 -0.363 + OH- 6.713e-07 5.368e-07 -6.173 -6.270 -0.097 (0) + H+ 2.200e-08 1.863e-08 -7.658 -7.730 -0.072 0.00 + H2O 5.551e+01 9.990e-01 1.744 -0.000 0.000 18.07 +C(-4) 1.669e-14 + CH4 1.669e-14 1.693e-14 -13.777 -13.771 0.006 (0) +C(4) 3.535e-04 + HCO3- 3.135e-04 2.568e-04 -3.504 -3.590 -0.087 24.29 + CaHCO3+ 2.050e-05 1.679e-05 -4.688 -4.775 -0.087 (0) + CO2 1.062e-05 1.077e-05 -4.974 -4.968 0.006 (0) + CaCO3 5.489e-06 5.565e-06 -5.261 -5.255 0.006 (0) + NaHCO3 1.697e-06 1.721e-06 -5.770 -5.764 0.006 (0) + CO3-2 1.437e-06 6.464e-07 -5.843 -6.190 -0.347 -3.78 + NaCO3- 1.768e-07 1.434e-07 -6.753 -6.843 -0.091 (0) + FeHCO3+ 8.172e-10 6.630e-10 -9.088 -9.178 -0.091 (0) + FeCO3 3.949e-10 4.003e-10 -9.404 -9.398 0.006 (0) +Ca 1.618e-02 + Ca+2 1.135e-02 5.125e-03 -1.945 -2.290 -0.345 -17.83 + CaSO4 4.805e-03 4.871e-03 -2.318 -2.312 0.006 (0) + CaHCO3+ 2.050e-05 1.679e-05 -4.688 -4.775 -0.087 (0) + CaCO3 5.489e-06 5.565e-06 -5.261 -5.255 0.006 (0) + CaOH+ 5.622e-08 4.561e-08 -7.250 -7.341 -0.091 (0) + CaHSO4+ 6.553e-10 5.316e-10 -9.184 -9.274 -0.091 (0) +Cl 1.500e-02 + Cl- 1.500e-02 1.202e-02 -1.824 -1.920 -0.096 17.82 + FeCl+ 5.281e-10 4.285e-10 -9.277 -9.368 -0.091 (0) + FeCl+2 5.429e-25 2.352e-25 -24.265 -24.629 -0.363 (0) + FeCl2+ 1.557e-26 1.263e-26 -25.808 -25.899 -0.091 (0) + FeCl3 1.498e-29 1.518e-29 -28.825 -28.819 0.006 (0) +Fe(2) 7.979e-08 + Fe+2 5.594e-08 2.582e-08 -7.252 -7.588 -0.336 (0) + FeSO4 2.157e-08 2.187e-08 -7.666 -7.660 0.006 (0) + FeHCO3+ 8.172e-10 6.630e-10 -9.088 -9.178 -0.091 (0) + FeOH+ 5.397e-10 4.378e-10 -9.268 -9.359 -0.091 (0) + FeCl+ 5.281e-10 4.285e-10 -9.277 -9.368 -0.091 (0) + FeCO3 3.949e-10 4.003e-10 -9.404 -9.398 0.006 (0) + FeHSO4+ 3.301e-15 2.678e-15 -14.481 -14.572 -0.091 (0) + Fe(HS)2 1.467e-18 1.487e-18 -17.834 -17.828 0.006 (0) + Fe(HS)3- 5.074e-26 4.116e-26 -25.295 -25.385 -0.091 (0) +Fe(3) 3.371e-14 + Fe(OH)3 2.714e-14 2.752e-14 -13.566 -13.560 0.006 (0) + Fe(OH)2+ 4.909e-15 3.983e-15 -14.309 -14.400 -0.091 (0) + Fe(OH)4- 1.659e-15 1.346e-15 -14.780 -14.871 -0.091 (0) + FeOH+2 5.177e-19 2.243e-19 -18.286 -18.649 -0.363 (0) + FeSO4+ 4.171e-23 3.384e-23 -22.380 -22.471 -0.091 (0) + Fe(SO4)2- 4.347e-24 3.527e-24 -23.362 -23.453 -0.091 (0) + Fe+3 2.894e-24 6.479e-25 -23.539 -24.188 -0.650 (0) + FeCl+2 5.429e-25 2.352e-25 -24.265 -24.629 -0.363 (0) + FeCl2+ 1.557e-26 1.263e-26 -25.808 -25.899 -0.091 (0) + FeCl3 1.498e-29 1.518e-29 -28.825 -28.819 0.006 (0) + FeHSO4+2 3.896e-30 1.688e-30 -29.409 -29.773 -0.363 (0) + Fe2(OH)2+4 3.843e-35 1.354e-36 -34.415 -35.868 -1.453 (0) + Fe3(OH)4+5 0.000e+00 0.000e+00 -45.678 -47.948 -2.270 (0) +H(0) 7.021e-12 + H2 3.511e-12 3.559e-12 -11.455 -11.449 0.006 (0) +Na 1.500e-02 + Na+ 1.465e-02 1.192e-02 -1.834 -1.924 -0.090 -1.21 + NaSO4- 3.506e-04 2.845e-04 -3.455 -3.546 -0.091 (0) + NaHCO3 1.697e-06 1.721e-06 -5.770 -5.764 0.006 (0) + NaCO3- 1.768e-07 1.434e-07 -6.753 -6.843 -0.091 (0) + NaOH 4.164e-09 4.222e-09 -8.380 -8.375 0.006 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -69.489 -69.484 0.006 (0) +S(-2) 3.587e-10 + HS- 3.179e-10 2.542e-10 -9.498 -9.595 -0.097 (0) + H2S 4.084e-11 4.141e-11 -10.389 -10.383 0.006 (0) + S-2 3.732e-15 1.648e-15 -14.428 -14.783 -0.355 (0) + Fe(HS)2 1.467e-18 1.487e-18 -17.834 -17.828 0.006 (0) + Fe(HS)3- 5.074e-26 4.116e-26 -25.295 -25.385 -0.091 (0) +S(6) 1.600e-02 + SO4-2 1.085e-02 4.763e-03 -1.965 -2.322 -0.357 13.98 + CaSO4 4.805e-03 4.871e-03 -2.318 -2.312 0.006 (0) + NaSO4- 3.506e-04 2.845e-04 -3.455 -3.546 -0.091 (0) + FeSO4 2.157e-08 2.187e-08 -7.666 -7.660 0.006 (0) + HSO4- 1.063e-08 8.628e-09 -7.973 -8.064 -0.091 (0) + CaHSO4+ 6.553e-10 5.316e-10 -9.184 -9.274 -0.091 (0) + FeHSO4+ 3.301e-15 2.678e-15 -14.481 -14.572 -0.091 (0) + FeSO4+ 4.171e-23 3.384e-23 -22.380 -22.471 -0.091 (0) + Fe(SO4)2- 4.347e-24 3.527e-24 -23.362 -23.453 -0.091 (0) + FeHSO4+2 3.896e-30 1.688e-30 -29.409 -29.773 -0.363 (0) ------------------------------Saturation indices------------------------------- @@ -1020,88 +1020,88 @@ Pyrite 0.00 -18.48 -18.48 1.000e+01 9.987e+00 -1.333e-02 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 6.681e-07 5.237e-07 -6.175 -6.281 -0.106 - H+ 2.279e-08 1.909e-08 -7.642 -7.719 -0.077 - H2O 5.551e+01 9.986e-01 1.744 -0.001 0.000 -C(-4) 1.534e-14 - CH4 1.534e-14 1.561e-14 -13.814 -13.807 0.007 -C(4) 3.526e-04 - HCO3- 3.108e-04 2.505e-04 -3.508 -3.601 -0.094 - CaHCO3+ 2.134e-05 1.720e-05 -4.671 -4.764 -0.094 - CO2 1.058e-05 1.077e-05 -4.975 -4.968 0.007 - CaCO3 5.470e-06 5.565e-06 -5.262 -5.255 0.007 - NaHCO3 2.706e-06 2.752e-06 -5.568 -5.560 0.007 - CO3-2 1.458e-06 6.155e-07 -5.836 -6.211 -0.374 - NaCO3- 2.804e-07 2.239e-07 -6.552 -6.650 -0.098 - FeHCO3+ 8.424e-10 6.727e-10 -9.074 -9.172 -0.098 - FeCO3 3.897e-10 3.964e-10 -9.409 -9.402 0.007 -Ca 1.785e-02 - Ca+2 1.266e-02 5.382e-03 -1.898 -2.269 -0.371 - CaSO4 5.162e-03 5.251e-03 -2.287 -2.280 0.007 - CaHCO3+ 2.134e-05 1.720e-05 -4.671 -4.764 -0.094 - CaCO3 5.470e-06 5.565e-06 -5.262 -5.255 0.007 - CaOH+ 5.853e-08 4.673e-08 -7.233 -7.330 -0.098 - CaHSO4+ 7.355e-10 5.872e-10 -9.133 -9.231 -0.098 -Cl 2.501e-02 - Cl- 2.501e-02 1.966e-02 -1.602 -1.706 -0.105 - FeCl+ 9.125e-10 7.286e-10 -9.040 -9.138 -0.098 - FeCl+2 1.019e-24 4.140e-25 -23.992 -24.383 -0.391 - FeCl2+ 4.553e-26 3.635e-26 -25.342 -25.439 -0.098 - FeCl3 7.025e-29 7.146e-29 -28.153 -28.146 0.007 -Fe(2) 8.735e-08 - Fe+2 6.170e-08 2.685e-08 -7.210 -7.571 -0.361 - FeSO4 2.295e-08 2.335e-08 -7.639 -7.632 0.007 - FeCl+ 9.125e-10 7.286e-10 -9.040 -9.138 -0.098 - FeHCO3+ 8.424e-10 6.727e-10 -9.074 -9.172 -0.098 - FeOH+ 5.563e-10 4.442e-10 -9.255 -9.352 -0.098 - FeCO3 3.897e-10 3.964e-10 -9.409 -9.402 0.007 - FeHSO4+ 3.669e-15 2.930e-15 -14.435 -14.533 -0.098 - Fe(HS)2 1.432e-18 1.457e-18 -17.844 -17.837 0.007 - Fe(HS)3- 4.903e-26 3.915e-26 -25.310 -25.407 -0.098 -Fe(3) 3.379e-14 - Fe(OH)3 2.704e-14 2.750e-14 -13.568 -13.561 0.007 - Fe(OH)2+ 5.111e-15 4.081e-15 -14.291 -14.389 -0.098 - Fe(OH)4- 1.644e-15 1.312e-15 -14.784 -14.882 -0.098 - FeOH+2 5.796e-19 2.356e-19 -18.237 -18.628 -0.391 - FeSO4+ 4.683e-23 3.739e-23 -22.329 -22.427 -0.098 - Fe(SO4)2- 5.010e-24 4.000e-24 -23.300 -23.398 -0.098 - Fe+3 3.432e-24 6.974e-25 -23.464 -24.156 -0.692 - FeCl+2 1.019e-24 4.140e-25 -23.992 -24.383 -0.391 - FeCl2+ 4.553e-26 3.635e-26 -25.342 -25.439 -0.098 - FeCl3 7.025e-29 7.146e-29 -28.153 -28.146 0.007 - FeHSO4+2 4.703e-30 1.911e-30 -29.328 -29.719 -0.391 - Fe2(OH)2+4 5.473e-35 1.494e-36 -34.262 -35.826 -1.564 - Fe3(OH)4+5 0.000e+00 0.000e+00 -45.451 -47.895 -2.444 -H(0) 6.856e-12 - H2 3.428e-12 3.487e-12 -11.465 -11.458 0.007 -Na 2.501e-02 - Na+ 2.441e-02 1.954e-02 -1.612 -1.709 -0.097 - NaSO4- 5.997e-04 4.788e-04 -3.222 -3.320 -0.098 - NaHCO3 2.706e-06 2.752e-06 -5.568 -5.560 0.007 - NaCO3- 2.804e-07 2.239e-07 -6.552 -6.650 -0.098 - NaOH 6.639e-09 6.753e-09 -8.178 -8.170 0.007 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -69.474 -69.466 0.007 -S(-2) 3.552e-10 - HS- 3.148e-10 2.467e-10 -9.502 -9.608 -0.106 - H2S 4.048e-11 4.118e-11 -10.393 -10.385 0.007 - S-2 3.777e-15 1.561e-15 -14.423 -14.807 -0.384 - Fe(HS)2 1.432e-18 1.457e-18 -17.844 -17.837 0.007 - Fe(HS)3- 4.903e-26 3.915e-26 -25.310 -25.407 -0.098 -S(6) 1.767e-02 - SO4-2 1.191e-02 4.890e-03 -1.924 -2.311 -0.387 - CaSO4 5.162e-03 5.251e-03 -2.287 -2.280 0.007 - NaSO4- 5.997e-04 4.788e-04 -3.222 -3.320 -0.098 - FeSO4 2.295e-08 2.335e-08 -7.639 -7.632 0.007 - HSO4- 1.137e-08 9.075e-09 -7.944 -8.042 -0.098 - CaHSO4+ 7.355e-10 5.872e-10 -9.133 -9.231 -0.098 - FeHSO4+ 3.669e-15 2.930e-15 -14.435 -14.533 -0.098 - FeSO4+ 4.683e-23 3.739e-23 -22.329 -22.427 -0.098 - Fe(SO4)2- 5.010e-24 4.000e-24 -23.300 -23.398 -0.098 - FeHSO4+2 4.703e-30 1.911e-30 -29.328 -29.719 -0.391 + OH- 6.681e-07 5.237e-07 -6.175 -6.281 -0.106 (0) + H+ 2.279e-08 1.909e-08 -7.642 -7.719 -0.077 0.00 + H2O 5.551e+01 9.986e-01 1.744 -0.001 0.000 18.07 +C(-4) 1.534e-14 + CH4 1.534e-14 1.561e-14 -13.814 -13.807 0.007 (0) +C(4) 3.526e-04 + HCO3- 3.108e-04 2.505e-04 -3.508 -3.601 -0.094 24.29 + CaHCO3+ 2.134e-05 1.720e-05 -4.671 -4.764 -0.094 (0) + CO2 1.058e-05 1.077e-05 -4.975 -4.968 0.007 (0) + CaCO3 5.470e-06 5.565e-06 -5.262 -5.255 0.007 (0) + NaHCO3 2.706e-06 2.752e-06 -5.568 -5.560 0.007 (0) + CO3-2 1.458e-06 6.155e-07 -5.836 -6.211 -0.374 -3.78 + NaCO3- 2.804e-07 2.239e-07 -6.552 -6.650 -0.098 (0) + FeHCO3+ 8.424e-10 6.727e-10 -9.074 -9.172 -0.098 (0) + FeCO3 3.897e-10 3.964e-10 -9.409 -9.402 0.007 (0) +Ca 1.785e-02 + Ca+2 1.266e-02 5.382e-03 -1.898 -2.269 -0.371 -17.83 + CaSO4 5.162e-03 5.251e-03 -2.287 -2.280 0.007 (0) + CaHCO3+ 2.134e-05 1.720e-05 -4.671 -4.764 -0.094 (0) + CaCO3 5.470e-06 5.565e-06 -5.262 -5.255 0.007 (0) + CaOH+ 5.853e-08 4.673e-08 -7.233 -7.330 -0.098 (0) + CaHSO4+ 7.355e-10 5.872e-10 -9.133 -9.231 -0.098 (0) +Cl 2.501e-02 + Cl- 2.501e-02 1.966e-02 -1.602 -1.706 -0.105 17.82 + FeCl+ 9.125e-10 7.286e-10 -9.040 -9.138 -0.098 (0) + FeCl+2 1.019e-24 4.140e-25 -23.992 -24.383 -0.391 (0) + FeCl2+ 4.553e-26 3.635e-26 -25.342 -25.439 -0.098 (0) + FeCl3 7.025e-29 7.146e-29 -28.153 -28.146 0.007 (0) +Fe(2) 8.735e-08 + Fe+2 6.170e-08 2.685e-08 -7.210 -7.571 -0.361 (0) + FeSO4 2.295e-08 2.335e-08 -7.639 -7.632 0.007 (0) + FeCl+ 9.125e-10 7.286e-10 -9.040 -9.138 -0.098 (0) + FeHCO3+ 8.424e-10 6.727e-10 -9.074 -9.172 -0.098 (0) + FeOH+ 5.563e-10 4.442e-10 -9.255 -9.352 -0.098 (0) + FeCO3 3.897e-10 3.964e-10 -9.409 -9.402 0.007 (0) + FeHSO4+ 3.669e-15 2.930e-15 -14.435 -14.533 -0.098 (0) + Fe(HS)2 1.432e-18 1.457e-18 -17.844 -17.837 0.007 (0) + Fe(HS)3- 4.903e-26 3.915e-26 -25.310 -25.407 -0.098 (0) +Fe(3) 3.379e-14 + Fe(OH)3 2.704e-14 2.750e-14 -13.568 -13.561 0.007 (0) + Fe(OH)2+ 5.111e-15 4.081e-15 -14.291 -14.389 -0.098 (0) + Fe(OH)4- 1.644e-15 1.312e-15 -14.784 -14.882 -0.098 (0) + FeOH+2 5.796e-19 2.356e-19 -18.237 -18.628 -0.391 (0) + FeSO4+ 4.683e-23 3.739e-23 -22.329 -22.427 -0.098 (0) + Fe(SO4)2- 5.010e-24 4.000e-24 -23.300 -23.398 -0.098 (0) + Fe+3 3.432e-24 6.974e-25 -23.464 -24.156 -0.692 (0) + FeCl+2 1.019e-24 4.140e-25 -23.992 -24.383 -0.391 (0) + FeCl2+ 4.553e-26 3.635e-26 -25.342 -25.439 -0.098 (0) + FeCl3 7.025e-29 7.146e-29 -28.153 -28.146 0.007 (0) + FeHSO4+2 4.703e-30 1.911e-30 -29.328 -29.719 -0.391 (0) + Fe2(OH)2+4 5.473e-35 1.494e-36 -34.262 -35.826 -1.564 (0) + Fe3(OH)4+5 0.000e+00 0.000e+00 -45.451 -47.895 -2.444 (0) +H(0) 6.856e-12 + H2 3.428e-12 3.487e-12 -11.465 -11.458 0.007 (0) +Na 2.501e-02 + Na+ 2.441e-02 1.954e-02 -1.612 -1.709 -0.097 -1.21 + NaSO4- 5.997e-04 4.788e-04 -3.222 -3.320 -0.098 (0) + NaHCO3 2.706e-06 2.752e-06 -5.568 -5.560 0.007 (0) + NaCO3- 2.804e-07 2.239e-07 -6.552 -6.650 -0.098 (0) + NaOH 6.639e-09 6.753e-09 -8.178 -8.170 0.007 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -69.474 -69.466 0.007 (0) +S(-2) 3.552e-10 + HS- 3.148e-10 2.467e-10 -9.502 -9.608 -0.106 (0) + H2S 4.048e-11 4.118e-11 -10.393 -10.385 0.007 (0) + S-2 3.777e-15 1.561e-15 -14.423 -14.807 -0.384 (0) + Fe(HS)2 1.432e-18 1.457e-18 -17.844 -17.837 0.007 (0) + Fe(HS)3- 4.903e-26 3.915e-26 -25.310 -25.407 -0.098 (0) +S(6) 1.767e-02 + SO4-2 1.191e-02 4.890e-03 -1.924 -2.311 -0.387 13.98 + CaSO4 5.162e-03 5.251e-03 -2.287 -2.280 0.007 (0) + NaSO4- 5.997e-04 4.788e-04 -3.222 -3.320 -0.098 (0) + FeSO4 2.295e-08 2.335e-08 -7.639 -7.632 0.007 (0) + HSO4- 1.137e-08 9.075e-09 -7.944 -8.042 -0.098 (0) + CaHSO4+ 7.355e-10 5.872e-10 -9.133 -9.231 -0.098 (0) + FeHSO4+ 3.669e-15 2.930e-15 -14.435 -14.533 -0.098 (0) + FeSO4+ 4.683e-23 3.739e-23 -22.329 -22.427 -0.098 (0) + Fe(SO4)2- 5.010e-24 4.000e-24 -23.300 -23.398 -0.098 (0) + FeHSO4+2 4.703e-30 1.911e-30 -29.328 -29.719 -0.391 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex6.out b/ex6.out index 1e847033..9fb091eb 100644 --- a/ex6.out +++ b/ex6.out @@ -85,16 +85,16 @@ Initial solution 1. PURE WATER ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.001e-07 1.001e-07 -7.000 -7.000 -0.000 - H+ 1.001e-07 1.001e-07 -7.000 -7.000 -0.000 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -H(0) 1.417e-25 - H2 7.087e-26 7.087e-26 -25.150 -25.150 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -42.081 -42.081 0.000 + OH- 1.001e-07 1.001e-07 -7.000 -7.000 -0.000 (0) + H+ 1.001e-07 1.001e-07 -7.000 -7.000 -0.000 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +H(0) 1.417e-25 + H2 7.087e-26 7.087e-26 -25.150 -25.150 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -42.081 -42.081 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -185,29 +185,29 @@ Kaolinite -3.80 1.90 5.71 0.000e+00 0 0.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.016e-07 1.015e-07 -6.993 -6.993 -0.000 - H+ 9.865e-08 9.861e-08 -7.006 -7.006 -0.000 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 2.671e-08 - Al(OH)4- 2.455e-08 2.454e-08 -7.610 -7.610 -0.000 - Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 - Al(OH)2+ 8.597e-10 8.594e-10 -9.066 -9.066 -0.000 - AlOH+2 1.083e-11 1.081e-11 -10.965 -10.966 -0.001 - Al+3 1.077e-13 1.073e-13 -12.968 -12.969 -0.002 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.099 -40.099 0.000 -K 2.671e-08 - K+ 2.671e-08 2.670e-08 -7.573 -7.574 -0.000 - KOH 9.388e-16 9.388e-16 -15.027 -15.027 0.000 -O(0) 1.314e-12 - O2 6.572e-13 6.572e-13 -12.182 -12.182 0.000 -Si 8.013e-08 - H4SiO4 8.001e-08 8.001e-08 -7.097 -7.097 0.000 - H3SiO4- 1.197e-10 1.196e-10 -9.922 -9.922 -0.000 - H2SiO4-2 8.267e-17 8.253e-17 -16.083 -16.083 -0.001 + OH- 1.016e-07 1.015e-07 -6.993 -6.993 -0.000 (0) + H+ 9.865e-08 9.861e-08 -7.006 -7.006 -0.000 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 2.671e-08 + Al(OH)4- 2.455e-08 2.454e-08 -7.610 -7.610 -0.000 (0) + Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 (0) + Al(OH)2+ 8.597e-10 8.594e-10 -9.066 -9.066 -0.000 (0) + AlOH+2 1.083e-11 1.081e-11 -10.965 -10.966 -0.001 (0) + Al+3 1.077e-13 1.073e-13 -12.968 -12.969 -0.002 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.099 -40.099 0.000 (0) +K 2.671e-08 + K+ 2.671e-08 2.670e-08 -7.573 -7.574 -0.000 9.03 + KOH 9.388e-16 9.388e-16 -15.027 -15.027 0.000 (0) +O(0) 1.314e-12 + O2 6.572e-13 6.572e-13 -12.182 -12.182 0.000 (0) +Si 8.013e-08 + H4SiO4 8.001e-08 8.001e-08 -7.097 -7.097 0.000 56.00 + H3SiO4- 1.197e-10 1.196e-10 -9.922 -9.922 -0.000 (0) + H2SiO4-2 8.267e-17 8.253e-17 -16.083 -16.083 -0.001 (0) ------------------------------Saturation indices------------------------------- @@ -299,29 +299,29 @@ Kaolinite -0.00 5.71 5.71 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.636e-06 1.633e-06 -5.786 -5.787 -0.001 - H+ 6.141e-09 6.131e-09 -8.212 -8.212 -0.001 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 3.968e-07 - Al(OH)4- 3.955e-07 3.948e-07 -6.403 -6.404 -0.001 - Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 - Al(OH)2+ 5.352e-11 5.343e-11 -10.271 -10.272 -0.001 - AlOH+2 4.208e-14 4.179e-14 -13.376 -13.379 -0.003 - Al+3 2.620e-17 2.579e-17 -16.582 -16.588 -0.007 -H(0) 8.674e-40 - H2 4.337e-40 4.337e-40 -39.363 -39.363 0.000 -K 2.179e-06 - K+ 2.179e-06 2.175e-06 -5.662 -5.663 -0.001 - KOH 1.230e-12 1.230e-12 -11.910 -11.910 0.000 -O(0) 4.433e-14 - O2 2.216e-14 2.216e-14 -13.654 -13.654 0.000 -Si 6.536e-06 - H4SiO4 6.383e-06 6.383e-06 -5.195 -5.195 0.000 - H3SiO4- 1.538e-07 1.535e-07 -6.813 -6.814 -0.001 - H2SiO4-2 1.715e-12 1.703e-12 -11.766 -11.769 -0.003 + OH- 1.636e-06 1.633e-06 -5.786 -5.787 -0.001 (0) + H+ 6.141e-09 6.131e-09 -8.212 -8.212 -0.001 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 3.968e-07 + Al(OH)4- 3.955e-07 3.948e-07 -6.403 -6.404 -0.001 (0) + Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 (0) + Al(OH)2+ 5.352e-11 5.343e-11 -10.271 -10.272 -0.001 (0) + AlOH+2 4.208e-14 4.179e-14 -13.376 -13.379 -0.003 (0) + Al+3 2.620e-17 2.579e-17 -16.582 -16.588 -0.007 (0) +H(0) 8.674e-40 + H2 4.337e-40 4.337e-40 -39.363 -39.363 0.000 (0) +K 2.179e-06 + K+ 2.179e-06 2.175e-06 -5.662 -5.663 -0.001 9.03 + KOH 1.230e-12 1.230e-12 -11.910 -11.910 0.000 (0) +O(0) 4.433e-14 + O2 2.216e-14 2.216e-14 -13.654 -13.654 0.000 (0) +Si 6.536e-06 + H4SiO4 6.383e-06 6.383e-06 -5.195 -5.195 0.000 56.00 + H3SiO4- 1.538e-07 1.535e-07 -6.813 -6.814 -0.001 (0) + H2SiO4-2 1.715e-12 1.703e-12 -11.766 -11.769 -0.003 (0) ------------------------------Saturation indices------------------------------- @@ -413,29 +413,29 @@ Kaolinite 0.00 5.71 5.71 0.000e+00 9.715e-06 9.715e-06 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.293e-05 1.286e-05 -4.888 -4.891 -0.002 - H+ 7.822e-10 7.782e-10 -9.107 -9.109 -0.002 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 5.851e-07 - Al(OH)4- 5.849e-07 5.818e-07 -6.233 -6.235 -0.002 - Al(OH)3 2.402e-10 2.402e-10 -9.619 -9.619 0.000 - Al(OH)2+ 1.275e-12 1.269e-12 -11.894 -11.897 -0.002 - AlOH+2 1.286e-16 1.260e-16 -15.891 -15.900 -0.009 - Al+3 1.034e-20 9.870e-21 -19.985 -20.006 -0.020 -H(0) 6.411e-40 - H2 3.206e-40 3.206e-40 -39.494 -39.494 0.000 -K 2.001e-05 - K+ 2.001e-05 1.991e-05 -4.699 -4.701 -0.002 - KOH 8.871e-11 8.872e-11 -10.052 -10.052 0.000 -O(0) 8.113e-14 - O2 4.057e-14 4.057e-14 -13.392 -13.392 0.000 -Si 4.062e-05 - H4SiO4 3.412e-05 3.412e-05 -4.467 -4.467 0.000 - H3SiO4- 6.498e-06 6.464e-06 -5.187 -5.189 -0.002 - H2SiO4-2 5.770e-10 5.651e-10 -9.239 -9.248 -0.009 + OH- 1.293e-05 1.286e-05 -4.888 -4.891 -0.002 (0) + H+ 7.822e-10 7.782e-10 -9.107 -9.109 -0.002 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 5.851e-07 + Al(OH)4- 5.849e-07 5.818e-07 -6.233 -6.235 -0.002 (0) + Al(OH)3 2.402e-10 2.402e-10 -9.619 -9.619 0.000 (0) + Al(OH)2+ 1.275e-12 1.269e-12 -11.894 -11.897 -0.002 (0) + AlOH+2 1.286e-16 1.260e-16 -15.891 -15.900 -0.009 (0) + Al+3 1.034e-20 9.870e-21 -19.985 -20.006 -0.020 (0) +H(0) 6.411e-40 + H2 3.206e-40 3.206e-40 -39.494 -39.494 0.000 (0) +K 2.001e-05 + K+ 2.001e-05 1.991e-05 -4.699 -4.701 -0.002 9.03 + KOH 8.871e-11 8.872e-11 -10.052 -10.052 0.000 (0) +O(0) 8.113e-14 + O2 4.057e-14 4.057e-14 -13.392 -13.392 0.000 (0) +Si 4.062e-05 + H4SiO4 3.412e-05 3.412e-05 -4.467 -4.467 0.000 56.00 + H3SiO4- 6.498e-06 6.464e-06 -5.187 -5.189 -0.002 (0) + H2SiO4-2 5.770e-10 5.651e-10 -9.239 -9.248 -0.009 (0) ------------------------------Saturation indices------------------------------- @@ -527,29 +527,29 @@ Kaolinite -0.72 4.99 5.71 0.000e+00 0 0.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.486e-05 2.453e-05 -4.605 -4.610 -0.006 - H+ 4.133e-10 4.080e-10 -9.384 -9.389 -0.006 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 5.990e-08 - Al(OH)4- 5.988e-08 5.911e-08 -7.223 -7.228 -0.006 - Al(OH)3 1.280e-11 1.280e-11 -10.893 -10.893 0.000 - Al(OH)2+ 3.590e-14 3.544e-14 -13.445 -13.451 -0.006 - AlOH+2 1.944e-18 1.845e-18 -17.711 -17.734 -0.023 - Al+3 8.505e-23 7.579e-23 -22.070 -22.120 -0.050 -H(0) 1.013e-39 - H2 5.064e-40 5.064e-40 -39.296 -39.295 0.000 -K 1.273e-04 - K+ 1.273e-04 1.256e-04 -3.895 -3.901 -0.006 - KOH 1.067e-09 1.067e-09 -8.972 -8.972 0.000 -O(0) 3.251e-14 - O2 1.625e-14 1.625e-14 -13.789 -13.789 0.000 -Si 3.818e-04 - H4SiO4 2.795e-04 2.795e-04 -3.554 -3.554 0.000 - H3SiO4- 1.023e-04 1.010e-04 -3.990 -3.996 -0.006 - H2SiO4-2 1.774e-08 1.684e-08 -7.751 -7.774 -0.023 + OH- 2.486e-05 2.453e-05 -4.605 -4.610 -0.006 (0) + H+ 4.133e-10 4.080e-10 -9.384 -9.389 -0.006 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 5.990e-08 + Al(OH)4- 5.988e-08 5.911e-08 -7.223 -7.228 -0.006 (0) + Al(OH)3 1.280e-11 1.280e-11 -10.893 -10.893 0.000 (0) + Al(OH)2+ 3.590e-14 3.544e-14 -13.445 -13.451 -0.006 (0) + AlOH+2 1.944e-18 1.845e-18 -17.711 -17.734 -0.023 (0) + Al+3 8.505e-23 7.579e-23 -22.070 -22.120 -0.050 (0) +H(0) 1.013e-39 + H2 5.064e-40 5.064e-40 -39.296 -39.295 0.000 (0) +K 1.273e-04 + K+ 1.273e-04 1.256e-04 -3.895 -3.901 -0.006 9.03 + KOH 1.067e-09 1.067e-09 -8.972 -8.972 0.000 (0) +O(0) 3.251e-14 + O2 1.625e-14 1.625e-14 -13.789 -13.789 0.000 (0) +Si 3.818e-04 + H4SiO4 2.795e-04 2.795e-04 -3.554 -3.554 0.000 56.00 + H3SiO4- 1.023e-04 1.010e-04 -3.990 -3.996 -0.006 (0) + H2SiO4-2 1.774e-08 1.684e-08 -7.751 -7.774 -0.023 (0) ------------------------------Saturation indices------------------------------- @@ -637,29 +637,29 @@ Kaolinite -0.00 5.71 5.71 1.000e+00 1.000e+00 1.237e-06 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.267e-06 2.262e-06 -5.645 -5.646 -0.001 - H+ 4.435e-09 4.426e-09 -8.353 -8.354 -0.001 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 5.493e-07 - Al(OH)4- 5.480e-07 5.469e-07 -6.261 -6.262 -0.001 - Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 - Al(OH)2+ 3.865e-11 3.857e-11 -10.413 -10.414 -0.001 - AlOH+2 2.196e-14 2.178e-14 -13.658 -13.662 -0.004 - Al+3 9.882e-18 9.704e-18 -17.005 -17.013 -0.008 -H(0) 7.444e-40 - H2 3.722e-40 3.722e-40 -39.429 -39.429 0.000 -K 3.023e-06 - K+ 3.023e-06 3.017e-06 -5.520 -5.520 -0.001 - KOH 2.364e-12 2.364e-12 -11.626 -11.626 0.000 -O(0) 6.019e-14 - O2 3.009e-14 3.009e-14 -13.522 -13.522 0.000 -Si 6.596e-06 - H4SiO4 6.383e-06 6.383e-06 -5.195 -5.195 0.000 - H3SiO4- 2.131e-07 2.127e-07 -6.671 -6.672 -0.001 - H2SiO4-2 3.295e-12 3.269e-12 -11.482 -11.486 -0.004 + OH- 2.267e-06 2.262e-06 -5.645 -5.646 -0.001 (0) + H+ 4.435e-09 4.426e-09 -8.353 -8.354 -0.001 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 5.493e-07 + Al(OH)4- 5.480e-07 5.469e-07 -6.261 -6.262 -0.001 (0) + Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 (0) + Al(OH)2+ 3.865e-11 3.857e-11 -10.413 -10.414 -0.001 (0) + AlOH+2 2.196e-14 2.178e-14 -13.658 -13.662 -0.004 (0) + Al+3 9.882e-18 9.704e-18 -17.005 -17.013 -0.008 (0) +H(0) 7.444e-40 + H2 3.722e-40 3.722e-40 -39.429 -39.429 0.000 (0) +K 3.023e-06 + K+ 3.023e-06 3.017e-06 -5.520 -5.520 -0.001 9.03 + KOH 2.364e-12 2.364e-12 -11.626 -11.626 0.000 (0) +O(0) 6.019e-14 + O2 3.009e-14 3.009e-14 -13.522 -13.522 0.000 (0) +Si 6.596e-06 + H4SiO4 6.383e-06 6.383e-06 -5.195 -5.195 0.000 56.00 + H3SiO4- 2.131e-07 2.127e-07 -6.671 -6.672 -0.001 (0) + H2SiO4-2 3.295e-12 3.269e-12 -11.482 -11.486 -0.004 (0) ------------------------------Saturation indices------------------------------- @@ -747,29 +747,29 @@ Kaolinite -0.00 5.71 5.71 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.183e-05 1.176e-05 -4.927 -4.930 -0.002 - H+ 8.558e-10 8.512e-10 -9.068 -9.070 -0.002 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 3.263e-07 - Al(OH)4- 3.262e-07 3.244e-07 -6.487 -6.489 -0.002 - Al(OH)3 1.465e-10 1.465e-10 -9.834 -9.834 0.000 - Al(OH)2+ 8.509e-13 8.463e-13 -12.070 -12.072 -0.002 - AlOH+2 9.393e-17 9.191e-17 -16.027 -16.037 -0.009 - Al+3 8.269e-21 7.876e-21 -20.083 -20.104 -0.021 -H(0) 2.179e-39 - H2 1.089e-39 1.089e-39 -38.963 -38.963 0.000 -K 2.190e-05 - K+ 2.190e-05 2.178e-05 -4.660 -4.662 -0.002 - KOH 8.871e-11 8.872e-11 -10.052 -10.052 0.000 -O(0) 7.024e-15 - O2 3.512e-15 3.512e-15 -14.454 -14.454 0.000 -Si 6.569e-05 - H4SiO4 5.595e-05 5.595e-05 -4.252 -4.252 0.000 - H3SiO4- 9.745e-06 9.692e-06 -5.011 -5.014 -0.002 - H2SiO4-2 7.916e-10 7.745e-10 -9.101 -9.111 -0.009 + OH- 1.183e-05 1.176e-05 -4.927 -4.930 -0.002 (0) + H+ 8.558e-10 8.512e-10 -9.068 -9.070 -0.002 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 3.263e-07 + Al(OH)4- 3.262e-07 3.244e-07 -6.487 -6.489 -0.002 (0) + Al(OH)3 1.465e-10 1.465e-10 -9.834 -9.834 0.000 (0) + Al(OH)2+ 8.509e-13 8.463e-13 -12.070 -12.072 -0.002 (0) + AlOH+2 9.393e-17 9.191e-17 -16.027 -16.037 -0.009 (0) + Al+3 8.269e-21 7.876e-21 -20.083 -20.104 -0.021 (0) +H(0) 2.179e-39 + H2 1.089e-39 1.089e-39 -38.963 -38.963 0.000 (0) +K 2.190e-05 + K+ 2.190e-05 2.178e-05 -4.660 -4.662 -0.002 9.03 + KOH 8.871e-11 8.872e-11 -10.052 -10.052 0.000 (0) +O(0) 7.024e-15 + O2 3.512e-15 3.512e-15 -14.454 -14.454 0.000 (0) +Si 6.569e-05 + H4SiO4 5.595e-05 5.595e-05 -4.252 -4.252 0.000 56.00 + H3SiO4- 9.745e-06 9.692e-06 -5.011 -5.014 -0.002 (0) + H2SiO4-2 7.916e-10 7.745e-10 -9.101 -9.111 -0.009 (0) ------------------------------Saturation indices------------------------------- @@ -882,29 +882,29 @@ Kaolinite -3.45 2.25 5.71 0.000e+00 0 0.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.077e-07 1.076e-07 -6.968 -6.968 -0.000 - H+ 9.306e-08 9.302e-08 -7.031 -7.031 -0.000 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 2.813e-08 - Al(OH)4- 2.603e-08 2.602e-08 -7.585 -7.585 -0.000 - Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 - Al(OH)2+ 8.110e-10 8.107e-10 -9.091 -9.091 -0.000 - AlOH+2 9.638e-12 9.621e-12 -11.016 -11.017 -0.001 - Al+3 9.044e-14 9.009e-14 -13.044 -13.045 -0.002 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.127 -40.127 0.000 -K 4.000e-08 - K+ 4.000e-08 3.998e-08 -7.398 -7.398 -0.000 - KOH 1.490e-15 1.490e-15 -14.827 -14.827 0.000 -O(0) 1.494e-12 - O2 7.470e-13 7.470e-13 -12.127 -12.127 0.000 -Si 1.200e-07 - H4SiO4 1.198e-07 1.198e-07 -6.922 -6.922 0.000 - H3SiO4- 1.900e-10 1.899e-10 -9.721 -9.721 -0.000 - H2SiO4-2 1.391e-16 1.389e-16 -15.857 -15.857 -0.001 + OH- 1.077e-07 1.076e-07 -6.968 -6.968 -0.000 (0) + H+ 9.306e-08 9.302e-08 -7.031 -7.031 -0.000 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 2.813e-08 + Al(OH)4- 2.603e-08 2.602e-08 -7.585 -7.585 -0.000 (0) + Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 (0) + Al(OH)2+ 8.110e-10 8.107e-10 -9.091 -9.091 -0.000 (0) + AlOH+2 9.638e-12 9.621e-12 -11.016 -11.017 -0.001 (0) + Al+3 9.044e-14 9.009e-14 -13.044 -13.045 -0.002 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.127 -40.127 0.000 (0) +K 4.000e-08 + K+ 4.000e-08 3.998e-08 -7.398 -7.398 -0.000 9.03 + KOH 1.490e-15 1.490e-15 -14.827 -14.827 0.000 (0) +O(0) 1.494e-12 + O2 7.470e-13 7.470e-13 -12.127 -12.127 0.000 (0) +Si 1.200e-07 + H4SiO4 1.198e-07 1.198e-07 -6.922 -6.922 0.000 56.00 + H3SiO4- 1.900e-10 1.899e-10 -9.721 -9.721 -0.000 (0) + H2SiO4-2 1.391e-16 1.389e-16 -15.857 -15.857 -0.001 (0) ------------------------------Saturation indices------------------------------- @@ -984,29 +984,29 @@ Kaolinite -2.85 2.86 5.71 0.000e+00 0 0.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.278e-07 1.277e-07 -6.894 -6.894 -0.000 - H+ 7.842e-08 7.838e-08 -7.106 -7.106 -0.000 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 3.287e-08 - Al(OH)4- 3.089e-08 3.088e-08 -7.510 -7.510 -0.000 - Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 - Al(OH)2+ 6.834e-10 6.831e-10 -9.165 -9.166 -0.000 - AlOH+2 6.845e-12 6.832e-12 -11.165 -11.165 -0.001 - Al+3 5.414e-14 5.391e-14 -13.267 -13.268 -0.002 -H(0) 2.308e-40 - H2 1.154e-40 1.154e-40 -39.938 -39.938 0.000 -K 8.000e-08 - K+ 8.000e-08 7.996e-08 -7.097 -7.097 -0.000 - KOH 3.537e-15 3.537e-15 -14.451 -14.451 0.000 -O(0) 6.262e-13 - O2 3.131e-13 3.131e-13 -12.504 -12.504 0.000 -Si 2.400e-07 - H4SiO4 2.395e-07 2.395e-07 -6.621 -6.621 0.000 - H3SiO4- 4.508e-10 4.506e-10 -9.346 -9.346 -0.000 - H2SiO4-2 3.918e-16 3.911e-16 -15.407 -15.408 -0.001 + OH- 1.278e-07 1.277e-07 -6.894 -6.894 -0.000 (0) + H+ 7.842e-08 7.838e-08 -7.106 -7.106 -0.000 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 3.287e-08 + Al(OH)4- 3.089e-08 3.088e-08 -7.510 -7.510 -0.000 (0) + Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 (0) + Al(OH)2+ 6.834e-10 6.831e-10 -9.165 -9.166 -0.000 (0) + AlOH+2 6.845e-12 6.832e-12 -11.165 -11.165 -0.001 (0) + Al+3 5.414e-14 5.391e-14 -13.267 -13.268 -0.002 (0) +H(0) 2.308e-40 + H2 1.154e-40 1.154e-40 -39.938 -39.938 0.000 (0) +K 8.000e-08 + K+ 8.000e-08 7.996e-08 -7.097 -7.097 -0.000 9.03 + KOH 3.537e-15 3.537e-15 -14.451 -14.451 0.000 (0) +O(0) 6.262e-13 + O2 3.131e-13 3.131e-13 -12.504 -12.504 0.000 (0) +Si 2.400e-07 + H4SiO4 2.395e-07 2.395e-07 -6.621 -6.621 0.000 56.00 + H3SiO4- 4.508e-10 4.506e-10 -9.346 -9.346 -0.000 (0) + H2SiO4-2 3.918e-16 3.911e-16 -15.407 -15.408 -0.001 (0) ------------------------------Saturation indices------------------------------- @@ -1086,29 +1086,29 @@ Kaolinite -2.25 3.46 5.71 0.000e+00 0 0.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.745e-07 1.744e-07 -6.758 -6.758 -0.000 - H+ 5.743e-08 5.740e-08 -7.241 -7.241 -0.000 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 4.398e-08 - Al(OH)4- 4.219e-08 4.217e-08 -7.375 -7.375 -0.000 - Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 - Al(OH)2+ 5.005e-10 5.002e-10 -9.301 -9.301 -0.000 - AlOH+2 3.671e-12 3.663e-12 -11.435 -11.436 -0.001 - Al+3 2.127e-14 2.117e-14 -13.672 -13.674 -0.002 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.113 -40.113 0.000 -K 1.600e-07 - K+ 1.600e-07 1.599e-07 -6.796 -6.796 -0.000 - KOH 9.661e-15 9.661e-15 -14.015 -14.015 0.000 -O(0) 1.405e-12 - O2 7.025e-13 7.025e-13 -12.153 -12.153 0.000 -Si 4.800e-07 - H4SiO4 4.788e-07 4.788e-07 -6.320 -6.320 0.000 - H3SiO4- 1.231e-09 1.230e-09 -8.910 -8.910 -0.000 - H2SiO4-2 1.461e-15 1.458e-15 -14.835 -14.836 -0.001 + OH- 1.745e-07 1.744e-07 -6.758 -6.758 -0.000 (0) + H+ 5.743e-08 5.740e-08 -7.241 -7.241 -0.000 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 4.398e-08 + Al(OH)4- 4.219e-08 4.217e-08 -7.375 -7.375 -0.000 (0) + Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 (0) + Al(OH)2+ 5.005e-10 5.002e-10 -9.301 -9.301 -0.000 (0) + AlOH+2 3.671e-12 3.663e-12 -11.435 -11.436 -0.001 (0) + Al+3 2.127e-14 2.117e-14 -13.672 -13.674 -0.002 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.113 -40.113 0.000 (0) +K 1.600e-07 + K+ 1.600e-07 1.599e-07 -6.796 -6.796 -0.000 9.03 + KOH 9.661e-15 9.661e-15 -14.015 -14.015 0.000 (0) +O(0) 1.405e-12 + O2 7.025e-13 7.025e-13 -12.153 -12.153 0.000 (0) +Si 4.800e-07 + H4SiO4 4.788e-07 4.788e-07 -6.320 -6.320 0.000 56.00 + H3SiO4- 1.231e-09 1.230e-09 -8.910 -8.910 -0.000 (0) + H2SiO4-2 1.461e-15 1.458e-15 -14.835 -14.836 -0.001 (0) ------------------------------Saturation indices------------------------------- @@ -1188,29 +1188,29 @@ Kaolinite -1.65 4.06 5.71 0.000e+00 0 0.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.832e-07 2.830e-07 -6.548 -6.548 -0.000 - H+ 3.539e-08 3.537e-08 -7.451 -7.451 -0.000 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 7.007e-08 - Al(OH)4- 6.848e-08 6.843e-08 -7.164 -7.165 -0.000 - Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 - Al(OH)2+ 3.085e-10 3.082e-10 -9.511 -9.511 -0.000 - AlOH+2 1.395e-12 1.391e-12 -11.855 -11.857 -0.001 - Al+3 4.984e-15 4.953e-15 -14.302 -14.305 -0.003 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.429 -40.429 0.000 -K 3.200e-07 - K+ 3.200e-07 3.198e-07 -6.495 -6.495 -0.000 - KOH 3.135e-14 3.135e-14 -13.504 -13.504 0.000 -O(0) 6.000e-12 - O2 3.000e-12 3.000e-12 -11.523 -11.523 0.000 -Si 9.600e-07 - H4SiO4 9.560e-07 9.560e-07 -6.020 -6.020 0.000 - H3SiO4- 3.988e-09 3.986e-09 -8.399 -8.400 -0.000 - H2SiO4-2 7.687e-15 7.665e-15 -14.114 -14.115 -0.001 + OH- 2.832e-07 2.830e-07 -6.548 -6.548 -0.000 (0) + H+ 3.539e-08 3.537e-08 -7.451 -7.451 -0.000 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 7.007e-08 + Al(OH)4- 6.848e-08 6.843e-08 -7.164 -7.165 -0.000 (0) + Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 (0) + Al(OH)2+ 3.085e-10 3.082e-10 -9.511 -9.511 -0.000 (0) + AlOH+2 1.395e-12 1.391e-12 -11.855 -11.857 -0.001 (0) + Al+3 4.984e-15 4.953e-15 -14.302 -14.305 -0.003 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.429 -40.429 0.000 (0) +K 3.200e-07 + K+ 3.200e-07 3.198e-07 -6.495 -6.495 -0.000 9.03 + KOH 3.135e-14 3.135e-14 -13.504 -13.504 0.000 (0) +O(0) 6.000e-12 + O2 3.000e-12 3.000e-12 -11.523 -11.523 0.000 (0) +Si 9.600e-07 + H4SiO4 9.560e-07 9.560e-07 -6.020 -6.020 0.000 56.00 + H3SiO4- 3.988e-09 3.986e-09 -8.399 -8.400 -0.000 (0) + H2SiO4-2 7.687e-15 7.665e-15 -14.114 -14.115 -0.001 (0) ------------------------------Saturation indices------------------------------- @@ -1290,29 +1290,29 @@ Kaolinite -1.05 4.66 5.71 0.000e+00 0 0.