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26398a44 lsp of databases, changed alk of e- to 1.0 in all databases, modified sit.dat 1c2e59be Tony revised latest sit with lsp 1693e0c1 New version from Tony 5faf092b Tony revisions to phreeqc_rates.dat and rate_xmpls 0bcc9db0 Tony tweaked phreeqc_rates.dat and added rate_xmpls test case. git-subtree-dir: database git-subtree-split: 26398a442446dc31463fb08c3d1cd06df609b633
13213 lines
313 KiB
Plaintext
13213 lines
313 KiB
Plaintext
# File 1 = C:\GitPrograms\phreeqc3-1\database\minteq.v4.dat, 15/03/2024 15:27, 13208 lines, 399299 bytes, md5=fa307060a8f8affd6f41cb15d2225ff6
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# Created 17 May 2024 14:30:41
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# c:\3rdParty\lsp\lsp.exe -f2 -k="asis" -ts "minteq.v4.dat"
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# $Id: minteq.v4.dat 11091 2016-04-21 15:20:05Z dlpark $
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SOLUTION_MASTER_SPECIES
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Alkalinity CO3-2 2 HCO3 61.0173
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E e- 1 0 0
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O H2O 0 O 16
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O(-2) H2O 0 O
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O(0) O2 0 O
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Ag Ag+ 0 Ag 107.868
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Al Al+3 0 Al 26.9815
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As H3AsO4 -1 As 74.9216
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As(3) H3AsO3 0 As
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As(5) H3AsO4 -1 As
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B H3BO3 0 B 10.81
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Ba Ba+2 0 Ba 137.33
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Be Be+2 0 Be 9.0122
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Br Br- 0 Br 79.904
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C CO3-2 2 CO3 12.0111
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C(4) CO3-2 2 CO3 12.0111
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Cyanide Cyanide- 1 Cyanide 26.0177
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Dom_a Dom_a 0 C 12.0111
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Dom_b Dom_b 0 C 12.0111
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Dom_c Dom_c 0 C 12.0111
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Ca Ca+2 0 Ca 40.078
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Cd Cd+2 0 Cd 112.41
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Cl Cl- 0 Cl 35.453
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Co Co+3 -1 Co 58.9332
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Co(2) Co+2 0 Co
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Co(3) Co+3 -1 Co
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Cr CrO4-2 1 Cr 51.996
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Cr(2) Cr+2 0 Cr
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Cr(3) Cr(OH)2+ 0 Cr
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Cr(6) CrO4-2 1 Cr
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Cu Cu+2 0 Cu 63.546
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Cu(1) Cu+ 0 Cu
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Cu(2) Cu+2 0 Cu
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F F- 0 F 18.9984
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Fe Fe+3 -2 Fe 55.847
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Fe(2) Fe+2 0 Fe
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|
Fe(3) Fe+3 -2 Fe
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|
H H+ -1 H 1.0079
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H(0) H2 0 H
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H(1) H+ -1 H
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Hg Hg(OH)2 0 Hg 200.59
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Hg(0) Hg 0 Hg
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|
Hg(1) Hg2+2 0 Hg
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|
Hg(2) Hg(OH)2 0 Hg
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I I- 0 I 126.904
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|
K K+ 0 K 39.0983
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Li Li+ 0 Li 6.941
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Mg Mg+2 0 Mg 24.305
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|
Mn Mn+3 0 Mn 54.938
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Mn(2) Mn+2 0 Mn
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Mn(3) Mn+3 0 Mn
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|
Mn(6) MnO4-2 0 Mn
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|
Mn(7) MnO4- 0 Mn
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|
Mo MoO4-2 0 Mo 95.94
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N NO3- 0 N 14.0067
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N(-3) NH4+ 0 N
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|
N(3) NO2- 0 N
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|
N(5) NO3- 0 N
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Na Na+ 0 Na 22.9898
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Ni Ni+2 0 Ni 58.69
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P PO4-3 2 P 30.9738
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Pb Pb+2 0 Pb 207.2
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S SO4-2 0 SO4 32.066
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S(-2) HS- 1 S
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#S(0) S 0.0 S
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S(6) SO4-2 0 SO4
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Sb Sb(OH)6- 0 Sb 121.75
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Sb(3) Sb(OH)3 0 Sb
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Sb(5) Sb(OH)6- 0 Sb
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Se SeO4-2 0 Se 78.96
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Se(-2) HSe- 0 Se
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Se(4) HSeO3- 0 Se
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Se(6) SeO4-2 0 Se
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Si H4SiO4 0 SiO2 28.0843
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Sn Sn(OH)6-2 0 Sn 118.71
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Sn(2) Sn(OH)2 0 Sn
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Sn(4) Sn(OH)6-2 0 Sn
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Sr Sr+2 0 Sr 87.62
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Tl Tl(OH)3 0 Tl 204.383
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Tl(1) Tl+ 0 Tl
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|
Tl(3) Tl(OH)3 0 Tl
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U UO2+2 0 U 238.029
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U(3) U+3 0 U
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U(4) U+4 -4 U
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U(5) UO2+ 0 U
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U(6) UO2+2 0 U
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V VO2+ -2 V 50.94
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V(2) V+2 0 V
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V(3) V+3 -3 V
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V(4) VO+2 0 V
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V(5) VO2+ -2 V
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Zn Zn+2 0 Zn 65.39
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Benzoate Benzoate- 0 121.116 121.116
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Phenylacetate Phenylacetate- 0 135.142 135.142
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Isophthalate Isophthalate-2 0 164.117 164.117
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Diethylamine Diethylamine 1 73.138 73.138
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Butylamine Butylamine 1 73.138 73.138
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|
Methylamine Methylamine 1 31.057 31.057
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|
Dimethylamine Dimethylamine 1 45.084 45.084
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Hexylamine Hexylamine 1 101.192 101.192
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Ethylenediamine Ethylenediamine 2 60.099 60.099
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Propylamine Propylamine 1 59.111 59.111
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Isopropylamine Isopropylamine 1 59.111 59.111
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Trimethylamine Trimethylamine 1 59.111 59.111
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Citrate Citrate-3 2 189.102 189.102
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Nta Nta-3 1 188.117 188.117
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Edta Edta-4 2 288.214 288.214
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Propionate Propionate- 1 73.072 73.072
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Butyrate Butyrate- 1 87.098 87.098
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Isobutyrate Isobutyrate- 1 87.098 87.098
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Two_picoline Two_picoline 1 93.128 93.128
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Three_picoline Three_picoline 1 93.128 93.128
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Four_picoline Four_picoline 1 93.128 93.128
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Formate Formate- 0 45.018 45.018
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Isovalerate Isovalerate- 1 101.125 101.125
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Valerate Valerate- 1 101.125 101.125
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Acetate Acetate- 1 59.045 59.045
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Tartarate Tartarate-2 0 148.072 148.072
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Glycine Glycine- 1 74.059 74.059
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Salicylate Salicylate-2 1 136.107 136.107
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Glutamate Glutamate-2 1 145.115 145.115
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Phthalate Phthalate-2 1 164.117 164.117
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SOLUTION_SPECIES
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e- = e-
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log_k 0
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H2O = H2O
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log_k 0
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Ag+ = Ag+
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|
log_k 0
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Al+3 = Al+3
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|
log_k 0
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H3AsO4 = H3AsO4
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log_k 0
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H3BO3 = H3BO3
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log_k 0
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Ba+2 = Ba+2
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|
log_k 0
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Be+2 = Be+2
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|
log_k 0
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|
Br- = Br-
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log_k 0
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CO3-2 = CO3-2
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log_k 0
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Cyanide- = Cyanide-
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log_k 0
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|
Dom_a = Dom_a
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log_k 0
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|
Dom_b = Dom_b
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|
log_k 0
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Dom_c = Dom_c
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log_k 0
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Ca+2 = Ca+2
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log_k 0
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Cd+2 = Cd+2
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log_k 0
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Cl- = Cl-
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log_k 0
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Co+3 = Co+3
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log_k 0
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CrO4-2 = CrO4-2
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log_k 0
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Cu+2 = Cu+2
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log_k 0
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F- = F-
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log_k 0
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Fe+3 = Fe+3
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|
log_k 0
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H+ = H+
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log_k 0
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Hg(OH)2 = Hg(OH)2
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log_k 0
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I- = I-
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|
log_k 0
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K+ = K+
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|
log_k 0
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|
Li+ = Li+
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|
log_k 0
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Mg+2 = Mg+2
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|
log_k 0
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|
Mn+3 = Mn+3
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log_k 0
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|
MoO4-2 = MoO4-2
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|
log_k 0
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|
NO3- = NO3-
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|
log_k 0
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|
Na+ = Na+
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|
log_k 0
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|
Ni+2 = Ni+2
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|
log_k 0
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|
PO4-3 = PO4-3
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|
log_k 0
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|
Pb+2 = Pb+2
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|
log_k 0
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|
SO4-2 = SO4-2
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|
log_k 0
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|
Sb(OH)6- = Sb(OH)6-
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|
log_k 0
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|
SeO4-2 = SeO4-2
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|
log_k 0
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|
H4SiO4 = H4SiO4
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|
log_k 0
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|
Sn(OH)6-2 = Sn(OH)6-2
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|
log_k 0
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|
Sr+2 = Sr+2
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|
log_k 0
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|
Tl(OH)3 = Tl(OH)3
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|
log_k 0
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|
UO2+2 = UO2+2
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|
log_k 0
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|
VO2+ = VO2+
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|
log_k 0
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|
Benzoate- = Benzoate-
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|
log_k 0
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|
Phenylacetate- = Phenylacetate-
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|
log_k 0
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|
Isophthalate-2 = Isophthalate-2
|
|
log_k 0
|
|
Zn+2 = Zn+2
|
|
log_k 0
|
|
Diethylamine = Diethylamine
|
|
log_k 0
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|
Butylamine = Butylamine
|
|
log_k 0
|
|
Methylamine = Methylamine
|
|
log_k 0
|
|
Dimethylamine = Dimethylamine
|
|
log_k 0
|
|
Hexylamine = Hexylamine
|
|
log_k 0
|
|
Ethylenediamine = Ethylenediamine
|
|
log_k 0
|
|
Propylamine = Propylamine
|
|
log_k 0
|
|
Isopropylamine = Isopropylamine
|
|
log_k 0
|
|
Trimethylamine = Trimethylamine
|
|
log_k 0
|
|
Citrate-3 = Citrate-3
|
|
log_k 0
|
|
Nta-3 = Nta-3
|
|
log_k 0
|
|
Edta-4 = Edta-4
|
|
log_k 0
|
|
Propionate- = Propionate-
|
|
log_k 0
|
|
Butyrate- = Butyrate-
|
|
log_k 0
|
|
Isobutyrate- = Isobutyrate-
|
|
log_k 0
|
|
Two_picoline = Two_picoline
|
|
log_k 0
|
|
Three_picoline = Three_picoline
|
|
log_k 0
|
|
Four_picoline = Four_picoline
|
|
log_k 0
|
|
Formate- = Formate-
|
|
log_k 0
|
|
Isovalerate- = Isovalerate-
|
|
log_k 0
|
|
Valerate- = Valerate-
|
|
log_k 0
|
|
Acetate- = Acetate-
|
|
log_k 0
|
|
Tartarate-2 = Tartarate-2
|
|
log_k 0
|
|
Glycine- = Glycine-
|
|
log_k 0
|
|
Salicylate-2 = Salicylate-2
|
|
log_k 0
|
|
Glutamate-2 = Glutamate-2
|
|
log_k 0
|
|
Phthalate-2 = Phthalate-2
|
|
log_k 0
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|
SOLUTION_SPECIES
|
|
Fe+3 + e- = Fe+2
|
|
log_k 13.032
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delta_h -42.7 kJ
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|
-gamma 0 0
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# Id: 2802810
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# log K source: Bard85
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# Delta H source: Bard85
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#T and ionic strength:
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H3AsO4 + 2 e- + 2 H+ = H3AsO3 + H2O
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|
log_k 18.898
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|
delta_h -125.6 kJ
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|
-gamma 0 0
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# Id: 600610
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|
# log K source: Bard85
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|
# Delta H source: MTQ3.11
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|
#T and ionic strength:
|
|
Sb(OH)6- + 2 e- + 3 H+ = Sb(OH)3 + 3 H2O
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|
log_k 24.31
|
|
delta_h 0 kJ
|
|
-gamma 0 0
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|
# Id: 7407410
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|
# log K source: Bard85
|
|
# Delta H source: MTQ3.11
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|
#T and ionic strength:
|
|
UO2+2 + 3 e- + 4 H+ = U+3 + 2 H2O
|
|
log_k 0.42
|
|
delta_h -42 kJ
|
|
-gamma 0 0
|
|
# Id: 8908930
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
UO2+2 + 2 e- + 4 H+ = U+4 + 2 H2O
|
|
log_k 9.216
|
|
delta_h -144.1 kJ
|
|
-gamma 0 0
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|
# Id: 8918930
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# log K source: MTQ3.11
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# Delta H source: MTQ3.11
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#T and ionic strength:
|
|
UO2+2 + e- = UO2+
|
|
log_k 2.785
|
|
delta_h -13.8 kJ
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|
-gamma 0 0
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# Id: 8928930
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# log K source: MTQ3.11
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# Delta H source: MTQ3.11
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|
#T and ionic strength:
|
|
e- + Mn+3 = Mn+2
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|
log_k 25.35
|
|
delta_h -107.8 kJ
|
|
-gamma 0 0
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|
# Id: 4704710
|
|
# log K source: Bard85
|
|
# Delta H source: MTQ3.11
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|
#T and ionic strength:
|
|
Co+3 + e- = Co+2
|
|
log_k 32.4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2002010
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|
# log K source: Bard85
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Cu+2 + e- = Cu+
|
|
log_k 2.69
|
|
delta_h 6.9 kJ
|
|
-gamma 0 0
|
|
# Id: 2302310
|
|
# log K source: Bard85
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
V+3 + e- = V+2
|
|
log_k -4.31
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9009010
|
|
# log K source: Bard85
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
VO+2 + e- + 2 H+ = V+3 + H2O
|
|
log_k 5.696
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9019020
|
|
# log K source: Bard85
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
VO2+ + e- + 2 H+ = VO+2 + H2O
|
|
log_k 16.903
|
|
delta_h -122.7 kJ
|
|
-gamma 0 0
|
|
# Id: 9029030
|
|
# log K source: Bard85
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
SO4-2 + 9 H+ + 8 e- = HS- + 4 H2O
|
|
log_k 33.66
|
|
delta_h -60.14 kJ
|
|
-gamma 0 0
|
|
# Id: 7307320
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Sn(OH)6-2 + 2 e- + 4 H+ = Sn(OH)2 + 4 H2O
|
|
log_k 19.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7907910
|
|
# log K source: Bard85
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Tl(OH)3 + 2 e- + 3 H+ = Tl+ + 3 H2O
|
|
log_k 45.55
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8708710
|
|
# log K source: Bard85
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
HSeO3- + 6 e- + 6 H+ = HSe- + 3 H2O
|
|
log_k 44.86
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7607610
|
|
# log K source: Bard85
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
SeO4-2 + 2 e- + 3 H+ = HSeO3- + H2O
|
|
log_k 36.308
|
|
delta_h -201.2 kJ
|
|
-gamma 0 0
|
|
# Id: 7617620
|
|
# log K source: Bard85
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
0.5 Hg2+2 + e- = Hg
|
|
log_k 6.5667
|
|
delta_h -45.735 kJ
|
|
-gamma 0 0
|
|
# Id: 3600000
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
|
|
2 Hg(OH)2 + 4 H+ + 2 e- = Hg2+2 + 4 H2O
|
|
log_k 43.185
|
|
delta_h -63.59 kJ
|
|
-gamma 0 0
|
|
# Id: 3603610
|
|
# log K source: Bard85
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + 2 H+ + e- = Cr+2 + 2 H2O
|
|
log_k 2.947
|
|
delta_h 6.36 kJ
|
|
-gamma 0 0
|
|
# Id: 2102110
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
CrO4-2 + 6 H+ + 3 e- = Cr(OH)2+ + 2 H2O
|
|
log_k 67.376
|
|
delta_h -103 kJ
|
|
-gamma 0 0
|
|
# Id: 2112120
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
|
|
2 H2O = O2 + 4 H+ + 4 e-
|
|
# Adjusted for equation to aqueous species
|
|
log_k -85.9951
|
|
-analytic 38.0229 7.99407E-3 -2.7655e+4 -1.4506e+1 199838.45
|
|
|
|
2 H+ + 2 e- = H2
|
|
log_k -3.15
|
|
delta_h -1.759 kcal
|
|
|
|
NO3- + 2 H+ + 2 e- = NO2- + H2O
|
|
log_k 28.57
|
|
delta_h -43.76 kcal
|
|
-gamma 3 0
|
|
|
|
NO3- + 10 H+ + 8 e- = NH4+ + 3 H2O
|
|
log_k 119.077
|
|
delta_h -187.055 kcal
|
|
-gamma 2.5 0
|
|
|
|
Mn+2 + 4 H2O = MnO4- + 8 H+ + 5 e-
|
|
log_k -127.794
|
|
delta_h 822.67 kJ
|
|
-gamma 3 0
|
|
# Id: 4700020
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
Mn+2 + 4 H2O = MnO4-2 + 8 H+ + 4 e-
|
|
log_k -118.422
|
|
delta_h 711.07 kJ
|
|
-gamma 5 0
|
|
# Id: 4700021
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
HS- = S-2 + H+
|
|
log_k -17.3
|
|
delta_h 49.4 kJ
|
|
-gamma 5 0
|
|
# Id: 3307301
|
|
# log K source: LMa1987
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength: 0.00 25.0
|
|
HSe- = Se-2 + H+
|
|
log_k -15
|
|
delta_h 48.116 kJ
|
|
-gamma 0 0
|
|
# Id: 3307601
|
|
# log K source: SCD3.02 (1968 DKa)
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl(OH)3 + 3 H+ = Tl+3 + 3 H2O
|
|
log_k 3.291
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8713300
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
0.5 Hg2+2 + e- = Hg
|
|
log_k 6.5667
|
|
delta_h -45.735 kJ
|
|
-gamma 0 0
|
|
# Id: 3600000
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
Hg(OH)2 + 2 H+ = Hg+2 + 2 H2O
|
|
log_k 6.194
|
|
delta_h -39.72 kJ
|
|
-gamma 0 0
|
|
# Id: 3613300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cr(OH)2+ + 2 H+ = Cr+3 + 2 H2O
|
|
log_k 9.5688
|
|
delta_h -129.62 kJ
|
|
-gamma 0 0
|
|
# Id: 2113300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.10 20.0
|
|
H2O = OH- + H+
|
|
log_k -13.997
|
|
delta_h 55.81 kJ
|
|
-gamma 3.5 0
|
|
# Id: 3300020
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Sn(OH)2 + 2 H+ = Sn+2 + 2 H2O
|
|
log_k 7.094
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7903301
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Sn(OH)2 + H+ = SnOH+ + H2O
|
|
log_k 3.697
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7903302
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Sn(OH)2 + H2O = Sn(OH)3- + H+
|
|
log_k -9.497
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7903303
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
2 Sn(OH)2 + 2 H+ = Sn2(OH)2+2 + 2 H2O
|
|
log_k 9.394
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7903304
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
3 Sn(OH)2 + 2 H+ = Sn3(OH)4+2 + 2 H2O
|
|
log_k 14.394
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7903305
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Sn(OH)2 = HSnO2- + H+
|
|
log_k -8.9347
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7903306
|
|
# log K source: Bard85
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Sn(OH)6-2 + 6 H+ = Sn+4 + 6 H2O
|
|
log_k 21.2194
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7913301
|
|
# log K source: Bard85
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Sn(OH)6-2 = SnO3-2 + 3 H2O
|
|
log_k -2.2099
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7913302
|
|
# log K source: Bard85
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Pb+2 + H2O = PbOH+ + H+
|
|
log_k -7.597
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6003300
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Pb+2 + 2 H2O = Pb(OH)2 + 2 H+
|
|
log_k -17.094
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6003301
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Pb+2 + 3 H2O = Pb(OH)3- + 3 H+
|
|
log_k -28.091
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6003302
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
2 Pb+2 + H2O = Pb2OH+3 + H+
|
|
log_k -6.397
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6003303
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
3 Pb+2 + 4 H2O = Pb3(OH)4+2 + 4 H+
|
|
log_k -23.888
|
|
delta_h 115.24 kJ
|
|
-gamma 0 0
|
|
# Id: 6003304
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Pb+2 + 4 H2O = Pb(OH)4-2 + 4 H+
|
|
log_k -39.699
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6003305
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
4 Pb+2 + 4 H2O = Pb4(OH)4+4 + 4 H+
|
|
log_k -19.988
|
|
delta_h 88.24 kJ
|
|
-gamma 0 0
|
|
# Id: 6003306
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
H3BO3 + F- = BF(OH)3-
|
|
log_k -0.399
|
|
delta_h 7.7404 kJ
|
|
-gamma 2.5 0
|
|
# Id: 902700
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
H3BO3 + 2 F- + H+ = BF2(OH)2- + H2O
|
|
log_k 7.63
|
|
delta_h 6.8408 kJ
|
|
-gamma 2.5 0
|
|
# Id: 902701
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
H3BO3 + 3 F- + 2 H+ = BF3OH- + 2 H2O
|
|
log_k 13.22
|
|
delta_h -20.4897 kJ
|
|
-gamma 2.5 0
|
|
# Id: 902702
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
Al+3 + H2O = AlOH+2 + H+
|
|
log_k -4.997
|
|
delta_h 47.81 kJ
|
|
-gamma 5.4 0
|
|
# Id: 303300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Al+3 + 2 H2O = Al(OH)2+ + 2 H+
|
|
log_k -10.094
|
|
delta_h 0 kJ
|
|
-gamma 5.4 0
|
|
# Id: 303301
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Al+3 + 3 H2O = Al(OH)3 + 3 H+
|
|
log_k -16.791
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 303303
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Al+3 + 4 H2O = Al(OH)4- + 4 H+
|
|
log_k -22.688
|
|
delta_h 173.24 kJ
|
|
-gamma 4.5 0
|
|
# Id: 303302
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl+ + H2O = TlOH + H+
|
|
log_k -13.207
|
|
delta_h 56.81 kJ
|
|
-gamma 0 0
|
|
# Id: 8703300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl(OH)3 + 2 H+ = TlOH+2 + 2 H2O
|
|
log_k 2.694
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8713301
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl(OH)3 + H+ = Tl(OH)2+ + H2O
|
|
log_k 1.897
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8713302
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl(OH)3 + H2O = Tl(OH)4- + H+
|
|
log_k -11.697
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8713303
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + H2O = ZnOH+ + H+
|
|
log_k -8.997
|
|
delta_h 55.81 kJ
|
|
-gamma 0 0
|
|
# Id: 9503300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + 2 H2O = Zn(OH)2 + 2 H+
|
|
log_k -17.794
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9503301
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + 3 H2O = Zn(OH)3- + 3 H+
|
|
log_k -28.091
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9503302
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + 4 H2O = Zn(OH)4-2 + 4 H+
|
|
log_k -40.488
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9503303
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + H2O = CdOH+ + H+
|
|
log_k -10.097
|
|
delta_h 54.81 kJ
|
|
-gamma 0 0
|
|
# Id: 1603300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + 2 H2O = Cd(OH)2 + 2 H+
|
|
log_k -20.294
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1603301
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + 3 H2O = Cd(OH)3- + 3 H+
|
|
log_k -32.505
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1603302
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 3.00 25.0
|
|
Cd+2 + 4 H2O = Cd(OH)4-2 + 4 H+
|
|
log_k -47.288
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1603303
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
2 Cd+2 + H2O = Cd2OH+3 + H+
|
|
log_k -9.397
|
|
delta_h 45.81 kJ
|
|
-gamma 0 0
|
|
# Id: 1603304
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Hg(OH)2 + H+ = HgOH+ + H2O
|
|
log_k 2.797
|
|
delta_h -18.91 kJ
|
|
-gamma 0 0
|
|
# Id: 3613302
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Hg(OH)2 + H2O = Hg(OH)3- + H+
|
|
log_k -14.897
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3613303
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+2 + H2O = CuOH+ + H+
|
|
log_k -7.497
|
|
delta_h 35.81 kJ
|
|
-gamma 4 0
|
|
# Id: 2313300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+2 + 2 H2O = Cu(OH)2 + 2 H+
|
|
log_k -16.194
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2313301
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+2 + 3 H2O = Cu(OH)3- + 3 H+
|
|
log_k -26.879
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2313302
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Cu+2 + 4 H2O = Cu(OH)4-2 + 4 H+
|
|
log_k -39.98
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2313303
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
2 Cu+2 + 2 H2O = Cu2(OH)2+2 + 2 H+
|
|
log_k -10.594
|
|
delta_h 76.62 kJ
|
|
-gamma 0 0
|
|
# Id: 2313304
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + H2O = AgOH + H+
|
|
log_k -11.997
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 203300
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + 2 H2O = Ag(OH)2- + 2 H+
|
|
log_k -24.004
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 203301
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Ni+2 + H2O = NiOH+ + H+
|
|
log_k -9.897
|
|
delta_h 51.81 kJ
|
|
-gamma 0 0
|
|
# Id: 5403300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ni+2 + 2 H2O = Ni(OH)2 + 2 H+
|
|
log_k -18.994
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5403301
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Ni+2 + 3 H2O = Ni(OH)3- + 3 H+
|
|
log_k -29.991
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5403302
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + H2O = CoOH+ + H+
|
|
log_k -9.697
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2003300
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + 2 H2O = Co(OH)2 + 2 H+
|
|
log_k -18.794
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2003301
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + 3 H2O = Co(OH)3- + 3 H+
|
|
log_k -31.491
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2003302
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + 4 H2O = Co(OH)4-2 + 4 H+
|
|
log_k -46.288
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2003303
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
2 Co+2 + H2O = Co2OH+3 + H+
|
|
log_k -10.997
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2003304
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
4 Co+2 + 4 H2O = Co4(OH)4+4 + 4 H+
|
|
log_k -30.488
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2003306
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + 2 H2O = CoOOH- + 3 H+
|
|
log_k -32.0915
|
|
delta_h 260.454 kJ
|
|
-gamma 0 0
|
|
# Id: 2003305
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Co+3 + H2O = CoOH+2 + H+
|
|
log_k -1.291
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2013300
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 3.00 25.0
|
|
Fe+2 + H2O = FeOH+ + H+
|
|
log_k -9.397
|
|
delta_h 55.81 kJ
|
|
-gamma 5 0
|
|
# Id: 2803300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Fe+2 + 2 H2O = Fe(OH)2 + 2 H+
|
|
log_k -20.494
|
|
delta_h 119.62 kJ
|
|
-gamma 0 0
|
|
# Id: 2803302
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Fe+2 + 3 H2O = Fe(OH)3- + 3 H+
|
|
log_k -28.991
|
|
delta_h 126.43 kJ
|
|
-gamma 5 0
|
|
# Id: 2803301
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Fe+3 + H2O = FeOH+2 + H+
|
|
log_k -2.187
|
|
delta_h 41.81 kJ
|
|
-gamma 5 0
|
|
# Id: 2813300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Fe+3 + 2 H2O = Fe(OH)2+ + 2 H+
|
|
log_k -4.594
|
|
delta_h 0 kJ
|
|
-gamma 5.4 0
|
|
# Id: 2813301
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Fe+3 + 3 H2O = Fe(OH)3 + 3 H+
|
|
log_k -12.56
|
|
delta_h 103.8 kJ
|
|
-gamma 0 0
|
|
# Id: 2813302
|
|
# log K source: Nord90
|
|
# Delta H source: Nord90
|
|
#T and ionic strength: 0.00 25.0
|
|
Fe+3 + 4 H2O = Fe(OH)4- + 4 H+
|
|
log_k -21.588
|
|
delta_h 0 kJ
|
|
-gamma 5.4 0
|
|
# Id: 2813303
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
2 Fe+3 + 2 H2O = Fe2(OH)2+4 + 2 H+
|
|
log_k -2.854
|
|
delta_h 57.62 kJ
|
|
-gamma 0 0
|
|
# Id: 2813304
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
3 Fe+3 + 4 H2O = Fe3(OH)4+5 + 4 H+
|
|
log_k -6.288
|
|
delta_h 65.24 kJ
|
|
-gamma 0 0
|
|
# Id: 2813305
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Mn+2 + H2O = MnOH+ + H+
|
|
log_k -10.597
|
|
delta_h 55.81 kJ
|
|
-gamma 5 0
|
|
# Id: 4703300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Mn+2 + 3 H2O = Mn(OH)3- + 3 H+
|
|
log_k -34.8
|
|
delta_h 0 kJ
|
|
-gamma 5 0
|
|
# Id: 4703301
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Mn+2 + 4 H2O = Mn(OH)4-2 + 4 H+
|
|
log_k -48.288
|
|
delta_h 0 kJ
|
|
-gamma 5 0
|
|
