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iphreeqc/iso.dat
Darth Vader 39086e3af2 Squashed 'database/' changes from 488636ae..20e6e440 
20e6e440 still produces different residuals
6ea9caf0 Tony H2S. Amm.dat, phreeqc.dat, pitzer.dat, utf8, updated test cases
c1c97a85 before H2S
a7be9fcf Updated Amm.dat, phreeqc.dat, pitzer.dat for H2S(g)
b40b25fd Another SIT database
fce334ff use cmake for valgrind tests
90f9cb53 checking in test cases using latest revisions. degree sign in pitzer.dat
d45a37e0 database UTF-8
3aa7a146 Tony database update, kinetic_rates example
f385cf57 Tony's updates March 10, 2021
88afb660 Tony's changes March 10, 2021.
4396def4 add databases
e4e5449a [wphast] updated date
4c209593 [phreeqc3] updated image location
beaab1d6 more characters
6b8138c2 fixed degree sign
759cac1f fixed some sit.dat characters
3f258562 updated databases
8be6ec5f update to charlton master
2560903d [phreeqci] Testing subtree merges
1d71804f Merge commit 'a400365a5e06a9cd2ac0aa6e2c51fa4797c631f8'
a400365a [phreeqc3] Testing subtree merges
4296b155 Merge commit '0e8069e37275f23d47e04bd6b7873ec56dfdf088'
0e8069e3 Fixed bug with more porosities than cells in TRANSPORT. Added silica sorption to databases. Revised CalPortDiff
fa7cbaf5 Added .gitlab-ci.yml
6a8d5088 Added .gitlab-ci.yml
cfc208b0 updated installer
164b85d3 Fixed some bugs with iso.dat inverse modeling, added test case. Still does not generate [13C](4) and [13C](-4) from SOLUTION
06e25ec8 Correction to core10.dat from Neveu

git-subtree-dir: database
git-subtree-split: 20e6e440f056358f9887ada878a76d8e3d4ecc64
2021-10-30 22:54:23 +00:00

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SOLUTION_MASTER_SPECIES
E e- 0 0 0.0
H H3O+ -1 H 1.008
H(0) H2 0 H
H(1) H3O+ -1 H
O H2O 0 O 16.00
O(0) O2 0 O
O(-2) H2O 0 O
Ca Ca+2 0 Ca 40.08
Mg Mg+2 0 Mg 24.312
Na Na+ 0 Na 22.9898
K K+ 0 K 39.102
Fe Fe+2 0.0 Fe 55.847
Fe(+2) Fe+2 0.0 Fe
Fe(+3) Fe+3 -2.0 Fe
Al Al+3 0.0 Al 26.9815
Si H4SiO4 0.0 SiO2 28.0843
Cl Cl- 0 Cl 35.453
C CO2 0 HCO3 12.0111
C(4) CO2 0 HCO3
C(-4) CH4 0 CH4
S SO4-2 0 S 31.972
S(6) SO4-2 0 SO4
S(-2) HS- 1 S
N NO3- 0 N 14.0067
N(+5) NO3- 0 N
N(+3) NO2- 0 N
N(0) N2 0 N
N(-3) NH4+ 0 N
P PO4-3 2.0 P 30.9738
F F- 0.0 F 18.9984
Br Br- 0.0 Br 79.904
Alkalinity CO2 0.0 50.05 50.05
SOLUTION_SPECIES
H3O+ = H3O+
log_k 0.000
-gamma 9.0000 0.0000
e- = e-
log_k 0.000
H2O = H2O
log_k 0.000
Ca+2 = Ca+2
log_k 0.000
-gamma 5.0000 0.1650
Mg+2 = Mg+2
log_k 0.000
-gamma 5.5000 0.2000
Na+ = Na+
log_k 0.000
-gamma 4.0000 0.0750
K+ = K+
log_k 0.000
-gamma 3.5000 0.0150
Fe+2 = Fe+2
log_k 0.000
-gamma 6.0000 0.0000
Al+3 = Al+3
log_k 0.000
-gamma 9.0000 0.0000
H4SiO4 = H4SiO4
log_k 0.000
Cl- = Cl-
log_k 0.000
-gamma 3.5000 0.0150
SO4-2 = SO4-2
log_k 0.000
-gamma 5.0000 -0.0400
NO3- = NO3-
log_k 0.000
-gamma 3.0000 0.0000
PO4-3 = PO4-3
log_k 0.000
-gamma 4.0000 0.0000
F- = F-
log_k 0.000
-gamma 3.5000 0.0000
Br- = Br-
log_k 0.000
-gamma 3.0000 0.0000
2H2O = OH- + H3O+
log_k -14.000
delta_h 13.362 kcal
-analytic -283.971 -0.05069842 13323.0 102.24447 -1119669.0
-gamma 3.5000 0.0000
6 H2O = O2 + 4 H3O+ + 4 e-
log_k -86.08
delta_h 134.79 kcal
2 H3O+ + 2 e- = H2 + 2H2O
log_k -3.15
delta_h -1.759 kcal
CO2 + 2H2O = HCO3- + H3O+
log_k -6.352
delta_h 2.177 kcal
-analytic -356.3094 -0.06092 21834.37 126.8339 -1684915
CO2 + 3H2O = CO3-2 + 2H3O+
log_k -16.681
delta_h 5.738 kcal
-analytic -464.1965 -0.09344813 26986.16 165.75951 -2248628.9
CO3-2 + 10 H3O+ + 8 e- = CH4 + 13 H2O
log_k 41.071
delta_h -61.039 kcal
SO4-2 + H3O+ = HSO4- + H2O
log_k 1.988
delta_h 3.85 kcal
-analytic -56.889 0.006473 2307.9 19.8858 0.0
SO4-2 + 9 H3O+ + 8 e- = HS- + 13 H2O
log_k 33.65
delta_h -60.140 kcal
-gamma 3.5000 0.0000
HS- + H2O = S-2 + H3O+
log_k -12.918
delta_h 12.1 kcal
-gamma 5.0000 0.0000
HS- + H3O+ = H2S + H2O
log_k 6.994
delta_h -5.300 kcal
-analytic -11.17 0.02386 3279.0
NO3- + 2 H3O+ + 2 e- = NO2- + 3H2O
log_k 28.570
delta_h -43.760 kcal
-gamma 3.0000 0.0000
2 NO3- + 12 H3O+ + 10e- = N2 + 18 H2O
log_k 207.080
delta_h -312.130 kcal
NH4+ + H2O = NH3 + H3O+
log_k -9.252
delta_h 12.48 kcal
-analytic 0.6322 -0.001225 -2835.76
NO3- + 10 H3O+ + 8 e- = NH4+ + 13 H2O
log_k 119.077
delta_h -187.055 kcal
-gamma 2.5000 0.0000
NH4+ + SO4-2 = NH4SO4-
log_k 1.11
PO4-3 + H3O+ = HPO4-2 + H2O
log_k 12.346
delta_h -3.530 kcal
-gamma 4.0000 0.0000
PO4-3 + 2 H3O+ = H2PO4- + 2H2O
log_k 19.553
delta_h -4.520 kcal
-gamma 4.5000 0.0000
H3O+ + F- = HF + H2O
log_k 3.18
delta_h 3.18 kcal
-analytic -2.033 0.012645 429.01
H3O+ + 2 F- = HF2- + H2O
log_k 3.760
delta_h 4.550 kcal
Ca+2 + OH- = CaOH+
log_k -12.780
Ca+2 + CO3-2 = CaCO3
log_k 3.224
delta_h 3.545 kcal
-analytic -1228.732 -0.299440 35512.75 485.818
#Ca+2 + HCO3- = CaHCO3+
Ca+2 + CO3-2 + H3O+ = CaHCO3+ + H2O
log_k 11.435
delta_h -0.871 kcal
-analytic 1317.0071 0.34546894 -39916.84 -517.70761 563713.9
-gamma 5.4000 0.0000
Ca+2 + SO4-2 = CaSO4
log_k 2.300
delta_h 1.650 kcal
Ca+2 + HSO4- = CaHSO4+
log_k 1.08
Ca+2 + PO4-3 = CaPO4-
log_k 6.459
delta_h 3.100 kcal
Ca+2 + HPO4-2 = CaHPO4
log_k 2.739
delta_h 3.3 kcal
Ca+2 + H2PO4- = CaH2PO4+
log_k 1.408
delta_h 3.4 kcal
Ca+2 + F- = CaF+
log_k 0.940
delta_h 4.120 kcal
Mg+2 + OH- = MgOH+
log_k -11.440
delta_h 15.952 kcal
Mg+2 + CO3-2 = MgCO3
log_k 2.98
delta_h 2.713 kcal
-analytic 0.9910 0.00667
Mg+2 + H3O+ + CO3-2 = MgHCO3+ + H2O
log_k 11.399
delta_h -2.771 kcal
-analytic 48.6721 0.03252849 -2614.335 -18.00263 563713.9
Mg+2 + SO4-2 = MgSO4
log_k 2.370
delta_h 4.550 kcal
Mg+2 + PO4-3 = MgPO4-
log_k 6.589
delta_h 3.100 kcal
Mg+2 + HPO4-2 = MgHPO4
log_k 2.87
delta_h 3.3 kcal
Mg+2 + H2PO4- = MgH2PO4+
log_k 1.513
delta_h 3.4 kcal
Mg+2 + F- = MgF+
log_k 1.820
delta_h 3.200 kcal
Na+ + OH- = NaOH
log_k -14.180
Na+ + CO3-2 = NaCO3-
log_k 1.270
delta_h 8.910 kcal
Na+ + HCO3- = NaHCO3
log_k -0.25
Na+ + SO4-2 = NaSO4-
log_k 0.700
delta_h 1.120 kcal
Na+ + HPO4-2 = NaHPO4-
log_k 0.29
Na+ + F- = NaF
log_k -0.240
K+ + OH- = KOH
log_k -14.460
K+ + SO4-2 = KSO4-
log_k 0.850
delta_h 2.250 kcal
-analytic 3.106 0.0 -673.6
K+ + HPO4-2 = KHPO4-
log_k 0.29
Fe+2 + 2H2O = FeOH+ + H3O+
log_k -9.500
delta_h 13.200 kcal
Fe+2 + Cl- = FeCl+
log_k 0.140
Fe+2 + CO3-2 = FeCO3
log_k 4.380
Fe+2 + HCO3- = FeHCO3+
log_k 2.0
Fe+2 + SO4-2 = FeSO4
log_k 2.250
delta_h 3.230 kcal
Fe+2 + HSO4- = FeHSO4+
log_k 1.08
Fe+2 + 2HS- = Fe(HS)2
log_k 8.95
Fe+2 + 3HS- = Fe(HS)3-
log_k 10.987
Fe+2 + HPO4-2 = FeHPO4
log_k 3.6
Fe+2 + H2PO4- = FeH2PO4+
log_k 2.7
Fe+2 + F- = FeF+
log_k 1.000
Fe+2 = Fe+3 + e-
log_k -13.020
delta_h 9.680 kcal
-gamma 9.0000 0.0000
Fe+3 + 2H2O = FeOH+2 + H3O+
log_k -2.19
delta_h 10.4 kcal
Fe+3 + 4H2O = Fe(OH)2+ + 2 H3O+
log_k -5.67
delta_h 17.1 kcal
Fe+3 + 6 H2O = Fe(OH)3 + 3 H3O+
log_k -12.56
delta_h 24.8 kcal
Fe+3 + 8 H2O = Fe(OH)4- + 4 H3O+
log_k -21.6
delta_h 31.9 kcal
2 Fe+3 + 4 H2O = Fe2(OH)2+4 + 2 H3O+
log_k -2.95
delta_h 13.5 kcal
3 Fe+3 + 8 H2O = Fe3(OH)4+5 + 4 H3O+
log_k -6.3
delta_h 14.3 kcal
Fe+3 + Cl- = FeCl+2
log_k 1.48
delta_h 5.6 kcal
Fe+3 + 2 Cl- = FeCl2+
log_k 2.13
Fe+3 + 3 Cl- = FeCl3
log_k 1.13
Fe+3 + SO4-2 = FeSO4+
log_k 4.04
delta_h 3.91 kcal
Fe+3 + HSO4- = FeHSO4+2
log_k 2.48
Fe+3 + 2 SO4-2 = Fe(SO4)2-
log_k 5.38
delta_h 4.60 kcal
Fe+3 + HPO4-2 = FeHPO4+
log_k 5.43
delta_h 5.76 kcal
Fe+3 + H2PO4- = FeH2PO4+2
log_k 5.43
Fe+3 + F- = FeF+2
log_k 6.2
delta_h 2.7 kcal
Fe+3 + 2 F- = FeF2+
log_k 10.8
delta_h 4.8 kcal
Fe+3 + 3 F- = FeF3
log_k 14.0
delta_h 5.4 kcal
Al+3 + 2H2O = AlOH+2 + H3O+
log_k -5.00
delta_h 11.49 kcal
-analytic -38.253 0.0 -656.27 14.327
Al+3 + 4 H2O = Al(OH)2+ + 2 H3O+
log_k -10.1
delta_h 26.90 kcal
-analytic 88.500 0.0 -9391.6 -27.121
Al+3 + 6 H2O = Al(OH)3 + 3 H3O+
log_k -16.9
delta_h 39.89 kcal
-analytic 226.374 0.0 -18247.8 -73.597
Al+3 + 8 H2O = Al(OH)4- + 4 H3O+
log_k -22.7
delta_h 42.30 kcal
-analytic 51.578 0.0 -11168.9 -14.865
Al+3 + SO4-2 = AlSO4+
log_k 3.5
delta_h 2.29 kcal
Al+3 + 2SO4-2 = Al(SO4)2-
log_k 5.0
delta_h 3.11 kcal
Al+3 + HSO4- = AlHSO4+2
log_k 0.46
Al+3 + F- = AlF+2
log_k 7.000
delta_h 1.060 kcal
Al+3 + 2 F- = AlF2+
log_k 12.700
delta_h 1.980 kcal
Al+3 + 3 F- = AlF3
log_k 16.800
delta_h 2.160 kcal
Al+3 + 4 F- = AlF4-
log_k 19.400
delta_h 2.200 kcal
Al+3 + 5 F- = AlF5-2
log_k 20.600
delta_h 1.840 kcal
Al+3 + 6 F- = AlF6-3
log_k 20.600
delta_h -1.670 kcal
H4SiO4 + H2O = H3SiO4- + H3O+
log_k -9.83
delta_h 6.12 kcal
-analytic -302.3724 -0.050698 15669.69 108.18466 -1119669.0
H4SiO4 + 2H2O= H2SiO4-2 + 2 H3O+
log_k -23.0
delta_h 17.6 kcal
-analytic -294.0184 -0.072650 11204.49 108.18466 -1119669.0
H4SiO4 + 4 H3O+ + 6 F- = SiF6-2 + 8 H2O
log_k 30.180
delta_h -16.260 kcal
PHASES
Calcite
CaCO3 = CO3-2 + Ca+2
log_k -8.480
delta_h -2.297 kcal
-analytic -171.9065 -0.077993 2839.319 71.595
Dolomite
CaMg(CO3)2 = Ca+2 + Mg+2 + 2 CO3-2
log_k -17.090
delta_h -9.436 kcal
Siderite
FeCO3 = Fe+2 + CO3-2
log_k -10.890
delta_h -2.480 kcal
Gypsum
CaSO4:2H2O = Ca+2 + SO4-2 + 2 H2O
log_k -4.580
delta_h -0.109 kcal
-analytic 68.2401 0.0 -3221.51 -25.0627
Anhydrite
CaSO4 = Ca+2 + SO4-2
log_k -4.360
delta_h -1.710 kcal
-analytic 197.52 0.0 -8669.8 -69.835
Hydroxyapatite
Ca5(PO4)3OH + 4 H3O+ = 5H2O + 3 HPO4-2 + 5 Ca+2
log_k -3.421
delta_h -36.155 kcal
Fluorite
CaF2 = Ca+2 + 2 F-
log_k -10.600
delta_h 4.690 kcal
-analytic 66.348 0.0 -4298.2 -25.271
SiO2(a)
SiO2 + 2 H2O = H4SiO4
log_k -2.710
delta_h 3.340 kcal
-analytic -0.26 0.0 -731.0
Chalcedony
SiO2 + 2 H2O = H4SiO4
log_k -3.550
delta_h 4.720 kcal
-analytic -0.09 0.0 -1032.0
Quartz
SiO2 + 2 H2O = H4SiO4
log_k -3.980
delta_h 5.990 kcal
-analytic 0.41 0.0 -1309.0
Gibbsite
Al(OH)3 + 3 H3O+ = Al+3 + 6 H2O
log_k 8.110
delta_h -22.800 kcal
Al(OH)3(a)
Al(OH)3 + 3 H3O+ = Al+3 + 6 H2O
log_k 10.800
delta_h -26.500 kcal
Kaolinite
Al2Si2O5(OH)4 + 6 H3O+ = 7H2O + 2 H4SiO4 + 2 Al+3
log_k 7.435
delta_h -35.300 kcal
Albite
NaAlSi3O8 + 8 H2O = Na+ + Al(OH)4- + 3 H4SiO4
log_k -18.002
delta_h 25.896 kcal
Anorthite
CaAl2Si2O8 + 8 H2O = Ca+2 + 2 Al(OH)4- + 2 H4SiO4
log_k -19.714
delta_h 11.580 kcal
K-feldspar
KAlSi3O8 + 8 H2O = K+ + Al(OH)4- + 3 H4SiO4
log_k -20.573
delta_h 30.820 kcal
K-mica
KAl3Si3O10(OH)2 + 10 H3O+ = K+ + 3 Al+3 + 3 H4SiO4 + 10H2O
log_k 12.703
delta_h -59.376 kcal
Chlorite(14A)
Mg5Al2Si3O10(OH)8 + 16 H3O+ = 5Mg+2 + 2Al+3 + 3H4SiO4 + 22H2O
log_k 68.38
delta_h -151.494 kcal
Ca-Montmorillonite
Ca0.165Al2.33Si3.67O10(OH)2 + 14 H2O = 0.165Ca+2 + 2.33 Al(OH)4- + 3.67 H4SiO4 + 2 H3O+
log_k -45.027
delta_h 58.373 kcal
Talc
Mg3Si4O10(OH)2 + 4 H2O + 6 H3O+ = 3 Mg+2 + 4 H4SiO4 + 6H2O
log_k 21.399
delta_h -46.352 kcal
Illite
K0.6Mg0.25Al2.3Si3.5O10(OH)2 + 12.4H2O = 0.6K+ + 0.25Mg+2 + 2.3Al(OH)4- + 3.5H4SiO4 + 1.2H3O+
log_k -40.267
delta_h 54.684 kcal
Chrysotile
Mg3Si2O5(OH)4 + 6 H3O+ = 7H2O + 2 H4SiO4 + 3 Mg+2
log_k 32.200
delta_h -46.800 kcal
-analytic 13.248 0.0 10217.1 -6.1894
Sepiolite
Mg2Si3O7.5OH:3H2O + 4 H3O+ + 0.5H2O = 2 Mg+2 + 3 H4SiO4 + 4H2O
log_k 15.760
delta_h -10.700 kcal
Sepiolite(d)
Mg2Si3O7.5OH:3H2O + 4 H3O+ + 0.5H2O = 2 Mg+2 + 3 H4SiO4 + 4H2O
log_k 18.660
Hematite
Fe2O3 + 6 H3O+ = 2 Fe+3 + 9 H2O
log_k -4.008
delta_h -30.845 kcal
Goethite
FeOOH + 3 H3O+ = Fe+3 + 5 H2O
log_k -1.000
delta_h -14.48 kcal
Fe(OH)3(a)
Fe(OH)3 + 3 H3O+ = Fe+3 + 6 H2O
log_k 4.891
Pyrite
FeS2 + 2H3O+ + 2e- = Fe+2 + 2HS- + 2H2O
log_k -18.479
delta_h 11.300 kcal
FeS(ppt)
FeS + H3O+ = Fe+2 + HS- + H2O
log_k -3.915
Mackinawite
FeS + H3O+ = Fe+2 + HS- + H2O
log_k -4.648
Sulfur
S + 2 H3O+ + 2e- = H2S + 2H2O
log_k 4.882
delta_h -9.5 kcal
Vivianite
Fe3(PO4)2:8H2O = 3 Fe+2 + 2 PO4-3 + 8 H2O
log_k -36.000
Halite
NaCl = Na+ + Cl-
log_k 1.582
delta_h 0.918 kcal
CO2(g)
CO2(g) = CO2
log_k -1.468
delta_h -4.776 kcal
-analytic 108.3865 0.01985076 -6919.53 -40.45154 669365.0
O2(g)
O2 = O2
# log_k -2.960
# delta_h -1.844 kcal
# log K from llnl.dat Dec 8, 2010
log_k -2.8983
-analytic -7.5001e+000 7.8981e-003 0.0000e+000 0.0000e+000 2.0027e+005
H2(g)
H2 = H2
log_k -3.150
delta_h -1.759 kcal
H2O(g)
H2O = H2O
log_k 1.51
delta_h -44.03 kJ
N2(g)
N2 = N2
log_k -3.260
delta_h -1.358 kcal
H2S(g)
H2S = H2S
log_k -0.997
delta_h -4.570 kcal
CH4(g)
CH4 = CH4
log_k -2.860
delta_h -3.373 kcal
NH3(g)
NH3 = NH3
log_k 1.770
delta_h -8.170 kcal
Melanterite
FeSO4:7H2O = 7 H2O + Fe+2 + SO4-2
log_k -2.209
delta_h 4.910 kcal
-analytic 1.447 -0.004153 0.0 0.0 -214949.0
Alunite
KAl3(SO4)2(OH)6 + 6 H3O+ = K+ + 3 Al+3 + 2 SO4-2 + 12H2O
log_k -1.400
delta_h -50.250 kcal
Jarosite-K
KFe3(SO4)2(OH)6 + 6 H3O+ = 3 Fe+3 + 12 H2O + K+ + 2 SO4-2
log_k -9.210
delta_h -31.280 kcal
EXCHANGE_MASTER_SPECIES
X X-
EXCHANGE_SPECIES
X- = X-
log_k 0.0
Na+ + X- = NaX
log_k 0.0
-gamma 4.0 0.075
K+ + X- = KX
log_k 0.7
-gamma 3.5 0.015
delta_h -4.3 # Jardine & Sparks, 1984
NH4+ + X- = NH4X
log_k 0.6
-gamma 2.5 0.0
delta_h -2.4 # Laudelout et al., 1968
Ca+2 + 2X- = CaX2
log_k 0.8
-gamma 5.0 0.165
delta_h 7.2 # Van Bladel & Gheyl, 1980
Mg+2 + 2X- = MgX2
log_k 0.6
-gamma 5.5 0.2
delta_h 7.4 # Laudelout et al., 1968
Fe+2 + 2X- = FeX2
log_k 0.44
-gamma 6.0 0.0
Al+3 + 3X- = AlX3
log_k 0.41
-gamma 9.0 0.0
AlOH+2 + 2X- = AlOHX2
log_k 0.89
-gamma 0.0 0.0
SURFACE_MASTER_SPECIES
Hfo_s Hfo_sOH
Hfo_w Hfo_wOH
SURFACE_SPECIES
# All surface data from
# Dzombak and Morel, 1990
#
#
# Acid-base data from table 5.7
#
# strong binding site--Hfo_s,
Hfo_sOH = Hfo_sOH
log_k 0.0
Hfo_sOH + H3O+ = Hfo_sOH2+ + H2O
log_k 7.29 # = pKa1,int
Hfo_sOH + H2O = Hfo_sO- + H3O+
log_k -8.93 # = -pKa2,int
# weak binding site--Hfo_w
Hfo_wOH = Hfo_wOH
log_k 0.0
Hfo_wOH + H3O+ = Hfo_wOH2+ + H2O
log_k 7.29 # = pKa1,int
Hfo_wOH + H2O = Hfo_wO- + H3O+
log_k -8.93 # = -pKa2,int
###############################################
# CATIONS #
###############################################
#
# Cations from table 10.1 or 10.5
#
# Calcium
Hfo_sOH + Ca+2 = Hfo_sOHCa+2
log_k 4.97
Hfo_wOH + Ca+2 + H2O = Hfo_wOCa+ + H3O+
log_k -5.85
#
# Derived constants table 10.5
#
# Magnesium
Hfo_wOH + Mg+2 + H2O = Hfo_wOMg+ + H3O+
log_k -4.6
# Iron
# Hfo_sOH + Fe+2 + H2O = Hfo_sOFe+ + H3O+
# log_k 0.7 # LFER using table 10.5
# Hfo_wOH + Fe+2 + H2O = Hfo_wOFe+ + H3O+
# log_k -2.5 # LFER using table 10.5
# Iron, strong site: Appelo, Van der Weiden, Tournassat & Charlet, subm.
Hfo_sOH + Fe+2 + H2O = Hfo_sOFe+ + H3O+
log_k -0.95
# Iron, weak site: Liger et al., GCA 63, 2939, re-optimized for D&M
Hfo_wOH + Fe+2 + H2O = Hfo_wOFe+ + H3O+
log_k -2.98
Hfo_wOH + Fe+2 + 3H2O = Hfo_wOFeOH + 2H3O+
log_k -11.55
###############################################
# ANIONS #
###############################################
#
# Anions from table 10.6
#
# Phosphate
Hfo_wOH + PO4-3 + 3 H3O+ = Hfo_wH2PO4 + 4H2O
log_k 31.29
Hfo_wOH + PO4-3 + 2 H3O+ = Hfo_wHPO4- + 3H2O
log_k 25.39
Hfo_wOH + PO4-3 + H3O+ = Hfo_wPO4-2 + 2H2O
log_k 17.72
#
# Anions from table 10.7
#
# Sulfate
Hfo_wOH + SO4-2 + H3O+ = Hfo_wSO4- + 2H2O
log_k 7.78
Hfo_wOH + SO4-2 = Hfo_wOHSO4-2
log_k 0.79
#
# Derived constants table 10.10
#
Hfo_wOH + F- + H3O+ = Hfo_wF + 2H2O
log_k 8.7
Hfo_wOH + F- = Hfo_wOHF-
log_k 1.6
#
# Carbonate: Van Geen et al., 1994 reoptimized for HFO
# 0.15 g HFO/L has 0.344 mM sites == 2 g of Van Geen's Goethite/L
#
# Hfo_wOH + CO3-2 + H3O+ = Hfo_wCO3- + 2H2O
# log_k 12.56
#
# Hfo_wOH + CO3-2 + 2 H3O+= Hfo_wHCO3 + 3 H2O
# log_k 20.62
# 9/19/96
# Added analytical expression for H2S, NH3, KSO4.
# Added species CaHSO4+.
# Added delta H for Goethite.
#
# Begin Isotope definitions
#
###############################################################################################
SOLUTION_MASTER_SPECIES
###############################################################################################
D D2O 0 D 2
D(1) D2O 0 D
D(0) HD 0 D
T HTO 0 T 3
T(1) HTO 0 T
T(0) HT 0 T
[18O] H2[18O] 0 [18O] 18
[18O](-2) H2[18O] 0 [18O] 18
[18O](0) O[18O] 0 [18O] 18
[13C] [13C]O2 0 [13C] 13
[13C](4) [13C]O2 0 [13C]
[13C](-4) [13C]H4 0 [13C]
[14C] [14C]O2 0 [14C] 14
[14C](4) [14C]O2 0 [14C]
[14C](-4) [14C]H4 0 [14C]
[34S] [34S]O4-2 0 [34S] 33.967
[34S](6) [34S]O4-2 0 [34S]
[34S](-2) H[34S]- 0 [34S]
[15N] [15N]O3- 0 [15N] 15.00010897312
[15N](5) [15N]O3- 0 [15N]
[15N](3) [15N]O2- 0 [15N]
[15N](0) N[15N] 0 [15N]
[15N](-3) [15N]H4+ 0 [15N]
###############################################################################################
ISOTOPES
###############################################################################################
H
-isotope D permil 155.76e-6 # VSMOW (Clark and Fritz, 1997)
-isotope T TU 1e-18 # Solomon and Cook, in eds, Cook and Herczeg, 2000
H(0)
-isotope D(0) permil 155.76e-6 # VSMOW (Clark and Fritz, 1997)
-isotope T(0) TU 1e-18 # Solomon and Cook, in eds, Cook and Herczeg, 2000
# 1 THO in 10^18 H2O
# -isotope T pCi/L 3.125e-18 #
#1e-18/3.2 = T/mol H2O
C
-isotope [13C] permil 0.0111802 # VPDB, Vienna Pee Dee Belemnite
# Chang and Li, 1990, Chinese Science Bulletin
-isotope [13C](4) permil 0.0111802 # VPDB, Vienna Pee Dee Belemnite
# Chang and Li, 1990, Chinese Science Bulletin
-isotope [13C](-4) permil 0.0111802 # VPDB, Vienna Pee Dee Belemnite
-isotope [14C] pmc 1.175887709e-12 # Mole fraction of 14C in Modern Carbon
-isotope [14C](4) pmc 1.175887709e-12 # Mole fraction of 14C in Modern Carbon
# 13.56 Modern Carbon dpm (Kalin, in eds, Cook and Herczeg, 2000)
-isotope [14C](-4) pmc 1.175887709e-12 # Mole fraction of 14C in Modern Carbon
C(4)
-isotope [13C](4) permil 0.0111802 # VPDB, Vienna Pee Dee Belemnite
# Chang and Li, 1990, Chinese Science Bulletin
-isotope [14C](4) pmc 1.175887709e-12 # Mole fraction of 14C in Modern Carbon
# 13.56 Modern Carbon dpm (Kalin, in eds, Cook and Herczeg, 2000)
# 13.56 Modern Carbon dpm (Kalin, in eds, Cook and Herczeg, 2000)
C(-4)
-isotope [13C](-4) permil 0.0111802 # VPDB, Vienna Pee Dee Belemnite
-isotope [14C](-4) pmc 1.175887709e-12 # Mole fraction of 14C in Modern Carbon
# 14C calculation
#
# lambda = ln(2)/(5730 yrs * 3.15576e7 sec/yr)
# mole/g carbon = -(dn/dt)/lambda = 0.226 dps / 3.8332476e-12 / 6.022136736e23
# mole C/g C NBS Oxalic Acid with 13C = -19.3: 0.08325783313
# mole 14C/mol Modern Carbon mol/g carbon/ (mole C/g C) = 1.175887709e-12
#
O
-isotope [18O] permil 2005.2e-6 # VSMOW (Clark and Fritz, 1997)
-isotope [18O](0) permil 2005.2e-6 # VSMOW (Clark and Fritz, 1997)
O(0)
-isotope [18O](0) permil 2005.2e-6 # VSMOW (Clark and Fritz, 1997)
S
# Coplen and others, 2002
-isotope [34S] permil 0.04416264 # VCDT, Vienna Canyon Diablo Troilite
-isotope [34S](6) permil 0.04416264 # VCDT
-isotope [34S](-2) permil 0.04416264 # VCDT
S(6)
-isotope [34S](6) permil 0.04416264 # VCDT
S(-2)
-isotope [34S](-2) permil 0.04416264 # VCDT
N
# Coplen and others, 2002
-isotope [15N] permil 0.003676867 # Air
-isotope [15N](5) permil 0.003676867 # Air
-isotope [15N](3) permil 0.003676867 # Air
-isotope [15N](0) permil 0.003676867 # Air
-isotope [15N](-3) permil 0.003676867 # Air
N(5)
-isotope [15N](5) permil 0.003676867 # Air
N(3)
-isotope [15N](3) permil 0.003676867 # Air
N(0)
-isotope [15N](0) permil 0.003676867 # Air
N(-3)
-isotope [15N](-3) permil 0.003676867 # Air
###############################################################################################
ISOTOPE_RATIOS
###############################################################################################
#
# Total aqueous ratios
#
R(D) D
R(T) T
R(18O) [18O]
R(13C) [13C]
R(14C) [14C]
R(15N) [15N]
R(34S) [34S]
# H2O(l) ratios
R(D)_H2O(l) D
R(T)_H2O(l) T
R(18O)_H2O(l) [18O]
# OH- ratios
R(D)_OH- D
R(T)_OH- T
R(18O)_OH- [18O]
# H3O+ ratios
R(D)_H3O+ D
R(T)_H3O+ T
R(18O)_H3O+ [18O]
# O2(aq) ratios
R(18O)_O2(aq) [18O]
# H2(aq) ratios
R(D)_H2(aq) D
R(T)_H2(aq) T
# CO2(aq) ratios
R(13C)_CO2(aq) [13C]
R(14C)_CO2(aq) [14C]
R(18O)_CO2(aq) [18O]
# HCO3- ratios
R(D)_HCO3- D
R(T)_HCO3- T
R(18O)_HCO3- [18O]
R(13C)_HCO3- [13C]
R(14C)_HCO3- [14C]
# CO3-2 ratios
R(18O)_CO3-2 [18O]
R(13C)_CO3-2 [13C]
R(14C)_CO3-2 [14C]
# CH4(aq) ratios
R(D)_CH4(aq) D
R(T)_CH4(aq) T
R(13C)_CH4(aq) [13C]
R(14C)_CH4(aq) [14C]
# SO4-2 ratios
R(34S)_SO4-2 [34S]
# HSO4- ratios
R(D)_HSO4- D
R(T)_HSO4- T
R(34S)_HSO4- [34S]
# S-2 ratios
R(34S)_S-2 [34S]
# HS- ratios
R(D)_HS- D
R(T)_HS- T
R(34S)_HS- [34S]
# H2S ratios
R(D)_H2S(aq) D
R(T)_H2S(aq) T
R(34S)_H2S(aq) [34S]
# NO3- ratios
R(15N)_NO3- [15N]
# NO2- ratios
R(15N)_NO2- [15N]
# N2(aq) ratios
R(15N)_N2(aq) [15N]
# NH3(aq) ratios
R(D)_NH3(aq) D
R(T)_NH3(aq) T
R(15N)_NH3(aq) [15N]
# NH4+ ratios
R(D)_NH4+ D
R(T)_NH4+ T
R(15N)_NH4+ [15N]
#
# Ratios for minerals and gases
#
# H2O(g) ratios
R(D)_H2O(g) D
R(T)_H2O(g) T
R(18O)_H2O(g) [18O]
# O2(g) ratios
R(18O)_O2(g) [18O]
# H2(g) ratios
R(D)_H2(g) D
R(T)_H2(g) T
# CO2(g) ratios
R(18O)_CO2(g) [18O]
R(13C)_CO2(g) [13C]
R(14C)_CO2(g) [14C]
# Calcite ratios
R(18O)_Calcite [18O]
R(13C)_Calcite [13C]
R(14C)_Calcite [14C]
# Pyrite ratios
R(34S)_Pyrite [34S]
# CH4(g) ratios
R(D)_CH4(g) D
R(T)_CH4(g) T
R(13C)_CH4(g) [13C]
R(14C)_CH4(g) [14C]
# H2S(g) ratios
R(D)_H2S(g) D
R(T)_H2S(g) T
R(34S)_H2S(g) [34S]
# Gypsum ratios
R(34S)_Gypsum [34S]
# Anhydrite ratios
R(34S)_Anhydrite [34S]
# N2(g) ratios
R(15N)_N2(g) [15N]
# NH3(g) ratios
R(D)_NH3(g) D
R(T)_NH3(g) T
R(15N)_NH3(g) [15N]
ISOTOPE_ALPHAS
# OH-
Alpha_D_OH-/H2O(l) Log_alpha_D_OH-/H2O(l)
Alpha_T_OH-/H2O(l) Log_alpha_T_OH-/H2O(l)
Alpha_18O_OH-/H2O(l) Log_alpha_18O_OH-/H2O(l)
# H3O+
Alpha_D_H3O+/H2O(l) Log_alpha_D_H3O+/H2O(l)
Alpha_T_H3O+/H2O(l) Log_alpha_T_H3O+/H2O(l)
Alpha_18O_H3O+/H2O(l) Log_alpha_18O_H3O+/H2O(l)
# O2(aq)
Alpha_18O_O2(aq)/H2O(l) Log_alpha_18O_O2(aq)/H2O(l)
# H2(aq)
Alpha_D_H2(aq)/H2O(l) Log_alpha_D_H2(aq)/H2O(l)
Alpha_T_H2(aq)/H2O(l) Log_alpha_T_H2(aq)/H2O(l)
# CO2(aq)
Alpha_18O_CO2(aq)/H2O(l) Log_alpha_18O_CO2(aq)/H2O(l)
Alpha_13C_CO2(aq)/CO2(g) Log_alpha_13C_CO2(aq)/CO2(g)
Alpha_14C_CO2(aq)/CO2(g) Log_alpha_14C_CO2(aq)/CO2(g)
# HCO3-
Alpha_D_HCO3-/H2O(l) Log_alpha_D_HCO3-/H2O(l)
Alpha_T_HCO3-/H2O(l) Log_alpha_T_HCO3-/H2O(l)
Alpha_18O_HCO3-/H2O(l) Log_alpha_18O_HCO3-/H2O(l)
Alpha_13C_HCO3-/CO2(aq) Log_alpha_13C_HCO3-/CO2(aq)
Alpha_14C_HCO3-/CO2(aq) Log_alpha_14C_HCO3-/CO2(aq)
Alpha_13C_HCO3-/CO2(g) Log_alpha_13C_HCO3-/CO2(g)
Alpha_14C_HCO3-/CO2(g) Log_alpha_14C_HCO3-/CO2(g)
# CO3-2
Alpha_18O_CO3-2/H2O(l) Log_alpha_18O_CO3-2/H2O(l)
Alpha_13C_CO3-2/CO2(aq) Log_alpha_13C_CO3-2/CO2(aq)
Alpha_14C_CO3-2/CO2(aq) Log_alpha_14C_CO3-2/CO2(aq)
Alpha_13C_CO3-2/CO2(g) Log_alpha_13C_CO3-2/CO2(g)
Alpha_14C_CO3-2/CO2(g) Log_alpha_14C_CO3-2/CO2(g)
# CH4(aq)
Alpha_D_CH4(aq)/H2O(l) Log_alpha_D_CH4(aq)/H2O(l)
Alpha_T_CH4(aq)/H2O(l) Log_alpha_T_CH4(aq)/H2O(l)
Alpha_13C_CH4(aq)/CO2(aq) Log_alpha_13C_CH4(aq)/CO2(aq)
Alpha_14C_CH4(aq)/CO2(aq) Log_alpha_14C_CH4(aq)/CO2(aq)
# HSO4-
Alpha_D_HSO4-/H2O(l) Log_alpha_D_HSO4-/H2O(l)
Alpha_T_HSO4-/H2O(l) Log_alpha_T_HSO4-/H2O(l)
Alpha_34S_HSO4-/SO4-2 Log_alpha_34S_HSO4-/SO4-2
# S-2
Alpha_34S_S-2/HS- Log_alpha_34S_S-2/HS-
# HS-
Alpha_D_HS-/H2O(l) Log_alpha_D_HS-/H2O(l)
Alpha_T_HS-/H2O(l) Log_alpha_T_HS-/H2O(l)
Alpha_34S_HS-/SO4-2 Log_alpha_34S_HS-/SO4-2
# H2S
Alpha_D_H2S(aq)/H2O(l) Log_alpha_D_H2S(aq)/H2O(l)
Alpha_T_H2S(aq)/H2O(l) Log_alpha_T_H2S(aq)/H2O(l)
Alpha_34S_H2S(aq)/HS- Log_alpha_34S_H2S(aq)/HS-
# NO2-
Alpha_15N_NO2-/NO3- Log_alpha_15N_NO2-/NO3-
# N2(aq)
Alpha_15N_N2(aq)/NO3- Log_alpha_15N_N2(aq)/NO3-
# NH3(aq)
Alpha_D_NH3(aq)/H2O(l) Log_alpha_D_NH3(aq)/H2O(l)
Alpha_T_NH3(aq)/H2O(l) Log_alpha_T_NH3(aq)/H2O(l)
Alpha_15N_NH3(aq)/NO3- Log_alpha_15N_NH3(aq)/NO3-
# NH4+
Alpha_D_NH4+/H2O(l) Log_alpha_D_NH4+/H2O(l)
Alpha_T_NH4+/H2O(l) Log_alpha_T_NH4+/H2O(l)
Alpha_15N_NH4+/NH3(aq) Log_alpha_15N_NH4+/NH3(aq)
# H2O(g)
Alpha_D_H2O(g)/H2O(l) Log_alpha_D_H2O(g)/H2O(l)
Alpha_T_H2O(g)/H2O(l) Log_alpha_T_H2O(g)/H2O(l)
Alpha_18O_H2O(g)/H2O(l) Log_alpha_18O_H2O(g)/H2O(l)
# O2(g)
Alpha_18O_O2(g)/H2O(l) Log_alpha_18O_O2(g)/H2O(l) #?
# H2(g)
Alpha_D_H2(g)/H2O(l) Log_alpha_D_H2(g)/H2O(l) #?
Alpha_T_H2(g)/H2O(l) Log_alpha_T_H2(g)/H2O(l) #?
# CO2(g)
Alpha_18O_CO2(g)/H2O(l) Log_alpha_18O_CO2(g)/H2O(l)
Alpha_13C_CO2(g)/CO2(aq) Log_alpha_13C_CO2(g)/CO2(aq)
Alpha_14C_CO2(g)/CO2(aq) Log_alpha_14C_CO2(g)/CO2(aq)
# Calcite
Alpha_18O_Calcite/H2O(l) Log_alpha_18O_Calcite/H2O(l)
Alpha_13C_Calcite/CO2(aq) Log_alpha_13C_Calcite/CO2(aq)
Alpha_13C_Calcite/CO2(g) Log_alpha_13C_Calcite/CO2(g)
Alpha_14C_Calcite/CO2(aq) Log_alpha_14C_Calcite/CO2(aq)
Alpha_14C_Calcite/CO2(g) Log_alpha_14C_Calcite/CO2(g)
# Pyrite
Alpha_34S_Pyrite/HS- Log_alpha_34S_Pyrite/HS-
# CH4(g)
Alpha_D_CH4(g)/H2O(l) Log_alpha_D_CH4(g)/H2O(l)
Alpha_T_CH4(g)/H2O(l) Log_alpha_T_CH4(g)/H2O(l)
Alpha_13C_CH4(g)/CO2(aq) Log_alpha_13C_CH4(g)/CO2(aq) #?
Alpha_14C_CH4(g)/CO2(aq) Log_alpha_14C_CH4(g)/CO2(aq) #?
# H2S(g)
Alpha_D_H2S(g)/H2S(aq) Log_alpha_D_H2S(g)/H2S(aq)
Alpha_T_H2S(g)/H2S(aq) Log_alpha_T_H2S(g)/H2S(aq)
Alpha_34S_H2S(g)/H2S(aq) Log_alpha_34S_H2S(g)/H2S(aq)
# Gypsum
Alpha_34S_Gypsum/SO4-2 Log_alpha_34S_Gypsum/SO4-2
# Anhydrite
Alpha_34S_Anhydrite/SO4-2 Log_alpha_34S_Anhydrite/SO4-2
# N2(g)
Alpha_15N_N2(g)/N2(aq) Log_alpha_15N_N2(g)/N2(aq)
# NH3(g)
Alpha_D_NH3(g)/H2O(l) Log_alpha_D_NH3(g)/H2O(l)
#Alpha_T_NH3(g)/H2O(l) Log_alpha_T_NH3(g)/H2O(l)
Alpha_15N_NH3(g)/NH3(aq) Log_alpha_15N_NH3(g)/NH3(aq)
NAMED_EXPRESSIONS
#
# OH- fractionation factors
#
Log_alpha_D_OH-/H2O(l) # 1000ln(alpha(25C)) = -1435
# 13.5 C
-ln_alpha1000 -1435.0
Log_alpha_T_OH-/H2O(l) # 1000ln(alpha(25C)) = -2870
# 13.5 C
-ln_alpha1000 -2870.0
Log_alpha_18O_OH-/H2O(l) # 1000ln(alpha(25C)) = -37.8
# 25 C
-ln_alpha1000 -37.777
#
# H3O- fractionation factors
#
Log_alpha_D_H3O+/H2O(l) # 1000ln(alpha(25C)) = 40.8
# 13.5 C
-ln_alpha1000 40.82
Log_alpha_T_H3O+/H2O(l) # 1000ln(alpha(25C)) = 81.6
# 13.5 C
-ln_alpha1000 81.64
Log_alpha_18O_H3O+/H2O(l) # 1000ln(alpha(25C)) = 22.9
# 25 C
-ln_alpha1000 22.86
#
# O2(aq) fractionation factors
#
Log_alpha_18O_O2(aq)/H2O(l)
-ln_alpha1000 0.0
#
# H2(aq) fractionation factors
#
Log_alpha_D_H2(aq)/H2O(l)
-ln_alpha1000 0
Log_alpha_T_H2(aq)/H2O(l)
-ln_alpha1000 0
#
# CO2(aq) fractionation factors
#
Log_alpha_18O_CO2(aq)/H2O(l) # 1000ln(alpha(25C)) = 41.2
# 0-100 C
-ln_alpha1000 -21.9285 0.0 19.43596e3 0.0 -0.181115e6
Log_alpha_13C_CO2(aq)/CO2(g) # 1000ln(alpha(25C)) -0.84
# Deines and others (1974)
-ln_alpha1000 -0.91 0.0 0.0 0.0 .0063e6
Log_alpha_14C_CO2(aq)/CO2(g) # 1000ln(alpha(25C)) -0.84
-add_logk Log_alpha_13C_CO2(aq)/CO2(g) 2
#
# HCO3- fractionation factors
#
Log_alpha_18O_HCO3-/H2O(l)
-ln_alpha1000 0.0 #?