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 5.193e-07 5.189e-07 -6.285 -6.285 -0.000 - H+ 1.931e-08 1.929e-08 -7.714 -7.715 -0.000 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 1.270e-07 - Al(OH)4- 1.256e-07 1.254e-07 -6.901 -6.902 -0.000 - Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 - Al(OH)2+ 1.683e-10 1.681e-10 -9.774 -9.774 -0.000 - AlOH+2 4.155e-13 4.139e-13 -12.381 -12.383 -0.002 - Al+3 8.109e-16 8.040e-16 -15.091 -15.095 -0.004 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.567 -40.567 0.000 -K 6.400e-07 - K+ 6.400e-07 6.394e-07 -6.194 -6.194 -0.000 - KOH 1.149e-13 1.149e-13 -12.940 -12.940 0.000 -O(0) 1.135e-11 - O2 5.673e-12 5.673e-12 -11.246 -11.246 0.000 -Si 1.920e-06 - H4SiO4 1.905e-06 1.905e-06 -5.720 -5.720 0.000 - H3SiO4- 1.458e-08 1.456e-08 -7.836 -7.837 -0.000 - H2SiO4-2 5.153e-14 5.134e-14 -13.288 -13.290 -0.002 + OH- 5.193e-07 5.189e-07 -6.285 -6.285 -0.000 (0) + H+ 1.931e-08 1.929e-08 -7.714 -7.715 -0.000 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 1.270e-07 + Al(OH)4- 1.256e-07 1.254e-07 -6.901 -6.902 -0.000 (0) + Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 (0) + Al(OH)2+ 1.683e-10 1.681e-10 -9.774 -9.774 -0.000 (0) + AlOH+2 4.155e-13 4.139e-13 -12.381 -12.383 -0.002 (0) + Al+3 8.109e-16 8.040e-16 -15.091 -15.095 -0.004 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.567 -40.567 0.000 (0) +K 6.400e-07 + K+ 6.400e-07 6.394e-07 -6.194 -6.194 -0.000 9.03 + KOH 1.149e-13 1.149e-13 -12.940 -12.940 0.000 (0) +O(0) 1.135e-11 + O2 5.673e-12 5.673e-12 -11.246 -11.246 0.000 (0) +Si 1.920e-06 + H4SiO4 1.905e-06 1.905e-06 -5.720 -5.720 0.000 56.00 + H3SiO4- 1.458e-08 1.456e-08 -7.836 -7.837 -0.000 (0) + H2SiO4-2 5.153e-14 5.134e-14 -13.288 -13.290 -0.002 (0) ------------------------------Saturation indices------------------------------- @@ -1392,29 +1392,29 @@ Kaolinite -0.67 5.04 5.71 0.000e+00 0 0.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 7.879e-07 7.870e-07 -6.104 -6.104 -0.001 - H+ 1.274e-08 1.272e-08 -7.895 -7.896 -0.001 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 1.919e-07 - Al(OH)4- 1.905e-07 1.903e-07 -6.720 -6.721 -0.001 - Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 - Al(OH)2+ 1.110e-10 1.109e-10 -9.955 -9.955 -0.001 - AlOH+2 1.808e-13 1.799e-13 -12.743 -12.745 -0.002 - Al+3 2.328e-16 2.304e-16 -15.633 -15.638 -0.005 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.520 -40.520 0.000 -K 1.000e-06 - K+ 1.000e-06 9.988e-07 -6.000 -6.001 -0.001 - KOH 2.723e-13 2.723e-13 -12.565 -12.565 0.000 -O(0) 9.161e-12 - O2 4.580e-12 4.580e-12 -11.339 -11.339 0.000 -Si 3.000e-06 - H4SiO4 2.966e-06 2.966e-06 -5.528 -5.528 0.000 - H3SiO4- 3.442e-08 3.438e-08 -7.463 -7.464 -0.001 - H2SiO4-2 1.847e-13 1.838e-13 -12.734 -12.736 -0.002 + OH- 7.879e-07 7.870e-07 -6.104 -6.104 -0.001 (0) + H+ 1.274e-08 1.272e-08 -7.895 -7.896 -0.001 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 1.919e-07 + Al(OH)4- 1.905e-07 1.903e-07 -6.720 -6.721 -0.001 (0) + Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 (0) + Al(OH)2+ 1.110e-10 1.109e-10 -9.955 -9.955 -0.001 (0) + AlOH+2 1.808e-13 1.799e-13 -12.743 -12.745 -0.002 (0) + Al+3 2.328e-16 2.304e-16 -15.633 -15.638 -0.005 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.520 -40.520 0.000 (0) +K 1.000e-06 + K+ 1.000e-06 9.988e-07 -6.000 -6.001 -0.001 9.03 + KOH 2.723e-13 2.723e-13 -12.565 -12.565 0.000 (0) +O(0) 9.161e-12 + O2 4.580e-12 4.580e-12 -11.339 -11.339 0.000 (0) +Si 3.000e-06 + H4SiO4 2.966e-06 2.966e-06 -5.528 -5.528 0.000 56.00 + H3SiO4- 3.442e-08 3.438e-08 -7.463 -7.464 -0.001 (0) + H2SiO4-2 1.847e-13 1.838e-13 -12.734 -12.736 -0.002 (0) ------------------------------Saturation indices------------------------------- @@ -1494,29 +1494,29 @@ Kaolinite -0.07 5.64 5.71 0.000e+00 0 0.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.511e-06 1.508e-06 -5.821 -5.822 -0.001 - H+ 6.648e-09 6.637e-09 -8.177 -8.178 -0.001 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 3.666e-07 - Al(OH)4- 3.653e-07 3.647e-07 -6.437 -6.438 -0.001 - Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 - Al(OH)2+ 5.794e-11 5.784e-11 -10.237 -10.238 -0.001 - AlOH+2 4.931e-14 4.898e-14 -13.307 -13.310 -0.003 - Al+3 3.322e-17 3.273e-17 -16.479 -16.485 -0.006 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.707 -40.707 0.000 -K 2.000e-06 - K+ 2.000e-06 1.997e-06 -5.699 -5.700 -0.001 - KOH 1.043e-12 1.043e-12 -11.982 -11.982 0.000 -O(0) 2.159e-11 - O2 1.080e-11 1.080e-11 -10.967 -10.967 0.000 -Si 6.000e-06 - H4SiO4 5.869e-06 5.869e-06 -5.231 -5.231 0.000 - H3SiO4- 1.306e-07 1.304e-07 -6.884 -6.885 -0.001 - H2SiO4-2 1.345e-12 1.336e-12 -11.871 -11.874 -0.003 + OH- 1.511e-06 1.508e-06 -5.821 -5.822 -0.001 (0) + H+ 6.648e-09 6.637e-09 -8.177 -8.178 -0.001 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 3.666e-07 + Al(OH)4- 3.653e-07 3.647e-07 -6.437 -6.438 -0.001 (0) + Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 (0) + Al(OH)2+ 5.794e-11 5.784e-11 -10.237 -10.238 -0.001 (0) + AlOH+2 4.931e-14 4.898e-14 -13.307 -13.310 -0.003 (0) + Al+3 3.322e-17 3.273e-17 -16.479 -16.485 -0.006 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.707 -40.707 0.000 (0) +K 2.000e-06 + K+ 2.000e-06 1.997e-06 -5.699 -5.700 -0.001 9.03 + KOH 1.043e-12 1.043e-12 -11.982 -11.982 0.000 (0) +O(0) 2.159e-11 + O2 1.080e-11 1.080e-11 -10.967 -10.967 0.000 (0) +Si 6.000e-06 + H4SiO4 5.869e-06 5.869e-06 -5.231 -5.231 0.000 56.00 + H3SiO4- 1.306e-07 1.304e-07 -6.884 -6.885 -0.001 (0) + H2SiO4-2 1.345e-12 1.336e-12 -11.871 -11.874 -0.003 (0) ------------------------------Saturation indices------------------------------- @@ -1596,29 +1596,29 @@ Kaolinite 0.00 5.71 5.71 0.000e+00 1.712e-06 1.712e-06 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 3.059e-06 3.051e-06 -5.514 -5.516 -0.001 - H+ 3.288e-09 3.281e-09 -8.483 -8.484 -0.001 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 5.761e-07 - Al(OH)4- 5.751e-07 5.737e-07 -6.240 -6.241 -0.001 - Al(OH)3 9.987e-10 9.987e-10 -9.001 -9.001 0.000 - Al(OH)2+ 2.229e-11 2.224e-11 -10.652 -10.653 -0.001 - AlOH+2 9.396e-15 9.309e-15 -14.027 -14.031 -0.004 - Al+3 3.140e-18 3.074e-18 -17.503 -17.512 -0.009 -H(0) 2.356e-39 - H2 1.178e-39 1.178e-39 -38.929 -38.929 0.000 -K 4.000e-06 - K+ 4.000e-06 3.991e-06 -5.398 -5.399 -0.001 - KOH 4.218e-12 4.218e-12 -11.375 -11.375 0.000 -O(0) 6.008e-15 - O2 3.004e-15 3.004e-15 -14.522 -14.522 0.000 -Si 8.576e-06 - H4SiO4 8.206e-06 8.206e-06 -5.086 -5.086 0.000 - H3SiO4- 3.697e-07 3.688e-07 -6.432 -6.433 -0.001 - H2SiO4-2 7.719e-12 7.647e-12 -11.112 -11.116 -0.004 + OH- 3.059e-06 3.051e-06 -5.514 -5.516 -0.001 (0) + H+ 3.288e-09 3.281e-09 -8.483 -8.484 -0.001 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 5.761e-07 + Al(OH)4- 5.751e-07 5.737e-07 -6.240 -6.241 -0.001 (0) + Al(OH)3 9.987e-10 9.987e-10 -9.001 -9.001 0.000 (0) + Al(OH)2+ 2.229e-11 2.224e-11 -10.652 -10.653 -0.001 (0) + AlOH+2 9.396e-15 9.309e-15 -14.027 -14.031 -0.004 (0) + Al+3 3.140e-18 3.074e-18 -17.503 -17.512 -0.009 (0) +H(0) 2.356e-39 + H2 1.178e-39 1.178e-39 -38.929 -38.929 0.000 (0) +K 4.000e-06 + K+ 4.000e-06 3.991e-06 -5.398 -5.399 -0.001 9.03 + KOH 4.218e-12 4.218e-12 -11.375 -11.375 0.000 (0) +O(0) 6.008e-15 + O2 3.004e-15 3.004e-15 -14.522 -14.522 0.000 (0) +Si 8.576e-06 + H4SiO4 8.206e-06 8.206e-06 -5.086 -5.086 0.000 56.00 + H3SiO4- 3.697e-07 3.688e-07 -6.432 -6.433 -0.001 (0) + H2SiO4-2 7.719e-12 7.647e-12 -11.112 -11.116 -0.004 (0) ------------------------------Saturation indices------------------------------- @@ -1698,29 +1698,29 @@ Kaolinite -0.00 5.71 5.71 0.000e+00 3.695e-06 3.695e-06 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 6.035e-06 6.015e-06 -5.219 -5.221 -0.001 - H+ 1.670e-09 1.664e-09 -8.777 -8.779 -0.001 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 6.110e-07 - Al(OH)4- 6.105e-07 6.084e-07 -6.214 -6.216 -0.001 - Al(OH)3 5.373e-10 5.373e-10 -9.270 -9.270 0.000 - Al(OH)2+ 6.089e-12 6.069e-12 -11.215 -11.217 -0.001 - AlOH+2 1.306e-15 1.289e-15 -14.884 -14.890 -0.006 - Al+3 2.224e-19 2.159e-19 -18.653 -18.666 -0.013 -H(0) 1.931e-39 - H2 9.655e-40 9.655e-40 -39.015 -39.015 0.000 -K 8.000e-06 - K+ 8.000e-06 7.974e-06 -5.097 -5.098 -0.001 - KOH 1.661e-11 1.661e-11 -10.780 -10.780 0.000 -O(0) 8.944e-15 - O2 4.472e-15 4.472e-15 -14.349 -14.349 0.000 -Si 1.661e-05 - H4SiO4 1.525e-05 1.525e-05 -4.817 -4.817 0.000 - H3SiO4- 1.356e-06 1.352e-06 -5.868 -5.869 -0.001 - H2SiO4-2 5.598e-11 5.524e-11 -10.252 -10.258 -0.006 + OH- 6.035e-06 6.015e-06 -5.219 -5.221 -0.001 (0) + H+ 1.670e-09 1.664e-09 -8.777 -8.779 -0.001 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 6.110e-07 + Al(OH)4- 6.105e-07 6.084e-07 -6.214 -6.216 -0.001 (0) + Al(OH)3 5.373e-10 5.373e-10 -9.270 -9.270 0.000 (0) + Al(OH)2+ 6.089e-12 6.069e-12 -11.215 -11.217 -0.001 (0) + AlOH+2 1.306e-15 1.289e-15 -14.884 -14.890 -0.006 (0) + Al+3 2.224e-19 2.159e-19 -18.653 -18.666 -0.013 (0) +H(0) 1.931e-39 + H2 9.655e-40 9.655e-40 -39.015 -39.015 0.000 (0) +K 8.000e-06 + K+ 8.000e-06 7.974e-06 -5.097 -5.098 -0.001 9.03 + KOH 1.661e-11 1.661e-11 -10.780 -10.780 0.000 (0) +O(0) 8.944e-15 + O2 4.472e-15 4.472e-15 -14.349 -14.349 0.000 (0) +Si 1.661e-05 + H4SiO4 1.525e-05 1.525e-05 -4.817 -4.817 0.000 56.00 + H3SiO4- 1.356e-06 1.352e-06 -5.868 -5.869 -0.001 (0) + H2SiO4-2 5.598e-11 5.524e-11 -10.252 -10.258 -0.006 (0) ------------------------------Saturation indices------------------------------- @@ -1800,29 +1800,29 @@ Kaolinite 0.00 5.71 5.71 0.000e+00 7.701e-06 7.701e-06 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.089e-05 1.084e-05 -4.963 -4.965 -0.002 - H+ 9.275e-10 9.232e-10 -9.033 -9.035 -0.002 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 5.987e-07 - Al(OH)4- 5.984e-07 5.956e-07 -6.223 -6.225 -0.002 - Al(OH)3 2.918e-10 2.918e-10 -9.535 -9.535 0.000 - Al(OH)2+ 1.837e-12 1.828e-12 -11.736 -11.738 -0.002 - AlOH+2 2.194e-16 2.153e-16 -15.659 -15.667 -0.008 - Al+3 2.087e-20 2.001e-20 -19.681 -19.699 -0.018 -H(0) 3.011e-39 - H2 1.505e-39 1.505e-39 -38.822 -38.822 0.000 -K 1.600e-05 - K+ 1.600e-05 1.593e-05 -4.796 -4.798 -0.002 - KOH 5.981e-11 5.981e-11 -10.223 -10.223 0.000 -O(0) 3.679e-15 - O2 1.840e-15 1.840e-15 -14.735 -14.735 0.000 -Si 3.260e-05 - H4SiO4 2.809e-05 2.809e-05 -4.551 -4.551 0.000 - H3SiO4- 4.508e-06 4.487e-06 -5.346 -5.348 -0.002 - H2SiO4-2 3.368e-10 3.306e-10 -9.473 -9.481 -0.008 + OH- 1.089e-05 1.084e-05 -4.963 -4.965 -0.002 (0) + H+ 9.275e-10 9.232e-10 -9.033 -9.035 -0.002 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 5.987e-07 + Al(OH)4- 5.984e-07 5.956e-07 -6.223 -6.225 -0.002 (0) + Al(OH)3 2.918e-10 2.918e-10 -9.535 -9.535 0.000 (0) + Al(OH)2+ 1.837e-12 1.828e-12 -11.736 -11.738 -0.002 (0) + AlOH+2 2.194e-16 2.153e-16 -15.659 -15.667 -0.008 (0) + Al+3 2.087e-20 2.001e-20 -19.681 -19.699 -0.018 (0) +H(0) 3.011e-39 + H2 1.505e-39 1.505e-39 -38.822 -38.822 0.000 (0) +K 1.600e-05 + K+ 1.600e-05 1.593e-05 -4.796 -4.798 -0.002 9.03 + KOH 5.981e-11 5.981e-11 -10.223 -10.223 0.000 (0) +O(0) 3.679e-15 + O2 1.840e-15 1.840e-15 -14.735 -14.735 0.000 (0) +Si 3.260e-05 + H4SiO4 2.809e-05 2.809e-05 -4.551 -4.551 0.000 56.00 + H3SiO4- 4.508e-06 4.487e-06 -5.346 -5.348 -0.002 (0) + H2SiO4-2 3.368e-10 3.306e-10 -9.473 -9.481 -0.008 (0) ------------------------------Saturation indices------------------------------- @@ -1902,29 +1902,29 @@ Kaolinite -0.00 5.71 5.71 0.000e+00 5.270e-07 5.270e-07 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.188e-05 1.182e-05 -4.925 -4.928 -0.002 - H+ 8.519e-10 8.473e-10 -9.070 -9.072 -0.002 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 3.349e-07 - Al(OH)4- 3.348e-07 3.330e-07 -6.475 -6.478 -0.002 - Al(OH)3 1.497e-10 1.497e-10 -9.825 -9.825 0.000 - Al(OH)2+ 8.654e-13 8.607e-13 -12.063 -12.065 -0.002 - AlOH+2 9.510e-17 9.305e-17 -16.022 -16.031 -0.009 - Al+3 8.332e-21 7.937e-21 -20.079 -20.100 -0.021 -H(0) 2.557e-40 - H2 1.278e-40 1.278e-40 -39.893 -39.893 0.000 -K 2.180e-05 - K+ 2.180e-05 2.168e-05 -4.662 -4.664 -0.002 - KOH 8.871e-11 8.872e-11 -10.052 -10.052 0.000 -O(0) 5.102e-13 - O2 2.551e-13 2.551e-13 -12.593 -12.593 0.000 -Si 6.434e-05 - H4SiO4 5.475e-05 5.475e-05 -4.262 -4.262 0.000 - H3SiO4- 9.581e-06 9.529e-06 -5.019 -5.021 -0.002 - H2SiO4-2 7.819e-10 7.650e-10 -9.107 -9.116 -0.009 + OH- 1.188e-05 1.182e-05 -4.925 -4.928 -0.002 (0) + H+ 8.519e-10 8.473e-10 -9.070 -9.072 -0.002 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 3.349e-07 + Al(OH)4- 3.348e-07 3.330e-07 -6.475 -6.478 -0.002 (0) + Al(OH)3 1.497e-10 1.497e-10 -9.825 -9.825 0.000 (0) + Al(OH)2+ 8.654e-13 8.607e-13 -12.063 -12.065 -0.002 (0) + AlOH+2 9.510e-17 9.305e-17 -16.022 -16.031 -0.009 (0) + Al+3 8.332e-21 7.937e-21 -20.079 -20.100 -0.021 (0) +H(0) 2.557e-40 + H2 1.278e-40 1.278e-40 -39.893 -39.893 0.000 (0) +K 2.180e-05 + K+ 2.180e-05 2.168e-05 -4.662 -4.664 -0.002 9.03 + KOH 8.871e-11 8.872e-11 -10.052 -10.052 0.000 (0) +O(0) 5.102e-13 + O2 2.551e-13 2.551e-13 -12.593 -12.593 0.000 (0) +Si 6.434e-05 + H4SiO4 5.475e-05 5.475e-05 -4.262 -4.262 0.000 56.00 + H3SiO4- 9.581e-06 9.529e-06 -5.019 -5.021 -0.002 (0) + H2SiO4-2 7.819e-10 7.650e-10 -9.107 -9.116 -0.009 (0) ------------------------------Saturation indices------------------------------- @@ -2004,29 +2004,29 @@ Kaolinite -0.30 5.41 5.71 0.000e+00 0 0.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.694e-05 1.681e-05 -4.771 -4.774 -0.003 - H+ 5.999e-10 5.954e-10 -9.222 -9.225 -0.003 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 1.812e-07 - Al(OH)4- 1.812e-07 1.798e-07 -6.742 -6.745 -0.003 - Al(OH)3 5.680e-11 5.680e-11 -10.246 -10.246 0.000 - Al(OH)2+ 2.313e-13 2.295e-13 -12.636 -12.639 -0.003 - AlOH+2 1.797e-17 1.744e-17 -16.745 -16.759 -0.013 - Al+3 1.118e-21 1.045e-21 -20.951 -20.981 -0.029 -H(0) 1.238e-39 - H2 6.191e-40 6.191e-40 -39.208 -39.208 0.000 -K 4.273e-05 - K+ 4.273e-05 4.240e-05 -4.369 -4.373 -0.003 - KOH 2.469e-10 2.469e-10 -9.607 -9.607 0.000 -O(0) 2.175e-14 - O2 1.087e-14 1.087e-14 -13.964 -13.964 0.000 -Si 1.282e-04 - H4SiO4 1.026e-04 1.026e-04 -3.989 -3.989 0.000 - H3SiO4- 2.560e-05 2.540e-05 -4.592 -4.595 -0.003 - H2SiO4-2 2.992e-09 2.902e-09 -8.524 -8.537 -0.013 + OH- 1.694e-05 1.681e-05 -4.771 -4.774 -0.003 (0) + H+ 5.999e-10 5.954e-10 -9.222 -9.225 -0.003 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 1.812e-07 + Al(OH)4- 1.812e-07 1.798e-07 -6.742 -6.745 -0.003 (0) + Al(OH)3 5.680e-11 5.680e-11 -10.246 -10.246 0.000 (0) + Al(OH)2+ 2.313e-13 2.295e-13 -12.636 -12.639 -0.003 (0) + AlOH+2 1.797e-17 1.744e-17 -16.745 -16.759 -0.013 (0) + Al+3 1.118e-21 1.045e-21 -20.951 -20.981 -0.029 (0) +H(0) 1.238e-39 + H2 6.191e-40 6.191e-40 -39.208 -39.208 0.000 (0) +K 4.273e-05 + K+ 4.273e-05 4.240e-05 -4.369 -4.373 -0.003 9.03 + KOH 2.469e-10 2.469e-10 -9.607 -9.607 0.000 (0) +O(0) 2.175e-14 + O2 1.087e-14 1.087e-14 -13.964 -13.964 0.000 (0) +Si 1.282e-04 + H4SiO4 1.026e-04 1.026e-04 -3.989 -3.989 0.000 56.00 + H3SiO4- 2.560e-05 2.540e-05 -4.592 -4.595 -0.003 (0) + H2SiO4-2 2.992e-09 2.902e-09 -8.524 -8.537 -0.013 (0) ------------------------------Saturation indices------------------------------- @@ -2106,29 +2106,29 @@ Kaolinite -0.48 5.23 5.71 0.000e+00 0 0.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.038e-05 2.019e-05 -4.691 -4.695 -0.004 - H+ 5.006e-10 4.959e-10 -9.301 -9.305 -0.004 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 1.179e-07 - Al(OH)4- 1.179e-07 1.167e-07 -6.929 -6.933 -0.004 - Al(OH)3 3.072e-11 3.072e-11 -10.513 -10.513 0.000 - Al(OH)2+ 1.044e-13 1.034e-13 -12.981 -12.985 -0.004 - AlOH+2 6.796e-18 6.543e-18 -17.168 -17.184 -0.016 - Al+3 3.554e-22 3.267e-22 -21.449 -21.486 -0.037 -H(0) 2.523e-39 - H2 1.261e-39 1.261e-39 -38.899 -38.899 0.000 -K 6.671e-05 - K+ 6.671e-05 6.608e-05 -4.176 -4.180 -0.004 - KOH 4.620e-10 4.620e-10 -9.335 -9.335 0.000 -O(0) 5.240e-15 - O2 2.620e-15 2.620e-15 -14.582 -14.582 0.000 -Si 2.001e-04 - H4SiO4 1.539e-04 1.539e-04 -3.813 -3.813 0.000 - H3SiO4- 4.620e-05 4.576e-05 -4.335 -4.339 -0.004 - H2SiO4-2 6.519e-09 6.277e-09 -8.186 -8.202 -0.016 + OH- 2.038e-05 2.019e-05 -4.691 -4.695 -0.004 (0) + H+ 5.006e-10 4.959e-10 -9.301 -9.305 -0.004 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 1.179e-07 + Al(OH)4- 1.179e-07 1.167e-07 -6.929 -6.933 -0.004 (0) + Al(OH)3 3.072e-11 3.072e-11 -10.513 -10.513 0.000 (0) + Al(OH)2+ 1.044e-13 1.034e-13 -12.981 -12.985 -0.004 (0) + AlOH+2 6.796e-18 6.543e-18 -17.168 -17.184 -0.016 (0) + Al+3 3.554e-22 3.267e-22 -21.449 -21.486 -0.037 (0) +H(0) 2.523e-39 + H2 1.261e-39 1.261e-39 -38.899 -38.899 0.000 (0) +K 6.671e-05 + K+ 6.671e-05 6.608e-05 -4.176 -4.180 -0.004 9.03 + KOH 4.620e-10 4.620e-10 -9.335 -9.335 0.000 (0) +O(0) 5.240e-15 + O2 2.620e-15 2.620e-15 -14.582 -14.582 0.000 (0) +Si 2.001e-04 + H4SiO4 1.539e-04 1.539e-04 -3.813 -3.813 0.000 56.00 + H3SiO4- 4.620e-05 4.576e-05 -4.335 -4.339 -0.004 (0) + H2SiO4-2 6.519e-09 6.277e-09 -8.186 -8.202 -0.016 (0) ------------------------------Saturation indices------------------------------- @@ -2208,29 +2208,29 @@ Kaolinite -0.72 4.99 5.71 0.000e+00 0 0.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.486e-05 2.453e-05 -4.605 -4.610 -0.006 - H+ 4.133e-10 4.080e-10 -9.384 -9.389 -0.006 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 5.990e-08 - Al(OH)4- 5.988e-08 5.911e-08 -7.223 -7.228 -0.006 - Al(OH)3 1.280e-11 1.280e-11 -10.893 -10.893 0.000 - Al(OH)2+ 3.590e-14 3.544e-14 -13.445 -13.451 -0.006 - AlOH+2 1.944e-18 1.845e-18 -17.711 -17.734 -0.023 - Al+3 8.505e-23 7.579e-23 -22.070 -22.120 -0.050 -H(0) 5.406e-40 - H2 2.703e-40 2.703e-40 -39.568 -39.568 0.000 -K 1.273e-04 - K+ 1.273e-04 1.256e-04 -3.895 -3.901 -0.006 - KOH 1.067e-09 1.067e-09 -8.972 -8.972 0.000 -O(0) 1.141e-13 - O2 5.705e-14 5.705e-14 -13.244 -13.244 0.000 -Si 3.818e-04 - H4SiO4 2.795e-04 2.795e-04 -3.554 -3.554 0.000 - H3SiO4- 1.023e-04 1.010e-04 -3.990 -3.996 -0.006 - H2SiO4-2 1.774e-08 1.684e-08 -7.751 -7.774 -0.023 + OH- 2.486e-05 2.453e-05 -4.605 -4.610 -0.006 (0) + H+ 4.133e-10 4.080e-10 -9.384 -9.389 -0.006 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 5.990e-08 + Al(OH)4- 5.988e-08 5.911e-08 -7.223 -7.228 -0.006 (0) + Al(OH)3 1.280e-11 1.280e-11 -10.893 -10.893 0.000 (0) + Al(OH)2+ 3.590e-14 3.544e-14 -13.445 -13.451 -0.006 (0) + AlOH+2 1.944e-18 1.845e-18 -17.711 -17.734 -0.023 (0) + Al+3 8.505e-23 7.579e-23 -22.070 -22.120 -0.050 (0) +H(0) 5.406e-40 + H2 2.703e-40 2.703e-40 -39.568 -39.568 0.000 (0) +K 1.273e-04 + K+ 1.273e-04 1.256e-04 -3.895 -3.901 -0.006 9.03 + KOH 1.067e-09 1.067e-09 -8.972 -8.972 0.000 (0) +O(0) 1.141e-13 + O2 5.705e-14 5.705e-14 -13.244 -13.244 0.000 (0) +Si 3.818e-04 + H4SiO4 2.795e-04 2.795e-04 -3.554 -3.554 0.000 56.00 + H3SiO4- 1.023e-04 1.010e-04 -3.990 -3.996 -0.006 (0) + H2SiO4-2 1.774e-08 1.684e-08 -7.751 -7.774 -0.023 (0) ------------------------------Saturation indices------------------------------- @@ -2384,29 +2384,29 @@ Initial solution 1. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.001e-07 1.001e-07 -6.999 -7.000 -0.000 - H+ 1.000e-07 1.000e-07 -7.000 -7.000 -0.000 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 1.000e-13 - Al(OH)4- 9.178e-14 9.175e-14 -13.037 -13.037 -0.000 - Al(OH)3 4.868e-15 4.868e-15 -14.313 -14.313 0.000 - Al(OH)2+ 3.305e-15 3.304e-15 -14.481 -14.481 -0.000 - AlOH+2 4.222e-17 4.215e-17 -16.375 -16.375 -0.001 - Al+3 4.258e-19 4.244e-19 -18.371 -18.372 -0.001 -H(0) 1.416e-25 - H2 7.079e-26 7.079e-26 -25.150 -25.150 0.000 -K 1.000e-13 - K+ 1.000e-13 9.996e-14 -13.000 -13.000 -0.000 - KOH 3.466e-21 3.466e-21 -20.460 -20.460 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 -Si 3.000e-13 - H4SiO4 2.996e-13 2.996e-13 -12.524 -12.524 0.000 - H3SiO4- 4.419e-16 4.417e-16 -15.355 -15.355 -0.000 - H2SiO4-2 3.009e-22 3.005e-22 -21.522 -21.522 -0.001 + OH- 1.001e-07 1.001e-07 -6.999 -7.000 -0.000 (0) + H+ 1.000e-07 1.000e-07 -7.000 -7.000 -0.000 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 1.000e-13 + Al(OH)4- 9.178e-14 9.175e-14 -13.037 -13.037 -0.000 (0) + Al(OH)3 4.868e-15 4.868e-15 -14.313 -14.313 0.000 (0) + Al(OH)2+ 3.305e-15 3.304e-15 -14.481 -14.481 -0.000 (0) + AlOH+2 4.222e-17 4.215e-17 -16.375 -16.375 -0.001 (0) + Al+3 4.258e-19 4.244e-19 -18.371 -18.372 -0.001 (0) +H(0) 1.416e-25 + H2 7.079e-26 7.079e-26 -25.150 -25.150 0.000 (0) +K 1.000e-13 + K+ 1.000e-13 9.996e-14 -13.000 -13.000 -0.000 9.04 + KOH 3.466e-21 3.466e-21 -20.460 -20.460 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 (0) +Si 3.000e-13 + H4SiO4 2.996e-13 2.996e-13 -12.524 -12.524 0.000 56.00 + H3SiO4- 4.419e-16 4.417e-16 -15.355 -15.355 -0.000 (0) + H2SiO4-2 3.009e-22 3.005e-22 -21.522 -21.522 -0.001 (0) ------------------------------Saturation indices------------------------------- @@ -2487,29 +2487,29 @@ Kaolinite -9.09 -3.38 5.71 0.000e+00 0 0.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.002e-07 1.002e-07 -6.999 -6.999 -0.000 - H+ 9.997e-08 9.993e-08 -7.000 -7.000 -0.000 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 1.266e-09 - Al(OH)4- 1.162e-09 1.161e-09 -8.935 -8.935 -0.000 - Al(OH)3 6.157e-11 6.157e-11 -10.211 -10.211 0.000 - Al(OH)2+ 4.178e-11 4.176e-11 -10.379 -10.379 -0.000 - AlOH+2 5.332e-13 5.324e-13 -12.273 -12.274 -0.001 - Al+3 5.375e-15 5.356e-15 -14.270 -14.271 -0.001 -H(0) 1.016e-39 - H2 5.080e-40 5.080e-40 -39.294 -39.294 0.000 -K 1.266e-09 - K+ 1.266e-09 1.265e-09 -8.898 -8.898 -0.000 - KOH 4.390e-17 4.390e-17 -16.358 -16.358 0.000 -O(0) 3.230e-14 - O2 1.615e-14 1.615e-14 -13.792 -13.792 0.000 -Si 3.797e-09 - H4SiO4 3.791e-09 3.791e-09 -8.421 -8.421 0.000 - H3SiO4- 5.596e-12 5.594e-12 -11.252 -11.252 -0.000 - H2SiO4-2 3.814e-18 3.808e-18 -17.419 -17.419 -0.001 + OH- 1.002e-07 1.002e-07 -6.999 -6.999 -0.000 (0) + H+ 9.997e-08 9.993e-08 -7.000 -7.000 -0.000 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 1.266e-09 + Al(OH)4- 1.162e-09 1.161e-09 -8.935 -8.935 -0.000 (0) + Al(OH)3 6.157e-11 6.157e-11 -10.211 -10.211 0.000 (0) + Al(OH)2+ 4.178e-11 4.176e-11 -10.379 -10.379 -0.000 (0) + AlOH+2 5.332e-13 5.324e-13 -12.273 -12.274 -0.001 (0) + Al+3 5.375e-15 5.356e-15 -14.270 -14.271 -0.001 (0) +H(0) 1.016e-39 + H2 5.080e-40 5.080e-40 -39.294 -39.294 0.000 (0) +K 1.266e-09 + K+ 1.266e-09 1.265e-09 -8.898 -8.898 -0.000 9.03 + KOH 4.390e-17 4.390e-17 -16.358 -16.358 0.000 (0) +O(0) 3.230e-14 + O2 1.615e-14 1.615e-14 -13.792 -13.792 0.000 (0) +Si 3.797e-09 + H4SiO4 3.791e-09 3.791e-09 -8.421 -8.421 0.000 56.00 + H3SiO4- 5.596e-12 5.594e-12 -11.252 -11.252 -0.000 (0) + H2SiO4-2 3.814e-18 3.808e-18 -17.419 -17.419 -0.001 (0) ------------------------------Saturation indices------------------------------- @@ -2586,29 +2586,29 @@ Kaolinite -4.93 0.78 5.71 0.000e+00 0 0.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.009e-07 1.009e-07 -6.996 -6.996 -0.000 - H+ 9.928e-08 9.924e-08 -7.003 -7.003 -0.000 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 1.392e-08 - Al(OH)4- 1.279e-08 1.278e-08 -7.893 -7.893 -0.000 - Al(OH)3 6.731e-10 6.731e-10 -9.172 -9.172 0.000 - Al(OH)2+ 4.535e-10 4.533e-10 -9.343 -9.344 -0.000 - AlOH+2 5.749e-12 5.740e-12 -11.240 -11.241 -0.001 - Al+3 5.755e-14 5.734e-14 -13.240 -13.242 -0.002 -H(0) 9.530e-40 - H2 4.765e-40 4.765e-40 -39.322 -39.322 0.000 -K 1.392e-08 - K+ 1.392e-08 1.392e-08 -7.856 -7.856 -0.000 - KOH 4.862e-16 4.862e-16 -15.313 -15.313 0.000 -O(0) 3.672e-14 - O2 1.836e-14 1.836e-14 -13.736 -13.736 0.000 -Si 4.176e-08 - H4SiO4 4.170e-08 4.170e-08 -7.380 -7.380 0.000 - H3SiO4- 6.199e-11 6.196e-11 -10.208 -10.208 -0.000 - H2SiO4-2 4.254e-17 4.247e-17 -16.371 -16.372 -0.001 + OH- 1.009e-07 1.009e-07 -6.996 -6.996 -0.000 (0) + H+ 9.928e-08 9.924e-08 -7.003 -7.003 -0.000 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 1.392e-08 + Al(OH)4- 1.279e-08 1.278e-08 -7.893 -7.893 -0.000 (0) + Al(OH)3 6.731e-10 6.731e-10 -9.172 -9.172 0.000 (0) + Al(OH)2+ 4.535e-10 4.533e-10 -9.343 -9.344 -0.000 (0) + AlOH+2 5.749e-12 5.740e-12 -11.240 -11.241 -0.001 (0) + Al+3 5.755e-14 5.734e-14 -13.240 -13.242 -0.002 (0) +H(0) 9.530e-40 + H2 4.765e-40 4.765e-40 -39.322 -39.322 0.000 (0) +K 1.392e-08 + K+ 1.392e-08 1.392e-08 -7.856 -7.856 -0.000 9.03 + KOH 4.862e-16 4.862e-16 -15.313 -15.313 0.000 (0) +O(0) 3.672e-14 + O2 1.836e-14 1.836e-14 -13.736 -13.736 0.000 (0) +Si 4.176e-08 + H4SiO4 4.170e-08 4.170e-08 -7.380 -7.380 0.000 56.00 + H3SiO4- 6.199e-11 6.196e-11 -10.208 -10.208 -0.000 (0) + H2SiO4-2 4.254e-17 4.247e-17 -16.371 -16.372 -0.001 (0) ------------------------------Saturation indices------------------------------- @@ -2686,29 +2686,29 @@ Kaolinite -2.36 3.35 5.71 0.000e+00 0 0.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.625e-07 1.624e-07 -6.789 -6.789 -0.000 - H+ 6.167e-08 6.164e-08 -7.210 -7.210 -0.000 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 4.111e-08 - Al(OH)4- 3.929e-08 3.927e-08 -7.406 -7.406 -0.000 - Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 - Al(OH)2+ 5.374e-10 5.372e-10 -9.270 -9.270 -0.000 - AlOH+2 4.233e-12 4.224e-12 -11.373 -11.374 -0.001 - Al+3 2.634e-14 2.621e-14 -13.579 -13.582 -0.002 -H(0) 1.100e-39 - H2 5.498e-40 5.498e-40 -39.260 -39.260 0.000 -K 1.405e-07 - K+ 1.405e-07 1.404e-07 -6.852 -6.853 -0.000 - KOH 7.899e-15 7.899e-15 -14.102 -14.102 0.000 -O(0) 2.758e-14 - O2 1.379e-14 1.379e-14 -13.860 -13.860 0.000 -Si 4.214e-07 - H4SiO4 4.204e-07 4.204e-07 -6.376 -6.376 0.000 - H3SiO4- 1.006e-09 1.006e-09 -8.997 -8.997 -0.000 - H2SiO4-2 1.112e-15 1.110e-15 -14.954 -14.955 -0.001 + OH- 1.625e-07 1.624e-07 -6.789 -6.789 -0.000 (0) + H+ 6.167e-08 6.164e-08 -7.210 -7.210 -0.000 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 4.111e-08 + Al(OH)4- 3.929e-08 3.927e-08 -7.406 -7.406 -0.000 (0) + Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 (0) + Al(OH)2+ 5.374e-10 5.372e-10 -9.270 -9.270 -0.000 (0) + AlOH+2 4.233e-12 4.224e-12 -11.373 -11.374 -0.001 (0) + Al+3 2.634e-14 2.621e-14 -13.579 -13.582 -0.002 (0) +H(0) 1.100e-39 + H2 5.498e-40 5.498e-40 -39.260 -39.260 0.000 (0) +K 1.405e-07 + K+ 1.405e-07 1.404e-07 -6.852 -6.853 -0.000 9.03 + KOH 7.899e-15 7.899e-15 -14.102 -14.102 0.000 (0) +O(0) 2.758e-14 + O2 1.379e-14 1.379e-14 -13.860 -13.860 0.000 (0) +Si 4.214e-07 + H4SiO4 4.204e-07 4.204e-07 -6.376 -6.376 0.000 56.00 + H3SiO4- 1.006e-09 1.006e-09 -8.997 -8.997 -0.000 (0) + H2SiO4-2 1.112e-15 1.110e-15 -14.954 -14.955 -0.001 (0) ------------------------------Saturation indices------------------------------- @@ -2786,29 +2786,29 @@ Kaolinite -0.37 5.33 5.71 0.000e+00 0 0.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.086e-06 1.085e-06 -5.964 -5.965 -0.001 - H+ 9.240e-09 9.228e-09 -8.034 -8.035 -0.001 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 2.640e-07 - Al(OH)4- 2.626e-07 2.623e-07 -6.581 -6.581 -0.001 - Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 - Al(OH)2+ 8.053e-11 8.042e-11 -10.094 -10.095 -0.001 - AlOH+2 9.521e-14 9.468e-14 -13.021 -13.024 -0.002 - Al+3 8.906e-17 8.796e-17 -16.050 -16.056 -0.005 -H(0) 7.899e-40 - H2 3.950e-40 3.950e-40 -39.403 -39.403 0.000 -K 1.406e-06 - K+ 1.406e-06 1.404e-06 -5.852 -5.853 -0.001 - KOH 5.276e-13 5.276e-13 -12.278 -12.278 0.000 -O(0) 5.344e-14 - O2 2.672e-14 2.672e-14 -13.573 -13.573 0.000 -Si 4.218e-06 - H4SiO4 4.152e-06 4.152e-06 -5.382 -5.382 0.000 - H3SiO4- 6.643e-08 6.634e-08 -7.178 -7.178 -0.001 - H2SiO4-2 4.918e-13 4.890e-13 -12.308 -12.311 -0.002 + OH- 1.086e-06 1.085e-06 -5.964 -5.965 -0.001 (0) + H+ 9.240e-09 9.228e-09 -8.034 -8.035 -0.001 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 2.640e-07 + Al(OH)4- 2.626e-07 2.623e-07 -6.581 -6.581 -0.001 (0) + Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 (0) + Al(OH)2+ 8.053e-11 8.042e-11 -10.094 -10.095 -0.001 (0) + AlOH+2 9.521e-14 9.468e-14 -13.021 -13.024 -0.002 (0) + Al+3 8.906e-17 8.796e-17 -16.050 -16.056 -0.005 (0) +H(0) 7.899e-40 + H2 3.950e-40 3.950e-40 -39.403 -39.403 0.000 (0) +K 1.406e-06 + K+ 1.406e-06 1.404e-06 -5.852 -5.853 -0.001 9.03 + KOH 5.276e-13 5.276e-13 -12.278 -12.278 0.000 (0) +O(0) 5.344e-14 + O2 2.672e-14 2.672e-14 -13.573 -13.573 0.000 (0) +Si 4.218e-06 + H4SiO4 4.152e-06 4.152e-06 -5.382 -5.382 0.000 56.00 + H3SiO4- 6.643e-08 6.634e-08 -7.178 -7.178 -0.001 (0) + H2SiO4-2 4.918e-13 4.890e-13 -12.308 -12.311 -0.002 (0) ------------------------------Saturation indices------------------------------- @@ -2888,29 +2888,29 @@ Kaolinite -0.00 5.71 5.71 0.000e+00 6.727e-06 6.727e-06 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 9.825e-06 9.782e-06 -5.008 -5.010 -0.002 - H+ 1.028e-09 1.023e-09 -8.988 -8.990 -0.002 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 6.045e-07 - Al(OH)4- 6.042e-07 6.015e-07 -6.219 -6.221 -0.002 - Al(OH)3 3.266e-10 3.266e-10 -9.486 -9.486 0.000 - Al(OH)2+ 2.279e-12 2.269e-12 -11.642 -11.644 -0.002 - AlOH+2 3.015e-16 2.963e-16 -15.521 -15.528 -0.008 - Al+3 3.174e-20 3.052e-20 -19.498 -19.515 -0.017 -H(0) 6.201e-40 - H2 3.100e-40 3.100e-40 -39.509 -39.509 0.000 -K 1.406e-05 - K+ 1.406e-05 1.400e-05 -4.852 -4.854 -0.002 - KOH 4.742e-11 4.742e-11 -10.324 -10.324 0.000 -O(0) 8.673e-14 - O2 4.336e-14 4.336e-14 -13.363 -13.363 0.000 -Si 2.872e-05 - H4SiO4 2.509e-05 2.509e-05 -4.600 -4.600 0.000 - H3SiO4- 3.631e-06 3.615e-06 -5.440 -5.442 -0.002 - H2SiO4-2 2.445e-10 2.403e-10 -9.612 -9.619 -0.008 + OH- 9.825e-06 9.782e-06 -5.008 -5.010 -0.002 (0) + H+ 1.028e-09 1.023e-09 -8.988 -8.990 -0.002 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 6.045e-07 + Al(OH)4- 6.042e-07 6.015e-07 -6.219 -6.221 -0.002 (0) + Al(OH)3 3.266e-10 3.266e-10 -9.486 -9.486 0.000 (0) + Al(OH)2+ 2.279e-12 2.269e-12 -11.642 -11.644 -0.002 (0) + AlOH+2 3.015e-16 2.963e-16 -15.521 -15.528 -0.008 (0) + Al+3 3.174e-20 3.052e-20 -19.498 -19.515 -0.017 (0) +H(0) 6.201e-40 + H2 3.100e-40 3.100e-40 -39.509 -39.509 0.000 (0) +K 1.406e-05 + K+ 1.406e-05 1.400e-05 -4.852 -4.854 -0.002 9.03 + KOH 4.742e-11 4.742e-11 -10.324 -10.324 0.000 (0) +O(0) 8.673e-14 + O2 4.336e-14 4.336e-14 -13.363 -13.363 0.000 (0) +Si 2.872e-05 + H4SiO4 2.509e-05 2.509e-05 -4.600 -4.600 0.000 56.00 + H3SiO4- 3.631e-06 3.615e-06 -5.440 -5.442 -0.002 (0) + H2SiO4-2 2.445e-10 2.403e-10 -9.612 -9.619 -0.008 (0) ------------------------------Saturation indices------------------------------- @@ -2992,29 +2992,29 @@ Kaolinite -0.57 5.14 5.71 6.727e-06 0 -6.727e-06 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.211e-05 2.187e-05 -4.655 -4.660 -0.005 - H+ 4.625e-10 4.577e-10 -9.335 -9.339 -0.005 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 9.274e-08 - Al(OH)4- 9.272e-08 9.174e-08 -7.033 -7.037 -0.005 - Al(OH)3 2.228e-11 2.228e-11 -10.652 -10.652 0.000 - Al(OH)2+ 6.994e-14 6.920e-14 -13.155 -13.160 -0.005 - AlOH+2 4.217e-18 4.041e-18 -17.375 -17.393 -0.018 - Al+3 2.046e-22 1.862e-22 -21.689 -21.730 -0.041 -H(0) 1.970e-13 - H2 9.851e-14 9.851e-14 -13.007 -13.007 0.000 -K 8.444e-05 - K+ 8.444e-05 8.355e-05 -4.073 -4.078 -0.005 - KOH 6.329e-10 6.329e-10 -9.199 -9.199 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -66.367 -66.367 0.000 -Si 2.533e-04 - H4SiO4 1.911e-04 1.911e-04 -3.719 -3.719 0.000 - H3SiO4- 6.222e-05 6.157e-05 -4.206 -4.211 -0.005 - H2SiO4-2 9.548e-09 9.150e-09 -8.020 -8.039 -0.018 + OH- 2.211e-05 2.187e-05 -4.655 -4.660 -0.005 (0) + H+ 4.625e-10 4.577e-10 -9.335 -9.339 -0.005 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 9.274e-08 + Al(OH)4- 9.272e-08 9.174e-08 -7.033 -7.037 -0.005 (0) + Al(OH)3 2.228e-11 2.228e-11 -10.652 -10.652 0.000 (0) + Al(OH)2+ 6.994e-14 6.920e-14 -13.155 -13.160 -0.005 (0) + AlOH+2 4.217e-18 4.041e-18 -17.375 -17.393 -0.018 (0) + Al+3 2.046e-22 1.862e-22 -21.689 -21.730 -0.041 (0) +H(0) 1.970e-13 + H2 9.851e-14 9.851e-14 -13.007 -13.007 0.000 (0) +K 8.444e-05 + K+ 8.444e-05 8.355e-05 -4.073 -4.078 -0.005 9.03 + KOH 6.329e-10 6.329e-10 -9.199 -9.199 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -66.367 -66.367 0.000 (0) +Si 2.533e-04 + H4SiO4 1.911e-04 1.911e-04 -3.719 -3.719 0.000 56.00 + H3SiO4- 6.222e-05 6.157e-05 -4.206 -4.211 -0.005 (0) + H2SiO4-2 9.548e-09 9.150e-09 -8.020 -8.039 -0.018 (0) ------------------------------Saturation indices------------------------------- @@ -3097,29 +3097,29 @@ Kaolinite -0.72 4.99 5.71 0.000e+00 0 0.000e+00 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.486e-05 2.453e-05 -4.605 -4.610 -0.006 - H+ 4.133e-10 4.080e-10 -9.384 -9.389 -0.006 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 5.990e-08 - Al(OH)4- 5.988e-08 5.911e-08 -7.223 -7.228 -0.006 - Al(OH)3 1.280e-11 1.280e-11 -10.893 -10.893 0.000 - Al(OH)2+ 3.590e-14 3.544e-14 -13.445 -13.451 -0.006 - AlOH+2 1.944e-18 1.845e-18 -17.711 -17.734 -0.023 - Al+3 8.505e-23 7.579e-23 -22.070 -22.120 -0.050 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -40.913 -40.913 0.000 -K 1.273e-04 - K+ 1.273e-04 1.256e-04 -3.895 -3.901 -0.006 - KOH 1.067e-09 1.067e-09 -8.972 -8.972 0.000 -O(0) 5.575e-11 - O2 2.788e-11 2.788e-11 -10.555 -10.555 0.000 -Si 3.818e-04 - H4SiO4 2.795e-04 2.795e-04 -3.554 -3.554 0.000 - H3SiO4- 1.023e-04 1.010e-04 -3.990 -3.996 -0.006 - H2SiO4-2 1.774e-08 1.684e-08 -7.751 -7.774 -0.023 + OH- 2.486e-05 2.453e-05 -4.605 -4.610 -0.006 (0) + H+ 4.133e-10 4.080e-10 -9.384 -9.389 -0.006 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 5.990e-08 + Al(OH)4- 5.988e-08 5.911e-08 -7.223 -7.228 -0.006 (0) + Al(OH)3 1.280e-11 1.280e-11 -10.893 -10.893 0.000 (0) + Al(OH)2+ 3.590e-14 3.544e-14 -13.445 -13.451 -0.006 (0) + AlOH+2 1.944e-18 1.845e-18 -17.711 -17.734 -0.023 (0) + Al+3 8.505e-23 7.579e-23 -22.070 -22.120 -0.050 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -40.913 -40.913 0.000 (0) +K 1.273e-04 + K+ 1.273e-04 1.256e-04 -3.895 -3.901 -0.006 9.03 + KOH 1.067e-09 1.067e-09 -8.972 -8.972 0.000 (0) +O(0) 5.575e-11 + O2 2.788e-11 2.788e-11 -10.555 -10.555 0.000 (0) +Si 3.818e-04 + H4SiO4 2.795e-04 2.795e-04 -3.554 -3.554 0.000 56.00 + H3SiO4- 1.023e-04 1.010e-04 -3.990 -3.996 -0.006 (0) + H2SiO4-2 1.774e-08 1.684e-08 -7.751 -7.774 -0.023 (0) ------------------------------Saturation indices------------------------------- @@ -3211,29 +3211,29 @@ Initial solution 1. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.040e-03 1.001e-03 -2.983 -3.000 -0.017 - H+ 1.037e-11 1.000e-11 -10.984 -11.000 -0.016 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 2.515e-04 - Al(OH)4- 2.515e-04 2.420e-04 -3.600 -3.616 -0.017 - Al(OH)3 1.284e-09 1.284e-09 -8.892 -8.891 0.000 - Al(OH)2+ 9.056e-14 8.715e-14 -13.043 -13.060 -0.017 - AlOH+2 1.296e-19 1.112e-19 -18.887 -18.954 -0.067 - Al+3 1.554e-25 1.120e-25 -24.809 -24.951 -0.142 -H(0) 1.416e-33 - H2 7.078e-34 7.079e-34 -33.150 -33.150 0.000 -K 1.040e-03 - K+ 1.039e-03 1.000e-03 -2.983 -3.000 -0.017 - KOH 3.466e-07 3.467e-07 -6.460 -6.460 0.000 -O(0) 1.663e-26 - O2 8.315e-27 8.317e-27 -26.080 -26.080 0.000 -Si 6.660e-06 - H3SiO4- 6.208e-06 5.974e-06 -5.207 -5.224 -0.017 - H4SiO4 4.050e-07 4.051e-07 -6.393 -6.392 0.000 - H2SiO4-2 4.737e-08 4.064e-08 -7.324 -7.391 -0.067 + OH- 1.040e-03 1.001e-03 -2.983 -3.000 -0.017 (0) + H+ 1.037e-11 1.000e-11 -10.984 -11.000 -0.016 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 2.515e-04 + Al(OH)4- 2.515e-04 2.420e-04 -3.600 -3.616 -0.017 (0) + Al(OH)3 1.284e-09 1.284e-09 -8.892 -8.891 0.000 (0) + Al(OH)2+ 9.056e-14 8.715e-14 -13.043 -13.060 -0.017 (0) + AlOH+2 1.296e-19 1.112e-19 -18.887 -18.954 -0.067 (0) + Al+3 1.554e-25 1.120e-25 -24.809 -24.951 -0.142 (0) +H(0) 1.416e-33 + H2 7.078e-34 7.079e-34 -33.150 -33.150 0.000 (0) +K 1.040e-03 + K+ 1.039e-03 1.000e-03 -2.983 -3.000 -0.017 9.04 + KOH 3.466e-07 3.467e-07 -6.460 -6.460 0.000 (0) +O(0) 1.663e-26 + O2 8.315e-27 8.317e-27 -26.080 -26.080 0.000 (0) +Si 6.660e-06 + H3SiO4- 6.208e-06 5.974e-06 -5.207 -5.224 -0.017 (0) + H4SiO4 4.050e-07 4.051e-07 -6.393 -6.392 0.000 56.00 + H2SiO4-2 4.737e-08 4.064e-08 -7.324 -7.391 -0.067 (0) ------------------------------Saturation indices------------------------------- @@ -3284,29 +3284,29 @@ Initial solution 2. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.043e-07 1.001e-07 -6.982 -7.000 -0.018 - H+ 1.039e-07 1.000e-07 -6.983 -7.000 -0.017 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 2.741e-08 - Al(OH)4- 2.521e-08 2.420e-08 -7.598 -7.616 -0.018 - Al(OH)3 1.284e-09 1.284e-09 -8.892 -8.891 0.000 - Al(OH)2+ 9.079e-10 8.716e-10 -9.042 -9.060 -0.018 - AlOH+2 1.309e-11 1.112e-11 -10.883 -10.954 -0.071 - Al+3 1.585e-13 1.120e-13 -12.800 -12.951 -0.151 -H(0) 1.415e-25 - H2 7.077e-26 7.079e-26 -25.150 -25.150 0.000 -K 2.666e-03 - K+ 2.666e-03 2.558e-03 -2.574 -2.592 -0.018 - KOH 8.868e-11 8.871e-11 -10.052 -10.052 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 -Si 6.390e-06 - H4SiO4 6.380e-06 6.382e-06 -5.195 -5.195 0.000 - H3SiO4- 9.802e-09 9.410e-09 -8.009 -8.026 -0.018 - H2SiO4-2 7.537e-15 6.401e-15 -14.123 -14.194 -0.071 + OH- 1.043e-07 1.001e-07 -6.982 -7.000 -0.018 (0) + H+ 1.039e-07 1.000e-07 -6.983 -7.000 -0.017 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 2.741e-08 + Al(OH)4- 2.521e-08 2.420e-08 -7.598 -7.616 -0.018 (0) + Al(OH)3 1.284e-09 1.284e-09 -8.892 -8.891 0.000 (0) + Al(OH)2+ 9.079e-10 8.716e-10 -9.042 -9.060 -0.018 (0) + AlOH+2 1.309e-11 1.112e-11 -10.883 -10.954 -0.071 (0) + Al+3 1.585e-13 1.120e-13 -12.800 -12.951 -0.151 (0) +H(0) 1.415e-25 + H2 7.077e-26 7.079e-26 -25.150 -25.150 0.000 (0) +K 2.666e-03 + K+ 2.666e-03 2.558e-03 -2.574 -2.592 -0.018 9.05 + KOH 8.868e-11 8.871e-11 -10.052 -10.052 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 (0) +Si 6.390e-06 + H4SiO4 6.380e-06 6.382e-06 -5.195 -5.195 0.000 56.00 + H3SiO4- 9.802e-09 9.410e-09 -8.009 -8.026 -0.018 (0) + H2SiO4-2 7.537e-15 6.401e-15 -14.123 -14.194 -0.071 (0) ------------------------------Saturation indices------------------------------- @@ -3357,29 +3357,29 @@ Initial solution 3. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.043e-07 1.001e-07 -6.982 -7.000 -0.018 - H+ 1.039e-07 1.000e-07 -6.983 -7.000 -0.017 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -Al 2.732e-10 - Al(OH)4- 2.512e-10 2.412e-10 -9.600 -9.618 -0.018 - Al(OH)3 1.279e-11 1.280e-11 -10.893 -10.893 0.000 - Al(OH)2+ 9.047e-12 8.685e-12 -11.043 -11.061 -0.018 - AlOH+2 1.305e-13 1.108e-13 -12.884 -12.955 -0.071 - Al+3 1.580e-15 1.116e-15 -14.801 -14.952 -0.151 -H(0) 1.415e-25 - H2 7.077e-26 7.079e-26 -25.150 -25.150 0.000 -K 2.666e-03 - K+ 2.666e-03 2.558e-03 -2.574 -2.592 -0.018 - KOH 8.868e-11 8.870e-11 -10.052 -10.052 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 -Si 6.412e-04 - H4SiO4 6.402e-04 6.404e-04 -3.194 -3.194 0.000 - H3SiO4- 9.837e-07 9.443e-07 -6.007 -6.025 -0.018 - H2SiO4-2 7.563e-13 6.423e-13 -12.121 -12.192 -0.071 + OH- 1.043e-07 1.001e-07 -6.982 -7.000 -0.018 (0) + H+ 1.039e-07 1.000e-07 -6.983 -7.000 -0.017 0.00 + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +Al 2.732e-10 + Al(OH)4- 2.512e-10 2.412e-10 -9.600 -9.618 -0.018 (0) + Al(OH)3 1.279e-11 1.280e-11 -10.893 -10.893 0.000 (0) + Al(OH)2+ 9.047e-12 8.685e-12 -11.043 -11.061 -0.018 (0) + AlOH+2 1.305e-13 1.108e-13 -12.884 -12.955 -0.071 (0) + Al+3 1.580e-15 1.116e-15 -14.801 -14.952 -0.151 (0) +H(0) 1.415e-25 + H2 7.077e-26 7.079e-26 -25.150 -25.150 0.000 (0) +K 2.666e-03 + K+ 2.666e-03 2.558e-03 -2.574 -2.592 -0.018 9.05 + KOH 8.868e-11 8.870e-11 -10.052 -10.052 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 (0) +Si 6.412e-04 + H4SiO4 6.402e-04 6.404e-04 -3.194 -3.194 0.000 56.00 + H3SiO4- 9.837e-07 9.443e-07 -6.007 -6.025 -0.018 (0) + H2SiO4-2 7.563e-13 6.423e-13 -12.121 -12.192 -0.071 (0) ------------------------------Saturation indices------------------------------- @@ -3430,29 +3430,29 @@ Initial solution 4. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.018e-07 1.000e-07 -6.992 -7.000 -0.008 - OH- 1.014e-07 9.956e-08 -6.994 -7.002 -0.008 - H2O 5.551e+01 9.946e-01 1.744 -0.002 0.000 -Al 5.251e-13 - Al(OH)4- 4.821e-13 4.736e-13 -12.317 -12.325 -0.008 - Al(OH)3 2.526e-14 2.526e-14 -13.598 -13.597 0.000 - Al(OH)2+ 1.755e-14 1.724e-14 -13.756 -13.763 -0.008 - AlOH+2 2.375e-16 2.212e-16 -15.624 -15.655 -0.031 - Al+3 2.618e-18 2.239e-18 -17.582 -17.650 -0.068 -H(0) 1.416e-25 - H2 7.079e-26 7.079e-26 -25.150 -25.150 0.000 -K 1.018e-08 - K+ 1.018e-08 1.000e-08 -7.992 -8.000 -0.008 - KOH 3.448e-16 3.448e-16 -15.462 -15.462 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -42.085 -42.085 0.000 -Si 3.205e-01 - H4SiO4 3.200e-01 3.200e-01 -0.495 -0.495 0.000 - H3SiO4- 4.803e-04 4.719e-04 -3.318 -3.326 -0.008 - H2SiO4-2 3.447e-10 3.210e-10 -9.463 -9.494 -0.031 + H+ 1.018e-07 1.000e-07 -6.992 -7.000 -0.008 0.00 + OH- 1.014e-07 9.956e-08 -6.994 -7.002 -0.008 (0) + H2O 5.551e+01 9.946e-01 1.744 -0.002 0.000 18.07 +Al 5.251e-13 + Al(OH)4- 4.821e-13 4.736e-13 -12.317 -12.325 -0.008 (0) + Al(OH)3 2.526e-14 2.526e-14 -13.598 -13.597 0.000 (0) + Al(OH)2+ 1.755e-14 1.724e-14 -13.756 -13.763 -0.008 (0) + AlOH+2 2.375e-16 2.212e-16 -15.624 -15.655 -0.031 (0) + Al+3 2.618e-18 2.239e-18 -17.582 -17.650 -0.068 (0) +H(0) 1.416e-25 + H2 7.079e-26 7.079e-26 -25.150 -25.150 0.000 (0) +K 1.018e-08 + K+ 1.018e-08 1.000e-08 -7.992 -8.000 -0.008 9.05 + KOH 3.448e-16 3.448e-16 -15.462 -15.462 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -42.085 -42.085 0.000 (0) +Si 3.205e-01 + H4SiO4 3.200e-01 3.200e-01 -0.495 -0.495 0.000 56.00 + H3SiO4- 4.803e-04 4.719e-04 -3.318 -3.326 -0.008 (0) + H2SiO4-2 3.447e-10 3.210e-10 -9.463 -9.494 -0.031 (0) ------------------------------Saturation indices------------------------------- @@ -3538,29 +3538,29 @@ Initial solution 1. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.044e-03 1.001e-03 -2.981 -3.000 -0.018 - H+ 1.040e-11 1.000e-11 -10.983 -11.000 -0.017 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 2.513e-06 - Al(OH)4- 2.513e-06 2.412e-06 -5.600 -5.618 -0.018 - Al(OH)3 1.279e-11 1.280e-11 -10.893 -10.893 0.000 - Al(OH)2+ 9.051e-16 8.685e-16 -15.043 -15.061 -0.018 - AlOH+2 1.307e-21 1.108e-21 -20.884 -20.955 -0.072 - Al+3 1.586e-27 1.116e-27 -26.800 -26.952 -0.153 -H(0) 1.415e-33 - H2 7.077e-34 7.079e-34 -33.150 -33.150 0.000 -K 1.043e-03 - K+ 1.042e-03 1.000e-03 -2.982 -3.000 -0.018 - KOH 3.466e-07 3.467e-07 -6.460 -6.460 0.000 -O(0) 1.663e-26 - O2 8.314e-27 8.317e-27 -26.080 -26.080 0.000 -Si 6.702e-04 - H3SiO4- 6.248e-04 5.995e-04 -3.204 -3.222 -0.018 - H4SiO4 4.064e-05 4.066e-05 -4.391 -4.391 0.000 - H2SiO4-2 4.811e-06 4.078e-06 -5.318 -5.390 -0.072 + OH- 1.044e-03 1.001e-03 -2.981 -3.000 -0.018 (0) + H+ 1.040e-11 1.000e-11 -10.983 -11.000 -0.017 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 2.513e-06 + Al(OH)4- 2.513e-06 2.412e-06 -5.600 -5.618 -0.018 (0) + Al(OH)3 1.279e-11 1.280e-11 -10.893 -10.893 0.000 (0) + Al(OH)2+ 9.051e-16 8.685e-16 -15.043 -15.061 -0.018 (0) + AlOH+2 1.307e-21 1.108e-21 -20.884 -20.955 -0.072 (0) + Al+3 1.586e-27 1.116e-27 -26.800 -26.952 -0.153 (0) +H(0) 1.415e-33 + H2 7.077e-34 7.079e-34 -33.150 -33.150 0.000 (0) +K 1.043e-03 + K+ 1.042e-03 1.000e-03 -2.982 -3.000 -0.018 9.04 + KOH 3.466e-07 3.467e-07 -6.460 -6.460 0.000 (0) +O(0) 1.663e-26 + O2 8.314e-27 8.317e-27 -26.080 -26.080 0.000 (0) +Si 6.702e-04 + H3SiO4- 6.248e-04 5.995e-04 -3.204 -3.222 -0.018 (0) + H4SiO4 4.064e-05 4.066e-05 -4.391 -4.391 0.000 56.00 + H2SiO4-2 4.811e-06 4.078e-06 -5.318 -5.390 -0.072 (0) ------------------------------Saturation indices------------------------------- @@ -3611,29 +3611,29 @@ Initial solution 2. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.043e-07 1.001e-07 -6.982 -7.000 -0.018 - H+ 1.039e-07 1.000e-07 -6.983 -7.000 -0.017 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -Al 2.732e-10 - Al(OH)4- 2.512e-10 2.412e-10 -9.600 -9.618 -0.018 - Al(OH)3 1.279e-11 1.280e-11 -10.893 -10.893 0.000 - Al(OH)2+ 9.047e-12 8.685e-12 -11.043 -11.061 -0.018 - AlOH+2 1.305e-13 1.108e-13 -12.884 -12.955 -0.071 - Al+3 1.580e-15 1.116e-15 -14.801 -14.952 -0.151 -H(0) 1.415e-25 - H2 7.077e-26 7.079e-26 -25.150 -25.150 0.000 -K 2.666e-03 - K+ 2.666e-03 2.558e-03 -2.574 -2.592 -0.018 - KOH 8.868e-11 8.870e-11 -10.052 -10.052 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 -Si 6.412e-04 - H4SiO4 6.402e-04 6.404e-04 -3.194 -3.194 0.000 - H3SiO4- 9.837e-07 9.443e-07 -6.007 -6.025 -0.018 - H2SiO4-2 7.563e-13 6.423e-13 -12.121 -12.192 -0.071 + OH- 1.043e-07 1.001e-07 -6.982 -7.000 -0.018 (0) + H+ 1.039e-07 1.000e-07 -6.983 -7.000 -0.017 0.00 + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +Al 2.732e-10 + Al(OH)4- 2.512e-10 2.412e-10 -9.600 -9.618 -0.018 (0) + Al(OH)3 1.279e-11 1.280e-11 -10.893 -10.893 0.000 (0) + Al(OH)2+ 9.047e-12 8.685e-12 -11.043 -11.061 -0.018 (0) + AlOH+2 1.305e-13 1.108e-13 -12.884 -12.955 -0.071 (0) + Al+3 1.580e-15 1.116e-15 -14.801 -14.952 -0.151 (0) +H(0) 1.415e-25 + H2 7.077e-26 7.079e-26 -25.150 -25.150 0.000 (0) +K 2.666e-03 + K+ 2.666e-03 2.558e-03 -2.574 -2.592 -0.018 9.05 + KOH 8.868e-11 8.870e-11 -10.052 -10.052 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 (0) +Si 6.412e-04 + H4SiO4 6.402e-04 6.404e-04 -3.194 -3.194 0.000 56.00 + H3SiO4- 9.837e-07 9.443e-07 -6.007 -6.025 -0.018 (0) + H2SiO4-2 7.563e-13 6.423e-13 -12.121 -12.192 -0.071 (0) ------------------------------Saturation indices------------------------------- @@ -3684,29 +3684,29 @@ Initial solution 3. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.043e-07 1.001e-07 -6.982 -7.000 -0.018 - H+ 1.039e-07 1.000e-07 -6.983 -7.000 -0.017 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 2.741e-08 - Al(OH)4- 2.521e-08 2.420e-08 -7.598 -7.616 -0.018 - Al(OH)3 1.284e-09 1.284e-09 -8.892 -8.891 0.000 - Al(OH)2+ 9.079e-10 8.716e-10 -9.042 -9.060 -0.018 - AlOH+2 1.309e-11 1.112e-11 -10.883 -10.954 -0.071 - Al+3 1.585e-13 1.120e-13 -12.800 -12.951 -0.151 -H(0) 1.415e-25 - H2 7.077e-26 7.079e-26 -25.150 -25.150 0.000 -K 2.666e-03 - K+ 2.666e-03 2.558e-03 -2.574 -2.592 -0.018 - KOH 8.868e-11 8.871e-11 -10.052 -10.052 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 -Si 6.390e-06 - H4SiO4 6.380e-06 6.382e-06 -5.195 -5.195 0.000 - H3SiO4- 9.802e-09 9.410e-09 -8.009 -8.026 -0.018 - H2SiO4-2 7.537e-15 6.401e-15 -14.123 -14.194 -0.071 + OH- 1.043e-07 1.001e-07 -6.982 -7.000 -0.018 (0) + H+ 1.039e-07 1.000e-07 -6.983 -7.000 -0.017 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 2.741e-08 + Al(OH)4- 2.521e-08 2.420e-08 -7.598 -7.616 -0.018 (0) + Al(OH)3 1.284e-09 1.284e-09 -8.892 -8.891 0.000 (0) + Al(OH)2+ 9.079e-10 8.716e-10 -9.042 -9.060 -0.018 (0) + AlOH+2 1.309e-11 1.112e-11 -10.883 -10.954 -0.071 (0) + Al+3 1.585e-13 1.120e-13 -12.800 -12.951 -0.151 (0) +H(0) 1.415e-25 + H2 7.077e-26 7.079e-26 -25.150 -25.150 0.000 (0) +K 2.666e-03 + K+ 2.666e-03 2.558e-03 -2.574 -2.592 -0.018 9.05 + KOH 8.868e-11 8.871e-11 -10.052 -10.052 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 (0) +Si 6.390e-06 + H4SiO4 6.380e-06 6.382e-06 -5.195 -5.195 0.000 56.00 + H3SiO4- 9.802e-09 9.410e-09 -8.009 -8.026 -0.018 (0) + H2SiO4-2 7.537e-15 6.401e-15 -14.123 -14.194 -0.071 (0) ------------------------------Saturation indices------------------------------- @@ -3757,29 +3757,29 @@ Initial solution 4. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.001e-07 1.001e-07 -6.999 -7.000 -0.000 - H+ 1.000e-07 1.000e-07 -7.000 -7.000 -0.000 - H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 -Al 2.638e-08 - Al(OH)4- 2.421e-08 2.420e-08 -7.616 -7.616 -0.000 - Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 - Al(OH)2+ 8.719e-10 8.715e-10 -9.060 -9.060 -0.000 - AlOH+2 1.114e-11 1.112e-11 -10.953 -10.954 -0.001 - Al+3 1.124e-13 1.119e-13 -12.949 -12.951 -0.002 -H(0) 1.416e-25 - H2 7.079e-26 7.079e-26 -25.150 -25.150 0.000 -K 1.000e-08 - K+ 1.000e-08 1.000e-08 -8.000 -8.000 -0.000 - KOH 3.467e-16 3.467e-16 -15.460 -15.460 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 -Si 6.392e-06 - H4SiO4 6.383e-06 6.383e-06 -5.195 -5.195 0.000 - H3SiO4- 9.415e-09 9.411e-09 -8.026 -8.026 -0.000 - H2SiO4-2 6.412e-15 6.402e-15 -14.193 -14.194 -0.001 + OH- 1.001e-07 1.001e-07 -6.999 -7.000 -0.000 (0) + H+ 1.000e-07 1.000e-07 -7.000 -7.000 -0.000 0.00 + H2O 5.551e+01 1.000e+00 1.744 -0.000 0.000 18.07 +Al 2.638e-08 + Al(OH)4- 2.421e-08 2.420e-08 -7.616 -7.616 -0.000 (0) + Al(OH)3 1.284e-09 1.284e-09 -8.891 -8.891 0.000 (0) + Al(OH)2+ 8.719e-10 8.715e-10 -9.060 -9.060 -0.000 (0) + AlOH+2 1.114e-11 1.112e-11 -10.953 -10.954 -0.001 (0) + Al+3 1.124e-13 1.119e-13 -12.949 -12.951 -0.002 (0) +H(0) 1.416e-25 + H2 7.079e-26 7.079e-26 -25.150 -25.150 0.000 (0) +K 1.000e-08 + K+ 1.000e-08 1.000e-08 -8.000 -8.000 -0.000 9.05 + KOH 3.467e-16 3.467e-16 -15.460 -15.460 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 (0) +Si 6.392e-06 + H4SiO4 6.383e-06 6.383e-06 -5.195 -5.195 0.000 56.00 + H3SiO4- 9.415e-09 9.411e-09 -8.026 -8.026 -0.000 (0) + H2SiO4-2 6.412e-15 6.402e-15 -14.193 -14.194 -0.001 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex7.out b/ex7.out index d17fcd86..0b200776 100644 --- a/ex7.out +++ b/ex7.out @@ -91,16 +91,16 @@ Initial solution 1. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.002e-07 1.001e-07 -6.999 -6.999 -0.000 - H+ 1.001e-07 1.000e-07 -7.000 -7.000 -0.000 - H2O 5.551e+01 1.000e+00 1.744 0.000 0.000 -H(0) 1.416e-25 - H2 7.079e-26 7.079e-26 -25.150 -25.150 0.000 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 + OH- 1.002e-07 1.001e-07 -6.999 -6.999 -0.000 (0) + H+ 1.001e-07 1.000e-07 -7.000 -7.000 -0.000 0.00 + H2O 5.551e+01 1.000e+00 1.744 0.000 0.000 18.07 +H(0) 1.416e-25 + H2 7.079e-26 7.079e-26 -25.150 -25.150 0.000 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -42.080 -42.080 0.000 (0) ------------------------------Saturation indices------------------------------- @@ -155,29 +155,29 @@ Calcite -0.00 -8.48 -8.48 1.000e+01 9.997e+00 -2.502e-03 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.159e-07 1.070e-07 -6.936 -6.971 -0.035 - OH- 1.025e-07 9.358e-08 -6.989 -7.029 -0.040 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -C(-4) 1.994e-24 - CH4 1.994e-24 1.997e-24 -23.700 -23.700 0.001 -C(4) 6.071e-03 - HCO3- 4.883e-03 4.476e-03 -2.311 -2.349 -0.038 - CO2 1.075e-03 1.077e-03 -2.969 -2.968 0.001 - CaHCO3+ 1.052e-04 9.640e-05 -3.978 -4.016 -0.038 - CaCO3 5.556e-06 5.565e-06 -5.255 -5.255 0.001 - CO3-2 2.778e-06 1.962e-06 -5.556 -5.707 -0.151 -Ca 2.502e-03 - Ca+2 2.391e-03 1.688e-03 -2.621 -2.773 -0.151 - CaHCO3+ 1.052e-04 9.640e-05 -3.978 -4.016 -0.038 - CaCO3 5.556e-06 5.565e-06 -5.255 -5.255 0.001 - CaOH+ 2.864e-09 2.619e-09 -8.543 -8.582 -0.039 -H(0) 7.410e-15 - H2 3.705e-15 3.711e-15 -14.431 -14.431 0.001 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -63.520 -63.519 0.001 + H+ 1.159e-07 1.070e-07 -6.936 -6.971 -0.035 0.00 + OH- 1.025e-07 9.358e-08 -6.989 -7.029 -0.040 (0) + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +C(-4) 1.994e-24 + CH4 1.994e-24 1.997e-24 -23.700 -23.700 0.001 (0) +C(4) 6.071e-03 + HCO3- 4.883e-03 4.476e-03 -2.311 -2.349 -0.038 24.29 + CO2 1.075e-03 1.077e-03 -2.969 -2.968 0.001 (0) + CaHCO3+ 1.052e-04 9.640e-05 -3.978 -4.016 -0.038 (0) + CaCO3 5.556e-06 5.565e-06 -5.255 -5.255 0.001 (0) + CO3-2 2.778e-06 1.962e-06 -5.556 -5.707 -0.151 -3.78 +Ca 2.502e-03 + Ca+2 2.391e-03 1.688e-03 -2.621 -2.773 -0.151 -17.83 + CaHCO3+ 1.052e-04 9.640e-05 -3.978 -4.016 -0.038 (0) + CaCO3 5.556e-06 5.565e-06 -5.255 -5.255 0.001 (0) + CaOH+ 2.864e-09 2.619e-09 -8.543 -8.582 -0.039 (0) +H(0) 7.410e-15 + H2 3.705e-15 3.711e-15 -14.431 -14.431 0.001 (0) +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -63.520 -63.519 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -303,53 +303,53 @@ Reaction 1. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.597e-07 1.474e-07 -6.797 -6.831 -0.035 - OH- 7.441e-08 6.790e-08 -7.128 -7.168 -0.040 - H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 -C(-4) 5.001e-04 - CH4 5.001e-04 5.009e-04 -3.301 -3.300 0.001 -C(4) 6.571e-03 - HCO3- 4.955e-03 4.541e-03 -2.305 -2.343 -0.038 - CO2 1.503e-03 1.505e-03 -2.823 -2.822 0.001 - CaHCO3+ 1.066e-04 9.767e-05 -3.972 -4.010 -0.038 - CaCO3 4.084e-06 4.091e-06 -5.389 -5.388 0.001 - CO3-2 2.049e-06 1.445e-06 -5.689 -5.840 -0.152 -Ca 2.502e-03 - Ca+2 2.391e-03 1.686e-03 -2.621 -2.773 -0.152 - CaHCO3+ 1.066e-04 9.767e-05 -3.972 -4.010 -0.038 - CaCO3 4.084e-06 4.091e-06 -5.389 -5.388 0.001 - CaOH+ 2.076e-09 1.897e-09 -8.683 -8.722 -0.039 -H(0) 8.575e-10 - H2 4.287e-10 4.295e-10 -9.368 -9.367 0.001 -N(-3) 6.986e-05 - NH4+ 6.962e-05 6.338e-05 -4.157 -4.198 -0.041 - NH3 2.446e-07 2.450e-07 -6.612 -6.611 0.001 -N(0) 1.394e-07 - N2 6.971e-08 6.983e-08 -7.157 -7.156 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -62.351 -62.391 -0.040 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -84.704 -84.744 -0.040 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -73.647 -73.646 0.001 + H+ 1.597e-07 1.474e-07 -6.797 -6.831 -0.035 0.00 + OH- 7.441e-08 6.790e-08 -7.128 -7.168 -0.040 (0) + H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 18.07 +C(-4) 5.001e-04 + CH4 5.001e-04 5.009e-04 -3.301 -3.300 0.001 (0) +C(4) 6.571e-03 + HCO3- 4.955e-03 4.541e-03 -2.305 -2.343 -0.038 24.33 + CO2 1.503e-03 1.505e-03 -2.823 -2.822 0.001 (0) + CaHCO3+ 1.066e-04 9.767e-05 -3.972 -4.010 -0.038 (0) + CaCO3 4.084e-06 4.091e-06 -5.389 -5.388 0.001 (0) + CO3-2 2.049e-06 1.445e-06 -5.689 -5.840 -0.152 -3.62 +Ca 2.502e-03 + Ca+2 2.391e-03 1.686e-03 -2.621 -2.773 -0.152 -17.67 + CaHCO3+ 1.066e-04 9.767e-05 -3.972 -4.010 -0.038 (0) + CaCO3 4.084e-06 4.091e-06 -5.389 -5.388 0.001 (0) + CaOH+ 2.076e-09 1.897e-09 -8.683 -8.722 -0.039 (0) +H(0) 8.575e-10 + H2 4.287e-10 4.295e-10 -9.368 -9.367 0.001 (0) +N(-3) 6.986e-05 + NH4+ 6.962e-05 6.338e-05 -4.157 -4.198 -0.041 (0) + NH3 2.446e-07 2.450e-07 -6.612 -6.611 0.001 (0) +N(0) 1.394e-07 + N2 6.971e-08 6.983e-08 -7.157 -7.156 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -62.351 -62.391 -0.040 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -84.704 -84.744 -0.040 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -73.647 -73.646 0.001 (0) ------------------------------Saturation indices------------------------------- Phase SI log IAP log K(298 K, 1 atm) - Aragonite -0.28* -8.61 -8.34 CaCO3 Delta_V -21.29 cm3/mol - Calcite -0.13* -8.61 -8.48 CaCO3 Delta_V -21.29 cm3/mol - CH4(g) -0.44* -3.30 -2.86 CH4 Delta_V -57.83 cm3/mol - CO2(g) -1.35* -2.82 -1.47 CO2 Delta_V -21.69 cm3/mol + Aragonite -0.28 -8.61 -8.34 CaCO3 + Calcite -0.13 -8.61 -8.48 CaCO3 + CH4(g) -0.44 -3.30 -2.86 CH4 + CO2(g) -1.35 -2.82 -1.47 CO2 H2(g) -6.22 -9.37 -3.15 H2 H2O(g) -1.51 -0.00 1.51 H2O N2(g) -3.90 -7.16 -3.26 N2 NH3(g) -8.38 -6.61 1.77 NH3 - O2(g) -70.75* -73.65 -2.89 O2 Delta_V 36.14 cm3/mol - * with Delta_V * (P - 1) / 2.3RT. + O2(g) -70.75 -73.65 -2.89 O2 + Reaction step 2. @@ -398,59 +398,59 @@ Reaction 1. Pressure (atm) = 1.10 Electrical balance (eq) = -1.080e-10 Percent error, 100*(Cat-|An|)/(Cat+|An|) = -0.00 - Iterations = 18 + Iterations = 33 Total H = 1.110169e+02 Total O = 5.552286e+01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 2.025e-07 1.869e-07 -6.693 -6.728 -0.035 - OH- 5.872e-08 5.356e-08 -7.231 -7.271 -0.040 - H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 -C(-4) 1.000e-03 - CH4 1.000e-03 1.002e-03 -3.000 -2.999 0.001 -C(4) 7.071e-03 - HCO3- 5.026e-03 4.604e-03 -2.299 -2.337 -0.038 - CO2 1.932e-03 1.935e-03 -2.714 -2.713 0.001 - CaHCO3+ 1.079e-04 9.887e-05 -3.967 -4.005 -0.038 - CaCO3 3.261e-06 3.267e-06 -5.487 -5.486 0.001 - CO3-2 1.641e-06 1.156e-06 -5.785 -5.937 -0.152 -Ca 2.502e-03 - Ca+2 2.391e-03 1.683e-03 -2.621 -2.774 -0.153 - CaHCO3+ 1.079e-04 9.887e-05 -3.967 -4.005 -0.038 - CaCO3 3.261e-06 3.267e-06 -5.487 -5.486 0.001 - CaOH+ 1.636e-09 1.494e-09 -8.786 -8.826 -0.039 -H(0) 9.576e-10 - H2 4.788e-10 4.796e-10 -9.320 -9.319 0.001 -N(-3) 1.398e-04 - NH4+ 1.394e-04 1.268e-04 -3.856 -3.897 -0.041 - NH3 3.861e-07 3.867e-07 -6.413 -6.413 0.001 -N(0) 2.494e-07 - N2 1.247e-07 1.249e-07 -6.904 -6.903 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -62.399 -62.440 -0.040 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -84.800 -84.841 -0.040 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -73.743 -73.742 0.001 + H+ 2.025e-07 1.869e-07 -6.693 -6.728 -0.035 0.00 + OH- 5.872e-08 5.356e-08 -7.231 -7.271 -0.040 (0) + H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 18.07 +C(-4) 1.000e-03 + CH4 1.000e-03 1.002e-03 -3.000 -2.999 0.001 (0) +C(4) 7.071e-03 + HCO3- 5.026e-03 4.604e-03 -2.299 -2.337 -0.038 24.33 + CO2 1.932e-03 1.935e-03 -2.714 -2.713 0.001 (0) + CaHCO3+ 1.079e-04 9.887e-05 -3.967 -4.005 -0.038 (0) + CaCO3 3.261e-06 3.267e-06 -5.487 -5.486 0.001 (0) + CO3-2 1.641e-06 1.156e-06 -5.785 -5.937 -0.152 -3.62 +Ca 2.502e-03 + Ca+2 2.391e-03 1.683e-03 -2.621 -2.774 -0.153 -17.67 + CaHCO3+ 1.079e-04 9.887e-05 -3.967 -4.005 -0.038 (0) + CaCO3 3.261e-06 3.267e-06 -5.487 -5.486 0.001 (0) + CaOH+ 1.636e-09 1.494e-09 -8.786 -8.826 -0.039 (0) +H(0) 9.576e-10 + H2 4.788e-10 4.796e-10 -9.320 -9.319 0.001 (0) +N(-3) 1.398e-04 + NH4+ 1.394e-04 1.268e-04 -3.856 -3.897 -0.041 (0) + NH3 3.861e-07 3.867e-07 -6.413 -6.413 0.001 (0) +N(0) 2.494e-07 + N2 1.247e-07 1.249e-07 -6.904 -6.903 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -62.399 -62.440 -0.040 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -84.800 -84.841 -0.040 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -73.743 -73.742 0.001 (0) ------------------------------Saturation indices------------------------------- Phase SI log IAP log K(298 K, 1 atm) - Aragonite -0.38* -8.71 -8.34 CaCO3 Delta_V -21.29 cm3/mol - Calcite -0.23* -8.71 -8.48 CaCO3 Delta_V -21.29 cm3/mol - CH4(g) -0.14* -3.00 -2.86 CH4 Delta_V -57.82 cm3/mol - CO2(g) -1.25* -2.71 -1.47 CO2 Delta_V -21.69 cm3/mol + Aragonite -0.38 -8.71 -8.34 CaCO3 + Calcite -0.23 -8.71 -8.48 CaCO3 + CH4(g) -0.14 -3.00 -2.86 CH4 + CO2(g) -1.25 -2.71 -1.47 CO2 H2(g) -6.17 -9.32 -3.15 H2 H2O(g) -1.51 -0.00 1.51 H2O N2(g) -3.64 -6.90 -3.26 N2 NH3(g) -8.18 -6.41 1.77 NH3 - O2(g) -70.85* -73.74 -2.89 O2 Delta_V 36.14 cm3/mol - * with Delta_V * (P - 1) / 2.3RT. + O2(g) -70.85 -73.74 -2.89 O2 + Reaction step 3. @@ -485,7 +485,7 @@ Total pressure: 1.10 atmospheres Component log P P Initial Final Delta CH4(g) -0.00 9.996e-01 0.000e+00 1.225e-04 1.225e-04 -CO2(g) -1.16 6.922e-02 0.000e+00 8.483e-06 8.483e-06 +CO2(g) -1.16 6.922e-02 0.000e+00 8.484e-06 8.484e-06 H2O(g) -1.51 3.090e-02 0.000e+00 3.787e-06 3.787e-06 N2(g) -3.49 3.228e-04 0.000e+00 3.956e-08 3.956e-08 @@ -512,59 +512,59 @@ N2(g) -3.49 3.228e-04 0.000e+00 3.956e-08 3.956e-08 Pressure (atm) = 1.10 Electrical balance (eq) = -1.080e-10 Percent error, 100*(Cat-|An|)/(Cat+|An|) = -0.00 - Iterations = 21 + Iterations = 23 Total H = 1.110186e+02 Total O = 5.552384e+01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 2.434e-07 2.245e-07 -6.614 -6.649 -0.035 - OH- 4.888e-08 4.457e-08 -7.311 -7.351 -0.040 - H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 -C(-4) 1.378e-03 - CH4 1.378e-03 1.380e-03 -2.861 -2.860 0.001 -C(4) 7.562e-03 - HCO3- 5.096e-03 4.667e-03 -2.293 -2.331 -0.038 - CO2 2.353e-03 2.357e-03 -2.628 -2.628 0.001 - CaHCO3+ 1.092e-04 1.000e-04 -3.962 -4.000 -0.038 - CaCO3 2.746e-06 2.751e-06 -5.561 -5.561 0.001 - CO3-2 1.386e-06 9.748e-07 -5.858 -6.011 -0.153 -Ca 2.502e-03 - Ca+2 2.390e-03 1.680e-03 -2.622 -2.775 -0.153 - CaHCO3+ 1.092e-04 1.000e-04 -3.962 -4.000 -0.038 - CaCO3 2.746e-06 2.751e-06 -5.561 -5.561 0.001 - CaOH+ 1.359e-09 1.241e-09 -8.867 -8.906 -0.039 -H(0) 9.876e-10 - H2 4.938e-10 4.946e-10 -9.306 -9.306 0.001 -N(-3) 2.096e-04 - NH4+ 2.091e-04 1.902e-04 -3.680 -3.721 -0.041 - NH3 4.819e-07 4.827e-07 -6.317 -6.316 0.001 -N(0) 3.542e-07 - N2 1.771e-07 1.774e-07 -6.752 -6.751 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -62.423 -62.463 -0.041 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -84.837 -84.878 -0.041 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -73.769 -73.769 0.001 + H+ 2.434e-07 2.245e-07 -6.614 -6.649 -0.035 0.00 + OH- 4.888e-08 4.457e-08 -7.311 -7.351 -0.040 (0) + H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 18.07 +C(-4) 1.378e-03 + CH4 1.378e-03 1.380e-03 -2.861 -2.860 0.001 (0) +C(4) 7.562e-03 + HCO3- 5.096e-03 4.667e-03 -2.293 -2.331 -0.038 24.33 + CO2 2.353e-03 2.357e-03 -2.628 -2.628 0.001 (0) + CaHCO3+ 1.092e-04 1.000e-04 -3.962 -4.000 -0.038 (0) + CaCO3 2.746e-06 2.751e-06 -5.561 -5.561 0.001 (0) + CO3-2 1.386e-06 9.748e-07 -5.858 -6.011 -0.153 -3.62 +Ca 2.502e-03 + Ca+2 2.390e-03 1.680e-03 -2.622 -2.775 -0.153 -17.67 + CaHCO3+ 1.092e-04 1.000e-04 -3.962 -4.000 -0.038 (0) + CaCO3 2.746e-06 2.751e-06 -5.561 -5.561 0.001 (0) + CaOH+ 1.359e-09 1.241e-09 -8.867 -8.906 -0.039 (0) +H(0) 9.876e-10 + H2 4.938e-10 4.946e-10 -9.306 -9.306 0.001 (0) +N(-3) 2.096e-04 + NH4+ 2.091e-04 1.902e-04 -3.680 -3.721 -0.041 (0) + NH3 4.819e-07 4.827e-07 -6.317 -6.316 0.001 (0) +N(0) 3.542e-07 + N2 1.771e-07 1.774e-07 -6.752 -6.751 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -62.423 -62.463 -0.041 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -84.837 -84.878 -0.041 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -73.769 -73.769 0.001 (0) ------------------------------Saturation indices------------------------------- Phase SI log IAP log K(298 K, 1 atm) - Aragonite -0.45* -8.79 -8.34 CaCO3 Delta_V -21.29 cm3/mol - Calcite -0.31* -8.79 -8.48 CaCO3 Delta_V -21.29 cm3/mol - CH4(g) -0.00* -2.86 -2.86 CH4 Delta_V -57.82 cm3/mol - CO2(g) -1.16* -2.63 -1.47 CO2 Delta_V -21.69 cm3/mol + Aragonite -0.45 -8.79 -8.34 CaCO3 + Calcite -0.31 -8.79 -8.48 CaCO3 + CH4(g) -0.00 -2.86 -2.86 CH4 + CO2(g) -1.16 -2.63 -1.47 CO2 H2(g) -6.16 -9.31 -3.15 H2 H2O(g) -1.51 -0.00 1.51 H2O N2(g) -3.49 -6.75 -3.26 N2 NH3(g) -8.09 -6.32 1.77 NH3 - O2(g) -70.88* -73.77 -2.89 O2 Delta_V 36.14 cm3/mol - * with Delta_V * (P - 1) / 2.3RT. + O2(g) -70.88 -73.77 -2.89 O2 + Reaction step 4. @@ -626,59 +626,59 @@ N2(g) -3.31 4.892e-04 0.000e+00 3.162e-07 3.162e-07 Pressure (atm) = 1.10 Electrical balance (eq) = -1.080e-10 Percent error, 100*(Cat-|An|)/(Cat+|An|) = -0.00 - Iterations = 19 + Iterations = 22 Total H = 1.110187e+02 Total O = 5.552474e+01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 2.798e-07 2.580e-07 -6.553 -6.588 -0.035 - OH- 4.256e-08 3.879e-08 -7.371 -7.411 -0.040 - H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 -C(-4) 1.362e-03 - CH4 1.362e-03 1.364e-03 -2.866 -2.865 0.001 -C(4) 8.018e-03 - HCO3- 5.165e-03 4.728e-03 -2.287 -2.325 -0.038 - CO2 2.739e-03 2.744e-03 -2.562 -2.562 0.001 - CaHCO3+ 1.105e-04 1.012e-04 -3.957 -3.995 -0.038 - CaCO3 2.417e-06 2.421e-06 -5.617 -5.616 0.001 - CO3-2 1.224e-06 8.595e-07 -5.912 -6.066 -0.153 -Ca 2.502e-03 - Ca+2 2.389e-03 1.677e-03 -2.622 -2.775 -0.154 - CaHCO3+ 1.105e-04 1.012e-04 -3.957 -3.995 -0.038 - CaCO3 2.417e-06 2.421e-06 -5.617 -5.616 0.001 - CaOH+ 1.181e-09 1.078e-09 -8.928 -8.967 -0.040 -H(0) 9.479e-10 - H2 4.740e-10 4.748e-10 -9.324 -9.323 0.001 -N(-3) 2.788e-04 - NH4+ 2.783e-04 2.530e-04 -3.556 -3.597 -0.041 - NH3 5.579e-07 5.588e-07 -6.253 -6.253 0.001 -N(0) 5.367e-07 - N2 2.684e-07 2.688e-07 -6.571 -6.571 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -62.366 -62.407 -0.041 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -84.763 -84.803 -0.041 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -73.734 -73.733 0.001 + H+ 2.798e-07 2.580e-07 -6.553 -6.588 -0.035 0.00 + OH- 4.256e-08 3.879e-08 -7.371 -7.411 -0.040 (0) + H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 18.07 +C(-4) 1.362e-03 + CH4 1.362e-03 1.364e-03 -2.866 -2.865 0.001 (0) +C(4) 8.018e-03 + HCO3- 5.165e-03 4.728e-03 -2.287 -2.325 -0.038 24.33 + CO2 2.739e-03 2.744e-03 -2.562 -2.562 0.001 (0) + CaHCO3+ 1.105e-04 1.012e-04 -3.957 -3.995 -0.038 (0) + CaCO3 2.417e-06 2.421e-06 -5.617 -5.616 0.001 (0) + CO3-2 1.224e-06 8.595e-07 -5.912 -6.066 -0.153 -3.62 +Ca 2.502e-03 + Ca+2 2.389e-03 1.677e-03 -2.622 -2.775 -0.154 -17.67 + CaHCO3+ 1.105e-04 1.012e-04 -3.957 -3.995 -0.038 (0) + CaCO3 2.417e-06 2.421e-06 -5.617 -5.616 0.001 (0) + CaOH+ 1.181e-09 1.078e-09 -8.928 -8.967 -0.040 (0) +H(0) 9.479e-10 + H2 4.740e-10 4.748e-10 -9.324 -9.323 0.001 (0) +N(-3) 2.788e-04 + NH4+ 2.783e-04 2.530e-04 -3.556 -3.597 -0.041 (0) + NH3 5.579e-07 5.588e-07 -6.253 -6.253 0.001 (0) +N(0) 5.367e-07 + N2 2.684e-07 2.688e-07 -6.571 -6.571 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -62.366 -62.407 -0.041 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -84.763 -84.803 -0.041 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -73.734 -73.733 0.001 (0) ------------------------------Saturation indices------------------------------- Phase SI log IAP log K(298 K, 1 atm) - Aragonite -0.51* -8.84 -8.34 CaCO3 Delta_V -21.29 cm3/mol - Calcite -0.36* -8.84 -8.48 CaCO3 Delta_V -21.29 cm3/mol - CH4(g) -0.01* -2.87 -2.86 CH4 Delta_V -57.82 cm3/mol - CO2(g) -1.09* -2.56 -1.47 CO2 Delta_V -21.69 cm3/mol + Aragonite -0.51 -8.84 -8.34 CaCO3 + Calcite -0.36 -8.84 -8.48 CaCO3 + CH4(g) -0.01 -2.87 -2.86 CH4 + CO2(g) -1.09 -2.56 -1.47 CO2 H2(g) -6.17 -9.32 -3.15 H2 H2O(g) -1.51 -0.00 1.51 H2O N2(g) -3.31 -6.57 -3.26 N2 NH3(g) -8.02 -6.25 1.77 NH3 - O2(g) -70.84* -73.73 -2.89 O2 Delta_V 36.14 cm3/mol - * with Delta_V * (P - 1) / 2.3RT. + O2(g) -70.84 -73.73 -2.89 O2 + Reaction step 5. @@ -746,53 +746,53 @@ N2(g) -2.89 1.290e-03 0.000e+00 3.685e-06 3.685e-06 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 4.054e-07 3.734e-07 -6.392 -6.428 -0.036 - OH- 2.945e-08 2.680e-08 -7.531 -7.572 -0.041 - H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 -C(-4) 1.303e-03 - CH4 1.303e-03 1.305e-03 -2.885 -2.884 0.001 -C(4) 9.718e-03 - HCO3- 5.434e-03 4.968e-03 -2.265 -2.304 -0.039 - CO2 4.165e-03 4.173e-03 -2.380 -2.380 0.001 - CaHCO3+ 1.155e-04 1.056e-04 -3.938 -3.976 -0.039 - CaCO3 1.743e-06 1.746e-06 -5.759 -5.758 0.001 - CO3-2 8.933e-07 6.241e-07 -6.049 -6.205 -0.156 -Ca 2.502e-03 - Ca+2 2.385e-03 1.665e-03 -2.623 -2.779 -0.156 - CaHCO3+ 1.155e-04 1.056e-04 -3.938 -3.976 -0.039 - CaCO3 1.743e-06 1.746e-06 -5.759 -5.758 0.001 - CaOH+ 8.116e-10 7.399e-10 -9.091 -9.131 -0.040 -H(0) 8.442e-10 - H2 4.221e-10 4.229e-10 -9.375 -9.374 0.001 -N(-3) 5.512e-04 - NH4+ 5.505e-04 4.997e-04 -3.259 -3.301 -0.042 - NH3 7.613e-07 7.627e-07 -6.118 -6.118 0.001 -N(0) 1.415e-06 - N2 7.076e-07 7.089e-07 -6.150 -6.149 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -62.240 -62.281 -0.041 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -84.586 -84.628 -0.041 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -73.633 -73.633 0.001 + H+ 4.054e-07 3.734e-07 -6.392 -6.428 -0.036 0.00 + OH- 2.945e-08 2.680e-08 -7.531 -7.572 -0.041 (0) + H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 18.07 +C(-4) 1.303e-03 + CH4 1.303e-03 1.305e-03 -2.885 -2.884 0.001 (0) +C(4) 9.718e-03 + HCO3- 5.434e-03 4.968e-03 -2.265 -2.304 -0.039 24.33 + CO2 4.165e-03 4.173e-03 -2.380 -2.380 0.001 (0) + CaHCO3+ 1.155e-04 1.056e-04 -3.938 -3.976 -0.039 (0) + CaCO3 1.743e-06 1.746e-06 -5.759 -5.758 0.001 (0) + CO3-2 8.933e-07 6.241e-07 -6.049 -6.205 -0.156 -3.61 +Ca 2.502e-03 + Ca+2 2.385e-03 1.665e-03 -2.623 -2.779 -0.156 -17.66 + CaHCO3+ 1.155e-04 1.056e-04 -3.938 -3.976 -0.039 (0) + CaCO3 1.743e-06 1.746e-06 -5.759 -5.758 0.001 (0) + CaOH+ 8.116e-10 7.399e-10 -9.091 -9.131 -0.040 (0) +H(0) 8.442e-10 + H2 4.221e-10 4.229e-10 -9.375 -9.374 0.001 (0) +N(-3) 5.512e-04 + NH4+ 5.505e-04 4.997e-04 -3.259 -3.301 -0.042 (0) + NH3 7.613e-07 7.627e-07 -6.118 -6.118 0.001 (0) +N(0) 1.415e-06 + N2 7.076e-07 7.089e-07 -6.150 -6.149 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -62.240 -62.281 -0.041 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -84.586 -84.628 -0.041 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -73.633 -73.633 0.001 (0) ------------------------------Saturation indices------------------------------- Phase SI log IAP log K(298 K, 1 atm) - Aragonite -0.65* -8.98 -8.34 CaCO3 Delta_V -21.28 cm3/mol - Calcite -0.50* -8.98 -8.48 CaCO3 Delta_V -21.28 cm3/mol - CH4(g) -0.02* -2.88 -2.86 CH4 Delta_V -57.82 cm3/mol - CO2(g) -0.91* -2.38 -1.47 CO2 Delta_V -21.68 cm3/mol + Aragonite -0.65 -8.98 -8.34 CaCO3 + Calcite -0.50 -8.98 -8.48 CaCO3 + CH4(g) -0.02 -2.88 -2.86 CH4 + CO2(g) -0.91 -2.38 -1.47 CO2 H2(g) -6.22 -9.37 -3.15 H2 H2O(g) -1.51 -0.00 1.51 H2O N2(g) -2.89 -6.15 -3.26 N2 NH3(g) -7.89 -6.12 1.77 NH3 - O2(g) -70.74* -73.63 -2.89 O2 Delta_V 36.14 cm3/mol - * with Delta_V * (P - 1) / 2.3RT. + O2(g) -70.74 -73.63 -2.89 O2 + Reaction step 6. @@ -828,7 +828,7 @@ Component log P P Initial Final Delta CH4(g) -0.06 8.745e-01 0.000e+00 6.817e-03 6.817e-03 CO2(g) -0.72 1.911e-01 0.000e+00 1.490e-03 1.490e-03 -H2O(g) -1.51 3.089e-02 0.000e+00 2.408e-04 2.408e-04 +H2O(g) -1.51 3.090e-02 0.000e+00 2.408e-04 2.408e-04 N2(g) -2.46 3.448e-03 0.000e+00 2.687e-05 2.687e-05 -----------------------------Solution composition------------------------------ @@ -860,53 +860,53 @@ N2(g) -2.46 3.448e-03 0.000e+00 2.687e-05 2.687e-05 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 5.812e-07 5.342e-07 -6.236 -6.272 -0.037 - OH- 2.064e-08 1.873e-08 -7.685 -7.727 -0.042 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -C(-4) 1.205e-03 - CH4 1.205e-03 1.207e-03 -2.919 -2.918 0.001 -C(4) 1.256e-02 - CO2 6.495e-03 6.508e-03 -2.187 -2.187 0.001 - HCO3- 5.938e-03 5.416e-03 -2.226 -2.266 -0.040 - CaHCO3+ 1.245e-04 1.136e-04 -3.905 -3.945 -0.040 - CaCO3 1.310e-06 1.312e-06 -5.883 -5.882 0.001 - CO3-2 6.871e-07 4.755e-07 -6.163 -6.323 -0.160 -Ca 2.502e-03 - Ca+2 2.376e-03 1.643e-03 -2.624 -2.784 -0.160 - CaHCO3+ 1.245e-04 1.136e-04 -3.905 -3.945 -0.040 - CaCO3 1.310e-06 1.312e-06 -5.883 -5.882 0.001 - CaOH+ 5.612e-10 5.103e-10 -9.251 -9.292 -0.041 -H(0) 7.408e-10 - H2 3.704e-10 3.711e-10 -9.431 -9.431 0.001 -N(-3) 1.063e-03 - NH4+ 1.062e-03 9.610e-04 -2.974 -3.017 -0.043 - NH3 1.023e-06 1.025e-06 -5.990 -5.989 0.001 -N(0) 3.782e-06 - N2 1.891e-06 1.895e-06 -5.723 -5.722 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -62.096 -62.138 -0.043 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -84.385 -84.428 -0.043 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -73.520 -73.519 0.001 + H+ 5.812e-07 5.342e-07 -6.236 -6.272 -0.037 0.00 + OH- 2.064e-08 1.873e-08 -7.685 -7.727 -0.042 (0) + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.07 +C(-4) 1.205e-03 + CH4 1.205e-03 1.207e-03 -2.919 -2.918 0.001 (0) +C(4) 1.256e-02 + CO2 6.495e-03 6.508e-03 -2.187 -2.187 0.001 (0) + HCO3- 5.938e-03 5.416e-03 -2.226 -2.266 -0.040 24.33 + CaHCO3+ 1.245e-04 1.136e-04 -3.905 -3.945 -0.040 (0) + CaCO3 1.310e-06 1.312e-06 -5.883 -5.882 0.001 (0) + CO3-2 6.871e-07 4.755e-07 -6.163 -6.323 -0.160 -3.61 +Ca 2.502e-03 + Ca+2 2.376e-03 1.643e-03 -2.624 -2.784 -0.160 -17.66 + CaHCO3+ 1.245e-04 1.136e-04 -3.905 -3.945 -0.040 (0) + CaCO3 1.310e-06 1.312e-06 -5.883 -5.882 0.001 (0) + CaOH+ 5.612e-10 5.103e-10 -9.251 -9.292 -0.041 (0) +H(0) 7.408e-10 + H2 3.704e-10 3.711e-10 -9.431 -9.431 0.001 (0) +N(-3) 1.063e-03 + NH4+ 1.062e-03 9.610e-04 -2.974 -3.017 -0.043 (0) + NH3 1.023e-06 1.025e-06 -5.990 -5.989 0.001 (0) +N(0) 3.782e-06 + N2 1.891e-06 1.895e-06 -5.723 -5.722 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -62.096 -62.138 -0.043 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -84.385 -84.428 -0.043 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -73.520 -73.519 0.001 (0) ------------------------------Saturation indices------------------------------- Phase SI log IAP log K(298 K, 1 atm) - Aragonite -0.77* -9.11 -8.34 CaCO3 Delta_V -21.27 cm3/mol - Calcite -0.63* -9.11 -8.48 CaCO3 Delta_V -21.27 cm3/mol - CH4(g) -0.06* -2.92 -2.86 CH4 Delta_V -57.82 cm3/mol - CO2(g) -0.72* -2.19 -1.47 CO2 Delta_V -21.68 cm3/mol + Aragonite -0.77 -9.11 -8.34 CaCO3 + Calcite -0.63 -9.11 -8.48 CaCO3 + CH4(g) -0.06 -2.92 -2.86 CH4 + CO2(g) -0.72 -2.19 -1.47 CO2 H2(g) -6.28 -9.43 -3.15 H2 H2O(g) -1.51 -0.00 1.51 H2O N2(g) -2.46 -5.72 -3.26 N2 NH3(g) -7.76 -5.99 1.77 NH3 - O2(g) -70.63* -73.52 -2.89 O2 Delta_V 36.14 cm3/mol - * with Delta_V * (P - 1) / 2.3RT. + O2(g) -70.63 -73.52 -2.89 O2 + Reaction step 7. @@ -968,59 +968,59 @@ N2(g) -2.04 9.143e-03 0.000e+00 1.771e-04 1.771e-04 Pressure (atm) = 1.10 Electrical balance (eq) = -1.080e-10 Percent error, 100*(Cat-|An|)/(Cat+|An|) = -0.00 - Iterations = 21 + Iterations = 19 Total H = 1.110217e+02 Total O = 5.554133e+01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 7.614e-07 6.977e-07 -6.118 -6.156 -0.038 - OH- 1.586e-08 1.434e-08 -7.800 -7.843 -0.044 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -C(-4) 1.072e-03 - CH4 1.072e-03 1.074e-03 -2.970 -2.969 0.001 -C(4) 1.647e-02 - CO2 9.590e-03 9.610e-03 -2.018 -2.017 0.001 - HCO3- 6.738e-03 6.123e-03 -2.171 -2.213 -0.042 - CaHCO3+ 1.384e-04 1.258e-04 -3.859 -3.900 -0.042 - CaCO3 1.111e-06 1.113e-06 -5.954 -5.953 0.001 - CO3-2 6.036e-07 4.116e-07 -6.219 -6.386 -0.166 -Ca 2.502e-03 - Ca+2 2.363e-03 1.610e-03 -2.627 -2.793 -0.167 - CaHCO3+ 1.384e-04 1.258e-04 -3.859 -3.900 -0.042 - CaCO3 1.111e-06 1.113e-06 -5.954 -5.953 0.001 - CaOH+ 4.227e-10 3.828e-10 -9.374 -9.417 -0.043 -H(0) 6.524e-10 - H2 3.262e-10 3.269e-10 -9.487 -9.486 0.001 -N(-3) 1.876e-03 - NH4+ 1.875e-03 1.690e-03 -2.727 -2.772 -0.045 - NH3 1.377e-06 1.380e-06 -5.861 -5.860 0.001 -N(0) 1.003e-05 - N2 5.014e-06 5.025e-06 -5.300 -5.299 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.916 -61.960 -0.044 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -84.150 -84.195 -0.044 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -73.410 -73.409 0.001 + H+ 7.614e-07 6.977e-07 -6.118 -6.156 -0.038 0.00 + OH- 1.586e-08 1.434e-08 -7.800 -7.843 -0.044 (0) + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.07 +C(-4) 1.072e-03 + CH4 1.072e-03 1.074e-03 -2.970 -2.969 0.001 (0) +C(4) 1.647e-02 + CO2 9.590e-03 9.610e-03 -2.018 -2.017 0.001 (0) + HCO3- 6.738e-03 6.123e-03 -2.171 -2.213 -0.042 24.33 + CaHCO3+ 1.384e-04 1.258e-04 -3.859 -3.900 -0.042 (0) + CaCO3 1.111e-06 1.113e-06 -5.954 -5.953 0.001 (0) + CO3-2 6.036e-07 4.116e-07 -6.219 -6.386 -0.166 -3.60 +Ca 2.502e-03 + Ca+2 2.363e-03 1.610e-03 -2.627 -2.793 -0.167 -17.65 + CaHCO3+ 1.384e-04 1.258e-04 -3.859 -3.900 -0.042 (0) + CaCO3 1.111e-06 1.113e-06 -5.954 -5.953 0.001 (0) + CaOH+ 4.227e-10 3.828e-10 -9.374 -9.417 -0.043 (0) +H(0) 6.524e-10 + H2 3.262e-10 3.269e-10 -9.487 -9.486 0.001 (0) +N(-3) 1.876e-03 + NH4+ 1.875e-03 1.690e-03 -2.727 -2.772 -0.045 (0) + NH3 1.377e-06 1.380e-06 -5.861 -5.860 0.001 (0) +N(0) 1.003e-05 + N2 5.014e-06 5.025e-06 -5.300 -5.299 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.916 -61.960 -0.044 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -84.150 -84.195 -0.044 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -73.410 -73.409 0.001 (0) ------------------------------Saturation indices------------------------------- Phase SI log IAP log K(298 K, 1 atm) - Aragonite -0.84* -9.18 -8.34 CaCO3 Delta_V -21.25 cm3/mol - Calcite -0.70* -9.18 -8.48 CaCO3 Delta_V -21.25 cm3/mol - CH4(g) -0.11* -2.97 -2.86 CH4 Delta_V -57.81 cm3/mol - CO2(g) -0.55* -2.02 -1.47 CO2 Delta_V -21.67 cm3/mol + Aragonite -0.84 -9.18 -8.34 CaCO3 + Calcite -0.70 -9.18 -8.48 CaCO3 + CH4(g) -0.11 -2.97 -2.86 CH4 + CO2(g) -0.55 -2.02 -1.47 CO2 H2(g) -6.34 -9.49 -3.15 H2 H2O(g) -1.51 -0.00 1.51 H2O N2(g) -2.04 -5.30 -3.26 N2 NH3(g) -7.63 -5.86 1.77 NH3 - O2(g) -70.52* -73.41 -2.89 O2 Delta_V 36.14 cm3/mol - * with Delta_V * (P - 1) / 2.3RT. + O2(g) -70.52 -73.41 -2.89 O2 + Reaction step 8. @@ -1080,7 +1080,7 @@ N2(g) -1.73 1.876e-02 0.000e+00 8.731e-04 8.731e-04 Total CO2 (mol/kg) = 2.024e-02 Temperature (deg C) = 25.00 Pressure (atm) = 1.10 - Electrical balance (eq) = -1.078e-10 + Electrical balance (eq) = -1.080e-10 Percent error, 100*(Cat-|An|)/(Cat+|An|) = -0.00 Iterations = 20 Total H = 1.110241e+02 @@ -1088,53 +1088,53 @@ N2(g) -1.73 1.876e-02 0.000e+00 8.731e-04 8.731e-04 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 8.922e-07 8.152e-07 -6.050 -6.089 -0.039 - OH- 1.363e-08 1.227e-08 -7.865 -7.911 -0.046 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -C(-4) 9.389e-04 - CH4 9.389e-04 9.410e-04 -3.027 -3.026 0.001 -C(4) 2.024e-02 - CO2 1.253e-02 1.256e-02 -1.902 -1.901 0.001 - HCO3- 7.562e-03 6.847e-03 -2.121 -2.164 -0.043 - CaHCO3+ 1.523e-04 1.379e-04 -3.817 -3.860 -0.043 - CaCO3 1.042e-06 1.045e-06 -5.982 -5.981 0.001 - CO3-2 5.859e-07 3.940e-07 -6.232 -6.405 -0.172 -Ca 2.502e-03 - Ca+2 2.349e-03 1.578e-03 -2.629 -2.802 -0.173 - CaHCO3+ 1.523e-04 1.379e-04 -3.817 -3.860 -0.043 - CaCO3 1.042e-06 1.045e-06 -5.982 -5.981 0.001 - CaOH+ 3.559e-10 3.212e-10 -9.449 -9.493 -0.045 -H(0) 5.903e-10 - H2 2.951e-10 2.958e-10 -9.530 -9.529 0.001 -N(-3) 2.713e-03 - NH4+ 2.712e-03 2.434e-03 -2.567 -2.614 -0.047 - NH3 1.698e-06 1.702e-06 -5.770 -5.769 0.001 -N(0) 2.057e-05 - N2 1.028e-05 1.031e-05 -4.988 -4.987 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.760 -61.807 -0.046 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -83.952 -83.998 -0.046 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -73.323 -73.322 0.001 + H+ 8.922e-07 8.152e-07 -6.050 -6.089 -0.039 0.00 + OH- 1.363e-08 1.227e-08 -7.865 -7.911 -0.046 (0) + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.07 +C(-4) 9.389e-04 + CH4 9.389e-04 9.410e-04 -3.027 -3.026 0.001 (0) +C(4) 2.024e-02 + CO2 1.253e-02 1.256e-02 -1.902 -1.901 0.001 (0) + HCO3- 7.562e-03 6.847e-03 -2.121 -2.164 -0.043 24.34 + CaHCO3+ 1.523e-04 1.379e-04 -3.817 -3.860 -0.043 (0) + CaCO3 1.042e-06 1.045e-06 -5.982 -5.981 0.001 (0) + CO3-2 5.859e-07 3.940e-07 -6.232 -6.405 -0.172 -3.59 +Ca 2.502e-03 + Ca+2 2.349e-03 1.578e-03 -2.629 -2.802 -0.173 -17.64 + CaHCO3+ 1.523e-04 1.379e-04 -3.817 -3.860 -0.043 (0) + CaCO3 1.042e-06 1.045e-06 -5.982 -5.981 0.001 (0) + CaOH+ 3.559e-10 3.212e-10 -9.449 -9.493 -0.045 (0) +H(0) 5.903e-10 + H2 2.951e-10 2.958e-10 -9.530 -9.529 0.001 (0) +N(-3) 2.713e-03 + NH4+ 2.712e-03 2.434e-03 -2.567 -2.614 -0.047 (0) + NH3 1.698e-06 1.702e-06 -5.770 -5.769 0.001 (0) +N(0) 2.057e-05 + N2 1.028e-05 1.031e-05 -4.988 -4.987 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.760 -61.807 -0.046 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -83.952 -83.998 -0.046 29.04 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -73.323 -73.322 0.001 (0) ------------------------------Saturation indices------------------------------- Phase SI log IAP log K(298 K, 1 atm) - Aragonite -0.87* -9.21 -8.34 CaCO3 Delta_V -21.24 cm3/mol - Calcite -0.73* -9.21 -8.48 CaCO3 Delta_V -21.24 cm3/mol - CH4(g) -0.17* -3.03 -2.86 CH4 Delta_V -57.80 cm3/mol - CO2(g) -0.43* -1.90 -1.47 CO2 Delta_V -21.66 cm3/mol + Aragonite -0.87 -9.21 -8.34 CaCO3 + Calcite -0.73 -9.21 -8.48 CaCO3 + CH4(g) -0.17 -3.03 -2.86 CH4 + CO2(g) -0.43 -1.90 -1.47 CO2 H2(g) -6.38 -9.53 -3.15 H2 H2O(g) -1.51 -0.00 1.51 H2O N2(g) -1.73 -4.99 -3.26 N2 NH3(g) -7.54 -5.77 1.77 NH3 - O2(g) -70.43* -73.32 -2.89 O2 Delta_V 36.14 cm3/mol - * with Delta_V * (P - 1) / 2.3RT. + O2(g) -70.43 -73.32 -2.89 O2 + Reaction step 9. @@ -1170,7 +1170,7 @@ Component log P P Initial Final Delta CH4(g) -0.21 6.175e-01 0.000e+00 6.373e-02 6.373e-02 CO2(g) -0.37 4.249e-01 0.000e+00 4.385e-02 4.385e-02 -H2O(g) -1.51 3.089e-02 0.000e+00 3.187e-03 3.187e-03 +H2O(g) -1.51 3.089e-02 0.000e+00 3.188e-03 3.188e-03 N2(g) -1.57 2.669e-02 0.000e+00 2.754e-03 2.754e-03 -----------------------------Solution composition------------------------------ @@ -1179,7 +1179,7 @@ N2(g) -1.57 2.669e-02 0.000e+00 2.754e-03 2.754e-03 C 2.350e-02 2.350e-02 Ca 2.502e-03 2.502e-03 - N 3.243e-03 3.242e-03 + N 3.242e-03 3.242e-03 ----------------------------Description of solution---------------------------- @@ -1194,61 +1194,61 @@ N2(g) -1.57 2.669e-02 0.000e+00 2.754e-03 2.754e-03 Total CO2 (mol/kg) = 2.265e-02 Temperature (deg C) = 25.00 Pressure (atm) = 1.10 - Electrical balance (eq) = -1.155e-10 + Electrical balance (eq) = -1.132e-10 Percent error, 100*(Cat-|An|)/(Cat+|An|) = -0.00 - Iterations = 31 + Iterations = 27 Total H = 1.110274e+02 Total O = 5.555498e+01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 9.687e-07 8.836e-07 -6.014 -6.054 -0.040 - OH- 1.260e-08 1.132e-08 -7.900 -7.946 -0.046 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -C(-4) 8.506e-04 - CH4 8.506e-04 8.526e-04 -3.070 -3.069 0.001 -C(4) 2.265e-02 - CO2 1.443e-02 1.447e-02 -1.841 -1.840 0.001 - HCO3- 8.053e-03 7.278e-03 -2.094 -2.138 -0.044 - CaHCO3+ 1.603e-04 1.449e-04 -3.795 -3.839 -0.044 - CaCO3 1.010e-06 1.012e-06 -5.996 -5.995 0.001 - CO3-2 5.792e-07 3.863e-07 -6.237 -6.413 -0.176 -Ca 2.502e-03 - Ca+2 2.341e-03 1.560e-03 -2.631 -2.807 -0.176 - CaHCO3+ 1.603e-04 1.449e-04 -3.795 -3.839 -0.044 - CaCO3 1.010e-06 1.012e-06 -5.996 -5.995 0.001 - CaOH+ 3.253e-10 2.929e-10 -9.488 -9.533 -0.046 -H(0) 5.558e-10 - H2 2.779e-10 2.786e-10 -9.556 -9.555 0.001 -N(-3) 3.213e-03 - NH4+ 3.211e-03 2.876e-03 -2.493 -2.541 -0.048 - NH3 1.850e-06 1.855e-06 -5.733 -5.732 0.001 -N(0) 2.926e-05 - N2 1.463e-05 1.467e-05 -4.835 -4.834 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.679 -61.726 -0.047 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -83.844 -83.891 -0.047 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -73.271 -73.270 0.001 + H+ 9.686e-07 8.836e-07 -6.014 -6.054 -0.040 0.00 + OH- 1.260e-08 1.132e-08 -7.900 -7.946 -0.046 (0) + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.07 +C(-4) 8.506e-04 + CH4 8.506e-04 8.526e-04 -3.070 -3.069 0.001 (0) +C(4) 2.265e-02 + CO2 1.443e-02 1.447e-02 -1.841 -1.840 0.001 (0) + HCO3- 8.053e-03 7.278e-03 -2.094 -2.138 -0.044 24.34 + CaHCO3+ 1.603e-04 1.449e-04 -3.795 -3.839 -0.044 (0) + CaCO3 1.010e-06 1.012e-06 -5.996 -5.995 0.001 (0) + CO3-2 5.792e-07 3.863e-07 -6.237 -6.413 -0.176 -3.59 +Ca 2.502e-03 + Ca+2 2.341e-03 1.560e-03 -2.631 -2.807 -0.176 -17.64 + CaHCO3+ 1.603e-04 1.449e-04 -3.795 -3.839 -0.044 (0) + CaCO3 1.010e-06 1.012e-06 -5.996 -5.995 0.001 (0) + CaOH+ 3.253e-10 2.929e-10 -9.488 -9.533 -0.046 (0) +H(0) 5.558e-10 + H2 2.779e-10 2.786e-10 -9.556 -9.555 0.001 (0) +N(-3) 3.213e-03 + NH4+ 3.211e-03 2.876e-03 -2.493 -2.541 -0.048 (0) + NH3 1.850e-06 1.855e-06 -5.733 -5.732 0.001 (0) +N(0) 2.926e-05 + N2 1.463e-05 1.467e-05 -4.835 -4.834 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.679 -61.726 -0.047 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -83.844 -83.891 -0.047 29.04 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -73.271 -73.270 0.001 (0) ------------------------------Saturation indices------------------------------- Phase SI log IAP log K(298 K, 1 atm) - Aragonite -0.88* -9.22 -8.34 CaCO3 Delta_V -21.23 cm3/mol - Calcite -0.74* -9.22 -8.48 CaCO3 Delta_V -21.23 cm3/mol - CH4(g) -0.21* -3.07 -2.86 CH4 Delta_V -57.80 cm3/mol - CO2(g) -0.37* -1.84 -1.47 CO2 Delta_V -21.66 cm3/mol + Aragonite -0.88 -9.22 -8.34 CaCO3 + Calcite -0.74 -9.22 -8.48 CaCO3 + CH4(g) -0.21 -3.07 -2.86 CH4 + CO2(g) -0.37 -1.84 -1.47 CO2 H2(g) -6.41 -9.56 -3.15 H2 H2O(g) -1.51 -0.00 1.51 H2O N2(g) -1.57 -4.83 -3.26 N2 NH3(g) -7.50 -5.73 1.77 NH3 - O2(g) -70.38* -73.27 -2.89 O2 Delta_V 36.14 cm3/mol - * with Delta_V * (P - 1) / 2.3RT. + O2(g) -70.38 -73.27 -2.89 O2 + Reaction step 10. @@ -1283,8 +1283,8 @@ Total pressure: 1.10 atmospheres Component log P P Initial Final Delta CH4(g) -0.24 5.809e-01 0.000e+00 1.295e-01 1.295e-01 -CO2(g) -0.34 4.569e-01 0.000e+00 1.018e-01 1.018e-01 -H2O(g) -1.51 3.089e-02 0.000e+00 6.884e-03 6.884e-03 +CO2(g) -0.34 4.568e-01 0.000e+00 1.018e-01 1.018e-01 +H2O(g) -1.51 3.089e-02 0.000e+00 6.885e-03 6.885e-03 N2(g) -1.50 3.141e-02 0.000e+00 7.000e-03 7.000e-03 -----------------------------Solution composition------------------------------ @@ -1308,61 +1308,61 @@ N2(g) -1.50 3.141e-02 0.000e+00 7.000e-03 7.000e-03 Total CO2 (mol/kg) = 2.398e-02 Temperature (deg C) = 25.00 Pressure (atm) = 1.10 - Electrical balance (eq) = -1.080e-10 + Electrical balance (eq) = -1.072e-10 Percent error, 100*(Cat-|An|)/(Cat+|An|) = -0.00 - Iterations = 25 + Iterations = 21 Total H = 1.110333e+02 Total O = 5.556033e+01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.012e-06 9.226e-07 -5.995 -6.035 -0.040 - OH- 1.208e-08 1.085e-08 -7.918 -7.965 -0.047 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -C(-4) 8.000e-04 - CH4 8.000e-04 8.020e-04 -3.097 -3.096 0.001 -C(4) 2.398e-02 - CO2 1.552e-02 1.556e-02 -1.809 -1.808 0.001 - HCO3- 8.301e-03 7.494e-03 -2.081 -2.125 -0.044 - CaHCO3+ 1.643e-04 1.483e-04 -3.784 -3.829 -0.044 - CaCO3 9.905e-07 9.929e-07 -6.004 -6.003 0.001 - CO3-2 5.736e-07 3.810e-07 -6.241 -6.419 -0.178 -Ca 2.502e-03 - Ca+2 2.337e-03 1.551e-03 -2.631 -2.809 -0.178 - CaHCO3+ 1.643e-04 1.483e-04 -3.784 -3.829 -0.044 - CaCO3 9.905e-07 9.929e-07 -6.004 -6.003 0.001 - CaOH+ 3.101e-10 2.789e-10 -9.509 -9.555 -0.046 -H(0) 5.375e-10 - H2 2.687e-10 2.694e-10 -9.571 -9.570 0.001 -N(-3) 3.466e-03 - NH4+ 3.464e-03 3.098e-03 -2.460 -2.509 -0.048 - NH3 1.909e-06 1.914e-06 -5.719 -5.718 0.001 -N(0) 3.443e-05 - N2 1.722e-05 1.726e-05 -4.764 -4.763 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.640 -61.688 -0.048 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -83.790 -83.838 -0.048 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -73.242 -73.241 0.001 + H+ 1.012e-06 9.226e-07 -5.995 -6.035 -0.040 0.00 + OH- 1.208e-08 1.085e-08 -7.918 -7.965 -0.047 (0) + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.07 +C(-4) 8.000e-04 + CH4 8.000e-04 8.020e-04 -3.097 -3.096 0.001 (0) +C(4) 2.398e-02 + CO2 1.552e-02 1.556e-02 -1.809 -1.808 0.001 (0) + HCO3- 8.301e-03 7.494e-03 -2.081 -2.125 -0.044 24.34 + CaHCO3+ 1.643e-04 1.483e-04 -3.784 -3.829 -0.044 (0) + CaCO3 9.905e-07 9.929e-07 -6.004 -6.003 0.001 (0) + CO3-2 5.736e-07 3.810e-07 -6.241 -6.419 -0.178 -3.59 +Ca 2.502e-03 + Ca+2 2.337e-03 1.551e-03 -2.631 -2.809 -0.178 -17.64 + CaHCO3+ 1.643e-04 1.483e-04 -3.784 -3.829 -0.044 (0) + CaCO3 9.905e-07 9.929e-07 -6.004 -6.003 0.001 (0) + CaOH+ 3.101e-10 2.789e-10 -9.509 -9.555 -0.046 (0) +H(0) 5.375e-10 + H2 2.687e-10 2.694e-10 -9.571 -9.570 0.001 (0) +N(-3) 3.465e-03 + NH4+ 3.464e-03 3.098e-03 -2.460 -2.509 -0.048 (0) + NH3 1.909e-06 1.914e-06 -5.719 -5.718 0.001 (0) +N(0) 3.443e-05 + N2 1.722e-05 1.726e-05 -4.764 -4.763 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.640 -61.688 -0.048 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -83.790 -83.838 -0.048 29.04 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -73.242 -73.241 0.001 (0) ------------------------------Saturation indices------------------------------- Phase SI log IAP log K(298 K, 1 atm) - Aragonite -0.89* -9.23 -8.34 CaCO3 Delta_V -21.22 cm3/mol - Calcite -0.75* -9.23 -8.48 CaCO3 Delta_V -21.22 cm3/mol - CH4(g) -0.24* -3.10 -2.86 CH4 Delta_V -57.79 cm3/mol - CO2(g) -0.34* -1.81 -1.47 CO2 Delta_V -21.66 cm3/mol + Aragonite -0.89 -9.23 -8.34 CaCO3 + Calcite -0.75 -9.23 -8.48 CaCO3 + CH4(g) -0.24 -3.10 -2.86 CH4 + CO2(g) -0.34 -1.81 -1.47 CO2 H2(g) -6.42 -9.57 -3.15 H2 H2O(g) -1.51 -0.00 1.51 H2O N2(g) -1.50 -4.76 -3.26 N2 NH3(g) -7.49 -5.72 1.77 NH3 - O2(g) -70.35* -73.24 -2.89 O2 Delta_V 36.14 cm3/mol - * with Delta_V * (P - 1) / 2.3RT. + O2(g) -70.35 -73.24 -2.89 O2 + Reaction step 11. @@ -1422,61 +1422,61 @@ N2(g) -1.47 3.380e-02 0.000e+00 1.569e-02 1.569e-02 Total CO2 (mol/kg) = 2.465e-02 Temperature (deg C) = 25.00 Pressure (atm) = 1.10 - Electrical balance (eq) = -1.080e-10 + Electrical balance (eq) = -1.102e-10 Percent error, 100*(Cat-|An|)/(Cat+|An|) = -0.00 - Iterations = 22 + Iterations = 27 Total H = 1.110447e+02 Total O = 5.556725e+01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.035e-06 9.427e-07 -5.985 -6.026 -0.040 - OH- 1.183e-08 1.061e-08 -7.927 -7.974 -0.047 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -C(-4) 7.743e-04 - CH4 7.743e-04 7.763e-04 -3.111 -3.110 0.001 -C(4) 2.465e-02 - CO2 1.607e-02 1.611e-02 -1.794 -1.793 0.001 - HCO3- 8.417e-03 7.595e-03 -2.075 -2.119 -0.045 - CaHCO3+ 1.661e-04 1.499e-04 -3.780 -3.824 -0.045 - CaCO3 9.797e-07 9.821e-07 -6.009 -6.008 0.001 - CO3-2 5.699e-07 3.779e-07 -6.244 -6.423 -0.178 -Ca 2.502e-03 - Ca+2 2.335e-03 1.547e-03 -2.632 -2.811 -0.179 - CaHCO3+ 1.661e-04 1.499e-04 -3.780 -3.824 -0.045 - CaCO3 9.797e-07 9.821e-07 -6.009 -6.008 0.001 - CaOH+ 3.028e-10 2.722e-10 -9.519 -9.565 -0.046 -H(0) 5.285e-10 - H2 2.642e-10 2.649e-10 -9.578 -9.577 0.001 -N(-3) 3.583e-03 - NH4+ 3.581e-03 3.202e-03 -2.446 -2.495 -0.049 - NH3 1.931e-06 1.935e-06 -5.714 -5.713 0.001 -N(0) 3.705e-05 - N2 1.853e-05 1.857e-05 -4.732 -4.731 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.622 -61.670 -0.048 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -83.765 -83.813 -0.048 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -73.228 -73.227 0.001 + H+ 1.035e-06 9.427e-07 -5.985 -6.026 -0.040 0.00 + OH- 1.183e-08 1.061e-08 -7.927 -7.974 -0.047 (0) + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.07 +C(-4) 7.743e-04 + CH4 7.743e-04 7.763e-04 -3.111 -3.110 0.001 (0) +C(4) 2.465e-02 + CO2 1.607e-02 1.611e-02 -1.794 -1.793 0.001 (0) + HCO3- 8.417e-03 7.595e-03 -2.075 -2.119 -0.045 24.34 + CaHCO3+ 1.661e-04 1.499e-04 -3.780 -3.824 -0.045 (0) + CaCO3 9.797e-07 9.821e-07 -6.009 -6.008 0.001 (0) + CO3-2 5.699e-07 3.779e-07 -6.244 -6.423 -0.178 -3.59 +Ca 2.502e-03 + Ca+2 2.335e-03 1.547e-03 -2.632 -2.811 -0.179 -17.64 + CaHCO3+ 1.661e-04 1.499e-04 -3.780 -3.824 -0.045 (0) + CaCO3 9.797e-07 9.821e-07 -6.009 -6.008 0.001 (0) + CaOH+ 3.028e-10 2.722e-10 -9.519 -9.565 -0.046 (0) +H(0) 5.285e-10 + H2 2.642e-10 2.649e-10 -9.578 -9.577 0.001 (0) +N(-3) 3.583e-03 + NH4+ 3.581e-03 3.202e-03 -2.446 -2.495 -0.049 (0) + NH3 1.931e-06 1.935e-06 -5.714 -5.713 0.001 (0) +N(0) 3.705e-05 + N2 1.853e-05 1.857e-05 -4.732 -4.731 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.622 -61.670 -0.048 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -83.765 -83.813 -0.048 29.04 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -73.228 -73.227 0.001 (0) ------------------------------Saturation indices------------------------------- Phase SI log IAP log K(298 K, 1 atm) - Aragonite -0.90* -9.23 -8.34 CaCO3 Delta_V -21.22 cm3/mol - Calcite -0.75* -9.23 -8.48 CaCO3 Delta_V -21.22 cm3/mol - CH4(g) -0.25* -3.11 -2.86 CH4 Delta_V -57.79 cm3/mol - CO2(g) -0.33* -1.79 -1.47 CO2 Delta_V -21.65 cm3/mol + Aragonite -0.90 -9.23 -8.34 CaCO3 + Calcite -0.75 -9.23 -8.48 CaCO3 + CH4(g) -0.25 -3.11 -2.86 CH4 + CO2(g) -0.33 -1.79 -1.47 CO2 H2(g) -6.43 -9.58 -3.15 H2 H2O(g) -1.51 -0.00 1.51 H2O N2(g) -1.47 -4.73 -3.26 N2 NH3(g) -7.48 -5.71 1.77 NH3 - O2(g) -70.33* -73.23 -2.89 O2 Delta_V 36.14 cm3/mol - * with Delta_V * (P - 1) / 2.3RT. + O2(g) -70.33 -73.23 -2.89 O2 + Reaction step 12. @@ -1536,61 +1536,61 @@ N2(g) -1.46 3.498e-02 0.000e+00 3.316e-02 3.316e-02 Total CO2 (mol/kg) = 2.498e-02 Temperature (deg C) = 25.00 Pressure (atm) = 1.10 - Electrical balance (eq) = -1.080e-10 + Electrical balance (eq) = -1.079e-10 Percent error, 100*(Cat-|An|)/(Cat+|An|) = -0.00 - Iterations = 23 + Iterations = 31 Total H = 1.110674e+02 Total O = 5.557919e+01 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.046e-06 9.529e-07 -5.980 -6.021 -0.041 - OH- 1.171e-08 1.050e-08 -7.932 -7.979 -0.047 - H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 -C(-4) 7.615e-04 - CH4 7.615e-04 7.634e-04 -3.118 -3.117 0.001 -C(4) 2.498e-02 - CO2 1.634e-02 1.639e-02 -1.787 -1.786 0.001 - HCO3- 8.471e-03 7.643e-03 -2.072 -2.117 -0.045 - CaHCO3+ 1.670e-04 1.507e-04 -3.777 -3.822 -0.045 - CaCO3 9.738e-07 9.762e-07 -6.012 -6.010 0.001 - CO3-2 5.678e-07 3.762e-07 -6.246 -6.425 -0.179 -Ca 2.501e-03 - Ca+2 2.333e-03 1.545e-03 -2.632 -2.811 -0.179 - CaHCO3+ 1.670e-04 1.507e-04 -3.777 -3.822 -0.045 - CaCO3 9.738e-07 9.762e-07 -6.012 -6.010 0.001 - CaOH+ 2.992e-10 2.689e-10 -9.524 -9.570 -0.046 -H(0) 5.240e-10 - H2 2.620e-10 2.627e-10 -9.582 -9.581 0.001 -N(-3) 3.640e-03 - NH4+ 3.638e-03 3.251e-03 -2.439 -2.488 -0.049 - NH3 1.940e-06 1.944e-06 -5.712 -5.711 0.001 -N(0) 3.835e-05 - N2 1.918e-05 1.922e-05 -4.717 -4.716 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.614 -61.662 -0.048 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -83.753 -83.801 -0.048 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -73.220 -73.219 0.001 + H+ 1.046e-06 9.529e-07 -5.980 -6.021 -0.041 0.00 + OH- 1.171e-08 1.050e-08 -7.932 -7.979 -0.047 (0) + H2O 5.551e+01 9.995e-01 1.744 -0.000 0.000 18.07 +C(-4) 7.615e-04 + CH4 7.615e-04 7.634e-04 -3.118 -3.117 0.001 (0) +C(4) 2.498e-02 + CO2 1.634e-02 1.639e-02 -1.787 -1.786 0.001 (0) + HCO3- 8.471e-03 7.643e-03 -2.072 -2.117 -0.045 24.34 + CaHCO3+ 1.670e-04 1.507e-04 -3.777 -3.822 -0.045 (0) + CaCO3 9.738e-07 9.762e-07 -6.012 -6.010 0.001 (0) + CO3-2 5.678e-07 3.762e-07 -6.246 -6.425 -0.179 -3.59 +Ca 2.501e-03 + Ca+2 2.333e-03 1.545e-03 -2.632 -2.811 -0.179 -17.64 + CaHCO3+ 1.670e-04 1.507e-04 -3.777 -3.822 -0.045 (0) + CaCO3 9.738e-07 9.762e-07 -6.012 -6.010 0.001 (0) + CaOH+ 2.992e-10 2.689e-10 -9.524 -9.570 -0.046 (0) +H(0) 5.240e-10 + H2 2.620e-10 2.627e-10 -9.582 -9.581 0.001 (0) +N(-3) 3.640e-03 + NH4+ 3.638e-03 3.251e-03 -2.439 -2.488 -0.049 (0) + NH3 1.940e-06 1.944e-06 -5.712 -5.711 0.001 (0) +N(0) 3.835e-05 + N2 1.918e-05 1.922e-05 -4.717 -4.716 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.614 -61.662 -0.048 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -83.753 -83.801 -0.048 29.04 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -73.220 -73.219 0.001 (0) ------------------------------Saturation indices------------------------------- Phase SI log IAP log K(298 K, 1 atm) - Aragonite -0.90* -9.24 -8.34 CaCO3 Delta_V -21.22 cm3/mol - Calcite -0.76* -9.24 -8.48 CaCO3 Delta_V -21.22 cm3/mol - CH4(g) -0.26* -3.12 -2.86 CH4 Delta_V -57.79 cm3/mol - CO2(g) -0.32* -1.79 -1.47 CO2 Delta_V -21.65 cm3/mol + Aragonite -0.90 -9.24 -8.34 CaCO3 + Calcite -0.76 -9.24 -8.48 CaCO3 + CH4(g) -0.26 -3.12 -2.86 CH4 + CO2(g) -0.32 -1.79 -1.47 CO2 H2(g) -6.43 -9.58 -3.15 H2 H2O(g) -1.51 -0.00 1.51 H2O N2(g) -1.46 -4.72 -3.26 N2 NH3(g) -7.48 -5.71 1.77 NH3 - O2(g) -70.33* -73.22 -2.89 O2 Delta_V 36.14 cm3/mol - * with Delta_V * (P - 1) / 2.3RT. + O2(g) -70.33 -73.22 -2.89 O2 + ------------------ End of simulation. @@ -1720,38 +1720,38 @@ N2(g) -4.45 3.548e-05 0.000e+00 3.363e-05 3.363e-05 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.176e-07 1.085e-07 -6.930 -6.964 -0.035 - OH- 1.010e-07 9.223e-08 -6.996 -7.035 -0.040 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -C(-4) 7.625e-07 - CH4 7.625e-07 7.638e-07 -6.118 -6.117 0.001 -C(4) 6.090e-03 - HCO3- 4.885e-03 4.479e-03 -2.311 -2.349 -0.038 - CO2 1.091e-03 1.093e-03 -2.962 -2.961 0.001 - CaHCO3+ 1.052e-04 9.645e-05 -3.978 -4.016 -0.038 - CaCO3 5.478e-06 5.488e-06 -5.261 -5.261 0.001 - CO3-2 2.740e-06 1.935e-06 -5.562 -5.713 -0.151 -Ca 2.502e-03 - Ca+2 2.391e-03 1.688e-03 -2.621 -2.773 -0.151 - CaHCO3+ 1.052e-04 9.645e-05 -3.978 -4.016 -0.038 - CaCO3 5.478e-06 5.488e-06 -5.261 -5.261 0.001 - CaOH+ 2.823e-09 2.581e-09 -8.549 -8.588 -0.039 -H(0) 1.836e-10 - H2 9.178e-11 9.194e-11 -10.037 -10.037 0.001 -N(-3) 2.695e-06 - NH4+ 2.682e-06 2.442e-06 -5.572 -5.612 -0.041 - NH3 1.280e-08 1.282e-08 -7.893 -7.892 0.001 -N(0) 3.893e-08 - N2 1.947e-08 1.950e-08 -7.711 -7.710 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.491 -61.531 -0.040 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -83.174 -83.214 -0.040 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -72.308 -72.307 0.001 + H+ 1.176e-07 1.085e-07 -6.930 -6.964 -0.035 0.00 + OH- 1.010e-07 9.223e-08 -6.996 -7.035 -0.040 (0) + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +C(-4) 7.625e-07 + CH4 7.625e-07 7.638e-07 -6.118 -6.117 0.001 (0) +C(4) 6.090e-03 + HCO3- 4.885e-03 4.479e-03 -2.311 -2.349 -0.038 24.33 + CO2 1.091e-03 1.093e-03 -2.962 -2.961 0.001 (0) + CaHCO3+ 