# Id: 4703302
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Mn+2 + 4 H2O = MnO4- + 8 H+ + 5 e-
|
|
log_k -127.794
|
|
delta_h 822.67 kJ
|
|
-gamma 3 0
|
|
# Id: 4700020
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
Mn+2 + 4 H2O = MnO4-2 + 8 H+ + 4 e-
|
|
log_k -118.422
|
|
delta_h 711.07 kJ
|
|
-gamma 5 0
|
|
# Id: 4700021
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + H+ = Cr(OH)+2 + H2O
|
|
log_k 5.9118
|
|
delta_h -77.91 kJ
|
|
-gamma 0 0
|
|
# Id: 2113301
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cr(OH)2+ + H2O = Cr(OH)3 + H+
|
|
log_k -8.4222
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2113302
|
|
# log K source: SCD3.02 (1983 RCa)
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Cr(OH)2+ + 2 H2O = Cr(OH)4- + 2 H+
|
|
log_k -17.8192
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2113303
|
|
# log K source: SCD3.02 (1983 RCa)
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Cr(OH)2+ = CrO2- + 2 H+
|
|
log_k -17.7456
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2113304
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
V+2 + H2O = VOH+ + H+
|
|
log_k -6.487
|
|
delta_h 59.81 kJ
|
|
-gamma 0 0
|
|
# Id: 9003300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
V+3 + H2O = VOH+2 + H+
|
|
log_k -2.297
|
|
delta_h 43.81 kJ
|
|
-gamma 0 0
|
|
# Id: 9013300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
V+3 + 2 H2O = V(OH)2+ + 2 H+
|
|
log_k -6.274
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9013301
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 20.0
|
|
V+3 + 3 H2O = V(OH)3 + 3 H+
|
|
log_k -3.0843
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9013302
|
|
# log K source: SCD3.02 (1978 TKa)
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.10 20.0
|
|
2 V+3 + 2 H2O = V2(OH)2+4 + 2 H+
|
|
log_k -3.794
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9013304
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
2 V+3 + 3 H2O = V2(OH)3+3 + 3 H+
|
|
log_k -10.1191
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9013303
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 3.00 25.0
|
|
VO+2 + 2 H2O = V(OH)3+ + H+
|
|
log_k -5.697
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9023300
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
2 VO+2 + 2 H2O = H2V2O4+2 + 2 H+
|
|
log_k -6.694
|
|
delta_h 53.62 kJ
|
|
-gamma 0 0
|
|
# Id: 9023301
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
U+4 + H2O = UOH+3 + H+
|
|
log_k -0.597
|
|
delta_h 47.81 kJ
|
|
-gamma 0 0
|
|
# Id: 8913300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
U+4 + 2 H2O = U(OH)2+2 + 2 H+
|
|
log_k -2.27
|
|
delta_h 74.1823 kJ
|
|
-gamma 0 0
|
|
# Id: 8913301
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
U+4 + 3 H2O = U(OH)3+ + 3 H+
|
|
log_k -4.935
|
|
delta_h 94.7467 kJ
|
|
-gamma 0 0
|
|
# Id: 8913302
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
U+4 + 4 H2O = U(OH)4 + 4 H+
|
|
log_k -8.498
|
|
delta_h 103.596 kJ
|
|
-gamma 0 0
|
|
# Id: 8913303
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
U+4 + 5 H2O = U(OH)5- + 5 H+
|
|
log_k -13.12
|
|
delta_h 115.374 kJ
|
|
-gamma 0 0
|
|
# Id: 8913304
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
6 U+4 + 15 H2O = U6(OH)15+9 + 15 H+
|
|
log_k -17.155
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8913305
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
UO2+2 + H2O = UO2OH+ + H+
|
|
log_k -5.897
|
|
delta_h 47.81 kJ
|
|
-gamma 0 0
|
|
# Id: 8933300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
2 UO2+2 + 2 H2O = (UO2)2(OH)2+2 + 2 H+
|
|
log_k -5.574
|
|
delta_h 41.82 kJ
|
|
-gamma 0 0
|
|
# Id: 8933301
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
3 UO2+2 + 5 H2O = (UO2)3(OH)5+ + 5 H+
|
|
log_k -15.585
|
|
delta_h 108.05 kJ
|
|
-gamma 0 0
|
|
# Id: 8933302
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Be+2 + H2O = BeOH+ + H+
|
|
log_k -5.397
|
|
delta_h 0 kJ
|
|
-gamma 6.5 0
|
|
# Id: 1103301
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Be+2 + 2 H2O = Be(OH)2 + 2 H+
|
|
log_k -13.594
|
|
delta_h 0 kJ
|
|
-gamma 6.5 0
|
|
# Id: 1103302
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Be+2 + 3 H2O = Be(OH)3- + 3 H+
|
|
log_k -23.191
|
|
delta_h 0 kJ
|
|
-gamma 6.5 0
|
|
# Id: 1103303
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Be+2 + 4 H2O = Be(OH)4-2 + 4 H+
|
|
log_k -37.388
|
|
delta_h 0 kJ
|
|
-gamma 6.5 0
|
|
# Id: 1103304
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
2 Be+2 + H2O = Be2OH+3 + H+
|
|
log_k -3.177
|
|
delta_h 0 kJ
|
|
-gamma 6.5 0
|
|
# Id: 1103305
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.10 25.0
|
|
3 Be+2 + 3 H2O = Be3(OH)3+3 + 3 H+
|
|
log_k -8.8076
|
|
delta_h 0 kJ
|
|
-gamma 6.5 0
|
|
# Id: 1103306
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.10 25.0
|
|
Mg+2 + H2O = MgOH+ + H+
|
|
log_k -11.397
|
|
delta_h 67.81 kJ
|
|
-gamma 6.5 0
|
|
# Id: 4603300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ca+2 + H2O = CaOH+ + H+
|
|
log_k -12.697
|
|
delta_h 64.11 kJ
|
|
-gamma 6 0
|
|
# Id: 1503300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Sr+2 + H2O = SrOH+ + H+
|
|
log_k -13.177
|
|
delta_h 60.81 kJ
|
|
-gamma 5 0
|
|
# Id: 8003300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ba+2 + H2O = BaOH+ + H+
|
|
log_k -13.357
|
|
delta_h 60.81 kJ
|
|
-gamma 5 0
|
|
# Id: 1003300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
H+ + F- = HF
|
|
log_k 3.17
|
|
delta_h 13.3 kJ
|
|
-gamma 0 0
|
|
# Id: 3302700
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
H+ + 2 F- = HF2-
|
|
log_k 3.75
|
|
delta_h 17.4 kJ
|
|
-gamma 3.5 0
|
|
# Id: 3302701
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
2 F- + 2 H+ = H2F2
|
|
log_k 6.768
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3302702
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Sb(OH)3 + F- + H+ = SbOF + 2 H2O
|
|
log_k 6.1864
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7402700
|
|
# log K source: PNL89
|
|
# Delta H source: PNL89
|
|
#T and ionic strength:
|
|
Sb(OH)3 + F- + H+ = Sb(OH)2F + H2O
|
|
log_k 6.1937
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7402702
|
|
# log K source: PNL89
|
|
# Delta H source: PNL89
|
|
#T and ionic strength:
|
|
H4SiO4 + 4 H+ + 6 F- = SiF6-2 + 4 H2O
|
|
log_k 30.18
|
|
delta_h -68 kJ
|
|
-gamma 5 0
|
|
# Id: 7702700
|
|
# log K source: Nord90
|
|
# Delta H source: Nord90
|
|
#T and ionic strength: 0.00 25.0
|
|
Sn(OH)2 + 2 H+ + F- = SnF+ + 2 H2O
|
|
log_k 11.582
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7902701
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Sn(OH)2 + 2 H+ + 2 F- = SnF2 + 2 H2O
|
|
log_k 14.386
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7902702
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Sn(OH)2 + 2 H+ + 3 F- = SnF3- + 2 H2O
|
|
log_k 17.206
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7902703
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Sn(OH)6-2 + 6 H+ + 6 F- = SnF6-2 + 6 H2O
|
|
log_k 33.5844
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7912701
|
|
# log K source: Bard85
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Pb+2 + F- = PbF+
|
|
log_k 1.848
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6002700
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Pb+2 + 2 F- = PbF2
|
|
log_k 3.142
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6002701
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Pb+2 + 3 F- = PbF3-
|
|
log_k 3.42
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6002702
|
|
# log K source: SCD3.02 (1956 TKa)
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Pb+2 + 4 F- = PbF4-2
|
|
log_k 3.1
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6002703
|
|
# log K source: SCD3.02 (1956 TKa)
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
H3BO3 + 3 H+ + 4 F- = BF4- + 3 H2O
|
|
log_k 19.912
|
|
delta_h -18.67 kJ
|
|
-gamma 2.5 0
|
|
# Id: 902703
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength: 1.00 25.0
|
|
Al+3 + F- = AlF+2
|
|
log_k 7
|
|
delta_h 4.6 kJ
|
|
-gamma 5.4 0
|
|
# Id: 302700
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Al+3 + 2 F- = AlF2+
|
|
log_k 12.6
|
|
delta_h 8.3 kJ
|
|
-gamma 5.4 0
|
|
# Id: 302701
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Al+3 + 3 F- = AlF3
|
|
log_k 16.7
|
|
delta_h 8.7 kJ
|
|
-gamma 0 0
|
|
# Id: 302702
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Al+3 + 4 F- = AlF4-
|
|
log_k 19.4
|
|
delta_h 8.7 kJ
|
|
-gamma 4.5 0
|
|
# Id: 302703
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl+ + F- = TlF
|
|
log_k 0.1
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8702700
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + F- = ZnF+
|
|
log_k 1.3
|
|
delta_h 11 kJ
|
|
-gamma 0 0
|
|
# Id: 9502700
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + F- = CdF+
|
|
log_k 1.2
|
|
delta_h 5 kJ
|
|
-gamma 0 0
|
|
# Id: 1602700
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + 2 F- = CdF2
|
|
log_k 1.5
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1602701
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Hg(OH)2 + 2 H+ + F- = HgF+ + 2 H2O
|
|
log_k 7.763
|
|
delta_h -35.72 kJ
|
|
-gamma 0 0
|
|
# Id: 3612701
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.50 25.0
|
|
Cu+2 + F- = CuF+
|
|
log_k 1.8
|
|
delta_h 13 kJ
|
|
-gamma 0 0
|
|
# Id: 2312700
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + F- = AgF
|
|
log_k 0.4
|
|
delta_h 12 kJ
|
|
-gamma 0 0
|
|
# Id: 202700
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ni+2 + F- = NiF+
|
|
log_k 1.4
|
|
delta_h 7.1 kJ
|
|
-gamma 0 0
|
|
# Id: 5402700
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + F- = CoF+
|
|
log_k 1.5
|
|
delta_h 9.2 kJ
|
|
-gamma 0 0
|
|
# Id: 2002700
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Fe+3 + F- = FeF+2
|
|
log_k 6.04
|
|
delta_h 10 kJ
|
|
-gamma 5 0
|
|
# Id: 2812700
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Fe+3 + 2 F- = FeF2+
|
|
log_k 10.4675
|
|
delta_h 17 kJ
|
|
-gamma 5 0
|
|
# Id: 2812701
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.50 25.0
|
|
Fe+3 + 3 F- = FeF3
|
|
log_k 13.617
|
|
delta_h 29 kJ
|
|
-gamma 0 0
|
|
# Id: 2812702
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.50 25.0
|
|
Mn+2 + F- = MnF+
|
|
log_k 1.6
|
|
delta_h 11 kJ
|
|
-gamma 5 0
|
|
# Id: 4702700
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cr(OH)2+ + 2 H+ + F- = CrF+2 + 2 H2O
|
|
log_k 14.7688
|
|
delta_h -70.2452 kJ
|
|
-gamma 0 0
|
|
# Id: 2112700
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
VO+2 + F- = VOF+
|
|
log_k 3.778
|
|
delta_h 7.9 kJ
|
|
-gamma 0 0
|
|
# Id: 9022700
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 1.00 25.0
|
|
VO+2 + 2 F- = VOF2
|
|
log_k 6.352
|
|
delta_h 14 kJ
|
|
-gamma 0 0
|
|
# Id: 9022701
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 1.00 25.0
|
|
VO+2 + 3 F- = VOF3-
|
|
log_k 7.902
|
|
delta_h 20 kJ
|
|
-gamma 0 0
|
|
# Id: 9022702
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 1.00 25.0
|
|
VO+2 + 4 F- = VOF4-2
|
|
log_k 8.508
|
|
delta_h 26 kJ
|
|
-gamma 0 0
|
|
# Id: 9022703
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 1.00 25.0
|
|
VO2+ + F- = VO2F
|
|
log_k 3.244
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9032700
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
VO2+ + 2 F- = VO2F2-
|
|
log_k 5.804
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9032701
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 20.0
|
|
VO2+ + 3 F- = VO2F3-2
|
|
log_k 6.9
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9032702
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 20.0
|
|
VO2+ + 4 F- = VO2F4-3
|
|
log_k 6.592
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9032703
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 20.0
|
|
U+4 + F- = UF+3
|
|
log_k 9.3
|
|
delta_h 21.1292 kJ
|
|
-gamma 0 0
|
|
# Id: 8912700
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
U+4 + 2 F- = UF2+2
|
|
log_k 16.4
|
|
delta_h 30.1248 kJ
|
|
-gamma 0 0
|
|
# Id: 8912701
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
U+4 + 3 F- = UF3+
|
|
log_k 21.6
|
|
delta_h 29.9156 kJ
|
|
-gamma 0 0
|
|
# Id: 8912702
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
U+4 + 4 F- = UF4
|
|
log_k 23.64
|
|
delta_h 19.2464 kJ
|
|
-gamma 0 0
|
|
# Id: 8912703
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
U+4 + 5 F- = UF5-
|
|
log_k 25.238
|
|
delta_h 20.2924 kJ
|
|
-gamma 0 0
|
|
# Id: 8912704
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
U+4 + 6 F- = UF6-2
|
|
log_k 27.718
|
|
delta_h 13.8072 kJ
|
|
-gamma 0 0
|
|
# Id: 8912705
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
UO2+2 + F- = UO2F+
|
|
log_k 5.14
|
|
delta_h 1 kJ
|
|
-gamma 0 0
|
|
# Id: 8932700
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
UO2+2 + 2 F- = UO2F2
|
|
log_k 8.6
|
|
delta_h 2 kJ
|
|
-gamma 0 0
|
|
# Id: 8932701
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
UO2+2 + 3 F- = UO2F3-
|
|
log_k 11
|
|
delta_h 2 kJ
|
|
-gamma 0 0
|
|
# Id: 8932702
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
UO2+2 + 4 F- = UO2F4-2
|
|
log_k 11.9
|
|
delta_h 0.4 kJ
|
|
-gamma 0 0
|
|
# Id: 8932703
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Be+2 + F- = BeF+
|
|
log_k 5.249
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1102701
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.50 25.0
|
|
Be+2 + 2 F- = BeF2
|
|
log_k 9.1285
|
|
delta_h -4 kJ
|
|
-gamma 0 0
|
|
# Id: 1102702
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.50 25.0
|
|
Be+2 + 3 F- = BeF3-
|
|
log_k 11.9085
|
|
delta_h -8 kJ
|
|
-gamma 0 0
|
|
# Id: 1102703
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.50 25.0
|
|
Mg+2 + F- = MgF+
|
|
log_k 2.05
|
|
delta_h 13 kJ
|
|
-gamma 4.5 0
|
|
# Id: 4602700
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ca+2 + F- = CaF+
|
|
log_k 1.038
|
|
delta_h 14 kJ
|
|
-gamma 5 0
|
|
# Id: 1502700
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 1.00 25.0
|
|
Sr+2 + F- = SrF+
|
|
log_k 0.548
|
|
delta_h 16 kJ
|
|
-gamma 0 0
|
|
# Id: 8002701
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 1.00 25.0
|
|
Na+ + F- = NaF
|
|
log_k -0.2
|
|
delta_h 12 kJ
|
|
-gamma 0 0
|
|
# Id: 5002700
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Sn(OH)2 + 2 H+ + Cl- = SnCl+ + 2 H2O
|
|
log_k 8.734
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7901801
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Sn(OH)2 + 2 H+ + 2 Cl- = SnCl2 + 2 H2O
|
|
log_k 9.524
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7901802
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Sn(OH)2 + 2 H+ + 3 Cl- = SnCl3- + 2 H2O
|
|
log_k 8.3505
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7901803
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 2.00 25.0
|
|
Pb+2 + Cl- = PbCl+
|
|
log_k 1.55
|
|
delta_h 8.7 kJ
|
|
-gamma 0 0
|
|
# Id: 6001800
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Pb+2 + 2 Cl- = PbCl2
|
|
log_k 2.2
|
|
delta_h 12 kJ
|
|
-gamma 0 0
|
|
# Id: 6001801
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Pb+2 + 3 Cl- = PbCl3-
|
|
log_k 1.8
|
|
delta_h 4 kJ
|
|
-gamma 0 0
|
|
# Id: 6001802
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Pb+2 + 4 Cl- = PbCl4-2
|
|
log_k 1.46
|
|
delta_h 14.7695 kJ
|
|
-gamma 0 0
|
|
# Id: 6001803
|
|
# log K source: SCD3.02 (1984 SEa)
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl+ + Cl- = TlCl
|
|
log_k 0.51
|
|
delta_h -6.2 kJ
|
|
-gamma 0 0
|
|
# Id: 8701800
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl+ + 2 Cl- = TlCl2-
|
|
log_k 0.28
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8701801
|
|
# log K source: SCD3.02 (1992 RAb)
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl(OH)3 + 3 H+ + Cl- = TlCl+2 + 3 H2O
|
|
log_k 11.011
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8711800
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl(OH)3 + 3 H+ + 2 Cl- = TlCl2+ + 3 H2O
|
|
log_k 16.771
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8711801
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl(OH)3 + 3 H+ + 3 Cl- = TlCl3 + 3 H2O
|
|
log_k 19.791
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8711802
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl(OH)3 + 3 H+ + 4 Cl- = TlCl4- + 3 H2O
|
|
log_k 21.591
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8711803
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl(OH)3 + Cl- + 2 H+ = TlOHCl+ + 2 H2O
|
|
log_k 10.629
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8711804
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Zn+2 + Cl- = ZnCl+
|
|
log_k 0.4
|
|
delta_h 5.4 kJ
|
|
-gamma 4 0
|
|
# Id: 9501800
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + 2 Cl- = ZnCl2
|
|
log_k 0.6
|
|
delta_h 37 kJ
|
|
-gamma 0 0
|
|
# Id: 9501801
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + 3 Cl- = ZnCl3-
|
|
log_k 0.5
|
|
delta_h 39.999 kJ
|
|
-gamma 4 0
|
|
# Id: 9501802
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Zn+2 + 4 Cl- = ZnCl4-2
|
|
log_k 0.199
|
|
delta_h 45.8566 kJ
|
|
-gamma 5 0
|
|
# Id: 9501803
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Zn+2 + H2O + Cl- = ZnOHCl + H+
|
|
log_k -7.48
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9501804
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Cd+2 + Cl- = CdCl+
|
|
log_k 1.98
|
|
delta_h 1 kJ
|
|
-gamma 0 0
|
|
# Id: 1601800
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + 2 Cl- = CdCl2
|
|
log_k 2.6
|
|
delta_h 3 kJ
|
|
-gamma 0 0
|
|
# Id: 1601801
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + 3 Cl- = CdCl3-
|
|
log_k 2.4
|
|
delta_h 10 kJ
|
|
-gamma 0 0
|
|
# Id: 1601802
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + H2O + Cl- = CdOHCl + H+
|
|
log_k -7.404
|
|
delta_h 18.2213 kJ
|
|
-gamma 0 0
|
|
# Id: 1601803
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Hg(OH)2 + 2 H+ + Cl- = HgCl+ + 2 H2O
|
|
log_k 13.494
|
|
delta_h -62.72 kJ
|
|
-gamma 0 0
|
|
# Id: 3611800
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Hg(OH)2 + 2 H+ + 2 Cl- = HgCl2 + 2 H2O
|
|
log_k 20.194
|
|
delta_h -92.42 kJ
|
|
-gamma 0 0
|
|
# Id: 3611801
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Hg(OH)2 + 2 H+ + 3 Cl- = HgCl3- + 2 H2O
|
|
log_k 21.194
|
|
delta_h -94.02 kJ
|
|
-gamma 0 0
|
|
# Id: 3611802
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Hg(OH)2 + 2 H+ + 4 Cl- = HgCl4-2 + 2 H2O
|
|
log_k 21.794
|
|
delta_h -100.72 kJ
|
|
-gamma 0 0
|
|
# Id: 3611803
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Hg(OH)2 + Cl- + I- + 2 H+ = HgClI + 2 H2O
|
|
log_k 25.532
|
|
delta_h -135.3 kJ
|
|
-gamma 0 0
|
|
# Id: 3611804
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
Hg(OH)2 + H+ + Cl- = HgClOH + H2O
|
|
log_k 10.444
|
|
delta_h -42.72 kJ
|
|
-gamma 0 0
|
|
# Id: 3611805
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 1.00 25.0
|
|
Cu+2 + Cl- = CuCl+
|
|
log_k 0.2
|
|
delta_h 8.3 kJ
|
|
-gamma 4 0
|
|
# Id: 2311800
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+2 + 2 Cl- = CuCl2
|
|
log_k -0.26
|
|
delta_h 44.183 kJ
|
|
-gamma 0 0
|
|
# Id: 2311801
|
|
# log K source: SCD3.02 (1989 IPa)
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+2 + 3 Cl- = CuCl3-
|
|
log_k -2.29
|
|
delta_h 57.279 kJ
|
|
-gamma 4 0
|
|
# Id: 2311802
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Cu+2 + 4 Cl- = CuCl4-2
|
|
log_k -4.59
|
|
delta_h 32.5515 kJ
|
|
-gamma 5 0
|
|
# Id: 2311803
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Cu+ + 2 Cl- = CuCl2-
|
|
log_k 5.42
|
|
delta_h -1.7573 kJ
|
|
-gamma 4 0
|
|
# Id: 2301800
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+ + 3 Cl- = CuCl3-2
|
|
log_k 4.75
|
|
delta_h 1.0878 kJ
|
|
-gamma 5 0
|
|
# Id: 2301801
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+ + Cl- = CuCl
|
|
log_k 3.1
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2301802
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + Cl- = AgCl
|
|
log_k 3.31
|
|
delta_h -12 kJ
|
|
-gamma 0 0
|
|
# Id: 201800
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + 2 Cl- = AgCl2-
|
|
log_k 5.25
|
|
delta_h -16 kJ
|
|
-gamma 0 0
|
|
# Id: 201801
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + 3 Cl- = AgCl3-2
|
|
log_k 5.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 201802
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + 4 Cl- = AgCl4-3
|
|
log_k 5.51
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 201803
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Ni+2 + Cl- = NiCl+
|
|
log_k 0.408
|
|
delta_h 2 kJ
|
|
-gamma 0 0
|
|
# Id: 5401800
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 1.00 25.0
|
|
Ni+2 + 2 Cl- = NiCl2
|
|
log_k -1.89
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5401801
|
|
# log K source: SCD3.02 (1989 IPa)
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + Cl- = CoCl+
|
|
log_k 0.539
|
|
delta_h 2 kJ
|
|
-gamma 0 0
|
|
# Id: 2001800
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.50 25.0
|
|
Co+3 + Cl- = CoCl+2
|
|
log_k 2.3085
|
|
delta_h 16 kJ
|
|
-gamma 0 0
|
|
# Id: 2011800
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.50 25.0
|
|
Fe+3 + Cl- = FeCl+2
|
|
log_k 1.48
|
|
delta_h 23 kJ
|
|
-gamma 5 0
|
|
# Id: 2811800
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Fe+3 + 2 Cl- = FeCl2+
|
|
log_k 2.13
|
|
delta_h 0 kJ
|
|
-gamma 5 0
|
|
# Id: 2811801
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Fe+3 + 3 Cl- = FeCl3
|
|
log_k 1.13
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2811802
|
|
# log K source: Nord90
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Mn+2 + Cl- = MnCl+
|
|
log_k 0.1
|
|
delta_h 0 kJ
|
|
-gamma 5 0
|
|
# Id: 4701800
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 20.0
|
|
Mn+2 + 2 Cl- = MnCl2
|
|
log_k 0.25
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4701801
|
|
# log K source: Nord90
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Mn+2 + 3 Cl- = MnCl3-
|
|
log_k -0.31
|
|
delta_h 0 kJ
|
|
-gamma 5 0
|
|
# Id: 4701802
|
|
# log K source: Nord90
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Cr(OH)2+ + 2 H+ + Cl- = CrCl+2 + 2 H2O
|
|
log_k 9.6808
|
|
delta_h -103.62 kJ
|
|
-gamma 0 0
|
|
# Id: 2111800
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 1.00 25.0
|
|
Cr(OH)2+ + 2 Cl- + 2 H+ = CrCl2+ + 2 H2O
|
|
log_k 8.658
|
|
delta_h -39.2208 kJ
|
|
-gamma 0 0
|
|
# Id: 2111801
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + 2 Cl- + H+ = CrOHCl2 + H2O
|
|
log_k 2.9627
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2111802
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
VO+2 + Cl- = VOCl+
|
|
log_k 0.448
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9021800
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 20.0
|
|
U+4 + Cl- = UCl+3
|
|
log_k 1.7
|
|
delta_h -20 kJ
|
|
-gamma 0 0
|
|
# Id: 8911800
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
UO2+2 + Cl- = UO2Cl+
|
|
log_k 0.21
|
|
delta_h 16 kJ
|
|
-gamma 0 0
|
|
# Id: 8931800
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Be+2 + Cl- = BeCl+
|
|
log_k 0.2009
|
|
delta_h 0 kJ
|
|
-gamma 5 0
|
|
# Id: 1101801
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.70 20.0
|
|
Sn(OH)2 + 2 H+ + Br- = SnBr+ + 2 H2O
|
|
log_k 8.254
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7901301
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Sn(OH)2 + 2 H+ + 2 Br- = SnBr2 + 2 H2O
|
|
log_k 8.794
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7901302
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Sn(OH)2 + 2 H+ + 3 Br- = SnBr3- + 2 H2O
|
|
log_k 7.48
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7901303
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 3.00 25.0
|
|
Pb+2 + Br- = PbBr+
|
|
log_k 1.7
|
|
delta_h 8 kJ
|
|
-gamma 0 0
|
|
# Id: 6001300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Pb+2 + 2 Br- = PbBr2
|
|
log_k 2.6
|
|
delta_h -4 kJ
|
|
-gamma 0 0
|
|
# Id: 6001301
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl+ + Br- = TlBr
|
|
log_k 0.91
|
|
delta_h -12 kJ
|
|
-gamma 0 0
|
|
# Id: 8701300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl+ + 2 Br- = TlBr2-
|
|
log_k -0.384
|
|
delta_h 12.36 kJ
|
|
-gamma 0 0
|
|
# Id: 8701301
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength: 4.00 25.0
|
|
Tl+ + Br- + Cl- = TlBrCl-
|
|
log_k 0.8165
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8701302
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Tl+ + I- + Br- = TlIBr-
|
|
log_k 2.185
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8703802
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Tl(OH)3 + 3 H+ + Br- = TlBr+2 + 3 H2O
|
|
log_k 12.803
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8711300
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Tl(OH)3 + 3 H+ + 2 Br- = TlBr2+ + 3 H2O
|
|
log_k 20.711
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8711301
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Tl(OH)3 + 3 Br- + 3 H+ = TlBr3 + 3 H2O
|
|
log_k 27.0244
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8711302
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Tl(OH)3 + 4 Br- + 3 H+ = TlBr4- + 3 H2O
|
|
log_k 31.1533
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8711303
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Zn+2 + Br- = ZnBr+
|
|
log_k -0.07
|
|
delta_h 1 kJ
|
|
-gamma 0 0
|
|
# Id: 9501300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + 2 Br- = ZnBr2
|
|
log_k -0.98
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9501301
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Cd+2 + Br- = CdBr+
|
|
log_k 2.15
|
|
delta_h -3 kJ
|
|
-gamma 0 0
|
|
# Id: 1601300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + 2 Br- = CdBr2
|
|
log_k 3
|
|
delta_h -3 kJ
|
|
-gamma 0 0
|
|
# Id: 1601301
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Hg(OH)2 + 2 H+ + Br- = HgBr+ + 2 H2O
|
|
log_k 15.803
|
|
delta_h -81.92 kJ
|
|
-gamma 0 0
|
|
# Id: 3611301
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.50 25.0
|
|
Hg(OH)2 + 2 H+ + 2 Br- = HgBr2 + 2 H2O
|
|
log_k 24.2725
|
|
delta_h -127.12 kJ
|
|
-gamma 0 0
|
|
# Id: 3611302
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.50 25.0
|
|
Hg(OH)2 + 2 H+ + 3 Br- = HgBr3- + 2 H2O
|
|
log_k 26.7025
|
|
delta_h -138.82 kJ
|
|
-gamma 0 0
|
|
# Id: 3611303
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.50 25.0
|
|
Hg(OH)2 + 2 H+ + 4 Br- = HgBr4-2 + 2 H2O
|
|
log_k 27.933
|
|
delta_h -153.72 kJ
|
|
-gamma 0 0
|
|
# Id: 3611304
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.50 25.0
|
|
Hg(OH)2 + Br- + Cl- + 2 H+ = HgBrCl + 2 H2O
|
|
log_k 22.1811
|
|
delta_h -113.77 kJ
|
|
-gamma 0 0
|
|
# Id: 3611305
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
Hg(OH)2 + Br- + I- + 2 H+ = HgBrI + 2 H2O
|
|
log_k 27.3133
|
|
delta_h -151.27 kJ
|
|
-gamma 0 0
|
|
# Id: 3611306
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
Hg(OH)2 + Br- + 3 I- + 2 H+ = HgBrI3-2 + 2 H2O
|
|
log_k 34.2135
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3611307
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Hg(OH)2 + 2 Br- + 2 I- + 2 H+ = HgBr2I2-2 + 2 H2O
|
|
log_k 32.3994
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3611308
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Hg(OH)2 + 3 Br- + I- + 2 H+ = HgBr3I-2 + 2 H2O
|
|
log_k 30.1528
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3611309
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Hg(OH)2 + H+ + Br- = HgBrOH + H2O
|
|
log_k 12.433
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3613301
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.50 25.0
|
|
Ag+ + Br- = AgBr
|
|
log_k 4.6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 201300
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + 2 Br- = AgBr2-
|
|
log_k 7.5
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 201301
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + 3 Br- = AgBr3-2
|
|
log_k 8.1
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 201302
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Ni+2 + Br- = NiBr+
|
|
log_k 0.5
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5401300
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + Br- + 2 H+ = CrBr+2 + 2 H2O
|
|
log_k 7.5519
|
|
delta_h -46.9068 kJ
|
|
-gamma 0 0
|
|
# Id: 2111300
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Be+2 + Br- = BeBr+
|
|
log_k 0.1009
|
|
delta_h 0 kJ
|
|
-gamma 5 0
|
|
# Id: 1101301
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.70 20.0
|
|
Pb+2 + I- = PbI+
|
|
log_k 2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6003800
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Pb+2 + 2 I- = PbI2
|
|
log_k 3.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6003801
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl+ + I- = TlI
|
|
log_k 1.4279
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8703800
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Tl+ + 2 I- = TlI2-
|
|
log_k 1.8588
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8703801
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Tl(OH)3 + 4 I- + 3 H+ = TlI4- + 3 H2O
|
|
log_k 34.7596
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8713800
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Zn+2 + I- = ZnI+
|
|
log_k -2.0427
|
|
delta_h -4 kJ
|
|
-gamma 0 0
|
|
# Id: 9503800
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 3.00 25.0
|
|
Zn+2 + 2 I- = ZnI2
|
|
log_k -1.69
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9503801
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Cd+2 + I- = CdI+
|
|
log_k 2.28
|
|
delta_h -9.6 kJ
|
|
-gamma 0 0
|
|
# Id: 1603800
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + 2 I- = CdI2
|
|
log_k 3.92
|
|
delta_h -12 kJ
|
|
-gamma 0 0
|
|
# Id: 1603801
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Hg(OH)2 + 2 H+ + I- = HgI+ + 2 H2O
|
|
log_k 19.603
|
|
delta_h -111.22 kJ
|
|
-gamma 0 0
|
|
# Id: 3613801
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.50 25.0
|
|
Hg(OH)2 + 2 H+ + 2 I- = HgI2 + 2 H2O
|
|
log_k 30.8225
|
|
delta_h -182.72 kJ
|
|
-gamma 0 0
|
|
# Id: 3613802
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.50 25.0
|
|
Hg(OH)2 + 2 H+ + 3 I- = HgI3- + 2 H2O
|
|
log_k 34.6025
|
|
delta_h -194.22 kJ
|
|
-gamma 0 0
|
|
# Id: 3613803
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength: 0.50 25.0
|
|
Hg(OH)2 + 2 H+ + 4 I- = HgI4-2 + 2 H2O
|
|
log_k 36.533
|
|
delta_h -220.72 kJ
|
|
-gamma 0 0
|
|
# Id: 3613804
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.50 25.0
|
|
Ag+ + I- = AgI
|
|
log_k 6.6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 203800
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 18.0
|
|
Ag+ + 2 I- = AgI2-
|
|
log_k 11.7
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 203801
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 18.0
|
|
Ag+ + 3 I- = AgI3-2
|
|
log_k 12.6
|
|
delta_h -122 kJ
|
|
-gamma 0 0
|
|
# Id: 203802
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + 4 I- = AgI4-3
|
|
log_k 14.229
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 203803
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 2.00 25.0
|
|
Cr(OH)2+ + I- + 2 H+ = CrI+2 + 2 H2O
|
|
log_k 4.8289
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2113800
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
H+ + HS- = H2S
|
|
log_k 7.02
|
|
delta_h -22 kJ
|
|
-gamma 0 0
|
|
# Id: 3307300
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Pb+2 + 2 HS- = Pb(HS)2
|
|
log_k 15.27
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6007300
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Pb+2 + 3 HS- = Pb(HS)3-
|
|
log_k 16.57
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6007301
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Tl+ + HS- = TlHS
|
|
log_k 2.474
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8707300
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
2 Tl+ + HS- = Tl2HS+
|
|
log_k 5.974
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8707301
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
2 Tl+ + 3 HS- + H2O = Tl2OH(HS)3-2 + H+
|
|
log_k 1.0044
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8707302
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
2 Tl+ + 2 HS- + 2 H2O = Tl2(OH)2(HS)2-2 + 2 H+
|
|
log_k -11.0681
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8707303
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Zn+2 + 2 HS- = Zn(HS)2
|
|
log_k 12.82
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9507300
|
|
# log K source: DHa1993
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + 3 HS- = Zn(HS)3-
|
|
log_k 16.1
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9507301
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Zn+2 + 3 HS- = ZnS(HS)2-2 + H+
|
|
log_k 6.12
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9507302
|
|
# log K source: DHa1993
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + 2 HS- + 2 HS- = Zn(HS)4-2
|
|
log_k 14.64
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9507303
|
|
# log K source: DHa1993
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + 2 HS- = ZnS(HS)- + H+
|
|
log_k 6.81
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9507304
|
|
# log K source: DHa1993
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + HS- = CdHS+
|
|
log_k 8.008
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1607300
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Cd+2 + 2 HS- = Cd(HS)2
|
|
log_k 15.212
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1607301
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Cd+2 + 3 HS- = Cd(HS)3-
|
|
log_k 17.112
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1607302
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Cd+2 + 4 HS- = Cd(HS)4-2
|
|
log_k 19.308
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1607303
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Hg(OH)2 + 2 HS- = HgS2-2 + 2 H2O
|
|
log_k 29.414
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3617300
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 20.0
|
|
Hg(OH)2 + 2 H+ + 2 HS- = Hg(HS)2 + 2 H2O
|
|
log_k 44.516
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3617301
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 20.0
|
|
Hg(OH)2 + H+ + 2 HS- = HgHS2- + 2 H2O
|
|
log_k 38.122
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3617302
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 20.0
|
|
Cu+2 + 3 HS- = Cu(HS)3-
|
|
log_k 25.899
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2317300
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Ag+ + HS- = AgHS
|
|
log_k 13.8145
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 207300
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.10 20.0
|
|
Ag+ + 2 HS- = Ag(HS)2-
|
|
log_k 17.9145
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 207301
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.10 20.0
|
|
Fe+2 + 2 HS- = Fe(HS)2
|
|
log_k 8.95
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2807300
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Fe+2 + 3 HS- = Fe(HS)3-
|
|
log_k 10.987
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2807301
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
HS- = S2-2 + H+
|
|
log_k -11.7828
|
|
delta_h 46.4 kJ
|
|
-gamma 0 0
|
|
-no_check
|
|
# Id: 7317300
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
HS- = S3-2 + H+
|
|
log_k -10.7667
|
|
delta_h 42.2 kJ
|
|
-gamma 0 0
|
|
-no_check
|
|
# Id: 7317301
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
HS- = S4-2 + H+
|
|
log_k -9.9608
|
|
delta_h 39.3 kJ
|
|
-gamma 0 0
|
|
-no_check
|
|
# Id: 7317302
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
HS- = S5-2 + H+
|
|
log_k -9.3651
|
|
delta_h 37.6 kJ
|
|
-gamma 0 0