Log_alpha_D_HCO3-/H2O(l)
-ln_alpha1000 0.0
Log_alpha_T_HCO3-/H2O(l)
-ln_alpha1000 0.0
Log_alpha_13C_HCO3-/CO2(g) # 1000ln(alpha(25C)) = 7.82
# Deines and others (1974)
-ln_alpha1000 -4.54 0.0 0.0 0.0 1.099e6
Log_alpha_13C_HCO3-/CO2(aq) # 1000ln(alpha(25C)) = 8.7
# 0-100 C
# -ln_alpha1000 -3.63 0.0 0.0 0.0 1.0927e6
-add_logk Log_alpha_13C_HCO3-/CO2(g) 1
-add_logk Log_alpha_13C_CO2(aq)/CO2(g) -1
Log_alpha_14C_HCO3-/CO2(g) # 1000ln(alpha(25C)) = 7.82
# Deines and others (1974)
-add_logk Log_alpha_13C_HCO3-/CO2(g) 2
Log_alpha_14C_HCO3-/CO2(aq) # 1000ln(alpha(25C)) = 17.3
# 0-100 C
# -ln_alpha1000 -7.26 0.0 0.0 0.0 2.1854e6
-add_logk Log_alpha_14C_HCO3-/CO2(g) 1
-add_logk Log_alpha_14C_CO2(aq)/CO2(g) -1
#
# CO3-2 fractionation factors
#
Log_alpha_18O_CO3-2/H2O(l)
-ln_alpha1000 0.0
Log_alpha_13C_CO3-2/CO2(g) # 1000ln(alpha(25C))
# Deines and others (1974)
-ln_alpha1000 -3.4 0.0 0.0 0.0 0.870e6
Log_alpha_13C_CO3-2/CO2(aq) # 1000ln(alpha(25C))
# 0-100 C
# -ln_alpha1000 -2.49 0.0 0.0 0.0 0.8637e6
-add_logk Log_alpha_13C_CO3-2/CO2(g) 1
-add_logk Log_alpha_13C_CO2(aq)/CO2(g) -1
Log_alpha_14C_CO3-2/CO2(g) # 1000ln(alpha(25C))
# Deines and others (1974)
-add_logk Log_alpha_13C_CO3-2/CO2(g) 2
Log_alpha_14C_CO3-2/CO2(aq) # 1000ln(alpha(25C))
#
# -ln_alpha1000 -2.49 0.0 0.0 0.0 0.8637e6
-add_logk Log_alpha_14C_CO3-2/CO2(g) 1
-add_logk Log_alpha_14C_CO2(aq)/CO2(g) -1
#
# CH4(aq) fractionation factors
#
Log_alpha_D_CH4(aq)/H2O(l)
-ln_alpha1000 0
Log_alpha_T_CH4(aq)/H2O(l)
-ln_alpha1000 0
Log_alpha_13C_CH4(aq)/CO2(aq)
-ln_alpha1000 0
Log_alpha_14C_CH4(aq)/CO2(aq)
-ln_alpha1000 0
#
# HSO4- fractionation factors
#
Log_alpha_D_HSO4-/H2O(l)
-ln_alpha1000 0
Log_alpha_T_HSO4-/H2O(l)
-ln_alpha1000 0
Log_alpha_34S_HSO4-/SO4-2
-ln_alpha1000 0.0
#
# S-2 fractionation factors
#
Log_alpha_34S_S-2/HS-
-ln_alpha1000 0.0
#
# HS- fractionation factors
#
Log_alpha_D_HS-/H2O(l)
-ln_alpha1000 0
Log_alpha_T_HS-/H2O(l)
-ln_alpha1000 0
Log_alpha_34S_HS-/SO4-2
-ln_alpha1000 0.0
#
# H2S fractionation factors
#
Log_alpha_D_H2S(aq)/H2O(l)
-ln_alpha1000 0
Log_alpha_T_H2S(aq)/H2O(l)
-ln_alpha1000 0
Log_alpha_34S_H2S(aq)/HS-
-ln_alpha1000 0.0
#
# NO2- fractionation factors
#
Log_alpha_15N_NO2-/NO3-
-ln_alpha1000 0.0
#
# N2(aq) fractionation factors
#
Log_alpha_15N_N2(aq)/NO3-
-ln_alpha1000 0.0
#
# NH3(aq) fractionation factors
#
Log_alpha_D_NH3(aq)/H2O(l)
-ln_alpha1000 0
Log_alpha_T_NH3(aq)/H2O(l)
-ln_alpha1000 0
Log_alpha_15N_NH3(aq)/NO3-
-ln_alpha1000 0
#
# NH4+ fractionation factors
#
Log_alpha_D_NH4+/H2O(l)
-ln_alpha1000 0
Log_alpha_T_NH4+/H2O(l)
-ln_alpha1000 0
Log_alpha_15N_NH4+/NH3(aq)
-ln_alpha1000 0
#
# H2O(g) fractionation factors
#
Log_alpha_D_H2O(g)/H2O(l) # 1000ln(alpha(25C)) = -76.4
# 0-100 C
-ln_alpha1000 -52.612 0.0 76.248e3 0.0 -24.844e6
Log_alpha_T_H2O(g)/H2O(l) # 1000ln(alpha(25C)) = -152.7
# 0-100 C
-ln_alpha1000 -105.224 0.0 152.496e3 0.0 -49.688e6
Log_alpha_18O_H2O(g)/H2O(l) # 1000ln(alpha(25C)) = -9.3
# 0-100 C
-ln_alpha1000 2.0667 0.0 0.4156e3 0.0 -1.137e6
#
# O2(g) fractionaton factors
#
Log_alpha_18O_O2(g)/H2O(l)
-ln_alpha1000 0.0
#
# H2(g) fractionaton factors
#
Log_alpha_D_H2(g)/H2O(l)
-ln_alpha1000 0
Log_alpha_T_H2(g)/H2O(l)
-ln_alpha1000 0
#
# CO2(g) fractionaton factors
#
Log_alpha_18O_CO2(g)/H2O(l) # 1000ln(alpha(25C)) = 40.151
# 0-100 C
-ln_alpha1000 -19.97 0.0 17.9942e3 0.0 -0.0206e6
# Battinga, written commun. 1973, cited in Friedman and O'Neill
Log_alpha_13C_CO2(g)/CO2(aq) # 1000ln(alpha(25C)) = 0.84
# 0-100 C
-ln_alpha1000 0.91 0.0 0.0 0.0 -0.0063e6
Log_alpha_14C_CO2(g)/CO2(aq) # 1000ln(alpha(25C)) = 1.7
# 0-100 C
-ln_alpha1000 1.82 0.0 0.0 0.0 -0.0126e6
#
# CO2-Calcite fractionation factors
#
#Log_alpha_18O_CO2(aq)/Calcite # 1000ln(alpha(25C)) = 13.6
# # 0-100 C
# -ln_alpha1000 -4.7383 0.0 12.05276e3 0.0 -1.963915e6
Log_alpha_18O_Calcite/H2O(l) # 1000ln(alpha(25C)) = 28.38
# O'Neil, Clayton and Mayeda (1969)
-ln_alpha1000 -2.89 0 0 0 2.78e6
Log_alpha_13C_Calcite/CO2(g) # 1000ln(alpha(25C))
# Deines and others (1974)
-ln_alpha1000 -3.63 0.0 0.0 0.0 1.194e6
Log_alpha_13C_Calcite/CO2(aq) # 1000ln(alpha(25C))
# Deines and others (1974)
-add_logk Log_alpha_13C_Calcite/CO2(g) 1
-add_logk Log_alpha_13C_CO2(aq)/CO2(g) -1
Log_alpha_14C_Calcite/CO2(g) # 1000ln(alpha(25C))
-add_logk Log_alpha_13C_Calcite/CO2(g) 2
Log_alpha_14C_Calcite/CO2(aq) # 1000ln(alpha(25C))
# Deines and others (1974)
-add_logk Log_alpha_14C_Calcite/CO2(g) 1
-add_logk Log_alpha_14C_CO2(aq)/CO2(g) -1
#
# Pyrite fractionation factors
#
Log_alpha_34S_Pyrite/HS-
-ln_alpha1000 0
#
# CH4(g) fractionation factors
#
Log_alpha_D_CH4(g)/H2O(l) #?
-ln_alpha1000 0.0
Log_alpha_T_CH4(g)/H2O(l) #?
-ln_alpha1000 0.0
Log_alpha_13C_CH4(g)/CO2(aq) #?
-ln_alpha1000 0.0
Log_alpha_14C_CH4(g)/CO2(aq) #?
-ln_alpha1000 0.0
#
# H2S(g) fractionation factors
#
Log_alpha_D_H2S(g)/H2S(aq)
-ln_alpha1000 0
Log_alpha_T_H2S(g)/H2S(aq)
-ln_alpha1000 0
Log_alpha_34S_H2S(g)/H2S(aq)
-ln_alpha1000 0
#
# Gypsum fractionation factors
#
Log_alpha_34S_Gypsum/SO4-2
-ln_alpha1000 0
#
# Anhydrite fractionation factors
#
Log_alpha_34S_Anhydrite/SO4-2
-ln_alpha1000 0
#
# N2(g) fractionation factors
#
Log_alpha_15N_N2(g)/N2(aq)
-ln_alpha1000 0
#
# NH3(g) fractionation factors
#
Log_alpha_D_NH3(g)/H2O(l) #?
-ln_alpha1000 0
Log_alpha_T_NH3(g)/H2O(l) #?
-ln_alpha1000 0
Log_alpha_15N_NH3(g)/NH3(aq)
-ln_alpha1000 0
###############################################################################################
CALCULATE_VALUES
###############################################################################################
#
# Ratios
#
R(D)
-start
10 ratio = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 100
30 total_D = TOT("D")
40 total_H = TOT("H")
50 ratio = total_D/total_H
100 save ratio
-end
R(T) ??
-start
10 ratio = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 100
30 total_T = TOT("T")
40 total_water = MOL("H2O")
50 ratio = total_T/total_water
100 save ratio
-end
R(18O)
-start
10 ratio = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 100
30 total_18O = TOT("[18O]")
40 total_16O = TOT("O")
50 ratio = total_18O/total_16O
100 save ratio
-end
R(13C)
-start
10 ratio = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 100
30 total_13C = TOT("[13C]")
40 total_12C = TOT("C")
50 ratio = total_13C/total_12C
100 save ratio
-end
R(14C)
-start
10 ratio = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 100
30 total_14C = TOT("[14C]")
40 total_C = TOT("C")
50 ratio = total_14C/total_C
100 save ratio
-end
R(15N)
-start
10 ratio = -9999.999
20 if (TOT("[15N]") <= 0) THEN GOTO 100
30 total_15N = TOT("[15N]")
40 total_14N = TOT("N")
50 ratio = total_15N/total_14N
100 save ratio
-end
R(34S)
-start
10 ratio = -9999.999
20 if (TOT("[34S]") <= 0) THEN GOTO 100
30 total_34S = TOT("[34S]")
40 total_32S = TOT("S")
50 ratio = total_34S/total_32S
100 save ratio
-end
#
# H2O(l) ratios
#
R(D)_H2O(l)
-start
10 ratio = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 100
30 total_D = sum_species("{H,D,T}2{O,[18O]}","D")
40 total_H = sum_species("{H,D,T}2{O,[18O]}","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_D/total_H
100 save ratio
-end
R(T)_H2O(l)
-start
10 ratio = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 100
30 total_T = sum_species("{H,D,T}2{O,[18O]}","T")
40 total_H = sum_species("{H,D,T}2{O,[18O]}","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_T/total_H
100 save ratio
-end
R(18O)_H2O(l)
-start
10 ratio = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 100
30 total_18O = sum_species("{H,D,T}2[18O]","[18O]")
40 total_16O = sum_species("{H,D,T}2O","O")
50 if (total_16O <= 0) THEN GOTO 100
60 ratio = total_18O/total_16O
100 save ratio
-end
#
# OH- ratios
#
R(D)_OH-
-start
10 ratio = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 100
30 total_D = sum_species("*{O,[18O]}D*","D")
40 total_H = sum_species("*{O,[18O]}H*","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_D/total_H
100 save ratio
-end
R(T)_OH-
-start
10 ratio = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 100
30 total_T = sum_species("*{O,[18O]}T*","T")
40 total_H = sum_species("*{O,[18O]}H*","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_T/total_H
100 save ratio
-end
R(18O)_OH-
-start
10 ratio = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 100
30 total_18O = sum_species("*[18O]{H,D,T}*","[18O]")
40 total_16O = sum_species("*O{H,D,T}*","O")
50 ratio = total_18O/total_16O
100 save ratio
-end
#
# H3O+ ratios
#
R(D)_H3O+
-start
10 ratio = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 100
30 total_D = sum_species("{H,D,T}3{O,[18O]}+","D")
40 total_H = sum_species("{H,D,T}3{O,[18O]}+","H")
50 ratio = total_D/total_H
100 save ratio
-end
R(T)_H3O+
-start
10 ratio = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 100
30 total_T = sum_species("{H,D,T}3{O,[18O]}+","T")
40 total_H = sum_species("{H,D,T}3{O,[18O]}+","H")
50 ratio = total_T/total_H
100 save ratio
-end
R(18O)_H3O+
-start
10 ratio = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 100
30 total_18O = sum_species("{H,D,T}3{O,[18O]}+","[18O]")
40 total_16O = sum_species("{H,D,T}3{O,[18O]}+","O")
50 ratio = total_18O/total_16O
100 save ratio
-end
#
# O2(aq) ratios
#
R(18O)_O2(aq)
-start
10 ratio = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 100
30 total_18O = sum_species("{O,[18O]}2","[18O]")
40 total_O = sum_species("{O,[18O]}2","O")
50 if (total_O <= 0) THEN GOTO 100
60 ratio = total_18O/total_O
100 save ratio
-end
#
# H2(aq) ratios
#
R(D)_H2(aq)
-start
10 ratio = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 100
30 total_D = sum_species("{H,D,T}2","D")
40 total_H = sum_species("{H,D,T}2","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_D/total_H
100 save ratio
-end
R(T)_H2(aq)
-start
10 ratio = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 100
30 total_T = sum_species("{H,D,T}2","T")
40 total_H = sum_species("{H,D,T}2","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_T/total_H
100 save ratio
-end
#
# CO2(aq) ratios
#
R(13C)_CO2(aq)
-start
10 ratio = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 100
30 total_13C = sum_species("[13C]{O,[18O]}2","[13C]")
40 total_12C = sum_species("C{O,[18O]}2","C")
50 if (total_12C <= 0) THEN GOTO 100
60 ratio = total_13C/total_12C
100 save ratio
-end
R(14C)_CO2(aq)
-start
10 ratio = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 100
30 total_14C = sum_species("[14C]{O,[18O]}2","[14C]")
40 total_12C = sum_species("C{O,[18O]}2","C")
50 if (total_12C <= 0) THEN GOTO 100
60 ratio = total_14C/total_12C
100 save ratio
-end
R(18O)_CO2(aq)
-start
10 ratio = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 100
30 if (TOT("C") <= 0) THEN GOTO 100
40 total_18O = sum_species("{C,[13C],[14C]}{O,[18O]}2","[18O]")
50 total_16O = sum_species("{C,[13C],[14C]}{O,[18O]}2","O")
60 if (total_16O <= 0) THEN GOTO 100
70 ratio = total_18O/total_16O
100 save ratio
-end
#
# HCO3- ratios
#
R(D)_HCO3-
-start
10 ratio = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 100
30 if (TOT("C") <= 0) THEN GOTO 100
40 total_D = sum_species("*D{C,[13C],[14C]}{O,[18O]}3*","D")
50 total_H = sum_species("*H{C,[13C],[14C]}{O,[18O]}3*","H")
60 if (total_H <= 0) THEN GOTO 100
70 ratio = total_D/total_H
100 save ratio
-end
R(T)_HCO3-
-start
10 ratio = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 100
30 if (TOT("C") <= 0) THEN GOTO 100
40 total_T = sum_species("*T{C,[13C],[14C]}{O,[18O]}3*","T")
50 total_H = sum_species("*H{C,[13C],[14C]}{O,[18O]}3*","H")
60 if (total_H <= 0) THEN GOTO 100
70 ratio = total_T/total_H
100 save ratio
-end
R(18O)_HCO3-
-start
10 ratio = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 100
30 if (TOT("C") <= 0) THEN GOTO 100
40 total_18O = sum_species("*{H,D,T}{C,[13C],[14C]}{O,[18O]}3*","[18O]")
50 total_16O = sum_species("*{H,D,T}{C,[13C],[14C]}{O,[18O]}3*","O")
60 if (total_16O <= 0) THEN GOTO 100
70 ratio = total_18O/total_16O
100 save ratio
-end
R(13C)_HCO3-
-start
10 ratio = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 100
30 total_13C = sum_species("*{H,D,T}[13C]{O,[18O]}3*","[13C]")
40 total_12C = sum_species("*{H,D,T}C{O,[18O]}3*","C")
50 if (total_12C <= 0) THEN GOTO 100
60 ratio = total_13C/total_12C
100 save ratio
-end
R(14C)_HCO3-
-start
10 ratio = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 100
30 total_14C = sum_species("*{H,D,T}[14C]{O,[18O]}3*","[14C]")
40 total_12C = sum_species("*{H,D,T}C{O,[18O]}3*","C")
50 if (total_12C <= 0) THEN GOTO 100
60 ratio = total_14C/total_12C
100 save ratio
-end
#
# CO3-2 ratios
#
R(18O)_CO3-2
-start
10 ratio = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 100
30 if (TOT("C") <= 0) THEN GOTO 100
40 total_18O = sum_species("*{C,[13C],[14C]}{O,[18O]}3*","[18O]") - sum_species("*{H,D,T}{C,[13C],[14C]}{O,[18O]}3*","[18O]")
50 total_16O = sum_species("*{C,[13C],[14C]}{O,[18O]}3*","O") - sum_species("*{H,D,T}{C,[13C],[14C]}{O,[18O]}3*","O")
60 if (total_16O <= 0) THEN GOTO 100
70 ratio = total_18O/total_16O
100 save ratio
-end
R(13C)_CO3-2
-start
10 ratio = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 100
30 total_13C = sum_species("*[13C]{O,[18O]}3*","[13C]") - sum_species("*{H,D,T}[13C]{O,[18O]}3*","[13C]")
40 total_12C = sum_species("*C{O,[18O]}3*","C") - sum_species("*{H,D,T}C{O,[18O]}3*","C")
50 if (total_12C <= 0) THEN GOTO 100
60 ratio = total_13C/total_12C
100 save ratio
-end
R(14C)_CO3-2
-start
10 ratio = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 100
30 total_14C = sum_species("*[14C]{O,[18O]}3*","[14C]") - sum_species("*{H,D,T}[14C]{O,[18O]}3*","[14C]")
40 total_12C = sum_species("*C{O,[18O]}3*","C") - sum_species("*{H,D,T}C{O,[18O]}3*","C")
50 if (total_12C <= 0) THEN GOTO 100
60 ratio = total_14C/total_12C
100 save ratio
-end
#
# CH4(aq) ratios
#
R(D)_CH4(aq)
-start
10 ratio = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 100
30 total_D = sum_species("{C,[13C],[14C]}{H,D,T}4","D")
40 total_H = sum_species("{C,[13C],[14C]}{H,D,T}4","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_D/total_H
100 save ratio
-end
R(T)_CH4(aq)
-start
10 ratio = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 100
30 total_T = sum_species("{C,[13C],[14C]}{H,D,T}4","T")
40 total_H = sum_species("{C,[13C],[14C]}{H,D,T}4","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_T/total_H
100 save ratio
-end
R(13C)_CH4(aq)
-start
10 ratio = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 100
30 total_13C = sum_species("[13C]{H,D,T}4","[13C]")
40 total_C = sum_species("C{H,D,T}4","C")
50 if (total_C <= 0) THEN GOTO 100
60 ratio = total_13C/total_C
100 save ratio
-end
R(14C)_CH4(aq)
-start
10 ratio = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 100
30 total_14C = sum_species("[14C]{H,D,T}4","[14C]")
40 total_C = sum_species("C{H,D,T}4","C")
50 if (total_C <= 0) THEN GOTO 100
60 ratio = total_14C/total_C
100 save ratio
-end
#
# SO4-2 ratios
#
R(34S)_SO4-2
-start
10 ratio = -9999.999
20 if (TOT("[34S]") <= 0) THEN GOTO 100
30 total_34S = sum_species("*[34S]O4*","[34S]") - sum_species("*{H,D,T}[34S]O4*","[34S]")
40 total_S = sum_species("*SO4*","S") - sum_species("*{H,D,T}SO4*","S")
50 if (total_S <= 0) THEN GOTO 100
60 ratio = total_34S/total_S
100 save ratio
-end
#
# HSO4- ratios
#
R(D)_HSO4-
-start
10 ratio = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 100
30 total_D = sum_species("*D{S,[34S]}O4*","D")
40 total_H = sum_species("*H{S,[34S]}O4*","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_D/total_H
100 save ratio
-end
R(T)_HSO4-
-start
10 ratio = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 100
30 total_T = sum_species("*T{S,[34S]}O4*","T")
40 total_H = sum_species("*H{S,[34S]}O4*","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_T/total_H
100 save ratio
-end
R(34S)_HSO4-
-start
10 ratio = -9999.999
20 if (TOT("[34S]") <= 0) THEN GOTO 100
30 total_34S = sum_species("*{H,D,T}[34S]O4*","[34S]")
40 total_S = sum_species("*{H,D,T}SO4*","S")
50 if (total_S <= 0) THEN GOTO 100
60 ratio = total_34S/total_S
100 save ratio
-end
#
# S-2 ratios
#
R(34S)_S-2
-start
10 ratio = -9999.999
20 if (TOT("[34S](-2)") <= 0) THEN GOTO 100
30 total_34S = MOL("[34S]-2")
40 total_S = MOL("S-2")
50 if (total_S <= 0) THEN GOTO 100
60 ratio = total_34S/total_S
100 save ratio
-end
#
# HS- ratios
#
R(D)_HS-
-start
10 ratio = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 100
30 total_D = sum_species("*D{S,[34S]}*","D") - sum_species("*D{S,[34S]}O4*","D")
40 total_H = sum_species("*H{S,[34S]}*","H") - sum_species("*H{S,[34S]}O4*","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_D/total_H
100 save ratio
-end
R(T)_HS-
-start
10 ratio = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 100
30 total_T = sum_species("*T{S,[34S]}*","T") - sum_species("*T{S,[34S]}O4*","T")
40 total_H = sum_species("*H{S,[34S]}*","H") - sum_species("*H{S,[34S]}O4*","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_T/total_H
100 save ratio
-end
R(34S)_HS-
-start
10 ratio = -9999.999
20 if (TOT("[34S]") <= 0) THEN GOTO 100
30 total_34S = sum_species("*{H,D,T}[34S]*","[34S]") - sum_species("*{H,D,T}[34S]O4*","[34S]")
40 total_S = sum_species("*{H,D,T}S*","S") - sum_species("*{H,D,T}SO4*","S")
50 if (total_S <= 0) THEN GOTO 100
60 ratio = total_34S/total_S
100 save ratio
-end
#
# H2S ratios
#
R(D)_H2S(aq)
-start
10 ratio = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 100
30 total_D = sum_species("*{H,D,T}2{S,[34S]}*","D") - sum_species("*{H,D,T}2{S,[34S]}O4*","D")
40 total_S = sum_species("*{H,D,T}2{S,[34S]}*","H") - sum_species("*{H,D,T}2{S,[34]}SO4*","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_D/total_H
100 save ratio
-end
R(T)_H2S(aq)
-start
10 ratio = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 100
30 total_T = sum_species("{H,D,T}2{S,[34S]}","T")
40 total_H = sum_species("{H,D,T}2{S,[34S]}","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_T/total_H
100 save ratio
-end
R(34S)_H2S(aq)
-start
10 ratio = -9999.999
20 if (TOT("[34S]") <= 0) THEN GOTO 100
30 total_34S = sum_species("{H,D,T}2[34S]","[34S]")
40 total_S = sum_species("{H,D,T}2S","S")
50 if (total_S <= 0) THEN GOTO 100
60 ratio = total_34S/total_S
100 save ratio
-end
#
# NO3- ratios
#
R(15N)_NO3-
-start
10 ratio = -9999.999
20 if (TOT("[15N]") <= 0) THEN GOTO 100
30 total_15N = TOT("[15N](5)")
40 total_N = TOT("N(5)")
50 if (total_N <= 0) THEN GOTO 100
60 ratio = total_15N/total_N
100 save ratio
-end
#
# NO2- ratios
#
R(15N)_NO2-
-start
10 ratio = -9999.999
20 if (TOT("[15N]") <= 0) THEN GOTO 100
30 total_15N = TOT("[15N](3)")
40 total_N = TOT("N(3)")
50 if (total_N <= 0) THEN GOTO 100
60 ratio = total_15N/total_N
100 save ratio
-end
#
# N2(aq) ratios
#
R(15N)_N2(aq)
-start
10 ratio = -9999.999
20 if (TOT("[15N]") <= 0) THEN GOTO 100
30 total_15N = TOT("[15N](0)")
40 total_N = TOT("N(0)")
50 if (total_N <= 0) THEN GOTO 100
60 ratio = total_15N/total_N
100 save ratio
-end
#
# NH3(aq) ratios
#
R(D)_NH3(aq)
-start
10 ratio = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 100
30 total_D = sum_species("{[15N],N}{H,D,T}3","D")
40 total_H = sum_species("{[15N],N}{H,D,T}3","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_D/total_H
100 save ratio
-end
R(T)_NH3(aq)
-start
10 ratio = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 100
30 total_T = sum_species("{[15N],N}{H,D,T}3","T")
40 total_H = sum_species("{[15N],N}{H,D,T}3","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_T/total_H
100 save ratio
-end
R(15N)_NH3(aq)
-start
10 ratio = -9999.999
20 if (TOT("[15N]") <= 0) THEN GOTO 100
30 total_15N = sum_species("[15N]{H,D,T}3","[15N]")
40 total_N = sum_species("N{H,D,T}3","N")
50 if (total_N <= 0) THEN GOTO 100
60 ratio = total_15N/total_N
100 save ratio
-end
#
# NH4+ ratios
#
R(D)_NH4+
-start
10 ratio = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 100
30 total_D = sum_species("*{[15N],N}{H,D,T}4*","D")
40 total_H = sum_species("*{[15N],N}{H,D,T}4*","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_D/total_H
100 save ratio
-end
R(T)_NH4+
-start
10 ratio = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 100
30 total_T = sum_species("*{[15N],N}{H,D,T}4*","T")
40 total_H = sum_species("*{[15N],N}{H,D,T}4*","H")
50 if (total_H <= 0) THEN GOTO 100
60 ratio = total_T/total_H
100 save ratio
-end
R(15N)_NH4+
-start
10 ratio = -9999.999
20 if (TOT("[15N]") <= 0) THEN GOTO 100
30 total_15N = sum_species("*[15N]{H,D,T}4*","[15N]")
40 total_N = sum_species("*N{H,D,T}4*","N")
50 if (total_N <= 0) THEN GOTO 100
60 ratio = total_15N/total_N
100 save ratio
-end
#
# Ratios for minerals and gases
#
#
# H2O(g) ratios
#
R(D)_H2O(g)
-start
10 ratio = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (GAS("H2O(g)") <= 0) THEN GOTO 1000
40 total_D = SUM_GAS("{H,D,T}2{O,[18O]}", "D")
50 total_H = SUM_GAS("{H,D,T}2{O,[18O]}", "H")
60 if (total_h <= 0) THEN GOTO 1000
70 ratio = total_D/total_H
1000 save ratio
-end
R(T)_H2O(g)
-start
10 ratio = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (GAS("H2O(g)") <= 0) THEN GOTO 1000
40 total_T = SUM_GAS("{H,D,T}2{O,[18O]}", "T")
50 total_H = SUM_GAS("{H,D,T}2{O,[18O]}", "H")
60 if (total_h <= 0) THEN GOTO 1000
70 ratio = total_T/total_H
1000 save ratio
-end
R(18O)_H2O(g)
-start
10 ratio = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 if (GAS("H2O(g)") <= 0) THEN GOTO 1000
40 total_18O = SUM_GAS("{H,D,T}2[18O]", "[18O]")
50 total_O = SUM_GAS("{H,D,T}2O", "O")
60 if (total_O <= 0) THEN GOTO 1000
70 ratio = total_18O/total_O
1000 save ratio
-end
#
# O2(g) ratios
#
R(18O)_O2(g)
-start
10 ratio = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 if (GAS("O2(g)") <= 0) THEN GOTO 1000
40 total_18O = SUM_GAS("{O,[18O]}2", "[18O]")
50 total_O = SUM_GAS("{O,[18O]}2", "O")
60 if (total_O <= 0) THEN GOTO 1000
70 ratio = total_18O/total_O
1000 save ratio
-end
#
# H2(g) ratios
#
R(D)_H2(g)
-start
10 ratio = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (GAS("H2(g)") <= 0) THEN GOTO 1000
40 total_D = SUM_GAS("{H,D,T}2", "D")
50 total_H = SUM_GAS("{H,D,T}2", "H")
60 if (total_H <= 0) THEN GOTO 1000
70 ratio = total_D/total_H
1000 save ratio
-end
R(T)_H2(g)
-start
10 ratio = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (GAS("H2(g)") <= 0) THEN GOTO 1000
40 total_T = SUM_GAS("{H,D,T}2", "T")
50 total_H = SUM_GAS("{H,D,T}2", "H")
60 if (total_H <= 0) THEN GOTO 1000
70 ratio = total_T/total_H
1000 save ratio
-end
#
# CO2(g) ratios
#
R(18O)_CO2(g)
-start
10 ratio = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 if (GAS("CO2(g)") <= 0) THEN GOTO 1000
40 total_18O = SUM_GAS("{C,[13C],[14C]}{O,[18O]}2", "[18O]")
50 total_O = SUM_GAS("{C,[13C],[14C]}{O,[18O]}2", "O")
60 if (total_O <= 0) THEN GOTO 1000
70 ratio = total_18O/total_O
1000 save ratio
-end
R(13C)_CO2(g)
-start
10 ratio = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 1000
30 if (GAS("CO2(g)") <= 0) THEN GOTO 1000
40 if (GAS("[13C]O2(g)") <= 0) THEN GOTO 1000
50 total_13C = SUM_GAS("[13C]{O,[18O]}2", "[13C]")
60 total_C = SUM_GAS("C{O,[18O]}2", "C")
70 if (total_C <= 0) THEN GOTO 1000
80 ratio = total_13C/total_C
1000 save ratio
-end
R(14C)_CO2(g)
-start
10 ratio = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 1000
30 if (GAS("CO2(g)") <= 0) THEN GOTO 1000
40 if (GAS("[14C]O2(g)") <= 0) THEN GOTO 1000
50 total_14C = SUM_GAS("[14C]{O,[18O]}2", "[14C]")
60 total_C = SUM_GAS("C{O,[18O]}2", "C")
70 if (total_C <= 0) THEN GOTO 1000
80 ratio = total_14C/total_C
1000 save ratio
-end
#
# Calcite ratios
#
R(18O)_Calcite
-start
10 ratio = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 if (S_S("Calcite") <= 0) THEN GOTO 1000
40 total_18O = SUM_S_S("Calcite", "[18O]")
50 total_O = SUM_S_S("Calcite", "O")
60 if (total_O <= 0) THEN GOTO 1000
70 ratio = total_18O/total_O
1000 save ratio
-end
R(13C)_Calcite
-start
10 ratio = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 1000
30 if (S_S("Calcite") <= 0) THEN GOTO 1000
40 total_13C = SUM_S_S("Calcite", "[13C]")
50 total_C = SUM_S_S("Calcite", "C")
60 if (total_C <= 0) THEN GOTO 1000
70 ratio = total_13C/total_C
1000 save ratio
-end
R(14C)_Calcite
-start
10 ratio = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 1000
30 if (S_S("Calcite") <= 0) THEN GOTO 1000
40 total_14C = SUM_S_S("Calcite", "[14C]")
50 total_C = SUM_S_S("Calcite", "C")
60 if (total_C <= 0) THEN GOTO 1000
70 ratio = total_14C/total_C
1000 save ratio
-end
#
# Pyrite ratios
#
R(34S)_Pyrite
-start
10 ratio = -9999.999
20 if (TOT("[34S]") <= 0) THEN GOTO 1000
30 if (S_S("Pyrite") <= 0) THEN GOTO 1000
40 total_34S = SUM_S_S("Pyrite", "[34S]")
50 total_S = SUM_S_S("Pyrite", "S")
60 if (total_S <= 0) THEN GOTO 1000
70 ratio = total_34S/total_S
1000 save ratio
-end
#
# CH4(g) ratios
#
R(D)_CH4(g)
-start
10 ratio = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (GAS("CH4(g)") <= 0) THEN GOTO 1000
40 total_D = SUM_GAS("{C,[13C],[14C]}{H,D,T}4", "D")
50 total_H = SUM_GAS("{C,[13C],[14C]}{H,D,T}4", "H")
60 if (total_H <= 0) THEN GOTO 1000
70 ratio = total_D/total_H
1000 save ratio
-end
R(T)_CH4(g)
-start
10 ratio = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (GAS("CH4(g)") <= 0) THEN GOTO 1000
40 total_T = SUM_GAS("{C,[13C],[14C]}{H,D,T}4", "T")
50 total_H = SUM_GAS("{C,[13C],[14C]}{H,D,T}4", "H")
60 if (total_H <= 0) THEN GOTO 1000
70 ratio = total_T/total_H
1000 save ratio
-end
R(13C)_CH4(g)
-start
10 ratio = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 1000
30 if (GAS("CH4(g)") <= 0) THEN GOTO 1000
40 total_13C = SUM_GAS("[13C]{H,D,T}4", "[13C]")
50 total_C = SUM_GAS("C{H,D,T}4", "C")
60 if (total_C <= 0) THEN GOTO 1000
70 ratio = total_13C/total_C
1000 save ratio
-end
R(14C)_CH4(g)
-start
10 ratio = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 1000
30 if (GAS("CH4(g)") <= 0) THEN GOTO 1000
40 total_14C = SUM_GAS("[14C]{H,D,T}4", "[14C]")
50 total_C = SUM_GAS("C{H,D,T}4", "C")
60 if (total_C <= 0) THEN GOTO 1000
70 ratio = total_14C/total_C
1000 save ratio
-end
#
# H2S(g) ratios
#
R(D)_H2S(g)
-start
10 ratio = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (GAS("H2S(g)") <= 0) THEN GOTO 1000
40 total_D = SUM_GAS("{H,D,T}2{S,[34S]}", "D")
50 total_H = SUM_GAS("{H,D,T}2{S,[34S]}", "H")
60 if (total_H <= 0) THEN GOTO 1000
70 ratio = total_D/total_H
1000 save ratio
-end
R(T)_H2S(g)
-start
10 ratio = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (GAS("H2S(g)") <= 0) THEN GOTO 1000
40 total_T = SUM_GAS("{H,D,T}2{S,[34S]}", "T")
50 total_H = SUM_GAS("{H,D,T}2{S,[34S]}", "H")
60 if (total_H <= 0) THEN GOTO 1000
70 ratio = total_T/total_H
1000 save ratio
-end
R(34S)_H2S(g)
-start
10 ratio = -9999.999
20 if (TOT("[34S]") <= 0) THEN GOTO 1000
30 if (GAS("H2S(g)") <= 0) THEN GOTO 1000
40 total_34S = SUM_GAS("{H,D,T}2[34S]", "[34S]")
50 total_S = SUM_GAS("{H,D,T}2S", "S")
60 if (total_S <= 0) THEN GOTO 1000
70 ratio = total_34S/total_S
1000 save ratio
-end
#
# Gypsum ratios
#
R(34S)_Gypsum
-start
10 ratio = -9999.999
20 if (TOT("[34S]") <= 0) THEN GOTO 1000
30 if (S_S("Gypsum") <= 0) THEN GOTO 1000
40 total_34S = SUM_S_S("Gypsum", "[34S]")
50 total_S = SUM_S_S("Gypsum", "S")
60 if (total_S <= 0) THEN GOTO 1000
70 ratio = total_34S/total_S
1000 save ratio
-end
#
# Anhydrite ratios
#
R(34S)_Anhydrite
-start
10 ratio = -9999.999
20 if (TOT("[34S]") <= 0) THEN GOTO 1000
30 if (S_S("Anhydrite") <= 0) THEN GOTO 1000
40 total_34S = SUM_S_S("Anhydrite", "[34S]")
50 total_S = SUM_S_S("Anhydrite", "S")
60 if (total_S <= 0) THEN GOTO 1000
70 ratio = total_34S/total_S
1000 save ratio
-end
#
# N2(g) ratios
#
R(15N)_N2(g)
-start
10 ratio = -9999.999
20 if (TOT("[15N]") <= 0) THEN GOTO 1000
30 if (GAS("N2(g)") <= 0) THEN GOTO 1000
40 total_15N = SUM_GAS("{[15N],N}2", "[15N]")
50 total_N = SUM_GAS("{[15N],N}2", "N")
60 if (total_N <= 0) THEN GOTO 1000
70 ratio = total_15N/total_N
1000 save ratio
-end
#
# NH3(g) ratios
#
R(D)_NH3(g)
-start
10 ratio = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (GAS("NH3(g)") <= 0) THEN GOTO 1000
40 total_D = SUM_GAS("{[15N],N}{H,D,T}3", "D")
50 total_H = SUM_GAS("{[15N],N}{H,D,T}3", "H")
60 if (total_H <= 0) THEN GOTO 1000
70 ratio = total_D/total_H
1000 save ratio
-end
R(T)_NH3(g)
-start
10 ratio = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (GAS("NH3(g)") <= 0) THEN GOTO 1000
40 total_T = SUM_GAS("{[15N],N}{H,D,T}3", "T")
50 total_H = SUM_GAS("{[15N],N}{H,D,T}3", "H")
60 if (total_H <= 0) THEN GOTO 1000
70 ratio = total_T/total_H
1000 save ratio
-end
R(15N)_NH3(g)
-start
10 ratio = -9999.999
20 if (TOT("[15N]") <= 0) THEN GOTO 1000
30 if (GAS("NH3(g)") <= 0) THEN GOTO 1000
40 total_15N = SUM_GAS("[15N]{H,D,T}3", "[15N]")
50 total_N = SUM_GAS("N{H,D,T}3", "N")
60 if (total_N <= 0) THEN GOTO 1000
70 ratio = total_15N/total_N
1000 save ratio
-end
###############################################################################################
CALCULATE_VALUES
###############################################################################################
#
# Alphas
#
#
# H2O(l) ratios
#
#
# OH- ratios
#
Alpha_D_OH-/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 r1 = CALC_VALUE("R(D)_OH-")
40 r2 = CALC_VALUE("R(D)_H2O(l)")
50 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_OH-/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 r1 = CALC_VALUE("R(T)_OH-")
40 r2 = CALC_VALUE("R(T)_H2O(l)")
50 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_18O_OH-/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 r1 = CALC_VALUE("R(18O)_OH-")
40 r2 = CALC_VALUE("R(18O)_H2O(l)")
50 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# H3O+ ratios
#
Alpha_D_H3O+/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 r1 = CALC_VALUE("R(D)_H3O+")
40 r2 = CALC_VALUE("R(D)_H2O(l)")
50 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_H3O+/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 r1 = CALC_VALUE("R(T)_H3O+")
40 r2 = CALC_VALUE("R(T)_H2O(l)")
50 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_18O_H3O+/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 r1 = CALC_VALUE("R(18O)_H3O+")
40 r2 = CALC_VALUE("R(18O)_H2O(l)")
50 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# O2(aq) ratios
#
Alpha_18O_O2(aq)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(18O)_O2(aq)")
60 r2 = CALC_VALUE("R(18O)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# H2(aq) ratios
#
Alpha_D_H2(aq)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(D)_H2(aq)")
60 r2 = CALC_VALUE("R(D)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_H2(aq)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(T)_H2(aq)")
60 r2 = CALC_VALUE("R(T)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# CO2(aq) ratios
#
Alpha_18O_CO2(aq)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 if (TOT("C") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(18O)_CO2(aq)")
50 r2 = CALC_VALUE("R(18O)_H2O(l)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_13C_CO2(aq)/CO2(g)
-start
10 alpha = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 1000
30 if (TOT("C") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(13C)_CO2(aq)")
50 r2 = CALC_VALUE("R(13C)_CO2(g)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_14C_CO2(aq)/CO2(g)
-start
10 alpha = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 1000
30 if (TOT("C") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(14C)_CO2(aq)")
50 r2 = CALC_VALUE("R(14C)_CO2(g)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# HCO3- ratios
#
Alpha_D_HCO3-/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (TOT("C") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(D)_HCO3-")
50 r2 = CALC_VALUE("R(D)_H2O(l)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_HCO3-/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (TOT("C") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(T)_HCO3-")
50 r2 = CALC_VALUE("R(T)_H2O(l)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_18O_HCO3-/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 if (TOT("C") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(18O)_HCO3-")
50 r2 = CALC_VALUE("R(18O)_H2O(l)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_18O_HCO3-/CO2(aq)
-start
10 alpha = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 if (TOT("C") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(18O)_HCO3-")
50 r2 = CALC_VALUE("R(18O)_CO2(aq)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_13C_HCO3-/CO2(g)
-start
10 alpha = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 1000
30 if (GAS("CO2(g)") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(13C)_HCO3-")
50 r2 = CALC_VALUE("R(13C)_CO2(g)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_13C_HCO3-/CO2(aq)
-start
10 alpha = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 1000
30 if (TOT("C") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(13C)_HCO3-")
50 r2 = CALC_VALUE("R(13C)_CO2(aq)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_14C_HCO3-/CO2(g)
-start
10 alpha = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 1000
30 if (GAS("CO2(g)") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(14C)_HCO3-")
50 r2 = CALC_VALUE("R(14C)_CO2(g)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_14C_HCO3-/CO2(aq)
-start
10 alpha = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 1000
30 if (TOT("C") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(14C)_HCO3-")
50 r2 = CALC_VALUE("R(14C)_CO2(aq)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# CO3-2 ratios
#
Alpha_18O_CO3-2/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 if (TOT("C") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(18O)_CO3-2")
50 r2 = CALC_VALUE("R(18O)_H2O(l)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_18O_CO3-2/CO2(aq)
-start
10 alpha = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 if (TOT("C") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(18O)_CO3-2")
50 r2 = CALC_VALUE("R(18O)_CO2(aq)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_13C_CO3-2/CO2(g)
-start
10 alpha = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 1000
30 if (GAS("CO2(g)") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(13C)_CO3-2")
50 r2 = CALC_VALUE("R(13C)_CO2(g)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_13C_CO3-2/CO2(aq) #?
-start
10 alpha = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 1000
30 if (TOT("C") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(13C)_CO3-2")
50 r2 = CALC_VALUE("R(13C)_CO2(aq)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_14C_CO3-2/CO2(g)
-start
10 alpha = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 1000
30 if (GAS("CO2(g)") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(14C)_CO3-2")
50 r2 = CALC_VALUE("R(14C)_CO2(g)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_14C_CO3-2/CO2(aq) #?
