poet/bench/surfex/SurfexEGU.pqi
2024-05-06 10:09:28 +00:00

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## Time-stamp: "Last modified 2024-04-12 10:59:59 delucia"
## KNOBS
## -logfile false
## -iterations 10000
## -convergence_tolerance 1E-12
## -step_size 2
## -pe_step_size 2
SOLUTION 1 ## Porewater composition Opalinus Clay, WITHOUT radionuclides, AFTER EQUI_PHASES
pe -2.627 ## Eh = -227 mV, Value from Bossart & Thury (2008)-> PC borehole measurement 2003, Eh still decreasing
density 1.01583 ## kg/dm³ = g/cm³
temp 13 ## mean temperature Mont Terri, Bossart & Thury (2008), calculations performed for 25°C
units mol/kgw
## Mean composition
pH 7.064
Na 2.763e-01
Cl 3.228e-01 charge
S(6) 1.653e-02 as SO4
Ca 2.173e-02
Mg 1.740e-02
K 1.902e-03
Sr 4.520e-04
Fe 1.435e-04
U 2.247e-09
SURFACE 1 Opalinus Clay, clay minerals
## calculated with rho_b=2.2903 kg/dm³, poro=0.1662
## 1 dm³ = 13.565641 kg_sed/kg_pw
-equil 1 ## equilibrate with solution 1
-sites_units density ## set unit for binding site density to sites/nm2
-donnan 4.9e-10 ## calculated after Wigger & Van Loon (2018) for ionic strength after equilibration with minerales for pCO2=2.2 log10 bar
# surface density SSA (m2/g) mass (g/kgw)
Kln_aOH 1.155 11. 3798.4 ## Kaolinite 28 wt% (aluminol and silanol sites)
Kln_siOH 1.155
Ill_sOH 0.05 100. 4205.35 ## Illite 31 wt% (weak und strong binding sites)
Ill_wOH 2.26 ## 2 % strong binding sites
Mll_sOH 0.05 100. 813.94 ## Montmorillonite = smektite = 6 wt% (weak und strong binding sites)
Mll_wOH 2.26 ## 2 % strong binding sites
EXCHANGE 1 Exchanger, only illite+montmorillonite
## Illite = 0.225 eq/kg_rock, Montmorillonit = 0.87 eq/kg_rock
-equil 1 ## equilibrate with solution 1
Z 0.9462 ## = Illite
Y 0.70813 ## = Montmorillonite
END
SOLUTION 2 ## Porewater composition Opalinus Clay, WITHOUT radionuclides, AFTER EQUI_PHASES
pe -2.627 ## Eh = -227 mV, Value from Bossart & Thury (2008)-> PC borehole measurement 2003, Eh still decreasing
density 1.01583 ## kg/dm³ = g/cm³
temp 13 ## mean temperature Mont Terri, Bossart & Thury (2008), calculations performed for 25°C
units mol/kgw
## Mean composition
pH 7.064
Na 2.763e-01
Cl 3.228e-01 charge
S(6) 1.653e-02 as SO4
Ca 2.173e-02
Mg 1.740e-02
K 1.902e-03
Sr 4.520e-04
Fe 1.435e-04
U 2.247e-09
SURFACE 2 Opalinus Clay, clay minerals
-equil 2 ## equilibrate with solution 2
-sites_units density ## set unit for binding site density to
## sites/nm2
-donnan 4.9e-10 ## calculated after Wigger & Van Loon (2018)
## for ionic strength after equilibration
## with minerales for pCO2=2.2 log10 bar
## surface density SSA (m2/g) mass (g/kgw)
Kln_aOH 1.155 11. 2798.4 ## Kaolinite 28 wt% (aluminol and silanol sites)
Kln_siOH 1.155
Ill_sOH 0.05 100. 1205.35 ## Illite 31 wt% (weak und strong binding sites)
Ill_wOH 2.26 ## 2 % strong binding sites
Mll_sOH 0.05 100. 113.94 ## Montmorillonite = smektite = 6 wt% (weak und strong binding sites)
Mll_wOH 2.26 ## 2 % strong binding sites
EXCHANGE 2 Exchanger, only illite+montmorillonite
## Illite = 0.225 eq/kg_rock, Montmorillonit = 0.87 eq/kg_rock
-equil 2 ## equilibrate with solution 1
Z 0.5 ## = Illite
Y 0.2 ## = Montmorillonite
END
SOLUTION 3
pe -2.627 ## Eh = -227 mV, Value from Bossart & Thury (2008)-> PC borehole measurement 2003, Eh still decreasing
density 1.01583 ## kg/dm³ = g/cm³
temp 13 ## mean temperature Mont Terri, Bossart & Thury (2008), calculations performed for 25°C
units mol/kgw
## Mean composition
pH 7.064
Na 3.763e-01
Cl 4.228e-01 charge
S(6) 1.653e-02 as SO4
Ca 2.173e-02
Mg 1.740e-02
K 1.902e-03
Sr 4.520e-04
Fe 1.435e-04
U 1e-6
C 1.991e-03
END
RUN_CELLS
END