|
|
-no_check
|
|
# Id: 7317303
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
HS- = S6-2 + H+
|
|
log_k -9.881
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
-no_check
|
|
# Id: 7317304
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
2 Sb(OH)3 + 4 HS- + 2 H+ = Sb2S4-2 + 6 H2O
|
|
log_k 49.3886
|
|
delta_h -321.78 kJ
|
|
-gamma 0 0
|
|
# Id: 7407300
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
Cu+ + 2 HS- = Cu(S4)2-3 + 2 H+
|
|
log_k 3.39
|
|
delta_h 0 kJ
|
|
-gamma 23 0
|
|
-no_check
|
|
# Id: 2307300
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Cu+ + 2 HS- = CuS4S5-3 + 2 H+
|
|
log_k 2.66
|
|
delta_h 0 kJ
|
|
-gamma 25 0
|
|
-no_check
|
|
# Id: 2307301
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Ag+ + 2 HS- = Ag(S4)2-3 + 2 H+
|
|
log_k 0.991
|
|
delta_h 0 kJ
|
|
-gamma 22 0
|
|
-no_check
|
|
# Id: 207302
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Ag+ + 2 HS- = AgS4S5-3 + 2 H+
|
|
log_k 0.68
|
|
delta_h 0 kJ
|
|
-gamma 24 0
|
|
-no_check
|
|
# Id: 207303
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Ag+ + 2 HS- = Ag(HS)S4-2 + H+
|
|
log_k 10.431
|
|
delta_h 0 kJ
|
|
-gamma 15 0
|
|
-no_check
|
|
# Id: 207304
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
H+ + SO4-2 = HSO4-
|
|
log_k 1.99
|
|
delta_h 22 kJ
|
|
-gamma 4.5 0
|
|
# Id: 3307320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
NH4+ + SO4-2 = NH4SO4-
|
|
log_k 1.03
|
|
delta_h 0 kJ
|
|
-gamma 5 0
|
|
# Id: 4907320
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Pb+2 + SO4-2 = PbSO4
|
|
log_k 2.69
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6007320
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Pb+2 + 2 SO4-2 = Pb(SO4)2-2
|
|
log_k 3.47
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6007321
|
|
# log K source: SCD3.02 (1960 RKa)
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Al+3 + SO4-2 = AlSO4+
|
|
log_k 3.89
|
|
delta_h 28 kJ
|
|
-gamma 4.5 0
|
|
# Id: 307320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Al+3 + 2 SO4-2 = Al(SO4)2-
|
|
log_k 4.92
|
|
delta_h 11.9 kJ
|
|
-gamma 4.5 0
|
|
# Id: 307321
|
|
# log K source: Nord90
|
|
# Delta H source: Nord90
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl+ + SO4-2 = TlSO4-
|
|
log_k 1.37
|
|
delta_h -0.8 kJ
|
|
-gamma 0 0
|
|
# Id: 8707320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + SO4-2 = ZnSO4
|
|
log_k 2.34
|
|
delta_h 6.2 kJ
|
|
-gamma 0 0
|
|
# Id: 9507320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + 2 SO4-2 = Zn(SO4)2-2
|
|
log_k 3.28
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9507321
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Cd+2 + SO4-2 = CdSO4
|
|
log_k 2.37
|
|
delta_h 8.7 kJ
|
|
-gamma 0 0
|
|
# Id: 1607320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + 2 SO4-2 = Cd(SO4)2-2
|
|
log_k 3.5
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1607321
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Hg(OH)2 + 2 H+ + SO4-2 = HgSO4 + 2 H2O
|
|
log_k 8.612
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3617320
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.50 25.0
|
|
Cu+2 + SO4-2 = CuSO4
|
|
log_k 2.36
|
|
delta_h 8.7 kJ
|
|
-gamma 0 0
|
|
# Id: 2317320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + SO4-2 = AgSO4-
|
|
log_k 1.3
|
|
delta_h 6.2 kJ
|
|
-gamma 0 0
|
|
# Id: 207320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ni+2 + SO4-2 = NiSO4
|
|
log_k 2.3
|
|
delta_h 5.8 kJ
|
|
-gamma 0 0
|
|
# Id: 5407320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ni+2 + 2 SO4-2 = Ni(SO4)2-2
|
|
log_k 0.82
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5407321
|
|
# log K source: SCD3.02 (1978 BLa)
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + SO4-2 = CoSO4
|
|
log_k 2.3
|
|
delta_h 6.2 kJ
|
|
-gamma 0 0
|
|
# Id: 2007320
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Fe+2 + SO4-2 = FeSO4
|
|
log_k 2.39
|
|
delta_h 8 kJ
|
|
-gamma 0 0
|
|
# Id: 2807320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Fe+3 + SO4-2 = FeSO4+
|
|
log_k 4.05
|
|
delta_h 25 kJ
|
|
-gamma 5 0
|
|
# Id: 2817320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Fe+3 + 2 SO4-2 = Fe(SO4)2-
|
|
log_k 5.38
|
|
delta_h 19.2 kJ
|
|
-gamma 0 0
|
|
# Id: 2817321
|
|
# log K source: Nord90
|
|
# Delta H source: Nord90
|
|
#T and ionic strength: 0.00 25.0
|
|
Mn+2 + SO4-2 = MnSO4
|
|
log_k 2.25
|
|
delta_h 8.7 kJ
|
|
-gamma 0 0
|
|
# Id: 4707320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cr(OH)2+ + 2 H+ + SO4-2 = CrSO4+ + 2 H2O
|
|
log_k 12.9371
|
|
delta_h -98.62 kJ
|
|
-gamma 0 0
|
|
# Id: 2117320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 1.00 50.0
|
|
Cr(OH)2+ + H+ + SO4-2 = CrOHSO4 + H2O
|
|
log_k 8.2871
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2117321
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.10 25.0
|
|
2 Cr(OH)2+ + SO4-2 + 2 H+ = Cr2(OH)2SO4+2 + 2 H2O
|
|
log_k 16.155
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2117323
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
2 Cr(OH)2+ + 2 SO4-2 + 2 H+ = Cr2(OH)2(SO4)2 + 2 H2O
|
|
log_k 17.9288
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2117324
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
U+4 + SO4-2 = USO4+2
|
|
log_k 6.6
|
|
delta_h 8 kJ
|
|
-gamma 0 0
|
|
# Id: 8917320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
U+4 + 2 SO4-2 = U(SO4)2
|
|
log_k 10.5
|
|
delta_h 33 kJ
|
|
-gamma 0 0
|
|
# Id: 8917321
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
UO2+2 + SO4-2 = UO2SO4
|
|
log_k 3.18
|
|
delta_h 20 kJ
|
|
-gamma 0 0
|
|
# Id: 8937320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
UO2+2 + 2 SO4-2 = UO2(SO4)2-2
|
|
log_k 4.3
|
|
delta_h 38 kJ
|
|
-gamma 0 0
|
|
# Id: 8937321
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
V+3 + SO4-2 = VSO4+
|
|
log_k 2.674
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9017320
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
VO+2 + SO4-2 = VOSO4
|
|
log_k 2.44
|
|
delta_h 17 kJ
|
|
-gamma 0 0
|
|
# Id: 9027320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
VO2+ + SO4-2 = VO2SO4-
|
|
log_k 1.378
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9037320
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 20.0
|
|
Be+2 + SO4-2 = BeSO4
|
|
log_k 2.19
|
|
delta_h 29 kJ
|
|
-gamma 0 0
|
|
# Id: 1107321
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Be+2 + 2 SO4-2 = Be(SO4)2-2
|
|
log_k 2.596
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1107322
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Mg+2 + SO4-2 = MgSO4
|
|
log_k 2.26
|
|
delta_h 5.8 kJ
|
|
-gamma 0 0
|
|
# Id: 4607320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ca+2 + SO4-2 = CaSO4
|
|
log_k 2.36
|
|
delta_h 7.1 kJ
|
|
-gamma 0 0
|
|
# Id: 1507320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Sr+2 + SO4-2 = SrSO4
|
|
log_k 2.3
|
|
delta_h 8 kJ
|
|
-gamma 0 0
|
|
# Id: 8007321
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Li+ + SO4-2 = LiSO4-
|
|
log_k 0.64
|
|
delta_h 0 kJ
|
|
-gamma 5 0
|
|
# Id: 4407320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Na+ + SO4-2 = NaSO4-
|
|
log_k 0.73
|
|
delta_h 1 kJ
|
|
-gamma 5.4 0
|
|
# Id: 5007320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
K+ + SO4-2 = KSO4-
|
|
log_k 0.85
|
|
delta_h 4.1 kJ
|
|
-gamma 5.4 0
|
|
# Id: 4107320
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
HSe- + H+ = H2Se
|
|
log_k 3.89
|
|
delta_h 3.3 kJ
|
|
-gamma 0 0
|
|
# Id: 3307600
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength: 0.00 25.0
|
|
2 Ag+ + HSe- = Ag2Se + H+
|
|
log_k 34.911
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 207600
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Ag+ + H2O + 2 HSe- = AgOH(Se)2-4 + 3 H+
|
|
log_k -20.509
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 207601
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Mn+2 + HSe- = MnSe + H+
|
|
log_k -5.385
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4707600
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
HSeO3- = SeO3-2 + H+
|
|
log_k -8.4
|
|
delta_h 5.02 kJ
|
|
-gamma 0 0
|
|
# Id: 3307611
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
HSeO3- + H+ = H2SeO3
|
|
log_k 2.63
|
|
delta_h 6.2 kJ
|
|
-gamma 0 0
|
|
# Id: 3307610
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + 2 HSeO3- = Cd(SeO3)2-2 + 2 H+
|
|
log_k -10.884
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1607610
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Ag+ + HSeO3- = AgSeO3- + H+
|
|
log_k -5.592
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 207610
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Ag+ + 2 HSeO3- = Ag(SeO3)2-3 + 2 H+
|
|
log_k -13.04
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 207611
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Fe+3 + HSeO3- = FeHSeO3+2
|
|
log_k 3.422
|
|
delta_h 25 kJ
|
|
-gamma 0 0
|
|
# Id: 2817610
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 1.00 25.0
|
|
SeO4-2 + H+ = HSeO4-
|
|
log_k 1.7
|
|
delta_h 23 kJ
|
|
-gamma 0 0
|
|
# Id: 3307620
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + SeO4-2 = ZnSeO4
|
|
log_k 2.19
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9507620
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + 2 SeO4-2 = Zn(SeO4)2-2
|
|
log_k 2.196
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9507621
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Cd+2 + SeO4-2 = CdSeO4
|
|
log_k 2.27
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1607620
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Ni+2 + SeO4-2 = NiSeO4
|
|
log_k 2.67
|
|
delta_h 14 kJ
|
|
-gamma 0 0
|
|
# Id: 5407620
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + SeO4-2 = CoSeO4
|
|
log_k 2.7
|
|
delta_h 12 kJ
|
|
-gamma 0 0
|
|
# Id: 2007621
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Mn+2 + SeO4-2 = MnSeO4
|
|
log_k 2.43
|
|
delta_h 14 kJ
|
|
-gamma 0 0
|
|
# Id: 4707620
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
NH4+ = NH3 + H+
|
|
log_k -9.244
|
|
delta_h 52 kJ
|
|
-gamma 0 0
|
|
# Id: 3304900
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + NH4+ = AgNH3+ + H+
|
|
log_k -5.934
|
|
delta_h -72 kJ
|
|
-gamma 0 0
|
|
# Id: 204901
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + 2 NH4+ = Ag(NH3)2+ + 2 H+
|
|
log_k -11.268
|
|
delta_h -160 kJ
|
|
-gamma 0 0
|
|
# Id: 204902
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Hg(OH)2 + H+ + NH4+ = HgNH3+2 + 2 H2O
|
|
log_k 5.75
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3614900
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 2.00 22.0
|
|
Hg(OH)2 + 2 NH4+ = Hg(NH3)2+2 + 2 H2O
|
|
log_k 5.506
|
|
delta_h -246.72 kJ
|
|
-gamma 0 0
|
|
# Id: 3614901
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 1.00 25.0
|
|
Hg(OH)2 + 3 NH4+ = Hg(NH3)3+2 + 2 H2O + H+
|
|
log_k -3.138
|
|
delta_h -312.72 kJ
|
|
-gamma 0 0
|
|
# Id: 3614902
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 2.00 25.0
|
|
Hg(OH)2 + 4 NH4+ = Hg(NH3)4+2 + 2 H2O + 2 H+
|
|
log_k -11.482
|
|
delta_h -379.72 kJ
|
|
-gamma 0 0
|
|
# Id: 3614903
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.10 25.0
|
|
Cu+2 + NH4+ = CuNH3+2 + H+
|
|
log_k -5.234
|
|
delta_h -72 kJ
|
|
-gamma 0 0
|
|
# Id: 2314901
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ni+2 + NH4+ = NiNH3+2 + H+
|
|
log_k -6.514
|
|
delta_h -67 kJ
|
|
-gamma 0 0
|
|
# Id: 5404901
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Ni+2 + 2 NH4+ = Ni(NH3)2+2 + 2 H+
|
|
log_k -13.598
|
|
delta_h -111.6 kJ
|
|
-gamma 0 0
|
|
# Id: 5404902
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Co+2 + NH4+ = Co(NH3)+2 + H+
|
|
log_k -7.164
|
|
delta_h -65 kJ
|
|
-gamma 0 0
|
|
# Id: 2004900
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Co+2 + 2 NH4+ = Co(NH3)2+2 + 2 H+
|
|
log_k -14.778
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2004901
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 2.00 25.0
|
|
Co+2 + 3 NH4+ = Co(NH3)3+2 + 3 H+
|
|
log_k -22.922
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2004902
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 2.00 25.0
|
|
Co+2 + 4 NH4+ = Co(NH3)4+2 + 4 H+
|
|
log_k -31.446
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2004903
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 2.00 30.0
|
|
Co+2 + 5 NH4+ = Co(NH3)5+2 + 5 H+
|
|
log_k -40.47
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2004904
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 2.00 30.0
|
|
Co+3 + 6 NH4+ + H2O = Co(NH3)6OH+2 + 7 H+
|
|
log_k -43.7148
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2014901
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Co+3 + 5 NH4+ + Cl- = Co(NH3)5Cl+2 + 5 H+
|
|
log_k -17.9584
|
|
delta_h 113.38 kJ
|
|
-gamma 0 0
|
|
# Id: 2014902
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
Co+3 + 6 NH4+ + Cl- = Co(NH3)6Cl+2 + 6 H+
|
|
log_k -33.9179
|
|
delta_h 104.34 kJ
|
|
-gamma 0 0
|
|
# Id: 2014903
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
Co+3 + 6 NH4+ + Br- = Co(NH3)6Br+2 + 6 H+
|
|
log_k -33.8884
|
|
delta_h 110.57 kJ
|
|
-gamma 0 0
|
|
# Id: 2014904
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
Co+3 + 6 NH4+ + I- = Co(NH3)6I+2 + 6 H+
|
|
log_k -33.4808
|
|
delta_h 115.44 kJ
|
|
-gamma 0 0
|
|
# Id: 2014905
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
Co+3 + 6 NH4+ + SO4-2 = Co(NH3)6SO4+ + 6 H+
|
|
log_k -28.9926
|
|
delta_h 124.5 kJ
|
|
-gamma 0 0
|
|
# Id: 2014906
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + 6 NH4+ = Cr(NH3)6+3 + 2 H2O + 4 H+
|
|
log_k -32.8952
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2114900
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 4.50 25.0
|
|
Cr(OH)2+ + 5 NH4+ = Cr(NH3)5OH+2 + 4 H+ + H2O
|
|
log_k -30.2759
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2114901
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + 6 NH4+ + Cl- = Cr(NH3)6Cl+2 + 2 H2O + 4 H+
|
|
log_k -31.7932
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2114904
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + 6 NH4+ + Br- = Cr(NH3)6Br+2 + 4 H+ + 2 H2O
|
|
log_k -31.887
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2114905
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + 6 NH4+ + I- = Cr(NH3)6I+2 + 4 H+ + 2 H2O
|
|
log_k -32.008
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2114906
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
#Cr(OH)2+ + 4NH4+ = cis+ + 4H+
|
|
# log_k -29.8574
|
|
# delta_h 0 kJ
|
|
# -gamma 0 0
|
|
# # Id: 4902113
|
|
# # log K source: MTQ3.11
|
|
# # Delta H source: MTQ3.11
|
|
# #T and ionic strength:
|
|
#Cr(OH)2+ + 4NH4+ = trans+ + 4H+
|
|
# log_k -30.5537
|
|
# delta_h 0 kJ
|
|
# -gamma 0 0
|
|
# # Id: 4902114
|
|
# # log K source: MTQ3.11
|
|
# # Delta H source: MTQ3.11
|
|
# #T and ionic strength:
|
|
Ca+2 + NH4+ = CaNH3+2 + H+
|
|
log_k -9.144
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1504901
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.50 25.0
|
|
Ca+2 + 2 NH4+ = Ca(NH3)2+2 + 2 H+
|
|
log_k -18.788
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1504902
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.50 25.0
|
|
Sr+2 + NH4+ = SrNH3+2 + H+
|
|
log_k -9.344
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8004901
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.50 25.0
|
|
Ba+2 + NH4+ = BaNH3+2 + H+
|
|
log_k -9.444
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1004901
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.50 25.0
|
|
Tl+ + NO2- = TlNO2
|
|
log_k 0.83
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8704910
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + NO2- = AgNO2
|
|
log_k 2.32
|
|
delta_h -29 kJ
|
|
-gamma 0 0
|
|
# Id: 204911
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + 2 NO2- = Ag(NO2)2-
|
|
log_k 2.51
|
|
delta_h -46 kJ
|
|
-gamma 0 0
|
|
# Id: 204910
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+2 + NO2- = CuNO2+
|
|
log_k 2.02
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2314911
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+2 + 2 NO2- = Cu(NO2)2
|
|
log_k 3.03
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2314912
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + NO2- = CoNO2+
|
|
log_k 0.848
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2004911
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Sn(OH)2 + 2 H+ + NO3- = SnNO3+ + 2 H2O
|
|
log_k 7.942
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7904921
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Pb+2 + NO3- = PbNO3+
|
|
log_k 1.17
|
|
delta_h 2 kJ
|
|
-gamma 0 0
|
|
# Id: 6004920
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Pb+2 + 2 NO3- = Pb(NO3)2
|
|
log_k 1.4
|
|
delta_h -6.6 kJ
|
|
-gamma 0 0
|
|
# Id: 6004921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl+ + NO3- = TlNO3
|
|
log_k 0.33
|
|
delta_h -2 kJ
|
|
-gamma 0 0
|
|
# Id: 8704920
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl(OH)3 + NO3- + 3 H+ = TlNO3+2 + 3 H2O
|
|
log_k 7.0073
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8714920
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Cd+2 + NO3- = CdNO3+
|
|
log_k 0.5
|
|
delta_h -21 kJ
|
|
-gamma 0 0
|
|
# Id: 1604920
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + 2 NO3- = Cd(NO3)2
|
|
log_k 0.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1604921
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Hg(OH)2 + 2 H+ + NO3- = HgNO3+ + 2 H2O
|
|
log_k 5.7613
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3614920
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 3.00 25.0
|
|
Hg(OH)2 + 2 H+ + 2 NO3- = Hg(NO3)2 + 2 H2O
|
|
log_k 5.38
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3614921
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 3.00 25.0
|
|
Cu+2 + NO3- = CuNO3+
|
|
log_k 0.5
|
|
delta_h -4.1 kJ
|
|
-gamma 0 0
|
|
# Id: 2314921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+2 + 2 NO3- = Cu(NO3)2
|
|
log_k -0.4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2314922
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + NO3- = ZnNO3+
|
|
log_k 0.4
|
|
delta_h -4.6 kJ
|
|
-gamma 0 0
|
|
# Id: 9504921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + 2 NO3- = Zn(NO3)2
|
|
log_k -0.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9504922
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + NO3- = AgNO3
|
|
log_k -0.1
|
|
delta_h 22.6 kJ
|
|
-gamma 0 0
|
|
# Id: 204920
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ni+2 + NO3- = NiNO3+
|
|
log_k 0.4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5404921
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + NO3- = CoNO3+
|
|
log_k 0.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2004921
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + 2 NO3- = Co(NO3)2
|
|
log_k 0.5085
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2004922
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.50 25.0
|
|
Fe+3 + NO3- = FeNO3+2
|
|
log_k 1
|
|
delta_h -37 kJ
|
|
-gamma 0 0
|
|
# Id: 2814921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Mn+2 + NO3- = MnNO3+
|
|
log_k 0.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4704921
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Mn+2 + 2 NO3- = Mn(NO3)2
|
|
log_k 0.6
|
|
delta_h -1.6569 kJ
|
|
-gamma 0 0
|
|
# Id: 4704920
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Cr(OH)2+ + NO3- + 2 H+ = CrNO3+2 + 2 H2O
|
|
log_k 8.2094
|
|
delta_h -65.4378 kJ
|
|
-gamma 0 0
|
|
# Id: 2114920
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
UO2+2 + NO3- = UO2NO3+
|
|
log_k 0.3
|
|
delta_h -12 kJ
|
|
-gamma 0 0
|
|
# Id: 8934921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
VO2+ + NO3- = VO2NO3
|
|
log_k -0.296
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9034920
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 20.0
|
|
Ca+2 + NO3- = CaNO3+
|
|
log_k 0.5
|
|
delta_h -5.4 kJ
|
|
-gamma 0 0
|
|
# Id: 1504921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Sr+2 + NO3- = SrNO3+
|
|
log_k 0.6
|
|
delta_h -10 kJ
|
|
-gamma 0 0
|
|
# Id: 8004921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ba+2 + NO3- = BaNO3+
|
|
log_k 0.7
|
|
delta_h -13 kJ
|
|
-gamma 0 0
|
|
# Id: 1004921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
H+ + Cyanide- = HCyanide
|
|
log_k 9.21
|
|
delta_h -43.63 kJ
|
|
-gamma 0 0
|
|
# Id: 3301431
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + Cyanide- = CdCyanide+
|
|
log_k 6.01
|
|
delta_h -30 kJ
|
|
-gamma 0 0
|
|
# Id: 1601431
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + 2 Cyanide- = Cd(Cyanide)2
|
|
log_k 11.12
|
|
delta_h -54.3 kJ
|
|
-gamma 0 0
|
|
# Id: 1601432
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + 3 Cyanide- = Cd(Cyanide)3-
|
|
log_k 15.65
|
|
delta_h -90.3 kJ
|
|
-gamma 0 0
|
|
# Id: 1601433
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + 4 Cyanide- = Cd(Cyanide)4-2
|
|
log_k 17.92
|
|
delta_h -112 kJ
|
|
-gamma 0 0
|
|
# Id: 1601434
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Hg(OH)2 + 2 H+ + Cyanide- = HgCyanide+ + 2 H2O
|
|
log_k 23.194
|
|
delta_h -136.72 kJ
|
|
-gamma 0 0
|
|
# Id: 3611431
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Hg(OH)2 + 2 H+ + 2 Cyanide- = Hg(Cyanide)2 + 2 H2O
|
|
log_k 38.944
|
|
delta_h 154.28 kJ
|
|
-gamma 0 0
|
|
# Id: 3611432
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Hg(OH)2 + 2 H+ + 3 Cyanide- = Hg(Cyanide)3- + 2 H2O
|
|
log_k 42.504
|
|
delta_h -262.72 kJ
|
|
-gamma 0 0
|
|
# Id: 3611433
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Hg(OH)2 + 2 H+ + 4 Cyanide- = Hg(Cyanide)4-2 + 2 H2O
|
|
log_k 45.164
|
|
delta_h -288.72 kJ
|
|
-gamma 0 0
|
|
# Id: 3611434
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+ + 2 Cyanide- = Cu(Cyanide)2-
|
|
log_k 21.9145
|
|
delta_h -121 kJ
|
|
-gamma 0 0
|
|
# Id: 2301432
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Cu+ + 3 Cyanide- = Cu(Cyanide)3-2
|
|
log_k 27.2145
|
|
delta_h -167.4 kJ
|
|
-gamma 0 0
|
|
# Id: 2301433
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+ + 4 Cyanide- = Cu(Cyanide)4-3
|
|
log_k 28.7145
|
|
delta_h -214.2 kJ
|
|
-gamma 0 0
|
|
# Id: 2301431
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + 2 Cyanide- = Ag(Cyanide)2-
|
|
log_k 20.48
|
|
delta_h -137 kJ
|
|
-gamma 0 0
|
|
# Id: 201432
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + 3 Cyanide- = Ag(Cyanide)3-2
|
|
log_k 21.7
|
|
delta_h -140 kJ
|
|
-gamma 0 0
|
|
# Id: 201433
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + H2O + Cyanide- = Ag(Cyanide)OH- + H+
|
|
log_k -0.777
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 201431
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Ni+2 + 4 Cyanide- = Ni(Cyanide)4-2
|
|
log_k 30.2
|
|
delta_h -180 kJ
|
|
-gamma 0 0
|
|
# Id: 5401431
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ni+2 + 4 Cyanide- + H+ = NiH(Cyanide)4-
|
|
log_k 36.0289
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5401432
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.10 25.0
|
|
Ni+2 + 4 Cyanide- + 2 H+ = NiH2Cyanide4
|
|
log_k 40.7434
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5401433
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.10 25.0
|
|
Ni+2 + 4 Cyanide- + 3 H+ = NiH3(Cyanide)4+
|
|
log_k 43.3434
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5401434
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.10 25.0
|
|
Co+2 + 3 Cyanide- = Co(Cyanide)3-
|
|
log_k 14.312
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2001431
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 1.00 25.0
|
|
Co+2 + 5 Cyanide- = Co(Cyanide)5-3
|
|
log_k 23
|
|
delta_h -257 kJ
|
|
-gamma 0 0
|
|
# Id: 2001432
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 1.00 25.0
|
|
Fe+2 + 6 Cyanide- = Fe(Cyanide)6-4
|
|
log_k 35.4
|
|
delta_h -358 kJ
|
|
-gamma 0 0
|
|
# Id: 2801431
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
H+ + Fe+2 + 6 Cyanide- = HFe(Cyanide)6-3
|
|
log_k 39.71
|
|
delta_h -356 kJ
|
|
-gamma 0 0
|
|
# Id: 2801432
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
2 H+ + Fe+2 + 6 Cyanide- = H2Fe(Cyanide)6-2
|
|
log_k 42.11
|
|
delta_h -352 kJ
|
|
-gamma 0 0
|
|
# Id: 2801433
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Fe+3 + 6 Cyanide- = Fe(Cyanide)6-3
|
|
log_k 43.6
|
|
delta_h -293 kJ
|
|
-gamma 0 0
|
|
# Id: 2811431
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
2 Fe+3 + 6 Cyanide- = Fe2(Cyanide)6
|
|
log_k 47.6355
|
|
delta_h -218 kJ
|
|
-gamma 0 0
|
|
# Id: 2811432
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.50 25.0
|
|
Sn(OH)2 + Fe+3 + 6 Cyanide- + 2 H+ = SnFe(Cyanide)6- + 2 H2O
|
|
log_k 53.54
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7901431
|
|
# log K source: Ba1987
|
|
# Delta H source:
|
|
#T and ionic strength: 0.00 25.0
|
|
NH4+ + Fe+2 + 6 Cyanide- = NH4Fe(Cyanide)6-3
|
|
log_k 37.7
|
|
delta_h -354 kJ
|
|
-gamma 0 0
|
|
# Id: 4901431
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl+ + Fe+2 + 6 Cyanide- = TlFe(Cyanide)6-3
|
|
log_k 38.4
|
|
delta_h -365.5 kJ
|
|
-gamma 0 0
|
|
# Id: 8701432
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Mg+2 + Fe+3 + 6 Cyanide- = MgFe(Cyanide)6-
|
|
log_k 46.39
|
|
delta_h -290 kJ
|
|
-gamma 0 0
|
|
# Id: 4601431
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Mg+2 + Fe+2 + 6 Cyanide- = MgFe(Cyanide)6-2
|
|
log_k 39.21
|
|
delta_h -346 kJ
|
|
-gamma 0 0
|
|
# Id: 4601432
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ca+2 + Fe+3 + 6 Cyanide- = CaFe(Cyanide)6-
|
|
log_k 46.43
|
|
delta_h -291 kJ
|
|
-gamma 0 0
|
|
# Id: 1501431
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ca+2 + Fe+2 + 6 Cyanide- = CaFe(Cyanide)6-2
|
|
log_k 39.1
|
|
delta_h -347 kJ
|
|
-gamma 0 0
|
|
# Id: 1501432
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
2 Ca+2 + Fe+2 + 6 Cyanide- = Ca2Fe(Cyanide)6
|
|
log_k 40.6
|
|
delta_h -350.201 kJ
|
|
-gamma 0 0
|
|
# Id: 1501433
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Sr+2 + Fe+3 + 6 Cyanide- = SrFe(Cyanide)6-
|
|
log_k 46.45
|
|
delta_h -292 kJ
|
|
-gamma 0 0
|
|
# Id: 8001431
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Sr+2 + Fe+2 + 6 Cyanide- = SrFe(Cyanide)6-2
|
|
log_k 39.1
|
|
delta_h -350 kJ
|
|
-gamma 0 0
|
|
# Id: 8001432
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ba+2 + Fe+2 + 6 Cyanide- = BaFe(Cyanide)6-2
|
|
log_k 39.19
|
|
delta_h -342 kJ
|
|
-gamma 0 0
|
|
# Id: 1001430
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ba+2 + Fe+3 + 6 Cyanide- = BaFe(Cyanide)6-
|
|
log_k 46.48
|
|
delta_h -292 kJ
|
|
-gamma 0 0
|
|
# Id: 1001431
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Na+ + Fe+2 + 6 Cyanide- = NaFe(Cyanide)6-3
|
|
log_k 37.6
|
|
delta_h -354 kJ
|
|
-gamma 0 0
|
|
# Id: 5001431
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
K+ + Fe+2 + 6 Cyanide- = KFe(Cyanide)6-3
|
|
log_k 37.75
|
|
delta_h -353.9 kJ
|
|
-gamma 0 0
|
|
# Id: 4101433
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
K+ + Fe+3 + 6 Cyanide- = KFe(Cyanide)6-2
|
|
log_k 45.04
|
|
delta_h -291 kJ
|
|
-gamma 0 0
|
|
# Id: 4101430
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
H+ + PO4-3 = HPO4-2
|
|
log_k 12.375
|
|
delta_h -15 kJ
|
|
-gamma 5 0
|
|
# Id: 3305800
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
2 H+ + PO4-3 = H2PO4-
|
|
log_k 19.573
|
|
delta_h -18 kJ
|
|
-gamma 5.4 0
|
|
# Id: 3305801
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
3 H+ + PO4-3 = H3PO4
|
|
log_k 21.721
|
|
delta_h -10.1 kJ
|
|
-gamma 0 0
|
|
# Id: 3305802
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + H+ + PO4-3 = CoHPO4
|
|
log_k 15.4128
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2005800
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.10 25.0
|
|
Fe+2 + 2 H+ + PO4-3 = FeH2PO4+
|
|
log_k 22.273
|
|
delta_h 0 kJ
|
|
-gamma 5.4 0
|
|
# Id: 2805800
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Fe+2 + H+ + PO4-3 = FeHPO4
|
|
log_k 15.975
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2805801
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Fe+3 + 2 H+ + PO4-3 = FeH2PO4+2
|
|
log_k 23.8515
|
|
delta_h 0 kJ
|
|
-gamma 5.4 0
|
|
# Id: 2815801
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.50 25.0
|
|
Fe+3 + H+ + PO4-3 = FeHPO4+
|
|
log_k 22.292
|
|
delta_h -30.5432 kJ
|
|
-gamma 5.4 0
|
|
# Id: 2815800
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.50 25.0
|
|
Cr(OH)2+ + 4 H+ + PO4-3 = CrH2PO4+2 + 2 H2O
|
|
log_k 31.9068
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2115800
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
U+4 + PO4-3 + H+ = UHPO4+2
|
|
log_k 24.443
|
|
delta_h 31.38 kJ
|
|
-gamma 0 0
|
|
# Id: 8915800
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
U+4 + 2 PO4-3 + 2 H+ = U(HPO4)2
|
|
log_k 46.833
|
|
delta_h 7.1128 kJ
|
|
-gamma 0 0
|
|
# Id: 8915801
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
U+4 + 3 PO4-3 + 3 H+ = U(HPO4)3-2
|
|
log_k 67.564
|
|
delta_h -32.6352 kJ
|
|
-gamma 0 0
|
|
# Id: 8915802
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
U+4 + 4 PO4-3 + 4 H+ = U(HPO4)4-4
|
|
log_k 88.483
|
|
delta_h -110.876 kJ
|
|
-gamma 0 0
|
|
# Id: 8915803
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
UO2+2 + H+ + PO4-3 = UO2HPO4
|
|
log_k 19.655
|
|
delta_h -8.7864 kJ
|
|
-gamma 0 0
|
|
# Id: 8935800
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
UO2+2 + 2 PO4-3 + 2 H+ = UO2(HPO4)2-2
|
|
log_k 42.988
|
|
delta_h -47.6934 kJ
|
|
-gamma 0 0
|
|
# Id: 8935801
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
UO2+2 + 2 H+ + PO4-3 = UO2H2PO4+
|
|
log_k 22.833
|
|
delta_h -15.4808 kJ
|
|
-gamma 0 0
|
|
# Id: 8935802
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
UO2+2 + 2 PO4-3 + 4 H+ = UO2(H2PO4)2
|
|
log_k 44.7
|
|
delta_h -69.036 kJ
|
|
-gamma 0 0
|
|
# Id: 8935803
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
UO2+2 + 3 PO4-3 + 6 H+ = UO2(H2PO4)3-
|
|
log_k 66.245
|
|
delta_h -119.662 kJ
|
|
-gamma 0 0
|
|
# Id: 8935804
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
UO2+2 + PO4-3 = UO2PO4-
|
|
log_k 13.25
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8935805
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Mg+2 + PO4-3 = MgPO4-
|
|
log_k 4.654
|
|
delta_h 12.9704 kJ
|
|
-gamma 5.4 0
|
|
# Id: 4605800
|
|
# log K source: SCD3.02 (1993 GMa)
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.20 25.0
|
|
Mg+2 + 2 H+ + PO4-3 = MgH2PO4+
|
|
log_k 21.2561
|
|
delta_h -4.6861 kJ
|
|
-gamma 5.4 0
|
|
# Id: 4605801
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 37.0
|
|
Mg+2 + H+ + PO4-3 = MgHPO4
|
|
log_k 15.175
|
|
delta_h -3 kJ
|
|
-gamma 0 0
|
|
# Id: 4605802
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ca+2 + H+ + PO4-3 = CaHPO4
|
|
log_k 15.035
|
|
delta_h -3 kJ
|
|
-gamma 0 0
|
|
# Id: 1505800
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ca+2 + PO4-3 = CaPO4-
|
|
log_k 6.46
|
|
delta_h 12.9704 kJ
|
|
-gamma 5.4 0
|
|
# Id: 1505801
|
|
# log K source: SCD3.02 (1993 GMa)
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Ca+2 + 2 H+ + PO4-3 = CaH2PO4+
|
|
log_k 20.923
|
|
delta_h -6 kJ
|
|
-gamma 5.4 0
|
|
# Id: 1505802
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Sr+2 + H+ + PO4-3 = SrHPO4
|
|
log_k 14.8728
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8005800
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.10 25.0
|
|
Sr+2 + 2 H+ + PO4-3 = SrH2PO4+
|
|
log_k 20.4019
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8005801
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.10 20.0
|
|
Na+ + H+ + PO4-3 = NaHPO4-
|
|
log_k 13.445
|
|
delta_h 0 kJ
|
|
-gamma 5.4 0
|
|
# Id: 5005800
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
K+ + H+ + PO4-3 = KHPO4-
|
|
log_k 13.255
|
|
delta_h 0 kJ
|
|
-gamma 5.4 0
|
|
# Id: 4105800
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
H3AsO3 = AsO3-3 + 3 H+
|
|
log_k -34.744
|
|
delta_h 84.726 kJ
|
|
-gamma 0 0
|
|
# Id: 3300602
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
H3AsO3 = HAsO3-2 + 2 H+
|
|
log_k -21.33
|
|
delta_h 59.4086 kJ
|
|
-gamma 0 0
|
|
# Id: 3300601
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
H3AsO3 = H2AsO3- + H+
|
|
log_k -9.29
|
|
delta_h 27.41 kJ
|
|
-gamma 0 0
|
|
# Id: 3300600
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength: 0.00 25.0
|
|
H3AsO3 + H+ = H4AsO3+
|
|
log_k -0.305
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3300603
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
H3AsO4 = AsO4-3 + 3 H+
|
|
log_k -20.7
|
|
delta_h 12.9 kJ
|
|
-gamma 0 0
|
|
# Id: 3300613
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
H3AsO4 = HAsO4-2 + 2 H+
|
|
log_k -9.2
|
|
delta_h -4.1 kJ
|
|
-gamma 0 0
|
|
# Id: 3300612
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
H3AsO4 = H2AsO4- + H+
|
|
log_k -2.24
|
|
delta_h -7.1 kJ
|
|
-gamma 0 0
|
|
# Id: 3300611
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Sb(OH)3 + H2O = Sb(OH)4- + H+
|
|
log_k -12.0429
|
|
delta_h 69.8519 kJ
|
|
-gamma 0 0
|
|
# Id: 7400020
|
|
# log K source: PNL89
|
|
# Delta H source: PNL89
|
|
#T and ionic strength:
|
|
Sb(OH)3 + H+ = Sb(OH)2+ + H2O
|
|
log_k 1.3853
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7403302
|
|
# log K source: PNL89
|
|
# Delta H source: PNL89
|
|
#T and ionic strength:
|
|
Sb(OH)3 = HSbO2 + H2O
|
|
log_k -0.0105
|
|
delta_h -0.13 kJ
|
|
-gamma 0 0
|
|
# Id: 7400021
|
|
# log K source: NIST2.1.1
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength:
|
|
Sb(OH)3 = SbO2- + H2O + H+
|
|
log_k -11.8011
|
|
delta_h 70.1866 kJ
|
|
-gamma 0 0
|
|
# Id: 7403301
|
|
# log K source: PNL89
|
|
# Delta H source: PNL89
|
|
#T and ionic strength:
|
|
Sb(OH)3 + H+ = SbO+ + 2 H2O
|
|
log_k 0.9228
|
|
delta_h 8.2425 kJ
|
|
-gamma 0 0
|
|
# Id: 7403300
|
|
# log K source: PNL89
|
|
# Delta H source: PNL89
|
|
#T and ionic strength:
|
|
Sb(OH)6- = SbO3- + 3 H2O
|
|
log_k 2.9319
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7410021
|
|
# log K source: PNL89
|
|
# Delta H source: PNL89
|
|
#T and ionic strength:
|
|
Sb(OH)6- + 2 H+ = SbO2+ + 4 H2O
|
|
log_k 2.3895
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7413300
|
|
# log K source: PNL89
|
|
# Delta H source: PNL89
|
|
#T and ionic strength:
|
|
H+ + CO3-2 = HCO3-
|
|
log_k 10.329
|
|
delta_h -14.6 kJ
|
|
-gamma 5.4 0
|
|
# Id: 3301400
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
2 H+ + CO3-2 = H2CO3
|
|
log_k 16.681
|
|
delta_h -23.76 kJ
|
|
-gamma 0 0
|
|
# Id: 3301401
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Pb+2 + 2 CO3-2 = Pb(CO3)2-2
|
|
log_k 9.938
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6001400
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.50 25.0
|
|
Pb+2 + CO3-2 = PbCO3
|
|
log_k 6.478
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6001401
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.50 25.0
|
|
Pb+2 + CO3-2 + H+ = PbHCO3+
|
|
log_k 13.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6001402
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
Zn+2 + CO3-2 = ZnCO3
|
|
log_k 4.76
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9501401
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + H+ + CO3-2 = ZnHCO3+
|
|
log_k 11.829
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9501400
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Hg(OH)2 + 2 H+ + CO3-2 = HgCO3 + 2 H2O
|
|
log_k 18.272
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3611401
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.50 25.0
|
|
Hg(OH)2 + 2 H+ + 2 CO3-2 = Hg(CO3)2-2 + 2 H2O
|
|
log_k 21.772
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3611402
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.50 25.0
|
|
Hg(OH)2 + 3 H+ + CO3-2 = HgHCO3+ + 2 H2O
|
|
log_k 22.542