-start
10 alpha = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 1000
30 if (TOT("C") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(14C)_CO3-2")
50 r2 = CALC_VALUE("R(14C)_CO2(aq)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# CH4(aq) ratios
#
Alpha_D_CH4(aq)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (TOT("C") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(D)_CH4(aq)")
60 r2 = CALC_VALUE("R(D)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_CH4(aq)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (TOT("C") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(T)_CH4(aq)")
60 r2 = CALC_VALUE("R(T)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_13C_CH4(aq)/CO2(aq)
-start
10 alpha = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 1000
30 if (TOT("C") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(13C)_CH4(aq)")
60 r2 = CALC_VALUE("R(13C)_CO2(aq)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_14C_CH4(aq)/CO2(aq)
-start
10 alpha = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 1000
30 if (TOT("C") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(14C)_CH4(aq)")
60 r2 = CALC_VALUE("R(14C)_CO2(aq)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# HSO4-2 ratios
#
Alpha_D_HSO4-/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (TOT("S(6)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(D)_HSO4-")
60 r2 = CALC_VALUE("R(D)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_HSO4-/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (TOT("S(6)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(T)_HSO4-")
60 r2 = CALC_VALUE("R(T)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_34S_HSO4-/SO4-2
-start
10 alpha = -9999.999
20 if (TOT("[34S]") <= 0) THEN GOTO 1000
30 if (TOT("S(6)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(34S)_HSO4-")
60 r2 = CALC_VALUE("R(34S)_SO4-2")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# S-2 ratios
#
Alpha_34S_S-2/HS-
-start
10 alpha = -9999.999
20 if (TOT("[34S]") <= 0) THEN GOTO 1000
30 if (TOT("S(-2)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(34S)_S-2")
60 r2 = CALC_VALUE("R(34S)_HS-")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# HS- ratios
#
Alpha_D_HS-/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (TOT("S(-2)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(D)_HS-")
60 r2 = CALC_VALUE("R(D)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_HS-/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (TOT("S(-2)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(T)_HS-")
60 r2 = CALC_VALUE("R(T)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_34S_HS-/SO4-2
-start
10 alpha = -9999.999
20 if (TOT("[34S]") <= 0) THEN GOTO 1000
30 if (TOT("S(6)") <= 0) THEN GOTO 1000
40 if (TOT("S(-2)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(34S)_HS-")
60 r2 = CALC_VALUE("R(34S)_SO4-2")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# H2S ratios
#
Alpha_D_H2S(aq)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (TOT("S(-2)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(D)_H2S(aq)")
60 r2 = CALC_VALUE("R(D)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_D_H2S(aq)/HS-
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (TOT("S(-2)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(D)_H2S(aq)")
60 r2 = CALC_VALUE("R(D)_HS-")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_H2S(aq)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (TOT("S(-2)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(T)_H2S(aq)")
60 r2 = CALC_VALUE("R(T)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_H2S(aq)/HS-
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (TOT("S(-2)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(T)_H2S(aq)")
60 r2 = CALC_VALUE("R(T)_HS-")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_34S_H2S(aq)/HS-
-start
10 alpha = -9999.999
20 if (TOT("[34S]") <= 0) THEN GOTO 1000
30 if (TOT("S(-2)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(34S)_H2S(aq)")
60 r2 = CALC_VALUE("R(34S)_HS-")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# NO3- ratios
#
Alpha_15N_NO2-/NO3-
-start
10 alpha = -9999.999
20 if (TOT("[15N]") <= 0) THEN GOTO 1000
30 if (TOT("N(5)") <= 0) THEN GOTO 1000
40 if (TOT("N(3)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(15N)_NO2-")
60 r2 = CALC_VALUE("R(15N)_NO3-")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# N2(aq) ratios
#
Alpha_15N_N2(aq)/NO3-
-start
10 alpha = -9999.999
20 if (TOT("[15N]") <= 0) THEN GOTO 1000
30 if (TOT("N(5)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(15N)_N2(aq)")
60 r2 = CALC_VALUE("R(15N)_NO3-")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# NH3(aq) ratios
#
Alpha_D_NH3(aq)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (TOT("N(-3)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(D)_NH3(aq)")
60 r2 = CALC_VALUE("R(D)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_NH3(aq)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (TOT("N(-3)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(T)_NH3(aq)")
60 r2 = CALC_VALUE("R(T)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_15N_NH3(aq)/NO3-
-start
10 alpha = -9999.999
20 if (TOT("[15N]") <= 0) THEN GOTO 1000
30 if (TOT("N(-3)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(15N)_NH3(aq)")
60 r2 = CALC_VALUE("R(15)_NO3-")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# NH4+ ratios
#
Alpha_D_NH4+/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (TOT("N(-3)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(D)_NH4+")
60 r2 = CALC_VALUE("R(D)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_NH4+/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (TOT("N(-3)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(T)_NH4+")
60 r2 = CALC_VALUE("R(T)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_15N_NH4+/NO3-
-start
10 alpha = -9999.999
20 if (TOT("[15N]") <= 0) THEN GOTO 1000
30 if (TOT("N(5)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(15N)_NH4+")
60 r2 = CALC_VALUE("R(15N)_NO3-")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_15N_NH4+/NH3(aq)
-start
10 alpha = -9999.999
20 if (TOT("[15N]") <= 0) THEN GOTO 1000
30 if (TOT("N(5)") <= 0) THEN GOTO 1000
40 if (TOT("N(-3)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(15N)_NH4+")
60 r2 = CALC_VALUE("R(15N)_NH3(aq)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# Ratios for minerals and gases
#
#
# H2O(g) ratios
#
Alpha_D_H2O(g)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (GAS("H2O(g)") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(D)_H2O(g)")
50 r2 = CALC_VALUE("R(D)_H2O(l)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_H2O(g)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (GAS("H2O(g)") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(T)_H2O(g)")
50 r2 = CALC_VALUE("R(T)_H2O(l)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_18O_H2O(g)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 if (GAS("H2O(g)") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(18O)_H2O(g)")
50 r2 = CALC_VALUE("R(18O)_H2O(l)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# O2(g) ratios
#
Alpha_18O_O2(aq)/O2(g)
-start
10 alpha = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 if (GAS("O2(g)") <= 0) THEN GOTO 1000
40 if (GAS("O[18O](g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(18O)_O2(aq)")
60 r2 = CALC_VALUE("R(18O)_O2(g)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_18O_O2(g)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 if (GAS("O2(g)") <= 0) THEN GOTO 1000
40 if (GAS("O[18O](g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(18O)_O2(g)")
60 r2 = CALC_VALUE("R(18O)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# H2(g) ratios
#
Alpha_D_H2(g)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (GAS("H2(g)") <= 0) THEN GOTO 1000
40 if (GAS("HD(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(D)_H2(g)")
60 r2 = CALC_VALUE("R(D)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_H2(g)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (GAS("H2(g)") <= 0) THEN GOTO 1000
40 if (GAS("HT(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(T)_H2(g)")
60 r2 = CALC_VALUE("R(T)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_D_H2(aq)/H2(g)
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (GAS("H2(g)") <= 0) THEN GOTO 1000
40 if (GAS("HD(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(D)_H2(aq)")
60 r2 = CALC_VALUE("R(D)_H2(g)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_H2(aq)/H2(g)
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (GAS("H2(g)") <= 0) THEN GOTO 1000
40 if (GAS("HT(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(T)_H2(aq)")
60 r2 = CALC_VALUE("R(T)_H2(g)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# CO2(g) ratios
#
Alpha_18O_CO2(g)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 if (GAS("CO2(g)") <= 0) THEN GOTO 1000
40 if (GAS("CO[18O](g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(18O)_CO2(g)")
60 r2 = CALC_VALUE("R(18O)_H2O(l)")
70 if (r1 <= 0) THEN GOTO 1000
80 if (r2 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_18O_CO2(g)/CO2(aq)
-start
10 alpha = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 if (GAS("CO2(g)") <= 0) THEN GOTO 1000
40 if (GAS("CO[18O](g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(18O)_CO2(g)")
60 r2 = CALC_VALUE("R(18O)_CO2(aq)")
70 if (r1 <= 0) THEN GOTO 1000
80 if (r2 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_13C_CO2(g)/CO2(aq)
-start
10 alpha = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 1000
30 if (GAS("CO2(g)") <= 0) THEN GOTO 1000
40 if (GAS("[13C]O2(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(13C)_CO2(g)")
60 r2 = CALC_VALUE("R(13C)_CO2(aq)")
70 if (r1 <= 0) THEN GOTO 1000
80 if (r2 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_14C_CO2(g)/CO2(aq)
-start
10 alpha = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 1000
30 if (GAS("CO2(g)") <= 0) THEN GOTO 1000
40 if (GAS("[134]O2(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(14C)_CO2(g)")
60 r2 = CALC_VALUE("R(14C)_CO2(aq)")
70 if (r1 <= 0) THEN GOTO 1000
80 if (r2 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# Calcite ratios
#
Alpha_18O_Calcite/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 if (S_S("Calcite") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(18O)_Calcite")
50 r2 = CALC_VALUE("R(18O)_H2O(l)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_18O_Calcite/CO3-2
-start
10 alpha = -9999.999
20 if (TOT("[18O]") <= 0) THEN GOTO 1000
30 if (S_S("Calcite") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(18O)_Calcite")
50 r2 = CALC_VALUE("R(18O)_CO3-2")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_13C_Calcite/CO2(g)
-start
10 alpha = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 1000
30 if (S_S("Calcite") <= 0) THEN GOTO 1000
35 if (GAS("CO2(g)") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(13C)_Calcite")
50 r2 = CALC_VALUE("R(13C)_CO2(g)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_13C_Calcite/CO2(aq)
-start
10 alpha = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 1000
30 if (S_S("Calcite") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(13C)_Calcite")
50 r2 = CALC_VALUE("R(13C)_CO2(aq)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_13C_Calcite/CO3-2
-start
10 alpha = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 1000
30 if (S_S("Calcite") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(13C)_Calcite")
50 r2 = CALC_VALUE("R(13C)_CO3-2")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_14C_Calcite/CO2(g)
-start
10 alpha = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 1000
30 if (S_S("Calcite") <= 0) THEN GOTO 1000
35 if (GAS("CO2(g)") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(14C)_Calcite")
50 r2 = CALC_VALUE("R(14C)_CO2(g)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_14C_Calcite/CO2(aq)
-start
10 alpha = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 1000
30 if (S_S("Calcite") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(14C)_Calcite")
50 r2 = CALC_VALUE("R(14C)_CO2(aq)")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_14C_Calcite/CO3-2
-start
10 alpha = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 1000
30 if (S_S("Calcite") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(14C)_Calcite")
50 r2 = CALC_VALUE("R(14C)_CO3-2")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# Pyrite ratios
#
Alpha_34S_Pyrite/HS-
-start
10 alpha = -9999.999
20 if (TOT("[34S]") <= 0) THEN GOTO 1000
30 if (S_S("Pyrite") <= 0) THEN GOTO 1000
40 r1 = CALC_VALUE("R(34S)_Pyrite")
50 r2 = CALC_VALUE("R(34S)_HS-")
60 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# CH4(g) ratios
#
Alpha_D_CH4(aq)/CH4(g)
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (GAS("CH4(g)") <= 0) THEN GOTO 1000
40 if (GAS("CH3D(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(D)_CH4(aq)")
60 r2 = CALC_VALUE("R(D)_CH4(g)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_D_CH4(g)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (GAS("CH4(g)") <= 0) THEN GOTO 1000
40 if (GAS("CH3D(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(D)_CH4(g)")
60 r2 = CALC_VALUE("R(D)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_CH4(aq)/CH4(g)
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (GAS("CH4(g)") <= 0) THEN GOTO 1000
40 if (GAS("CH3T(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(T)_CH4(aq)")
60 r2 = CALC_VALUE("R(T)_CH4(g)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_CH4(g)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (GAS("CH4(g)") <= 0) THEN GOTO 1000
40 if (GAS("CH3T(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(T)_CH4(g)")
60 r2 = CALC_VALUE("R(T)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_13C_CH4(g)/CO2(aq)
-start
10 alpha = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 1000
30 if (GAS("CH4(g)") <= 0) THEN GOTO 1000
40 if (GAS("[13C]H4(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(13C)_CH4(g)")
60 r2 = CALC_VALUE("R(13C)_CO2(aq)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_13C_CH4(aq)/CH4(g)
-start
10 alpha = -9999.999
20 if (TOT("[13C]") <= 0) THEN GOTO 1000
30 if (GAS("CH4(g)") <= 0) THEN GOTO 1000
40 if (GAS("[13C]H4(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(13C)_CH4(aq)")
60 r2 = CALC_VALUE("R(13C)_CH4(g)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_14C_CH4(g)/CO2(aq)
-start
10 alpha = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 1000
30 if (GAS("CH4(g)") <= 0) THEN GOTO 1000
40 if (GAS("[14C]H4(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(14C)_CH4(g)")
60 r2 = CALC_VALUE("R(14C)_CO2(aq)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_14C_CH4(aq)/CH4(g)
-start
10 alpha = -9999.999
20 if (TOT("[14C]") <= 0) THEN GOTO 1000
30 if (GAS("CH4(g)") <= 0) THEN GOTO 1000
40 if (GAS("[14C]H4(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(14C)_CH4(aq)")
60 r2 = CALC_VALUE("R(14C)_CH4(g)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# H2S(g) ratios
#
Alpha_D_H2S(g)/H2S(aq)
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (TOT("S(-2)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(D)_H2S(g)")
60 r2 = CALC_VALUE("R(D)_H2S(aq)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_H2S(g)/H2S(aq)
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (TOT("S(-2)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(T)_H2S(g)")
60 r2 = CALC_VALUE("R(T)_H2S(aq)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_34S_H2S(g)/H2S(aq)
-start
10 alpha = -9999.999
20 if (TOT("[34S]") <= 0) THEN GOTO 1000
30 if (TOT("S(6)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(34S)_H2S(g)")
60 r2 = CALC_VALUE("R(34S)_H2S(aq)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# Gypsum ratios
#
Alpha_34S_Gypsum/SO4-2
-start
10 alpha = -9999.999
20 if (TOT("[34S]") <= 0) THEN GOTO 1000
30 if (TOT("S(6)") <= 0) THEN GOTO 1000
40 if (S_S("Gypsum") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(34S)_Gypsum")
60 r2 = CALC_VALUE("R(34S)_SO4-2")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# Anhydrite ratios
#
Alpha_34S_Anhydrite/SO4-2
-start
10 alpha = -9999.999
20 if (TOT("[34S]") <= 0) THEN GOTO 1000
30 if (TOT("S(6)") <= 0) THEN GOTO 1000
40 if (S_S("Anhydrite") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(34S)_Anhydrite")
60 r2 = CALC_VALUE("R(34S)_SO4-2")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# N2(g) ratios
#
Alpha_15N_N2(g)/N2(aq)
-start
10 alpha = -9999.999
20 if (TOT("[15N]") <= 0) THEN GOTO 1000
30 if (TOT("N(0)") <= 0) THEN GOTO 1000
40 if (GAS("N2(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(15N)_N2(g)")
60 r2 = CALC_VALUE("R(15N)_N2(aq)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
#
# NH3(g) ratios
#
Alpha_D_NH3(g)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("D") <= 0) THEN GOTO 1000
30 if (TOT("N(-3)") <= 0) THEN GOTO 1000
40 if (GAS("NH3(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(D)_NH3(g)")
60 r2 = CALC_VALUE("R(D)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_T_NH3(g)/H2O(l)
-start
10 alpha = -9999.999
20 if (TOT("T") <= 0) THEN GOTO 1000
30 if (TOT("N(-3)") <= 0) THEN GOTO 1000
40 if (GAS("NH3(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(T)_NH3(g)")
60 r2 = CALC_VALUE("R(T)_H2O(l)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
Alpha_15N_NH3(g)/NH3(aq)
-start
10 alpha = -9999.999
20 if (TOT("[15N]") <= 0) THEN GOTO 1000
30 if (TOT("N(-3)") <= 0) THEN GOTO 1000
40 if (GAS("NH3(g)") <= 0) THEN GOTO 1000
50 r1 = CALC_VALUE("R(15N)_NH3(g)")
60 r2 = CALC_VALUE("R(15N)_NH3(aq)")
70 if (r2 <= 0) THEN GOTO 1000
80 if (r1 <= -9999) THEN GOTO 1000
90 alpha = r1/r2
1000 save alpha
-end
###############################################################################################
SOLUTION_SPECIES
###############################################################################################
D2O = D2O
-activity_water
log_k 0
HTO = HTO
-activity_water
log_k 0
H2[18O] = H2[18O]
-activity_water
log_k 0
CO2 = CO2
log_k 0
[13C]O2 = [13C]O2
log_k 0
[14C]O2 = [14C]O2
log_k 0
[34S]O4-2 = [34S]O4-2
log_k 0.0
-gamma 5.0000 -0.0400
[15N]O3- = [15N]O3-
log_k 0.0
-gamma 3.0000 0.0000
#
# H2O reactions
# last update July 31, 2006
# checked September 19, 2006
#
0.5H2O + 0.5D2O = HDO
log_k 0.301029995663 # log10(2)
-activity_water
HDO + HTO = DTO + H2O
-mole_balance DTO
log_k -0.301029995663 # log10(1/2)
-activity_water
2HTO = T2O + H2O
-mole_balance T2O
log_k -0.6020599913279623960 # log10(1/4)
-activity_water
H2[18O] + HDO = HD[18O] + H2O
-mole_balance HD[18O]
log_k 0.0
-activity_water
H2[18O] + HTO = HT[18O] + H2O
-mole_balance HT[18O]
log_k 0.0
-activity_water
DTO + H2[18O] = DT[18O] + H2O
-mole_balance DT[18O]
log_k 0.0
-activity_water
D2O + H2[18O] = D2[18O] + H2O
-mole_balance D2[18O]
log_k 0.0
-activity_water
H2[18O] + T2O = T2[18O] + H2O
-mole_balance T2[18O]
log_k 0.0
-activity_water
#
# OH- reactions
# last update July 31, 2006
# checked September 19, 2006
#
OH- + HDO = OD- + H2O
-mole_balance OD
log_k -0.301029995663 # -log10(2)
-add_logk Log_alpha_D_OH-/H2O(l) 1.0
-gamma 3.5000 0.0000
OH- + HTO = OT- + H2O
-mole_balance OT
log_k -0.301029995663 # -log10(2)
-add_logk Log_alpha_T_OH-/H2O(l) 1.0
-gamma 3.5000 0.0000
OH- + H2[18O] = [18O]H- + H2O
-mole_balance [18O]H
-add_logk Log_alpha_18O_OH-/H2O(l) 1.0
-gamma 3.5000 0.0000
[18O]H- + OD- = [18O]D- + OH-
-mole_balance [18O]D
log_k 0.0
-gamma 3.5000 0.0000
[18O]H- + OT- = [18O]T- + OH-
-mole_balance [18O]T
log_k 0.0
-gamma 3.5000 0.0000
#
# H3O+ reactions
# last update July 31, 2006
# checked September 19, 2006
#
H3O+ + HDO = H2DO+ + H2O
-mole_balance H2DO
log_k 0.176091259055 # log10(1.5)
-add_logk Log_alpha_D_H3O+/H2O(l) 1.0
-gamma 9.0000 0.0000
2H2DO+ = HD2O+ + H3O+
-mole_balance HD2O
log_k -0.477121254719662 # log10(1/3)
-gamma 9.0000 0.0000
H2DO+ + HD2O+ = D3O+ + H3O+
-mole_balance D3O
log_k -0.954242509439324 # log10(1/9)
-gamma 9.0000 0.0000
H3O+ + HTO = H2TO+ + H2O
-mole_balance H2TO
log_k 0.176091259055 # log10(1.5)
-add_logk Log_alpha_T_H3O+/H2O(l) 1.0
-gamma 9.0000 0.0000
2H2TO+ = HT2O+ + H3O+
-mole_balance HT2O
log_k -0.477121254719662 # log10(1/3)
-gamma 9.0000 0.0000
H2TO+ + HT2O+ = T3O+ + H3O+
-mole_balance T3O
log_k -0.954242509439324 # log10(1/9)
-gamma 9.0000 0.0000
H2TO+ + H2DO+ = HDTO+ + H3O+
-mole_balance HDTO
log_k -0.477121254719662 # log10(1/3)
-gamma 9.0000 0.0000
H2TO+ + HD2O+ = D2TO+ + H3O+
-mole_balance D2TO
log_k -0.477121254719662 # log10(1/3)
-gamma 9.0000 0.0000
H2DO+ + HT2O+ = DT2O+ + H3O+
-mole_balance DT2O
log_k -0.477121254719662 # log10(1/3)
-gamma 9.0000 0.0000
H3O+ + H2[18O] = H3[18O]+ + H2O
-mole_balance H3[18O]
-add_logk Log_alpha_18O_H3O+/H2O(l) 1.0
-gamma 9.0000 0.0000
H3[18O]+ + H2DO+ = H2D[18O]+ + H3O+
-mole_balance H2D[18O]
log_k 0.0
-gamma 9.0000 0.0000
H3[18O]+ + HD2O+ = HD2[18O]+ + H3O+
-mole_balance HD2[18O]
log_k 0.0
-gamma 9.0000 0.0000
H3[18O]+ + D3O+ = D3[18O]+ + H3O+
-mole_balance D3[18O]
log_k 0.0
-gamma 9.0000 0.0000
H3[18O]+ + H2TO+ = H2T[18O]+ + H3O+
-mole_balance H2T[18O]
log_k 0.0
-gamma 9.0000 0.0000
H3[18O]+ + HT2O+ = HT2[18O]+ + H3O+
-mole_balance HT2[18O]
log_k 0.0
-gamma 9.0000 0.0000
H3[18O]+ + T3O+ = T3[18O]+ + H3O+
-mole_balance T3[18O]
log_k 0.0
-gamma 9.0000 0.0000
H3[18O]+ + HDTO+ = HDT[18O]+ + H3O+
-mole_balance HDT[18O]
log_k 0.0
-gamma 9.0000 0.0000
H3[18O]+ + D2TO+ = D2T[18O]+ + H3O+
-mole_balance D2T[18O]
log_k 0.0
-gamma 9.0000 0.0000
H3[18O]+ + DT2O+ = DT2[18O]+ + H3O+
-mole_balance DT2[18O]
log_k 0.0
-gamma 9.0000 0.0000
#
# O2 reactions
# last update July 31, 2006
# checked September 19, 2006
#
O2 + H2[18O] = O[18O] + H2O
log_k 0.301029995663 # log10(2)
-add_logk Log_alpha_18O_O2(aq)/H2O(l) 1.0
-mole_balance O(0)[18O](0)
2O[18O] = [18O]2 + O2
log_k -0.602059991327962396 # -log10(4)
-mole_balance [18O](0)2
#
# H2 reactions
# last update July 31, 2006
# checked September 19, 2006
#
H2 + HDO = HD + H2O
-mole_balance H(0)D(0)
-add_logk Log_alpha_D_H2(aq)/H2O(l) 1.0
2HD = D2 + H2
-mole_balance D(0)2
log_k -0.602059991327962396 # -log10(4)
H2 + HTO = HT + H2O
-mole_balance H(0)T(0)
-add_logk Log_alpha_T_H2(aq)/H2O(l) 1.0
2HT = T2 + H2
-mole_balance T(0)2
log_k -0.602059991327962396 # -log10(4)
HT + HD = DT + H2
-mole_balance D(0)T(0)
log_k -0.301029995663 # -log10(2)
#
# CO2 reactions
# last update July 31, 2006
# Checked September 19, 2006
#
CO2 + H2[18O] = CO[18O] + H2O
log_k 0.301029995663 # log10(2)
-add_logk Log_alpha_18O_CO2(aq)/H2O(l) 1.0
2CO[18O] = C[18O]2 + CO2
log_k -0.6020599913279623960 # log10(1/4)
[13C]O2 + CO[18O] = [13C]O[18O] + CO2
log_k 0
[13C]O2 + C[18O]2 = [13C][18O]2 + CO2
log_k 0
[14C]O2 + CO[18O] = [14C]O[18O] + CO2
log_k 0
[14C]O2 + C[18O]2 = [14C][18O]2 + CO2
log_k 0
#
# HCO3- reactions
# last update July 31, 2006
# Checked September 19, 2006
#
HCO3- + H2[18O] = HCO2[18O]- + H2O
-add_logk Log_alpha_18O_HCO3-/H2O(l) 1.0
HCO2[18O]- = HCO[18O]O-
HCO2[18O]- = HC[18O]O2-
2HCO2[18O]- = HCO[18O]2- + HCO3-
HCO[18O]2- = HC[18O]O[18O]-
HCO[18O]2- = HC[18O]2O-
3HCO2[18O]- = HC[18O]3- + 2HCO3-
HDO + HCO3- = DCO3- + H2O
log_k -0.301029995663 # -log10(2)
-add_logk Log_alpha_D_HCO3-/H2O(l) 1.0
DCO3- + HCO2[18O]- = DCO2[18O]- + HCO3-
DCO3- + HCO[18O]O- = DCO[18O]O- + HCO3-
DCO3- + HC[18O]O2- = DC[18O]O2- + HCO3-
DCO3- + HCO[18O]2- = DCO[18O]2- + HCO3-
DCO3- + HC[18O]O[18O]- = DC[18O]O[18O]- + HCO3-
DCO3- + HC[18O]2O- = DC[18O]2O- + HCO3-
DCO3- + HC[18O]3- = DC[18O]3- + HCO3-
HTO + HCO3- = TCO3- + H2O
log_k -0.301029995663 # -log10(2)
-add_logk Log_alpha_T_HCO3-/H2O(l) 1.0
TCO3- + HCO2[18O]- = TCO2[18O]- + HCO3-
TCO3- + HCO[18O]O- = TCO[18O]O- + HCO3-
TCO3- + HC[18O]O2- = TC[18O]O2- + HCO3-
TCO3- + HCO[18O]2- = TCO[18O]2- + HCO3-
TCO3- + HC[18O]O[18O]- = TC[18O]O[18O]- + HCO3-
TCO3- + HC[18O]2O- = TC[18O]2O- + HCO3-
TCO3- + HC[18O]3- = TC[18O]3- + HCO3-
HCO3- + [13C]O2 = H[13C]O3- + CO2
-add_logk Log_alpha_13C_HCO3-/CO2(aq) 1.0
H[13C]O3- + HCO2[18O]- = H[13C]O2[18O]- + HCO3-
H[13C]O3- + HCO[18O]O- = H[13C]O[18O]O- + HCO3-
H[13C]O3- + HC[18O]O2- = H[13C][18O]O2- + HCO3-
H[13C]O3- + HCO[18O]2- = H[13C]O[18O]2- + HCO3-
H[13C]O3- + HC[18O]O[18O]- = H[13C][18O]O[18O]- + HCO3-
H[13C]O3- + HC[18O]2O- = H[13C][18O]2O- + HCO3-
H[13C]O3- + HC[18O]3- = H[13C][18O]3- + HCO3-
DCO3- + H[13C]O3- = D[13C]O3- + HCO3-
H[13C]O3- + DCO2[18O]- = D[13C]O2[18O]- + HCO3-
H[13C]O3- + DCO[18O]O- = D[13C]O[18O]O- + HCO3-
H[13C]O3- + DC[18O]O2- = D[13C][18O]O2- + HCO3-
H[13C]O3- + DCO[18O]2- = D[13C]O[18O]2- + HCO3-
H[13C]O3- + DC[18O]O[18O]- = D[13C][18O]O[18O]- + HCO3-
H[13C]O3- + DC[18O]2O- = D[13C][18O]2O- + HCO3-
H[13C]O3- + DC[18O]3- = D[13C][18O]3- + HCO3-
TCO3- + H[13C]O3- = T[13C]O3- + HCO3-
H[13C]O3- + TCO2[18O]- = T[13C]O2[18O]- + HCO3-
H[13C]O3- + TCO[18O]O- = T[13C]O[18O]O- + HCO3-
H[13C]O3- + TC[18O]O2- = T[13C][18O]O2- + HCO3-
H[13C]O3- + TCO[18O]2- = T[13C]O[18O]2- + HCO3-
H[13C]O3- + TC[18O]O[18O]- = T[13C][18O]O[18O]- + HCO3-
H[13C]O3- + TC[18O]2O- = T[13C][18O]2O- + HCO3-
H[13C]O3- + TC[18O]3- = T[13C][18O]3- + HCO3-
HCO3- + [14C]O2 = H[14C]O3- + CO2
-add_logk Log_alpha_14C_HCO3-/CO2(aq) 1.0
H[14C]O3- + HCO2[18O]- = H[14C]O2[18O]- + HCO3-
H[14C]O3- + HCO[18O]O- = H[14C]O[18O]O- + HCO3-
H[14C]O3- + HC[18O]O2- = H[14C][18O]O2- + HCO3-
H[14C]O3- + HCO[18O]2- = H[14C]O[18O]2- + HCO3-
H[14C]O3- + HC[18O]O[18O]- = H[14C][18O]O[18O]- + HCO3-
H[14C]O3- + HC[18O]2O- = H[14C][18O]2O- + HCO3-
H[14C]O3- + HC[18O]3- = H[14C][18O]3- + HCO3-
DCO3- + H[14C]O3- = D[14C]O3- + HCO3-
H[14C]O3- + DCO2[18O]- = D[14C]O2[18O]- + HCO3-
H[14C]O3- + DCO[18O]O- = D[14C]O[18O]O- + HCO3-
H[14C]O3- + DC[18O]O2- = D[14C][18O]O2- + HCO3-
H[14C]O3- + DCO[18O]2- = D[14C]O[18O]2- + HCO3-
H[14C]O3- + DC[18O]O[18O]- = D[14C][18O]O[18O]- + HCO3-
H[14C]O3- + DC[18O]2O- = D[14C][18O]2O- + HCO3-
H[14C]O3- + DC[18O]3- = D[14C][18O]3- + HCO3-
TCO3- + H[14C]O3- = T[14C]O3- + HCO3-
H[14C]O3- + TCO2[18O]- = T[14C]O2[18O]- + HCO3-
H[14C]O3- + TCO[18O]O- = T[14C]O[18O]O- + HCO3-
H[14C]O3- + TC[18O]O2- = T[14C][18O]O2- + HCO3-
H[14C]O3- + TCO[18O]2- = T[14C]O[18O]2- + HCO3-
H[14C]O3- + TC[18O]O[18O]- = T[14C][18O]O[18O]- + HCO3-
H[14C]O3- + TC[18O]2O- = T[14C][18O]2O- + HCO3-
H[14C]O3- + TC[18O]3- = T[14C][18O]3- + HCO3-
#
# CO3-2 reactions
# last update July 31, 2006
# Checked September 19, 2006
#
CO3-2 + H2[18O] = CO2[18O]-2 + H2O
log_k 0.477121254719 # log10(3)
-add_logk Log_alpha_18O_CO3-2/H2O(l) 1.0
2CO2[18O]-2 = CO[18O]2-2 + CO3-2
log_k -0.477121254719 # -log10(3)
CO2[18O]-2 + CO[18O]2-2 = C[18O]3-2 + CO3-2
log_k -0.954242509439324 # log10(1/9)
CO3-2 + [13C]O2 = [13C]O3-2 + CO2
-add_logk Log_alpha_13C_CO3-2/CO2(aq) 1.0
[13C]O3-2 + CO2[18O]-2 = [13C]O2[18O]-2 + CO3-2
log_k 0.0
[13C]O3-2 + CO[18O]2-2 = [13C]O[18O]2-2 + CO3-2
log_k 0.0
[13C]O3-2 + C[18O]3-2 = [13C][18O]3-2 + CO3-2
log_k 0.0
CO3-2 + [14C]O2 = [14C]O3-2 + CO2
-add_logk Log_alpha_14C_CO3-2/CO2(aq) 1.0
[14C]O3-2 + CO2[18O]-2 = [14C]O2[18O]-2 + CO3-2
log_k 0.0
[14C]O3-2 + CO[18O]2-2 = [14C]O[18O]2-2 + CO3-2
log_k 0.0
[14C]O3-2 + C[18O]3-2 = [14C][18O]3-2 + CO3-2
log_k 0.0
#
# CH4 reactions
# Updated September 19, 2006
# Checked September 19, 2006
#
CH4 + HDO = CH3D + H2O
log_k 0.301029995663981198 # log10(2)
-add_logk Log_alpha_D_CH4(aq)/H2O(l) 1.0
2CH3D = CH2D2 + CH4
log_k -0.42596873227228 # log10(3/8)
3CH3D = CHD3 + 2CH4
log_k -1.20411998265 # log10(1/16)
4CH3D = CD4 + 3CH4
log_k -2.408239965311 # log10(1/256)
CH4 + HTO = CH3T + H2O
log_k 0.301029995663981198 # log10(2)
-add_logk Log_alpha_T_CH4(aq)/H2O(l) 1.0
2CH3T = CH2T2 + CH4
log_k -0.42596873227228 # log10(3/8)
3CH3T = CHT3 + 2CH4
log_k -1.20411998265 # log10(1/16)
4CH3T = CT4 + 3CH4
log_k -2.408239965311 # log10(1/256)
#
# Added mixed DT C methane species May 19, 2006
#
CH3T + CHD3 = CD3T + CH4
log_k -0.602059991327962396 # -log10(4)
CH2T2 + CH2D2 = CD2T2 + CH4
log_k -0.7781512503836 # -log10(6)
CHT3 + CH3D = CDT3 + CH4
log_k -0.602059991327962396 # -log10(4)
[13C]O2 + CH4 = [13C]H4 + CO2
-add_logk Log_alpha_13C_CH4(aq)/CO2(aq) 1.0
[13C]H4 + CH3D = [13C]H3D + CH4
[13C]H4 + CH2D2 = [13C]H2D2 + CH4
[13C]H4 + CHD3 = [13C]HD3 + CH4
[13C]H4 + CD4 = [13C]D4 + CH4
[13C]H4 + CH3T = [13C]H3T + CH4
[13C]H4 + CH2T2 = [13C]H2T2 + CH4
[13C]H4 + CHT3 = [13C]HT3 + CH4
[13C]H4 + CT4 = [13C]T4 + CH4
[13C]H4 + CD3T = [13C]D3T + CH4
[13C]H4 + CD2T2 = [13C]D2T2 + CH4
