TITLE Example 13A.--1 mmol/l NaCl/NO3 enters column with stagnant zones. Implicit definition of first-order exchange model. SOLUTION 0 # 1 mmol/l NaCl units mmol/l pH 7.0 pe 13.0 O2(g) -0.7 Na 1.0 # Na has Retardation = 2 Cl 1.0 # Cl has Retardation = 1, stagnant exchange N(5) 1.0 # NO3 is conservative # charge imbalance is no problem ... END SOLUTION 1-41 # Column with KNO3 units mmol/l pH 7.0 pe 13.0 O2(g) -0.7 K 1.0 N(5) 1.0 EXCHANGE 1-41 -equil 1 X 1.e-3 EXCHANGE_SPECIES # For linear exchange, make KX exch. coeff. equal to NaX K+ + X- = KX log_k 0.0 -gamma 3.5 0.015 END TRANSPORT -cells 20 -shifts 5 -flow_d forward -timest 3600 -bcon flux flux -diffc 0.0 -length 0.1 -disp 0.015 -stag 1 6.8e-6 0.3 0.1 # 1 stagnant layer^, ^alpha, ^theta(m), ^theta(im) PRINT -reset false -echo true END SOLUTION 0 # Original solution reenters units mmol/l pH 7.0 pe 13.0 O2(g) -0.7 K 1.0 N(5) 1.0 TRANSPORT -shifts 10 -punch_frequency 10 -punch_cells 1-20 SELECTED_OUTPUT -file ex13a.sel -reset false -solution -distance true USER_PUNCH -head Cl_mmol Na_mmol 10 PUNCH TOT("Cl")*1000, TOT("Na")*1000 END