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3611403
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.50 25.0
|
|
Cd+2 + CO3-2 = CdCO3
|
|
log_k 4.3578
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1601401
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.10 25.0
|
|
Cd+2 + H+ + CO3-2 = CdHCO3+
|
|
log_k 10.6863
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1601400
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 3.00 25.0
|
|
Cd+2 + 2 CO3-2 = Cd(CO3)2-2
|
|
log_k 7.2278
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1601403
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.10 20.0
|
|
Cu+2 + CO3-2 = CuCO3
|
|
log_k 6.77
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2311400
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+2 + H+ + CO3-2 = CuHCO3+
|
|
log_k 12.129
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2311402
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+2 + 2 CO3-2 = Cu(CO3)2-2
|
|
log_k 10.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2311401
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Ni+2 + CO3-2 = NiCO3
|
|
log_k 4.5718
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5401401
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.70 25.0
|
|
Ni+2 + H+ + CO3-2 = NiHCO3+
|
|
log_k 12.4199
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5401400
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.70 25.0
|
|
Co+2 + CO3-2 = CoCO3
|
|
log_k 4.228
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2001400
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.50 25.0
|
|
Co+2 + H+ + CO3-2 = CoHCO3+
|
|
log_k 12.2199
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2001401
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.70 25.0
|
|
Fe+2 + H+ + CO3-2 = FeHCO3+
|
|
log_k 11.429
|
|
delta_h 0 kJ
|
|
-gamma 6 0
|
|
# Id: 2801400
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Mn+2 + H+ + CO3-2 = MnHCO3+
|
|
log_k 11.629
|
|
delta_h -10.6 kJ
|
|
-gamma 5 0
|
|
# Id: 4701400
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
UO2+2 + CO3-2 = UO2CO3
|
|
log_k 9.6
|
|
delta_h 4 kJ
|
|
-gamma 0 0
|
|
# Id: 8931400
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
UO2+2 + 2 CO3-2 = UO2(CO3)2-2
|
|
log_k 16.9
|
|
delta_h 16 kJ
|
|
-gamma 0 0
|
|
# Id: 8931401
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
UO2+2 + 3 CO3-2 = UO2(CO3)3-4
|
|
log_k 21.6
|
|
delta_h -40 kJ
|
|
-gamma 0 0
|
|
# Id: 8931402
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Be+2 + CO3-2 = BeCO3
|
|
log_k 6.2546
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1101401
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 3.00 25.0
|
|
Mg+2 + CO3-2 = MgCO3
|
|
log_k 2.92
|
|
delta_h 12 kJ
|
|
-gamma 0 0
|
|
# Id: 4601400
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Mg+2 + H+ + CO3-2 = MgHCO3+
|
|
log_k 11.339
|
|
delta_h -10.6 kJ
|
|
-gamma 4 0
|
|
# Id: 4601401
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Ca+2 + H+ + CO3-2 = CaHCO3+
|
|
log_k 11.599
|
|
delta_h 5.4 kJ
|
|
-gamma 6 0
|
|
# Id: 1501400
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
CO3-2 + Ca+2 = CaCO3
|
|
log_k 3.2
|
|
delta_h 16 kJ
|
|
-gamma 0 0
|
|
# Id: 1501401
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
Sr+2 + CO3-2 = SrCO3
|
|
log_k 2.81
|
|
delta_h 20 kJ
|
|
-gamma 0 0
|
|
# Id: 8001401
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Sr+2 + H+ + CO3-2 = SrHCO3+
|
|
log_k 11.539
|
|
delta_h 10.4 kJ
|
|
-gamma 6 0
|
|
# Id: 8001400
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ba+2 + CO3-2 = BaCO3
|
|
log_k 2.71
|
|
delta_h 16 kJ
|
|
-gamma 0 0
|
|
# Id: 1001401
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ba+2 + H+ + CO3-2 = BaHCO3+
|
|
log_k 11.309
|
|
delta_h 10.4 kJ
|
|
-gamma 6 0
|
|
# Id: 1001400
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Na+ + CO3-2 = NaCO3-
|
|
log_k 1.27
|
|
delta_h -20.35 kJ
|
|
-gamma 5.4 0
|
|
# Id: 5001400
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength: 0.00 25.0
|
|
Na+ + H+ + CO3-2 = NaHCO3
|
|
log_k 10.079
|
|
delta_h -28.3301 kJ
|
|
-gamma 0 0
|
|
# Id: 5001401
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST2.1.1
|
|
#T and ionic strength: 0.00 25.0
|
|
H4SiO4 = H2SiO4-2 + 2 H+
|
|
log_k -23.04
|
|
delta_h 61 kJ
|
|
-gamma 5.4 0
|
|
# Id: 3307701
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
H4SiO4 = H3SiO4- + H+
|
|
log_k -9.84
|
|
delta_h 20 kJ
|
|
-gamma 4 0
|
|
# Id: 3307700
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
UO2+2 + H4SiO4 = UO2H3SiO4+ + H+
|
|
log_k -1.9111
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8937700
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.10 25.0
|
|
H3BO3 = H2BO3- + H+
|
|
log_k -9.236
|
|
delta_h 13 kJ
|
|
-gamma 2.5 0
|
|
# Id: 3300900
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
2 H3BO3 = H5(BO3)2- + H+
|
|
log_k -9.306
|
|
delta_h 8.4 kJ
|
|
-gamma 2.5 0
|
|
# Id: 3300901
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
3 H3BO3 = H8(BO3)3- + H+
|
|
log_k -7.306
|
|
delta_h 29.4 kJ
|
|
-gamma 2.5 0
|
|
# Id: 3300902
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + H3BO3 = AgH2BO3 + H+
|
|
log_k -8.036
|
|
delta_h 0 kJ
|
|
-gamma 2.5 0
|
|
# Id: 200901
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Mg+2 + H3BO3 = MgH2BO3+ + H+
|
|
log_k -7.696
|
|
delta_h 13 kJ
|
|
-gamma 2.5 0
|
|
# Id: 4600901
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ca+2 + H3BO3 = CaH2BO3+ + H+
|
|
log_k -7.476
|
|
delta_h 17 kJ
|
|
-gamma 2.5 0
|
|
# Id: 1500901
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Sr+2 + H3BO3 = SrH2BO3+ + H+
|
|
log_k -7.686
|
|
delta_h 17 kJ
|
|
-gamma 2.5 0
|
|
# Id: 8000901
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ba+2 + H3BO3 = BaH2BO3+ + H+
|
|
log_k -7.746
|
|
delta_h 17 kJ
|
|
-gamma 2.5 0
|
|
# Id: 1000901
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Na+ + H3BO3 = NaH2BO3 + H+
|
|
log_k -9.036
|
|
delta_h 0 kJ
|
|
-gamma 2.5 0
|
|
# Id: 5000901
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
CrO4-2 + H+ = HCrO4-
|
|
log_k 6.51
|
|
delta_h 2 kJ
|
|
-gamma 0 0
|
|
# Id: 2123300
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
CrO4-2 + 2 H+ = H2CrO4
|
|
log_k 6.4188
|
|
delta_h 39 kJ
|
|
-gamma 0 0
|
|
# Id: 2123301
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 20.0
|
|
2 CrO4-2 + 2 H+ = Cr2O7-2 + H2O
|
|
log_k 14.56
|
|
delta_h -15 kJ
|
|
-gamma 0 0
|
|
# Id: 2123302
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
CrO4-2 + Cl- + 2 H+ = CrO3Cl- + H2O
|
|
log_k 7.3086
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2121800
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
CrO4-2 + SO4-2 + 2 H+ = CrO3SO4-2 + H2O
|
|
log_k 8.9937
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2127320
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
CrO4-2 + 4 H+ + PO4-3 = CrO3H2PO4- + H2O
|
|
log_k 29.3634
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2125800
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
CrO4-2 + 3 H+ + PO4-3 = CrO3HPO4-2 + H2O
|
|
log_k 26.6806
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2125801
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
CrO4-2 + Na+ = NaCrO4-
|
|
log_k 0.6963
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5002120
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
K+ + CrO4-2 = KCrO4-
|
|
log_k 0.57
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4102120
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 18.0
|
|
MoO4-2 + H+ = HMoO4-
|
|
log_k 4.2988
|
|
delta_h 20 kJ
|
|
-gamma 0 0
|
|
# Id: 3304801
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 20.0
|
|
MoO4-2 + 2 H+ = H2MoO4
|
|
log_k 8.1636
|
|
delta_h -26 kJ
|
|
-gamma 0 0
|
|
# Id: 3304802
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 20.0
|
|
7 MoO4-2 + 8 H+ = Mo7O24-6 + 4 H2O
|
|
log_k 52.99
|
|
delta_h -228 kJ
|
|
-gamma 0 0
|
|
# Id: 3304803
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
7 MoO4-2 + 9 H+ = HMo7O24-5 + 4 H2O
|
|
log_k 59.3768
|
|
delta_h -218 kJ
|
|
-gamma 0 0
|
|
# Id: 3304804
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
7 MoO4-2 + 10 H+ = H2Mo7O24-4 + 4 H2O
|
|
log_k 64.159
|
|
delta_h -215 kJ
|
|
-gamma 0 0
|
|
# Id: 3304805
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
7 MoO4-2 + 11 H+ = H3Mo7O24-3 + 4 H2O
|
|
log_k 67.405
|
|
delta_h -217 kJ
|
|
-gamma 0 0
|
|
# Id: 3304806
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 1.00 25.0
|
|
6 MoO4-2 + Al+3 + 6 H+ = AlMo6O21-3 + 3 H2O
|
|
log_k 54.9925
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 304801
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.50 25.0
|
|
MoO4-2 + 2 Ag+ = Ag2MoO4
|
|
log_k -0.4219
|
|
delta_h -1.18 kJ
|
|
-gamma 0 0
|
|
# Id: 204801
|
|
# log K source: Bard85
|
|
# Delta H source: Bard85
|
|
#T and ionic strength:
|
|
VO2+ + 2 H2O = VO4-3 + 4 H+
|
|
log_k -30.2
|
|
delta_h -25 kJ
|
|
-gamma 0 0
|
|
# Id: 9033303
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
VO2+ + 2 H2O = HVO4-2 + 3 H+
|
|
log_k -15.9
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9033302
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
VO2+ + 2 H2O = H2VO4- + 2 H+
|
|
log_k -7.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9033301
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
VO2+ + 2 H2O = H3VO4 + H+
|
|
log_k -3.3
|
|
delta_h 44.4759 kJ
|
|
-gamma 0 0
|
|
# Id: 9033300
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
2 VO2+ + 3 H2O = V2O7-4 + 6 H+
|
|
log_k -31.24
|
|
delta_h -28 kJ
|
|
-gamma 0 0
|
|
# Id: 9030020
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
2 VO2+ + 3 H2O = HV2O7-3 + 5 H+
|
|
log_k -20.67
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9030021
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
2 VO2+ + 3 H2O = H3V2O7- + 3 H+
|
|
log_k -3.79
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9030022
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
3 VO2+ + 3 H2O = V3O9-3 + 6 H+
|
|
log_k -15.88
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9030023
|
|
# log K source: MTQ3.11
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength:
|
|
4 VO2+ + 4 H2O = V4O12-4 + 8 H+
|
|
log_k -20.56
|
|
delta_h -87 kJ
|
|
-gamma 0 0
|
|
# Id: 9030024
|
|
# log K source: NIST46.3
|
|
# Delta H source: NIST46.3
|
|
#T and ionic strength: 0.00 25.0
|
|
10 VO2+ + 8 H2O = V10O28-6 + 16 H+
|
|
log_k -24.0943
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9030025
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.10 20.0
|
|
10 VO2+ + 8 H2O = HV10O28-5 + 15 H+
|
|
log_k -15.9076
|
|
delta_h 90.0397 kJ
|
|
-gamma 0 0
|
|
# Id: 9030026
|
|
# log K source: NIST46.4
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.10 20.0
|
|
10 VO2+ + 8 H2O = H2V10O28-4 + 14 H+
|
|
log_k -10.7
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9030027
|
|
# log K source: NIST46.3
|
|
# Delta H source: MTQ3.11
|
|
#T and ionic strength: 0.00 25.0
|
|
Benzoate- + H+ = H(Benzoate)
|
|
log_k 4.202
|
|
delta_h -0.4602 kJ
|
|
-gamma 0 0
|
|
# Id: 3309171
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Benzoate- + Pb+2 = Pb(Benzoate)+
|
|
log_k 2.4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009171
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Benzoate- + Al+3 = Al(Benzoate)+2
|
|
log_k 2.05
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 309171
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Benzoate- + Al+3 + H2O = AlOH(Benzoate)+ + H+
|
|
log_k -0.56
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 309172
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Benzoate- + Zn+2 = Zn(Benzoate)+
|
|
log_k 1.7
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509171
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Benzoate- + Cd+2 = Cd(Benzoate)+
|
|
log_k 1.8
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609171
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
2 Benzoate- + Cd+2 = Cd(Benzoate)2
|
|
log_k 1.82
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609172
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Benzoate- + Cu+2 = Cu(Benzoate)+
|
|
log_k 2.19
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319171
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Benzoate- + Ag+ = Ag(Benzoate)
|
|
log_k 0.91
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 209171
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Benzoate- + Ni+2 = Ni(Benzoate)+
|
|
log_k 1.86
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409171
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Co+2 + Benzoate- = Co(Benzoate)+
|
|
log_k 1.0537
|
|
delta_h 12 kJ
|
|
-gamma 0 0
|
|
# Id: 2009171
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.50 30.0
|
|
Benzoate- + Mn+2 = Mn(Benzoate)+
|
|
log_k 2.06
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4709171
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Benzoate- + Mg+2 = Mg(Benzoate)+
|
|
log_k 1.26
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4609171
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Benzoate- + Ca+2 = Ca(Benzoate)+
|
|
log_k 1.55
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1509171
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Phenylacetate- + H+ = H(Phenylacetate)
|
|
log_k 4.31
|
|
delta_h 2.1757 kJ
|
|
-gamma 0 0
|
|
# Id: 3309181
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Phenylacetate- + Zn+2 = Zn(Phenylacetate)+
|
|
log_k 1.57
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509181
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Phenylacetate- + Cu+2 = Cu(Phenylacetate)+
|
|
log_k 1.97
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319181
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Co+2 + Phenylacetate- = Co(Phenylacetate)+
|
|
log_k 0.591
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009181
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 2.00 25.0
|
|
Co+2 + 2 Phenylacetate- = Co(Phenylacetate)2
|
|
log_k 0.4765
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009182
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 2.00 25.0
|
|
Isophthalate-2 + H+ = H(Isophthalate)-
|
|
log_k 4.5
|
|
delta_h 1.6736 kJ
|
|
-gamma 0 0
|
|
# Id: 3309201
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Isophthalate-2 + 2 H+ = H2(Isophthalate)
|
|
log_k 8
|
|
delta_h 1.6736 kJ
|
|
-gamma 0 0
|
|
# Id: 3309202
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Isophthalate-2 + Pb+2 = Pb(Isophthalate)
|
|
log_k 2.99
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009201
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
2 Isophthalate-2 + Pb+2 = Pb(Isophthalate)2-2
|
|
log_k 4.18
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009202
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Isophthalate-2 + Pb+2 + H+ = PbH(Isophthalate)+
|
|
log_k 6.69
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009203
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Isophthalate-2 + Cd+2 = Cd(Isophthalate)
|
|
log_k 2.15
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609201
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
2 Isophthalate-2 + Cd+2 = Cd(Isophthalate)2-2
|
|
log_k 2.99
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609202
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Isophthalate-2 + Cd+2 + H+ = CdH(Isophthalate)+
|
|
log_k 5.73
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609203
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Isophthalate-2 + Ca+2 = Ca(Isophthalate)
|
|
log_k 2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1509200
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Isophthalate-2 + Ba+2 = Ba(Isophthalate)
|
|
log_k 1.55
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1009201
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
H+ + Diethylamine = H(Diethylamine)+
|
|
log_k 10.933
|
|
delta_h -53.1368 kJ
|
|
-gamma 0 0
|
|
# Id: 3309551
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Diethylamine = Zn(Diethylamine)+2
|
|
log_k 2.74
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509551
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Zn+2 + 2 Diethylamine = Zn(Diethylamine)2+2
|
|
log_k 5.27
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509552
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Zn+2 + 3 Diethylamine = Zn(Diethylamine)3+2
|
|
log_k 7.71
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509553
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Zn+2 + 4 Diethylamine = Zn(Diethylamine)4+2
|
|
log_k 9.84
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509554
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + Diethylamine = Cd(Diethylamine)+2
|
|
log_k 2.73
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609551
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + 2 Diethylamine = Cd(Diethylamine)2+2
|
|
log_k 4.86
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609552
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + 3 Diethylamine = Cd(Diethylamine)3+2
|
|
log_k 6.37
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609553
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + 4 Diethylamine = Cd(Diethylamine)4+2
|
|
log_k 7.32
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609554
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Ag+ + Diethylamine = Ag(Diethylamine)+
|
|
log_k 2.98
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 209551
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + 2 Diethylamine = Ag(Diethylamine)2+
|
|
log_k 6.38
|
|
delta_h -44.7688 kJ
|
|
-gamma 0 0
|
|
# Id: 209552
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Diethylamine = Ni(Diethylamine)+2
|
|
log_k 2.78
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409551
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Ni+2 + 2 Diethylamine = Ni(Diethylamine)2+2
|
|
log_k 4.97
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409552
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Ni+2 + 3 Diethylamine = Ni(Diethylamine)3+2
|
|
log_k 6.72
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409553
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Ni+2 + 4 Diethylamine = Ni(Diethylamine)4+2
|
|
log_k 7.93
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409554
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Ni+2 + 5 Diethylamine = Ni(Diethylamine)5+2
|
|
log_k 8.87
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409555
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
H+ + Butylamine = H(Butylamine)+
|
|
log_k 10.64
|
|
delta_h -58.2831 kJ
|
|
-gamma 0 0
|
|
# Id: 3309561
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + Butylamine + 2 H+ = Hg(Butylamine)+2 + 2 H2O
|
|
log_k 14.84
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619561
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + 2 Butylamine + 2 H+ = Hg(Butylamine)2+2 + 2 H2O
|
|
log_k 24.24
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619562
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + 3 Butylamine + 2 H+ = Hg(Butylamine)3+2 + 2 H2O
|
|
log_k 25.1
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619563
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + 4 Butylamine + 2 H+ = Hg(Butylamine)4+2 + 2 H2O
|
|
log_k 26.1
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619564
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + Butylamine = Ag(Butylamine)+
|
|
log_k 3.42
|
|
delta_h -16.736 kJ
|
|
-gamma 0 0
|
|
# Id: 209561
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + 2 Butylamine = Ag(Butylamine)2+
|
|
log_k 7.47
|
|
delta_h -52.7184 kJ
|
|
-gamma 0 0
|
|
# Id: 209562
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
H+ + Methylamine = H(Methylamine)+
|
|
log_k 10.64
|
|
delta_h -55.2288 kJ
|
|
-gamma 0 0
|
|
# Id: 3309581
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + Methylamine = Cd(Methylamine)+2
|
|
log_k 2.75
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609581
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + 2 Methylamine = Cd(Methylamine)2+2
|
|
log_k 4.81
|
|
delta_h -29.288 kJ
|
|
-gamma 0 0
|
|
# Id: 1609582
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + 3 Methylamine = Cd(Methylamine)3+2
|
|
log_k 5.94
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609583
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + 4 Methylamine = Cd(Methylamine)4+2
|
|
log_k 6.55
|
|
delta_h -58.576 kJ
|
|
-gamma 0 0
|
|
# Id: 1609584
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + Methylamine + 2 H+ = Hg(Methylamine)+2 + 2 H2O
|
|
log_k 14.76
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619581
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + 2 Methylamine + 2 H+ = Hg(Methylamine)2+2 + 2 H2O
|
|
log_k 23.96
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619582
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + 3 Methylamine + 2 H+ = Hg(Methylamine)3+2 + 2 H2O
|
|
log_k 24.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619583
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + 4 Methylamine + 2 H+ = Hg(Methylamine)4+2 + 2 H2O
|
|
log_k 24.6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619584
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Methylamine = Cu(Methylamine)+2
|
|
log_k 4.11
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319581
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 2 Methylamine = Cu(Methylamine)2+2
|
|
log_k 7.51
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319582
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 3 Methylamine = Cu(Methylamine)3+2
|
|
log_k 10.21
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319583
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 4 Methylamine = Cu(Methylamine)4+2
|
|
log_k 12.08
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319584
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + Methylamine = Ag(Methylamine)+
|
|
log_k 3.07
|
|
delta_h -12.552 kJ
|
|
-gamma 0 0
|
|
# Id: 209581
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + 2 Methylamine = Ag(Methylamine)2+
|
|
log_k 6.89
|
|
delta_h -48.9528 kJ
|
|
-gamma 0 0
|
|
# Id: 209582
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Methylamine = Ni(Methylamine)+2
|
|
log_k 2.23
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409581
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
H+ + Dimethylamine = H(Dimethylamine)+
|
|
log_k 10.774
|
|
delta_h -50.208 kJ
|
|
-gamma 0 0
|
|
# Id: 3309591
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + 2 Dimethylamine = Ag(Dimethylamine)2+
|
|
log_k 5.37
|
|
delta_h -40.5848 kJ
|
|
-gamma 0 0
|
|
# Id: 209591
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Dimethylamine = Ni(Dimethylamine)+2
|
|
log_k 1.47
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409591
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
H+ + Hexylamine = H(Hexylamine)+
|
|
log_k 10.63
|
|
delta_h -58.576 kJ
|
|
-gamma 0 0
|
|
# Id: 3309611
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + Hexylamine = Ag(Hexylamine)+
|
|
log_k 3.54
|
|
delta_h -25.104 kJ
|
|
-gamma 0 0
|
|
# Id: 209611
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + 2 Hexylamine = Ag(Hexylamine)2+
|
|
log_k 7.55
|
|
delta_h -53.1368 kJ
|
|
-gamma 0 0
|
|
# Id: 209612
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
H+ + Ethylenediamine = H(Ethylenediamine)+
|
|
log_k 9.928
|
|
delta_h -49.7896 kJ
|
|
-gamma 0 0
|
|
# Id: 3309631
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
2 H+ + Ethylenediamine = H2(Ethylenediamine)+2
|
|
log_k 16.776
|
|
delta_h -95.3952 kJ
|
|
-gamma 0 0
|
|
# Id: 3309632
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Pb+2 + Ethylenediamine = Pb(Ethylenediamine)+2
|
|
log_k 5.04
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009631
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Pb+2 + 2 Ethylenediamine = Pb(Ethylenediamine)2+2
|
|
log_k 8.5
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009632
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Ethylenediamine = Zn(Ethylenediamine)+2
|
|
log_k 5.66
|
|
delta_h -29.288 kJ
|
|
-gamma 0 0
|
|
# Id: 9509631
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + 2 Ethylenediamine = Zn(Ethylenediamine)2+2
|
|
log_k 10.6
|
|
delta_h -48.116 kJ
|
|
-gamma 0 0
|
|
# Id: 9509632
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + 3 Ethylenediamine = Zn(Ethylenediamine)3+2
|
|
log_k 13.9
|
|
delta_h -71.5464 kJ
|
|
-gamma 0 0
|
|
# Id: 9509633
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + Ethylenediamine = Cd(Ethylenediamine)+2
|
|
log_k 5.41
|
|
delta_h -28.4512 kJ
|
|
-gamma 0 0
|
|
# Id: 1609631
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + 2 Ethylenediamine = Cd(Ethylenediamine)2+2
|
|
log_k 9.9
|
|
delta_h -55.6472 kJ
|
|
-gamma 0 0
|
|
# Id: 1609632
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + 3 Ethylenediamine = Cd(Ethylenediamine)3+2
|
|
log_k 11.6
|
|
delta_h -82.4248 kJ
|
|
-gamma 0 0
|
|
# Id: 1609633
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + Ethylenediamine + 2 H+ = Hg(Ethylenediamine)+2 + 2 H2O
|
|
log_k 20.4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619631
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + 2 Ethylenediamine + 2 H+ = Hg(Ethylenediamine)2+2 + 2 H2O
|
|
log_k 29.3
|
|
delta_h -173.218 kJ
|
|
-gamma 0 0
|
|
# Id: 3619632
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + 2 Ethylenediamine + 3 H+ = HgH(Ethylenediamine)2+3 + 2 H2O
|
|
log_k 34.7
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619633
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+ + 2 Ethylenediamine = Cu(Ethylenediamine)2+
|
|
log_k 11.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2309631
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Ethylenediamine = Cu(Ethylenediamine)+2
|
|
log_k 10.5
|
|
delta_h -52.7184 kJ
|
|
-gamma 0 0
|
|
# Id: 2319631
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 2 Ethylenediamine = Cu(Ethylenediamine)2+2
|
|
log_k 19.6
|
|
delta_h -105.437 kJ
|
|
-gamma 0 0
|
|
# Id: 2319632
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + Ethylenediamine = Ag(Ethylenediamine)+
|
|
log_k 4.6
|
|
delta_h -48.9528 kJ
|
|
-gamma 0 0
|
|
# Id: 209631
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + 2 Ethylenediamine = Ag(Ethylenediamine)2+
|
|
log_k 7.5
|
|
delta_h -52.3 kJ
|
|
-gamma 0 0
|
|
# Id: 209632
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + Ethylenediamine + H+ = AgH(Ethylenediamine)+2
|
|
log_k 11.99
|
|
delta_h -75.312 kJ
|
|
-gamma 0 0
|
|
# Id: 209633
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
2 Ag+ + Ethylenediamine = Ag2(Ethylenediamine)+2
|
|
log_k 6.5
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 209634
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
2 Ag+ + 2 Ethylenediamine = Ag2(Ethylenediamine)2+2
|
|
log_k 12.7
|
|
delta_h -97.0688 kJ
|
|
-gamma 0 0
|
|
# Id: 209635
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + 2 Ethylenediamine + 2 H+ = Ag(HEthylenediamine)2+3
|
|
log_k 24
|
|
delta_h -150.206 kJ
|
|
-gamma 0 0
|
|
# Id: 209636
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + 2 Ethylenediamine + H+ = AgH(Ethylenediamine)2+2
|
|
log_k 8.4
|
|
delta_h -47.6976 kJ
|
|
-gamma 0 0
|
|
# Id: 209637
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Ethylenediamine = Ni(Ethylenediamine)+2
|
|
log_k 7.32
|
|
delta_h -37.656 kJ
|
|
-gamma 0 0
|
|
# Id: 5409631
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + 2 Ethylenediamine = Ni(Ethylenediamine)2+2
|
|
log_k 13.5
|
|
delta_h -76.5672 kJ
|
|
-gamma 0 0
|
|
# Id: 5409632
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + 3 Ethylenediamine = Ni(Ethylenediamine)3+2
|
|
log_k 17.6
|
|
delta_h -117.152 kJ
|
|
-gamma 0 0
|
|
# Id: 5409633
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Co+2 + Ethylenediamine = Co(Ethylenediamine)+2
|
|
log_k 5.5
|
|
delta_h -28 kJ
|
|
-gamma 0 0
|
|
# Id: 2009631
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Co+2 + 2 Ethylenediamine = Co(Ethylenediamine)2+2
|
|
log_k 10.1
|
|
delta_h -58.5 kJ
|
|
-gamma 0 0
|
|
# Id: 2009632
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Co+2 + 3 Ethylenediamine = Co(Ethylenediamine)3+2
|
|
log_k 13.2
|
|
delta_h -92.8 kJ
|
|
-gamma 0 0
|
|
# Id: 2009633
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Co+3 + 2 Ethylenediamine = Co(Ethylenediamine)2+3
|
|
log_k 34.7
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2019631
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 1.00 25.0
|
|
Co+3 + 3 Ethylenediamine = Co(Ethylenediamine)3+3
|
|
log_k 48.69
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2019632
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 1.50 30.0
|
|
Fe+2 + Ethylenediamine = Fe(Ethylenediamine)+2
|
|
log_k 4.26
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2809631
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+2 + 2 Ethylenediamine = Fe(Ethylenediamine)2+2
|
|
log_k 7.73
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2809632
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+2 + 3 Ethylenediamine = Fe(Ethylenediamine)3+2
|
|
log_k 10.17
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2809633
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mn+2 + Ethylenediamine = Mn(Ethylenediamine)+2
|
|
log_k 2.74
|
|
delta_h -11.7152 kJ
|
|
-gamma 0 0
|
|
# Id: 4709631
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mn+2 + 2 Ethylenediamine = Mn(Ethylenediamine)2+2
|
|
log_k 4.8
|
|
delta_h -25.104 kJ
|
|
-gamma 0 0
|
|
# Id: 4709632
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + 2 Ethylenediamine + 2 H+ = Cr(Ethylenediamine)2+3 + 2 H2O
|
|
log_k 22.57
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119631
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + 3 Ethylenediamine + 2 H+ = Cr(Ethylenediamine)3+3 + 2 H2O
|
|
log_k 29
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119632
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mg+2 + Ethylenediamine = Mg(Ethylenediamine)+2
|
|
log_k 0.37
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4609631
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + Ethylenediamine = Ca(Ethylenediamine)+2
|
|
log_k 0.11
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1509631
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
H+ + Propylamine = H(Propylamine)+
|
|
log_k 10.566
|
|
delta_h -57.53 kJ
|
|
-gamma 0 0
|
|
# Id: 3309641
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Propylamine = Zn(Propylamine)+2
|
|
log_k 2.42
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509641
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Zn+2 + 2 Propylamine = Zn(Propylamine)2+2
|
|
log_k 4.85
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509642
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Zn+2 + 3 Propylamine = Zn(Propylamine)3+2
|
|
log_k 7.38
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509643
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Zn+2 + 4 Propylamine = Zn(Propylamine)4+2
|
|
log_k 9.49
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509644
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + Propylamine = Cd(Propylamine)+2
|
|
log_k 2.62
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609641
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + 2 Propylamine = Cd(Propylamine)2+2
|
|
log_k 4.64
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609642
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + 3 Propylamine = Cd(Propylamine)3+2
|
|
log_k 6.03
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609643
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Ag+ + Propylamine = Ag(Propylamine)+
|
|
log_k 3.45
|
|
delta_h -12.552 kJ
|
|
-gamma 0 0
|
|
# Id: 209641
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + 2 Propylamine = Ag(Propylamine)2+
|
|
log_k 7.44
|
|
delta_h -53.1368 kJ
|
|
-gamma 0 0
|
|
# Id: 209642
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Propylamine = Ni(Propylamine)+2
|
|
log_k 2.81
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409641
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Ni+2 + 2 Propylamine = Ni(Propylamine)2+2
|
|
log_k 5.02
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409642
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Ni+2 + 3 Propylamine = Ni(Propylamine)3+2
|
|
log_k 6.79
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409643
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Ni+2 + 4 Propylamine = Ni(Propylamine)4+2
|
|
log_k 8.31
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409644
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
H+ + Isopropylamine = H(Isopropylamine)+
|
|
log_k 10.67
|
|
delta_h -58.3668 kJ
|
|
-gamma 0 0
|
|
# Id: 3309651
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Isopropylamine = Zn(Isopropylamine)+2
|
|
log_k 2.37
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509651
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Zn+2 + 2 Isopropylamine = Zn(Isopropylamine)2+2
|
|
log_k 4.67
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509652
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Zn+2 + 3 Isopropylamine = Zn(Isopropylamine)3+2
|
|
log_k 7.14
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509653
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Zn+2 + 4 Isopropylamine = Zn(Isopropylamine)4+2
|
|
log_k 9.44
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509654
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + Isopropylamine = Cd(Isopropylamine)+2
|
|
log_k 2.55
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609651
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + 2 Isopropylamine = Cd(Isopropylamine)2+2
|
|
log_k 4.57
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609652
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + 3 Isopropylamine = Cd(Isopropylamine)3+2
|
|
log_k 6.07
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609653
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + 4 Isopropylamine = Cd(Isopropylamine)4+2
|
|
log_k 6.9
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609654
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Hg(OH)2 + Isopropylamine + 2 H+ = Hg(Isopropylamine)+2 + 2 H2O
|
|
log_k 14.85
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619651
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + 2 Isopropylamine + 2 H+ = Hg(Isopropylamine)2+2 + 2 H2O
|
|
log_k 24.37
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619652
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + Isopropylamine = Ag(Isopropylamine)+
|
|
log_k 3.67
|
|
delta_h -23.8488 kJ
|
|
-gamma 0 0
|
|
# Id: 209651
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + 2 Isopropylamine = Ag(Isopropylamine)2+
|
|
log_k 7.77
|
|
delta_h -59.8312 kJ
|
|
-gamma 0 0
|
|
# Id: 209652
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Isopropylamine = Ni(Isopropylamine)+2
|
|
log_k 2.71
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409651
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Ni+2 + 2 Isopropylamine = Ni(Isopropylamine)2+2
|
|
log_k 4.86
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409652
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Ni+2 + 3 Isopropylamine = Ni(Isopropylamine)3+2
|
|
log_k 6.57
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409653
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Ni+2 + 4 Isopropylamine = Ni(Isopropylamine)4+2
|
|
log_k 7.83
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409654
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Ni+2 + 5 Isopropylamine = Ni(Isopropylamine)5+2
|
|
log_k 8.43
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409655