[13C]H4 + CDT3 = [13C]DT3 + CH4
[14C]O2 + CH4 = [14C]H4 + CO2
-add_logk Log_alpha_14C_CH4(aq)/CO2(aq) 1.0
#
# Added mixed DT 14C methane species May 19, 2006
#
[14C]H4 + CH3D = [14C]H3D + CH4
[14C]H4 + CH2D2 = [14C]H2D2 + CH4
[14C]H4 + CHD3 = [14C]HD3 + CH4
[14C]H4 + CD4 = [14C]D4 + CH4
[14C]H4 + CH3T = [14C]H3T + CH4
[14C]H4 + CH2T2 = [14C]H2T2 + CH4
[14C]H4 + CHT3 = [14C]HT3 + CH4
[14C]H4 + CT4 = [14C]T4 + CH4
[14C]H4 + CD3T = [14C]D3T + CH4
[14C]H4 + CD2T2 = [14C]D2T2 + CH4
[14C]H4 + CDT3 = [14C]DT3 + CH4
#
# HSO4- reactions
# Updated September 28, 2006
# Checked September 28, 2006
#
HSO4- + HDO = DSO4- + H2O
log_k -0.301029995663 # -log10(2)
-add_logk Log_alpha_D_HSO4-/H2O(l) 1.0
-mole_balance DS(6)O4-
HSO4- + HTO = TSO4- + H2O
log_k -0.301029995663 # -log10(2)
-add_logk Log_alpha_T_HSO4-/H2O(l) 1.0
-mole_balance TS(6)O4-
[34S]O4-2 + HSO4- = H[34S]O4- + SO4-2
-add_logk Log_alpha_34S_HSO4-/SO4-2 1.0
-mole_balance H[34S](6)O4-
H[34S]O4- + DSO4- = D[34S]O4- + HSO4-
-mole_balance D[34S](6)O4
H[34S]O4- + TSO4- = T[34S]O4- + HSO4-
-mole_balance T[34S](6)O4-
#
# S-2 reactions
#
S-2 + H[34S]- = [34S]-2 + HS-
-add_logk Log_alpha_34S_S-2/HS- 1.0
-mole_balance [34S](-2)
-gamma 5.0000 0.0000
#
# HS- reactions
#
HS- + HDO = DS- + H2O
log_k -0.301029995663 # -log10(2)
-add_logk Log_alpha_D_HS-/H2O(l) 1.0
-mole_balance DS(-2)
-gamma 3.5000 0.0000
HS- + HTO = TS- + H2O
log_k -0.301029995663 # -log10(2)
-add_logk Log_alpha_T_HS-/H2O(l) 1.0
-mole_balance TS(-2)
-gamma 3.5000 0.0000
HS- + [34S]O4-2 = H[34S]- + SO4-2
-add_logk Log_alpha_34S_HS-/SO4-2 1.0
-mole_balance H[34S](-2)
-gamma 3.5000 0.0000
H[34S]- + DS- = D[34S]- + HS-
-gamma 3.5000 0.0000
-mole_balance D[34S](-2)
H[34S]- + TS- = T[34S]- + HS-
-gamma 3.5000 0.0000
-mole_balance T[34S](-2)
#
# H2S reactions
#
H2S + HDO = HDS + H2O
-add_logk Log_alpha_D_H2S(aq)/H2O(l) 1.0
-mole_balance HDS(-2)
2HDS = D2S + H2S
log_k -0.602059991327962396 # -log10(4)
-mole_balance D2S(-2)
H2S + HTO = HTS + H2O
-add_logk Log_alpha_T_H2S(aq)/H2O(l) 1.0
-mole_balance HTS(-2)
2HTS = T2S + H2S
log_k -0.602059991327962396 # -log10(4)
-mole_balance T2S(-2)
HDS + HTS = DTS + H2S
log_k -0.301029995663 # log10(1/2)
-mole_balance DTS(-2)
H[34S]- + H2S = H2[34S] + HS-
-add_logk Log_alpha_34S_H2S(aq)/HS- 1.0
-mole_balance H2[34S](-2)
H2[34S] + HDS = HD[34S] + H2S
-mole_balance HD[34S](-2)
H2[34S] + D2S = D2[34S] + H2S
-mole_balance D2[34S](-2)
H2[34S] + HTS = HT[34S] + H2S
-mole_balance HT[34S](-2)
H2[34S] + T2S = T2[34S] + H2S
-mole_balance T2[34S](-2)
H2[34S] + DTS = DT[34S] + H2S
-mole_balance DT[34S](-2)
#
# NO2- reactions
# Updated March 20, 2006
# Updated September 19, 2006
# Checked September 19, 2006
#
[15N]O3- + NO2- = [15N]O2- + NO3-
-add_logk Log_alpha_15N_NO2-/NO3- 1.0
-gamma 3.0000 0.0000
#
# N2 reactions
#
N2 + [15N]O3- = N[15N] + NO3-
log_k 0.301029995663 # log10(2)
-add_logk Log_alpha_15N_N2(aq)/NO3- 1.0
-mole_balance [15N](0)N(0)
2N[15N] = [15N]2 + N2
log_k -0.602059991327962396 # -log10(4)
-mole_balance [15N](0)2
#
# NH3 reactions
#
HDO + NH3 = NH2D + H2O
log_k 0.176091259055 # log10(1.5)
-add_logk Log_alpha_D_NH3(aq)/H2O(l) 1.0
2NH2D = NHD2 + NH3
log_k -0.477121254719 # -log10(3)
3NH2D = ND3 + 2NH3
-logk -1.431363764158 # log10(1/27)
HTO + NH3 = NH2T + H2O
log_k 0.176091259055 # log10(1.5)
-add_logk Log_alpha_T_NH3(aq)/H2O(l) 1.0
2NH2T = NHT2 + NH3
log_k -0.477121254719662 # log10(1/3)
3NH2T = NT3 + 2NH3
-logk -1.431363764158 # log10(1/27)
NHD2 + NH2T = ND2T + NH3
log_k -0.477121254719 # -log10(3)
NH2D + NHT2 = NDT2 + NH3
log_k -0.477121254719 # -log10(3)
# Checked September 19, 2006
NH3 + [15N]O3- = [15N]H3 + NO3-
-add_logk Log_alpha_15N_NH3(aq)/NO3- 1.0
-mole_balance [15N](-3)H3
[15N]H3 + NH2D = [15N]H2D + NH3
[15N]H3 + NHD2 = [15N]HD2 + NH3
[15N]H3 + ND3 = [15N]D3 + NH3
[15N]H3 + NH2T = [15N]H2T + NH3
[15N]H3 + NHT2 = [15N]HT2 + NH3
[15N]H3 + NT3 = [15N]T3 + NH3
[15N]H3 + ND2T = [15N]D2T + NH3
[15N]H3 + NDT2 = [15N]DT2 + NH3
#
# NH4+ reactions
# Updated September 19, 2006
# Checked September 19, 2006
#
HDO + NH4+ = NH3D+ + H2O
log_k 0.301029995663 # log10(2)
-add_logk Log_alpha_D_NH4+/H2O(l) 1.0
-mole_balance N(-3)H3D
-gamma 2.5000 0.0000
2NH3D+ = NH2D2+ + NH4+
log_k -0.42596873227228 # log10(3/8)
-mole_balance N(-3)H2D2
-gamma 2.5000 0.0000
3NH3D+ = NHD3+ + 2NH4+
log_k -1.20411998265 # log10(1/16)
-mole_balance N(-3)HD3
-gamma 2.5000 0.0000
4NH3D+ = ND4+ + 3NH4+
log_k -2.408239965311 # log10(1/256)
-mole_balance N(-3)D4
-gamma 2.5000 0.0000
HTO + NH4+ = NH3T+ + H2O
log_k 0.301029995663 # log10(2)
-add_logk Log_alpha_T_NH4+/H2O(l) 1.0
-mole_balance N(-3)H3T
-gamma 2.5000 0.0000
2NH3T+ = NH2T2+ + NH4+
log_k -0.42596873227228 # log10(3/8)
-mole_balance N(-3)H2T2
-gamma 2.5000 0.0000
3NH3T+ = NHT3+ + 2NH4+
log_k -1.20411998265 # log10(1/16)
-mole_balance N(-3)HT3
-gamma 2.5000 0.0000
4NH3T+ = NT4+ + 3NH4+
log_k -2.408239965311 # log10(1/256)
-mole_balance N(-3)T4
-gamma 2.5000 0.0000
#
# Updated September 19, 2006
# Checked September 19, 2006
#
NHD3+ + NH3T+ = ND3T+ + NH4+
log_k -0.602059991327962396 # -log10(4)
-mole_balance N(-3)D3T
-gamma 2.5000 0.0000
NH2D2+ + NH2T2+ = ND2T2+ + NH4+
log_k -0.7781512503836 # -log10(6)
-mole_balance N(-3)D2T2
-gamma 2.5000 0.0000
NH3D+ + NHT3+ = NDT3+ + NH4+
log_k -0.602059991327962396 # -log10(4)
-mole_balance N(-3)DT3
-gamma 2.5000 0.0000
[15N]H3 + NH4+ = [15N]H4+ + NH3
-add_logk Log_alpha_15N_NH4+/NH3(aq) 1.0
-mole_balance [15N](-3)H4
-gamma 2.5000 0.0000
[15N]H4+ + NH3D+ = [15N]H3D+ + NH4+
-mole_balance [15N](-3)H3D
-gamma 2.5000 0.0000
[15N]H4+ + NH2D2+ = [15N]H2D2+ + NH4+
-mole_balance [15N](-3)H2D2
-gamma 2.5000 0.0000
[15N]H4+ + NHD3+ = [15N]HD3+ + NH4+
-mole_balance [15N](-3)HD3
-gamma 2.5000 0.0000
[15N]H4+ + ND4+ = [15N]D4+ + NH4+
-mole_balance [15N](-3)D4+
-gamma 2.5000 0.0000
[15N]H4+ + NH3T+ = [15N]H3T+ + NH4+
-mole_balance [15N](-3)H3T
-gamma 2.5000 0.0000
[15N]H4+ + NH2T2+ = [15N]H2T2+ + NH4+
-mole_balance [15N](-3)H2T2
-gamma 2.5000 0.0000
[15N]H4+ + NHT3+ = [15N]HT3+ + NH4+
-mole_balance [15N](-3)HT3
-gamma 2.5000 0.0000
[15N]H4+ + NT4+ = [15N]T4+ + NH4+
-mole_balance [15N](-3)T4+
-gamma 2.5000 0.0000
[15N]H4+ + ND3T+ = [15N]D3T+ + NH4+
-mole_balance [15N](-3)D3T
-gamma 2.5000 0.0000
[15N]H4+ + ND2T2+ = [15N]D2T2+ + NH4+
-mole_balance [15N](-3)D2T2
-gamma 2.5000 0.0000
[15N]H4+ + NDT3+ = [15N]DT3+ + NH4+
-mole_balance [15N](-3)DT3
-gamma 2.5000 0.0000
#
# Missing NH4SO4- reactions
#
#
# Missing PO4-2 reactions
#
#
# Missing HPO4-2 reactions
#
#
# Missing H2PO4- reactions
#
#
# Added HF reactions 16Dec09
#
HF + HDO = DF + H2O
HF + HTO = TF + H2O
#
# Added HF2- reactions 16Dec09
#
HF2- + HDO = DF2- + H2O
HF2- + HTO = TF2- + H2O
#
# CaOH reactions
#
CaOH+ + [18O]H- = Ca[18O]H+ + OH-
-mole_balance Ca[18O]H
CaOH+ + OD- = CaOD+ + OH-
-mole_balance CaOD
CaOH+ + [18O]D- = Ca[18O]D+ + OH-
-mole_balance Ca[18O]D
CaOH+ + OT- = CaOT+ + OH-
-mole_balance CaOT+
CaOH+ + [18O]T- = Ca[18O]T+ + OH-
-mole_balance Ca[18O]T
#
# CaCO3 reactions
#
CaCO3 + CO2[18O]-2 = CaCO2[18O] + CO3-2
CaCO3 + CO[18O]2-2 = CaCO[18O]2 + CO3-2
CaCO3 + C[18O]3-2 = CaC[18O]3 + CO3-2
CaCO3 + [13C]O3-2 = Ca[13C]O3 + CO3-2
CaCO3 + [13C]O2[18O]-2 = Ca[13C]O2[18O] + CO3-2
CaCO3 + [13C]O[18O]2-2 = Ca[13C]O[18O]2 + CO3-2
CaCO3 + [13C][18O]3-2 = Ca[13C][18O]3 + CO3-2
CaCO3 + [14C]O3-2 = Ca[14C]O3 + CO3-2
CaCO3 + [14C]O2[18O]-2 = Ca[14C]O2[18O] + CO3-2
CaCO3 + [14C]O[18O]2-2 = Ca[14C]O[18O]2 + CO3-2
CaCO3 + [14C][18O]3-2 = Ca[14C][18O]3 + CO3-2
#
# CaHCO3+ reactions
#
CaHCO3+ + HCO2[18O]- = CaHCO2[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + HCO[18O]O- = CaHCO[18O]O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + HC[18O]O2- = CaHC[18O]O2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + HCO[18O]2- = CaHCO[18O]2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + HC[18O]O[18O]- = CaHC[18O]O[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + HC[18O]2O- = CaHC[18O]2O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + HC[18O]3- = CaHC[18O]3+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + H[13C]O3- = CaH[13C]O3+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + H[13C]O2[18O]- = CaH[13C]O2[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + H[13C]O[18O]O- = CaH[13C]O[18O]O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + H[13C][18O]O2- = CaH[13C][18O]O2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + H[13C]O[18O]2- = CaH[13C]O[18O]2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + H[13C][18O]O[18O]- = CaH[13C][18O]O[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + H[13C][18O]2O- = CaH[13C][18O]2O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + H[13C][18O]3- = CaH[13C][18O]3+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + H[14C]O3- = CaH[14C]O3+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + H[14C]O2[18O]- = CaH[14C]O2[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + H[14C]O[18O]O- = CaH[14C]O[18O]O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + H[14C][18O]O2- = CaH[14C][18O]O2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + H[14C]O[18O]2- = CaH[14C]O[18O]2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + H[14C][18O]O[18O]- = CaH[14C][18O]O[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + H[14C][18O]2O- = CaH[14C][18O]2O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + H[14C][18O]3- = CaH[14C][18O]3+ + HCO3-
-gamma 5.4000 0.0000
# DCO3-
CaHCO3+ + DCO3- = CaDCO3+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + DCO2[18O]- = CaDCO2[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + DCO[18O]O- = CaDCO[18O]O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + DC[18O]O2- = CaDC[18O]O2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + DCO[18O]2- = CaDCO[18O]2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + DC[18O]O[18O]- = CaDC[18O]O[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + DC[18O]2O- = CaDC[18O]2O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + DC[18O]3- = CaDC[18O]3+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + D[13C]O3- = CaD[13C]O3+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + D[13C]O2[18O]- = CaD[13C]O2[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + D[13C]O[18O]O- = CaD[13C]O[18O]O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + D[13C][18O]O2- = CaD[13C][18O]O2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + D[13C]O[18O]2- = CaD[13C]O[18O]2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + D[13C][18O]O[18O]- = CaD[13C][18O]O[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + D[13C][18O]2O- = CaD[13C][18O]2O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + D[13C][18O]3- = CaD[13C][18O]3+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + D[14C]O3- = CaD[14C]O3+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + D[14C]O2[18O]- = CaD[14C]O2[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + D[14C]O[18O]O- = CaD[14C]O[18O]O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + D[14C][18O]O2- = CaD[14C][18O]O2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + D[14C]O[18O]2- = CaD[14C]O[18O]2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + D[14C][18O]O[18O]- = CaD[14C][18O]O[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + D[14C][18O]2O- = CaD[14C][18O]2O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + D[14C][18O]3- = CaD[14C][18O]3+ + HCO3-
-gamma 5.4000 0.0000
# TCO3-
CaHCO3+ + TCO3- = CaTCO3+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + TCO2[18O]- = CaTCO2[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + TCO[18O]O- = CaTCO[18O]O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + TC[18O]O2- = CaTC[18O]O2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + TCO[18O]2- = CaTCO[18O]2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + TC[18O]O[18O]- = CaTC[18O]O[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + TC[18O]2O- = CaTC[18O]2O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + TC[18O]3- = CaTC[18O]3+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + T[13C]O3- = CaT[13C]O3+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + T[13C]O2[18O]- = CaT[13C]O2[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + T[13C]O[18O]O- = CaT[13C]O[18O]O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + T[13C][18O]O2- = CaT[13C][18O]O2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + T[13C]O[18O]2- = CaT[13C]O[18O]2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + T[13C][18O]O[18O]- = CaT[13C][18O]O[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + T[13C][18O]2O- = CaT[13C][18O]2O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + T[13C][18O]3- = CaT[13C][18O]3+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + T[14C]O3- = CaT[14C]O3+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + T[14C]O2[18O]- = CaT[14C]O2[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + T[14C]O[18O]O- = CaT[14C]O[18O]O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + T[14C][18O]O2- = CaT[14C][18O]O2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + T[14C]O[18O]2- = CaT[14C]O[18O]2+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + T[14C][18O]O[18O]- = CaT[14C][18O]O[18O]+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + T[14C][18O]2O- = CaT[14C][18O]2O+ + HCO3-
-gamma 5.4000 0.0000
CaHCO3+ + T[14C][18O]3- = CaT[14C][18O]3+ + HCO3-
-gamma 5.4000 0.0000
#
# CaSO4 reactions
#
# Updated May 17, 2006
CaSO4 + [34S]O4-2 = Ca[34S]O4 + SO4-2
#
# CaHSO4+ reactions
#
CaHSO4+ + H[34S]O4- = CaH[34S]O4+ + HSO4-
CaHSO4+ + D[34S]O4- = CaD[34S]O4+ + HSO4-
CaHSO4+ + T[34S]O4- = CaT[34S]O4+ + HSO4-
#
# Missing CaPO4- reactions
#
#
# Missing CaHPO4 reactions
#
#
# Missing CaH2PO4+ reactions
#
#
# MgOH+ reactions
#
MgOH+ + [18O]H- = Mg[18O]H+ + OH-
MgOH+ + OD- = MgOD+ + OH-
MgOH+ + [18O]D- = Mg[18O]D+ + OH-
MgOH+ + OT- = MgOT+ + OH-
MgOH+ + [18O]T- = Mg[18O]T+ + OH-
#
# MgCO3 reactions
#
MgCO3 + CO2[18O]-2 = MgCO2[18O] + CO3-2
MgCO3 + CO[18O]2-2 = MgCO[18O]2 + CO3-2
MgCO3 + C[18O]3-2 = MgC[18O]3 + CO3-2
MgCO3 + [13C]O3-2 = Mg[13C]O3 + CO3-2
MgCO3 + [13C]O2[18O]-2 = Mg[13C]O2[18O] + CO3-2
MgCO3 + [13C]O[18O]2-2 = Mg[13C]O[18O]2 + CO3-2
MgCO3 + [13C][18O]3-2 = Mg[13C][18O]3 + CO3-2
MgCO3 + [14C]O3-2 = Mg[14C]O3 + CO3-2
MgCO3 + [14C]O2[18O]-2 = Mg[14C]O2[18O] + CO3-2
MgCO3 + [14C]O[18O]2-2 = Mg[14C]O[18O]2 + CO3-2
MgCO3 + [14C][18O]3-2 = Mg[14C][18O]3 + CO3-2
#
# MgHCO3+ reactions
#
MgHCO3+ + HCO2[18O]- = MgHCO2[18O]+ + HCO3-
MgHCO3+ + HCO[18O]O- = MgHCO[18O]O+ + HCO3-
MgHCO3+ + HC[18O]O2- = MgHC[18O]O2+ + HCO3-
MgHCO3+ + HCO[18O]2- = MgHCO[18O]2+ + HCO3-
MgHCO3+ + HC[18O]O[18O]- = MgHC[18O]O[18O]+ + HCO3-
MgHCO3+ + HC[18O]2O- = MgHC[18O]2O+ + HCO3-
MgHCO3+ + HC[18O]3- = MgHC[18O]3+ + HCO3-
MgHCO3+ + H[13C]O3- = MgH[13C]O3+ + HCO3-
MgHCO3+ + H[13C]O2[18O]- = MgH[13C]O2[18O]+ + HCO3-
MgHCO3+ + H[13C]O[18O]O- = MgH[13C]O[18O]O+ + HCO3-
MgHCO3+ + H[13C][18O]O2- = MgH[13C][18O]O2+ + HCO3-
MgHCO3+ + H[13C]O[18O]2- = MgH[13C]O[18O]2+ + HCO3-
MgHCO3+ + H[13C][18O]O[18O]- = MgH[13C][18O]O[18O]+ + HCO3-
MgHCO3+ + H[13C][18O]2O- = MgH[13C][18O]2O+ + HCO3-
MgHCO3+ + H[13C][18O]3- = MgH[13C][18O]3+ + HCO3-
MgHCO3+ + H[14C]O3- = MgH[14C]O3+ + HCO3-
MgHCO3+ + H[14C]O2[18O]- = MgH[14C]O2[18O]+ + HCO3-
MgHCO3+ + H[14C]O[18O]O- = MgH[14C]O[18O]O+ + HCO3-
MgHCO3+ + H[14C][18O]O2- = MgH[14C][18O]O2+ + HCO3-
MgHCO3+ + H[14C]O[18O]2- = MgH[14C]O[18O]2+ + HCO3-
MgHCO3+ + H[14C][18O]O[18O]- = MgH[14C][18O]O[18O]+ + HCO3-
MgHCO3+ + H[14C][18O]2O- = MgH[14C][18O]2O+ + HCO3-
MgHCO3+ + H[14C][18O]3- = MgH[14C][18O]3+ + HCO3-
# DCO3-
MgHCO3+ + DCO3- = MgDCO3+ + HCO3-
MgHCO3+ + DCO2[18O]- = MgDCO2[18O]+ + HCO3-
MgHCO3+ + DCO[18O]O- = MgDCO[18O]O+ + HCO3-
MgHCO3+ + DC[18O]O2- = MgDC[18O]O2+ + HCO3-
MgHCO3+ + DCO[18O]2- = MgDCO[18O]2+ + HCO3-
MgHCO3+ + DC[18O]O[18O]- = MgDC[18O]O[18O]+ + HCO3-
MgHCO3+ + DC[18O]2O- = MgDC[18O]2O+ + HCO3-
MgHCO3+ + DC[18O]3- = MgDC[18O]3+ + HCO3-
MgHCO3+ + D[13C]O3- = MgD[13C]O3+ + HCO3-
MgHCO3+ + D[13C]O2[18O]- = MgD[13C]O2[18O]+ + HCO3-
MgHCO3+ + D[13C]O[18O]O- = MgD[13C]O[18O]O+ + HCO3-
MgHCO3+ + D[13C][18O]O2- = MgD[13C][18O]O2+ + HCO3-
MgHCO3+ + D[13C]O[18O]2- = MgD[13C]O[18O]2+ + HCO3-
MgHCO3+ + D[13C][18O]O[18O]- = MgD[13C][18O]O[18O]+ + HCO3-
MgHCO3+ + D[13C][18O]2O- = MgD[13C][18O]2O+ + HCO3-
MgHCO3+ + D[13C][18O]3- = MgD[13C][18O]3+ + HCO3-
MgHCO3+ + D[14C]O3- = MgD[14C]O3+ + HCO3-
MgHCO3+ + D[14C]O2[18O]- = MgD[14C]O2[18O]+ + HCO3-
MgHCO3+ + D[14C]O[18O]O- = MgD[14C]O[18O]O+ + HCO3-
MgHCO3+ + D[14C][18O]O2- = MgD[14C][18O]O2+ + HCO3-
MgHCO3+ + D[14C]O[18O]2- = MgD[14C]O[18O]2+ + HCO3-
MgHCO3+ + D[14C][18O]O[18O]- = MgD[14C][18O]O[18O]+ + HCO3-
MgHCO3+ + D[14C][18O]2O- = MgD[14C][18O]2O+ + HCO3-
MgHCO3+ + D[14C][18O]3- = MgD[14C][18O]3+ + HCO3-
# TCO3-
MgHCO3+ + TCO3- = MgTCO3+ + HCO3-
MgHCO3+ + TCO2[18O]- = MgTCO2[18O]+ + HCO3-
MgHCO3+ + TCO[18O]O- = MgTCO[18O]O+ + HCO3-
MgHCO3+ + TC[18O]O2- = MgTC[18O]O2+ + HCO3-
MgHCO3+ + TCO[18O]2- = MgTCO[18O]2+ + HCO3-
MgHCO3+ + TC[18O]O[18O]- = MgTC[18O]O[18O]+ + HCO3-
MgHCO3+ + TC[18O]2O- = MgTC[18O]2O+ + HCO3-
MgHCO3+ + TC[18O]3- = MgTC[18O]3+ + HCO3-
MgHCO3+ + T[13C]O3- = MgT[13C]O3+ + HCO3-
MgHCO3+ + T[13C]O2[18O]- = MgT[13C]O2[18O]+ + HCO3-
MgHCO3+ + T[13C]O[18O]O- = MgT[13C]O[18O]O+ + HCO3-
MgHCO3+ + T[13C][18O]O2- = MgT[13C][18O]O2+ + HCO3-
MgHCO3+ + T[13C]O[18O]2- = MgT[13C]O[18O]2+ + HCO3-
MgHCO3+ + T[13C][18O]O[18O]- = MgT[13C][18O]O[18O]+ + HCO3-
MgHCO3+ + T[13C][18O]2O- = MgT[13C][18O]2O+ + HCO3-
MgHCO3+ + T[13C][18O]3- = MgT[13C][18O]3+ + HCO3-
MgHCO3+ + T[14C]O3- = MgT[14C]O3+ + HCO3-
MgHCO3+ + T[14C]O2[18O]- = MgT[14C]O2[18O]+ + HCO3-
MgHCO3+ + T[14C]O[18O]O- = MgT[14C]O[18O]O+ + HCO3-
MgHCO3+ + T[14C][18O]O2- = MgT[14C][18O]O2+ + HCO3-
MgHCO3+ + T[14C]O[18O]2- = MgT[14C]O[18O]2+ + HCO3-
MgHCO3+ + T[14C][18O]O[18O]- = MgT[14C][18O]O[18O]+ + HCO3-
MgHCO3+ + T[14C][18O]2O- = MgT[14C][18O]2O+ + HCO3-
MgHCO3+ + T[14C][18O]3- = MgT[14C][18O]3+ + HCO3-
#
# MgSO4 reactions
#
MgSO4 + [34S]O4-2 = Mg[34S]O4 + SO4-2
#
# Missing MgPO4- reactions
#
#
# Missing MgHPO4 reactions
#
#
# Missing Mg2PO4+ reactions
#
#
# NaOH reactions
#
NaOH + [18O]H- = Na[18O]H + OH-
NaOH + OD- = NaOD + OH-
NaOH + [18O]D- = Na[18O]D + OH-
NaOH + OT- = NaOT + OH-
NaOH + [18O]T- = Na[18O]T + OH-
#
# NaCO3- reactions
#
NaCO3- + CO2[18O]-2 = NaCO2[18O]- + CO3-2
NaCO3- + CO[18O]2-2 = NaCO[18O]2- + CO3-2
NaCO3- + C[18O]3-2 = NaC[18O]3- + CO3-2
NaCO3- + [13C]O3-2 = Na[13C]O3- + CO3-2
NaCO3- + [13C]O2[18O]-2 = Na[13C]O2[18O]- + CO3-2
NaCO3- + [13C]O[18O]2-2 = Na[13C]O[18O]2- + CO3-2
NaCO3- + [13C][18O]3-2 = Na[13C][18O]3- + CO3-2
NaCO3- + [14C]O3-2 = Na[14C]O3- + CO3-2
NaCO3- + [14C]O2[18O]-2 = Na[14C]O2[18O]- + CO3-2
NaCO3- + [14C]O[18O]2-2 = Na[14C]O[18O]2- + CO3-2
NaCO3- + [14C][18O]3-2 = Na[14C][18O]3- + CO3-2
#
# NaHCO3 reactions
#
NaHCO3 + HCO2[18O]- = NaHCO2[18O] + HCO3-
NaHCO3 + HCO[18O]O- = NaHCO[18O]O + HCO3-
NaHCO3 + HC[18O]O2- = NaHC[18O]O2 + HCO3-
NaHCO3 + HCO[18O]2- = NaHCO[18O]2 + HCO3-
NaHCO3 + HC[18O]O[18O]- = NaHC[18O]O[18O] + HCO3-
NaHCO3 + HC[18O]2O- = NaHC[18O]2O + HCO3-
NaHCO3 + HC[18O]3- = NaHC[18O]3 + HCO3-
NaHCO3 + H[13C]O3- = NaH[13C]O3 + HCO3-
NaHCO3 + H[13C]O2[18O]- = NaH[13C]O2[18O] + HCO3-
NaHCO3 + H[13C]O[18O]O- = NaH[13C]O[18O]O + HCO3-
NaHCO3 + H[13C][18O]O2- = NaH[13C][18O]O2 + HCO3-
NaHCO3 + H[13C]O[18O]2- = NaH[13C]O[18O]2 + HCO3-
NaHCO3 + H[13C][18O]O[18O]- = NaH[13C][18O]O[18O] + HCO3-
NaHCO3 + H[13C][18O]2O- = NaH[13C][18O]2O + HCO3-
NaHCO3 + H[13C][18O]3- = NaH[13C][18O]3 + HCO3-
NaHCO3 + H[14C]O3- = NaH[14C]O3 + HCO3-
NaHCO3 + H[14C]O2[18O]- = NaH[14C]O2[18O] + HCO3-
NaHCO3 + H[14C]O[18O]O- = NaH[14C]O[18O]O + HCO3-
NaHCO3 + H[14C][18O]O2- = NaH[14C][18O]O2 + HCO3-
NaHCO3 + H[14C]O[18O]2- = NaH[14C]O[18O]2 + HCO3-
NaHCO3 + H[14C][18O]O[18O]- = NaH[14C][18O]O[18O] + HCO3-
NaHCO3 + H[14C][18O]2O- = NaH[14C][18O]2O + HCO3-
NaHCO3 + H[14C][18O]3- = NaH[14C][18O]3 + HCO3-
# DCO3-
NaHCO3 + DCO3- = NaDCO3 + HCO3-
NaHCO3 + DCO2[18O]- = NaDCO2[18O] + HCO3-
NaHCO3 + DCO[18O]O- = NaDCO[18O]O + HCO3-
NaHCO3 + DC[18O]O2- = NaDC[18O]O2 + HCO3-
NaHCO3 + DCO[18O]2- = NaDCO[18O]2 + HCO3-
NaHCO3 + DC[18O]O[18O]- = NaDC[18O]O[18O] + HCO3-
NaHCO3 + DC[18O]2O- = NaDC[18O]2O + HCO3-
NaHCO3 + DC[18O]3- = NaDC[18O]3 + HCO3-
NaHCO3 + D[13C]O3- = NaD[13C]O3 + HCO3-
NaHCO3 + D[13C]O2[18O]- = NaD[13C]O2[18O] + HCO3-
NaHCO3 + D[13C]O[18O]O- = NaD[13C]O[18O]O + HCO3-
NaHCO3 + D[13C][18O]O2- = NaD[13C][18O]O2 + HCO3-
NaHCO3 + D[13C]O[18O]2- = NaD[13C]O[18O]2 + HCO3-
NaHCO3 + D[13C][18O]O[18O]- = NaD[13C][18O]O[18O] + HCO3-
NaHCO3 + D[13C][18O]2O- = NaD[13C][18O]2O + HCO3-
NaHCO3 + D[13C][18O]3- = NaD[13C][18O]3 + HCO3-
NaHCO3 + D[14C]O3- = NaD[14C]O3 + HCO3-
NaHCO3 + D[14C]O2[18O]- = NaD[14C]O2[18O] + HCO3-
NaHCO3 + D[14C]O[18O]O- = NaD[14C]O[18O]O + HCO3-
NaHCO3 + D[14C][18O]O2- = NaD[14C][18O]O2 + HCO3-
NaHCO3 + D[14C]O[18O]2- = NaD[14C]O[18O]2 + HCO3-
NaHCO3 + D[14C][18O]O[18O]- = NaD[14C][18O]O[18O] + HCO3-
NaHCO3 + D[14C][18O]2O- = NaD[14C][18O]2O + HCO3-
NaHCO3 + D[14C][18O]3- = NaD[14C][18O]3 + HCO3-
# TCO3-
NaHCO3 + TCO3- = NaTCO3 + HCO3-
NaHCO3 + TCO2[18O]- = NaTCO2[18O] + HCO3-
NaHCO3 + TCO[18O]O- = NaTCO[18O]O + HCO3-
NaHCO3 + TC[18O]O2- = NaTC[18O]O2 + HCO3-
NaHCO3 + TCO[18O]2- = NaTCO[18O]2 + HCO3-
NaHCO3 + TC[18O]O[18O]- = NaTC[18O]O[18O] + HCO3-
NaHCO3 + TC[18O]2O- = NaTC[18O]2O + HCO3-
NaHCO3 + TC[18O]3- = NaTC[18O]3 + HCO3-
NaHCO3 + T[13C]O3- = NaT[13C]O3 + HCO3-
NaHCO3 + T[13C]O2[18O]- = NaT[13C]O2[18O] + HCO3-
NaHCO3 + T[13C]O[18O]O- = NaT[13C]O[18O]O + HCO3-
NaHCO3 + T[13C][18O]O2- = NaT[13C][18O]O2 + HCO3-
NaHCO3 + T[13C]O[18O]2- = NaT[13C]O[18O]2 + HCO3-
NaHCO3 + T[13C][18O]O[18O]- = NaT[13C][18O]O[18O] + HCO3-
NaHCO3 + T[13C][18O]2O- = NaT[13C][18O]2O + HCO3-
NaHCO3 + T[13C][18O]3- = NaT[13C][18O]3 + HCO3-
NaHCO3 + T[14C]O3- = NaT[14C]O3 + HCO3-
NaHCO3 + T[14C]O2[18O]- = NaT[14C]O2[18O] + HCO3-
NaHCO3 + T[14C]O[18O]O- = NaT[14C]O[18O]O + HCO3-
NaHCO3 + T[14C][18O]O2- = NaT[14C][18O]O2 + HCO3-
NaHCO3 + T[14C]O[18O]2- = NaT[14C]O[18O]2 + HCO3-
NaHCO3 + T[14C][18O]O[18O]- = NaT[14C][18O]O[18O] + HCO3-
NaHCO3 + T[14C][18O]2O- = NaT[14C][18O]2O + HCO3-
NaHCO3 + T[14C][18O]3- = NaT[14C][18O]3 + HCO3-
#
# NaSO4- reactions
#
NaSO4- + [34S]O4-2 = Na[34S]O4- + SO4-2
#
# Missing NaHPO4- reactions
#
#
# KOH reactions
#
KOH + [18O]H- = K[18O]H + OH-
KOH + OD- = KOD + OH-
KOH + [18O]D- = K[18O]D + OH-
KOH + OT- = KOT + OH-
KOH + [18O]T- = K[18O]T + OH-
#
# KSO4- reactions
#
KSO4- + [34S]O4-2 = K[34S]O4- + SO4-2
#
# Added FeOH+ reactions 16Dec09
#
FeOH+ + OD- = FeOD+ + OH-
FeOH+ + OT- = FeOT+ + OH-
FeOH+ + [18O]H- = Fe[18O]H+ + OH-
FeOH+ + [18O]D- = Fe[18O]D+ + OH-
FeOH+ + [18O]T- = Fe[18O]T+ + OH-
#
# Added FeCO3 reactions 16Dec09
# Checked 17Dec09
#
FeCO3 + CO2[18O]-2 = FeCO2[18O] + CO3-2
FeCO3 + CO[18O]2-2 = FeCO[18O]2 + CO3-2
FeCO3 + C[18O]3-2 = FeC[18O]3 + CO3-2
FeCO3 + [13C]O3-2 = Fe[13C]O3 + CO3-2
FeCO3 + [13C]O2[18O]-2 = Fe[13C]O2[18O] + CO3-2
FeCO3 + [13C]O[18O]2-2 = Fe[13C]O[18O]2 + CO3-2
FeCO3 + [13C][18O]3-2 = Fe[13C][18O]3 + CO3-2
FeCO3 + [14C]O3-2 = Fe[14C]O3 + CO3-2
FeCO3 + [14C]O2[18O]-2 = Fe[14C]O2[18O] + CO3-2
FeCO3 + [14C]O[18O]2-2 = Fe[14C]O[18O]2 + CO3-2
FeCO3 + [14C][18O]3-2 = Fe[14C][18O]3 + CO3-2
#
# Added FeHCO3+ reactions 16Dec09
# Revised 17Dec09
#
FeHCO3+ + HCO2[18O]- = FeHCO2[18O]+ + HCO3-
FeHCO3+ + HCO[18O]O- = FeHCO[18O]O+ + HCO3-
FeHCO3+ + HCO[18O]2- = FeHCO[18O]2+ + HCO3-
FeHCO3+ + HC[18O]O2- = FeHC[18O]O2+ + HCO3-
FeHCO3+ + HC[18O]O[18O]- = FeHC[18O]O[18O]+ + HCO3-
FeHCO3+ + HC[18O]2O- = FeHC[18O]2O+ + HCO3-
FeHCO3+ + HC[18O]3- = FeHC[18O]3+ + HCO3-
FeHCO3+ + H[13C]O3- = FeH[13C]O3+ + HCO3-
FeHCO3+ + H[13C]O2[18O]- = FeH[13C]O2[18O]+ + HCO3-
FeHCO3+ + H[13C]O[18O]O- = FeH[13C]O[18O]O+ + HCO3-
FeHCO3+ + H[13C]O[18O]2- = FeH[13C]O[18O]2+ + HCO3-
FeHCO3+ + H[13C][18O]O2- = FeH[13C][18O]O2+ + HCO3-
FeHCO3+ + H[13C][18O]O[18O]- = FeH[13C][18O]O[18O]+ + HCO3-
FeHCO3+ + H[13C][18O]2O- = FeH[13C][18O]2O+ + HCO3-
FeHCO3+ + H[13C][18O]3- = FeH[13C][18O]3+ + HCO3-
FeHCO3+ + H[14C]O3- = FeH[14C]O3+ + HCO3-
FeHCO3+ + H[14C]O2[18O]- = FeH[14C]O2[18O]+ + HCO3-
FeHCO3+ + H[14C]O[18O]O- = FeH[14C]O[18O]O+ + HCO3-
FeHCO3+ + H[14C]O[18O]2- = FeH[14C]O[18O]2+ + HCO3-
FeHCO3+ + H[14C][18O]O2- = FeH[14C][18O]O2+ + HCO3-
FeHCO3+ + H[14C][18O]O[18O]- = FeH[14C][18O]O[18O]+ + HCO3-
FeHCO3+ + H[14C][18O]2O- = FeH[14C][18O]2O+ + HCO3-
FeHCO3+ + H[14C][18O]3- = FeH[14C][18O]3+ + HCO3-
FeHCO3+ + DCO3- = FeDCO3+ + HCO3-
FeHCO3+ + DCO2[18O]- = FeDCO2[18O]+ + HCO3-
FeHCO3+ + DCO[18O]O- = FeDCO[18O]O+ + HCO3-
FeHCO3+ + DCO[18O]2- = FeDCO[18O]2+ + HCO3-
FeHCO3+ + DC[18O]O2- = FeDC[18O]O2+ + HCO3-
FeHCO3+ + DC[18O]O[18O]- = FeDC[18O]O[18O]+ + HCO3-
FeHCO3+ + DC[18O]2O- = FeDC[18O]2O+ + HCO3-
FeHCO3+ + DC[18O]3- = FeDC[18O]3+ + HCO3-
FeHCO3+ + D[13C]O3- = FeD[13C]O3+ + HCO3-
FeHCO3+ + D[13C]O2[18O]- = FeD[13C]O2[18O]+ + HCO3-
FeHCO3+ + D[13C]O[18O]O- = FeD[13C]O[18O]O+ + HCO3-
FeHCO3+ + D[13C]O[18O]2- = FeD[13C]O[18O]2+ + HCO3-
FeHCO3+ + D[13C][18O]O2- = FeD[13C][18O]O2+ + HCO3-
FeHCO3+ + D[13C][18O]O[18O]- = FeD[13C][18O]O[18O]+ + HCO3-
FeHCO3+ + D[13C][18O]2O- = FeD[13C][18O]2O+ + HCO3-
FeHCO3+ + D[13C][18O]3- = FeD[13C][18O]3+ + HCO3-
FeHCO3+ + D[14C]O3- = FeD[14C]O3+ + HCO3-
FeHCO3+ + D[14C]O2[18O]- = FeD[14C]O2[18O]+ + HCO3-
FeHCO3+ + D[14C]O[18O]O- = FeD[14C]O[18O]O+ + HCO3-
FeHCO3+ + D[14C]O[18O]2- = FeD[14C]O[18O]2+ + HCO3-
FeHCO3+ + D[14C][18O]O2- = FeD[14C][18O]O2+ + HCO3-
FeHCO3+ + D[14C][18O]O[18O]- = FeD[14C][18O]O[18O]+ + HCO3-
FeHCO3+ + D[14C][18O]2O- = FeD[14C][18O]2O+ + HCO3-
FeHCO3+ + D[14C][18O]3- = FeD[14C][18O]3+ + HCO3-
FeHCO3+ + TCO3- = FeTCO3+ + HCO3-
FeHCO3+ + TCO2[18O]- = FeTCO2[18O]+ + HCO3-
FeHCO3+ + TCO[18O]O- = FeTCO[18O]O+ + HCO3-
FeHCO3+ + TCO[18O]2- = FeTCO[18O]2+ + HCO3-
FeHCO3+ + TC[18O]O2- = FeTC[18O]O2+ + HCO3-
FeHCO3+ + TC[18O]O[18O]- = FeTC[18O]O[18O]+ + HCO3-
FeHCO3+ + TC[18O]2O- = FeTC[18O]2O+ + HCO3-
FeHCO3+ + TC[18O]3- = FeTC[18O]3+ + HCO3-
FeHCO3+ + T[13C]O3- = FeT[13C]O3+ + HCO3-
FeHCO3+ + T[13C]O2[18O]- = FeT[13C]O2[18O]+ + HCO3-
FeHCO3+ + T[13C]O[18O]O- = FeT[13C]O[18O]O+ + HCO3-
FeHCO3+ + T[13C]O[18O]2- = FeT[13C]O[18O]2+ + HCO3-
FeHCO3+ + T[13C][18O]O2- = FeT[13C][18O]O2+ + HCO3-
FeHCO3+ + T[13C][18O]O[18O]- = FeT[13C][18O]O[18O]+ + HCO3-
FeHCO3+ + T[13C][18O]2O- = FeT[13C][18O]2O+ + HCO3-
FeHCO3+ + T[13C][18O]3- = FeT[13C][18O]3+ + HCO3-
FeHCO3+ + T[14C]O3- = FeT[14C]O3+ + HCO3-
FeHCO3+ + T[14C]O2[18O]- = FeT[14C]O2[18O]+ + HCO3-
FeHCO3+ + T[14C]O[18O]O- = FeT[14C]O[18O]O+ + HCO3-
FeHCO3+ + T[14C]O[18O]2- = FeT[14C]O[18O]2+ + HCO3-
FeHCO3+ + T[14C][18O]O2- = FeT[14C][18O]O2+ + HCO3-
FeHCO3+ + T[14C][18O]O[18O]- = FeT[14C][18O]O[18O]+ + HCO3-
FeHCO3+ + T[14C][18O]2O- = FeT[14C][18O]2O+ + HCO3-
FeHCO3+ + T[14C][18O]3- = FeT[14C][18O]3+ + HCO3-
#
# Added FeSO4 reactions 16Dec09
#
FeSO4 + [34S]O4-2 = Fe[34S]O4 + SO4-2
#
# Added FeHSO4+ reactions 16Dec09
#
FeHSO4+ + DSO4- = FeDSO4+ + HSO4-
FeHSO4+ + TSO4- = FeTSO4+ + HSO4-
FeHSO4+ + H[34S]O4- = FeH[34S]O4+ + HSO4-
FeHSO4+ + D[34S]O4- = FeD[34S]O4+ + HSO4-
FeHSO4+ + T[34S]O4- = FeT[34S]O4+ + HSO4-
#
# Added Fe(HS)2 reactions 16Dec09
# Revised 17Dec09, limited the number of species
#
Fe(HS)2 + HS- + DS- = FeHSDS + 2HS-
Fe(HS)2 + HS- + TS- = FeHSTS + 2HS-
Fe(HS)2 + HS- + H[34S]- = FeHSH[34S] + 2HS-
Fe(HS)2 + HS- + D[34S]- = FeHSD[34S] + 2HS-
Fe(HS)2 + HS- + T[34S]- = FeHST[34S] + 2HS-
Fe(HS)2 + DS- + HS- = FeDSHS + 2HS-
Fe(HS)2 + DS- + DS- = FeDSDS + 2HS-
Fe(HS)2 + DS- + TS- = FeDSTS + 2HS-
Fe(HS)2 + DS- + H[34S]- = FeDSH[34S] + 2HS-
Fe(HS)2 + DS- + D[34S]- = FeDSD[34S] + 2HS-
Fe(HS)2 + DS- + T[34S]- = FeDST[34S] + 2HS-
Fe(HS)2 + TS- + HS- = FeTSHS + 2HS-
Fe(HS)2 + TS- + DS- = FeTSDS + 2HS-
Fe(HS)2 + TS- + H[34S]- = FeTSH[34S] + 2HS-
Fe(HS)2 + TS- + D[34S]- = FeTSD[34S] + 2HS-
Fe(HS)2 + H[34S]- + HS- = FeH[34S]HS + 2HS-
Fe(HS)2 + H[34S]- + DS- = FeH[34S]DS + 2HS-
Fe(HS)2 + H[34S]- + TS- = FeH[34S]TS + 2HS-
Fe(HS)2 + H[34S]- + H[34S]- = FeH[34S]H[34S] + 2HS-
Fe(HS)2 + H[34S]- + D[34S]- = FeH[34S]D[34S] + 2HS-
Fe(HS)2 + H[34S]- + T[34S]- = FeH[34S]T[34S] + 2HS-
Fe(HS)2 + D[34S]- + HS- = FeD[34S]HS + 2HS-
Fe(HS)2 + D[34S]- + DS- = FeD[34S]DS + 2HS-
Fe(HS)2 + D[34S]- + TS- = FeD[34S]TS + 2HS-
Fe(HS)2 + D[34S]- + H[34S]- = FeD[34S]H[34S] + 2HS-
Fe(HS)2 + D[34S]- + D[34S]- = FeD[34S]D[34S] + 2HS-
Fe(HS)2 + D[34S]- + T[34S]- = FeD[34S]T[34S] + 2HS-
Fe(HS)2 + T[34S]- + HS- = FeT[34S]HS + 2HS-
Fe(HS)2 + T[34S]- + DS- = FeT[34S]DS + 2HS-