1.052e-04 9.645e-05 -3.978 -4.016 -0.038 (0) + CaCO3 5.478e-06 5.488e-06 -5.261 -5.261 0.001 (0) + CO3-2 2.740e-06 1.935e-06 -5.562 -5.713 -0.151 -3.62 +Ca 2.502e-03 + Ca+2 2.391e-03 1.688e-03 -2.621 -2.773 -0.151 -17.67 + CaHCO3+ 1.052e-04 9.645e-05 -3.978 -4.016 -0.038 (0) + CaCO3 5.478e-06 5.488e-06 -5.261 -5.261 0.001 (0) + CaOH+ 2.823e-09 2.581e-09 -8.549 -8.588 -0.039 (0) +H(0) 1.836e-10 + H2 9.178e-11 9.194e-11 -10.037 -10.037 0.001 (0) +N(-3) 2.695e-06 + NH4+ 2.682e-06 2.442e-06 -5.572 -5.612 -0.041 (0) + NH3 1.280e-08 1.282e-08 -7.893 -7.892 0.001 (0) +N(0) 3.893e-08 + N2 1.947e-08 1.950e-08 -7.711 -7.710 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.491 -61.531 -0.040 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -83.174 -83.214 -0.040 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -72.308 -72.307 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -1834,38 +1834,38 @@ N2(g) -4.15 7.118e-05 0.000e+00 6.746e-05 6.746e-05 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.193e-07 1.101e-07 -6.923 -6.958 -0.035 - OH- 9.959e-08 9.091e-08 -7.002 -7.041 -0.040 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -C(-4) 1.525e-06 - CH4 1.525e-06 1.528e-06 -5.817 -5.816 0.001 -C(4) 6.109e-03 - HCO3- 4.888e-03 4.481e-03 -2.311 -2.349 -0.038 - CO2 1.107e-03 1.109e-03 -2.956 -2.955 0.001 - CaHCO3+ 1.053e-04 9.649e-05 -3.978 -4.016 -0.038 - CaCO3 5.403e-06 5.412e-06 -5.267 -5.267 0.001 - CO3-2 2.702e-06 1.909e-06 -5.568 -5.719 -0.151 -Ca 2.502e-03 - Ca+2 2.391e-03 1.688e-03 -2.621 -2.773 -0.151 - CaHCO3+ 1.053e-04 9.649e-05 -3.978 -4.016 -0.038 - CaCO3 5.403e-06 5.412e-06 -5.267 -5.267 0.001 - CaOH+ 2.782e-09 2.544e-09 -8.556 -8.595 -0.039 -H(0) 2.175e-10 - H2 1.087e-10 1.089e-10 -9.964 -9.963 0.001 -N(-3) 4.993e-06 - NH4+ 4.970e-06 4.526e-06 -5.304 -5.344 -0.041 - NH3 2.339e-08 2.342e-08 -7.631 -7.630 0.001 -N(0) 7.810e-08 - N2 3.905e-08 3.911e-08 -7.408 -7.408 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.456 -61.496 -0.040 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -83.214 -83.254 -0.040 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -72.455 -72.454 0.001 + H+ 1.193e-07 1.101e-07 -6.923 -6.958 -0.035 0.00 + OH- 9.959e-08 9.091e-08 -7.002 -7.041 -0.040 (0) + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +C(-4) 1.525e-06 + CH4 1.525e-06 1.528e-06 -5.817 -5.816 0.001 (0) +C(4) 6.109e-03 + HCO3- 4.888e-03 4.481e-03 -2.311 -2.349 -0.038 24.33 + CO2 1.107e-03 1.109e-03 -2.956 -2.955 0.001 (0) + CaHCO3+ 1.053e-04 9.649e-05 -3.978 -4.016 -0.038 (0) + CaCO3 5.403e-06 5.412e-06 -5.267 -5.267 0.001 (0) + CO3-2 2.702e-06 1.909e-06 -5.568 -5.719 -0.151 -3.62 +Ca 2.502e-03 + Ca+2 2.391e-03 1.688e-03 -2.621 -2.773 -0.151 -17.67 + CaHCO3+ 1.053e-04 9.649e-05 -3.978 -4.016 -0.038 (0) + CaCO3 5.403e-06 5.412e-06 -5.267 -5.267 0.001 (0) + CaOH+ 2.782e-09 2.544e-09 -8.556 -8.595 -0.039 (0) +H(0) 2.175e-10 + H2 1.087e-10 1.089e-10 -9.964 -9.963 0.001 (0) +N(-3) 4.993e-06 + NH4+ 4.970e-06 4.526e-06 -5.304 -5.344 -0.041 (0) + NH3 2.339e-08 2.342e-08 -7.631 -7.630 0.001 (0) +N(0) 7.810e-08 + N2 3.905e-08 3.911e-08 -7.408 -7.408 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.456 -61.496 -0.040 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -83.214 -83.254 -0.040 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -72.455 -72.454 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -1948,38 +1948,38 @@ N2(g) -3.97 1.069e-04 0.000e+00 1.013e-04 1.013e-04 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.210e-07 1.117e-07 -6.917 -6.952 -0.035 - OH- 9.819e-08 8.963e-08 -7.008 -7.048 -0.040 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -C(-4) 2.288e-06 - CH4 2.288e-06 2.292e-06 -5.641 -5.640 0.001 -C(4) 6.127e-03 - HCO3- 4.890e-03 4.483e-03 -2.311 -2.348 -0.038 - CO2 1.124e-03 1.126e-03 -2.949 -2.949 0.001 - CaHCO3+ 1.053e-04 9.653e-05 -3.978 -4.015 -0.038 - CaCO3 5.329e-06 5.338e-06 -5.273 -5.273 0.001 - CO3-2 2.666e-06 1.883e-06 -5.574 -5.725 -0.151 -Ca 2.502e-03 - Ca+2 2.392e-03 1.688e-03 -2.621 -2.773 -0.151 - CaHCO3+ 1.053e-04 9.653e-05 -3.978 -4.015 -0.038 - CaCO3 5.329e-06 5.338e-06 -5.273 -5.273 0.001 - CaOH+ 2.743e-09 2.508e-09 -8.562 -8.601 -0.039 -H(0) 2.398e-10 - H2 1.199e-10 1.201e-10 -9.921 -9.920 0.001 -N(-3) 7.187e-06 - NH4+ 7.153e-06 6.514e-06 -5.145 -5.186 -0.041 - NH3 3.319e-08 3.324e-08 -7.479 -7.478 0.001 -N(0) 1.173e-07 - N2 5.866e-08 5.876e-08 -7.232 -7.231 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.438 -61.478 -0.040 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -83.237 -83.278 -0.040 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -72.540 -72.539 0.001 + H+ 1.210e-07 1.117e-07 -6.917 -6.952 -0.035 0.00 + OH- 9.819e-08 8.963e-08 -7.008 -7.048 -0.040 (0) + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +C(-4) 2.288e-06 + CH4 2.288e-06 2.292e-06 -5.641 -5.640 0.001 (0) +C(4) 6.127e-03 + HCO3- 4.890e-03 4.483e-03 -2.311 -2.348 -0.038 24.33 + CO2 1.124e-03 1.126e-03 -2.949 -2.949 0.001 (0) + CaHCO3+ 1.053e-04 9.653e-05 -3.978 -4.015 -0.038 (0) + CaCO3 5.329e-06 5.338e-06 -5.273 -5.273 0.001 (0) + CO3-2 2.666e-06 1.883e-06 -5.574 -5.725 -0.151 -3.62 +Ca 2.502e-03 + Ca+2 2.392e-03 1.688e-03 -2.621 -2.773 -0.151 -17.67 + CaHCO3+ 1.053e-04 9.653e-05 -3.978 -4.015 -0.038 (0) + CaCO3 5.329e-06 5.338e-06 -5.273 -5.273 0.001 (0) + CaOH+ 2.743e-09 2.508e-09 -8.562 -8.601 -0.039 (0) +H(0) 2.398e-10 + H2 1.199e-10 1.201e-10 -9.921 -9.920 0.001 (0) +N(-3) 7.187e-06 + NH4+ 7.153e-06 6.514e-06 -5.145 -5.186 -0.041 (0) + NH3 3.319e-08 3.324e-08 -7.479 -7.478 0.001 (0) +N(0) 1.173e-07 + N2 5.866e-08 5.876e-08 -7.232 -7.231 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.438 -61.478 -0.040 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -83.237 -83.278 -0.040 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -72.540 -72.539 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -2062,38 +2062,38 @@ N2(g) -3.85 1.427e-04 0.000e+00 1.353e-04 1.353e-04 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.227e-07 1.132e-07 -6.911 -6.946 -0.035 - OH- 9.683e-08 8.839e-08 -7.014 -7.054 -0.040 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -C(-4) 3.051e-06 - CH4 3.051e-06 3.056e-06 -5.516 -5.515 0.001 -C(4) 6.146e-03 - HCO3- 4.892e-03 4.485e-03 -2.310 -2.348 -0.038 - CO2 1.140e-03 1.142e-03 -2.943 -2.942 0.001 - CaHCO3+ 1.053e-04 9.657e-05 -3.977 -4.015 -0.038 - CaCO3 5.257e-06 5.266e-06 -5.279 -5.279 0.001 - CO3-2 2.630e-06 1.857e-06 -5.580 -5.731 -0.151 -Ca 2.502e-03 - Ca+2 2.392e-03 1.688e-03 -2.621 -2.773 -0.151 - CaHCO3+ 1.053e-04 9.657e-05 -3.977 -4.015 -0.038 - CaCO3 5.257e-06 5.266e-06 -5.279 -5.279 0.001 - CaOH+ 2.705e-09 2.473e-09 -8.568 -8.607 -0.039 -H(0) 2.568e-10 - H2 1.284e-10 1.286e-10 -9.891 -9.891 0.001 -N(-3) 9.327e-06 - NH4+ 9.285e-06 8.455e-06 -5.032 -5.073 -0.041 - NH3 4.248e-08 4.255e-08 -7.372 -7.371 0.001 -N(0) 1.566e-07 - N2 7.829e-08 7.842e-08 -7.106 -7.106 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.426 -61.466 -0.040 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -83.255 -83.295 -0.040 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -72.599 -72.599 0.001 + H+ 1.227e-07 1.132e-07 -6.911 -6.946 -0.035 0.00 + OH- 9.683e-08 8.839e-08 -7.014 -7.054 -0.040 (0) + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +C(-4) 3.051e-06 + CH4 3.051e-06 3.056e-06 -5.516 -5.515 0.001 (0) +C(4) 6.146e-03 + HCO3- 4.892e-03 4.485e-03 -2.310 -2.348 -0.038 24.33 + CO2 1.140e-03 1.142e-03 -2.943 -2.942 0.001 (0) + CaHCO3+ 1.053e-04 9.657e-05 -3.977 -4.015 -0.038 (0) + CaCO3 5.257e-06 5.266e-06 -5.279 -5.279 0.001 (0) + CO3-2 2.630e-06 1.857e-06 -5.580 -5.731 -0.151 -3.62 +Ca 2.502e-03 + Ca+2 2.392e-03 1.688e-03 -2.621 -2.773 -0.151 -17.67 + CaHCO3+ 1.053e-04 9.657e-05 -3.977 -4.015 -0.038 (0) + CaCO3 5.257e-06 5.266e-06 -5.279 -5.279 0.001 (0) + CaOH+ 2.705e-09 2.473e-09 -8.568 -8.607 -0.039 (0) +H(0) 2.568e-10 + H2 1.284e-10 1.286e-10 -9.891 -9.891 0.001 (0) +N(-3) 9.327e-06 + NH4+ 9.285e-06 8.455e-06 -5.032 -5.073 -0.041 (0) + NH3 4.248e-08 4.255e-08 -7.372 -7.371 0.001 (0) +N(0) 1.566e-07 + N2 7.829e-08 7.842e-08 -7.106 -7.106 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.426 -61.466 -0.040 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -83.255 -83.295 -0.040 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -72.599 -72.599 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -2176,38 +2176,38 @@ N2(g) -3.54 2.859e-04 0.000e+00 2.710e-04 2.710e-04 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.295e-07 1.195e-07 -6.888 -6.923 -0.035 - OH- 9.174e-08 8.374e-08 -7.037 -7.077 -0.040 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -C(-4) 6.102e-06 - CH4 6.102e-06 6.113e-06 -5.214 -5.214 0.001 -C(4) 6.220e-03 - HCO3- 4.901e-03 4.493e-03 -2.310 -2.347 -0.038 - CO2 1.206e-03 1.208e-03 -2.919 -2.918 0.001 - CaHCO3+ 1.055e-04 9.673e-05 -3.977 -4.014 -0.038 - CaCO3 4.989e-06 4.997e-06 -5.302 -5.301 0.001 - CO3-2 2.497e-06 1.763e-06 -5.603 -5.754 -0.151 -Ca 2.502e-03 - Ca+2 2.392e-03 1.687e-03 -2.621 -2.773 -0.151 - CaHCO3+ 1.055e-04 9.673e-05 -3.977 -4.014 -0.038 - CaCO3 4.989e-06 4.997e-06 -5.302 -5.301 0.001 - CaOH+ 2.563e-09 2.343e-09 -8.591 -8.630 -0.039 -H(0) 3.011e-10 - H2 1.506e-10 1.508e-10 -9.822 -9.822 0.001 -N(-3) 1.769e-05 - NH4+ 1.762e-05 1.604e-05 -4.754 -4.795 -0.041 - NH3 7.636e-08 7.649e-08 -7.117 -7.116 0.001 -N(0) 3.137e-07 - N2 1.569e-07 1.571e-07 -6.805 -6.804 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.402 -61.442 -0.040 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -83.301 -83.341 -0.040 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -72.738 -72.737 0.001 + H+ 1.295e-07 1.195e-07 -6.888 -6.923 -0.035 0.00 + OH- 9.174e-08 8.374e-08 -7.037 -7.077 -0.040 (0) + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +C(-4) 6.102e-06 + CH4 6.102e-06 6.113e-06 -5.214 -5.214 0.001 (0) +C(4) 6.220e-03 + HCO3- 4.901e-03 4.493e-03 -2.310 -2.347 -0.038 24.33 + CO2 1.206e-03 1.208e-03 -2.919 -2.918 0.001 (0) + CaHCO3+ 1.055e-04 9.673e-05 -3.977 -4.014 -0.038 (0) + CaCO3 4.989e-06 4.997e-06 -5.302 -5.301 0.001 (0) + CO3-2 2.497e-06 1.763e-06 -5.603 -5.754 -0.151 -3.62 +Ca 2.502e-03 + Ca+2 2.392e-03 1.687e-03 -2.621 -2.773 -0.151 -17.67 + CaHCO3+ 1.055e-04 9.673e-05 -3.977 -4.014 -0.038 (0) + CaCO3 4.989e-06 4.997e-06 -5.302 -5.301 0.001 (0) + CaOH+ 2.563e-09 2.343e-09 -8.591 -8.630 -0.039 (0) +H(0) 3.011e-10 + H2 1.506e-10 1.508e-10 -9.822 -9.822 0.001 (0) +N(-3) 1.769e-05 + NH4+ 1.762e-05 1.604e-05 -4.754 -4.795 -0.041 (0) + NH3 7.636e-08 7.649e-08 -7.117 -7.116 0.001 (0) +N(0) 3.137e-07 + N2 1.569e-07 1.571e-07 -6.805 -6.804 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.402 -61.442 -0.040 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -83.301 -83.341 -0.040 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -72.738 -72.737 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -2290,38 +2290,38 @@ N2(g) -3.24 5.723e-04 0.000e+00 5.424e-04 5.424e-04 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.430e-07 1.320e-07 -6.845 -6.879 -0.035 - OH- 8.306e-08 7.581e-08 -7.081 -7.120 -0.040 - H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 -C(-4) 1.221e-05 - CH4 1.221e-05 1.223e-05 -4.913 -4.913 0.001 -C(4) 6.368e-03 - HCO3- 4.919e-03 4.509e-03 -2.308 -2.346 -0.038 - CO2 1.336e-03 1.339e-03 -2.874 -2.873 0.001 - CaHCO3+ 1.059e-04 9.704e-05 -3.975 -4.013 -0.038 - CaCO3 4.531e-06 4.539e-06 -5.344 -5.343 0.001 - CO3-2 2.269e-06 1.602e-06 -5.644 -5.795 -0.151 -Ca 2.502e-03 - Ca+2 2.392e-03 1.687e-03 -2.621 -2.773 -0.152 - CaHCO3+ 1.059e-04 9.704e-05 -3.975 -4.013 -0.038 - CaCO3 4.531e-06 4.539e-06 -5.344 -5.343 0.001 - CaOH+ 2.319e-09 2.120e-09 -8.635 -8.674 -0.039 -H(0) 3.490e-10 - H2 1.745e-10 1.748e-10 -9.758 -9.757 0.001 -N(-3) 3.449e-05 - NH4+ 3.436e-05 3.128e-05 -4.464 -4.505 -0.041 - NH3 1.348e-07 1.350e-07 -6.870 -6.870 0.001 -N(0) 6.279e-07 - N2 3.140e-07 3.145e-07 -6.503 -6.502 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.391 -61.431 -0.040 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -83.353 -83.393 -0.040 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -72.866 -72.865 0.001 + H+ 1.430e-07 1.320e-07 -6.845 -6.879 -0.035 0.00 + OH- 8.306e-08 7.581e-08 -7.081 -7.120 -0.040 (0) + H2O 5.551e+01 9.999e-01 1.744 -0.000 0.000 18.07 +C(-4) 1.221e-05 + CH4 1.221e-05 1.223e-05 -4.913 -4.913 0.001 (0) +C(4) 6.368e-03 + HCO3- 4.919e-03 4.509e-03 -2.308 -2.346 -0.038 24.33 + CO2 1.336e-03 1.339e-03 -2.874 -2.873 0.001 (0) + CaHCO3+ 1.059e-04 9.704e-05 -3.975 -4.013 -0.038 (0) + CaCO3 4.531e-06 4.539e-06 -5.344 -5.343 0.001 (0) + CO3-2 2.269e-06 1.602e-06 -5.644 -5.795 -0.151 -3.62 +Ca 2.502e-03 + Ca+2 2.392e-03 1.687e-03 -2.621 -2.773 -0.152 -17.67 + CaHCO3+ 1.059e-04 9.704e-05 -3.975 -4.013 -0.038 (0) + CaCO3 4.531e-06 4.539e-06 -5.344 -5.343 0.001 (0) + CaOH+ 2.319e-09 2.120e-09 -8.635 -8.674 -0.039 (0) +H(0) 3.490e-10 + H2 1.745e-10 1.748e-10 -9.758 -9.757 0.001 (0) +N(-3) 3.449e-05 + NH4+ 3.436e-05 3.128e-05 -4.464 -4.505 -0.041 (0) + NH3 1.348e-07 1.350e-07 -6.870 -6.870 0.001 (0) +N(0) 6.279e-07 + N2 3.140e-07 3.145e-07 -6.503 -6.502 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.391 -61.431 -0.040 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -83.353 -83.393 -0.040 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -72.866 -72.865 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -2404,38 +2404,38 @@ N2(g) -2.94 1.144e-03 0.000e+00 1.084e-03 1.084e-03 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.698e-07 1.567e-07 -6.770 -6.805 -0.035 - OH- 6.999e-08 6.386e-08 -7.155 -7.195 -0.040 - H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 -C(-4) 2.441e-05 - CH4 2.441e-05 2.445e-05 -4.612 -4.612 0.001 -C(4) 6.666e-03 - HCO3- 4.956e-03 4.542e-03 -2.305 -2.343 -0.038 - CO2 1.598e-03 1.601e-03 -2.796 -2.796 0.001 - CaHCO3+ 1.066e-04 9.768e-05 -3.972 -4.010 -0.038 - CaCO3 3.842e-06 3.848e-06 -5.415 -5.415 0.001 - CO3-2 1.927e-06 1.359e-06 -5.715 -5.867 -0.152 -Ca 2.502e-03 - Ca+2 2.392e-03 1.686e-03 -2.621 -2.773 -0.152 - CaHCO3+ 1.066e-04 9.768e-05 -3.972 -4.010 -0.038 - CaCO3 3.842e-06 3.848e-06 -5.415 -5.415 0.001 - CaOH+ 1.953e-09 1.785e-09 -8.709 -8.748 -0.039 -H(0) 3.969e-10 - H2 1.985e-10 1.988e-10 -9.702 -9.702 0.001 -N(-3) 7.017e-05 - NH4+ 6.994e-05 6.367e-05 -4.155 -4.196 -0.041 - NH3 2.311e-07 2.315e-07 -6.636 -6.635 0.001 -N(0) 1.255e-06 - N2 6.276e-07 6.286e-07 -6.202 -6.202 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.398 -61.439 -0.040 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -83.417 -83.457 -0.040 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -72.978 -72.977 0.001 + H+ 1.698e-07 1.567e-07 -6.770 -6.805 -0.035 0.00 + OH- 6.999e-08 6.386e-08 -7.155 -7.195 -0.040 (0) + H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 18.07 +C(-4) 2.441e-05 + CH4 2.441e-05 2.445e-05 -4.612 -4.612 0.001 (0) +C(4) 6.666e-03 + HCO3- 4.956e-03 4.542e-03 -2.305 -2.343 -0.038 24.33 + CO2 1.598e-03 1.601e-03 -2.796 -2.796 0.001 (0) + CaHCO3+ 1.066e-04 9.768e-05 -3.972 -4.010 -0.038 (0) + CaCO3 3.842e-06 3.848e-06 -5.415 -5.415 0.001 (0) + CO3-2 1.927e-06 1.359e-06 -5.715 -5.867 -0.152 -3.62 +Ca 2.502e-03 + Ca+2 2.392e-03 1.686e-03 -2.621 -2.773 -0.152 -17.67 + CaHCO3+ 1.066e-04 9.768e-05 -3.972 -4.010 -0.038 (0) + CaCO3 3.842e-06 3.848e-06 -5.415 -5.415 0.001 (0) + CaOH+ 1.953e-09 1.785e-09 -8.709 -8.748 -0.039 (0) +H(0) 3.969e-10 + H2 1.985e-10 1.988e-10 -9.702 -9.702 0.001 (0) +N(-3) 7.017e-05 + NH4+ 6.994e-05 6.367e-05 -4.155 -4.196 -0.041 (0) + NH3 2.311e-07 2.315e-07 -6.636 -6.635 0.001 (0) +N(0) 1.255e-06 + N2 6.276e-07 6.286e-07 -6.202 -6.202 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.398 -61.439 -0.040 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -83.417 -83.457 -0.040 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -72.978 -72.977 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -2518,38 +2518,38 @@ N2(g) -2.64 2.282e-03 0.000e+00 2.163e-03 2.163e-03 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 2.219e-07 2.047e-07 -6.654 -6.689 -0.035 - OH- 5.360e-08 4.889e-08 -7.271 -7.311 -0.040 - H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 -C(-4) 4.881e-05 - CH4 4.881e-05 4.890e-05 -4.311 -4.311 0.001 -C(4) 7.271e-03 - HCO3- 5.038e-03 4.615e-03 -2.298 -2.336 -0.038 - CO2 2.121e-03 2.125e-03 -2.673 -2.673 0.001 - CaHCO3+ 1.081e-04 9.905e-05 -3.966 -4.004 -0.038 - CaCO3 2.982e-06 2.987e-06 -5.525 -5.525 0.001 - CO3-2 1.501e-06 1.057e-06 -5.824 -5.976 -0.152 -Ca 2.502e-03 - Ca+2 2.391e-03 1.682e-03 -2.621 -2.774 -0.153 - CaHCO3+ 1.081e-04 9.905e-05 -3.966 -4.004 -0.038 - CaCO3 2.982e-06 2.987e-06 -5.525 -5.525 0.001 - CaOH+ 1.493e-09 1.364e-09 -8.826 -8.865 -0.039 -H(0) 4.397e-10 - H2 2.199e-10 2.202e-10 -9.658 -9.657 0.001 -N(-3) 1.509e-04 - NH4+ 1.506e-04 1.370e-04 -3.822 -3.863 -0.041 - NH3 3.807e-07 3.813e-07 -6.419 -6.419 0.001 -N(0) 2.504e-06 - N2 1.252e-06 1.254e-06 -5.902 -5.902 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.431 -61.471 -0.040 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -83.494 -83.534 -0.040 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -73.067 -73.066 0.001 + H+ 2.219e-07 2.047e-07 -6.654 -6.689 -0.035 0.00 + OH- 5.360e-08 4.889e-08 -7.271 -7.311 -0.040 (0) + H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 18.07 +C(-4) 4.881e-05 + CH4 4.881e-05 4.890e-05 -4.311 -4.311 0.001 (0) +C(4) 7.271e-03 + HCO3- 5.038e-03 4.615e-03 -2.298 -2.336 -0.038 24.33 + CO2 2.121e-03 2.125e-03 -2.673 -2.673 0.001 (0) + CaHCO3+ 1.081e-04 9.905e-05 -3.966 -4.004 -0.038 (0) + CaCO3 2.982e-06 2.987e-06 -5.525 -5.525 0.001 (0) + CO3-2 1.501e-06 1.057e-06 -5.824 -5.976 -0.152 -3.62 +Ca 2.502e-03 + Ca+2 2.391e-03 1.682e-03 -2.621 -2.774 -0.153 -17.67 + CaHCO3+ 1.081e-04 9.905e-05 -3.966 -4.004 -0.038 (0) + CaCO3 2.982e-06 2.987e-06 -5.525 -5.525 0.001 (0) + CaOH+ 1.493e-09 1.364e-09 -8.826 -8.865 -0.039 (0) +H(0) 4.397e-10 + H2 2.199e-10 2.202e-10 -9.658 -9.657 0.001 (0) +N(-3) 1.509e-04 + NH4+ 1.506e-04 1.370e-04 -3.822 -3.863 -0.041 (0) + NH3 3.807e-07 3.813e-07 -6.419 -6.419 0.001 (0) +N(0) 2.504e-06 + N2 1.252e-06 1.254e-06 -5.902 -5.902 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.431 -61.471 -0.040 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -83.494 -83.534 -0.040 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -73.067 -73.066 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -2632,38 +2632,38 @@ N2(g) -2.35 4.438e-03 0.000e+00 4.206e-03 4.206e-03 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 3.154e-07 2.908e-07 -6.501 -6.536 -0.035 - OH- 3.778e-08 3.442e-08 -7.423 -7.463 -0.040 - H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 -C(-4) 9.531e-05 - CH4 9.531e-05 9.548e-05 -4.021 -4.020 0.001 -C(4) 8.450e-03 - HCO3- 5.218e-03 4.776e-03 -2.282 -2.321 -0.038 - CO2 3.117e-03 3.123e-03 -2.506 -2.505 0.001 - CaHCO3+ 1.115e-04 1.020e-04 -3.953 -3.991 -0.038 - CaCO3 2.163e-06 2.167e-06 -5.665 -5.664 0.001 - CO3-2 1.098e-06 7.703e-07 -5.959 -6.113 -0.154 -Ca 2.502e-03 - Ca+2 2.388e-03 1.674e-03 -2.622 -2.776 -0.154 - CaHCO3+ 1.115e-04 1.020e-04 -3.953 -3.991 -0.038 - CaCO3 2.163e-06 2.167e-06 -5.665 -5.664 0.001 - CaOH+ 1.047e-09 9.555e-10 -8.980 -9.020 -0.040 -H(0) 4.721e-10 - H2 2.360e-10 2.364e-10 -9.627 -9.626 0.001 -N(-3) 3.326e-04 - NH4+ 3.320e-04 3.018e-04 -3.479 -3.520 -0.041 - NH3 5.905e-07 5.915e-07 -6.229 -6.228 0.001 -N(0) 4.869e-06 - N2 2.434e-06 2.439e-06 -5.614 -5.613 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.485 -61.526 -0.041 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -83.579 -83.620 -0.041 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -73.128 -73.128 0.001 + H+ 3.154e-07 2.908e-07 -6.501 -6.536 -0.035 0.00 + OH- 3.778e-08 3.442e-08 -7.423 -7.463 -0.040 (0) + H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 18.07 +C(-4) 9.531e-05 + CH4 9.531e-05 9.548e-05 -4.021 -4.020 0.001 (0) +C(4) 8.450e-03 + HCO3- 5.218e-03 4.776e-03 -2.282 -2.321 -0.038 24.33 + CO2 3.117e-03 3.123e-03 -2.506 -2.505 0.001 (0) + CaHCO3+ 1.115e-04 1.020e-04 -3.953 -3.991 -0.038 (0) + CaCO3 2.163e-06 2.167e-06 -5.665 -5.664 0.001 (0) + CO3-2 1.098e-06 7.703e-07 -5.959 -6.113 -0.154 -3.62 +Ca 2.502e-03 + Ca+2 2.388e-03 1.674e-03 -2.622 -2.776 -0.154 -17.67 + CaHCO3+ 1.115e-04 1.020e-04 -3.953 -3.991 -0.038 (0) + CaCO3 2.163e-06 2.167e-06 -5.665 -5.664 0.001 (0) + CaOH+ 1.047e-09 9.555e-10 -8.980 -9.020 -0.040 (0) +H(0) 4.721e-10 + H2 2.360e-10 2.364e-10 -9.627 -9.626 0.001 (0) +N(-3) 3.326e-04 + NH4+ 3.320e-04 3.018e-04 -3.479 -3.520 -0.041 (0) + NH3 5.905e-07 5.915e-07 -6.229 -6.228 0.001 (0) +N(0) 4.869e-06 + N2 2.434e-06 2.439e-06 -5.614 -5.613 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.485 -61.526 -0.041 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -83.579 -83.620 -0.041 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -73.128 -73.128 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -2746,38 +2746,38 @@ N2(g) -2.05 8.819e-03 0.000e+00 8.359e-03 8.359e-03 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 4.837e-07 4.451e-07 -6.315 -6.351 -0.036 - OH- 2.473e-08 2.248e-08 -7.607 -7.648 -0.041 - H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 -C(-4) 1.905e-04 - CH4 1.905e-04 1.909e-04 -3.720 -3.719 0.001 -C(4) 1.093e-02 - HCO3- 5.651e-03 5.161e-03 -2.248 -2.287 -0.039 - CO2 5.157e-03 5.167e-03 -2.288 -2.287 0.001 - CaHCO3+ 1.193e-04 1.090e-04 -3.923 -3.963 -0.039 - CaCO3 1.509e-06 1.512e-06 -5.821 -5.820 0.001 - CO3-2 7.815e-07 5.437e-07 -6.107 -6.265 -0.158 -Ca 2.502e-03 - Ca+2 2.381e-03 1.655e-03 -2.623 -2.781 -0.158 - CaHCO3+ 1.193e-04 1.090e-04 -3.923 -3.963 -0.039 - CaCO3 1.509e-06 1.512e-06 -5.821 -5.820 0.001 - CaOH+ 6.775e-10 6.170e-10 -9.169 -9.210 -0.041 -H(0) 4.949e-10 - H2 2.474e-10 2.479e-10 -9.607 -9.606 0.001 -N(-3) 7.721e-04 - NH4+ 7.712e-04 6.992e-04 -3.113 -3.155 -0.043 - NH3 8.935e-07 8.952e-07 -6.049 -6.048 0.001 -N(0) 9.675e-06 - N2 4.837e-06 4.846e-06 -5.315 -5.315 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.550 -61.592 -0.042 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -83.665 -83.707 -0.042 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -73.170 -73.169 0.001 + H+ 4.837e-07 4.451e-07 -6.315 -6.351 -0.036 0.00 + OH- 2.473e-08 2.248e-08 -7.607 -7.648 -0.041 (0) + H2O 5.551e+01 9.998e-01 1.744 -0.000 0.000 18.07 +C(-4) 1.905e-04 + CH4 1.905e-04 1.909e-04 -3.720 -3.719 0.001 (0) +C(4) 1.093e-02 + HCO3- 5.651e-03 5.161e-03 -2.248 -2.287 -0.039 24.33 + CO2 5.157e-03 5.167e-03 -2.288 -2.287 0.001 (0) + CaHCO3+ 1.193e-04 1.090e-04 -3.923 -3.963 -0.039 (0) + CaCO3 1.509e-06 1.512e-06 -5.821 -5.820 0.001 (0) + CO3-2 7.815e-07 5.437e-07 -6.107 -6.265 -0.158 -3.61 +Ca 2.502e-03 + Ca+2 2.381e-03 1.655e-03 -2.623 -2.781 -0.158 -17.66 + CaHCO3+ 1.193e-04 1.090e-04 -3.923 -3.963 -0.039 (0) + CaCO3 1.509e-06 1.512e-06 -5.821 -5.820 0.001 (0) + CaOH+ 6.775e-10 6.170e-10 -9.169 -9.210 -0.041 (0) +H(0) 4.949e-10 + H2 2.474e-10 2.479e-10 -9.607 -9.606 0.001 (0) +N(-3) 7.721e-04 + NH4+ 7.712e-04 6.992e-04 -3.113 -3.155 -0.043 (0) + NH3 8.935e-07 8.952e-07 -6.049 -6.048 0.001 (0) +N(0) 9.675e-06 + N2 4.837e-06 4.846e-06 -5.315 -5.315 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.550 -61.592 -0.042 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -83.665 -83.707 -0.042 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -73.170 -73.169 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -2860,38 +2860,38 @@ N2(g) -1.76 1.753e-02 0.000e+00 1.661e-02 1.661e-02 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 7.461e-07 6.841e-07 -6.127 -6.165 -0.038 - OH- 1.617e-08 1.463e-08 -7.791 -7.835 -0.044 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -C(-4) 3.809e-04 - CH4 3.809e-04 3.817e-04 -3.419 -3.418 0.001 -C(4) 1.598e-02 - CO2 9.233e-03 9.252e-03 -2.035 -2.034 0.001 - HCO3- 6.614e-03 6.013e-03 -2.180 -2.221 -0.041 - CaHCO3+ 1.362e-04 1.239e-04 -3.866 -3.907 -0.041 - CaCO3 1.116e-06 1.118e-06 -5.952 -5.952 0.001 - CO3-2 6.031e-07 4.122e-07 -6.220 -6.385 -0.165 -Ca 2.501e-03 - Ca+2 2.364e-03 1.614e-03 -2.626 -2.792 -0.166 - CaHCO3+ 1.362e-04 1.239e-04 -3.866 -3.907 -0.041 - CaCO3 1.116e-06 1.118e-06 -5.952 -5.952 0.001 - CaOH+ 4.320e-10 3.915e-10 -9.365 -9.407 -0.043 -H(0) 5.086e-10 - H2 2.543e-10 2.548e-10 -9.595 -9.594 0.001 -N(-3) 1.752e-03 - NH4+ 1.750e-03 1.579e-03 -2.757 -2.802 -0.045 - NH3 1.312e-06 1.315e-06 -5.882 -5.881 0.001 -N(0) 1.923e-05 - N2 9.613e-06 9.633e-06 -5.017 -5.016 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.604 -61.648 -0.044 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -83.730 -83.774 -0.044 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -73.194 -73.193 0.001 + H+ 7.461e-07 6.841e-07 -6.127 -6.165 -0.038 0.00 + OH- 1.617e-08 1.463e-08 -7.791 -7.835 -0.044 (0) + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.07 +C(-4) 3.809e-04 + CH4 3.809e-04 3.817e-04 -3.419 -3.418 0.001 (0) +C(4) 1.598e-02 + CO2 9.233e-03 9.252e-03 -2.035 -2.034 0.001 (0) + HCO3- 6.614e-03 6.013e-03 -2.180 -2.221 -0.041 24.33 + CaHCO3+ 1.362e-04 1.239e-04 -3.866 -3.907 -0.041 (0) + CaCO3 1.116e-06 1.118e-06 -5.952 -5.952 0.001 (0) + CO3-2 6.031e-07 4.122e-07 -6.220 -6.385 -0.165 -3.60 +Ca 2.501e-03 + Ca+2 2.364e-03 1.614e-03 -2.626 -2.792 -0.166 -17.65 + CaHCO3+ 1.362e-04 1.239e-04 -3.866 -3.907 -0.041 (0) + CaCO3 1.116e-06 1.118e-06 -5.952 -5.952 0.001 (0) + CaOH+ 4.320e-10 3.915e-10 -9.365 -9.407 -0.043 (0) +H(0) 5.086e-10 + H2 2.543e-10 2.548e-10 -9.595 -9.594 0.001 (0) +N(-3) 1.752e-03 + NH4+ 1.750e-03 1.579e-03 -2.757 -2.802 -0.045 (0) + NH3 1.312e-06 1.315e-06 -5.882 -5.881 0.001 (0) +N(0) 1.923e-05 + N2 9.613e-06 9.633e-06 -5.017 -5.016 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.604 -61.648 -0.044 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -83.730 -83.774 -0.044 29.03 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -73.194 -73.193 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -2942,7 +2942,7 @@ Component log P P Initial Final Delta CH4(g) -0.26 5.529e-01 1.371e-21 5.241e-01 5.241e-01 CO2(g) -0.29 5.117e-01 2.997e-02 4.851e-01 4.551e-01 -H2O(g) -1.51 3.089e-02 2.929e-02 2.927e-02 -1.220e-05 +H2O(g) -1.51 3.089e-02 2.929e-02 2.928e-02 -9.211e-06 N2(g) -1.46 3.493e-02 0.000e+00 3.311e-02 3.311e-02 -----------------------------Solution composition------------------------------ @@ -2974,53 +2974,53 @@ N2(g) -1.46 3.493e-02 0.000e+00 3.311e-02 3.311e-02 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.101e-06 1.002e-06 -5.958 -5.999 -0.041 - OH- 1.114e-08 9.982e-09 -7.953 -8.001 -0.047 - H2O 5.551e+01 9.994e-01 1.744 -0.000 0.000 -C(-4) 7.616e-04 - CH4 7.616e-04 7.635e-04 -3.118 -3.117 0.001 -C(4) 2.612e-02 - CO2 1.738e-02 1.742e-02 -1.760 -1.759 0.001 - HCO3- 8.568e-03 7.727e-03 -2.067 -2.112 -0.045 - CaHCO3+ 1.684e-04 1.519e-04 -3.774 -3.818 -0.045 - CaCO3 9.336e-07 9.359e-07 -6.030 -6.029 0.001 - CO3-2 5.466e-07 3.616e-07 -6.262 -6.442 -0.179 -Ca 2.500e-03 - Ca+2 2.331e-03 1.541e-03 -2.633 -2.812 -0.180 - CaHCO3+ 1.684e-04 1.519e-04 -3.774 -3.818 -0.045 - CaCO3 9.336e-07 9.359e-07 -6.030 -6.029 0.001 - CaOH+ 2.838e-10 2.550e-10 -9.547 -9.594 -0.046 -H(0) 5.160e-10 - H2 2.580e-10 2.587e-10 -9.588 -9.587 0.001 -N(-3) 3.740e-03 - NH4+ 3.738e-03 3.339e-03 -2.427 -2.476 -0.049 - NH3 1.894e-06 1.899e-06 -5.723 -5.722 0.001 -N(0) 3.830e-05 - N2 1.915e-05 1.920e-05 -4.718 -4.717 0.001 -N(3) 0.000e+00 - NO2- 0.000e+00 0.000e+00 -61.626 -61.674 -0.048 -N(5) 0.000e+00 - NO3- 0.000e+00 0.000e+00 -83.759 -83.807 -0.048 -O(0) 0.000e+00 - O2 0.000e+00 0.000e+00 -73.207 -73.206 0.001 + H+ 1.101e-06 1.002e-06 -5.958 -5.999 -0.041 0.00 + OH- 1.114e-08 9.982e-09 -7.953 -8.001 -0.047 (0) + H2O 5.551e+01 9.994e-01 1.744 -0.000 0.000 18.07 +C(-4) 7.616e-04 + CH4 7.616e-04 7.635e-04 -3.118 -3.117 0.001 (0) +C(4) 2.612e-02 + CO2 1.738e-02 1.742e-02 -1.760 -1.759 0.001 (0) + HCO3- 8.568e-03 7.727e-03 -2.067 -2.112 -0.045 24.34 + CaHCO3+ 1.684e-04 1.519e-04 -3.774 -3.818 -0.045 (0) + CaCO3 9.336e-07 9.359e-07 -6.030 -6.029 0.001 (0) + CO3-2 5.466e-07 3.616e-07 -6.262 -6.442 -0.179 -3.59 +Ca 2.500e-03 + Ca+2 2.331e-03 1.541e-03 -2.633 -2.812 -0.180 -17.64 + CaHCO3+ 1.684e-04 1.519e-04 -3.774 -3.818 -0.045 (0) + CaCO3 9.336e-07 9.359e-07 -6.030 -6.029 0.001 (0) + CaOH+ 2.838e-10 2.550e-10 -9.547 -9.594 -0.046 (0) +H(0) 5.160e-10 + H2 2.580e-10 2.587e-10 -9.588 -9.587 0.001 (0) +N(-3) 3.740e-03 + NH4+ 3.738e-03 3.339e-03 -2.427 -2.476 -0.049 (0) + NH3 1.894e-06 1.899e-06 -5.723 -5.722 0.001 (0) +N(0) 3.830e-05 + N2 1.915e-05 1.920e-05 -4.718 -4.717 0.001 (0) +N(3) 0.000e+00 + NO2- 0.000e+00 0.000e+00 -61.626 -61.674 -0.048 (0) +N(5) 0.000e+00 + NO3- 0.000e+00 0.000e+00 -83.759 -83.807 -0.048 29.04 +O(0) 0.000e+00 + O2 0.000e+00 0.000e+00 -73.207 -73.206 0.001 (0) ------------------------------Saturation indices------------------------------- Phase SI log IAP log K(298 K, 1 atm) - Aragonite -0.92* -9.25 -8.34 CaCO3 Delta_V -21.22 cm3/mol - Calcite -0.77* -9.25 -8.48 CaCO3 Delta_V -21.22 cm3/mol - CH4(g) -0.26* -3.12 -2.86 CH4 Delta_V -57.79 cm3/mol - CO2(g) -0.29* -1.76 -1.47 CO2 Delta_V -21.65 cm3/mol + Aragonite -0.92 -9.25 -8.34 CaCO3 + Calcite -0.77 -9.25 -8.48 CaCO3 + CH4(g) -0.26 -3.12 -2.86 CH4 + CO2(g) -0.29 -1.76 -1.47 CO2 H2(g) -6.44 -9.59 -3.15 H2 H2O(g) -1.51 -0.00 1.51 H2O N2(g) -1.46 -4.72 -3.26 N2 NH3(g) -7.49 -5.72 1.77 NH3 - O2(g) -70.31* -73.21 -2.89 O2 Delta_V 36.14 cm3/mol - * with Delta_V * (P - 1) / 2.3RT. + O2(g) -70.31 -73.21 -2.89 O2 + ------------------ End of simulation. diff --git a/ex7.sel b/ex7.sel index 329371ba..7e307a70 100644 --- a/ex7.sel +++ b/ex7.sel @@ -1,28 +1,28 @@ sim state reaction si_CO2(g) si_CH4(g) si_N2(g) si_NH3(g) pressure total mol volume g_CO2(g) g_CH4(g) g_N2(g) g_NH3(g) 1 i_soln -99 -999.9990 -999.9990 -999.9990 -999.9990 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 1 react -99 -1.5000 -20.8396 -999.9990 -999.9990 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 - 2 react 1.0000e-03 -1.3544 -0.4403 -3.8960 -8.3808 1.1000e+00 1.0000e-25 2.2242e-24 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 - 2 react 2.0000e-03 -1.2454 -0.1393 -3.6435 -8.1826 1.1000e+00 1.0000e-25 2.2242e-24 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 - 2 react 3.0000e-03 -1.1598 -0.0002 -3.4911 -8.0863 1.1000e+00 1.3481e-04 2.9985e-03 8.4834e-06 1.2250e-04 3.9560e-08 0.0000e+00 - 2 react 4.0000e-03 -1.0937 -0.0052 -3.3105 -8.0227 1.1000e+00 7.1109e-04 1.5816e-02 5.2096e-05 6.3870e-04 3.1624e-07 0.0000e+00 - 2 react 8.0000e-03 -0.9117 -0.0244 -2.8894 -7.8876 1.1000e+00 3.1426e-03 6.9898e-02 3.5011e-04 2.7006e-03 3.6855e-06 0.0000e+00 - 2 react 1.6000e-02 -0.7187 -0.0582 -2.4625 -7.7592 1.1000e+00 8.5740e-03 1.9070e-01 1.4898e-03 6.8165e-03 2.6873e-05 0.0000e+00 - 2 react 3.2000e-02 -0.5494 -0.1092 -2.0389 -7.6301 1.1000e+00 2.1308e-02 4.7393e-01 5.4673e-03 1.5065e-02 1.7711e-04 0.0000e+00 - 2 react 6.4000e-02 -0.4332 -0.1665 -1.7268 -7.5391 1.1000e+00 5.1201e-02 1.1388e+00 1.7166e-02 3.1724e-02 8.7312e-04 0.0000e+00 - 2 react 1.2500e-01 -0.3717 -0.2093 -1.5737 -7.5017 1.1000e+00 1.1352e-01 2.5248e+00 4.3848e-02 6.3726e-02 2.7539e-03 0.0000e+00 - 2 react 2.5000e-01 -0.3402 -0.2359 -1.5030 -7.4881 1.1000e+00 2.4517e-01 5.4531e+00 1.0182e-01 1.2946e-01 7.0001e-03 0.0000e+00 - 2 react 5.0000e-01 -0.3250 -0.2501 -1.4711 -7.4832 1.1000e+00 5.1067e-01 1.1358e+01 2.1963e-01 2.6101e-01 1.5690e-02 0.0000e+00 - 2 react 1.0000e+00 -0.3176 -0.2574 -1.4562 -7.4812 1.1000e+00 1.0428e+00 2.3193e+01 4.5619e-01 5.2412e-01 3.3161e-02 0.0000e+00 + 2 react 1.0000e-03 -1.3544 -0.4403 -3.8960 -8.3808 1.1000e+00 1.0000e-25 3.0000e-27 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 + 2 react 2.0000e-03 -1.2454 -0.1393 -3.6435 -8.1826 1.1000e+00 1.0000e-25 3.0000e-27 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 + 2 react 3.0000e-03 -1.1598 -0.0002 -3.4911 -8.0863 1.1000e+00 1.3482e-04 4.0445e-06 8.4836e-06 1.2251e-04 3.9562e-08 0.0000e+00 + 2 react 4.0000e-03 -1.0937 -0.0052 -3.3105 -8.0227 1.1000e+00 7.1109e-04 2.1333e-05 5.2097e-05 6.3871e-04 3.1624e-07 0.0000e+00 + 2 react 8.0000e-03 -0.9117 -0.0244 -2.8894 -7.8876 1.1000e+00 3.1427e-03 9.4280e-05 3.5011e-04 2.7006e-03 3.6855e-06 0.0000e+00 + 2 react 1.6000e-02 -0.7187 -0.0582 -2.4625 -7.7592 1.1000e+00 8.5740e-03 2.5722e-04 1.4898e-03 6.8165e-03 2.6873e-05 0.0000e+00 + 2 react 3.2000e-02 -0.5494 -0.1092 -2.0389 -7.6301 1.1000e+00 2.1308e-02 6.3924e-04 5.4673e-03 1.5065e-02 1.7711e-04 0.0000e+00 + 2 react 6.4000e-02 -0.4332 -0.1665 -1.7268 -7.5391 1.1000e+00 5.1201e-02 1.5360e-03 1.7166e-02 3.1724e-02 8.7312e-04 0.0000e+00 + 2 react 1.2500e-01 -0.3717 -0.2093 -1.5737 -7.5017 1.1000e+00 1.1352e-01 3.4055e-03 4.3848e-02 6.3726e-02 2.7539e-03 0.0000e+00 + 2 react 2.5000e-01 -0.3402 -0.2359 -1.5030 -7.4881 1.1000e+00 2.4517e-01 7.3552e-03 1.0182e-01 1.2946e-01 7.0001e-03 0.0000e+00 + 2 react 5.0000e-01 -0.3250 -0.2501 -1.4711 -7.4832 1.1000e+00 5.1067e-01 1.5320e-02 2.1963e-01 2.6101e-01 1.5690e-02 0.0000e+00 + 2 react 1.0000e+00 -0.3176 -0.2574 -1.4562 -7.4812 1.1000e+00 1.0428e+00 3.1283e-02 4.5619e-01 5.2412e-01 3.3161e-02 0.0000e+00 3 i_gas -99 -1.5000 -20.8396 -999.9990 -999.9990 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 - 3 react 1.0000e-03 -1.4934 -3.2570 -4.4500 -9.6620 6.3591e-02 6.0274e-02 2.3190e+01 3.0429e-02 5.2448e-04 3.3633e-05 0.0000e+00 - 3 react 2.0000e-03 -1.4870 -2.9559 -4.1477 -9.4003 6.4661e-02 6.1288e-02 2.3190e+01 3.0885e-02 1.0491e-03 6.7465e-05 0.0000e+00 - 3 react 3.0000e-03 -1.4806 -2.7798 -3.9709 -9.2483 6.5731e-02 6.2303e-02 2.3190e+01 3.1341e-02 1.5738e-03 1.0135e-04 0.0000e+00 - 3 react 4.0000e-03 -1.4744 -2.6548 -3.8456 -9.1411 6.6802e-02 6.3317e-02 2.3190e+01 3.1797e-02 2.0985e-03 1.3526e-04 0.0000e+00 - 3 react 8.0000e-03 -1.4501 -2.3538 -3.5438 -8.8864 7.1083e-02 6.7376e-02 2.3190e+01 3.3621e-02 4.1973e-03 2.7100e-04 0.0000e+00 - 3 react 1.6000e-02 -1.4054 -2.0527 -3.2424 -8.6396 7.9647e-02 7.5493e-02 2.3190e+01 3.7269e-02 8.3949e-03 5.4244e-04 0.0000e+00 - 3 react 3.2000e-02 -1.3278 -1.7517 -2.9416 -8.4054 9.6771e-02 9.1724e-02 2.3190e+01 4.4564e-02 1.6789e-02 1.0843e-03 0.0000e+00 - 3 react 6.4000e-02 -1.2048 -1.4507 -2.6416 -8.1887 1.3101e-01 1.2417e-01 2.3190e+01 5.9149e-02 3.3575e-02 2.1633e-03 0.0000e+00 - 3 react 1.2500e-01 -1.0375 -1.1601 -2.3528 -7.9980 1.9622e-01 1.8599e-01 2.3190e+01 8.6937e-02 6.5561e-02 4.2062e-03 0.0000e+00 - 3 react 2.5000e-01 -0.8189 -0.8592 -2.0546 -7.8181 3.2976e-01 3.1256e-01 2.3190e+01 1.4384e-01 1.3108e-01 8.3591e-03 0.0000e+00 - 3 react 5.0000e-01 -0.5658 -0.5583 -1.7563 -7.6510 5.9669e-01 5.6557e-01 2.3190e+01 2.5759e-01 2.6209e-01 1.6614e-02 0.0000e+00 - 3 react 1.0000e+00 -0.2909 -0.2573 -1.4568 -7.4915 1.1305e+00 1.0715e+00 2.3190e+01 4.8506e-01 5.2408e-01 3.3109e-02 0.0000e+00 + 3 react 1.0000e-03 -1.4934 -3.2570 -4.4500 -9.6620 6.3591e-02 6.0274e-02 1.8082e-03 3.0429e-02 5.2448e-04 3.3633e-05 0.0000e+00 + 3 react 2.0000e-03 -1.4870 -2.9559 -4.1477 -9.4003 6.4661e-02 6.1288e-02 1.8387e-03 3.0885e-02 1.0491e-03 6.7465e-05 0.0000e+00 + 3 react 3.0000e-03 -1.4806 -2.7798 -3.9709 -9.2483 6.5731e-02 6.2303e-02 1.8691e-03 3.1341e-02 1.5738e-03 1.0135e-04 0.0000e+00 + 3 react 4.0000e-03 -1.4744 -2.6548 -3.8456 -9.1411 6.6802e-02 6.3317e-02 1.8995e-03 3.1797e-02 2.0985e-03 1.3526e-04 0.0000e+00 + 3 react 8.0000e-03 -1.4501 -2.3538 -3.5438 -8.8864 7.1083e-02 6.7376e-02 2.0213e-03 3.3621e-02 4.1973e-03 2.7100e-04 0.0000e+00 + 3 react 1.6000e-02 -1.4054 -2.0527 -3.2424 -8.6396 7.9647e-02 7.5493e-02 2.2648e-03 3.7269e-02 8.3949e-03 5.4244e-04 0.0000e+00 + 3 react 3.2000e-02 -1.3278 -1.7517 -2.9416 -8.4054 9.6771e-02 9.1724e-02 2.7517e-03 4.4564e-02 1.6789e-02 1.0843e-03 0.0000e+00 + 3 react 6.4000e-02 -1.2048 -1.4507 -2.6416 -8.1887 1.3101e-01 1.2417e-01 3.7252e-03 5.9149e-02 3.3575e-02 2.1633e-03 0.0000e+00 + 3 react 1.2500e-01 -1.0375 -1.1601 -2.3528 -7.9980 1.9622e-01 1.8599e-01 5.5797e-03 8.6937e-02 6.5561e-02 4.2062e-03 0.0000e+00 + 3 react 2.5000e-01 -0.8189 -0.8592 -2.0546 -7.8181 3.2976e-01 3.1256e-01 9.3769e-03 1.4384e-01 1.3108e-01 8.3591e-03 0.0000e+00 + 3 react 5.0000e-01 -0.5658 -0.5583 -1.7563 -7.6510 5.9669e-01 5.6557e-01 1.6967e-02 2.5759e-01 2.6209e-01 1.6614e-02 0.0000e+00 + 3 react 1.0000e+00 -0.2909 -0.2573 -1.4568 -7.4915 1.1305e+00 1.0715e+00 3.2146e-02 4.8506e-01 5.2408e-01 3.3109e-02 0.0000e+00 diff --git a/ex8.out b/ex8.out index 7404fb7f..8b5ef6a1 100644 --- a/ex8.out +++ b/ex8.out @@ -106,27 +106,27 @@ WARNING: USER_PUNCH: Headings count doesn't match number of calls to PUNCH. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.310e-06 9.977e-07 -5.883 -6.001 -0.118 - H+ 1.211e-08 1.000e-08 -7.917 -8.000 -0.083 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 1.384e-27 - H2 6.918e-28 7.079e-28 -27.160 -27.150 0.010 -N(5) 1.000e-01 - NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 -Na 1.000e-01 - Na+ 1.000e-01 7.829e-02 -1.000 -1.106 -0.106 - NaOH 5.038e-08 5.155e-08 -7.298 -7.288 0.010 -O(0) 1.615e-38 - O2 8.073e-39 8.261e-39 -38.093 -38.083 0.010 -Zn 1.000e-07 - Zn+2 9.102e-08 3.428e-08 -7.041 -7.465 -0.424 - ZnOH+ 4.793e-09 3.746e-09 -8.319 -8.426 -0.107 - Zn(OH)2 4.189e-09 4.286e-09 -8.378 -8.368 0.010 - Zn(OH)3- 1.729e-12 1.351e-12 -11.762 -11.869 -0.107 - Zn(OH)4-2 5.721e-17 2.134e-17 -16.243 -16.671 -0.428 + OH- 1.310e-06 9.977e-07 -5.883 -6.001 -0.118 (0) + H+ 1.211e-08 1.000e-08 -7.917 -8.000 -0.083 0.00 + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 1.384e-27 + H2 6.918e-28 7.079e-28 -27.160 -27.150 0.010 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 28.99 +Na 1.000e-01 + Na+ 1.000e-01 7.829e-02 -1.000 -1.106 -0.106 -1.21 + NaOH 5.038e-08 5.155e-08 -7.298 -7.288 0.010 (0) +O(0) 1.615e-38 + O2 8.073e-39 8.261e-39 -38.093 -38.083 0.010 (0) +Zn 1.000e-07 + Zn+2 9.102e-08 3.428e-08 -7.041 -7.465 -0.424 (0) + ZnOH+ 4.793e-09 3.746e-09 -8.319 -8.426 -0.107 (0) + Zn(OH)2 4.189e-09 4.286e-09 -8.378 -8.368 0.010 (0) + Zn(OH)3- 1.729e-12 1.351e-12 -11.762 -11.869 -0.107 (0) + Zn(OH)4-2 5.721e-17 2.134e-17 -16.243 -16.671 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -199,27 +199,27 @@ Initial solution 2. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.310e-06 9.977e-07 -5.883 -6.001 -0.118 - H+ 1.211e-08 1.000e-08 -7.917 -8.000 -0.083 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 1.384e-27 - H2 6.918e-28 7.079e-28 -27.160 -27.150 0.010 -N(5) 1.000e-01 - NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 -Na 9.981e-02 - Na+ 9.981e-02 7.814e-02 -1.001 -1.107 -0.106 - NaOH 5.028e-08 5.145e-08 -7.299 -7.289 0.010 -O(0) 1.615e-38 - O2 8.073e-39 8.261e-39 -38.093 -38.083 0.010 -Zn 1.000e-04 - Zn+2 9.102e-05 3.427e-05 -4.041 -4.465 -0.424 - ZnOH+ 4.792e-06 3.745e-06 -5.319 -5.427 -0.107 - Zn(OH)2 4.187e-06 4.285e-06 -5.378 -5.368 0.010 - Zn(OH)3- 1.728e-09 1.350e-09 -8.762 -8.870 -0.107 - Zn(OH)4-2 5.721e-14 2.133e-14 -13.243 -13.671 -0.428 + OH- 1.310e-06 9.977e-07 -5.883 -6.001 -0.118 (0) + H+ 1.211e-08 1.000e-08 -7.917 -8.000 -0.083 0.00 + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 1.384e-27 + H2 6.918e-28 7.079e-28 -27.160 -27.150 0.010 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 29.14 +Na 9.981e-02 + Na+ 9.981e-02 7.814e-02 -1.001 -1.107 -0.106 -1.06 + NaOH 5.028e-08 5.145e-08 -7.299 -7.289 0.010 (0) +O(0) 1.615e-38 + O2 8.073e-39 8.261e-39 -38.093 -38.083 0.010 (0) +Zn 1.000e-04 + Zn+2 9.102e-05 3.427e-05 -4.041 -4.465 -0.424 (0) + ZnOH+ 4.792e-06 3.745e-06 -5.319 -5.427 -0.107 (0) + Zn(OH)2 4.187e-06 4.285e-06 -5.378 -5.368 0.010 (0) + Zn(OH)3- 1.728e-09 1.350e-09 -8.762 -8.870 -0.107 (0) + Zn(OH)4-2 5.721e-14 2.133e-14 -13.243 -13.671 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -354,34 +354,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.211e-05 1.000e-05 -4.917 -5.000 -0.083 - OH- 1.309e-09 9.977e-10 -8.883 -9.001 -0.118 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -43.349 -43.339 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -52.670 -52.798 -0.128 - NH3 0.000e+00 0.000e+00 -57.052 -57.042 0.010 -N(0) 1.543e-06 - N2 7.717e-07 7.897e-07 -6.113 -6.103 0.010 -N(3) 2.412e-13 - NO2- 2.412e-13 1.818e-13 -12.618 -12.740 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 -Na 9.987e-02 - Na+ 9.987e-02 7.819e-02 -1.001 -1.107 -0.106 - NaOH 5.032e-11 5.149e-11 -10.298 -10.288 0.010 -O(0) 3.859e-06 - O2 1.929e-06 1.974e-06 -5.715 -5.705 0.010 -Zn 9.967e-08 - Zn+2 9.967e-08 3.754e-08 -7.001 -7.425 -0.424 - ZnOH+ 5.250e-12 4.103e-12 -11.280 -11.387 -0.107 - Zn(OH)2 4.588e-15 4.695e-15 -14.338 -14.328 0.010 - Zn(OH)3- 1.893e-21 1.479e-21 -20.723 -20.830 -0.107 - Zn(OH)4-2 6.265e-29 2.337e-29 -28.203 -28.631 -0.428 + H+ 1.211e-05 1.000e-05 -4.917 -5.000 -0.083 0.00 + OH- 1.309e-09 9.977e-10 -8.883 -9.001 -0.118 (0) + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -43.349 -43.339 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -52.670 -52.798 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -57.052 -57.042 0.010 (0) +N(0) 1.543e-06 + N2 7.717e-07 7.897e-07 -6.113 -6.103 0.010 (0) +N(3) 2.412e-13 + NO2- 2.412e-13 1.818e-13 -12.618 -12.740 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 29.09 +Na 9.987e-02 + Na+ 9.987e-02 7.819e-02 -1.001 -1.107 -0.106 -1.11 + NaOH 5.032e-11 5.149e-11 -10.298 -10.288 0.010 (0) +O(0) 3.859e-06 + O2 1.929e-06 1.974e-06 -5.715 -5.705 0.010 (0) +Zn 9.967e-08 + Zn+2 9.967e-08 3.754e-08 -7.001 -7.425 -0.424 (0) + ZnOH+ 5.250e-12 4.103e-12 -11.280 -11.387 -0.107 (0) + Zn(OH)2 4.588e-15 4.695e-15 -14.338 -14.328 0.010 (0) + Zn(OH)3- 1.893e-21 1.479e-21 -20.723 -20.830 -0.107 (0) + Zn(OH)4-2 6.265e-29 2.337e-29 -28.203 -28.631 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -488,34 +488,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 6.812e-06 5.623e-06 -5.167 -5.250 -0.083 - OH- 2.329e-09 1.774e-09 -8.633 -8.751 -0.118 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -43.278 -43.268 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -52.884 -53.012 -0.128 - NH3 0.000e+00 0.000e+00 -57.017 -57.007 0.010 -N(0) 1.111e-06 - N2 5.554e-07 5.683e-07 -6.255 -6.245 0.010 -N(3) 2.843e-13 - NO2- 2.843e-13 2.143e-13 -12.546 -12.669 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 -Na 9.990e-02 - Na+ 9.990e-02 7.821e-02 -1.000 -1.107 -0.106 - NaOH 8.949e-11 9.158e-11 -10.048 -10.038 0.010 -O(0) 2.777e-06 - O2 1.388e-06 1.421e-06 -5.857 -5.847 0.010 -Zn 9.910e-08 - Zn+2 9.909e-08 3.733e-08 -7.004 -7.428 -0.424 - ZnOH+ 9.281e-12 7.254e-12 -11.032 -11.139 -0.107 - Zn(OH)2 1.442e-14 1.476e-14 -13.841 -13.831 0.010 - Zn(OH)3- 1.058e-20 8.272e-21 -19.975 -20.082 -0.107 - Zn(OH)4-2 6.228e-28 2.323e-28 -27.206 -27.634 -0.428 + H+ 6.812e-06 5.623e-06 -5.167 -5.250 -0.083 0.00 + OH- 2.329e-09 1.774e-09 -8.633 -8.751 -0.118 (0) + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -43.278 -43.268 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -52.884 -53.012 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -57.017 -57.007 0.010 (0) +N(0) 1.111e-06 + N2 5.554e-07 5.683e-07 -6.255 -6.245 0.010 (0) +N(3) 2.843e-13 + NO2- 2.843e-13 2.143e-13 -12.546 -12.669 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 29.09 +Na 9.990e-02 + Na+ 9.990e-02 7.821e-02 -1.000 -1.107 -0.106 -1.11 + NaOH 8.949e-11 9.158e-11 -10.048 -10.038 0.010 (0) +O(0) 2.777e-06 + O2 1.388e-06 1.421e-06 -5.857 -5.847 0.010 (0) +Zn 9.910e-08 + Zn+2 9.909e-08 3.733e-08 -7.004 -7.428 -0.424 (0) + ZnOH+ 9.281e-12 7.254e-12 -11.032 -11.139 -0.107 (0) + Zn(OH)2 1.442e-14 1.476e-14 -13.841 -13.831 0.010 (0) + Zn(OH)3- 1.058e-20 8.272e-21 -19.975 -20.082 -0.107 (0) + Zn(OH)4-2 6.228e-28 2.323e-28 -27.206 -27.634 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -622,34 +622,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 3.830e-06 3.162e-06 -5.417 -5.500 -0.083 - OH- 4.141e-09 3.155e-09 -8.383 -8.501 -0.118 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -43.206 -43.196 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -53.099 -53.227 -0.128 - NH3 0.000e+00 0.000e+00 -56.981 -56.971 0.010 -N(0) 7.994e-07 - N2 3.997e-07 4.090e-07 -6.398 -6.388 0.010 -N(3) 3.351e-13 - NO2- 3.351e-13 2.526e-13 -12.475 -12.598 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 -Na 9.991e-02 - Na+ 9.991e-02 7.822e-02 -1.000 -1.107 -0.106 - NaOH 1.592e-10 1.629e-10 -9.798 -9.788 0.010 -O(0) 1.998e-06 - O2 9.992e-07 1.023e-06 -6.000 -5.990 0.010 -Zn 9.758e-08 - Zn+2 9.757e-08 3.675e-08 -7.011 -7.435 -0.424 - ZnOH+ 1.625e-11 1.270e-11 -10.789 -10.896 -0.107 - Zn(OH)2 4.491e-14 4.595e-14 -13.348 -13.338 0.010 - Zn(OH)3- 5.860e-20 4.580e-20 -19.232 -19.339 -0.107 - Zn(OH)4-2 6.133e-27 2.288e-27 -26.212 -26.641 -0.428 + H+ 3.830e-06 3.162e-06 -5.417 -5.500 -0.083 0.00 + OH- 4.141e-09 3.155e-09 -8.383 -8.501 -0.118 (0) + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -43.206 -43.196 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -53.099 -53.227 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.981 -56.971 0.010 (0) +N(0) 7.994e-07 + N2 3.997e-07 4.090e-07 -6.398 -6.388 0.010 (0) +N(3) 3.351e-13 + NO2- 3.351e-13 2.526e-13 -12.475 -12.598 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 29.09 +Na 9.991e-02 + Na+ 9.991e-02 7.822e-02 -1.000 -1.107 -0.106 -1.11 + NaOH 1.592e-10 1.629e-10 -9.798 -9.788 0.010 (0) +O(0) 1.998e-06 + O2 9.992e-07 1.023e-06 -6.000 -5.990 0.010 (0) +Zn 9.758e-08 + Zn+2 9.757e-08 3.675e-08 -7.011 -7.435 -0.424 (0) + ZnOH+ 1.625e-11 1.270e-11 -10.789 -10.896 -0.107 (0) + Zn(OH)2 4.491e-14 4.595e-14 -13.348 -13.338 0.010 (0) + Zn(OH)3- 5.860e-20 4.580e-20 -19.232 -19.339 -0.107 (0) + Zn(OH)4-2 6.133e-27 2.288e-27 -26.212 -26.641 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -756,34 +756,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 2.154e-06 1.778e-06 -5.667 -5.750 -0.083 - OH- 7.364e-09 5.610e-09 -8.133 -8.251 -0.118 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -43.135 -43.125 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -53.313 -53.441 -0.128 - NH3 0.000e+00 0.000e+00 -56.945 -56.935 0.010 -N(0) 5.753e-07 - N2 2.877e-07 2.944e-07 -6.541 -6.531 0.010 -N(3) 3.950e-13 - NO2- 3.950e-13 2.977e-13 -12.403 -12.526 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 -Na 9.993e-02 - Na+ 9.993e-02 7.824e-02 -1.000 -1.107 -0.106 - NaOH 2.831e-10 2.897e-10 -9.548 -9.538 0.010 -O(0) 1.438e-06 - O2 7.191e-07 7.359e-07 -6.143 -6.133 0.010 -Zn 9.368e-08 - Zn+2 9.366e-08 3.528e-08 -7.028 -7.452 -0.424 - ZnOH+ 2.774e-11 2.168e-11 -10.557 -10.664 -0.107 - Zn(OH)2 1.363e-13 1.395e-13 -12.865 -12.855 0.010 - Zn(OH)3- 3.163e-19 2.472e-19 -18.500 -18.607 -0.107 - Zn(OH)4-2 5.887e-26 2.196e-26 -25.230 -25.658 -0.428 + H+ 2.154e-06 1.778e-06 -5.667 -5.750 -0.083 0.00 + OH- 7.364e-09 5.610e-09 -8.133 -8.251 -0.118 (0) + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -43.135 -43.125 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -53.313 -53.441 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.945 -56.935 0.010 (0) +N(0) 5.753e-07 + N2 2.877e-07 2.944e-07 -6.541 -6.531 0.010 (0) +N(3) 3.950e-13 + NO2- 3.950e-13 2.977e-13 -12.403 -12.526 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 29.09 +Na 9.993e-02 + Na+ 9.993e-02 7.824e-02 -1.000 -1.107 -0.106 -1.11 + NaOH 2.831e-10 2.897e-10 -9.548 -9.538 0.010 (0) +O(0) 1.438e-06 + O2 7.191e-07 7.359e-07 -6.143 -6.133 0.010 (0) +Zn 9.368e-08 + Zn+2 9.366e-08 3.528e-08 -7.028 -7.452 -0.424 (0) + ZnOH+ 2.774e-11 2.168e-11 -10.557 -10.664 -0.107 (0) + Zn(OH)2 1.363e-13 1.395e-13 -12.865 -12.855 0.010 (0) + Zn(OH)3- 3.163e-19 2.472e-19 -18.500 -18.607 -0.107 (0) + Zn(OH)4-2 5.887e-26 2.196e-26 -25.230 -25.658 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -890,34 +890,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.211e-06 1.000e-06 -5.917 -6.000 -0.083 - OH- 1.310e-08 9.977e-09 -7.883 -8.001 -0.118 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -43.063 -43.053 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -53.527 -53.655 -0.128 - NH3 0.000e+00 0.000e+00 -56.909 -56.899 0.010 -N(0) 4.140e-07 - N2 2.070e-07 2.118e-07 -6.684 -6.674 0.010 -N(3) 4.656e-13 - NO2- 4.656e-13 3.509e-13 -12.332 -12.455 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 -Na 9.994e-02 - Na+ 9.994e-02 7.824e-02 -1.000 -1.107 -0.106 - NaOH 5.035e-10 5.152e-10 -9.298 -9.288 0.010 -O(0) 1.035e-06 - O2 5.176e-07 5.296e-07 -6.286 -6.276 0.010 -Zn 8.452e-08 - Zn+2 8.448e-08 3.182e-08 -7.073 -7.497 -0.424 - ZnOH+ 4.449e-11 3.477e-11 -10.352 -10.459 -0.107 - Zn(OH)2 3.888e-13 3.979e-13 -12.410 -12.400 0.010 - Zn(OH)3- 1.604e-18 1.254e-18 -17.795 -17.902 -0.107 - Zn(OH)4-2 5.310e-25 1.981e-25 -24.275 -24.703 -0.428 + H+ 1.211e-06 1.000e-06 -5.917 -6.000 -0.083 0.00 + OH- 1.310e-08 9.977e-09 -7.883 -8.001 -0.118 (0) + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -43.063 -43.053 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -53.527 -53.655 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.909 -56.899 0.010 (0) +N(0) 4.140e-07 + N2 2.070e-07 2.118e-07 -6.684 -6.674 0.010 (0) +N(3) 4.656e-13 + NO2- 4.656e-13 3.509e-13 -12.332 -12.455 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 29.09 +Na 9.994e-02 + Na+ 9.994e-02 7.824e-02 -1.000 -1.107 -0.106 -1.11 + NaOH 5.035e-10 5.152e-10 -9.298 -9.288 0.010 (0) +O(0) 1.035e-06 + O2 5.176e-07 5.296e-07 -6.286 -6.276 0.010 (0) +Zn 8.452e-08 + Zn+2 8.448e-08 3.182e-08 -7.073 -7.497 -0.424 (0) + ZnOH+ 4.449e-11 3.477e-11 -10.352 -10.459 -0.107 (0) + Zn(OH)2 3.888e-13 3.979e-13 -12.410 -12.400 0.010 (0) + Zn(OH)3- 1.604e-18 1.254e-18 -17.795 -17.902 -0.107 (0) + Zn(OH)4-2 5.310e-25 1.981e-25 -24.275 -24.703 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -1024,34 +1024,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 6.812e-07 5.623e-07 -6.167 -6.250 -0.083 - OH- 2.329e-08 1.774e-08 -7.633 -7.751 -0.118 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.992 -42.982 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -53.742 -53.869 -0.128 - NH3 0.000e+00 0.000e+00 -56.874 -56.864 0.010 -N(0) 2.980e-07 - N2 1.490e-07 1.525e-07 -6.827 -6.817 0.010 -N(3) 5.488e-13 - NO2- 5.488e-13 4.137e-13 -12.261 -12.383 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 -Na 9.995e-02 - Na+ 9.995e-02 7.825e-02 -1.000 -1.106 -0.106 - NaOH 8.954e-10 9.163e-10 -9.048 -9.038 0.010 -O(0) 7.449e-07 - O2 3.725e-07 3.811e-07 -6.429 -6.419 0.010 -Zn 6.676e-08 - Zn+2 6.670e-08 2.512e-08 -7.176 -7.600 -0.424 - ZnOH+ 6.247e-11 4.882e-11 -10.204 -10.311 -0.107 - Zn(OH)2 9.707e-13 9.933e-13 -12.013 -12.003 0.010 - Zn(OH)3- 7.123e-18 5.567e-18 -17.147 -17.254 -0.107 - Zn(OH)4-2 4.192e-24 1.564e-24 -23.378 -23.806 -0.428 + H+ 6.812e-07 5.623e-07 -6.167 -6.250 -0.083 0.00 + OH- 2.329e-08 1.774e-08 -7.633 -7.751 -0.118 (0) + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.992 -42.982 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -53.742 -53.869 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.874 -56.864 0.010 (0) +N(0) 2.980e-07 + N2 1.490e-07 1.525e-07 -6.827 -6.817 0.010 (0) +N(3) 5.488e-13 + NO2- 5.488e-13 4.137e-13 -12.261 -12.383 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 29.09 +Na 9.995e-02 + Na+ 9.995e-02 7.825e-02 -1.000 -1.106 -0.106 -1.11 + NaOH 8.954e-10 9.163e-10 -9.048 -9.038 0.010 (0) +O(0) 7.449e-07 + O2 3.725e-07 3.811e-07 -6.429 -6.419 0.010 (0) +Zn 6.676e-08 + Zn+2 6.670e-08 2.512e-08 -7.176 -7.600 -0.424 (0) + ZnOH+ 6.247e-11 4.882e-11 -10.204 -10.311 -0.107 (0) + Zn(OH)2 9.707e-13 9.933e-13 -12.013 -12.003 0.010 (0) + Zn(OH)3- 7.123e-18 5.567e-18 -17.147 -17.254 -0.107 (0) + Zn(OH)4-2 4.192e-24 1.564e-24 -23.378 -23.806 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -1158,34 +1158,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 3.831e-07 3.162e-07 -6.417 -6.500 -0.083 - OH- 4.141e-08 3.155e-08 -7.383 -7.501 -0.118 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.921 -42.911 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -53.956 -54.084 -0.128 - NH3 0.000e+00 0.000e+00 -56.838 -56.828 0.010 -N(0) 2.145e-07 - N2 1.072e-07 1.097e-07 -6.970 -6.960 0.010 -N(3) 6.470e-13 - NO2- 6.470e-13 4.876e-13 -12.189 -12.312 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 -Na 9.996e-02 - Na+ 9.996e-02 7.826e-02 -1.000 -1.106 -0.106 - NaOH 1.592e-09 1.630e-09 -8.798 -8.788 0.010 -O(0) 5.361e-07 - O2 2.681e-07 2.743e-07 -6.572 -6.562 0.010 -Zn 4.239e-08 - Zn+2 4.232e-08 1.594e-08 -7.373 -7.797 -0.424 - ZnOH+ 7.049e-11 5.509e-11 -10.152 -10.259 -0.107 - Zn(OH)2 1.948e-12 1.993e-12 -11.710 -11.700 0.010 - Zn(OH)3- 2.542e-17 1.986e-17 -16.595 -16.702 -0.107 - Zn(OH)4-2 2.660e-23 9.922e-24 -22.575 -23.003 -0.428 + H+ 3.831e-07 3.162e-07 -6.417 -6.500 -0.083 0.00 + OH- 4.141e-08 3.155e-08 -7.383 -7.501 -0.118 (0) + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.921 -42.911 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -53.956 -54.084 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.838 -56.828 0.010 (0) +N(0) 2.145e-07 + N2 1.072e-07 1.097e-07 -6.970 -6.960 0.010 (0) +N(3) 6.470e-13 + NO2- 6.470e-13 4.876e-13 -12.189 -12.312 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 29.09 +Na 9.996e-02 + Na+ 9.996e-02 7.826e-02 -1.000 -1.106 -0.106 -1.11 + NaOH 1.592e-09 1.630e-09 -8.798 -8.788 0.010 (0) +O(0) 5.361e-07 + O2 2.681e-07 2.743e-07 -6.572 -6.562 0.010 (0) +Zn 4.239e-08 + Zn+2 4.232e-08 1.594e-08 -7.373 -7.797 -0.424 (0) + ZnOH+ 7.049e-11 5.509e-11 -10.152 -10.259 -0.107 (0) + Zn(OH)2 1.948e-12 1.993e-12 -11.710 -11.700 0.010 (0) + Zn(OH)3- 2.542e-17 1.986e-17 -16.595 -16.702 -0.107 (0) + Zn(OH)4-2 2.660e-23 9.922e-24 -22.575 -23.003 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -1292,34 +1292,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 2.154e-07 1.778e-07 -6.667 -6.750 -0.083 - OH- 7.364e-08 5.610e-08 -7.133 -7.251 -0.118 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.849 -42.839 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -54.170 -54.298 -0.128 - NH3 0.000e+00 0.000e+00 -56.802 -56.792 0.010 -N(0) 1.543e-07 - N2 7.717e-08 7.897e-08 -7.113 -7.103 0.010 -N(3) 7.626e-13 - NO2- 7.626e-13 5.748e-13 -12.118 -12.240 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 -Na 9.997e-02 - Na+ 9.997e-02 7.827e-02 -1.000 -1.106 -0.106 - NaOH 2.832e-09 2.898e-09 -8.548 -8.538 0.010 -O(0) 3.858e-07 - O2 1.929e-07 1.974e-07 -6.715 -6.705 0.010 -Zn 2.112e-08 - Zn+2 2.105e-08 7.929e-09 -7.677 -8.101 -0.424 - ZnOH+ 6.235e-11 4.872e-11 -10.205 -10.312 -0.107 - Zn(OH)2 3.064e-12 3.135e-12 -11.514 -11.504 0.010 - Zn(OH)3- 7.110e-17 5.556e-17 -16.148 -16.255 -0.107 - Zn(OH)4-2 1.323e-22 4.935e-23 -21.878 -22.307 -0.428 + H+ 2.154e-07 1.778e-07 -6.667 -6.750 -0.083 0.00 + OH- 7.364e-08 5.610e-08 -7.133 -7.251 -0.118 (0) + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.849 -42.839 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -54.170 -54.298 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.802 -56.792 0.010 (0) +N(0) 1.543e-07 + N2 7.717e-08 7.897e-08 -7.113 -7.103 0.010 (0) +N(3) 7.626e-13 + NO2- 7.626e-13 5.748e-13 -12.118 -12.240 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 29.09 +Na 9.997e-02 + Na+ 9.997e-02 7.827e-02 -1.000 -1.106 -0.106 -1.11 + NaOH 2.832e-09 2.898e-09 -8.548 -8.538 0.010 (0) +O(0) 3.858e-07 + O2 1.929e-07 1.974e-07 -6.715 -6.705 0.010 (0) +Zn 2.112e-08 + Zn+2 2.105e-08 7.929e-09 -7.677 -8.101 -0.424 (0) + ZnOH+ 6.235e-11 4.872e-11 -10.205 -10.312 -0.107 (0) + Zn(OH)2 3.064e-12 3.135e-12 -11.514 -11.504 0.010 (0) + Zn(OH)3- 7.110e-17 5.556e-17 -16.148 -16.255 -0.107 (0) + Zn(OH)4-2 1.323e-22 4.935e-23 -21.878 -22.307 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -1426,34 +1426,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.310e-07 9.977e-08 -6.883 -7.001 -0.118 - H+ 1.211e-07 1.000e-07 -6.917 -7.000 -0.083 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.778 -42.768 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -54.384 -54.512 -0.128 - NH3 0.000e+00 0.000e+00 -56.767 -56.757 0.010 -N(0) 1.111e-07 - N2 5.554e-08 5.683e-08 -7.255 -7.245 0.010 -N(3) 8.990e-13 - NO2- 8.990e-13 6.775e-13 -12.046 -12.169 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 -Na 9.998e-02 - Na+ 9.998e-02 7.827e-02 -1.000 -1.106 -0.106 - NaOH 5.037e-09 5.154e-09 -8.298 -8.288 0.010 -O(0) 2.777e-07 - O2 1.388e-07 1.421e-07 -6.857 -6.847 0.010 -Zn 8.799e-09 - Zn+2 8.749e-09 3.295e-09 -8.058 -8.482 -0.424 - ZnOH+ 4.608e-11 3.601e-11 -10.336 -10.444 -0.107 - Zn(OH)2 4.027e-12 4.121e-12 -11.395 -11.385 0.010 - Zn(OH)3- 1.662e-16 1.299e-16 -15.779 -15.887 -0.107 - Zn(OH)4-2 5.499e-22 2.051e-22 -21.260 -21.688 -0.428 + OH- 1.310e-07 9.977e-08 -6.883 -7.001 -0.118 (0) + H+ 1.211e-07 1.000e-07 -6.917 -7.000 -0.083 0.00 + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.778 -42.768 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -54.384 -54.512 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.767 -56.757 0.010 (0) +N(0) 1.111e-07 + N2 5.554e-08 5.683e-08 -7.255 -7.245 0.010 (0) +N(3) 8.990e-13 + NO2- 8.990e-13 6.775e-13 -12.046 -12.169 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 29.09 +Na 9.998e-02 + Na+ 9.998e-02 7.827e-02 -1.000 -1.106 -0.106 -1.11 + NaOH 5.037e-09 5.154e-09 -8.298 -8.288 0.010 (0) +O(0) 2.777e-07 + O2 1.388e-07 1.421e-07 -6.857 -6.847 0.010 (0) +Zn 8.799e-09 + Zn+2 8.749e-09 3.295e-09 -8.058 -8.482 -0.424 (0) + ZnOH+ 4.608e-11 3.601e-11 -10.336 -10.444 -0.107 (0) + Zn(OH)2 4.027e-12 4.121e-12 -11.395 -11.385 0.010 (0) + Zn(OH)3- 1.662e-16 1.299e-16 -15.779 -15.887 -0.107 (0) + Zn(OH)4-2 5.499e-22 2.051e-22 -21.260 -21.688 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -1560,34 +1560,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.329e-07 1.774e-07 -6.633 -6.751 -0.118 - H+ 6.812e-08 5.623e-08 -7.167 -7.250 -0.083 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.706 -42.696 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -54.599 -54.727 -0.128 - NH3 0.000e+00 0.000e+00 -56.731 -56.721 0.010 -N(0) 7.994e-08 - N2 3.997e-08 4.090e-08 -7.398 -7.388 0.010 -N(3) 1.060e-12 - NO2- 1.060e-12 7.987e-13 -11.975 -12.098 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 -Na 9.998e-02 - Na+ 9.998e-02 7.828e-02 -1.000 -1.106 -0.106 - NaOH 8.957e-09 9.166e-09 -8.048 -8.038 0.010 -O(0) 1.998e-07 - O2 9.992e-08 1.022e-07 -7.000 -6.990 0.010 -Zn 3.336e-09 - Zn+2 3.300e-09 1.243e-09 -8.481 -8.906 -0.424 - ZnOH+ 3.091e-11 2.415e-11 -10.510 -10.617 -0.107 - Zn(OH)2 4.803e-12 4.915e-12 -11.319 -11.309 0.010 - Zn(OH)3- 3.524e-16 2.754e-16 -15.453 -15.560 -0.107 - Zn(OH)4-2 2.074e-21 7.736e-22 -20.683 -21.111 -0.428 + OH- 2.329e-07 1.774e-07 -6.633 -6.751 -0.118 (0) + H+ 6.812e-08 5.623e-08 -7.167 -7.250 -0.083 0.00 + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.706 -42.696 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -54.599 -54.727 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.731 -56.721 0.010 (0) +N(0) 7.994e-08 + N2 3.997e-08 4.090e-08 -7.398 -7.388 0.010 (0) +N(3) 1.060e-12 + NO2- 1.060e-12 7.987e-13 -11.975 -12.098 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 29.09 +Na 9.998e-02 + Na+ 9.998e-02 7.828e-02 -1.000 -1.106 -0.106 -1.11 + NaOH 8.957e-09 9.166e-09 -8.048 -8.038 0.010 (0) +O(0) 1.998e-07 + O2 9.992e-08 1.022e-07 -7.000 -6.990 0.010 (0) +Zn 3.336e-09 + Zn+2 3.300e-09 1.243e-09 -8.481 -8.906 -0.424 (0) + ZnOH+ 3.091e-11 2.415e-11 -10.510 -10.617 -0.107 (0) + Zn(OH)2 4.803e-12 4.915e-12 -11.319 -11.309 0.010 (0) + Zn(OH)3- 3.524e-16 2.754e-16 -15.453 -15.560 -0.107 (0) + Zn(OH)4-2 2.074e-21 7.736e-22 -20.683 -21.111 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -1694,34 +1694,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 4.141e-07 3.155e-07 -6.383 -6.501 -0.118 - H+ 3.831e-08 3.162e-08 -7.417 -7.500 -0.083 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.635 -42.625 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -54.813 -54.941 -0.128 - NH3 0.000e+00 0.000e+00 -56.695 -56.685 0.010 -N(0) 5.753e-08 - N2 2.876e-08 2.943e-08 -7.541 -7.531 0.010 -N(3) 1.249e-12 - NO2- 1.249e-12 9.414e-13 -11.903 -12.026 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 -Na 9.999e-02 - Na+ 9.999e-02 7.828e-02 -1.000 -1.106 -0.106 - NaOH 1.593e-08 1.630e-08 -7.798 -7.788 0.010 -O(0) 1.438e-07 - O2 7.191e-08 7.359e-08 -7.143 -7.133 0.010 -Zn 1.216e-09 - Zn+2 1.190e-09 4.483e-10 -8.924 -9.348 -0.424 - ZnOH+ 1.982e-11 1.549e-11 -10.703 -10.810 -0.107 - Zn(OH)2 5.478e-12 5.606e-12 -11.261 -11.251 0.010 - Zn(OH)3- 7.149e-16 5.587e-16 -15.146 -15.253 -0.107 - Zn(OH)4-2 7.481e-21 2.790e-21 -20.126 -20.554 -0.428 + OH- 4.141e-07 3.155e-07 -6.383 -6.501 -0.118 (0) + H+ 3.831e-08 3.162e-08 -7.417 -7.500 -0.083 0.00 + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.635 -42.625 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -54.813 -54.941 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.695 -56.685 0.010 (0) +N(0) 5.753e-08 + N2 2.876e-08 2.943e-08 -7.541 -7.531 0.010 (0) +N(3) 1.249e-12 + NO2- 1.249e-12 9.414e-13 -11.903 -12.026 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 29.09 +Na 9.999e-02 + Na+ 9.999e-02 7.828e-02 -1.000 -1.106 -0.106 -1.11 + NaOH 1.593e-08 1.630e-08 -7.798 -7.788 0.010 (0) +O(0) 1.438e-07 + O2 7.191e-08 7.359e-08 -7.143 -7.133 0.010 (0) +Zn 1.216e-09 + Zn+2 1.190e-09 4.483e-10 -8.924 -9.348 -0.424 (0) + ZnOH+ 1.982e-11 1.549e-11 -10.703 -10.810 -0.107 (0) + Zn(OH)2 5.478e-12 5.606e-12 -11.261 -11.251 0.010 (0) + Zn(OH)3- 7.149e-16 5.587e-16 -15.146 -15.253 -0.107 (0) + Zn(OH)4-2 7.481e-21 2.790e-21 -20.126 -20.554 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -1828,34 +1828,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 7.364e-07 5.610e-07 -6.133 -6.251 -0.118 - H+ 2.154e-08 1.778e-08 -7.667 -7.750 -0.083 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.563 -42.553 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -55.027 -55.155 -0.128 - NH3 0.000e+00 0.000e+00 -56.659 -56.649 0.010 -N(0) 4.140e-08 - N2 2.070e-08 2.118e-08 -7.684 -7.674 0.010 -N(3) 1.472e-12 - NO2- 1.472e-12 1.110e-12 -11.832 -11.955 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 -Na 1.000e-01 - Na+ 1.000e-01 7.829e-02 -1.000 -1.106 -0.106 - NaOH 2.833e-08 2.899e-08 -7.548 -7.538 0.010 -O(0) 1.035e-07 - O2 5.175e-08 5.296e-08 -7.286 -7.276 0.010 -Zn 4.397e-10 - Zn+2 4.211e-10 1.586e-10 -9.376 -9.800 -0.424 - ZnOH+ 1.247e-11 9.747e-12 -10.904 -11.011 -0.107 - Zn(OH)2 6.129e-12 6.272e-12 -11.213 -11.203 0.010 - Zn(OH)3- 1.422e-15 1.112e-15 -14.847 -14.954 -0.107 - Zn(OH)4-2 2.647e-20 9.873e-21 -19.577 -20.006 -0.428 + OH- 7.364e-07 5.610e-07 -6.133 -6.251 -0.118 (0) + H+ 2.154e-08 1.778e-08 -7.667 -7.750 -0.083 0.00 + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.563 -42.553 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -55.027 -55.155 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.659 -56.649 0.010 (0) +N(0) 4.140e-08 + N2 2.070e-08 2.118e-08 -7.684 -7.674 0.010 (0) +N(3) 1.472e-12 + NO2- 1.472e-12 1.110e-12 -11.832 -11.955 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 29.09 +Na 1.000e-01 + Na+ 1.000e-01 7.829e-02 -1.000 -1.106 -0.106 -1.11 + NaOH 2.833e-08 2.899e-08 -7.548 -7.538 0.010 (0) +O(0) 1.035e-07 + O2 5.175e-08 5.296e-08 -7.286 -7.276 0.010 (0) +Zn 4.397e-10 + Zn+2 4.211e-10 1.586e-10 -9.376 -9.800 -0.424 (0) + ZnOH+ 1.247e-11 9.747e-12 -10.904 -11.011 -0.107 (0) + Zn(OH)2 6.129e-12 6.272e-12 -11.213 -11.203 0.010 (0) + Zn(OH)3- 1.422e-15 1.112e-15 -14.847 -14.954 -0.107 (0) + Zn(OH)4-2 2.647e-20 9.873e-21 -19.577 -20.006 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -1962,34 +1962,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.310e-06 9.977e-07 -5.883 -6.001 -0.118 - H+ 1.211e-08 1.000e-08 -7.917 -8.000 -0.083 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.492 -42.482 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -55.242 -55.369 -0.128 - NH3 0.000e+00 0.000e+00 -56.624 -56.614 0.010 -N(0) 2.980e-08 - N2 1.490e-08 1.525e-08 -7.827 -7.817 0.010 -N(3) 1.736e-12 - NO2- 1.736e-12 1.308e-12 -11.761 -11.883 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 -Na 1.000e-01 - Na+ 1.000e-01 7.829e-02 -1.000 -1.106 -0.106 - NaOH 5.038e-08 5.155e-08 -7.298 -7.288 0.010 -O(0) 7.449e-08 - O2 3.725e-08 3.811e-08 -7.429 -7.419 0.010 -Zn 1.626e-10 - Zn+2 1.480e-10 5.574e-11 -9.830 -10.254 -0.424 - ZnOH+ 7.794e-12 6.091e-12 -11.108 -11.215 -0.107 - Zn(OH)2 6.811e-12 6.969e-12 -11.167 -11.157 0.010 - Zn(OH)3- 2.811e-15 2.196e-15 -14.551 -14.658 -0.107 - Zn(OH)4-2 9.302e-20 3.469e-20 -19.031 -19.460 -0.428 + OH- 1.310e-06 9.977e-07 -5.883 -6.001 -0.118 (0) + H+ 1.211e-08 1.000e-08 -7.917 -8.000 -0.083 0.00 + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.492 -42.482 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -55.242 -55.369 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.624 -56.614 0.010 (0) +N(0) 2.980e-08 + N2 1.490e-08 1.525e-08 -7.827 -7.817 0.010 (0) +N(3) 1.736e-12 + NO2- 1.736e-12 1.308e-12 -11.761 -11.883 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 29.09 +Na 1.000e-01 + Na+ 1.000e-01 7.829e-02 -1.000 -1.106 -0.106 -1.11 + NaOH 5.038e-08 5.155e-08 -7.298 -7.288 0.010 (0) +O(0) 7.449e-08 + O2 3.725e-08 3.811e-08 -7.429 -7.419 0.010 (0) +Zn 1.626e-10 + Zn+2 1.480e-10 5.574e-11 -9.830 -10.254 -0.424 (0) + ZnOH+ 7.794e-12 6.091e-12 -11.108 -11.215 -0.107 (0) + Zn(OH)2 6.811e-12 6.969e-12 -11.167 -11.157 0.010 (0) + Zn(OH)3- 2.811e-15 2.196e-15 -14.551 -14.658 -0.107 (0) + Zn(OH)4-2 9.302e-20 3.469e-20 -19.031 -19.460 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -2128,34 +2128,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.211e-05 1.000e-05 -4.917 -5.000 -0.083 - OH- 1.310e-09 9.977e-10 -8.883 -9.001 -0.118 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -43.349 -43.339 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -52.670 -52.798 -0.128 - NH3 0.000e+00 0.000e+00 -57.052 -57.042 0.010 -N(0) 1.543e-06 - N2 7.717e-07 7.897e-07 -6.113 -6.103 0.010 -N(3) 2.412e-13 - NO2- 2.412e-13 1.818e-13 -12.618 -12.741 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 -Na 9.967e-02 - Na+ 9.967e-02 7.803e-02 -1.001 -1.108 -0.106 - NaOH 5.021e-11 5.138e-11 -10.299 -10.289 0.010 -O(0) 3.858e-06 - O2 1.929e-06 1.974e-06 -5.715 -5.705 0.010 -Zn 9.969e-05 - Zn+2 9.969e-05 3.754e-05 -4.001 -4.426 -0.424 - ZnOH+ 5.249e-09 4.102e-09 -8.280 -8.387 -0.107 - Zn(OH)2 4.587e-12 4.694e-12 -11.338 -11.328 0.010 - Zn(OH)3- 1.893e-18 1.479e-18 -17.723 -17.830 -0.107 - Zn(OH)4-2 6.266e-26 2.337e-26 -25.203 -25.631 -0.428 + H+ 1.211e-05 1.000e-05 -4.917 -5.000 -0.083 0.00 + OH- 1.310e-09 9.977e-10 -8.883 -9.001 -0.118 (0) + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -43.349 -43.339 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -52.670 -52.798 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -57.052 -57.042 0.010 (0) +N(0) 1.543e-06 + N2 7.717e-07 7.897e-07 -6.113 -6.103 0.010 (0) +N(3) 2.412e-13 + NO2- 2.412e-13 1.818e-13 -12.618 -12.741 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 29.09 +Na 9.967e-02 + Na+ 9.967e-02 7.803e-02 -1.001 -1.108 -0.106 -1.11 + NaOH 5.021e-11 5.138e-11 -10.299 -10.289 0.010 (0) +O(0) 3.858e-06 + O2 1.929e-06 1.974e-06 -5.715 -5.705 0.010 (0) +Zn 9.969e-05 + Zn+2 9.969e-05 3.754e-05 -4.001 -4.426 -0.424 (0) + ZnOH+ 5.249e-09 4.102e-09 -8.280 -8.387 -0.107 (0) + Zn(OH)2 4.587e-12 4.694e-12 -11.338 -11.328 0.010 (0) + Zn(OH)3- 1.893e-18 1.479e-18 -17.723 -17.830 -0.107 (0) + Zn(OH)4-2 6.266e-26 2.337e-26 -25.203 -25.631 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -2262,34 +2262,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 6.812e-06 5.623e-06 -5.167 -5.250 -0.083 - OH- 2.329e-09 1.774e-09 -8.633 -8.751 -0.118 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -43.278 -43.268 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -52.884 -53.012 -0.128 - NH3 0.000e+00 0.000e+00 -57.016 -57.006 0.010 -N(0) 1.111e-06 - N2 5.555e-07 5.684e-07 -6.255 -6.245 0.010 -N(3) 2.843e-13 - NO2- 2.843e-13 2.143e-13 -12.546 -12.669 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 -Na 9.970e-02 - Na+ 9.970e-02 7.805e-02 -1.001 -1.108 -0.106 - NaOH 8.931e-11 9.139e-11 -10.049 -10.039 0.010 -O(0) 2.776e-06 - O2 1.388e-06 1.421e-06 -5.858 -5.848 0.010 -Zn 9.923e-05 - Zn+2 9.922e-05 3.736e-05 -4.003 -4.428 -0.424 - ZnOH+ 9.291e-09 7.261e-09 -8.032 -8.139 -0.107 - Zn(OH)2 1.444e-11 1.477e-11 -10.841 -10.831 0.010 - Zn(OH)3- 1.060e-17 8.280e-18 -16.975 -17.082 -0.107 - Zn(OH)4-2 6.236e-25 2.326e-25 -24.205 -24.633 -0.428 + H+ 6.812e-06 5.623e-06 -5.167 -5.250 -0.083 0.00 + OH- 2.329e-09 1.774e-09 -8.633 -8.751 -0.118 (0) + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -43.278 -43.268 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -52.884 -53.012 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -57.016 -57.006 0.010 (0) +N(0) 1.111e-06 + N2 5.555e-07 5.684e-07 -6.255 -6.245 0.010 (0) +N(3) 2.843e-13 + NO2- 2.843e-13 2.143e-13 -12.546 -12.669 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 29.09 +Na 9.970e-02 + Na+ 9.970e-02 7.805e-02 -1.001 -1.108 -0.106 -1.11 + NaOH 8.931e-11 9.139e-11 -10.049 -10.039 0.010 (0) +O(0) 2.776e-06 + O2 1.388e-06 1.421e-06 -5.858 -5.848 0.010 (0) +Zn 9.923e-05 + Zn+2 9.922e-05 3.736e-05 -4.003 -4.428 -0.424 (0) + ZnOH+ 9.291e-09 7.261e-09 -8.032 -8.139 -0.107 (0) + Zn(OH)2 1.444e-11 1.477e-11 -10.841 -10.831 0.010 (0) + Zn(OH)3- 1.060e-17 8.280e-18 -16.975 -17.082 -0.107 (0) + Zn(OH)4-2 6.236e-25 2.326e-25 -24.205 -24.633 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -2396,34 +2396,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 3.831e-06 3.162e-06 -5.417 -5.500 -0.083 - OH- 4.141e-09 3.155e-09 -8.383 -8.501 -0.118 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -43.206 -43.196 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -53.098 -53.226 -0.128 - NH3 0.000e+00 0.000e+00 -56.981 -56.971 0.010 -N(0) 7.999e-07 - N2 4.000e-07 4.093e-07 -6.398 -6.388 0.010 -N(3) 3.352e-13 - NO2- 3.352e-13 2.526e-13 -12.475 -12.598 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 -Na 9.972e-02 - Na+ 9.972e-02 7.806e-02 -1.001 -1.108 -0.106 - NaOH 1.588e-10 1.625e-10 -9.799 -9.789 0.010 -O(0) 1.998e-06 - O2 9.989e-07 1.022e-06 -6.000 -5.990 0.010 -Zn 9.832e-05 - Zn+2 9.830e-05 3.702e-05 -4.007 -4.432 -0.424 - ZnOH+ 1.637e-08 1.279e-08 -7.786 -7.893 -0.107 - Zn(OH)2 4.523e-11 4.628e-11 -10.345 -10.335 0.010 - Zn(OH)3- 5.903e-17 4.613e-17 -16.229 -16.336 -0.107 - Zn(OH)4-2 6.178e-24 2.304e-24 -23.209 -23.638 -0.428 + H+ 3.831e-06 3.162e-06 -5.417 -5.500 -0.083 0.00 + OH- 4.141e-09 3.155e-09 -8.383 -8.501 -0.118 (0) + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -43.206 -43.196 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -53.098 -53.226 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.981 -56.971 0.010 (0) +N(0) 7.999e-07 + N2 4.000e-07 4.093e-07 -6.398 -6.388 0.010 (0) +N(3) 3.352e-13 + NO2- 3.352e-13 2.526e-13 -12.475 -12.598 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 29.09 +Na 9.972e-02 + Na+ 9.972e-02 7.806e-02 -1.001 -1.108 -0.106 -1.11 + NaOH 1.588e-10 1.625e-10 -9.799 -9.789 0.010 (0) +O(0) 1.998e-06 + O2 9.989e-07 1.022e-06 -6.000 -5.990 0.010 (0) +Zn 9.832e-05 + Zn+2 9.830e-05 3.702e-05 -4.007 -4.432 -0.424 (0) + ZnOH+ 1.637e-08 1.279e-08 -7.786 -7.893 -0.107 (0) + Zn(OH)2 4.523e-11 4.628e-11 -10.345 -10.335 0.010 (0) + Zn(OH)3- 5.903e-17 4.613e-17 -16.229 -16.336 -0.107 (0) + Zn(OH)4-2 6.178e-24 2.304e-24 -23.209 -23.638 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -2530,34 +2530,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 2.154e-06 1.778e-06 -5.667 -5.750 -0.083 - OH- 7.365e-09 5.610e-09 -8.133 -8.251 -0.118 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -43.135 -43.125 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -53.313 -53.441 -0.128 - NH3 0.000e+00 0.000e+00 -56.945 -56.935 0.010 -N(0) 5.753e-07 - N2 2.876e-07 2.943e-07 -6.541 -6.531 0.010 -N(3) 3.950e-13 - NO2- 3.950e-13 2.977e-13 -12.403 -12.526 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 -Na 9.973e-02 - Na+ 9.973e-02 7.808e-02 -1.001 -1.107 -0.106 - NaOH 2.825e-10 2.891e-10 -9.549 -9.539 0.010 -O(0) 1.438e-06 - O2 7.191e-07 7.358e-07 -6.143 -6.133 0.010 -Zn 9.698e-05 - Zn+2 9.695e-05 3.651e-05 -4.013 -4.438 -0.424 - ZnOH+ 2.871e-08 2.243e-08 -7.542 -7.649 -0.107 - Zn(OH)2 1.411e-10 1.443e-10 -9.851 -9.841 0.010 - Zn(OH)3- 3.274e-16 2.558e-16 -15.485 -15.592 -0.107 - Zn(OH)4-2 6.093e-23 2.272e-23 -22.215 -22.644 -0.428 + H+ 2.154e-06 1.778e-06 -5.667 -5.750 -0.083 0.00 + OH- 7.365e-09 5.610e-09 -8.133 -8.251 -0.118 (0) + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -43.135 -43.125 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -53.313 -53.441 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.945 -56.935 0.010 (0) +N(0) 5.753e-07 + N2 2.876e-07 2.943e-07 -6.541 -6.531 0.010 (0) +N(3) 3.950e-13 + NO2- 3.950e-13 2.977e-13 -12.403 -12.526 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 29.09 +Na 9.973e-02 + Na+ 9.973e-02 7.808e-02 -1.001 -1.107 -0.106 -1.11 + NaOH 2.825e-10 2.891e-10 -9.549 -9.539 0.010 (0) +O(0) 1.438e-06 + O2 7.191e-07 7.358e-07 -6.143 -6.133 0.010 (0) +Zn 9.698e-05 + Zn+2 9.695e-05 3.651e-05 -4.013 -4.438 -0.424 (0) + ZnOH+ 2.871e-08 2.243e-08 -7.542 -7.649 -0.107 (0) + Zn(OH)2 1.411e-10 1.443e-10 -9.851 -9.841 0.010 (0) + Zn(OH)3- 3.274e-16 2.558e-16 -15.485 -15.592 -0.107 (0) + Zn(OH)4-2 6.093e-23 2.272e-23 -22.215 -22.644 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -2664,34 +2664,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.211e-06 1.000e-06 -5.917 -6.000 -0.083 - OH- 1.310e-08 9.977e-09 -7.883 -8.001 -0.118 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -43.063 -43.053 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -53.527 -53.655 -0.128 - NH3 0.000e+00 0.000e+00 -56.909 -56.899 0.010 -N(0) 4.140e-07 - N2 2.070e-07 2.118e-07 -6.684 -6.674 0.010 -N(3) 4.656e-13 - NO2- 4.656e-13 3.509e-13 -12.332 -12.455 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 -Na 9.975e-02 - Na+ 9.975e-02 7.809e-02 -1.001 -1.107 -0.106 - NaOH 5.025e-10 5.142e-10 -9.299 -9.289 0.010 -O(0) 1.035e-06 - O2 5.175e-07 5.296e-07 -6.286 -6.276 0.010 -Zn 9.549e-05 - Zn+2 9.544e-05 3.594e-05 -4.020 -4.444 -0.424 - ZnOH+ 5.025e-08 3.927e-08 -7.299 -7.406 -0.107 - Zn(OH)2 4.391e-10 4.493e-10 -9.357 -9.347 0.010 - Zn(OH)3- 1.812e-15 1.416e-15 -14.742 -14.849 -0.107 - Zn(OH)4-2 5.998e-22 2.237e-22 -21.222 -21.650 -0.428 + H+ 1.211e-06 1.000e-06 -5.917 -6.000 -0.083 0.00 + OH- 1.310e-08 9.977e-09 -7.883 -8.001 -0.118 (0) + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -43.063 -43.053 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -53.527 -53.655 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.909 -56.899 0.010 (0) +N(0) 4.140e-07 + N2 2.070e-07 2.118e-07 -6.684 -6.674 0.010 (0) +N(3) 4.656e-13 + NO2- 4.656e-13 3.509e-13 -12.332 -12.455 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 29.09 +Na 9.975e-02 + Na+ 9.975e-02 7.809e-02 -1.001 -1.107 -0.106 -1.11 + NaOH 5.025e-10 5.142e-10 -9.299 -9.289 0.010 (0) +O(0) 1.035e-06 + O2 5.175e-07 5.296e-07 -6.286 -6.276 0.010 (0) +Zn 9.549e-05 + Zn+2 9.544e-05 3.594e-05 -4.020 -4.444 -0.424 (0) + ZnOH+ 5.025e-08 3.927e-08 -7.299 -7.406 -0.107 (0) + Zn(OH)2 4.391e-10 4.493e-10 -9.357 -9.347 0.010 (0) + Zn(OH)3- 1.812e-15 1.416e-15 -14.742 -14.849 -0.107 (0) + Zn(OH)4-2 5.998e-22 2.237e-22 -21.222 -21.650 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -2798,34 +2798,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 6.812e-07 5.623e-07 -6.167 -6.250 -0.083 - OH- 2.329e-08 1.774e-08 -7.633 -7.751 -0.118 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.992 -42.982 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -53.742 -53.869 -0.128 - NH3 0.000e+00 0.000e+00 -56.874 -56.864 0.010 -N(0) 2.980e-07 - N2 1.490e-07 1.525e-07 -6.827 -6.817 0.010 -N(3) 5.489e-13 - NO2- 5.489e-13 4.137e-13 -12.261 -12.383 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 -Na 9.976e-02 - Na+ 9.976e-02 7.810e-02 -1.001 -1.107 -0.106 - NaOH 8.936e-10 9.145e-10 -9.049 -9.039 0.010 -O(0) 7.448e-07 - O2 3.724e-07 3.811e-07 -6.429 -6.419 0.010 -Zn 9.374e-05 - Zn+2 9.365e-05 3.526e-05 -4.028 -4.453 -0.424 - ZnOH+ 8.769e-08 6.853e-08 -7.057 -7.164 -0.107 - Zn(OH)2 1.363e-09 1.394e-09 -8.866 -8.856 0.010 - Zn(OH)3- 1.000e-14 7.814e-15 -14.000 -14.107 -0.107 - Zn(OH)4-2 5.886e-21 2.195e-21 -20.230 -20.659 -0.428 + H+ 6.812e-07 5.623e-07 -6.167 -6.250 -0.083 0.00 + OH- 2.329e-08 1.774e-08 -7.633 -7.751 -0.118 (0) + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.992 -42.982 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -53.742 -53.869 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.874 -56.864 0.010 (0) +N(0) 2.980e-07 + N2 1.490e-07 1.525e-07 -6.827 -6.817 0.010 (0) +N(3) 5.489e-13 + NO2- 5.489e-13 4.137e-13 -12.261 -12.383 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 29.09 +Na 9.976e-02 + Na+ 9.976e-02 7.810e-02 -1.001 -1.107 -0.106 -1.11 + NaOH 8.936e-10 9.145e-10 -9.049 -9.039 0.010 (0) +O(0) 7.448e-07 + O2 3.724e-07 3.811e-07 -6.429 -6.419 0.010 (0) +Zn 9.374e-05 + Zn+2 9.365e-05 3.526e-05 -4.028 -4.453 -0.424 (0) + ZnOH+ 8.769e-08 6.853e-08 -7.057 -7.164 -0.107 (0) + Zn(OH)2 1.363e-09 1.394e-09 -8.866 -8.856 0.010 (0) + Zn(OH)3- 1.000e-14 7.814e-15 -14.000 -14.107 -0.107 (0) + Zn(OH)4-2 5.886e-21 2.195e-21 -20.230 -20.659 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -2932,34 +2932,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 3.831e-07 3.162e-07 -6.417 -6.500 -0.083 - OH- 4.141e-08 3.155e-08 -7.383 -7.501 -0.118 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.921 -42.911 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -53.956 -54.084 -0.128 - NH3 0.000e+00 0.000e+00 -56.838 -56.828 0.010 -N(0) 2.145e-07 - N2 1.073e-07 1.098e-07 -6.970 -6.960 0.010 -N(3) 6.470e-13 - NO2- 6.470e-13 4.876e-13 -12.189 -12.312 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 -Na 9.978e-02 - Na+ 9.978e-02 7.811e-02 -1.001 -1.107 -0.106 - NaOH 1.589e-09 1.626e-09 -8.799 -8.789 0.010 -O(0) 5.360e-07 - O2 2.680e-07 2.742e-07 -6.572 -6.562 0.010 -Zn 9.074e-05 - Zn+2 9.058e-05 3.411e-05 -4.043 -4.467 -0.424 - ZnOH+ 1.508e-07 1.179e-07 -6.822 -6.929 -0.107 - Zn(OH)2 4.168e-09 4.265e-09 -8.380 -8.370 0.010 - Zn(OH)3- 5.439e-14 4.250e-14 -13.264 -13.372 -0.107 - Zn(OH)4-2 5.693e-20 2.123e-20 -19.245 -19.673 -0.428 + H+ 3.831e-07 3.162e-07 -6.417 -6.500 -0.083 0.00 + OH- 4.141e-08 3.155e-08 -7.383 -7.501 -0.118 (0) + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.921 -42.911 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -53.956 -54.084 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.838 -56.828 0.010 (0) +N(0) 2.145e-07 + N2 1.073e-07 1.098e-07 -6.970 -6.960 0.010 (0) +N(3) 6.470e-13 + NO2- 6.470e-13 4.876e-13 -12.189 -12.312 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 29.09 +Na 9.978e-02 + Na+ 9.978e-02 7.811e-02 -1.001 -1.107 -0.106 -1.11 + NaOH 1.589e-09 1.626e-09 -8.799 -8.789 0.010 (0) +O(0) 5.360e-07 + O2 2.680e-07 2.742e-07 -6.572 -6.562 0.010 (0) +Zn 9.074e-05 + Zn+2 9.058e-05 3.411e-05 -4.043 -4.467 -0.424 (0) + ZnOH+ 1.508e-07 1.179e-07 -6.822 -6.929 -0.107 (0) + Zn(OH)2 4.168e-09 4.265e-09 -8.380 -8.370 0.010 (0) + Zn(OH)3- 5.439e-14 4.250e-14 -13.264 -13.372 -0.107 (0) + Zn(OH)4-2 5.693e-20 2.123e-20 -19.245 -19.673 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -3066,34 +3066,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 2.154e-07 1.778e-07 -6.667 -6.750 -0.083 - OH- 7.365e-08 5.610e-08 -7.133 -7.251 -0.118 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.849 -42.839 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -54.170 -54.297 -0.128 - NH3 0.000e+00 0.000e+00 -56.802 -56.792 0.010 -N(0) 1.546e-07 - N2 7.729e-08 7.909e-08 -7.112 -7.102 0.010 -N(3) 7.629e-13 - NO2- 7.629e-13 5.749e-13 -12.118 -12.240 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 -Na 9.980e-02 - Na+ 9.980e-02 7.813e-02 -1.001 -1.107 -0.106 - NaOH 2.827e-09 2.893e-09 -8.549 -8.539 0.010 -O(0) 3.856e-07 - O2 1.928e-07 1.973e-07 -6.715 -6.705 0.010 -Zn 8.483e-05 - Zn+2 8.457e-05 3.184e-05 -4.073 -4.497 -0.424 - ZnOH+ 2.504e-07 1.957e-07 -6.601 -6.708 -0.107 - Zn(OH)2 1.230e-08 1.259e-08 -7.910 -7.900 0.010 - Zn(OH)3- 2.856e-13 2.231e-13 -12.544 -12.651 -0.107 - Zn(OH)4-2 5.315e-19 1.982e-19 -18.274 -18.703 -0.428 + H+ 2.154e-07 1.778e-07 -6.667 -6.750 -0.083 0.00 + OH- 7.365e-08 5.610e-08 -7.133 -7.251 -0.118 (0) + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.849 -42.839 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -54.170 -54.297 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.802 -56.792 0.010 (0) +N(0) 1.546e-07 + N2 7.729e-08 7.909e-08 -7.112 -7.102 0.010 (0) +N(3) 7.629e-13 + NO2- 7.629e-13 5.749e-13 -12.118 -12.240 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 29.09 +Na 9.980e-02 + Na+ 9.980e-02 7.813e-02 -1.001 -1.107 -0.106 -1.11 + NaOH 2.827e-09 2.893e-09 -8.549 -8.539 0.010 (0) +O(0) 3.856e-07 + O2 1.928e-07 1.973e-07 -6.715 -6.705 0.010 (0) +Zn 8.483e-05 + Zn+2 8.457e-05 3.184e-05 -4.073 -4.497 -0.424 (0) + ZnOH+ 2.504e-07 1.957e-07 -6.601 -6.708 -0.107 (0) + Zn(OH)2 1.230e-08 1.259e-08 -7.910 -7.900 0.010 (0) + Zn(OH)3- 2.856e-13 2.231e-13 -12.544 -12.651 -0.107 (0) + Zn(OH)4-2 5.315e-19 1.982e-19 -18.274 -18.703 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -3200,34 +3200,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.310e-07 9.977e-08 -6.883 -7.001 -0.118 - H+ 1.211e-07 1.000e-07 -6.917 -7.000 -0.083 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.778 -42.768 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -54.384 -54.512 -0.128 - NH3 0.000e+00 0.000e+00 -56.767 -56.757 0.010 -N(0) 1.111e-07 - N2 5.553e-08 5.683e-08 -7.255 -7.245 0.010 -N(3) 8.990e-13 - NO2- 8.990e-13 6.775e-13 -12.046 -12.169 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 -Na 9.982e-02 - Na+ 9.982e-02 7.815e-02 -1.001 -1.107 -0.106 - NaOH 5.028e-09 5.146e-09 -8.299 -8.289 0.010 -O(0) 2.777e-07 - O2 1.388e-07 1.421e-07 -6.858 -6.848 0.010 -Zn 7.501e-05 - Zn+2 7.458e-05 2.808e-05 -4.127 -4.552 -0.424 - ZnOH+ 3.927e-07 3.069e-07 -6.406 -6.513 -0.107 - Zn(OH)2 3.432e-08 3.512e-08 -7.465 -7.454 0.010 - Zn(OH)3- 1.416e-12 1.107e-12 -11.849 -11.956 -0.107 - Zn(OH)4-2 4.688e-18 1.748e-18 -17.329 -17.757 -0.428 + OH- 1.310e-07 9.977e-08 -6.883 -7.001 -0.118 (0) + H+ 1.211e-07 1.000e-07 -6.917 -7.000 -0.083 0.00 + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.778 -42.768 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -54.384 -54.512 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.767 -56.757 0.010 (0) +N(0) 1.111e-07 + N2 5.553e-08 5.683e-08 -7.255 -7.245 0.010 (0) +N(3) 8.990e-13 + NO2- 8.990e-13 6.775e-13 -12.046 -12.169 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 29.09 +Na 9.982e-02 + Na+ 9.982e-02 7.815e-02 -1.001 -1.107 -0.106 -1.11 + NaOH 5.028e-09 5.146e-09 -8.299 -8.289 0.010 (0) +O(0) 2.777e-07 + O2 1.388e-07 1.421e-07 -6.858 -6.848 0.010 (0) +Zn 7.501e-05 + Zn+2 7.458e-05 2.808e-05 -4.127 -4.552 -0.424 (0) + ZnOH+ 3.927e-07 3.069e-07 -6.406 -6.513 -0.107 (0) + Zn(OH)2 3.432e-08 3.512e-08 -7.465 -7.454 0.010 (0) + Zn(OH)3- 1.416e-12 1.107e-12 -11.849 -11.956 -0.107 (0) + Zn(OH)4-2 4.688e-18 1.748e-18 -17.329 -17.757 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -3334,34 +3334,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 2.329e-07 1.774e-07 -6.633 -6.751 -0.118 - H+ 6.812e-08 5.623e-08 -7.167 -7.250 -0.083 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.706 -42.696 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -54.599 -54.727 -0.128 - NH3 0.000e+00 0.000e+00 -56.731 -56.721 0.010 -N(0) 7.993e-08 - N2 3.997e-08 4.090e-08 -7.398 -7.388 0.010 -N(3) 1.060e-12 - NO2- 1.060e-12 7.986e-13 -11.975 -12.098 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 -Na 9.985e-02 - Na+ 9.985e-02 7.817e-02 -1.001 -1.107 -0.106 - NaOH 8.944e-09 9.153e-09 -8.048 -8.038 0.010 -O(0) 1.998e-07 - O2 9.992e-08 1.022e-07 -7.000 -6.990 0.010 -Zn 6.245e-05 - Zn+2 6.179e-05 2.327e-05 -4.209 -4.633 -0.424 - ZnOH+ 5.786e-07 4.521e-07 -6.238 -6.345 -0.107 - Zn(OH)2 8.990e-08 9.200e-08 -7.046 -7.036 0.010 - Zn(OH)3- 6.598e-12 5.156e-12 -11.181 -11.288 -0.107 - Zn(OH)4-2 3.883e-17 1.448e-17 -16.411 -16.839 -0.428 + OH- 2.329e-07 1.774e-07 -6.633 -6.751 -0.118 (0) + H+ 6.812e-08 5.623e-08 -7.167 -7.250 -0.083 0.00 + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.706 -42.696 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -54.599 -54.727 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.731 -56.721 0.010 (0) +N(0) 7.993e-08 + N2 3.997e-08 4.090e-08 -7.398 -7.388 0.010 (0) +N(3) 1.060e-12 + NO2- 1.060e-12 7.986e-13 -11.975 -12.098 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.536e-02 -1.000 -1.123 -0.123 29.09 +Na 9.985e-02 + Na+ 9.985e-02 7.817e-02 -1.001 -1.107 -0.106 -1.11 + NaOH 8.944e-09 9.153e-09 -8.048 -8.038 0.010 (0) +O(0) 1.998e-07 + O2 9.992e-08 1.022e-07 -7.000 -6.990 0.010 (0) +Zn 6.245e-05 + Zn+2 6.179e-05 2.327e-05 -4.209 -4.633 -0.424 (0) + ZnOH+ 5.786e-07 4.521e-07 -6.238 -6.345 -0.107 (0) + Zn(OH)2 8.990e-08 9.200e-08 -7.046 -7.036 0.010 (0) + Zn(OH)3- 6.598e-12 5.156e-12 -11.181 -11.288 -0.107 (0) + Zn(OH)4-2 3.883e-17 1.448e-17 -16.411 -16.839 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -3468,34 +3468,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 4.141e-07 3.155e-07 -6.383 -6.501 -0.118 - H+ 3.831e-08 3.162e-08 -7.417 -7.500 -0.083 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.635 -42.625 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -54.813 -54.941 -0.128 - NH3 0.000e+00 0.000e+00 -56.695 -56.685 0.010 -N(0) 5.753e-08 - N2 2.876e-08 2.943e-08 -7.541 -7.531 0.010 -N(3) 1.249e-12 - NO2- 1.249e-12 9.414e-13 -11.903 -12.026 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 -Na 9.988e-02 - Na+ 9.988e-02 7.819e-02 -1.001 -1.107 -0.106 - NaOH 1.591e-08 1.628e-08 -7.798 -7.788 0.010 -O(0) 1.438e-07 - O2 7.191e-08 7.359e-08 -7.143 -7.133 0.010 -Zn 4.942e-05 - Zn+2 4.839e-05 1.822e-05 -4.315 -4.739 -0.424 - ZnOH+ 8.058e-07 6.297e-07 -6.094 -6.201 -0.107 - Zn(OH)2 2.227e-07 2.278e-07 -6.652 -6.642 0.010 - Zn(OH)3- 2.906e-11 2.271e-11 -10.537 -10.644 -0.107 - Zn(OH)4-2 3.041e-16 1.134e-16 -15.517 -15.945 -0.428 + OH- 4.141e-07 3.155e-07 -6.383 -6.501 -0.118 (0) + H+ 3.831e-08 3.162e-08 -7.417 -7.500 -0.083 0.00 + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.635 -42.625 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -54.813 -54.941 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.695 -56.685 0.010 (0) +N(0) 5.753e-08 + N2 2.876e-08 2.943e-08 -7.541 -7.531 0.010 (0) +N(3) 1.249e-12 + NO2- 1.249e-12 9.414e-13 -11.903 -12.026 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 29.09 +Na 9.988e-02 + Na+ 9.988e-02 7.819e-02 -1.001 -1.107 -0.106 -1.11 + NaOH 1.591e-08 1.628e-08 -7.798 -7.788 0.010 (0) +O(0) 1.438e-07 + O2 7.191e-08 7.359e-08 -7.143 -7.133 0.010 (0) +Zn 4.942e-05 + Zn+2 4.839e-05 1.822e-05 -4.315 -4.739 -0.424 (0) + ZnOH+ 8.058e-07 6.297e-07 -6.094 -6.201 -0.107 (0) + Zn(OH)2 2.227e-07 2.278e-07 -6.652 -6.642 0.010 (0) + Zn(OH)3- 2.906e-11 2.271e-11 -10.537 -10.644 -0.107 (0) + Zn(OH)4-2 3.041e-16 1.134e-16 -15.517 -15.945 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -3602,34 +3602,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 7.364e-07 5.610e-07 -6.133 -6.251 -0.118 - H+ 2.154e-08 1.778e-08 -7.667 -7.750 -0.083 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.563 -42.553 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -55.025 -55.153 -0.128 - NH3 0.000e+00 0.000e+00 -56.657 -56.647 0.010 -N(0) 4.168e-08 - N2 2.084e-08 2.132e-08 -7.681 -7.671 0.010 -N(3) 1.474e-12 - NO2- 1.474e-12 1.111e-12 -11.831 -11.954 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 -Na 9.991e-02 - Na+ 9.991e-02 7.821e-02 -1.000 -1.107 -0.106 - NaOH 2.830e-08 2.896e-08 -7.548 -7.538 0.010 -O(0) 1.032e-07 - O2 5.162e-08 5.282e-08 -7.287 -7.277 0.010 -Zn 3.750e-05 - Zn+2 3.592e-05 1.353e-05 -4.445 -4.869 -0.424 - ZnOH+ 1.064e-06 8.312e-07 -5.973 -6.080 -0.107 - Zn(OH)2 5.227e-07 5.349e-07 -6.282 -6.272 0.010 - Zn(OH)3- 1.213e-10 9.479e-11 -9.916 -10.023 -0.107 - Zn(OH)4-2 2.258e-15 8.419e-16 -14.646 -15.075 -0.428 + OH- 7.364e-07 5.610e-07 -6.133 -6.251 -0.118 (0) + H+ 2.154e-08 1.778e-08 -7.667 -7.750 -0.083 0.00 + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.563 -42.553 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -55.025 -55.153 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.657 -56.647 0.010 (0) +N(0) 4.168e-08 + N2 2.084e-08 2.132e-08 -7.681 -7.671 0.010 (0) +N(3) 1.474e-12 + NO2- 1.474e-12 1.111e-12 -11.831 -11.954 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 29.09 +Na 9.991e-02 + Na+ 9.991e-02 7.821e-02 -1.000 -1.107 -0.106 -1.11 + NaOH 2.830e-08 2.896e-08 -7.548 -7.538 0.010 (0) +O(0) 1.032e-07 + O2 5.162e-08 5.282e-08 -7.287 -7.277 0.010 (0) +Zn 3.750e-05 + Zn+2 3.592e-05 1.353e-05 -4.445 -4.869 -0.424 (0) + ZnOH+ 1.064e-06 8.312e-07 -5.973 -6.080 -0.107 (0) + Zn(OH)2 5.227e-07 5.349e-07 -6.282 -6.272 0.010 (0) + Zn(OH)3- 1.213e-10 9.479e-11 -9.916 -10.023 -0.107 (0) + Zn(OH)4-2 2.258e-15 8.419e-16 -14.646 -15.075 -0.428 (0) ------------------------------Saturation indices------------------------------- @@ -3736,34 +3736,34 @@ Hfo_w ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.310e-06 9.977e-07 -5.883 -6.001 -0.118 - H+ 1.211e-08 1.000e-08 -7.917 -8.000 -0.083 - H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -42.492 -42.482 0.010 -N(-3) 0.000e+00 - NH4+ 0.000e+00 0.000e+00 -55.242 -55.369 -0.128 - NH3 0.000e+00 0.000e+00 -56.624 -56.614 0.010 -N(0) 2.980e-08 - N2 1.490e-08 1.525e-08 -7.827 -7.817 0.010 -N(3) 1.736e-12 - NO2- 1.736e-12 1.308e-12 -11.761 -11.883 -0.123 -N(5) 1.000e-01 - NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 -Na 9.993e-02 - Na+ 9.993e-02 7.823e-02 -1.000 -1.107 -0.106 - NaOH 5.034e-08 5.151e-08 -7.298 -7.288 0.010 -O(0) 7.449e-08 - O2 3.725e-08 3.811e-08 -7.429 -7.419 0.010 -Zn 2.761e-05 - Zn+2 2.513e-05 9.463e-06 -4.600 -5.024 -0.424 - ZnOH+ 1.323e-06 1.034e-06 -5.878 -5.985 -0.107 - Zn(OH)2 1.156e-06 1.183e-06 -5.937 -5.927 0.010 - Zn(OH)3- 4.772e-10 3.729e-10 -9.321 -9.428 -0.107 - Zn(OH)4-2 1.579e-14 5.890e-15 -13.802 -14.230 -0.428 + OH- 1.310e-06 9.977e-07 -5.883 -6.001 -0.118 (0) + H+ 1.211e-08 1.000e-08 -7.917 -8.000 -0.083 0.00 + H2O 5.551e+01 9.966e-01 1.744 -0.001 0.000 18.07 +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -42.492 -42.482 0.010 (0) +N(-3) 0.000e+00 + NH4+ 0.000e+00 0.000e+00 -55.242 -55.369 -0.128 17.96 + NH3 0.000e+00 0.000e+00 -56.624 -56.614 0.010 (0) +N(0) 2.980e-08 + N2 1.490e-08 1.525e-08 -7.827 -7.817 0.010 (0) +N(3) 1.736e-12 + NO2- 1.736e-12 1.308e-12 -11.761 -11.883 -0.123 (0) +N(5) 1.000e-01 + NO3- 1.000e-01 7.537e-02 -1.000 -1.123 -0.123 29.09 +Na 9.993e-02 + Na+ 9.993e-02 7.823e-02 -1.000 -1.107 -0.106 -1.11 + NaOH 5.034e-08 5.151e-08 -7.298 -7.288 0.010 (0) +O(0) 7.449e-08 + O2 3.725e-08 3.811e-08 -7.429 -7.419 0.010 (0) +Zn 2.761e-05 + Zn+2 2.513e-05 9.463e-06 -4.600 -5.024 -0.424 (0) + ZnOH+ 1.323e-06 1.034e-06 -5.878 -5.985 -0.107 (0) + Zn(OH)2 1.156e-06 1.183e-06 -5.937 -5.927 0.010 (0) + Zn(OH)3- 4.772e-10 3.729e-10 -9.321 -9.428 -0.107 (0) + Zn(OH)4-2 1.579e-14 5.890e-15 -13.802 -14.230 -0.428 (0) ------------------------------Saturation indices------------------------------- diff --git a/ex9.out b/ex9.out index 67e52687..cce92ac5 100644 --- a/ex9.out +++ b/ex9.out @@ -195,26 +195,26 @@ Initial solution 1. ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - OH- 1.113e-07 1.001e-07 -6.953 -7.000 -0.046 - H+ 1.096e-07 1.000e-07 -6.960 -7.000 -0.040 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -Cl 1.020e-02 - Cl- 1.020e-02 9.171e-03 -1.991 -2.038 -0.046 - Fe_diCl+ 9.149e-07 8.242e-07 -6.039 -6.084 -0.045 -Fe_di 1.000e-04 - Fe_di+2 9.886e-05 6.510e-05 -4.005 -4.186 -0.181 - Fe_diCl+ 9.149e-07 8.242e-07 -6.039 -6.084 -0.045 - Fe_diOH+ 2.285e-07 2.058e-07 -6.641 -6.687 -0.045 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 -Na 1.000e-02 - Na+ 1.000e-02 9.019e-03 -2.000 -2.045 -0.045 - NaOH 5.943e-10 5.957e-10 -9.226 -9.225 0.001 -O(0) 5.466e-04 - O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 + OH- 1.113e-07 1.001e-07 -6.953 -7.000 -0.046 (0) + H+ 1.096e-07 1.000e-07 -6.960 -7.000 -0.040 0.00 + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.07 +Cl 1.020e-02 + Cl- 1.020e-02 9.171e-03 -1.991 -2.038 -0.046 17.82 + Fe_diCl+ 9.149e-07 8.242e-07 -6.039 -6.084 -0.045 (0) +Fe_di 1.000e-04 + Fe_di+2 9.886e-05 6.510e-05 -4.005 -4.186 -0.181 (0) + Fe_diCl+ 9.149e-07 8.242e-07 -6.039 -6.084 -0.045 (0) + Fe_diOH+ 2.285e-07 2.058e-07 -6.641 -6.687 -0.045 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 (0) +Na 1.000e-02 + Na+ 1.000e-02 9.019e-03 -2.000 -2.045 -0.045 -1.21 + NaOH 5.943e-10 5.957e-10 -9.226 -9.225 0.001 (0) +O(0) 5.466e-04 + O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -284,40 +284,40 @@ O2(g) -0.67 -3.56 -2.89 1.000e+01 1.000e+01 -2.645e-07 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 9.821e-07 8.962e-07 -6.008 -6.048 -0.040 - OH- 1.242e-08 1.117e-08 -7.906 -7.952 -0.046 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -Cl 1.020e-02 - Cl- 1.020e-02 9.171e-03 -1.991 -2.038 -0.046 - Fe_diCl+ 9.071e-07 8.172e-07 -6.042 -6.088 -0.045 - Fe_triCl+2 1.330e-13 8.757e-14 -12.876 -13.058 -0.181 - Fe_triCl2+ 3.982e-15 3.587e-15 -14.400 -14.445 -0.045 - Fe_triCl3 3.282e-18 3.290e-18 -17.484 -17.483 0.001 -Fe_di 9.894e-05 - Fe_di+2 9.801e-05 6.455e-05 -4.009 -4.190 -0.181 - Fe_diCl+ 9.071e-07 8.172e-07 -6.042 -6.088 -0.045 - Fe_diOH+ 2.527e-08 2.277e-08 -7.597 -7.643 -0.045 -Fe_tri 1.058e-06 - Fe_tri(OH)2+ 9.336e-07 8.410e-07 -6.030 -6.075 -0.045 - Fe_tri(OH)3 1.206e-07 1.209e-07 -6.919 -6.918 0.001 - Fe_triOH+2 3.457e-09 2.277e-09 -8.461 -8.643 -0.181 - Fe_tri(OH)4- 1.365e-10 1.229e-10 -9.865 -9.910 -0.045 - Fe_tri+3 8.092e-13 3.162e-13 -12.092 -12.500 -0.408 - Fe_triCl+2 1.330e-13 8.757e-14 -12.876 -13.058 -0.181 - Fe_triCl2+ 3.982e-15 3.587e-15 -14.400 -14.445 -0.045 - Fe_tri2(OH)2+4 7.418e-16 1.396e-16 -15.130 -15.855 -0.726 - Fe_triCl3 3.282e-18 3.290e-18 -17.484 -17.483 0.001 - Fe_tri3(OH)4+5 3.336e-19 2.452e-20 -18.477 -19.610 -1.134 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 -Na 1.000e-02 - Na+ 1.000e-02 9.019e-03 -2.000 -2.045 -0.045 - NaOH 6.631e-11 6.647e-11 -10.178 -10.177 0.001 -O(0) 5.466e-04 - O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 + H+ 9.821e-07 8.962e-07 -6.008 -6.048 -0.040 0.00 + OH- 1.242e-08 1.117e-08 -7.906 -7.952 -0.046 (0) + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.07 +Cl 1.020e-02 + Cl- 1.020e-02 9.171e-03 -1.991 -2.038 -0.046 17.87 + Fe_diCl+ 9.071e-07 8.172e-07 -6.042 -6.088 -0.045 (0) + Fe_triCl+2 1.330e-13 8.757e-14 -12.876 -13.058 -0.181 (0) + Fe_triCl2+ 3.982e-15 3.587e-15 -14.400 -14.445 -0.045 (0) + Fe_triCl3 3.282e-18 3.290e-18 -17.484 -17.483 0.001 (0) +Fe_di 9.894e-05 + Fe_di+2 9.801e-05 6.455e-05 -4.009 -4.190 -0.181 (0) + Fe_diCl+ 9.071e-07 8.172e-07 -6.042 -6.088 -0.045 (0) + Fe_diOH+ 2.527e-08 2.277e-08 -7.597 -7.643 -0.045 (0) +Fe_tri 1.058e-06 + Fe_tri(OH)2+ 9.336e-07 8.410e-07 -6.030 -6.075 -0.045 (0) + Fe_tri(OH)3 1.206e-07 1.209e-07 -6.919 -6.918 0.001 (0) + Fe_triOH+2 3.457e-09 2.277e-09 -8.461 -8.643 -0.181 (0) + Fe_tri(OH)4- 1.365e-10 1.229e-10 -9.865 -9.910 -0.045 (0) + Fe_tri+3 8.092e-13 3.162e-13 -12.092 -12.500 -0.408 (0) + Fe_triCl+2 1.330e-13 8.757e-14 -12.876 -13.058 -0.181 (0) + Fe_triCl2+ 3.982e-15 3.587e-15 -14.400 -14.445 -0.045 (0) + Fe_tri2(OH)2+4 7.418e-16 1.396e-16 -15.130 -15.855 -0.726 (0) + Fe_triCl3 3.282e-18 3.290e-18 -17.484 -17.483 0.001 (0) + Fe_tri3(OH)4+5 3.336e-19 2.452e-20 -18.477 -19.610 -1.134 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 (0) +Na 1.000e-02 + Na+ 1.000e-02 9.019e-03 -2.000 -2.045 -0.045 -1.16 + NaOH 6.631e-11 6.647e-11 -10.178 -10.177 0.001 (0) +O(0) 5.466e-04 + O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -382,40 +382,40 @@ O2(g) -0.67 -3.56 -2.89 1.000e+01 1.000e+01 -1.841e-07 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.699e-06 1.550e-06 -5.770 -5.810 -0.040 - OH- 7.183e-09 6.457e-09 -8.144 -8.190 -0.046 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -Cl 1.020e-02 - Cl- 1.020e-02 9.171e-03 -1.991 -2.038 -0.046 - Fe_diCl+ 9.005e-07 8.112e-07 -6.046 -6.091 -0.045 - Fe_triCl+2 7.069e-13 4.656e-13 -12.151 -12.332 -0.181 - Fe_triCl2+ 2.117e-14 1.907e-14 -13.674 -13.720 -0.045 - Fe_triCl3 1.745e-17 1.749e-17 -16.758 -16.757 0.001 -Fe_di 9.821e-05 - Fe_di+2 9.729e-05 6.408e-05 -4.012 -4.193 -0.181 - Fe_diCl+ 9.005e-07 8.112e-07 -6.046 -6.091 -0.045 - Fe_diOH+ 1.451e-08 1.307e-08 -7.838 -7.884 -0.045 -Fe_tri 1.794e-06 - Fe_tri(OH)2+ 1.660e-06 1.495e-06 -5.780 -5.825 -0.045 - Fe_tri(OH)3 1.239e-07 1.242e-07 -6.907 -6.906 0.001 - Fe_triOH+2 1.063e-08 7.000e-09 -7.974 -8.155 -0.181 - Fe_tri(OH)4- 8.110e-11 7.306e-11 -10.091 -10.136 -0.045 - Fe_tri+3 4.302e-12 1.681e-12 -11.366 -11.774 -0.408 - Fe_triCl+2 7.069e-13 4.656e-13 -12.151 -12.332 -0.181 - Fe_triCl2+ 2.117e-14 1.907e-14 -13.674 -13.720 -0.045 - Fe_tri2(OH)2+4 7.010e-15 1.319e-15 -14.154 -14.880 -0.726 - Fe_triCl3 1.745e-17 1.749e-17 -16.758 -16.757 0.001 - Fe_tri3(OH)4+5 5.604e-18 4.120e-19 -17.252 -18.385 -1.134 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 -Na 1.000e-02 - Na+ 1.000e-02 9.019e-03 -2.000 -2.045 -0.045 - NaOH 3.834e-11 3.843e-11 -10.416 -10.415 0.001 -O(0) 5.466e-04 - O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 + H+ 1.699e-06 1.550e-06 -5.770 -5.810 -0.040 0.00 + OH- 7.183e-09 6.457e-09 -8.144 -8.190 -0.046 (0) + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.07 +Cl 1.020e-02 + Cl- 1.020e-02 9.171e-03 -1.991 -2.038 -0.046 17.87 + Fe_diCl+ 9.005e-07 8.112e-07 -6.046 -6.091 -0.045 (0) + Fe_triCl+2 7.069e-13 4.656e-13 -12.151 -12.332 -0.181 (0) + Fe_triCl2+ 2.117e-14 1.907e-14 -13.674 -13.720 -0.045 (0) + Fe_triCl3 1.745e-17 1.749e-17 -16.758 -16.757 0.001 (0) +Fe_di 9.821e-05 + Fe_di+2 9.729e-05 6.408e-05 -4.012 -4.193 -0.181 (0) + Fe_diCl+ 9.005e-07 8.112e-07 -6.046 -6.091 -0.045 (0) + Fe_diOH+ 1.451e-08 1.307e-08 -7.838 -7.884 -0.045 (0) +Fe_tri 1.794e-06 + Fe_tri(OH)2+ 1.660e-06 1.495e-06 -5.780 -5.825 -0.045 (0) + Fe_tri(OH)3 1.239e-07 1.242e-07 -6.907 -6.906 0.001 (0) + Fe_triOH+2 1.063e-08 7.000e-09 -7.974 -8.155 -0.181 (0) + Fe_tri(OH)4- 8.110e-11 7.306e-11 -10.091 -10.136 -0.045 (0) + Fe_tri+3 4.302e-12 1.681e-12 -11.366 -11.774 -0.408 (0) + Fe_triCl+2 7.069e-13 4.656e-13 -12.151 -12.332 -0.181 (0) + Fe_triCl2+ 2.117e-14 1.907e-14 -13.674 -13.720 -0.045 (0) + Fe_tri2(OH)2+4 7.010e-15 1.319e-15 -14.154 -14.880 -0.726 (0) + Fe_triCl3 1.745e-17 1.749e-17 -16.758 -16.757 0.001 (0) + Fe_tri3(OH)4+5 5.604e-18 4.120e-19 -17.252 -18.385 -1.134 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 (0) +Na 1.000e-02 + Na+ 1.000e-02 9.019e-03 -2.000 -2.045 -0.045 -1.16 + NaOH 3.834e-11 3.843e-11 -10.416 -10.415 0.001 (0) +O(0) 5.466e-04 + O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -480,40 +480,40 @@ O2(g) -0.67 -3.56 -2.89 1.000e+01 1.000e+01 -4.036e-07 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 3.274e-06 2.988e-06 -5.485 -5.525 -0.040 - OH- 3.726e-09 3.349e-09 -8.429 -8.475 -0.046 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -Cl 1.020e-02 - Cl- 1.020e-02 9.171e-03 -1.991 -2.038 -0.046 - Fe_diCl+ 8.857e-07 7.979e-07 -6.053 -6.098 -0.045 - Fe_triCl+2 5.132e-12 3.380e-12 -11.290 -11.471 -0.181 - Fe_triCl2+ 1.537e-13 1.385e-13 -12.813 -12.859 -0.045 - Fe_triCl3 1.267e-16 1.270e-16 -15.897 -15.896 0.001 -Fe_di 9.659e-05 - Fe_di+2 9.570e-05 6.303e-05 -4.019 -4.200 -0.181 - Fe_diCl+ 8.857e-07 7.979e-07 -6.053 -6.098 -0.045 - Fe_diOH+ 7.403e-09 6.669e-09 -8.131 -8.176 -0.045 -Fe_tri 3.408e-06 - Fe_tri(OH)2+ 3.242e-06 2.921e-06 -5.489 -5.534 -0.045 - Fe_tri(OH)3 1.256e-07 1.259e-07 -6.901 -6.900 0.001 - Fe_triOH+2 4.003e-08 2.636e-08 -7.398 -7.579 -0.181 - Fe_tri(OH)4- 4.265e-11 3.842e-11 -10.370 -10.415 -0.045 - Fe_tri+3 3.123e-11 1.220e-11 -10.505 -10.913 -0.408 - Fe_triCl+2 5.132e-12 3.380e-12 -11.290 -11.471 -0.181 - Fe_triCl2+ 1.537e-13 1.385e-13 -12.813 -12.859 -0.045 - Fe_tri2(OH)2+4 9.943e-14 1.871e-14 -13.002 -13.728 -0.725 - Fe_tri3(OH)4+5 1.553e-16 1.142e-17 -15.809 -16.942 -1.134 - Fe_triCl3 1.267e-16 1.270e-16 -15.897 -15.896 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 -Na 1.000e-02 - Na+ 1.000e-02 9.019e-03 -2.000 -2.045 -0.045 - NaOH 1.989e-11 1.994e-11 -10.701 -10.700 0.001 -O(0) 5.466e-04 - O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 + H+ 3.274e-06 2.988e-06 -5.485 -5.525 -0.040 0.00 + OH- 3.726e-09 3.349e-09 -8.429 -8.475 -0.046 (0) + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.07 +Cl 1.020e-02 + Cl- 1.020e-02 9.171e-03 -1.991 -2.038 -0.046 17.87 + Fe_diCl+ 8.857e-07 7.979e-07 -6.053 -6.098 -0.045 (0) + Fe_triCl+2 5.132e-12 3.380e-12 -11.290 -11.471 -0.181 (0) + Fe_triCl2+ 1.537e-13 1.385e-13 -12.813 -12.859 -0.045 (0) + Fe_triCl3 1.267e-16 1.270e-16 -15.897 -15.896 0.001 (0) +Fe_di 9.659e-05 + Fe_di+2 9.570e-05 6.303e-05 -4.019 -4.200 -0.181 (0) + Fe_diCl+ 8.857e-07 7.979e-07 -6.053 -6.098 -0.045 (0) + Fe_diOH+ 7.403e-09 6.669e-09 -8.131 -8.176 -0.045 (0) +Fe_tri 3.408e-06 + Fe_tri(OH)2+ 3.242e-06 2.921e-06 -5.489 -5.534 -0.045 (0) + Fe_tri(OH)3 1.256e-07 1.259e-07 -6.901 -6.900 0.001 (0) + Fe_triOH+2 4.003e-08 2.636e-08 -7.398 -7.579 -0.181 (0) + Fe_tri(OH)4- 4.265e-11 3.842e-11 -10.370 -10.415 -0.045 (0) + Fe_tri+3 3.123e-11 1.220e-11 -10.505 -10.913 -0.408 (0) + Fe_triCl+2 5.132e-12 3.380e-12 -11.290 -11.471 -0.181 (0) + Fe_triCl2+ 1.537e-13 1.385e-13 -12.813 -12.859 -0.045 (0) + Fe_tri2(OH)2+4 9.943e-14 1.871e-14 -13.002 -13.728 -0.725 (0) + Fe_tri3(OH)4+5 1.553e-16 1.142e-17 -15.809 -16.942 -1.134 (0) + Fe_triCl3 1.267e-16 1.270e-16 -15.897 -15.896 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 (0) +Na 1.000e-02 + Na+ 1.000e-02 9.019e-03 -2.000 -2.045 -0.045 -1.16 + NaOH 1.989e-11 1.994e-11 -10.701 -10.700 0.001 (0) +O(0) 5.466e-04 + O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -578,40 +578,40 @@ O2(g) -0.67 -3.56 -2.89 1.000e+01 1.000e+01 -4.883e-07 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 5.163e-06 4.711e-06 -5.287 -5.327 -0.040 - OH- 2.363e-09 2.124e-09 -8.627 -8.673 -0.046 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -Cl 1.020e-02 - Cl- 1.020e-02 9.171e-03 -1.991 -2.038 -0.046 - Fe_diCl+ 8.679e-07 7.819e-07 -6.062 -6.107 -0.045 - Fe_triCl+2 2.021e-11 1.331e-11 -10.694 -10.876 -0.181 - Fe_triCl2+ 6.053e-13 5.453e-13 -12.218 -12.263 -0.045 - Fe_triCl3 4.990e-16 5.001e-16 -15.302 -15.301 0.001 -Fe_di 9.464e-05 - Fe_di+2 9.377e-05 6.176e-05 -4.028 -4.209 -0.181 - Fe_diCl+ 8.679e-07 7.819e-07 -6.062 -6.107 -0.045 - Fe_diOH+ 4.600e-09 4.144e-09 -8.337 -8.383 -0.045 -Fe_tri 5.361e-06 - Fe_tri(OH)2+ 5.135e-06 4.626e-06 -5.289 -5.335 -0.045 - Fe_tri(OH)3 1.261e-07 1.264e-07 -6.899 -6.898 0.001 - Fe_triOH+2 9.996e-08 6.584e-08 -7.000 -7.182 -0.181 - Fe_tri+3 1.230e-10 4.806e-11 -9.910 -10.318 -0.408 - Fe_tri(OH)4- 2.716e-11 2.447e-11 -10.566 -10.611 -0.045 - Fe_triCl+2 2.021e-11 1.331e-11 -10.694 -10.876 -0.181 - Fe_tri2(OH)2+4 6.200e-13 1.167e-13 -12.208 -12.933 -0.725 - Fe_triCl2+ 6.053e-13 5.453e-13 -12.218 -12.263 -0.045 - Fe_tri3(OH)4+5 1.533e-15 1.128e-16 -14.814 -15.948 -1.133 - Fe_triCl3 4.990e-16 5.001e-16 -15.302 -15.301 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 -Na 1.000e-02 - Na+ 1.000e-02 9.019e-03 -2.000 -2.045 -0.045 - NaOH 1.261e-11 1.264e-11 -10.899 -10.898 0.001 -O(0) 5.466e-04 - O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 + H+ 5.163e-06 4.711e-06 -5.287 -5.327 -0.040 0.00 + OH- 2.363e-09 2.124e-09 -8.627 -8.673 -0.046 (0) + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.07 +Cl 1.020e-02 + Cl- 1.020e-02 9.171e-03 -1.991 -2.038 -0.046 17.87 + Fe_diCl+ 8.679e-07 7.819e-07 -6.062 -6.107 -0.045 (0) + Fe_triCl+2 2.021e-11 1.331e-11 -10.694 -10.876 -0.181 (0) + Fe_triCl2+ 6.053e-13 5.453e-13 -12.218 -12.263 -0.045 (0) + Fe_triCl3 4.990e-16 5.001e-16 -15.302 -15.301 0.001 (0) +Fe_di 9.464e-05 + Fe_di+2 9.377e-05 6.176e-05 -4.028 -4.209 -0.181 (0) + Fe_diCl+ 8.679e-07 7.819e-07 -6.062 -6.107 -0.045 (0) + Fe_diOH+ 4.600e-09 4.144e-09 -8.337 -8.383 -0.045 (0) +Fe_tri 5.361e-06 + Fe_tri(OH)2+ 5.135e-06 4.626e-06 -5.289 -5.335 -0.045 (0) + Fe_tri(OH)3 1.261e-07 1.264e-07 -6.899 -6.898 0.001 (0) + Fe_triOH+2 9.996e-08 6.584e-08 -7.000 -7.182 -0.181 (0) + Fe_tri+3 1.230e-10 4.806e-11 -9.910 -10.318 -0.408 (0) + Fe_tri(OH)4- 2.716e-11 2.447e-11 -10.566 -10.611 -0.045 (0) + Fe_triCl+2 2.021e-11 1.331e-11 -10.694 -10.876 -0.181 (0) + Fe_tri2(OH)2+4 6.200e-13 1.167e-13 -12.208 -12.933 -0.725 (0) + Fe_triCl2+ 6.053e-13 5.453e-13 -12.218 -12.263 -0.045 (0) + Fe_tri3(OH)4+5 1.533e-15 1.128e-16 -14.814 -15.948 -1.133 (0) + Fe_triCl3 4.990e-16 5.001e-16 -15.302 -15.301 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 (0) +Na 1.000e-02 + Na+ 1.000e-02 9.019e-03 -2.000 -2.045 -0.045 -1.16 + NaOH 1.261e-11 1.264e-11 -10.899 -10.898 0.001 (0) +O(0) 5.466e-04 + O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -676,40 +676,40 @@ O2(g) -0.67 -3.56 -2.89 1.000e+01 1.000e+01 -4.689e-07 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 6.954e-06 6.346e-06 -5.158 -5.197 -0.040 - OH- 1.754e-09 1.577e-09 -8.756 -8.802 -0.046 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -Cl 1.020e-02 - Cl- 1.020e-02 9.171e-03 -1.991 -2.038 -0.046 - Fe_diCl+ 8.507e-07 7.664e-07 -6.070 -6.116 -0.045 - Fe_triCl+2 4.947e-11 3.258e-11 -10.306 -10.487 -0.181 - Fe_triCl2+ 1.482e-12 1.335e-12 -11.829 -11.875 -0.045 - Fe_triCl3 1.221e-15 1.224e-15 -14.913 -14.912 0.001 -Fe_di 9.276e-05 - Fe_di+2 9.191e-05 6.054e-05 -4.037 -4.218 -0.181 - Fe_diCl+ 8.507e-07 7.664e-07 -6.070 -6.116 -0.045 - Fe_diOH+ 3.347e-09 3.016e-09 -8.475 -8.521 -0.045 -Fe_tri 7.236e-06 - Fe_tri(OH)2+ 6.928e-06 6.241e-06 -5.159 -5.205 -0.045 - Fe_triOH+2 1.817e-07 1.196e-07 -6.741 -6.922 -0.181 - Fe_tri(OH)3 1.263e-07 1.266e-07 -6.898 -6.897 0.001 - Fe_tri+3 3.010e-10 1.176e-10 -9.521 -9.929 -0.408 - Fe_triCl+2 4.947e-11 3.258e-11 -10.306 -10.487 -0.181 - Fe_tri(OH)4- 2.020e-11 1.819e-11 -10.695 -10.740 -0.045 - Fe_tri2(OH)2+4 2.047e-12 3.853e-13 -11.689 -12.414 -0.725 - Fe_triCl2+ 1.482e-12 1.335e-12 -11.829 -11.875 -0.045 - Fe_tri3(OH)4+5 6.830e-15 5.024e-16 -14.166 -15.299 -1.133 - Fe_triCl3 1.221e-15 1.224e-15 -14.913 -14.912 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 -Na 1.000e-02 - Na+ 1.000e-02 9.019e-03 -2.000 -2.045 -0.045 - NaOH 9.365e-12 9.387e-12 -11.029 -11.027 0.001 -O(0) 5.466e-04 - O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 + H+ 6.954e-06 6.346e-06 -5.158 -5.197 -0.040 0.00 + OH- 1.754e-09 1.577e-09 -8.756 -8.802 -0.046 (0) + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.07 +Cl 1.020e-02 + Cl- 1.020e-02 9.171e-03 -1.991 -2.038 -0.046 17.87 + Fe_diCl+ 8.507e-07 7.664e-07 -6.070 -6.116 -0.045 (0) + Fe_triCl+2 4.947e-11 3.258e-11 -10.306 -10.487 -0.181 (0) + Fe_triCl2+ 1.482e-12 1.335e-12 -11.829 -11.875 -0.045 (0) + Fe_triCl3 1.221e-15 1.224e-15 -14.913 -14.912 0.001 (0) +Fe_di 9.276e-05 + Fe_di+2 9.191e-05 6.054e-05 -4.037 -4.218 -0.181 (0) + Fe_diCl+ 8.507e-07 7.664e-07 -6.070 -6.116 -0.045 (0) + Fe_diOH+ 3.347e-09 3.016e-09 -8.475 -8.521 -0.045 (0) +Fe_tri 7.236e-06 + Fe_tri(OH)2+ 6.928e-06 6.241e-06 -5.159 -5.205 -0.045 (0) + Fe_triOH+2 1.817e-07 1.196e-07 -6.741 -6.922 -0.181 (0) + Fe_tri(OH)3 1.263e-07 1.266e-07 -6.898 -6.897 0.001 (0) + Fe_tri+3 3.010e-10 1.176e-10 -9.521 -9.929 -0.408 (0) + Fe_triCl+2 4.947e-11 3.258e-11 -10.306 -10.487 -0.181 (0) + Fe_tri(OH)4- 2.020e-11 1.819e-11 -10.695 -10.740 -0.045 (0) + Fe_tri2(OH)2+4 2.047e-12 3.853e-13 -11.689 -12.414 -0.725 (0) + Fe_triCl2+ 1.482e-12 1.335e-12 -11.829 -11.875 -0.045 (0) + Fe_tri3(OH)4+5 6.830e-15 5.024e-16 -14.166 -15.299 -1.133 (0) + Fe_triCl3 1.221e-15 1.224e-15 -14.913 -14.912 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 (0) +Na 1.000e-02 + Na+ 1.000e-02 9.019e-03 -2.000 -2.045 -0.045 -1.16 + NaOH 9.365e-12 9.387e-12 -11.029 -11.027 0.001 (0) +O(0) 5.466e-04 + O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -774,40 +774,40 @@ O2(g) -0.67 -3.56 -2.89 1.000e+01 1.000e+01 -6.017e-07 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 9.220e-06 8.414e-06 -5.035 -5.075 -0.040 - OH- 1.323e-09 1.189e-09 -8.878 -8.925 -0.046 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -Cl 1.020e-02 - Cl- 1.020e-02 9.172e-03 -1.991 -2.038 -0.046 - Fe_diCl+ 8.287e-07 7.466e-07 -6.082 -6.127 -0.045 - Fe_triCl+2 1.154e-10 7.603e-11 -9.938 -10.119 -0.181 - Fe_triCl2+ 3.457e-12 3.115e-12 -11.461 -11.507 -0.045 - Fe_triCl3 2.850e-15 2.857e-15 -14.545 -14.544 0.001 -Fe_di 9.036e-05 - Fe_di+2 8.953e-05 5.897e-05 -4.048 -4.229 -0.181 - Fe_diCl+ 8.287e-07 7.466e-07 -6.082 -6.127 -0.045 - Fe_diOH+ 2.459e-09 2.216e-09 -8.609 -8.655 -0.045 -Fe_tri 9.642e-06 - Fe_tri(OH)2+ 9.195e-06 8.284e-06 -5.036 -5.082 -0.045 - Fe_triOH+2 3.197e-07 2.106e-07 -6.495 -6.677 -0.181 - Fe_tri(OH)3 1.265e-07 1.268e-07 -6.898 -6.897 0.001 - Fe_tri+3 7.023e-10 2.745e-10 -9.153 -9.561 -0.408 - Fe_triCl+2 1.154e-10 7.603e-11 -9.938 -10.119 -0.181 - Fe_tri(OH)4- 1.525e-11 1.374e-11 -10.817 -10.862 -0.045 - Fe_tri2(OH)2+4 6.340e-12 1.193e-12 -11.198 -11.923 -0.725 - Fe_triCl2+ 3.457e-12 3.115e-12 -11.461 -11.507 -0.045 - Fe_tri3(OH)4+5 2.807e-14 2.065e-15 -13.552 -14.685 -1.133 - Fe_triCl3 2.850e-15 2.857e-15 -14.545 -14.544 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 -Na 1.000e-02 - Na+ 1.000e-02 9.020e-03 -2.000 -2.045 -0.045 - NaOH 7.063e-12 7.080e-12 -11.151 -11.150 0.001 -O(0) 5.466e-04 - O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 + H+ 9.220e-06 8.414e-06 -5.035 -5.075 -0.040 0.00 + OH- 1.323e-09 1.189e-09 -8.878 -8.925 -0.046 (0) + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.07 +Cl 1.020e-02 + Cl- 1.020e-02 9.172e-03 -1.991 -2.038 -0.046 17.87 + Fe_diCl+ 8.287e-07 7.466e-07 -6.082 -6.127 -0.045 (0) + Fe_triCl+2 1.154e-10 7.603e-11 -9.938 -10.119 -0.181 (0) + Fe_triCl2+ 3.457e-12 3.115e-12 -11.461 -11.507 -0.045 (0) + Fe_triCl3 2.850e-15 2.857e-15 -14.545 -14.544 0.001 (0) +Fe_di 9.036e-05 + Fe_di+2 8.953e-05 5.897e-05 -4.048 -4.229 -0.181 (0) + Fe_diCl+ 8.287e-07 7.466e-07 -6.082 -6.127 -0.045 (0) + Fe_diOH+ 2.459e-09 2.216e-09 -8.609 -8.655 -0.045 (0) +Fe_tri 9.642e-06 + Fe_tri(OH)2+ 9.195e-06 8.284e-06 -5.036 -5.082 -0.045 (0) + Fe_triOH+2 3.197e-07 2.106e-07 -6.495 -6.677 -0.181 (0) + Fe_tri(OH)3 1.265e-07 1.268e-07 -6.898 -6.897 0.001 (0) + Fe_tri+3 7.023e-10 2.745e-10 -9.153 -9.561 -0.408 (0) + Fe_triCl+2 1.154e-10 7.603e-11 -9.938 -10.119 -0.181 (0) + Fe_tri(OH)4- 1.525e-11 1.374e-11 -10.817 -10.862 -0.045 (0) + Fe_tri2(OH)2+4 6.340e-12 1.193e-12 -11.198 -11.923 -0.725 (0) + Fe_triCl2+ 3.457e-12 3.115e-12 -11.461 -11.507 -0.045 (0) + Fe_tri3(OH)4+5 2.807e-14 2.065e-15 -13.552 -14.685 -1.133 (0) + Fe_triCl3 2.850e-15 2.857e-15 -14.545 -14.544 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 (0) +Na 1.000e-02 + Na+ 1.000e-02 9.020e-03 -2.000 -2.045 -0.045 -1.16 + NaOH 7.063e-12 7.080e-12 -11.151 -11.150 0.001 (0) +O(0) 5.466e-04 + O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -872,40 +872,40 @@ O2(g) -0.67 -3.56 -2.89 1.000e+01 1.000e+01 -6.156e-07 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.150e-05 1.050e-05 -4.939 -4.979 -0.040 - OH- 1.061e-09 9.534e-10 -8.974 -9.021 -0.046 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -Cl 1.020e-02 - Cl- 1.020e-02 9.172e-03 -1.991 -2.038 -0.046 - Fe_diCl+ 8.062e-07 7.263e-07 -6.094 -6.139 -0.045 - Fe_triCl+2 2.242e-10 1.477e-10 -9.649 -9.831 -0.181 - Fe_triCl2+ 6.716e-12 6.050e-12 -11.173 -11.218 -0.045 - Fe_triCl3 5.536e-15 5.549e-15 -14.257 -14.256 0.001 -Fe_di 8.790e-05 - Fe_di+2 8.709e-05 5.737e-05 -4.060 -4.241 -0.181 - Fe_diCl+ 8.062e-07 7.263e-07 -6.094 -6.139 -0.045 - Fe_diOH+ 1.918e-09 1.728e-09 -8.717 -8.763 -0.045 -Fe_tri 1.210e-05 - Fe_tri(OH)2+ 1.148e-05 1.034e-05 -4.940 -4.985 -0.045 - Fe_triOH+2 4.978e-07 3.279e-07 -6.303 -6.484 -0.181 - Fe_tri(OH)3 1.266e-07 1.269e-07 -6.898 -6.897 0.001 - Fe_tri+3 1.364e-09 5.332e-10 -8.865 -9.273 -0.408 - Fe_triCl+2 2.242e-10 1.477e-10 -9.649 -9.831 -0.181 - Fe_tri2(OH)2+4 1.537e-11 2.894e-12 -10.813 -11.539 -0.725 - Fe_tri(OH)4- 1.223e-11 1.102e-11 -10.912 -10.958 -0.045 - Fe_triCl2+ 6.716e-12 6.050e-12 -11.173 -11.218 -0.045 - Fe_tri3(OH)4+5 8.494e-14 6.251e-15 -13.071 -14.204 -1.133 - Fe_triCl3 5.536e-15 5.549e-15 -14.257 -14.256 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 -Na 1.000e-02 - Na+ 1.000e-02 9.020e-03 -2.000 -2.045 -0.045 - NaOH 5.662e-12 5.676e-12 -11.247 -11.246 0.001 -O(0) 5.466e-04 - O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 + H+ 1.150e-05 1.050e-05 -4.939 -4.979 -0.040 0.00 + OH- 1.061e-09 9.534e-10 -8.974 -9.021 -0.046 (0) + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.07 +Cl 1.020e-02 + Cl- 1.020e-02 9.172e-03 -1.991 -2.038 -0.046 17.87 + Fe_diCl+ 8.062e-07 7.263e-07 -6.094 -6.139 -0.045 (0) + Fe_triCl+2 2.242e-10 1.477e-10 -9.649 -9.831 -0.181 (0) + Fe_triCl2+ 6.716e-12 6.050e-12 -11.173 -11.218 -0.045 (0) + Fe_triCl3 5.536e-15 5.549e-15 -14.257 -14.256 0.001 (0) +Fe_di 8.790e-05 + Fe_di+2 8.709e-05 5.737e-05 -4.060 -4.241 -0.181 (0) + Fe_diCl+ 8.062e-07 7.263e-07 -6.094 -6.139 -0.045 (0) + Fe_diOH+ 1.918e-09 1.728e-09 -8.717 -8.763 -0.045 (0) +Fe_tri 1.210e-05 + Fe_tri(OH)2+ 1.148e-05 1.034e-05 -4.940 -4.985 -0.045 (0) + Fe_triOH+2 4.978e-07 3.279e-07 -6.303 -6.484 -0.181 (0) + Fe_tri(OH)3 1.266e-07 1.269e-07 -6.898 -6.897 0.001 (0) + Fe_tri+3 1.364e-09 5.332e-10 -8.865 -9.273 -0.408 (0) + Fe_triCl+2 2.242e-10 1.477e-10 -9.649 -9.831 -0.181 (0) + Fe_tri2(OH)2+4 1.537e-11 2.894e-12 -10.813 -11.539 -0.725 (0) + Fe_tri(OH)4- 1.223e-11 1.102e-11 -10.912 -10.958 -0.045 (0) + Fe_triCl2+ 6.716e-12 6.050e-12 -11.173 -11.218 -0.045 (0) + Fe_tri3(OH)4+5 8.494e-14 6.251e-15 -13.071 -14.204 -1.133 (0) + Fe_triCl3 5.536e-15 5.549e-15 -14.257 -14.256 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 (0) +Na 1.000e-02 + Na+ 1.000e-02 9.020e-03 -2.000 -2.045 -0.045 -1.16 + NaOH 5.662e-12 5.676e-12 -11.247 -11.246 0.001 (0) +O(0) 5.466e-04 + O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -970,40 +970,40 @@ O2(g) -0.67 -3.56 -2.89 1.000e+01 1.000e+01 -7.722e-07 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.431e-05 1.306e-05 -4.844 -4.884 -0.040 - OH- 8.523e-10 7.662e-10 -9.069 -9.116 -0.046 - H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 -Cl 1.020e-02 - Cl- 1.020e-02 9.172e-03 -1.991 -2.038 -0.046 - Fe_diCl+ 7.779e-07 7.008e-07 -6.109 -6.154 -0.045 - Fe_triCl+2 4.323e-10 2.848e-10 -9.364 -9.546 -0.181 - Fe_triCl2+ 1.295e-11 1.167e-11 -10.888 -10.933 -0.045 - Fe_triCl3 1.068e-14 1.070e-14 -13.972 -13.971 0.001 -Fe_di 8.481e-05 - Fe_di+2 8.403e-05 5.535e-05 -4.076 -4.257 -0.181 - Fe_diCl+ 7.779e-07 7.008e-07 -6.109 -6.154 -0.045 - Fe_diOH+ 1.487e-09 1.340e-09 -8.828 -8.873 -0.045 -Fe_tri 1.519e-05 - Fe_tri(OH)2+ 1.429e-05 1.288e-05 -4.845 -4.890 -0.045 - Fe_triOH+2 7.712e-07 5.080e-07 -6.113 -6.294 -0.181 - Fe_tri(OH)3 1.266e-07 1.269e-07 -6.897 -6.896 0.001 - Fe_tri+3 2.630e-09 1.028e-09 -8.580 -8.988 -0.408 - Fe_triCl+2 4.323e-10 2.848e-10 -9.364 -9.546 -0.181 - Fe_tri2(OH)2+4 3.689e-11 6.947e-12 -10.433 -11.158 -0.725 - Fe_triCl2+ 1.295e-11 1.167e-11 -10.888 -10.933 -0.045 - Fe_tri(OH)4- 9.835e-12 8.861e-12 -11.007 -11.053 -0.045 - Fe_tri3(OH)4+5 2.539e-13 1.869e-14 -12.595 -13.728 -1.133 - Fe_triCl3 1.068e-14 1.070e-14 -13.972 -13.971 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 -Na 1.000e-02 - Na+ 1.000e-02 9.020e-03 -2.000 -2.045 -0.045 - NaOH 4.550e-12 4.561e-12 -11.342 -11.341 0.001 -O(0) 5.466e-04 - O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 + H+ 1.431e-05 1.306e-05 -4.844 -4.884 -0.040 0.00 + OH- 8.523e-10 7.662e-10 -9.069 -9.116 -0.046 (0) + H2O 5.551e+01 9.997e-01 1.744 -0.000 0.000 18.07 +Cl 1.020e-02 + Cl- 1.020e-02 9.172e-03 -1.991 -2.038 -0.046 17.87 + Fe_diCl+ 7.779e-07 7.008e-07 -6.109 -6.154 -0.045 (0) + Fe_triCl+2 4.323e-10 2.848e-10 -9.364 -9.546 -0.181 (0) + Fe_triCl2+ 1.295e-11 1.167e-11 -10.888 -10.933 -0.045 (0) + Fe_triCl3 1.068e-14 1.070e-14 -13.972 -13.971 0.001 (0) +Fe_di 8.481e-05 + Fe_di+2 8.403e-05 5.535e-05 -4.076 -4.257 -0.181 (0) + Fe_diCl+ 7.779e-07 7.008e-07 -6.109 -6.154 -0.045 (0) + Fe_diOH+ 1.487e-09 1.340e-09 -8.828 -8.873 -0.045 (0) +Fe_tri 1.519e-05 + Fe_tri(OH)2+ 1.429e-05 1.288e-05 -4.845 -4.890 -0.045 (0) + Fe_triOH+2 7.712e-07 5.080e-07 -6.113 -6.294 -0.181 (0) + Fe_tri(OH)3 1.266e-07 1.269e-07 -6.897 -6.896 0.001 (0) + Fe_tri+3 2.630e-09 1.028e-09 -8.580 -8.988 -0.408 (0) + Fe_triCl+2 4.323e-10 2.848e-10 -9.364 -9.546 -0.181 (0) + Fe_tri2(OH)2+4 3.689e-11 6.947e-12 -10.433 -11.158 -0.725 (0) + Fe_triCl2+ 1.295e-11 1.167e-11 -10.888 -10.933 -0.045 (0) + Fe_tri(OH)4- 9.835e-12 8.861e-12 -11.007 -11.053 -0.045 (0) + Fe_tri3(OH)4+5 2.539e-13 1.869e-14 -12.595 -13.728 -1.133 (0) + Fe_triCl3 1.068e-14 1.070e-14 -13.972 -13.971 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 (0) +Na 1.000e-02 + Na+ 1.000e-02 9.020e-03 -2.000 -2.045 -0.045 -1.16 + NaOH 4.550e-12 4.561e-12 -11.342 -11.341 0.001 (0) +O(0) 5.466e-04 + O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -1068,40 +1068,40 @@ O2(g) -0.67 -3.56 -2.89 1.000e+01 1.000e+01 -5.394e-07 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.624e-05 1.482e-05 -4.789 -4.829 -0.040 - OH- 7.509e-10 6.751e-10 -9.124 -9.171 -0.046 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Cl 1.020e-02 - Cl- 1.020e-02 9.172e-03 -1.991 -2.038 -0.046 - Fe_diCl+ 7.581e-07 6.830e-07 -6.120 -6.166 -0.045 - Fe_triCl+2 6.322e-10 4.164e-10 -9.199 -9.380 -0.181 - Fe_triCl2+ 1.894e-11 1.706e-11 -10.723 -10.768 -0.045 - Fe_triCl3 1.561e-14 1.565e-14 -13.807 -13.806 0.001 -Fe_di 8.265e-05 - Fe_di+2 8.189e-05 5.395e-05 -4.087 -4.268 -0.181 - Fe_diCl+ 7.581e-07 6.830e-07 -6.120 -6.166 -0.045 - Fe_diOH+ 1.277e-09 1.150e-09 -8.894 -8.939 -0.045 -Fe_tri 1.735e-05 - Fe_tri(OH)2+ 1.622e-05 1.462e-05 -4.790 -4.835 -0.045 - Fe_triOH+2 9.937e-07 6.546e-07 -6.003 -6.184 -0.181 - Fe_tri(OH)3 1.267e-07 1.270e-07 -6.897 -6.896 0.001 - Fe_tri+3 3.845e-09 1.503e-09 -8.415 -8.823 -0.408 - Fe_triCl+2 6.322e-10 4.164e-10 -9.199 -9.380 -0.181 - Fe_tri2(OH)2+4 6.124e-11 1.153e-11 -10.213 -10.938 -0.725 - Fe_triCl2+ 1.894e-11 1.706e-11 -10.723 -10.768 -0.045 - Fe_tri(OH)4- 8.668e-12 7.809e-12 -11.062 -11.107 -0.045 - Fe_tri3(OH)4+5 4.783e-13 3.522e-14 -12.320 -13.453 -1.133 - Fe_triCl3 1.561e-14 1.565e-14 -13.807 -13.806 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 -Na 1.000e-02 - Na+ 1.000e-02 9.020e-03 -2.000 -2.045 -0.045 - NaOH 4.009e-12 4.019e-12 -11.397 -11.396 0.001 -O(0) 5.466e-04 - O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 + H+ 1.624e-05 1.482e-05 -4.789 -4.829 -0.040 0.00 + OH- 7.509e-10 6.751e-10 -9.124 -9.171 -0.046 (0) + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.07 +Cl 1.020e-02 + Cl- 1.020e-02 9.172e-03 -1.991 -2.038 -0.046 17.87 + Fe_diCl+ 7.581e-07 6.830e-07 -6.120 -6.166 -0.045 (0) + Fe_triCl+2 6.322e-10 4.164e-10 -9.199 -9.380 -0.181 (0) + Fe_triCl2+ 1.894e-11 1.706e-11 -10.723 -10.768 -0.045 (0) + Fe_triCl3 1.561e-14 1.565e-14 -13.807 -13.806 0.001 (0) +Fe_di 8.265e-05 + Fe_di+2 8.189e-05 5.395e-05 -4.087 -4.268 -0.181 (0) + Fe_diCl+ 7.581e-07 6.830e-07 -6.120 -6.166 -0.045 (0) + Fe_diOH+ 1.277e-09 1.150e-09 -8.894 -8.939 -0.045 (0) +Fe_tri 1.735e-05 + Fe_tri(OH)2+ 1.622e-05 1.462e-05 -4.790 -4.835 -0.045 (0) + Fe_triOH+2 9.937e-07 6.546e-07 -6.003 -6.184 -0.181 (0) + Fe_tri(OH)3 1.267e-07 1.270e-07 -6.897 -6.896 0.001 (0) + Fe_tri+3 3.845e-09 1.503e-09 -8.415 -8.823 -0.408 (0) + Fe_triCl+2 6.322e-10 4.164e-10 -9.199 -9.380 -0.181 (0) + Fe_tri2(OH)2+4 6.124e-11 1.153e-11 -10.213 -10.938 -0.725 (0) + Fe_triCl2+ 1.894e-11 1.706e-11 -10.723 -10.768 -0.045 (0) + Fe_tri(OH)4- 8.668e-12 7.809e-12 -11.062 -11.107 -0.045 (0) + Fe_tri3(OH)4+5 4.783e-13 3.522e-14 -12.320 -13.453 -1.133 (0) + Fe_triCl3 1.561e-14 1.565e-14 -13.807 -13.806 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 (0) +Na 1.000e-02 + Na+ 1.000e-02 9.020e-03 -2.000 -2.045 -0.045 -1.16 + NaOH 4.009e-12 4.019e-12 -11.397 -11.396 0.001 (0) +O(0) 5.466e-04 + O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -1166,40 +1166,40 @@ O2(g) -0.67 -3.56 -2.89 1.000e+01 1.000e+01 -4.279e-07 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.776e-05 1.621e-05 -4.751 -4.790 -0.040 - OH- 6.869e-10 6.175e-10 -9.163 -9.209 -0.046 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Cl 1.020e-02 - Cl- 1.020e-02 9.172e-03 -1.991 -2.038 -0.046 - Fe_diCl+ 7.425e-07 6.689e-07 -6.129 -6.175 -0.045 - Fe_triCl+2 8.261e-10 5.442e-10 -9.083 -9.264 -0.181 - Fe_triCl2+ 2.475e-11 2.230e-11 -10.606 -10.652 -0.045 - Fe_triCl3 2.040e-14 2.045e-14 -13.690 -13.689 0.001 -Fe_di 8.094e-05 - Fe_di+2 8.020e-05 5.283e-05 -4.096 -4.277 -0.181 - Fe_diCl+ 7.425e-07 6.689e-07 -6.129 -6.175 -0.045 - Fe_diOH+ 1.144e-09 1.031e-09 -8.942 -8.987 -0.045 -Fe_tri 1.906e-05 - Fe_tri(OH)2+ 1.774e-05 1.598e-05 -4.751 -4.796 -0.045 - Fe_triOH+2 1.188e-06 7.825e-07 -5.925 -6.107 -0.181 - Fe_tri(OH)3 1.267e-07 1.270e-07 -6.897 -6.896 0.001 - Fe_tri+3 5.025e-09 1.965e-09 -8.299 -8.707 -0.408 - Fe_triCl+2 8.261e-10 5.442e-10 -9.083 -9.264 -0.181 - Fe_tri2(OH)2+4 8.749e-11 1.648e-11 -10.058 -10.783 -0.725 - Fe_triCl2+ 2.475e-11 2.230e-11 -10.606 -10.652 -0.045 - Fe_tri(OH)4- 7.930e-12 7.145e-12 -11.101 -11.146 -0.045 - Fe_tri3(OH)4+5 7.472e-13 5.503e-14 -12.127 -13.259 -1.133 - Fe_triCl3 2.040e-14 2.045e-14 -13.690 -13.689 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 -Na 1.000e-02 - Na+ 1.000e-02 9.020e-03 -2.000 -2.045 -0.045 - NaOH 3.667e-12 3.676e-12 -11.436 -11.435 0.001 -O(0) 5.466e-04 - O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 + H+ 1.776e-05 1.621e-05 -4.751 -4.790 -0.040 0.00 + OH- 6.869e-10 6.175e-10 -9.163 -9.209 -0.046 (0) + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.07 +Cl 1.020e-02 + Cl- 1.020e-02 9.172e-03 -1.991 -2.038 -0.046 17.87 + Fe_diCl+ 7.425e-07 6.689e-07 -6.129 -6.175 -0.045 (0) + Fe_triCl+2 8.261e-10 5.442e-10 -9.083 -9.264 -0.181 (0) + Fe_triCl2+ 2.475e-11 2.230e-11 -10.606 -10.652 -0.045 (0) + Fe_triCl3 2.040e-14 2.045e-14 -13.690 -13.689 0.001 (0) +Fe_di 8.094e-05 + Fe_di+2 8.020e-05 5.283e-05 -4.096 -4.277 -0.181 (0) + Fe_diCl+ 7.425e-07 6.689e-07 -6.129 -6.175 -0.045 (0) + Fe_diOH+ 1.144e-09 1.031e-09 -8.942 -8.987 -0.045 (0) +Fe_tri 1.906e-05 + Fe_tri(OH)2+ 1.774e-05 1.598e-05 -4.751 -4.796 -0.045 (0) + Fe_triOH+2 1.188e-06 7.825e-07 -5.925 -6.107 -0.181 (0) + Fe_tri(OH)3 1.267e-07 1.270e-07 -6.897 -6.896 0.001 (0) + Fe_tri+3 5.025e-09 1.965e-09 -8.299 -8.707 -0.408 (0) + Fe_triCl+2 8.261e-10 5.442e-10 -9.083 -9.264 -0.181 (0) + Fe_tri2(OH)2+4 8.749e-11 1.648e-11 -10.058 -10.783 -0.725 (0) + Fe_triCl2+ 2.475e-11 2.230e-11 -10.606 -10.652 -0.045 (0) + Fe_tri(OH)4- 7.930e-12 7.145e-12 -11.101 -11.146 -0.045 (0) + Fe_tri3(OH)4+5 7.472e-13 5.503e-14 -12.127 -13.259 -1.133 (0) + Fe_triCl3 2.040e-14 2.045e-14 -13.690 -13.689 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 (0) +Na 1.000e-02 + Na+ 1.000e-02 9.020e-03 -2.000 -2.045 -0.045 -1.16 + NaOH 3.667e-12 3.676e-12 -11.436 -11.435 0.001 (0) +O(0) 5.466e-04 + O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 (0) ------------------------------Saturation indices------------------------------- @@ -1264,40 +1264,40 @@ O2(g) -0.67 -3.56 -2.89 1.000e+01 1.000e+01 -3.603e-07 ----------------------------Distribution of species---------------------------- - Log Log Log - Species Molality Activity Molality Activity Gamma + Log Log Log mole V + Species Molality Activity Molality Activity Gamma cm3/mol - H+ 1.902e-05 1.736e-05 -4.721 -4.760 -0.040 - OH- 6.413e-10 5.765e-10 -9.193 -9.239 -0.046 - H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 -Cl 1.020e-02 - Cl- 1.020e-02 9.172e-03 -1.991 -2.038 -0.046 - Fe_diCl+ 7.293e-07 6.570e-07 -6.137 -6.182 -0.045 - Fe_triCl+2 1.015e-09 6.689e-10 -8.993 -9.175 -0.181 - Fe_triCl2+ 3.042e-11 2.740e-11 -10.517 -10.562 -0.045 - Fe_triCl3 2.508e-14 2.513e-14 -13.601 -13.600 0.001 -Fe_di 7.950e-05 - Fe_di+2 7.877e-05 5.189e-05 -4.104 -4.285 -0.181 - Fe_diCl+ 7.293e-07 6.570e-07 -6.137 -6.182 -0.045 - Fe_diOH+ 1.049e-09 9.450e-10 -8.979 -9.025 -0.045 -Fe_tri 2.050e-05 - Fe_tri(OH)2+ 1.900e-05 1.712e-05 -4.721 -4.766 -0.045 - Fe_triOH+2 1.363e-06 8.979e-07 -5.866 -6.047 -0.181 - Fe_tri(OH)3 1.267e-07 1.270e-07 -6.897 -6.896 0.001 - Fe_tri+3 6.176e-09 2.415e-09 -8.209 -8.617 -0.408 - Fe_triCl+2 1.015e-09 6.689e-10 -8.993 -9.175 -0.181 - Fe_tri2(OH)2+4 1.152e-10 2.170e-11 -9.939 -10.664 -0.725 - Fe_triCl2+ 3.042e-11 2.740e-11 -10.517 -10.562 -0.045 - Fe_tri(OH)4- 7.405e-12 6.671e-12 -11.130 -11.176 -0.045 - Fe_tri3(OH)4+5 1.054e-12 7.762e-14 -11.977 -13.110 -1.133 - Fe_triCl3 2.508e-14 2.513e-14 -13.601 -13.600 0.001 -H(0) 0.000e+00 - H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 -Na 1.000e-02 - Na+ 1.000e-02 9.020e-03 -2.000 -2.045 -0.045 - NaOH 3.424e-12 3.432e-12 -11.465 -11.464 0.001 -O(0) 5.466e-04 - O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 + H+ 1.902e-05 1.736e-05 -4.721 -4.760 -0.040 0.00 + OH- 6.413e-10 5.765e-10 -9.193 -9.239 -0.046 (0) + H2O 5.551e+01 9.996e-01 1.744 -0.000 0.000 18.07 +Cl 1.020e-02 + Cl- 1.020e-02 9.172e-03 -1.991 -2.038 -0.046 17.87 + Fe_diCl+ 7.293e-07 6.570e-07 -6.137 -6.182 -0.045 (0) + Fe_triCl+2 1.015e-09 6.689e-10 -8.993 -9.175 -0.181 (0) + Fe_triCl2+ 3.042e-11 2.740e-11 -10.517 -10.562 -0.045 (0) + Fe_triCl3 2.508e-14 2.513e-14 -13.601 -13.600 0.001 (0) +Fe_di 7.950e-05 + Fe_di+2 7.877e-05 5.189e-05 -4.104 -4.285 -0.181 (0) + Fe_diCl+ 7.293e-07 6.570e-07 -6.137 -6.182 -0.045 (0) + Fe_diOH+ 1.049e-09 9.450e-10 -8.979 -9.025 -0.045 (0) +Fe_tri 2.050e-05 + Fe_tri(OH)2+ 1.900e-05 1.712e-05 -4.721 -4.766 -0.045 (0) + Fe_triOH+2 1.363e-06 8.979e-07 -5.866 -6.047 -0.181 (0) + Fe_tri(OH)3 1.267e-07 1.270e-07 -6.897 -6.896 0.001 (0) + Fe_tri+3 6.176e-09 2.415e-09 -8.209 -8.617 -0.408 (0) + Fe_triCl+2 1.015e-09 6.689e-10 -8.993 -9.175 -0.181 (0) + Fe_tri2(OH)2+4 1.152e-10 2.170e-11 -9.939 -10.664 -0.725 (0) + Fe_triCl2+ 3.042e-11 2.740e-11 -10.517 -10.562 -0.045 (0) + Fe_tri(OH)4- 7.405e-12 6.671e-12 -11.130 -11.176 -0.045 (0) + Fe_tri3(OH)4+5 1.054e-12 7.762e-14 -11.977 -13.110 -1.133 (0) + Fe_triCl3 2.508e-14 2.513e-14 -13.601 -13.600 0.001 (0) +H(0) 0.000e+00 + H2 0.000e+00 0.000e+00 -44.410 -44.409 0.001 (0) +Na 1.000e-02 + Na+ 1.000e-02 9.020e-03 -2.000 -2.045 -0.045 -1.16 + NaOH 3.424e-12 3.432e-12 -11.465 -11.464 0.001 (0) +O(0) 5.466e-04 + O2 2.733e-04 2.739e-04 -3.563 -3.562 0.001 (0) ------------------------------Saturation indices-------------------------------