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
H+ + Trimethylamine = H(Trimethylamine)+
|
|
log_k 9.8
|
|
delta_h -36.8192 kJ
|
|
-gamma 0 0
|
|
# Id: 3309661
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + Trimethylamine = Ag(Trimethylamine)+
|
|
log_k 1.701
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 209661
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
H+ + Citrate-3 = H(Citrate)-2
|
|
log_k 6.396
|
|
delta_h 3.3472 kJ
|
|
-gamma 0 0
|
|
# Id: 3309671
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
2 H+ + Citrate-3 = H2(Citrate)-
|
|
log_k 11.157
|
|
delta_h 1.297 kJ
|
|
-gamma 0 0
|
|
# Id: 3309672
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
3 H+ + Citrate-3 = H3(Citrate)
|
|
log_k 14.285
|
|
delta_h -2.7614 kJ
|
|
-gamma 0 0
|
|
# Id: 3309673
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Pb+2 + Citrate-3 = Pb(Citrate)-
|
|
log_k 7.27
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009671
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Pb+2 + 2 Citrate-3 = Pb(Citrate)2-4
|
|
log_k 6.53
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009672
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Al+3 + Citrate-3 = Al(Citrate)
|
|
log_k 9.97
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 309671
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Al+3 + 2 Citrate-3 = Al(Citrate)2-3
|
|
log_k 14.8
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 309672
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Al+3 + Citrate-3 + H+ = AlH(Citrate)+
|
|
log_k 12.85
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 309673
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Tl+ + Citrate-3 = Tl(Citrate)-2
|
|
log_k 1.48
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8709671
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Citrate-3 = Zn(Citrate)-
|
|
log_k 6.21
|
|
delta_h 8.368 kJ
|
|
-gamma 0 0
|
|
# Id: 9509671
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + 2 Citrate-3 = Zn(Citrate)2-4
|
|
log_k 7.4
|
|
delta_h 25.104 kJ
|
|
-gamma 0 0
|
|
# Id: 9509672
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Citrate-3 + H+ = ZnH(Citrate)
|
|
log_k 10.2
|
|
delta_h 3.3472 kJ
|
|
-gamma 0 0
|
|
# Id: 9509673
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Citrate-3 + 2 H+ = ZnH2(Citrate)+
|
|
log_k 12.84
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509674
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + Citrate-3 = Cd(Citrate)-
|
|
log_k 4.98
|
|
delta_h 8.368 kJ
|
|
-gamma 0 0
|
|
# Id: 1609671
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + Citrate-3 + H+ = CdH(Citrate)
|
|
log_k 9.44
|
|
delta_h 3.3472 kJ
|
|
-gamma 0 0
|
|
# Id: 1609672
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + Citrate-3 + 2 H+ = CdH2(Citrate)+
|
|
log_k 12.9
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609673
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + 2 Citrate-3 = Cd(Citrate)2-4
|
|
log_k 5.9
|
|
delta_h 20.92 kJ
|
|
-gamma 0 0
|
|
# Id: 1609674
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + Citrate-3 + 2 H+ = Hg(Citrate)- + 2 H2O
|
|
log_k 18.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619671
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Citrate-3 = Cu(Citrate)-
|
|
log_k 7.57
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319671
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cu+2 + 2 Citrate-3 = Cu(Citrate)2-4
|
|
log_k 8.9
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319672
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cu+2 + Citrate-3 + H+ = CuH(Citrate)
|
|
log_k 10.87
|
|
delta_h 11.7152 kJ
|
|
-gamma 0 0
|
|
# Id: 2319673
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Citrate-3 + 2 H+ = CuH2(Citrate)+
|
|
log_k 13.23
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319674
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
2 Cu+2 + 2 Citrate-3 = Cu2(Citrate)2-2
|
|
log_k 16.9
|
|
delta_h 41.84 kJ
|
|
-gamma 0 0
|
|
# Id: 2319675
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Citrate-3 = Ni(Citrate)-
|
|
log_k 6.59
|
|
delta_h 16.736 kJ
|
|
-gamma 0 0
|
|
# Id: 5409671
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Citrate-3 + H+ = NiH(Citrate)
|
|
log_k 10.5
|
|
delta_h 15.8992 kJ
|
|
-gamma 0 0
|
|
# Id: 5409672
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Citrate-3 + 2 H+ = NiH2(Citrate)+
|
|
log_k 13.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409673
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + 2 Citrate-3 = Ni(Citrate)2-4
|
|
log_k 8.77
|
|
delta_h 12.552 kJ
|
|
-gamma 0 0
|
|
# Id: 5409674
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + 2 Citrate-3 + H+ = NiH(Citrate)2-3
|
|
log_k 14.9
|
|
delta_h 32.6352 kJ
|
|
-gamma 0 0
|
|
# Id: 5409675
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Co+2 + Citrate-3 = Co(Citrate)-
|
|
log_k 6.1867
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009671
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Co+2 + H+ + Citrate-3 = CoHCitrate
|
|
log_k 10.4438
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009672
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Co+2 + 2 H+ + Citrate-3 = CoH2Citrate+
|
|
log_k 12.7859
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009673
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 20.0
|
|
Fe+2 + Citrate-3 = Fe(Citrate)-
|
|
log_k 6.1
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2809671
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+2 + Citrate-3 + H+ = FeH(Citrate)
|
|
log_k 10.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2809672
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+3 + Citrate-3 = Fe(Citrate)
|
|
log_k 13.1
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2819671
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+3 + Citrate-3 + H+ = FeH(Citrate)+
|
|
log_k 14.4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2819672
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mn+2 + Citrate-3 = Mn(Citrate)-
|
|
log_k 4.28
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4709671
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Mn+2 + Citrate-3 + H+ = MnH(Citrate)
|
|
log_k 9.6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4709672
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Be+2 + Citrate-3 = Be(Citrate)-
|
|
log_k 5.534
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1109671
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 1.00 25.0
|
|
Be+2 + H+ + Citrate-3 = BeH(Citrate)
|
|
log_k 9.442
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1109672
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 1.00 25.0
|
|
Ca+2 + Citrate-3 = Ca(Citrate)-
|
|
log_k 4.87
|
|
delta_h -8.368 kJ
|
|
-gamma 0 0
|
|
# Id: 1509671
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + Citrate-3 + H+ = CaH(Citrate)
|
|
log_k 9.26
|
|
delta_h -0.8368 kJ
|
|
-gamma 0 0
|
|
# Id: 1509672
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + Citrate-3 + 2 H+ = CaH2(Citrate)+
|
|
log_k 12.257
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1509673
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Mg+2 + Citrate-3 = Mg(Citrate)-
|
|
log_k 4.89
|
|
delta_h 8.368 kJ
|
|
-gamma 0 0
|
|
# Id: 4609671
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mg+2 + Citrate-3 + H+ = MgH(Citrate)
|
|
log_k 8.91
|
|
delta_h 3.3472 kJ
|
|
-gamma 0 0
|
|
# Id: 4609672
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mg+2 + Citrate-3 + 2 H+ = MgH2(Citrate)+
|
|
log_k 12.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4609673
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Sr+2 + Citrate-3 = Sr(Citrate)-
|
|
log_k 4.3367
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8009671
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Sr+2 + H+ + Citrate-3 = SrH(Citrate)
|
|
log_k 8.9738
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8009672
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Sr+2 + 2 H+ + Citrate-3 = SrH2(Citrate)+
|
|
log_k 12.4859
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8009673
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Ba+2 + Citrate-3 = Ba(Citrate)-
|
|
log_k 4.1
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1009671
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ba+2 + Citrate-3 + H+ = BaH(Citrate)
|
|
log_k 8.74
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1009672
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ba+2 + Citrate-3 + 2 H+ = BaH2(Citrate)+
|
|
log_k 12.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1009673
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Na+ + Citrate-3 = Na(Citrate)-2
|
|
log_k 1.03
|
|
delta_h -2.8033 kJ
|
|
-gamma 0 0
|
|
# Id: 5009671
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
2 Na+ + Citrate-3 = Na2(Citrate)-
|
|
log_k 1.5
|
|
delta_h -5.1045 kJ
|
|
-gamma 0 0
|
|
# Id: 5009672
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Na+ + Citrate-3 + H+ = NaH(Citrate)-
|
|
log_k 6.45
|
|
delta_h -3.5982 kJ
|
|
-gamma 0 0
|
|
# Id: 5009673
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
K+ + Citrate-3 = K(Citrate)-2
|
|
log_k 1.1
|
|
delta_h 5.4392 kJ
|
|
-gamma 0 0
|
|
# Id: 4109671
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
H+ + Nta-3 = H(Nta)-2
|
|
log_k 10.278
|
|
delta_h -18.828 kJ
|
|
-gamma 0 0
|
|
# Id: 3309681
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
2 H+ + Nta-3 = H2(Nta)-
|
|
log_k 13.22
|
|
delta_h -17.9912 kJ
|
|
-gamma 0 0
|
|
# Id: 3309682
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
3 H+ + Nta-3 = H3(Nta)
|
|
log_k 15.22
|
|
delta_h -16.3176 kJ
|
|
-gamma 0 0
|
|
# Id: 3309683
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
4 H+ + Nta-3 = H4(Nta)+
|
|
log_k 16.22
|
|
delta_h -16.3176 kJ
|
|
-gamma 0 0
|
|
# Id: 3309684
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Pb+2 + Nta-3 = Pb(Nta)-
|
|
log_k 12.7
|
|
delta_h -15.8992 kJ
|
|
-gamma 0 0
|
|
# Id: 6009681
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Pb+2 + Nta-3 + H+ = PbH(Nta)
|
|
log_k 15.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009682
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Al+3 + Nta-3 = Al(Nta)
|
|
log_k 13.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 309681
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Al+3 + Nta-3 + H+ = AlH(Nta)+
|
|
log_k 15.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 309682
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Al+3 + Nta-3 + H2O = AlOH(Nta)- + H+
|
|
log_k 8
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 309683
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Tl+ + Nta-3 = Tl(Nta)-2
|
|
log_k 5.39
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8709681
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Nta-3 = Zn(Nta)-
|
|
log_k 11.95
|
|
delta_h -3.7656 kJ
|
|
-gamma 0 0
|
|
# Id: 9509681
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + 2 Nta-3 = Zn(Nta)2-4
|
|
log_k 14.88
|
|
delta_h -15.0624 kJ
|
|
-gamma 0 0
|
|
# Id: 9509682
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Nta-3 + H2O = ZnOH(Nta)-2 + H+
|
|
log_k 1.46
|
|
delta_h 46.4424 kJ
|
|
-gamma 0 0
|
|
# Id: 9509683
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + Nta-3 = Cd(Nta)-
|
|
log_k 11.07
|
|
delta_h -16.736 kJ
|
|
-gamma 0 0
|
|
# Id: 1609681
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + 2 Nta-3 = Cd(Nta)2-4
|
|
log_k 15.03
|
|
delta_h -38.0744 kJ
|
|
-gamma 0 0
|
|
# Id: 1609682
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + Nta-3 + H2O = CdOH(Nta)-2 + H+
|
|
log_k -0.61
|
|
delta_h 29.288 kJ
|
|
-gamma 0 0
|
|
# Id: 1609683
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + Nta-3 + 2 H+ = Hg(Nta)- + 2 H2O
|
|
log_k 21.7
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619681
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Nta-3 = Cu(Nta)-
|
|
log_k 14.4
|
|
delta_h -7.9496 kJ
|
|
-gamma 0 0
|
|
# Id: 2319681
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 2 Nta-3 = Cu(Nta)2-4
|
|
log_k 18.1
|
|
delta_h -37.2376 kJ
|
|
-gamma 0 0
|
|
# Id: 2319682
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Nta-3 + H+ = CuH(Nta)
|
|
log_k 16.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319683
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Nta-3 + H2O = CuOH(Nta)-2 + H+
|
|
log_k 4.8
|
|
delta_h 25.5224 kJ
|
|
-gamma 0 0
|
|
# Id: 2319684
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + Nta-3 = Ag(Nta)-2
|
|
log_k 6
|
|
delta_h -26.3592 kJ
|
|
-gamma 0 0
|
|
# Id: 209681
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Nta-3 = Ni(Nta)-
|
|
log_k 12.79
|
|
delta_h -10.0416 kJ
|
|
-gamma 0 0
|
|
# Id: 5409681
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + 2 Nta-3 = Ni(Nta)2-4
|
|
log_k 16.96
|
|
delta_h -32.6352 kJ
|
|
-gamma 0 0
|
|
# Id: 5409682
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Nta-3 + H2O = NiOH(Nta)-2 + H+
|
|
log_k 1.5
|
|
delta_h 15.0624 kJ
|
|
-gamma 0 0
|
|
# Id: 5409683
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Co+2 + Nta-3 = Co(Nta)-
|
|
log_k 11.6667
|
|
delta_h -0.4 kJ
|
|
-gamma 0 0
|
|
# Id: 2009681
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Co+2 + 2 Nta-3 = Co(Nta)2-4
|
|
log_k 14.9734
|
|
delta_h -20 kJ
|
|
-gamma 0 0
|
|
# Id: 2009682
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Co+2 + Nta-3 + H2O = CoOH(Nta)-2 + H+
|
|
log_k 0.4378
|
|
delta_h 45.6 kJ
|
|
-gamma 0 0
|
|
# Id: 2009683
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Fe+2 + Nta-3 = Fe(Nta)-
|
|
log_k 10.19
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2809681
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+2 + 2 Nta-3 = Fe(Nta)2-4
|
|
log_k 12.62
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2809682
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+2 + Nta-3 + H+ = FeH(Nta)
|
|
log_k 12.29
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2809683
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+2 + Nta-3 + H2O = FeOH(Nta)-2 + H+
|
|
log_k -1.06
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2809684
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+3 + Nta-3 = Fe(Nta)
|
|
log_k 17.8
|
|
delta_h 13.3888 kJ
|
|
-gamma 0 0
|
|
# Id: 2819681
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+3 + 2 Nta-3 = Fe(Nta)2-3
|
|
log_k 25.9
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2819682
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+3 + Nta-3 + H2O = FeOH(Nta)- + H+
|
|
log_k 13.23
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2819683
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mn+2 + Nta-3 = Mn(Nta)-
|
|
log_k 8.573
|
|
delta_h 5.8576 kJ
|
|
-gamma 0 0
|
|
# Id: 4709681
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mn+2 + 2 Nta-3 = Mn(Nta)2-4
|
|
log_k 11.58
|
|
delta_h -17.1544 kJ
|
|
-gamma 0 0
|
|
# Id: 4709682
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + Nta-3 + 2 H+ = Cr(Nta) + 2 H2O
|
|
log_k 21.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119681
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + 2 Nta-3 + 2 H+ = Cr(Nta)2-3 + 2 H2O
|
|
log_k 29.5
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119682
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
MoO4-2 + 2 H+ + Nta-3 = MoO3(Nta)-3 + H2O
|
|
log_k 19.5434
|
|
delta_h -69 kJ
|
|
-gamma 0 0
|
|
# Id: 4809681
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
MoO4-2 + 3 H+ + Nta-3 = MoO3H(Nta)-2 + H2O
|
|
log_k 23.3954
|
|
delta_h -71 kJ
|
|
-gamma 0 0
|
|
# Id: 4809682
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 1.00 25.0
|
|
MoO4-2 + 4 H+ + Nta-3 = MoO3H2(Nta)- + H2O
|
|
log_k 25.3534
|
|
delta_h -71 kJ
|
|
-gamma 0 0
|
|
# Id: 4809683
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 1.00 25.0
|
|
Be+2 + Nta-3 = Be(Nta)-
|
|
log_k 9.0767
|
|
delta_h 25 kJ
|
|
-gamma 0 0
|
|
# Id: 1109681
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Mg+2 + Nta-3 = Mg(Nta)-
|
|
log_k 6.5
|
|
delta_h 17.9912 kJ
|
|
-gamma 0 0
|
|
# Id: 4609681
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + Nta-3 = Ca(Nta)-
|
|
log_k 7.608
|
|
delta_h -5.6902 kJ
|
|
-gamma 0 0
|
|
# Id: 1509681
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + 2 Nta-3 = Ca(Nta)2-4
|
|
log_k 8.81
|
|
delta_h -32.6352 kJ
|
|
-gamma 0 0
|
|
# Id: 1509682
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Sr+2 + Nta-3 = Sr(Nta)-
|
|
log_k 6.2767
|
|
delta_h -2.2 kJ
|
|
-gamma 0 0
|
|
# Id: 8009681
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Ba+2 + Nta-3 = Ba(Nta)-
|
|
log_k 5.875
|
|
delta_h -6.025 kJ
|
|
-gamma 0 0
|
|
# Id: 1009681
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
H+ + Edta-4 = H(Edta)-3
|
|
log_k 10.948
|
|
delta_h -23.4304 kJ
|
|
-gamma 0 0
|
|
# Id: 3309691
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
2 H+ + Edta-4 = H2(Edta)-2
|
|
log_k 17.221
|
|
delta_h -41.0032 kJ
|
|
-gamma 0 0
|
|
# Id: 3309692
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
3 H+ + Edta-4 = H3(Edta)-
|
|
log_k 20.34
|
|
delta_h -35.564 kJ
|
|
-gamma 0 0
|
|
# Id: 3309693
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
4 H+ + Edta-4 = H4(Edta)
|
|
log_k 22.5
|
|
delta_h -34.3088 kJ
|
|
-gamma 0 0
|
|
# Id: 3309694
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
5 H+ + Edta-4 = H5(Edta)+
|
|
log_k 24
|
|
delta_h -32.2168 kJ
|
|
-gamma 0 0
|
|
# Id: 3309695
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Sn(OH)2 + 2 H+ + Edta-4 = Sn(Edta)-2 + 2 H2O
|
|
log_k 27.026
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7909691
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 1.00 20.0
|
|
Sn(OH)2 + 3 H+ + Edta-4 = SnH(Edta)- + 2 H2O
|
|
log_k 29.934
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7909692
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 1.00 20.0
|
|
Sn(OH)2 + 4 H+ + Edta-4 = SnH2(Edta) + 2 H2O
|
|
log_k 31.638
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7909693
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 1.00 20.0
|
|
Pb+2 + Edta-4 = Pb(Edta)-2
|
|
log_k 19.8
|
|
delta_h -54.8104 kJ
|
|
-gamma 0 0
|
|
# Id: 6009691
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Pb+2 + Edta-4 + H+ = PbH(Edta)-
|
|
log_k 23
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009692
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Pb+2 + Edta-4 + 2 H+ = PbH2(Edta)
|
|
log_k 24.9
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009693
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Al+3 + Edta-4 = Al(Edta)-
|
|
log_k 19.1
|
|
delta_h 52.7184 kJ
|
|
-gamma 0 0
|
|
# Id: 309690
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Al+3 + Edta-4 + H+ = AlH(Edta)
|
|
log_k 21.8
|
|
delta_h 36.4008 kJ
|
|
-gamma 0 0
|
|
# Id: 309691
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Al+3 + Edta-4 + H2O = AlOH(Edta)-2 + H+
|
|
log_k 12.8
|
|
delta_h 73.6384 kJ
|
|
-gamma 0 0
|
|
# Id: 309692
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Tl+ + Edta-4 = Tl(Edta)-3
|
|
log_k 7.27
|
|
delta_h -43.5136 kJ
|
|
-gamma 0 0
|
|
# Id: 8709691
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Tl+ + Edta-4 + H+ = TlH(Edta)-2
|
|
log_k 13.68
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8709692
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Edta-4 = Zn(Edta)-2
|
|
log_k 18
|
|
delta_h -19.2464 kJ
|
|
-gamma 0 0
|
|
# Id: 9509691
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Edta-4 + H+ = ZnH(Edta)-
|
|
log_k 21.4
|
|
delta_h -28.4512 kJ
|
|
-gamma 0 0
|
|
# Id: 9509692
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Edta-4 + H2O = ZnOH(Edta)-3 + H+
|
|
log_k 5.8
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509693
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + Edta-4 = Cd(Edta)-2
|
|
log_k 18.2
|
|
delta_h -38.0744 kJ
|
|
-gamma 0 0
|
|
# Id: 1609691
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + Edta-4 + H+ = CdH(Edta)-
|
|
log_k 21.5
|
|
delta_h -39.748 kJ
|
|
-gamma 0 0
|
|
# Id: 1609692
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + Edta-4 + 2 H+ = Hg(Edta)-2 + 2 H2O
|
|
log_k 29.3
|
|
delta_h -125.102 kJ
|
|
-gamma 0 0
|
|
# Id: 3619691
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + Edta-4 + 3 H+ = HgH(Edta)- + 2 H2O
|
|
log_k 32.9
|
|
delta_h -128.449 kJ
|
|
-gamma 0 0
|
|
# Id: 3619692
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Edta-4 = Cu(Edta)-2
|
|
log_k 20.5
|
|
delta_h -34.7272 kJ
|
|
-gamma 0 0
|
|
# Id: 2319691
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Edta-4 + H+ = CuH(Edta)-
|
|
log_k 24
|
|
delta_h -43.0952 kJ
|
|
-gamma 0 0
|
|
# Id: 2319692
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Edta-4 + 2 H+ = CuH2(Edta)
|
|
log_k 26.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319693
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Edta-4 + H2O = CuOH(Edta)-3 + H+
|
|
log_k 8.5
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319694
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + Edta-4 = Ag(Edta)-3
|
|
log_k 8.08
|
|
delta_h -31.38 kJ
|
|
-gamma 0 0
|
|
# Id: 209691
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + Edta-4 + H+ = AgH(Edta)-2
|
|
log_k 15.21
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 209693
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Ni+2 + Edta-4 = Ni(Edta)-2
|
|
log_k 20.1
|
|
delta_h -30.9616 kJ
|
|
-gamma 0 0
|
|
# Id: 5409691
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Edta-4 + H+ = NiH(Edta)-
|
|
log_k 23.6
|
|
delta_h -38.4928 kJ
|
|
-gamma 0 0
|
|
# Id: 5409692
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Edta-4 + H2O = NiOH(Edta)-3 + H+
|
|
log_k 7.6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409693
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Co+2 + Edta-4 = Co(Edta)-2
|
|
log_k 18.1657
|
|
delta_h -15 kJ
|
|
-gamma 0 0
|
|
# Id: 2009691
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Co+2 + Edta-4 + H+ = CoH(Edta)-
|
|
log_k 21.5946
|
|
delta_h -22.9 kJ
|
|
-gamma 0 0
|
|
# Id: 2009692
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Co+2 + Edta-4 + 2 H+ = CoH2(Edta)
|
|
log_k 23.4986
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009693
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 1.00 25.0
|
|
Co+3 + Edta-4 = Co(Edta)-
|
|
log_k 43.9735
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2019691
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Co+3 + Edta-4 + H+ = CoH(Edta)
|
|
log_k 47.168
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2019692
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 20.0
|
|
Fe+2 + Edta-4 = Fe(Edta)-2
|
|
log_k 16
|
|
delta_h -16.736 kJ
|
|
-gamma 0 0
|
|
# Id: 2809690
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+2 + Edta-4 + H+ = FeH(Edta)-
|
|
log_k 19.06
|
|
delta_h -27.6144 kJ
|
|
-gamma 0 0
|
|
# Id: 2809691
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+2 + Edta-4 + H2O = FeOH(Edta)-3 + H+
|
|
log_k 6.5
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2809692
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Fe+2 + Edta-4 + 2 H2O = Fe(OH)2(Edta)-4 + 2 H+
|
|
log_k -4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2809693
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Fe+3 + Edta-4 = Fe(Edta)-
|
|
log_k 27.7
|
|
delta_h -11.2968 kJ
|
|
-gamma 0 0
|
|
# Id: 2819690
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+3 + Edta-4 + H+ = FeH(Edta)
|
|
log_k 29.2
|
|
delta_h -11.7152 kJ
|
|
-gamma 0 0
|
|
# Id: 2819691
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+3 + Edta-4 + H2O = FeOH(Edta)-2 + H+
|
|
log_k 19.9
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2819692
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+3 + Edta-4 + 2 H2O = Fe(OH)2(Edta)-3 + 2 H+
|
|
log_k 9.85
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2819693
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Mn+2 + Edta-4 = Mn(Edta)-2
|
|
log_k 15.6
|
|
delta_h -19.2464 kJ
|
|
-gamma 0 0
|
|
# Id: 4709691
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mn+2 + Edta-4 + H+ = MnH(Edta)-
|
|
log_k 19.1
|
|
delta_h -24.2672 kJ
|
|
-gamma 0 0
|
|
# Id: 4709692
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cr+2 + Edta-4 = Cr(Edta)-2
|
|
log_k 15.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2109691
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cr+2 + Edta-4 + H+ = CrH(Edta)-
|
|
log_k 19.1
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2109692
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + Edta-4 + 2 H+ = Cr(Edta)- + 2 H2O
|
|
log_k 35.5
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119691
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + Edta-4 + 3 H+ = CrH(Edta) + 2 H2O
|
|
log_k 37.4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119692
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + Edta-4 + H+ = CrOH(Edta)-2 + H2O
|
|
log_k 27.7
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119693
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Be+2 + Edta-4 = Be(Edta)-2
|
|
log_k 11.4157
|
|
delta_h 41 kJ
|
|
-gamma 0 0
|
|
# Id: 1109691
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Mg+2 + Edta-4 = Mg(Edta)-2
|
|
log_k 10.57
|
|
delta_h 13.8072 kJ
|
|
-gamma 0 0
|
|
# Id: 4609690
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mg+2 + Edta-4 + H+ = MgH(Edta)-
|
|
log_k 14.97
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4609691
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + Edta-4 = Ca(Edta)-2
|
|
log_k 12.42
|
|
delta_h -25.5224 kJ
|
|
-gamma 0 0
|
|
# Id: 1509690
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + Edta-4 + H+ = CaH(Edta)-
|
|
log_k 15.9
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1509691
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Sr+2 + Edta-4 = Sr(Edta)-2
|
|
log_k 10.4357
|
|
delta_h -17 kJ
|
|
-gamma 0 0
|
|
# Id: 8009691
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Sr+2 + Edta-4 + H+ = SrH(Edta)-
|
|
log_k 14.7946
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8009692
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 20.0
|
|
Ba+2 + Edta-4 = Ba(Edta)-2
|
|
log_k 7.72
|
|
delta_h -20.5016 kJ
|
|
-gamma 0 0
|
|
# Id: 1009691
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Na+ + Edta-4 = Na(Edta)-3
|
|
log_k 2.7
|
|
delta_h -5.8576 kJ
|
|
-gamma 0 0
|
|
# Id: 5009690
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
K+ + Edta-4 = K(Edta)-3
|
|
log_k 1.7
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4109690
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
H+ + Propionate- = H(Propionate)
|
|
log_k 4.874
|
|
delta_h 0.66 kJ
|
|
-gamma 0 0
|
|
# Id: 3309711
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Pb+2 + Propionate- = Pb(Propionate)+
|
|
log_k 2.64
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009711
|
|
# log K source: NIST46.4
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength: 0.00 35.0
|
|
Pb+2 + 2 Propionate- = Pb(Propionate)2
|
|
log_k 3.1765
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009712
|
|
# log K source: NIST46.4
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength: 2.00 25.0
|
|
Zn+2 + Propionate- = Zn(Propionate)+
|
|
log_k 1.4389
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509711
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Zn+2 + 2 Propionate- = Zn(Propionate)2
|
|
log_k 1.842
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509712
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 1.00 25.0
|
|
Cd+2 + Propionate- = Cd(Propionate)+
|
|
log_k 1.598
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609711
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 1.00 25.0
|
|
Cd+2 + 2 Propionate- = Cd(Propionate)2
|
|
log_k 2.472
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609712
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 1.00 25.0
|
|
Hg(OH)2 + 2 H+ + Propionate- = Hg(Propionate)+ + 2 H2O
|
|
log_k 10.594
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619711
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+2 + Propionate- = Cu(Propionate)+
|
|
log_k 2.22
|
|
delta_h 4.1 kJ
|
|
-gamma 0 0
|
|
# Id: 2319711
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+2 + 2 Propionate- = Cu(Propionate)2
|
|
log_k 3.5
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319712
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.00 25.0
|
|
Ni+2 + Propionate- = Ni(Propionate)+
|
|
log_k 0.908
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409711
|
|
# log K source: NIST46.4
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength: 1.00 25.0
|
|
Co+2 + Propionate- = Co(Propionate)+
|
|
log_k 0.671
|
|
delta_h 4.6 kJ
|
|
-gamma 0 0
|
|
# Id: 2009711
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 2.00 25.0
|
|
Co+2 + 2 Propionate- = Co(Propionate)2
|
|
log_k 0.5565
|
|
delta_h 16 kJ
|
|
-gamma 0 0
|
|
# Id: 2009712
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 2.00 25.0
|
|
Fe+3 + Propionate- = Fe(Propionate)+2
|
|
log_k 4.012
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2819711
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 1.00 20.0
|
|
Cr(OH)2+ + 2 H+ + Propionate- = Cr(Propionate)+2 + 2 H2O
|
|
log_k 15.0773
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119711
|
|
# log K source: NIST46.4
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength: 0.50 25.0
|
|
Cr(OH)2+ + 2 H+ + 2 Propionate- = Cr(Propionate)2+ + 2 H2O
|
|
log_k 17.9563
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119712
|
|
# log K source: NIST46.4
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength: 0.50 25.0
|
|
Cr(OH)2+ + 2 H+ + 3 Propionate- = Cr(Propionate)3 + 2 H2O
|
|
log_k 20.8858
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119713
|
|
# log K source: NIST46.4
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength: 0.50 25.0
|
|
Mg+2 + Propionate- = Mg(Propionate)+
|
|
log_k 0.9689
|
|
delta_h 4.2677 kJ
|
|
-gamma 0 0
|
|
# Id: 4609710
|
|
# log K source: NIST46.4
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength: 0.10 25.0
|
|
Ca+2 + Propionate- = Ca(Propionate)+
|
|
log_k 0.9289
|
|
delta_h 3.3472 kJ
|
|
-gamma 0 0
|
|
# Id: 1509710
|
|
# log K source: NIST46.4
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength: 0.10 25.0
|
|
Sr+2 + Propionate- = Sr(Propionate)+
|
|
log_k 0.8589
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8009711
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Ba+2 + Propionate- = Ba(Propionate)+
|
|
log_k 0.7689
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1009711
|
|
# log K source: NIST46.4
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength: 0.10 25.0
|
|
Ba+2 + 2 Propionate- = Ba(Propionate)2
|
|
log_k 0.9834
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1009712
|
|
# log K source: NIST46.4
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength: 0.10 25.0
|
|
H+ + Butyrate- = H(Butyrate)
|
|
log_k 4.819
|
|
delta_h 2.8 kJ
|
|
-gamma 0 0
|
|
# Id: 3309721
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Pb+2 + Butyrate- = Pb(Butyrate)+
|
|
log_k 2.101
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009721
|
|
# log K source: NIST46.4
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength: 2.00 25.0
|
|
Zn+2 + Butyrate- = Zn(Butyrate)+
|
|
log_k 1.4289
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509721
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Hg(OH)2 + 2 H+ + Butyrate- = Hg(Butyrate)+ + 2 H2O
|
|
log_k 10.3529
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619721
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Cu+2 + Butyrate- = Cu(Butyrate)+
|
|
log_k 2.14
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319721
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.00 25.0
|
|
Ni+2 + Butyrate- = Ni(Butyrate)+
|
|
log_k 0.691
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409721
|
|
# log K source: NIST46.4
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength: 2.00 25.0
|
|
Co+2 + Butyrate- = Co(Butyrate)+
|
|
log_k 0.591
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009721
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 2.00 25.0
|
|
Co+2 + 2 Butyrate- = Co(Butyrate)2
|
|
log_k 0.7765
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009722
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 2.00 25.0
|
|
Mg+2 + Butyrate- = Mg(Butyrate)+
|
|
log_k 0.9589
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4609720
|
|
# log K source: NIST46.4
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength: 0.10 25.0
|
|
Ca+2 + Butyrate- = Ca(Butyrate)+
|
|
log_k 0.9389
|
|
delta_h 3.3472 kJ
|
|
-gamma 0 0
|
|
# Id: 1509720
|
|
# log K source: NIST46.4
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength: 0.10 25.0
|
|
Sr+2 + Butyrate- = Sr(Butyrate)+
|
|
log_k 0.7889
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8009721
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Ba+2 + Butyrate- = Ba(Butyrate)+
|
|
log_k 0.7389
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1009721
|
|
# log K source: NIST46.4
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength: 0.10 25.0
|
|
Ba+2 + 2 Butyrate- = Ba(Butyrate)2
|
|
log_k 0.88
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1009722
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
H+ + Isobutyrate- = H(Isobutyrate)
|
|
log_k 4.849
|
|
delta_h 3.2217 kJ
|
|
-gamma 0 0
|
|
# Id: 3309731
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Isobutyrate- = Zn(Isobutyrate)+
|
|
log_k 1.44
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509731
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Isobutyrate- = Cu(Isobutyrate)+
|
|
log_k 2.17
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319731
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 2 Isobutyrate- = Cu(Isobutyrate)2
|
|
log_k 3.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319732
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+3 + Isobutyrate- = Fe(Isobutyrate)+2
|
|
log_k 4.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2819731
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + Isobutyrate- = Ca(Isobutyrate)+
|
|
log_k 0.51
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1509731
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
H+ + Two_picoline = H(Two_picoline)+
|
|
log_k 5.95
|
|
delta_h -25.5224 kJ
|
|
-gamma 0 0
|
|
# Id: 3309801
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Two_picoline = Cu(Two_picoline)+2
|
|
log_k 1.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319801
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 2 Two_picoline = Cu(Two_picoline)2+2
|
|
log_k 2.8
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319802
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+ + Two_picoline = Cu(Two_picoline)+
|
|
log_k 5.4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2309801
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+ + 2 Two_picoline = Cu(Two_picoline)2+
|
|
log_k 7.65
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2309802
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+ + 3 Two_picoline = Cu(Two_picoline)3+
|
|
log_k 8.5
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2309803
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + Two_picoline = Ag(Two_picoline)+
|
|
log_k 2.32
|
|
delta_h -24.2672 kJ
|
|
-gamma 0 0
|
|
# Id: 209801
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + 2 Two_picoline = Ag(Two_picoline)2+
|
|
log_k 4.68
|
|
delta_h -42.6768 kJ
|
|
-gamma 0 0
|
|
# Id: 209802
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Two_picoline = Ni(Two_picoline)+2
|
|
log_k 0.4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409801
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
H+ + Three_picoline = H(Three_picoline)+
|
|
log_k 5.7
|
|
delta_h -23.8488 kJ
|
|
-gamma 0 0
|
|