Fe(HS)2 + T[34S]- + H[34S]- = FeT[34S]H[34S] + 2HS-
Fe(HS)2 + T[34S]- + D[34S]- = FeT[34S]D[34S] + 2HS-
#
# Added Fe(HS)3- reactions 16Dec09
# Revised 17Dec09, limited the number of species
#
Fe(HS)3- + HS- + HS- + DS- = FeHSHSDS- + 3HS-
Fe(HS)3- + HS- + HS- + TS- = FeHSHSTS- + 3HS-
Fe(HS)3- + HS- + HS- + H[34S]- = FeHSHSH[34S]- + 3HS-
Fe(HS)3- + HS- + HS- + D[34S]- = FeHSHSD[34S]- + 3HS-
Fe(HS)3- + HS- + HS- + T[34S]- = FeHSHST[34S]- + 3HS-
Fe(HS)3- + HS- + DS- + HS- = FeHSDSHS- + 3HS-
Fe(HS)3- + HS- + DS- + DS- = FeHSDSDS- + 3HS-
Fe(HS)3- + HS- + DS- + TS- = FeHSDSTS- + 3HS-
Fe(HS)3- + HS- + DS- + H[34S]- = FeHSDSH[34S]- + 3HS-
Fe(HS)3- + HS- + DS- + D[34S]- = FeHSDSD[34S]- + 3HS-
Fe(HS)3- + HS- + DS- + T[34S]- = FeHSDST[34S]- + 3HS-
Fe(HS)3- + HS- + TS- + HS- = FeHSTSHS- + 3HS-
Fe(HS)3- + HS- + TS- + DS- = FeHSTSDS- + 3HS-
Fe(HS)3- + HS- + TS- + H[34S]- = FeHSTSH[34S]- + 3HS-
Fe(HS)3- + HS- + TS- + D[34S]- = FeHSTSD[34S]- + 3HS-
Fe(HS)3- + HS- + H[34S]- + HS- = FeHSH[34S]HS- + 3HS-
Fe(HS)3- + HS- + H[34S]- + DS- = FeHSH[34S]DS- + 3HS-
Fe(HS)3- + HS- + H[34S]- + TS- = FeHSH[34S]TS- + 3HS-
Fe(HS)3- + HS- + H[34S]- + H[34S]- = FeHSH[34S]H[34S]- + 3HS-
Fe(HS)3- + HS- + H[34S]- + D[34S]- = FeHSH[34S]D[34S]- + 3HS-
Fe(HS)3- + HS- + H[34S]- + T[34S]- = FeHSH[34S]T[34S]- + 3HS-
Fe(HS)3- + HS- + D[34S]- + HS- = FeHSD[34S]HS- + 3HS-
Fe(HS)3- + HS- + D[34S]- + DS- = FeHSD[34S]DS- + 3HS-
Fe(HS)3- + HS- + D[34S]- + TS- = FeHSD[34S]TS- + 3HS-
Fe(HS)3- + HS- + D[34S]- + H[34S]- = FeHSD[34S]H[34S]- + 3HS-
Fe(HS)3- + HS- + D[34S]- + D[34S]- = FeHSD[34S]D[34S]- + 3HS-
Fe(HS)3- + HS- + D[34S]- + T[34S]- = FeHSD[34S]T[34S]- + 3HS-
Fe(HS)3- + HS- + T[34S]- + HS- = FeHST[34S]HS- + 3HS-
Fe(HS)3- + HS- + T[34S]- + DS- = FeHST[34S]DS- + 3HS-
Fe(HS)3- + HS- + T[34S]- + H[34S]- = FeHST[34S]H[34S]- + 3HS-
Fe(HS)3- + HS- + T[34S]- + D[34S]- = FeHST[34S]D[34S]- + 3HS-
Fe(HS)3- + DS- + HS- + HS- = FeDSHSHS- + 3HS-
Fe(HS)3- + DS- + HS- + DS- = FeDSHSDS- + 3HS-
Fe(HS)3- + DS- + HS- + TS- = FeDSHSTS- + 3HS-
Fe(HS)3- + DS- + HS- + H[34S]- = FeDSHSH[34S]- + 3HS-
Fe(HS)3- + DS- + HS- + D[34S]- = FeDSHSD[34S]- + 3HS-
Fe(HS)3- + DS- + HS- + T[34S]- = FeDSHST[34S]- + 3HS-
Fe(HS)3- + DS- + DS- + HS- = FeDSDSHS- + 3HS-
Fe(HS)3- + DS- + DS- + TS- = FeDSDSTS- + 3HS-
Fe(HS)3- + DS- + DS- + H[34S]- = FeDSDSH[34S]- + 3HS-
Fe(HS)3- + DS- + DS- + T[34S]- = FeDSDST[34S]- + 3HS-
Fe(HS)3- + DS- + TS- + HS- = FeDSTSHS- + 3HS-
Fe(HS)3- + DS- + TS- + DS- = FeDSTSDS- + 3HS-
Fe(HS)3- + DS- + TS- + H[34S]- = FeDSTSH[34S]- + 3HS-
Fe(HS)3- + DS- + TS- + D[34S]- = FeDSTSD[34S]- + 3HS-
Fe(HS)3- + DS- + H[34S]- + HS- = FeDSH[34S]HS- + 3HS-
Fe(HS)3- + DS- + H[34S]- + DS- = FeDSH[34S]DS- + 3HS-
Fe(HS)3- + DS- + H[34S]- + TS- = FeDSH[34S]TS- + 3HS-
Fe(HS)3- + DS- + H[34S]- + H[34S]- = FeDSH[34S]H[34S]- + 3HS-
Fe(HS)3- + DS- + H[34S]- + D[34S]- = FeDSH[34S]D[34S]- + 3HS-
Fe(HS)3- + DS- + H[34S]- + T[34S]- = FeDSH[34S]T[34S]- + 3HS-
Fe(HS)3- + DS- + D[34S]- + HS- = FeDSD[34S]HS- + 3HS-
Fe(HS)3- + DS- + D[34S]- + TS- = FeDSD[34S]TS- + 3HS-
Fe(HS)3- + DS- + D[34S]- + H[34S]- = FeDSD[34S]H[34S]- + 3HS-
Fe(HS)3- + DS- + T[34S]- + HS- = FeDST[34S]HS- + 3HS-
Fe(HS)3- + DS- + T[34S]- + DS- = FeDST[34S]DS- + 3HS-
Fe(HS)3- + DS- + T[34S]- + H[34S]- = FeDST[34S]H[34S]- + 3HS-
Fe(HS)3- + TS- + HS- + HS- = FeTSHSHS- + 3HS-
Fe(HS)3- + TS- + HS- + DS- = FeTSHSDS- + 3HS-
Fe(HS)3- + TS- + HS- + H[34S]- = FeTSHSH[34S]- + 3HS-
Fe(HS)3- + TS- + HS- + D[34S]- = FeTSHSD[34S]- + 3HS-
Fe(HS)3- + TS- + DS- + HS- = FeTSDSHS- + 3HS-
Fe(HS)3- + TS- + DS- + DS- = FeTSDSDS- + 3HS-
Fe(HS)3- + TS- + DS- + H[34S]- = FeTSDSH[34S]- + 3HS-
Fe(HS)3- + TS- + DS- + D[34S]- = FeTSDSD[34S]- + 3HS-
Fe(HS)3- + TS- + H[34S]- + HS- = FeTSH[34S]HS- + 3HS-
Fe(HS)3- + TS- + H[34S]- + DS- = FeTSH[34S]DS- + 3HS-
Fe(HS)3- + TS- + H[34S]- + H[34S]- = FeTSH[34S]H[34S]- + 3HS-
Fe(HS)3- + TS- + H[34S]- + D[34S]- = FeTSH[34S]D[34S]- + 3HS-
Fe(HS)3- + TS- + D[34S]- + HS- = FeTSD[34S]HS- + 3HS-
Fe(HS)3- + TS- + D[34S]- + DS- = FeTSD[34S]DS- + 3HS-
Fe(HS)3- + TS- + D[34S]- + H[34S]- = FeTSD[34S]H[34S]- + 3HS-
Fe(HS)3- + H[34S]- + HS- + HS- = FeH[34S]HSHS- + 3HS-
Fe(HS)3- + H[34S]- + HS- + DS- = FeH[34S]HSDS- + 3HS-
Fe(HS)3- + H[34S]- + HS- + TS- = FeH[34S]HSTS- + 3HS-
Fe(HS)3- + H[34S]- + HS- + H[34S]- = FeH[34S]HSH[34S]- + 3HS-
Fe(HS)3- + H[34S]- + HS- + D[34S]- = FeH[34S]HSD[34S]- + 3HS-
Fe(HS)3- + H[34S]- + HS- + T[34S]- = FeH[34S]HST[34S]- + 3HS-
Fe(HS)3- + H[34S]- + DS- + HS- = FeH[34S]DSHS- + 3HS-
Fe(HS)3- + H[34S]- + DS- + DS- = FeH[34S]DSDS- + 3HS-
Fe(HS)3- + H[34S]- + DS- + TS- = FeH[34S]DSTS- + 3HS-
Fe(HS)3- + H[34S]- + DS- + H[34S]- = FeH[34S]DSH[34S]- + 3HS-
Fe(HS)3- + H[34S]- + DS- + D[34S]- = FeH[34S]DSD[34S]- + 3HS-
Fe(HS)3- + H[34S]- + DS- + T[34S]- = FeH[34S]DST[34S]- + 3HS-
Fe(HS)3- + H[34S]- + TS- + HS- = FeH[34S]TSHS- + 3HS-
Fe(HS)3- + H[34S]- + TS- + DS- = FeH[34S]TSDS- + 3HS-
Fe(HS)3- + H[34S]- + TS- + H[34S]- = FeH[34S]TSH[34S]- + 3HS-
Fe(HS)3- + H[34S]- + TS- + D[34S]- = FeH[34S]TSD[34S]- + 3HS-
Fe(HS)3- + H[34S]- + H[34S]- + HS- = FeH[34S]H[34S]HS- + 3HS-
Fe(HS)3- + H[34S]- + H[34S]- + DS- = FeH[34S]H[34S]DS- + 3HS-
Fe(HS)3- + H[34S]- + H[34S]- + TS- = FeH[34S]H[34S]TS- + 3HS-
Fe(HS)3- + H[34S]- + H[34S]- + H[34S]- = FeH[34S]H[34S]H[34S]- + 3HS-
Fe(HS)3- + H[34S]- + H[34S]- + D[34S]- = FeH[34S]H[34S]D[34S]- + 3HS-
Fe(HS)3- + H[34S]- + H[34S]- + T[34S]- = FeH[34S]H[34S]T[34S]- + 3HS-
Fe(HS)3- + H[34S]- + D[34S]- + HS- = FeH[34S]D[34S]HS- + 3HS-
Fe(HS)3- + H[34S]- + D[34S]- + DS- = FeH[34S]D[34S]DS- + 3HS-
Fe(HS)3- + H[34S]- + D[34S]- + TS- = FeH[34S]D[34S]TS- + 3HS-
Fe(HS)3- + H[34S]- + D[34S]- + H[34S]- = FeH[34S]D[34S]H[34S]- + 3HS-
Fe(HS)3- + H[34S]- + T[34S]- + HS- = FeH[34S]T[34S]HS- + 3HS-
Fe(HS)3- + H[34S]- + T[34S]- + DS- = FeH[34S]T[34S]DS- + 3HS-
Fe(HS)3- + H[34S]- + T[34S]- + H[34S]- = FeH[34S]T[34S]H[34S]- + 3HS-
Fe(HS)3- + D[34S]- + HS- + HS- = FeD[34S]HSHS- + 3HS-
Fe(HS)3- + D[34S]- + HS- + DS- = FeD[34S]HSDS- + 3HS-
Fe(HS)3- + D[34S]- + HS- + TS- = FeD[34S]HSTS- + 3HS-
Fe(HS)3- + D[34S]- + HS- + H[34S]- = FeD[34S]HSH[34S]- + 3HS-
Fe(HS)3- + D[34S]- + HS- + D[34S]- = FeD[34S]HSD[34S]- + 3HS-
Fe(HS)3- + D[34S]- + HS- + T[34S]- = FeD[34S]HST[34S]- + 3HS-
Fe(HS)3- + D[34S]- + DS- + HS- = FeD[34S]DSHS- + 3HS-
Fe(HS)3- + D[34S]- + DS- + TS- = FeD[34S]DSTS- + 3HS-
Fe(HS)3- + D[34S]- + DS- + H[34S]- = FeD[34S]DSH[34S]- + 3HS-
Fe(HS)3- + D[34S]- + TS- + HS- = FeD[34S]TSHS- + 3HS-
Fe(HS)3- + D[34S]- + TS- + DS- = FeD[34S]TSDS- + 3HS-
Fe(HS)3- + D[34S]- + TS- + H[34S]- = FeD[34S]TSH[34S]- + 3HS-
Fe(HS)3- + D[34S]- + H[34S]- + HS- = FeD[34S]H[34S]HS- + 3HS-
Fe(HS)3- + D[34S]- + H[34S]- + DS- = FeD[34S]H[34S]DS- + 3HS-
Fe(HS)3- + D[34S]- + H[34S]- + TS- = FeD[34S]H[34S]TS- + 3HS-
Fe(HS)3- + D[34S]- + H[34S]- + H[34S]- = FeD[34S]H[34S]H[34S]- + 3HS-
Fe(HS)3- + D[34S]- + D[34S]- + HS- = FeD[34S]D[34S]HS- + 3HS-
Fe(HS)3- + D[34S]- + T[34S]- + HS- = FeD[34S]T[34S]HS- + 3HS-
Fe(HS)3- + T[34S]- + HS- + HS- = FeT[34S]HSHS- + 3HS-
Fe(HS)3- + T[34S]- + HS- + DS- = FeT[34S]HSDS- + 3HS-
Fe(HS)3- + T[34S]- + HS- + H[34S]- = FeT[34S]HSH[34S]- + 3HS-
Fe(HS)3- + T[34S]- + HS- + D[34S]- = FeT[34S]HSD[34S]- + 3HS-
Fe(HS)3- + T[34S]- + DS- + HS- = FeT[34S]DSHS- + 3HS-
Fe(HS)3- + T[34S]- + DS- + DS- = FeT[34S]DSDS- + 3HS-
Fe(HS)3- + T[34S]- + DS- + H[34S]- = FeT[34S]DSH[34S]- + 3HS-
Fe(HS)3- + T[34S]- + H[34S]- + HS- = FeT[34S]H[34S]HS- + 3HS-
Fe(HS)3- + T[34S]- + H[34S]- + DS- = FeT[34S]H[34S]DS- + 3HS-
Fe(HS)3- + T[34S]- + H[34S]- + H[34S]- = FeT[34S]H[34S]H[34S]- + 3HS-
Fe(HS)3- + T[34S]- + D[34S]- + HS- = FeT[34S]D[34S]HS- + 3HS-
#
# Missing FeHPO4 reactions
#
#
# Missing FeH2PO4+ reactions
#
#
# Added FeOH+2 reactions 16Dec09
#
FeOH+2 + OD- = FeOD+2 + OH-
FeOH+2 + OT- = FeOT+2 + OH-
FeOH+2 + [18O]H- = Fe[18O]H+2 + OH-
FeOH+2 + [18O]D- = Fe[18O]D+2 + OH-
FeOH+2 + [18O]T- = Fe[18O]T+2 + OH-
#
# Added Fe(OH)2+ reactions 16Dec09
# Revised 17Dec09, limited the number of species
#
Fe(OH)2+ + OH- + OD- = FeOHOD+ + 2OH-
Fe(OH)2+ + OH- + OT- = FeOHOT+ + 2OH-
Fe(OH)2+ + OH- + [18O]H- = FeOH[18O]H+ + 2OH-
Fe(OH)2+ + OH- + [18O]D- = FeOH[18O]D+ + 2OH-
Fe(OH)2+ + OH- + [18O]T- = FeOH[18O]T+ + 2OH-
Fe(OH)2+ + OD- + OH- = FeODOH+ + 2OH-
Fe(OH)2+ + OD- + OD- = FeODOD+ + 2OH-
Fe(OH)2+ + OD- + OT- = FeODOT+ + 2OH-
Fe(OH)2+ + OD- + [18O]H- = FeOD[18O]H+ + 2OH-
Fe(OH)2+ + OD- + [18O]D- = FeOD[18O]D+ + 2OH-
Fe(OH)2+ + OD- + [18O]T- = FeOD[18O]T+ + 2OH-
Fe(OH)2+ + OT- + OH- = FeOTOH+ + 2OH-
Fe(OH)2+ + OT- + OD- = FeOTOD+ + 2OH-
Fe(OH)2+ + OT- + [18O]H- = FeOT[18O]H+ + 2OH-
Fe(OH)2+ + OT- + [18O]D- = FeOT[18O]D+ + 2OH-
Fe(OH)2+ + [18O]H- + OH- = Fe[18O]HOH+ + 2OH-
Fe(OH)2+ + [18O]H- + OD- = Fe[18O]HOD+ + 2OH-
Fe(OH)2+ + [18O]H- + OT- = Fe[18O]HOT+ + 2OH-
Fe(OH)2+ + [18O]H- + [18O]H- = Fe[18O]H[18O]H+ + 2OH-
Fe(OH)2+ + [18O]H- + [18O]D- = Fe[18O]H[18O]D+ + 2OH-
Fe(OH)2+ + [18O]H- + [18O]T- = Fe[18O]H[18O]T+ + 2OH-
Fe(OH)2+ + [18O]D- + OH- = Fe[18O]DOH+ + 2OH-
Fe(OH)2+ + [18O]D- + OD- = Fe[18O]DOD+ + 2OH-
Fe(OH)2+ + [18O]D- + OT- = Fe[18O]DOT+ + 2OH-
Fe(OH)2+ + [18O]D- + [18O]H- = Fe[18O]D[18O]H+ + 2OH-
Fe(OH)2+ + [18O]D- + [18O]D- = Fe[18O]D[18O]D+ + 2OH-
Fe(OH)2+ + [18O]D- + [18O]T- = Fe[18O]D[18O]T+ + 2OH-
Fe(OH)2+ + [18O]T- + OH- = Fe[18O]TOH+ + 2OH-
Fe(OH)2+ + [18O]T- + OD- = Fe[18O]TOD+ + 2OH-
Fe(OH)2+ + [18O]T- + [18O]H- = Fe[18O]T[18O]H+ + 2OH-
Fe(OH)2+ + [18O]T- + [18O]D- = Fe[18O]T[18O]D+ + 2OH-
#
# Added Fe(OH)3 reactions 16Dec09
# Revised 17Dec09, limited the number of species
#
Fe(OH)3 + OH- + OH- + OD- = FeOHOHOD + 3OH-
Fe(OH)3 + OH- + OH- + OT- = FeOHOHOT + 3OH-
Fe(OH)3 + OH- + OH- + [18O]H- = FeOHOH[18O]H + 3OH-
Fe(OH)3 + OH- + OH- + [18O]D- = FeOHOH[18O]D + 3OH-
Fe(OH)3 + OH- + OH- + [18O]T- = FeOHOH[18O]T + 3OH-
Fe(OH)3 + OH- + OD- + OH- = FeOHODOH + 3OH-
Fe(OH)3 + OH- + OD- + OD- = FeOHODOD + 3OH-
Fe(OH)3 + OH- + OD- + OT- = FeOHODOT + 3OH-
Fe(OH)3 + OH- + OD- + [18O]H- = FeOHOD[18O]H + 3OH-
Fe(OH)3 + OH- + OD- + [18O]D- = FeOHOD[18O]D + 3OH-
Fe(OH)3 + OH- + OD- + [18O]T- = FeOHOD[18O]T + 3OH-
Fe(OH)3 + OH- + OT- + OH- = FeOHOTOH + 3OH-
Fe(OH)3 + OH- + OT- + OD- = FeOHOTOD + 3OH-
Fe(OH)3 + OH- + OT- + [18O]H- = FeOHOT[18O]H + 3OH-
Fe(OH)3 + OH- + OT- + [18O]D- = FeOHOT[18O]D + 3OH-
Fe(OH)3 + OH- + [18O]H- + OH- = FeOH[18O]HOH + 3OH-
Fe(OH)3 + OH- + [18O]H- + OD- = FeOH[18O]HOD + 3OH-
Fe(OH)3 + OH- + [18O]H- + OT- = FeOH[18O]HOT + 3OH-
Fe(OH)3 + OH- + [18O]H- + [18O]H- = FeOH[18O]H[18O]H + 3OH-
Fe(OH)3 + OH- + [18O]H- + [18O]D- = FeOH[18O]H[18O]D + 3OH-
Fe(OH)3 + OH- + [18O]H- + [18O]T- = FeOH[18O]H[18O]T + 3OH-
Fe(OH)3 + OH- + [18O]D- + OH- = FeOH[18O]DOH + 3OH-
Fe(OH)3 + OH- + [18O]D- + OD- = FeOH[18O]DOD + 3OH-
Fe(OH)3 + OH- + [18O]D- + OT- = FeOH[18O]DOT + 3OH-
Fe(OH)3 + OH- + [18O]D- + [18O]H- = FeOH[18O]D[18O]H + 3OH-
Fe(OH)3 + OH- + [18O]D- + [18O]D- = FeOH[18O]D[18O]D + 3OH-
Fe(OH)3 + OH- + [18O]D- + [18O]T- = FeOH[18O]D[18O]T + 3OH-
Fe(OH)3 + OH- + [18O]T- + OH- = FeOH[18O]TOH + 3OH-
Fe(OH)3 + OH- + [18O]T- + OD- = FeOH[18O]TOD + 3OH-
Fe(OH)3 + OH- + [18O]T- + [18O]H- = FeOH[18O]T[18O]H + 3OH-
Fe(OH)3 + OH- + [18O]T- + [18O]D- = FeOH[18O]T[18O]D + 3OH-
Fe(OH)3 + OD- + OH- + OH- = FeODOHOH + 3OH-
Fe(OH)3 + OD- + OH- + OD- = FeODOHOD + 3OH-
Fe(OH)3 + OD- + OH- + OT- = FeODOHOT + 3OH-
Fe(OH)3 + OD- + OH- + [18O]H- = FeODOH[18O]H + 3OH-
Fe(OH)3 + OD- + OH- + [18O]D- = FeODOH[18O]D + 3OH-
Fe(OH)3 + OD- + OH- + [18O]T- = FeODOH[18O]T + 3OH-
Fe(OH)3 + OD- + OD- + OH- = FeODODOH + 3OH-
Fe(OH)3 + OD- + OD- + OT- = FeODODOT + 3OH-
Fe(OH)3 + OD- + OD- + [18O]H- = FeODOD[18O]H + 3OH-
Fe(OH)3 + OD- + OD- + [18O]T- = FeODOD[18O]T + 3OH-
Fe(OH)3 + OD- + OT- + OH- = FeODOTOH + 3OH-
Fe(OH)3 + OD- + OT- + OD- = FeODOTOD + 3OH-
Fe(OH)3 + OD- + OT- + [18O]H- = FeODOT[18O]H + 3OH-
Fe(OH)3 + OD- + OT- + [18O]D- = FeODOT[18O]D + 3OH-
Fe(OH)3 + OD- + [18O]H- + OH- = FeOD[18O]HOH + 3OH-
Fe(OH)3 + OD- + [18O]H- + OD- = FeOD[18O]HOD + 3OH-
Fe(OH)3 + OD- + [18O]H- + OT- = FeOD[18O]HOT + 3OH-
Fe(OH)3 + OD- + [18O]H- + [18O]H- = FeOD[18O]H[18O]H + 3OH-
Fe(OH)3 + OD- + [18O]H- + [18O]D- = FeOD[18O]H[18O]D + 3OH-
Fe(OH)3 + OD- + [18O]H- + [18O]T- = FeOD[18O]H[18O]T + 3OH-
Fe(OH)3 + OD- + [18O]D- + OH- = FeOD[18O]DOH + 3OH-
Fe(OH)3 + OD- + [18O]D- + OT- = FeOD[18O]DOT + 3OH-
Fe(OH)3 + OD- + [18O]D- + [18O]H- = FeOD[18O]D[18O]H + 3OH-
Fe(OH)3 + OD- + [18O]T- + OH- = FeOD[18O]TOH + 3OH-
Fe(OH)3 + OD- + [18O]T- + OD- = FeOD[18O]TOD + 3OH-
Fe(OH)3 + OD- + [18O]T- + [18O]H- = FeOD[18O]T[18O]H + 3OH-
Fe(OH)3 + OT- + OH- + OH- = FeOTOHOH + 3OH-
Fe(OH)3 + OT- + OH- + OD- = FeOTOHOD + 3OH-
Fe(OH)3 + OT- + OH- + [18O]H- = FeOTOH[18O]H + 3OH-
Fe(OH)3 + OT- + OH- + [18O]D- = FeOTOH[18O]D + 3OH-
Fe(OH)3 + OT- + OD- + OH- = FeOTODOH + 3OH-
Fe(OH)3 + OT- + OD- + OD- = FeOTODOD + 3OH-
Fe(OH)3 + OT- + OD- + [18O]H- = FeOTOD[18O]H + 3OH-
Fe(OH)3 + OT- + OD- + [18O]D- = FeOTOD[18O]D + 3OH-
Fe(OH)3 + OT- + [18O]H- + OH- = FeOT[18O]HOH + 3OH-
Fe(OH)3 + OT- + [18O]H- + OD- = FeOT[18O]HOD + 3OH-
Fe(OH)3 + OT- + [18O]H- + [18O]H- = FeOT[18O]H[18O]H + 3OH-
Fe(OH)3 + OT- + [18O]H- + [18O]D- = FeOT[18O]H[18O]D + 3OH-
Fe(OH)3 + OT- + [18O]D- + OH- = FeOT[18O]DOH + 3OH-
Fe(OH)3 + OT- + [18O]D- + OD- = FeOT[18O]DOD + 3OH-
Fe(OH)3 + OT- + [18O]D- + [18O]H- = FeOT[18O]D[18O]H + 3OH-
Fe(OH)3 + [18O]H- + OH- + OH- = Fe[18O]HOHOH + 3OH-
Fe(OH)3 + [18O]H- + OH- + OD- = Fe[18O]HOHOD + 3OH-
Fe(OH)3 + [18O]H- + OH- + OT- = Fe[18O]HOHOT + 3OH-
Fe(OH)3 + [18O]H- + OH- + [18O]H- = Fe[18O]HOH[18O]H + 3OH-
Fe(OH)3 + [18O]H- + OH- + [18O]D- = Fe[18O]HOH[18O]D + 3OH-
Fe(OH)3 + [18O]H- + OH- + [18O]T- = Fe[18O]HOH[18O]T + 3OH-
Fe(OH)3 + [18O]H- + OD- + OH- = Fe[18O]HODOH + 3OH-
Fe(OH)3 + [18O]H- + OD- + OD- = Fe[18O]HODOD + 3OH-
Fe(OH)3 + [18O]H- + OD- + OT- = Fe[18O]HODOT + 3OH-
Fe(OH)3 + [18O]H- + OD- + [18O]H- = Fe[18O]HOD[18O]H + 3OH-
Fe(OH)3 + [18O]H- + OD- + [18O]D- = Fe[18O]HOD[18O]D + 3OH-
Fe(OH)3 + [18O]H- + OD- + [18O]T- = Fe[18O]HOD[18O]T + 3OH-
Fe(OH)3 + [18O]H- + OT- + OH- = Fe[18O]HOTOH + 3OH-
Fe(OH)3 + [18O]H- + OT- + OD- = Fe[18O]HOTOD + 3OH-
Fe(OH)3 + [18O]H- + OT- + [18O]H- = Fe[18O]HOT[18O]H + 3OH-
Fe(OH)3 + [18O]H- + OT- + [18O]D- = Fe[18O]HOT[18O]D + 3OH-
Fe(OH)3 + [18O]H- + [18O]H- + OH- = Fe[18O]H[18O]HOH + 3OH-
Fe(OH)3 + [18O]H- + [18O]H- + OD- = Fe[18O]H[18O]HOD + 3OH-
Fe(OH)3 + [18O]H- + [18O]H- + OT- = Fe[18O]H[18O]HOT + 3OH-
Fe(OH)3 + [18O]H- + [18O]D- + OH- = Fe[18O]H[18O]DOH + 3OH-
Fe(OH)3 + [18O]H- + [18O]D- + OD- = Fe[18O]H[18O]DOD + 3OH-
Fe(OH)3 + [18O]H- + [18O]D- + OT- = Fe[18O]H[18O]DOT + 3OH-
Fe(OH)3 + [18O]H- + [18O]T- + OH- = Fe[18O]H[18O]TOH + 3OH-
Fe(OH)3 + [18O]H- + [18O]T- + OD- = Fe[18O]H[18O]TOD + 3OH-
Fe(OH)3 + [18O]D- + OH- + OH- = Fe[18O]DOHOH + 3OH-
Fe(OH)3 + [18O]D- + OH- + OD- = Fe[18O]DOHOD + 3OH-
Fe(OH)3 + [18O]D- + OH- + OT- = Fe[18O]DOHOT + 3OH-
Fe(OH)3 + [18O]D- + OH- + [18O]H- = Fe[18O]DOH[18O]H + 3OH-
Fe(OH)3 + [18O]D- + OH- + [18O]D- = Fe[18O]DOH[18O]D + 3OH-
Fe(OH)3 + [18O]D- + OH- + [18O]T- = Fe[18O]DOH[18O]T + 3OH-
Fe(OH)3 + [18O]D- + OD- + OH- = Fe[18O]DODOH + 3OH-
Fe(OH)3 + [18O]D- + OD- + OT- = Fe[18O]DODOT + 3OH-
Fe(OH)3 + [18O]D- + OD- + [18O]H- = Fe[18O]DOD[18O]H + 3OH-
Fe(OH)3 + [18O]D- + OT- + OH- = Fe[18O]DOTOH + 3OH-
Fe(OH)3 + [18O]D- + OT- + OD- = Fe[18O]DOTOD + 3OH-
Fe(OH)3 + [18O]D- + OT- + [18O]H- = Fe[18O]DOT[18O]H + 3OH-
Fe(OH)3 + [18O]D- + [18O]H- + OH- = Fe[18O]D[18O]HOH + 3OH-
Fe(OH)3 + [18O]D- + [18O]H- + OD- = Fe[18O]D[18O]HOD + 3OH-
Fe(OH)3 + [18O]D- + [18O]H- + OT- = Fe[18O]D[18O]HOT + 3OH-
Fe(OH)3 + [18O]D- + [18O]D- + OH- = Fe[18O]D[18O]DOH + 3OH-
Fe(OH)3 + [18O]D- + [18O]T- + OH- = Fe[18O]D[18O]TOH + 3OH-
Fe(OH)3 + [18O]T- + OH- + OH- = Fe[18O]TOHOH + 3OH-
Fe(OH)3 + [18O]T- + OH- + OD- = Fe[18O]TOHOD + 3OH-
Fe(OH)3 + [18O]T- + OH- + [18O]H- = Fe[18O]TOH[18O]H + 3OH-
Fe(OH)3 + [18O]T- + OH- + [18O]D- = Fe[18O]TOH[18O]D + 3OH-
Fe(OH)3 + [18O]T- + OD- + OH- = Fe[18O]TODOH + 3OH-
Fe(OH)3 + [18O]T- + OD- + OD- = Fe[18O]TODOD + 3OH-
Fe(OH)3 + [18O]T- + OD- + [18O]H- = Fe[18O]TOD[18O]H + 3OH-
Fe(OH)3 + [18O]T- + [18O]H- + OH- = Fe[18O]T[18O]HOH + 3OH-
Fe(OH)3 + [18O]T- + [18O]H- + OD- = Fe[18O]T[18O]HOD + 3OH-
Fe(OH)3 + [18O]T- + [18O]D- + OH- = Fe[18O]T[18O]DOH + 3OH-
#
# Added Fe(OH)4- reactions 16Dec09
# Revised 17Dec09, limited the number of species
#
Fe(OH)4- + OH- + OH- + OH- + OD- = FeOHOHOHOD- + 4OH-
Fe(OH)4- + OH- + OH- + OH- + OT- = FeOHOHOHOT- + 4OH-
Fe(OH)4- + OH- + OH- + OH- + [18O]H- = FeOHOHOH[18O]H- + 4OH-
Fe(OH)4- + OH- + OH- + OH- + [18O]D- = FeOHOHOH[18O]D- + 4OH-
Fe(OH)4- + OH- + OH- + OH- + [18O]T- = FeOHOHOH[18O]T- + 4OH-
Fe(OH)4- + OH- + OH- + OD- + OH- = FeOHOHODOH- + 4OH-
Fe(OH)4- + OH- + OH- + OD- + OD- = FeOHOHODOD- + 4OH-
Fe(OH)4- + OH- + OH- + OD- + OT- = FeOHOHODOT- + 4OH-
Fe(OH)4- + OH- + OH- + OD- + [18O]H- = FeOHOHOD[18O]H- + 4OH-
Fe(OH)4- + OH- + OH- + OD- + [18O]D- = FeOHOHOD[18O]D- + 4OH-
Fe(OH)4- + OH- + OH- + OD- + [18O]T- = FeOHOHOD[18O]T- + 4OH-
Fe(OH)4- + OH- + OH- + OT- + OH- = FeOHOHOTOH- + 4OH-
Fe(OH)4- + OH- + OH- + OT- + OD- = FeOHOHOTOD- + 4OH-
Fe(OH)4- + OH- + OH- + OT- + [18O]H- = FeOHOHOT[18O]H- + 4OH-
Fe(OH)4- + OH- + OH- + OT- + [18O]D- = FeOHOHOT[18O]D- + 4OH-
Fe(OH)4- + OH- + OH- + [18O]H- + OH- = FeOHOH[18O]HOH- + 4OH-
Fe(OH)4- + OH- + OH- + [18O]H- + OD- = FeOHOH[18O]HOD- + 4OH-
Fe(OH)4- + OH- + OH- + [18O]H- + OT- = FeOHOH[18O]HOT- + 4OH-
Fe(OH)4- + OH- + OH- + [18O]H- + [18O]H- = FeOHOH[18O]H[18O]H- + 4OH-
Fe(OH)4- + OH- + OH- + [18O]H- + [18O]D- = FeOHOH[18O]H[18O]D- + 4OH-
Fe(OH)4- + OH- + OH- + [18O]H- + [18O]T- = FeOHOH[18O]H[18O]T- + 4OH-
Fe(OH)4- + OH- + OH- + [18O]D- + OH- = FeOHOH[18O]DOH- + 4OH-
Fe(OH)4- + OH- + OH- + [18O]D- + OD- = FeOHOH[18O]DOD- + 4OH-
Fe(OH)4- + OH- + OH- + [18O]D- + OT- = FeOHOH[18O]DOT- + 4OH-
Fe(OH)4- + OH- + OH- + [18O]D- + [18O]H- = FeOHOH[18O]D[18O]H- + 4OH-
Fe(OH)4- + OH- + OH- + [18O]D- + [18O]D- = FeOHOH[18O]D[18O]D- + 4OH-
Fe(OH)4- + OH- + OH- + [18O]D- + [18O]T- = FeOHOH[18O]D[18O]T- + 4OH-
Fe(OH)4- + OH- + OH- + [18O]T- + OH- = FeOHOH[18O]TOH- + 4OH-
Fe(OH)4- + OH- + OH- + [18O]T- + OD- = FeOHOH[18O]TOD- + 4OH-
Fe(OH)4- + OH- + OH- + [18O]T- + [18O]H- = FeOHOH[18O]T[18O]H- + 4OH-
Fe(OH)4- + OH- + OH- + [18O]T- + [18O]D- = FeOHOH[18O]T[18O]D- + 4OH-
Fe(OH)4- + OH- + OD- + OH- + OH- = FeOHODOHOH- + 4OH-
Fe(OH)4- + OH- + OD- + OH- + OD- = FeOHODOHOD- + 4OH-
Fe(OH)4- + OH- + OD- + OH- + OT- = FeOHODOHOT- + 4OH-
Fe(OH)4- + OH- + OD- + OH- + [18O]H- = FeOHODOH[18O]H- + 4OH-
Fe(OH)4- + OH- + OD- + OH- + [18O]D- = FeOHODOH[18O]D- + 4OH-
Fe(OH)4- + OH- + OD- + OH- + [18O]T- = FeOHODOH[18O]T- + 4OH-
Fe(OH)4- + OH- + OD- + OD- + OH- = FeOHODODOH- + 4OH-
Fe(OH)4- + OH- + OD- + OD- + OT- = FeOHODODOT- + 4OH-
Fe(OH)4- + OH- + OD- + OD- + [18O]H- = FeOHODOD[18O]H- + 4OH-
Fe(OH)4- + OH- + OD- + OD- + [18O]T- = FeOHODOD[18O]T- + 4OH-
Fe(OH)4- + OH- + OD- + OT- + OH- = FeOHODOTOH- + 4OH-
Fe(OH)4- + OH- + OD- + OT- + OD- = FeOHODOTOD- + 4OH-
Fe(OH)4- + OH- + OD- + OT- + [18O]H- = FeOHODOT[18O]H- + 4OH-
Fe(OH)4- + OH- + OD- + OT- + [18O]D- = FeOHODOT[18O]D- + 4OH-
Fe(OH)4- + OH- + OD- + [18O]H- + OH- = FeOHOD[18O]HOH- + 4OH-
Fe(OH)4- + OH- + OD- + [18O]H- + OD- = FeOHOD[18O]HOD- + 4OH-
Fe(OH)4- + OH- + OD- + [18O]H- + OT- = FeOHOD[18O]HOT- + 4OH-
Fe(OH)4- + OH- + OD- + [18O]H- + [18O]H- = FeOHOD[18O]H[18O]H- + 4OH-
Fe(OH)4- + OH- + OD- + [18O]H- + [18O]D- = FeOHOD[18O]H[18O]D- + 4OH-
Fe(OH)4- + OH- + OD- + [18O]H- + [18O]T- = FeOHOD[18O]H[18O]T- + 4OH-
Fe(OH)4- + OH- + OD- + [18O]D- + OH- = FeOHOD[18O]DOH- + 4OH-
Fe(OH)4- + OH- + OD- + [18O]D- + OT- = FeOHOD[18O]DOT- + 4OH-
Fe(OH)4- + OH- + OD- + [18O]D- + [18O]H- = FeOHOD[18O]D[18O]H- + 4OH-
Fe(OH)4- + OH- + OD- + [18O]T- + OH- = FeOHOD[18O]TOH- + 4OH-
Fe(OH)4- + OH- + OD- + [18O]T- + OD- = FeOHOD[18O]TOD- + 4OH-
Fe(OH)4- + OH- + OD- + [18O]T- + [18O]H- = FeOHOD[18O]T[18O]H- + 4OH-
Fe(OH)4- + OH- + OT- + OH- + OH- = FeOHOTOHOH- + 4OH-
Fe(OH)4- + OH- + OT- + OH- + OD- = FeOHOTOHOD- + 4OH-
Fe(OH)4- + OH- + OT- + OH- + [18O]H- = FeOHOTOH[18O]H- + 4OH-
Fe(OH)4- + OH- + OT- + OH- + [18O]D- = FeOHOTOH[18O]D- + 4OH-
Fe(OH)4- + OH- + OT- + OD- + OH- = FeOHOTODOH- + 4OH-
Fe(OH)4- + OH- + OT- + OD- + OD- = FeOHOTODOD- + 4OH-
Fe(OH)4- + OH- + OT- + OD- + [18O]H- = FeOHOTOD[18O]H- + 4OH-
Fe(OH)4- + OH- + OT- + OD- + [18O]D- = FeOHOTOD[18O]D- + 4OH-
Fe(OH)4- + OH- + OT- + [18O]H- + OH- = FeOHOT[18O]HOH- + 4OH-
Fe(OH)4- + OH- + OT- + [18O]H- + OD- = FeOHOT[18O]HOD- + 4OH-
Fe(OH)4- + OH- + OT- + [18O]H- + [18O]H- = FeOHOT[18O]H[18O]H- + 4OH-
Fe(OH)4- + OH- + OT- + [18O]H- + [18O]D- = FeOHOT[18O]H[18O]D- + 4OH-
Fe(OH)4- + OH- + OT- + [18O]D- + OH- = FeOHOT[18O]DOH- + 4OH-
Fe(OH)4- + OH- + OT- + [18O]D- + OD- = FeOHOT[18O]DOD- + 4OH-
Fe(OH)4- + OH- + OT- + [18O]D- + [18O]H- = FeOHOT[18O]D[18O]H- + 4OH-
Fe(OH)4- + OH- + [18O]H- + OH- + OH- = FeOH[18O]HOHOH- + 4OH-
Fe(OH)4- + OH- + [18O]H- + OH- + OD- = FeOH[18O]HOHOD- + 4OH-
Fe(OH)4- + OH- + [18O]H- + OH- + OT- = FeOH[18O]HOHOT- + 4OH-
Fe(OH)4- + OH- + [18O]H- + OH- + [18O]H- = FeOH[18O]HOH[18O]H- + 4OH-
Fe(OH)4- + OH- + [18O]H- + OH- + [18O]D- = FeOH[18O]HOH[18O]D- + 4OH-
Fe(OH)4- + OH- + [18O]H- + OH- + [18O]T- = FeOH[18O]HOH[18O]T- + 4OH-
Fe(OH)4- + OH- + [18O]H- + OD- + OH- = FeOH[18O]HODOH- + 4OH-
Fe(OH)4- + OH- + [18O]H- + OD- + OD- = FeOH[18O]HODOD- + 4OH-
Fe(OH)4- + OH- + [18O]H- + OD- + OT- = FeOH[18O]HODOT- + 4OH-
Fe(OH)4- + OH- + [18O]H- + OD- + [18O]H- = FeOH[18O]HOD[18O]H- + 4OH-
Fe(OH)4- + OH- + [18O]H- + OD- + [18O]D- = FeOH[18O]HOD[18O]D- + 4OH-
Fe(OH)4- + OH- + [18O]H- + OD- + [18O]T- = FeOH[18O]HOD[18O]T- + 4OH-
Fe(OH)4- + OH- + [18O]H- + OT- + OH- = FeOH[18O]HOTOH- + 4OH-
Fe(OH)4- + OH- + [18O]H- + OT- + OD- = FeOH[18O]HOTOD- + 4OH-
Fe(OH)4- + OH- + [18O]H- + OT- + [18O]H- = FeOH[18O]HOT[18O]H- + 4OH-
Fe(OH)4- + OH- + [18O]H- + OT- + [18O]D- = FeOH[18O]HOT[18O]D- + 4OH-
Fe(OH)4- + OH- + [18O]H- + [18O]H- + OH- = FeOH[18O]H[18O]HOH- + 4OH-
Fe(OH)4- + OH- + [18O]H- + [18O]H- + OD- = FeOH[18O]H[18O]HOD- + 4OH-
Fe(OH)4- + OH- + [18O]H- + [18O]H- + OT- = FeOH[18O]H[18O]HOT- + 4OH-
Fe(OH)4- + OH- + [18O]H- + [18O]D- + OH- = FeOH[18O]H[18O]DOH- + 4OH-
Fe(OH)4- + OH- + [18O]H- + [18O]D- + OD- = FeOH[18O]H[18O]DOD- + 4OH-
Fe(OH)4- + OH- + [18O]H- + [18O]D- + OT- = FeOH[18O]H[18O]DOT- + 4OH-
Fe(OH)4- + OH- + [18O]H- + [18O]T- + OH- = FeOH[18O]H[18O]TOH- + 4OH-
Fe(OH)4- + OH- + [18O]H- + [18O]T- + OD- = FeOH[18O]H[18O]TOD- + 4OH-
Fe(OH)4- + OH- + [18O]D- + OH- + OH- = FeOH[18O]DOHOH- + 4OH-
Fe(OH)4- + OH- + [18O]D- + OH- + OD- = FeOH[18O]DOHOD- + 4OH-
Fe(OH)4- + OH- + [18O]D- + OH- + OT- = FeOH[18O]DOHOT- + 4OH-
Fe(OH)4- + OH- + [18O]D- + OH- + [18O]H- = FeOH[18O]DOH[18O]H- + 4OH-
Fe(OH)4- + OH- + [18O]D- + OH- + [18O]D- = FeOH[18O]DOH[18O]D- + 4OH-
Fe(OH)4- + OH- + [18O]D- + OH- + [18O]T- = FeOH[18O]DOH[18O]T- + 4OH-
Fe(OH)4- + OH- + [18O]D- + OD- + OH- = FeOH[18O]DODOH- + 4OH-
Fe(OH)4- + OH- + [18O]D- + OD- + OT- = FeOH[18O]DODOT- + 4OH-
Fe(OH)4- + OH- + [18O]D- + OD- + [18O]H- = FeOH[18O]DOD[18O]H- + 4OH-
Fe(OH)4- + OH- + [18O]D- + OT- + OH- = FeOH[18O]DOTOH- + 4OH-
Fe(OH)4- + OH- + [18O]D- + OT- + OD- = FeOH[18O]DOTOD- + 4OH-
Fe(OH)4- + OH- + [18O]D- + OT- + [18O]H- = FeOH[18O]DOT[18O]H- + 4OH-
Fe(OH)4- + OH- + [18O]D- + [18O]H- + OH- = FeOH[18O]D[18O]HOH- + 4OH-
Fe(OH)4- + OH- + [18O]D- + [18O]H- + OD- = FeOH[18O]D[18O]HOD- + 4OH-
Fe(OH)4- + OH- + [18O]D- + [18O]H- + OT- = FeOH[18O]D[18O]HOT- + 4OH-
Fe(OH)4- + OH- + [18O]D- + [18O]D- + OH- = FeOH[18O]D[18O]DOH- + 4OH-
Fe(OH)4- + OH- + [18O]D- + [18O]T- + OH- = FeOH[18O]D[18O]TOH- + 4OH-
Fe(OH)4- + OH- + [18O]T- + OH- + OH- = FeOH[18O]TOHOH- + 4OH-
Fe(OH)4- + OH- + [18O]T- + OH- + OD- = FeOH[18O]TOHOD- + 4OH-
Fe(OH)4- + OH- + [18O]T- + OH- + [18O]H- = FeOH[18O]TOH[18O]H- + 4OH-
Fe(OH)4- + OH- + [18O]T- + OH- + [18O]D- = FeOH[18O]TOH[18O]D- + 4OH-
Fe(OH)4- + OH- + [18O]T- + OD- + OH- = FeOH[18O]TODOH- + 4OH-
Fe(OH)4- + OH- + [18O]T- + OD- + OD- = FeOH[18O]TODOD- + 4OH-
Fe(OH)4- + OH- + [18O]T- + OD- + [18O]H- = FeOH[18O]TOD[18O]H- + 4OH-
Fe(OH)4- + OH- + [18O]T- + [18O]H- + OH- = FeOH[18O]T[18O]HOH- + 4OH-
Fe(OH)4- + OH- + [18O]T- + [18O]H- + OD- = FeOH[18O]T[18O]HOD- + 4OH-
Fe(OH)4- + OH- + [18O]T- + [18O]D- + OH- = FeOH[18O]T[18O]DOH- + 4OH-
Fe(OH)4- + OD- + OH- + OH- + OH- = FeODOHOHOH- + 4OH-
Fe(OH)4- + OD- + OH- + OH- + OD- = FeODOHOHOD- + 4OH-
Fe(OH)4- + OD- + OH- + OH- + OT- = FeODOHOHOT- + 4OH-
Fe(OH)4- + OD- + OH- + OH- + [18O]H- = FeODOHOH[18O]H- + 4OH-
Fe(OH)4- + OD- + OH- + OH- + [18O]D- = FeODOHOH[18O]D- + 4OH-
Fe(OH)4- + OD- + OH- + OH- + [18O]T- = FeODOHOH[18O]T- + 4OH-
Fe(OH)4- + OD- + OH- + OD- + OH- = FeODOHODOH- + 4OH-
Fe(OH)4- + OD- + OH- + OD- + OT- = FeODOHODOT- + 4OH-
Fe(OH)4- + OD- + OH- + OD- + [18O]H- = FeODOHOD[18O]H- + 4OH-
Fe(OH)4- + OD- + OH- + OD- + [18O]T- = FeODOHOD[18O]T- + 4OH-
Fe(OH)4- + OD- + OH- + OT- + OH- = FeODOHOTOH- + 4OH-
Fe(OH)4- + OD- + OH- + OT- + OD- = FeODOHOTOD- + 4OH-
Fe(OH)4- + OD- + OH- + OT- + [18O]H- = FeODOHOT[18O]H- + 4OH-
Fe(OH)4- + OD- + OH- + OT- + [18O]D- = FeODOHOT[18O]D- + 4OH-
Fe(OH)4- + OD- + OH- + [18O]H- + OH- = FeODOH[18O]HOH- + 4OH-
Fe(OH)4- + OD- + OH- + [18O]H- + OD- = FeODOH[18O]HOD- + 4OH-
Fe(OH)4- + OD- + OH- + [18O]H- + OT- = FeODOH[18O]HOT- + 4OH-
Fe(OH)4- + OD- + OH- + [18O]H- + [18O]H- = FeODOH[18O]H[18O]H- + 4OH-
Fe(OH)4- + OD- + OH- + [18O]H- + [18O]D- = FeODOH[18O]H[18O]D- + 4OH-
Fe(OH)4- + OD- + OH- + [18O]H- + [18O]T- = FeODOH[18O]H[18O]T- + 4OH-
Fe(OH)4- + OD- + OH- + [18O]D- + OH- = FeODOH[18O]DOH- + 4OH-
Fe(OH)4- + OD- + OH- + [18O]D- + OT- = FeODOH[18O]DOT- + 4OH-
Fe(OH)4- + OD- + OH- + [18O]D- + [18O]H- = FeODOH[18O]D[18O]H- + 4OH-
Fe(OH)4- + OD- + OH- + [18O]T- + OH- = FeODOH[18O]TOH- + 4OH-
Fe(OH)4- + OD- + OH- + [18O]T- + OD- = FeODOH[18O]TOD- + 4OH-
Fe(OH)4- + OD- + OH- + [18O]T- + [18O]H- = FeODOH[18O]T[18O]H- + 4OH-
Fe(OH)4- + OD- + OD- + OH- + OH- = FeODODOHOH- + 4OH-
Fe(OH)4- + OD- + OD- + OH- + OT- = FeODODOHOT- + 4OH-
Fe(OH)4- + OD- + OD- + OH- + [18O]H- = FeODODOH[18O]H- + 4OH-
Fe(OH)4- + OD- + OD- + OH- + [18O]T- = FeODODOH[18O]T- + 4OH-
Fe(OH)4- + OD- + OD- + OT- + OH- = FeODODOTOH- + 4OH-
Fe(OH)4- + OD- + OD- + OT- + [18O]H- = FeODODOT[18O]H- + 4OH-
Fe(OH)4- + OD- + OD- + [18O]H- + OH- = FeODOD[18O]HOH- + 4OH-
Fe(OH)4- + OD- + OD- + [18O]H- + OT- = FeODOD[18O]HOT- + 4OH-
Fe(OH)4- + OD- + OD- + [18O]H- + [18O]H- = FeODOD[18O]H[18O]H- + 4OH-
Fe(OH)4- + OD- + OD- + [18O]T- + OH- = FeODOD[18O]TOH- + 4OH-
Fe(OH)4- + OD- + OT- + OH- + OH- = FeODOTOHOH- + 4OH-
Fe(OH)4- + OD- + OT- + OH- + OD- = FeODOTOHOD- + 4OH-
Fe(OH)4- + OD- + OT- + OH- + [18O]H- = FeODOTOH[18O]H- + 4OH-
Fe(OH)4- + OD- + OT- + OH- + [18O]D- = FeODOTOH[18O]D- + 4OH-
Fe(OH)4- + OD- + OT- + OD- + OH- = FeODOTODOH- + 4OH-
Fe(OH)4- + OD- + OT- + OD- + [18O]H- = FeODOTOD[18O]H- + 4OH-
Fe(OH)4- + OD- + OT- + [18O]H- + OH- = FeODOT[18O]HOH- + 4OH-
Fe(OH)4- + OD- + OT- + [18O]H- + OD- = FeODOT[18O]HOD- + 4OH-
Fe(OH)4- + OD- + OT- + [18O]H- + [18O]H- = FeODOT[18O]H[18O]H- + 4OH-
Fe(OH)4- + OD- + OT- + [18O]D- + OH- = FeODOT[18O]DOH- + 4OH-
Fe(OH)4- + OD- + [18O]H- + OH- + OH- = FeOD[18O]HOHOH- + 4OH-
Fe(OH)4- + OD- + [18O]H- + OH- + OD- = FeOD[18O]HOHOD- + 4OH-
Fe(OH)4- + OD- + [18O]H- + OH- + OT- = FeOD[18O]HOHOT- + 4OH-
Fe(OH)4- + OD- + [18O]H- + OH- + [18O]H- = FeOD[18O]HOH[18O]H- + 4OH-
Fe(OH)4- + OD- + [18O]H- + OH- + [18O]D- = FeOD[18O]HOH[18O]D- + 4OH-
Fe(OH)4- + OD- + [18O]H- + OH- + [18O]T- = FeOD[18O]HOH[18O]T- + 4OH-
Fe(OH)4- + OD- + [18O]H- + OD- + OH- = FeOD[18O]HODOH- + 4OH-
Fe(OH)4- + OD- + [18O]H- + OD- + OT- = FeOD[18O]HODOT- + 4OH-
Fe(OH)4- + OD- + [18O]H- + OD- + [18O]H- = FeOD[18O]HOD[18O]H- + 4OH-
Fe(OH)4- + OD- + [18O]H- + OT- + OH- = FeOD[18O]HOTOH- + 4OH-
Fe(OH)4- + OD- + [18O]H- + OT- + OD- = FeOD[18O]HOTOD- + 4OH-
Fe(OH)4- + OD- + [18O]H- + OT- + [18O]H- = FeOD[18O]HOT[18O]H- + 4OH-
Fe(OH)4- + OD- + [18O]H- + [18O]H- + OH- = FeOD[18O]H[18O]HOH- + 4OH-
Fe(OH)4- + OD- + [18O]H- + [18O]H- + OD- = FeOD[18O]H[18O]HOD- + 4OH-
Fe(OH)4- + OD- + [18O]H- + [18O]H- + OT- = FeOD[18O]H[18O]HOT- + 4OH-
Fe(OH)4- + OD- + [18O]H- + [18O]D- + OH- = FeOD[18O]H[18O]DOH- + 4OH-
Fe(OH)4- + OD- + [18O]H- + [18O]T- + OH- = FeOD[18O]H[18O]TOH- + 4OH-
Fe(OH)4- + OD- + [18O]D- + OH- + OH- = FeOD[18O]DOHOH- + 4OH-
Fe(OH)4- + OD- + [18O]D- + OH- + OT- = FeOD[18O]DOHOT- + 4OH-
Fe(OH)4- + OD- + [18O]D- + OH- + [18O]H- = FeOD[18O]DOH[18O]H- + 4OH-
Fe(OH)4- + OD- + [18O]D- + OT- + OH- = FeOD[18O]DOTOH- + 4OH-
Fe(OH)4- + OD- + [18O]D- + [18O]H- + OH- = FeOD[18O]D[18O]HOH- + 4OH-
