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has test files only now. Will copy cpp branch here as src Phreeqc src will be subdirectory of src, like phast git-svn-id: svn://136.177.114.72/svn_GW/phreeqcpp/trunk@784 1feff8c3-07ed-0310-ac33-dd36852eb9cd
79 lines
2.0 KiB
Plaintext
79 lines
2.0 KiB
Plaintext
TITLE Example 12.--Advective and diffusive transport of heat and solutes.
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Constant boundary condition at one end, closed at other.
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The problem is designed so that temperature should equal Na-conc
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(in mmol/kgw) after diffusion.
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EXCHANGE_SPECIES
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Na+ + X- = NaX
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log_k 0.0
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-gamma 4.0 0.075
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H+ + X- = HX
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log_k -99.
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-gamma 9.0 0.0
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K+ + X- = KX
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log_k 0.0
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-gamma 3.5 0.015
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SOLUTION 0 24.0 mM KNO3
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units mol/kgw
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temp 0 # Incoming solution 0C
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pH 7.0
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pe 12.0 O2(g) -0.67
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K 24.e-3
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N(5) 24.e-3
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SOLUTION 1-20 0.001 mM KCl
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units mol/kgw
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temp 25 # Column is at 25C
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pH 7.0
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pe 12.0 O2(g) -0.67
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K 1e-6
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Cl 1e-6
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EXCHANGE 1-20
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KX 0.048
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TRANSPORT # Make column temperature 0C, displace Cl
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-cells 20
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-shifts 19
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-flow_d forward
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-bcon flux flux
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-length 1.0
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-disp 0.0 # No dispersion
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-diffc 0.0 # No diffusion
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-thermal_diffusion 1.0 # No retardation for heat
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PRINT
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-reset false
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-echo true
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END
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SOLUTION 0 Fixed temp 24C, and NaCl conc (first type boundary cond) at inlet
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units mol/kgw
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temp 24
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pH 7.0
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pe 12.0 O2(g) -0.67
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Na 24.e-3
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Cl 24.e-3
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SOLUTION 20 Same as soln 0 in cell 20 at closed column end (second type boundary cond)
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units mol/kgw
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temp 24
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pH 7.0
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pe 12.0 O2(g) -0.67
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Na 24.e-3
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Cl 24.e-3
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EXCHANGE 20
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NaX 0.048
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TRANSPORT # Diffuse 24C, NaCl solution from column end
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-shifts 1
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-flow_d diffusion
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-bcon constant closed
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-thermal_diffusion 3.0 # heat is retarded equal to Na
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-diffc 0.3e-9 # m^2/s
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-timest 1.0e+10 # 317 years, 19 substeps will be used
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SELECTED_OUTPUT
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-file ex12.sel
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-high_precision true
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-reset false
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-dist true
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-temp true
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USER_PUNCH
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-head Na_mmol K_mmol Cl_mmol
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10 PUNCH TOT("Na")*1000, TOT("K")*1000, TOT("Cl")*1000
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END
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