# Id: 3309811
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Three_picoline = Zn(Three_picoline)+2
|
|
log_k 1
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509811
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + 2 Three_picoline = Zn(Three_picoline)2+2
|
|
log_k 2.1
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509812
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + 3 Three_picoline = Zn(Three_picoline)3+2
|
|
log_k 2.6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509813
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + 4 Three_picoline = Zn(Three_picoline)4+2
|
|
log_k 3.7
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509814
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + Three_picoline = Cd(Three_picoline)+2
|
|
log_k 1.42
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609811
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + 2 Three_picoline = Cd(Three_picoline)2+2
|
|
log_k 2.27
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609812
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + 3 Three_picoline = Cd(Three_picoline)3+2
|
|
log_k 3.6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609813
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + 4 Three_picoline = Cd(Three_picoline)4+2
|
|
log_k 4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609814
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+ + Three_picoline = Cu(Three_picoline)+
|
|
log_k 5.6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2309811
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+ + 2 Three_picoline = Cu(Three_picoline)2+
|
|
log_k 7.78
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2309812
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+ + 3 Three_picoline = Cu(Three_picoline)3+
|
|
log_k 8.6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2309813
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+ + 4 Three_picoline = Cu(Three_picoline)4+
|
|
log_k 9
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2309814
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Three_picoline = Cu(Three_picoline)+2
|
|
log_k 2.77
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319811
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 2 Three_picoline = Cu(Three_picoline)2+2
|
|
log_k 4.8
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319812
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 3 Three_picoline = Cu(Three_picoline)3+2
|
|
log_k 6.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319813
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 4 Three_picoline = Cu(Three_picoline)4+2
|
|
log_k 7.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319814
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + Three_picoline = Ag(Three_picoline)+
|
|
log_k 2.2
|
|
delta_h -21.7568 kJ
|
|
-gamma 0 0
|
|
# Id: 209811
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + 2 Three_picoline = Ag(Three_picoline)2+
|
|
log_k 4.46
|
|
delta_h -49.7896 kJ
|
|
-gamma 0 0
|
|
# Id: 209812
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Three_picoline = Ni(Three_picoline)+2
|
|
log_k 1.87
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409811
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + 2 Three_picoline = Ni(Three_picoline)2+2
|
|
log_k 3.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409812
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + 3 Three_picoline = Ni(Three_picoline)3+2
|
|
log_k 4.1
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409813
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + 4 Three_picoline = Ni(Three_picoline)4+2
|
|
log_k 4.6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409814
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Co+2 + Three_picoline = Co(Three_picoline)+2
|
|
log_k 1.4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009811
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.50 25.0
|
|
Co+2 + 2 Three_picoline = Co(Three_picoline)2+2
|
|
log_k 2.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009812
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.50 25.0
|
|
Co+2 + 3 Three_picoline = Co(Three_picoline)3+2
|
|
log_k 2.5
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009813
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.50 25.0
|
|
H+ + Four_picoline = H(Four_picoline)+
|
|
log_k 6.03
|
|
delta_h -25.3132 kJ
|
|
-gamma 0 0
|
|
# Id: 3309821
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Four_picoline = Zn(Four_picoline)+2
|
|
log_k 1.4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509821
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + 2 Four_picoline = Zn(Four_picoline)2+2
|
|
log_k 2.11
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509822
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + 3 Four_picoline = Zn(Four_picoline)3+2
|
|
log_k 2.85
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509823
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + Four_picoline = Cd(Four_picoline)+2
|
|
log_k 1.59
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609821
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + 2 Four_picoline = Cd(Four_picoline)2+2
|
|
log_k 2.4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609822
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + 3 Four_picoline = Cd(Four_picoline)3+2
|
|
log_k 3.18
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609823
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + 4 Four_picoline = Cd(Four_picoline)4+2
|
|
log_k 4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609824
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+ + Four_picoline = Cu(Four_picoline)+
|
|
log_k 5.65
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2309821
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+ + 2 Four_picoline = Cu(Four_picoline)2+
|
|
log_k 8.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2309822
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+ + 3 Four_picoline = Cu(Four_picoline)3+
|
|
log_k 8.8
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2309823
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+ + 4 Four_picoline = Cu(Four_picoline)4+
|
|
log_k 9.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2309824
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Four_picoline = Cu(Four_picoline)+2
|
|
log_k 2.88
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319821
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 2 Four_picoline = Cu(Four_picoline)2+2
|
|
log_k 5.16
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319822
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 3 Four_picoline = Cu(Four_picoline)3+2
|
|
log_k 6.77
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319823
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 4 Four_picoline = Cu(Four_picoline)4+2
|
|
log_k 8.08
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319824
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 5 Four_picoline = Cu(Four_picoline)5+2
|
|
log_k 8.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319825
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + Four_picoline = Ag(Four_picoline)+
|
|
log_k 2.03
|
|
delta_h -25.5224 kJ
|
|
-gamma 0 0
|
|
# Id: 209821
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + 2 Four_picoline = Ag(Four_picoline)2+
|
|
log_k 4.39
|
|
delta_h -53.5552 kJ
|
|
-gamma 0 0
|
|
# Id: 209822
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Four_picoline = Ni(Four_picoline)+2
|
|
log_k 2.11
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409821
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + 2 Four_picoline = Ni(Four_picoline)2+2
|
|
log_k 3.59
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409822
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + 3 Four_picoline = Ni(Four_picoline)3+2
|
|
log_k 4.34
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409823
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + 4 Four_picoline = Ni(Four_picoline)4+2
|
|
log_k 4.7
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409824
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Co+2 + Four_picoline = Co(Four_picoline)+2
|
|
log_k 1.56
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009821
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.50 25.0
|
|
Co+2 + 2 Four_picoline = Co(Four_picoline)2+2
|
|
log_k 2.51
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009822
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.50 25.0
|
|
Co+2 + 3 Four_picoline = Co(Four_picoline)3+2
|
|
log_k 2.94
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009823
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.50 25.0
|
|
Co+2 + 4 Four_picoline = Co(Four_picoline)4+2
|
|
log_k 3.17
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009824
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.50 25.0
|
|
H+ + Formate- = H(Formate)
|
|
log_k 3.745
|
|
delta_h 0.1674 kJ
|
|
-gamma 0 0
|
|
# Id: 3309831
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Pb+2 + Formate- = Pb(Formate)+
|
|
log_k 2.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009831
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Zn+2 + Formate- = Zn(Formate)+
|
|
log_k 1.44
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509831
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + Formate- = Cd(Formate)+
|
|
log_k 1.7
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609831
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Hg(OH)2 + Formate- + 2 H+ = Hg(Formate)+ + 2 H2O
|
|
log_k 9.6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619831
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Formate- = Cu(Formate)+
|
|
log_k 2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319831
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Formate- = Ni(Formate)+
|
|
log_k 1.22
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409831
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Co+2 + Formate- = Co(Formate)+
|
|
log_k 1.209
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009831
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.50 30.0
|
|
Co+2 + 2 Formate- = Co(Formate)2
|
|
log_k 1.1365
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009832
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 2.00 25.0
|
|
Cr+2 + Formate- = Cr(Formate)+
|
|
log_k 1.07
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2109831
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mg+2 + Formate- = Mg(Formate)+
|
|
log_k 1.43
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4609831
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + Formate- = Ca(Formate)+
|
|
log_k 1.43
|
|
delta_h 4.184 kJ
|
|
-gamma 0 0
|
|
# Id: 1509831
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Sr+2 + Formate- = Sr(Formate)+
|
|
log_k 1.39
|
|
delta_h 4 kJ
|
|
-gamma 0 0
|
|
# Id: 8009831
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ba+2 + Formate- = Ba(Formate)+
|
|
log_k 1.38
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1009831
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
H+ + Isovalerate- = H(Isovalerate)
|
|
log_k 4.781
|
|
delta_h 4.5606 kJ
|
|
-gamma 0 0
|
|
# Id: 3309841
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Isovalerate- = Zn(Isovalerate)+
|
|
log_k 1.39
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509841
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Isovalerate- = Cu(Isovalerate)+
|
|
log_k 2.08
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319841
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + Isovalerate- = Ca(Isovalerate)+
|
|
log_k 0.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1509841
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
H+ + Valerate- = H(Valerate)
|
|
log_k 4.843
|
|
delta_h 2.887 kJ
|
|
-gamma 0 0
|
|
# Id: 3309851
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Valerate- = Cu(Valerate)+
|
|
log_k 2.12
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319851
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + Valerate- = Ca(Valerate)+
|
|
log_k 0.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1509851
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Ba+2 + Valerate- = Ba(Valerate)+
|
|
log_k -0.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1009851
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
H+ + Acetate- = H(Acetate)
|
|
log_k 4.757
|
|
delta_h 0.41 kJ
|
|
-gamma 0 0
|
|
# Id: 3309921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Sn(OH)2 + 2 H+ + Acetate- = Sn(Acetate)+ + 2 H2O
|
|
log_k 10.0213
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7909921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 3.00 25.0
|
|
Sn(OH)2 + 2 H+ + 2 Acetate- = Sn(Acetate)2 + 2 H2O
|
|
log_k 12.32
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7909922
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 3.00 25.0
|
|
Sn(OH)2 + 2 H+ + 3 Acetate- = Sn(Acetate)3- + 2 H2O
|
|
log_k 13.55
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7909923
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 3.00 25.0
|
|
Pb+2 + Acetate- = Pb(Acetate)+
|
|
log_k 2.68
|
|
delta_h -0.4 kJ
|
|
-gamma 0 0
|
|
# Id: 6009921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Pb+2 + 2 Acetate- = Pb(Acetate)2
|
|
log_k 4.08
|
|
delta_h -0.8 kJ
|
|
-gamma 0 0
|
|
# Id: 6009922
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Tl+ + Acetate- = Tl(Acetate)
|
|
log_k -0.11
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8709921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + Acetate- = Zn(Acetate)+
|
|
log_k 1.58
|
|
delta_h 8.3 kJ
|
|
-gamma 0 0
|
|
# Id: 9509921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Zn+2 + 2 Acetate- = Zn(Acetate)2
|
|
log_k 2.6434
|
|
delta_h 22 kJ
|
|
-gamma 0 0
|
|
# Id: 9509922
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Cd+2 + Acetate- = Cd(Acetate)+
|
|
log_k 1.93
|
|
delta_h 9.6 kJ
|
|
-gamma 0 0
|
|
# Id: 1609921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Cd+2 + 2 Acetate- = Cd(Acetate)2
|
|
log_k 2.86
|
|
delta_h 15 kJ
|
|
-gamma 0 0
|
|
# Id: 1609922
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Hg(OH)2 + 2 H+ + Acetate- = Hg(Acetate)+ + 2 H2O
|
|
log_k 10.494
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619920
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.00 25.0
|
|
Hg(OH)2 + 2 H+ + 2 Acetate- = Hg(Acetate)2 + 2 H2O
|
|
log_k 13.83
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619921
|
|
# log K source: NIST46.4
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength: 3.00 25.0
|
|
Cu+2 + Acetate- = Cu(Acetate)+
|
|
log_k 2.21
|
|
delta_h 7.1 kJ
|
|
-gamma 0 0
|
|
# Id: 2319921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+2 + 2 Acetate- = Cu(Acetate)2
|
|
log_k 3.4
|
|
delta_h 12 kJ
|
|
-gamma 0 0
|
|
# Id: 2319922
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Cu+2 + 3 Acetate- = Cu(Acetate)3-
|
|
log_k 3.9434
|
|
delta_h 6.2 kJ
|
|
-gamma 0 0
|
|
# Id: 2319923
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Ag+ + Acetate- = Ag(Acetate)
|
|
log_k 0.73
|
|
delta_h 3 kJ
|
|
-gamma 0 0
|
|
# Id: 209921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ag+ + 2 Acetate- = Ag(Acetate)2-
|
|
log_k 0.64
|
|
delta_h 3 kJ
|
|
-gamma 0 0
|
|
# Id: 209922
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ni+2 + Acetate- = Ni(Acetate)+
|
|
log_k 1.37
|
|
delta_h 8.7 kJ
|
|
-gamma 0 0
|
|
# Id: 5409921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Ni+2 + 2 Acetate- = Ni(Acetate)2
|
|
log_k 2.1
|
|
delta_h 10 kJ
|
|
-gamma 0 0
|
|
# Id: 5409922
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + Acetate- = Co(Acetate)+
|
|
log_k 1.38
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + 2 Acetate- = Co(Acetate)2
|
|
log_k 0.7565
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009922
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 2.00 25.0
|
|
Fe+2 + Acetate- = Fe(Acetate)+
|
|
log_k 1.4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2809920
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.00 25.0
|
|
Fe+3 + Acetate- = Fe(Acetate)+2
|
|
log_k 4.0234
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2819920
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 20.0
|
|
Fe+3 + 2 Acetate- = Fe(Acetate)2+
|
|
log_k 7.5723
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2819921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 20.0
|
|
Fe+3 + 3 Acetate- = Fe(Acetate)3
|
|
log_k 9.5867
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2819922
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 20.0
|
|
Mn+2 + Acetate- = Mn(Acetate)+
|
|
log_k 1.4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4709920
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.00 25.0
|
|
Cr+2 + Acetate- = Cr(Acetate)+
|
|
log_k 1.8
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2109921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.00 25.0
|
|
Cr+2 + 2 Acetate- = Cr(Acetate)2
|
|
log_k 2.92
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2109922
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.00 25.0
|
|
Cr(OH)2+ + 2 H+ + Acetate- = Cr(Acetate)+2 + 2 H2O
|
|
log_k 15.0073
|
|
delta_h -125.62 kJ
|
|
-gamma 0 0
|
|
# Id: 2119921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.50 25.0
|
|
Cr(OH)2+ + 2 H+ + 2 Acetate- = Cr(Acetate)2+ + 2 H2O
|
|
log_k 17.9963
|
|
delta_h -117.62 kJ
|
|
-gamma 0 0
|
|
# Id: 2119922
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.50 25.0
|
|
Cr(OH)2+ + 2 H+ + 3 Acetate- = Cr(Acetate)3 + 2 H2O
|
|
log_k 20.7858
|
|
delta_h -96.62 kJ
|
|
-gamma 0 0
|
|
# Id: 2119923
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.50 25.0
|
|
Be+2 + Acetate- = Be(Acetate)+
|
|
log_k 2.0489
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1109921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Be+2 + 2 Acetate- = Be(Acetate)2
|
|
log_k 3.0034
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1109922
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Mg+2 + Acetate- = Mg(Acetate)+
|
|
log_k 1.27
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4609920
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.00 25.0
|
|
Ca+2 + Acetate- = Ca(Acetate)+
|
|
log_k 1.18
|
|
delta_h 4 kJ
|
|
-gamma 0 0
|
|
# Id: 1509920
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Sr+2 + Acetate- = Sr(Acetate)+
|
|
log_k 1.14
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8009921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.00 25.0
|
|
Ba+2 + Acetate- = Ba(Acetate)+
|
|
log_k 1.07
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1009921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.00 25.0
|
|
Na+ + Acetate- = Na(Acetate)
|
|
log_k -0.18
|
|
delta_h 12 kJ
|
|
-gamma 0 0
|
|
# Id: 5009920
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
K+ + Acetate- = K(Acetate)
|
|
log_k -0.1955
|
|
delta_h 4.184 kJ
|
|
-gamma 0 0
|
|
# Id: 4109921
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
H+ + Tartarate-2 = H(Tartarate)-
|
|
log_k 4.366
|
|
delta_h -0.7531 kJ
|
|
-gamma 0 0
|
|
# Id: 3309931
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
2 H+ + Tartarate-2 = H2(Tartarate)
|
|
log_k 7.402
|
|
delta_h -3.6819 kJ
|
|
-gamma 0 0
|
|
# Id: 3309932
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Sn(OH)2 + 2 H+ + Tartarate-2 = Sn(Tartarate) + 2 H2O
|
|
log_k 13.1518
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 7909931
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 20.0
|
|
Pb+2 + Tartarate-2 = Pb(Tartarate)
|
|
log_k 3.98
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009931
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Al+3 + 2 Tartarate-2 = Al(Tartarate)2-
|
|
log_k 9.37
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 309931
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Tl+ + Tartarate-2 = Tl(Tartarate)-
|
|
log_k 1.4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8709931
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Tl+ + Tartarate-2 + H+ = TlH(Tartarate)
|
|
log_k 4.8
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8709932
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Tartarate-2 = Zn(Tartarate)
|
|
log_k 3.43
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509931
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + 2 Tartarate-2 = Zn(Tartarate)2-2
|
|
log_k 5.5
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509932
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Tartarate-2 + H+ = ZnH(Tartarate)+
|
|
log_k 5.9
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509933
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + Tartarate-2 = Cd(Tartarate)
|
|
log_k 2.7
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609931
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + 2 Tartarate-2 = Cd(Tartarate)2-2
|
|
log_k 4.1
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609932
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + Tartarate-2 + 2 H+ = Hg(Tartarate) + 2 H2O
|
|
log_k 14
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619931
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Tartarate-2 = Cu(Tartarate)
|
|
log_k 3.97
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319931
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Tartarate-2 + H+ = CuH(Tartarate)+
|
|
log_k 6.7
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319932
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Tartarate-2 = Ni(Tartarate)
|
|
log_k 3.46
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409931
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Tartarate-2 + H+ = NiH(Tartarate)+
|
|
log_k 5.89
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409932
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Co+2 + Tartarate-2 = Co(Tartarate)
|
|
log_k 3.05
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009931
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + 2 Tartarate-2 = Co(Tartarate)2-2
|
|
log_k 4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009932
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + H+ + Tartarate-2 = CoH(Tartarate)+
|
|
log_k 5.754
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009933
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 1.00 20.0
|
|
Fe+2 + Tartarate-2 = Fe(Tartarate)
|
|
log_k 3.1
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2809931
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+3 + Tartarate-2 = Fe(Tartarate)+
|
|
log_k 7.78
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2819931
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mn+2 + Tartarate-2 = Mn(Tartarate)
|
|
log_k 3.38
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4709931
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mn+2 + Tartarate-2 + H+ = MnH(Tartarate)+
|
|
log_k 6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4709932
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mg+2 + Tartarate-2 = Mg(Tartarate)
|
|
log_k 2.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4609931
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mg+2 + Tartarate-2 + H+ = MgH(Tartarate)+
|
|
log_k 5.75
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4609932
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Be+2 + Tartarate-2 = Be(Tartarate)
|
|
log_k 2.768
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1109931
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.50 25.0
|
|
Be+2 + 2 Tartarate-2 = Be(Tartarate)2-2
|
|
log_k 4.008
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1109932
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.50 25.0
|
|
Ca+2 + Tartarate-2 = Ca(Tartarate)
|
|
log_k 2.8
|
|
delta_h -8.368 kJ
|
|
-gamma 0 0
|
|
# Id: 1509931
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + Tartarate-2 + H+ = CaH(Tartarate)+
|
|
log_k 5.86
|
|
delta_h -9.1211 kJ
|
|
-gamma 0 0
|
|
# Id: 1509932
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Sr+2 + Tartarate-2 = Sr(Tartarate)
|
|
log_k 2.55
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8009931
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.00 20.0
|
|
Sr+2 + H+ + Tartarate-2 = SrH(Tartarate)+
|
|
log_k 5.8949
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8009932
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Ba+2 + Tartarate-2 = Ba(Tartarate)
|
|
log_k 2.54
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1009931
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ba+2 + Tartarate-2 + H+ = BaH(Tartarate)+
|
|
log_k 5.77
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1009932
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Na+ + Tartarate-2 = Na(Tartarate)-
|
|
log_k 0.9
|
|
delta_h -0.8368 kJ
|
|
-gamma 0 0
|
|
# Id: 5009931
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Na+ + Tartarate-2 + H+ = NaH(Tartarate)
|
|
log_k 4.58
|
|
delta_h -2.8451 kJ
|
|
-gamma 0 0
|
|
# Id: 5009932
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
K+ + Tartarate-2 = K(Tartarate)-
|
|
log_k 0.8
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4109931
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
H+ + Glycine- = H(Glycine)
|
|
log_k 9.778
|
|
delta_h -44.3504 kJ
|
|
-gamma 0 0
|
|
# Id: 3309941
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
2 H+ + Glycine- = H2(Glycine)+
|
|
log_k 12.128
|
|
delta_h -48.4507 kJ
|
|
-gamma 0 0
|
|
# Id: 3309942
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Pb+2 + Glycine- = Pb(Glycine)+
|
|
log_k 5.47
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009941
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Pb+2 + 2 Glycine- = Pb(Glycine)2
|
|
log_k 8.86
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009942
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Tl+ + Glycine- = Tl(Glycine)
|
|
log_k 1.72
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8709941
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Glycine- = Zn(Glycine)+
|
|
log_k 5.38
|
|
delta_h -11.7152 kJ
|
|
-gamma 0 0
|
|
# Id: 9509941
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + 2 Glycine- = Zn(Glycine)2
|
|
log_k 9.81
|
|
delta_h -24.2672 kJ
|
|
-gamma 0 0
|
|
# Id: 9509942
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + 3 Glycine- = Zn(Glycine)3-
|
|
log_k 12.3
|
|
delta_h -39.748 kJ
|
|
-gamma 0 0
|
|
# Id: 9509943
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + Glycine- = Cd(Glycine)+
|
|
log_k 4.69
|
|
delta_h -8.7864 kJ
|
|
-gamma 0 0
|
|
# Id: 1609941
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + 2 Glycine- = Cd(Glycine)2
|
|
log_k 8.4
|
|
delta_h -22.5936 kJ
|
|
-gamma 0 0
|
|
# Id: 1609942
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + 3 Glycine- = Cd(Glycine)3-
|
|
log_k 10.7
|
|
delta_h -35.9824 kJ
|
|
-gamma 0 0
|
|
# Id: 1609943
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + Glycine- + 2 H+ = Hg(Glycine)+ + 2 H2O
|
|
log_k 17
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619941
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Hg(OH)2 + 2 Glycine- + 2 H+ = Hg(Glycine)2 + 2 H2O
|
|
log_k 25.8
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619942
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cu+ + 2 Glycine- = Cu(Glycine)2-
|
|
log_k 10.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2309941
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Glycine- = Cu(Glycine)+
|
|
log_k 8.57
|
|
delta_h -25.104 kJ
|
|
-gamma 0 0
|
|
# Id: 2319941
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 2 Glycine- = Cu(Glycine)2
|
|
log_k 15.7
|
|
delta_h -54.8104 kJ
|
|
-gamma 0 0
|
|
# Id: 2319942
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + Glycine- = Ag(Glycine)
|
|
log_k 3.51
|
|
delta_h -19.2464 kJ
|
|
-gamma 0 0
|
|
# Id: 209941
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + 2 Glycine- = Ag(Glycine)2-
|
|
log_k 6.89
|
|
delta_h -48.116 kJ
|
|
-gamma 0 0
|
|
# Id: 209942
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Glycine- = Ni(Glycine)+
|
|
log_k 6.15
|
|
delta_h -18.828 kJ
|
|
-gamma 0 0
|
|
# Id: 5409941
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + 2 Glycine- = Ni(Glycine)2
|
|
log_k 11.12
|
|
delta_h -38.0744 kJ
|
|
-gamma 0 0
|
|
# Id: 5409942
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + 3 Glycine- = Ni(Glycine)3-
|
|
log_k 14.63
|
|
delta_h -62.3416 kJ
|
|
-gamma 0 0
|
|
# Id: 5409943
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Co+2 + Glycine- = Co(Glycine)+
|
|
log_k 5.07
|
|
delta_h -12 kJ
|
|
-gamma 0 0
|
|
# Id: 2009941
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + 2 Glycine- = Co(Glycine)2
|
|
log_k 9.07
|
|
delta_h -26 kJ
|
|
-gamma 0 0
|
|
# Id: 2009942
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + 3 Glycine- = Co(Glycine)3-
|
|
log_k 11.6
|
|
delta_h -41 kJ
|
|
-gamma 0 0
|
|
# Id: 2009943
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + Glycine- + H2O = CoOH(Glycine) + H+
|
|
log_k -5.02
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009944
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Fe+2 + Glycine- = Fe(Glycine)+
|
|
log_k 4.31
|
|
delta_h -15.0624 kJ
|
|
-gamma 0 0
|
|
# Id: 2809941
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+2 + 2 Glycine- = Fe(Glycine)2
|
|
log_k 8.29
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2809942
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+3 + Glycine- = Fe(Glycine)+2
|
|
log_k 9.38
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2819941
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+3 + Glycine- + H+ = FeH(Glycine)+3
|
|
log_k 11.55
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2819942
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mn+2 + Glycine- = Mn(Glycine)+
|
|
log_k 3.19
|
|
delta_h -1.2552 kJ
|
|
-gamma 0 0
|
|
# Id: 4709941
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mn+2 + 2 Glycine- = Mn(Glycine)2
|
|
log_k 5.4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4709942
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + Glycine- + 2 H+ = Cr(Glycine)+2 + 2 H2O
|
|
log_k 18.7
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119941
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + 2 Glycine- + 2 H+ = Cr(Glycine)2+ + 2 H2O
|
|
log_k 25.6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119942
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + 3 Glycine- + 2 H+ = Cr(Glycine)3 + 2 H2O
|
|
log_k 31.6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119943
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Mg+2 + Glycine- = Mg(Glycine)+
|
|
log_k 2.08
|
|
delta_h 4.184 kJ
|
|
-gamma 0 0
|
|
# Id: 4609941
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + Glycine- = Ca(Glycine)+
|
|
log_k 1.39
|
|
delta_h -4.184 kJ
|
|
-gamma 0 0
|
|
# Id: 1509941
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + Glycine- + H+ = CaH(Glycine)+2
|
|
log_k 10.1
|
|
delta_h -35.9824 kJ
|
|
-gamma 0 0
|
|
# Id: 1509942
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Sr+2 + Glycine- = Sr(Glycine)+
|
|
log_k 0.91
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8009941
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.00 25.0
|
|
Ba+2 + Glycine- = Ba(Glycine)+
|
|
log_k 0.77
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1009941
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
H+ + Salicylate-2 = H(Salicylate)-
|
|
log_k 13.7
|
|
delta_h -35.7732 kJ
|
|
-gamma 0 0
|
|
# Id: 3309951
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
2 H+ + Salicylate-2 = H2(Salicylate)
|
|
log_k 16.8
|
|
delta_h -38.7857 kJ
|
|
-gamma 0 0
|
|
# Id: 3309952
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Salicylate-2 = Zn(Salicylate)
|
|
log_k 7.71
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509951
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Zn+2 + Salicylate-2 + H+ = ZnH(Salicylate)+
|
|
log_k 15.5
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509952
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + Salicylate-2 = Cd(Salicylate)
|
|
log_k 6.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609951
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + Salicylate-2 + H+ = CdH(Salicylate)+
|
|
log_k 16
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609952
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Salicylate-2 = Cu(Salicylate)
|
|
log_k 11.3
|
|
delta_h -17.9912 kJ
|
|
-gamma 0 0
|
|
# Id: 2319951
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 2 Salicylate-2 = Cu(Salicylate)2-2
|
|
log_k 19.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319952
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Salicylate-2 + H+ = CuH(Salicylate)+
|
|
log_k 14.8
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2319953
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Salicylate-2 = Ni(Salicylate)
|
|
log_k 8.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409951
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + 2 Salicylate-2 = Ni(Salicylate)2-2
|
|
log_k 12.64
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409952
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Co+2 + Salicylate-2 = Co(Salicylate)
|
|
log_k 7.4289
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009951
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 20.0
|
|
Co+2 + 2 Salicylate-2 = Co(Salicylate)2-2
|
|
log_k 11.8
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009952
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 20.0
|
|
Fe+2 + Salicylate-2 = Fe(Salicylate)
|
|
log_k 7.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2809951
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+2 + 2 Salicylate-2 = Fe(Salicylate)2-2
|
|
log_k 11.6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2809952
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+3 + Salicylate-2 = Fe(Salicylate)+
|
|
log_k 17.6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2819951
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Fe+3 + 2 Salicylate-2 = Fe(Salicylate)2-
|
|
log_k 29.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2819952
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mn+2 + Salicylate-2 = Mn(Salicylate)
|
|
log_k 6.5
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4709951
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mn+2 + 2 Salicylate-2 = Mn(Salicylate)2-2
|
|
log_k 10.1
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4709952
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Be+2 + Salicylate-2 = Be(Salicylate)
|
|
log_k 13.3889
|
|
delta_h -31.7732 kJ
|
|
-gamma 0 0
|
|
# Id: 1109951
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.10 25.0
|
|
Be+2 + 2 Salicylate-2 = Be(Salicylate)2-2
|
|
log_k 23.25
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1109952
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Mg+2 + Salicylate-2 = Mg(Salicylate)
|
|
log_k 5.76
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4609951
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Mg+2 + Salicylate-2 + H+ = MgH(Salicylate)+
|
|
log_k 15.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4609952
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Ca+2 + Salicylate-2 = Ca(Salicylate)
|
|
log_k 4.05
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1509951
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + Salicylate-2 + H+ = CaH(Salicylate)+
|
|
log_k 14.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1509952
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ba+2 + Salicylate-2 + H+ = BaH(Salicylate)+
|
|
log_k 13.9
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1009951
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
H+ + Glutamate-2 = H(Glutamate)-
|
|
log_k 9.96
|
|