Fe(OH)4- + OD- + [18O]T- + OH- + OH- = FeOD[18O]TOHOH- + 4OH-
Fe(OH)4- + OD- + [18O]T- + OH- + OD- = FeOD[18O]TOHOD- + 4OH-
Fe(OH)4- + OD- + [18O]T- + OH- + [18O]H- = FeOD[18O]TOH[18O]H- + 4OH-
Fe(OH)4- + OD- + [18O]T- + OD- + OH- = FeOD[18O]TODOH- + 4OH-
Fe(OH)4- + OD- + [18O]T- + [18O]H- + OH- = FeOD[18O]T[18O]HOH- + 4OH-
Fe(OH)4- + OT- + OH- + OH- + OH- = FeOTOHOHOH- + 4OH-
Fe(OH)4- + OT- + OH- + OH- + OD- = FeOTOHOHOD- + 4OH-
Fe(OH)4- + OT- + OH- + OH- + [18O]H- = FeOTOHOH[18O]H- + 4OH-
Fe(OH)4- + OT- + OH- + OH- + [18O]D- = FeOTOHOH[18O]D- + 4OH-
Fe(OH)4- + OT- + OH- + OD- + OH- = FeOTOHODOH- + 4OH-
Fe(OH)4- + OT- + OH- + OD- + OD- = FeOTOHODOD- + 4OH-
Fe(OH)4- + OT- + OH- + OD- + [18O]H- = FeOTOHOD[18O]H- + 4OH-
Fe(OH)4- + OT- + OH- + OD- + [18O]D- = FeOTOHOD[18O]D- + 4OH-
Fe(OH)4- + OT- + OH- + [18O]H- + OH- = FeOTOH[18O]HOH- + 4OH-
Fe(OH)4- + OT- + OH- + [18O]H- + OD- = FeOTOH[18O]HOD- + 4OH-
Fe(OH)4- + OT- + OH- + [18O]H- + [18O]H- = FeOTOH[18O]H[18O]H- + 4OH-
Fe(OH)4- + OT- + OH- + [18O]H- + [18O]D- = FeOTOH[18O]H[18O]D- + 4OH-
Fe(OH)4- + OT- + OH- + [18O]D- + OH- = FeOTOH[18O]DOH- + 4OH-
Fe(OH)4- + OT- + OH- + [18O]D- + OD- = FeOTOH[18O]DOD- + 4OH-
Fe(OH)4- + OT- + OH- + [18O]D- + [18O]H- = FeOTOH[18O]D[18O]H- + 4OH-
Fe(OH)4- + OT- + OD- + OH- + OH- = FeOTODOHOH- + 4OH-
Fe(OH)4- + OT- + OD- + OH- + OD- = FeOTODOHOD- + 4OH-
Fe(OH)4- + OT- + OD- + OH- + [18O]H- = FeOTODOH[18O]H- + 4OH-
Fe(OH)4- + OT- + OD- + OH- + [18O]D- = FeOTODOH[18O]D- + 4OH-
Fe(OH)4- + OT- + OD- + OD- + OH- = FeOTODODOH- + 4OH-
Fe(OH)4- + OT- + OD- + OD- + [18O]H- = FeOTODOD[18O]H- + 4OH-
Fe(OH)4- + OT- + OD- + [18O]H- + OH- = FeOTOD[18O]HOH- + 4OH-
Fe(OH)4- + OT- + OD- + [18O]H- + OD- = FeOTOD[18O]HOD- + 4OH-
Fe(OH)4- + OT- + OD- + [18O]H- + [18O]H- = FeOTOD[18O]H[18O]H- + 4OH-
Fe(OH)4- + OT- + OD- + [18O]D- + OH- = FeOTOD[18O]DOH- + 4OH-
Fe(OH)4- + OT- + [18O]H- + OH- + OH- = FeOT[18O]HOHOH- + 4OH-
Fe(OH)4- + OT- + [18O]H- + OH- + OD- = FeOT[18O]HOHOD- + 4OH-
Fe(OH)4- + OT- + [18O]H- + OH- + [18O]H- = FeOT[18O]HOH[18O]H- + 4OH-
Fe(OH)4- + OT- + [18O]H- + OH- + [18O]D- = FeOT[18O]HOH[18O]D- + 4OH-
Fe(OH)4- + OT- + [18O]H- + OD- + OH- = FeOT[18O]HODOH- + 4OH-
Fe(OH)4- + OT- + [18O]H- + OD- + OD- = FeOT[18O]HODOD- + 4OH-
Fe(OH)4- + OT- + [18O]H- + OD- + [18O]H- = FeOT[18O]HOD[18O]H- + 4OH-
Fe(OH)4- + OT- + [18O]H- + [18O]H- + OH- = FeOT[18O]H[18O]HOH- + 4OH-
Fe(OH)4- + OT- + [18O]H- + [18O]H- + OD- = FeOT[18O]H[18O]HOD- + 4OH-
Fe(OH)4- + OT- + [18O]H- + [18O]D- + OH- = FeOT[18O]H[18O]DOH- + 4OH-
Fe(OH)4- + OT- + [18O]D- + OH- + OH- = FeOT[18O]DOHOH- + 4OH-
Fe(OH)4- + OT- + [18O]D- + OH- + OD- = FeOT[18O]DOHOD- + 4OH-
Fe(OH)4- + OT- + [18O]D- + OH- + [18O]H- = FeOT[18O]DOH[18O]H- + 4OH-
Fe(OH)4- + OT- + [18O]D- + OD- + OH- = FeOT[18O]DODOH- + 4OH-
Fe(OH)4- + OT- + [18O]D- + [18O]H- + OH- = FeOT[18O]D[18O]HOH- + 4OH-
Fe(OH)4- + [18O]H- + OH- + OH- + OH- = Fe[18O]HOHOHOH- + 4OH-
Fe(OH)4- + [18O]H- + OH- + OH- + OD- = Fe[18O]HOHOHOD- + 4OH-
Fe(OH)4- + [18O]H- + OH- + OH- + OT- = Fe[18O]HOHOHOT- + 4OH-
Fe(OH)4- + [18O]H- + OH- + OH- + [18O]H- = Fe[18O]HOHOH[18O]H- + 4OH-
Fe(OH)4- + [18O]H- + OH- + OH- + [18O]D- = Fe[18O]HOHOH[18O]D- + 4OH-
Fe(OH)4- + [18O]H- + OH- + OH- + [18O]T- = Fe[18O]HOHOH[18O]T- + 4OH-
Fe(OH)4- + [18O]H- + OH- + OD- + OH- = Fe[18O]HOHODOH- + 4OH-
Fe(OH)4- + [18O]H- + OH- + OD- + OD- = Fe[18O]HOHODOD- + 4OH-
Fe(OH)4- + [18O]H- + OH- + OD- + OT- = Fe[18O]HOHODOT- + 4OH-
Fe(OH)4- + [18O]H- + OH- + OD- + [18O]H- = Fe[18O]HOHOD[18O]H- + 4OH-
Fe(OH)4- + [18O]H- + OH- + OD- + [18O]D- = Fe[18O]HOHOD[18O]D- + 4OH-
Fe(OH)4- + [18O]H- + OH- + OD- + [18O]T- = Fe[18O]HOHOD[18O]T- + 4OH-
Fe(OH)4- + [18O]H- + OH- + OT- + OH- = Fe[18O]HOHOTOH- + 4OH-
Fe(OH)4- + [18O]H- + OH- + OT- + OD- = Fe[18O]HOHOTOD- + 4OH-
Fe(OH)4- + [18O]H- + OH- + OT- + [18O]H- = Fe[18O]HOHOT[18O]H- + 4OH-
Fe(OH)4- + [18O]H- + OH- + OT- + [18O]D- = Fe[18O]HOHOT[18O]D- + 4OH-
Fe(OH)4- + [18O]H- + OH- + [18O]H- + OH- = Fe[18O]HOH[18O]HOH- + 4OH-
Fe(OH)4- + [18O]H- + OH- + [18O]H- + OD- = Fe[18O]HOH[18O]HOD- + 4OH-
Fe(OH)4- + [18O]H- + OH- + [18O]H- + OT- = Fe[18O]HOH[18O]HOT- + 4OH-
Fe(OH)4- + [18O]H- + OH- + [18O]D- + OH- = Fe[18O]HOH[18O]DOH- + 4OH-
Fe(OH)4- + [18O]H- + OH- + [18O]D- + OD- = Fe[18O]HOH[18O]DOD- + 4OH-
Fe(OH)4- + [18O]H- + OH- + [18O]D- + OT- = Fe[18O]HOH[18O]DOT- + 4OH-
Fe(OH)4- + [18O]H- + OH- + [18O]T- + OH- = Fe[18O]HOH[18O]TOH- + 4OH-
Fe(OH)4- + [18O]H- + OH- + [18O]T- + OD- = Fe[18O]HOH[18O]TOD- + 4OH-
Fe(OH)4- + [18O]H- + OD- + OH- + OH- = Fe[18O]HODOHOH- + 4OH-
Fe(OH)4- + [18O]H- + OD- + OH- + OD- = Fe[18O]HODOHOD- + 4OH-
Fe(OH)4- + [18O]H- + OD- + OH- + OT- = Fe[18O]HODOHOT- + 4OH-
Fe(OH)4- + [18O]H- + OD- + OH- + [18O]H- = Fe[18O]HODOH[18O]H- + 4OH-
Fe(OH)4- + [18O]H- + OD- + OH- + [18O]D- = Fe[18O]HODOH[18O]D- + 4OH-
Fe(OH)4- + [18O]H- + OD- + OH- + [18O]T- = Fe[18O]HODOH[18O]T- + 4OH-
Fe(OH)4- + [18O]H- + OD- + OD- + OH- = Fe[18O]HODODOH- + 4OH-
Fe(OH)4- + [18O]H- + OD- + OD- + OT- = Fe[18O]HODODOT- + 4OH-
Fe(OH)4- + [18O]H- + OD- + OD- + [18O]H- = Fe[18O]HODOD[18O]H- + 4OH-
Fe(OH)4- + [18O]H- + OD- + OT- + OH- = Fe[18O]HODOTOH- + 4OH-
Fe(OH)4- + [18O]H- + OD- + OT- + OD- = Fe[18O]HODOTOD- + 4OH-
Fe(OH)4- + [18O]H- + OD- + OT- + [18O]H- = Fe[18O]HODOT[18O]H- + 4OH-
Fe(OH)4- + [18O]H- + OD- + [18O]H- + OH- = Fe[18O]HOD[18O]HOH- + 4OH-
Fe(OH)4- + [18O]H- + OD- + [18O]H- + OD- = Fe[18O]HOD[18O]HOD- + 4OH-
Fe(OH)4- + [18O]H- + OD- + [18O]H- + OT- = Fe[18O]HOD[18O]HOT- + 4OH-
Fe(OH)4- + [18O]H- + OD- + [18O]D- + OH- = Fe[18O]HOD[18O]DOH- + 4OH-
Fe(OH)4- + [18O]H- + OD- + [18O]T- + OH- = Fe[18O]HOD[18O]TOH- + 4OH-
Fe(OH)4- + [18O]H- + OT- + OH- + OH- = Fe[18O]HOTOHOH- + 4OH-
Fe(OH)4- + [18O]H- + OT- + OH- + OD- = Fe[18O]HOTOHOD- + 4OH-
Fe(OH)4- + [18O]H- + OT- + OH- + [18O]H- = Fe[18O]HOTOH[18O]H- + 4OH-
Fe(OH)4- + [18O]H- + OT- + OH- + [18O]D- = Fe[18O]HOTOH[18O]D- + 4OH-
Fe(OH)4- + [18O]H- + OT- + OD- + OH- = Fe[18O]HOTODOH- + 4OH-
Fe(OH)4- + [18O]H- + OT- + OD- + OD- = Fe[18O]HOTODOD- + 4OH-
Fe(OH)4- + [18O]H- + OT- + OD- + [18O]H- = Fe[18O]HOTOD[18O]H- + 4OH-
Fe(OH)4- + [18O]H- + OT- + [18O]H- + OH- = Fe[18O]HOT[18O]HOH- + 4OH-
Fe(OH)4- + [18O]H- + OT- + [18O]H- + OD- = Fe[18O]HOT[18O]HOD- + 4OH-
Fe(OH)4- + [18O]H- + OT- + [18O]D- + OH- = Fe[18O]HOT[18O]DOH- + 4OH-
Fe(OH)4- + [18O]H- + [18O]H- + OH- + OH- = Fe[18O]H[18O]HOHOH- + 4OH-
Fe(OH)4- + [18O]H- + [18O]H- + OH- + OD- = Fe[18O]H[18O]HOHOD- + 4OH-
Fe(OH)4- + [18O]H- + [18O]H- + OH- + OT- = Fe[18O]H[18O]HOHOT- + 4OH-
Fe(OH)4- + [18O]H- + [18O]H- + OD- + OH- = Fe[18O]H[18O]HODOH- + 4OH-
Fe(OH)4- + [18O]H- + [18O]H- + OD- + OD- = Fe[18O]H[18O]HODOD- + 4OH-
Fe(OH)4- + [18O]H- + [18O]H- + OD- + OT- = Fe[18O]H[18O]HODOT- + 4OH-
Fe(OH)4- + [18O]H- + [18O]H- + OT- + OH- = Fe[18O]H[18O]HOTOH- + 4OH-
Fe(OH)4- + [18O]H- + [18O]H- + OT- + OD- = Fe[18O]H[18O]HOTOD- + 4OH-
Fe(OH)4- + [18O]H- + [18O]D- + OH- + OH- = Fe[18O]H[18O]DOHOH- + 4OH-
Fe(OH)4- + [18O]H- + [18O]D- + OH- + OD- = Fe[18O]H[18O]DOHOD- + 4OH-
Fe(OH)4- + [18O]H- + [18O]D- + OH- + OT- = Fe[18O]H[18O]DOHOT- + 4OH-
Fe(OH)4- + [18O]H- + [18O]D- + OD- + OH- = Fe[18O]H[18O]DODOH- + 4OH-
Fe(OH)4- + [18O]H- + [18O]D- + OT- + OH- = Fe[18O]H[18O]DOTOH- + 4OH-
Fe(OH)4- + [18O]H- + [18O]T- + OH- + OH- = Fe[18O]H[18O]TOHOH- + 4OH-
Fe(OH)4- + [18O]H- + [18O]T- + OH- + OD- = Fe[18O]H[18O]TOHOD- + 4OH-
Fe(OH)4- + [18O]H- + [18O]T- + OD- + OH- = Fe[18O]H[18O]TODOH- + 4OH-
Fe(OH)4- + [18O]D- + OH- + OH- + OH- = Fe[18O]DOHOHOH- + 4OH-
Fe(OH)4- + [18O]D- + OH- + OH- + OD- = Fe[18O]DOHOHOD- + 4OH-
Fe(OH)4- + [18O]D- + OH- + OH- + OT- = Fe[18O]DOHOHOT- + 4OH-
Fe(OH)4- + [18O]D- + OH- + OH- + [18O]H- = Fe[18O]DOHOH[18O]H- + 4OH-
Fe(OH)4- + [18O]D- + OH- + OH- + [18O]D- = Fe[18O]DOHOH[18O]D- + 4OH-
Fe(OH)4- + [18O]D- + OH- + OH- + [18O]T- = Fe[18O]DOHOH[18O]T- + 4OH-
Fe(OH)4- + [18O]D- + OH- + OD- + OH- = Fe[18O]DOHODOH- + 4OH-
Fe(OH)4- + [18O]D- + OH- + OD- + OT- = Fe[18O]DOHODOT- + 4OH-
Fe(OH)4- + [18O]D- + OH- + OD- + [18O]H- = Fe[18O]DOHOD[18O]H- + 4OH-
Fe(OH)4- + [18O]D- + OH- + OT- + OH- = Fe[18O]DOHOTOH- + 4OH-
Fe(OH)4- + [18O]D- + OH- + OT- + OD- = Fe[18O]DOHOTOD- + 4OH-
Fe(OH)4- + [18O]D- + OH- + OT- + [18O]H- = Fe[18O]DOHOT[18O]H- + 4OH-
Fe(OH)4- + [18O]D- + OH- + [18O]H- + OH- = Fe[18O]DOH[18O]HOH- + 4OH-
Fe(OH)4- + [18O]D- + OH- + [18O]H- + OD- = Fe[18O]DOH[18O]HOD- + 4OH-
Fe(OH)4- + [18O]D- + OH- + [18O]H- + OT- = Fe[18O]DOH[18O]HOT- + 4OH-
Fe(OH)4- + [18O]D- + OH- + [18O]D- + OH- = Fe[18O]DOH[18O]DOH- + 4OH-
Fe(OH)4- + [18O]D- + OH- + [18O]T- + OH- = Fe[18O]DOH[18O]TOH- + 4OH-
Fe(OH)4- + [18O]D- + OD- + OH- + OH- = Fe[18O]DODOHOH- + 4OH-
Fe(OH)4- + [18O]D- + OD- + OH- + OT- = Fe[18O]DODOHOT- + 4OH-
Fe(OH)4- + [18O]D- + OD- + OH- + [18O]H- = Fe[18O]DODOH[18O]H- + 4OH-
Fe(OH)4- + [18O]D- + OD- + OT- + OH- = Fe[18O]DODOTOH- + 4OH-
Fe(OH)4- + [18O]D- + OD- + [18O]H- + OH- = Fe[18O]DOD[18O]HOH- + 4OH-
Fe(OH)4- + [18O]D- + OT- + OH- + OH- = Fe[18O]DOTOHOH- + 4OH-
Fe(OH)4- + [18O]D- + OT- + OH- + OD- = Fe[18O]DOTOHOD- + 4OH-
Fe(OH)4- + [18O]D- + OT- + OH- + [18O]H- = Fe[18O]DOTOH[18O]H- + 4OH-
Fe(OH)4- + [18O]D- + OT- + OD- + OH- = Fe[18O]DOTODOH- + 4OH-
Fe(OH)4- + [18O]D- + OT- + [18O]H- + OH- = Fe[18O]DOT[18O]HOH- + 4OH-
Fe(OH)4- + [18O]D- + [18O]H- + OH- + OH- = Fe[18O]D[18O]HOHOH- + 4OH-
Fe(OH)4- + [18O]D- + [18O]H- + OH- + OD- = Fe[18O]D[18O]HOHOD- + 4OH-
Fe(OH)4- + [18O]D- + [18O]H- + OH- + OT- = Fe[18O]D[18O]HOHOT- + 4OH-
Fe(OH)4- + [18O]D- + [18O]H- + OD- + OH- = Fe[18O]D[18O]HODOH- + 4OH-
Fe(OH)4- + [18O]D- + [18O]H- + OT- + OH- = Fe[18O]D[18O]HOTOH- + 4OH-
Fe(OH)4- + [18O]D- + [18O]D- + OH- + OH- = Fe[18O]D[18O]DOHOH- + 4OH-
Fe(OH)4- + [18O]D- + [18O]T- + OH- + OH- = Fe[18O]D[18O]TOHOH- + 4OH-
Fe(OH)4- + [18O]T- + OH- + OH- + OH- = Fe[18O]TOHOHOH- + 4OH-
Fe(OH)4- + [18O]T- + OH- + OH- + OD- = Fe[18O]TOHOHOD- + 4OH-
Fe(OH)4- + [18O]T- + OH- + OH- + [18O]H- = Fe[18O]TOHOH[18O]H- + 4OH-
Fe(OH)4- + [18O]T- + OH- + OH- + [18O]D- = Fe[18O]TOHOH[18O]D- + 4OH-
Fe(OH)4- + [18O]T- + OH- + OD- + OH- = Fe[18O]TOHODOH- + 4OH-
Fe(OH)4- + [18O]T- + OH- + OD- + OD- = Fe[18O]TOHODOD- + 4OH-
Fe(OH)4- + [18O]T- + OH- + OD- + [18O]H- = Fe[18O]TOHOD[18O]H- + 4OH-
Fe(OH)4- + [18O]T- + OH- + [18O]H- + OH- = Fe[18O]TOH[18O]HOH- + 4OH-
Fe(OH)4- + [18O]T- + OH- + [18O]H- + OD- = Fe[18O]TOH[18O]HOD- + 4OH-
Fe(OH)4- + [18O]T- + OH- + [18O]D- + OH- = Fe[18O]TOH[18O]DOH- + 4OH-
Fe(OH)4- + [18O]T- + OD- + OH- + OH- = Fe[18O]TODOHOH- + 4OH-
Fe(OH)4- + [18O]T- + OD- + OH- + OD- = Fe[18O]TODOHOD- + 4OH-
Fe(OH)4- + [18O]T- + OD- + OH- + [18O]H- = Fe[18O]TODOH[18O]H- + 4OH-
Fe(OH)4- + [18O]T- + OD- + OD- + OH- = Fe[18O]TODODOH- + 4OH-
Fe(OH)4- + [18O]T- + OD- + [18O]H- + OH- = Fe[18O]TOD[18O]HOH- + 4OH-
Fe(OH)4- + [18O]T- + [18O]H- + OH- + OH- = Fe[18O]T[18O]HOHOH- + 4OH-
Fe(OH)4- + [18O]T- + [18O]H- + OH- + OD- = Fe[18O]T[18O]HOHOD- + 4OH-
Fe(OH)4- + [18O]T- + [18O]H- + OD- + OH- = Fe[18O]T[18O]HODOH- + 4OH-
Fe(OH)4- + [18O]T- + [18O]D- + OH- + OH- = Fe[18O]T[18O]DOHOH- + 4OH-
#
# Added Fe2(OH)2+4 reactions 16Dec09
# Revised 17Dec09, limited the number of species
#
Fe2(OH)2+4 + OH- + OD- = Fe2OHOD+4 + 2OH-
Fe2(OH)2+4 + OH- + OT- = Fe2OHOT+4 + 2OH-
Fe2(OH)2+4 + OH- + [18O]H- = Fe2OH[18O]H+4 + 2OH-
Fe2(OH)2+4 + OH- + [18O]D- = Fe2OH[18O]D+4 + 2OH-
Fe2(OH)2+4 + OH- + [18O]T- = Fe2OH[18O]T+4 + 2OH-
Fe2(OH)2+4 + OD- + OH- = Fe2ODOH+4 + 2OH-
Fe2(OH)2+4 + OD- + OD- = Fe2ODOD+4 + 2OH-
Fe2(OH)2+4 + OD- + OT- = Fe2ODOT+4 + 2OH-
Fe2(OH)2+4 + OD- + [18O]H- = Fe2OD[18O]H+4 + 2OH-
Fe2(OH)2+4 + OD- + [18O]D- = Fe2OD[18O]D+4 + 2OH-
Fe2(OH)2+4 + OD- + [18O]T- = Fe2OD[18O]T+4 + 2OH-
Fe2(OH)2+4 + OT- + OH- = Fe2OTOH+4 + 2OH-
Fe2(OH)2+4 + OT- + OD- = Fe2OTOD+4 + 2OH-
Fe2(OH)2+4 + OT- + [18O]H- = Fe2OT[18O]H+4 + 2OH-
Fe2(OH)2+4 + OT- + [18O]D- = Fe2OT[18O]D+4 + 2OH-
Fe2(OH)2+4 + [18O]H- + OH- = Fe2[18O]HOH+4 + 2OH-
Fe2(OH)2+4 + [18O]H- + OD- = Fe2[18O]HOD+4 + 2OH-
Fe2(OH)2+4 + [18O]H- + OT- = Fe2[18O]HOT+4 + 2OH-
Fe2(OH)2+4 + [18O]H- + [18O]H- = Fe2[18O]H[18O]H+4 + 2OH-
Fe2(OH)2+4 + [18O]H- + [18O]D- = Fe2[18O]H[18O]D+4 + 2OH-
Fe2(OH)2+4 + [18O]H- + [18O]T- = Fe2[18O]H[18O]T+4 + 2OH-
Fe2(OH)2+4 + [18O]D- + OH- = Fe2[18O]DOH+4 + 2OH-
Fe2(OH)2+4 + [18O]D- + OD- = Fe2[18O]DOD+4 + 2OH-
Fe2(OH)2+4 + [18O]D- + OT- = Fe2[18O]DOT+4 + 2OH-
Fe2(OH)2+4 + [18O]D- + [18O]H- = Fe2[18O]D[18O]H+4 + 2OH-
Fe2(OH)2+4 + [18O]D- + [18O]D- = Fe2[18O]D[18O]D+4 + 2OH-
Fe2(OH)2+4 + [18O]D- + [18O]T- = Fe2[18O]D[18O]T+4 + 2OH-
Fe2(OH)2+4 + [18O]T- + OH- = Fe2[18O]TOH+4 + 2OH-
Fe2(OH)2+4 + [18O]T- + OD- = Fe2[18O]TOD+4 + 2OH-
Fe2(OH)2+4 + [18O]T- + [18O]H- = Fe2[18O]T[18O]H+4 + 2OH-
Fe2(OH)2+4 + [18O]T- + [18O]D- = Fe2[18O]T[18O]D+4 + 2OH-
#
# Added Fe3(OH)4+5 reactions 16Dec09
# Revised 17Dec09, limited the number of species
#
Fe3(OH)4+5 + OH- + OH- + OH- + OD- = Fe3OHOHOHOD+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + OH- + OT- = Fe3OHOHOHOT+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + OH- + [18O]H- = Fe3OHOHOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + OH- + [18O]D- = Fe3OHOHOH[18O]D+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + OH- + [18O]T- = Fe3OHOHOH[18O]T+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + OD- + OH- = Fe3OHOHODOH+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + OD- + OD- = Fe3OHOHODOD+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + OD- + OT- = Fe3OHOHODOT+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + OD- + [18O]H- = Fe3OHOHOD[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + OD- + [18O]D- = Fe3OHOHOD[18O]D+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + OD- + [18O]T- = Fe3OHOHOD[18O]T+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + OT- + OH- = Fe3OHOHOTOH+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + OT- + OD- = Fe3OHOHOTOD+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + OT- + [18O]H- = Fe3OHOHOT[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + OT- + [18O]D- = Fe3OHOHOT[18O]D+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + [18O]H- + OH- = Fe3OHOH[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + [18O]H- + OD- = Fe3OHOH[18O]HOD+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + [18O]H- + OT- = Fe3OHOH[18O]HOT+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + [18O]H- + [18O]H- = Fe3OHOH[18O]H[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + [18O]H- + [18O]D- = Fe3OHOH[18O]H[18O]D+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + [18O]H- + [18O]T- = Fe3OHOH[18O]H[18O]T+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + [18O]D- + OH- = Fe3OHOH[18O]DOH+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + [18O]D- + OD- = Fe3OHOH[18O]DOD+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + [18O]D- + OT- = Fe3OHOH[18O]DOT+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + [18O]D- + [18O]H- = Fe3OHOH[18O]D[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + [18O]D- + [18O]D- = Fe3OHOH[18O]D[18O]D+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + [18O]D- + [18O]T- = Fe3OHOH[18O]D[18O]T+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + [18O]T- + OH- = Fe3OHOH[18O]TOH+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + [18O]T- + OD- = Fe3OHOH[18O]TOD+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + [18O]T- + [18O]H- = Fe3OHOH[18O]T[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + OH- + [18O]T- + [18O]D- = Fe3OHOH[18O]T[18O]D+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + OH- + OH- = Fe3OHODOHOH+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + OH- + OD- = Fe3OHODOHOD+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + OH- + OT- = Fe3OHODOHOT+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + OH- + [18O]H- = Fe3OHODOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + OH- + [18O]D- = Fe3OHODOH[18O]D+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + OH- + [18O]T- = Fe3OHODOH[18O]T+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + OD- + OH- = Fe3OHODODOH+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + OD- + OT- = Fe3OHODODOT+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + OD- + [18O]H- = Fe3OHODOD[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + OD- + [18O]T- = Fe3OHODOD[18O]T+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + OT- + OH- = Fe3OHODOTOH+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + OT- + OD- = Fe3OHODOTOD+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + OT- + [18O]H- = Fe3OHODOT[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + OT- + [18O]D- = Fe3OHODOT[18O]D+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + [18O]H- + OH- = Fe3OHOD[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + [18O]H- + OD- = Fe3OHOD[18O]HOD+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + [18O]H- + OT- = Fe3OHOD[18O]HOT+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + [18O]H- + [18O]H- = Fe3OHOD[18O]H[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + [18O]H- + [18O]D- = Fe3OHOD[18O]H[18O]D+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + [18O]H- + [18O]T- = Fe3OHOD[18O]H[18O]T+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + [18O]D- + OH- = Fe3OHOD[18O]DOH+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + [18O]D- + OT- = Fe3OHOD[18O]DOT+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + [18O]D- + [18O]H- = Fe3OHOD[18O]D[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + [18O]T- + OH- = Fe3OHOD[18O]TOH+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + [18O]T- + OD- = Fe3OHOD[18O]TOD+5 + 4OH-
Fe3(OH)4+5 + OH- + OD- + [18O]T- + [18O]H- = Fe3OHOD[18O]T[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + OT- + OH- + OH- = Fe3OHOTOHOH+5 + 4OH-
Fe3(OH)4+5 + OH- + OT- + OH- + OD- = Fe3OHOTOHOD+5 + 4OH-
Fe3(OH)4+5 + OH- + OT- + OH- + [18O]H- = Fe3OHOTOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + OT- + OH- + [18O]D- = Fe3OHOTOH[18O]D+5 + 4OH-
Fe3(OH)4+5 + OH- + OT- + OD- + OH- = Fe3OHOTODOH+5 + 4OH-
Fe3(OH)4+5 + OH- + OT- + OD- + OD- = Fe3OHOTODOD+5 + 4OH-
Fe3(OH)4+5 + OH- + OT- + OD- + [18O]H- = Fe3OHOTOD[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + OT- + OD- + [18O]D- = Fe3OHOTOD[18O]D+5 + 4OH-
Fe3(OH)4+5 + OH- + OT- + [18O]H- + OH- = Fe3OHOT[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + OH- + OT- + [18O]H- + OD- = Fe3OHOT[18O]HOD+5 + 4OH-
Fe3(OH)4+5 + OH- + OT- + [18O]H- + [18O]H- = Fe3OHOT[18O]H[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + OT- + [18O]H- + [18O]D- = Fe3OHOT[18O]H[18O]D+5 + 4OH-
Fe3(OH)4+5 + OH- + OT- + [18O]D- + OH- = Fe3OHOT[18O]DOH+5 + 4OH-
Fe3(OH)4+5 + OH- + OT- + [18O]D- + OD- = Fe3OHOT[18O]DOD+5 + 4OH-
Fe3(OH)4+5 + OH- + OT- + [18O]D- + [18O]H- = Fe3OHOT[18O]D[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + OH- + OH- = Fe3OH[18O]HOHOH+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + OH- + OD- = Fe3OH[18O]HOHOD+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + OH- + OT- = Fe3OH[18O]HOHOT+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + OH- + [18O]H- = Fe3OH[18O]HOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + OH- + [18O]D- = Fe3OH[18O]HOH[18O]D+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + OH- + [18O]T- = Fe3OH[18O]HOH[18O]T+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + OD- + OH- = Fe3OH[18O]HODOH+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + OD- + OD- = Fe3OH[18O]HODOD+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + OD- + OT- = Fe3OH[18O]HODOT+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + OD- + [18O]H- = Fe3OH[18O]HOD[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + OD- + [18O]D- = Fe3OH[18O]HOD[18O]D+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + OD- + [18O]T- = Fe3OH[18O]HOD[18O]T+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + OT- + OH- = Fe3OH[18O]HOTOH+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + OT- + OD- = Fe3OH[18O]HOTOD+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + OT- + [18O]H- = Fe3OH[18O]HOT[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + OT- + [18O]D- = Fe3OH[18O]HOT[18O]D+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + [18O]H- + OH- = Fe3OH[18O]H[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + [18O]H- + OD- = Fe3OH[18O]H[18O]HOD+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + [18O]H- + OT- = Fe3OH[18O]H[18O]HOT+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + [18O]D- + OH- = Fe3OH[18O]H[18O]DOH+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + [18O]D- + OD- = Fe3OH[18O]H[18O]DOD+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + [18O]D- + OT- = Fe3OH[18O]H[18O]DOT+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + [18O]T- + OH- = Fe3OH[18O]H[18O]TOH+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]H- + [18O]T- + OD- = Fe3OH[18O]H[18O]TOD+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]D- + OH- + OH- = Fe3OH[18O]DOHOH+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]D- + OH- + OD- = Fe3OH[18O]DOHOD+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]D- + OH- + OT- = Fe3OH[18O]DOHOT+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]D- + OH- + [18O]H- = Fe3OH[18O]DOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]D- + OH- + [18O]D- = Fe3OH[18O]DOH[18O]D+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]D- + OH- + [18O]T- = Fe3OH[18O]DOH[18O]T+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]D- + OD- + OH- = Fe3OH[18O]DODOH+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]D- + OD- + OT- = Fe3OH[18O]DODOT+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]D- + OD- + [18O]H- = Fe3OH[18O]DOD[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]D- + OT- + OH- = Fe3OH[18O]DOTOH+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]D- + OT- + OD- = Fe3OH[18O]DOTOD+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]D- + OT- + [18O]H- = Fe3OH[18O]DOT[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]D- + [18O]H- + OH- = Fe3OH[18O]D[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]D- + [18O]H- + OD- = Fe3OH[18O]D[18O]HOD+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]D- + [18O]H- + OT- = Fe3OH[18O]D[18O]HOT+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]D- + [18O]D- + OH- = Fe3OH[18O]D[18O]DOH+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]D- + [18O]T- + OH- = Fe3OH[18O]D[18O]TOH+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]T- + OH- + OH- = Fe3OH[18O]TOHOH+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]T- + OH- + OD- = Fe3OH[18O]TOHOD+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]T- + OH- + [18O]H- = Fe3OH[18O]TOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]T- + OH- + [18O]D- = Fe3OH[18O]TOH[18O]D+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]T- + OD- + OH- = Fe3OH[18O]TODOH+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]T- + OD- + OD- = Fe3OH[18O]TODOD+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]T- + OD- + [18O]H- = Fe3OH[18O]TOD[18O]H+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]T- + [18O]H- + OH- = Fe3OH[18O]T[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]T- + [18O]H- + OD- = Fe3OH[18O]T[18O]HOD+5 + 4OH-
Fe3(OH)4+5 + OH- + [18O]T- + [18O]D- + OH- = Fe3OH[18O]T[18O]DOH+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + OH- + OH- = Fe3ODOHOHOH+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + OH- + OD- = Fe3ODOHOHOD+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + OH- + OT- = Fe3ODOHOHOT+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + OH- + [18O]H- = Fe3ODOHOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + OH- + [18O]D- = Fe3ODOHOH[18O]D+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + OH- + [18O]T- = Fe3ODOHOH[18O]T+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + OD- + OH- = Fe3ODOHODOH+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + OD- + OT- = Fe3ODOHODOT+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + OD- + [18O]H- = Fe3ODOHOD[18O]H+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + OD- + [18O]T- = Fe3ODOHOD[18O]T+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + OT- + OH- = Fe3ODOHOTOH+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + OT- + OD- = Fe3ODOHOTOD+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + OT- + [18O]H- = Fe3ODOHOT[18O]H+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + OT- + [18O]D- = Fe3ODOHOT[18O]D+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + [18O]H- + OH- = Fe3ODOH[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + [18O]H- + OD- = Fe3ODOH[18O]HOD+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + [18O]H- + OT- = Fe3ODOH[18O]HOT+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + [18O]H- + [18O]H- = Fe3ODOH[18O]H[18O]H+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + [18O]H- + [18O]D- = Fe3ODOH[18O]H[18O]D+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + [18O]H- + [18O]T- = Fe3ODOH[18O]H[18O]T+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + [18O]D- + OH- = Fe3ODOH[18O]DOH+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + [18O]D- + OT- = Fe3ODOH[18O]DOT+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + [18O]D- + [18O]H- = Fe3ODOH[18O]D[18O]H+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + [18O]T- + OH- = Fe3ODOH[18O]TOH+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + [18O]T- + OD- = Fe3ODOH[18O]TOD+5 + 4OH-
Fe3(OH)4+5 + OD- + OH- + [18O]T- + [18O]H- = Fe3ODOH[18O]T[18O]H+5 + 4OH-
Fe3(OH)4+5 + OD- + OD- + OH- + OH- = Fe3ODODOHOH+5 + 4OH-
Fe3(OH)4+5 + OD- + OD- + OH- + OT- = Fe3ODODOHOT+5 + 4OH-
Fe3(OH)4+5 + OD- + OD- + OH- + [18O]H- = Fe3ODODOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + OD- + OD- + OH- + [18O]T- = Fe3ODODOH[18O]T+5 + 4OH-
Fe3(OH)4+5 + OD- + OD- + OT- + OH- = Fe3ODODOTOH+5 + 4OH-
Fe3(OH)4+5 + OD- + OD- + OT- + [18O]H- = Fe3ODODOT[18O]H+5 + 4OH-
Fe3(OH)4+5 + OD- + OD- + [18O]H- + OH- = Fe3ODOD[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + OD- + OD- + [18O]H- + OT- = Fe3ODOD[18O]HOT+5 + 4OH-
Fe3(OH)4+5 + OD- + OD- + [18O]H- + [18O]H- = Fe3ODOD[18O]H[18O]H+5 + 4OH-
Fe3(OH)4+5 + OD- + OD- + [18O]T- + OH- = Fe3ODOD[18O]TOH+5 + 4OH-
Fe3(OH)4+5 + OD- + OT- + OH- + OH- = Fe3ODOTOHOH+5 + 4OH-
Fe3(OH)4+5 + OD- + OT- + OH- + OD- = Fe3ODOTOHOD+5 + 4OH-
Fe3(OH)4+5 + OD- + OT- + OH- + [18O]H- = Fe3ODOTOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + OD- + OT- + OH- + [18O]D- = Fe3ODOTOH[18O]D+5 + 4OH-
Fe3(OH)4+5 + OD- + OT- + OD- + OH- = Fe3ODOTODOH+5 + 4OH-
Fe3(OH)4+5 + OD- + OT- + OD- + [18O]H- = Fe3ODOTOD[18O]H+5 + 4OH-
Fe3(OH)4+5 + OD- + OT- + [18O]H- + OH- = Fe3ODOT[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + OD- + OT- + [18O]H- + OD- = Fe3ODOT[18O]HOD+5 + 4OH-
Fe3(OH)4+5 + OD- + OT- + [18O]H- + [18O]H- = Fe3ODOT[18O]H[18O]H+5 + 4OH-
Fe3(OH)4+5 + OD- + OT- + [18O]D- + OH- = Fe3ODOT[18O]DOH+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]H- + OH- + OH- = Fe3OD[18O]HOHOH+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]H- + OH- + OD- = Fe3OD[18O]HOHOD+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]H- + OH- + OT- = Fe3OD[18O]HOHOT+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]H- + OH- + [18O]H- = Fe3OD[18O]HOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]H- + OH- + [18O]D- = Fe3OD[18O]HOH[18O]D+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]H- + OH- + [18O]T- = Fe3OD[18O]HOH[18O]T+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]H- + OD- + OH- = Fe3OD[18O]HODOH+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]H- + OD- + OT- = Fe3OD[18O]HODOT+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]H- + OD- + [18O]H- = Fe3OD[18O]HOD[18O]H+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]H- + OT- + OH- = Fe3OD[18O]HOTOH+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]H- + OT- + OD- = Fe3OD[18O]HOTOD+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]H- + OT- + [18O]H- = Fe3OD[18O]HOT[18O]H+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]H- + [18O]H- + OH- = Fe3OD[18O]H[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]H- + [18O]H- + OD- = Fe3OD[18O]H[18O]HOD+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]H- + [18O]H- + OT- = Fe3OD[18O]H[18O]HOT+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]H- + [18O]D- + OH- = Fe3OD[18O]H[18O]DOH+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]H- + [18O]T- + OH- = Fe3OD[18O]H[18O]TOH+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]D- + OH- + OH- = Fe3OD[18O]DOHOH+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]D- + OH- + OT- = Fe3OD[18O]DOHOT+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]D- + OH- + [18O]H- = Fe3OD[18O]DOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]D- + OT- + OH- = Fe3OD[18O]DOTOH+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]D- + [18O]H- + OH- = Fe3OD[18O]D[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]T- + OH- + OH- = Fe3OD[18O]TOHOH+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]T- + OH- + OD- = Fe3OD[18O]TOHOD+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]T- + OH- + [18O]H- = Fe3OD[18O]TOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]T- + OD- + OH- = Fe3OD[18O]TODOH+5 + 4OH-
Fe3(OH)4+5 + OD- + [18O]T- + [18O]H- + OH- = Fe3OD[18O]T[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + OT- + OH- + OH- + OH- = Fe3OTOHOHOH+5 + 4OH-
Fe3(OH)4+5 + OT- + OH- + OH- + OD- = Fe3OTOHOHOD+5 + 4OH-
Fe3(OH)4+5 + OT- + OH- + OH- + [18O]H- = Fe3OTOHOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + OT- + OH- + OH- + [18O]D- = Fe3OTOHOH[18O]D+5 + 4OH-
Fe3(OH)4+5 + OT- + OH- + OD- + OH- = Fe3OTOHODOH+5 + 4OH-
Fe3(OH)4+5 + OT- + OH- + OD- + OD- = Fe3OTOHODOD+5 + 4OH-
Fe3(OH)4+5 + OT- + OH- + OD- + [18O]H- = Fe3OTOHOD[18O]H+5 + 4OH-
Fe3(OH)4+5 + OT- + OH- + OD- + [18O]D- = Fe3OTOHOD[18O]D+5 + 4OH-
Fe3(OH)4+5 + OT- + OH- + [18O]H- + OH- = Fe3OTOH[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + OT- + OH- + [18O]H- + OD- = Fe3OTOH[18O]HOD+5 + 4OH-
Fe3(OH)4+5 + OT- + OH- + [18O]H- + [18O]H- = Fe3OTOH[18O]H[18O]H+5 + 4OH-
Fe3(OH)4+5 + OT- + OH- + [18O]H- + [18O]D- = Fe3OTOH[18O]H[18O]D+5 + 4OH-
Fe3(OH)4+5 + OT- + OH- + [18O]D- + OH- = Fe3OTOH[18O]DOH+5 + 4OH-
Fe3(OH)4+5 + OT- + OH- + [18O]D- + OD- = Fe3OTOH[18O]DOD+5 + 4OH-
Fe3(OH)4+5 + OT- + OH- + [18O]D- + [18O]H- = Fe3OTOH[18O]D[18O]H+5 + 4OH-
Fe3(OH)4+5 + OT- + OD- + OH- + OH- = Fe3OTODOHOH+5 + 4OH-
Fe3(OH)4+5 + OT- + OD- + OH- + OD- = Fe3OTODOHOD+5 + 4OH-
Fe3(OH)4+5 + OT- + OD- + OH- + [18O]H- = Fe3OTODOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + OT- + OD- + OH- + [18O]D- = Fe3OTODOH[18O]D+5 + 4OH-
Fe3(OH)4+5 + OT- + OD- + OD- + OH- = Fe3OTODODOH+5 + 4OH-
Fe3(OH)4+5 + OT- + OD- + OD- + [18O]H- = Fe3OTODOD[18O]H+5 + 4OH-
Fe3(OH)4+5 + OT- + OD- + [18O]H- + OH- = Fe3OTOD[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + OT- + OD- + [18O]H- + OD- = Fe3OTOD[18O]HOD+5 + 4OH-
Fe3(OH)4+5 + OT- + OD- + [18O]H- + [18O]H- = Fe3OTOD[18O]H[18O]H+5 + 4OH-
Fe3(OH)4+5 + OT- + OD- + [18O]D- + OH- = Fe3OTOD[18O]DOH+5 + 4OH-
Fe3(OH)4+5 + OT- + [18O]H- + OH- + OH- = Fe3OT[18O]HOHOH+5 + 4OH-
Fe3(OH)4+5 + OT- + [18O]H- + OH- + OD- = Fe3OT[18O]HOHOD+5 + 4OH-
Fe3(OH)4+5 + OT- + [18O]H- + OH- + [18O]H- = Fe3OT[18O]HOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + OT- + [18O]H- + OH- + [18O]D- = Fe3OT[18O]HOH[18O]D+5 + 4OH-
Fe3(OH)4+5 + OT- + [18O]H- + OD- + OH- = Fe3OT[18O]HODOH+5 + 4OH-
Fe3(OH)4+5 + OT- + [18O]H- + OD- + OD- = Fe3OT[18O]HODOD+5 + 4OH-
Fe3(OH)4+5 + OT- + [18O]H- + OD- + [18O]H- = Fe3OT[18O]HOD[18O]H+5 + 4OH-
Fe3(OH)4+5 + OT- + [18O]H- + [18O]H- + OH- = Fe3OT[18O]H[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + OT- + [18O]H- + [18O]H- + OD- = Fe3OT[18O]H[18O]HOD+5 + 4OH-
Fe3(OH)4+5 + OT- + [18O]H- + [18O]D- + OH- = Fe3OT[18O]H[18O]DOH+5 + 4OH-
Fe3(OH)4+5 + OT- + [18O]D- + OH- + OH- = Fe3OT[18O]DOHOH+5 + 4OH-
Fe3(OH)4+5 + OT- + [18O]D- + OH- + OD- = Fe3OT[18O]DOHOD+5 + 4OH-
Fe3(OH)4+5 + OT- + [18O]D- + OH- + [18O]H- = Fe3OT[18O]DOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + OT- + [18O]D- + OD- + OH- = Fe3OT[18O]DODOH+5 + 4OH-
Fe3(OH)4+5 + OT- + [18O]D- + [18O]H- + OH- = Fe3OT[18O]D[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + OH- + OH- = Fe3[18O]HOHOHOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + OH- + OD- = Fe3[18O]HOHOHOD+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + OH- + OT- = Fe3[18O]HOHOHOT+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + OH- + [18O]H- = Fe3[18O]HOHOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + OH- + [18O]D- = Fe3[18O]HOHOH[18O]D+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + OH- + [18O]T- = Fe3[18O]HOHOH[18O]T+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + OD- + OH- = Fe3[18O]HOHODOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + OD- + OD- = Fe3[18O]HOHODOD+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + OD- + OT- = Fe3[18O]HOHODOT+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + OD- + [18O]H- = Fe3[18O]HOHOD[18O]H+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + OD- + [18O]D- = Fe3[18O]HOHOD[18O]D+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + OD- + [18O]T- = Fe3[18O]HOHOD[18O]T+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + OT- + OH- = Fe3[18O]HOHOTOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + OT- + OD- = Fe3[18O]HOHOTOD+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + OT- + [18O]H- = Fe3[18O]HOHOT[18O]H+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + OT- + [18O]D- = Fe3[18O]HOHOT[18O]D+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + [18O]H- + OH- = Fe3[18O]HOH[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + [18O]H- + OD- = Fe3[18O]HOH[18O]HOD+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + [18O]H- + OT- = Fe3[18O]HOH[18O]HOT+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + [18O]D- + OH- = Fe3[18O]HOH[18O]DOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + [18O]D- + OD- = Fe3[18O]HOH[18O]DOD+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + [18O]D- + OT- = Fe3[18O]HOH[18O]DOT+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + [18O]T- + OH- = Fe3[18O]HOH[18O]TOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OH- + [18O]T- + OD- = Fe3[18O]HOH[18O]TOD+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OD- + OH- + OH- = Fe3[18O]HODOHOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OD- + OH- + OD- = Fe3[18O]HODOHOD+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OD- + OH- + OT- = Fe3[18O]HODOHOT+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OD- + OH- + [18O]H- = Fe3[18O]HODOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OD- + OH- + [18O]D- = Fe3[18O]HODOH[18O]D+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OD- + OH- + [18O]T- = Fe3[18O]HODOH[18O]T+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OD- + OD- + OH- = Fe3[18O]HODODOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OD- + OD- + OT- = Fe3[18O]HODODOT+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OD- + OD- + [18O]H- = Fe3[18O]HODOD[18O]H+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OD- + OT- + OH- = Fe3[18O]HODOTOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OD- + OT- + OD- = Fe3[18O]HODOTOD+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OD- + OT- + [18O]H- = Fe3[18O]HODOT[18O]H+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OD- + [18O]H- + OH- = Fe3[18O]HOD[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OD- + [18O]H- + OD- = Fe3[18O]HOD[18O]HOD+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OD- + [18O]H- + OT- = Fe3[18O]HOD[18O]HOT+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OD- + [18O]D- + OH- = Fe3[18O]HOD[18O]DOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OD- + [18O]T- + OH- = Fe3[18O]HOD[18O]TOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OT- + OH- + OH- = Fe3[18O]HOTOHOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OT- + OH- + OD- = Fe3[18O]HOTOHOD+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OT- + OH- + [18O]H- = Fe3[18O]HOTOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OT- + OH- + [18O]D- = Fe3[18O]HOTOH[18O]D+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OT- + OD- + OH- = Fe3[18O]HOTODOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OT- + OD- + OD- = Fe3[18O]HOTODOD+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OT- + OD- + [18O]H- = Fe3[18O]HOTOD[18O]H+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OT- + [18O]H- + OH- = Fe3[18O]HOT[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OT- + [18O]H- + OD- = Fe3[18O]HOT[18O]HOD+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + OT- + [18O]D- + OH- = Fe3[18O]HOT[18O]DOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + [18O]H- + OH- + OH- = Fe3[18O]H[18O]HOHOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + [18O]H- + OH- + OD- = Fe3[18O]H[18O]HOHOD+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + [18O]H- + OH- + OT- = Fe3[18O]H[18O]HOHOT+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + [18O]H- + OD- + OH- = Fe3[18O]H[18O]HODOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + [18O]H- + OD- + OD- = Fe3[18O]H[18O]HODOD+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + [18O]H- + OD- + OT- = Fe3[18O]H[18O]HODOT+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + [18O]H- + OT- + OH- = Fe3[18O]H[18O]HOTOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + [18O]H- + OT- + OD- = Fe3[18O]H[18O]HOTOD+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + [18O]D- + OH- + OH- = Fe3[18O]H[18O]DOHOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + [18O]D- + OH- + OD- = Fe3[18O]H[18O]DOHOD+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + [18O]D- + OH- + OT- = Fe3[18O]H[18O]DOHOT+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + [18O]D- + OD- + OH- = Fe3[18O]H[18O]DODOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + [18O]D- + OT- + OH- = Fe3[18O]H[18O]DOTOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + [18O]T- + OH- + OH- = Fe3[18O]H[18O]TOHOH+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + [18O]T- + OH- + OD- = Fe3[18O]H[18O]TOHOD+5 + 4OH-
Fe3(OH)4+5 + [18O]H- + [18O]T- + OD- + OH- = Fe3[18O]H[18O]TODOH+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OH- + OH- + OH- = Fe3[18O]DOHOHOH+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OH- + OH- + OD- = Fe3[18O]DOHOHOD+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OH- + OH- + OT- = Fe3[18O]DOHOHOT+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OH- + OH- + [18O]H- = Fe3[18O]DOHOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OH- + OH- + [18O]D- = Fe3[18O]DOHOH[18O]D+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OH- + OH- + [18O]T- = Fe3[18O]DOHOH[18O]T+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OH- + OD- + OH- = Fe3[18O]DOHODOH+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OH- + OD- + OT- = Fe3[18O]DOHODOT+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OH- + OD- + [18O]H- = Fe3[18O]DOHOD[18O]H+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OH- + OT- + OH- = Fe3[18O]DOHOTOH+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OH- + OT- + OD- = Fe3[18O]DOHOTOD+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OH- + OT- + [18O]H- = Fe3[18O]DOHOT[18O]H+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OH- + [18O]H- + OH- = Fe3[18O]DOH[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OH- + [18O]H- + OD- = Fe3[18O]DOH[18O]HOD+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OH- + [18O]H- + OT- = Fe3[18O]DOH[18O]HOT+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OH- + [18O]D- + OH- = Fe3[18O]DOH[18O]DOH+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OH- + [18O]T- + OH- = Fe3[18O]DOH[18O]TOH+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OD- + OH- + OH- = Fe3[18O]DODOHOH+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OD- + OH- + OT- = Fe3[18O]DODOHOT+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OD- + OH- + [18O]H- = Fe3[18O]DODOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OD- + OT- + OH- = Fe3[18O]DODOTOH+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OD- + [18O]H- + OH- = Fe3[18O]DOD[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OT- + OH- + OH- = Fe3[18O]DOTOHOH+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OT- + OH- + OD- = Fe3[18O]DOTOHOD+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OT- + OH- + [18O]H- = Fe3[18O]DOTOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OT- + OD- + OH- = Fe3[18O]DOTODOH+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + OT- + [18O]H- + OH- = Fe3[18O]DOT[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + [18O]H- + OH- + OH- = Fe3[18O]D[18O]HOHOH+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + [18O]H- + OH- + OD- = Fe3[18O]D[18O]HOHOD+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + [18O]H- + OH- + OT- = Fe3[18O]D[18O]HOHOT+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + [18O]H- + OD- + OH- = Fe3[18O]D[18O]HODOH+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + [18O]H- + OT- + OH- = Fe3[18O]D[18O]HOTOH+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + [18O]D- + OH- + OH- = Fe3[18O]D[18O]DOHOH+5 + 4OH-
Fe3(OH)4+5 + [18O]D- + [18O]T- + OH- + OH- = Fe3[18O]D[18O]TOHOH+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + OH- + OH- + OH- = Fe3[18O]TOHOHOH+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + OH- + OH- + OD- = Fe3[18O]TOHOHOD+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + OH- + OH- + [18O]H- = Fe3[18O]TOHOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + OH- + OH- + [18O]D- = Fe3[18O]TOHOH[18O]D+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + OH- + OD- + OH- = Fe3[18O]TOHODOH+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + OH- + OD- + OD- = Fe3[18O]TOHODOD+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + OH- + OD- + [18O]H- = Fe3[18O]TOHOD[18O]H+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + OH- + [18O]H- + OH- = Fe3[18O]TOH[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + OH- + [18O]H- + OD- = Fe3[18O]TOH[18O]HOD+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + OH- + [18O]D- + OH- = Fe3[18O]TOH[18O]DOH+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + OD- + OH- + OH- = Fe3[18O]TODOHOH+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + OD- + OH- + OD- = Fe3[18O]TODOHOD+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + OD- + OH- + [18O]H- = Fe3[18O]TODOH[18O]H+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + OD- + OD- + OH- = Fe3[18O]TODODOH+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + OD- + [18O]H- + OH- = Fe3[18O]TOD[18O]HOH+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + [18O]H- + OH- + OH- = Fe3[18O]T[18O]HOHOH+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + [18O]H- + OH- + OD- = Fe3[18O]T[18O]HOHOD+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + [18O]H- + OD- + OH- = Fe3[18O]T[18O]HODOH+5 + 4OH-
Fe3(OH)4+5 + [18O]T- + [18O]D- + OH- + OH- = Fe3[18O]T[18O]DOHOH+5 + 4OH-
#
# Added FeSO4+ reactions 16Dec09
#
FeSO4+ + [34S]O4-2 = Fe[34S]O4+ + SO4-2
#
# Added FeHSO4+2 reactions 16Dec09
#
FeHSO4+2 + DSO4- = FeDSO4+2 + HSO4-
FeHSO4+2 + TSO4- = FeTSO4+2 + HSO4-
FeHSO4+2 + H[34S]O4- = FeH[34S]O4+2 + HSO4-
FeHSO4+2 + D[34S]O4- = FeD[34S]O4+2 + HSO4-
FeHSO4+2 + T[34S]O4- = FeT[34S]O4+2 + HSO4-
#
# Added Fe(SO4)2- reactions 16Dec09
# Revised 17Dec09
#
Fe(SO4)2- + SO4-2 + [34S]O4-2 = FeSO4[34S]O4- + 2SO4-2
Fe(SO4)2- + [34S]O4-2 + SO4-2 = Fe[34S]O4SO4- + 2SO4-2
Fe(SO4)2- + [34S]O4-2 + [34S]O4-2 = Fe[34S]O4[34S]O4- + 2SO4-2
#
# Missing FeHPO4+ reactions
#
#
# Missing FeH2PO4+2 reactions
#
#
# Added AlOH+2 reactions 16Dec09
#
AlOH+2 + OD- = AlOD+2 + OH-
AlOH+2 + OT- = AlOT+2 + OH-
AlOH+2 + [18O]H- = Al[18O]H+2 + OH-
AlOH+2 + [18O]D- = Al[18O]D+2 + OH-
AlOH+2 + [18O]T- = Al[18O]T+2 + OH-
#
# Added Al(OH)2+ reactions 16Dec09
# Revised 17Dec09, limited the number of species
#
Al(OH)2+ + OH- + OD- = AlOHOD+ + 2OH-
Al(OH)2+ + OH- + OT- = AlOHOT+ + 2OH-
Al(OH)2+ + OH- + [18O]H- = AlOH[18O]H+ + 2OH-
Al(OH)2+ + OH- + [18O]D- = AlOH[18O]D+ + 2OH-
Al(OH)2+ + OH- + [18O]T- = AlOH[18O]T+ + 2OH-
Al(OH)2+ + OD- + OH- = AlODOH+ + 2OH-
Al(OH)2+ + OD- + OD- = AlODOD+ + 2OH-
Al(OH)2+ + OD- + OT- = AlODOT+ + 2OH-
Al(OH)2+ + OD- + [18O]H- = AlOD[18O]H+ + 2OH-
Al(OH)2+ + OD- + [18O]D- = AlOD[18O]D+ + 2OH-
Al(OH)2+ + OD- + [18O]T- = AlOD[18O]T+ + 2OH-
Al(OH)2+ + OT- + OH- = AlOTOH+ + 2OH-
Al(OH)2+ + OT- + OD- = AlOTOD+ + 2OH-
Al(OH)2+ + OT- + [18O]H- = AlOT[18O]H+ + 2OH-
Al(OH)2+ + OT- + [18O]D- = AlOT[18O]D+ + 2OH-
Al(OH)2+ + [18O]H- + OH- = Al[18O]HOH+ + 2OH-
Al(OH)2+ + [18O]H- + OD- = Al[18O]HOD+ + 2OH-
Al(OH)2+ + [18O]H- + OT- = Al[18O]HOT+ + 2OH-
Al(OH)2+ + [18O]H- + [18O]H- = Al[18O]H[18O]H+ + 2OH-
Al(OH)2+ + [18O]H- + [18O]D- = Al[18O]H[18O]D+ + 2OH-
Al(OH)2+ + [18O]H- + [18O]T- = Al[18O]H[18O]T+ + 2OH-
Al(OH)2+ + [18O]D- + OH- = Al[18O]DOH+ + 2OH-
Al(OH)2+ + [18O]D- + OD- = Al[18O]DOD+ + 2OH-
Al(OH)2+ + [18O]D- + OT- = Al[18O]DOT+ + 2OH-
Al(OH)2+ + [18O]D- + [18O]H- = Al[18O]D[18O]H+ + 2OH-
Al(OH)2+ + [18O]D- + [18O]D- = Al[18O]D[18O]D+ + 2OH-
Al(OH)2+ + [18O]D- + [18O]T- = Al[18O]D[18O]T+ + 2OH-
Al(OH)2+ + [18O]T- + OH- = Al[18O]TOH+ + 2OH-
Al(OH)2+ + [18O]T- + OD- = Al[18O]TOD+ + 2OH-
Al(OH)2+ + [18O]T- + [18O]H- = Al[18O]T[18O]H+ + 2OH-
Al(OH)2+ + [18O]T- + [18O]D- = Al[18O]T[18O]D+ + 2OH-
#
# Added Al(OH)3 reactions 16Dec09
# Revised 17Dec09, limited the number of species
#
Al(OH)3 + OH- + OH- + OD- = AlOHOHOD + 3OH-
Al(OH)3 + OH- + OH- + OT- = AlOHOHOT + 3OH-
Al(OH)3 + OH- + OH- + [18O]H- = AlOHOH[18O]H + 3OH-
Al(OH)3 + OH- + OH- + [18O]D- = AlOHOH[18O]D + 3OH-
Al(OH)3 + OH- + OH- + [18O]T- = AlOHOH[18O]T + 3OH-
Al(OH)3 + OH- + OD- + OH- = AlOHODOH + 3OH-
Al(OH)3 + OH- + OD- + OD- = AlOHODOD + 3OH-
Al(OH)3 + OH- + OD- + OT- = AlOHODOT + 3OH-
Al(OH)3 + OH- + OD- + [18O]H- = AlOHOD[18O]H + 3OH-
Al(OH)3 + OH- + OD- + [18O]D- = AlOHOD[18O]D + 3OH-
Al(OH)3 + OH- + OD- + [18O]T- = AlOHOD[18O]T + 3OH-
Al(OH)3 + OH- + OT- + OH- = AlOHOTOH + 3OH-
Al(OH)3 + OH- + OT- + OD- = AlOHOTOD + 3OH-
Al(OH)3 + OH- + OT- + [18O]H- = AlOHOT[18O]H + 3OH-
Al(OH)3 + OH- + OT- + [18O]D- = AlOHOT[18O]D + 3OH-
Al(OH)3 + OH- + [18O]H- + OH- = AlOH[18O]HOH + 3OH-
Al(OH)3 + OH- + [18O]H- + OD- = AlOH[18O]HOD + 3OH-
Al(OH)3 + OH- + [18O]H- + OT- = AlOH[18O]HOT + 3OH-
Al(OH)3 + OH- + [18O]H- + [18O]H- = AlOH[18O]H[18O]H + 3OH-
Al(OH)3 + OH- + [18O]H- + [18O]D- = AlOH[18O]H[18O]D + 3OH-
Al(OH)3 + OH- + [18O]H- + [18O]T- = AlOH[18O]H[18O]T + 3OH-
Al(OH)3 + OH- + [18O]D- + OH- = AlOH[18O]DOH + 3OH-
Al(OH)3 + OH- + [18O]D- + OD- = AlOH[18O]DOD + 3OH-
Al(OH)3 + OH- + [18O]D- + OT- = AlOH[18O]DOT + 3OH-
Al(OH)3 + OH- + [18O]D- + [18O]H- = AlOH[18O]D[18O]H + 3OH-
Al(OH)3 + OH- + [18O]D- + [18O]D- = AlOH[18O]D[18O]D + 3OH-
Al(OH)3 + OH- + [18O]D- + [18O]T- = AlOH[18O]D[18O]T + 3OH-
Al(OH)3 + OH- + [18O]T- + OH- = AlOH[18O]TOH + 3OH-
Al(OH)3 + OH- + [18O]T- + OD- = AlOH[18O]TOD + 3OH-
Al(OH)3 + OH- + [18O]T- + [18O]H- = AlOH[18O]T[18O]H + 3OH-
Al(OH)3 + OH- + [18O]T- + [18O]D- = AlOH[18O]T[18O]D + 3OH-
Al(OH)3 + OD- + OH- + OH- = AlODOHOH + 3OH-
Al(OH)3 + OD- + OH- + OD- = AlODOHOD + 3OH-
Al(OH)3 + OD- + OH- + OT- = AlODOHOT + 3OH-
Al(OH)3 + OD- + OH- + [18O]H- = AlODOH[18O]H + 3OH-
Al(OH)3 + OD- + OH- + [18O]D- = AlODOH[18O]D + 3OH-
Al(OH)3 + OD- + OH- + [18O]T- = AlODOH[18O]T + 3OH-
Al(OH)3 + OD- + OD- + OH- = AlODODOH + 3OH-
Al(OH)3 + OD- + OD- + OT- = AlODODOT + 3OH-
Al(OH)3 + OD- + OD- + [18O]H- = AlODOD[18O]H + 3OH-
Al(OH)3 + OD- + OD- + [18O]T- = AlODOD[18O]T + 3OH-
Al(OH)3 + OD- + OT- + OH- = AlODOTOH + 3OH-
Al(OH)3 + OD- + OT- + OD- = AlODOTOD + 3OH-
Al(OH)3 + OD- + OT- + [18O]H- = AlODOT[18O]H + 3OH-
Al(OH)3 + OD- + OT- + [18O]D- = AlODOT[18O]D + 3OH-
Al(OH)3 + OD- + [18O]H- + OH- = AlOD[18O]HOH + 3OH-
Al(OH)3 + OD- + [18O]H- + OD- = AlOD[18O]HOD + 3OH-
Al(OH)3 + OD- + [18O]H- + OT- = AlOD[18O]HOT + 3OH-
Al(OH)3 + OD- + [18O]H- + [18O]H- = AlOD[18O]H[18O]H + 3OH-
Al(OH)3 + OD- + [18O]H- + [18O]D- = AlOD[18O]H[18O]D + 3OH-
Al(OH)3 + OD- + [18O]H- + [18O]T- = AlOD[18O]H[18O]T + 3OH-
Al(OH)3 + OD- + [18O]D- + OH- = AlOD[18O]DOH + 3OH-
Al(OH)3 + OD- + [18O]D- + OT- = AlOD[18O]DOT + 3OH-
Al(OH)3 + OD- + [18O]D- + [18O]H- = AlOD[18O]D[18O]H + 3OH-
Al(OH)3 + OD- + [18O]T- + OH- = AlOD[18O]TOH + 3OH-
Al(OH)3 + OD- + [18O]T- + OD- = AlOD[18O]TOD + 3OH-
Al(OH)3 + OD- + [18O]T- + [18O]H- = AlOD[18O]T[18O]H + 3OH-
Al(OH)3 + OT- + OH- + OH- = AlOTOHOH + 3OH-
Al(OH)3 + OT- + OH- + OD- = AlOTOHOD + 3OH-
Al(OH)3 + OT- + OH- + [18O]H- = AlOTOH[18O]H + 3OH-
Al(OH)3 + OT- + OH- + [18O]D- = AlOTOH[18O]D + 3OH-
Al(OH)3 + OT- + OD- + OH- = AlOTODOH + 3OH-
Al(OH)3 + OT- + OD- + OD- = AlOTODOD + 3OH-
Al(OH)3 + OT- + OD- + [18O]H- = AlOTOD[18O]H + 3OH-
Al(OH)3 + OT- + OD- + [18O]D- = AlOTOD[18O]D + 3OH-
Al(OH)3 + OT- + [18O]H- + OH- = AlOT[18O]HOH + 3OH-
Al(OH)3 + OT- + [18O]H- + OD- = AlOT[18O]HOD + 3OH-
Al(OH)3 + OT- + [18O]H- + [18O]H- = AlOT[18O]H[18O]H + 3OH-
Al(OH)3 + OT- + [18O]H- + [18O]D- = AlOT[18O]H[18O]D + 3OH-
Al(OH)3 + OT- + [18O]D- + OH- = AlOT[18O]DOH + 3OH-
Al(OH)3 + OT- + [18O]D- + OD- = AlOT[18O]DOD + 3OH-
Al(OH)3 + OT- + [18O]D- + [18O]H- = AlOT[18O]D[18O]H + 3OH-
Al(OH)3 + [18O]H- + OH- + OH- = Al[18O]HOHOH + 3OH-
Al(OH)3 + [18O]H- + OH- + OD- = Al[18O]HOHOD + 3OH-
Al(OH)3 + [18O]H- + OH- + OT- = Al[18O]HOHOT + 3OH-
Al(OH)3 + [18O]H- + OH- + [18O]H- = Al[18O]HOH[18O]H + 3OH-
Al(OH)3 + [18O]H- + OH- + [18O]D- = Al[18O]HOH[18O]D + 3OH-
Al(OH)3 + [18O]H- + OH- + [18O]T- = Al[18O]HOH[18O]T + 3OH-
Al(OH)3 + [18O]H- + OD- + OH- = Al[18O]HODOH + 3OH-
Al(OH)3 + [18O]H- + OD- + OD- = Al[18O]HODOD + 3OH-
Al(OH)3 + [18O]H- + OD- + OT- = Al[18O]HODOT + 3OH-
Al(OH)3 + [18O]H- + OD- + [18O]H- = Al[18O]HOD[18O]H + 3OH-
Al(OH)3 + [18O]H- + OD- + [18O]D- = Al[18O]HOD[18O]D + 3OH-
Al(OH)3 + [18O]H- + OD- + [18O]T- = Al[18O]HOD[18O]T + 3OH-
Al(OH)3 + [18O]H- + OT- + OH- = Al[18O]HOTOH + 3OH-
Al(OH)3 + [18O]H- + OT- + OD- = Al[18O]HOTOD + 3OH-
Al(OH)3 + [18O]H- + OT- + [18O]H- = Al[18O]HOT[18O]H + 3OH-
Al(OH)3 + [18O]H- + OT- + [18O]D- = Al[18O]HOT[18O]D + 3OH-
Al(OH)3 + [18O]H- + [18O]H- + OH- = Al[18O]H[18O]HOH + 3OH-
Al(OH)3 + [18O]H- + [18O]H- + OD- = Al[18O]H[18O]HOD + 3OH-
Al(OH)3 + [18O]H- + [18O]H- + OT- = Al[18O]H[18O]HOT + 3OH-
Al(OH)3 + [18O]H- + [18O]D- + OH- = Al[18O]H[18O]DOH + 3OH-
Al(OH)3 + [18O]H- + [18O]D- + OD- = Al[18O]H[18O]DOD + 3OH-
Al(OH)3 + [18O]H- + [18O]D- + OT- = Al[18O]H[18O]DOT + 3OH-
Al(OH)3 + [18O]H- + [18O]T- + OH- = Al[18O]H[18O]TOH + 3OH-
Al(OH)3 + [18O]H- + [18O]T- + OD- = Al[18O]H[18O]TOD + 3OH-
Al(OH)3 + [18O]D- + OH- + OH- = Al[18O]DOHOH + 3OH-
Al(OH)3 + [18O]D- + OH- + OD- = Al[18O]DOHOD + 3OH-
Al(OH)3 + [18O]D- + OH- + OT- = Al[18O]DOHOT + 3OH-
Al(OH)3 + [18O]D- + OH- + [18O]H- = Al[18O]DOH[18O]H + 3OH-
Al(OH)3 + [18O]D- + OH- + [18O]D- = Al[18O]DOH[18O]D + 3OH-
Al(OH)3 + [18O]D- + OH- + [18O]T- = Al[18O]DOH[18O]T + 3OH-
Al(OH)3 + [18O]D- + OD- + OH- = Al[18O]DODOH + 3OH-
Al(OH)3 + [18O]D- + OD- + OT- = Al[18O]DODOT + 3OH-
Al(OH)3 + [18O]D- + OD- + [18O]H- = Al[18O]DOD[18O]H + 3OH-
Al(OH)3 + [18O]D- + OT- + OH- = Al[18O]DOTOH + 3OH-
Al(OH)3 + [18O]D- + OT- + OD- = Al[18O]DOTOD + 3OH-
Al(OH)3 + [18O]D- + OT- + [18O]H- = Al[18O]DOT[18O]H + 3OH-
Al(OH)3 + [18O]D- + [18O]H- + OH- = Al[18O]D[18O]HOH + 3OH-
Al(OH)3 + [18O]D- + [18O]H- + OD- = Al[18O]D[18O]HOD + 3OH-
Al(OH)3 + [18O]D- + [18O]H- + OT- = Al[18O]D[18O]HOT + 3OH-
Al(OH)3 + [18O]D- + [18O]D- + OH- = Al[18O]D[18O]DOH + 3OH-
Al(OH)3 + [18O]D- + [18O]T- + OH- = Al[18O]D[18O]TOH + 3OH-
Al(OH)3 + [18O]T- + OH- + OH- = Al[18O]TOHOH + 3OH-
Al(OH)3 + [18O]T- + OH- + OD- = Al[18O]TOHOD + 3OH-
Al(OH)3 + [18O]T- + OH- + [18O]H- = Al[18O]TOH[18O]H + 3OH-
Al(OH)3 + [18O]T- + OH- + [18O]D- = Al[18O]TOH[18O]D + 3OH-
Al(OH)3 + [18O]T- + OD- + OH- = Al[18O]TODOH + 3OH-
Al(OH)3 + [18O]T- + OD- + OD- = Al[18O]TODOD + 3OH-
Al(OH)3 + [18O]T- + OD- + [18O]H- = Al[18O]TOD[18O]H + 3OH-
Al(OH)3 + [18O]T- + [18O]H- + OH- = Al[18O]T[18O]HOH + 3OH-
Al(OH)3 + [18O]T- + [18O]H- + OD- = Al[18O]T[18O]HOD + 3OH-
Al(OH)3 + [18O]T- + [18O]D- + OH- = Al[18O]T[18O]DOH + 3OH-
#
# Added Al(OH)4- reactions 16Dec09
# Revised 17Dec09, limited the number of species
#
Al(OH)4- + OH- + OH- + OH- + OD- = AlOHOHOHOD- + 4OH-
Al(OH)4- + OH- + OH- + OH- + OT- = AlOHOHOHOT- + 4OH-
Al(OH)4- + OH- + OH- + OH- + [18O]H- = AlOHOHOH[18O]H- + 4OH-
Al(OH)4- + OH- + OH- + OH- + [18O]D- = AlOHOHOH[18O]D- + 4OH-
Al(OH)4- + OH- + OH- + OH- + [18O]T- = AlOHOHOH[18O]T- + 4OH-
Al(OH)4- + OH- + OH- + OD- + OH- = AlOHOHODOH- + 4OH-
Al(OH)4- + OH- + OH- + OD- + OD- = AlOHOHODOD- + 4OH-
Al(OH)4- + OH- + OH- + OD- + OT- = AlOHOHODOT- + 4OH-
Al(OH)4- + OH- + OH- + OD- + [18O]H- = AlOHOHOD[18O]H- + 4OH-
Al(OH)4- + OH- + OH- + OD- + [18O]D- = AlOHOHOD[18O]D- + 4OH-
Al(OH)4- + OH- + OH- + OD- + [18O]T- = AlOHOHOD[18O]T- + 4OH-
Al(OH)4- + OH- + OH- + OT- + OH- = AlOHOHOTOH- + 4OH-
Al(OH)4- + OH- + OH- + OT- + OD- = AlOHOHOTOD- + 4OH-
Al(OH)4- + OH- + OH- + OT- + [18O]H- = AlOHOHOT[18O]H- + 4OH-
Al(OH)4- + OH- + OH- + OT- + [18O]D- = AlOHOHOT[18O]D- + 4OH-
Al(OH)4- + OH- + OH- + [18O]H- + OH- = AlOHOH[18O]HOH- + 4OH-
Al(OH)4- + OH- + OH- + [18O]H- + OD- = AlOHOH[18O]HOD- + 4OH-
Al(OH)4- + OH- + OH- + [18O]H- + OT- = AlOHOH[18O]HOT- + 4OH-
Al(OH)4- + OH- + OH- + [18O]H- + [18O]H- = AlOHOH[18O]H[18O]H- + 4OH-
Al(OH)4- + OH- + OH- + [18O]H- + [18O]D- = AlOHOH[18O]H[18O]D- + 4OH-
Al(OH)4- + OH- + OH- + [18O]H- + [18O]T- = AlOHOH[18O]H[18O]T- + 4OH-
Al(OH)4- + OH- + OH- + [18O]D- + OH- = AlOHOH[18O]DOH- + 4OH-
Al(OH)4- + OH- + OH- + [18O]D- + OD- = AlOHOH[18O]DOD- + 4OH-
Al(OH)4- + OH- + OH- + [18O]D- + OT- = AlOHOH[18O]DOT- + 4OH-
Al(OH)4- + OH- + OH- + [18O]D- + [18O]H- = AlOHOH[18O]D[18O]H- + 4OH-
Al(OH)4- + OH- + OH- + [18O]D- + [18O]D- = AlOHOH[18O]D[18O]D- + 4OH-
Al(OH)4- + OH- + OH- + [18O]D- + [18O]T- = AlOHOH[18O]D[18O]T- + 4OH-
Al(OH)4- + OH- + OH- + [18O]T- + OH- = AlOHOH[18O]TOH- + 4OH-
Al(OH)4- + OH- + OH- + [18O]T- + OD- = AlOHOH[18O]TOD- + 4OH-
Al(OH)4- + OH- + OH- + [18O]T- + [18O]H- = AlOHOH[18O]T[18O]H- + 4OH-
Al(OH)4- + OH- + OH- + [18O]T- + [18O]D- = AlOHOH[18O]T[18O]D- + 4OH-
Al(OH)4- + OH- + OD- + OH- + OH- = AlOHODOHOH- + 4OH-
Al(OH)4- + OH- + OD- + OH- + OD- = AlOHODOHOD- + 4OH-
Al(OH)4- + OH- + OD- + OH- + OT- = AlOHODOHOT- + 4OH-
Al(OH)4- + OH- + OD- + OH- + [18O]H- = AlOHODOH[18O]H- + 4OH-
Al(OH)4- + OH- + OD- + OH- + [18O]D- = AlOHODOH[18O]D- + 4OH-
Al(OH)4- + OH- + OD- + OH- + [18O]T- = AlOHODOH[18O]T- + 4OH-
Al(OH)4- + OH- + OD- + OD- + OH- = AlOHODODOH- + 4OH-
Al(OH)4- + OH- + OD- + OD- + OT- = AlOHODODOT- + 4OH-
Al(OH)4- + OH- + OD- + OD- + [18O]H- = AlOHODOD[18O]H- + 4OH-
Al(OH)4- + OH- + OD- + OD- + [18O]T- = AlOHODOD[18O]T- + 4OH-
Al(OH)4- + OH- + OD- + OT- + OH- = AlOHODOTOH- + 4OH-
Al(OH)4- + OH- + OD- + OT- + OD- = AlOHODOTOD- + 4OH-
Al(OH)4- + OH- + OD- + OT- + [18O]H- = AlOHODOT[18O]H- + 4OH-
Al(OH)4- + OH- + OD- + OT- + [18O]D- = AlOHODOT[18O]D- + 4OH-
Al(OH)4- + OH- + OD- + [18O]H- + OH- = AlOHOD[18O]HOH- + 4OH-
Al(OH)4- + OH- + OD- + [18O]H- + OD- = AlOHOD[18O]HOD- + 4OH-
Al(OH)4- + OH- + OD- + [18O]H- + OT- = AlOHOD[18O]HOT- + 4OH-
Al(OH)4- + OH- + OD- + [18O]H- + [18O]H- = AlOHOD[18O]H[18O]H- + 4OH-
Al(OH)4- + OH- + OD- + [18O]H- + [18O]D- = AlOHOD[18O]H[18O]D- + 4OH-
Al(OH)4- + OH- + OD- + [18O]H- + [18O]T- = AlOHOD[18O]H[18O]T- + 4OH-
Al(OH)4- + OH- + OD- + [18O]D- + OH- = AlOHOD[18O]DOH- + 4OH-
Al(OH)4- + OH- + OD- + [18O]D- + OT- = AlOHOD[18O]DOT- + 4OH-
Al(OH)4- + OH- + OD- + [18O]D- + [18O]H- = AlOHOD[18O]D[18O]H- + 4OH-
Al(OH)4- + OH- + OD- + [18O]T- + OH- = AlOHOD[18O]TOH- + 4OH-
Al(OH)4- + OH- + OD- + [18O]T- + OD- = AlOHOD[18O]TOD- + 4OH-
Al(OH)4- + OH- + OD- + [18O]T- + [18O]H- = AlOHOD[18O]T[18O]H- + 4OH-
Al(OH)4- + OH- + OT- + OH- + OH- = AlOHOTOHOH- + 4OH-
Al(OH)4- + OH- + OT- + OH- + OD- = AlOHOTOHOD- + 4OH-
Al(OH)4- + OH- + OT- + OH- + [18O]H- = AlOHOTOH[18O]H- + 4OH-
Al(OH)4- + OH- + OT- + OH- + [18O]D- = AlOHOTOH[18O]D- + 4OH-
Al(OH)4- + OH- + OT- + OD- + OH- = AlOHOTODOH- + 4OH-
Al(OH)4- + OH- + OT- + OD- + OD- = AlOHOTODOD- + 4OH-
Al(OH)4- + OH- + OT- + OD- + [18O]H- = AlOHOTOD[18O]H- + 4OH-
Al(OH)4- + OH- + OT- + OD- + [18O]D- = AlOHOTOD[18O]D- + 4OH-
Al(OH)4- + OH- + OT- + [18O]H- + OH- = AlOHOT[18O]HOH- + 4OH-
Al(OH)4- + OH- + OT- + [18O]H- + OD- = AlOHOT[18O]HOD- + 4OH-
Al(OH)4- + OH- + OT- + [18O]H- + [18O]H- = AlOHOT[18O]H[18O]H- + 4OH-
Al(OH)4- + OH- + OT- + [18O]H- + [18O]D- = AlOHOT[18O]H[18O]D- + 4OH-
Al(OH)4- + OH- + OT- + [18O]D- + OH- = AlOHOT[18O]DOH- + 4OH-
Al(OH)4- + OH- + OT- + [18O]D- + OD- = AlOHOT[18O]DOD- + 4OH-
Al(OH)4- + OH- + OT- + [18O]D- + [18O]H- = AlOHOT[18O]D[18O]H- + 4OH-
Al(OH)4- + OH- + [18O]H- + OH- + OH- = AlOH[18O]HOHOH- + 4OH-
Al(OH)4- + OH- + [18O]H- + OH- + OD- = AlOH[18O]HOHOD- + 4OH-
Al(OH)4- + OH- + [18O]H- + OH- + OT- = AlOH[18O]HOHOT- + 4OH-