delta_h -41.0032 kJ
|
|
-gamma 0 0
|
|
# Id: 3309961
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
2 H+ + Glutamate-2 = H2(Glutamate)
|
|
log_k 14.26
|
|
delta_h -43.5136 kJ
|
|
-gamma 0 0
|
|
# Id: 3309962
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
3 H+ + Glutamate-2 = H3(Glutamate)+
|
|
log_k 16.42
|
|
delta_h -46.8608 kJ
|
|
-gamma 0 0
|
|
# Id: 3309963
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Pb+2 + Glutamate-2 = Pb(Glutamate)
|
|
log_k 6.43
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009961
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Pb+2 + 2 Glutamate-2 = Pb(Glutamate)2-2
|
|
log_k 8.61
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009962
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Pb+2 + Glutamate-2 + H+ = PbH(Glutamate)+
|
|
log_k 14.08
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009963
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Al+3 + Glutamate-2 + H+ = AlH(Glutamate)+2
|
|
log_k 13.07
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 309961
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Glutamate-2 = Zn(Glutamate)
|
|
log_k 6.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509961
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Zn+2 + 2 Glutamate-2 = Zn(Glutamate)2-2
|
|
log_k 9.13
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509962
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Zn+2 + 3 Glutamate-2 = Zn(Glutamate)3-4
|
|
log_k 9.8
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509963
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cd+2 + Glutamate-2 = Cd(Glutamate)
|
|
log_k 4.7
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609961
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + 2 Glutamate-2 = Cd(Glutamate)2-2
|
|
log_k 7.59
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609962
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Hg(OH)2 + Glutamate-2 + 2 H+ = Hg(Glutamate) + 2 H2O
|
|
log_k 19.8
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619961
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Hg(OH)2 + 2 Glutamate-2 + 2 H+ = Hg(Glutamate)2-2 + 2 H2O
|
|
log_k 26.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 3619962
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cu+2 + Glutamate-2 = Cu(Glutamate)
|
|
log_k 9.17
|
|
delta_h -20.92 kJ
|
|
-gamma 0 0
|
|
# Id: 2319961
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 2 Glutamate-2 = Cu(Glutamate)2-2
|
|
log_k 15.78
|
|
delta_h -48.116 kJ
|
|
-gamma 0 0
|
|
# Id: 2319962
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Glutamate-2 + H+ = CuH(Glutamate)+
|
|
log_k 13.3
|
|
delta_h -28.0328 kJ
|
|
-gamma 0 0
|
|
# Id: 2319963
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + Glutamate-2 = Ag(Glutamate)-
|
|
log_k 4.22
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 209961
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ag+ + 2 Glutamate-2 = Ag(Glutamate)2-3
|
|
log_k 7.36
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 209962
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
2 Ag+ + Glutamate-2 = Ag2(Glutamate)
|
|
log_k 3.4
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 209963
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Glutamate-2 = Ni(Glutamate)
|
|
log_k 6.47
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409961
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + 2 Glutamate-2 = Ni(Glutamate)2-2
|
|
log_k 10.7
|
|
delta_h -30.9616 kJ
|
|
-gamma 0 0
|
|
# Id: 5409962
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Co+2 + Glutamate-2 = Co(Glutamate)
|
|
log_k 5.4178
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009961
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Co+2 + 2 Glutamate-2 = Co(Glutamate)2-2
|
|
log_k 8.7178
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009962
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Mn+2 + Glutamate-2 = Mn(Glutamate)
|
|
log_k 4.95
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4709961
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Mn+2 + 2 Glutamate-2 = Mn(Glutamate)2-2
|
|
log_k 8.48
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4709962
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + Glutamate-2 + 2 H+ = Cr(Glutamate)+ + 2 H2O
|
|
log_k 22.6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119961
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + 2 Glutamate-2 + 2 H+ = Cr(Glutamate)2- + 2 H2O
|
|
log_k 30.7
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119962
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + Glutamate-2 + 3 H+ = CrH(Glutamate)+2 + 2 H2O
|
|
log_k 25.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119963
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Mg+2 + Glutamate-2 = Mg(Glutamate)
|
|
log_k 2.8
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4609961
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + Glutamate-2 = Ca(Glutamate)
|
|
log_k 2.06
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1509961
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + Glutamate-2 + H+ = CaH(Glutamate)+
|
|
log_k 11.13
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1509962
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Sr+2 + Glutamate-2 = Sr(Glutamate)
|
|
log_k 2.2278
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 8009961
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Ba+2 + Glutamate-2 = Ba(Glutamate)
|
|
log_k 2.14
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1009961
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
H+ + Phthalate-2 = H(Phthalate)-
|
|
log_k 5.408
|
|
delta_h 2.1757 kJ
|
|
-gamma 0 0
|
|
# Id: 3309971
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
2 H+ + Phthalate-2 = H2(Phthalate)
|
|
log_k 8.358
|
|
delta_h 4.8534 kJ
|
|
-gamma 0 0
|
|
# Id: 3309972
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Pb+2 + Phthalate-2 = Pb(Phthalate)
|
|
log_k 4.26
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009971
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Pb+2 + 2 Phthalate-2 = Pb(Phthalate)2-2
|
|
log_k 4.83
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009972
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Pb+2 + Phthalate-2 + H+ = PbH(Phthalate)+
|
|
log_k 6.98
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 6009973
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Al+3 + Phthalate-2 = Al(Phthalate)+
|
|
log_k 4.56
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 309971
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Al+3 + 2 Phthalate-2 = Al(Phthalate)2-
|
|
log_k 7.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 309972
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + Phthalate-2 = Zn(Phthalate)
|
|
log_k 2.91
|
|
delta_h 13.3888 kJ
|
|
-gamma 0 0
|
|
# Id: 9509971
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Zn+2 + 2 Phthalate-2 = Zn(Phthalate)2-2
|
|
log_k 4.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 9509972
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + Phthalate-2 = Cd(Phthalate)
|
|
log_k 3.43
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609971
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + Phthalate-2 + H+ = CdH(Phthalate)+
|
|
log_k 6.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609973
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cd+2 + 2 Phthalate-2 = Cd(Phthalate)2-2
|
|
log_k 3.7
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1609972
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Phthalate-2 = Cu(Phthalate)
|
|
log_k 4.02
|
|
delta_h 8.368 kJ
|
|
-gamma 0 0
|
|
# Id: 2319971
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + Phthalate-2 + H+ = CuH(Phthalate)+
|
|
log_k 7.1
|
|
delta_h 3.8493 kJ
|
|
-gamma 0 0
|
|
# Id: 2319970
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cu+2 + 2 Phthalate-2 = Cu(Phthalate)2-2
|
|
log_k 5.3
|
|
delta_h 15.8992 kJ
|
|
-gamma 0 0
|
|
# Id: 2319972
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Phthalate-2 = Ni(Phthalate)
|
|
log_k 2.95
|
|
delta_h 7.5312 kJ
|
|
-gamma 0 0
|
|
# Id: 5409971
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ni+2 + Phthalate-2 + H+ = NiH(Phthalate)+
|
|
log_k 6.6
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 5409972
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Co+2 + Phthalate-2 = Co(Phthalate)
|
|
log_k 2.83
|
|
delta_h 7.9 kJ
|
|
-gamma 0 0
|
|
# Id: 2009971
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.4
|
|
#T and ionic strength: 0.00 25.0
|
|
Co+2 + H+ + Phthalate-2 = CoH(Phthalate)+
|
|
log_k 7.227
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2009972
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.50 25.0
|
|
Mn+2 + Phthalate-2 = Mn(Phthalate)
|
|
log_k 2.74
|
|
delta_h 10.0416 kJ
|
|
-gamma 0 0
|
|
# Id: 4709971
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + Phthalate-2 + 2 H+ = Cr(Phthalate)+ + 2 H2O
|
|
log_k 16.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119971
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + 2 Phthalate-2 + 2 H+ = Cr(Phthalate)2- + 2 H2O
|
|
log_k 21.2
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119972
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Cr(OH)2+ + 3 Phthalate-2 + 2 H+ = Cr(Phthalate)3-3 + 2 H2O
|
|
log_k 23.3
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 2119973
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Be+2 + Phthalate-2 = Be(Phthalate)
|
|
log_k 4.8278
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1109971
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Be+2 + 2 Phthalate-2 = Be(Phthalate)2-2
|
|
log_k 6.5478
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1109972
|
|
# log K source: NIST46.4
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength: 0.10 25.0
|
|
Mg+2 + Phthalate-2 = Mg(Phthalate)
|
|
log_k 2.49
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 4609971
|
|
# log K source: SCD2.62
|
|
# Delta H source: SCD2.62
|
|
#T and ionic strength:
|
|
Ca+2 + Phthalate-2 = Ca(Phthalate)
|
|
log_k 2.45
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1509970
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ca+2 + Phthalate-2 + H+ = CaH(Phthalate)+
|
|
log_k 6.43
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1509971
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Ba+2 + Phthalate-2 = Ba(Phthalate)
|
|
log_k 2.33
|
|
delta_h 0 kJ
|
|
-gamma 0 0
|
|
# Id: 1009971
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
Na+ + Phthalate-2 = Na(Phthalate)-
|
|
log_k 0.8
|
|
delta_h 4.184 kJ
|
|
-gamma 0 0
|
|
# Id: 5009970
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
K+ + Phthalate-2 = K(Phthalate)-
|
|
log_k 0.7
|
|
delta_h 3.7656 kJ
|
|
-gamma 0 0
|
|
# Id: 4109971
|
|
# log K source: NIST46.2
|
|
# Delta H source: NIST46.2
|
|
#T and ionic strength:
|
|
PHASES
|
|
Sulfur
|
|
S + H+ + 2 e- = HS-
|
|
log_k -2.1449
|
|
delta_h -16.3 kJ
|
|
Semetal(hex
|
|
Se + H+ + 2 e- = HSe-
|
|
log_k -7.7084
|
|
delta_h 15.9 kJ
|
|
Semetal(am)
|
|
Se + H+ + 2 e- = HSe-
|
|
log_k -7.1099
|
|
delta_h 10.8784 kJ
|
|
Sbmetal
|
|
Sb + 3 H2O = Sb(OH)3 + 3 H+ + 3 e-
|
|
log_k -11.6889
|
|
delta_h 83.89 kJ
|
|
Snmetal(wht)
|
|
Sn + 2 H2O = Sn(OH)2 + 2 H+ + 2 e-
|
|
log_k -2.3266
|
|
delta_h -0 kJ
|
|
Pbmetal
|
|
Pb = Pb+2 + 2 e-
|
|
log_k 4.2462
|
|
delta_h 0.92 kJ
|
|
Tlmetal
|
|
Tl = Tl+ + e-
|
|
log_k 5.6762
|
|
delta_h 5.36 kJ
|
|
Znmetal
|
|
Zn = Zn+2 + 2 e-
|
|
log_k 25.7886
|
|
delta_h -153.39 kJ
|
|
Cdmetal(alpha)
|
|
Cd = Cd+2 + 2 e-
|
|
log_k 13.5147
|
|
delta_h -75.33 kJ
|
|
Cdmetal(gamma)
|
|
Cd = Cd+2 + 2 e-
|
|
log_k 13.618
|
|
delta_h -75.92 kJ
|
|
Hgmetal(l)
|
|
Hg = 0.5 Hg2+2 + e-
|
|
log_k -13.4517
|
|
delta_h 83.435 kJ
|
|
Cumetal
|
|
Cu = Cu+ + e-
|
|
log_k -8.756
|
|
delta_h 71.67 kJ
|
|
Agmetal
|
|
Ag = Ag+ + e-
|
|
log_k -13.5065
|
|
delta_h 105.79 kJ
|
|
Crmetal
|
|
Cr = Cr+2 + 2 e-
|
|
log_k 30.4831
|
|
delta_h -172 kJ
|
|
Vmetal
|
|
V = V+3 + 3 e-
|
|
log_k 44.0253
|
|
delta_h -259 kJ
|
|
Stibnite
|
|
Sb2S3 + 6 H2O = 2 Sb(OH)3 + 3 H+ + 3 HS-
|
|
log_k -50.46
|
|
delta_h 293.78 kJ
|
|
Orpiment
|
|
As2S3 + 6 H2O = 2 H3AsO3 + 3 HS- + 3 H+
|
|
log_k -61.0663
|
|
delta_h 350.68 kJ
|
|
Realgar
|
|
AsS + 3 H2O = H3AsO3 + HS- + 2 H+ + e-
|
|
log_k -19.747
|
|
delta_h 127.8 kJ
|
|
SnS
|
|
SnS + 2 H2O = Sn(OH)2 + H+ + HS-
|
|
log_k -19.114
|
|
delta_h -0 kJ
|
|
SnS2
|
|
SnS2 + 6 H2O = Sn(OH)6-2 + 4 H+ + 2 HS-
|
|
log_k -57.4538
|
|
delta_h -0 kJ
|
|
Galena
|
|
PbS + H+ = Pb+2 + HS-
|
|
log_k -13.97
|
|
delta_h 80 kJ
|
|
Tl2S
|
|
Tl2S + H+ = 2 Tl+ + HS-
|
|
log_k -7.19
|
|
delta_h 91.52 kJ
|
|
ZnS(am)
|
|
ZnS + H+ = Zn+2 + HS-
|
|
log_k -9.052
|
|
delta_h 15.3553 kJ
|
|
Sphalerite
|
|
ZnS + H+ = Zn+2 + HS-
|
|
log_k -11.45
|
|
delta_h 30 kJ
|
|
Wurtzite
|
|
ZnS + H+ = Zn+2 + HS-
|
|
log_k -8.95
|
|
delta_h 21.171 kJ
|
|
Greenockite
|
|
CdS + H+ = Cd+2 + HS-
|
|
log_k -14.36
|
|
delta_h 55 kJ
|
|
Hg2S
|
|
Hg2S + H+ = Hg2+2 + HS-
|
|
log_k -11.6765
|
|
delta_h 69.7473 kJ
|
|
Cinnabar
|
|
HgS + 2 H2O = Hg(OH)2 + H+ + HS-
|
|
log_k -45.694
|
|
delta_h 253.76 kJ
|
|
Metacinnabar
|
|
HgS + 2 H2O = Hg(OH)2 + H+ + HS-
|
|
log_k -45.094
|
|
delta_h 253.72 kJ
|
|
Chalcocite
|
|
Cu2S + H+ = 2 Cu+ + HS-
|
|
log_k -34.92
|
|
delta_h 168 kJ
|
|
Djurleite
|
|
Cu0.066Cu1.868S + H+ = 0.066 Cu+2 + 1.868 Cu+ + HS-
|
|
log_k -33.92
|
|
delta_h 200.334 kJ
|
|
Anilite
|
|
Cu0.25Cu1.5S + H+ = 0.25 Cu+2 + 1.5 Cu+ + HS-
|
|
log_k -31.878
|
|
delta_h 182.15 kJ
|
|
BlaubleiII
|
|
Cu0.6Cu0.8S + H+ = 0.6 Cu+2 + 0.8 Cu+ + HS-
|
|
log_k -27.279
|
|
delta_h -0 kJ
|
|
BlaubleiI
|
|
Cu0.9Cu0.2S + H+ = 0.9 Cu+2 + 0.2 Cu+ + HS-
|
|
log_k -24.162
|
|
delta_h -0 kJ
|
|
Covellite
|
|
CuS + H+ = Cu+2 + HS-
|
|
log_k -22.3
|
|
delta_h 97 kJ
|
|
Chalcopyrite
|
|
CuFeS2 + 2 H+ = Cu+2 + Fe+2 + 2 HS-
|
|
log_k -35.27
|
|
delta_h 148.448 kJ
|
|
Acanthite
|
|
Ag2S + H+ = 2 Ag+ + HS-
|
|
log_k -36.22
|
|
delta_h 227 kJ
|
|
NiS(alpha)
|
|
NiS + H+ = Ni+2 + HS-
|
|
log_k -5.6
|
|
delta_h -0 kJ
|
|
NiS(beta)
|
|
NiS + H+ = Ni+2 + HS-
|
|
log_k -11.1
|
|
delta_h -0 kJ
|
|
NiS(gamma)
|
|
NiS + H+ = Ni+2 + HS-
|
|
log_k -12.8
|
|
delta_h -0 kJ
|
|
CoS(alpha)
|
|
CoS + H+ = Co+2 + HS-
|
|
log_k -7.44
|
|
delta_h -0 kJ
|
|
CoS(beta)
|
|
CoS + H+ = Co+2 + HS-
|
|
log_k -11.07
|
|
delta_h -0 kJ
|
|
FeS(ppt)
|
|
FeS + H+ = Fe+2 + HS-
|
|
log_k -2.95
|
|
delta_h -11 kJ
|
|
Greigite
|
|
Fe3S4 + 4 H+ = 2 Fe+3 + Fe+2 + 4 HS-
|
|
log_k -45.035
|
|
delta_h -0 kJ
|
|
Mackinawite
|
|
FeS + H+ = Fe+2 + HS-
|
|
log_k -3.6
|
|
delta_h -0 kJ
|
|
Pyrite
|
|
FeS2 + 2 H+ + 2 e- = Fe+2 + 2 HS-
|
|
log_k -18.5082
|
|
delta_h 49.844 kJ
|
|
MnS(grn)
|
|
MnS + H+ = Mn+2 + HS-
|
|
log_k 0.17
|
|
delta_h -32 kJ
|
|
MnS(pnk)
|
|
MnS + H+ = Mn+2 + HS-
|
|
log_k 3.34
|
|
delta_h -0 kJ
|
|
MoS2
|
|
MoS2 + 4 H2O = MoO4-2 + 6 H+ + 2 HS- + 2 e-
|
|
log_k -70.2596
|
|
delta_h 389.02 kJ
|
|
BeS
|
|
BeS + H+ = Be+2 + HS-
|
|
log_k 19.38
|
|
delta_h -0 kJ
|
|
BaS
|
|
BaS + H+ = Ba+2 + HS-
|
|
log_k 16.18
|
|
delta_h -0 kJ
|
|
Hg2(Cyanide)2
|
|
Hg2(Cyanide)2 = Hg2+2 + 2 Cyanide-
|
|
log_k -39.3
|
|
delta_h -0 kJ
|
|
CuCyanide
|
|
CuCyanide = Cu+ + Cyanide-
|
|
log_k -19.5
|
|
delta_h -19 kJ
|
|
AgCyanide
|
|
AgCyanide = Ag+ + Cyanide-
|
|
log_k -15.74
|
|
delta_h 110.395 kJ
|
|
Ag2(Cyanide)2
|
|
Ag2(Cyanide)2 = 2 Ag+ + 2 Cyanide-
|
|
log_k -11.3289
|
|
delta_h -0 kJ
|
|
NaCyanide(cubic)
|
|
NaCyanide = Cyanide- + Na+
|
|
log_k 1.6012
|
|
delta_h 0.969 kJ
|
|
KCyanide(cubic)
|
|
KCyanide = Cyanide- + K+
|
|
log_k 1.4188
|
|
delta_h 11.93 kJ
|
|
Pb2Fe(Cyanide)6
|
|
Pb2Fe(Cyanide)6 = 2 Pb+2 + Fe+2 + 6 Cyanide-
|
|
log_k -53.42
|
|
delta_h -0 kJ
|
|
Zn2Fe(Cyanide)6
|
|
Zn2Fe(Cyanide)6 = 2 Zn+2 + Fe+2 + 6 Cyanide-
|
|
log_k -51.08
|
|
delta_h -0 kJ
|
|
Cd2Fe(Cyanide)6
|
|
Cd2Fe(Cyanide)6 = 2 Cd+2 + Fe+2 + 6 Cyanide-
|
|
log_k -52.78
|
|
delta_h -0 kJ
|
|
Ag4Fe(Cyanide)6
|
|
Ag4Fe(Cyanide)6 = 4 Ag+ + Fe+2 + 6 Cyanide-
|
|
log_k -79.47
|
|
delta_h -0 kJ
|
|
Ag3Fe(Cyanide)6
|
|
Ag3Fe(Cyanide)6 = 3 Ag+ + Fe+3 + 6 Cyanide-
|
|
log_k -72.7867
|
|
delta_h -0 kJ
|
|
Mn3(Fe(Cyanide)6)2
|
|
Mn3(Fe(Cyanide)6)2 = 3 Mn+2 + 2 Fe+3 + 12 Cyanide-
|
|
log_k -105.4
|
|
delta_h -0 kJ
|
|
Sb2Se3
|
|
Sb2Se3 + 6 H2O = 2 Sb(OH)3 + 3 HSe- + 3 H+
|
|
log_k -67.7571
|
|
delta_h 343.046 kJ
|
|
SnSe
|
|
SnSe + 2 H2O = Sn(OH)2 + H+ + HSe-
|
|
log_k -30.494
|
|
delta_h -0 kJ
|
|
SnSe2
|
|
SnSe2 + 6 H2O = Sn(OH)6-2 + 4 H+ + 2 HSe-
|
|
log_k -65.1189
|
|
delta_h -0 kJ
|
|
Clausthalite
|
|
PbSe + H+ = Pb+2 + HSe-
|
|
log_k -27.1
|
|
delta_h 119.72 kJ
|
|
Tl2Se
|
|
Tl2Se + H+ = 2 Tl+ + HSe-
|
|
log_k -18.1
|
|
delta_h 85.62 kJ
|
|
ZnSe
|
|
ZnSe + H+ = Zn+2 + HSe-
|
|
log_k -14.4
|
|
delta_h 25.51 kJ
|
|
CdSe
|
|
CdSe + H+ = Cd+2 + HSe-
|
|
log_k -20.2
|
|
delta_h 75.9814 kJ
|
|
HgSe
|
|
HgSe + 2 H2O = Hg(OH)2 + H+ + HSe-
|
|
log_k -55.694
|
|
delta_h -0 kJ
|
|
Cu2Se(alpha)
|
|
Cu2Se + H+ = 2 Cu+ + HSe-
|
|
log_k -45.8
|
|
delta_h 214.263 kJ
|
|
Cu3Se2
|
|
Cu3Se2 + 2 H+ = 2 HSe- + 2 Cu+ + Cu+2
|
|
log_k -63.4911
|
|
delta_h 340.327 kJ
|
|
CuSe
|
|
CuSe + H+ = Cu+2 + HSe-
|
|
log_k -33.1
|
|
delta_h 121.127 kJ
|
|
CuSe2
|
|
CuSe2 + 2 H+ + 2 e- = 2 HSe- + Cu+2
|
|
log_k -33.3655
|
|
delta_h 140.582 kJ
|
|
Ag2Se
|
|
Ag2Se + H+ = 2 Ag+ + HSe-
|
|
log_k -48.7
|
|
delta_h 265.48 kJ
|
|
NiSe
|
|
NiSe + H+ = Ni+2 + HSe-
|
|
log_k -17.7
|
|
delta_h -0 kJ
|
|
CoSe
|
|
CoSe + H+ = Co+2 + HSe-
|
|
log_k -16.2
|
|
delta_h -0 kJ
|
|
FeSe
|
|
FeSe + H+ = Fe+2 + HSe-
|
|
log_k -11
|
|
delta_h 2.092 kJ
|
|
Ferroselite
|
|
FeSe2 + 2 H+ + 2 e- = 2 HSe- + Fe+2
|
|
log_k -18.5959
|
|
delta_h 47.2792 kJ
|
|
MnSe
|
|
MnSe + H+ = Mn+2 + HSe-
|
|
log_k 3.5
|
|
delta_h -98.15 kJ
|
|
AlSb
|
|
AlSb + 3 H2O = Sb(OH)3 + 6 e- + Al+3 + 3 H+
|
|
log_k 65.6241
|
|
delta_h -0 kJ
|
|
ZnSb
|
|
ZnSb + 3 H2O = Sb(OH)3 + 5 e- + Zn+2 + 3 H+
|
|
log_k 11.0138
|
|
delta_h -54.8773 kJ
|
|
CdSb
|
|
CdSb + 3 H2O = Sb(OH)3 + 5 e- + 3 H+ + Cd+2
|
|
log_k -0.3501
|
|
delta_h 22.36 kJ
|
|
Cu2Sb:3H2O
|
|
Cu2Sb:3H2O = Sb(OH)3 + 6 e- + 3 H+ + Cu+ + Cu+2
|
|
log_k -34.8827
|
|
delta_h 233.237 kJ
|
|
Cu3Sb
|
|
Cu3Sb + 3 H2O = Sb(OH)3 + 6 e- + 3 H+ + 3 Cu+
|
|
log_k -42.5937
|
|
delta_h 308.131 kJ
|
|
#Ag4Sb
|
|
# Ag4Sb + 3H2O = Sb(OH)3 + 6e- + 3Ag+ + 3H+
|
|
# log_k -56.1818
|
|
# delta_h -0 kJ
|
|
Breithauptite
|
|
NiSb + 3 H2O = Sb(OH)3 + 5 e- + 3 H+ + Ni+2
|
|
log_k -18.5225
|
|
delta_h 96.0019 kJ
|
|
MnSb
|
|
MnSb + 3 H2O = Mn+3 + Sb(OH)3 + 6 e- + 3 H+
|
|
log_k -2.9099
|
|
delta_h 21.1083 kJ
|
|
Mn2Sb
|
|
Mn2Sb + 3 H2O = 2 Mn+2 + Sb(OH)3 + 7 e- + 3 H+
|
|
log_k 61.0796
|
|
delta_h -0 kJ
|
|
USb2
|
|
USb2 + 8 H2O = UO2+2 + 2 Sb(OH)3 + 12 e- + 10 H+
|
|
log_k 29.5771
|
|
delta_h -103.56 kJ
|
|
U3Sb4
|
|
U3Sb4 + 12 H2O = 3 U+4 + 4 Sb(OH)3 + 24 e- + 12 H+
|
|
log_k 152.383
|
|
delta_h -986.04 kJ
|
|
Mg2Sb3
|
|
Mg2Sb3 + 9 H2O = 2 Mg+2 + 3 Sb(OH)3 + 9 H+ + 13 e-
|
|
log_k 74.6838
|
|
delta_h -0 kJ
|
|
Ca3Sb2
|
|
Ca3Sb2 + 6 H2O = 3 Ca+2 + 2 Sb(OH)3 + 6 H+ + 12 e-
|
|
log_k 142.974
|
|
delta_h -732.744 kJ
|
|
NaSb
|
|
NaSb + 3 H2O = Na+ + Sb(OH)3 + 3 H+ + 4 e-
|
|
log_k 23.1658
|
|
delta_h -93.45 kJ
|
|
Na3Sb
|
|
Na3Sb + 3 H2O = 3 Na+ + Sb(OH)3 + 3 H+ + 6 e-
|
|
log_k 94.4517
|
|
delta_h -432.13 kJ
|
|
SeO2
|
|
SeO2 + H2O = HSeO3- + H+
|
|
log_k 0.1246
|
|
delta_h 1.4016 kJ
|
|
SeO3
|
|
SeO3 + H2O = SeO4-2 + 2 H+
|
|
log_k 21.044
|
|
delta_h -146.377 kJ
|
|
Sb2O5
|
|
Sb2O5 + 7 H2O = 2 Sb(OH)6- + 2 H+
|
|
log_k -9.6674
|
|
delta_h -0 kJ
|
|
SbO2
|
|
SbO2 + 4 H2O = Sb(OH)6- + e- + 2 H+
|
|
log_k -27.8241
|
|
delta_h -0 kJ
|
|
Sb2O4
|
|
Sb2O4 + 2 H2O + 2 H+ + 2 e- = 2 Sb(OH)3
|
|
log_k 3.4021
|
|
delta_h -68.04 kJ
|
|
Sb4O6(cubic)
|
|
Sb4O6 + 6 H2O = 4 Sb(OH)3
|
|
log_k -18.2612
|
|
delta_h 61.1801 kJ
|
|
Sb4O6(orth)
|
|
Sb4O6 + 6 H2O = 4 Sb(OH)3
|
|
log_k -17.9012
|
|
delta_h 37.6801 kJ
|
|
Sb(OH)3
|
|
Sb(OH)3 = Sb(OH)3
|
|
log_k -7.1099
|
|
delta_h 30.1248 kJ
|
|
Senarmontite
|
|
Sb2O3 + 3 H2O = 2 Sb(OH)3
|
|
log_k -12.3654
|
|
delta_h 30.6478 kJ
|
|
Valentinite
|
|
Sb2O3 + 3 H2O = 2 Sb(OH)3
|
|
log_k -8.4806
|
|
delta_h 19.0163 kJ
|
|
Chalcedony
|
|
SiO2 + 2 H2O = H4SiO4
|
|
log_k -3.55
|
|
delta_h 19.7 kJ
|
|
Cristobalite
|
|
SiO2 + 2 H2O = H4SiO4
|
|
log_k -3.35
|
|
delta_h 20.006 kJ
|
|
Quartz
|
|
SiO2 + 2 H2O = H4SiO4
|
|
log_k -4
|
|
delta_h 22.36 kJ
|
|
SiO2(am-gel)
|
|
SiO2 + 2 H2O = H4SiO4
|
|
log_k -2.71
|
|
delta_h 14 kJ
|
|
SiO2(am-ppt)
|
|
SiO2 + 2 H2O = H4SiO4
|
|
log_k -2.74
|
|
delta_h 15.15 kJ
|
|
SnO
|
|
SnO + H2O = Sn(OH)2
|
|
log_k -4.9141
|
|
delta_h -0 kJ
|
|
SnO2
|
|
SnO2 + 4 H2O = Sn(OH)6-2 + 2 H+
|
|
log_k -28.9749
|
|
delta_h -0 kJ
|
|
Sn(OH)2
|
|
Sn(OH)2 = Sn(OH)2
|
|
log_k -5.4309
|
|
delta_h -0 kJ
|
|
Sn(OH)4
|
|
Sn(OH)4 + 2 H2O = Sn(OH)6-2 + 2 H+
|
|
log_k -22.2808
|
|
delta_h -0 kJ
|
|
H2Sn(OH)6
|
|
H2Sn(OH)6 = Sn(OH)6-2 + 2 H+
|
|
log_k -23.5281
|
|
delta_h -0 kJ
|
|
Massicot
|
|
PbO + 2 H+ = Pb+2 + H2O
|
|
log_k 12.894
|
|
delta_h -66.848 kJ
|
|
Litharge
|
|
PbO + 2 H+ = Pb+2 + H2O
|
|
log_k 12.694
|
|
delta_h -65.501 kJ
|
|
PbO:0.3H2O
|
|
PbO:0.33H2O + 2 H+ = Pb+2 + 1.33 H2O
|
|
log_k 12.98
|
|
delta_h -0 kJ
|
|
Plattnerite
|
|
PbO2 + 4 H+ + 2 e- = Pb+2 + 2 H2O
|
|
log_k 49.6001
|
|
delta_h -296.27 kJ
|
|
Pb(OH)2
|
|
Pb(OH)2 + 2 H+ = Pb+2 + 2 H2O
|
|
log_k 8.15
|
|
delta_h -58.5342 kJ
|
|
Pb2O(OH)2
|
|
Pb2O(OH)2 + 4 H+ = 2 Pb+2 + 3 H2O
|
|
log_k 26.188
|
|
delta_h -0 kJ
|
|
Al(OH)3(am)
|
|
Al(OH)3 + 3 H+ = Al+3 + 3 H2O
|
|
log_k 10.8
|
|
delta_h -111 kJ
|
|
Boehmite
|
|
AlOOH + 3 H+ = Al+3 + 2 H2O
|
|
log_k 8.578
|
|
delta_h -117.696 kJ
|
|
Diaspore
|
|
AlOOH + 3 H+ = Al+3 + 2 H2O
|
|
log_k 6.873
|
|
delta_h -103.052 kJ
|
|
Gibbsite
|
|
Al(OH)3 + 3 H+ = Al+3 + 3 H2O
|
|
log_k 8.291
|
|
delta_h -95.3952 kJ
|
|
Tl2O
|
|
Tl2O + 2 H+ = 2 Tl+ + H2O
|
|
log_k 27.0915
|
|
delta_h -96.41 kJ
|
|
TlOH
|
|
TlOH + H+ = Tl+ + H2O
|
|
log_k 12.9186
|
|
delta_h -41.57 kJ
|
|
Avicennite
|
|
Tl2O3 + 3 H2O = 2 Tl(OH)3
|
|
log_k -13
|
|
delta_h -0 kJ
|
|
Tl(OH)3
|
|
Tl(OH)3 = Tl(OH)3
|
|
log_k -5.441
|
|
delta_h -0 kJ
|
|
Zn(OH)2(am)
|
|
Zn(OH)2 + 2 H+ = Zn+2 + 2 H2O
|
|
log_k 12.474
|
|
delta_h -80.62 kJ
|
|
Zn(OH)2
|
|
Zn(OH)2 + 2 H+ = Zn+2 + 2 H2O
|
|
log_k 12.2
|
|
delta_h -0 kJ
|
|
Zn(OH)2(beta)
|
|
Zn(OH)2 + 2 H+ = Zn+2 + 2 H2O
|
|
log_k 11.754
|
|
delta_h -83.14 kJ
|
|
Zn(OH)2(gamma)
|
|
Zn(OH)2 + 2 H+ = Zn+2 + 2 H2O
|
|
log_k 11.734
|
|
delta_h -0 kJ
|
|
Zn(OH)2(epsilon)
|
|
Zn(OH)2 + 2 H+ = Zn+2 + 2 H2O
|
|
log_k 11.534
|
|
delta_h -81.8 kJ
|
|
ZnO(active)
|
|
ZnO + 2 H+ = Zn+2 + H2O
|
|
log_k 11.1884
|
|
delta_h -88.76 kJ
|
|
Zincite
|
|
ZnO + 2 H+ = Zn+2 + H2O
|
|
log_k 11.334
|
|
delta_h -89.62 kJ
|
|
Cd(OH)2(am)
|
|
Cd(OH)2 + 2 H+ = Cd+2 + 2 H2O
|
|
log_k 13.73
|
|
delta_h -86.9017 kJ
|
|
Cd(OH)2
|
|
Cd(OH)2 + 2 H+ = Cd+2 + 2 H2O
|
|
log_k 13.644
|
|
delta_h -94.62 kJ
|
|
Monteponite
|
|
CdO + 2 H+ = Cd+2 + H2O
|
|
log_k 15.1034
|
|
delta_h -103.4 kJ
|
|
Hg2(OH)2
|
|
Hg2(OH)2 + 2 H+ = Hg2+2 + 2 H2O
|
|
log_k 5.2603
|
|
delta_h -0 kJ
|
|
Montroydite
|
|
HgO + H2O = Hg(OH)2
|
|
log_k -3.64
|
|
delta_h -38.9 kJ
|
|
Hg(OH)2
|
|
Hg(OH)2 = Hg(OH)2
|
|
log_k -3.4963
|
|
delta_h -0 kJ
|
|
Cuprite
|
|
Cu2O + 2 H+ = 2 Cu+ + H2O
|
|
log_k -1.406
|
|
delta_h -124.02 kJ
|
|
Cu(OH)2
|
|
Cu(OH)2 + 2 H+ = Cu+2 + 2 H2O
|
|
log_k 8.674
|
|
delta_h -56.42 kJ
|
|
Tenorite
|
|
CuO + 2 H+ = Cu+2 + H2O
|
|
log_k 7.644
|
|
delta_h -64.867 kJ
|
|
Ag2O
|
|
Ag2O + 2 H+ = 2 Ag+ + H2O
|
|
log_k 12.574
|
|
delta_h -45.62 kJ
|
|
Ni(OH)2
|
|
Ni(OH)2 + 2 H+ = Ni+2 + 2 H2O
|
|
log_k 12.794
|
|
delta_h -95.96 kJ
|
|
Bunsenite
|
|
NiO + 2 H+ = Ni+2 + H2O
|
|
log_k 12.4456
|
|
delta_h -100.13 kJ
|
|
CoO
|
|
CoO + 2 H+ = Co+2 + H2O
|
|
log_k 13.5864
|
|
delta_h -106.295 kJ
|
|
Co(OH)2
|
|
Co(OH)2 + 2 H+ = Co+2 + 2 H2O
|
|
log_k 13.094
|
|
delta_h -0 kJ
|
|
Co(OH)3
|
|
Co(OH)3 + 3 H+ = Co+3 + 3 H2O
|
|
log_k -2.309
|
|
delta_h -92.43 kJ
|
|
#Wustite-0.11
|
|
# WUSTITE-0.11 + 2H+ = 0.947Fe+2 + H2O
|
|
# log_k 11.6879
|
|
# delta_h -103.938 kJ
|
|
Fe(OH)2
|
|
Fe(OH)2 + 2 H+ = Fe+2 + 2 H2O
|
|
log_k 13.564
|
|
delta_h -0 kJ
|
|
Ferrihydrite
|
|
Fe(OH)3 + 3 H+ = Fe+3 + 3 H2O
|
|
log_k 3.191
|
|
delta_h -73.374 kJ
|
|
Fe3(OH)8
|
|
Fe3(OH)8 + 8 H+ = 2 Fe+3 + Fe+2 + 8 H2O
|
|
log_k 20.222
|
|
delta_h -0 kJ
|
|
Goethite
|
|
FeOOH + 3 H+ = Fe+3 + 2 H2O
|
|
log_k 0.491
|
|
delta_h -60.5843 kJ
|
|
Pyrolusite
|
|
MnO2 + 4 H+ + 2 e- = Mn+2 + 2 H2O
|
|
log_k 41.38
|
|
delta_h -272 kJ
|
|
Birnessite
|
|
MnO2 + 4 H+ + e- = Mn+3 + 2 H2O
|
|
log_k 18.091
|
|
delta_h -0 kJ
|
|
Nsutite
|
|
MnO2 + 4 H+ + e- = Mn+3 + 2 H2O
|
|
log_k 17.504
|
|
delta_h -0 kJ
|
|
Pyrochroite
|
|
Mn(OH)2 + 2 H+ = Mn+2 + 2 H2O
|
|
log_k 15.194
|
|
delta_h -97.0099 kJ
|
|
Manganite
|
|
MnOOH + 3 H+ + e- = Mn+2 + 2 H2O
|
|
log_k 25.34
|
|
delta_h -0 kJ
|
|
Cr(OH)2
|
|
Cr(OH)2 + 2 H+ = Cr+2 + 2 H2O
|
|
log_k 10.8189
|
|
delta_h -35.6058 kJ
|
|
Cr(OH)3(am)
|
|
Cr(OH)3 + H+ = Cr(OH)2+ + H2O
|
|
log_k -0.75
|
|
delta_h -0 kJ
|
|
Cr(OH)3
|
|
Cr(OH)3 + H+ = Cr(OH)2+ + H2O
|
|
log_k 1.3355
|
|
delta_h -29.7692 kJ
|
|
CrO3
|
|
CrO3 + H2O = CrO4-2 + 2 H+
|
|
log_k -3.2105
|
|
delta_h -5.2091 kJ
|
|
MoO3
|
|
MoO3 + H2O = MoO4-2 + 2 H+
|
|
log_k -8
|
|
delta_h -0 kJ
|
|
VO
|
|
VO + 2 H+ = V+3 + H2O + e-
|
|
log_k 14.7563
|
|
delta_h -113.041 kJ
|
|
V(OH)3
|
|
V(OH)3 + 3 H+ = V+3 + 3 H2O
|
|
log_k 7.591
|
|
delta_h -0 kJ
|
|
VO(OH)2
|
|
VO(OH)2 + 2 H+ = VO+2 + 2 H2O
|
|
log_k 5.1506
|
|
delta_h -0 kJ
|
|
Uraninite
|
|
UO2 + 4 H+ = U+4 + 2 H2O
|
|
log_k -4.6693
|
|
delta_h -77.86 kJ
|
|
UO2(am)
|
|
UO2 + 4 H+ = U+4 + 2 H2O
|
|
log_k 0.934
|
|
delta_h -109.746 kJ
|
|
UO3
|
|
UO3 + 2 H+ = UO2+2 + H2O
|
|
log_k 7.7
|
|
delta_h -81.0299 kJ
|
|
Gummite
|
|
UO3 + 2 H+ = UO2+2 + H2O
|
|
log_k 7.6718
|
|
delta_h -81.0299 kJ
|
|
UO2(OH)2(beta)
|
|
UO2(OH)2 + 2 H+ = UO2+2 + 2 H2O
|
|
log_k 5.6116
|
|
delta_h -56.7599 kJ
|
|
Schoepite
|
|
UO2(OH)2:H2O + 2 H+ = UO2+2 + 3 H2O
|
|
log_k 5.994
|
|
delta_h -49.79 kJ
|
|
Be(OH)2(am)
|
|
Be(OH)2 + 2 H+ = Be+2 + 2 H2O
|
|
log_k 7.194
|
|
delta_h -0 kJ
|
|
Be(OH)2(alpha)
|
|
Be(OH)2 + 2 H+ = Be+2 + 2 H2O
|
|
log_k 6.894
|
|
delta_h -0 kJ
|
|
Be(OH)2(beta)
|
|
Be(OH)2 + 2 H+ = Be+2 + 2 H2O
|
|
log_k 6.494
|
|
delta_h -0 kJ
|
|
Brucite
|
|
Mg(OH)2 + 2 H+ = Mg+2 + 2 H2O
|
|
log_k 16.844
|
|
delta_h -113.996 kJ
|
|
Periclase
|
|
MgO + 2 H+ = Mg+2 + H2O
|
|
log_k 21.5841
|
|
delta_h -151.23 kJ
|
|
Mg(OH)2(active)
|
|
Mg(OH)2 + 2 H+ = Mg+2 + 2 H2O
|
|
log_k 18.794
|
|
delta_h -0 kJ
|
|
Lime
|
|
CaO + 2 H+ = Ca+2 + H2O
|
|
log_k 32.6993
|
|
delta_h -193.91 kJ
|
|
Portlandite
|
|
Ca(OH)2 + 2 H+ = Ca+2 + 2 H2O
|
|
log_k 22.804
|
|
delta_h -128.62 kJ
|
|
Ba(OH)2:8H2O
|
|
Ba(OH)2:8H2O + 2 H+ = Ba+2 + 10 H2O
|
|
log_k 24.394
|
|
delta_h -54.32 kJ
|
|
Cu(SbO3)2
|
|
Cu(SbO3)2 + 6 H+ + 4 e- = 2 Sb(OH)3 + Cu+2
|
|
log_k 45.2105
|
|
delta_h -0 kJ
|
|
Arsenolite
|
|
As4O6 + 6 H2O = 4 H3AsO3
|
|
log_k -2.76
|
|
delta_h 59.9567 kJ
|
|
Claudetite
|
|
As4O6 + 6 H2O = 4 H3AsO3
|
|
log_k -3.065
|
|
delta_h 55.6054 kJ
|
|
As2O5
|
|
As2O5 + 3 H2O = 2 H3AsO4
|
|
log_k 6.7061
|
|
delta_h -22.64 kJ
|
|
Pb2O3
|
|
Pb2O3 + 6 H+ + 2 e- = 2 Pb+2 + 3 H2O
|
|
log_k 61.04
|
|
delta_h -0 kJ
|
|
Minium
|
|
Pb3O4 + 8 H+ + 2 e- = 3 Pb+2 + 4 H2O
|
|
log_k 73.5219
|
|
delta_h -421.874 kJ
|
|
Al2O3
|
|
Al2O3 + 6 H+ = 2 Al+3 + 3 H2O
|
|
log_k 19.6524
|
|
delta_h -258.59 kJ
|
|
Co3O4
|
|
Co3O4 + 8 H+ = Co+2 + 2 Co+3 + 4 H2O
|
|
log_k -10.4956
|
|
delta_h -107.5 kJ
|
|
CoFe2O4
|
|
CoFe2O4 + 8 H+ = Co+2 + 2 Fe+3 + 4 H2O
|
|
log_k -3.5281
|
|
delta_h -158.82 kJ
|
|
Magnetite
|
|
Fe3O4 + 8 H+ = 2 Fe+3 + Fe+2 + 4 H2O
|
|
log_k 3.4028
|
|
delta_h -208.526 kJ
|
|
Hercynite
|
|
FeAl2O4 + 8 H+ = Fe+2 + 2 Al+3 + 4 H2O
|
|
log_k 22.893
|
|
delta_h -313.92 kJ
|
|
Hematite
|
|
Fe2O3 + 6 H+ = 2 Fe+3 + 3 H2O
|
|
log_k -1.418
|
|
delta_h -128.987 kJ
|
|
Maghemite
|
|
Fe2O3 + 6 H+ = 2 Fe+3 + 3 H2O
|
|
log_k 6.386
|
|
delta_h -0 kJ
|
|
Lepidocrocite
|
|
FeOOH + 3 H+ = Fe+3 + 2 H2O
|
|
log_k 1.371
|
|
delta_h -0 kJ
|
|
Hausmannite
|
|
Mn3O4 + 8 H+ + 2 e- = 3 Mn+2 + 4 H2O
|
|
log_k 61.03
|
|
delta_h -421 kJ
|
|
Bixbyite
|
|
Mn2O3 + 6 H+ = 2 Mn+3 + 3 H2O
|
|
log_k -0.6445
|
|
delta_h -124.49 kJ
|
|
Cr2O3
|
|
Cr2O3 + H2O + 2 H+ = 2 Cr(OH)2+
|
|
log_k -2.3576
|
|
delta_h -50.731 kJ
|
|
#V2O3
|
|
# V2O3 + 3H+ = V+3 + 1.5H2O
|
|
# log_k 4.9
|
|
# delta_h -82.5085 kJ
|
|
V3O5
|
|
V3O5 + 4 H+ = 3 VO+2 + 2 H2O + 2 e-
|
|
log_k 1.8361
|
|
delta_h -98.46 kJ
|
|
#V2O4
|
|
# V2O4 + 2H+ = VO+2 + H2O
|
|
# log_k 4.27
|
|
# delta_h -58.8689 kJ
|
|
V4O7
|
|
V4O7 + 6 H+ = 4 VO+2 + 3 H2O + 2 e-
|
|
log_k 7.1865
|
|
delta_h -163.89 kJ
|
|
V6O13
|
|
V6O13 + 2 H+ = 6 VO2+ + H2O + 4 e-
|
|
log_k -60.86
|
|
delta_h 271.5 kJ
|
|
V2O5
|
|
V2O5 + 2 H+ = 2 VO2+ + H2O
|
|
log_k -1.36
|
|
delta_h 34 kJ
|
|
U4O9
|
|
U4O9 + 18 H+ + 2 e- = 4 U+4 + 9 H2O
|
|
log_k -3.0198
|
|
delta_h -426.87 kJ
|
|
U3O8
|
|
U3O8 + 16 H+ + 4 e- = 3 U+4 + 8 H2O
|
|
log_k 21.0834
|
|
delta_h -485.44 kJ
|
|
Spinel
|
|
MgAl2O4 + 8 H+ = Mg+2 + 2 Al+3 + 4 H2O
|
|
log_k 36.8476
|
|
delta_h -388.012 kJ
|
|
Magnesioferrite
|
|
Fe2MgO4 + 8 H+ = Mg+2 + 2 Fe+3 + 4 H2O
|
|
log_k 16.8597
|
|
delta_h -278.92 kJ
|
|
Natron
|
|
Na2CO3:10H2O = 2 Na+ + CO3-2 + 10 H2O
|
|
log_k -1.311
|
|
delta_h 65.8771 kJ
|
|
Cuprousferrite
|
|
CuFeO2 + 4 H+ = Cu+ + Fe+3 + 2 H2O
|
|
log_k -8.9171
|
|
delta_h -15.89 kJ
|
|
Cupricferrite
|
|
CuFe2O4 + 8 H+ = Cu+2 + 2 Fe+3 + 4 H2O
|
|
log_k 5.9882
|
|
delta_h -210.21 kJ
|
|
FeCr2O4
|
|
FeCr2O4 + 4 H+ = 2 Cr(OH)2+ + Fe+2
|
|
log_k 7.2003
|
|
delta_h -140.4 kJ
|
|
MgCr2O4
|
|
MgCr2O4 + 4 H+ = 2 Cr(OH)2+ + Mg+2
|
|
log_k 16.2007
|
|
delta_h -179.4 kJ
|
|
SbF3
|
|
SbF3 + 3 H2O = Sb(OH)3 + 3 H+ + 3 F-
|
|
log_k -10.2251
|
|
delta_h -6.7279 kJ
|
|
PbF2
|
|
PbF2 = Pb+2 + 2 F-
|
|
log_k -7.44
|
|
delta_h 20 kJ
|
|
ZnF2
|
|
ZnF2 = Zn+2 + 2 F-
|
|
log_k -0.5343
|
|
delta_h -59.69 kJ
|
|
CdF2
|
|
CdF2 = Cd+2 + 2 F-
|
|
log_k -1.2124
|
|
delta_h -46.22 kJ
|
|
Hg2F2
|
|
Hg2F2 = Hg2+2 + 2 F-
|
|
log_k -10.3623
|
|
delta_h -18.486 kJ
|
|
CuF
|
|
CuF = Cu+ + F-
|
|
log_k -4.9056
|
|
delta_h 16.648 kJ
|
|
CuF2
|
|
CuF2 = Cu+2 + 2 F-
|
|
log_k 1.115
|
|
delta_h -66.901 kJ
|
|
CuF2:2H2O
|
|
CuF2:2H2O = Cu+2 + 2 F- + 2 H2O
|
|
log_k -4.55
|
|
delta_h -15.2716 kJ
|
|
AgF:4H2O
|
|
AgF:4H2O = Ag+ + F- + 4 H2O
|
|
log_k 1.0491
|
|
delta_h 15.4202 kJ
|
|
CoF2
|
|
CoF2 = Co+2 + 2 F-
|
|
log_k -1.5969
|
|
delta_h -57.368 kJ
|
|
CoF3
|
|
CoF3 = Co+3 + 3 F-
|
|
log_k -1.4581
|
|
delta_h -123.692 kJ
|
|
CrF3
|
|
CrF3 + 2 H2O = Cr(OH)2+ + 3 F- + 2 H+
|
|
log_k -11.3367
|
|
delta_h -23.3901 kJ
|
|
VF4
|
|
VF4 + H2O = VO+2 + 4 F- + 2 H+
|
|
log_k 14.93
|
|
delta_h -199.117 kJ
|
|
UF4
|
|
UF4 = U+4 + 4 F-
|
|
log_k -29.5371
|
|
delta_h -79.0776 kJ
|
|
UF4:2.5H2O
|
|
UF4:2.5H2O = U+4 + 4 F- + 2.5 H2O
|
|
log_k -32.7179
|
|
delta_h 24.325 kJ
|
|
MgF2
|
|
MgF2 = Mg+2 + 2 F-
|
|
log_k -8.13
|
|
delta_h -8 kJ
|
|
Fluorite
|
|
CaF2 = Ca+2 + 2 F-
|
|
log_k -10.5
|
|
delta_h 8 kJ
|
|
SrF2
|
|
SrF2 = Sr+2 + 2 F-
|
|
log_k -8.58
|
|
delta_h 4 kJ
|
|
BaF2
|
|
BaF2 = Ba+2 + 2 F-
|
|
log_k -5.82
|
|
delta_h 4 kJ
|
|
Cryolite
|
|
Na3AlF6 = 3 Na+ + Al+3 + 6 F-
|
|
log_k -33.84
|
|
delta_h 38 kJ
|
|
SbCl3
|
|
SbCl3 + 3 H2O = Sb(OH)3 + 3 Cl- + 3 H+
|
|
log_k 0.5719
|
|
delta_h -35.18 kJ
|
|
SnCl2
|
|
SnCl2 + 2 H2O = Sn(OH)2 + 2 H+ + 2 Cl-
|
|
log_k -9.2752
|
|
delta_h -0 kJ
|
|
Cotunnite
|
|
PbCl2 = Pb+2 + 2 Cl-
|
|
log_k -4.78
|
|
delta_h 26.166 kJ
|
|
Matlockite
|
|
PbClF = Pb+2 + Cl- + F-
|
|
log_k -8.9733
|
|
delta_h 33.19 kJ
|
|
Phosgenite
|
|
PbCl2:PbCO3 = 2 Pb+2 + 2 Cl- + CO3-2
|
|
log_k -19.81
|
|
delta_h -0 kJ
|
|
Laurionite
|
|
PbOHCl + H+ = Pb+2 + Cl- + H2O
|
|
log_k 0.623
|
|
delta_h -0 kJ
|
|
Pb2(OH)3Cl
|
|
Pb2(OH)3Cl + 3 H+ = 2 Pb+2 + 3 H2O + Cl-
|
|
log_k 8.793
|
|
delta_h -0 kJ
|
|
TlCl
|
|
TlCl = Tl+ + Cl-
|
|
log_k -3.74
|
|
delta_h 41 kJ
|
|
ZnCl2
|
|
ZnCl2 = Zn+2 + 2 Cl-
|
|
log_k 7.05
|
|
delta_h -72.5 kJ
|
|
Zn2(OH)3Cl
|
|
Zn2(OH)3Cl + 3 H+ = 2 Zn+2 + 3 H2O + Cl-
|
|
log_k 15.191
|
|
delta_h -0 kJ
|
|
Zn5(OH)8Cl2
|
|
Zn5(OH)8Cl2 + 8 H+ = 5 Zn+2 + 8 H2O + 2 Cl-
|
|
log_k 38.5
|
|
delta_h -0 kJ
|
|
CdCl2
|
|
CdCl2 = Cd+2 + 2 Cl-
|
|
log_k -0.6588
|
|
delta_h -18.58 kJ
|
|
CdCl2:1H2O
|
|
CdCl2:H2O = Cd+2 + 2 Cl- + H2O
|
|
log_k -1.6932
|
|
delta_h -7.47 kJ
|
|
CdCl2:2.5H2O
|
|
CdCl2:2.5H2O = Cd+2 + 2 Cl- + 2.5 H2O
|
|
log_k -1.913
|
|
delta_h 7.2849 kJ
|
|
CdOHCl
|
|
CdOHCl + H+ = Cd+2 + H2O + Cl-
|
|
log_k 3.5373
|
|
delta_h -30.93 kJ
|
|
Calomel
|
|
Hg2Cl2 = Hg2+2 + 2 Cl-
|
|
log_k -17.91
|
|
delta_h 92 kJ
|
|
HgCl2
|
|
HgCl2 + 2 H2O = Hg(OH)2 + 2 Cl- + 2 H+
|
|
log_k -21.2621
|
|
delta_h 107.82 kJ
|
|
Nantokite
|
|
CuCl = Cu+ + Cl-
|
|
log_k -6.73
|
|
delta_h 42.662 kJ
|
|
Melanothallite
|
|
CuCl2 = Cu+2 + 2 Cl-
|
|
log_k 6.2572
|
|
delta_h -63.407 kJ
|
|
Atacamite
|
|
Cu2(OH)3Cl + 3 H+ = 2 Cu+2 + 3 H2O + Cl-
|
|
log_k 7.391
|
|
delta_h -93.43 kJ
|
|
Cerargyrite
|
|
AgCl = Ag+ + Cl-
|
|
log_k -9.75
|
|
delta_h 65.2 kJ
|
|
CoCl2
|
|
CoCl2 = Co+2 + 2 Cl-
|
|
log_k 8.2672
|
|
delta_h -79.815 kJ
|
|
CoCl2:6H2O
|
|
CoCl2:6H2O = Co+2 + 2 Cl- + 6 H2O
|
|
log_k 2.5365
|
|
delta_h 8.0598 kJ
|
|
(Co(NH3)6)Cl3
|
|
(Co(NH3)6)Cl3 + 6 H+ = Co+3 + 6 NH4+ + 3 Cl-
|
|
log_k 20.0317
|
|
delta_h -33.1 kJ
|
|
(Co(NH3)5OH2)Cl3
|
|
(Co(NH3)5OH2)Cl3 + 5 H+ = Co+3 + 5 NH4+ + 3 Cl- + H2O
|
|
log_k 11.7351
|
|
delta_h -25.37 kJ
|
|
(Co(NH3)5Cl)Cl2
|
|
(Co(NH3)5Cl)Cl2 + 5 H+ = Co+3 + 5 NH4+ + 3 Cl-
|
|
log_k 4.5102
|
|
delta_h -10.74 kJ
|
|
Fe(OH)2.7Cl.3
|
|
Fe(OH)2.7Cl.3 + 2.7 H+ = Fe+3 + 2.7 H2O + 0.3 Cl-
|
|
log_k -3.04
|
|
delta_h -0 kJ
|
|
MnCl2:4H2O
|
|
MnCl2:4H2O = Mn+2 + 2 Cl- + 4 H2O
|
|
log_k 2.7151
|
|
delta_h -10.83 kJ
|
|
CrCl2
|
|
CrCl2 = Cr+2 + 2 Cl-
|
|
log_k 14.0917
|
|
delta_h -110.76 kJ
|
|
CrCl3
|
|
CrCl3 + 2 H2O = Cr(OH)2+ + 3 Cl- + 2 H+
|
|
log_k 15.1145
|
|
delta_h -121.08 kJ
|
|
VCl2
|
|
VCl2 = V+3 + 2 Cl- + e-
|
|
log_k 18.8744
|
|
delta_h -141.16 kJ
|
|
VCl3
|
|
VCl3 = V+3 + 3 Cl-
|
|
log_k 23.4326
|
|
delta_h -179.54 kJ
|
|
VOCl
|
|
VOCl + 2 H+ = V+3 + Cl- + H2O
|
|
log_k 11.1524
|
|
delta_h -104.91 kJ
|
|
VOCl2
|
|
VOCl2 = VO+2 + 2 Cl-
|
|
log_k 12.7603
|
|
delta_h -117.76 kJ
|
|
VO2Cl
|
|
VO2Cl = VO2+ + Cl-
|
|
log_k 2.8413
|
|
delta_h -40.28 kJ
|
|
Halite
|
|
NaCl = Na+ + Cl-
|
|
log_k 1.6025
|
|
delta_h 3.7 kJ
|
|
SbBr3
|
|
SbBr3 + 3 H2O = Sb(OH)3 + 3 Br- + 3 H+
|
|
log_k 0.9689
|
|
delta_h -20.94 kJ
|
|
SnBr2
|
|
SnBr2 + 2 H2O = Sn(OH)2 + 2 H+ + 2 Br-
|
|
log_k -9.5443
|
|
delta_h -0 kJ
|
|
SnBr4
|
|
SnBr4 + 6 H2O = Sn(OH)6-2 + 6 H+ + 4 Br-
|
|
log_k -28.8468
|
|
delta_h -0 kJ
|
|
PbBr2
|
|
PbBr2 = Pb+2 + 2 Br-
|
|
log_k -5.3
|
|
delta_h 35.499 kJ
|
|
PbBrF
|
|
PbBrF = Pb+2 + Br- + F-
|
|
log_k -8.49
|
|
delta_h -0 kJ
|
|
TlBr
|
|
TlBr = Tl+ + Br-
|
|
log_k -5.44
|
|
delta_h 54 kJ
|
|
ZnBr2:2H2O
|
|
ZnBr2:2H2O = Zn+2 + 2 Br- + 2 H2O
|
|
log_k 5.2005
|
|
delta_h -30.67 kJ
|
|
CdBr2:4H2O
|
|
CdBr2:4H2O = Cd+2 + 2 Br- + 4 H2O
|
|
log_k -2.425
|
|
delta_h 30.5001 kJ
|
|
Hg2Br2
|
|
Hg2Br2 = Hg2+2 + 2 Br-
|
|
log_k -22.25
|
|
delta_h 133 kJ
|
|
HgBr2
|
|
HgBr2 + 2 H2O = Hg(OH)2 + 2 Br- + 2 H+
|
|
log_k -25.2734
|
|
delta_h 138.492 kJ
|
|
CuBr
|
|
CuBr = Cu+ + Br-
|
|
log_k -8.3
|
|
delta_h 54.86 kJ
|
|
Cu2(OH)3Br
|
|
Cu2(OH)3Br + 3 H+ = 2 Cu+2 + 3 H2O + Br-
|
|
log_k 7.9085
|
|
delta_h -93.43 kJ
|
|
Bromyrite
|
|
AgBr = Ag+ + Br-
|
|
log_k -12.3
|
|
delta_h 84.5 kJ
|
|
(Co(NH3)6)Br3
|
|
(Co(NH3)6)Br3 + 6 H+ = Co+3 + 6 NH4+ + 3 Br-
|
|
log_k 18.3142
|
|
delta_h -21.1899 kJ
|
|
(Co(NH3)5Cl)Br2
|
|
(Co(NH3)5Cl)Br2 + 5 H+ = Co+3 + 5 NH4+ + Cl- + 2 Br-
|
|
log_k 5.0295
|
|
delta_h -6.4 kJ
|
|
CrBr3
|
|
CrBr3 + 2 H2O = Cr(OH)2+ + 3 Br- + 2 H+
|
|
log_k 19.9086
|
|
delta_h -141.323 kJ
|
|
AsI3
|
|
AsI3 + 3 H2O = H3AsO3 + 3 I- + 3 H+
|
|
log_k 4.2307
|
|
delta_h 3.15 kJ
|
|
SbI3
|
|
SbI3 + 3 H2O = Sb(OH)3 + 3 H+ + 3 I-
|
|
log_k -0.538
|
|