Al(OH)4- + OH- + [18O]H- + OH- + [18O]H- = AlOH[18O]HOH[18O]H- + 4OH-
Al(OH)4- + OH- + [18O]H- + OH- + [18O]D- = AlOH[18O]HOH[18O]D- + 4OH-
Al(OH)4- + OH- + [18O]H- + OH- + [18O]T- = AlOH[18O]HOH[18O]T- + 4OH-
Al(OH)4- + OH- + [18O]H- + OD- + OH- = AlOH[18O]HODOH- + 4OH-
Al(OH)4- + OH- + [18O]H- + OD- + OD- = AlOH[18O]HODOD- + 4OH-
Al(OH)4- + OH- + [18O]H- + OD- + OT- = AlOH[18O]HODOT- + 4OH-
Al(OH)4- + OH- + [18O]H- + OD- + [18O]H- = AlOH[18O]HOD[18O]H- + 4OH-
Al(OH)4- + OH- + [18O]H- + OD- + [18O]D- = AlOH[18O]HOD[18O]D- + 4OH-
Al(OH)4- + OH- + [18O]H- + OD- + [18O]T- = AlOH[18O]HOD[18O]T- + 4OH-
Al(OH)4- + OH- + [18O]H- + OT- + OH- = AlOH[18O]HOTOH- + 4OH-
Al(OH)4- + OH- + [18O]H- + OT- + OD- = AlOH[18O]HOTOD- + 4OH-
Al(OH)4- + OH- + [18O]H- + OT- + [18O]H- = AlOH[18O]HOT[18O]H- + 4OH-
Al(OH)4- + OH- + [18O]H- + OT- + [18O]D- = AlOH[18O]HOT[18O]D- + 4OH-
Al(OH)4- + OH- + [18O]H- + [18O]H- + OH- = AlOH[18O]H[18O]HOH- + 4OH-
Al(OH)4- + OH- + [18O]H- + [18O]H- + OD- = AlOH[18O]H[18O]HOD- + 4OH-
Al(OH)4- + OH- + [18O]H- + [18O]H- + OT- = AlOH[18O]H[18O]HOT- + 4OH-
Al(OH)4- + OH- + [18O]H- + [18O]D- + OH- = AlOH[18O]H[18O]DOH- + 4OH-
Al(OH)4- + OH- + [18O]H- + [18O]D- + OD- = AlOH[18O]H[18O]DOD- + 4OH-
Al(OH)4- + OH- + [18O]H- + [18O]D- + OT- = AlOH[18O]H[18O]DOT- + 4OH-
Al(OH)4- + OH- + [18O]H- + [18O]T- + OH- = AlOH[18O]H[18O]TOH- + 4OH-
Al(OH)4- + OH- + [18O]H- + [18O]T- + OD- = AlOH[18O]H[18O]TOD- + 4OH-
Al(OH)4- + OH- + [18O]D- + OH- + OH- = AlOH[18O]DOHOH- + 4OH-
Al(OH)4- + OH- + [18O]D- + OH- + OD- = AlOH[18O]DOHOD- + 4OH-
Al(OH)4- + OH- + [18O]D- + OH- + OT- = AlOH[18O]DOHOT- + 4OH-
Al(OH)4- + OH- + [18O]D- + OH- + [18O]H- = AlOH[18O]DOH[18O]H- + 4OH-
Al(OH)4- + OH- + [18O]D- + OH- + [18O]D- = AlOH[18O]DOH[18O]D- + 4OH-
Al(OH)4- + OH- + [18O]D- + OH- + [18O]T- = AlOH[18O]DOH[18O]T- + 4OH-
Al(OH)4- + OH- + [18O]D- + OD- + OH- = AlOH[18O]DODOH- + 4OH-
Al(OH)4- + OH- + [18O]D- + OD- + OT- = AlOH[18O]DODOT- + 4OH-
Al(OH)4- + OH- + [18O]D- + OD- + [18O]H- = AlOH[18O]DOD[18O]H- + 4OH-
Al(OH)4- + OH- + [18O]D- + OT- + OH- = AlOH[18O]DOTOH- + 4OH-
Al(OH)4- + OH- + [18O]D- + OT- + OD- = AlOH[18O]DOTOD- + 4OH-
Al(OH)4- + OH- + [18O]D- + OT- + [18O]H- = AlOH[18O]DOT[18O]H- + 4OH-
Al(OH)4- + OH- + [18O]D- + [18O]H- + OH- = AlOH[18O]D[18O]HOH- + 4OH-
Al(OH)4- + OH- + [18O]D- + [18O]H- + OD- = AlOH[18O]D[18O]HOD- + 4OH-
Al(OH)4- + OH- + [18O]D- + [18O]H- + OT- = AlOH[18O]D[18O]HOT- + 4OH-
Al(OH)4- + OH- + [18O]D- + [18O]D- + OH- = AlOH[18O]D[18O]DOH- + 4OH-
Al(OH)4- + OH- + [18O]D- + [18O]T- + OH- = AlOH[18O]D[18O]TOH- + 4OH-
Al(OH)4- + OH- + [18O]T- + OH- + OH- = AlOH[18O]TOHOH- + 4OH-
Al(OH)4- + OH- + [18O]T- + OH- + OD- = AlOH[18O]TOHOD- + 4OH-
Al(OH)4- + OH- + [18O]T- + OH- + [18O]H- = AlOH[18O]TOH[18O]H- + 4OH-
Al(OH)4- + OH- + [18O]T- + OH- + [18O]D- = AlOH[18O]TOH[18O]D- + 4OH-
Al(OH)4- + OH- + [18O]T- + OD- + OH- = AlOH[18O]TODOH- + 4OH-
Al(OH)4- + OH- + [18O]T- + OD- + OD- = AlOH[18O]TODOD- + 4OH-
Al(OH)4- + OH- + [18O]T- + OD- + [18O]H- = AlOH[18O]TOD[18O]H- + 4OH-
Al(OH)4- + OH- + [18O]T- + [18O]H- + OH- = AlOH[18O]T[18O]HOH- + 4OH-
Al(OH)4- + OH- + [18O]T- + [18O]H- + OD- = AlOH[18O]T[18O]HOD- + 4OH-
Al(OH)4- + OH- + [18O]T- + [18O]D- + OH- = AlOH[18O]T[18O]DOH- + 4OH-
Al(OH)4- + OD- + OH- + OH- + OH- = AlODOHOHOH- + 4OH-
Al(OH)4- + OD- + OH- + OH- + OD- = AlODOHOHOD- + 4OH-
Al(OH)4- + OD- + OH- + OH- + OT- = AlODOHOHOT- + 4OH-
Al(OH)4- + OD- + OH- + OH- + [18O]H- = AlODOHOH[18O]H- + 4OH-
Al(OH)4- + OD- + OH- + OH- + [18O]D- = AlODOHOH[18O]D- + 4OH-
Al(OH)4- + OD- + OH- + OH- + [18O]T- = AlODOHOH[18O]T- + 4OH-
Al(OH)4- + OD- + OH- + OD- + OH- = AlODOHODOH- + 4OH-
Al(OH)4- + OD- + OH- + OD- + OT- = AlODOHODOT- + 4OH-
Al(OH)4- + OD- + OH- + OD- + [18O]H- = AlODOHOD[18O]H- + 4OH-
Al(OH)4- + OD- + OH- + OD- + [18O]T- = AlODOHOD[18O]T- + 4OH-
Al(OH)4- + OD- + OH- + OT- + OH- = AlODOHOTOH- + 4OH-
Al(OH)4- + OD- + OH- + OT- + OD- = AlODOHOTOD- + 4OH-
Al(OH)4- + OD- + OH- + OT- + [18O]H- = AlODOHOT[18O]H- + 4OH-
Al(OH)4- + OD- + OH- + OT- + [18O]D- = AlODOHOT[18O]D- + 4OH-
Al(OH)4- + OD- + OH- + [18O]H- + OH- = AlODOH[18O]HOH- + 4OH-
Al(OH)4- + OD- + OH- + [18O]H- + OD- = AlODOH[18O]HOD- + 4OH-
Al(OH)4- + OD- + OH- + [18O]H- + OT- = AlODOH[18O]HOT- + 4OH-
Al(OH)4- + OD- + OH- + [18O]H- + [18O]H- = AlODOH[18O]H[18O]H- + 4OH-
Al(OH)4- + OD- + OH- + [18O]H- + [18O]D- = AlODOH[18O]H[18O]D- + 4OH-
Al(OH)4- + OD- + OH- + [18O]H- + [18O]T- = AlODOH[18O]H[18O]T- + 4OH-
Al(OH)4- + OD- + OH- + [18O]D- + OH- = AlODOH[18O]DOH- + 4OH-
Al(OH)4- + OD- + OH- + [18O]D- + OT- = AlODOH[18O]DOT- + 4OH-
Al(OH)4- + OD- + OH- + [18O]D- + [18O]H- = AlODOH[18O]D[18O]H- + 4OH-
Al(OH)4- + OD- + OH- + [18O]T- + OH- = AlODOH[18O]TOH- + 4OH-
Al(OH)4- + OD- + OH- + [18O]T- + OD- = AlODOH[18O]TOD- + 4OH-
Al(OH)4- + OD- + OH- + [18O]T- + [18O]H- = AlODOH[18O]T[18O]H- + 4OH-
Al(OH)4- + OD- + OD- + OH- + OH- = AlODODOHOH- + 4OH-
Al(OH)4- + OD- + OD- + OH- + OT- = AlODODOHOT- + 4OH-
Al(OH)4- + OD- + OD- + OH- + [18O]H- = AlODODOH[18O]H- + 4OH-
Al(OH)4- + OD- + OD- + OH- + [18O]T- = AlODODOH[18O]T- + 4OH-
Al(OH)4- + OD- + OD- + OT- + OH- = AlODODOTOH- + 4OH-
Al(OH)4- + OD- + OD- + OT- + [18O]H- = AlODODOT[18O]H- + 4OH-
Al(OH)4- + OD- + OD- + [18O]H- + OH- = AlODOD[18O]HOH- + 4OH-
Al(OH)4- + OD- + OD- + [18O]H- + OT- = AlODOD[18O]HOT- + 4OH-
Al(OH)4- + OD- + OD- + [18O]H- + [18O]H- = AlODOD[18O]H[18O]H- + 4OH-
Al(OH)4- + OD- + OD- + [18O]T- + OH- = AlODOD[18O]TOH- + 4OH-
Al(OH)4- + OD- + OT- + OH- + OH- = AlODOTOHOH- + 4OH-
Al(OH)4- + OD- + OT- + OH- + OD- = AlODOTOHOD- + 4OH-
Al(OH)4- + OD- + OT- + OH- + [18O]H- = AlODOTOH[18O]H- + 4OH-
Al(OH)4- + OD- + OT- + OH- + [18O]D- = AlODOTOH[18O]D- + 4OH-
Al(OH)4- + OD- + OT- + OD- + OH- = AlODOTODOH- + 4OH-
Al(OH)4- + OD- + OT- + OD- + [18O]H- = AlODOTOD[18O]H- + 4OH-
Al(OH)4- + OD- + OT- + [18O]H- + OH- = AlODOT[18O]HOH- + 4OH-
Al(OH)4- + OD- + OT- + [18O]H- + OD- = AlODOT[18O]HOD- + 4OH-
Al(OH)4- + OD- + OT- + [18O]H- + [18O]H- = AlODOT[18O]H[18O]H- + 4OH-
Al(OH)4- + OD- + OT- + [18O]D- + OH- = AlODOT[18O]DOH- + 4OH-
Al(OH)4- + OD- + [18O]H- + OH- + OH- = AlOD[18O]HOHOH- + 4OH-
Al(OH)4- + OD- + [18O]H- + OH- + OD- = AlOD[18O]HOHOD- + 4OH-
Al(OH)4- + OD- + [18O]H- + OH- + OT- = AlOD[18O]HOHOT- + 4OH-
Al(OH)4- + OD- + [18O]H- + OH- + [18O]H- = AlOD[18O]HOH[18O]H- + 4OH-
Al(OH)4- + OD- + [18O]H- + OH- + [18O]D- = AlOD[18O]HOH[18O]D- + 4OH-
Al(OH)4- + OD- + [18O]H- + OH- + [18O]T- = AlOD[18O]HOH[18O]T- + 4OH-
Al(OH)4- + OD- + [18O]H- + OD- + OH- = AlOD[18O]HODOH- + 4OH-
Al(OH)4- + OD- + [18O]H- + OD- + OT- = AlOD[18O]HODOT- + 4OH-
Al(OH)4- + OD- + [18O]H- + OD- + [18O]H- = AlOD[18O]HOD[18O]H- + 4OH-
Al(OH)4- + OD- + [18O]H- + OT- + OH- = AlOD[18O]HOTOH- + 4OH-
Al(OH)4- + OD- + [18O]H- + OT- + OD- = AlOD[18O]HOTOD- + 4OH-
Al(OH)4- + OD- + [18O]H- + OT- + [18O]H- = AlOD[18O]HOT[18O]H- + 4OH-
Al(OH)4- + OD- + [18O]H- + [18O]H- + OH- = AlOD[18O]H[18O]HOH- + 4OH-
Al(OH)4- + OD- + [18O]H- + [18O]H- + OD- = AlOD[18O]H[18O]HOD- + 4OH-
Al(OH)4- + OD- + [18O]H- + [18O]H- + OT- = AlOD[18O]H[18O]HOT- + 4OH-
Al(OH)4- + OD- + [18O]H- + [18O]D- + OH- = AlOD[18O]H[18O]DOH- + 4OH-
Al(OH)4- + OD- + [18O]H- + [18O]T- + OH- = AlOD[18O]H[18O]TOH- + 4OH-
Al(OH)4- + OD- + [18O]D- + OH- + OH- = AlOD[18O]DOHOH- + 4OH-
Al(OH)4- + OD- + [18O]D- + OH- + OT- = AlOD[18O]DOHOT- + 4OH-
Al(OH)4- + OD- + [18O]D- + OH- + [18O]H- = AlOD[18O]DOH[18O]H- + 4OH-
Al(OH)4- + OD- + [18O]D- + OT- + OH- = AlOD[18O]DOTOH- + 4OH-
Al(OH)4- + OD- + [18O]D- + [18O]H- + OH- = AlOD[18O]D[18O]HOH- + 4OH-
Al(OH)4- + OD- + [18O]T- + OH- + OH- = AlOD[18O]TOHOH- + 4OH-
Al(OH)4- + OD- + [18O]T- + OH- + OD- = AlOD[18O]TOHOD- + 4OH-
Al(OH)4- + OD- + [18O]T- + OH- + [18O]H- = AlOD[18O]TOH[18O]H- + 4OH-
Al(OH)4- + OD- + [18O]T- + OD- + OH- = AlOD[18O]TODOH- + 4OH-
Al(OH)4- + OD- + [18O]T- + [18O]H- + OH- = AlOD[18O]T[18O]HOH- + 4OH-
Al(OH)4- + OT- + OH- + OH- + OH- = AlOTOHOHOH- + 4OH-
Al(OH)4- + OT- + OH- + OH- + OD- = AlOTOHOHOD- + 4OH-
Al(OH)4- + OT- + OH- + OH- + [18O]H- = AlOTOHOH[18O]H- + 4OH-
Al(OH)4- + OT- + OH- + OH- + [18O]D- = AlOTOHOH[18O]D- + 4OH-
Al(OH)4- + OT- + OH- + OD- + OH- = AlOTOHODOH- + 4OH-
Al(OH)4- + OT- + OH- + OD- + OD- = AlOTOHODOD- + 4OH-
Al(OH)4- + OT- + OH- + OD- + [18O]H- = AlOTOHOD[18O]H- + 4OH-
Al(OH)4- + OT- + OH- + OD- + [18O]D- = AlOTOHOD[18O]D- + 4OH-
Al(OH)4- + OT- + OH- + [18O]H- + OH- = AlOTOH[18O]HOH- + 4OH-
Al(OH)4- + OT- + OH- + [18O]H- + OD- = AlOTOH[18O]HOD- + 4OH-
Al(OH)4- + OT- + OH- + [18O]H- + [18O]H- = AlOTOH[18O]H[18O]H- + 4OH-
Al(OH)4- + OT- + OH- + [18O]H- + [18O]D- = AlOTOH[18O]H[18O]D- + 4OH-
Al(OH)4- + OT- + OH- + [18O]D- + OH- = AlOTOH[18O]DOH- + 4OH-
Al(OH)4- + OT- + OH- + [18O]D- + OD- = AlOTOH[18O]DOD- + 4OH-
Al(OH)4- + OT- + OH- + [18O]D- + [18O]H- = AlOTOH[18O]D[18O]H- + 4OH-
Al(OH)4- + OT- + OD- + OH- + OH- = AlOTODOHOH- + 4OH-
Al(OH)4- + OT- + OD- + OH- + OD- = AlOTODOHOD- + 4OH-
Al(OH)4- + OT- + OD- + OH- + [18O]H- = AlOTODOH[18O]H- + 4OH-
Al(OH)4- + OT- + OD- + OH- + [18O]D- = AlOTODOH[18O]D- + 4OH-
Al(OH)4- + OT- + OD- + OD- + OH- = AlOTODODOH- + 4OH-
Al(OH)4- + OT- + OD- + OD- + [18O]H- = AlOTODOD[18O]H- + 4OH-
Al(OH)4- + OT- + OD- + [18O]H- + OH- = AlOTOD[18O]HOH- + 4OH-
Al(OH)4- + OT- + OD- + [18O]H- + OD- = AlOTOD[18O]HOD- + 4OH-
Al(OH)4- + OT- + OD- + [18O]H- + [18O]H- = AlOTOD[18O]H[18O]H- + 4OH-
Al(OH)4- + OT- + OD- + [18O]D- + OH- = AlOTOD[18O]DOH- + 4OH-
Al(OH)4- + OT- + [18O]H- + OH- + OH- = AlOT[18O]HOHOH- + 4OH-
Al(OH)4- + OT- + [18O]H- + OH- + OD- = AlOT[18O]HOHOD- + 4OH-
Al(OH)4- + OT- + [18O]H- + OH- + [18O]H- = AlOT[18O]HOH[18O]H- + 4OH-
Al(OH)4- + OT- + [18O]H- + OH- + [18O]D- = AlOT[18O]HOH[18O]D- + 4OH-
Al(OH)4- + OT- + [18O]H- + OD- + OH- = AlOT[18O]HODOH- + 4OH-
Al(OH)4- + OT- + [18O]H- + OD- + OD- = AlOT[18O]HODOD- + 4OH-
Al(OH)4- + OT- + [18O]H- + OD- + [18O]H- = AlOT[18O]HOD[18O]H- + 4OH-
Al(OH)4- + OT- + [18O]H- + [18O]H- + OH- = AlOT[18O]H[18O]HOH- + 4OH-
Al(OH)4- + OT- + [18O]H- + [18O]H- + OD- = AlOT[18O]H[18O]HOD- + 4OH-
Al(OH)4- + OT- + [18O]H- + [18O]D- + OH- = AlOT[18O]H[18O]DOH- + 4OH-
Al(OH)4- + OT- + [18O]D- + OH- + OH- = AlOT[18O]DOHOH- + 4OH-
Al(OH)4- + OT- + [18O]D- + OH- + OD- = AlOT[18O]DOHOD- + 4OH-
Al(OH)4- + OT- + [18O]D- + OH- + [18O]H- = AlOT[18O]DOH[18O]H- + 4OH-
Al(OH)4- + OT- + [18O]D- + OD- + OH- = AlOT[18O]DODOH- + 4OH-
Al(OH)4- + OT- + [18O]D- + [18O]H- + OH- = AlOT[18O]D[18O]HOH- + 4OH-
Al(OH)4- + [18O]H- + OH- + OH- + OH- = Al[18O]HOHOHOH- + 4OH-
Al(OH)4- + [18O]H- + OH- + OH- + OD- = Al[18O]HOHOHOD- + 4OH-
Al(OH)4- + [18O]H- + OH- + OH- + OT- = Al[18O]HOHOHOT- + 4OH-
Al(OH)4- + [18O]H- + OH- + OH- + [18O]H- = Al[18O]HOHOH[18O]H- + 4OH-
Al(OH)4- + [18O]H- + OH- + OH- + [18O]D- = Al[18O]HOHOH[18O]D- + 4OH-
Al(OH)4- + [18O]H- + OH- + OH- + [18O]T- = Al[18O]HOHOH[18O]T- + 4OH-
Al(OH)4- + [18O]H- + OH- + OD- + OH- = Al[18O]HOHODOH- + 4OH-
Al(OH)4- + [18O]H- + OH- + OD- + OD- = Al[18O]HOHODOD- + 4OH-
Al(OH)4- + [18O]H- + OH- + OD- + OT- = Al[18O]HOHODOT- + 4OH-
Al(OH)4- + [18O]H- + OH- + OD- + [18O]H- = Al[18O]HOHOD[18O]H- + 4OH-
Al(OH)4- + [18O]H- + OH- + OD- + [18O]D- = Al[18O]HOHOD[18O]D- + 4OH-
Al(OH)4- + [18O]H- + OH- + OD- + [18O]T- = Al[18O]HOHOD[18O]T- + 4OH-
Al(OH)4- + [18O]H- + OH- + OT- + OH- = Al[18O]HOHOTOH- + 4OH-
Al(OH)4- + [18O]H- + OH- + OT- + OD- = Al[18O]HOHOTOD- + 4OH-
Al(OH)4- + [18O]H- + OH- + OT- + [18O]H- = Al[18O]HOHOT[18O]H- + 4OH-
Al(OH)4- + [18O]H- + OH- + OT- + [18O]D- = Al[18O]HOHOT[18O]D- + 4OH-
Al(OH)4- + [18O]H- + OH- + [18O]H- + OH- = Al[18O]HOH[18O]HOH- + 4OH-
Al(OH)4- + [18O]H- + OH- + [18O]H- + OD- = Al[18O]HOH[18O]HOD- + 4OH-
Al(OH)4- + [18O]H- + OH- + [18O]H- + OT- = Al[18O]HOH[18O]HOT- + 4OH-
Al(OH)4- + [18O]H- + OH- + [18O]D- + OH- = Al[18O]HOH[18O]DOH- + 4OH-
Al(OH)4- + [18O]H- + OH- + [18O]D- + OD- = Al[18O]HOH[18O]DOD- + 4OH-
Al(OH)4- + [18O]H- + OH- + [18O]D- + OT- = Al[18O]HOH[18O]DOT- + 4OH-
Al(OH)4- + [18O]H- + OH- + [18O]T- + OH- = Al[18O]HOH[18O]TOH- + 4OH-
Al(OH)4- + [18O]H- + OH- + [18O]T- + OD- = Al[18O]HOH[18O]TOD- + 4OH-
Al(OH)4- + [18O]H- + OD- + OH- + OH- = Al[18O]HODOHOH- + 4OH-
Al(OH)4- + [18O]H- + OD- + OH- + OD- = Al[18O]HODOHOD- + 4OH-
Al(OH)4- + [18O]H- + OD- + OH- + OT- = Al[18O]HODOHOT- + 4OH-
Al(OH)4- + [18O]H- + OD- + OH- + [18O]H- = Al[18O]HODOH[18O]H- + 4OH-
Al(OH)4- + [18O]H- + OD- + OH- + [18O]D- = Al[18O]HODOH[18O]D- + 4OH-
Al(OH)4- + [18O]H- + OD- + OH- + [18O]T- = Al[18O]HODOH[18O]T- + 4OH-
Al(OH)4- + [18O]H- + OD- + OD- + OH- = Al[18O]HODODOH- + 4OH-
Al(OH)4- + [18O]H- + OD- + OD- + OT- = Al[18O]HODODOT- + 4OH-
Al(OH)4- + [18O]H- + OD- + OD- + [18O]H- = Al[18O]HODOD[18O]H- + 4OH-
Al(OH)4- + [18O]H- + OD- + OT- + OH- = Al[18O]HODOTOH- + 4OH-
Al(OH)4- + [18O]H- + OD- + OT- + OD- = Al[18O]HODOTOD- + 4OH-
Al(OH)4- + [18O]H- + OD- + OT- + [18O]H- = Al[18O]HODOT[18O]H- + 4OH-
Al(OH)4- + [18O]H- + OD- + [18O]H- + OH- = Al[18O]HOD[18O]HOH- + 4OH-
Al(OH)4- + [18O]H- + OD- + [18O]H- + OD- = Al[18O]HOD[18O]HOD- + 4OH-
Al(OH)4- + [18O]H- + OD- + [18O]H- + OT- = Al[18O]HOD[18O]HOT- + 4OH-
Al(OH)4- + [18O]H- + OD- + [18O]D- + OH- = Al[18O]HOD[18O]DOH- + 4OH-
Al(OH)4- + [18O]H- + OD- + [18O]T- + OH- = Al[18O]HOD[18O]TOH- + 4OH-
Al(OH)4- + [18O]H- + OT- + OH- + OH- = Al[18O]HOTOHOH- + 4OH-
Al(OH)4- + [18O]H- + OT- + OH- + OD- = Al[18O]HOTOHOD- + 4OH-
Al(OH)4- + [18O]H- + OT- + OH- + [18O]H- = Al[18O]HOTOH[18O]H- + 4OH-
Al(OH)4- + [18O]H- + OT- + OH- + [18O]D- = Al[18O]HOTOH[18O]D- + 4OH-
Al(OH)4- + [18O]H- + OT- + OD- + OH- = Al[18O]HOTODOH- + 4OH-
Al(OH)4- + [18O]H- + OT- + OD- + OD- = Al[18O]HOTODOD- + 4OH-
Al(OH)4- + [18O]H- + OT- + OD- + [18O]H- = Al[18O]HOTOD[18O]H- + 4OH-
Al(OH)4- + [18O]H- + OT- + [18O]H- + OH- = Al[18O]HOT[18O]HOH- + 4OH-
Al(OH)4- + [18O]H- + OT- + [18O]H- + OD- = Al[18O]HOT[18O]HOD- + 4OH-
Al(OH)4- + [18O]H- + OT- + [18O]D- + OH- = Al[18O]HOT[18O]DOH- + 4OH-
Al(OH)4- + [18O]H- + [18O]H- + OH- + OH- = Al[18O]H[18O]HOHOH- + 4OH-
Al(OH)4- + [18O]H- + [18O]H- + OH- + OD- = Al[18O]H[18O]HOHOD- + 4OH-
Al(OH)4- + [18O]H- + [18O]H- + OH- + OT- = Al[18O]H[18O]HOHOT- + 4OH-
Al(OH)4- + [18O]H- + [18O]H- + OD- + OH- = Al[18O]H[18O]HODOH- + 4OH-
Al(OH)4- + [18O]H- + [18O]H- + OD- + OD- = Al[18O]H[18O]HODOD- + 4OH-
Al(OH)4- + [18O]H- + [18O]H- + OD- + OT- = Al[18O]H[18O]HODOT- + 4OH-
Al(OH)4- + [18O]H- + [18O]H- + OT- + OH- = Al[18O]H[18O]HOTOH- + 4OH-
Al(OH)4- + [18O]H- + [18O]H- + OT- + OD- = Al[18O]H[18O]HOTOD- + 4OH-
Al(OH)4- + [18O]H- + [18O]D- + OH- + OH- = Al[18O]H[18O]DOHOH- + 4OH-
Al(OH)4- + [18O]H- + [18O]D- + OH- + OD- = Al[18O]H[18O]DOHOD- + 4OH-
Al(OH)4- + [18O]H- + [18O]D- + OH- + OT- = Al[18O]H[18O]DOHOT- + 4OH-
Al(OH)4- + [18O]H- + [18O]D- + OD- + OH- = Al[18O]H[18O]DODOH- + 4OH-
Al(OH)4- + [18O]H- + [18O]D- + OT- + OH- = Al[18O]H[18O]DOTOH- + 4OH-
Al(OH)4- + [18O]H- + [18O]T- + OH- + OH- = Al[18O]H[18O]TOHOH- + 4OH-
Al(OH)4- + [18O]H- + [18O]T- + OH- + OD- = Al[18O]H[18O]TOHOD- + 4OH-
Al(OH)4- + [18O]H- + [18O]T- + OD- + OH- = Al[18O]H[18O]TODOH- + 4OH-
Al(OH)4- + [18O]D- + OH- + OH- + OH- = Al[18O]DOHOHOH- + 4OH-
Al(OH)4- + [18O]D- + OH- + OH- + OD- = Al[18O]DOHOHOD- + 4OH-
Al(OH)4- + [18O]D- + OH- + OH- + OT- = Al[18O]DOHOHOT- + 4OH-
Al(OH)4- + [18O]D- + OH- + OH- + [18O]H- = Al[18O]DOHOH[18O]H- + 4OH-
Al(OH)4- + [18O]D- + OH- + OH- + [18O]D- = Al[18O]DOHOH[18O]D- + 4OH-
Al(OH)4- + [18O]D- + OH- + OH- + [18O]T- = Al[18O]DOHOH[18O]T- + 4OH-
Al(OH)4- + [18O]D- + OH- + OD- + OH- = Al[18O]DOHODOH- + 4OH-
Al(OH)4- + [18O]D- + OH- + OD- + OT- = Al[18O]DOHODOT- + 4OH-
Al(OH)4- + [18O]D- + OH- + OD- + [18O]H- = Al[18O]DOHOD[18O]H- + 4OH-
Al(OH)4- + [18O]D- + OH- + OT- + OH- = Al[18O]DOHOTOH- + 4OH-
Al(OH)4- + [18O]D- + OH- + OT- + OD- = Al[18O]DOHOTOD- + 4OH-
Al(OH)4- + [18O]D- + OH- + OT- + [18O]H- = Al[18O]DOHOT[18O]H- + 4OH-
Al(OH)4- + [18O]D- + OH- + [18O]H- + OH- = Al[18O]DOH[18O]HOH- + 4OH-
Al(OH)4- + [18O]D- + OH- + [18O]H- + OD- = Al[18O]DOH[18O]HOD- + 4OH-
Al(OH)4- + [18O]D- + OH- + [18O]H- + OT- = Al[18O]DOH[18O]HOT- + 4OH-
Al(OH)4- + [18O]D- + OH- + [18O]D- + OH- = Al[18O]DOH[18O]DOH- + 4OH-
Al(OH)4- + [18O]D- + OH- + [18O]T- + OH- = Al[18O]DOH[18O]TOH- + 4OH-
Al(OH)4- + [18O]D- + OD- + OH- + OH- = Al[18O]DODOHOH- + 4OH-
Al(OH)4- + [18O]D- + OD- + OH- + OT- = Al[18O]DODOHOT- + 4OH-
Al(OH)4- + [18O]D- + OD- + OH- + [18O]H- = Al[18O]DODOH[18O]H- + 4OH-
Al(OH)4- + [18O]D- + OD- + OT- + OH- = Al[18O]DODOTOH- + 4OH-
Al(OH)4- + [18O]D- + OD- + [18O]H- + OH- = Al[18O]DOD[18O]HOH- + 4OH-
Al(OH)4- + [18O]D- + OT- + OH- + OH- = Al[18O]DOTOHOH- + 4OH-
Al(OH)4- + [18O]D- + OT- + OH- + OD- = Al[18O]DOTOHOD- + 4OH-
Al(OH)4- + [18O]D- + OT- + OH- + [18O]H- = Al[18O]DOTOH[18O]H- + 4OH-
Al(OH)4- + [18O]D- + OT- + OD- + OH- = Al[18O]DOTODOH- + 4OH-
Al(OH)4- + [18O]D- + OT- + [18O]H- + OH- = Al[18O]DOT[18O]HOH- + 4OH-
Al(OH)4- + [18O]D- + [18O]H- + OH- + OH- = Al[18O]D[18O]HOHOH- + 4OH-
Al(OH)4- + [18O]D- + [18O]H- + OH- + OD- = Al[18O]D[18O]HOHOD- + 4OH-
Al(OH)4- + [18O]D- + [18O]H- + OH- + OT- = Al[18O]D[18O]HOHOT- + 4OH-
Al(OH)4- + [18O]D- + [18O]H- + OD- + OH- = Al[18O]D[18O]HODOH- + 4OH-
Al(OH)4- + [18O]D- + [18O]H- + OT- + OH- = Al[18O]D[18O]HOTOH- + 4OH-
Al(OH)4- + [18O]D- + [18O]D- + OH- + OH- = Al[18O]D[18O]DOHOH- + 4OH-
Al(OH)4- + [18O]D- + [18O]T- + OH- + OH- = Al[18O]D[18O]TOHOH- + 4OH-
Al(OH)4- + [18O]T- + OH- + OH- + OH- = Al[18O]TOHOHOH- + 4OH-
Al(OH)4- + [18O]T- + OH- + OH- + OD- = Al[18O]TOHOHOD- + 4OH-
Al(OH)4- + [18O]T- + OH- + OH- + [18O]H- = Al[18O]TOHOH[18O]H- + 4OH-
Al(OH)4- + [18O]T- + OH- + OH- + [18O]D- = Al[18O]TOHOH[18O]D- + 4OH-
Al(OH)4- + [18O]T- + OH- + OD- + OH- = Al[18O]TOHODOH- + 4OH-
Al(OH)4- + [18O]T- + OH- + OD- + OD- = Al[18O]TOHODOD- + 4OH-
Al(OH)4- + [18O]T- + OH- + OD- + [18O]H- = Al[18O]TOHOD[18O]H- + 4OH-
Al(OH)4- + [18O]T- + OH- + [18O]H- + OH- = Al[18O]TOH[18O]HOH- + 4OH-
Al(OH)4- + [18O]T- + OH- + [18O]H- + OD- = Al[18O]TOH[18O]HOD- + 4OH-
Al(OH)4- + [18O]T- + OH- + [18O]D- + OH- = Al[18O]TOH[18O]DOH- + 4OH-
Al(OH)4- + [18O]T- + OD- + OH- + OH- = Al[18O]TODOHOH- + 4OH-
Al(OH)4- + [18O]T- + OD- + OH- + OD- = Al[18O]TODOHOD- + 4OH-
Al(OH)4- + [18O]T- + OD- + OH- + [18O]H- = Al[18O]TODOH[18O]H- + 4OH-
Al(OH)4- + [18O]T- + OD- + OD- + OH- = Al[18O]TODODOH- + 4OH-
Al(OH)4- + [18O]T- + OD- + [18O]H- + OH- = Al[18O]TOD[18O]HOH- + 4OH-
Al(OH)4- + [18O]T- + [18O]H- + OH- + OH- = Al[18O]T[18O]HOHOH- + 4OH-
Al(OH)4- + [18O]T- + [18O]H- + OH- + OD- = Al[18O]T[18O]HOHOD- + 4OH-
Al(OH)4- + [18O]T- + [18O]H- + OD- + OH- = Al[18O]T[18O]HODOH- + 4OH-
Al(OH)4- + [18O]T- + [18O]D- + OH- + OH- = Al[18O]T[18O]DOHOH- + 4OH-
#
# Added AlSO4+ reactions 16Dec09
#
AlSO4+ + [34S]O4-2 = Al[34S]O4+ + SO4-2
#
# Added Al(SO4)2- reactions 16Dec09
# Revised 17Dec09, limited the number of species
#
Al(SO4)2- + SO4-2 + [34S]O4-2 = AlSO4[34S]O4- + 2SO4-2
Al(SO4)2- + [34S]O4-2 + SO4-2 = Al[34S]O4SO4- + 2SO4-2
Al(SO4)2- + [34S]O4-2 + [34S]O4-2 = Al[34S]O4[34S]O4- + 2SO4-2
#
# Added AlHSO4+2 reactions 16Dec09
#
AlHSO4+2 + DSO4- = AlDSO4+2 + HSO4-
AlHSO4+2 + TSO4- = AlTSO4+2 + HSO4-
AlHSO4+2 + H[34S]O4- = AlH[34S]O4+2 + HSO4-
AlHSO4+2 + D[34S]O4- = AlD[34S]O4+2 + HSO4-
AlHSO4+2 + T[34S]O4- = AlT[34S]O4+2 + HSO4-
#
# Missing H4SiO4 reactions
#
#
# Missing H3SiO4- reactions
#
#
# Missing H2SiO4-2 reactions
#
###############################################################################################
PHASES
###############################################################################################
#
# Water vapor - Water
# last update March 20, 2006
# Updated September 19, 2006
# Checked September 19, 2006
#
HDO(g)
HDO(g) + H2O(l) = H2O(g) + HDO(aq)
-add_logk Log_alpha_D_H2O(g)/H2O(l) -1.0
HTO(g)
HTO(g) + H2O(l) = H2O(g) + HTO(aq)
-add_logk Log_alpha_T_H2O(g)/H2O(l) -1.0
DTO(g)
DTO(g) + H2O(g) = HDO(g) + HTO(g)
log_k 0.301029995663 # log10(2)
D2O(g)
D2O(g) + H2O(g) = 2HDO(g)
log_k 0.602059991327962396 # log10(4)
T2O(g)
T2O(g) + H2O(g) = 2HTO(g)
log_k 0.602059991327962396 # log10(4)
H2[18O](g)
H2[18O](g) + H2O(l) = H2O(g) + H2[18O](aq)
-add_logk Log_alpha_18O_H2O(g)/H2O(l) -1.0
HD[18O](g)
HD[18O](g) + H2O(g) = HDO(g) + H2[18O](g)
log_k 0.0
HT[18O](g)
HT[18O](g) + H2O(g) = HTO(g) + H2[18O](g)
log_k 0.0
D2[18O](g)
D2[18O](g) + H2O(g) = D2O(g) + H2[18O](g)
log_k 0.0
T2[18O](g)
T2[18O](g) + H2O(g) = T2O(g) + H2[18O](g)
log_k 0.0
DT[18O](g)
DT[18O](g) + H2O(g) = DTO(g) + H2[18O](g)
log_k 0.0
#
# O2 gas - O2 aqueous
# last update March 20, 2006
# Updated September 19, 2006
# Checked September 19, 2006
#
O[18O](g)
O[18O](g) + H2O(l) = O2(g) + H2[18O](aq)
## symmetry K ??
-add_logk Log_alpha_18O_O2(g)/H2O(l) -1.0
[18O]2(g)
[18O]2(g) + O2(g) = 2O[18O](g)
log_k 0.602059991327962396 # log10(4)
#
# H2 gas - H2 aqueous
# last update March 20, 2006
# Updated September 19, 2006
# Checked September 19, 2006
#
HD(g)
HD(g) + H2O(l) = H2(g) + HDO(aq)
-add_logk Log_alpha_D_H2(g)/H2O(l) -1.0
HT(g)
HT(g) + H2O(l) = H2(g) + HTO(aq)
-add_logk Log_alpha_T_H2(g)/H2O(l) -1.0
D2(g)
D2(g) + H2(g) = 2HD(g)
log_k 0.602059991327962396 # log10(4)
T2(g)
T2(g) + H2(g) = 2HT(g)
log_k 0.602059991327962396 # log10(4)
DT(g)
DT(g) + H2(g) = HD(g) + HT(g)
log_k 0.301029995663 # log10(2)
#
# CO2 gas - CO2 aqueous
# last update March 20, 2006
# Updated September 19, 2006
# Checked September 19, 2006
#
CO[18O](g)
CO[18O](g) + H2O(l) = H2[18O](aq) + CO2(g)
log_k -0.301029995663 # -log10(2)
-add_logk Log_alpha_18O_CO2(g)/H2O(l) -1.0
C[18O]2(g)
C[18O]2(g) + CO2(g) = 2CO[18O](g)
log_k 0.602059991327962396 # log10(4)
[13C]O2(g)
[13C]O2(g) + CO2(aq) = [13C]O2(aq) + CO2(g)
-add_logk Log_alpha_13C_CO2(g)/CO2(aq) -1.0
[13C]O[18O](g)
[13C]O[18O](g) + CO2(g) = [13C]O2(g) + CO[18O](g)
log_k 0
[13C][18O]2(g)
[13C][18O]2(g) + CO2(g) = C[18O]2(g) + [13C]O2(g)
log_k 0
[14C]O2(g)
[14C]O2(g) + CO2(aq) = [14C]O2(aq) + CO2(g)
-add_logk Log_alpha_14C_CO2(g)/CO2(aq) -1.0
[14C]O[18O](g)
[14C]O[18O](g) + CO2(g) = [14C]O2(g) + CO[18O](g)
log_k 0
[14C][18O]2(g)
[14C][18O]2(g) + CO2(g) = [14C]O2(g) + C[18O]2(g)
log_k 0
#
# Calcite
# last update Feb 13, 2006
# Updated September 19, 2006
# Checked September 19, 2006
#
CaCO2[18O](s)
CaCO2[18O](s) + H2O(l) = H2[18O](aq) + Calcite(s)
log_k -0.477121254719 # -log10(3) ???
-add_logk Log_alpha_18O_Calcite/H2O(l) -1.0
CaCO[18O]2(s)
CaCO[18O]2(s) + Calcite(s) = 2CaCO2[18O](s)
log_k 0.477121254719 # log10(3)
CaC[18O]3(s)
CaC[18O]3(s) + 2Calcite(s) = 3CaCO2[18O](s)
log_k 1.431363764158 # log10(27)
Ca[13C]O3(s)
Ca[13C]O3(s) + CO2 = [13C]O2 + Calcite(s)
-add_logk Log_alpha_13C_Calcite/CO2(aq) -1.0
Ca[13C]O2[18O](s)
Ca[13C]O2[18O](s) + Calcite(s) = Ca[13C]O3(s) + CaCO2[18O](s)
log_k 0
Ca[13C]O[18O]2(s)
Ca[13C]O[18O]2(s) + Calcite(s) = Ca[13C]O3(s) + CaCO[18O]2(s)
log_k 0
Ca[13C][18O]3(s)
Ca[13C][18O]3(s) + Calcite(s) = Ca[13C]O3(s) + CaC[18O]3(s)
log_k 0
Ca[14C]O3(s)
Ca[14C]O3(s) + CO2 = Calcite(s) + [14C]O2
-add_logk Log_alpha_14C_Calcite/CO2(aq) -1.0
Ca[14C]O2[18O](s)
Ca[14C]O2[18O](s) + Calcite(s) = Ca[14C]O3(s) + CaCO2[18O](s)
log_k 0
Ca[14C]O[18O]2(s)
Ca[14C]O[18O]2(s) + Calcite(s) = Ca[14C]O3(s) + CaCO[18O]2(s)
log_k 0
Ca[14C][18O]3(s)
Ca[14C][18O]3(s) + Calcite(s) = Ca[14C]O3(s) + CaC[18O]3(s)
log_k 0
#
# Pyrite, March 20, 2006
# Update September 28, 2006
# Checked September 28, 2006
#
Pyrite_FeS[34S]
FeS[34S](s) + HS- = Pyrite(s) + H[34S]-
-add_logk Log_alpha_34S_Pyrite/HS- -1.0
Pyrite_Fe[34S]S
Fe[34S]S(s) = Pyrite_FeS[34S](s)
Pyrite_Fe[34S]2
Fe[34S]2(s) + Pyrite(s) = 2Pyrite_FeS[34S](s)
#
# CH4 reactions
# last update March 20, 2006
# Updated September 19, 2006
# Checked September 19, 2006
#
CH3D(g)
CH3D(g) + H2O(l) = CH4(g) + HDO(aq)
log_k -0.301029995663 # -log10(2) ???
-add_logk Log_alpha_D_CH4(g)/H2O(l) -1.0
CH2D2(g)
CH2D2(g) + CH4(g) = 2CH3D(g)
log_k 0.42596873227228 # log10(8/3)
CHD3(g)
CHD3(g) + 2CH4(g) = 3CH3D(g)
log_k 1.20411998265 # log10(16)
CD4(g)
CD4(g) + 3CH4(g) = 4CH3D(g)
log_k 2.408239965311 # log10(256)
CH3T(g)
CH3T(g) + H2O(l) = CH4(g) + HTO(aq)
log_k -0.301029995663 # -log10(2) ???
-add_logk Log_alpha_T_CH4(g)/H2O(l) -1.0
CH2T2(g)
CH2T2(g) + CH4(g) = 2CH3T(g)
log_k 0.42596873227228 # log10(8/3)
CHT3(g)
CHT3(g) + 2CH4(g) = 3CH3T(g)
log_k 1.20411998265 # log10(16)
CT4(g)
CT4(g) + 3CH4(g) = 4CH3T(g)
log_k 2.408239965311 # log10(256)
CD3T(g)
CD3T(g) + CH4(g) = CHD3(g) + CH3T(g)
log_k 0.602059991327962396 # log10(4)
CD2T2(g)
CD2T2(g) + CH4(g) = CH2D2(g) + CH2T2(g)
log_k 0.7781512503836 # log10(6)
CDT3(g)
CDT3(g) + CH4(g) = CHT3(g) + CH3D(g)
log_k 0.602059991327962396 # log10(4)
[13C]H4(g)
[13C]H4(g) + CO2(aq) = [13C]O2(aq) + CH4(g)
-add_logk Log_alpha_13C_CH4(g)/CO2(aq) -1.0
[13C]H3D(g)
[13C]H3D(g) + CH4(g) = CH3D(g) + [13C]H4(g)
[13C]H2D2(g)
[13C]H2D2(g) + CH4(g) = CH2D2(g) + [13C]H4(g)
[13C]HD3(g)
[13C]HD3(g) + CH4(g) = CHD3(g) + [13C]H4(g)
[13C]D4(g)
[13C]D4(g) + CH4(g) = CD4(g) + [13C]H4(g)
[13C]H3T(g)
[13C]H3T(g) + CH4(g) = CH3T(g) + [13C]H4(g)
[13C]H2T2(g)
[13C]H2T2(g) + CH4(g) = CH2T2(g) + [13C]H4(g)
[13C]HT3(g)
[13C]HT3(g) + CH4(g) = CHT3(g) + [13C]H4(g)
[13C]T4(g)
[13C]T4(g) + CH4(g) = CT4(g) + [13C]H4(g)
[13C]D3T(g)
[13C]D3T(g) + CH4(g) = CD3T(g) + [13C]H4(g)
[13C]D2T2(g)
[13C]D2T2(g) + CH4(g) = CD2T2(g) + [13C]H4(g)
[13C]DT3(g)
[13C]DT3(g) + CH4(g) = CDT3(g) + [13C]H4(g)
[13C]T4(g)
[13C]T4(g) + CH4(g) = CT4(g) + [13C]H4(g)
[14C]H4(g)
[14C]H4(g) + CO2(aq) = [14C]O2(aq) + CH4(g)
-add_logk Log_alpha_14C_CH4(g)/CO2(aq) -1.0
[14C]H3D(g)
[14C]H3D(g) + CH4(g) = CH3D(g) + [14C]H4(g)
[14C]H2D2(g)
[14C]H2D2(g) + CH4(g) = CH2D2(g) + [14C]H4(g)
[14C]HD3(g)
[14C]HD3(g) + CH4(g) = CHD3(g) + [14C]H4(g)
[14C]D4(g)
[14C]D4(g) + CH4(g) = CD4(g) + [14C]H4(g)
[14C]H3T(g)
[14C]H3T(g) + CH4(g) = CH3T(g) + [14C]H4(g)
[14C]H2T2(g)
[14C]H2T2(g) + CH4(g) = CH2T2(g) + [14C]H4(g)
[14C]HT3(g)
[14C]HT3(g) + CH4(g) = CHT3(g) + [14C]H4(g)
[14C]T4(g)
[14C]T4(g) + CH4(g) = CT4(g) + [14C]H4(g)
[14C]D3T(g)
[14C]D3T(g) + CH4(g) = CD3T(g) + [14C]H4(g)
[14C]D2T2(g)
[14C]D2T2(g) + CH4(g) = CD2T2(g) + [14C]H4(g)
[14C]DT3(g)
[14C]DT3(g) + CH4(g) = CDT3(g) + [14C]H4(g)
[14C]T4(g)
[14C]T4(g) + CH4(g) = CT4(g) + [14C]H4(g)
#
# updated March 20, 2006
# Updated September 28, 2006
# Checked September 28, 2006
#
HDS(g)
HDS(g) + H2S(aq) = HDS(aq) + H2S(g)
-add_logk Log_alpha_D_H2S(g)/H2S(aq) -1.0
D2S(g)
D2S(g) + H2S(g) = 2HDS(g)
log_k 0.602059991327962396 # log10(4)
HTS(g)
HTS(g) + H2S(aq) = HTS(aq) + H2S(g)
-add_logk Log_alpha_T_H2S(g)/H2S(aq) -1.0
T2S(g)
T2S(g) + H2S(g) = 2HTS(g)
log_k 0.602059991327962396 # log10(4)
DTS(g)
DTS(g) + H2S(g) = HDS(g) + HTS(g)
log_k 0.301029995663 # log10(2)
H2[34S](g)
H2[34S](g) + H2S(aq) = H2[34S](aq) + H2S(g)
-add_logk Log_alpha_34S_H2S(g)/H2S(aq) -1.0
HD[34S](g)
HD[34S](g) + H2S(g) = HDS(g) + H2[34S](g)
D2[34S](g)
D2[34S](g) + H2S(g) = D2S(g) + H2[34S](g)
HT[34S](g)
HT[34S](g) + H2S(g) = HTS(g) + H2[34S](g)
T2[34S](g)
T2[34S](g) + H2S(g) = T2S(g) + H2[34S](g)
DT[34S](g)
DT[34S](g) + H2S(g) = DTS(g) + H2[34S](g)
#
# Gypsum and anhydrite
#
Ca[34S]O4:2H2O
Ca[34S]O4:2H2O + SO4-2 = [34S]O4-2 + Gypsum(s)
-add_logk Log_alpha_34S_Gypsum/SO4-2 -1.0
Ca[34S]O4
Ca[34S]O4 + SO4-2 = [34S]O4-2 + Anhydrite(s)
-add_logk Log_alpha_34S_Anhydrite/SO4-2 -1.0
#
# Nitrogen phases
# Checked September 19, 2006
#
N[15N](g)
N[15N](g) + N2(aq) = N[15N](aq) + N2(g)
-add_logk Log_alpha_15N_N2(g)/N2(aq) -1.0
[15N]2(g)
[15N]2(g) + N2(g) = 2N[15N](g)
log_k 0.602059991327962396 # log10(4)
NH2D(g)
NH2D(g) + H2O(l) = NH3(g) + HDO(aq)
## symmetry K??
-add_logk Log_alpha_D_NH3(g)/H2O(l) -1.0
NHD2(g)
NHD2(g) + NH3(g) = 2NH2D(g)
log_k 0.477121254719 # log10(3)
ND3(g)
ND3(g) + 2NH3(g) = 3NH2D(g)
-logk 1.431363764158 # log10(27)
NH2T(g)
NH2T(g) + H2O(l) = NH3(g) + HTO(aq)
## symmetry K??
-add_logk Log_alpha_T_NH3(g)/H2O(l) -1.0
NHT2(g)
NHT2(g) + NH3(g) = 2NH2T(g)
log_k 0.477121254719 # log10(3)
NT3(g)
NT3(g) + 2NH3(g) = 3NH2T(g)
-logk 1.431363764158 # log10(27)
ND2T(g)
ND2T(g) + NH3(g) = NHD2(g) + NH2T(g)
log_k 0.477121254719 # log10(3)
NDT2(g)
NDT2(g) + NH3(g) = NH2D(g) + NHT2(g)
log_k 0.477121254719 # log10(3)
[15N]H3(g)
[15N]H3(g) + NH3(aq) = [15N]H3(aq) + NH3(g)
-add_logk Log_alpha_15N_NH3(g)/NH3(aq) -1.0
[15N]H2D(g)
[15N]H2D(g) + NH3(g) = NH2D(g) + [15N]H3(g)
[15N]HD2(g)
[15N]HD2(g) + NH3(g) = NHD2(g) + [15N]H3(g)
[15N]D3(g)
[15N]D3(g) + NH3(g) = ND3(g) + [15N]H3(g)
[15N]H2T(g)
[15N]H2T(g) + NH3(g) = NH2T(g) + [15N]H3(g)
[15N]HT2(g)
[15N]HT2(g) + NH3(g) = NHT2(g) + [15N]H3(g)
[15N]T3(g)
[15N]T3(g) + NH3(g) = NT3(g) + [15N]H3(g)
[15N]D2T(g)
[15N]D2T(g) + NH3(g) = ND2T(g) + [15N]H3(g)
[15N]DT2(g)
[15N]DT2(g) + NH3(g) = NDT2(g) + [15N]H3(g)
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