delta_h 13.5896 kJ
|
|
PbI2
|
|
PbI2 = Pb+2 + 2 I-
|
|
log_k -8.1
|
|
delta_h 62 kJ
|
|
TlI
|
|
TlI = Tl+ + I-
|
|
log_k -7.23
|
|
delta_h 75 kJ
|
|
ZnI2
|
|
ZnI2 = Zn+2 + 2 I-
|
|
log_k 7.3055
|
|
delta_h -58.92 kJ
|
|
CdI2
|
|
CdI2 = Cd+2 + 2 I-
|
|
log_k -3.5389
|
|
delta_h 13.82 kJ
|
|
Hg2I2
|
|
Hg2I2 = Hg2+2 + 2 I-
|
|
log_k -28.34
|
|
delta_h 163 kJ
|
|
Coccinite
|
|
HgI2 + 2 H2O = Hg(OH)2 + 2 H+ + 2 I-
|
|
log_k -34.9525
|
|
delta_h 210.72 kJ
|
|
HgI2:2NH3
|
|
HgI2:2NH3 + 2 H2O = Hg(OH)2 + 2 I- + 2 NH4+
|
|
log_k -16.2293
|
|
delta_h 132.18 kJ
|
|
HgI2:6NH3
|
|
HgI2:6NH3 + 2 H2O + 4 H+ = Hg(OH)2 + 2 I- + 6 NH4+
|
|
log_k 33.7335
|
|
delta_h -90.3599 kJ
|
|
CuI
|
|
CuI = Cu+ + I-
|
|
log_k -12
|
|
delta_h 82.69 kJ
|
|
Iodyrite
|
|
AgI = Ag+ + I-
|
|
log_k -16.08
|
|
delta_h 110 kJ
|
|
(Co(NH3)6)I3
|
|
(Co(NH3)6)I3 + 6 H+ = Co+3 + 6 NH4+ + 3 I-
|
|
log_k 16.5831
|
|
delta_h -9.6999 kJ
|
|
(Co(NH3)5Cl)I2
|
|
(Co(NH3)5Cl)I2 + 5 H+ = Co+3 + 5 NH4+ + Cl- + 2 I-
|
|
log_k 5.5981
|
|
delta_h 0.66 kJ
|
|
CrI3
|
|
CrI3 + 2 H2O = Cr(OH)2+ + 3 I- + 2 H+
|
|
log_k 20.4767
|
|
delta_h -134.419 kJ
|
|
Cerussite
|
|
PbCO3 = Pb+2 + CO3-2
|
|
log_k -13.13
|
|
delta_h 24.79 kJ
|
|
Pb2OCO3
|
|
Pb2OCO3 + 2 H+ = 2 Pb+2 + H2O + CO3-2
|
|
log_k -0.5578
|
|
delta_h -40.8199 kJ
|
|
Pb3O2CO3
|
|
Pb3O2CO3 + 4 H+ = 3 Pb+2 + CO3-2 + 2 H2O
|
|
log_k 11.02
|
|
delta_h -110.583 kJ
|
|
Hydrocerussite
|
|
Pb3(OH)2(CO3)2 + 2 H+ = 3 Pb+2 + 2 H2O + 2 CO3-2
|
|
log_k -18.7705
|
|
delta_h -0 kJ
|
|
Pb10(OH)6O(CO3)6
|
|
Pb10(OH)6O(CO3)6 + 8 H+ = 10 Pb+2 + 6 CO3-2 + 7 H2O
|
|
log_k -8.76
|
|
delta_h -0 kJ
|
|
Tl2CO3
|
|
Tl2CO3 = 2 Tl+ + CO3-2
|
|
log_k -3.8367
|
|
delta_h 35.49 kJ
|
|
Smithsonite
|
|
ZnCO3 = Zn+2 + CO3-2
|
|
log_k -10
|
|
delta_h -15.84 kJ
|
|
ZnCO3:1H2O
|
|
ZnCO3:H2O = Zn+2 + CO3-2 + H2O
|
|
log_k -10.26
|
|
delta_h -0 kJ
|
|
Otavite
|
|
CdCO3 = Cd+2 + CO3-2
|
|
log_k -12
|
|
delta_h -0.55 kJ
|
|
Hg2CO3
|
|
Hg2CO3 = Hg2+2 + CO3-2
|
|
log_k -16.05
|
|
delta_h 45.14 kJ
|
|
Hg3O2CO3
|
|
Hg3O2CO3 + 4 H2O = 3 Hg(OH)2 + 2 H+ + CO3-2
|
|
log_k -29.682
|
|
delta_h -0 kJ
|
|
CuCO3
|
|
CuCO3 = Cu+2 + CO3-2
|
|
log_k -11.5
|
|
delta_h -0 kJ
|
|
Malachite
|
|
Cu2(OH)2CO3 + 2 H+ = 2 Cu+2 + 2 H2O + CO3-2
|
|
log_k -5.306
|
|
delta_h 76.38 kJ
|
|
Azurite
|
|
Cu3(OH)2(CO3)2 + 2 H+ = 3 Cu+2 + 2 H2O + 2 CO3-2
|
|
log_k -16.906
|
|
delta_h -95.22 kJ
|
|
Ag2CO3
|
|
Ag2CO3 = 2 Ag+ + CO3-2
|
|
log_k -11.09
|
|
delta_h 42.15 kJ
|
|
NiCO3
|
|
NiCO3 = Ni+2 + CO3-2
|
|
log_k -6.87
|
|
delta_h -41.589 kJ
|
|
CoCO3
|
|
CoCO3 = Co+2 + CO3-2
|
|
log_k -9.98
|
|
delta_h -12.7612 kJ
|
|
Siderite
|
|
FeCO3 = Fe+2 + CO3-2
|
|
log_k -10.24
|
|
delta_h -16 kJ
|
|
Rhodochrosite
|
|
MnCO3 = Mn+2 + CO3-2
|
|
log_k -10.58
|
|
delta_h -1.88 kJ
|
|
Rutherfordine
|
|
UO2CO3 = UO2+2 + CO3-2
|
|
log_k -14.5
|
|
delta_h -3.03 kJ
|
|
Artinite
|
|
MgCO3:Mg(OH)2:3H2O + 2 H+ = 2 Mg+2 + CO3-2 + 5 H2O
|
|
log_k 9.6
|
|
delta_h -120.257 kJ
|
|
Hydromagnesite
|
|
Mg5(CO3)4(OH)2:4H2O + 2 H+ = 5 Mg+2 + 4 CO3-2 + 6 H2O
|
|
log_k -8.766
|
|
delta_h -218.447 kJ
|
|
Magnesite
|
|
MgCO3 = Mg+2 + CO3-2
|
|
log_k -7.46
|
|
delta_h 20 kJ
|
|
Nesquehonite
|
|
MgCO3:3H2O = Mg+2 + CO3-2 + 3 H2O
|
|
log_k -4.67
|
|
delta_h -24.2212 kJ
|
|
Aragonite
|
|
CaCO3 = Ca+2 + CO3-2
|
|
log_k -8.3
|
|
delta_h -12 kJ
|
|
Calcite
|
|
CaCO3 = Ca+2 + CO3-2
|
|
log_k -8.48
|
|
delta_h -8 kJ
|
|
Dolomite(ordered)
|
|
CaMg(CO3)2 = Ca+2 + Mg+2 + 2 CO3-2
|
|
log_k -17.09
|
|
delta_h -39.5 kJ
|
|
Dolomite(disordered)
|
|
CaMg(CO3)2 = Ca+2 + Mg+2 + 2 CO3-2
|
|
log_k -16.54
|
|
delta_h -46.4 kJ
|
|
Huntite
|
|
CaMg3(CO3)4 = 3 Mg+2 + Ca+2 + 4 CO3-2
|
|
log_k -29.968
|
|
delta_h -107.78 kJ
|
|
Strontianite
|
|
SrCO3 = Sr+2 + CO3-2
|
|
log_k -9.27
|
|
delta_h -0 kJ
|
|
Witherite
|
|
BaCO3 = Ba+2 + CO3-2
|
|
log_k -8.57
|
|
delta_h 4 kJ
|
|
Thermonatrite
|
|
Na2CO3:H2O = 2 Na+ + CO3-2 + H2O
|
|
log_k 0.637
|
|
delta_h -10.4799 kJ
|
|
TlNO3
|
|
TlNO3 = Tl+ + NO3-
|
|
log_k -1.6127
|
|
delta_h 42.44 kJ
|
|
Zn(NO3)2:6H2O
|
|
Zn(NO3)2:6H2O = Zn+2 + 2 NO3- + 6 H2O
|
|
log_k 3.3153
|
|
delta_h 24.5698 kJ
|
|
Cu2(OH)3NO3
|
|
Cu2(OH)3NO3 + 3 H+ = 2 Cu+2 + 3 H2O + NO3-
|
|
log_k 9.251
|
|
delta_h -72.5924 kJ
|
|
(Co(NH3)6)(NO3)3
|
|
(Co(NH3)6)(NO3)3 + 6 H+ = Co+3 + 6 NH4+ + 3 NO3-
|
|
log_k 17.9343
|
|
delta_h 1.59 kJ
|
|
(Co(NH3)5Cl)(NO3)2
|
|
(Co(NH3)5Cl)(NO3)2 + 5 H+ = Co+3 + 5 NH4+ + Cl- + 2 NO3-
|
|
log_k 6.2887
|
|
delta_h 6.4199 kJ
|
|
UO2(NO3)2
|
|
UO2(NO3)2 = UO2+2 + 2 NO3-
|
|
log_k 12.1476
|
|
delta_h -83.3999 kJ
|
|
UO2(NO3)2:2H2O
|
|
UO2(NO3)2:2H2O = UO2+2 + 2 NO3- + 2 H2O
|
|
log_k 4.851
|
|
delta_h -25.355 kJ
|
|
UO2(NO3)2:3H2O
|
|
UO2(NO3)2:3H2O = UO2+2 + 2 NO3- + 3 H2O
|
|
log_k 3.39
|
|
delta_h -9.1599 kJ
|
|
UO2(NO3)2:6H2O
|
|
UO2(NO3)2:6H2O = UO2+2 + 2 NO3- + 6 H2O
|
|
log_k 2.0464
|
|
delta_h 20.8201 kJ
|
|
Pb(BO2)2
|
|
Pb(BO2)2 + 2 H2O + 2 H+ = Pb+2 + 2 H3BO3
|
|
log_k 6.5192
|
|
delta_h -15.6119 kJ
|
|
Zn(BO2)2
|
|
Zn(BO2)2 + 2 H2O + 2 H+ = Zn+2 + 2 H3BO3
|
|
log_k 8.29
|
|
delta_h -0 kJ
|
|
Cd(BO2)2
|
|
Cd(BO2)2 + 2 H2O + 2 H+ = Cd+2 + 2 H3BO3
|
|
log_k 9.84
|
|
delta_h -0 kJ
|
|
Co(BO2)2
|
|
Co(BO2)2 + 2 H2O + 2 H+ = Co+2 + 2 H3BO3
|
|
log_k 27.0703
|
|
delta_h -0 kJ
|
|
SnSO4
|
|
SnSO4 + 2 H2O = Sn(OH)2 + 2 H+ + SO4-2
|
|
log_k -56.9747
|
|
delta_h -0 kJ
|
|
Sn(SO4)2
|
|
Sn(SO4)2 + 6 H2O = Sn(OH)6-2 + 6 H+ + 2 SO4-2
|
|
log_k -15.2123
|
|
delta_h -0 kJ
|
|
Larnakite
|
|
PbO:PbSO4 + 2 H+ = 2 Pb+2 + SO4-2 + H2O
|
|
log_k -0.4344
|
|
delta_h -21.83 kJ
|
|
Pb3O2SO4
|
|
Pb3O2SO4 + 4 H+ = 3 Pb+2 + SO4-2 + 2 H2O
|
|
log_k 10.6864
|
|
delta_h -79.14 kJ
|
|
Pb4O3SO4
|
|
Pb4O3SO4 + 6 H+ = 4 Pb+2 + SO4-2 + 3 H2O
|
|
log_k 21.8772
|
|
delta_h -136.45 kJ
|
|
Anglesite
|
|
PbSO4 = Pb+2 + SO4-2
|
|
log_k -7.79
|
|
delta_h 12 kJ
|
|
Pb4(OH)6SO4
|
|
Pb4(OH)6SO4 + 6 H+ = 4 Pb+2 + SO4-2 + 6 H2O
|
|
log_k 21.1
|
|
delta_h -0 kJ
|
|
AlOHSO4
|
|
AlOHSO4 + H+ = Al+3 + SO4-2 + H2O
|
|
log_k -3.23
|
|
delta_h -0 kJ
|
|
Al4(OH)10SO4
|
|
Al4(OH)10SO4 + 10 H+ = 4 Al+3 + SO4-2 + 10 H2O
|
|
log_k 22.7
|
|
delta_h -0 kJ
|
|
Tl2SO4
|
|
Tl2SO4 = 2 Tl+ + SO4-2
|
|
log_k -3.7868
|
|
delta_h 33.1799 kJ
|
|
Zn2(OH)2SO4
|
|
Zn2(OH)2SO4 + 2 H+ = 2 Zn+2 + 2 H2O + SO4-2
|
|
log_k 7.5
|
|
delta_h -0 kJ
|
|
Zn4(OH)6SO4
|
|
Zn4(OH)6SO4 + 6 H+ = 4 Zn+2 + 6 H2O + SO4-2
|
|
log_k 28.4
|
|
delta_h -0 kJ
|
|
Zn3O(SO4)2
|
|
Zn3O(SO4)2 + 2 H+ = 3 Zn+2 + 2 SO4-2 + H2O
|
|
log_k 18.9135
|
|
delta_h -258.08 kJ
|
|
Zincosite
|
|
ZnSO4 = Zn+2 + SO4-2
|
|
log_k 3.9297
|
|
delta_h -82.586 kJ
|
|
ZnSO4:1H2O
|
|
ZnSO4:H2O = Zn+2 + SO4-2 + H2O
|
|
log_k -0.638
|
|
delta_h -44.0699 kJ
|
|
Bianchite
|
|
ZnSO4:6H2O = Zn+2 + SO4-2 + 6 H2O
|
|
log_k -1.765
|
|
delta_h -0.6694 kJ
|
|
Goslarite
|
|
ZnSO4:7H2O = Zn+2 + SO4-2 + 7 H2O
|
|
log_k -2.0112
|
|
delta_h 14.21 kJ
|
|
Cd3(OH)4SO4
|
|
Cd3(OH)4SO4 + 4 H+ = 3 Cd+2 + 4 H2O + SO4-2
|
|
log_k 22.56
|
|
delta_h -0 kJ
|
|
Cd3(OH)2(SO4)2
|
|
Cd3(OH)2(SO4)2 + 2 H+ = 3 Cd+2 + 2 H2O + 2 SO4-2
|
|
log_k 6.71
|
|
delta_h -0 kJ
|
|
Cd4(OH)6SO4
|
|
Cd4(OH)6SO4 + 6 H+ = 4 Cd+2 + 6 H2O + SO4-2
|
|
log_k 28.4
|
|
delta_h -0 kJ
|
|
CdSO4
|
|
CdSO4 = Cd+2 + SO4-2
|
|
log_k -0.1722
|
|
delta_h -51.98 kJ
|
|
CdSO4:1H2O
|
|
CdSO4:H2O = Cd+2 + SO4-2 + H2O
|
|
log_k -1.7261
|
|
delta_h -31.5399 kJ
|
|
CdSO4:2.67H2O
|
|
CdSO4:2.67H2O = Cd+2 + SO4-2 + 2.67 H2O
|
|
log_k -1.873
|
|
delta_h -17.9912 kJ
|
|
Hg2SO4
|
|
Hg2SO4 = Hg2+2 + SO4-2
|
|
log_k -6.13
|
|
delta_h 5.4 kJ
|
|
HgSO4
|
|
HgSO4 + 2 H2O = Hg(OH)2 + SO4-2 + 2 H+
|
|
log_k -9.4189
|
|
delta_h 14.6858 kJ
|
|
Cu2SO4
|
|
Cu2SO4 = 2 Cu+ + SO4-2
|
|
log_k -1.95
|
|
delta_h -19.079 kJ
|
|
Antlerite
|
|
Cu3(OH)4SO4 + 4 H+ = 3 Cu+2 + 4 H2O + SO4-2
|
|
log_k 8.788
|
|
delta_h -0 kJ
|
|
Brochantite
|
|
Cu4(OH)6SO4 + 6 H+ = 4 Cu+2 + 6 H2O + SO4-2
|
|
log_k 15.222
|
|
delta_h -202.86 kJ
|
|
Langite
|
|
Cu4(OH)6SO4:H2O + 6 H+ = 4 Cu+2 + 7 H2O + SO4-2
|
|
log_k 17.4886
|
|
delta_h -165.55 kJ
|
|
CuOCuSO4
|
|
CuOCuSO4 + 2 H+ = 2 Cu+2 + H2O + SO4-2
|
|
log_k 10.3032
|
|
delta_h -137.777 kJ
|
|
CuSO4
|
|
CuSO4 = Cu+2 + SO4-2
|
|
log_k 2.9395
|
|
delta_h -73.04 kJ
|
|
Chalcanthite
|
|
CuSO4:5H2O = Cu+2 + SO4-2 + 5 H2O
|
|
log_k -2.64
|
|
delta_h 6.025 kJ
|
|
Ag2SO4
|
|
Ag2SO4 = 2 Ag+ + SO4-2
|
|
log_k -4.82
|
|
delta_h 17 kJ
|
|
Ni4(OH)6SO4
|
|
Ni4(OH)6SO4 + 6 H+ = 4 Ni+2 + SO4-2 + 6 H2O
|
|
log_k 32
|
|
delta_h -0 kJ
|
|
Retgersite
|
|
NiSO4:6H2O = Ni+2 + SO4-2 + 6 H2O
|
|
log_k -2.04
|
|
delta_h 4.6024 kJ
|
|
Morenosite
|
|
NiSO4:7H2O = Ni+2 + SO4-2 + 7 H2O
|
|
log_k -2.1449
|
|
delta_h 12.1802 kJ
|
|
CoSO4
|
|
CoSO4 = Co+2 + SO4-2
|
|
log_k 2.8024
|
|
delta_h -79.277 kJ
|
|
CoSO4:6H2O
|
|
CoSO4:6H2O = Co+2 + SO4-2 + 6 H2O
|
|
log_k -2.4726
|
|
delta_h 1.0801 kJ
|
|
Melanterite
|
|
FeSO4:7H2O = Fe+2 + SO4-2 + 7 H2O
|
|
log_k -2.209
|
|
delta_h 20.5 kJ
|
|
Fe2(SO4)3
|
|
Fe2(SO4)3 = 2 Fe+3 + 3 SO4-2
|
|
log_k -3.7343
|
|
delta_h -242.028 kJ
|
|
H-Jarosite
|
|
(H3O)Fe3(SO4)2(OH)6 + 5 H+ = 3 Fe+3 + 2 SO4-2 + 7 H2O
|
|
log_k -12.1
|
|
delta_h -230.748 kJ
|
|
Na-Jarosite
|
|
NaFe3(SO4)2(OH)6 + 6 H+ = Na+ + 3 Fe+3 + 2 SO4-2 + 6 H2O
|
|
log_k -11.2
|
|
delta_h -151.377 kJ
|
|
K-Jarosite
|
|
KFe3(SO4)2(OH)6 + 6 H+ = K+ + 3 Fe+3 + 2 SO4-2 + 6 H2O
|
|
log_k -14.8
|
|
delta_h -130.875 kJ
|
|
MnSO4
|
|
MnSO4 = Mn+2 + SO4-2
|
|
log_k 2.5831
|
|
delta_h -64.8401 kJ
|
|
Mn2(SO4)3
|
|
Mn2(SO4)3 = 2 Mn+3 + 3 SO4-2
|
|
log_k -5.711
|
|
delta_h -163.427 kJ
|
|
VOSO4
|
|
VOSO4 = VO+2 + SO4-2
|
|
log_k 3.6097
|
|
delta_h -86.7401 kJ
|
|
Epsomite
|
|
MgSO4:7H2O = Mg+2 + SO4-2 + 7 H2O
|
|
log_k -2.1265
|
|
delta_h 11.5601 kJ
|
|
Anhydrite
|
|
CaSO4 = Ca+2 + SO4-2
|
|
log_k -4.36
|
|
delta_h -7.2 kJ
|
|
Gypsum
|
|
CaSO4:2H2O = Ca+2 + SO4-2 + 2 H2O
|
|
log_k -4.61
|
|
delta_h 1 kJ
|
|
Celestite
|
|
SrSO4 = Sr+2 + SO4-2
|
|
log_k -6.62
|
|
delta_h 2 kJ
|
|
Barite
|
|
BaSO4 = Ba+2 + SO4-2
|
|
log_k -9.98
|
|
delta_h 23 kJ
|
|
Mirabilite
|
|
Na2SO4:10H2O = 2 Na+ + SO4-2 + 10 H2O
|
|
log_k -1.114
|
|
delta_h 79.4416 kJ
|
|
Thenardite
|
|
Na2SO4 = 2 Na+ + SO4-2
|
|
log_k 0.3217
|
|
delta_h -9.121 kJ
|
|
K-Alum
|
|
KAl(SO4)2:12H2O = K+ + Al+3 + 2 SO4-2 + 12 H2O
|
|
log_k -5.17
|
|
delta_h 30.2085 kJ
|
|
Alunite
|
|
KAl3(SO4)2(OH)6 + 6 H+ = K+ + 3 Al+3 + 2 SO4-2 + 6 H2O
|
|
log_k -1.4
|
|
delta_h -210 kJ
|
|
(NH4)2CrO4
|
|
(NH4)2CrO4 = CrO4-2 + 2 NH4+
|
|
log_k 0.4046
|
|
delta_h 9.163 kJ
|
|
PbCrO4
|
|
PbCrO4 = Pb+2 + CrO4-2
|
|
log_k -12.6
|
|
delta_h 44.18 kJ
|
|
Tl2CrO4
|
|
Tl2CrO4 = 2 Tl+ + CrO4-2
|
|
log_k -12.01
|
|
delta_h 74.27 kJ
|
|
Hg2CrO4
|
|
Hg2CrO4 = Hg2+2 + CrO4-2
|
|
log_k -8.7
|
|
delta_h -0 kJ
|
|
CuCrO4
|
|
CuCrO4 = Cu+2 + CrO4-2
|
|
log_k -5.44
|
|
delta_h -0 kJ
|
|
Ag2CrO4
|
|
Ag2CrO4 = 2 Ag+ + CrO4-2
|
|
log_k -11.59
|
|
delta_h 62 kJ
|
|
MgCrO4
|
|
MgCrO4 = CrO4-2 + Mg+2
|
|
log_k 5.3801
|
|
delta_h -88.9518 kJ
|
|
CaCrO4
|
|
CaCrO4 = Ca+2 + CrO4-2
|
|
log_k -2.2657
|
|
delta_h -26.945 kJ
|
|
SrCrO4
|
|
SrCrO4 = Sr+2 + CrO4-2
|
|
log_k -4.65
|
|
delta_h -10.1253 kJ
|
|
BaCrO4
|
|
BaCrO4 = Ba+2 + CrO4-2
|
|
log_k -9.67
|
|
delta_h 33 kJ
|
|
Li2CrO4
|
|
Li2CrO4 = CrO4-2 + 2 Li+
|
|
log_k 4.8568
|
|
delta_h -45.2792 kJ
|
|
Na2CrO4
|
|
Na2CrO4 = CrO4-2 + 2 Na+
|
|
log_k 2.9302
|
|
delta_h -19.6301 kJ
|
|
Na2Cr2O7
|
|
Na2Cr2O7 + H2O = 2 CrO4-2 + 2 Na+ + 2 H+
|
|
log_k -9.8953
|
|
delta_h 22.1961 kJ
|
|
K2CrO4
|
|
K2CrO4 = CrO4-2 + 2 K+
|
|
log_k -0.5134
|
|
delta_h 18.2699 kJ
|
|
K2Cr2O7
|
|
K2Cr2O7 + H2O = 2 CrO4-2 + 2 K+ + 2 H+
|
|
log_k -17.2424
|
|
delta_h 80.7499 kJ
|
|
Hg2SeO3
|
|
Hg2SeO3 + H+ = Hg2+2 + HSeO3-
|
|
log_k -4.657
|
|
delta_h -0 kJ
|
|
HgSeO3
|
|
HgSeO3 + 2 H2O = Hg(OH)2 + H+ + HSeO3-
|
|
log_k -12.43
|
|
delta_h -0 kJ
|
|
Ag2SeO3
|
|
Ag2SeO3 + H+ = 2 Ag+ + HSeO3-
|
|
log_k -7.15
|
|
delta_h 39.68 kJ
|
|
CuSeO3:2H2O
|
|
CuSeO3:2H2O + H+ = Cu+2 + HSeO3- + 2 H2O
|
|
log_k 0.5116
|
|
delta_h -36.861 kJ
|
|
NiSeO3:2H2O
|
|
NiSeO3:2H2O + H+ = HSeO3- + Ni+2 + 2 H2O
|
|
log_k 2.8147
|
|
delta_h -31.0034 kJ
|
|
CoSeO3
|
|
CoSeO3 + H+ = Co+2 + HSeO3-
|
|
log_k 1.32
|
|
delta_h -0 kJ
|
|
Fe2(SeO3)3:2H2O
|
|
Fe2(SeO3)3:2H2O + 3 H+ = 3 HSeO3- + 2 Fe+3 + 2 H2O
|
|
log_k -20.6262
|
|
delta_h -0 kJ
|
|
Fe2(OH)4SeO3
|
|
Fe2(OH)4SeO3 + 5 H+ = HSeO3- + 2 Fe+3 + 4 H2O
|
|
log_k 1.5539
|
|
delta_h -0 kJ
|
|
MnSeO3
|
|
MnSeO3 + H+ = Mn+2 + HSeO3-
|
|
log_k 1.13
|
|
delta_h -0 kJ
|
|
MnSeO3:2H2O
|
|
MnSeO3:2H2O + H+ = HSeO3- + Mn+2 + 2 H2O
|
|
log_k 0.9822
|
|
delta_h 8.4935 kJ
|
|
MgSeO3:6H2O
|
|
MgSeO3:6H2O + H+ = Mg+2 + HSeO3- + 6 H2O
|
|
log_k 3.0554
|
|
delta_h 5.23 kJ
|
|
CaSeO3:2H2O
|
|
CaSeO3:2H2O + H+ = HSeO3- + Ca+2 + 2 H2O
|
|
log_k 2.8139
|
|
delta_h -19.4556 kJ
|
|
SrSeO3
|
|
SrSeO3 + H+ = Sr+2 + HSeO3-
|
|
log_k 2.3
|
|
delta_h -0 kJ
|
|
BaSeO3
|
|
BaSeO3 + H+ = Ba+2 + HSeO3-
|
|
log_k 1.83
|
|
delta_h 11.98 kJ
|
|
Na2SeO3:5H2O
|
|
Na2SeO3:5H2O + H+ = 2 Na+ + HSeO3- + 5 H2O
|
|
log_k 10.3
|
|
delta_h -0 kJ
|
|
PbSeO4
|
|
PbSeO4 = Pb+2 + SeO4-2
|
|
log_k -6.84
|
|
delta_h 15 kJ
|
|
Tl2SeO4
|
|
Tl2SeO4 = 2 Tl+ + SeO4-2
|
|
log_k -4.1
|
|
delta_h 43 kJ
|
|
ZnSeO4:6H2O
|
|
ZnSeO4:6H2O = Zn+2 + SeO4-2 + 6 H2O
|
|
log_k -1.52
|
|
delta_h -0 kJ
|
|
CdSeO4:2H2O
|
|
CdSeO4:2H2O = Cd+2 + SeO4-2 + 2 H2O
|
|
log_k -1.85
|
|
delta_h -0 kJ
|
|
Ag2SeO4
|
|
Ag2SeO4 = 2 Ag+ + SeO4-2
|
|
log_k -8.91
|
|
delta_h -43.5 kJ
|
|
CuSeO4:5H2O
|
|
CuSeO4:5H2O = Cu+2 + SeO4-2 + 5 H2O
|
|
log_k -2.44
|
|
delta_h -0 kJ
|
|
NiSeO4:6H2O
|
|
NiSeO4:6H2O = Ni+2 + SeO4-2 + 6 H2O
|
|
log_k -1.52
|
|
delta_h -0 kJ
|
|
CoSeO4:6H2O
|
|
CoSeO4:6H2O = Co+2 + SeO4-2 + 6 H2O
|
|
log_k -1.53
|
|
delta_h -0 kJ
|
|
MnSeO4:5H2O
|
|
MnSeO4:5H2O = Mn+2 + SeO4-2 + 5 H2O
|
|
log_k -2.05
|
|
delta_h -0 kJ
|
|
UO2SeO4:4H2O
|
|
UO2SeO4:4H2O = UO2+2 + SeO4-2 + 4 H2O
|
|
log_k -2.25
|
|
delta_h -0 kJ
|
|
MgSeO4:6H2O
|
|
MgSeO4:6H2O = Mg+2 + SeO4-2 + 6 H2O
|
|
log_k -1.2
|
|
delta_h -0 kJ
|
|
CaSeO4:2H2O
|
|
CaSeO4:2H2O = Ca+2 + SeO4-2 + 2 H2O
|
|
log_k -3.02
|
|
delta_h -8.3 kJ
|
|
SrSeO4
|
|
SrSeO4 = Sr+2 + SeO4-2
|
|
log_k -4.4
|
|
delta_h 0.4 kJ
|
|
BaSeO4
|
|
BaSeO4 = Ba+2 + SeO4-2
|
|
log_k -7.46
|
|
delta_h 22 kJ
|
|
BeSeO4:4H2O
|
|
BeSeO4:4H2O = Be+2 + SeO4-2 + 4 H2O
|
|
log_k -2.94
|
|
delta_h -0 kJ
|
|
Na2SeO4
|
|
Na2SeO4 = 2 Na+ + SeO4-2
|
|
log_k 1.28
|
|
delta_h -0 kJ
|
|
K2SeO4
|
|
K2SeO4 = 2 K+ + SeO4-2
|
|
log_k -0.73
|
|
delta_h -0 kJ
|
|
(NH4)2SeO4
|
|
(NH4)2SeO4 = 2 NH4+ + SeO4-2
|
|
log_k 0.45
|
|
delta_h -0 kJ
|
|
H2MoO4
|
|
H2MoO4 = MoO4-2 + 2 H+
|
|
log_k -12.8765
|
|
delta_h 49 kJ
|
|
PbMoO4
|
|
PbMoO4 = Pb+2 + MoO4-2
|
|
log_k -15.62
|
|
delta_h 53.93 kJ
|
|
Al2(MoO4)3
|
|
Al2(MoO4)3 = 3 MoO4-2 + 2 Al+3
|
|
log_k 2.3675
|
|
delta_h -260.8 kJ
|
|
Tl2MoO4
|
|
Tl2MoO4 = MoO4-2 + 2 Tl+
|
|
log_k -7.9887
|
|
delta_h -0 kJ
|
|
ZnMoO4
|
|
ZnMoO4 = MoO4-2 + Zn+2
|
|
log_k -10.1254
|
|
delta_h -10.6901 kJ
|
|
CdMoO4
|
|
CdMoO4 = MoO4-2 + Cd+2
|
|
log_k -14.1497
|
|
delta_h 19.48 kJ
|
|
CuMoO4
|
|
CuMoO4 = MoO4-2 + Cu+2
|
|
log_k -13.0762
|
|
delta_h 12.2 kJ
|
|
Ag2MoO4
|
|
Ag2MoO4 = 2 Ag+ + MoO4-2
|
|
log_k -11.55
|
|
delta_h 52.7 kJ
|
|
NiMoO4
|
|
NiMoO4 = MoO4-2 + Ni+2
|
|
log_k -11.1421
|
|
delta_h 1.3 kJ
|
|
CoMoO4
|
|
CoMoO4 = MoO4-2 + Co+2
|
|
log_k -7.7609
|
|
delta_h -23.3999 kJ
|
|
FeMoO4
|
|
FeMoO4 = MoO4-2 + Fe+2
|
|
log_k -10.091
|
|
delta_h -11.1 kJ
|
|
BeMoO4
|
|
BeMoO4 = MoO4-2 + Be+2
|
|
log_k -1.7817
|
|
delta_h -56.4 kJ
|
|
MgMoO4
|
|
MgMoO4 = Mg+2 + MoO4-2
|
|
log_k -1.85
|
|
delta_h -0 kJ
|
|
CaMoO4
|
|
CaMoO4 = Ca+2 + MoO4-2
|
|
log_k -7.95
|
|
delta_h -2 kJ
|
|
BaMoO4
|
|
BaMoO4 = MoO4-2 + Ba+2
|
|
log_k -6.9603
|
|
delta_h 10.96 kJ
|
|
Li2MoO4
|
|
Li2MoO4 = MoO4-2 + 2 Li+
|
|
log_k 2.4416
|
|
delta_h -33.9399 kJ
|
|
Na2MoO4
|
|
Na2MoO4 = MoO4-2 + 2 Na+
|
|
log_k 1.4901
|
|
delta_h -9.98 kJ
|
|
Na2MoO4:2H2O
|
|
Na2MoO4:2H2O = MoO4-2 + 2 Na+ + 2 H2O
|
|
log_k 1.224
|
|
delta_h -0 kJ
|
|
Na2Mo2O7
|
|
Na2Mo2O7 + H2O = 2 MoO4-2 + 2 Na+ + 2 H+
|
|
log_k -16.5966
|
|
delta_h 56.2502 kJ
|
|
K2MoO4
|
|
K2MoO4 = MoO4-2 + 2 K+
|
|
log_k 3.2619
|
|
delta_h -3.38 kJ
|
|
PbHPO4
|
|
PbHPO4 = Pb+2 + H+ + PO4-3
|
|
log_k -23.805
|
|
delta_h -0 kJ
|
|
Pb3(PO4)2
|
|
Pb3(PO4)2 = 3 Pb+2 + 2 PO4-3
|
|
log_k -43.53
|
|
delta_h -0 kJ
|
|
Pyromorphite
|
|
Pb5(PO4)3Cl = 5 Pb+2 + 3 PO4-3 + Cl-
|
|
log_k -84.43
|
|
delta_h -0 kJ
|
|
Hydroxylpyromorphite
|
|
Pb5(PO4)3OH + H+ = 5 Pb+2 + 3 PO4-3 + H2O
|
|
log_k -62.79
|
|
delta_h -0 kJ
|
|
Plumbgummite
|
|
PbAl3(PO4)2(OH)5:H2O + 5 H+ = Pb+2 + 3 Al+3 + 2 PO4-3 + 6 H2O
|
|
log_k -32.79
|
|
delta_h -0 kJ
|
|
Hinsdalite
|
|
PbAl3PO4SO4(OH)6 + 6 H+ = Pb+2 + 3 Al+3 + PO4-3 + SO4-2 + 6 H2O
|
|
log_k -2.5
|
|
delta_h -0 kJ
|
|
Tsumebite
|
|
Pb2CuPO4(OH)3:3H2O + 3 H+ = 2 Pb+2 + Cu+2 + PO4-3 + 6 H2O
|
|
log_k -9.79
|
|
delta_h -0 kJ
|
|
Zn3(PO4)2:4H2O
|
|
Zn3(PO4)2:4H2O = 3 Zn+2 + 2 PO4-3 + 4 H2O
|
|
log_k -35.42
|
|
delta_h -0 kJ
|
|
Cd3(PO4)2
|
|
Cd3(PO4)2 = 3 Cd+2 + 2 PO4-3
|
|
log_k -32.6
|
|
delta_h -0 kJ
|
|
Hg2HPO4
|
|
Hg2HPO4 = Hg2+2 + H+ + PO4-3
|
|
log_k -24.775
|
|
delta_h -0 kJ
|
|
Cu3(PO4)2
|
|
Cu3(PO4)2 = 3 Cu+2 + 2 PO4-3
|
|
log_k -36.85
|
|
delta_h -0 kJ
|
|
Cu3(PO4)2:3H2O
|
|
Cu3(PO4)2:3H2O = 3 Cu+2 + 2 PO4-3 + 3 H2O
|
|
log_k -35.12
|
|
delta_h -0 kJ
|
|
Ag3PO4
|
|
Ag3PO4 = 3 Ag+ + PO4-3
|
|
log_k -17.59
|
|
delta_h -0 kJ
|
|
Ni3(PO4)2
|
|
Ni3(PO4)2 = 3 Ni+2 + 2 PO4-3
|
|
log_k -31.3
|
|
delta_h -0 kJ
|
|
CoHPO4
|
|
CoHPO4 = Co+2 + PO4-3 + H+
|
|
log_k -19.0607
|
|
delta_h -0 kJ
|
|
Co3(PO4)2
|
|
Co3(PO4)2 = 3 Co+2 + 2 PO4-3
|
|
log_k -34.6877
|
|
delta_h -0 kJ
|
|
Vivianite
|
|
Fe3(PO4)2:8H2O = 3 Fe+2 + 2 PO4-3 + 8 H2O
|
|
log_k -36
|
|
delta_h -0 kJ
|
|
Strengite
|
|
FePO4:2H2O = Fe+3 + PO4-3 + 2 H2O
|
|
log_k -26.4
|
|
delta_h -9.3601 kJ
|
|
Mn3(PO4)2
|
|
Mn3(PO4)2 = 3 Mn+2 + 2 PO4-3
|
|
log_k -23.827
|
|
delta_h 8.8701 kJ
|
|
MnHPO4
|
|
MnHPO4 = Mn+2 + PO4-3 + H+
|
|
log_k -25.4
|
|
delta_h -0 kJ
|
|
(VO)3(PO4)2
|
|
(VO)3(PO4)2 = 3 VO+2 + 2 PO4-3
|
|
log_k -25.1
|
|
delta_h -0 kJ
|
|
Mg3(PO4)2
|
|
Mg3(PO4)2 = 3 Mg+2 + 2 PO4-3
|
|
log_k -23.28
|
|
delta_h -0 kJ
|
|
MgHPO4:3H2O
|
|
MgHPO4:3H2O = Mg+2 + H+ + PO4-3 + 3 H2O
|
|
log_k -18.175
|
|
delta_h -0 kJ
|
|
FCO3Apatite
|
|
Ca9.316Na0.36Mg0.144(PO4)4.8(CO3)1.2F2.48 = 9.316 Ca+2 + 0.36 Na+ + 0.144 Mg+2 + 4.8 PO4-3 + 1.2 CO3-2 + 2.48 F-
|
|
log_k -114.4
|
|
delta_h 164.808 kJ
|
|
Hydroxylapatite
|
|
Ca5(PO4)3OH + H+ = 5 Ca+2 + 3 PO4-3 + H2O
|
|
log_k -44.333
|
|
delta_h -0 kJ
|
|
CaHPO4:2H2O
|
|
CaHPO4:2H2O = Ca+2 + H+ + PO4-3 + 2 H2O
|
|
log_k -18.995
|
|
delta_h 23 kJ
|
|
CaHPO4
|
|
CaHPO4 = Ca+2 + H+ + PO4-3
|
|
log_k -19.275
|
|
delta_h 31 kJ
|
|
Ca3(PO4)2(beta)
|
|
Ca3(PO4)2 = 3 Ca+2 + 2 PO4-3
|
|
log_k -28.92
|
|
delta_h 54 kJ
|
|
Ca4H(PO4)3:3H2O
|
|
Ca4H(PO4)3:3H2O = 4 Ca+2 + H+ + 3 PO4-3 + 3 H2O
|
|
log_k -47.08
|
|
delta_h -0 kJ
|
|
SrHPO4
|
|
SrHPO4 = Sr+2 + H+ + PO4-3
|
|
log_k -19.295
|
|
delta_h -0 kJ
|
|
BaHPO4
|
|
BaHPO4 = Ba+2 + H+ + PO4-3
|
|
log_k -19.775
|
|
delta_h -0 kJ
|
|
U(HPO4)2:4H2O
|
|
U(HPO4)2:4H2O = U+4 + 2 PO4-3 + 2 H+ + 4 H2O
|
|
log_k -51.584
|
|
delta_h 16.0666 kJ
|
|
(UO2)3(PO4)2
|
|
(UO2)3(PO4)2 = 3 UO2+2 + 2 PO4-3
|
|
log_k -49.4
|
|
delta_h 397.062 kJ
|
|
UO2HPO4
|
|
UO2HPO4 = UO2+2 + H+ + PO4-3
|
|
log_k -24.225
|
|
delta_h -0 kJ
|
|
Uramphite
|
|
(NH4)2(UO2)2(PO4)2 = 2 UO2+2 + 2 NH4+ + 2 PO4-3
|
|
log_k -51.749
|
|
delta_h 40.5848 kJ
|
|
Przhevalskite
|
|
Pb(UO2)2(PO4)2 = 2 UO2+2 + Pb+2 + 2 PO4-3
|
|
log_k -44.365
|
|
delta_h -46.024 kJ
|
|
Torbernite
|
|
Cu(UO2)2(PO4)2 = 2 UO2+2 + Cu+2 + 2 PO4-3
|
|
log_k -45.279
|
|
delta_h -66.5256 kJ
|
|
Bassetite
|
|
Fe(UO2)2(PO4)2 = 2 UO2+2 + Fe+2 + 2 PO4-3
|
|
log_k -44.485
|
|
delta_h -83.2616 kJ
|
|
Saleeite
|
|
Mg(UO2)2(PO4)2 = 2 UO2+2 + Mg+2 + 2 PO4-3
|
|
log_k -43.646
|
|
delta_h -84.4331 kJ
|
|
Ningyoite
|
|
CaU(PO4)2:2H2O = U+4 + Ca+2 + 2 PO4-3 + 2 H2O
|
|
log_k -53.906
|
|
delta_h -9.4977 kJ
|
|
H-Autunite
|
|
H2(UO2)2(PO4)2 = 2 UO2+2 + 2 H+ + 2 PO4-3
|
|
log_k -47.931
|
|
delta_h -15.0624 kJ
|
|
Autunite
|
|
Ca(UO2)2(PO4)2 = 2 UO2+2 + Ca+2 + 2 PO4-3
|
|
log_k -43.927
|
|
delta_h -59.9986 kJ
|
|
Sr-Autunite
|
|
Sr(UO2)2(PO4)2 = 2 UO2+2 + Sr+2 + 2 PO4-3
|
|
log_k -44.457
|
|
delta_h -54.6012 kJ
|
|
Na-Autunite
|
|
Na2(UO2)2(PO4)2 = 2 UO2+2 + 2 Na+ + 2 PO4-3
|
|
log_k -47.409
|
|
delta_h -1.9246 kJ
|
|
K-Autunite
|
|
K2(UO2)2(PO4)2 = 2 UO2+2 + 2 K+ + 2 PO4-3
|
|
log_k -48.244
|
|
delta_h 24.5182 kJ
|
|
Uranocircite
|
|
Ba(UO2)2(PO4)2 = 2 UO2+2 + Ba+2 + 2 PO4-3
|
|
log_k -44.631
|
|
delta_h -42.2584 kJ
|
|
Pb3(AsO4)2
|
|
Pb3(AsO4)2 + 6 H+ = 3 Pb+2 + 2 H3AsO4
|
|
log_k 5.8
|
|
delta_h -0 kJ
|
|
AlAsO4:2H2O
|
|
AlAsO4:2H2O + 3 H+ = Al+3 + H3AsO4 + 2 H2O
|
|
log_k 4.8
|
|
delta_h -0 kJ
|
|
Zn3(AsO4)2:2.5H2O
|
|
Zn3(AsO4)2:2.5H2O + 6 H+ = 3 Zn+2 + 2 H3AsO4 + 2.5 H2O
|
|
log_k 13.65
|
|
delta_h -0 kJ
|
|
Cu3(AsO4)2:2H2O
|
|
Cu3(AsO4)2:2H2O + 6 H+ = 3 Cu+2 + 2 H3AsO4 + 2 H2O
|
|
log_k 6.1
|
|
delta_h -0 kJ
|
|
Ag3AsO3
|
|
Ag3AsO3 + 3 H+ = 3 Ag+ + H3AsO3
|
|
log_k 2.1573
|
|
delta_h -0 kJ
|
|
Ag3AsO4
|
|
Ag3AsO4 + 3 H+ = 3 Ag+ + H3AsO4
|
|
log_k -2.7867
|
|
delta_h -0 kJ
|
|
Ni3(AsO4)2:8H2O
|
|
Ni3(AsO4)2:8H2O + 6 H+ = 3 Ni+2 + 2 H3AsO4 + 8 H2O
|
|
log_k 15.7
|
|
delta_h -0 kJ
|
|
Co3(AsO4)2
|
|
Co3(AsO4)2 + 6 H+ = 3 Co+2 + 2 H3AsO4
|
|
log_k 13.0341
|
|
delta_h -0 kJ
|
|
FeAsO4:2H2O
|
|
FeAsO4:2H2O + 3 H+ = Fe+3 + H3AsO4 + 2 H2O
|
|
log_k 0.4
|
|
delta_h -0 kJ
|
|
Mn3(AsO4)2:8H2O
|
|
Mn3(AsO4)2:8H2O + 6 H+ = 3 Mn+2 + 2 H3AsO4 + 8 H2O
|
|
log_k 12.5
|
|
delta_h -0 kJ
|
|
Ca3(AsO4)2:4H2O
|
|
Ca3(AsO4)2:4H2O + 6 H+ = 3 Ca+2 + 2 H3AsO4 + 4 H2O
|
|
log_k 22.3
|
|
delta_h -0 kJ
|
|
Ba3(AsO4)2
|
|
Ba3(AsO4)2 + 6 H+ = 3 Ba+2 + 2 H3AsO4
|
|
log_k -8.91
|
|
delta_h 11.0458 kJ
|
|
#NH4VO3
|
|
# NH4VO3 + 2H+ = 2VO2+ + H2O
|
|
# log_k 3.8
|
|
# delta_h 30 kJ
|
|
Pb3(VO4)2
|
|
Pb3(VO4)2 + 8 H+ = 3 Pb+2 + 2 VO2+ + 4 H2O
|
|
log_k 6.14
|
|
delta_h -72.6342 kJ
|
|
Pb2V2O7
|
|
Pb2V2O7 + 6 H+ = 2 Pb+2 + 2 VO2+ + 3 H2O
|
|
log_k -1.9
|
|
delta_h -26.945 kJ
|
|
AgVO3
|
|
AgVO3 + 2 H+ = Ag+ + VO2+ + H2O
|
|
log_k 0.77
|
|
delta_h -0 kJ
|
|
Ag2HVO4
|
|
Ag2HVO4 + 3 H+ = 2 Ag+ + VO2+ + 2 H2O
|
|
log_k 1.48
|
|
delta_h -0 kJ
|
|
Ag3H2VO5
|
|
Ag3H2VO5 + 4 H+ = 3 Ag+ + VO2+ + 3 H2O
|
|
log_k 5.18
|
|
delta_h -0 kJ
|
|
Fe(VO3)2
|
|
Fe(VO3)2 + 4 H+ = Fe+2 + 2 VO2+ + 2 H2O
|
|
log_k -3.72
|
|
delta_h -61.6722 kJ
|
|
Mn(VO3)2
|
|
Mn(VO3)2 + 4 H+ = Mn+2 + 2 VO2+ + 2 H2O
|
|
log_k 4.9
|
|
delta_h -92.4664 kJ
|
|
Mg(VO3)2
|
|
Mg(VO3)2 + 4 H+ = Mg+2 + 2 VO2+ + 2 H2O
|
|
log_k 11.28
|
|
delta_h -136.649 kJ
|
|
Mg2V2O7
|
|
Mg2V2O7 + 6 H+ = 2 Mg+2 + 2 VO2+ + 3 H2O
|
|
log_k 26.36
|
|
delta_h -255.224 kJ
|
|
Carnotite
|
|
KUO2VO4 + 4 H+ = K+ + UO2+2 + VO2+ + 2 H2O
|
|
log_k 0.23
|
|
delta_h -36.4008 kJ
|
|
Tyuyamunite
|
|
Ca(UO2)2(VO4)2 + 8 H+ = Ca+2 + 2 UO2+2 + 2 VO2+ + 4 H2O
|
|
log_k 4.08
|
|
delta_h -153.134 kJ
|
|
Ca(VO3)2
|
|
Ca(VO3)2 + 4 H+ = Ca+2 + 2 VO2+ + 2 H2O
|
|
log_k 5.66
|
|
delta_h -84.7678 kJ
|
|
Ca3(VO4)2
|
|
Ca3(VO4)2 + 8 H+ = 3 Ca+2 + 2 VO2+ + 4 H2O
|
|
log_k 38.96
|
|
delta_h -293.466 kJ
|
|
Ca2V2O7
|
|
Ca2V2O7 + 6 H+ = 2 Ca+2 + 2 VO2+ + 3 H2O
|
|
log_k 17.5
|
|
delta_h -159.494 kJ
|
|
Ca3(VO4)2:4H2O
|
|
Ca3(VO4)2:4H2O + 8 H+ = 3 Ca+2 + 2 VO2+ + 8 H2O
|
|
log_k 39.86
|
|
delta_h -0 kJ
|
|
Ca2V2O7:2H2O
|
|
Ca2V2O7:2H2O + 6 H+ = 2 Ca+2 + 2 VO2+ + 5 H2O
|
|
log_k 21.552
|
|
delta_h -0 kJ
|
|
Ba3(VO4)2:4H2O
|
|
Ba3(VO4)2:4H2O + 8 H+ = 3 Ba+2 + 2 VO2+ + 8 H2O
|
|
log_k 32.94
|
|
delta_h -0 kJ
|
|
Ba2V2O7:2H2O
|
|
Ba2V2O7:2H2O + 6 H+ = 2 Ba+2 + 2 VO2+ + 5 H2O
|
|
log_k 15.872
|
|
delta_h -0 kJ
|
|
NaVO3
|
|
NaVO3 + 2 H+ = Na+ + VO2+ + H2O
|
|
log_k 3.8582
|
|
delta_h -30.1799 kJ
|
|
Na3VO4
|
|
Na3VO4 + 4 H+ = 3 Na+ + VO2+ + 2 H2O
|
|
log_k 36.6812
|
|
delta_h -184.61 kJ
|
|
Na4V2O7
|
|
Na4V2O7 + 6 H+ = 4 Na+ + 2 VO2+ + 3 H2O
|
|
log_k 37.4
|
|
delta_h -201.083 kJ
|
|
Halloysite
|
|
Al2Si2O5(OH)4 + 6 H+ = 2 Al+3 + 2 H4SiO4 + H2O
|
|
log_k 9.5749
|
|
delta_h -181.43 kJ
|
|
Kaolinite
|
|
Al2Si2O5(OH)4 + 6 H+ = 2 Al+3 + 2 H4SiO4 + H2O
|
|
log_k 7.435
|
|
delta_h -148 kJ
|
|
Greenalite
|
|
Fe3Si2O5(OH)4 + 6 H+ = 3 Fe+2 + 2 H4SiO4 + H2O
|
|
log_k 20.81
|
|
delta_h -0 kJ
|
|
Chrysotile
|
|
Mg3Si2O5(OH)4 + 6 H+ = 3 Mg+2 + 2 H4SiO4 + H2O
|
|
log_k 32.2
|
|
delta_h -196 kJ
|
|
Sepiolite
|
|
Mg2Si3O7.5OH:3H2O + 4 H+ + 0.5 H2O = 2 Mg+2 + 3 H4SiO4
|
|
log_k 15.76
|
|
delta_h -114.089 kJ
|
|
Sepiolite(A)
|
|
Mg2Si3O7.5OH:3H2O + 0.5 H2O + 4 H+ = 2 Mg+2 + 3 H4SiO4
|
|
log_k 18.78
|
|
delta_h -0 kJ
|
|
PHASES
|
|
O2(g)
|
|
O2 + 4 H+ + 4 e- = 2 H2O
|
|
log_k 83.0894
|
|
delta_h -571.66 kJ
|
|
CH4(g)
|
|
CH4 + 3 H2O = CO3-2 + 8 e- + 10 H+
|
|
log_k -41.0452
|
|
delta_h 257.133 kJ
|
|
CO2(g)
|
|
CO2 + H2O = 2 H+ + CO3-2
|
|
log_k -18.147
|
|
delta_h 4.06 kJ
|
|
H2S(g)
|
|
H2S = H+ + HS-
|
|
log_k -8.01
|
|
delta_h -0 kJ
|
|
H2Se(g)
|
|
H2Se = HSe- + H+
|
|
log_k -4.96
|
|
delta_h -15.3 kJ
|
|
Hg(g)
|
|
Hg = 0.5 Hg2+2 + e-
|
|
log_k -7.8733
|
|
delta_h 22.055 kJ
|
|
Hg2(g)
|
|
Hg2 = Hg2+2 + 2 e-
|
|
log_k -14.9554
|
|
delta_h 58.07 kJ
|
|
Hg(CH3)2(g)
|
|
Hg(CH3)2 + 8 H2O = Hg(OH)2 + 2 CO3-2 + 16 e- + 20 H+
|
|
log_k -73.7066
|
|
delta_h 481.99 kJ
|
|
HgF(g)
|
|
HgF = 0.5 Hg2+2 + F-
|
|
log_k 32.6756
|
|
delta_h -254.844 kJ
|
|
HgF2(g)
|
|
HgF2 + 2 H2O = Hg(OH)2 + 2 F- + 2 H+
|
|
log_k 12.5652
|
|
delta_h -165.186 kJ
|
|
HgCl(g)
|
|
HgCl = 0.5 Hg2+2 + Cl-
|
|
log_k 19.4966
|
|
delta_h -162.095 kJ
|
|
HgBr(g)
|
|
HgBr = 0.5 Hg2+2 + Br-
|
|
log_k 16.7566
|
|
delta_h -142.157 kJ
|
|
HgBr2(g)
|
|
HgBr2 + 2 H2O = Hg(OH)2 + 2 Br- + 2 H+
|
|
log_k -18.3881
|
|
delta_h 54.494 kJ
|
|
HgI(g)
|
|
HgI = 0.5 Hg2+2 + I-
|
|
log_k 11.3322
|
|
delta_h -106.815 kJ
|
|
HgI2(g)
|
|
HgI2 + 2 H2O = Hg(OH)2 + 2 I- + 2 H+
|
|
log_k -27.2259
|
|
delta_h 114.429 kJ
|
|
SURFACE_MASTER_SPECIES
|
|
Hfo_s Hfo_sOH
|
|
Hfo_w Hfo_wOH
|
|
SURFACE_SPECIES
|
|
Hfo_wOH = Hfo_wOH
|
|
log_k 0
|
|
Hfo_sOH = Hfo_sOH
|
|
log_k 0
|
|
Hfo_sOH + H+ = Hfo_sOH2+
|
|
log_k 7.29
|
|
delta_h 0 kJ
|
|
# Id: 8113302
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH = Hfo_sO- + H+
|
|
log_k -8.93
|
|
delta_h 0 kJ
|
|
# Id: 8113301
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + H+ = Hfo_wOH2+
|
|
log_k 7.29
|
|
delta_h 0 kJ
|
|
# Id: 8123302
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH = Hfo_wO- + H+
|
|
log_k -8.93
|
|
delta_h 0 kJ
|
|
# Id: 8123301
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + Ba+2 = Hfo_sOHBa+2
|
|
log_k 5.46
|
|
delta_h 0 kJ
|
|
# Id: 8111000
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + Ba+2 = Hfo_wOBa+ + H+
|
|
log_k -7.2
|
|
delta_h 0 kJ
|
|
# Id: 8121000
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + Ca+2 = Hfo_sOHCa+2
|
|
log_k 4.97
|
|
delta_h 0 kJ
|
|
# Id: 8111500
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + Ca+2 = Hfo_wOCa+ + H+
|
|
log_k -5.85
|
|
delta_h 0 kJ
|
|
# Id: 8121500
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + Mg+2 = Hfo_wOMg+ + H+
|
|
log_k -4.6
|
|
delta_h 0 kJ
|
|
# Id: 8124600
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + Ag+ = Hfo_sOAg + H+
|
|
log_k -1.72
|
|
delta_h 0 kJ
|
|
# Id: 8110200
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + Ag+ = Hfo_wOAg + H+
|
|
log_k -5.3
|
|
delta_h 0 kJ
|
|
# Id: 8120200
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + Ni+2 = Hfo_sONi+ + H+
|
|
log_k 0.37
|
|
delta_h 0 kJ
|
|
# Id: 8115400
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + Ni+2 = Hfo_wONi+ + H+
|
|
log_k -2.5
|
|
delta_h 0 kJ
|
|
# Id: 8125400
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + Cd+2 = Hfo_sOCd+ + H+
|
|
log_k 0.47
|
|
delta_h 0 kJ
|
|
# Id: 8111600
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + Cd+2 = Hfo_wOCd+ + H+
|
|
log_k -2.9
|
|
delta_h 0 kJ
|
|
# Id: 8121600
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + Co+2 = Hfo_sOCo+ + H+
|
|
log_k -0.46
|
|
delta_h 0 kJ
|
|
# Id: 8112000
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + Co+2 = Hfo_wOCo+ + H+
|
|
log_k -3.01
|
|
delta_h 0 kJ
|
|
# Id: 8122000
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + Zn+2 = Hfo_sOZn+ + H+
|
|
log_k 0.99
|
|
delta_h 0 kJ
|
|
# Id: 8119500
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + Zn+2 = Hfo_wOZn+ + H+
|
|
log_k -1.99
|
|
delta_h 0 kJ
|
|
# Id: 8129500
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + Cu+2 = Hfo_sOCu+ + H+
|
|
log_k 2.89
|
|
delta_h 0 kJ
|
|
# Id: 8112310
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + Cu+2 = Hfo_wOCu+ + H+
|
|
log_k 0.6
|
|
delta_h 0 kJ
|
|
# Id: 8123100
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + Pb+2 = Hfo_sOPb+ + H+
|
|
log_k 4.65
|
|
delta_h 0 kJ
|
|
# Id: 8116000
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + Pb+2 = Hfo_wOPb+ + H+
|
|
log_k 0.3
|
|
delta_h 0 kJ
|
|
# Id: 8126000
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + Be+2 = Hfo_sOBe+ + H+
|
|
log_k 5.7
|
|
delta_h 0 kJ
|
|
# Id: 8111100
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + Be+2 = Hfo_wOBe+ + H+
|
|
log_k 3.3
|
|
delta_h 0 kJ
|
|
# Id: 8121100
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + Hg(OH)2 + H+ = Hfo_sOHg+ + 2 H2O
|
|
log_k 13.95
|
|
delta_h 0 kJ
|
|
# Id: 8113610
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + Hg(OH)2 + H+ = Hfo_wOHg+ + 2 H2O
|
|
log_k 12.64
|
|
delta_h 0 kJ
|
|
# Id: 8123610
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + Sn(OH)2 + H+ = Hfo_sOSn+ + 2 H2O
|
|
log_k 15.1
|
|
delta_h 0 kJ
|
|
# Id: 8117900
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + Sn(OH)2 + H+ = Hfo_wOSn+ + 2 H2O
|
|
log_k 13
|
|
delta_h 0 kJ
|
|
# Id: 8127900
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + Cr(OH)2+ = Hfo_sOCrOH+ + H2O
|
|
log_k 11.63
|
|
delta_h 0 kJ
|
|
# Id: 8112110
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + H3AsO3 = Hfo_sH2AsO3 + H2O
|
|
log_k 5.41
|
|
delta_h 0 kJ
|
|
# Id: 8110600
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + H3AsO3 = Hfo_wH2AsO3 + H2O
|
|
log_k 5.41
|
|
delta_h 0 kJ
|
|
# Id: 8120600
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + H3BO3 = Hfo_sH2BO3 + H2O
|
|
log_k 0.62
|
|
delta_h 0 kJ
|
|
# Id: 8110900
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + H3BO3 = Hfo_wH2BO3 + H2O
|
|
log_k 0.62
|
|
delta_h 0 kJ
|
|
# Id: 8120900
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + PO4-3 + 3 H+ = Hfo_sH2PO4 + H2O
|
|
log_k 31.29
|
|
delta_h 0 kJ
|
|
# Id: 8115800
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + PO4-3 + 3 H+ = Hfo_wH2PO4 + H2O
|
|
log_k 31.29
|
|
delta_h 0 kJ
|
|
# Id: 8125800
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + PO4-3 + 2 H+ = Hfo_sHPO4- + H2O
|
|
log_k 25.39
|
|
delta_h 0 kJ
|
|
# Id: 8115801
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + PO4-3 + 2 H+ = Hfo_wHPO4- + H2O
|
|
log_k 25.39
|
|
delta_h 0 kJ
|
|
# Id: 8125801
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + PO4-3 + H+ = Hfo_sPO4-2 + H2O
|
|
log_k 17.72
|
|
delta_h 0 kJ
|
|
# Id: 8115802
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + PO4-3 + H+ = Hfo_wPO4-2 + H2O
|
|
log_k 17.72
|
|
delta_h 0 kJ
|
|
# Id: 8125802
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + H3AsO4 = Hfo_sH2AsO4 + H2O
|
|
log_k 8.61
|
|
delta_h 0 kJ
|
|
# Id: 8110610
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + H3AsO4 = Hfo_wH2AsO4 + H2O
|
|
log_k 8.61
|
|
delta_h 0 kJ
|
|
# Id: 8120610
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + H3AsO4 = Hfo_sHAsO4- + H2O + H+
|
|
log_k 2.81
|
|
delta_h 0 kJ
|
|
# Id: 8110611
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + H3AsO4 = Hfo_wHAsO4- + H2O + H+
|
|
log_k 2.81
|
|
delta_h 0 kJ
|
|
# Id: 8120611
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + H3AsO4 = Hfo_sOHAsO4-3 + 3 H+
|
|
log_k -10.12
|
|
delta_h 0 kJ
|
|
# Id: 8110613
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + H3AsO4 = Hfo_wOHAsO4-3 + 3 H+
|
|
log_k -10.12
|
|
delta_h 0 kJ
|
|
# Id: 8120613
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + VO2+ + 2 H2O = Hfo_sOHVO4-3 + 4 H+
|
|
log_k -16.63
|
|
delta_h 0 kJ
|
|
# Id: 8119031
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + VO2+ + 2 H2O = Hfo_wOHVO4-3 + 4 H+
|
|
log_k -16.63
|
|
delta_h 0 kJ
|
|
# Id: 8129031
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + SO4-2 + H+ = Hfo_sSO4- + H2O
|
|
log_k 7.78
|
|
delta_h 0 kJ
|
|
# Id: 8117320
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + SO4-2 + H+ = Hfo_wSO4- + H2O
|
|
log_k 7.78
|
|
delta_h 0 kJ
|
|
# Id: 8127320
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + SO4-2 = Hfo_sOHSO4-2
|
|
log_k 0.79
|
|
delta_h 0 kJ
|
|
# Id: 8117321
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + SO4-2 = Hfo_wOHSO4-2
|
|
log_k 0.79
|
|
delta_h 0 kJ
|
|
# Id: 8127321
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + HSeO3- = Hfo_sSeO3- + H2O
|
|
log_k 4.29
|
|
delta_h 0 kJ
|
|
# Id: 8117610
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + HSeO3- = Hfo_wSeO3- + H2O
|
|
log_k 4.29
|
|
delta_h 0 kJ
|
|
# Id: 8127610
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + HSeO3- = Hfo_sOHSeO3-2 + H+
|
|
log_k -3.23
|
|
delta_h 0 kJ
|
|
# Id: 8117611
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + HSeO3- = Hfo_wOHSeO3-2 + H+
|
|
log_k -3.23
|
|
delta_h 0 kJ
|
|
# Id: 8127611
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + SeO4-2 + H+ = Hfo_sSeO4- + H2O
|
|
log_k 7.73
|
|
delta_h 0 kJ
|
|
# Id: 8117620
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + SeO4-2 + H+ = Hfo_wSeO4- + H2O
|
|
log_k 7.73
|
|
delta_h 0 kJ
|
|
# Id: 8127620
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + SeO4-2 = Hfo_sOHSeO4-2
|
|
log_k 0.8
|
|
delta_h 0 kJ
|
|
# Id: 8117621
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + SeO4-2 = Hfo_wOHSeO4-2
|
|
log_k 0.8
|
|
delta_h 0 kJ
|
|
# Id: 8127621
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + CrO4-2 + H+ = Hfo_sCrO4- + H2O
|
|
log_k 10.85
|
|
delta_h 0 kJ
|
|
# Id: 8112120
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + CrO4-2 + H+ = Hfo_wCrO4- + H2O
|
|
log_k 10.85
|
|
delta_h 0 kJ
|
|
# Id: 8122120
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + CrO4-2 = Hfo_sOHCrO4-2
|
|
log_k 3.9
|
|
delta_h 0 kJ
|
|
# Id: 8112121
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + CrO4-2 = Hfo_wOHCrO4-2
|
|
log_k 3.9
|
|
delta_h 0 kJ
|
|
# Id: 8122121
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + MoO4-2 + H+ = Hfo_sMoO4- + H2O
|
|
log_k 9.5
|
|
delta_h 0 kJ
|
|
# Id: 8114800
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + MoO4-2 + H+ = Hfo_wMoO4- + H2O
|
|
log_k 9.5
|
|
delta_h 0 kJ
|
|
# Id: 8124800
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + MoO4-2 = Hfo_sOHMoO4-2
|
|
log_k 2.4
|
|
delta_h 0 kJ
|
|
# Id: 8114801
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + MoO4-2 = Hfo_wOHMoO4-2
|
|
log_k 2.4
|
|
delta_h 0 kJ
|
|
# Id: 8124801
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + Sb(OH)6- + H+ = Hfo_sSbO(OH)4 + 2 H2O
|
|
log_k 8.4
|
|
delta_h 0 kJ
|
|
# Id: 8117410
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + Sb(OH)6- + H+ = Hfo_wSbO(OH)4 + 2 H2O
|
|
log_k 8.4
|
|
delta_h 0 kJ
|
|
# Id: 8127410
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + Sb(OH)6- = Hfo_sOHSbO(OH)4- + H2O
|
|
log_k 1.3
|
|
delta_h 0 kJ
|
|
# Id: 8117411
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + Sb(OH)6- = Hfo_wOHSbO(OH)4- + H2O
|
|
log_k 1.3
|
|
delta_h 0 kJ
|
|
# Id: 8127411
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + Cyanide- + H+ = Hfo_sCyanide + H2O
|
|
log_k 13
|
|
delta_h 0 kJ
|
|
# Id: 8111430
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + Cyanide- + H+ = Hfo_wCyanide + H2O
|
|
log_k 13
|
|
delta_h 0 kJ
|
|
# Id: 8121430
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_sOH + Cyanide- = Hfo_sOHCyanide-
|
|
log_k 5.7
|
|
delta_h 0 kJ
|
|
# Id: 8111431
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
Hfo_wOH + Cyanide- = Hfo_wOHCyanide-
|
|
log_k 5.7
|
|
delta_h 0 kJ
|
|
# Id: 8121431
|
|
# log K source:
|
|
# Delta H source:
|
|
#T and ionic strength:
|
|
END
|
|
|
|
|